# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_4213
_database_code_depnum_ccdc_archive 'CCDC 1483899'
_audit_update_record             
;
2016-06-07 deposited with the CCDC.
2016-06-26 downloaded from the CCDC.
;
_audit_creation_date             2016-06-07
_audit_creation_method           
;
  Olex2 1.1
  (compiled 2011.02.15 svn.r1672, GUI svn.r3494)
;
_chemical_name_common            
;
  2-Phosphorindoline 2-oxide
;
_chemical_name_systematic        
;
 2-Benzoyl-1-ethoxy-1-oxoazacyclohexano[3,2,1-h,i]phosphorindoline 
;
_chemical_formula_moiety         'C19 H20 N O3 P'
_chemical_formula_sum            'C19 H20 N O3 P'
_chemical_formula_weight         341.33
_chemical_absolute_configuration ad
_chemical_melting_point          '142-144 deg'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           29
_space_group_name_H-M_alt        'P c a 21'
_space_group_name_Hall           'P 2c -2ac'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, z+1/2'
3 '-x+1/2, y, z+1/2'
4 'x+1/2, -y, z'

_cell_length_a                   20.0597(8)
_cell_length_b                   10.2411(3)
_cell_length_c                   8.0519(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     1654.14(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    1986
_cell_measurement_temperature    142.0
_cell_measurement_theta_max      29.1002
_cell_measurement_theta_min      3.0403
_exptl_absorpt_coefficient_mu    0.183
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.86685
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellowish
_exptl_crystal_density_diffrn    1.371
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             720
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.30
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0261
_diffrn_reflns_av_unetI/netI     0.0415
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            5042
_diffrn_reflns_theta_full        25.99
_diffrn_reflns_theta_max         25.99
_diffrn_reflns_theta_min         3.24
_diffrn_ambient_temperature      142.0
_diffrn_detector_area_resol_mean 16.0971
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   -4.00   22.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       21.1390   73.0000  -31.0000 26

#__ type_ start__ end____ width___ exp.time_
  2 omega   40.00   67.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       21.1390   73.0000  -31.0000 27

#__ type_ start__ end____ width___ exp.time_
  3 omega   -5.00   94.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       21.1390   37.0000  120.0000 99

#__ type_ start__ end____ width___ exp.time_
  4 omega   33.00   58.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       21.1390   37.0000 -180.0000 25
;
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0230634000
_diffrn_orient_matrix_UB_12      0.0062608000
_diffrn_orient_matrix_UB_13      0.0663005000
_diffrn_orient_matrix_UB_21      -0.0138183000
_diffrn_orient_matrix_UB_22      0.0561306000
_diffrn_orient_matrix_UB_23      -0.0385308000
_diffrn_orient_matrix_UB_31      -0.0229466000
_diffrn_orient_matrix_UB_32      -0.0400998000
_diffrn_orient_matrix_UB_33      -0.0434010000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_source                   'Enhance (Mo) X-ray Source'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                2515
_reflns_number_total             2710
_reflns_odcompleteness_completeness 99.65
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_molecular_graphics    
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material  
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    
'A short history of SHELX (Sheldrick, 2007)/Bruker'
_refine_diff_density_max         0.191
_refine_diff_density_min         -0.299
_refine_diff_density_rms         0.038
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.06(10)
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     218
_refine_ls_number_reflns         2710
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0382
_refine_ls_R_factor_gt           0.0343
_refine_ls_restrained_S_all      1.025
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0461P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0805
_refine_ls_wR_factor_ref         0.0835
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P -0.03877(3) -0.19284(5) -0.29497(8) 0.01901(14) Uani 1 1 d . . .
O2 O -0.05899(8) -0.09040(14) -0.4126(2) 0.0263(4) Uani 1 1 d . . .
O3 O -0.10081(8) -0.27313(14) -0.2272(2) 0.0263(4) Uani 1 1 d . . .
N1 N 0.01401(10) -0.30618(17) -0.3596(3) 0.0235(5) Uani 1 1 d . . .
C9 C 0.07272(11) -0.2311(2) -0.1237(3) 0.0207(5) Uani 1 1 d . . .
C10 C 0.01130(11) -0.1441(2) -0.1139(3) 0.0195(5) Uani 1 1 d . . .
H10 H 0.0256 -0.0513 -0.1290 0.023 Uiso 1 1 calc R . .
C4 C 0.12346(11) -0.40198(18) -0.2947(3) 0.0243(5) Uani 1 1 d . . .
C5 C 0.07140(11) -0.31558(19) -0.2596(3) 0.0214(5) Uani 1 1 d . . .
C17 C -0.12759(11) -0.1016(2) 0.2118(3) 0.0260(5) Uani 1 1 d . . .
H17 H -0.1149 -0.1693 0.2861 0.031 Uiso 1 1 calc R . .
O1 O -0.00833(9) -0.23182(18) 0.1560(2) 0.0406(5) Uani 1 1 d . . .
C12 C -0.08726(11) -0.0726(2) 0.0750(3) 0.0228(5) Uani 1 1 d . . .
C8 C 0.12646(11) -0.2321(2) -0.0167(3) 0.0258(5) Uani 1 1 d . . .
H8 H 0.1278 -0.1747 0.0759 0.031 Uiso 1 1 calc R . .
C7 C 0.17888(13) -0.3190(2) -0.0467(3) 0.0307(6) Uani 1 1 d . . .
H7 H 0.2159 -0.3219 0.0267 0.037 Uiso 1 1 calc R . .
C13 C -0.10581(11) 0.0286(2) -0.0314(3) 0.0253(5) Uani 1 1 d . . .
H13 H -0.0782 0.0508 -0.1230 0.030 Uiso 1 1 calc R . .
C1 C 0.00420(12) -0.3977(2) -0.4982(3) 0.0263(5) Uani 1 1 d . . .
H1A H -0.0255 -0.3578 -0.5824 0.032 Uiso 1 1 calc R . .
H1B H -0.0173 -0.4785 -0.4571 0.032 Uiso 1 1 calc R . .
C11 C -0.02660(11) -0.1550(2) 0.0492(3) 0.0234(5) Uani 1 1 d . . .
C6 C 0.17674(13) -0.4013(2) -0.1841(3) 0.0282(6) Uani 1 1 d . . .
H6 H 0.2130 -0.4591 -0.2031 0.034 Uiso 1 1 calc R . .
C14 C -0.16439(12) 0.0968(2) -0.0036(4) 0.0292(5) Uani 1 1 d . . .
H14 H -0.1773 0.1643 -0.0777 0.035 Uiso 1 1 calc R . .
C16 C -0.18578(11) -0.0324(2) 0.2399(3) 0.0312(6) Uani 1 1 d . . .
H16 H -0.2130 -0.0528 0.3329 0.037 Uiso 1 1 calc R . .
C18 C -0.16913(11) -0.2339(2) -0.2572(4) 0.0328(6) Uani 1 1 d . . .
H18A H -0.1701 -0.1431 -0.2996 0.039 Uiso 1 1 calc R . .
H18B H -0.1946 -0.2367 -0.1520 0.039 Uiso 1 1 calc R . .
C2 C 0.07066(13) -0.4303(2) -0.5759(3) 0.0322(6) Uani 1 1 d . . .
H2A H 0.0902 -0.3504 -0.6251 0.039 Uiso 1 1 calc R . .
H2B H 0.0639 -0.4945 -0.6664 0.039 Uiso 1 1 calc R . .
C19 C -0.20050(15) -0.3236(3) -0.3815(4) 0.0495(8) Uani 1 1 d . . .
H19A H -0.1945 -0.4143 -0.3457 0.074 Uiso 1 1 calc R . .
H19B H -0.1793 -0.3111 -0.4900 0.074 Uiso 1 1 calc R . .
H19C H -0.2482 -0.3041 -0.3902 0.074 Uiso 1 1 calc R . .
C3 C 0.11935(13) -0.4871(2) -0.4472(3) 0.0327(6) Uani 1 1 d . . .
H3A H 0.1044 -0.5757 -0.4149 0.039 Uiso 1 1 calc R . .
H3B H 0.1642 -0.4950 -0.4977 0.039 Uiso 1 1 calc R . .
C15 C -0.20436(11) 0.0668(2) 0.1323(3) 0.0315(6) Uani 1 1 d . . .
H15 H -0.2443 0.1142 0.1513 0.038 Uiso 1 1 calc R . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O2 1.4705(16) . ?
P1 O3 1.5883(16) . ?
P1 N1 1.6549(19) . ?
P1 C10 1.839(2) . ?
O3 C18 1.448(3) . ?
N1 C5 1.408(3) . ?
N1 C1 1.471(3) . ?
C9 C10 1.522(3) . ?
C9 C5 1.395(3) . ?
C9 C8 1.380(3) . ?
C10 H10 1.0000 . ?
C10 C11 1.522(3) . ?
C4 C5 1.398(3) . ?
C4 C6 1.391(3) . ?
C4 C3 1.509(4) . ?
C17 H17 0.9500 . ?
C17 C12 1.399(3) . ?
C17 C16 1.384(3) . ?
O1 C11 1.221(3) . ?
C12 C13 1.395(3) . ?
C12 C11 1.495(3) . ?
C8 H8 0.9500 . ?
C8 C7 1.399(3) . ?
C7 H7 0.9500 . ?
C7 C6 1.391(3) . ?
C13 H13 0.9500 . ?
C13 C14 1.385(3) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C1 C2 1.510(3) . ?
C6 H6 0.9500 . ?
C14 H14 0.9500 . ?
C14 C15 1.391(4) . ?
C16 H16 0.9500 . ?
C16 C15 1.386(3) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C18 C19 1.497(4) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C2 C3 1.538(3) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C15 H15 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 P1 O3 112.00(9) . . ?
O2 P1 N1 118.32(11) . . ?
O2 P1 C10 117.88(10) . . ?
O3 P1 N1 104.25(9) . . ?
O3 P1 C10 107.23(10) . . ?
N1 P1 C10 95.16(10) . . ?
C18 O3 P1 122.70(14) . . ?
C5 N1 P1 113.05(15) . . ?
C5 N1 C1 119.98(18) . . ?
C1 N1 P1 126.86(17) . . ?
C5 C9 C10 112.8(2) . . ?
C8 C9 C10 127.2(2) . . ?
C8 C9 C5 120.0(2) . . ?
P1 C10 H10 108.5 . . ?
C9 C10 P1 104.01(15) . . ?
C9 C10 H10 108.5 . . ?
C11 C10 P1 113.04(15) . . ?
C11 C10 C9 113.95(19) . . ?
C11 C10 H10 108.5 . . ?
C5 C4 C3 119.3(2) . . ?
C6 C4 C5 116.2(2) . . ?
C6 C4 C3 124.5(2) . . ?
C9 C5 N1 114.92(19) . . ?
C9 C5 C4 122.5(2) . . ?
C4 C5 N1 122.6(2) . . ?
C12 C17 H17 119.8 . . ?
C16 C17 H17 119.8 . . ?
C16 C17 C12 120.5(2) . . ?
C17 C12 C11 117.4(2) . . ?
C13 C12 C17 119.1(2) . . ?
C13 C12 C11 123.5(2) . . ?
C9 C8 H8 120.5 . . ?
C9 C8 C7 119.0(2) . . ?
C7 C8 H8 120.5 . . ?
C8 C7 H7 120.0 . . ?
C6 C7 C8 120.0(2) . . ?
C6 C7 H7 120.0 . . ?
C12 C13 H13 119.9 . . ?
C14 C13 C12 120.1(2) . . ?
C14 C13 H13 119.9 . . ?
N1 C1 H1A 109.7 . . ?
N1 C1 H1B 109.7 . . ?
N1 C1 C2 109.7(2) . . ?
H1A C1 H1B 108.2 . . ?
C2 C1 H1A 109.7 . . ?
C2 C1 H1B 109.7 . . ?
O1 C11 C10 120.3(2) . . ?
O1 C11 C12 120.7(2) . . ?
C12 C11 C10 119.0(2) . . ?
C4 C6 H6 118.8 . . ?
C7 C6 C4 122.4(2) . . ?
C7 C6 H6 118.8 . . ?
C13 C14 H14 119.8 . . ?
C13 C14 C15 120.3(2) . . ?
C15 C14 H14 119.8 . . ?
C17 C16 H16 120.0 . . ?
C17 C16 C15 120.0(2) . . ?
C15 C16 H16 120.0 . . ?
O3 C18 H18A 109.7 . . ?
O3 C18 H18B 109.7 . . ?
O3 C18 C19 109.8(2) . . ?
H18A C18 H18B 108.2 . . ?
C19 C18 H18A 109.7 . . ?
C19 C18 H18B 109.7 . . ?
C1 C2 H2A 109.3 . . ?
C1 C2 H2B 109.3 . . ?
C1 C2 C3 111.4(2) . . ?
H2A C2 H2B 108.0 . . ?
C3 C2 H2A 109.3 . . ?
C3 C2 H2B 109.3 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C4 C3 C2 111.38(19) . . ?
C4 C3 H3A 109.4 . . ?
C4 C3 H3B 109.4 . . ?
C2 C3 H3A 109.4 . . ?
C2 C3 H3B 109.4 . . ?
H3A C3 H3B 108.0 . . ?
C14 C15 H15 120.1 . . ?
C16 C15 C14 119.9(2) . . ?
C16 C15 H15 120.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 O3 C18 C19 107.2(2) . . . . ?
P1 N1 C5 C9 1.4(3) . . . . ?
P1 N1 C5 C4 -177.89(17) . . . . ?
P1 N1 C1 C2 149.32(18) . . . . ?
P1 C10 C11 O1 116.1(2) . . . . ?
P1 C10 C11 C12 -62.5(2) . . . . ?
O2 P1 O3 C18 -9.8(2) . . . . ?
O2 P1 N1 C5 124.33(16) . . . . ?
O2 P1 N1 C1 -59.7(2) . . . . ?
O2 P1 C10 C9 -125.17(15) . . . . ?
O2 P1 C10 C11 110.72(17) . . . . ?
O3 P1 N1 C5 -110.51(16) . . . . ?
O3 P1 N1 C1 65.5(2) . . . . ?
O3 P1 C10 C9 107.41(14) . . . . ?
O3 P1 C10 C11 -16.69(18) . . . . ?
N1 P1 O3 C18 -138.89(19) . . . . ?
N1 P1 C10 C9 0.75(16) . . . . ?
N1 P1 C10 C11 -123.36(17) . . . . ?
N1 C1 C2 C3 56.9(3) . . . . ?
C9 C10 C11 O1 -2.4(3) . . . . ?
C9 C10 C11 C12 178.98(19) . . . . ?
C9 C8 C7 C6 0.9(4) . . . . ?
C10 P1 O3 C18 120.97(19) . . . . ?
C10 P1 N1 C5 -1.26(17) . . . . ?
C10 P1 N1 C1 174.74(19) . . . . ?
C10 C9 C5 N1 -0.8(3) . . . . ?
C10 C9 C5 C4 178.5(2) . . . . ?
C10 C9 C8 C7 -179.5(2) . . . . ?
C5 N1 C1 C2 -34.9(3) . . . . ?
C5 C9 C10 P1 -0.1(2) . . . . ?
C5 C9 C10 C11 123.4(2) . . . . ?
C5 C9 C8 C7 -0.2(3) . . . . ?
C5 C4 C6 C7 -0.5(3) . . . . ?
C5 C4 C3 C2 21.3(3) . . . . ?
C17 C12 C13 C14 -1.7(3) . . . . ?
C17 C12 C11 C10 168.7(2) . . . . ?
C17 C12 C11 O1 -10.0(3) . . . . ?
C17 C16 C15 C14 -0.2(4) . . . . ?
C12 C17 C16 C15 -0.2(4) . . . . ?
C12 C13 C14 C15 1.4(3) . . . . ?
C8 C9 C10 P1 179.3(2) . . . . ?
C8 C9 C10 C11 -57.2(3) . . . . ?
C8 C9 C5 N1 179.7(2) . . . . ?
C8 C9 C5 C4 -0.9(3) . . . . ?
C8 C7 C6 C4 -0.6(4) . . . . ?
C13 C12 C11 C10 -10.1(3) . . . . ?
C13 C12 C11 O1 171.2(2) . . . . ?
C13 C14 C15 C16 -0.4(4) . . . . ?
C1 N1 C5 C9 -174.9(2) . . . . ?
C1 N1 C5 C4 5.8(3) . . . . ?
C1 C2 C3 C4 -50.6(3) . . . . ?
C11 C12 C13 C14 177.0(2) . . . . ?
C6 C4 C5 N1 -179.5(2) . . . . ?
C6 C4 C5 C9 1.2(3) . . . . ?
C6 C4 C3 C2 -157.8(2) . . . . ?
C16 C17 C12 C13 1.1(3) . . . . ?
C16 C17 C12 C11 -177.7(2) . . . . ?
C3 C4 C5 N1 1.3(3) . . . . ?
C3 C4 C5 C9 -178.0(2) . . . . ?
C3 C4 C6 C7 178.7(2) . . . . ?

_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
_solvent_exptl_crystal_recrystallization_method 'ethyl acetate'
