# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_151204g
_audit_block_doi                 10.5517/ccdc.csd.cc1kl9gx
_database_code_depnum_ccdc_archive 'CCDC 1447559'
_audit_update_record             
;
2016-07-12 deposited with the CCDC.
2016-07-14 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C56 H72 Ag4 N8 O21'
_chemical_formula_weight         1624.70

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   15.6811(14)
_cell_length_b                   18.0103(15)
_cell_length_c                   23.9667(19)
_cell_angle_alpha                90.00
_cell_angle_beta                 94.5940(10)
_cell_angle_gamma                90.00
_cell_volume                     6747.0(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    3489
_cell_measurement_theta_min      2.793
_cell_measurement_theta_max      22.394

_exptl_crystal_description       block
_exptl_crystal_colour            white
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.11
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3280
_exptl_absorpt_coefficient_mu    1.219
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6284
_exptl_absorpt_correction_T_max  0.8775
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            33136
_diffrn_reflns_av_R_equivalents  0.1027
_diffrn_reflns_av_sigmaI/netI    0.1524
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.26
_diffrn_reflns_theta_max         25.02
_reflns_number_total             11853
_reflns_number_gt                4343
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0398P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11853
_refine_ls_number_parameters     812
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1960
_refine_ls_R_factor_gt           0.0698
_refine_ls_wR_factor_ref         0.1720
_refine_ls_wR_factor_gt          0.1447
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_restrained_S_all      1.073
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.30239(6) 0.78963(5) 0.51800(3) 0.0535(3) Uani 1 1 d . . .
Ag2 Ag 0.48826(6) 0.71479(5) 0.48605(3) 0.0573(3) Uani 1 1 d . . .
Ag3 Ag 0.96708(6) 0.77660(5) 0.46092(3) 0.0562(3) Uani 1 1 d . . .
Ag4 Ag 0.83594(6) 0.70885(5) 0.55463(3) 0.0561(3) Uani 1 1 d . . .
N1 N 0.2090(6) 0.7721(5) 0.4460(3) 0.046(3) Uani 1 1 d . . .
N2 N 0.3657(6) 0.7666(6) 0.6024(3) 0.047(3) Uani 1 1 d . . .
N3 N 0.4096(6) 0.7079(6) 0.4060(3) 0.054(3) Uani 1 1 d . . .
N4 N 0.5742(6) 0.7199(6) 0.5613(3) 0.048(2) Uani 1 1 d . . .
N5 N 1.0575(6) 0.7794(6) 0.5354(3) 0.050(3) Uani 1 1 d . . .
N6 N 0.8883(6) 0.7770(6) 0.3823(3) 0.052(3) Uani 1 1 d . . .
N7 N 0.9052(6) 0.7305(5) 0.6359(3) 0.046(3) Uani 1 1 d . . .
N8 N 0.7392(6) 0.7302(6) 0.4844(3) 0.050(3) Uani 1 1 d . . .
O1 O 0.3337(5) 0.9321(5) 0.5043(3) 0.065(2) Uani 1 1 d . . .
O2 O 0.4493(5) 0.8623(4) 0.4919(3) 0.058(2) Uani 1 1 d . . .
O3 O 0.3657(7) 0.9944(6) 0.3651(3) 0.087(3) Uani 1 1 d . . .
O4 O 0.4810(6) 0.9721(6) 0.3205(3) 0.097(4) Uani 1 1 d . . .
O5 O 0.9297(5) 0.6352(4) 0.4820(3) 0.059(2) Uani 1 1 d . . .
O6 O 0.8517(5) 0.5662(5) 0.5377(3) 0.069(3) Uani 1 1 d . . .
O7 O 0.8082(8) 0.4885(7) 0.4010(5) 0.114(4) Uani 1 1 d . . .
O8 O 0.8864(8) 0.5112(6) 0.3285(5) 0.137(5) Uani 1 1 d . . .
O9 O 0.2605(6) 0.9683(5) 0.2649(4) 0.127(4) Uani 1 1 d . . .
H9C H 0.2974 0.9785 0.2917 0.152 Uiso 1 1 d R . .
H9D H 0.2817 0.9781 0.2342 0.152 Uiso 1 1 d R . .
O10 O 0.7262(6) 0.4516(5) 0.4949(4) 0.119(4) Uani 1 1 d . . .
H10C H 0.7560 0.4819 0.5155 0.142 Uiso 1 1 d R . .
H10D H 0.7425 0.4545 0.4620 0.142 Uiso 1 1 d R . .
O11 O 0.2346(7) 0.0375(5) 0.4332(5) 0.138(4) Uani 1 1 d . . .
H11C H 0.2536 0.0098 0.4600 0.166 Uiso 1 1 d R . .
H11D H 0.2674 0.0327 0.4068 0.166 Uiso 1 1 d R . .
O12 O 0.8094(7) 0.5037(5) 0.6410(4) 0.124(4) Uani 1 1 d . . .
H12C H 0.8237 0.5220 0.6104 0.148 Uiso 1 1 d R . .
H12D H 0.8545 0.4935 0.6615 0.148 Uiso 1 1 d R . .
O13 O 0.0466(7) 0.5326(5) 0.2871(3) 0.117(4) Uani 1 1 d . . .
H13C H 0.0414 0.5149 0.2541 0.141 Uiso 1 1 d R . .
H13D H -0.0008 0.5273 0.3015 0.141 Uiso 1 1 d R . .
O14 O 0.0808(8) 0.9816(6) 0.2700(4) 0.153(5) Uani 1 1 d . . .
H14C H 0.1341 0.9772 0.2665 0.184 Uiso 1 1 d R . .
H14D H 0.0739 0.9906 0.3041 0.184 Uiso 1 1 d R . .
O15 O 0.2388(8) 0.0074(6) 0.5806(5) 0.162(5) Uani 1 1 d . . .
H15C H 0.2674 -0.0152 0.5572 0.195 Uiso 1 1 d R . .
H15D H 0.2691 0.0103 0.6115 0.195 Uiso 1 1 d R . .
O16 O 0.9343(7) 0.9533(6) 0.4658(4) 0.153(5) Uani 1 1 d . . .
H16C H 0.8848 0.9652 0.4517 0.183 Uiso 1 1 d R . .
H16D H 0.9432 0.9718 0.4984 0.183 Uiso 1 1 d R . .
O17 O 0.6548(8) 0.9833(6) 0.3093(5) 0.164(5) Uani 1 1 d . . .
H17C H 0.6038 0.9789 0.3185 0.197 Uiso 1 1 d R . .
H17D H 0.6527 0.9911 0.2742 0.197 Uiso 1 1 d R . .
O18 O 0.4481(7) 0.5298(6) 0.5393(5) 0.159(5) Uani 1 1 d . . .
H18C H 0.3960 0.5331 0.5267 0.238 Uiso 1 1 d R . .
H18D H 0.4765 0.5107 0.5142 0.238 Uiso 0.50 1 d PR A -1
H18E H 0.4523 0.5018 0.5679 0.238 Uiso 0.50 1 d PR B 1
O19 O 0.9352(8) 0.9866(6) 0.6117(5) 0.158(5) Uani 1 1 d . . .
H19C H 0.8854 0.9812 0.5954 0.190 Uiso 1 1 d R . .
H19D H 0.9681 1.0029 0.5880 0.190 Uiso 1 1 d R . .
O20 O 0.7110(10) 0.5152(7) 0.2841(6) 0.219(7) Uani 1 1 d . . .
H20C H 0.7104 0.5060 0.3188 0.263 Uiso 1 1 d R . .
H20D H 0.7630 0.5194 0.2771 0.263 Uiso 1 1 d R . .
O21 O 0.9633(13) 0.0169(9) 0.1736(8) 0.138(10) Uani 0.602(18) 1 d P C 1
H21E H 0.9982 0.0066 0.2015 0.165 Uiso 0.602(18) 1 d PR C 1
H21F H 0.9129 0.0158 0.1842 0.165 Uiso 0.602(18) 1 d PR C 1
O21' O 0.885(2) 0.0009(13) 0.1230(13) 0.137(15) Uani 0.398(18) 1 d P C 2
H21G H 0.8307 -0.0025 0.1166 0.165 Uiso 0.398(18) 1 d PR C 2
H21H H 0.9076 -0.0102 0.0931 0.165 Uiso 0.398(18) 1 d PR C 2
C1 C 0.4116(9) 0.9231(7) 0.4910(4) 0.050(3) Uani 1 1 d . . .
C2 C 0.4640(7) 0.9922(6) 0.4754(4) 0.042(3) Uani 1 1 d . . .
H2 H 0.4252 1.0349 0.4728 0.050 Uiso 1 1 calc R . .
C3 C 0.5017(7) 0.9832(6) 0.4190(4) 0.056(3) Uani 1 1 d . . .
H3A H 0.5336 0.9370 0.4204 0.067 Uiso 1 1 calc R . .
H3B H 0.5429 1.0229 0.4159 0.067 Uiso 1 1 calc R . .
C4 C 0.4422(11) 0.9827(8) 0.3631(6) 0.074(4) Uani 1 1 d . . .
C5 C 0.1794(7) 0.8303(7) 0.4141(4) 0.056(3) Uani 1 1 d . . .
H5 H 0.1950 0.8780 0.4259 0.067 Uiso 1 1 calc R . .
C6 C 0.1264(8) 0.8224(7) 0.3641(4) 0.061(4) Uani 1 1 d . . .
H6 H 0.1085 0.8637 0.3430 0.073 Uiso 1 1 calc R . .
C7 C 0.1010(8) 0.7500(7) 0.3471(5) 0.053(3) Uani 1 1 d . . .
C8 C 0.1286(7) 0.6901(7) 0.3816(4) 0.056(3) Uani 1 1 d . . .
H8 H 0.1109 0.6419 0.3727 0.067 Uiso 1 1 calc R . .
C9 C 0.1820(7) 0.7039(7) 0.4282(4) 0.052(3) Uani 1 1 d . . .
H9 H 0.2015 0.6633 0.4495 0.062 Uiso 1 1 calc R . .
C10 C 0.3922(7) 0.8238(6) 0.6352(4) 0.049(3) Uani 1 1 d . . .
H10 H 0.3772 0.8718 0.6239 0.058 Uiso 1 1 calc R . .
C11 C 0.4418(7) 0.8134(7) 0.6859(4) 0.052(3) Uani 1 1 d . . .
H11 H 0.4604 0.8543 0.7072 0.063 Uiso 1 1 calc R . .
C12 C 0.4635(7) 0.7412(7) 0.7046(4) 0.048(3) Uani 1 1 d . . .
C13 C 0.4326(7) 0.6833(6) 0.6708(4) 0.053(3) Uani 1 1 d . . .
H13 H 0.4436 0.6345 0.6819 0.063 Uiso 1 1 calc R . .
C14 C 0.3853(8) 0.6970(7) 0.6204(5) 0.059(4) Uani 1 1 d . . .
H14 H 0.3664 0.6570 0.5982 0.071 Uiso 1 1 calc R . .
C15 C 0.0447(8) 0.7307(8) 0.2942(5) 0.068(4) Uani 1 1 d . . .
H15 H 0.0305 0.6810 0.2888 0.081 Uiso 1 1 calc R . .
C16 C 0.0156(7) 0.7759(7) 0.2570(5) 0.061(4) Uani 1 1 d . . .
H16 H 0.0286 0.8257 0.2635 0.073 Uiso 1 1 calc R . .
C17 C 0.3854(7) 0.7726(7) 0.3807(4) 0.048(3) Uani 1 1 d . . .
H17 H 0.4003 0.8170 0.3987 0.057 Uiso 1 1 calc R . .
C18 C 0.3395(7) 0.7750(7) 0.3290(4) 0.053(3) Uani 1 1 d . . .
H18 H 0.3260 0.8208 0.3126 0.063 Uiso 1 1 calc R . .
C19 C 0.3129(7) 0.7096(7) 0.3008(4) 0.048(3) Uani 1 1 d . . .
C20 C 0.3366(7) 0.6423(6) 0.3290(4) 0.056(3) Uani 1 1 d . . .
H20 H 0.3192 0.5971 0.3132 0.067 Uiso 1 1 calc R . .
C21 C 0.3850(7) 0.6435(7) 0.3793(4) 0.056(3) Uani 1 1 d . . .
H21 H 0.4017 0.5985 0.3959 0.068 Uiso 1 1 calc R . .
C22 C 0.5964(7) 0.7865(7) 0.5859(4) 0.050(3) Uani 1 1 d . . .
H22 H 0.5748 0.8297 0.5688 0.059 Uiso 1 1 calc R . .
C23 C 0.6486(7) 0.7931(6) 0.6342(4) 0.050(3) Uani 1 1 d . . .
H23 H 0.6614 0.8402 0.6485 0.060 Uiso 1 1 calc R . .
C24 C 0.6838(7) 0.7302(7) 0.6629(4) 0.047(3) Uani 1 1 d . . .
C25 C 0.6633(7) 0.6616(6) 0.6371(4) 0.054(3) Uani 1 1 d . . .
H25 H 0.6851 0.6180 0.6534 0.065 Uiso 1 1 calc R . .
C26 C 0.6103(7) 0.6582(7) 0.5873(4) 0.056(3) Uani 1 1 d . . .
H26 H 0.5991 0.6119 0.5710 0.067 Uiso 1 1 calc R . .
C27 C 0.2599(7) 0.7081(7) 0.2463(4) 0.053(3) Uani 1 1 d . . .
H27 H 0.2425 0.6619 0.2321 0.064 Uiso 1 1 calc R . .
C28 C 0.7358(7) 0.7328(6) 0.7167(4) 0.051(3) Uani 1 1 d . . .
H28 H 0.7539 0.6873 0.7316 0.061 Uiso 1 1 calc R . .
C29 C 0.9087(9) 0.5737(7) 0.5027(5) 0.058(4) Uani 1 1 d . . .
C30 C 0.9543(7) 0.5014(6) 0.4848(5) 0.057(3) Uani 1 1 d . . .
H30 H 0.9215 0.4579 0.4953 0.069 Uiso 1 1 calc R . .
C31 C 0.9619(8) 0.5011(6) 0.4191(5) 0.064(4) Uani 1 1 d . . .
H31A H 0.9944 0.5445 0.4094 0.077 Uiso 1 1 calc R . .
H31B H 0.9942 0.4576 0.4096 0.077 Uiso 1 1 calc R . .
C32 C 0.8761(13) 0.5012(10) 0.3830(8) 0.090(6) Uani 1 1 d . . .
C33 C 1.0865(8) 0.8446(7) 0.5598(5) 0.064(4) Uani 1 1 d . . .
H33 H 1.0710 0.8894 0.5427 0.077 Uiso 1 1 calc R . .
C34 C 1.1385(8) 0.8449(7) 0.6095(5) 0.060(4) Uani 1 1 d . . .
H34 H 1.1587 0.8898 0.6245 0.072 Uiso 1 1 calc R . .
C35 C 1.1610(7) 0.7784(7) 0.6375(4) 0.050(3) Uani 1 1 d . . .
C36 C 1.1332(7) 0.7129(7) 0.6104(4) 0.052(3) Uani 1 1 d . . .
H36 H 1.1493 0.6670 0.6257 0.062 Uiso 1 1 calc R . .
C37 C 1.0811(7) 0.7168(7) 0.5603(4) 0.053(3) Uani 1 1 d . . .
H37 H 1.0621 0.6725 0.5436 0.064 Uiso 1 1 calc R . .
C38 C 0.8681(8) 0.8404(7) 0.3537(5) 0.064(4) Uani 1 1 d . . .
H38 H 0.8879 0.8854 0.3688 0.077 Uiso 1 1 calc R . .
C39 C 0.8186(8) 0.8410(7) 0.3023(4) 0.061(4) Uani 1 1 d . . .
H39 H 0.8053 0.8856 0.2842 0.073 Uiso 1 1 calc R . .
C40 C 0.7888(7) 0.7727(7) 0.2781(4) 0.048(3) Uani 1 1 d . . .
C41 C 0.8120(7) 0.7076(7) 0.3083(4) 0.052(3) Uani 1 1 d . . .
H41 H 0.7946 0.6616 0.2940 0.063 Uiso 1 1 calc R . .
C42 C 0.8605(7) 0.7121(7) 0.3588(4) 0.050(3) Uani 1 1 d . . .
H42 H 0.8748 0.6682 0.3777 0.060 Uiso 1 1 calc R . .
C43 C 1.2124(7) 0.7805(7) 0.6923(5) 0.058(3) Uani 1 1 d . . .
H43 H 1.2274 0.8274 0.7060 0.069 Uiso 1 1 calc R . .
C44 C 0.7387(7) 0.7751(7) 0.2235(5) 0.057(3) Uani 1 1 d . . .
H44 H 0.7243 0.8221 0.2097 0.068 Uiso 1 1 calc R . .
C45 C 0.9277(7) 0.8011(7) 0.6531(4) 0.056(3) Uani 1 1 d . . .
H45 H 0.9112 0.8406 0.6297 0.067 Uiso 1 1 calc R . .
C46 C 0.9731(7) 0.8164(7) 0.7030(5) 0.055(3) Uani 1 1 d . . .
H46 H 0.9864 0.8654 0.7125 0.066 Uiso 1 1 calc R . .
C47 C 0.9998(7) 0.7592(7) 0.7399(5) 0.053(3) Uani 1 1 d . . .
C48 C 0.9783(7) 0.6853(7) 0.7225(5) 0.055(3) Uani 1 1 d . . .
H48 H 0.9937 0.6447 0.7451 0.066 Uiso 1 1 calc R . .
C49 C 0.9334(7) 0.6762(7) 0.6704(5) 0.054(3) Uani 1 1 d . . .
H49 H 0.9221 0.6277 0.6586 0.065 Uiso 1 1 calc R . .
C50 C 0.7183(7) 0.7991(7) 0.4659(4) 0.053(3) Uani 1 1 d . . .
H50 H 0.7398 0.8391 0.4873 0.063 Uiso 1 1 calc R . .
C51 C 0.6683(7) 0.8145(7) 0.4183(5) 0.056(4) Uani 1 1 d . . .
H51 H 0.6579 0.8635 0.4076 0.068 Uiso 1 1 calc R . .
C52 C 0.6317(8) 0.7552(7) 0.3849(4) 0.052(3) Uani 1 1 d . . .
C53 C 0.6524(7) 0.6838(7) 0.4052(4) 0.054(3) Uani 1 1 d . . .
H53 H 0.6303 0.6429 0.3852 0.065 Uiso 1 1 calc R . .
C54 C 0.7039(7) 0.6721(7) 0.4534(4) 0.054(3) Uani 1 1 d . . .
H54 H 0.7151 0.6238 0.4654 0.065 Uiso 1 1 calc R . .
C55 C 1.0519(7) 0.7754(7) 0.7934(5) 0.059(4) Uani 1 1 d . . .
H55 H 1.0652 0.8250 0.8004 0.071 Uiso 1 1 calc R . .
C56 C 1.0808(7) 0.7281(7) 0.8315(5) 0.055(3) Uani 1 1 d . . .
H56 H 1.0681 0.6784 0.8245 0.065 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.195(8) . ?
Ag1 N2 2.220(8) . ?
Ag1 O1 2.637(8) . ?
Ag1 Ag2 3.3550(13) . ?
Ag2 N4 2.165(8) . ?
Ag2 N3 2.201(8) . ?
Ag2 O2 2.732(8) . ?
Ag3 N6 2.169(8) . ?
Ag3 N5 2.188(8) . ?
Ag3 O5 2.670(8) . ?
Ag4 N7 2.188(8) . ?
Ag4 N8 2.208(8) . ?
Ag4 O6 2.616(8) . ?
Ag4 O5 2.713(8) . ?
N1 C9 1.357(12) . ?
N1 C5 1.358(12) . ?
N2 C10 1.341(12) . ?
N2 C14 1.352(12) . ?
N3 C17 1.353(12) . ?
N3 C21 1.366(12) . ?
N4 C22 1.369(12) . ?
N4 C26 1.374(12) . ?
N5 C37 1.316(12) . ?
N5 C33 1.373(13) . ?
N6 C38 1.355(13) . ?
N6 C42 1.356(12) . ?
N7 C49 1.334(12) . ?
N7 C45 1.374(12) . ?
N8 C50 1.350(12) . ?
N8 C54 1.373(13) . ?
O1 C1 1.298(13) . ?
O2 C1 1.243(12) . ?
O3 C4 1.223(16) . ?
O4 C4 1.244(15) . ?
O5 C29 1.267(13) . ?
O6 C29 1.281(14) . ?
O7 C32 1.202(19) . ?
O8 C32 1.342(18) . ?
O9 H9C 0.8500 . ?
O9 H9D 0.8498 . ?
O10 H10C 0.8499 . ?
O10 H10D 0.8501 . ?
O11 H11C 0.8500 . ?
O11 H11D 0.8499 . ?
O12 H12C 0.8500 . ?
O12 H12D 0.8500 . ?
O13 H13C 0.8501 . ?
O13 H13D 0.8501 . ?
O14 H14C 0.8501 . ?
O14 H14D 0.8499 . ?
O15 H15C 0.8502 . ?
O15 H15D 0.8501 . ?
O16 H16C 0.8501 . ?
O16 H16D 0.8499 . ?
O17 H17C 0.8500 . ?
O17 H17D 0.8500 . ?
O18 H18C 0.8501 . ?
O18 H18D 0.8494 . ?
O18 H18E 0.8501 . ?
O19 H19C 0.8500 . ?
O19 H19D 0.8499 . ?
O20 H20C 0.8501 . ?
O20 H20D 0.8498 . ?
O21 H21E 0.8500 . ?
O21 H21F 0.8501 . ?
O21' H21G 0.8500 . ?
O21' H21H 0.8502 . ?
C1 C2 1.553(15) . ?
C2 C3 1.528(13) . ?
C2 C2 1.591(18) 3_676 ?
C2 H2 0.9800 . ?
C3 C4 1.569(15) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C5 C6 1.410(13) . ?
C5 H5 0.9300 . ?
C6 C7 1.414(14) . ?
C6 H6 0.9300 . ?
C7 C8 1.406(14) . ?
C7 C15 1.526(14) . ?
C8 C9 1.364(13) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
C10 C11 1.402(13) . ?
C10 H10 0.9300 . ?
C11 C12 1.408(14) . ?
C11 H11 0.9300 . ?
C12 C13 1.385(14) . ?
C12 C16 1.475(14) 4_676 ?
C13 C14 1.388(13) . ?
C13 H13 0.9300 . ?
C14 H14 0.9300 . ?
C15 C16 1.264(14) . ?
C15 H15 0.9300 . ?
C16 C12 1.475(14) 4_575 ?
C16 H16 0.9300 . ?
C17 C18 1.383(12) . ?
C17 H17 0.9300 . ?
C18 C19 1.404(13) . ?
C18 H18 0.9300 . ?
C19 C20 1.423(13) . ?
C19 C27 1.492(13) . ?
C20 C21 1.372(13) . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
C22 C23 1.368(12) . ?
C22 H22 0.9300 . ?
C23 C24 1.415(13) . ?
C23 H23 0.9300 . ?
C24 C25 1.406(14) . ?
C24 C28 1.469(13) . ?
C25 C26 1.401(13) . ?
C25 H25 0.9300 . ?
C26 H26 0.9300 . ?
C27 C28 1.318(13) 4_575 ?
C27 H27 0.9300 . ?
C28 C27 1.318(13) 4_676 ?
C28 H28 0.9300 . ?
C29 C30 1.562(15) . ?
C30 C30 1.56(2) 3_766 ?
C30 C31 1.588(14) . ?
C30 H30 0.9800 . ?
C31 C32 1.541(19) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C33 C34 1.389(13) . ?
C33 H33 0.9300 . ?
C34 C35 1.404(14) . ?
C34 H34 0.9300 . ?
C35 C36 1.399(14) . ?
C35 C43 1.485(13) . ?
C36 C37 1.400(12) . ?
C36 H36 0.9300 . ?
C37 H37 0.9300 . ?
C38 C39 1.402(13) . ?
C38 H38 0.9300 . ?
C39 C40 1.422(14) . ?
C39 H39 0.9300 . ?
C40 C41 1.408(13) . ?
C40 C44 1.474(13) . ?
C41 C42 1.379(12) . ?
C41 H41 0.9300 . ?
C42 H42 0.9300 . ?
C43 C44 1.296(13) 4_676 ?
C43 H43 0.9300 . ?
C44 C43 1.296(13) 4_575 ?
C44 H44 0.9300 . ?
C45 C46 1.370(13) . ?
C45 H45 0.9300 . ?
C46 C47 1.399(14) . ?
C46 H46 0.9300 . ?
C47 C48 1.427(14) . ?
C47 C55 1.493(14) . ?
C48 C49 1.392(13) . ?
C48 H48 0.9300 . ?
C49 H49 0.9300 . ?
C50 C51 1.360(13) . ?
C50 H50 0.9300 . ?
C51 C52 1.427(14) . ?
C51 H51 0.9300 . ?
C52 C53 1.405(14) . ?
C52 C56 1.483(14) 4_575 ?
C53 C54 1.372(13) . ?
C53 H53 0.9300 . ?
C54 H54 0.9300 . ?
C55 C56 1.303(13) . ?
C55 H55 0.9300 . ?
C56 C52 1.483(14) 4_676 ?
C56 H56 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N2 155.6(4) . . ?
N1 Ag1 O1 99.3(3) . . ?
N2 Ag1 O1 102.8(3) . . ?
N1 Ag1 Ag2 107.5(2) . . ?
N2 Ag1 Ag2 78.4(2) . . ?
O1 Ag1 Ag2 100.87(19) . . ?
N4 Ag2 N3 175.6(3) . . ?
N4 Ag2 O2 92.5(3) . . ?
N3 Ag2 O2 89.3(3) . . ?
N4 Ag2 Ag1 106.7(2) . . ?
N3 Ag2 Ag1 77.6(3) . . ?
O2 Ag2 Ag1 52.84(17) . . ?
N6 Ag3 N5 174.2(4) . . ?
N6 Ag3 O5 92.8(3) . . ?
N5 Ag3 O5 90.3(3) . . ?
N7 Ag4 N8 155.5(3) . . ?
N7 Ag4 O6 105.5(3) . . ?
N8 Ag4 O6 96.9(3) . . ?
N7 Ag4 O5 113.7(3) . . ?
N8 Ag4 O5 88.3(3) . . ?
O6 Ag4 O5 50.0(2) . . ?
C9 N1 C5 116.0(9) . . ?
C9 N1 Ag1 123.3(7) . . ?
C5 N1 Ag1 120.5(8) . . ?
C10 N2 C14 118.3(9) . . ?
C10 N2 Ag1 119.0(8) . . ?
C14 N2 Ag1 122.5(7) . . ?
C17 N3 C21 117.6(9) . . ?
C17 N3 Ag2 117.4(8) . . ?
C21 N3 Ag2 125.0(8) . . ?
C22 N4 C26 115.6(9) . . ?
C22 N4 Ag2 121.0(7) . . ?
C26 N4 Ag2 123.4(8) . . ?
C37 N5 C33 117.9(9) . . ?
C37 N5 Ag3 119.4(8) . . ?
C33 N5 Ag3 122.6(8) . . ?
C38 N6 C42 117.5(9) . . ?
C38 N6 Ag3 122.4(8) . . ?
C42 N6 Ag3 120.0(7) . . ?
C49 N7 C45 115.3(9) . . ?
C49 N7 Ag4 122.5(8) . . ?
C45 N7 Ag4 122.0(7) . . ?
C50 N8 C54 116.5(9) . . ?
C50 N8 Ag4 122.9(7) . . ?
C54 N8 Ag4 120.2(8) . . ?
C1 O1 Ag1 95.6(8) . . ?
C1 O2 Ag2 164.3(8) . . ?
C29 O5 Ag3 167.2(8) . . ?
C29 O5 Ag4 90.3(8) . . ?
Ag3 O5 Ag4 78.1(2) . . ?
C29 O6 Ag4 94.4(8) . . ?
H9C O9 H9D 108.7 . . ?
H10C O10 H10D 107.8 . . ?
H11C O11 H11D 107.8 . . ?
H12C O12 H12D 108.5 . . ?
H13C O13 H13D 108.3 . . ?
H14C O14 H14D 108.3 . . ?
H15C O15 H15D 108.4 . . ?
H16C O16 H16D 110.1 . . ?
H17C O17 H17D 108.0 . . ?
H18C O18 H18D 108.7 . . ?
H18C O18 H18E 109.8 . . ?
H18D O18 H18E 108.7 . . ?
H19C O19 H19D 108.6 . . ?
H20C O20 H20D 107.3 . . ?
H21E O21 H21F 108.4 . . ?
H21G O21' H21H 108.4 . . ?
O2 C1 O1 124.2(12) . . ?
O2 C1 C2 116.7(11) . . ?
O1 C1 C2 119.0(11) . . ?
C3 C2 C1 112.2(8) . . ?
C3 C2 C2 111.9(11) . 3_676 ?
C1 C2 C2 108.8(10) . 3_676 ?
C3 C2 H2 108.0 . . ?
C1 C2 H2 108.0 . . ?
C2 C2 H2 108.0 3_676 . ?
C2 C3 C4 120.7(11) . . ?
C2 C3 H3A 107.2 . . ?
C4 C3 H3A 107.2 . . ?
C2 C3 H3B 107.2 . . ?
C4 C3 H3B 107.2 . . ?
H3A C3 H3B 106.8 . . ?
O3 C4 O4 127.1(14) . . ?
O3 C4 C3 118.9(13) . . ?
O4 C4 C3 113.9(14) . . ?
N1 C5 C6 123.5(11) . . ?
N1 C5 H5 118.2 . . ?
C6 C5 H5 118.2 . . ?
C5 C6 C7 118.1(11) . . ?
C5 C6 H6 121.0 . . ?
C7 C6 H6 121.0 . . ?
C8 C7 C6 118.2(10) . . ?
C8 C7 C15 116.4(11) . . ?
C6 C7 C15 125.4(11) . . ?
C9 C8 C7 118.7(11) . . ?
C9 C8 H8 120.6 . . ?
C7 C8 H8 120.6 . . ?
N1 C9 C8 125.4(11) . . ?
N1 C9 H9 117.3 . . ?
C8 C9 H9 117.3 . . ?
N2 C10 C11 122.0(10) . . ?
N2 C10 H10 119.0 . . ?
C11 C10 H10 119.0 . . ?
C10 C11 C12 120.2(10) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C13 C12 C11 116.4(10) . . ?
C13 C12 C16 119.1(11) . 4_676 ?
C11 C12 C16 124.6(11) . 4_676 ?
C12 C13 C14 120.8(11) . . ?
C12 C13 H13 119.6 . . ?
C14 C13 H13 119.6 . . ?
N2 C14 C13 122.3(10) . . ?
N2 C14 H14 118.8 . . ?
C13 C14 H14 118.8 . . ?
C16 C15 C7 126.3(13) . . ?
C16 C15 H15 116.9 . . ?
C7 C15 H15 116.9 . . ?
C15 C16 C12 127.6(13) . 4_575 ?
C15 C16 H16 116.2 . . ?
C12 C16 H16 116.2 4_575 . ?
N3 C17 C18 122.4(10) . . ?
N3 C17 H17 118.8 . . ?
C18 C17 H17 118.8 . . ?
C17 C18 C19 121.2(10) . . ?
C17 C18 H18 119.4 . . ?
C19 C18 H18 119.4 . . ?
C18 C19 C20 115.4(9) . . ?
C18 C19 C27 124.1(10) . . ?
C20 C19 C27 120.4(10) . . ?
C21 C20 C19 120.7(11) . . ?
C21 C20 H20 119.7 . . ?
C19 C20 H20 119.7 . . ?
N3 C21 C20 122.6(10) . . ?
N3 C21 H21 118.7 . . ?
C20 C21 H21 118.7 . . ?
C23 C22 N4 123.7(10) . . ?
C23 C22 H22 118.2 . . ?
N4 C22 H22 118.2 . . ?
C22 C23 C24 121.7(11) . . ?
C22 C23 H23 119.1 . . ?
C24 C23 H23 119.1 . . ?
C25 C24 C23 115.0(10) . . ?
C25 C24 C28 120.4(10) . . ?
C23 C24 C28 124.6(11) . . ?
C26 C25 C24 120.9(10) . . ?
C26 C25 H25 119.6 . . ?
C24 C25 H25 119.6 . . ?
N4 C26 C25 123.0(11) . . ?
N4 C26 H26 118.5 . . ?
C25 C26 H26 118.5 . . ?
C28 C27 C19 124.9(11) 4_575 . ?
C28 C27 H27 117.6 4_575 . ?
C19 C27 H27 117.6 . . ?
C27 C28 C24 127.8(11) 4_676 . ?
C27 C28 H28 116.1 4_676 . ?
C24 C28 H28 116.1 . . ?
O5 C29 O6 124.4(13) . . ?
O5 C29 C30 118.9(12) . . ?
O6 C29 C30 116.7(12) . . ?
C30 C30 C29 108.8(11) 3_766 . ?
C30 C30 C31 108.9(13) 3_766 . ?
C29 C30 C31 110.3(9) . . ?
C30 C30 H30 109.6 3_766 . ?
C29 C30 H30 109.6 . . ?
C31 C30 H30 109.6 . . ?
C32 C31 C30 115.1(12) . . ?
C32 C31 H31A 108.5 . . ?
C30 C31 H31A 108.5 . . ?
C32 C31 H31B 108.5 . . ?
C30 C31 H31B 108.5 . . ?
H31A C31 H31B 107.5 . . ?
O7 C32 O8 123.7(18) . . ?
O7 C32 C31 123.8(17) . . ?
O8 C32 C31 112.3(17) . . ?
N5 C33 C34 121.5(11) . . ?
N5 C33 H33 119.3 . . ?
C34 C33 H33 119.3 . . ?
C33 C34 C35 120.9(11) . . ?
C33 C34 H34 119.5 . . ?
C35 C34 H34 119.5 . . ?
C36 C35 C34 116.1(10) . . ?
C36 C35 C43 123.9(11) . . ?
C34 C35 C43 120.0(11) . . ?
C35 C36 C37 119.7(11) . . ?
C35 C36 H36 120.2 . . ?
C37 C36 H36 120.2 . . ?
N5 C37 C36 123.8(11) . . ?
N5 C37 H37 118.1 . . ?
C36 C37 H37 118.1 . . ?
N6 C38 C39 122.7(11) . . ?
N6 C38 H38 118.6 . . ?
C39 C38 H38 118.6 . . ?
C38 C39 C40 119.5(11) . . ?
C38 C39 H39 120.3 . . ?
C40 C39 H39 120.3 . . ?
C41 C40 C39 116.6(10) . . ?
C41 C40 C44 125.3(11) . . ?
C39 C40 C44 118.1(11) . . ?
C42 C41 C40 120.3(11) . . ?
C42 C41 H41 119.9 . . ?
C40 C41 H41 119.9 . . ?
N6 C42 C41 123.4(10) . . ?
N6 C42 H42 118.3 . . ?
C41 C42 H42 118.3 . . ?
C44 C43 C35 128.0(12) 4_676 . ?
C44 C43 H43 116.0 4_676 . ?
C35 C43 H43 116.0 . . ?
C43 C44 C40 127.8(12) 4_575 . ?
C43 C44 H44 116.1 4_575 . ?
C40 C44 H44 116.1 . . ?
C46 C45 N7 123.5(11) . . ?
C46 C45 H45 118.3 . . ?
N7 C45 H45 118.3 . . ?
C45 C46 C47 120.8(11) . . ?
C45 C46 H46 119.6 . . ?
C47 C46 H46 119.6 . . ?
C46 C47 C48 116.8(11) . . ?
C46 C47 C55 121.0(11) . . ?
C48 C47 C55 122.2(11) . . ?
C49 C48 C47 117.6(11) . . ?
C49 C48 H48 121.2 . . ?
C47 C48 H48 121.2 . . ?
N7 C49 C48 126.0(11) . . ?
N7 C49 H49 117.0 . . ?
C48 C49 H49 117.0 . . ?
N8 C50 C51 124.8(11) . . ?
N8 C50 H50 117.6 . . ?
C51 C50 H50 117.6 . . ?
C50 C51 C52 119.9(11) . . ?
C50 C51 H51 120.1 . . ?
C52 C51 H51 120.1 . . ?
C53 C52 C51 114.8(10) . . ?
C53 C52 C56 125.3(11) . 4_575 ?
C51 C52 C56 119.8(11) . 4_575 ?
C54 C53 C52 122.4(11) . . ?
C54 C53 H53 118.8 . . ?
C52 C53 H53 118.8 . . ?
C53 C54 N8 121.6(11) . . ?
C53 C54 H54 119.2 . . ?
N8 C54 H54 119.2 . . ?
C56 C55 C47 127.6(12) . . ?
C56 C55 H55 116.2 . . ?
C47 C55 H55 116.2 . . ?
C55 C56 C52 127.3(12) . 4_676 ?
C55 C56 H56 116.4 . . ?
C52 C56 H56 116.4 4_676 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag1 Ag2 N4 -172.7(4) . . . . ?
N2 Ag1 Ag2 N4 -17.2(4) . . . . ?
O1 Ag1 Ag2 N4 83.8(3) . . . . ?
N1 Ag1 Ag2 N3 8.5(4) . . . . ?
N2 Ag1 Ag2 N3 164.0(4) . . . . ?
O1 Ag1 Ag2 N3 -95.0(3) . . . . ?
N1 Ag1 Ag2 O2 107.1(3) . . . . ?
N2 Ag1 Ag2 O2 -97.3(3) . . . . ?
O1 Ag1 Ag2 O2 3.7(2) . . . . ?
N2 Ag1 N1 C9 -36.3(14) . . . . ?
O1 Ag1 N1 C9 168.9(9) . . . . ?
Ag2 Ag1 N1 C9 64.3(9) . . . . ?
N2 Ag1 N1 C5 148.4(9) . . . . ?
O1 Ag1 N1 C5 -6.3(9) . . . . ?
Ag2 Ag1 N1 C5 -110.9(8) . . . . ?
N1 Ag1 N2 C10 -142.2(9) . . . . ?
O1 Ag1 N2 C10 12.2(9) . . . . ?
Ag2 Ag1 N2 C10 110.9(8) . . . . ?
N1 Ag1 N2 C14 43.5(14) . . . . ?
O1 Ag1 N2 C14 -162.0(9) . . . . ?
Ag2 Ag1 N2 C14 -63.3(9) . . . . ?
N4 Ag2 N3 C17 -100(5) . . . . ?
O2 Ag2 N3 C17 13.4(8) . . . . ?
Ag1 Ag2 N3 C17 65.3(8) . . . . ?
N4 Ag2 N3 C21 79(5) . . . . ?
O2 Ag2 N3 C21 -168.3(9) . . . . ?
Ag1 Ag2 N3 C21 -116.3(9) . . . . ?
N3 Ag2 N4 C22 104(5) . . . . ?
O2 Ag2 N4 C22 -8.9(8) . . . . ?
Ag1 Ag2 N4 C22 -60.7(9) . . . . ?
N3 Ag2 N4 C26 -75(5) . . . . ?
O2 Ag2 N4 C26 171.6(9) . . . . ?
Ag1 Ag2 N4 C26 119.8(8) . . . . ?
N6 Ag3 N5 C37 -109(4) . . . . ?
O5 Ag3 N5 C37 13.3(9) . . . . ?
N6 Ag3 N5 C33 75(4) . . . . ?
O5 Ag3 N5 C33 -162.1(9) . . . . ?
N5 Ag3 N6 C38 -69(4) . . . . ?
O5 Ag3 N6 C38 168.4(9) . . . . ?
N5 Ag3 N6 C42 108(4) . . . . ?
O5 Ag3 N6 C42 -14.5(9) . . . . ?
N8 Ag4 N7 C49 144.5(9) . . . . ?
O6 Ag4 N7 C49 -10.6(9) . . . . ?
O5 Ag4 N7 C49 -63.3(9) . . . . ?
N8 Ag4 N7 C45 -40.1(14) . . . . ?
O6 Ag4 N7 C45 164.8(8) . . . . ?
O5 Ag4 N7 C45 112.1(9) . . . . ?
N7 Ag4 N8 C50 37.4(14) . . . . ?
O6 Ag4 N8 C50 -166.7(9) . . . . ?
O5 Ag4 N8 C50 -117.3(9) . . . . ?
N7 Ag4 N8 C54 -149.7(9) . . . . ?
O6 Ag4 N8 C54 6.2(9) . . . . ?
O5 Ag4 N8 C54 55.6(8) . . . . ?
N1 Ag1 O1 C1 -111.2(6) . . . . ?
N2 Ag1 O1 C1 79.2(7) . . . . ?
Ag2 Ag1 O1 C1 -1.3(6) . . . . ?
N4 Ag2 O2 C1 -138(3) . . . . ?
N3 Ag2 O2 C1 46(3) . . . . ?
Ag1 Ag2 O2 C1 -29(3) . . . . ?
N6 Ag3 O5 C29 -132(4) . . . . ?
N5 Ag3 O5 C29 53(4) . . . . ?
N6 Ag3 O5 Ag4 -105.8(3) . . . . ?
N5 Ag3 O5 Ag4 79.1(3) . . . . ?
N7 Ag4 O5 C29 85.7(7) . . . . ?
N8 Ag4 O5 C29 -105.5(7) . . . . ?
O6 Ag4 O5 C29 -5.0(7) . . . . ?
N7 Ag4 O5 Ag3 -88.7(3) . . . . ?
N8 Ag4 O5 Ag3 80.1(3) . . . . ?
O6 Ag4 O5 Ag3 -179.4(3) . . . . ?
N7 Ag4 O6 C29 -103.3(7) . . . . ?
N8 Ag4 O6 C29 86.9(7) . . . . ?
O5 Ag4 O6 C29 4.9(6) . . . . ?
Ag2 O2 C1 O1 33(3) . . . . ?
Ag2 O2 C1 C2 -150(2) . . . . ?
Ag1 O1 C1 O2 -5.2(11) . . . . ?
Ag1 O1 C1 C2 177.8(7) . . . . ?
O2 C1 C2 C3 55.9(12) . . . . ?
O1 C1 C2 C3 -127.0(10) . . . . ?
O2 C1 C2 C2 -68.4(13) . . . 3_676 ?
O1 C1 C2 C2 108.7(12) . . . 3_676 ?
C1 C2 C3 C4 69.3(13) . . . . ?
C2 C2 C3 C4 -168.2(11) 3_676 . . . ?
C2 C3 C4 O3 5(2) . . . . ?
C2 C3 C4 O4 -177.4(11) . . . . ?
C9 N1 C5 C6 -2.3(17) . . . . ?
Ag1 N1 C5 C6 173.3(9) . . . . ?
N1 C5 C6 C7 1.6(19) . . . . ?
C5 C6 C7 C8 1.3(18) . . . . ?
C5 C6 C7 C15 -179.4(11) . . . . ?
C6 C7 C8 C9 -3.3(18) . . . . ?
C15 C7 C8 C9 177.3(10) . . . . ?
C5 N1 C9 C8 0.1(17) . . . . ?
Ag1 N1 C9 C8 -175.3(9) . . . . ?
C7 C8 C9 N1 2.7(19) . . . . ?
C14 N2 C10 C11 2.5(17) . . . . ?
Ag1 N2 C10 C11 -172.0(8) . . . . ?
N2 C10 C11 C12 -1.7(18) . . . . ?
C10 C11 C12 C13 -0.6(17) . . . . ?
C10 C11 C12 C16 179.6(10) . . . 4_676 ?
C11 C12 C13 C14 2.1(18) . . . . ?
C16 C12 C13 C14 -178.2(10) 4_676 . . . ?
C10 N2 C14 C13 -1.0(18) . . . . ?
Ag1 N2 C14 C13 173.3(8) . . . . ?
C12 C13 C14 N2 -1.3(19) . . . . ?
C8 C7 C15 C16 -177.6(13) . . . . ?
C6 C7 C15 C16 3(2) . . . . ?
C7 C15 C16 C12 177.8(11) . . . 4_575 ?
C21 N3 C17 C18 -1.7(17) . . . . ?
Ag2 N3 C17 C18 176.8(8) . . . . ?
N3 C17 C18 C19 2.2(18) . . . . ?
C17 C18 C19 C20 -0.1(17) . . . . ?
C17 C18 C19 C27 177.1(10) . . . . ?
C18 C19 C20 C21 -2.3(17) . . . . ?
C27 C19 C20 C21 -179.6(10) . . . . ?
C17 N3 C21 C20 -0.9(17) . . . . ?
Ag2 N3 C21 C20 -179.2(8) . . . . ?
C19 C20 C21 N3 2.9(19) . . . . ?
C26 N4 C22 C23 -2.2(16) . . . . ?
Ag2 N4 C22 C23 178.3(8) . . . . ?
N4 C22 C23 C24 -0.3(18) . . . . ?
C22 C23 C24 C25 2.0(17) . . . . ?
C22 C23 C24 C28 -175.9(10) . . . . ?
C23 C24 C25 C26 -1.2(17) . . . . ?
C28 C24 C25 C26 176.8(10) . . . . ?
C22 N4 C26 C25 3.0(16) . . . . ?
Ag2 N4 C26 C25 -177.5(8) . . . . ?
C24 C25 C26 N4 -1.3(18) . . . . ?
C18 C19 C27 C28 4.0(19) . . . 4_575 ?
C20 C19 C27 C28 -178.9(12) . . . 4_575 ?
C25 C24 C28 C27 -179.4(12) . . . 4_676 ?
C23 C24 C28 C27 -2(2) . . . 4_676 ?
Ag3 O5 C29 O6 35(4) . . . . ?
Ag4 O5 C29 O6 9.5(12) . . . . ?
Ag3 O5 C29 C30 -146(3) . . . . ?
Ag4 O5 C29 C30 -170.8(9) . . . . ?
Ag4 O6 C29 O5 -9.9(13) . . . . ?
Ag4 O6 C29 C30 170.4(8) . . . . ?
O5 C29 C30 C30 75.9(15) . . . 3_766 ?
O6 C29 C30 C30 -104.4(15) . . . 3_766 ?
O5 C29 C30 C31 -43.6(14) . . . . ?
O6 C29 C30 C31 136.2(11) . . . . ?
C30 C30 C31 C32 178.1(12) 3_766 . . . ?
C29 C30 C31 C32 -62.6(14) . . . . ?
C30 C31 C32 O7 -13(2) . . . . ?
C30 C31 C32 O8 171.5(11) . . . . ?
C37 N5 C33 C34 -0.6(18) . . . . ?
Ag3 N5 C33 C34 174.9(8) . . . . ?
N5 C33 C34 C35 -2.1(19) . . . . ?
C33 C34 C35 C36 4.4(18) . . . . ?
C33 C34 C35 C43 -176.3(10) . . . . ?
C34 C35 C36 C37 -4.2(17) . . . . ?
C43 C35 C36 C37 176.5(10) . . . . ?
C33 N5 C37 C36 0.7(17) . . . . ?
Ag3 N5 C37 C36 -174.9(8) . . . . ?
C35 C36 C37 N5 1.8(18) . . . . ?
C42 N6 C38 C39 1.6(18) . . . . ?
Ag3 N6 C38 C39 178.7(8) . . . . ?
N6 C38 C39 C40 -1.0(19) . . . . ?
C38 C39 C40 C41 -0.2(17) . . . . ?
C38 C39 C40 C44 -178.5(10) . . . . ?
C39 C40 C41 C42 0.6(17) . . . . ?
C44 C40 C41 C42 178.9(10) . . . . ?
C38 N6 C42 C41 -1.1(17) . . . . ?
Ag3 N6 C42 C41 -178.3(8) . . . . ?
C40 C41 C42 N6 0.0(18) . . . . ?
C36 C35 C43 C44 0(2) . . . 4_676 ?
C34 C35 C43 C44 -179.8(13) . . . 4_676 ?
C41 C40 C44 C43 -5(2) . . . 4_575 ?
C39 C40 C44 C43 173.5(13) . . . 4_575 ?
C49 N7 C45 C46 -2.4(17) . . . . ?
Ag4 N7 C45 C46 -178.1(8) . . . . ?
N7 C45 C46 C47 0.2(18) . . . . ?
C45 C46 C47 C48 0.8(18) . . . . ?
C45 C46 C47 C55 177.9(10) . . . . ?
C46 C47 C48 C49 0.5(17) . . . . ?
C55 C47 C48 C49 -176.6(10) . . . . ?
C45 N7 C49 C48 3.9(18) . . . . ?
Ag4 N7 C49 C48 179.5(9) . . . . ?
C47 C48 C49 N7 -3.0(19) . . . . ?
C54 N8 C50 C51 -2.7(17) . . . . ?
Ag4 N8 C50 C51 170.5(9) . . . . ?
N8 C50 C51 C52 1.8(19) . . . . ?
C50 C51 C52 C53 -0.3(17) . . . . ?
C50 C51 C52 C56 -176.9(10) . . . 4_575 ?
C51 C52 C53 C54 -0.2(18) . . . . ?
C56 C52 C53 C54 176.2(11) 4_575 . . . ?
C52 C53 C54 N8 -0.8(19) . . . . ?
C50 N8 C54 C53 2.1(17) . . . . ?
Ag4 N8 C54 C53 -171.3(8) . . . . ?
C46 C47 C55 C56 179.8(12) . . . . ?
C48 C47 C55 C56 -3(2) . . . . ?
C47 C55 C56 C52 -179.3(11) . . . 4_676 ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O9 H9C O3 0.85 2.01 2.842(12) 168.0 .
O9 H9D O12 0.85 2.33 3.165(13) 166.9 4_575
O10 H10C O6 0.85 2.17 2.977(13) 158.2 .
O10 H10D O7 0.85 1.95 2.761(16) 158.4 .
O11 H11C O1 0.85 2.11 2.916(13) 158.4 1_545
O11 H11D O3 0.85 2.03 2.834(15) 158.7 1_545
O12 H12C O6 0.85 2.00 2.847(12) 177.3 .
O12 H12D O13 0.85 1.96 2.806(14) 175.9 3_666
O15 H15D O17 0.85 2.16 3.012(17) 179.2 3_666
O16 H16C O15 0.85 2.09 2.936(16) 178.0 3_666
O18 H18C O10 0.85 1.96 2.810(13) 173.3 3_666
O18 H18D O18 0.85 1.95 2.80(2) 174.4 3_666
O19 H19C O11 0.85 1.98 2.824(15) 172.5 3_666
O13 H13C O4 0.85 1.95 2.801(11) 175.0 2_545
O13 H13D O8 0.85 1.95 2.801(17) 175.0 1_455
O14 H14C O9 0.85 1.99 2.841(15) 175.5 .
O14 H14D O19 0.85 2.08 2.924(15) 176.6 3_676
O16 H16D O16 0.85 2.45 3.04(2) 127.2 3_776
O19 H19D O16 0.85 2.22 3.068(16) 173.4 3_776
O17 H17C O4 0.85 1.93 2.767(15) 166.3 .
O17 H17D O8 0.85 2.51 3.351(16) 168.1 2_655
O20 H20C O21' 0.85 2.12 2.79(3) 135.7 2_655
O20 H20C O7 0.85 2.42 3.119(17) 140.1 .
O20 H20D O8 0.85 2.21 2.869(18) 134.0 .
O20 H20D O17 0.85 2.61 3.244(19) 132.7 2_645
O21 H21F O20 0.85 2.14 2.99(2) 176.5 2_645
O21' H21G O7 0.85 2.19 3.04(3) 179.2 2_645
O21 H21E O14 0.85 2.06 2.91(2) 178.9 1_645
O21' H21H O18 0.85 1.52 2.37(3) 179.5 4_665

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        25.02
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         1.330
_refine_diff_density_min         -1.025
_refine_diff_density_rms         0.145


# start Validation Reply Form
_vrf_PLAT417_I                   
;
PROBLEM: Short Inter D-H..H-D       H18C   ..  H21H    ..       1.64 Ang.  
RESPONSE: This results from the serious disorder of H18 and H21 
attached onto O atoms of the water molecules.
;
