# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 874430'
_audit_update_record             
;
2016-03-08 deposited with the CCDC.
2016-06-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H38 Cu N4 O10'
_chemical_formula_weight         606.12

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.802(3)
_cell_length_b                   11.002(4)
_cell_length_c                   14.295(5)
_cell_angle_alpha                85.036(6)
_cell_angle_beta                 87.910(6)
_cell_angle_gamma                65.323(5)
_cell_volume                     1395.6(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.442
_exptl_crystal_F_000             638
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    0.843
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            8466
_diffrn_reflns_av_unetI/netI     0.0585
_diffrn_reflns_av_R_equivalents  0.0378
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.430
_diffrn_reflns_theta_max         23.924
_diffrn_reflns_theta_full        23.924
_diffrn_measured_fraction_theta_max 0.962
_diffrn_measured_fraction_theta_full 0.962
_diffrn_reflns_Laue_measured_fraction_max 0.962
_diffrn_reflns_Laue_measured_fraction_full 0.962
_diffrn_reflns_point_group_measured_fraction_max 0.962
_diffrn_reflns_point_group_measured_fraction_full 0.962
_reflns_number_total             4183
_reflns_number_gt                3470
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1385P)²+19.7356P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4183
_refine_ls_number_parameters     352
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1263
_refine_ls_R_factor_gt           0.1143
_refine_ls_wR_factor_ref         0.3309
_refine_ls_wR_factor_gt          0.3230
_refine_ls_goodness_of_fit_ref   1.127
_refine_ls_restrained_S_all      1.127
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.21260(13) 0.24141(12) 0.63648(10) 0.0368(5) Uani 1 1 d . . . . .
C1 C 0.4587(12) 0.2842(11) 0.7087(8) 0.040(3) Uani 1 1 d . . . . .
C2 C 0.5421(12) 0.1337(10) 0.7283(8) 0.040(3) Uani 1 1 d . . . . .
H2 H 0.6496 0.1125 0.7281 0.048 Uiso 1 1 calc R U . . .
C3 C 0.5167(11) 0.0483(9) 0.6584(8) 0.034(2) Uani 1 1 d . . . . .
C4 C 0.5023(17) 0.0918(14) 0.8260(9) 0.060(3) Uani 1 1 d . . . . .
H4A H 0.3945 0.1194 0.8288 0.072 Uiso 1 1 calc R U . . .
H4B H 0.5493 -0.0054 0.8349 0.072 Uiso 1 1 calc R U . . .
C5 C 0.547(3) 0.147(2) 0.9071(12) 0.103(7) Uani 1 1 d . . . . .
H5A H 0.5100 0.2438 0.8952 0.124 Uiso 1 1 calc R U . . .
H5B H 0.4991 0.1294 0.9638 0.124 Uiso 1 1 calc R U . . .
C6 C 0.714(3) 0.091(3) 0.9243(14) 0.124(10) Uani 1 1 d . . . . .
H6A H 0.7312 0.1438 0.9690 0.149 Uiso 1 1 calc R U . . .
H6B H 0.7611 0.1032 0.8658 0.149 Uiso 1 1 calc R U . . .
C7 C 0.793(3) -0.055(3) 0.9597(16) 0.124(8) Uani 1 1 d . . . . .
H7A H 0.8975 -0.0773 0.9675 0.186 Uiso 1 1 calc R U . . .
H7B H 0.7503 -0.0692 1.0190 0.186 Uiso 1 1 calc R U . . .
H7C H 0.7804 -0.1100 0.9153 0.186 Uiso 1 1 calc R U . . .
C8 C -0.0886(12) 0.4179(10) 0.6749(8) 0.037(2) Uani 1 1 d . . . . .
C9 C -0.1013(12) 0.3010(10) 0.7321(8) 0.038(2) Uani 1 1 d . . . . .
H9 H -0.2079 0.3227 0.7435 0.046 Uiso 1 1 calc R U . . .
C10 C -0.0311(11) 0.1686(10) 0.6865(8) 0.035(2) Uani 1 1 d . . . . .
C11 C -0.0225(19) 0.2799(16) 0.8276(9) 0.068(4) Uani 1 1 d . . . . .
H11A H -0.0256 0.2008 0.8614 0.081 Uiso 1 1 calc R U . . .
H11B H 0.0823 0.2604 0.8153 0.081 Uiso 1 1 calc R U . . .
C12 C -0.081(2) 0.3892(17) 0.8901(11) 0.080(5) Uani 1 1 d . . . . .
H12A H -0.0082 0.3696 0.9399 0.096 Uiso 1 1 calc R U . . .
H12B H -0.0879 0.4709 0.8547 0.096 Uiso 1 1 calc R U . . .
C13 C -0.224(3) 0.414(2) 0.9323(18) 0.120(8) Uani 1 1 d . . . . .
H13A H -0.2151 0.3350 0.9718 0.144 Uiso 1 1 calc R U . . .
H13B H -0.2953 0.4278 0.8830 0.144 Uiso 1 1 calc R U . . .
C14 C -0.290(3) 0.541(2) 0.9945(17) 0.135(10) Uani 1 1 d . . . . .
H14A H -0.3852 0.5503 1.0199 0.202 Uiso 1 1 calc R U . . .
H14B H -0.2215 0.5276 1.0448 0.202 Uiso 1 1 calc R U . . .
H14C H -0.3018 0.6205 0.9558 0.202 Uiso 1 1 calc R U . . .
C15 C 0.2133(13) 0.6654(11) 0.7667(8) 0.043(3) Uani 1 1 d . . . . .
C16 C 0.1507(15) 0.7922(13) 0.7984(9) 0.054(3) Uani 1 1 d . . . . .
H16 H 0.0480 0.8337 0.8098 0.065 Uiso 1 1 calc R U . . .
C17 C 0.2390(19) 0.8562(13) 0.8130(10) 0.069(4) Uani 1 1 d . . . . .
H17 H 0.1959 0.9420 0.8338 0.082 Uiso 1 1 calc R U . . .
C18 C 0.393(2) 0.7962(16) 0.7973(11) 0.075(4) Uani 1 1 d . . . . .
H18 H 0.4531 0.8406 0.8062 0.091 Uiso 1 1 calc R U . . .
C19 C 0.4515(15) 0.6695(13) 0.7684(10) 0.058(3) Uani 1 1 d . . . . .
H19 H 0.5544 0.6251 0.7587 0.070 Uiso 1 1 calc R U . . .
C20 C 0.1162(11) 0.8188(11) 0.5586(8) 0.038(2) Uani 1 1 d . . . . .
C21 C 0.1809(13) 0.6970(11) 0.5172(8) 0.043(3) Uani 1 1 d . . . . .
H21 H 0.1234 0.6499 0.5078 0.051 Uiso 1 1 calc R U . . .
C22 C 0.3279(13) 0.6465(11) 0.4905(9) 0.046(3) Uani 1 1 d . . . . .
H22 H 0.3700 0.5656 0.4626 0.055 Uiso 1 1 calc R U . . .
C23 C 0.4145(13) 0.7150(12) 0.5047(9) 0.047(3) Uani 1 1 d . . . . .
H23 H 0.5148 0.6803 0.4866 0.057 Uiso 1 1 calc R U . . .
C24 C 0.3543(13) 0.8303(11) 0.5443(8) 0.044(3) Uani 1 1 d . . . . .
H24 H 0.4125 0.8763 0.5546 0.053 Uiso 1 1 calc R U . . .
N1 N 0.3620(11) 0.6085(9) 0.7538(7) 0.047(2) Uani 1 1 d . . . . .
H1 H 0.4022 0.5288 0.7352 0.056 Uiso 1 1 calc R U . . .
N2 N 0.1341(12) 0.5991(10) 0.7489(8) 0.057(3) Uani 1 1 d . . . . .
H2A H 0.1779 0.5201 0.7292 0.068 Uiso 1 1 calc R U . . .
H2B H 0.0384 0.6345 0.7569 0.068 Uiso 1 1 calc R U . . .
N3 N 0.2039(10) 0.8827(9) 0.5704(6) 0.040(2) Uani 1 1 d . . . . .
H3 H 0.1659 0.9585 0.5949 0.048 Uiso 1 1 calc R U . . .
N4 N -0.0228(11) 0.8724(10) 0.5865(7) 0.052(3) Uani 1 1 d . . . . .
H4C H -0.0569 0.9474 0.6120 0.062 Uiso 1 1 calc R U . . .
H4D H -0.0806 0.8327 0.5795 0.062 Uiso 1 1 calc R U . . .
O1 O 0.3263(8) 0.3355(7) 0.6777(6) 0.048(2) Uani 1 1 d . . . . .
O2 O 0.5230(9) 0.3551(7) 0.7259(7) 0.054(2) Uani 1 1 d . . . . .
O3 O 0.3909(8) 0.0778(7) 0.6251(6) 0.0445(19) Uani 1 1 d . . . . .
O4 O 0.6272(8) -0.0590(7) 0.6412(6) 0.0451(19) Uani 1 1 d . . . . .
O5 O 0.0348(7) 0.4066(6) 0.6405(6) 0.0371(17) Uani 1 1 d . . . . .
O6 O -0.2042(8) 0.5221(7) 0.6633(6) 0.047(2) Uani 1 1 d . . . . .
O7 O 0.0964(8) 0.1349(7) 0.6439(5) 0.0390(17) Uani 1 1 d . . . . .
O8 O -0.0967(9) 0.0939(8) 0.6931(7) 0.054(2) Uani 1 1 d . . . . .
O1W O 0.2170(8) 0.2679(7) 0.4746(6) 0.0428(18) Uani 1 1 d . . . . .
H1W1 H 0.2899 0.2016 0.4533 0.051 Uiso 1 1 d R U . . .
H2W1 H 0.2122 0.3386 0.4430 0.051 Uiso 1 1 d R U . . .
O2W O -0.1918(10) 0.7306(10) 0.7645(7) 0.063(2) Uani 1 1 d . . . . .
H1W2 H -0.2153 0.6667 0.7545 0.076 Uiso 1 1 d R U . . .
H2W2 H -0.2660 0.8038 0.7482 0.076 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 O5 1.926(6) . ?
Cu1 O3 1.930(7) . ?
Cu1 O7 1.941(7) . ?
Cu1 O1 1.944(7) . ?
Cu1 O1W 2.308(8) . ?
C1 O2 1.232(13) . ?
C1 O1 1.260(13) . ?
C1 C2 1.515(15) . ?
C2 C4 1.522(18) . ?
C2 C3 1.522(15) . ?
C2 H2 0.9800 . ?
C3 O3 1.238(12) . ?
C3 O4 1.262(12) . ?
C4 C5 1.51(2) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.50(3) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 C7 1.50(3) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 O6 1.234(13) . ?
C8 O5 1.251(12) . ?
C8 C9 1.510(15) . ?
C9 C10 1.521(14) . ?
C9 C11 1.546(18) . ?
C9 H9 0.9800 . ?
C10 O8 1.233(13) . ?
C10 O7 1.291(12) . ?
C11 C12 1.46(2) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 C13 1.43(3) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.60(3) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 N2 1.311(15) . ?
C15 N1 1.337(15) . ?
C15 C16 1.380(17) . ?
C16 C17 1.36(2) . ?
C16 H16 0.9300 . ?
C17 C18 1.39(2) . ?
C17 H17 0.9300 . ?
C18 C19 1.36(2) . ?
C18 H18 0.9300 . ?
C19 N1 1.338(16) . ?
C19 H19 0.9300 . ?
C20 N4 1.301(14) . ?
C20 N3 1.340(14) . ?
C20 C21 1.396(16) . ?
C21 C22 1.364(16) . ?
C21 H21 0.9300 . ?
C22 C23 1.379(16) . ?
C22 H22 0.9300 . ?
C23 C24 1.324(16) . ?
C23 H23 0.9300 . ?
C24 N3 1.390(14) . ?
C24 H24 0.9300 . ?
N1 H1 0.8600 . ?
N2 H2A 0.8600 . ?
N2 H2B 0.8600 . ?
N3 H3 0.8600 . ?
N4 H4C 0.8600 . ?
N4 H4D 0.8600 . ?
O1W H1W1 0.8499 . ?
O1W H2W1 0.8499 . ?
O2W H1W2 0.8500 . ?
O2W H2W2 0.8499 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Cu1 O3 176.9(4) . . ?
O5 Cu1 O7 92.3(3) . . ?
O3 Cu1 O7 88.3(3) . . ?
O5 Cu1 O1 88.0(3) . . ?
O3 Cu1 O1 92.6(3) . . ?
O7 Cu1 O1 159.2(4) . . ?
O5 Cu1 O1W 91.0(3) . . ?
O3 Cu1 O1W 85.9(3) . . ?
O7 Cu1 O1W 95.9(3) . . ?
O1 Cu1 O1W 104.8(3) . . ?
O2 C1 O1 121.0(10) . . ?
O2 C1 C2 118.1(10) . . ?
O1 C1 C2 120.8(9) . . ?
C1 C2 C4 109.6(9) . . ?
C1 C2 C3 116.1(9) . . ?
C4 C2 C3 108.5(9) . . ?
C1 C2 H2 107.4 . . ?
C4 C2 H2 107.4 . . ?
C3 C2 H2 107.4 . . ?
O3 C3 O4 121.4(9) . . ?
O3 C3 C2 121.6(9) . . ?
O4 C3 C2 116.9(9) . . ?
C5 C4 C2 116.1(13) . . ?
C5 C4 H4A 108.3 . . ?
C2 C4 H4A 108.3 . . ?
C5 C4 H4B 108.3 . . ?
C2 C4 H4B 108.3 . . ?
H4A C4 H4B 107.4 . . ?
C6 C5 C4 114.6(17) . . ?
C6 C5 H5A 108.6 . . ?
C4 C5 H5A 108.6 . . ?
C6 C5 H5B 108.6 . . ?
C4 C5 H5B 108.6 . . ?
H5A C5 H5B 107.6 . . ?
C5 C6 C7 118.3(18) . . ?
C5 C6 H6A 107.7 . . ?
C7 C6 H6A 107.7 . . ?
C5 C6 H6B 107.7 . . ?
C7 C6 H6B 107.7 . . ?
H6A C6 H6B 107.1 . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
O6 C8 O5 122.4(10) . . ?
O6 C8 C9 117.3(9) . . ?
O5 C8 C9 120.3(9) . . ?
C8 C9 C10 114.5(9) . . ?
C8 C9 C11 109.1(9) . . ?
C10 C9 C11 107.3(10) . . ?
C8 C9 H9 108.6 . . ?
C10 C9 H9 108.6 . . ?
C11 C9 H9 108.6 . . ?
O8 C10 O7 121.3(9) . . ?
O8 C10 C9 118.6(9) . . ?
O7 C10 C9 120.1(9) . . ?
C12 C11 C9 118.1(14) . . ?
C12 C11 H11A 107.8 . . ?
C9 C11 H11A 107.8 . . ?
C12 C11 H11B 107.8 . . ?
C9 C11 H11B 107.8 . . ?
H11A C11 H11B 107.1 . . ?
C13 C12 C11 116.2(16) . . ?
C13 C12 H12A 108.2 . . ?
C11 C12 H12A 108.2 . . ?
C13 C12 H12B 108.2 . . ?
C11 C12 H12B 108.2 . . ?
H12A C12 H12B 107.4 . . ?
C12 C13 C14 115.0(19) . . ?
C12 C13 H13A 108.5 . . ?
C14 C13 H13A 108.5 . . ?
C12 C13 H13B 108.5 . . ?
C14 C13 H13B 108.5 . . ?
H13A C13 H13B 107.5 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N2 C15 N1 119.1(10) . . ?
N2 C15 C16 123.1(12) . . ?
N1 C15 C16 117.8(11) . . ?
C17 C16 C15 119.9(13) . . ?
C17 C16 H16 120.1 . . ?
C15 C16 H16 120.1 . . ?
C16 C17 C18 121.2(13) . . ?
C16 C17 H17 119.4 . . ?
C18 C17 H17 119.4 . . ?
C19 C18 C17 117.4(14) . . ?
C19 C18 H18 121.3 . . ?
C17 C18 H18 121.3 . . ?
N1 C19 C18 120.3(13) . . ?
N1 C19 H19 119.8 . . ?
C18 C19 H19 119.8 . . ?
N4 C20 N3 118.8(10) . . ?
N4 C20 C21 123.8(11) . . ?
N3 C20 C21 117.4(10) . . ?
C22 C21 C20 120.4(10) . . ?
C22 C21 H21 119.8 . . ?
C20 C21 H21 119.8 . . ?
C21 C22 C23 120.3(11) . . ?
C21 C22 H22 119.9 . . ?
C23 C22 H22 119.9 . . ?
C24 C23 C22 119.7(11) . . ?
C24 C23 H23 120.1 . . ?
C22 C23 H23 120.1 . . ?
C23 C24 N3 120.0(10) . . ?
C23 C24 H24 120.0 . . ?
N3 C24 H24 120.0 . . ?
C15 N1 C19 123.3(10) . . ?
C15 N1 H1 118.3 . . ?
C19 N1 H1 118.3 . . ?
C15 N2 H2A 120.0 . . ?
C15 N2 H2B 120.0 . . ?
H2A N2 H2B 120.0 . . ?
C20 N3 C24 122.1(9) . . ?
C20 N3 H3 118.9 . . ?
C24 N3 H3 118.9 . . ?
C20 N4 H4C 120.0 . . ?
C20 N4 H4D 120.0 . . ?
H4C N4 H4D 120.0 . . ?
C1 O1 Cu1 127.2(7) . . ?
C3 O3 Cu1 127.4(7) . . ?
C8 O5 Cu1 125.5(6) . . ?
C10 O7 Cu1 124.0(6) . . ?
Cu1 O1W H1W1 110.1 . . ?
Cu1 O1W H2W1 124.6 . . ?
H1W1 O1W H2W1 107.7 . . ?
H1W2 O2W H2W2 107.7 . . ?

_refine_diff_density_max         2.495
_refine_diff_density_min         -1.268
_refine_diff_density_rms         0.164

