# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_160717c
_database_code_depnum_ccdc_archive 'CCDC 1531083'
_audit_update_record             
;
2017-02-04 deposited with the CCDC.
2017-05-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H21 O2 P'
_chemical_formula_weight         420.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.9300(8)
_cell_length_b                   19.1231(16)
_cell_length_c                   11.1659(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 109.173(2)
_cell_angle_gamma                90.00
_cell_volume                     2204.4(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    1627
_cell_measurement_theta_min      2.242
_cell_measurement_theta_max      20.165

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.267
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             880
_exptl_absorpt_coefficient_mu    0.147
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9395
_exptl_absorpt_correction_T_max  0.9811
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            10998
_diffrn_reflns_av_R_equivalents  0.0712
_diffrn_reflns_av_sigmaI/netI    0.0951
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.24
_diffrn_reflns_theta_max         25.02
_reflns_number_total             3866
_reflns_number_gt                1917
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0359P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3866
_refine_ls_number_parameters     318
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1282
_refine_ls_R_factor_gt           0.0537
_refine_ls_wR_factor_ref         0.1204
_refine_ls_wR_factor_gt          0.1019
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.57862(8) 0.31285(4) 0.33072(8) 0.0427(3) Uani 1 1 d . . .
O1 O 0.8621(2) 0.12327(11) 0.6351(2) 0.0684(8) Uani 1 1 d . . .
O2 O 0.58326(18) 0.30991(10) 0.19982(18) 0.0521(6) Uani 1 1 d . . .
C1 C 0.7731(3) 0.14974(17) 0.5514(3) 0.0471(9) Uani 1 1 d . . .
C2 C 0.7575(3) 0.22721(15) 0.5221(3) 0.0382(8) Uani 1 1 d . A .
C3 C 0.6501(3) 0.23593(15) 0.4196(3) 0.0396(8) Uani 1 1 d . . .
C4 C 0.5908(3) 0.16575(15) 0.3762(3) 0.0407(8) Uani 1 1 d . . .
C5 C 0.6638(3) 0.11479(16) 0.4565(3) 0.0465(9) Uani 1 1 d . . .
C6 C 0.6308(3) 0.04531(18) 0.4400(4) 0.0630(10) Uani 1 1 d . . .
H6 H 0.6803 0.0117 0.4950 0.076 Uiso 1 1 calc R . .
C7 C 0.5222(3) 0.02635(18) 0.3400(4) 0.0672(11) Uani 1 1 d . . .
H7 H 0.4970 -0.0203 0.3280 0.081 Uiso 1 1 calc R . .
C8 C 0.4525(3) 0.07617(19) 0.2593(4) 0.0640(11) Uani 1 1 d . . .
H8 H 0.3811 0.0627 0.1911 0.077 Uiso 1 1 calc R . .
C9 C 0.4850(3) 0.14685(18) 0.2758(3) 0.0531(9) Uani 1 1 d . . .
H9 H 0.4360 0.1803 0.2200 0.064 Uiso 1 1 calc R . .
C10 C 0.8520(3) 0.27698(16) 0.6018(3) 0.0413(8) Uani 1 1 d . . .
C11 C 0.952(4) 0.3037(19) 0.565(4) 0.051(6) Uani 0.55(4) 1 d P A 1
H11 H 0.9577 0.2913 0.4865 0.061 Uiso 0.55(4) 1 calc PR A 1
C12 C 1.043(4) 0.348(2) 0.643(4) 0.058(6) Uani 0.55(4) 1 d P A 1
H12 H 1.1084 0.3667 0.6162 0.070 Uiso 0.55(4) 1 calc PR A 1
C13 C 1.0359(4) 0.36617(19) 0.7625(4) 0.0602(10) Uani 1 1 d . . .
C14 C 0.943(2) 0.3342(12) 0.803(2) 0.055(4) Uani 0.55(4) 1 d P A 1
H14 H 0.9414 0.3424 0.8843 0.066 Uiso 0.55(4) 1 calc PR A 1
C15 C 0.8534(17) 0.2903(13) 0.723(2) 0.052(4) Uani 0.55(4) 1 d P A 1
H15 H 0.7919 0.2690 0.7522 0.062 Uiso 0.55(4) 1 calc PR A 1
C11' C 0.969(5) 0.288(3) 0.586(5) 0.050(7) Uani 0.45(4) 1 d P A 2
H11' H 0.9890 0.2661 0.5210 0.060 Uiso 0.45(4) 1 calc PR A 2
C12' C 1.058(5) 0.333(2) 0.668(5) 0.054(7) Uani 0.45(4) 1 d P A 2
H12' H 1.1369 0.3403 0.6550 0.065 Uiso 0.45(4) 1 calc PR A 2
C14' C 0.912(3) 0.3600(17) 0.775(2) 0.063(5) Uani 0.45(4) 1 d P A 2
H14' H 0.8905 0.3859 0.8361 0.075 Uiso 0.45(4) 1 calc PR A 2
C15' C 0.824(3) 0.3160(15) 0.698(2) 0.056(5) Uani 0.45(4) 1 d P A 2
H15' H 0.7432 0.3112 0.7075 0.067 Uiso 0.45(4) 1 calc PR A 2
C16 C 1.1344(4) 0.41456(19) 0.8514(4) 0.0989(15) Uani 1 1 d . A .
H16A H 1.2185 0.3931 0.8760 0.148 Uiso 1 1 calc R . .
H16B H 1.1105 0.4232 0.9255 0.148 Uiso 1 1 calc R . .
H16C H 1.1367 0.4580 0.8091 0.148 Uiso 1 1 calc R . .
C17 C 0.6593(3) 0.38797(15) 0.4148(3) 0.0453(8) Uani 1 1 d . . .
C18 C 0.7574(3) 0.41763(17) 0.3805(3) 0.0573(10) Uani 1 1 d . . .
H18 H 0.7781 0.3988 0.3128 0.069 Uiso 1 1 calc R . .
C19 C 0.8254(3) 0.4743(2) 0.4436(4) 0.0723(12) Uani 1 1 d . . .
H19 H 0.8915 0.4933 0.4185 0.087 Uiso 1 1 calc R . .
C20 C 0.7969(4) 0.5027(2) 0.5421(4) 0.0775(13) Uani 1 1 d . . .
H20 H 0.8444 0.5404 0.5859 0.093 Uiso 1 1 calc R . .
C21 C 0.6988(4) 0.4759(2) 0.5768(4) 0.0937(14) Uani 1 1 d . . .
H21 H 0.6775 0.4960 0.6432 0.112 Uiso 1 1 calc R . .
C22 C 0.6307(4) 0.4190(2) 0.5139(4) 0.0778(12) Uani 1 1 d . . .
H22 H 0.5638 0.4009 0.5387 0.093 Uiso 1 1 calc R . .
C23 C 0.4168(3) 0.31333(15) 0.3369(3) 0.0425(8) Uani 1 1 d . . .
C24 C 0.3831(3) 0.28390(16) 0.4352(3) 0.0520(9) Uani 1 1 d . . .
H24 H 0.4463 0.2632 0.5030 0.062 Uiso 1 1 calc R . .
C25 C 0.2557(3) 0.28531(17) 0.4326(4) 0.0606(10) Uani 1 1 d . . .
H25 H 0.2337 0.2660 0.4992 0.073 Uiso 1 1 calc R . .
C26 C 0.1620(3) 0.31489(18) 0.3326(4) 0.0614(10) Uani 1 1 d . . .
H26 H 0.0764 0.3150 0.3311 0.074 Uiso 1 1 calc R . .
C27 C 0.1931(3) 0.34441(18) 0.2346(4) 0.0643(11) Uani 1 1 d . . .
H27 H 0.1290 0.3649 0.1672 0.077 Uiso 1 1 calc R . .
C28 C 0.3205(3) 0.34360(16) 0.2362(3) 0.0532(9) Uani 1 1 d . . .
H28 H 0.3416 0.3634 0.1695 0.064 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O2 1.480(2) . ?
P1 C17 1.783(3) . ?
P1 C23 1.793(3) . ?
P1 C3 1.803(3) . ?
O1 C1 1.216(3) . ?
C1 C5 1.472(4) . ?
C1 C2 1.515(4) . ?
C2 C3 1.354(4) . ?
C2 C10 1.470(4) . ?
C3 C4 1.500(4) . ?
C4 C9 1.369(4) . ?
C4 C5 1.385(4) . ?
C5 C6 1.373(4) . ?
C6 C7 1.384(4) . ?
C6 H6 0.9300 . ?
C7 C8 1.360(4) . ?
C7 H7 0.9300 . ?
C8 C9 1.394(4) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
C10 C11' 1.36(6) . ?
C10 C15 1.37(2) . ?
C10 C11 1.38(5) . ?
C10 C15' 1.42(3) . ?
C11 C12 1.38(6) . ?
C11 H11 0.9300 . ?
C12 C13 1.40(5) . ?
C12 H12 0.9300 . ?
C13 C12' 1.32(6) . ?
C13 C14 1.38(2) . ?
C13 C14' 1.42(3) . ?
C13 C16 1.517(4) . ?
C14 C15 1.37(2) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C11' C12' 1.39(8) . ?
C11' H11' 0.9300 . ?
C12' H12' 0.9300 . ?
C14' C15' 1.35(3) . ?
C14' H14' 0.9300 . ?
C15' H15' 0.9300 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C18 1.373(4) . ?
C17 C22 1.378(4) . ?
C18 C19 1.371(4) . ?
C18 H18 0.9300 . ?
C19 C20 1.351(5) . ?
C19 H19 0.9300 . ?
C20 C21 1.355(5) . ?
C20 H20 0.9300 . ?
C21 C22 1.374(5) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 C24 1.386(4) . ?
C23 C28 1.389(4) . ?
C24 C25 1.383(4) . ?
C24 H24 0.9300 . ?
C25 C26 1.365(4) . ?
C25 H25 0.9300 . ?
C26 C27 1.370(5) . ?
C26 H26 0.9300 . ?
C27 C28 1.386(4) . ?
C27 H27 0.9300 . ?
C28 H28 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 P1 C17 112.28(15) . . ?
O2 P1 C23 113.11(13) . . ?
C17 P1 C23 107.43(15) . . ?
O2 P1 C3 111.30(13) . . ?
C17 P1 C3 108.51(14) . . ?
C23 P1 C3 103.75(14) . . ?
O1 C1 C5 128.3(3) . . ?
O1 C1 C2 125.3(3) . . ?
C5 C1 C2 106.4(3) . . ?
C3 C2 C10 132.4(3) . . ?
C3 C2 C1 107.9(3) . . ?
C10 C2 C1 119.7(3) . . ?
C2 C3 C4 109.0(3) . . ?
C2 C3 P1 131.6(2) . . ?
C4 C3 P1 119.3(2) . . ?
C9 C4 C5 119.7(3) . . ?
C9 C4 C3 131.3(3) . . ?
C5 C4 C3 109.0(3) . . ?
C6 C5 C4 121.6(3) . . ?
C6 C5 C1 130.6(3) . . ?
C4 C5 C1 107.8(3) . . ?
C5 C6 C7 118.6(3) . . ?
C5 C6 H6 120.7 . . ?
C7 C6 H6 120.7 . . ?
C8 C7 C6 119.7(3) . . ?
C8 C7 H7 120.1 . . ?
C6 C7 H7 120.1 . . ?
C7 C8 C9 122.0(3) . . ?
C7 C8 H8 119.0 . . ?
C9 C8 H8 119.0 . . ?
C4 C9 C8 118.3(3) . . ?
C4 C9 H9 120.9 . . ?
C8 C9 H9 120.9 . . ?
C11' C10 C15 113(2) . . ?
C11' C10 C11 16(3) . . ?
C15 C10 C11 118(2) . . ?
C11' C10 C15' 117(3) . . ?
C15 C10 C15' 25.0(7) . . ?
C11 C10 C15' 115(2) . . ?
C11' C10 C2 122(2) . . ?
C15 C10 C2 119.7(9) . . ?
C11 C10 C2 122(2) . . ?
C15' C10 C2 121.0(11) . . ?
C12 C11 C10 121(4) . . ?
C12 C11 H11 119.5 . . ?
C10 C11 H11 119.5 . . ?
C11 C12 C13 120(4) . . ?
C11 C12 H12 120.1 . . ?
C13 C12 H12 120.1 . . ?
C12' C13 C14 113(2) . . ?
C12' C13 C12 16(2) . . ?
C14 C13 C12 119(2) . . ?
C12' C13 C14' 118(3) . . ?
C14 C13 C14' 25.7(7) . . ?
C12 C13 C14' 115(2) . . ?
C12' C13 C16 123(2) . . ?
C14 C13 C16 119.8(9) . . ?
C12 C13 C16 121.4(19) . . ?
C14' C13 C16 118.9(11) . . ?
C15 C14 C13 120.4(16) . . ?
C15 C14 H14 119.8 . . ?
C13 C14 H14 119.8 . . ?
C14 C15 C10 121.7(16) . . ?
C14 C15 H15 119.2 . . ?
C10 C15 H15 119.2 . . ?
C10 C11' C12' 120(5) . . ?
C10 C11' H11' 120.1 . . ?
C12' C11' H11' 120.1 . . ?
C13 C12' C11' 123(5) . . ?
C13 C12' H12' 118.4 . . ?
C11' C12' H12' 118.4 . . ?
C15' C14' C13 119(2) . . ?
C15' C14' H14' 120.4 . . ?
C13 C14' H14' 120.4 . . ?
C14' C15' C10 122(2) . . ?
C14' C15' H15' 119.1 . . ?
C10 C15' H15' 119.1 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C22 116.7(3) . . ?
C18 C17 P1 118.8(3) . . ?
C22 C17 P1 124.4(3) . . ?
C19 C18 C17 121.6(4) . . ?
C19 C18 H18 119.2 . . ?
C17 C18 H18 119.2 . . ?
C20 C19 C18 120.3(4) . . ?
C20 C19 H19 119.9 . . ?
C18 C19 H19 119.9 . . ?
C19 C20 C21 119.8(4) . . ?
C19 C20 H20 120.1 . . ?
C21 C20 H20 120.1 . . ?
C20 C21 C22 119.9(4) . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C21 C22 C17 121.6(4) . . ?
C21 C22 H22 119.2 . . ?
C17 C22 H22 119.2 . . ?
C24 C23 C28 118.9(3) . . ?
C24 C23 P1 123.4(2) . . ?
C28 C23 P1 117.7(3) . . ?
C25 C24 C23 120.2(3) . . ?
C25 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
C26 C25 C24 120.3(3) . . ?
C26 C25 H25 119.8 . . ?
C24 C25 H25 119.8 . . ?
C25 C26 C27 120.5(3) . . ?
C25 C26 H26 119.7 . . ?
C27 C26 H26 119.7 . . ?
C26 C27 C28 119.8(3) . . ?
C26 C27 H27 120.1 . . ?
C28 C27 H27 120.1 . . ?
C27 C28 C23 120.4(3) . . ?
C27 C28 H28 119.8 . . ?
C23 C28 H28 119.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 177.4(3) . . . . ?
C5 C1 C2 C3 -0.4(3) . . . . ?
O1 C1 C2 C10 -2.9(5) . . . . ?
C5 C1 C2 C10 179.4(3) . . . . ?
C10 C2 C3 C4 179.9(3) . . . . ?
C1 C2 C3 C4 -0.4(3) . . . . ?
C10 C2 C3 P1 3.1(6) . . . . ?
C1 C2 C3 P1 -177.2(2) . . . . ?
O2 P1 C3 C2 114.3(3) . . . . ?
C17 P1 C3 C2 -9.7(4) . . . . ?
C23 P1 C3 C2 -123.7(3) . . . . ?
O2 P1 C3 C4 -62.2(2) . . . . ?
C17 P1 C3 C4 173.8(2) . . . . ?
C23 P1 C3 C4 59.8(3) . . . . ?
C2 C3 C4 C9 -177.8(3) . . . . ?
P1 C3 C4 C9 -0.6(5) . . . . ?
C2 C3 C4 C5 1.1(3) . . . . ?
P1 C3 C4 C5 178.4(2) . . . . ?
C9 C4 C5 C6 -1.7(5) . . . . ?
C3 C4 C5 C6 179.2(3) . . . . ?
C9 C4 C5 C1 177.7(3) . . . . ?
C3 C4 C5 C1 -1.3(4) . . . . ?
O1 C1 C5 C6 2.8(6) . . . . ?
C2 C1 C5 C6 -179.5(3) . . . . ?
O1 C1 C5 C4 -176.6(3) . . . . ?
C2 C1 C5 C4 1.1(4) . . . . ?
C4 C5 C6 C7 0.4(5) . . . . ?
C1 C5 C6 C7 -178.9(3) . . . . ?
C5 C6 C7 C8 1.3(5) . . . . ?
C6 C7 C8 C9 -1.7(6) . . . . ?
C5 C4 C9 C8 1.3(5) . . . . ?
C3 C4 C9 C8 -179.9(3) . . . . ?
C7 C8 C9 C4 0.4(5) . . . . ?
C3 C2 C10 C11' -100(2) . . . . ?
C1 C2 C10 C11' 81(2) . . . . ?
C3 C2 C10 C15 108.4(12) . . . . ?
C1 C2 C10 C15 -71.3(12) . . . . ?
C3 C2 C10 C11 -80.8(16) . . . . ?
C1 C2 C10 C11 99.5(16) . . . . ?
C3 C2 C10 C15' 79.4(16) . . . . ?
C1 C2 C10 C15' -100.3(15) . . . . ?
C11' C10 C11 C12 -82(16) . . . . ?
C15 C10 C11 C12 -7(3) . . . . ?
C15' C10 C11 C12 21(3) . . . . ?
C2 C10 C11 C12 -178(2) . . . . ?
C10 C11 C12 C13 1(4) . . . . ?
C11 C12 C13 C12' 80(14) . . . . ?
C11 C12 C13 C14 5(3) . . . . ?
C11 C12 C13 C14' -24(3) . . . . ?
C11 C12 C13 C16 179.4(19) . . . . ?
C12' C13 C14 C15 -23(2) . . . . ?
C12 C13 C14 C15 -5.1(19) . . . . ?
C14' C13 C14 C15 85(4) . . . . ?
C16 C13 C14 C15 180.0(7) . . . . ?
C13 C14 C15 C10 -0.4(15) . . . . ?
C11' C10 C15 C14 23(2) . . . . ?
C11 C10 C15 C14 6.3(18) . . . . ?
C15' C10 C15 C14 -82(4) . . . . ?
C2 C10 C15 C14 177.4(8) . . . . ?
C15 C10 C11' C12' -23(4) . . . . ?
C11 C10 C11' C12' 89(16) . . . . ?
C15' C10 C11' C12' 4(4) . . . . ?
C2 C10 C11' C12' -177(2) . . . . ?
C14 C13 C12' C11' 23(4) . . . . ?
C12 C13 C12' C11' -89(15) . . . . ?
C14' C13 C12' C11' -5(4) . . . . ?
C16 C13 C12' C11' 180(2) . . . . ?
C10 C11' C12' C13 0(5) . . . . ?
C12' C13 C14' C15' 6(2) . . . . ?
C14 C13 C14' C15' -80(4) . . . . ?
C12 C13 C14' C15' 24(2) . . . . ?
C16 C13 C14' C15' -178.8(10) . . . . ?
C13 C14' C15' C10 -1(2) . . . . ?
C11' C10 C15' C14' -3(2) . . . . ?
C15 C10 C15' C14' 83(4) . . . . ?
C11 C10 C15' C14' -21(2) . . . . ?
C2 C10 C15' C14' 177.4(10) . . . . ?
O2 P1 C17 C18 -26.5(3) . . . . ?
C23 P1 C17 C18 -151.5(2) . . . . ?
C3 P1 C17 C18 97.0(3) . . . . ?
O2 P1 C17 C22 153.8(3) . . . . ?
C23 P1 C17 C22 28.8(3) . . . . ?
C3 P1 C17 C22 -82.7(3) . . . . ?
C22 C17 C18 C19 1.4(5) . . . . ?
P1 C17 C18 C19 -178.3(3) . . . . ?
C17 C18 C19 C20 -0.1(5) . . . . ?
C18 C19 C20 C21 -1.4(6) . . . . ?
C19 C20 C21 C22 1.6(7) . . . . ?
C20 C21 C22 C17 -0.2(7) . . . . ?
C18 C17 C22 C21 -1.3(5) . . . . ?
P1 C17 C22 C21 178.4(3) . . . . ?
O2 P1 C23 C24 148.4(3) . . . . ?
C17 P1 C23 C24 -87.1(3) . . . . ?
C3 P1 C23 C24 27.7(3) . . . . ?
O2 P1 C23 C28 -30.2(3) . . . . ?
C17 P1 C23 C28 94.3(3) . . . . ?
C3 P1 C23 C28 -150.9(2) . . . . ?
C28 C23 C24 C25 -0.4(5) . . . . ?
P1 C23 C24 C25 -179.0(2) . . . . ?
C23 C24 C25 C26 0.8(5) . . . . ?
C24 C25 C26 C27 -0.9(5) . . . . ?
C25 C26 C27 C28 0.7(5) . . . . ?
C26 C27 C28 C23 -0.3(5) . . . . ?
C24 C23 C28 C27 0.2(5) . . . . ?
P1 C23 C28 C27 178.8(2) . . . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        25.02
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         0.259
_refine_diff_density_min         -0.254
_refine_diff_density_rms         0.048
