# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_dk
_database_code_depnum_ccdc_archive 'CCDC 1504790'
_audit_update_record             
;
2016-09-18 deposited with the CCDC.
2017-01-15 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C55 H57 Cl3 Eu N7 O2'
_chemical_formula_weight         1106.39

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.0210(3)
_cell_length_b                   19.9533(3)
_cell_length_c                   15.8740(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.235(2)
_cell_angle_gamma                90.00
_cell_volume                     5359.32(16)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    22013
_cell_measurement_theta_min      2.15
_cell_measurement_theta_max      27.48

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.25
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.371
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2264
_exptl_absorpt_coefficient_mu    1.366
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Oxford Diffraction Supernova'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            22013
_diffrn_reflns_av_R_equivalents  0.0517
_diffrn_reflns_av_sigmaI/netI    0.0648
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.58
_diffrn_reflns_theta_max         26.29
_reflns_number_total             10576
_reflns_number_gt                8383
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1176P)²+22.2389P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10576
_refine_ls_number_parameters     603
_refine_ls_number_restraints     348
_refine_ls_R_factor_all          0.0918
_refine_ls_R_factor_gt           0.0751
_refine_ls_wR_factor_ref         0.2224
_refine_ls_wR_factor_gt          0.2076
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_restrained_S_all      1.126
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.03912(3) 0.731183(18) 0.40270(2) 0.03742(16) Uani 1 1 d . . .
Cl2 Cl 0.08957(11) 0.63627(8) 0.30325(10) 0.0339(4) Uani 1 1 d . . .
Cl3 Cl 0.13386(13) 0.81214(9) 0.32427(13) 0.0437(5) Uani 1 1 d . . .
Cl1 Cl -0.09025(15) 0.74651(13) 0.29662(14) 0.0546(5) Uani 1 1 d . . .
N1 N 0.0200(4) 0.7349(3) 0.5674(4) 0.0309(12) Uani 1 1 d . . .
N2 N -0.0320(4) 0.6326(3) 0.4578(3) 0.0315(12) Uani 1 1 d . . .
N3 N 0.1600(4) 0.7090(3) 0.5054(4) 0.0351(13) Uani 1 1 d . . .
N6 N 0.2342(4) 0.7358(4) 0.6255(4) 0.0452(16) Uani 1 1 d . . .
N5 N -0.0714(4) 0.5674(3) 0.5603(3) 0.0310(12) Uani 1 1 d . . .
N4 N -0.0081(4) 0.8419(3) 0.4590(4) 0.0340(13) Uani 1 1 d . . .
N7 N -0.0981(4) 0.8898(3) 0.5334(4) 0.0327(13) Uani 1 1 d . . .
C1 C 0.4718(13) 1.0277(11) 0.5966(13) 0.137(7) Uani 1 1 d U . .
H1A H 0.4242 1.0310 0.5622 0.205 Uiso 1 1 calc R . .
H1B H 0.5115 1.0591 0.5921 0.205 Uiso 1 1 calc R . .
C2 C 0.4826(10) 0.9808(9) 0.6492(11) 0.100(4) Uani 1 1 d U . .
H2A H 0.5309 0.9788 0.6827 0.120 Uiso 1 1 calc R . .
C3 C 0.4221(8) 0.9272(7) 0.6614(9) 0.078(3) Uani 1 1 d U . .
C4 C 0.4434(7) 0.8798(7) 0.7223(8) 0.073(3) Uani 1 1 d U . .
H4A H 0.4928 0.8817 0.7538 0.088 Uiso 1 1 calc R . .
C5 C 0.3904(6) 0.8290(6) 0.7364(7) 0.062(2) Uani 1 1 d U . .
H5A H 0.4052 0.7960 0.7763 0.075 Uiso 1 1 calc R . .
C6 C 0.3168(5) 0.8268(5) 0.6925(5) 0.0463(17) Uani 1 1 d U . .
C7 C 0.2970(7) 0.8772(6) 0.6335(7) 0.067(2) Uani 1 1 d U . .
H7A H 0.2469 0.8778 0.6036 0.081 Uiso 1 1 calc R . .
C8 C 0.3506(8) 0.9262(7) 0.6189(9) 0.079(3) Uani 1 1 d U . .
H8A H 0.3365 0.9591 0.5786 0.095 Uiso 1 1 calc R . .
C9 C 0.2603(6) 0.7710(5) 0.7065(5) 0.053(2) Uani 1 1 d U . .
H9A H 0.2859 0.7393 0.7469 0.064 Uiso 1 1 calc R . .
H9B H 0.2146 0.7892 0.7301 0.064 Uiso 1 1 calc R . .
C10 C 0.1623(5) 0.7380(4) 0.5816(5) 0.0359(15) Uani 1 1 d U . .
C11 C 0.2835(5) 0.7023(5) 0.5769(5) 0.0491(18) Uani 1 1 d U . .
C12 C 0.3627(6) 0.6851(7) 0.5923(7) 0.067(2) Uani 1 1 d U . .
H12A H 0.3932 0.6966 0.6424 0.080 Uiso 1 1 calc R . .
C13 C 0.3936(7) 0.6501(7) 0.5293(8) 0.075(3) Uani 1 1 d U . .
H13A H 0.4462 0.6367 0.5379 0.090 Uiso 1 1 calc R . .
C14 C 0.3484(6) 0.6333(7) 0.4511(8) 0.067(2) Uani 1 1 d U . .
H14A H 0.3717 0.6097 0.4098 0.080 Uiso 1 1 calc R . .
C15 C 0.2700(6) 0.6521(5) 0.4368(6) 0.0527(19) Uani 1 1 d U . .
H15A H 0.2399 0.6420 0.3859 0.063 Uiso 1 1 calc R . .
C16 C 0.2376(5) 0.6864(4) 0.5005(5) 0.0432(17) Uani 1 1 d U . .
C17 C 0.0904(5) 0.7685(4) 0.6125(4) 0.0360(15) Uani 1 1 d U . .
H17A H 0.0914 0.7621 0.6732 0.043 Uiso 1 1 calc R . .
H17B H 0.0886 0.8163 0.6008 0.043 Uiso 1 1 calc R . .
C18 C -0.0521(5) 0.7748(4) 0.5778(5) 0.0355(15) Uani 1 1 d U . .
H18A H -0.0989 0.7481 0.5617 0.043 Uiso 1 1 calc R . .
H18B H -0.0523 0.7880 0.6366 0.043 Uiso 1 1 calc R . .
C19 C -0.0527(4) 0.8354(4) 0.5232(4) 0.0310(14) Uani 1 1 d U . .
C20 C -0.0273(5) 0.9055(3) 0.4250(4) 0.0318(14) Uani 1 1 d U . .
C21 C -0.0839(5) 0.9358(4) 0.4704(4) 0.0333(14) Uani 1 1 d U . .
C22 C -0.1154(5) 0.9985(4) 0.4503(5) 0.0383(15) Uani 1 1 d U . .
H22A H -0.1542 1.0174 0.4798 0.046 Uiso 1 1 calc R . .
C23 C -0.0861(5) 1.0314(4) 0.3839(5) 0.0400(16) Uani 1 1 d U . .
H23A H -0.1056 1.0737 0.3683 0.048 Uiso 1 1 calc R . .
C24 C -0.0288(5) 1.0035(4) 0.3402(4) 0.0368(15) Uani 1 1 d U . .
H24A H -0.0101 1.0276 0.2964 0.044 Uiso 1 1 calc R . .
C25 C 0.0017(5) 0.9403(4) 0.3598(4) 0.0356(15) Uani 1 1 d U . .
H25A H 0.0406 0.9219 0.3299 0.043 Uiso 1 1 calc R . .
C26 C -0.1559(5) 0.8983(4) 0.5938(5) 0.0430(17) Uani 1 1 d U . .
H26A H -0.1604 0.9456 0.6062 0.052 Uiso 1 1 calc R . .
H26B H -0.1365 0.8758 0.6462 0.052 Uiso 1 1 calc R . .
C27 C -0.2359(6) 0.8716(7) 0.5642(8) 0.068(2) Uani 1 1 d U . .
C28 C -0.2873(9) 0.8658(10) 0.6215(12) 0.106(4) Uani 1 1 d U . .
H28A H -0.2717 0.8773 0.6775 0.127 Uiso 1 1 calc R . .
C29 C -0.3628(10) 0.8430(11) 0.5991(14) 0.123(4) Uani 1 1 d U . .
H29A H -0.3968 0.8386 0.6408 0.147 Uiso 1 1 calc R . .
C30 C -0.3878(10) 0.8275(12) 0.5224(14) 0.125(4) Uani 1 1 d U . .
C31 C -0.3336(10) 0.8299(11) 0.4605(12) 0.125(4) Uani 1 1 d U . .
H31A H -0.3467 0.8137 0.4059 0.150 Uiso 1 1 calc R . .
C32 C -0.2613(9) 0.8573(10) 0.4852(10) 0.105(4) Uani 1 1 d U . .
H32A H -0.2281 0.8663 0.4437 0.126 Uiso 1 1 calc R . .
C33 C -0.4677(12) 0.8036(13) 0.5084(14) 0.145(5) Uani 1 1 d DU . .
H33A H -0.4955 0.8013 0.5557 0.174 Uiso 1 1 calc R . .
C34 C -0.5056(17) 0.7846(13) 0.4359(15) 0.169(8) Uani 1 1 d DU . .
H34A H -0.4804 0.7859 0.3867 0.254 Uiso 1 1 calc R . .
H34C H -0.5576 0.7699 0.4336 0.254 Uiso 1 1 calc R . .
C35 C 0.0116(5) 0.6680(3) 0.6049(4) 0.0315(14) Uani 1 1 d U . .
H35A H -0.0166 0.6717 0.6546 0.038 Uiso 1 1 calc R . .
H35B H 0.0634 0.6493 0.6224 0.038 Uiso 1 1 calc R . .
C36 C -0.0326(4) 0.6229(3) 0.5416(4) 0.0305(13) Uani 1 1 d U . .
C37 C -0.0740(4) 0.5784(3) 0.4206(4) 0.0302(13) Uani 1 1 d U . .
C38 C -0.0937(5) 0.5628(4) 0.3355(5) 0.0380(15) Uani 1 1 d U . .
H38A H -0.0784 0.5901 0.2927 0.046 Uiso 1 1 calc R . .
C39 C -0.1378(5) 0.5042(4) 0.3170(5) 0.0417(16) Uani 1 1 d U . .
H39A H -0.1514 0.4922 0.2607 0.050 Uiso 1 1 calc R . .
C40 C -0.1617(5) 0.4635(4) 0.3808(5) 0.0454(17) Uani 1 1 d U . .
H40A H -0.1906 0.4250 0.3660 0.054 Uiso 1 1 calc R . .
C41 C -0.1434(5) 0.4791(4) 0.4663(5) 0.0418(16) Uani 1 1 d U . .
H41A H -0.1597 0.4523 0.5091 0.050 Uiso 1 1 calc R . .
C42 C -0.0994(5) 0.5371(4) 0.4837(5) 0.0346(14) Uani 1 1 d U . .
C43 C -0.0917(5) 0.5457(4) 0.6439(5) 0.0386(16) Uani 1 1 d U . .
H43A H -0.0537 0.5647 0.6874 0.046 Uiso 1 1 calc R . .
H43B H -0.0874 0.4973 0.6477 0.046 Uiso 1 1 calc R . .
C44 C -0.1726(6) 0.5659(5) 0.6607(6) 0.0494(18) Uani 1 1 d DU . .
C45 C -0.2018(9) 0.6303(8) 0.6479(11) 0.096(3) Uani 1 1 d U . .
H45A H -0.1704 0.6623 0.6253 0.115 Uiso 1 1 calc R . .
C46 C -0.2759(10) 0.6487(10) 0.6677(13) 0.112(4) Uani 1 1 d U . .
H46A H -0.2925 0.6929 0.6608 0.134 Uiso 1 1 calc R . .
C47 C -0.3233(9) 0.6037(10) 0.6963(11) 0.101(3) Uani 1 1 d U . .
C48 C -0.2979(9) 0.5407(10) 0.7044(12) 0.109(4) Uani 1 1 d U . .
H48A H -0.3324 0.5080 0.7200 0.130 Uiso 1 1 calc R . .
C49 C -0.2228(8) 0.5223(8) 0.6908(10) 0.092(3) Uani 1 1 d DU . .
H49A H -0.2062 0.4786 0.7027 0.111 Uiso 1 1 calc R . .
C50 C -0.4053(10) 0.6227(12) 0.7132(12) 0.118(4) Uani 1 1 d U . .
H50A H -0.4392 0.5876 0.7228 0.141 Uiso 1 1 calc R . .
C51 C -0.4346(12) 0.6832(14) 0.7161(15) 0.152(7) Uani 1 1 d U . .
H51B H -0.4033 0.7202 0.7070 0.228 Uiso 1 1 calc R . .
H51C H -0.4867 0.6892 0.7272 0.228 Uiso 1 1 calc R . .
C52 C 0.3236(11) 0.9190(13) 0.3001(13) 0.134(7) Uani 1 1 d U . .
H52A H 0.3783 0.9081 0.2983 0.201 Uiso 1 1 calc R . .
H52B H 0.3121 0.9609 0.2716 0.201 Uiso 1 1 calc R . .
H52C H 0.2912 0.8844 0.2724 0.201 Uiso 1 1 calc R . .
C53 C 0.3065(10) 0.9249(13) 0.3912(13) 0.135(7) Uani 1 1 d U . .
H53A H 0.3193 0.8827 0.4198 0.162 Uiso 1 1 calc R . .
H53B H 0.3406 0.9591 0.4191 0.162 Uiso 1 1 calc R . .
O1 O 0.2293(5) 0.9408(4) 0.3995(6) 0.078(2) Uani 1 1 d . . .
H1C H 0.1842 0.9491 0.3730 0.094 Uiso 1 1 d R . .
C55 C 0.678(3) 0.878(3) 0.911(4) 0.646(17) Uani 1 1 d DU . .
H55A H 0.7249 0.9046 0.9060 0.775 Uiso 1 1 calc R . .
H55B H 0.6802 0.8608 0.9680 0.775 Uiso 1 1 calc R . .
C54 C 0.611(5) 0.917(3) 0.893(5) 0.64(2) Uiso 1 1 d DU . .
H54A H 0.5933 0.9333 0.9444 0.954 Uiso 1 1 calc R . .
H54B H 0.5695 0.8908 0.8626 0.954 Uiso 1 1 calc R . .
H54C H 0.6226 0.9546 0.8581 0.954 Uiso 1 1 calc R . .
O2 O 0.674(3) 0.826(3) 0.853(3) 0.50(3) Uiso 1 1 d D . .
H2C H 0.6931 0.8007 0.8174 0.743 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 N2 2.516(6) . ?
Eu1 N3 2.522(7) . ?
Eu1 N4 2.545(6) . ?
Eu1 Cl1 2.641(2) . ?
Eu1 Cl2 2.6666(16) . ?
Eu1 N1 2.671(6) . ?
Eu1 Cl3 2.6824(18) . ?
N1 C35 1.475(8) . ?
N1 C17 1.487(9) . ?
N1 C18 1.488(10) . ?
N2 C36 1.346(8) . ?
N2 C37 1.393(9) . ?
N3 C10 1.337(9) . ?
N3 C16 1.406(11) . ?
N6 C10 1.341(11) . ?
N6 C11 1.373(12) . ?
N6 C9 1.491(10) . ?
N5 C36 1.340(9) . ?
N5 C42 1.394(9) . ?
N5 C43 1.472(9) . ?
N4 C19 1.342(9) . ?
N4 C20 1.404(9) . ?
N7 C19 1.352(9) . ?
N7 C21 1.397(9) . ?
N7 C26 1.455(9) . ?
C1 C2 1.25(2) . ?
C2 C3 1.512(19) . ?
C3 C8 1.325(19) . ?
C3 C4 1.373(19) . ?
C4 C5 1.392(16) . ?
C5 C6 1.366(13) . ?
C6 C7 1.390(15) . ?
C6 C9 1.503(12) . ?
C7 C8 1.374(17) . ?
C10 C17 1.497(12) . ?
C11 C12 1.387(14) . ?
C11 C16 1.406(12) . ?
C12 C13 1.369(16) . ?
C13 C14 1.428(17) . ?
C14 C15 1.381(14) . ?
C15 C16 1.385(13) . ?
C18 C19 1.487(10) . ?
C20 C25 1.382(10) . ?
C20 C21 1.401(10) . ?
C21 C22 1.386(10) . ?
C22 C23 1.380(11) . ?
C23 C24 1.375(12) . ?
C24 C25 1.386(10) . ?
C26 C27 1.491(14) . ?
C27 C32 1.31(2) . ?
C27 C28 1.333(18) . ?
C28 C29 1.37(2) . ?
C29 C30 1.28(3) . ?
C30 C31 1.42(3) . ?
C30 C33 1.44(2) . ?
C31 C32 1.36(2) . ?
C33 C34 1.314(18) . ?
C35 C36 1.490(10) . ?
C37 C38 1.390(10) . ?
C37 C42 1.402(10) . ?
C38 C39 1.402(11) . ?
C39 C40 1.392(12) . ?
C40 C41 1.394(12) . ?
C41 C42 1.389(11) . ?
C43 C44 1.486(12) . ?
C44 C49 1.343(13) . ?
C44 C45 1.385(18) . ?
C45 C46 1.38(2) . ?
C46 C47 1.32(2) . ?
C47 C48 1.33(2) . ?
C47 C50 1.50(2) . ?
C48 C49 1.37(2) . ?
C50 C51 1.31(3) . ?
C52 C53 1.51(2) . ?
C53 O1 1.374(19) . ?
C55 O2 1.38(2) . ?
C55 C54 1.39(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Eu1 N3 91.6(2) . . ?
N2 Eu1 N4 112.0(2) . . ?
N3 Eu1 N4 101.0(2) . . ?
N2 Eu1 Cl1 85.01(15) . . ?
N3 Eu1 Cl1 176.38(15) . . ?
N4 Eu1 Cl1 81.41(15) . . ?
N2 Eu1 Cl2 81.28(14) . . ?
N3 Eu1 Cl2 88.03(14) . . ?
N4 Eu1 Cl2 163.43(13) . . ?
Cl1 Eu1 Cl2 90.26(7) . . ?
N2 Eu1 N1 64.34(17) . . ?
N3 Eu1 N1 63.2(2) . . ?
N4 Eu1 N1 63.60(18) . . ?
Cl1 Eu1 N1 116.07(15) . . ?
Cl2 Eu1 N1 132.89(13) . . ?
N2 Eu1 Cl3 165.54(14) . . ?
N3 Eu1 Cl3 85.20(15) . . ?
N4 Eu1 Cl3 82.48(14) . . ?
Cl1 Eu1 Cl3 97.82(8) . . ?
Cl2 Eu1 Cl3 84.51(5) . . ?
N1 Eu1 Cl3 125.52(13) . . ?
C35 N1 C17 108.9(6) . . ?
C35 N1 C18 108.8(6) . . ?
C17 N1 C18 109.6(6) . . ?
C35 N1 Eu1 113.4(4) . . ?
C17 N1 Eu1 107.8(4) . . ?
C18 N1 Eu1 108.2(4) . . ?
C36 N2 C37 104.4(6) . . ?
C36 N2 Eu1 120.8(5) . . ?
C37 N2 Eu1 134.7(4) . . ?
C10 N3 C16 104.7(7) . . ?
C10 N3 Eu1 116.7(5) . . ?
C16 N3 Eu1 136.5(5) . . ?
C10 N6 C11 107.7(7) . . ?
C10 N6 C9 127.0(8) . . ?
C11 N6 C9 124.7(8) . . ?
C36 N5 C42 107.2(5) . . ?
C36 N5 C43 127.7(6) . . ?
C42 N5 C43 124.6(6) . . ?
C19 N4 C20 104.5(6) . . ?
C19 N4 Eu1 114.2(5) . . ?
C20 N4 Eu1 135.9(4) . . ?
C19 N7 C21 107.1(6) . . ?
C19 N7 C26 127.4(6) . . ?
C21 N7 C26 125.3(6) . . ?
C1 C2 C3 124.1(18) . . ?
C8 C3 C4 120.4(12) . . ?
C8 C3 C2 123.1(15) . . ?
C4 C3 C2 116.4(13) . . ?
C3 C4 C5 119.2(12) . . ?
C6 C5 C4 121.1(11) . . ?
C5 C6 C7 117.5(9) . . ?
C5 C6 C9 120.9(9) . . ?
C7 C6 C9 121.6(9) . . ?
C8 C7 C6 120.8(11) . . ?
C3 C8 C7 121.0(13) . . ?
N6 C9 C6 110.9(7) . . ?
N3 C10 N6 112.9(7) . . ?
N3 C10 C17 121.9(7) . . ?
N6 C10 C17 125.2(7) . . ?
N6 C11 C12 131.6(9) . . ?
N6 C11 C16 106.1(8) . . ?
C12 C11 C16 122.3(9) . . ?
C13 C12 C11 116.1(10) . . ?
C12 C13 C14 122.8(11) . . ?
C15 C14 C13 119.9(10) . . ?
C14 C15 C16 117.9(9) . . ?
C15 C16 C11 120.9(8) . . ?
C15 C16 N3 130.5(8) . . ?
C11 C16 N3 108.5(7) . . ?
N1 C17 C10 107.6(6) . . ?
C19 C18 N1 109.0(6) . . ?
N4 C19 N7 113.1(6) . . ?
N4 C19 C18 123.4(6) . . ?
N7 C19 C18 123.5(6) . . ?
C25 C20 C21 119.3(7) . . ?
C25 C20 N4 130.9(7) . . ?
C21 C20 N4 109.7(6) . . ?
C22 C21 N7 131.6(7) . . ?
C22 C21 C20 122.9(7) . . ?
N7 C21 C20 105.5(6) . . ?
C23 C22 C21 116.3(7) . . ?
C24 C23 C22 121.8(7) . . ?
C23 C24 C25 121.7(7) . . ?
C20 C25 C24 118.0(7) . . ?
N7 C26 C27 114.2(8) . . ?
C32 C27 C28 117.5(14) . . ?
C32 C27 C26 125.0(11) . . ?
C28 C27 C26 117.4(12) . . ?
C27 C28 C29 121.1(18) . . ?
C30 C29 C28 122.0(19) . . ?
C29 C30 C31 118.3(17) . . ?
C29 C30 C33 116(2) . . ?
C31 C30 C33 125(2) . . ?
C32 C31 C30 116.7(19) . . ?
C27 C32 C31 123.6(16) . . ?
C34 C33 C30 127(2) . . ?
N1 C35 C36 109.8(5) . . ?
N5 C36 N2 113.3(6) . . ?
N5 C36 C35 125.1(6) . . ?
N2 C36 C35 121.5(6) . . ?
C38 C37 N2 130.2(6) . . ?
C38 C37 C42 120.1(7) . . ?
N2 C37 C42 109.7(6) . . ?
C37 C38 C39 117.2(7) . . ?
C40 C39 C38 121.7(7) . . ?
C39 C40 C41 121.8(7) . . ?
C42 C41 C40 115.9(7) . . ?
C41 C42 N5 131.3(7) . . ?
C41 C42 C37 123.3(7) . . ?
N5 C42 C37 105.4(6) . . ?
N5 C43 C44 113.2(7) . . ?
C49 C44 C45 114.9(12) . . ?
C49 C44 C43 121.8(10) . . ?
C45 C44 C43 123.3(9) . . ?
C44 C45 C46 122.3(15) . . ?
C47 C46 C45 120.3(18) . . ?
C46 C47 C48 118.1(15) . . ?
C46 C47 C50 120.3(19) . . ?
C48 C47 C50 121.4(18) . . ?
C47 C48 C49 122.5(16) . . ?
C44 C49 C48 121.6(15) . . ?
C51 C50 C47 127(2) . . ?
O1 C53 C52 113.3(16) . . ?
O2 C55 C54 108(2) . . ?

_diffrn_measured_fraction_theta_max 0.973
_diffrn_reflns_theta_full        26.29
_diffrn_measured_fraction_theta_full 0.973
_refine_diff_density_max         1.960
_refine_diff_density_min         -1.206
_refine_diff_density_rms         0.167
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: EtOH'
