# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1441079'
_audit_update_record             
;
2015-12-08 deposited with the CCDC.
2016-02-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C56 H30 Eu2 N4 O16'
_chemical_formula_weight         1318.76

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.6136(6)
_cell_length_b                   13.4816(8)
_cell_length_c                   16.2810(11)
_cell_angle_alpha                89.934(5)
_cell_angle_beta                 78.409(5)
_cell_angle_gamma                71.845(5)
_cell_volume                     2367.6(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3939
_cell_measurement_theta_min      4.0990
_cell_measurement_theta_max      71.3660

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.850
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1296
_exptl_absorpt_coefficient_mu    19.480
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2731
_exptl_absorpt_correction_T_max  0.3048
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            14745
_diffrn_reflns_av_R_equivalents  0.0927
_diffrn_reflns_av_sigmaI/netI    0.1446
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         2.78
_diffrn_reflns_theta_max         67.02
_reflns_number_total             8435
_reflns_number_gt                5872
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0695P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8435
_refine_ls_number_parameters     704
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.1036
_refine_ls_R_factor_gt           0.0743
_refine_ls_wR_factor_ref         0.1981
_refine_ls_wR_factor_gt          0.1696
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.03398(5) 1.12891(4) 0.97083(4) 0.01781(17) Uani 1 1 d . . .
Eu2 Eu 0.03901(5) 0.34861(4) 0.47243(4) 0.02245(18) Uani 1 1 d . . .
C1 C 0.2407(15) 0.1978(13) 0.2988(10) 0.064(5) Uani 1 1 d . . .
H1 H 0.2275 0.2646 0.2796 0.077 Uiso 1 1 calc R . .
C2 C 0.316(2) 0.1150(12) 0.2466(11) 0.093(8) Uani 1 1 d . . .
H2 H 0.3541 0.1252 0.1928 0.112 Uiso 1 1 calc R . .
C3 C 0.3342(19) 0.0178(12) 0.2729(10) 0.081(6) Uani 1 1 d . . .
H3 H 0.3829 -0.0393 0.2362 0.097 Uiso 1 1 calc R . .
C4 C 0.2823(15) 0.0017(10) 0.3536(9) 0.054(4) Uani 1 1 d . . .
C5 C 0.2051(11) 0.0908(9) 0.4053(9) 0.038(3) Uani 1 1 d . . .
C6 C 0.1435(10) 0.0789(8) 0.4876(8) 0.033(3) Uani 1 1 d . . .
C7 C 0.1597(12) -0.0236(9) 0.5143(9) 0.041(3) Uani 1 1 d . . .
C8 C 0.2345(15) -0.1111(11) 0.4618(10) 0.061(4) Uani 1 1 d . . .
H8 H 0.2439 -0.1776 0.4809 0.074 Uiso 1 1 calc R . .
C9 C 0.2931(18) -0.1007(11) 0.3844(11) 0.073(5) Uani 1 1 d . . .
H9 H 0.3414 -0.1601 0.3499 0.088 Uiso 1 1 calc R . .
C10 C 0.0992(13) -0.0325(10) 0.5968(8) 0.043(3) Uani 1 1 d . . .
H10 H 0.1057 -0.0984 0.6166 0.052 Uiso 1 1 calc R . .
C11 C 0.0307(14) 0.0552(11) 0.6481(10) 0.053(4) Uani 1 1 d . . .
H11 H -0.0078 0.0499 0.7031 0.064 Uiso 1 1 calc R . .
C12 C 0.0201(13) 0.1553(11) 0.6149(8) 0.047(3) Uani 1 1 d . . .
H12 H -0.0260 0.2148 0.6498 0.056 Uiso 1 1 calc R . .
C13 C 0.3019(9) 0.4551(8) 0.5765(6) 0.021(2) Uani 1 1 d . . .
C14 C 0.4158(9) 0.3810(8) 0.5780(7) 0.027(2) Uani 1 1 d . . .
H14 H 0.4323 0.3122 0.5583 0.033 Uiso 1 1 calc R . .
C15 C 0.5039(10) 0.4089(9) 0.6085(8) 0.039(3) Uani 1 1 d . . .
H15 H 0.5800 0.3594 0.6095 0.047 Uiso 1 1 calc R . .
C16 C 0.4786(10) 0.5116(9) 0.6379(8) 0.037(3) Uani 1 1 d . . .
H16 H 0.5398 0.5302 0.6571 0.044 Uiso 1 1 calc R . .
C17 C 0.3645(9) 0.5881(9) 0.6398(6) 0.026(2) Uani 1 1 d . . .
C18 C 0.2778(9) 0.5583(8) 0.6066(6) 0.019(2) Uani 1 1 d U . .
C19 C 0.1603(9) 0.6389(8) 0.5980(7) 0.027(2) Uani 1 1 d . . .
C20 C 0.2102(9) 0.4169(8) 0.5424(7) 0.027(2) Uani 1 1 d . . .
C21 C 0.3442(9) 0.6954(8) 0.6703(7) 0.024(2) Uani 1 1 d . . .
C22 C 0.4078(11) 0.7563(9) 0.6222(7) 0.033(3) Uani 1 1 d . . .
H22 H 0.4639 0.7262 0.5726 0.040 Uiso 1 1 calc R . .
C23 C 0.3902(11) 0.8579(9) 0.6455(7) 0.032(3) Uani 1 1 d . . .
C24 C 0.4473(12) 0.9205(10) 0.5858(8) 0.043(3) Uani 1 1 d . . .
C25 C 0.3088(10) 0.9042(8) 0.7197(7) 0.031(3) Uani 1 1 d . . .
H25 H 0.2992 0.9727 0.7365 0.038 Uiso 1 1 calc R . .
C26 C 0.2423(8) 0.8495(7) 0.7684(7) 0.021(2) Uani 1 1 d . . .
C27 C 0.1511(9) 0.9017(9) 0.8482(7) 0.024(2) Uani 1 1 d . . .
C28 C 0.2582(9) 0.7465(8) 0.7422(7) 0.025(2) Uani 1 1 d . . .
H28 H 0.2097 0.7108 0.7738 0.030 Uiso 1 1 calc R . .
C29 C -0.1628(10) 1.2134(8) 0.8937(7) 0.029(2) Uani 1 1 d U . .
C30 C -0.2824(9) 1.1971(9) 0.8875(7) 0.026(2) Uani 1 1 d . . .
C31 C -0.3068(9) 1.1085(9) 0.9242(7) 0.028(2) Uani 1 1 d . . .
C32 C -0.2129(9) 1.0238(8) 0.9584(7) 0.026(2) Uani 1 1 d . . .
C33 C -0.4252(10) 1.0987(9) 0.9274(8) 0.036(3) Uani 1 1 d . . .
H33 H -0.4428 1.0403 0.9497 0.043 Uiso 1 1 calc R . .
C34 C -0.5148(11) 1.1743(10) 0.8981(9) 0.043(3) Uani 1 1 d . . .
H34 H -0.5936 1.1686 0.9029 0.051 Uiso 1 1 calc R . .
C35 C -0.4871(10) 1.2589(9) 0.8612(8) 0.037(3) Uani 1 1 d . . .
H35 H -0.5474 1.3087 0.8399 0.044 Uiso 1 1 calc R . .
C36 C -0.3721(10) 1.2711(9) 0.8551(7) 0.032(3) Uani 1 1 d . . .
C37 C -0.3535(9) 1.3701(8) 0.8227(7) 0.027(2) Uani 1 1 d . . .
C38 C -0.2580(9) 1.3773(8) 0.7583(7) 0.026(2) Uani 1 1 d . . .
H38 H -0.1979 1.3160 0.7330 0.032 Uiso 1 1 calc R . .
C39 C -0.2491(9) 1.4734(8) 0.7303(7) 0.028(2) Uani 1 1 d . . .
C40 C -0.1508(10) 1.4779(9) 0.6557(7) 0.026(2) Uani 1 1 d . . .
C41 C -0.3349(10) 1.5654(9) 0.7710(7) 0.031(3) Uani 1 1 d . . .
H41 H -0.3303 1.6301 0.7537 0.037 Uiso 1 1 calc R . .
C42 C -0.4283(9) 1.5593(8) 0.8383(7) 0.027(2) Uani 1 1 d . . .
C43 C -0.4382(9) 1.4644(9) 0.8633(7) 0.030(3) Uani 1 1 d . . .
H43 H -0.5017 1.4624 0.9077 0.036 Uiso 1 1 calc R . .
C44 C -0.5238(11) 1.6616(10) 0.8786(9) 0.041(3) Uani 1 1 d . . .
C45 C 0.0470(10) 1.3016(9) 1.1260(7) 0.031(3) Uani 1 1 d . . .
H45 H 0.0175 1.2558 1.1604 0.037 Uiso 1 1 calc R . .
C46 C 0.0604(12) 1.3890(11) 1.1637(8) 0.044(3) Uani 1 1 d . . .
H46 H 0.0371 1.4010 1.2218 0.053 Uiso 1 1 calc R . .
C47 C 0.1068(10) 1.4567(10) 1.1173(8) 0.036(3) Uani 1 1 d . . .
H47 H 0.1157 1.5147 1.1429 0.043 Uiso 1 1 calc R . .
C48 C 0.1418(10) 1.4370(9) 1.0281(7) 0.030(3) Uani 1 1 d . . .
C49 C 0.1242(10) 1.3463(8) 0.9952(8) 0.029(3) Uani 1 1 d . . .
C50 C 0.1902(11) 1.5030(10) 0.9725(9) 0.043(3) Uani 1 1 d . . .
H50 H 0.2032 1.5613 0.9946 0.052 Uiso 1 1 calc R . .
C51 C 0.2171(11) 1.4828(9) 0.8899(8) 0.037(3) Uani 1 1 d . . .
H51 H 0.2449 1.5288 0.8548 0.045 Uiso 1 1 calc R . .
C52 C 0.2038(10) 1.3914(9) 0.8541(8) 0.032(3) Uani 1 1 d . . .
C53 C 0.1570(8) 1.3240(8) 0.9069(7) 0.026(2) Uani 1 1 d . . .
C54 C 0.2333(11) 1.3671(11) 0.7684(9) 0.044(3) Uani 1 1 d . . .
H54 H 0.2634 1.4106 0.7317 0.053 Uiso 1 1 calc R . .
C55 C 0.2178(13) 1.2787(12) 0.7380(8) 0.048(4) Uani 1 1 d . . .
H55 H 0.2366 1.2618 0.6804 0.057 Uiso 1 1 calc R . .
C56 C 0.1739(10) 1.2141(9) 0.7936(7) 0.032(3) Uani 1 1 d . . .
H56 H 0.1647 1.1538 0.7722 0.039 Uiso 1 1 calc R . .
N1 N 0.1448(7) 1.2349(6) 0.8757(6) 0.0219(18) Uani 1 1 d . . .
N2 N 0.0740(8) 1.2809(6) 1.0442(5) 0.0229(19) Uani 1 1 d . . .
N3 N 0.0720(9) 0.1679(8) 0.5374(7) 0.041(3) Uani 1 1 d . . .
N4 N 0.1848(9) 0.1876(7) 0.3769(7) 0.035(2) Uani 1 1 d . . .
O1 O 0.2296(7) 0.3236(6) 0.5260(6) 0.0352(19) Uani 1 1 d . . .
O2 O 0.1074(6) 0.4859(6) 0.5346(5) 0.0292(17) Uani 1 1 d . . .
O3 O 0.0602(7) 0.6544(7) 0.6522(5) 0.044(2) Uani 1 1 d . . .
O4 O 0.1567(8) 0.6840(7) 0.5305(6) 0.043(2) Uani 1 1 d . . .
O5 O 0.0952(7) 0.8474(6) 0.8919(5) 0.040(2) Uani 1 1 d . . .
O6 O 0.1448(7) 0.9936(6) 0.8649(4) 0.0292(17) Uani 1 1 d . . .
O7 O 0.4126(11) 1.0193(7) 0.6059(7) 0.077(4) Uani 1 1 d . . .
H7 H 0.4484 1.0479 0.5696 0.116 Uiso 1 1 calc R . .
O8 O 0.5186(11) 0.8776(8) 0.5189(7) 0.077(4) Uani 1 1 d . . .
O9 O -0.0672(7) 1.1775(7) 0.8378(5) 0.040(2) Uani 1 1 d . . .
O10 O -0.1608(7) 1.2591(6) 0.9607(6) 0.036(2) Uani 1 1 d . . .
O11 O -0.1096(6) 1.0369(6) 0.9611(5) 0.0264(16) Uani 1 1 d . . .
O12 O -0.2361(7) 0.9448(6) 0.9838(6) 0.041(2) Uani 1 1 d . . .
O13 O -0.0805(7) 1.3935(5) 0.6148(5) 0.037(2) Uani 1 1 d . . .
O14 O -0.1456(7) 1.5681(6) 0.6361(5) 0.0313(18) Uani 1 1 d . . .
O15 O -0.5140(10) 1.7448(8) 0.8688(7) 0.061(3) Uani 1 1 d . . .
O16 O -0.6204(9) 1.6419(7) 0.9270(7) 0.061(3) Uani 1 1 d . . .
H16A H -0.6535 1.6882 0.9648 0.091 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.368(7) . ?
Eu1 O5 2.389(7) 2_577 ?
Eu1 O10 2.429(8) . ?
Eu1 O11 2.482(7) 2_577 ?
Eu1 O12 2.507(8) 2_577 ?
Eu1 N1 2.537(8) . ?
Eu1 N2 2.581(8) . ?
Eu1 O9 2.654(9) . ?
Eu1 C32 2.859(11) 2_577 ?
Eu1 Eu1 3.8740(11) 2_577 ?
Eu2 O2 2.366(7) 2_566 ?
Eu2 O13 2.420(8) 1_545 ?
Eu2 O14 2.429(7) 2_576 ?
Eu2 O4 2.455(8) 2_566 ?
Eu2 O1 2.467(8) . ?
Eu2 O2 2.515(8) . ?
Eu2 O3 2.533(9) 2_566 ?
Eu2 N4 2.580(9) . ?
Eu2 N3 2.603(11) . ?
Eu2 C19 2.743(10) 2_566 ?
Eu2 Eu2 3.9580(12) 2_566 ?
C1 N4 1.334(17) . ?
C1 C2 1.35(2) . ?
C1 H1 0.9300 . ?
C2 C3 1.34(2) . ?
C2 H2 0.9300 . ?
C3 C4 1.38(2) . ?
C3 H3 0.9300 . ?
C4 C5 1.408(17) . ?
C4 C9 1.446(18) . ?
C5 N4 1.351(14) . ?
C5 C6 1.420(18) . ?
C6 N3 1.377(14) . ?
C6 C7 1.415(16) . ?
C7 C8 1.394(18) . ?
C7 C10 1.409(18) . ?
C8 C9 1.34(2) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
C10 C11 1.370(19) . ?
C10 H10 0.9300 . ?
C11 C12 1.432(18) . ?
C11 H11 0.9300 . ?
C12 N3 1.320(16) . ?
C12 H12 0.9300 . ?
C13 C14 1.393(14) . ?
C13 C18 1.399(14) . ?
C13 C20 1.512(14) . ?
C14 C15 1.371(16) . ?
C14 H14 0.9300 . ?
C15 C16 1.387(16) . ?
C15 H15 0.9300 . ?
C16 C17 1.397(15) . ?
C16 H16 0.9300 . ?
C17 C18 1.392(14) . ?
C17 C21 1.462(15) . ?
C18 C19 1.489(13) . ?
C19 O4 1.258(14) . ?
C19 O3 1.269(13) . ?
C19 Eu2 2.743(10) 2_566 ?
C20 O1 1.226(12) . ?
C20 O2 1.295(12) . ?
C21 C28 1.394(14) . ?
C21 C22 1.407(14) . ?
C22 C23 1.363(15) . ?
C22 H22 0.9300 . ?
C23 C25 1.384(15) . ?
C23 C24 1.478(14) . ?
C24 O8 1.244(15) . ?
C24 O7 1.287(14) . ?
C25 C26 1.370(14) . ?
C25 H25 0.9300 . ?
C26 C28 1.399(14) . ?
C26 C27 1.513(14) . ?
C27 O6 1.245(12) . ?
C27 O5 1.253(13) . ?
C28 H28 0.9300 . ?
C29 O9 1.247(13) . ?
C29 O10 1.261(14) . ?
C29 C30 1.494(14) . ?
C30 C36 1.390(15) . ?
C30 C31 1.415(15) . ?
C31 C33 1.412(14) . ?
C31 C32 1.507(15) . ?
C32 O12 1.230(13) . ?
C32 O11 1.274(12) . ?
C32 Eu1 2.859(11) 2_577 ?
C33 C34 1.373(16) . ?
C33 H33 0.9300 . ?
C34 C35 1.384(16) . ?
C34 H34 0.9300 . ?
C35 C36 1.380(16) . ?
C35 H35 0.9300 . ?
C36 C37 1.496(15) . ?
C37 C38 1.392(14) . ?
C37 C43 1.408(15) . ?
C38 C39 1.400(15) . ?
C38 H38 0.9300 . ?
C39 C41 1.392(15) . ?
C39 C40 1.506(14) . ?
C40 O13 1.268(13) . ?
C40 O14 1.274(13) . ?
C41 C42 1.400(15) . ?
C41 H41 0.9300 . ?
C42 C43 1.373(15) . ?
C42 C44 1.523(16) . ?
C43 H43 0.9300 . ?
C44 O15 1.170(15) . ?
C44 O16 1.333(14) . ?
C45 N2 1.316(14) . ?
C45 C46 1.394(17) . ?
C45 H45 0.9300 . ?
C46 C47 1.355(18) . ?
C46 H46 0.9300 . ?
C47 C48 1.428(17) . ?
C47 H47 0.9300 . ?
C48 C49 1.423(16) . ?
C48 C50 1.425(16) . ?
C49 N2 1.373(13) . ?
C49 C53 1.419(16) . ?
C50 C51 1.328(18) . ?
C50 H50 0.9300 . ?
C51 C52 1.426(16) . ?
C51 H51 0.9300 . ?
C52 C54 1.384(18) . ?
C52 C53 1.406(15) . ?
C53 N1 1.362(13) . ?
C54 C55 1.367(18) . ?
C54 H54 0.9300 . ?
C55 C56 1.388(16) . ?
C55 H55 0.9300 . ?
C56 N1 1.318(14) . ?
C56 H56 0.9300 . ?
O2 Eu2 2.366(7) 2_566 ?
O3 Eu2 2.533(9) 2_566 ?
O4 Eu2 2.455(8) 2_566 ?
O5 Eu1 2.389(7) 2_577 ?
O7 H7 0.8200 . ?
O11 Eu1 2.482(7) 2_577 ?
O12 Eu1 2.507(8) 2_577 ?
O13 Eu2 2.420(8) 1_565 ?
O14 Eu2 2.429(7) 2_576 ?
O16 H16A 0.8200 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O5 139.4(3) . 2_577 ?
O6 Eu1 O10 122.6(3) . . ?
O5 Eu1 O10 74.2(3) 2_577 . ?
O6 Eu1 O11 71.3(2) . 2_577 ?
O5 Eu1 O11 74.0(3) 2_577 2_577 ?
O10 Eu1 O11 139.3(3) . 2_577 ?
O6 Eu1 O12 78.3(3) . 2_577 ?
O5 Eu1 O12 96.3(3) 2_577 2_577 ?
O10 Eu1 O12 157.0(3) . 2_577 ?
O11 Eu1 O12 51.8(2) 2_577 2_577 ?
O6 Eu1 N1 83.2(2) . . ?
O5 Eu1 N1 136.9(3) 2_577 . ?
O10 Eu1 N1 88.1(3) . . ?
O11 Eu1 N1 132.7(2) 2_577 . ?
O12 Eu1 N1 84.9(3) 2_577 . ?
O6 Eu1 N2 137.4(3) . . ?
O5 Eu1 N2 75.3(3) 2_577 . ?
O10 Eu1 N2 84.5(3) . . ?
O11 Eu1 N2 111.0(3) 2_577 . ?
O12 Eu1 N2 72.7(3) 2_577 . ?
N1 Eu1 N2 64.0(3) . . ?
O6 Eu1 O9 73.3(3) . . ?
O5 Eu1 O9 120.0(3) 2_577 . ?
O10 Eu1 O9 50.7(3) . . ?
O11 Eu1 O9 133.6(3) 2_577 . ?
O12 Eu1 O9 143.7(3) 2_577 . ?
N1 Eu1 O9 69.8(3) . . ?
N2 Eu1 O9 115.3(3) . . ?
O6 Eu1 C32 72.7(3) . 2_577 ?
O5 Eu1 C32 85.4(3) 2_577 2_577 ?
O10 Eu1 C32 159.5(3) . 2_577 ?
O11 Eu1 C32 26.4(2) 2_577 2_577 ?
O12 Eu1 C32 25.4(3) 2_577 2_577 ?
N1 Eu1 C32 108.5(3) . 2_577 ?
N2 Eu1 C32 91.9(3) . 2_577 ?
O9 Eu1 C32 145.9(3) . 2_577 ?
O6 Eu1 Eu1 69.13(17) . 2_577 ?
O5 Eu1 Eu1 70.46(18) 2_577 2_577 ?
O10 Eu1 Eu1 107.65(19) . 2_577 ?
O11 Eu1 Eu1 36.66(17) 2_577 2_577 ?
O12 Eu1 Eu1 88.05(19) 2_577 2_577 ?
N1 Eu1 Eu1 152.27(18) . 2_577 ?
N2 Eu1 Eu1 138.3(2) . 2_577 ?
O9 Eu1 Eu1 102.18(18) . 2_577 ?
C32 Eu1 Eu1 62.73(19) 2_577 2_577 ?
O2 Eu2 O13 75.8(3) 2_566 1_545 ?
O2 Eu2 O14 75.5(2) 2_566 2_576 ?
O13 Eu2 O14 137.3(2) 1_545 2_576 ?
O2 Eu2 O4 73.9(3) 2_566 2_566 ?
O13 Eu2 O4 75.4(3) 1_545 2_566 ?
O14 Eu2 O4 124.7(3) 2_576 2_566 ?
O2 Eu2 O1 123.8(2) 2_566 . ?
O13 Eu2 O1 89.1(3) 1_545 . ?
O14 Eu2 O1 81.4(3) 2_576 . ?
O4 Eu2 O1 153.3(3) 2_566 . ?
O2 Eu2 O2 71.6(3) 2_566 . ?
O13 Eu2 O2 72.7(3) 1_545 . ?
O14 Eu2 O2 68.6(2) 2_576 . ?
O4 Eu2 O2 137.6(3) 2_566 . ?
O1 Eu2 O2 52.2(2) . . ?
O2 Eu2 O3 70.1(3) 2_566 2_566 ?
O13 Eu2 O3 122.6(3) 1_545 2_566 ?
O14 Eu2 O3 74.9(3) 2_576 2_566 ?
O4 Eu2 O3 51.7(3) 2_566 2_566 ?
O1 Eu2 O3 148.3(3) . 2_566 ?
O2 Eu2 O3 132.2(3) . 2_566 ?
O2 Eu2 N4 140.8(3) 2_566 . ?
O13 Eu2 N4 140.2(3) 1_545 . ?
O14 Eu2 N4 79.2(3) 2_576 . ?
O4 Eu2 N4 97.4(3) 2_566 . ?
O1 Eu2 N4 80.5(3) . . ?
O2 Eu2 N4 125.0(3) . . ?
O3 Eu2 N4 74.7(3) 2_566 . ?
O2 Eu2 N3 144.6(3) 2_566 . ?
O13 Eu2 N3 76.7(3) 1_545 . ?
O14 Eu2 N3 139.4(3) 2_576 . ?
O4 Eu2 N3 77.9(3) 2_566 . ?
O1 Eu2 N3 77.4(3) . . ?
O2 Eu2 N3 120.0(3) . . ?
O3 Eu2 N3 107.8(3) 2_566 . ?
N4 Eu2 N3 63.6(3) . . ?
O2 Eu2 C19 60.6(3) 2_566 2_566 ?
O13 Eu2 C19 95.3(3) 1_545 2_566 ?
O14 Eu2 C19 97.4(3) 2_576 2_566 ?
O4 Eu2 C19 27.3(3) 2_566 2_566 ?
O1 Eu2 C19 174.6(3) . 2_566 ?
O2 Eu2 C19 132.2(3) . 2_566 ?
O3 Eu2 C19 27.5(3) 2_566 2_566 ?
N4 Eu2 C19 94.1(3) . 2_566 ?
N3 Eu2 C19 100.6(3) . 2_566 ?
O2 Eu2 Eu2 37.08(18) 2_566 2_566 ?
O13 Eu2 Eu2 70.40(17) 1_545 2_566 ?
O14 Eu2 Eu2 67.55(16) 2_576 2_566 ?
O4 Eu2 Eu2 107.6(2) 2_566 2_566 ?
O1 Eu2 Eu2 86.73(17) . 2_566 ?
O2 Eu2 Eu2 34.56(17) . 2_566 ?
O3 Eu2 Eu2 102.9(2) 2_566 2_566 ?
N4 Eu2 Eu2 145.8(2) . 2_566 ?
N3 Eu2 Eu2 143.6(2) . 2_566 ?
C19 Eu2 Eu2 97.7(2) 2_566 2_566 ?
N4 C1 C2 122.6(15) . . ?
N4 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C3 C2 C1 119.5(16) . . ?
C3 C2 H2 120.3 . . ?
C1 C2 H2 120.3 . . ?
C2 C3 C4 120.9(14) . . ?
C2 C3 H3 119.5 . . ?
C4 C3 H3 119.5 . . ?
C3 C4 C5 117.2(13) . . ?
C3 C4 C9 123.6(13) . . ?
C5 C4 C9 118.9(14) . . ?
N4 C5 C4 121.0(13) . . ?
N4 C5 C6 119.2(11) . . ?
C4 C5 C6 119.8(11) . . ?
N3 C6 C7 123.5(12) . . ?
N3 C6 C5 118.1(10) . . ?
C7 C6 C5 118.4(11) . . ?
C8 C7 C10 121.9(13) . . ?
C8 C7 C6 121.2(13) . . ?
C10 C7 C6 116.9(11) . . ?
C9 C8 C7 120.9(14) . . ?
C9 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
C8 C9 C4 120.7(14) . . ?
C8 C9 H9 119.6 . . ?
C4 C9 H9 119.6 . . ?
C11 C10 C7 120.4(12) . . ?
C11 C10 H10 119.8 . . ?
C7 C10 H10 119.8 . . ?
C10 C11 C12 118.2(13) . . ?
C10 C11 H11 120.9 . . ?
C12 C11 H11 120.9 . . ?
N3 C12 C11 123.7(13) . . ?
N3 C12 H12 118.2 . . ?
C11 C12 H12 118.2 . . ?
C14 C13 C18 119.4(9) . . ?
C14 C13 C20 116.6(9) . . ?
C18 C13 C20 124.0(9) . . ?
C15 C14 C13 120.3(10) . . ?
C15 C14 H14 119.8 . . ?
C13 C14 H14 119.8 . . ?
C14 C15 C16 119.4(10) . . ?
C14 C15 H15 120.3 . . ?
C16 C15 H15 120.3 . . ?
C15 C16 C17 122.4(11) . . ?
C15 C16 H16 118.8 . . ?
C17 C16 H16 118.8 . . ?
C18 C17 C16 117.0(10) . . ?
C18 C17 C21 123.1(10) . . ?
C16 C17 C21 119.8(10) . . ?
C17 C18 C13 121.4(9) . . ?
C17 C18 C19 119.5(9) . . ?
C13 C18 C19 119.0(9) . . ?
O4 C19 O3 118.8(10) . . ?
O4 C19 C18 118.7(10) . . ?
O3 C19 C18 122.0(10) . . ?
O4 C19 Eu2 63.5(6) . 2_566 ?
O3 C19 Eu2 67.0(6) . 2_566 ?
C18 C19 Eu2 137.8(7) . 2_566 ?
O1 C20 O2 120.8(10) . . ?
O1 C20 C13 121.6(9) . . ?
O2 C20 C13 117.6(9) . . ?
C28 C21 C22 115.8(10) . . ?
C28 C21 C17 124.7(9) . . ?
C22 C21 C17 119.3(9) . . ?
C23 C22 C21 122.4(10) . . ?
C23 C22 H22 118.8 . . ?
C21 C22 H22 118.8 . . ?
C22 C23 C25 120.0(10) . . ?
C22 C23 C24 118.8(10) . . ?
C25 C23 C24 120.8(10) . . ?
O8 C24 O7 124.3(11) . . ?
O8 C24 C23 119.7(11) . . ?
O7 C24 C23 115.8(10) . . ?
C26 C25 C23 120.3(10) . . ?
C26 C25 H25 119.9 . . ?
C23 C25 H25 119.9 . . ?
C25 C26 C28 119.0(9) . . ?
C25 C26 C27 119.9(9) . . ?
C28 C26 C27 121.1(9) . . ?
O6 C27 O5 127.2(10) . . ?
O6 C27 C26 115.2(9) . . ?
O5 C27 C26 117.4(9) . . ?
C21 C28 C26 122.3(9) . . ?
C21 C28 H28 118.8 . . ?
C26 C28 H28 118.8 . . ?
O9 C29 O10 121.3(11) . . ?
O9 C29 C30 121.7(11) . . ?
O10 C29 C30 116.8(9) . . ?
C36 C30 C31 120.7(9) . . ?
C36 C30 C29 121.6(10) . . ?
C31 C30 C29 117.4(10) . . ?
C33 C31 C30 117.9(10) . . ?
C33 C31 C32 118.6(10) . . ?
C30 C31 C32 123.5(9) . . ?
O12 C32 O11 121.1(10) . . ?
O12 C32 C31 120.7(9) . . ?
O11 C32 C31 118.2(9) . . ?
O12 C32 Eu1 61.1(6) . 2_577 ?
O11 C32 Eu1 60.1(6) . 2_577 ?
C31 C32 Eu1 177.0(8) . 2_577 ?
C34 C33 C31 121.0(11) . . ?
C34 C33 H33 119.5 . . ?
C31 C33 H33 119.5 . . ?
C33 C34 C35 119.6(10) . . ?
C33 C34 H34 120.2 . . ?
C35 C34 H34 120.2 . . ?
C36 C35 C34 121.6(11) . . ?
C36 C35 H35 119.2 . . ?
C34 C35 H35 119.2 . . ?
C35 C36 C30 119.2(11) . . ?
C35 C36 C37 118.3(10) . . ?
C30 C36 C37 122.1(10) . . ?
C38 C37 C43 117.2(10) . . ?
C38 C37 C36 126.0(10) . . ?
C43 C37 C36 116.7(10) . . ?
C37 C38 C39 122.4(10) . . ?
C37 C38 H38 118.8 . . ?
C39 C38 H38 118.8 . . ?
C41 C39 C38 119.0(10) . . ?
C41 C39 C40 120.1(10) . . ?
C38 C39 C40 120.9(9) . . ?
O13 C40 O14 123.6(10) . . ?
O13 C40 C39 119.2(10) . . ?
O14 C40 C39 117.1(10) . . ?
C39 C41 C42 119.1(11) . . ?
C39 C41 H41 120.4 . . ?
C42 C41 H41 120.4 . . ?
C43 C42 C41 121.2(10) . . ?
C43 C42 C44 121.2(10) . . ?
C41 C42 C44 117.5(10) . . ?
C42 C43 C37 120.9(10) . . ?
C42 C43 H43 119.5 . . ?
C37 C43 H43 119.5 . . ?
O15 C44 O16 125.1(12) . . ?
O15 C44 C42 125.3(12) . . ?
O16 C44 C42 109.6(10) . . ?
N2 C45 C46 123.1(11) . . ?
N2 C45 H45 118.5 . . ?
C46 C45 H45 118.5 . . ?
C47 C46 C45 121.3(12) . . ?
C47 C46 H46 119.4 . . ?
C45 C46 H46 119.4 . . ?
C46 C47 C48 118.6(11) . . ?
C46 C47 H47 120.7 . . ?
C48 C47 H47 120.7 . . ?
C49 C48 C50 120.0(11) . . ?
C49 C48 C47 116.2(11) . . ?
C50 C48 C47 123.8(11) . . ?
N2 C49 C53 118.3(10) . . ?
N2 C49 C48 123.5(11) . . ?
C53 C49 C48 118.2(10) . . ?
C51 C50 C48 121.2(12) . . ?
C51 C50 H50 119.4 . . ?
C48 C50 H50 119.4 . . ?
C50 C51 C52 120.8(11) . . ?
C50 C51 H51 119.6 . . ?
C52 C51 H51 119.6 . . ?
C54 C52 C53 118.1(11) . . ?
C54 C52 C51 122.2(11) . . ?
C53 C52 C51 119.7(11) . . ?
N1 C53 C52 121.7(10) . . ?
N1 C53 C49 118.2(10) . . ?
C52 C53 C49 120.1(10) . . ?
C55 C54 C52 119.5(11) . . ?
C55 C54 H54 120.3 . . ?
C52 C54 H54 120.3 . . ?
C54 C55 C56 119.5(12) . . ?
C54 C55 H55 120.2 . . ?
C56 C55 H55 120.2 . . ?
N1 C56 C55 122.7(11) . . ?
N1 C56 H56 118.7 . . ?
C55 C56 H56 118.7 . . ?
C56 N1 C53 118.5(9) . . ?
C56 N1 Eu1 120.3(7) . . ?
C53 N1 Eu1 120.3(7) . . ?
C45 N2 C49 117.3(9) . . ?
C45 N2 Eu1 124.2(7) . . ?
C49 N2 Eu1 118.5(7) . . ?
C12 N3 C6 117.2(12) . . ?
C12 N3 Eu2 123.9(8) . . ?
C6 N3 Eu2 118.8(8) . . ?
C1 N4 C5 118.7(12) . . ?
C1 N4 Eu2 121.1(9) . . ?
C5 N4 Eu2 120.1(9) . . ?
C20 O1 Eu2 95.4(6) . . ?
C20 O2 Eu2 159.5(7) . 2_566 ?
C20 O2 Eu2 91.4(6) . . ?
Eu2 O2 Eu2 108.4(3) 2_566 . ?
C19 O3 Eu2 85.5(7) . 2_566 ?
C19 O4 Eu2 89.2(6) . 2_566 ?
C27 O5 Eu1 134.5(7) . 2_577 ?
C27 O6 Eu1 138.0(7) . . ?
C24 O7 H7 109.5 . . ?
C29 O9 Eu1 81.6(7) . . ?
C29 O10 Eu1 91.3(6) . . ?
C32 O11 Eu1 93.5(6) . 2_577 ?
C32 O12 Eu1 93.5(7) . 2_577 ?
C40 O13 Eu2 134.7(7) . 1_565 ?
C40 O14 Eu2 140.6(7) . 2_576 ?
C44 O16 H16A 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N4 C1 C2 C3 1(3) . . . . ?
C1 C2 C3 C4 -3(4) . . . . ?
C2 C3 C4 C5 3(3) . . . . ?
C2 C3 C4 C9 177(2) . . . . ?
C3 C4 C5 N4 -1(2) . . . . ?
C9 C4 C5 N4 -175.0(15) . . . . ?
C3 C4 C5 C6 176.6(16) . . . . ?
C9 C4 C5 C6 3(2) . . . . ?
N4 C5 C6 N3 -4.5(18) . . . . ?
C4 C5 C6 N3 177.9(13) . . . . ?
N4 C5 C6 C7 176.0(12) . . . . ?
C4 C5 C6 C7 -1.6(19) . . . . ?
N3 C6 C7 C8 -179.1(14) . . . . ?
C5 C6 C7 C8 0(2) . . . . ?
N3 C6 C7 C10 -1(2) . . . . ?
C5 C6 C7 C10 178.9(12) . . . . ?
C10 C7 C8 C9 -178.7(17) . . . . ?
C6 C7 C8 C9 0(3) . . . . ?
C7 C8 C9 C4 1(3) . . . . ?
C3 C4 C9 C8 -176(2) . . . . ?
C5 C4 C9 C8 -2(3) . . . . ?
C8 C7 C10 C11 177.0(15) . . . . ?
C6 C7 C10 C11 -1(2) . . . . ?
C7 C10 C11 C12 2(2) . . . . ?
C10 C11 C12 N3 0(2) . . . . ?
C18 C13 C14 C15 -0.2(16) . . . . ?
C20 C13 C14 C15 -179.5(11) . . . . ?
C13 C14 C15 C16 0.0(19) . . . . ?
C14 C15 C16 C17 2(2) . . . . ?
C15 C16 C17 C18 -3.2(18) . . . . ?
C15 C16 C17 C21 -179.1(12) . . . . ?
C16 C17 C18 C13 2.9(15) . . . . ?
C21 C17 C18 C13 178.7(9) . . . . ?
C16 C17 C18 C19 -173.2(10) . . . . ?
C21 C17 C18 C19 2.6(15) . . . . ?
C14 C13 C18 C17 -1.3(15) . . . . ?
C20 C13 C18 C17 177.9(9) . . . . ?
C14 C13 C18 C19 174.8(10) . . . . ?
C20 C13 C18 C19 -6.0(15) . . . . ?
C17 C18 C19 O4 90.8(12) . . . . ?
C13 C18 C19 O4 -85.4(12) . . . . ?
C17 C18 C19 O3 -97.8(12) . . . . ?
C13 C18 C19 O3 86.0(13) . . . . ?
C17 C18 C19 Eu2 172.0(8) . . . 2_566 ?
C13 C18 C19 Eu2 -4.2(16) . . . 2_566 ?
C14 C13 C20 O1 8.0(15) . . . . ?
C18 C13 C20 O1 -171.3(10) . . . . ?
C14 C13 C20 O2 -175.0(9) . . . . ?
C18 C13 C20 O2 5.8(15) . . . . ?
C18 C17 C21 C28 68.9(15) . . . . ?
C16 C17 C21 C28 -115.4(13) . . . . ?
C18 C17 C21 C22 -106.2(12) . . . . ?
C16 C17 C21 C22 69.5(15) . . . . ?
C28 C21 C22 C23 2.3(18) . . . . ?
C17 C21 C22 C23 177.8(11) . . . . ?
C21 C22 C23 C25 1(2) . . . . ?
C21 C22 C23 C24 -171.6(12) . . . . ?
C22 C23 C24 O8 -6(2) . . . . ?
C25 C23 C24 O8 -178.8(15) . . . . ?
C22 C23 C24 O7 169.9(14) . . . . ?
C25 C23 C24 O7 -3(2) . . . . ?
C22 C23 C25 C26 -2(2) . . . . ?
C24 C23 C25 C26 170.2(12) . . . . ?
C23 C25 C26 C28 0.1(18) . . . . ?
C23 C25 C26 C27 -178.4(11) . . . . ?
C25 C26 C27 O6 -1.3(15) . . . . ?
C28 C26 C27 O6 -179.7(10) . . . . ?
C25 C26 C27 O5 -178.0(11) . . . . ?
C28 C26 C27 O5 3.5(15) . . . . ?
C22 C21 C28 C26 -4.6(16) . . . . ?
C17 C21 C28 C26 -179.8(10) . . . . ?
C25 C26 C28 C21 3.5(17) . . . . ?
C27 C26 C28 C21 -178.1(10) . . . . ?
O9 C29 C30 C36 -94.9(13) . . . . ?
O10 C29 C30 C36 89.7(13) . . . . ?
O9 C29 C30 C31 91.8(13) . . . . ?
O10 C29 C30 C31 -83.7(13) . . . . ?
C36 C30 C31 C33 -0.6(17) . . . . ?
C29 C30 C31 C33 172.8(10) . . . . ?
C36 C30 C31 C32 178.3(10) . . . . ?
C29 C30 C31 C32 -8.3(16) . . . . ?
C33 C31 C32 O12 4.4(17) . . . . ?
C30 C31 C32 O12 -174.5(11) . . . . ?
C33 C31 C32 O11 -174.8(10) . . . . ?
C30 C31 C32 O11 6.3(16) . . . . ?
C33 C31 C32 Eu1 -121(14) . . . 2_577 ?
C30 C31 C32 Eu1 60(14) . . . 2_577 ?
C30 C31 C33 C34 -1.9(18) . . . . ?
C32 C31 C33 C34 179.2(12) . . . . ?
C31 C33 C34 C35 3(2) . . . . ?
C33 C34 C35 C36 -2(2) . . . . ?
C34 C35 C36 C30 -1(2) . . . . ?
C34 C35 C36 C37 -173.7(12) . . . . ?
C31 C30 C36 C35 1.7(17) . . . . ?
C29 C30 C36 C35 -171.4(11) . . . . ?
C31 C30 C36 C37 174.6(10) . . . . ?
C29 C30 C36 C37 1.5(17) . . . . ?
C35 C36 C37 C38 -128.9(13) . . . . ?
C30 C36 C37 C38 58.2(17) . . . . ?
C35 C36 C37 C43 53.6(16) . . . . ?
C30 C36 C37 C43 -119.3(12) . . . . ?
C43 C37 C38 C39 -4.1(17) . . . . ?
C36 C37 C38 C39 178.5(11) . . . . ?
C37 C38 C39 C41 3.4(17) . . . . ?
C37 C38 C39 C40 -174.7(10) . . . . ?
C41 C39 C40 O13 -173.7(11) . . . . ?
C38 C39 C40 O13 4.4(17) . . . . ?
C41 C39 C40 O14 4.5(16) . . . . ?
C38 C39 C40 O14 -177.4(10) . . . . ?
C38 C39 C41 C42 -0.5(17) . . . . ?
C40 C39 C41 C42 177.7(10) . . . . ?
C39 C41 C42 C43 -1.6(18) . . . . ?
C39 C41 C42 C44 -177.3(11) . . . . ?
C41 C42 C43 C37 0.9(18) . . . . ?
C44 C42 C43 C37 176.5(11) . . . . ?
C38 C37 C43 C42 1.9(17) . . . . ?
C36 C37 C43 C42 179.6(11) . . . . ?
C43 C42 C44 O15 169.7(14) . . . . ?
C41 C42 C44 O15 -15(2) . . . . ?
C43 C42 C44 O16 -10.2(18) . . . . ?
C41 C42 C44 O16 165.5(11) . . . . ?
N2 C45 C46 C47 -2.3(19) . . . . ?
C45 C46 C47 C48 0.2(18) . . . . ?
C46 C47 C48 C49 0.1(16) . . . . ?
C46 C47 C48 C50 179.2(12) . . . . ?
C50 C48 C49 N2 -177.6(10) . . . . ?
C47 C48 C49 N2 1.5(15) . . . . ?
C50 C48 C49 C53 0.5(15) . . . . ?
C47 C48 C49 C53 179.6(9) . . . . ?
C49 C48 C50 C51 1.4(17) . . . . ?
C47 C48 C50 C51 -177.6(12) . . . . ?
C48 C50 C51 C52 -3.0(19) . . . . ?
C50 C51 C52 C54 -178.7(12) . . . . ?
C50 C51 C52 C53 2.6(18) . . . . ?
C54 C52 C53 N1 2.5(16) . . . . ?
C51 C52 C53 N1 -178.8(10) . . . . ?
C54 C52 C53 C49 -179.4(10) . . . . ?
C51 C52 C53 C49 -0.6(16) . . . . ?
N2 C49 C53 N1 -4.5(14) . . . . ?
C48 C49 C53 N1 177.4(9) . . . . ?
N2 C49 C53 C52 177.3(10) . . . . ?
C48 C49 C53 C52 -0.8(15) . . . . ?
C53 C52 C54 C55 -0.9(18) . . . . ?
C51 C52 C54 C55 -179.6(12) . . . . ?
C52 C54 C55 C56 -1(2) . . . . ?
C54 C55 C56 N1 1(2) . . . . ?
C55 C56 N1 C53 0.8(17) . . . . ?
C55 C56 N1 Eu1 170.3(10) . . . . ?
C52 C53 N1 C56 -2.4(15) . . . . ?
C49 C53 N1 C56 179.4(9) . . . . ?
C52 C53 N1 Eu1 -171.9(7) . . . . ?
C49 C53 N1 Eu1 9.9(12) . . . . ?
O6 Eu1 N1 C56 30.8(8) . . . . ?
O5 Eu1 N1 C56 -156.6(8) 2_577 . . . ?
O10 Eu1 N1 C56 -92.4(8) . . . . ?
O11 Eu1 N1 C56 87.5(8) 2_577 . . . ?
O12 Eu1 N1 C56 109.6(8) 2_577 . . . ?
N2 Eu1 N1 C56 -177.2(9) . . . . ?
O9 Eu1 N1 C56 -43.9(8) . . . . ?
C32 Eu1 N1 C56 99.9(8) 2_577 . . . ?
Eu1 Eu1 N1 C56 33.7(10) 2_577 . . . ?
O6 Eu1 N1 C53 -159.9(7) . . . . ?
O5 Eu1 N1 C53 12.7(9) 2_577 . . . ?
O10 Eu1 N1 C53 77.0(7) . . . . ?
O11 Eu1 N1 C53 -103.2(7) 2_577 . . . ?
O12 Eu1 N1 C53 -81.1(7) 2_577 . . . ?
N2 Eu1 N1 C53 -7.9(7) . . . . ?
O9 Eu1 N1 C53 125.5(7) . . . . ?
C32 Eu1 N1 C53 -90.7(7) 2_577 . . . ?
Eu1 Eu1 N1 C53 -157.0(5) 2_577 . . . ?
C46 C45 N2 C49 3.8(16) . . . . ?
C46 C45 N2 Eu1 -174.8(8) . . . . ?
C53 C49 N2 C45 178.5(9) . . . . ?
C48 C49 N2 C45 -3.5(15) . . . . ?
C53 C49 N2 Eu1 -2.9(12) . . . . ?
C48 C49 N2 Eu1 175.2(8) . . . . ?
O6 Eu1 N2 C45 -132.6(8) . . . . ?
O5 Eu1 N2 C45 18.2(8) 2_577 . . . ?
O10 Eu1 N2 C45 93.3(8) . . . . ?
O11 Eu1 N2 C45 -47.8(9) 2_577 . . . ?
O12 Eu1 N2 C45 -83.4(8) 2_577 . . . ?
N1 Eu1 N2 C45 -176.1(9) . . . . ?
O9 Eu1 N2 C45 134.8(8) . . . . ?
C32 Eu1 N2 C45 -66.5(8) 2_577 . . . ?
Eu1 Eu1 N2 C45 -17.1(10) 2_577 . . . ?
O6 Eu1 N2 C49 48.9(9) . . . . ?
O5 Eu1 N2 C49 -160.3(8) 2_577 . . . ?
O10 Eu1 N2 C49 -85.2(8) . . . . ?
O11 Eu1 N2 C49 133.7(7) 2_577 . . . ?
O12 Eu1 N2 C49 98.1(8) 2_577 . . . ?
N1 Eu1 N2 C49 5.4(7) . . . . ?
O9 Eu1 N2 C49 -43.7(8) . . . . ?
C32 Eu1 N2 C49 115.0(8) 2_577 . . . ?
Eu1 Eu1 N2 C49 164.3(6) 2_577 . . . ?
C11 C12 N3 C6 -2(2) . . . . ?
C11 C12 N3 Eu2 174.9(11) . . . . ?
C7 C6 N3 C12 2.4(19) . . . . ?
C5 C6 N3 C12 -177.0(12) . . . . ?
C7 C6 N3 Eu2 -175.0(9) . . . . ?
C5 C6 N3 Eu2 5.6(15) . . . . ?
O2 Eu2 N3 C12 -38.1(14) 2_566 . . . ?
O13 Eu2 N3 C12 1.7(11) 1_545 . . . ?
O14 Eu2 N3 C12 153.9(10) 2_576 . . . ?
O4 Eu2 N3 C12 -75.9(11) 2_566 . . . ?
O1 Eu2 N3 C12 93.8(11) . . . . ?
O2 Eu2 N3 C12 62.5(11) . . . . ?
O3 Eu2 N3 C12 -118.7(11) 2_566 . . . ?
N4 Eu2 N3 C12 179.4(12) . . . . ?
C19 Eu2 N3 C12 -91.3(11) 2_566 . . . ?
Eu2 Eu2 N3 C12 27.5(13) 2_566 . . . ?
O2 Eu2 N3 C6 139.0(8) 2_566 . . . ?
O13 Eu2 N3 C6 178.9(9) 1_545 . . . ?
O14 Eu2 N3 C6 -29.0(11) 2_576 . . . ?
O4 Eu2 N3 C6 101.2(9) 2_566 . . . ?
O1 Eu2 N3 C6 -89.1(9) . . . . ?
O2 Eu2 N3 C6 -120.4(9) . . . . ?
O3 Eu2 N3 C6 58.5(9) 2_566 . . . ?
N4 Eu2 N3 C6 -3.5(8) . . . . ?
C19 Eu2 N3 C6 85.8(9) 2_566 . . . ?
Eu2 Eu2 N3 C6 -155.4(7) 2_566 . . . ?
C2 C1 N4 C5 1(3) . . . . ?
C2 C1 N4 Eu2 -178.7(16) . . . . ?
C4 C5 N4 C1 -1(2) . . . . ?
C6 C5 N4 C1 -178.4(13) . . . . ?
C4 C5 N4 Eu2 178.7(11) . . . . ?
C6 C5 N4 Eu2 1.1(16) . . . . ?
O2 Eu2 N4 C1 34.6(13) 2_566 . . . ?
O13 Eu2 N4 C1 -175.7(10) 1_545 . . . ?
O14 Eu2 N4 C1 -15.8(11) 2_576 . . . ?
O4 Eu2 N4 C1 108.2(11) 2_566 . . . ?
O1 Eu2 N4 C1 -98.8(11) . . . . ?
O2 Eu2 N4 C1 -69.8(12) . . . . ?
O3 Eu2 N4 C1 61.4(11) 2_566 . . . ?
N3 Eu2 N4 C1 -179.3(12) . . . . ?
C19 Eu2 N4 C1 81.0(12) 2_566 . . . ?
Eu2 Eu2 N4 C1 -29.2(13) 2_566 . . . ?
O2 Eu2 N4 C5 -144.9(8) 2_566 . . . ?
O13 Eu2 N4 C5 4.8(12) 1_545 . . . ?
O14 Eu2 N4 C5 164.7(10) 2_576 . . . ?
O4 Eu2 N4 C5 -71.3(9) 2_566 . . . ?
O1 Eu2 N4 C5 81.7(9) . . . . ?
O2 Eu2 N4 C5 110.6(9) . . . . ?
O3 Eu2 N4 C5 -118.2(9) 2_566 . . . ?
N3 Eu2 N4 C5 1.2(9) . . . . ?
C19 Eu2 N4 C5 -98.6(9) 2_566 . . . ?
Eu2 Eu2 N4 C5 151.3(7) 2_566 . . . ?
O2 C20 O1 Eu2 5.4(11) . . . . ?
C13 C20 O1 Eu2 -177.7(9) . . . . ?
O2 Eu2 O1 C20 0.5(8) 2_566 . . . ?
O13 Eu2 O1 C20 -71.7(7) 1_545 . . . ?
O14 Eu2 O1 C20 66.5(7) 2_576 . . . ?
O4 Eu2 O1 C20 -125.4(8) 2_566 . . . ?
O2 Eu2 O1 C20 -3.0(6) . . . . ?
O3 Eu2 O1 C20 108.2(8) 2_566 . . . ?
N4 Eu2 O1 C20 146.9(7) . . . . ?
N3 Eu2 O1 C20 -148.3(7) . . . . ?
C19 Eu2 O1 C20 144(3) 2_566 . . . ?
Eu2 Eu2 O1 C20 -1.3(7) 2_566 . . . ?
O1 C20 O2 Eu2 -169.2(14) . . . 2_566 ?
C13 C20 O2 Eu2 14(3) . . . 2_566 ?
O1 C20 O2 Eu2 -5.3(11) . . . . ?
C13 C20 O2 Eu2 177.7(8) . . . . ?
O2 Eu2 O2 C20 -174.1(7) 2_566 . . . ?
O13 Eu2 O2 C20 105.5(6) 1_545 . . . ?
O14 Eu2 O2 C20 -92.9(6) 2_576 . . . ?
O4 Eu2 O2 C20 148.6(6) 2_566 . . . ?
O1 Eu2 O2 C20 2.8(6) . . . . ?
O3 Eu2 O2 C20 -135.8(6) 2_566 . . . ?
N4 Eu2 O2 C20 -34.3(7) . . . . ?
N3 Eu2 O2 C20 42.7(7) . . . . ?
C19 Eu2 O2 C20 -173.2(6) 2_566 . . . ?
Eu2 Eu2 O2 C20 -174.1(7) 2_566 . . . ?
O2 Eu2 O2 Eu2 0.0 2_566 . . 2_566 ?
O13 Eu2 O2 Eu2 -80.4(3) 1_545 . . 2_566 ?
O14 Eu2 O2 Eu2 81.2(3) 2_576 . . 2_566 ?
O4 Eu2 O2 Eu2 -37.3(5) 2_566 . . 2_566 ?
O1 Eu2 O2 Eu2 177.0(5) . . . 2_566 ?
O3 Eu2 O2 Eu2 38.3(4) 2_566 . . 2_566 ?
N4 Eu2 O2 Eu2 139.8(3) . . . 2_566 ?
N3 Eu2 O2 Eu2 -143.1(3) . . . 2_566 ?
C19 Eu2 O2 Eu2 0.9(5) 2_566 . . 2_566 ?
O4 C19 O3 Eu2 38.2(10) . . . 2_566 ?
C18 C19 O3 Eu2 -133.2(9) . . . 2_566 ?
O3 C19 O4 Eu2 -39.5(10) . . . 2_566 ?
C18 C19 O4 Eu2 132.2(8) . . . 2_566 ?
O6 C27 O5 Eu1 -6.6(19) . . . 2_577 ?
C26 C27 O5 Eu1 169.7(7) . . . 2_577 ?
O5 C27 O6 Eu1 -3.7(19) . . . . ?
C26 C27 O6 Eu1 180.0(7) . . . . ?
O5 Eu1 O6 C27 12.8(13) 2_577 . . . ?
O10 Eu1 O6 C27 -91.7(11) . . . . ?
O11 Eu1 O6 C27 45.5(10) 2_577 . . . ?
O12 Eu1 O6 C27 98.9(11) 2_577 . . . ?
N1 Eu1 O6 C27 -175.0(11) . . . . ?
N2 Eu1 O6 C27 146.5(10) . . . . ?
O9 Eu1 O6 C27 -104.0(11) . . . . ?
C32 Eu1 O6 C27 73.2(11) 2_577 . . . ?
Eu1 Eu1 O6 C27 6.5(10) 2_577 . . . ?
O10 C29 O9 Eu1 38.3(10) . . . . ?
C30 C29 O9 Eu1 -136.9(10) . . . . ?
O6 Eu1 O9 C29 145.7(7) . . . . ?
O5 Eu1 O9 C29 7.8(7) 2_577 . . . ?
O10 Eu1 O9 C29 -20.8(6) . . . . ?
O11 Eu1 O9 C29 104.1(7) 2_577 . . . ?
O12 Eu1 O9 C29 -174.3(6) 2_577 . . . ?
N1 Eu1 O9 C29 -125.5(7) . . . . ?
N2 Eu1 O9 C29 -79.2(7) . . . . ?
C32 Eu1 O9 C29 141.0(7) 2_577 . . . ?
Eu1 Eu1 O9 C29 82.1(6) 2_577 . . . ?
O9 C29 O10 Eu1 -42.1(11) . . . . ?
C30 C29 O10 Eu1 133.4(9) . . . . ?
O6 Eu1 O10 C29 5.0(7) . . . . ?
O5 Eu1 O10 C29 -134.1(7) 2_577 . . . ?
O11 Eu1 O10 C29 -94.2(7) 2_577 . . . ?
O12 Eu1 O10 C29 157.7(7) 2_577 . . . ?
N1 Eu1 O10 C29 85.6(7) . . . . ?
N2 Eu1 O10 C29 149.7(7) . . . . ?
O9 Eu1 O10 C29 20.3(6) . . . . ?
C32 Eu1 O10 C29 -129.7(9) 2_577 . . . ?
Eu1 Eu1 O10 C29 -71.1(7) 2_577 . . . ?
O12 C32 O11 Eu1 -2.0(11) . . . 2_577 ?
C31 C32 O11 Eu1 177.3(9) . . . 2_577 ?
O11 C32 O12 Eu1 1.9(11) . . . 2_577 ?
C31 C32 O12 Eu1 -177.3(9) . . . 2_577 ?
O14 C40 O13 Eu2 -22.8(18) . . . 1_565 ?
C39 C40 O13 Eu2 155.3(8) . . . 1_565 ?
O13 C40 O14 Eu2 4.5(19) . . . 2_576 ?
C39 C40 O14 Eu2 -173.6(8) . . . 2_576 ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        67.02
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.956
_refine_diff_density_min         -1.413
_refine_diff_density_rms         0.193
