# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_qxx19
_database_code_depnum_ccdc_archive 'CCDC 1476276'
_audit_update_record             
;
2016-07-18 deposited with the CCDC.
2016-07-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H28 Ag5 Al N14 O44 W12'
_chemical_formula_sum            'C28 H28 Ag5 Al N14 O44 W12'
_chemical_formula_weight         4037.06

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'C 2/c'
_symmetry_space_group_name_Hall  '-C 2yc'
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   23.342(3)
_cell_length_b                   20.685(3)
_cell_length_c                   12.5402(16)
_cell_angle_alpha                90.00
_cell_angle_beta                 97.970(2)
_cell_angle_gamma                90.00
_cell_volume                     5996.3(13)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    3740
_cell_measurement_theta_min      2.56
_cell_measurement_theta_max      27.59

_exptl_crystal_description       block
_exptl_crystal_colour            white
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    4.472
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             7128
_exptl_absorpt_coefficient_mu    24.633
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4321
_exptl_absorpt_correction_T_max  0.5146
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart APEX CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            13618
_diffrn_reflns_av_R_equivalents  0.0464
_diffrn_reflns_av_sigmaI/netI    0.0850
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_theta_min         2.56
_diffrn_reflns_theta_max         27.59
_reflns_number_total             6912
_reflns_number_gt                4585
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    SHELXP-97
_computing_publication_material  SHELXTL

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0906P)²+527.8513P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6912
_refine_ls_number_parameters     474
_refine_ls_number_restraints     128
_refine_ls_R_factor_all          0.1209
_refine_ls_R_factor_gt           0.0800
_refine_ls_wR_factor_ref         0.1385
_refine_ls_wR_factor_gt          0.1019
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_restrained_S_all      1.077
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.17288(7) 1.13617(7) 0.32826(11) 0.0373(4) Uani 1 1 d U . .
W2 W 0.18877(8) 1.31543(8) 0.71547(11) 0.0484(5) Uani 1 1 d U . .
W3 W 0.22507(8) 1.09487(8) 0.59665(14) 0.0484(5) Uani 1 1 d U . .
W4 W 0.30497(8) 1.20761(10) 0.76496(11) 0.0522(5) Uani 1 1 d U . .
Ag1 Ag 0.5000 0.5900(3) 0.2500 0.0707(16) Uani 1 2 d S . .
Ag2 Ag 0.5000 0.9459(3) 0.2500 0.0771(17) Uani 1 2 d SU . .
W6 W 0.11028(7) 1.20427(8) 0.54184(14) 0.0477(5) Uani 1 1 d U . .
O1 O 0.1566(17) 1.1371(18) 0.610(2) 0.073(11) Uani 1 1 d . . .
O2 O 0.2368(18) 1.2495(18) 0.781(3) 0.083(10) Uani 1 1 d U . .
O3 O 0.158(2) 1.210(2) 0.244(4) 0.102(17) Uani 1 1 d . . .
O4 O 0.2013(14) 1.0826(14) 0.445(2) 0.057(5) Uani 1 1 d U . .
O5 O 0.3314(16) 1.1861(16) 0.892(2) 0.073(10) Uani 1 1 d . . .
O6 O 0.0937(19) 1.2834(16) 0.472(3) 0.062(6) Uani 1 1 d U . .
O7 O 0.1601(18) 1.3477(18) 0.821(3) 0.084(11) Uani 1 1 d . . .
Al1 Al 0.2500 1.2500 0.5000 0.029(2) Uani 1 2 d SU . .
Ag3 Ag 0.0000 0.8075(4) 0.2500 0.099(2) Uani 1 2 d SU . .
Ag4 Ag 0.2632(3) 0.9235(3) 0.5650(5) 0.1146(19) Uani 1 1 d . . .
N1 N 0.333(3) 0.950(2) 0.483(4) 0.10(2) Uani 1 1 d U . .
N2 N 0.1838(19) 0.887(2) 0.462(3) 0.072(12) Uani 1 1 d . . .
O8 O 0.0819(14) 1.4143(14) 0.429(2) 0.056(8) Uani 1 1 d . . .
O9 O 0.0453(14) 1.181(2) 0.564(2) 0.076(10) Uani 1 1 d . . .
O10 O 0.2137(18) 1.0201(15) 0.641(2) 0.074(10) Uani 1 1 d . . .
O11 O 0.1337(16) 1.0818(17) 0.254(3) 0.086(13) Uani 1 1 d . . .
O12 O 0.1995(17) 1.412(3) 0.443(4) 0.15(3) Uani 1 1 d . . .
O13 O 0.1145(19) 1.1666(19) 0.408(3) 0.086(13) Uani 1 1 d . . .
N3 N 0.5000 0.829(3) 0.2500 0.079(19) Uani 1 2 d S . .
N4 N 0.5000 0.697(2) 0.2500 0.049(11) Uani 1 2 d SU . .
N5 N 0.5006(18) 0.5338(18) 0.095(3) 0.055(10) Uani 1 1 d . . .
W5 W 0.13589(8) 1.36090(9) 0.45157(16) 0.0601(6) Uani 1 1 d U . .
O14 O 0.154(2) 1.3694(15) 0.601(3) 0.067(6) Uani 1 1 d U . .
O15 O 0.1350(17) 1.2507(15) 0.674(3) 0.064(5) Uani 1 1 d U . .
O16 O 0.3140(15) 1.2274(19) 0.450(3) 0.077(10) Uani 1 1 d U . .
N6 N 0.082(2) 0.844(3) 0.345(4) 0.083(14) Uani 1 1 d . . .
C1 C 0.476(2) 0.730(2) 0.320(4) 0.059(12) Uani 1 1 d . . .
H1 H 0.4585 0.7080 0.3715 0.070 Uiso 1 1 calc R . .
C2 C 0.153(3) 0.921(3) 0.387(4) 0.075(16) Uani 1 1 d . . .
H2 H 0.1660 0.9627 0.3775 0.090 Uiso 1 1 calc R . .
C3 C 0.476(2) 0.798(2) 0.321(4) 0.062(12) Uani 1 1 d . . .
H3 H 0.4590 0.8206 0.3719 0.075 Uiso 1 1 calc R . .
C4 C 0.548(2) 0.509(2) 0.068(3) 0.057(12) Uani 1 1 d . . .
H4 H 0.5828 0.5154 0.1131 0.069 Uiso 1 1 calc R . .
C5 C 0.453(2) 0.526(2) 0.027(3) 0.056(11) Uani 1 1 d . . .
H5 H 0.4189 0.5444 0.0427 0.068 Uiso 1 1 calc R . .
C6 C 0.392(3) 0.937(3) 0.516(4) 0.084(19) Uani 1 1 d . . .
H6 H 0.4041 0.9250 0.5864 0.101 Uiso 1 1 calc R . .
O17 O 0.2010(14) 1.1892(15) 0.483(2) 0.061(6) Uani 1 1 d U . .
O18 O 0.1386(17) 1.329(3) 0.310(4) 0.123(10) Uani 1 1 d U . .
O19 O 0.2336(14) 1.2194(14) 0.372(2) 0.054(5) Uani 1 1 d U . .
O20 O 0.2529(15) 1.3698(19) 0.712(4) 0.088(14) Uani 1 1 d . . .
O21 O 0.2806(15) 1.1851(18) 0.590(2) 0.056(5) Uani 1 1 d U . .
C7 C 0.108(3) 0.903(3) 0.326(4) 0.085(19) Uani 1 1 d . . .
H7 H 0.0916 0.9288 0.2700 0.102 Uiso 1 1 calc R . .
C8 C 0.116(3) 0.807(3) 0.415(5) 0.10(2) Uani 1 1 d . . .
H8 H 0.1027 0.7659 0.4281 0.121 Uiso 1 1 calc R . .
C9 C 0.370(4) 0.979(4) 0.315(4) 0.11(3) Uani 1 1 d . . .
H9 H 0.3613 0.9944 0.2450 0.137 Uiso 1 1 calc R . .
N7 N 0.425(2) 0.961(2) 0.353(3) 0.078(14) Uani 1 1 d . . .
C10 C 0.430(3) 0.942(3) 0.447(5) 0.091(19) Uani 1 1 d . . .
H10 H 0.4674 0.9295 0.4756 0.109 Uiso 1 1 calc R . .
C11 C 0.168(3) 0.825(3) 0.468(4) 0.10(2) Uani 1 1 d . . .
H11 H 0.1919 0.7953 0.5081 0.120 Uiso 1 1 calc R . .
C13 C 0.330(4) 0.976(3) 0.377(5) 0.10(2) Uani 1 1 d U . .
H13 H 0.2938 0.9936 0.3483 0.124 Uiso 1 1 calc R . .
O22 O 0.2552(16) 1.135(2) 0.730(3) 0.059(6) Uani 1 1 d U . .
N10 N 0.0000 0.698(4) 0.2500 0.103(8) Uani 1 2 d SU . .
C14 C -0.022(3) 0.660(4) 0.330(6) 0.102(7) Uani 1 1 d U . .
H14 H -0.0339 0.6816 0.3882 0.122 Uiso 1 1 calc R . .
C15 C 0.473(4) 1.098(4) 0.328(7) 0.14(3) Uani 1 1 d . . .
H15 H 0.4529 1.0778 0.3769 0.173 Uiso 1 1 calc R . .
N11 N 0.5000 1.057(3) 0.2500 0.082(12) Uani 1 2 d SU . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O11 1.65(3) . ?
W1 O3 1.86(3) . ?
W1 O4 1.88(3) . ?
W1 O20 1.88(4) 7_576 ?
W1 O13 1.90(4) . ?
W1 O17 2.25(3) . ?
W1 O19 2.25(3) . ?
W2 O7 1.70(3) . ?
W2 O15 1.86(3) . ?
W2 O20 1.88(4) . ?
W2 O2 1.88(4) . ?
W2 O14 1.91(3) . ?
W2 O16 2.25(3) 7_576 ?
W2 O19 2.36(3) 7_576 ?
W3 O10 1.68(3) . ?
W3 O1 1.85(3) . ?
W3 O12 1.90(4) 7_576 ?
W3 O22 1.92(3) . ?
W3 O4 1.93(3) . ?
W3 O21 2.28(3) . ?
W3 O17 2.43(3) . ?
W4 O5 1.69(2) . ?
W4 O2 1.85(4) . ?
W4 O18 1.89(4) 7_576 ?
W4 O22 1.91(4) . ?
W4 O3 1.92(4) 7_576 ?
W4 O21 2.24(3) . ?
W4 O19 2.37(3) 7_576 ?
Ag1 N4 2.21(5) . ?
Ag1 N5 2.26(3) 2_655 ?
Ag1 N5 2.26(3) . ?
Ag2 N11 2.30(7) . ?
Ag2 N7 2.33(5) . ?
Ag2 N7 2.33(5) 2_655 ?
Ag2 N3 2.43(7) . ?
W6 O9 1.65(3) . ?
W6 O6 1.87(3) . ?
W6 O13 1.87(3) . ?
W6 O1 1.89(3) . ?
W6 O15 1.93(3) . ?
W6 O16 2.25(4) 7_576 ?
W6 O17 2.36(3) . ?
O3 W4 1.92(4) 7_576 ?
O6 W5 1.92(4) . ?
Al1 O17 1.69(3) . ?
Al1 O17 1.69(3) 7_576 ?
Al1 O19 1.72(3) 7_576 ?
Al1 O19 1.72(3) . ?
Al1 O16 1.76(3) . ?
Al1 O16 1.76(3) 7_576 ?
Al1 O21 1.83(4) . ?
Al1 O21 1.83(4) 7_576 ?
Ag3 N6 2.24(5) . ?
Ag3 N6 2.24(5) 2 ?
Ag3 N10 2.26(9) . ?
Ag4 N1 2.12(8) . ?
Ag4 N2 2.24(5) . ?
N1 C6 1.40(8) . ?
N1 C13 1.43(8) . ?
N2 C2 1.30(6) . ?
N2 C11 1.33(7) . ?
O8 W5 1.67(3) . ?
O12 W5 1.84(4) . ?
O12 W3 1.90(4) 7_576 ?
N3 C3 1.27(6) . ?
N3 C3 1.27(6) 2_655 ?
N4 C1 1.30(5) . ?
N4 C1 1.30(6) 2_655 ?
N5 C4 1.30(6) . ?
N5 C5 1.32(5) . ?
W5 O14 1.87(3) . ?
W5 O18 1.90(4) . ?
W5 O21 2.29(4) 7_576 ?
W5 O16 2.41(4) 7_576 ?
O16 W2 2.25(3) 7_576 ?
O16 W6 2.25(4) 7_576 ?
O16 W5 2.41(4) 7_576 ?
N6 C8 1.33(8) . ?
N6 C7 1.39(8) . ?
C1 C3 1.41(6) . ?
C2 C7 1.28(8) . ?
C4 C5 1.40(6) 5_665 ?
C5 C4 1.40(6) 5_665 ?
C6 C10 1.33(8) . ?
O18 W4 1.89(4) 7_576 ?
O19 W2 2.36(3) 7_576 ?
O19 W4 2.37(3) 7_576 ?
O20 W1 1.88(4) 7_576 ?
O21 W5 2.29(4) 7_576 ?
C8 C11 1.36(8) . ?
C9 C13 1.30(10) . ?
C9 N7 1.36(9) . ?
N7 C10 1.24(7) . ?
N10 C14 1.43(8) 2 ?
N10 C14 1.43(8) . ?
C14 C15 1.29(10) 3_445 ?
C15 C14 1.29(10) 3 ?
C15 N11 1.49(8) . ?
N11 C15 1.49(8) 2_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 W1 O3 101(2) . . ?
O11 W1 O4 98.4(17) . . ?
O3 W1 O4 161(2) . . ?
O11 W1 O20 105(2) . 7_576 ?
O3 W1 O20 90.2(17) . 7_576 ?
O4 W1 O20 86.0(15) . 7_576 ?
O11 W1 O13 98(2) . . ?
O3 W1 O13 86.6(16) . . ?
O4 W1 O13 89.3(13) . . ?
O20 W1 O13 157(2) 7_576 . ?
O11 W1 O17 153.1(18) . . ?
O3 W1 O17 95.9(19) . . ?
O4 W1 O17 65.6(12) . . ?
O20 W1 O17 95.5(18) 7_576 . ?
O13 W1 O17 61.9(16) . . ?
O11 W1 O19 159.7(18) . . ?
O3 W1 O19 64.6(19) . . ?
O4 W1 O19 96.9(12) . . ?
O20 W1 O19 62.7(17) 7_576 . ?
O13 W1 O19 95.3(17) . . ?
O17 W1 O19 47.1(11) . . ?
O7 W2 O15 100.3(18) . . ?
O7 W2 O20 101(2) . . ?
O15 W2 O20 159(2) . . ?
O7 W2 O2 102.8(18) . . ?
O15 W2 O2 86.5(16) . . ?
O20 W2 O2 90.9(16) . . ?
O7 W2 O14 100.6(19) . . ?
O15 W2 O14 90.7(15) . . ?
O20 W2 O14 83.6(18) . . ?
O2 W2 O14 156.6(18) . . ?
O7 W2 O16 155.3(17) . 7_576 ?
O15 W2 O16 61.7(15) . 7_576 ?
O20 W2 O16 97.8(18) . 7_576 ?
O2 W2 O16 93.4(15) . 7_576 ?
O14 W2 O16 65.1(14) . 7_576 ?
O7 W2 O19 153.2(16) . 7_576 ?
O15 W2 O19 100.5(14) . 7_576 ?
O20 W2 O19 60.4(15) . 7_576 ?
O2 W2 O19 62.0(14) . 7_576 ?
O14 W2 O19 95.9(16) . 7_576 ?
O16 W2 O19 51.5(11) 7_576 7_576 ?
O10 W3 O1 103.1(18) . . ?
O10 W3 O12 102(3) . 7_576 ?
O1 W3 O12 155(2) . 7_576 ?
O10 W3 O22 99.7(18) . . ?
O1 W3 O22 85.9(16) . . ?
O12 W3 O22 91.2(16) 7_576 . ?
O10 W3 O4 99.8(14) . . ?
O1 W3 O4 91.2(13) . . ?
O12 W3 O4 83.2(18) 7_576 . ?
O22 W3 O4 160.5(18) . . ?
O10 W3 O21 152.1(16) . . ?
O1 W3 O21 96.9(16) . . ?
O12 W3 O21 60(2) 7_576 . ?
O22 W3 O21 62.2(16) . . ?
O4 W3 O21 99.1(12) . . ?
O10 W3 O17 154.0(15) . . ?
O1 W3 O17 62.8(13) . . ?
O12 W3 O17 93(2) 7_576 . ?
O22 W3 O17 100.8(16) . . ?
O4 W3 O17 61.0(11) . . ?
O21 W3 O17 53.8(12) . . ?
O5 W4 O2 103.2(17) . . ?
O5 W4 O18 100(2) . 7_576 ?
O2 W4 O18 156(2) . 7_576 ?
O5 W4 O22 98.0(19) . . ?
O2 W4 O22 83.4(16) . . ?
O18 W4 O22 90.9(16) 7_576 . ?
O5 W4 O3 100.4(19) . 7_576 ?
O2 W4 O3 89.3(17) . 7_576 ?
O18 W4 O3 89(2) 7_576 7_576 ?
O22 W4 O3 161(2) . 7_576 ?
O5 W4 O21 151.8(16) . . ?
O2 W4 O21 95.7(15) . . ?
O18 W4 O21 61.6(17) 7_576 . ?
O22 W4 O21 63.2(16) . . ?
O3 W4 O21 100.6(17) 7_576 . ?
O5 W4 O19 154.8(14) . 7_576 ?
O2 W4 O19 62.1(14) . 7_576 ?
O18 W4 O19 97(2) 7_576 7_576 ?
O22 W4 O19 100.2(16) . 7_576 ?
O3 W4 O19 61.3(16) 7_576 7_576 ?
O21 W4 O19 53.4(13) . 7_576 ?
N4 Ag1 N5 120.9(10) . 2_655 ?
N4 Ag1 N5 120.9(10) . . ?
N5 Ag1 N5 118(2) 2_655 . ?
N11 Ag2 N7 82.3(11) . . ?
N11 Ag2 N7 82.3(11) . 2_655 ?
N7 Ag2 N7 165(2) . 2_655 ?
N11 Ag2 N3 180.000(14) . . ?
N7 Ag2 N3 97.7(11) . . ?
N7 Ag2 N3 97.7(11) 2_655 . ?
O9 W6 O6 101.2(19) . . ?
O9 W6 O13 101.2(18) . . ?
O6 W6 O13 88.8(15) . . ?
O9 W6 O1 101.2(18) . . ?
O6 W6 O1 157.3(19) . . ?
O13 W6 O1 90.2(13) . . ?
O9 W6 O15 100.0(17) . . ?
O6 W6 O15 89.0(14) . . ?
O13 W6 O15 158.7(19) . . ?
O1 W6 O15 83.8(15) . . ?
O9 W6 O16 155.1(16) . 7_576 ?
O6 W6 O16 65.2(15) . 7_576 ?
O13 W6 O16 99.3(17) . 7_576 ?
O1 W6 O16 92.6(16) . 7_576 ?
O15 W6 O16 60.8(14) . 7_576 ?
O9 W6 O17 154.3(16) . . ?
O6 W6 O17 96.2(17) . . ?
O13 W6 O17 60.1(15) . . ?
O1 W6 O17 64.1(13) . . ?
O15 W6 O17 99.1(14) . . ?
O16 W6 O17 50.5(11) 7_576 . ?
W3 O1 W6 138.7(19) . . ?
W4 O2 W2 140(2) . . ?
W1 O3 W4 135(3) . 7_576 ?
W1 O4 W3 135.5(16) . . ?
W6 O6 W5 136(2) . . ?
O17 Al1 O17 179.996(6) . 7_576 ?
O17 Al1 O19 116.6(14) . 7_576 ?
O17 Al1 O19 63.4(14) 7_576 7_576 ?
O17 Al1 O19 63.4(14) . . ?
O17 Al1 O19 116.6(14) 7_576 . ?
O19 Al1 O19 180(2) 7_576 . ?
O17 Al1 O16 110.5(17) . . ?
O17 Al1 O16 69.5(17) 7_576 . ?
O19 Al1 O16 109.7(16) 7_576 . ?
O19 Al1 O16 70.3(16) . . ?
O17 Al1 O16 69.5(17) . 7_576 ?
O17 Al1 O16 110.5(17) 7_576 7_576 ?
O19 Al1 O16 70.3(16) 7_576 7_576 ?
O19 Al1 O16 109.7(16) . 7_576 ?
O16 Al1 O16 179.998(7) . 7_576 ?
O17 Al1 O21 74.4(15) . . ?
O17 Al1 O21 105.6(15) 7_576 . ?
O19 Al1 O21 71.2(14) 7_576 . ?
O19 Al1 O21 108.8(14) . . ?
O16 Al1 O21 75.2(17) . . ?
O16 Al1 O21 104.8(17) 7_576 . ?
O17 Al1 O21 105.6(15) . 7_576 ?
O17 Al1 O21 74.4(15) 7_576 7_576 ?
O19 Al1 O21 108.8(14) 7_576 7_576 ?
O19 Al1 O21 71.2(14) . 7_576 ?
O16 Al1 O21 104.8(17) . 7_576 ?
O16 Al1 O21 75.2(17) 7_576 7_576 ?
O21 Al1 O21 179.997(7) . 7_576 ?
N6 Ag3 N6 141(3) . 2 ?
N6 Ag3 N10 109.4(14) . . ?
N6 Ag3 N10 109.4(14) 2 . ?
N1 Ag4 N2 116.0(17) . . ?
C6 N1 C13 106(6) . . ?
C6 N1 Ag4 127(4) . . ?
C13 N1 Ag4 127(5) . . ?
C2 N2 C11 116(5) . . ?
C2 N2 Ag4 124(4) . . ?
C11 N2 Ag4 120(3) . . ?
W5 O12 W3 139(3) . 7_576 ?
W6 O13 W1 138(2) . . ?
C3 N3 C3 121(7) . 2_655 ?
C3 N3 Ag2 120(4) . . ?
C3 N3 Ag2 120(4) 2_655 . ?
C1 N4 C1 117(6) . 2_655 ?
C1 N4 Ag1 122(3) . . ?
C1 N4 Ag1 122(3) 2_655 . ?
C4 N5 C5 117(4) . . ?
C4 N5 Ag1 122(3) . . ?
C5 N5 Ag1 121(3) . . ?
O8 W5 O12 102(2) . . ?
O8 W5 O14 99.9(16) . . ?
O12 W5 O14 86(2) . . ?
O8 W5 O18 101(2) . . ?
O12 W5 O18 90.8(19) . . ?
O14 W5 O18 159(2) . . ?
O8 W5 O6 100.8(16) . . ?
O12 W5 O6 157(2) . . ?
O14 W5 O6 89.6(15) . . ?
O18 W5 O6 85(2) . . ?
O8 W5 O21 151.6(14) . 7_576 ?
O12 W5 O21 60.5(18) . 7_576 ?
O14 W5 O21 100.5(16) . 7_576 ?
O18 W5 O21 60.4(16) . 7_576 ?
O6 W5 O21 98.8(16) . 7_576 ?
O8 W5 O16 152.8(14) . 7_576 ?
O12 W5 O16 97(2) . 7_576 ?
O14 W5 O16 62.2(13) . 7_576 ?
O18 W5 O16 98(2) . 7_576 ?
O6 W5 O16 61.3(14) . 7_576 ?
O21 W5 O16 55.5(12) 7_576 7_576 ?
W5 O14 W2 135.5(19) . . ?
W2 O15 W6 135(2) . . ?
Al1 O16 W2 120.9(17) . 7_576 ?
Al1 O16 W6 121.1(19) . 7_576 ?
W2 O16 W6 102.0(15) 7_576 7_576 ?
Al1 O16 W5 113.4(19) . 7_576 ?
W2 O16 W5 97.1(13) 7_576 7_576 ?
W6 O16 W5 97.6(12) 7_576 7_576 ?
C8 N6 C7 113(5) . . ?
C8 N6 Ag3 123(5) . . ?
C7 N6 Ag3 124(4) . . ?
N4 C1 C3 122(5) . . ?
C7 C2 N2 127(6) . . ?
N3 C3 C1 119(5) . . ?
N5 C4 C5 121(4) . 5_665 ?
N5 C5 C4 122(5) . 5_665 ?
C10 C6 N1 121(6) . . ?
Al1 O17 W1 125.5(15) . . ?
Al1 O17 W6 118.9(15) . . ?
W1 O17 W6 99.6(12) . . ?
Al1 O17 W3 115.2(16) . . ?
W1 O17 W3 97.5(11) . . ?
W6 O17 W3 93.9(10) . . ?
W4 O18 W5 136(3) 7_576 . ?
Al1 O19 W1 124.0(16) . . ?
Al1 O19 W2 117.4(15) . 7_576 ?
W1 O19 W2 98.8(12) . 7_576 ?
Al1 O19 W4 117.1(15) . 7_576 ?
W1 O19 W4 98.6(11) . 7_576 ?
W2 O19 W4 95.7(11) 7_576 7_576 ?
W2 O20 W1 137(3) . 7_576 ?
Al1 O21 W4 118.3(17) . . ?
Al1 O21 W3 116.5(16) . . ?
W4 O21 W3 101.7(13) . . ?
Al1 O21 W5 115.8(15) . 7_576 ?
W4 O21 W5 101.6(14) . 7_576 ?
W3 O21 W5 100.1(15) . 7_576 ?
C2 C7 N6 120(5) . . ?
N6 C8 C11 125(6) . . ?
C13 C9 N7 121(6) . . ?
C10 N7 C9 112(6) . . ?
C10 N7 Ag2 121(5) . . ?
C9 N7 Ag2 126(3) . . ?
N7 C10 C6 131(7) . . ?
N2 C11 C8 118(6) . . ?
C9 C13 N1 128(7) . . ?
W4 O22 W3 133(3) . . ?
C14 N10 C14 113(9) 2 . ?
C14 N10 Ag3 123(5) 2 . ?
C14 N10 Ag3 123(5) . . ?
C15 C14 N10 125(8) 3_445 . ?
C14 C15 N11 122(8) 3 . ?
C15 N11 C15 111(9) 2_655 . ?
C15 N11 Ag2 124(4) 2_655 . ?
C15 N11 Ag2 124(4) . . ?

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        27.59
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         2.071
_refine_diff_density_min         -2.596
_refine_diff_density_rms         0.279
