# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1469785'
_audit_update_record             
;
2016-03-21 deposited with the CCDC.
2016-05-31 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C107 H88 Au2 Cl8 N2 O8 P6 Pt S2'
_chemical_formula_weight         2652.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.7978(1)
_cell_length_b                   14.9854(3)
_cell_length_c                   16.8833(3)
_cell_angle_alpha                84.385(8)
_cell_angle_beta                 74.318(8)
_cell_angle_gamma                70.229(7)
_cell_volume                     2933.52(8)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    8314
_cell_measurement_theta_min      2.4909
_cell_measurement_theta_max      27.4546

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.501
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1302
_exptl_absorpt_coefficient_mu    4.034
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.212
_exptl_absorpt_correction_T_max  0.446
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  Molybdenum
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18723
_diffrn_reflns_av_R_equivalents  0.0625
_diffrn_reflns_av_sigmaI/netI    0.1078
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.39
_diffrn_reflns_theta_max         25.00
_reflns_number_total             9910
_reflns_number_gt                7138
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0663P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9910
_refine_ls_number_parameters     574
_refine_ls_number_restraints     109
_refine_ls_R_factor_all          0.0574
_refine_ls_R_factor_gt           0.0489
_refine_ls_wR_factor_ref         0.1482
_refine_ls_wR_factor_gt          0.1440
_refine_ls_goodness_of_fit_ref   0.995
_refine_ls_restrained_S_all      1.010
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.0000 0.5000 0.5000 0.03360(14) Uani 1 2 d S . .
Au1 Au 0.24458(3) 0.39284(2) 0.430789(19) 0.04355(14) Uani 1 1 d . . .
S1 S -0.4504(4) 0.7269(4) -0.0558(2) 0.196(3) Uani 1 1 d U . .
P1 P 0.22765(19) 0.24758(14) 0.48234(14) 0.0427(5) Uani 1 1 d . . .
P2 P -0.03051(18) 0.35563(14) 0.53211(13) 0.0391(5) Uani 1 1 d . . .
P3 P 0.27575(18) 0.53160(15) 0.37477(13) 0.0429(5) Uani 1 1 d . . .
N1 N -0.3180(7) 0.6699(7) 0.0786(5) 0.076(3) Uani 1 1 d . . .
C1 C 0.0900(6) 0.2671(6) 0.5609(5) 0.0398(19) Uani 1 1 d . . .
H1A H 0.0741 0.2075 0.5714 0.048 Uiso 1 1 calc R . .
H1B H 0.0976 0.2863 0.6117 0.048 Uiso 1 1 calc R . .
C2 C 0.1458(6) 0.6288(6) 0.3694(5) 0.0413(19) Uani 1 1 d . . .
H2A H 0.1172 0.6169 0.3252 0.050 Uiso 1 1 calc R . .
H2B H 0.1643 0.6871 0.3565 0.050 Uiso 1 1 calc R . .
C3 C 0.3394(9) 0.1786(6) 0.5314(6) 0.060(3) Uani 1 1 d . . .
C4 C 0.4522(7) 0.1465(7) 0.4815(7) 0.070(3) Uani 1 1 d . . .
H4A H 0.4678 0.1596 0.4253 0.084 Uiso 1 1 calc R . .
C5 C 0.5428(9) 0.0929(8) 0.5194(10) 0.090(4) Uani 1 1 d . . .
H5A H 0.6173 0.0698 0.4865 0.108 Uiso 1 1 calc R . .
C6 C 0.5230(11) 0.0749(8) 0.6020(9) 0.086(4) Uani 1 1 d . . .
H6A H 0.5828 0.0403 0.6254 0.103 Uiso 1 1 calc R . .
C7 C 0.4103(10) 0.1098(8) 0.6507(8) 0.092(4) Uani 1 1 d . . .
H7A H 0.3952 0.0991 0.7073 0.110 Uiso 1 1 calc R . .
C8 C 0.3205(10) 0.1604(8) 0.6152(7) 0.079(3) Uani 1 1 d . . .
H8A H 0.2463 0.1823 0.6486 0.095 Uiso 1 1 calc R . .
C9 C 0.2324(7) 0.1705(6) 0.4067(6) 0.050(2) Uani 1 1 d . . .
C10 C 0.1875(8) 0.0950(6) 0.4289(7) 0.072(3) Uani 1 1 d . . .
H10A H 0.1589 0.0816 0.4838 0.086 Uiso 1 1 calc R . .
C11 C 0.1870(10) 0.0399(8) 0.3653(10) 0.097(4) Uani 1 1 d . . .
H11A H 0.1569 -0.0096 0.3790 0.116 Uiso 1 1 calc R . .
C12 C 0.2289(11) 0.0577(10) 0.2867(10) 0.103(5) Uani 1 1 d . . .
H12A H 0.2264 0.0204 0.2468 0.123 Uiso 1 1 calc R . .
C13 C 0.2766(11) 0.1305(10) 0.2615(8) 0.104(4) Uani 1 1 d . . .
H13A H 0.3055 0.1427 0.2063 0.125 Uiso 1 1 calc R . .
C14 C 0.2779(9) 0.1837(8) 0.3247(7) 0.080(3) Uani 1 1 d . . .
H14A H 0.3118 0.2309 0.3102 0.096 Uiso 1 1 calc R . .
C15 C -0.0680(8) 0.2942(6) 0.4620(5) 0.053(2) Uani 1 1 d . . .
C16 C -0.1198(7) 0.2264(6) 0.4897(7) 0.063(3) Uani 1 1 d . . .
H16A H -0.1454 0.2174 0.5460 0.075 Uiso 1 1 calc R . .
C17 C -0.1340(9) 0.1723(8) 0.4356(9) 0.084(4) Uani 1 1 d . . .
H17A H -0.1670 0.1253 0.4554 0.101 Uiso 1 1 calc R . .
C18 C -0.1013(12) 0.1857(9) 0.3553(10) 0.102(5) Uani 1 1 d . . .
H18A H -0.1164 0.1511 0.3194 0.122 Uiso 1 1 calc R . .
C19 C -0.0435(11) 0.2524(8) 0.3235(7) 0.096(4) Uani 1 1 d . . .
H19A H -0.0165 0.2585 0.2670 0.115 Uiso 1 1 calc R . .
C20 C -0.0275(9) 0.3074(6) 0.3755(6) 0.064(3) Uani 1 1 d . . .
H20A H 0.0087 0.3523 0.3554 0.077 Uiso 1 1 calc R . .
C21 C 0.3596(7) 0.5174(7) 0.2715(5) 0.050(2) Uani 1 1 d . . .
C22 C 0.4556(8) 0.4361(8) 0.2533(6) 0.068(3) Uani 1 1 d . . .
H22A H 0.4704 0.3905 0.2939 0.082 Uiso 1 1 calc R . .
C23 C 0.5308(9) 0.4223(10) 0.1733(7) 0.088(4) Uani 1 1 d . . .
H23A H 0.5938 0.3673 0.1615 0.106 Uiso 1 1 calc R . .
C24 C 0.5110(11) 0.4896(11) 0.1135(7) 0.100(4) Uani 1 1 d . . .
H24A H 0.5652 0.4829 0.0632 0.120 Uiso 1 1 calc R . .
C25 C 0.4111(11) 0.5681(10) 0.1264(7) 0.095(4) Uani 1 1 d . . .
H25A H 0.3933 0.6094 0.0836 0.114 Uiso 1 1 calc R . .
C26 C 0.3368(9) 0.5829(8) 0.2082(6) 0.077(3) Uani 1 1 d . . .
H26A H 0.2723 0.6369 0.2192 0.093 Uiso 1 1 calc R . .
C27 C 0.3466(6) 0.5778(5) 0.4302(5) 0.0409(19) Uani 1 1 d . . .
C28 C 0.4150(8) 0.6335(7) 0.3906(6) 0.063(3) Uani 1 1 d . . .
H28A H 0.4213 0.6473 0.3349 0.075 Uiso 1 1 calc R . .
C29 C 0.4737(10) 0.6689(8) 0.4317(7) 0.081(3) Uani 1 1 d . . .
H29A H 0.5254 0.6998 0.4043 0.098 Uiso 1 1 calc R . .
C30 C 0.4487(9) 0.6544(7) 0.5187(7) 0.077(3) Uani 1 1 d . . .
H30A H 0.4808 0.6815 0.5491 0.093 Uiso 1 1 calc R . .
C31 C 0.3784(8) 0.6017(7) 0.5608(6) 0.062(2) Uani 1 1 d . . .
H31A H 0.3644 0.5933 0.6176 0.074 Uiso 1 1 calc R . .
C32 C 0.3304(6) 0.5624(6) 0.5144(5) 0.047(2) Uani 1 1 d . . .
H32A H 0.2862 0.5247 0.5405 0.056 Uiso 1 1 calc R . .
C33 C -0.0603(6) 0.5259(5) 0.3994(5) 0.0379(18) Uani 1 1 d . . .
C34 C -0.0989(7) 0.5493(6) 0.3412(5) 0.046(2) Uani 1 1 d . . .
C35 C -0.1528(8) 0.5803(6) 0.2720(5) 0.053(2) Uani 1 1 d . . .
C36 C -0.2189(8) 0.5307(7) 0.2503(5) 0.062(2) Uani 1 1 d . . .
H36A H -0.2302 0.4785 0.2816 0.074 Uiso 1 1 calc R . .
C37 C -0.2638(8) 0.5574(8) 0.1870(6) 0.074(3) Uani 1 1 d . . .
H37A H -0.3029 0.5220 0.1723 0.088 Uiso 1 1 calc R . .
C38 C -0.2534(8) 0.6375(8) 0.1422(5) 0.060(3) Uani 1 1 d . . .
C39 C -0.1940(8) 0.6871(7) 0.1610(5) 0.059(2) Uani 1 1 d . . .
H39A H -0.1871 0.7409 0.1305 0.071 Uiso 1 1 calc R . .
C40 C -0.1435(7) 0.6584(6) 0.2249(5) 0.056(2) Uani 1 1 d . . .
H40A H -0.1015 0.6930 0.2368 0.067 Uiso 1 1 calc R . .
C41 C -0.4287(10) 0.7270(8) 0.1005(6) 0.078(3) Uani 1 1 d U . .
C42 C -0.4828(11) 0.7570(9) 0.1846(7) 0.094(3) Uani 1 1 d U . .
H42A H -0.4398 0.7412 0.2234 0.113 Uiso 1 1 calc R . .
C43 C -0.5992(11) 0.8097(9) 0.2080(9) 0.108(3) Uani 1 1 d U . .
H43A H -0.6332 0.8261 0.2630 0.129 Uiso 1 1 calc R . .
C44 C -0.6675(13) 0.8389(10) 0.1501(9) 0.111(3) Uani 1 1 d U . .
H44A H -0.7453 0.8733 0.1659 0.133 Uiso 1 1 calc R . .
C45 C -0.6110(11) 0.8129(9) 0.0683(8) 0.107(3) Uani 1 1 d U . .
H45A H -0.6517 0.8321 0.0282 0.128 Uiso 1 1 calc R . .
C46 C -0.5019(10) 0.7622(9) 0.0469(7) 0.092(3) Uani 1 1 d U . .
C47 C -0.3154(10) 0.6585(11) -0.0667(6) 0.108(3) Uani 1 1 d U . .
C48 C -0.2571(11) 0.6244(11) -0.1426(7) 0.114(3) Uani 1 1 d U . .
H48A H -0.2950 0.6437 -0.1843 0.136 Uiso 1 1 calc R . .
C49 C -0.1539(12) 0.5677(12) -0.1621(8) 0.147(4) Uani 1 1 d U . .
H49A H -0.1168 0.5437 -0.2147 0.177 Uiso 1 1 calc R . .
C50 C -0.1020(13) 0.5454(13) -0.0960(8) 0.163(5) Uani 1 1 d U . .
H50A H -0.0273 0.5034 -0.1068 0.196 Uiso 1 1 calc R . .
C51 C -0.1510(11) 0.5796(11) -0.0158(7) 0.132(4) Uani 1 1 d U . .
H51A H -0.1109 0.5651 0.0248 0.159 Uiso 1 1 calc R . .
C52 C -0.2592(10) 0.6343(10) -0.0027(6) 0.088(3) Uani 1 1 d U . .
Cl1 Cl 0.9974(3) 0.1016(2) 0.7187(2) 0.0950(10) Uani 1 1 d . . .
O4 O 0.9699(8) 0.0361(7) 0.7782(5) 0.121(3) Uani 1 1 d . . .
O3 O 1.0912(12) 0.0532(8) 0.6482(7) 0.181(6) Uani 1 1 d . . .
O2 O 1.0114(12) 0.1774(9) 0.7471(7) 0.192(6) Uani 1 1 d . . .
O1 O 0.8983(11) 0.1397(8) 0.6895(8) 0.165(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.006 0.000 0.000 815 113 ' '
_platon_squeeze_details          
;
The unit cell contains 3 CH2Cl2 molecules which have been treated as 
a diffuse contribution to the overall scattering without specific atom 
positions by SQUEEZE/PLATON. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C33 2.002(8) . ?
Pt1 C33 2.002(8) 2_566 ?
Pt1 P2 2.314(2) 2_566 ?
Pt1 P2 2.314(2) . ?
Pt1 Au1 2.9549(4) . ?
Pt1 Au1 2.9549(4) 2_566 ?
Au1 P3 2.313(2) . ?
Au1 P1 2.322(2) . ?
S1 C47 1.654(13) . ?
S1 C46 1.746(12) . ?
P1 C9 1.779(9) . ?
P1 C3 1.809(10) . ?
P1 C1 1.847(8) . ?
P2 C1 1.808(8) . ?
P2 C15 1.815(9) . ?
P2 C2 1.874(8) 2_566 ?
P3 C21 1.773(9) . ?
P3 C27 1.785(8) . ?
P3 C2 1.820(8) . ?
N1 C41 1.354(13) . ?
N1 C52 1.431(12) . ?
N1 C38 1.477(11) . ?
C2 P2 1.874(8) 2_566 ?
C3 C8 1.386(13) . ?
C3 C4 1.406(13) . ?
C4 C5 1.439(14) . ?
C5 C6 1.366(16) . ?
C6 C7 1.401(15) . ?
C7 C8 1.396(13) . ?
C9 C14 1.372(13) . ?
C9 C10 1.411(12) . ?
C10 C11 1.419(14) . ?
C11 C12 1.327(17) . ?
C12 C13 1.401(18) . ?
C13 C14 1.400(14) . ?
C15 C16 1.373(12) . ?
C15 C20 1.430(12) . ?
C16 C17 1.364(14) . ?
C17 C18 1.323(17) . ?
C18 C19 1.420(17) . ?
C19 C20 1.358(13) . ?
C21 C22 1.395(13) . ?
C21 C26 1.400(13) . ?
C22 C23 1.417(13) . ?
C23 C24 1.366(16) . ?
C24 C25 1.395(16) . ?
C25 C26 1.438(14) . ?
C27 C32 1.387(11) . ?
C27 C28 1.407(11) . ?
C28 C29 1.397(12) . ?
C29 C30 1.427(14) . ?
C30 C31 1.402(13) . ?
C31 C32 1.391(12) . ?
C33 C34 1.188(10) . ?
C34 C35 1.473(11) . ?
C35 C40 1.370(11) . ?
C35 C36 1.431(11) . ?
C36 C37 1.313(11) . ?
C37 C38 1.382(13) . ?
C38 C39 1.336(13) . ?
C39 C40 1.367(11) . ?
C41 C46 1.417(14) . ?
C41 C42 1.442(14) . ?
C42 C43 1.395(16) . ?
C43 C44 1.424(17) . ?
C44 C45 1.399(17) . ?
C45 C46 1.312(15) . ?
C47 C48 1.348(14) . ?
C47 C52 1.407(13) . ?
C48 C49 1.278(17) . ?
C49 C50 1.405(17) . ?
C50 C51 1.395(16) . ?
C51 C52 1.320(15) . ?
Cl1 O2 1.358(10) . ?
Cl1 O4 1.394(8) . ?
Cl1 O1 1.404(11) . ?
Cl1 O3 1.481(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C33 Pt1 C33 180.000(1) . 2_566 ?
C33 Pt1 P2 83.8(2) . 2_566 ?
C33 Pt1 P2 96.2(2) 2_566 2_566 ?
C33 Pt1 P2 96.2(2) . . ?
C33 Pt1 P2 83.8(2) 2_566 . ?
P2 Pt1 P2 180.0 2_566 . ?
C33 Pt1 Au1 101.7(2) . . ?
C33 Pt1 Au1 78.3(2) 2_566 . ?
P2 Pt1 Au1 92.38(5) 2_566 . ?
P2 Pt1 Au1 87.62(5) . . ?
C33 Pt1 Au1 78.3(2) . 2_566 ?
C33 Pt1 Au1 101.7(2) 2_566 2_566 ?
P2 Pt1 Au1 87.62(5) 2_566 2_566 ?
P2 Pt1 Au1 92.38(5) . 2_566 ?
Au1 Pt1 Au1 180.000(1) . 2_566 ?
P3 Au1 P1 175.70(7) . . ?
P3 Au1 Pt1 89.87(5) . . ?
P1 Au1 Pt1 94.43(6) . . ?
C47 S1 C46 106.1(5) . . ?
C9 P1 C3 104.4(4) . . ?
C9 P1 C1 107.7(4) . . ?
C3 P1 C1 106.7(4) . . ?
C9 P1 Au1 114.2(3) . . ?
C3 P1 Au1 114.0(3) . . ?
C1 P1 Au1 109.4(3) . . ?
C1 P2 C15 104.2(4) . . ?
C1 P2 C2 101.9(4) . 2_566 ?
C15 P2 C2 106.6(4) . 2_566 ?
C1 P2 Pt1 112.2(3) . . ?
C15 P2 Pt1 122.6(3) . . ?
C2 P2 Pt1 107.3(3) 2_566 . ?
C21 P3 C27 106.8(4) . . ?
C21 P3 C2 103.9(4) . . ?
C27 P3 C2 105.0(4) . . ?
C21 P3 Au1 112.4(3) . . ?
C27 P3 Au1 113.4(3) . . ?
C2 P3 Au1 114.4(3) . . ?
C41 N1 C52 124.2(8) . . ?
C41 N1 C38 119.1(8) . . ?
C52 N1 C38 116.6(8) . . ?
P2 C1 P1 113.9(4) . . ?
P3 C2 P2 112.6(4) . 2_566 ?
C8 C3 C4 118.9(10) . . ?
C8 C3 P1 123.7(8) . . ?
C4 C3 P1 117.4(8) . . ?
C3 C4 C5 118.3(11) . . ?
C6 C5 C4 122.2(12) . . ?
C5 C6 C7 118.3(11) . . ?
C8 C7 C6 120.6(11) . . ?
C3 C8 C7 121.6(11) . . ?
C14 C9 C10 117.8(9) . . ?
C14 C9 P1 121.0(8) . . ?
C10 C9 P1 121.2(7) . . ?
C9 C10 C11 118.5(11) . . ?
C12 C11 C10 121.2(13) . . ?
C11 C12 C13 122.6(13) . . ?
C14 C13 C12 115.8(12) . . ?
C9 C14 C13 124.1(11) . . ?
C16 C15 C20 119.5(8) . . ?
C16 C15 P2 121.4(7) . . ?
C20 C15 P2 118.5(7) . . ?
C17 C16 C15 120.7(10) . . ?
C18 C17 C16 120.9(12) . . ?
C17 C18 C19 120.5(11) . . ?
C20 C19 C18 120.2(12) . . ?
C19 C20 C15 118.1(10) . . ?
C22 C21 C26 118.5(8) . . ?
C22 C21 P3 117.2(7) . . ?
C26 C21 P3 124.3(7) . . ?
C21 C22 C23 120.6(10) . . ?
C24 C23 C22 120.2(11) . . ?
C23 C24 C25 121.4(11) . . ?
C24 C25 C26 117.8(11) . . ?
C21 C26 C25 121.2(11) . . ?
C32 C27 C28 119.0(8) . . ?
C32 C27 P3 119.9(6) . . ?
C28 C27 P3 121.0(6) . . ?
C29 C28 C27 122.5(8) . . ?
C28 C29 C30 115.2(9) . . ?
C31 C30 C29 123.7(9) . . ?
C32 C31 C30 117.3(9) . . ?
C27 C32 C31 121.8(8) . . ?
C34 C33 Pt1 174.4(7) . . ?
C33 C34 C35 176.9(9) . . ?
C40 C35 C36 116.0(8) . . ?
C40 C35 C34 122.2(8) . . ?
C36 C35 C34 121.8(8) . . ?
C37 C36 C35 121.2(9) . . ?
C36 C37 C38 120.5(9) . . ?
C39 C38 C37 120.4(8) . . ?
C39 C38 N1 122.0(9) . . ?
C37 C38 N1 117.4(9) . . ?
C38 C39 C40 119.8(9) . . ?
C39 C40 C35 122.0(9) . . ?
N1 C41 C46 125.5(10) . . ?
N1 C41 C42 120.7(10) . . ?
C46 C41 C42 113.7(11) . . ?
C43 C42 C41 120.4(12) . . ?
C42 C43 C44 121.8(13) . . ?
C45 C44 C43 116.3(13) . . ?
C46 C45 C44 121.5(13) . . ?
C45 C46 C41 126.0(12) . . ?
C45 C46 S1 114.8(9) . . ?
C41 C46 S1 118.9(9) . . ?
C48 C47 C52 119.0(11) . . ?
C48 C47 S1 116.4(9) . . ?
C52 C47 S1 124.6(9) . . ?
C49 C48 C47 125.4(12) . . ?
C48 C49 C50 113.3(12) . . ?
C51 C50 C49 126.8(14) . . ?
C52 C51 C50 114.0(12) . . ?
C51 C52 C47 121.4(11) . . ?
C51 C52 N1 118.0(9) . . ?
C47 C52 N1 120.6(10) . . ?
O2 Cl1 O4 115.8(7) . . ?
O2 Cl1 O1 104.7(9) . . ?
O4 Cl1 O1 103.3(6) . . ?
O2 Cl1 O3 114.4(8) . . ?
O4 Cl1 O3 110.9(6) . . ?
O1 Cl1 O3 106.5(9) . . ?

_diffrn_measured_fraction_theta_max 0.960
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.960
_refine_diff_density_max         1.533
_refine_diff_density_min         -1.534
_refine_diff_density_rms         0.147
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
_solvent_exptl_crystal_recrystallization_method CH2Cl2
