data_a
_audit_creation_date              2016-09-13
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2015.08.17 svn.r3210 for OlexSys, GUI svn.r5083)
;
_publ_contact_author_address      ?
_publ_contact_author_email        ?
_publ_contact_author_name         ''
_publ_contact_author_phone        ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common             ?
_chemical_name_systematic         ?
_chemical_formula_moiety          'Eu In2 S4'
_chemical_formula_sum             'Eu In2 S4'
_chemical_formula_weight          509.84
_chemical_melting_point           ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'Eu' 'Eu' -0.1578 3.6682
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'In' 'In' -0.7276 1.3100
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'S' 'S' 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system       'orthorhombic'
_space_group_IT_number            70
_space_group_name_H-M_alt         'F d d d'
_space_group_name_Hall            '-F 2uv 2vw'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x+3/4, -y+3/4, z'
 '-x+3/4, y, -z+3/4'
 'x, -y+3/4, -z+3/4'
 'x, y+1/2, z+1/2'
 '-x+3/4, -y+5/4, z+1/2'
 '-x+3/4, y+1/2, -z+5/4'
 'x, -y+5/4, -z+5/4'
 'x+1/2, y, z+1/2'
 '-x+5/4, -y+3/4, z+1/2'
 '-x+5/4, y, -z+5/4'
 'x+1/2, -y+3/4, -z+5/4'
 'x+1/2, y+1/2, z'
 '-x+5/4, -y+5/4, z'
 '-x+5/4, y+1/2, -z+3/4'
 'x+1/2, -y+5/4, -z+3/4'
 '-x, -y, -z'
 'x-3/4, y-3/4, -z'
 'x-3/4, -y, z-3/4'
 '-x, y-3/4, z-3/4'
 '-x, -y+1/2, -z+1/2'
 'x-3/4, y-1/4, -z+1/2'
 'x-3/4, -y+1/2, z-1/4'
 '-x, y-1/4, z-1/4'
 '-x+1/2, -y, -z+1/2'
 'x-1/4, y-3/4, -z+1/2'
 'x-1/4, -y, z-1/4'
 '-x+1/2, y-3/4, z-1/4'
 '-x+1/2, -y+1/2, -z'
 'x-1/4, y-1/4, -z'
 'x-1/4, -y+1/2, z-3/4'
 '-x+1/2, y-1/4, z-3/4'

_cell_length_a                    13.016(3)
_cell_length_b                    20.772(5)
_cell_length_c                    21.076(5)
_cell_angle_alpha                 90
_cell_angle_beta                  90
_cell_angle_gamma                 90
_cell_volume                      5699(2)
_cell_formula_units_Z             32
_cell_measurement_reflns_used     5817     
_cell_measurement_temperature     296(2)
_cell_measurement_theta_max       27.5131   
_cell_measurement_theta_min       3.4382  
_shelx_estimated_absorpt_T_max    0.324
_shelx_estimated_absorpt_T_min    0.295
_exptl_absorpt_coefficient_mu     16.166
_exptl_absorpt_correction_T_max   0.233    
_exptl_absorpt_correction_T_min   0.216    
_exptl_absorpt_correction_type    'MULTI-SCAN'
_exptl_absorpt_process_details    ?
_exptl_absorpt_special_details    ?
_exptl_crystal_colour             brown
_exptl_crystal_density_diffrn     4.754
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     ?
_exptl_crystal_description        block
_exptl_crystal_F_000              7200
_exptl_crystal_size_max           0.1
_exptl_crystal_size_mid           0.1
_exptl_crystal_size_min           0.09
_exptl_transmission_factor_max    ?
_exptl_transmission_factor_min    ?
_diffrn_reflns_av_R_equivalents   0.0581
_diffrn_reflns_av_unetI/netI      0.0416
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max        14
_diffrn_reflns_limit_h_min        -15
_diffrn_reflns_limit_k_max        25
_diffrn_reflns_limit_k_min        -22
_diffrn_reflns_limit_l_max        25
_diffrn_reflns_limit_l_min        -25
_diffrn_reflns_number             9320
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full         25.242
_diffrn_reflns_theta_max          25.480
_diffrn_reflns_theta_min          2.084
_diffrn_ambient_temperature       296.15
_diffrn_detector_area_resol_mean  ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type   'Bruker APEX II CCD'   
_diffrn_measurement_method        'phi and omega scans'     
_diffrn_radiation_monochromator   'graphite'
_diffrn_radiation_type            MoK\a
_diffrn_radiation_wavelength      0.71073
_diffrn_source                    ?
_reflns_Friedel_coverage          0.000
_reflns_Friedel_fraction_full     .
_reflns_Friedel_fraction_max      .
_reflns_number_gt                 1011
_reflns_number_total              1329
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression      'I > 2σ(I)'
_computing_cell_refinement        ?
_computing_data_collection        ?
_computing_data_reduction         ?
_computing_molecular_graphics     'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material   'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement   'ShelXL (Sheldrick, 2015)'
_computing_structure_solution     'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max          1.627
_refine_diff_density_min          -2.332
_refine_diff_density_rms          0.493
_refine_ls_extinction_coef        0.000549(18)
_refine_ls_extinction_expression  'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
_refine_ls_extinction_method      'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref    1.090
_refine_ls_hydrogen_treatment     undef
_refine_ls_matrix_type            full
_refine_ls_number_parameters      67
_refine_ls_number_reflns          1329
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0428
_refine_ls_R_factor_gt            0.0327
_refine_ls_restrained_S_all       1.090
_refine_ls_shift/su_max           0.001
_refine_ls_shift/su_mean          0.000
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0364P)²+232.8061P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme       calc
_refine_ls_wR_factor_gt           0.0793
_refine_ls_wR_factor_ref          0.0878
_refine_special_details           ?
_olex2_refinement_description
;
;
_atom_sites_solution_hydrogens    .
_atom_sites_solution_primary      ?
_atom_sites_solution_secondary    ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Eu1 Eu 0.6250 0.1250 0.1250 0.0133(3) Uani 1 4 d S T P . .
 Eu2 Eu 0.8750 0.12817(3) 0.3750 0.0140(2) Uani 1 2 d S T P . .
 Eu3 Eu 0.8750 0.3750 0.3750 0.0134(3) Uani 1 4 d S T P . .
 In1 In 0.62603(4) 0.25068(3) 0.26191(3) 0.0127(2) Uani 1 1 d . . . . .
 In2 In 0.90916(4) 0.25005(3) 0.19622(2) 0.0129(2) Uani 1 1 d . . . . .
 S1 S 0.73196(14) 0.25153(12) 0.16263(9) 0.0118(4) Uani 1 1 d . . . . .
 S2 S 0.99922(16) 0.16050(10) 0.25031(12) 0.0130(4) Uani 1 1 d . . . . .
 S3 S 0.50188(16) 0.16142(10) 0.25017(12) 0.0141(5) Uani 1 1 d . . . . .
 S4 S 0.75628(14) 0.25142(13) 0.34345(9) 0.0133(4) Uani 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Eu1 In1 3.8913(9) 11_554 ?
 Eu1 In1 3.8913(9) . ?
 Eu1 In1 3.8913(9) 14_545 ?
 Eu1 In1 3.8913(9) 8_544 ?
 Eu1 S1 3.078(2) 14_545 ?
 Eu1 S1 3.078(2) . ?
 Eu1 S1 3.078(2) 8_544 ?
 Eu1 S1 3.078(2) 11_554 ?
 Eu1 S3 3.178(3) 14_545 ?
 Eu1 S3 3.178(3) . ?
 Eu1 S3 3.178(3) 8_544 ?
 Eu1 S3 3.178(3) 11_554 ?
 Eu2 In1 3.9167(10) 32_656 ?
 Eu2 In1 3.9167(10) 22_655 ?
 Eu2 S1 3.080(2) 22_655 ?
 Eu2 S1 3.080(2) 32_656 ?
 Eu2 S2 3.158(2) 3_655 ?
 Eu2 S2 3.158(2) . ?
 Eu2 S3 3.213(2) 16_545 ?
 Eu2 S3 3.213(2) 14_545 ?
 Eu2 S4 3.063(3) 3_655 ?
 Eu2 S4 3.063(3) . ?
 Eu3 S2 3.194(2) 26_565 ?
 Eu3 S2 3.194(2) 21_755 ?
 Eu3 S2 3.194(2) 20_766 ?
 Eu3 S2 3.194(2) 31_556 ?
 Eu3 S4 3.069(3) 3_655 ?
 Eu3 S4 3.069(3) 4 ?
 Eu3 S4 3.069(3) . ?
 Eu3 S4 3.069(3) 2_655 ?
 In1 Eu2 3.9167(10) 26_565 ?
 In1 In1 3.3193(12) 21_655 ?
 In1 S1 2.506(2) . ?
 In1 S3 2.472(2) . ?
 In1 S3 2.484(2) 21_655 ?
 In1 S4 2.4141(19) . ?
 In2 In2 3.2757(11) 21_755 ?
 In2 S1 2.4129(19) . ?
 In2 S2 2.477(2) . ?
 In2 S2 2.479(2) 21_755 ?
 In2 S4 2.508(2) 23_655 ?
 S1 Eu2 3.080(2) 26_565 ?
 S2 Eu3 3.194(2) 21_755 ?
 S2 In2 2.479(2) 21_755 ?
 S3 Eu2 3.213(2) 14_545 ?
 S3 In1 2.484(2) 21_655 ?
 S4 In2 2.508(2) 31_556 ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 In1 Eu1 In1 95.73(3) 11_554 . ?
 In1 Eu1 In1 179.604(14) 11_554 14_545 ?
 In1 Eu1 In1 95.73(3) 8_544 14_545 ?
 In1 Eu1 In1 179.604(14) 8_544 . ?
 In1 Eu1 In1 84.27(3) 14_545 . ?
 In1 Eu1 In1 84.27(3) 8_544 11_554 ?
 S1 Eu1 In1 139.67(4) 14_545 11_554 ?
 S1 Eu1 In1 40.05(4) 8_544 8_544 ?
 S1 Eu1 In1 112.54(4) 14_545 . ?
 S1 Eu1 In1 112.54(4) 8_544 11_554 ?
 S1 Eu1 In1 139.67(4) . 8_544 ?
 S1 Eu1 In1 40.05(4) 11_554 11_554 ?
 S1 Eu1 In1 67.65(4) 14_545 8_544 ?
 S1 Eu1 In1 139.67(4) 8_544 . ?
 S1 Eu1 In1 112.54(4) 11_554 8_544 ?
 S1 Eu1 In1 67.65(4) 11_554 . ?
 S1 Eu1 In1 40.05(4) . . ?
 S1 Eu1 In1 40.05(4) 14_545 14_545 ?
 S1 Eu1 In1 67.65(4) . 11_554 ?
 S1 Eu1 In1 139.67(4) 11_554 14_545 ?
 S1 Eu1 In1 112.54(4) . 14_545 ?
 S1 Eu1 In1 67.65(4) 8_544 14_545 ?
 S1 Eu1 S1 150.14(7) . 14_545 ?
 S1 Eu1 S1 126.22(8) 14_545 11_554 ?
 S1 Eu1 S1 62.74(8) . 11_554 ?
 S1 Eu1 S1 126.22(8) . 8_544 ?
 S1 Eu1 S1 62.73(8) 14_545 8_544 ?
 S1 Eu1 S1 150.14(7) 8_544 11_554 ?
 S1 Eu1 S3 79.10(5) 8_544 8_544 ?
 S1 Eu1 S3 76.19(6) 8_544 11_554 ?
 S1 Eu1 S3 77.44(6) . 11_554 ?
 S1 Eu1 S3 76.19(6) . 14_545 ?
 S1 Eu1 S3 77.44(6) 14_545 8_544 ?
 S1 Eu1 S3 77.44(6) 8_544 14_545 ?
 S1 Eu1 S3 76.19(6) 11_554 8_544 ?
 S1 Eu1 S3 79.10(5) . . ?
 S1 Eu1 S3 79.10(5) 14_545 14_545 ?
 S1 Eu1 S3 76.19(6) 14_545 . ?
 S1 Eu1 S3 130.18(5) 11_554 14_545 ?
 S1 Eu1 S3 130.18(5) 8_544 . ?
 S1 Eu1 S3 130.18(5) 14_545 11_554 ?
 S1 Eu1 S3 77.44(6) 11_554 . ?
 S1 Eu1 S3 79.10(5) 11_554 11_554 ?
 S1 Eu1 S3 130.18(5) . 8_544 ?
 S3 Eu1 In1 39.33(4) 14_545 14_545 ?
 S3 Eu1 In1 39.33(4) . . ?
 S3 Eu1 In1 62.77(4) 8_544 11_554 ?
 S3 Eu1 In1 140.99(4) 11_554 14_545 ?
 S3 Eu1 In1 62.77(4) 14_545 . ?
 S3 Eu1 In1 39.33(4) 8_544 8_544 ?
 S3 Eu1 In1 140.99(4) 14_545 11_554 ?
 S3 Eu1 In1 140.99(4) . 8_544 ?
 S3 Eu1 In1 140.99(4) 8_544 . ?
 S3 Eu1 In1 117.01(4) . 11_554 ?
 S3 Eu1 In1 39.33(4) 11_554 11_554 ?
 S3 Eu1 In1 117.01(4) 11_554 . ?
 S3 Eu1 In1 62.77(4) . 14_545 ?
 S3 Eu1 In1 62.77(4) 11_554 8_544 ?
 S3 Eu1 In1 117.01(4) 8_544 14_545 ?
 S3 Eu1 In1 117.01(4) 14_545 8_544 ?
 S3 Eu1 S3 67.79(9) 8_544 11_554 ?
 S3 Eu1 S3 119.43(9) . 8_544 ?
 S3 Eu1 S3 152.46(8) . 11_554 ?
 S3 Eu1 S3 119.43(9) 14_545 11_554 ?
 S3 Eu1 S3 67.79(9) . 14_545 ?
 S3 Eu1 S3 152.45(8) 8_544 14_545 ?
 In1 Eu2 In1 94.91(3) 22_655 32_656 ?
 S1 Eu2 In1 67.28(4) 22_655 32_656 ?
 S1 Eu2 In1 39.76(4) 22_655 22_655 ?
 S1 Eu2 In1 39.76(4) 32_656 32_656 ?
 S1 Eu2 In1 67.28(4) 32_656 22_655 ?
 S1 Eu2 S1 62.69(8) 32_656 22_655 ?
 S1 Eu2 S2 128.86(5) 22_655 3_655 ?
 S1 Eu2 S2 74.69(5) 22_655 . ?
 S1 Eu2 S2 74.69(5) 32_656 3_655 ?
 S1 Eu2 S2 128.85(5) 32_656 . ?
 S1 Eu2 S3 76.11(6) 32_656 14_545 ?
 S1 Eu2 S3 76.11(6) 22_655 16_545 ?
 S1 Eu2 S3 78.63(5) 32_656 16_545 ?
 S1 Eu2 S3 78.63(5) 22_655 14_545 ?
 S2 Eu2 In1 61.90(4) . 22_655 ?
 S2 Eu2 In1 139.35(4) 3_655 22_655 ?
 S2 Eu2 In1 139.35(4) . 32_656 ?
 S2 Eu2 In1 61.90(4) 3_655 32_656 ?
 S2 Eu2 S2 155.44(8) 3_655 . ?
 S2 Eu2 S3 68.67(7) . 14_545 ?
 S2 Eu2 S3 118.21(7) . 16_545 ?
 S2 Eu2 S3 118.21(7) 3_655 14_545 ?
 S2 Eu2 S3 68.67(7) 3_655 16_545 ?
 S3 Eu2 In1 39.24(4) 14_545 22_655 ?
 S3 Eu2 In1 115.37(5) 14_545 32_656 ?
 S3 Eu2 In1 115.37(5) 16_545 22_655 ?
 S3 Eu2 In1 39.24(4) 16_545 32_656 ?
 S3 Eu2 S3 150.34(8) 14_545 16_545 ?
 S4 Eu2 In1 136.32(4) 3_655 22_655 ?
 S4 Eu2 In1 114.01(4) . 22_655 ?
 S4 Eu2 In1 136.32(4) . 32_656 ?
 S4 Eu2 In1 114.01(4) 3_655 32_656 ?
 S4 Eu2 S1 152.36(5) 3_655 32_656 ?
 S4 Eu2 S1 122.80(6) 3_655 22_655 ?
 S4 Eu2 S1 152.36(5) . 22_655 ?
 S4 Eu2 S1 122.80(6) . 32_656 ?
 S4 Eu2 S2 75.20(6) . 3_655 ?
 S4 Eu2 S2 84.26(6) . . ?
 S4 Eu2 S2 84.26(6) 3_655 3_655 ?
 S4 Eu2 S2 75.20(6) 3_655 . ?
 S4 Eu2 S3 77.11(6) 3_655 16_545 ?
 S4 Eu2 S3 77.11(6) . 14_545 ?
 S4 Eu2 S3 130.61(6) 3_655 14_545 ?
 S4 Eu2 S3 130.61(6) . 16_545 ?
 S4 Eu2 S4 66.62(8) 3_655 . ?
 S2 Eu3 S2 118.32(8) 26_565 31_556 ?
 S2 Eu3 S2 118.32(8) 20_766 21_755 ?
 S2 Eu3 S2 68.42(8) 26_565 21_755 ?
 S2 Eu3 S2 153.30(8) 20_766 26_565 ?
 S2 Eu3 S2 153.30(8) 21_755 31_556 ?
 S2 Eu3 S2 68.42(8) 20_766 31_556 ?
 S4 Eu3 S2 129.08(5) 3_655 26_565 ?
 S4 Eu3 S2 83.44(5) 2_655 26_565 ?
 S4 Eu3 S2 75.87(6) 3_655 20_766 ?
 S4 Eu3 S2 74.21(6) 2_655 20_766 ?
 S4 Eu3 S2 75.87(6) 4 31_556 ?
 S4 Eu3 S2 83.44(5) 3_655 31_556 ?
 S4 Eu3 S2 129.08(5) . 20_766 ?
 S4 Eu3 S2 83.44(5) 4 20_766 ?
 S4 Eu3 S2 129.08(5) 2_655 31_556 ?
 S4 Eu3 S2 129.08(5) 4 21_755 ?
 S4 Eu3 S2 74.21(6) 4 26_565 ?
 S4 Eu3 S2 74.21(6) 3_655 21_755 ?
 S4 Eu3 S2 83.44(5) . 21_755 ?
 S4 Eu3 S2 75.87(6) 2_655 21_755 ?
 S4 Eu3 S2 75.87(6) . 26_565 ?
 S4 Eu3 S2 74.21(6) . 31_556 ?
 S4 Eu3 S4 119.54(8) . 4 ?
 S4 Eu3 S4 154.98(7) . 2_655 ?
 S4 Eu3 S4 119.54(8) 2_655 3_655 ?
 S4 Eu3 S4 66.48(8) 2_655 4 ?
 S4 Eu3 S4 66.48(8) . 3_655 ?
 S4 Eu3 S4 154.98(7) 4 3_655 ?
 Eu1 In1 Eu2 84.68(2) . 26_565 ?
 In1 In1 Eu1 83.03(2) 21_655 . ?
 In1 In1 Eu2 83.74(2) 21_655 26_565 ?
 S1 In1 Eu1 52.22(6) . . ?
 S1 In1 Eu2 51.83(6) . 26_565 ?
 S1 In1 In1 114.68(5) . 21_655 ?
 S3 In1 Eu1 54.57(6) . . ?
 S3 In1 Eu1 114.51(6) 21_655 . ?
 S3 In1 Eu2 54.91(6) 21_655 26_565 ?
 S3 In1 Eu2 115.54(6) . 26_565 ?
 S3 In1 In1 47.80(5) 21_655 21_655 ?
 S3 In1 In1 48.11(5) . 21_655 ?
 S3 In1 S1 106.34(8) . . ?
 S3 In1 S1 106.14(8) 21_655 . ?
 S3 In1 S3 95.91(7) . 21_655 ?
 S4 In1 Eu1 122.32(6) . . ?
 S4 In1 Eu2 121.50(6) . 26_565 ?
 S4 In1 In1 143.31(6) . 21_655 ?
 S4 In1 S1 102.00(7) . . ?
 S4 In1 S3 122.61(9) . 21_655 ?
 S4 In1 S3 122.36(8) . . ?
 S1 In2 In2 153.27(6) . 21_755 ?
 S1 In2 S2 125.71(8) . 21_755 ?
 S1 In2 S2 126.66(8) . . ?
 S1 In2 S4 103.21(6) . 23_655 ?
 S2 In2 In2 48.59(6) 21_755 21_755 ?
 S2 In2 In2 48.65(6) . 21_755 ?
 S2 In2 S2 97.24(7) . 21_755 ?
 S2 In2 S4 99.16(8) 21_755 23_655 ?
 S2 In2 S4 98.62(8) . 23_655 ?
 S4 In2 In2 103.52(5) 23_655 21_755 ?
 Eu1 S1 Eu2 117.29(6) . 26_565 ?
 In1 S1 Eu1 87.73(7) . . ?
 In1 S1 Eu2 88.41(7) . 26_565 ?
 In2 S1 Eu1 119.81(9) . . ?
 In2 S1 Eu2 121.23(9) . 26_565 ?
 In2 S1 In1 106.31(7) . . ?
 Eu2 S2 Eu3 154.37(8) . 21_755 ?
 In2 S2 Eu2 107.48(8) . . ?
 In2 S2 Eu2 91.57(8) 21_755 . ?
 In2 S2 Eu3 92.03(8) . 21_755 ?
 In2 S2 Eu3 107.60(7) 21_755 21_755 ?
 In2 S2 In2 82.76(7) . 21_755 ?
 Eu1 S3 Eu2 151.39(8) . 14_545 ?
 In1 S3 Eu1 115.33(9) 21_655 . ?
 In1 S3 Eu1 86.10(7) . . ?
 In1 S3 Eu2 116.49(9) . 14_545 ?
 In1 S3 Eu2 85.85(7) 21_655 14_545 ?
 In1 S3 In1 84.09(7) . 21_655 ?
 Eu2 S4 Eu3 113.45(6) . . ?
 In1 S4 Eu2 120.23(10) . . ?
 In1 S4 Eu3 120.87(10) . . ?
 In1 S4 In2 105.12(8) . 31_556 ?
 In2 S4 Eu2 93.24(7) 31_556 . ?
 In2 S4 Eu3 94.41(7) 31_556 . ?

_shelx_SHELXL_version_number      '2014/7'
_olex2_submission_special_instructions 'No special instructions were received'
