# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_Pb09Eu10-BDC
_database_code_depnum_ccdc_archive 'CCDC 1490068'
_audit_update_record             
;
2016-07-04 deposited with the CCDC.
2017-01-09 downloaded from the CCDC.
;


#=============================================================================
_audit_creation_method           'SHELXL-2014/6, manual editing plus enCIFer'
_audit_creation_date             '04 Julho 2016'
#=============================================================================

#=============================================================================
# GENERAL AND CHEMICAL DATA
#=============================================================================

_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C8 H4 Eu0.10 O4 Pb0.85'
_chemical_formula_sum            'C8 H4 Eu0.10 O4 Pb0.85'
_chemical_formula_weight         355.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

#=============================================================================
# CRYSTAL DATA
#=============================================================================

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   7.6820(12)
_cell_length_b                   10.2672(15)
_cell_length_c                   18.256(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1439.9(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    180(2)
_cell_measurement_reflns_used    3087
_cell_measurement_theta_min      3.50
_cell_measurement_theta_max      29.09

_exptl_crystal_description       Prism
_exptl_crystal_colour            Colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.279
_exptl_crystal_F_000             1280
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.080
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.020
_exptl_absorpt_coefficient_mu    20.768
_shelx_estimated_absorpt_T_min   0.287
_shelx_estimated_absorpt_T_max   0.681
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2874
_exptl_absorpt_correction_T_max  0.6815
_exptl_absorpt_process_details   
; 
 SADABS V2012/1 (Bruker 2001) 
;

#=============================================================================
# EXPERIMENTAL DATA
#============================================================================= 

_exptl_special_details           
;
 ?
;
_diffrn_ambient_temperature      180(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker X8 Kappa CCD APEX II'
_diffrn_measurement_method       'ω / φ scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_interval_time  .
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            11484
_diffrn_reflns_av_unetI/netI     0.0372
_diffrn_reflns_av_R_equivalents  0.0452
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.969
_diffrn_reflns_theta_max         29.125
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             1922
_reflns_number_gt                1421
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 2012.4 (Bruker, 2012b)'
_computing_cell_refinement       'SAINT V8.27b (Bruker, 2012a)'
_computing_data_reduction        'SAINT V8.27b (Bruker, 2012a)'
_computing_structure_solution    'SHELXS (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2015)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'SHELXL-2014/6 (Sheldrick, 2015)'


#=============================================================================
# REFINEMENT DATA
#=============================================================================

_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0167P)²+3.0217P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         1922
_refine_ls_number_parameters     118
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0445
_refine_ls_R_factor_gt           0.0253
_refine_ls_wR_factor_ref         0.0543
_refine_ls_wR_factor_gt          0.0477
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pb1 Pb 1.00736(2) 0.79737(2) 0.01871(2) 0.01171(7) Uani 0.85 1 d . . P . .
Eu1 Eu 1.00736(2) 0.79737(2) 0.01871(2) 0.01171(7) Uani 0.1 1 d . . P . .
O1 O 0.8208(4) 0.5909(3) 0.0233(2) 0.0211(8) Uani 1 1 d . . . . .
O2 O 0.8059(4) 0.3787(3) 0.0529(2) 0.0178(8) Uani 1 1 d . . . . .
O3 O 0.9732(4) 0.5305(3) 0.42006(19) 0.0200(8) Uani 1 1 d . . . . .
O4 O 0.8396(5) 0.7184(3) 0.4028(2) 0.0212(8) Uani 1 1 d . . . . .
C1 C 0.8282(6) 0.4981(5) 0.0691(3) 0.0148(11) Uani 1 1 d . . . . .
C2 C 0.8611(6) 0.5301(5) 0.1480(3) 0.0160(11) Uani 1 1 d . . . . .
C3 C 0.8011(6) 0.6482(5) 0.1768(3) 0.0198(12) Uani 1 1 d . . . . .
H3 H 0.7555 0.7127 0.1448 0.024 Uiso 1 1 calc R U . . .
C4 C 0.8074(6) 0.6718(5) 0.2511(3) 0.0182(11) Uani 1 1 d . . . . .
H4 H 0.7624 0.7511 0.2701 0.022 Uiso 1 1 calc R U . . .
C5 C 0.8796(6) 0.5795(5) 0.2990(3) 0.0176(11) Uani 1 1 d . . . . .
C6 C 0.9468(7) 0.4647(5) 0.2700(3) 0.0168(11) Uani 1 1 d . . . . .
H6 H 1.0014 0.4032 0.3014 0.020 Uiso 1 1 calc R U . . .
C7 C 0.9347(7) 0.4395(5) 0.1957(3) 0.0190(12) Uani 1 1 d . . . . .
H7 H 0.9772 0.3593 0.1769 0.023 Uiso 1 1 calc R U . . .
C8 C 0.8945(6) 0.6098(5) 0.3780(3) 0.0172(11) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pb1 O4 2.483(4) 7_575 ?
Pb1 O3 2.537(4) 7_575 ?
Pb1 O1 2.560(3) . ?
Pb1 O2 2.623(3) 8_765 ?
Pb1 O3 2.646(3) 3_755 ?
Pb1 O2 2.652(3) 5_765 ?
Pb1 O1 2.775(4) 4_565 ?
O1 C1 1.269(6) . ?
O1 Eu1 2.775(4) 4_465 ?
O1 Pb1 2.775(4) 4_465 ?
O1 Pb1 3.930(3) 8_755 ?
O2 C1 1.273(6) . ?
O2 Eu1 2.623(3) 8_755 ?
O2 Pb1 2.623(3) 8_755 ?
O2 Pb1 2.652(3) 5_765 ?
O2 Eu1 2.652(3) 5_765 ?
O3 C8 1.272(6) . ?
O3 Eu1 2.537(4) 7_576 ?
O3 Pb1 2.537(4) 7_576 ?
O3 Pb1 2.646(3) 3_745 ?
O3 Eu1 2.646(3) 3_745 ?
O4 C8 1.275(6) . ?
O4 Eu1 2.483(4) 7_576 ?
O4 Pb1 2.483(4) 7_576 ?
O4 Pb1 3.037(4) 6_556 ?
O4 Eu1 3.037(4) 6_556 ?
C1 C2 1.499(7) . ?
C1 Pb1 3.427(5) 8_755 ?
C1 Pb1 3.613(5) 4_465 ?
C1 Pb1 3.656(5) 5_765 ?
C2 C7 1.394(7) . ?
C2 C3 1.399(7) . ?
C3 C4 1.379(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.403(7) . ?
C4 H4 0.9500 . ?
C5 C6 1.392(7) . ?
C5 C8 1.480(7) . ?
C6 C7 1.383(7) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Pb1 O3 52.18(11) 7_575 7_575 ?
O4 Pb1 O1 71.53(11) 7_575 . ?
O3 Pb1 O1 122.83(11) 7_575 . ?
O4 Pb1 O2 75.36(11) 7_575 8_765 ?
O3 Pb1 O2 81.50(11) 7_575 8_765 ?
O1 Pb1 O2 75.05(11) . 8_765 ?
O4 Pb1 O3 116.64(11) 7_575 3_755 ?
O3 Pb1 O3 71.07(13) 7_575 3_755 ?
O1 Pb1 O3 140.06(11) . 3_755 ?
O2 Pb1 O3 70.32(10) 8_765 3_755 ?
O4 Pb1 O2 79.40(11) 7_575 5_765 ?
O3 Pb1 O2 100.42(11) 7_575 5_765 ?
O1 Pb1 O2 75.80(11) . 5_765 ?
O2 Pb1 O2 146.16(9) 8_765 5_765 ?
O3 Pb1 O2 142.59(10) 3_755 5_765 ?
O4 Pb1 O1 103.99(11) 7_575 4_565 ?
O3 Pb1 O1 66.77(10) 7_575 4_565 ?
O1 Pb1 O1 146.82(8) . 4_565 ?
O2 Pb1 O1 136.92(10) 8_765 4_565 ?
O3 Pb1 O1 72.18(10) 3_755 4_565 ?
O2 Pb1 O1 71.10(10) 5_765 4_565 ?
C1 O1 Pb1 128.2(3) . . ?
C1 O1 Eu1 122.1(3) . 4_465 ?
Pb1 O1 Eu1 97.7 . 4_465 ?
C1 O1 Pb1 122.1(3) . 4_465 ?
Pb1 O1 Pb1 97.74(11) . 4_465 ?
C1 O1 Pb1 57.8(3) . 8_755 ?
Pb1 O1 Pb1 173.39(13) . 8_755 ?
Eu1 O1 Pb1 75.8 4_465 8_755 ?
Pb1 O1 Pb1 75.79(7) 4_465 8_755 ?
C1 O2 Eu1 119.1(3) . 8_755 ?
C1 O2 Pb1 119.1(3) . 8_755 ?
C1 O2 Pb1 134.3(3) . 5_765 ?
Eu1 O2 Pb1 99.3 8_755 5_765 ?
Pb1 O2 Pb1 99.33(11) 8_755 5_765 ?
C1 O2 Eu1 134.3(3) . 5_765 ?
Eu1 O2 Eu1 99.33(11) 8_755 5_765 ?
Pb1 O2 Eu1 99.33(11) 8_755 5_765 ?
C8 O3 Eu1 91.8(3) . 7_576 ?
C8 O3 Pb1 91.8(3) . 7_576 ?
C8 O3 Pb1 149.4(3) . 3_745 ?
Eu1 O3 Pb1 108.9 7_576 3_745 ?
Pb1 O3 Pb1 108.93(13) 7_576 3_745 ?
C8 O3 Eu1 149.4(3) . 3_745 ?
Eu1 O3 Eu1 108.93(13) 7_576 3_745 ?
C8 O4 Eu1 94.2(3) . 7_576 ?
C8 O4 Pb1 132.7(3) . 6_556 ?
Eu1 O4 Pb1 92.9 7_576 6_556 ?
Pb1 O4 Pb1 92.94(11) 7_576 6_556 ?
C8 O4 Eu1 132.7(3) . 6_556 ?
Eu1 O4 Eu1 92.94(11) 7_576 6_556 ?
O1 C1 O2 124.3(5) . . ?
O1 C1 C2 118.4(4) . . ?
O2 C1 C2 117.2(4) . . ?
O2 C1 Pb1 147.1(3) . . ?
C2 C1 Pb1 89.7(3) . . ?
O2 C1 Pb1 111.4(3) . 4_465 ?
C2 C1 Pb1 114.5(3) . 4_465 ?
Pb1 C1 Pb1 73.57(9) 8_755 4_465 ?
Pb1 C1 Pb1 68.92(9) . 4_465 ?
C2 C1 Pb1 123.0(3) . 5_765 ?
Pb1 C1 Pb1 69.09(9) 8_755 5_765 ?
Pb1 C1 Pb1 118.59(13) . 5_765 ?
Pb1 C1 Pb1 121.55(14) 4_465 5_765 ?
C7 C2 C3 118.5(5) . . ?
C7 C2 C1 121.5(5) . . ?
C3 C2 C1 119.7(5) . . ?
C7 C2 Pb1 138.8(3) . . ?
C3 C2 Pb1 72.8(3) . . ?
C1 C2 Pb1 67.0(3) . . ?
C4 C3 C2 120.7(5) . . ?
C4 C3 Pb1 133.8(3) . . ?
C2 C3 Pb1 85.6(3) . . ?
C4 C3 H3 119.7 . . ?
C2 C3 H3 119.7 . . ?
Pb1 C3 H3 51.5 . . ?
C3 C4 C5 120.5(5) . . ?
C3 C4 H4 119.7 . . ?
C5 C4 H4 119.7 . . ?
C6 C5 C4 118.8(5) . . ?
C6 C5 C8 121.4(5) . . ?
C4 C5 C8 119.7(4) . . ?
C7 C6 C5 120.4(5) . . ?
C7 C6 H6 119.8 . . ?
C5 C6 H6 119.8 . . ?
C6 C7 C2 121.0(5) . . ?
C6 C7 H7 119.5 . . ?
C2 C7 H7 119.5 . . ?
O3 C8 O4 120.2(5) . . ?
O3 C8 C5 119.4(4) . . ?
O4 C8 C5 120.3(5) . . ?
O3 C8 Eu1 61.9(3) . 7_576 ?
O4 C8 Eu1 59.5(3) . 7_576 ?
C5 C8 Eu1 164.6(3) . 7_576 ?
O3 C8 Pb1 61.9(3) . 7_576 ?
O4 C8 Pb1 59.5(3) . 7_576 ?
O4 C8 Pb1 128.9(3) . 3_745 ?
C5 C8 Pb1 108.8(3) . 3_745 ?
Eu1 C8 Pb1 77.1 7_576 3_745 ?
Pb1 C8 Pb1 77.08(12) 7_576 3_745 ?
C5 C8 Pb1 120.1(3) . 6_556 ?
Eu1 C8 Pb1 69.2 7_576 6_556 ?
Pb1 C8 Pb1 69.17(11) 7_576 6_556 ?
Pb1 C8 Pb1 108.61(12) 3_745 6_556 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pb1 O1 C1 O2 -142.7(4) . . . . ?
Eu1 O1 C1 O2 83.2(5) 4_465 . . . ?
Pb1 O1 C1 O2 83.2(5) 4_465 . . . ?
Pb1 O1 C1 O2 40.7(4) 8_755 . . . ?
Pb1 O1 C1 C2 38.8(6) . . . . ?
Eu1 O1 C1 C2 -95.3(4) 4_465 . . . ?
Pb1 O1 C1 C2 -95.3(4) 4_465 . . . ?
Pb1 O1 C1 C2 -137.7(5) 8_755 . . . ?
Pb1 O1 C1 Pb1 176.5(2) . . . 8_755 ?
Eu1 O1 C1 Pb1 42.5(3) 4_465 . . 8_755 ?
Pb1 O1 C1 Pb1 42.5(3) 4_465 . . 8_755 ?
Eu1 O1 C1 Pb1 -134.1(5) 4_465 . . . ?
Pb1 O1 C1 Pb1 -134.1(5) 4_465 . . . ?
Pb1 O1 C1 Pb1 -176.5(2) 8_755 . . . ?
Pb1 O1 C1 Pb1 134.1(5) . . . 4_465 ?
Eu1 O1 C1 Pb1 0.0 4_465 . . 4_465 ?
Pb1 O1 C1 Pb1 -42.5(3) 8_755 . . 4_465 ?
Pb1 O1 C1 Pb1 -110.9(3) . . . 5_765 ?
Eu1 O1 C1 Pb1 115.0(2) 4_465 . . 5_765 ?
Pb1 O1 C1 Pb1 115.0(2) 4_465 . . 5_765 ?
Pb1 O1 C1 Pb1 72.54(19) 8_755 . . 5_765 ?
Eu1 O2 C1 O1 -71.2(6) 8_755 . . . ?
Pb1 O2 C1 O1 -71.2(6) 8_755 . . . ?
Pb1 O2 C1 O1 72.0(6) 5_765 . . . ?
Eu1 O2 C1 O1 72.0(6) 5_765 . . . ?
Eu1 O2 C1 C2 107.3(4) 8_755 . . . ?
Pb1 O2 C1 C2 107.3(4) 8_755 . . . ?
Pb1 O2 C1 C2 -109.5(5) 5_765 . . . ?
Eu1 O2 C1 C2 -109.5(5) 5_765 . . . ?
Eu1 O2 C1 Pb1 0.0 8_755 . . 8_755 ?
Pb1 O2 C1 Pb1 143.2(6) 5_765 . . 8_755 ?
Eu1 O2 C1 Pb1 143.2(6) 5_765 . . 8_755 ?
Eu1 O2 C1 Pb1 -111.2(5) 8_755 . . . ?
Pb1 O2 C1 Pb1 -111.2(5) 8_755 . . . ?
Pb1 O2 C1 Pb1 32.0(8) 5_765 . . . ?
Eu1 O2 C1 Pb1 32.0(8) 5_765 . . . ?
Eu1 O2 C1 Pb1 -27.3(4) 8_755 . . 4_465 ?
Pb1 O2 C1 Pb1 -27.3(4) 8_755 . . 4_465 ?
Pb1 O2 C1 Pb1 116.0(3) 5_765 . . 4_465 ?
Eu1 O2 C1 Pb1 116.0(3) 5_765 . . 4_465 ?
Eu1 O2 C1 Pb1 -143.2(6) 8_755 . . 5_765 ?
Pb1 O2 C1 Pb1 -143.2(6) 8_755 . . 5_765 ?
Eu1 O2 C1 Pb1 0.0 5_765 . . 5_765 ?
O1 C1 C2 C7 -155.5(5) . . . . ?
O2 C1 C2 C7 26.0(7) . . . . ?
Pb1 C1 C2 C7 74.2(5) 8_755 . . . ?
Pb1 C1 C2 C7 -134.3(4) . . . . ?
Pb1 C1 C2 C7 159.2(4) 4_465 . . . ?
Pb1 C1 C2 C7 -9.8(6) 5_765 . . . ?
O1 C1 C2 C3 31.2(7) . . . . ?
O2 C1 C2 C3 -147.4(5) . . . . ?
Pb1 C1 C2 C3 -99.1(5) 8_755 . . . ?
Pb1 C1 C2 C3 52.4(4) . . . . ?
Pb1 C1 C2 C3 -14.2(5) 4_465 . . . ?
Pb1 C1 C2 C3 176.9(3) 5_765 . . . ?
O1 C1 C2 Pb1 -21.2(3) . . . . ?
O2 C1 C2 Pb1 160.2(4) . . . . ?
Pb1 C1 C2 Pb1 -151.5(3) 8_755 . . . ?
Pb1 C1 C2 Pb1 -66.55(18) 4_465 . . . ?
Pb1 C1 C2 Pb1 124.5(3) 5_765 . . . ?
C7 C2 C3 C4 -2.9(7) . . . . ?
C1 C2 C3 C4 170.6(5) . . . . ?
Pb1 C2 C3 C4 -139.6(5) . . . . ?
C7 C2 C3 Pb1 136.7(4) . . . . ?
C1 C2 C3 Pb1 -49.8(4) . . . . ?
C2 C3 C4 C5 2.2(7) . . . . ?
Pb1 C3 C4 C5 -114.3(5) . . . . ?
C3 C4 C5 C6 0.9(7) . . . . ?
C3 C4 C5 C8 176.5(5) . . . . ?
C4 C5 C6 C7 -3.1(8) . . . . ?
C8 C5 C6 C7 -178.6(5) . . . . ?
C5 C6 C7 C2 2.4(8) . . . . ?
C3 C2 C7 C6 0.6(7) . . . . ?
C1 C2 C7 C6 -172.8(5) . . . . ?
Pb1 C2 C7 C6 96.9(6) . . . . ?
Eu1 O3 C8 O4 -12.7(5) 7_576 . . . ?
Pb1 O3 C8 O4 -12.7(5) 7_576 . . . ?
Pb1 O3 C8 O4 121.1(6) 3_745 . . . ?
Eu1 O3 C8 O4 121.1(6) 3_745 . . . ?
Eu1 O3 C8 C5 162.5(4) 7_576 . . . ?
Pb1 O3 C8 C5 162.5(4) 7_576 . . . ?
Pb1 O3 C8 C5 -63.7(8) 3_745 . . . ?
Eu1 O3 C8 C5 -63.7(8) 3_745 . . . ?
Pb1 O3 C8 Eu1 0.000(1) 7_576 . . 7_576 ?
Pb1 O3 C8 Eu1 133.8(6) 3_745 . . 7_576 ?
Eu1 O3 C8 Eu1 133.8(6) 3_745 . . 7_576 ?
Eu1 O3 C8 Pb1 0.000(1) 7_576 . . 7_576 ?
Pb1 O3 C8 Pb1 133.8(6) 3_745 . . 7_576 ?
Eu1 O3 C8 Pb1 133.8(6) 3_745 . . 7_576 ?
Eu1 O3 C8 Pb1 -133.8(6) 7_576 . . 3_745 ?
Pb1 O3 C8 Pb1 -133.8(6) 7_576 . . 3_745 ?
Eu1 O3 C8 Pb1 0.000(1) 3_745 . . 3_745 ?
Eu1 O3 C8 Pb1 -49.4(2) 7_576 . . 6_556 ?
Pb1 O3 C8 Pb1 -49.4(2) 7_576 . . 6_556 ?
Pb1 O3 C8 Pb1 84.4(6) 3_745 . . 6_556 ?
Eu1 O3 C8 Pb1 84.4(6) 3_745 . . 6_556 ?
Eu1 O4 C8 O3 13.0(5) 7_576 . . . ?
Pb1 O4 C8 O3 13.0(5) 7_576 . . . ?
Pb1 O4 C8 O3 -84.9(6) 6_556 . . . ?
Eu1 O4 C8 O3 -84.9(6) 6_556 . . . ?
Eu1 O4 C8 C5 -162.2(4) 7_576 . . . ?
Pb1 O4 C8 C5 -162.2(4) 7_576 . . . ?
Pb1 O4 C8 C5 99.9(5) 6_556 . . . ?
Eu1 O4 C8 C5 99.9(5) 6_556 . . . ?
Pb1 O4 C8 Eu1 0.000(2) 7_576 . . 7_576 ?
Pb1 O4 C8 Eu1 -97.9(4) 6_556 . . 7_576 ?
Eu1 O4 C8 Eu1 -97.9(4) 6_556 . . 7_576 ?
Eu1 O4 C8 Pb1 0.000(2) 7_576 . . 7_576 ?
Pb1 O4 C8 Pb1 -97.9(4) 6_556 . . 7_576 ?
Eu1 O4 C8 Pb1 -97.9(4) 6_556 . . 7_576 ?
Eu1 O4 C8 Pb1 36.0(3) 7_576 . . 3_745 ?
Pb1 O4 C8 Pb1 36.0(3) 7_576 . . 3_745 ?
Pb1 O4 C8 Pb1 -61.9(5) 6_556 . . 3_745 ?
Eu1 O4 C8 Pb1 -61.9(5) 6_556 . . 3_745 ?
Eu1 O4 C8 Pb1 97.9(4) 7_576 . . 6_556 ?
Pb1 O4 C8 Pb1 97.9(4) 7_576 . . 6_556 ?
Eu1 O4 C8 Pb1 0.000(1) 6_556 . . 6_556 ?
C6 C5 C8 O3 1.3(7) . . . . ?
C4 C5 C8 O3 -174.1(4) . . . . ?
C6 C5 C8 O4 176.6(5) . . . . ?
C4 C5 C8 O4 1.1(7) . . . . ?
C6 C5 C8 Eu1 91.9(14) . . . 7_576 ?
C4 C5 C8 Eu1 -83.6(14) . . . 7_576 ?
C6 C5 C8 Pb1 91.9(14) . . . 7_576 ?
C4 C5 C8 Pb1 -83.6(14) . . . 7_576 ?
C6 C5 C8 Pb1 -18.3(5) . . . 3_745 ?
C4 C5 C8 Pb1 166.2(4) . . . 3_745 ?
C6 C5 C8 Pb1 -144.2(4) . . . 6_556 ?
C4 C5 C8 Pb1 40.3(6) . . . 6_556 ?

_refine_diff_density_max         1.476
_refine_diff_density_min         -1.406
_refine_diff_density_rms         0.228

_shelxl_version_number           2014/6

