# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_oz565_cjp1009
_database_code_depnum_ccdc_archive 'CCDC 1537396'
_audit_update_record             
;
2017-03-11 deposited with the CCDC.
2017-05-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        (PNP)Rh(ZnPh)(Ph)
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C38 H50 N P2 Rh Zn'
_chemical_formula_weight         751.01

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           9
_space_group_name_H-M_alt        'C c'
_space_group_name_Hall           'C -2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'

_cell_length_a                   11.751(2)
_cell_length_b                   37.418(7)
_cell_length_c                   17.055(4)
_cell_angle_alpha                90
_cell_angle_beta                 109.766(2)
_cell_angle_gamma                90
_cell_volume                     7057(2)
_cell_formula_units_Z            8
_cell_measurement_temperature    110(2)
_cell_measurement_reflns_used    9713
_cell_measurement_theta_min      4.921
_cell_measurement_theta_max      55.422

_exptl_crystal_description       block
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.414
_exptl_crystal_F_000             3120
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.110
_exptl_absorpt_coefficient_mu    1.265
_shelx_estimated_absorpt_T_min   0.751
_shelx_estimated_absorpt_T_max   0.873
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6341
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      110(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            41364
_diffrn_reflns_av_unetI/netI     0.0363
_diffrn_reflns_av_R_equivalents  0.0222
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -48
_diffrn_reflns_limit_k_max       48
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         2.177
_diffrn_reflns_theta_max         27.708
_diffrn_reflns_theta_full        26.000
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             16168
_reflns_number_gt                15930
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.993
_reflns_Friedel_fraction_max     0.986
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          'Refined as a 2-component twin., Twin'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0217P)²+5.0036P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 7591 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.036(3)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         16168
_refine_ls_number_parameters     796
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0231
_refine_ls_R_factor_gt           0.0225
_refine_ls_wR_factor_ref         0.0542
_refine_ls_wR_factor_gt          0.0536
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_restrained_S_all      1.006
_refine_ls_shift/su_max          0.043
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.54989(2) 0.43071(2) 0.36402(2) 0.01323(6) Uani 1 1 d . . . . .
P1 P 0.62183(9) 0.47644(3) 0.45538(6) 0.0148(2) Uani 1 1 d . . . . .
C1' C 0.1915(4) 0.36448(10) 0.5782(3) 0.0178(8) Uani 1 1 d . . . . .
N1' N 0.2532(3) 0.27512(9) 0.7340(2) 0.0173(7) Uani 1 1 d . . . . .
P1' P 0.19050(9) 0.27795(3) 0.55508(6) 0.0147(2) Uani 1 1 d . . . . .
Zn1' Zn 0.42016(4) 0.30313(2) 0.71173(3) 0.02221(11) Uani 1 1 d . . . . .
Rh1' Rh 0.21751(2) 0.32113(2) 0.65330(2) 0.01349(6) Uani 1 1 d . . . . .
Zn1 Zn 0.70166(4) 0.44272(2) 0.30907(3) 0.02134(11) Uani 1 1 d . . . . .
N1 N 0.4892(3) 0.47482(9) 0.2811(2) 0.0175(7) Uani 1 1 d . . . . .
C1 C 0.6130(4) 0.38903(11) 0.4449(3) 0.0190(8) Uani 1 1 d . . . . .
C2 C 0.7062(4) 0.36597(11) 0.4450(3) 0.0246(9) Uani 1 1 d . . . . .
H2 H 0.7441 0.3691 0.4044 0.029 Uiso 1 1 calc R U . . .
P2' P 0.22488(9) 0.35108(3) 0.77180(6) 0.0165(2) Uani 1 1 d . . . . .
P2 P 0.43754(9) 0.39795(3) 0.25166(6) 0.01504(19) Uani 1 1 d . . . . .
C2' C 0.0787(4) 0.37031(11) 0.5162(3) 0.0212(8) Uani 1 1 d . . . . .
H2' H 0.0167 0.3531 0.5091 0.025 Uiso 1 1 calc R U . . .
C3 C 0.7456(4) 0.33830(13) 0.5032(3) 0.0337(11) Uani 1 1 d . . . . .
H3 H 0.8093 0.3231 0.5013 0.040 Uiso 1 1 calc R U . . .
C3' C 0.0540(5) 0.40059(12) 0.4645(3) 0.0277(10) Uani 1 1 d . . . . .
H3' H -0.0235 0.4036 0.4234 0.033 Uiso 1 1 calc R U . . .
C4 C 0.6930(5) 0.33284(13) 0.5633(3) 0.0361(12) Uani 1 1 d . . . . .
H4 H 0.7198 0.3141 0.6028 0.043 Uiso 1 1 calc R U . . .
C4' C 0.1425(5) 0.42592(12) 0.4737(3) 0.0303(11) Uani 1 1 d . . . . .
H4' H 0.1267 0.4465 0.4390 0.036 Uiso 1 1 calc R U . . .
C5 C 0.6001(5) 0.35533(13) 0.5649(3) 0.0317(11) Uani 1 1 d . . . . .
H5 H 0.5628 0.3520 0.6058 0.038 Uiso 1 1 calc R U . . .
C5' C 0.2538(5) 0.42104(12) 0.5334(3) 0.0300(10) Uani 1 1 d . . . . .
H5' H 0.3152 0.4384 0.5396 0.036 Uiso 1 1 calc R U . . .
C6' C 0.2786(4) 0.39129(11) 0.5849(3) 0.0234(9) Uani 1 1 d . . . . .
H6' H 0.3565 0.3889 0.6260 0.028 Uiso 1 1 calc R U . . .
C6 C 0.5610(4) 0.38281(12) 0.5066(3) 0.0253(9) Uani 1 1 d . . . . .
H6 H 0.4970 0.3978 0.5088 0.030 Uiso 1 1 calc R U . . .
C7' C 0.5891(4) 0.28821(11) 0.7467(3) 0.0214(9) Uani 1 1 d . . . . .
C7 C 0.8315(4) 0.45617(12) 0.2679(3) 0.0229(9) Uani 1 1 d . . . . .
C8 C 0.8625(5) 0.43653(13) 0.2086(4) 0.0369(12) Uani 1 1 d . . . . .
H8 H 0.8164 0.4160 0.1845 0.044 Uiso 1 1 calc R U . . .
C8' C 0.6220(4) 0.25657(13) 0.7178(3) 0.0274(10) Uani 1 1 d . . . . .
H8' H 0.5608 0.2411 0.6842 0.033 Uiso 1 1 calc R U . . .
C9 C 0.9591(5) 0.44627(14) 0.1841(4) 0.0393(13) Uani 1 1 d . . . . .
H9 H 0.9766 0.4327 0.1425 0.047 Uiso 1 1 calc R U . . .
C9' C 0.7434(5) 0.24704(14) 0.7372(3) 0.0348(12) Uani 1 1 d . . . . .
H9' H 0.7631 0.2254 0.7156 0.042 Uiso 1 1 calc R U . . .
C10 C 1.0296(4) 0.47511(13) 0.2187(3) 0.0321(11) Uani 1 1 d . . . . .
H10 H 1.0969 0.4813 0.2027 0.038 Uiso 1 1 calc R U . . .
C21 C 0.2679(4) 0.42703(11) 0.1058(3) 0.0199(8) Uani 1 1 d . . . . .
H21 H 0.2534 0.4032 0.0859 0.024 Uiso 1 1 calc R U . . .
C21' C 0.1735(4) 0.31726(12) 0.9052(3) 0.0237(9) Uani 1 1 d . . . . .
H21' H 0.1682 0.3407 0.9252 0.028 Uiso 1 1 calc R U . . .
C11 C 1.0010(5) 0.49479(14) 0.2770(3) 0.0369(12) Uani 1 1 d . . . . .
H11 H 1.0491 0.5149 0.3017 0.044 Uiso 1 1 calc R U . . .
C12 C 0.9032(5) 0.48583(13) 0.3005(3) 0.0308(11) Uani 1 1 d . . . . .
H12 H 0.8843 0.5003 0.3402 0.037 Uiso 1 1 calc R U . . .
C12' C 0.6832(5) 0.30907(14) 0.7977(4) 0.0374(12) Uani 1 1 d . . . . .
H12' H 0.6646 0.3308 0.8196 0.045 Uiso 1 1 calc R U . . .
C13 C 0.5493(4) 0.50739(10) 0.3008(3) 0.0176(8) Uani 1 1 d . . . . .
C13' C 0.2805(3) 0.24229(10) 0.7045(2) 0.0152(7) Uani 1 1 d . . . . .
C14 C 0.6270(4) 0.51235(10) 0.3848(3) 0.0180(8) Uani 1 1 d . . . . .
C14' C 0.2611(3) 0.23933(10) 0.6182(2) 0.0155(7) Uani 1 1 d . . . . .
C16 C 0.7049(4) 0.56822(11) 0.3494(3) 0.0265(10) Uani 1 1 d . . . . .
C15 C 0.7022(4) 0.54230(11) 0.4074(3) 0.0220(9) Uani 1 1 d . . . . .
H15 H 0.7528 0.5450 0.4638 0.026 Uiso 1 1 calc R U . . .
C15' C 0.2943(4) 0.20843(10) 0.5854(3) 0.0183(8) Uani 1 1 d . . . . .
H15' H 0.2796 0.2071 0.5272 0.022 Uiso 1 1 calc R U . . .
C17 C 0.6273(4) 0.56388(11) 0.2692(3) 0.0261(10) Uani 1 1 d . . . . .
H17 H 0.6260 0.5816 0.2291 0.031 Uiso 1 1 calc R U . . .
C18 C 0.5509(4) 0.53474(11) 0.2442(3) 0.0238(9) Uani 1 1 d . . . . .
H18 H 0.4987 0.5331 0.1880 0.029 Uiso 1 1 calc R U . . .
C18' C 0.3391(4) 0.21294(11) 0.7553(3) 0.0186(8) Uani 1 1 d . . . . .
H18' H 0.3569 0.2141 0.8138 0.022 Uiso 1 1 calc R U . . .
C19 C 0.3904(4) 0.46926(10) 0.2091(2) 0.0166(8) Uani 1 1 d . . . . .
C19' C 0.2195(3) 0.27850(10) 0.8048(2) 0.0159(8) Uani 1 1 d . . . . .
C10' C 0.8335(4) 0.26798(14) 0.7862(3) 0.0323(11) Uani 1 1 d . . . . .
H10' H 0.9157 0.2613 0.7987 0.039 Uiso 1 1 calc R U . . .
C38 C 0.2676(4) 0.40027(13) 0.3301(3) 0.0288(10) Uani 1 1 d . . . . .
H38A H 0.2252 0.4198 0.2936 0.043 Uiso 1 1 calc R U . . .
H38B H 0.3341 0.4101 0.3770 0.043 Uiso 1 1 calc R U . . .
H38C H 0.2111 0.3876 0.3514 0.043 Uiso 1 1 calc R U . . .
C38' C -0.0232(4) 0.35928(14) 0.7083(3) 0.0332(11) Uani 1 1 d . . . . .
H38D H -0.0944 0.3740 0.7029 0.050 Uiso 1 1 calc R U . . .
H38E H -0.0300 0.3365 0.7346 0.050 Uiso 1 1 calc R U . . .
H38F H -0.0183 0.3548 0.6529 0.050 Uiso 1 1 calc R U . . .
C37 C 0.2173(4) 0.35729(12) 0.2107(3) 0.0300(10) Uani 1 1 d . . . . .
H37A H 0.1689 0.3759 0.1740 0.045 Uiso 1 1 calc R U . . .
H37B H 0.1656 0.3432 0.2336 0.045 Uiso 1 1 calc R U . . .
H37C H 0.2523 0.3416 0.1788 0.045 Uiso 1 1 calc R U . . .
C37' C 0.1008(5) 0.41568(13) 0.7253(3) 0.0390(12) Uani 1 1 d . . . . .
H37D H 0.1198 0.4127 0.6740 0.059 Uiso 1 1 calc R U . . .
H37E H 0.1652 0.4294 0.7658 0.059 Uiso 1 1 calc R U . . .
H37F H 0.0238 0.4284 0.7128 0.059 Uiso 1 1 calc R U . . .
C36 C 0.3180(4) 0.37450(11) 0.2813(3) 0.0216(9) Uani 1 1 d . . . . .
H36 H 0.3590 0.3549 0.3205 0.026 Uiso 1 1 calc R U . . .
C36' C 0.0906(4) 0.37884(12) 0.7619(3) 0.0269(10) Uani 1 1 d . . . . .
H36' H 0.0855 0.3823 0.8187 0.032 Uiso 1 1 calc R U . . .
C35 C 0.5231(5) 0.32962(11) 0.2337(3) 0.0300(10) Uani 1 1 d . . . . .
H35A H 0.4531 0.3184 0.2426 0.045 Uiso 1 1 calc R U . . .
H35B H 0.5860 0.3340 0.2877 0.045 Uiso 1 1 calc R U . . .
H35C H 0.5548 0.3137 0.2003 0.045 Uiso 1 1 calc R U . . .
C35' C 0.4726(5) 0.36295(14) 0.8485(3) 0.0359(11) Uani 1 1 d . . . . .
H35D H 0.4865 0.3616 0.7951 0.054 Uiso 1 1 calc R U . . .
H35E H 0.4740 0.3388 0.8711 0.054 Uiso 1 1 calc R U . . .
H35F H 0.5362 0.3774 0.8877 0.054 Uiso 1 1 calc R U . . .
C34 C 0.5856(5) 0.38031(13) 0.1607(3) 0.0310(10) Uani 1 1 d . . . . .
H34A H 0.6031 0.3637 0.1218 0.047 Uiso 1 1 calc R U . . .
H34B H 0.6584 0.3836 0.2096 0.047 Uiso 1 1 calc R U . . .
H34C H 0.5604 0.4034 0.1332 0.047 Uiso 1 1 calc R U . . .
C34' C 0.3438(5) 0.39146(15) 0.9197(3) 0.0420(13) Uani 1 1 d . . . . .
H34D H 0.2631 0.4012 0.9114 0.063 Uiso 1 1 calc R U . . .
H34E H 0.4048 0.4099 0.9442 0.063 Uiso 1 1 calc R U . . .
H34F H 0.3584 0.3708 0.9571 0.063 Uiso 1 1 calc R U . . .
C33 C 0.4847(4) 0.36517(11) 0.1878(3) 0.0214(9) Uani 1 1 d . . . . .
H33 H 0.4137 0.3604 0.1365 0.026 Uiso 1 1 calc R U . . .
C33' C 0.3516(4) 0.37980(12) 0.8357(3) 0.0262(10) Uani 1 1 d . . . . .
H33' H 0.3486 0.4021 0.8028 0.031 Uiso 1 1 calc R U . . .
C32 C 0.7587(4) 0.45314(13) 0.6130(3) 0.0278(10) Uani 1 1 d . . . . .
H32A H 0.6932 0.4613 0.6321 0.042 Uiso 1 1 calc R U . . .
H32B H 0.8356 0.4540 0.6595 0.042 Uiso 1 1 calc R U . . .
H32C H 0.7427 0.4285 0.5925 0.042 Uiso 1 1 calc R U . . .
C32' C 0.1742(5) 0.30508(13) 0.4001(3) 0.0300(10) Uani 1 1 d . . . . .
H32D H 0.2083 0.3062 0.3550 0.045 Uiso 1 1 calc R U . . .
H32E H 0.1784 0.3288 0.4254 0.045 Uiso 1 1 calc R U . . .
H32F H 0.0897 0.2974 0.3774 0.045 Uiso 1 1 calc R U . . .
C31 C 0.8706(4) 0.46610(13) 0.5148(3) 0.0263(10) Uani 1 1 d . . . . .
H31A H 0.8557 0.4419 0.4914 0.039 Uiso 1 1 calc R U . . .
H31B H 0.9457 0.4663 0.5628 0.039 Uiso 1 1 calc R U . . .
H31C H 0.8778 0.4827 0.4723 0.039 Uiso 1 1 calc R U . . .
C31' C 0.3799(4) 0.28791(14) 0.4957(3) 0.0329(11) Uani 1 1 d . . . . .
H31D H 0.4109 0.2852 0.4494 0.049 Uiso 1 1 calc R U . . .
H31E H 0.4246 0.2721 0.5415 0.049 Uiso 1 1 calc R U . . .
H31F H 0.3903 0.3128 0.5150 0.049 Uiso 1 1 calc R U . . .
C30 C 0.7659(4) 0.47747(11) 0.5425(3) 0.0199(8) Uani 1 1 d . . . . .
H30 H 0.7809 0.5025 0.5641 0.024 Uiso 1 1 calc R U . . .
C30' C 0.2468(4) 0.27828(11) 0.4664(2) 0.0195(8) Uani 1 1 d . . . . .
H30' H 0.2363 0.2539 0.4411 0.023 Uiso 1 1 calc R U . . .
C17' C 0.3703(4) 0.18285(10) 0.7205(3) 0.0219(9) Uani 1 1 d . . . . .
H17' H 0.4083 0.1636 0.7560 0.026 Uiso 1 1 calc R U . . .
C26' C 0.1031(6) 0.29384(15) 1.0201(3) 0.0415(13) Uani 1 1 d . . . . .
H26A H 0.1324 0.3169 1.0464 0.062 Uiso 1 1 calc R U . . .
H26B H 0.1347 0.2746 1.0606 0.062 Uiso 1 1 calc R U . . .
H26C H 0.0145 0.2935 1.0008 0.062 Uiso 1 1 calc R U . . .
C16' C 0.3482(4) 0.17966(10) 0.6357(3) 0.0202(8) Uani 1 1 d . . . . .
C20 C 0.3608(4) 0.43339(10) 0.1809(2) 0.0167(8) Uani 1 1 d . . . . .
C20' C 0.2089(4) 0.31325(11) 0.8348(2) 0.0164(8) Uani 1 1 d . . . . .
C22 C 0.1957(4) 0.45406(12) 0.0587(3) 0.0234(9) Uani 1 1 d . . . . .
C22' C 0.1458(4) 0.28846(13) 0.9467(3) 0.0258(9) Uani 1 1 d . . . . .
C23 C 0.2196(4) 0.48855(12) 0.0902(3) 0.0252(9) Uani 1 1 d . . . . .
H23 H 0.1694 0.5076 0.0609 0.030 Uiso 1 1 calc R U . . .
C23' C 0.1523(4) 0.25465(12) 0.9147(3) 0.0235(9) Uani 1 1 d . . . . .
H23' H 0.1318 0.2344 0.9409 0.028 Uiso 1 1 calc R U . . .
C25 C 0.7929(5) 0.59930(13) 0.3742(4) 0.0400(13) Uani 1 1 d . . . . .
H25A H 0.8754 0.5906 0.3848 0.060 Uiso 1 1 calc R U . . .
H25B H 0.7877 0.6105 0.4249 0.060 Uiso 1 1 calc R U . . .
H25C H 0.7725 0.6169 0.3291 0.060 Uiso 1 1 calc R U . . .
C25' C 0.3809(4) 0.14626(11) 0.5975(3) 0.0280(10) Uani 1 1 d . . . . .
H25D H 0.3100 0.1307 0.5773 0.042 Uiso 1 1 calc R U . . .
H25E H 0.4464 0.1336 0.6398 0.042 Uiso 1 1 calc R U . . .
H25F H 0.4075 0.1530 0.5509 0.042 Uiso 1 1 calc R U . . .
C24 C 0.3135(4) 0.49608(11) 0.1625(3) 0.0209(8) Uani 1 1 d . . . . .
H24 H 0.3267 0.5201 0.1813 0.025 Uiso 1 1 calc R U . . .
C24' C 0.1876(4) 0.24944(11) 0.8460(2) 0.0195(8) Uani 1 1 d . . . . .
H24' H 0.1906 0.2259 0.8262 0.023 Uiso 1 1 calc R U . . .
C11' C 0.8039(5) 0.29902(15) 0.8175(4) 0.0400(13) Uani 1 1 d . . . . .
H11' H 0.8661 0.3138 0.8528 0.048 Uiso 1 1 calc R U . . .
C26 C 0.0936(5) 0.44633(14) -0.0222(3) 0.0367(12) Uani 1 1 d . . . . .
H26D H 0.1147 0.4557 -0.0691 0.055 Uiso 1 1 calc R U . . .
H26E H 0.0193 0.4578 -0.0210 0.055 Uiso 1 1 calc R U . . .
H26F H 0.0810 0.4205 -0.0286 0.055 Uiso 1 1 calc R U . . .
C27 C 0.5070(4) 0.49199(11) 0.5012(3) 0.0196(8) Uani 1 1 d . . . . .
H27 H 0.4965 0.4725 0.5384 0.023 Uiso 1 1 calc R U . . .
C27' C 0.0285(4) 0.26489(11) 0.5113(2) 0.0183(8) Uani 1 1 d . . . . .
H27' H -0.0151 0.2843 0.4724 0.022 Uiso 1 1 calc R U . . .
C28 C 0.3845(4) 0.49793(12) 0.4332(3) 0.0249(9) Uani 1 1 d . . . . .
H28A H 0.3908 0.5177 0.3972 0.037 Uiso 1 1 calc R U . . .
H28B H 0.3238 0.5038 0.4589 0.037 Uiso 1 1 calc R U . . .
H28C H 0.3603 0.4761 0.3998 0.037 Uiso 1 1 calc R U . . .
C28' C -0.0259(4) 0.26268(13) 0.5812(3) 0.0263(10) Uani 1 1 d . . . . .
H28D H -0.1137 0.2597 0.5569 0.039 Uiso 1 1 calc R U . . .
H28E H -0.0077 0.2847 0.6142 0.039 Uiso 1 1 calc R U . . .
H28F H 0.0091 0.2422 0.6172 0.039 Uiso 1 1 calc R U . . .
C29 C 0.5460(4) 0.52578(12) 0.5544(3) 0.0251(9) Uani 1 1 d . . . . .
H29A H 0.5627 0.5449 0.5207 0.038 Uiso 1 1 calc R U . . .
H29B H 0.6191 0.5207 0.6020 0.038 Uiso 1 1 calc R U . . .
H29C H 0.4810 0.5333 0.5747 0.038 Uiso 1 1 calc R U . . .
C29' C 0.0075(4) 0.22990(12) 0.4614(3) 0.0279(10) Uani 1 1 d . . . . .
H29D H -0.0792 0.2244 0.4404 0.042 Uiso 1 1 calc R U . . .
H29E H 0.0512 0.2104 0.4976 0.042 Uiso 1 1 calc R U . . .
H29F H 0.0370 0.2325 0.4145 0.042 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 2.048(4) . ?
Rh1 N1 2.133(3) . ?
Rh1 P1 2.2760(11) . ?
Rh1 P2 2.2819(11) . ?
Rh1 Zn1 2.3217(6) . ?
P1 C14 1.819(4) . ?
P1 C30 1.837(4) . ?
P1 C27 1.866(4) . ?
C1' C2' 1.405(6) . ?
C1' C6' 1.409(6) . ?
C1' Rh1' 2.025(4) . ?
N1' C19' 1.397(5) . ?
N1' C13' 1.405(5) . ?
N1' Rh1' 2.155(3) . ?
P1' C14' 1.825(4) . ?
P1' C30' 1.844(4) . ?
P1' C27' 1.860(4) . ?
P1' Rh1' 2.2710(11) . ?
Zn1' C7' 1.951(4) . ?
Zn1' Rh1' 2.3478(7) . ?
Rh1' P2' 2.2869(11) . ?
Zn1 C7 1.949(4) . ?
N1 C19 1.390(5) . ?
N1 C13 1.392(5) . ?
C1 C2 1.394(6) . ?
C1 C6 1.403(7) . ?
C2 C3 1.400(6) . ?
C2 H2 0.9500 . ?
P2' C20' 1.825(4) . ?
P2' C36' 1.848(5) . ?
P2' C33' 1.861(4) . ?
P2 C20 1.814(4) . ?
P2 C33 1.845(4) . ?
P2 C36 1.865(4) . ?
C2' C3' 1.405(6) . ?
C2' H2' 0.9500 . ?
C3 C4 1.380(8) . ?
C3 H3 0.9500 . ?
C3' C4' 1.376(7) . ?
C3' H3' 0.9500 . ?
C4 C5 1.385(8) . ?
C4 H4 0.9500 . ?
C4' C5' 1.371(7) . ?
C4' H4' 0.9500 . ?
C5 C6 1.395(6) . ?
C5 H5 0.9500 . ?
C5' C6' 1.387(6) . ?
C5' H5' 0.9500 . ?
C6' H6' 0.9500 . ?
C6 H6 0.9500 . ?
C7' C8' 1.387(6) . ?
C7' C12' 1.391(6) . ?
C7 C12 1.391(7) . ?
C7 C8 1.395(7) . ?
C8 C9 1.384(7) . ?
C8 H8 0.9500 . ?
C8' C9' 1.397(7) . ?
C8' H8' 0.9500 . ?
C9 C10 1.367(7) . ?
C9 H9 0.9500 . ?
C9' C10' 1.355(7) . ?
C9' H9' 0.9500 . ?
C10 C11 1.367(8) . ?
C10 H10 0.9500 . ?
C21 C22 1.388(6) . ?
C21 C20 1.395(6) . ?
C21 H21 0.9500 . ?
C21' C22' 1.387(6) . ?
C21' C20' 1.406(6) . ?
C21' H21' 0.9500 . ?
C11 C12 1.380(7) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C12' C11' 1.395(7) . ?
C12' H12' 0.9500 . ?
C13 C18 1.411(6) . ?
C13 C14 1.426(6) . ?
C13' C14' 1.415(5) . ?
C13' C18' 1.423(5) . ?
C14 C15 1.398(6) . ?
C14' C15' 1.397(5) . ?
C16 C17 1.374(7) . ?
C16 C15 1.393(6) . ?
C16 C25 1.518(6) . ?
C15 H15 0.9500 . ?
C15' C16' 1.389(6) . ?
C15' H15' 0.9500 . ?
C17 C18 1.385(6) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C18' C17' 1.379(6) . ?
C18' H18' 0.9500 . ?
C19 C24 1.404(6) . ?
C19 C20 1.428(5) . ?
C19' C24' 1.413(6) . ?
C19' C20' 1.419(5) . ?
C10' C11' 1.370(7) . ?
C10' H10' 0.9500 . ?
C38 C36 1.519(6) . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C38' C36' 1.528(7) . ?
C38' H38D 0.9800 . ?
C38' H38E 0.9800 . ?
C38' H38F 0.9800 . ?
C37 C36 1.517(6) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C37' C36' 1.534(7) . ?
C37' H37D 0.9800 . ?
C37' H37E 0.9800 . ?
C37' H37F 0.9800 . ?
C36 H36 1.0000 . ?
C36' H36' 1.0000 . ?
C35 C33 1.532(6) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C35' C33' 1.502(7) . ?
C35' H35D 0.9800 . ?
C35' H35E 0.9800 . ?
C35' H35F 0.9800 . ?
C34 C33 1.520(6) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C34' C33' 1.529(7) . ?
C34' H34D 0.9800 . ?
C34' H34E 0.9800 . ?
C34' H34F 0.9800 . ?
C33 H33 1.0000 . ?
C33' H33' 1.0000 . ?
C32 C30 1.533(6) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C32' C30' 1.537(6) . ?
C32' H32D 0.9800 . ?
C32' H32E 0.9800 . ?
C32' H32F 0.9800 . ?
C31 C30 1.520(6) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C31' C30' 1.516(6) . ?
C31' H31D 0.9800 . ?
C31' H31E 0.9800 . ?
C31' H31F 0.9800 . ?
C30 H30 1.0000 . ?
C30' H30' 1.0000 . ?
C17' C16' 1.385(6) . ?
C17' H17' 0.9500 . ?
C26' C22' 1.511(6) . ?
C26' H26A 0.9800 . ?
C26' H26B 0.9800 . ?
C26' H26C 0.9800 . ?
C16' C25' 1.517(6) . ?
C22 C23 1.390(6) . ?
C22 C26 1.519(6) . ?
C22' C23' 1.390(6) . ?
C23 C24 1.377(6) . ?
C23 H23 0.9500 . ?
C23' C24' 1.383(6) . ?
C23' H23' 0.9500 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C25' H25D 0.9800 . ?
C25' H25E 0.9800 . ?
C25' H25F 0.9800 . ?
C24 H24 0.9500 . ?
C24' H24' 0.9500 . ?
C11' H11' 0.9500 . ?
C26 H26D 0.9800 . ?
C26 H26E 0.9800 . ?
C26 H26F 0.9800 . ?
C27 C28 1.528(6) . ?
C27 C29 1.534(6) . ?
C27 H27 1.0000 . ?
C27' C28' 1.534(6) . ?
C27' C29' 1.535(6) . ?
C27' H27' 1.0000 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C28' H28D 0.9800 . ?
C28' H28E 0.9800 . ?
C28' H28F 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C29' H29D 0.9800 . ?
C29' H29E 0.9800 . ?
C29' H29F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 N1 178.36(16) . . ?
C1 Rh1 P1 98.35(12) . . ?
N1 Rh1 P1 80.55(9) . . ?
C1 Rh1 P2 97.56(12) . . ?
N1 Rh1 P2 83.68(10) . . ?
P1 Rh1 P2 162.62(4) . . ?
C1 Rh1 Zn1 105.49(13) . . ?
N1 Rh1 Zn1 73.32(10) . . ?
P1 Rh1 Zn1 88.44(3) . . ?
P2 Rh1 Zn1 94.03(3) . . ?
C14 P1 C30 107.0(2) . . ?
C14 P1 C27 103.75(19) . . ?
C30 P1 C27 104.72(19) . . ?
C14 P1 Rh1 100.94(14) . . ?
C30 P1 Rh1 126.65(14) . . ?
C27 P1 Rh1 111.54(14) . . ?
C2' C1' C6' 115.2(4) . . ?
C2' C1' Rh1' 120.1(3) . . ?
C6' C1' Rh1' 124.6(3) . . ?
C19' N1' C13' 123.6(3) . . ?
C19' N1' Rh1' 115.4(3) . . ?
C13' N1' Rh1' 119.2(3) . . ?
C14' P1' C30' 105.77(19) . . ?
C14' P1' C27' 103.17(18) . . ?
C30' P1' C27' 105.93(19) . . ?
C14' P1' Rh1' 101.87(13) . . ?
C30' P1' Rh1' 126.93(14) . . ?
C27' P1' Rh1' 110.61(13) . . ?
C7' Zn1' Rh1' 173.15(13) . . ?
C1' Rh1' N1' 177.57(16) . . ?
C1' Rh1' P1' 98.60(12) . . ?
N1' Rh1' P1' 81.45(9) . . ?
C1' Rh1' P2' 96.84(12) . . ?
N1' Rh1' P2' 83.45(10) . . ?
P1' Rh1' P2' 162.67(4) . . ?
C1' Rh1' Zn1' 114.37(12) . . ?
N1' Rh1' Zn1' 63.21(10) . . ?
P1' Rh1' Zn1' 88.72(3) . . ?
P2' Rh1' Zn1' 92.04(3) . . ?
C7 Zn1 Rh1 175.62(14) . . ?
C19 N1 C13 123.3(3) . . ?
C19 N1 Rh1 117.5(3) . . ?
C13 N1 Rh1 119.2(3) . . ?
C2 C1 C6 116.0(4) . . ?
C2 C1 Rh1 125.2(3) . . ?
C6 C1 Rh1 118.8(3) . . ?
C1 C2 C3 121.9(5) . . ?
C1 C2 H2 119.0 . . ?
C3 C2 H2 119.0 . . ?
C20' P2' C36' 103.6(2) . . ?
C20' P2' C33' 108.9(2) . . ?
C36' P2' C33' 102.6(2) . . ?
C20' P2' Rh1' 99.18(13) . . ?
C36' P2' Rh1' 114.75(15) . . ?
C33' P2' Rh1' 125.74(16) . . ?
C20 P2 C33 105.94(19) . . ?
C20 P2 C36 105.88(19) . . ?
C33 P2 C36 104.6(2) . . ?
C20 P2 Rh1 100.47(13) . . ?
C33 P2 Rh1 130.44(15) . . ?
C36 P2 Rh1 107.46(14) . . ?
C3' C2' C1' 122.7(4) . . ?
C3' C2' H2' 118.7 . . ?
C1' C2' H2' 118.7 . . ?
C4 C3 C2 120.8(5) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
C4' C3' C2' 119.8(4) . . ?
C4' C3' H3' 120.1 . . ?
C2' C3' H3' 120.1 . . ?
C3 C4 C5 118.6(4) . . ?
C3 C4 H4 120.7 . . ?
C5 C4 H4 120.7 . . ?
C5' C4' C3' 119.1(4) . . ?
C5' C4' H4' 120.4 . . ?
C3' C4' H4' 120.4 . . ?
C4 C5 C6 120.4(5) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C4' C5' C6' 121.4(5) . . ?
C4' C5' H5' 119.3 . . ?
C6' C5' H5' 119.3 . . ?
C5' C6' C1' 121.9(4) . . ?
C5' C6' H6' 119.1 . . ?
C1' C6' H6' 119.1 . . ?
C5 C6 C1 122.3(5) . . ?
C5 C6 H6 118.9 . . ?
C1 C6 H6 118.9 . . ?
C8' C7' C12' 116.3(4) . . ?
C8' C7' Zn1' 120.8(3) . . ?
C12' C7' Zn1' 122.8(3) . . ?
C12 C7 C8 116.0(4) . . ?
C12 C7 Zn1 120.3(3) . . ?
C8 C7 Zn1 123.6(4) . . ?
C9 C8 C7 121.5(5) . . ?
C9 C8 H8 119.2 . . ?
C7 C8 H8 119.2 . . ?
C7' C8' C9' 121.3(4) . . ?
C7' C8' H8' 119.4 . . ?
C9' C8' H8' 119.4 . . ?
C10 C9 C8 121.0(5) . . ?
C10 C9 H9 119.5 . . ?
C8 C9 H9 119.5 . . ?
C10' C9' C8' 121.4(5) . . ?
C10' C9' H9' 119.3 . . ?
C8' C9' H9' 119.3 . . ?
C11 C10 C9 118.5(5) . . ?
C11 C10 H10 120.7 . . ?
C9 C10 H10 120.7 . . ?
C22 C21 C20 122.9(4) . . ?
C22 C21 H21 118.6 . . ?
C20 C21 H21 118.6 . . ?
C22' C21' C20' 122.8(4) . . ?
C22' C21' H21' 118.6 . . ?
C20' C21' H21' 118.6 . . ?
C10 C11 C12 120.9(5) . . ?
C10 C11 H11 119.5 . . ?
C12 C11 H11 119.5 . . ?
C11 C12 C7 121.9(5) . . ?
C11 C12 H12 119.0 . . ?
C7 C12 H12 119.0 . . ?
C7' C12' C11' 121.9(5) . . ?
C7' C12' H12' 119.1 . . ?
C11' C12' H12' 119.1 . . ?
N1 C13 C18 126.3(4) . . ?
N1 C13 C14 117.2(3) . . ?
C18 C13 C14 116.1(4) . . ?
N1' C13' C14' 117.7(3) . . ?
N1' C13' C18' 125.4(4) . . ?
C14' C13' C18' 116.5(4) . . ?
C15 C14 C13 120.8(4) . . ?
C15 C14 P1 124.7(3) . . ?
C13 C14 P1 114.5(3) . . ?
C15' C14' C13' 120.9(4) . . ?
C15' C14' P1' 123.5(3) . . ?
C13' C14' P1' 115.7(3) . . ?
C17 C16 C15 117.2(4) . . ?
C17 C16 C25 121.9(4) . . ?
C15 C16 C25 120.9(5) . . ?
C16 C15 C14 121.8(4) . . ?
C16 C15 H15 119.1 . . ?
C14 C15 H15 119.1 . . ?
C16' C15' C14' 121.7(4) . . ?
C16' C15' H15' 119.2 . . ?
C14' C15' H15' 119.2 . . ?
C16 C17 C18 122.8(4) . . ?
C16 C17 H17 118.6 . . ?
C18 C17 H17 118.6 . . ?
C17 C18 C13 121.2(4) . . ?
C17 C18 H18 119.4 . . ?
C13 C18 H18 119.4 . . ?
C17' C18' C13' 120.8(4) . . ?
C17' C18' H18' 119.6 . . ?
C13' C18' H18' 119.6 . . ?
N1 C19 C24 125.4(4) . . ?
N1 C19 C20 118.2(4) . . ?
C24 C19 C20 116.4(4) . . ?
N1' C19' C24' 124.1(4) . . ?
N1' C19' C20' 118.7(4) . . ?
C24' C19' C20' 117.1(4) . . ?
C9' C10' C11' 118.8(5) . . ?
C9' C10' H10' 120.6 . . ?
C11' C10' H10' 120.6 . . ?
C36 C38 H38A 109.5 . . ?
C36 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C36 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C36' C38' H38D 109.5 . . ?
C36' C38' H38E 109.5 . . ?
H38D C38' H38E 109.5 . . ?
C36' C38' H38F 109.5 . . ?
H38D C38' H38F 109.5 . . ?
H38E C38' H38F 109.5 . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C36' C37' H37D 109.5 . . ?
C36' C37' H37E 109.5 . . ?
H37D C37' H37E 109.5 . . ?
C36' C37' H37F 109.5 . . ?
H37D C37' H37F 109.5 . . ?
H37E C37' H37F 109.5 . . ?
C37 C36 C38 111.2(4) . . ?
C37 C36 P2 116.2(3) . . ?
C38 C36 P2 108.6(3) . . ?
C37 C36 H36 106.8 . . ?
C38 C36 H36 106.8 . . ?
P2 C36 H36 106.8 . . ?
C38' C36' C37' 111.1(4) . . ?
C38' C36' P2' 109.4(3) . . ?
C37' C36' P2' 111.2(3) . . ?
C38' C36' H36' 108.4 . . ?
C37' C36' H36' 108.4 . . ?
P2' C36' H36' 108.4 . . ?
C33 C35 H35A 109.5 . . ?
C33 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C33 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C33' C35' H35D 109.5 . . ?
C33' C35' H35E 109.5 . . ?
H35D C35' H35E 109.5 . . ?
C33' C35' H35F 109.5 . . ?
H35D C35' H35F 109.5 . . ?
H35E C35' H35F 109.5 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33' C34' H34D 109.5 . . ?
C33' C34' H34E 109.5 . . ?
H34D C34' H34E 109.5 . . ?
C33' C34' H34F 109.5 . . ?
H34D C34' H34F 109.5 . . ?
H34E C34' H34F 109.5 . . ?
C34 C33 C35 110.7(4) . . ?
C34 C33 P2 110.7(3) . . ?
C35 C33 P2 111.8(3) . . ?
C34 C33 H33 107.8 . . ?
C35 C33 H33 107.8 . . ?
P2 C33 H33 107.8 . . ?
C35' C33' C34' 109.7(4) . . ?
C35' C33' P2' 111.9(3) . . ?
C34' C33' P2' 115.1(4) . . ?
C35' C33' H33' 106.5 . . ?
C34' C33' H33' 106.5 . . ?
P2' C33' H33' 106.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C30' C32' H32D 109.5 . . ?
C30' C32' H32E 109.5 . . ?
H32D C32' H32E 109.5 . . ?
C30' C32' H32F 109.5 . . ?
H32D C32' H32F 109.5 . . ?
H32E C32' H32F 109.5 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30' C31' H31D 109.5 . . ?
C30' C31' H31E 109.5 . . ?
H31D C31' H31E 109.5 . . ?
C30' C31' H31F 109.5 . . ?
H31D C31' H31F 109.5 . . ?
H31E C31' H31F 109.5 . . ?
C31 C30 C32 110.1(4) . . ?
C31 C30 P1 111.3(3) . . ?
C32 C30 P1 110.0(3) . . ?
C31 C30 H30 108.5 . . ?
C32 C30 H30 108.5 . . ?
P1 C30 H30 108.5 . . ?
C31' C30' C32' 109.9(4) . . ?
C31' C30' P1' 110.4(3) . . ?
C32' C30' P1' 110.2(3) . . ?
C31' C30' H30' 108.8 . . ?
C32' C30' H30' 108.8 . . ?
P1' C30' H30' 108.8 . . ?
C18' C17' C16' 122.4(4) . . ?
C18' C17' H17' 118.8 . . ?
C16' C17' H17' 118.8 . . ?
C22' C26' H26A 109.5 . . ?
C22' C26' H26B 109.5 . . ?
H26A C26' H26B 109.5 . . ?
C22' C26' H26C 109.5 . . ?
H26A C26' H26C 109.5 . . ?
H26B C26' H26C 109.5 . . ?
C17' C16' C15' 117.6(4) . . ?
C17' C16' C25' 122.2(4) . . ?
C15' C16' C25' 120.2(4) . . ?
C21 C20 C19 119.7(4) . . ?
C21 C20 P2 123.0(3) . . ?
C19 C20 P2 117.0(3) . . ?
C21' C20' C19' 119.6(4) . . ?
C21' C20' P2' 122.6(3) . . ?
C19' C20' P2' 117.4(3) . . ?
C21 C22 C23 116.7(4) . . ?
C21 C22 C26 121.8(4) . . ?
C23 C22 C26 121.5(4) . . ?
C21' C22' C23' 116.9(4) . . ?
C21' C22' C26' 121.4(4) . . ?
C23' C22' C26' 121.6(4) . . ?
C24 C23 C22 122.1(4) . . ?
C24 C23 H23 118.9 . . ?
C22 C23 H23 118.9 . . ?
C24' C23' C22' 122.2(4) . . ?
C24' C23' H23' 118.9 . . ?
C22' C23' H23' 118.9 . . ?
C16 C25 H25A 109.5 . . ?
C16 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C16 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C16' C25' H25D 109.5 . . ?
C16' C25' H25E 109.5 . . ?
H25D C25' H25E 109.5 . . ?
C16' C25' H25F 109.5 . . ?
H25D C25' H25F 109.5 . . ?
H25E C25' H25F 109.5 . . ?
C23 C24 C19 121.9(4) . . ?
C23 C24 H24 119.0 . . ?
C19 C24 H24 119.0 . . ?
C23' C24' C19' 121.3(4) . . ?
C23' C24' H24' 119.4 . . ?
C19' C24' H24' 119.4 . . ?
C10' C11' C12' 120.4(5) . . ?
C10' C11' H11' 119.8 . . ?
C12' C11' H11' 119.8 . . ?
C22 C26 H26D 109.5 . . ?
C22 C26 H26E 109.5 . . ?
H26D C26 H26E 109.5 . . ?
C22 C26 H26F 109.5 . . ?
H26D C26 H26F 109.5 . . ?
H26E C26 H26F 109.5 . . ?
C28 C27 C29 110.2(4) . . ?
C28 C27 P1 110.9(3) . . ?
C29 C27 P1 113.0(3) . . ?
C28 C27 H27 107.5 . . ?
C29 C27 H27 107.5 . . ?
P1 C27 H27 107.5 . . ?
C28' C27' C29' 110.7(4) . . ?
C28' C27' P1' 109.9(3) . . ?
C29' C27' P1' 113.4(3) . . ?
C28' C27' H27' 107.5 . . ?
C29' C27' H27' 107.5 . . ?
P1' C27' H27' 107.5 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27' C28' H28D 109.5 . . ?
C27' C28' H28E 109.5 . . ?
H28D C28' H28E 109.5 . . ?
C27' C28' H28F 109.5 . . ?
H28D C28' H28F 109.5 . . ?
H28E C28' H28F 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27' C29' H29D 109.5 . . ?
C27' C29' H29E 109.5 . . ?
H29D C29' H29E 109.5 . . ?
C27' C29' H29F 109.5 . . ?
H29D C29' H29F 109.5 . . ?
H29E C29' H29F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -0.1(6) . . . . ?
Rh1 C1 C2 C3 179.1(3) . . . . ?
C6' C1' C2' C3' 0.1(6) . . . . ?
Rh1' C1' C2' C3' 177.5(3) . . . . ?
C1 C2 C3 C4 -0.1(7) . . . . ?
C1' C2' C3' C4' 0.1(7) . . . . ?
C2 C3 C4 C5 0.1(7) . . . . ?
C2' C3' C4' C5' 0.1(7) . . . . ?
C3 C4 C5 C6 0.1(7) . . . . ?
C3' C4' C5' C6' -0.4(7) . . . . ?
C4' C5' C6' C1' 0.6(7) . . . . ?
C2' C1' C6' C5' -0.4(6) . . . . ?
Rh1' C1' C6' C5' -177.6(3) . . . . ?
C4 C5 C6 C1 -0.2(7) . . . . ?
C2 C1 C6 C5 0.2(6) . . . . ?
Rh1 C1 C6 C5 -179.0(3) . . . . ?
C12 C7 C8 C9 -0.1(8) . . . . ?
Zn1 C7 C8 C9 -177.0(4) . . . . ?
C12' C7' C8' C9' -1.9(7) . . . . ?
Zn1' C7' C8' C9' 174.9(4) . . . . ?
C7 C8 C9 C10 1.6(9) . . . . ?
C7' C8' C9' C10' 1.3(8) . . . . ?
C8 C9 C10 C11 -1.6(8) . . . . ?
C9 C10 C11 C12 0.0(8) . . . . ?
C10 C11 C12 C7 1.6(8) . . . . ?
C8 C7 C12 C11 -1.5(7) . . . . ?
Zn1 C7 C12 C11 175.6(4) . . . . ?
C8' C7' C12' C11' 1.1(8) . . . . ?
Zn1' C7' C12' C11' -175.6(4) . . . . ?
C19 N1 C13 C18 -23.1(6) . . . . ?
Rh1 N1 C13 C18 156.8(3) . . . . ?
C19 N1 C13 C14 164.0(4) . . . . ?
Rh1 N1 C13 C14 -16.2(5) . . . . ?
C19' N1' C13' C14' 152.6(4) . . . . ?
Rh1' N1' C13' C14' -11.6(5) . . . . ?
C19' N1' C13' C18' -35.0(6) . . . . ?
Rh1' N1' C13' C18' 160.7(3) . . . . ?
N1 C13 C14 C15 171.8(4) . . . . ?
C18 C13 C14 C15 -1.9(6) . . . . ?
N1 C13 C14 P1 -6.3(5) . . . . ?
C18 C13 C14 P1 -180.0(3) . . . . ?
C30 P1 C14 C15 -21.9(4) . . . . ?
C27 P1 C14 C15 88.5(4) . . . . ?
Rh1 P1 C14 C15 -155.9(3) . . . . ?
C30 P1 C14 C13 156.1(3) . . . . ?
C27 P1 C14 C13 -93.5(3) . . . . ?
Rh1 P1 C14 C13 22.1(3) . . . . ?
N1' C13' C14' C15' 175.3(4) . . . . ?
C18' C13' C14' C15' 2.3(6) . . . . ?
N1' C13' C14' P1' -4.9(5) . . . . ?
C18' C13' C14' P1' -178.0(3) . . . . ?
C30' P1' C14' C15' -29.4(4) . . . . ?
C27' P1' C14' C15' 81.7(4) . . . . ?
Rh1' P1' C14' C15' -163.6(3) . . . . ?
C30' P1' C14' C13' 150.9(3) . . . . ?
C27' P1' C14' C13' -98.0(3) . . . . ?
Rh1' P1' C14' C13' 16.7(3) . . . . ?
C17 C16 C15 C14 2.2(6) . . . . ?
C25 C16 C15 C14 -176.1(4) . . . . ?
C13 C14 C15 C16 -0.3(6) . . . . ?
P1 C14 C15 C16 177.6(3) . . . . ?
C13' C14' C15' C16' -0.6(6) . . . . ?
P1' C14' C15' C16' 179.7(3) . . . . ?
C15 C16 C17 C18 -1.9(7) . . . . ?
C25 C16 C17 C18 176.5(4) . . . . ?
C16 C17 C18 C13 -0.4(7) . . . . ?
N1 C13 C18 C17 -170.8(4) . . . . ?
C14 C13 C18 C17 2.2(6) . . . . ?
N1' C13' C18' C17' -174.9(4) . . . . ?
C14' C13' C18' C17' -2.4(6) . . . . ?
C13 N1 C19 C24 -22.6(6) . . . . ?
Rh1 N1 C19 C24 157.6(3) . . . . ?
C13 N1 C19 C20 159.7(4) . . . . ?
Rh1 N1 C19 C20 -20.2(5) . . . . ?
C13' N1' C19' C24' -12.0(6) . . . . ?
Rh1' N1' C19' C24' 152.8(3) . . . . ?
C13' N1' C19' C20' 172.1(4) . . . . ?
Rh1' N1' C19' C20' -23.1(4) . . . . ?
C8' C9' C10' C11' 0.3(8) . . . . ?
C20 P2 C36 C37 61.1(4) . . . . ?
C33 P2 C36 C37 -50.5(4) . . . . ?
Rh1 P2 C36 C37 167.8(3) . . . . ?
C20 P2 C36 C38 -65.0(3) . . . . ?
C33 P2 C36 C38 -176.7(3) . . . . ?
Rh1 P2 C36 C38 41.7(3) . . . . ?
C20' P2' C36' C38' -68.2(4) . . . . ?
C33' P2' C36' C38' 178.5(3) . . . . ?
Rh1' P2' C36' C38' 38.8(4) . . . . ?
C20' P2' C36' C37' 168.8(3) . . . . ?
C33' P2' C36' C37' 55.4(4) . . . . ?
Rh1' P2' C36' C37' -84.2(3) . . . . ?
C20 P2 C33 C34 70.0(4) . . . . ?
C36 P2 C33 C34 -178.4(3) . . . . ?
Rh1 P2 C33 C34 -49.5(4) . . . . ?
C20 P2 C33 C35 -166.1(3) . . . . ?
C36 P2 C33 C35 -54.5(4) . . . . ?
Rh1 P2 C33 C35 74.4(4) . . . . ?
C20' P2' C33' C35' 73.3(4) . . . . ?
C36' P2' C33' C35' -177.3(4) . . . . ?
Rh1' P2' C33' C35' -43.7(4) . . . . ?
C20' P2' C33' C34' -52.8(4) . . . . ?
C36' P2' C33' C34' 56.6(4) . . . . ?
Rh1' P2' C33' C34' -169.8(3) . . . . ?
C14 P1 C30 C31 -69.1(3) . . . . ?
C27 P1 C30 C31 -178.8(3) . . . . ?
Rh1 P1 C30 C31 49.2(4) . . . . ?
C14 P1 C30 C32 168.6(3) . . . . ?
C27 P1 C30 C32 58.9(3) . . . . ?
Rh1 P1 C30 C32 -73.1(3) . . . . ?
C14' P1' C30' C31' -69.7(4) . . . . ?
C27' P1' C30' C31' -178.8(3) . . . . ?
Rh1' P1' C30' C31' 48.9(4) . . . . ?
C14' P1' C30' C32' 168.7(3) . . . . ?
C27' P1' C30' C32' 59.6(3) . . . . ?
Rh1' P1' C30' C32' -72.6(3) . . . . ?
C13' C18' C17' C16' 0.8(6) . . . . ?
C18' C17' C16' C15' 1.0(6) . . . . ?
C18' C17' C16' C25' -179.0(4) . . . . ?
C14' C15' C16' C17' -1.1(6) . . . . ?
C14' C15' C16' C25' 178.9(4) . . . . ?
C22 C21 C20 C19 -4.6(6) . . . . ?
C22 C21 C20 P2 168.7(3) . . . . ?
N1 C19 C20 C21 -175.3(4) . . . . ?
C24 C19 C20 C21 6.7(6) . . . . ?
N1 C19 C20 P2 11.0(5) . . . . ?
C24 C19 C20 P2 -167.0(3) . . . . ?
C33 P2 C20 C21 51.0(4) . . . . ?
C36 P2 C20 C21 -59.7(4) . . . . ?
Rh1 P2 C20 C21 -171.4(3) . . . . ?
C33 P2 C20 C19 -135.5(3) . . . . ?
C36 P2 C20 C19 113.8(3) . . . . ?
Rh1 P2 C20 C19 2.1(3) . . . . ?
C22' C21' C20' C19' -1.2(6) . . . . ?
C22' C21' C20' P2' 171.2(3) . . . . ?
N1' C19' C20' C21' 179.1(4) . . . . ?
C24' C19' C20' C21' 2.9(6) . . . . ?
N1' C19' C20' P2' 6.3(5) . . . . ?
C24' C19' C20' P2' -169.9(3) . . . . ?
C36' P2' C20' C21' -42.9(4) . . . . ?
C33' P2' C20' C21' 65.8(4) . . . . ?
Rh1' P2' C20' C21' -161.3(3) . . . . ?
C36' P2' C20' C19' 129.6(3) . . . . ?
C33' P2' C20' C19' -121.7(3) . . . . ?
Rh1' P2' C20' C19' 11.2(3) . . . . ?
C20 C21 C22 C23 -0.4(6) . . . . ?
C20 C21 C22 C26 -178.9(4) . . . . ?
C20' C21' C22' C23' -1.1(7) . . . . ?
C20' C21' C22' C26' -177.5(5) . . . . ?
C21 C22 C23 C24 3.0(6) . . . . ?
C26 C22 C23 C24 -178.5(4) . . . . ?
C21' C22' C23' C24' 1.6(7) . . . . ?
C26' C22' C23' C24' 178.0(4) . . . . ?
C22 C23 C24 C19 -0.6(7) . . . . ?
N1 C19 C24 C23 177.9(4) . . . . ?
C20 C19 C24 C23 -4.3(6) . . . . ?
C22' C23' C24' C19' 0.2(6) . . . . ?
N1' C19' C24' C23' -178.5(4) . . . . ?
C20' C19' C24' C23' -2.5(6) . . . . ?
C9' C10' C11' C12' -1.2(9) . . . . ?
C7' C12' C11' C10' 0.5(9) . . . . ?
C14 P1 C27 C28 59.5(3) . . . . ?
C30 P1 C27 C28 171.5(3) . . . . ?
Rh1 P1 C27 C28 -48.4(3) . . . . ?
C14 P1 C27 C29 -64.9(3) . . . . ?
C30 P1 C27 C29 47.2(4) . . . . ?
Rh1 P1 C27 C29 -172.7(3) . . . . ?
C14' P1' C27' C28' 67.3(3) . . . . ?
C30' P1' C27' C28' 178.2(3) . . . . ?
Rh1' P1' C27' C28' -41.0(3) . . . . ?
C14' P1' C27' C29' -57.3(3) . . . . ?
C30' P1' C27' C29' 53.7(4) . . . . ?
Rh1' P1' C27' C29' -165.5(3) . . . . ?

_refine_diff_density_max         0.602
_refine_diff_density_min         -0.378
_refine_diff_density_rms         0.054


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: pentane'
_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_oz562_cjp963
_database_code_depnum_ccdc_archive 'CCDC 1537395'
_audit_update_record             
;
2017-03-11 deposited with the CCDC.
2017-05-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        '[(PNP)Rh(Ph)]2[μ-Zn]'
_chemical_name_common            none
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C64 H90 N2 P4 Rh2 Zn'
_chemical_formula_weight         1282.44

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.924(3)
_cell_length_b                   14.202(2)
_cell_length_c                   28.341(5)
_cell_angle_alpha                90
_cell_angle_beta                 98.235(2)
_cell_angle_gamma                90
_cell_volume                     6343.2(17)
_cell_formula_units_Z            4
_cell_measurement_temperature    110(2)
_cell_measurement_reflns_used    9961
_cell_measurement_theta_min      5.049
_cell_measurement_theta_max      52.616

_exptl_crystal_description       plate
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.343
_exptl_crystal_F_000             2672
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.170
_exptl_crystal_size_min          0.030
_exptl_absorpt_coefficient_mu    1.029
_shelx_estimated_absorpt_T_min   0.748
_shelx_estimated_absorpt_T_max   0.970
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6611
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      110(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            66861
_diffrn_reflns_av_unetI/netI     0.0333
_diffrn_reflns_av_R_equivalents  0.0445
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         1.996
_diffrn_reflns_theta_max         26.396
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             12907
_reflns_number_gt                10556
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ', SQUEEZE'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0447P)²+6.8887P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         12907
_refine_ls_number_parameters     678
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0459
_refine_ls_R_factor_gt           0.0338
_refine_ls_wR_factor_ref         0.0897
_refine_ls_wR_factor_gt          0.0826
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.14392(2) 0.39355(2) 0.40397(2) 0.01282(6) Uani 1 1 d . . . . .
N1 N 0.06696(14) 0.28832(16) 0.36669(8) 0.0152(5) Uani 1 1 d . . . . .
C1 C 0.20463(17) 0.50354(19) 0.44167(10) 0.0159(6) Uani 1 1 d . . . . .
C2 C 0.25241(18) 0.5754(2) 0.42442(11) 0.0203(6) Uani 1 1 d . . . . .
H2 H 0.2693 0.5681 0.3938 0.024 Uiso 1 1 calc R U . . .
N2 N 0.35284(14) 0.51097(16) 0.28335(8) 0.0160(5) Uani 1 1 d . . . . .
Rh2 Rh 0.36678(2) 0.37194(2) 0.30994(2) 0.01366(6) Uani 1 1 d . . . . .
Zn1 Zn 0.25803(2) 0.38277(2) 0.35875(2) 0.01578(8) Uani 1 1 d . . . . .
P1 P 0.16857(5) 0.26892(5) 0.45674(3) 0.01596(15) Uani 1 1 d . . . . .
P2 P 0.06298(4) 0.49328(5) 0.35334(3) 0.01434(15) Uani 1 1 d . . . . .
P3 P 0.28178(5) 0.33673(6) 0.24067(3) 0.02234(17) Uani 1 1 d . . . . .
C3 C 0.2760(2) 0.6564(2) 0.45010(12) 0.0282(7) Uani 1 1 d . . . . .
H3 H 0.3082 0.7032 0.4368 0.034 Uiso 1 1 calc R U . . .
P4 P 0.47404(4) 0.44336(5) 0.36028(3) 0.01543(15) Uani 1 1 d . . . . .
C4 C 0.25322(19) 0.6701(2) 0.49490(11) 0.0263(7) Uani 1 1 d . . . . .
H4 H 0.2680 0.7265 0.5121 0.032 Uiso 1 1 calc R U . . .
C64 C 0.43488(19) 0.4435(2) 0.45318(10) 0.0229(6) Uani 1 1 d . . . . .
H64A H 0.4265 0.5118 0.4538 0.034 Uiso 1 1 calc R U . . .
H64B H 0.4498 0.4200 0.4858 0.034 Uiso 1 1 calc R U . . .
H64C H 0.3824 0.4131 0.4383 0.034 Uiso 1 1 calc R U . . .
C63 C 0.5355(2) 0.3181(2) 0.43092(11) 0.0253(7) Uani 1 1 d . . . . .
H63A H 0.4879 0.2762 0.4197 0.038 Uiso 1 1 calc R U . . .
H63B H 0.5551 0.3060 0.4647 0.038 Uiso 1 1 calc R U . . .
H63C H 0.5820 0.3066 0.4125 0.038 Uiso 1 1 calc R U . . .
C62 C 0.50638(18) 0.4209(2) 0.42444(10) 0.0200(6) Uani 1 1 d . . . . .
H62 H 0.5557 0.4625 0.4359 0.024 Uiso 1 1 calc R U . . .
C61 C 0.5674(2) 0.4955(3) 0.28820(12) 0.0324(8) Uani 1 1 d . . . . .
H61A H 0.6174 0.4846 0.2724 0.049 Uiso 1 1 calc R U . . .
H61B H 0.5631 0.5627 0.2953 0.049 Uiso 1 1 calc R U . . .
H61C H 0.5164 0.4753 0.2672 0.049 Uiso 1 1 calc R U . . .
C60 C 0.6535(2) 0.4742(3) 0.36774(13) 0.0369(9) Uani 1 1 d . . . . .
H60A H 0.7037 0.4705 0.3514 0.055 Uiso 1 1 calc R U . . .
H60B H 0.6621 0.4347 0.3964 0.055 Uiso 1 1 calc R U . . .
H60C H 0.6446 0.5396 0.3768 0.055 Uiso 1 1 calc R U . . .
C59 C 0.57583(18) 0.4395(2) 0.33438(11) 0.0218(6) Uani 1 1 d . . . . .
H59 H 0.5864 0.3723 0.3264 0.026 Uiso 1 1 calc R U . . .
C5 C 0.2087(2) 0.6000(2) 0.51382(11) 0.0256(7) Uani 1 1 d . . . . .
H5 H 0.1934 0.6073 0.5448 0.031 Uiso 1 1 calc R U . . .
C6 C 0.18585(19) 0.5189(2) 0.48798(10) 0.0217(6) Uani 1 1 d . . . . .
H6 H 0.1560 0.4713 0.5023 0.026 Uiso 1 1 calc R U . . .
C7 C 0.08596(18) 0.19328(19) 0.37517(10) 0.0173(6) Uani 1 1 d . . . . .
C8 C 0.13841(18) 0.1694(2) 0.41824(10) 0.0186(6) Uani 1 1 d . . . . .
C9 C 0.16062(19) 0.0764(2) 0.42922(11) 0.0221(6) Uani 1 1 d . . . . .
H9 H 0.1949 0.0629 0.4587 0.027 Uiso 1 1 calc R U . . .
C10 C 0.1343(2) 0.0030(2) 0.39850(12) 0.0274(7) Uani 1 1 d . . . . .
C11 C 0.0862(2) 0.0269(2) 0.35533(11) 0.0259(7) Uani 1 1 d . . . . .
H11 H 0.0688 -0.0217 0.3330 0.031 Uiso 1 1 calc R U . . .
C12 C 0.06267(19) 0.1184(2) 0.34360(11) 0.0224(6) Uani 1 1 d . . . . .
H12 H 0.0300 0.1311 0.3135 0.027 Uiso 1 1 calc R U . . .
C13 C -0.00423(17) 0.3165(2) 0.33593(10) 0.0163(6) Uani 1 1 d . . . . .
C16 C -0.14255(18) 0.3803(2) 0.26746(10) 0.0197(6) Uani 1 1 d . . . . .
C15 C -0.07622(18) 0.4394(2) 0.28508(10) 0.0191(6) Uani 1 1 d . . . . .
H15 H -0.0757 0.5016 0.2727 0.023 Uiso 1 1 calc R U . . .
C14 C -0.01018(18) 0.4120(2) 0.32005(10) 0.0175(6) Uani 1 1 d . . . . .
C19 C 0.1593(3) -0.0973(2) 0.41111(14) 0.0423(10) Uani 1 1 d . . . . .
H19A H 0.1081 -0.1355 0.4114 0.063 Uiso 1 1 calc R U . . .
H19B H 0.1935 -0.0990 0.4427 0.063 Uiso 1 1 calc R U . . .
H19C H 0.1924 -0.1226 0.3874 0.063 Uiso 1 1 calc R U . . .
C18 C -0.07582(18) 0.2598(2) 0.32122(10) 0.0198(6) Uani 1 1 d . . . . .
H18 H -0.0783 0.1983 0.3342 0.024 Uiso 1 1 calc R U . . .
C17 C -0.14208(19) 0.2911(2) 0.28861(11) 0.0219(6) Uani 1 1 d . . . . .
H17 H -0.1894 0.2507 0.2801 0.026 Uiso 1 1 calc R U . . .
C20 C -0.21362(19) 0.4103(2) 0.22957(12) 0.0279(7) Uani 1 1 d . . . . .
H20A H -0.2069 0.3798 0.1993 0.042 Uiso 1 1 calc R U . . .
H20B H -0.2121 0.4788 0.2257 0.042 Uiso 1 1 calc R U . . .
H20C H -0.2681 0.3918 0.2390 0.042 Uiso 1 1 calc R U . . .
C21 C 0.26912(18) 0.2381(2) 0.49443(10) 0.0200(6) Uani 1 1 d . . . . .
H21 H 0.2593 0.1807 0.5134 0.024 Uiso 1 1 calc R U . . .
C22 C 0.33714(19) 0.2157(2) 0.46385(11) 0.0249(7) Uani 1 1 d . . . . .
H22A H 0.3244 0.1552 0.4478 0.037 Uiso 1 1 calc R U . . .
H22B H 0.3924 0.2120 0.4840 0.037 Uiso 1 1 calc R U . . .
H22C H 0.3386 0.2653 0.4400 0.037 Uiso 1 1 calc R U . . .
C23 C 0.2956(2) 0.3188(2) 0.52912(10) 0.0246(7) Uani 1 1 d . . . . .
H23A H 0.3049 0.3758 0.5111 0.037 Uiso 1 1 calc R U . . .
H23B H 0.3482 0.3018 0.5498 0.037 Uiso 1 1 calc R U . . .
H23C H 0.2507 0.3303 0.5487 0.037 Uiso 1 1 calc R U . . .
C24 C 0.08765(19) 0.2653(2) 0.49892(10) 0.0219(6) Uani 1 1 d . . . . .
H24 H 0.0861 0.3291 0.5137 0.026 Uiso 1 1 calc R U . . .
C31 C -0.0784(2) 0.6053(2) 0.37254(12) 0.0294(7) Uani 1 1 d . . . . .
H31A H -0.0607 0.6536 0.3513 0.044 Uiso 1 1 calc R U . . .
H31B H -0.1058 0.6355 0.3974 0.044 Uiso 1 1 calc R U . . .
H31C H -0.1185 0.5622 0.3541 0.044 Uiso 1 1 calc R U . . .
C30 C -0.00067(18) 0.5503(2) 0.39554(10) 0.0197(6) Uani 1 1 d . . . . .
H30 H 0.0374 0.5956 0.4154 0.024 Uiso 1 1 calc R U . . .
C29 C 0.1313(2) 0.5553(2) 0.27484(12) 0.0286(7) Uani 1 1 d . . . . .
H29A H 0.1026 0.5024 0.2571 0.043 Uiso 1 1 calc R U . . .
H29B H 0.1869 0.5347 0.2909 0.043 Uiso 1 1 calc R U . . .
H29C H 0.1389 0.6066 0.2527 0.043 Uiso 1 1 calc R U . . .
C28 C 0.1148(2) 0.6800(2) 0.33543(12) 0.0275(7) Uani 1 1 d . . . . .
H28A H 0.1116 0.7306 0.3118 0.041 Uiso 1 1 calc R U . . .
H28B H 0.1742 0.6696 0.3491 0.041 Uiso 1 1 calc R U . . .
H28C H 0.0820 0.6976 0.3608 0.041 Uiso 1 1 calc R U . . .
C27 C 0.07838(18) 0.5895(2) 0.31147(10) 0.0192(6) Uani 1 1 d . . . . .
H27 H 0.0211 0.6055 0.2939 0.023 Uiso 1 1 calc R U . . .
C26 C 0.1075(2) 0.1934(2) 0.53947(11) 0.0303(7) Uani 1 1 d . . . . .
H26A H 0.1174 0.1315 0.5260 0.045 Uiso 1 1 calc R U . . .
H26B H 0.0594 0.1896 0.5574 0.045 Uiso 1 1 calc R U . . .
H26C H 0.1583 0.2133 0.5608 0.045 Uiso 1 1 calc R U . . .
C25 C -0.00126(19) 0.2446(2) 0.47251(12) 0.0281(7) Uani 1 1 d . . . . .
H25A H -0.0114 0.2829 0.4435 0.042 Uiso 1 1 calc R U . . .
H25B H -0.0437 0.2601 0.4932 0.042 Uiso 1 1 calc R U . . .
H25C H -0.0056 0.1778 0.4640 0.042 Uiso 1 1 calc R U . . .
C32 C -0.0275(2) 0.4759(2) 0.42900(11) 0.0259(7) Uani 1 1 d . . . . .
H32A H -0.0655 0.4305 0.4107 0.039 Uiso 1 1 calc R U . . .
H32B H -0.0571 0.5061 0.4530 0.039 Uiso 1 1 calc R U . . .
H32C H 0.0229 0.4430 0.4449 0.039 Uiso 1 1 calc R U . . .
C38 C 0.46160(19) 0.1911(2) 0.32155(11) 0.0222(6) Uani 1 1 d . . . . .
H38 H 0.5040 0.2294 0.3109 0.027 Uiso 1 1 calc R U . . .
C37 C 0.4779(2) 0.0960(2) 0.32841(11) 0.0246(7) Uani 1 1 d . . . . .
H37 H 0.5303 0.0706 0.3221 0.030 Uiso 1 1 calc R U . . .
C36 C 0.4184(2) 0.0377(2) 0.34431(11) 0.0272(7) Uani 1 1 d . . . . .
H36 H 0.4291 -0.0278 0.3487 0.033 Uiso 1 1 calc R U . . .
C35 C 0.3432(2) 0.0764(2) 0.35369(11) 0.0251(7) Uani 1 1 d . . . . .
H35 H 0.3020 0.0376 0.3652 0.030 Uiso 1 1 calc R U . . .
C34 C 0.32728(19) 0.1718(2) 0.34647(10) 0.0199(6) Uani 1 1 d . . . . .
H34 H 0.2748 0.1964 0.3532 0.024 Uiso 1 1 calc R U . . .
C33 C 0.38508(18) 0.23381(19) 0.32968(10) 0.0173(6) Uani 1 1 d . . . . .
C39 C 0.31364(17) 0.5255(2) 0.23687(10) 0.0179(6) Uani 1 1 d . . . . .
C40 C 0.26703(18) 0.4508(2) 0.21240(10) 0.0187(6) Uani 1 1 d . . . . .
C41 C 0.2199(2) 0.4652(2) 0.16762(10) 0.0250(7) Uani 1 1 d . . . . .
H41 H 0.1870 0.4147 0.1528 0.030 Uiso 1 1 calc R U . . .
C42 C 0.2192(2) 0.5506(2) 0.14396(11) 0.0305(8) Uani 1 1 d . . . . .
C43 C 0.2725(2) 0.6206(2) 0.16568(11) 0.0284(7) Uani 1 1 d . . . . .
H43 H 0.2773 0.6782 0.1493 0.034 Uiso 1 1 calc R U . . .
C44 C 0.31883(19) 0.6088(2) 0.21052(11) 0.0217(6) Uani 1 1 d . . . . .
H44 H 0.3550 0.6581 0.2238 0.026 Uiso 1 1 calc R U . . .
C45 C 0.38029(17) 0.5849(2) 0.31413(10) 0.0163(6) Uani 1 1 d . . . . .
C46 C 0.44178(17) 0.56501(19) 0.35421(10) 0.0163(6) Uani 1 1 d . . . . .
C47 C 0.47024(18) 0.6353(2) 0.38704(10) 0.0184(6) Uani 1 1 d . . . . .
H47 H 0.5129 0.6205 0.4129 0.022 Uiso 1 1 calc R U . . .
C48 C 0.43792(19) 0.7265(2) 0.38293(10) 0.0206(6) Uani 1 1 d . . . . .
C51 C 0.1647(3) 0.5658(3) 0.09622(12) 0.0477(11) Uani 1 1 d . . . . .
H51A H 0.1827 0.5225 0.0727 0.072 Uiso 1 1 calc R U . . .
H51B H 0.1710 0.6309 0.0858 0.072 Uiso 1 1 calc R U . . .
H51C H 0.1051 0.5538 0.0993 0.072 Uiso 1 1 calc R U . . .
C50 C 0.34627(18) 0.6765(2) 0.31147(10) 0.0190(6) Uani 1 1 d . . . . .
H50 H 0.3030 0.6920 0.2860 0.023 Uiso 1 1 calc R U . . .
C49 C 0.37413(19) 0.7442(2) 0.34484(10) 0.0206(6) Uani 1 1 d . . . . .
H49 H 0.3491 0.8050 0.3418 0.025 Uiso 1 1 calc R U . . .
C52 C 0.4689(2) 0.8011(2) 0.41904(11) 0.0288(7) Uani 1 1 d . . . . .
H52A H 0.5184 0.8329 0.4094 0.043 Uiso 1 1 calc R U . . .
H52B H 0.4849 0.7717 0.4503 0.043 Uiso 1 1 calc R U . . .
H52C H 0.4237 0.8471 0.4209 0.043 Uiso 1 1 calc R U . . .
C53 C 0.3572(3) 0.2748(2) 0.20584(11) 0.0433(10) Uani 1 1 d . . . . .
H53 H 0.3696 0.2120 0.2213 0.052 Uiso 1 1 calc R U . . .
C54 C 0.4400(3) 0.3276(3) 0.21077(14) 0.0476(11) Uani 1 1 d . . . . .
H54A H 0.4807 0.2927 0.1946 0.071 Uiso 1 1 calc R U . . .
H54B H 0.4625 0.3344 0.2446 0.071 Uiso 1 1 calc R U . . .
H54C H 0.4306 0.3901 0.1963 0.071 Uiso 1 1 calc R U . . .
C55 C 0.3234(3) 0.2559(3) 0.15359(13) 0.0619(14) Uani 1 1 d . . . . .
H55A H 0.3197 0.3153 0.1358 0.093 Uiso 1 1 calc R U . . .
H55B H 0.2669 0.2273 0.1512 0.093 Uiso 1 1 calc R U . . .
H55C H 0.3619 0.2128 0.1402 0.093 Uiso 1 1 calc R U . . .
C56 C 0.1871(2) 0.2639(3) 0.22439(14) 0.0437(10) Uani 1 1 d . . . . .
H56A H 0.1721 0.2650 0.1889 0.052 Uiso 1 1 calc R U . . .
C57 C 0.2005(4) 0.1645(3) 0.23976(16) 0.081(2) Uani 1 1 d . . . . .
H57A H 0.1502 0.1274 0.2276 0.121 Uiso 1 1 calc R U . . .
H57B H 0.2101 0.1615 0.2747 0.121 Uiso 1 1 calc R U . . .
H57C H 0.2501 0.1391 0.2272 0.121 Uiso 1 1 calc R U . . .
C58 C 0.1178(3) 0.3024(3) 0.24482(17) 0.0673(14) Uani 1 1 d . . . . .
H58A H 0.0852 0.3449 0.2219 0.101 Uiso 1 1 calc R U . . .
H58B H 0.1395 0.3374 0.2738 0.101 Uiso 1 1 calc R U . . .
H58C H 0.0809 0.2512 0.2528 0.101 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 2.054(3) . ?
Rh1 N1 2.117(2) . ?
Rh1 P2 2.2795(7) . ?
Rh1 P1 2.3141(8) . ?
Rh1 Zn1 2.3738(5) . ?
N1 C13 1.387(3) . ?
N1 C7 1.396(3) . ?
C1 C2 1.402(4) . ?
C1 C6 1.404(4) . ?
C2 C3 1.385(4) . ?
C2 H2 0.9500 . ?
N2 C39 1.390(4) . ?
N2 C45 1.395(4) . ?
N2 Rh2 2.114(2) . ?
Rh2 C33 2.049(3) . ?
Rh2 P3 2.2749(8) . ?
Rh2 P4 2.2986(8) . ?
Rh2 Zn1 2.3711(5) . ?
P1 C8 1.808(3) . ?
P1 C21 1.846(3) . ?
P1 C24 1.880(3) . ?
P2 C14 1.807(3) . ?
P2 C27 1.850(3) . ?
P2 C30 1.860(3) . ?
P3 C40 1.808(3) . ?
P3 C56 1.832(4) . ?
P3 C53 1.879(4) . ?
C3 C4 1.383(5) . ?
C3 H3 0.9500 . ?
P4 C46 1.804(3) . ?
P4 C62 1.845(3) . ?
P4 C59 1.874(3) . ?
C4 C5 1.375(5) . ?
C4 H4 0.9500 . ?
C64 C62 1.526(4) . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C63 C62 1.534(4) . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C62 H62 1.0000 . ?
C61 C59 1.521(4) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C60 C59 1.527(4) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C59 H59 1.0000 . ?
C5 C6 1.385(4) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.405(4) . ?
C7 C8 1.418(4) . ?
C8 C9 1.391(4) . ?
C9 C10 1.384(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.389(5) . ?
C10 C19 1.509(4) . ?
C11 C12 1.381(4) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.410(4) . ?
C13 C14 1.428(4) . ?
C16 C15 1.386(4) . ?
C16 C17 1.401(4) . ?
C16 C20 1.506(4) . ?
C15 C14 1.393(4) . ?
C15 H15 0.9500 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C18 C17 1.373(4) . ?
C18 H18 0.9500 . ?
C17 H17 0.9500 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.515(4) . ?
C21 C23 1.529(4) . ?
C21 H21 1.0000 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 C25 1.532(4) . ?
C24 C26 1.536(4) . ?
C24 H24 1.0000 . ?
C31 C30 1.529(4) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C30 C32 1.521(4) . ?
C30 H30 1.0000 . ?
C29 C27 1.508(4) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C28 C27 1.527(4) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C27 H27 1.0000 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C38 C37 1.384(4) . ?
C38 C33 1.409(4) . ?
C38 H38 0.9500 . ?
C37 C36 1.381(4) . ?
C37 H37 0.9500 . ?
C36 C35 1.378(5) . ?
C36 H36 0.9500 . ?
C35 C34 1.388(4) . ?
C35 H35 0.9500 . ?
C34 C33 1.405(4) . ?
C34 H34 0.9500 . ?
C39 C44 1.407(4) . ?
C39 C40 1.418(4) . ?
C40 C41 1.394(4) . ?
C41 C42 1.385(5) . ?
C41 H41 0.9500 . ?
C42 C43 1.392(5) . ?
C42 C51 1.515(4) . ?
C43 C44 1.385(4) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C50 1.407(4) . ?
C45 C46 1.418(4) . ?
C46 C47 1.396(4) . ?
C47 C48 1.392(4) . ?
C47 H47 0.9500 . ?
C48 C49 1.395(4) . ?
C48 C52 1.506(4) . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C50 C49 1.377(4) . ?
C50 H50 0.9500 . ?
C49 H49 0.9500 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 C54 1.505(6) . ?
C53 C55 1.525(5) . ?
C53 H53 1.0000 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 C58 1.427(6) . ?
C56 C57 1.483(6) . ?
C56 H56A 1.0000 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 N1 172.80(10) . . ?
C1 Rh1 P2 92.09(8) . . ?
N1 Rh1 P2 83.67(6) . . ?
C1 Rh1 P1 102.82(8) . . ?
N1 Rh1 P1 79.34(6) . . ?
P2 Rh1 P1 155.54(3) . . ?
C1 Rh1 Zn1 89.44(8) . . ?
N1 Rh1 Zn1 96.79(6) . . ?
P2 Rh1 Zn1 96.19(2) . . ?
P1 Rh1 Zn1 103.15(2) . . ?
C13 N1 C7 121.7(2) . . ?
C13 N1 Rh1 118.19(18) . . ?
C7 N1 Rh1 120.05(18) . . ?
C2 C1 C6 114.3(3) . . ?
C2 C1 Rh1 127.6(2) . . ?
C6 C1 Rh1 117.2(2) . . ?
C3 C2 C1 122.8(3) . . ?
C3 C2 H2 118.6 . . ?
C1 C2 H2 118.6 . . ?
C39 N2 C45 122.6(2) . . ?
C39 N2 Rh2 119.13(18) . . ?
C45 N2 Rh2 118.22(18) . . ?
C33 Rh2 N2 174.33(10) . . ?
C33 Rh2 P3 93.96(8) . . ?
N2 Rh2 P3 83.02(6) . . ?
C33 Rh2 P4 100.89(8) . . ?
N2 Rh2 P4 80.78(6) . . ?
P3 Rh2 P4 158.44(3) . . ?
C33 Rh2 Zn1 89.43(8) . . ?
N2 Rh2 Zn1 95.69(6) . . ?
P3 Rh2 Zn1 97.11(3) . . ?
P4 Rh2 Zn1 98.58(2) . . ?
Rh2 Zn1 Rh1 177.030(16) . . ?
C8 P1 C21 107.30(13) . . ?
C8 P1 C24 102.44(13) . . ?
C21 P1 C24 104.02(13) . . ?
C8 P1 Rh1 101.66(10) . . ?
C21 P1 Rh1 127.47(10) . . ?
C24 P1 Rh1 111.32(10) . . ?
C14 P2 C27 105.77(13) . . ?
C14 P2 C30 104.11(13) . . ?
C27 P2 C30 103.03(13) . . ?
C14 P2 Rh1 101.31(10) . . ?
C27 P2 Rh1 138.43(10) . . ?
C30 P2 Rh1 100.18(9) . . ?
C40 P3 C56 110.15(16) . . ?
C40 P3 C53 103.84(14) . . ?
C56 P3 C53 99.68(19) . . ?
C40 P3 Rh2 102.06(10) . . ?
C56 P3 Rh2 135.06(13) . . ?
C53 P3 Rh2 102.13(12) . . ?
C4 C3 C2 120.9(3) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
C46 P4 C62 107.18(13) . . ?
C46 P4 C59 103.98(13) . . ?
C62 P4 C59 104.24(13) . . ?
C46 P4 Rh2 100.79(9) . . ?
C62 P4 Rh2 127.80(10) . . ?
C59 P4 Rh2 110.57(10) . . ?
C5 C4 C3 118.2(3) . . ?
C5 C4 H4 120.9 . . ?
C3 C4 H4 120.9 . . ?
C62 C64 H64A 109.5 . . ?
C62 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C62 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C62 C63 H63A 109.5 . . ?
C62 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C62 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C64 C62 C63 111.8(2) . . ?
C64 C62 P4 111.42(19) . . ?
C63 C62 P4 108.6(2) . . ?
C64 C62 H62 108.3 . . ?
C63 C62 H62 108.3 . . ?
P4 C62 H62 108.3 . . ?
C59 C61 H61A 109.5 . . ?
C59 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C59 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C61 C59 C60 109.1(3) . . ?
C61 C59 P4 110.3(2) . . ?
C60 C59 P4 114.7(2) . . ?
C61 C59 H59 107.5 . . ?
C60 C59 H59 107.5 . . ?
P4 C59 H59 107.5 . . ?
C4 C5 C6 120.5(3) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C5 C6 C1 123.3(3) . . ?
C5 C6 H6 118.4 . . ?
C1 C6 H6 118.4 . . ?
N1 C7 C12 126.2(3) . . ?
N1 C7 C8 117.7(2) . . ?
C12 C7 C8 115.9(3) . . ?
C9 C8 C7 121.3(3) . . ?
C9 C8 P1 124.8(2) . . ?
C7 C8 P1 113.9(2) . . ?
C10 C9 C8 122.0(3) . . ?
C10 C9 H9 119.0 . . ?
C8 C9 H9 119.0 . . ?
C9 C10 C11 116.7(3) . . ?
C9 C10 C19 121.1(3) . . ?
C11 C10 C19 122.2(3) . . ?
C12 C11 C10 122.5(3) . . ?
C12 C11 H11 118.7 . . ?
C10 C11 H11 118.7 . . ?
C11 C12 C7 121.4(3) . . ?
C11 C12 H12 119.3 . . ?
C7 C12 H12 119.3 . . ?
N1 C13 C18 125.1(3) . . ?
N1 C13 C14 119.0(2) . . ?
C18 C13 C14 115.8(3) . . ?
C15 C16 C17 115.9(3) . . ?
C15 C16 C20 122.8(3) . . ?
C17 C16 C20 121.2(3) . . ?
C16 C15 C14 123.1(3) . . ?
C16 C15 H15 118.5 . . ?
C14 C15 H15 118.5 . . ?
C15 C14 C13 119.9(3) . . ?
C15 C14 P2 123.9(2) . . ?
C13 C14 P2 115.7(2) . . ?
C10 C19 H19A 109.5 . . ?
C10 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C10 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C18 C13 121.7(3) . . ?
C17 C18 H18 119.2 . . ?
C13 C18 H18 119.2 . . ?
C18 C17 C16 122.5(3) . . ?
C18 C17 H17 118.8 . . ?
C16 C17 H17 118.8 . . ?
C16 C20 H20A 109.5 . . ?
C16 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C16 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 C23 111.8(3) . . ?
C22 C21 P1 110.54(19) . . ?
C23 C21 P1 109.3(2) . . ?
C22 C21 H21 108.4 . . ?
C23 C21 H21 108.4 . . ?
P1 C21 H21 108.4 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C25 C24 C26 108.4(3) . . ?
C25 C24 P1 111.4(2) . . ?
C26 C24 P1 114.1(2) . . ?
C25 C24 H24 107.6 . . ?
C26 C24 H24 107.6 . . ?
P1 C24 H24 107.6 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C32 C30 C31 109.8(3) . . ?
C32 C30 P2 109.0(2) . . ?
C31 C30 P2 115.5(2) . . ?
C32 C30 H30 107.4 . . ?
C31 C30 H30 107.4 . . ?
P2 C30 H30 107.4 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C29 C27 C28 111.3(3) . . ?
C29 C27 P2 110.0(2) . . ?
C28 C27 P2 114.4(2) . . ?
C29 C27 H27 106.9 . . ?
C28 C27 H27 106.9 . . ?
P2 C27 H27 106.9 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C37 C38 C33 123.1(3) . . ?
C37 C38 H38 118.5 . . ?
C33 C38 H38 118.5 . . ?
C36 C37 C38 120.5(3) . . ?
C36 C37 H37 119.7 . . ?
C38 C37 H37 119.7 . . ?
C35 C36 C37 118.6(3) . . ?
C35 C36 H36 120.7 . . ?
C37 C36 H36 120.7 . . ?
C36 C35 C34 120.5(3) . . ?
C36 C35 H35 119.8 . . ?
C34 C35 H35 119.8 . . ?
C35 C34 C33 123.1(3) . . ?
C35 C34 H34 118.4 . . ?
C33 C34 H34 118.4 . . ?
C34 C33 C38 114.2(3) . . ?
C34 C33 Rh2 128.2(2) . . ?
C38 C33 Rh2 117.4(2) . . ?
N2 C39 C44 125.1(3) . . ?
N2 C39 C40 119.0(3) . . ?
C44 C39 C40 115.8(3) . . ?
C41 C40 C39 120.8(3) . . ?
C41 C40 P3 123.6(2) . . ?
C39 C40 P3 115.3(2) . . ?
C42 C41 C40 122.3(3) . . ?
C42 C41 H41 118.8 . . ?
C40 C41 H41 118.8 . . ?
C41 C42 C43 116.7(3) . . ?
C41 C42 C51 121.4(3) . . ?
C43 C42 C51 121.9(3) . . ?
C44 C43 C42 122.0(3) . . ?
C44 C43 H43 119.0 . . ?
C42 C43 H43 119.0 . . ?
C43 C44 C39 121.7(3) . . ?
C43 C44 H44 119.2 . . ?
C39 C44 H44 119.2 . . ?
N2 C45 C50 125.4(3) . . ?
N2 C45 C46 118.0(2) . . ?
C50 C45 C46 116.3(3) . . ?
C47 C46 C45 120.8(3) . . ?
C47 C46 P4 124.1(2) . . ?
C45 C46 P4 115.0(2) . . ?
C48 C47 C46 121.9(3) . . ?
C48 C47 H47 119.0 . . ?
C46 C47 H47 119.0 . . ?
C47 C48 C49 116.9(3) . . ?
C47 C48 C52 121.1(3) . . ?
C49 C48 C52 122.0(3) . . ?
C42 C51 H51A 109.5 . . ?
C42 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C42 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C49 C50 C45 121.7(3) . . ?
C49 C50 H50 119.2 . . ?
C45 C50 H50 119.2 . . ?
C50 C49 C48 122.2(3) . . ?
C50 C49 H49 118.9 . . ?
C48 C49 H49 118.9 . . ?
C48 C52 H52A 109.5 . . ?
C48 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C48 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C54 C53 C55 111.1(4) . . ?
C54 C53 P3 109.6(2) . . ?
C55 C53 P3 115.4(3) . . ?
C54 C53 H53 106.7 . . ?
C55 C53 H53 106.7 . . ?
P3 C53 H53 106.7 . . ?
C53 C54 H54A 109.5 . . ?
C53 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C53 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C53 C55 H55A 109.5 . . ?
C53 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C53 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C58 C56 C57 109.4(4) . . ?
C58 C56 P3 109.8(3) . . ?
C57 C56 P3 112.6(3) . . ?
C58 C56 H56A 108.3 . . ?
C57 C56 H56A 108.3 . . ?
P3 C56 H56A 108.3 . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C56 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C56 C58 H58A 109.5 . . ?
C56 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
C56 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -2.6(4) . . . . ?
Rh1 C1 C2 C3 166.3(2) . . . . ?
C1 C2 C3 C4 0.3(5) . . . . ?
C2 C3 C4 C5 1.8(5) . . . . ?
C46 P4 C62 C64 57.1(2) . . . . ?
C59 P4 C62 C64 167.0(2) . . . . ?
Rh2 P4 C62 C64 -62.1(2) . . . . ?
C46 P4 C62 C63 -179.2(2) . . . . ?
C59 P4 C62 C63 -69.4(2) . . . . ?
Rh2 P4 C62 C63 61.6(2) . . . . ?
C46 P4 C59 C61 -43.9(2) . . . . ?
C62 P4 C59 C61 -156.0(2) . . . . ?
Rh2 P4 C59 C61 63.5(2) . . . . ?
C46 P4 C59 C60 79.8(3) . . . . ?
C62 P4 C59 C60 -32.4(3) . . . . ?
Rh2 P4 C59 C60 -172.8(2) . . . . ?
C3 C4 C5 C6 -1.4(5) . . . . ?
C4 C5 C6 C1 -1.1(5) . . . . ?
C2 C1 C6 C5 3.0(4) . . . . ?
Rh1 C1 C6 C5 -167.0(2) . . . . ?
C13 N1 C7 C12 27.4(4) . . . . ?
Rh1 N1 C7 C12 -155.9(2) . . . . ?
C13 N1 C7 C8 -157.1(3) . . . . ?
Rh1 N1 C7 C8 19.6(3) . . . . ?
N1 C7 C8 C9 -179.7(3) . . . . ?
C12 C7 C8 C9 -3.7(4) . . . . ?
N1 C7 C8 P1 2.5(3) . . . . ?
C12 C7 C8 P1 178.5(2) . . . . ?
C21 P1 C8 C9 27.5(3) . . . . ?
C24 P1 C8 C9 -81.7(3) . . . . ?
Rh1 P1 C8 C9 163.1(2) . . . . ?
C21 P1 C8 C7 -154.8(2) . . . . ?
C24 P1 C8 C7 96.0(2) . . . . ?
Rh1 P1 C8 C7 -19.2(2) . . . . ?
C7 C8 C9 C10 1.3(5) . . . . ?
P1 C8 C9 C10 178.9(2) . . . . ?
C8 C9 C10 C11 1.6(5) . . . . ?
C8 C9 C10 C19 179.9(3) . . . . ?
C9 C10 C11 C12 -2.1(5) . . . . ?
C19 C10 C11 C12 179.7(3) . . . . ?
C10 C11 C12 C7 -0.4(5) . . . . ?
N1 C7 C12 C11 178.8(3) . . . . ?
C8 C7 C12 C11 3.2(4) . . . . ?
C7 N1 C13 C18 19.4(4) . . . . ?
Rh1 N1 C13 C18 -157.4(2) . . . . ?
C7 N1 C13 C14 -165.5(3) . . . . ?
Rh1 N1 C13 C14 17.7(3) . . . . ?
C17 C16 C15 C14 3.0(4) . . . . ?
C20 C16 C15 C14 -179.9(3) . . . . ?
C16 C15 C14 C13 6.3(4) . . . . ?
C16 C15 C14 P2 -165.2(2) . . . . ?
N1 C13 C14 C15 172.8(3) . . . . ?
C18 C13 C14 C15 -11.7(4) . . . . ?
N1 C13 C14 P2 -15.1(3) . . . . ?
C18 C13 C14 P2 160.5(2) . . . . ?
C27 P2 C14 C15 -34.5(3) . . . . ?
C30 P2 C14 C15 73.7(3) . . . . ?
Rh1 P2 C14 C15 177.4(2) . . . . ?
C27 P2 C14 C13 153.7(2) . . . . ?
C30 P2 C14 C13 -98.1(2) . . . . ?
Rh1 P2 C14 C13 5.6(2) . . . . ?
N1 C13 C18 C17 -176.4(3) . . . . ?
C14 C13 C18 C17 8.3(4) . . . . ?
C13 C18 C17 C16 0.9(5) . . . . ?
C15 C16 C17 C18 -6.6(4) . . . . ?
C20 C16 C17 C18 176.2(3) . . . . ?
C8 P1 C21 C22 58.7(2) . . . . ?
C24 P1 C21 C22 166.8(2) . . . . ?
Rh1 P1 C21 C22 -61.6(2) . . . . ?
C8 P1 C21 C23 -177.8(2) . . . . ?
C24 P1 C21 C23 -69.7(2) . . . . ?
Rh1 P1 C21 C23 61.9(2) . . . . ?
C8 P1 C24 C25 -42.5(2) . . . . ?
C21 P1 C24 C25 -154.2(2) . . . . ?
Rh1 P1 C24 C25 65.4(2) . . . . ?
C8 P1 C24 C26 80.5(2) . . . . ?
C21 P1 C24 C26 -31.2(3) . . . . ?
Rh1 P1 C24 C26 -171.55(19) . . . . ?
C14 P2 C30 C32 63.1(2) . . . . ?
C27 P2 C30 C32 173.3(2) . . . . ?
Rh1 P2 C30 C32 -41.4(2) . . . . ?
C14 P2 C30 C31 -61.1(3) . . . . ?
C27 P2 C30 C31 49.2(3) . . . . ?
Rh1 P2 C30 C31 -165.6(2) . . . . ?
C14 P2 C27 C29 -72.2(2) . . . . ?
C30 P2 C27 C29 178.8(2) . . . . ?
Rh1 P2 C27 C29 56.5(3) . . . . ?
C14 P2 C27 C28 161.7(2) . . . . ?
C30 P2 C27 C28 52.7(2) . . . . ?
Rh1 P2 C27 C28 -69.6(3) . . . . ?
C33 C38 C37 C36 -0.6(5) . . . . ?
C38 C37 C36 C35 -0.8(5) . . . . ?
C37 C36 C35 C34 1.1(5) . . . . ?
C36 C35 C34 C33 -0.2(5) . . . . ?
C35 C34 C33 C38 -1.1(4) . . . . ?
C35 C34 C33 Rh2 172.4(2) . . . . ?
C37 C38 C33 C34 1.4(4) . . . . ?
C37 C38 C33 Rh2 -172.8(2) . . . . ?
C45 N2 C39 C44 20.0(4) . . . . ?
Rh2 N2 C39 C44 -162.9(2) . . . . ?
C45 N2 C39 C40 -162.6(3) . . . . ?
Rh2 N2 C39 C40 14.5(3) . . . . ?
N2 C39 C40 C41 173.6(3) . . . . ?
C44 C39 C40 C41 -8.8(4) . . . . ?
N2 C39 C40 P3 -12.0(3) . . . . ?
C44 C39 C40 P3 165.6(2) . . . . ?
C56 P3 C40 C41 -33.3(3) . . . . ?
C53 P3 C40 C41 72.7(3) . . . . ?
Rh2 P3 C40 C41 178.6(2) . . . . ?
C56 P3 C40 C39 152.5(2) . . . . ?
C53 P3 C40 C39 -101.5(2) . . . . ?
Rh2 P3 C40 C39 4.4(2) . . . . ?
C39 C40 C41 C42 3.1(5) . . . . ?
P3 C40 C41 C42 -170.8(2) . . . . ?
C40 C41 C42 C43 4.0(5) . . . . ?
C40 C41 C42 C51 -177.5(3) . . . . ?
C41 C42 C43 C44 -5.2(5) . . . . ?
C51 C42 C43 C44 176.3(3) . . . . ?
C42 C43 C44 C39 -0.8(5) . . . . ?
N2 C39 C44 C43 -174.8(3) . . . . ?
C40 C39 C44 C43 7.7(4) . . . . ?
C39 N2 C45 C50 26.0(4) . . . . ?
Rh2 N2 C45 C50 -151.1(2) . . . . ?
C39 N2 C45 C46 -160.4(3) . . . . ?
Rh2 N2 C45 C46 22.5(3) . . . . ?
N2 C45 C46 C47 -178.3(2) . . . . ?
C50 C45 C46 C47 -4.2(4) . . . . ?
N2 C45 C46 P4 -1.5(3) . . . . ?
C50 C45 C46 P4 172.6(2) . . . . ?
C62 P4 C46 C47 25.0(3) . . . . ?
C59 P4 C46 C47 -85.0(3) . . . . ?
Rh2 P4 C46 C47 160.4(2) . . . . ?
C62 P4 C46 C45 -151.7(2) . . . . ?
C59 P4 C46 C45 98.3(2) . . . . ?
Rh2 P4 C46 C45 -16.3(2) . . . . ?
C45 C46 C47 C48 2.2(4) . . . . ?
P4 C46 C47 C48 -174.3(2) . . . . ?
C46 C47 C48 C49 1.3(4) . . . . ?
C46 C47 C48 C52 179.4(3) . . . . ?
N2 C45 C50 C49 176.5(3) . . . . ?
C46 C45 C50 C49 2.9(4) . . . . ?
C45 C50 C49 C48 0.5(5) . . . . ?
C47 C48 C49 C50 -2.6(4) . . . . ?
C52 C48 C49 C50 179.3(3) . . . . ?
C40 P3 C53 C54 62.0(3) . . . . ?
C56 P3 C53 C54 175.7(3) . . . . ?
Rh2 P3 C53 C54 -43.8(2) . . . . ?
C40 P3 C53 C55 -64.3(3) . . . . ?
C56 P3 C53 C55 49.4(3) . . . . ?
Rh2 P3 C53 C55 -170.1(3) . . . . ?
C40 P3 C56 C58 -67.4(3) . . . . ?
C53 P3 C56 C58 -176.2(3) . . . . ?
Rh2 P3 C56 C58 65.6(4) . . . . ?
C40 P3 C56 C57 170.4(3) . . . . ?
C53 P3 C56 C57 61.7(4) . . . . ?
Rh2 P3 C56 C57 -56.5(4) . . . . ?

_refine_diff_density_max         1.896
_refine_diff_density_min         -0.682
_refine_diff_density_rms         0.094



_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: pentane'
_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cjp1126
_database_code_depnum_ccdc_archive 'CCDC 1537397'
_audit_update_record             
;
2017-03-11 deposited with the CCDC.
2017-05-23 downloaded from the CCDC.
;
_vrf_THETM01_cjp1126             
;
PROBLEM: The value of sine(theta_max)/wavelength is less than 0.575
RESPONSE: Data was collected with Copper radiation near the resolution 
limit of the instrument
;
_vrf_PLAT029_cjp1126             
;
PROBLEM: _diffrn_measured_fraction_theta_full value Low .      0.952 Note  
RESPONSE: Data was collected with Copper radiation near the resolution 
limit of the instrument
;
_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        '[(PNP)Rh(H)]2[?-ZnCl4]'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C57 H92 Cl4 N2 P4 Rh2 Zn'
_chemical_formula_weight         1342.19

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn -1.5491 0.6778 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.5314(3)
_cell_length_b                   26.3935(7)
_cell_length_c                   23.9279(8)
_cell_angle_alpha                90
_cell_angle_beta                 92.463(2)
_cell_angle_gamma                90
_cell_volume                     6644.9(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    110(2)
_cell_measurement_reflns_used    9990
_cell_measurement_theta_min      4.987
_cell_measurement_theta_max      116.080

_exptl_crystal_description       block
_exptl_crystal_colour            purple
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.342
_exptl_crystal_F_000             2784
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.110
_exptl_absorpt_coefficient_mu    7.037
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6035
_exptl_absorpt_correction_T_max  0.7514
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      110(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            64176
_diffrn_reflns_av_unetI/netI     0.0347
_diffrn_reflns_av_R_equivalents  0.0519
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.494
_diffrn_reflns_theta_max         58.202
_diffrn_reflns_theta_full        58.202
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measured_fraction_theta_full 0.952
_diffrn_reflns_Laue_measured_fraction_max 0.952
_diffrn_reflns_Laue_measured_fraction_full 0.952
_diffrn_reflns_point_group_measured_fraction_max 0.952
_diffrn_reflns_point_group_measured_fraction_full 0.952
_reflns_number_total             8887
_reflns_number_gt                7444
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ', SQUEEZE'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0393P)²+36.4091P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8887
_refine_ls_number_parameters     653
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0618
_refine_ls_R_factor_gt           0.0466
_refine_ls_wR_factor_ref         0.1137
_refine_ls_wR_factor_gt          0.1043
_refine_ls_goodness_of_fit_ref   1.099
_refine_ls_restrained_S_all      1.099
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.29307(4) 0.27198(2) 0.43129(2) 0.02035(13) Uani 1 1 d . . . . .
Rh2 Rh -0.02132(4) 0.44507(2) 0.28668(2) 0.01998(13) Uani 1 1 d . . . . .
Zn1 Zn 0.17675(7) 0.37454(3) 0.36607(4) 0.0242(2) Uani 1 1 d . . . . .
Cl1 Cl 0.09692(13) 0.32115(5) 0.43220(6) 0.0236(3) Uani 1 1 d . . . . .
Cl2 Cl 0.38109(13) 0.34900(5) 0.37642(7) 0.0258(3) Uani 1 1 d . . . . .
Cl3 Cl 0.05979(13) 0.35902(5) 0.28372(6) 0.0244(3) Uani 1 1 d . . . . .
Cl4 Cl 0.15079(14) 0.45871(5) 0.36705(7) 0.0265(3) Uani 1 1 d . . . . .
P1 P 0.36898(15) 0.29603(6) 0.51911(7) 0.0230(3) Uani 1 1 d . . . . .
P2 P 0.24940(14) 0.22107(5) 0.35431(7) 0.0212(3) Uani 1 1 d . . . . .
P3 P -0.19231(14) 0.43166(5) 0.34258(7) 0.0222(4) Uani 1 1 d . . . . .
P4 P 0.09099(14) 0.47769(5) 0.21385(7) 0.0210(3) Uani 1 1 d . . . . .
N1 N 0.4625(5) 0.23456(17) 0.4320(2) 0.0241(12) Uani 1 1 d . . . . .
N2 N -0.0769(4) 0.51826(17) 0.2912(2) 0.0214(11) Uani 1 1 d . . . . .
C1 C 0.5638(6) 0.2557(2) 0.4641(3) 0.0224(14) Uani 1 1 d . . . . .
C2 C 0.6925(6) 0.2484(2) 0.4518(3) 0.0246(14) Uani 1 1 d . . . . .
H2 H 0.713997 0.227217 0.421532 0.030 Uiso 1 1 calc R U . . .
C3 C 0.7867(6) 0.2720(2) 0.4840(3) 0.0274(15) Uani 1 1 d . . . . .
H3 H 0.872881 0.266403 0.475401 0.033 Uiso 1 1 calc R U . . .
C4 C 0.7608(6) 0.3034(2) 0.5279(3) 0.0262(14) Uani 1 1 d . . . . .
C5 C 0.6357(6) 0.3109(2) 0.5403(3) 0.0246(14) Uani 1 1 d . . . . .
H5 H 0.616278 0.332123 0.570851 0.030 Uiso 1 1 calc R U . . .
C6 C 0.5369(6) 0.2880(2) 0.5088(3) 0.0253(14) Uani 1 1 d . . . . .
C7 C 0.4661(6) 0.1869(2) 0.4078(3) 0.0239(14) Uani 1 1 d . . . . .
C8 C 0.5575(6) 0.1496(2) 0.4218(3) 0.0253(14) Uani 1 1 d . . . . .
H8 H 0.622194 0.156864 0.449523 0.030 Uiso 1 1 calc R U . . .
C9 C 0.5554(6) 0.1028(2) 0.3961(3) 0.0269(15) Uani 1 1 d . . . . .
H9 H 0.619653 0.078886 0.406306 0.032 Uiso 1 1 calc R U . . .
C10 C 0.4627(6) 0.0894(2) 0.3558(3) 0.0259(15) Uani 1 1 d . . . . .
C11 C 0.3692(6) 0.1250(2) 0.3431(3) 0.0228(14) Uani 1 1 d . . . . .
H11 H 0.302426 0.116608 0.316716 0.027 Uiso 1 1 calc R U . . .
C12 C 0.3704(6) 0.1731(2) 0.3681(3) 0.0235(14) Uani 1 1 d . . . . .
C13 C 0.8678(6) 0.3311(3) 0.5603(3) 0.0389(17) Uani 1 1 d . . . . .
H13A H 0.909228 0.354684 0.535222 0.058 Uiso 1 1 calc R U . . .
H13B H 0.930206 0.306391 0.574994 0.058 Uiso 1 1 calc R U . . .
H13C H 0.832713 0.349912 0.591337 0.058 Uiso 1 1 calc R U . . .
C14 C 0.4627(6) 0.0384(2) 0.3276(3) 0.0335(16) Uani 1 1 d . . . . .
H14A H 0.375521 0.029289 0.315587 0.050 Uiso 1 1 calc R U . . .
H14B H 0.496990 0.012922 0.353860 0.050 Uiso 1 1 calc R U . . .
H14C H 0.515530 0.039921 0.294883 0.050 Uiso 1 1 calc R U . . .
C15 C 0.3354(7) 0.2504(2) 0.5762(3) 0.0344(16) Uani 1 1 d . . . . .
H15 H 0.360016 0.266790 0.612706 0.041 Uiso 1 1 calc R U . . .
C16 C 0.4098(8) 0.2028(3) 0.5718(4) 0.066(3) Uani 1 1 d . . . . .
H16A H 0.384181 0.185114 0.537136 0.099 Uiso 1 1 calc R U . . .
H16B H 0.393795 0.180915 0.603905 0.099 Uiso 1 1 calc R U . . .
H16C H 0.500636 0.210864 0.571652 0.099 Uiso 1 1 calc R U . . .
C17 C 0.1932(7) 0.2365(3) 0.5768(4) 0.052(2) Uani 1 1 d . . . . .
H17A H 0.142923 0.267450 0.581088 0.078 Uiso 1 1 calc R U . . .
H17B H 0.179035 0.213633 0.608173 0.078 Uiso 1 1 calc R U . . .
H17C H 0.167216 0.219783 0.541617 0.078 Uiso 1 1 calc R U . . .
C18 C 0.3505(6) 0.3586(2) 0.5521(3) 0.0280(15) Uani 1 1 d . . . . .
H18 H 0.410506 0.360036 0.585649 0.034 Uiso 1 1 calc R U . . .
C19 C 0.3857(6) 0.4019(2) 0.5130(3) 0.0317(16) Uani 1 1 d . . . . .
H19A H 0.468869 0.395029 0.497727 0.048 Uiso 1 1 calc R U . . .
H19B H 0.389376 0.433831 0.533899 0.048 Uiso 1 1 calc R U . . .
H19C H 0.321436 0.404519 0.482263 0.048 Uiso 1 1 calc R U . . .
C20 C 0.2158(6) 0.3668(3) 0.5725(3) 0.0329(16) Uani 1 1 d . . . . .
H20A H 0.153934 0.362466 0.541087 0.049 Uiso 1 1 calc R U . . .
H20B H 0.208691 0.401052 0.587750 0.049 Uiso 1 1 calc R U . . .
H20C H 0.198724 0.341922 0.601698 0.049 Uiso 1 1 calc R U . . .
C21 C 0.2772(6) 0.2465(2) 0.2836(3) 0.0265(15) Uani 1 1 d . . . . .
H21 H 0.233787 0.280182 0.280810 0.032 Uiso 1 1 calc R U . . .
C22 C 0.4180(6) 0.2560(2) 0.2774(3) 0.0359(17) Uani 1 1 d . . . . .
H22A H 0.462754 0.223537 0.275865 0.054 Uiso 1 1 calc R U . . .
H22B H 0.451645 0.275644 0.309505 0.054 Uiso 1 1 calc R U . . .
H22C H 0.430396 0.275003 0.242881 0.054 Uiso 1 1 calc R U . . .
C23 C 0.2250(7) 0.2144(2) 0.2345(3) 0.0330(16) Uani 1 1 d . . . . .
H23A H 0.239431 0.231954 0.199302 0.049 Uiso 1 1 calc R U . . .
H23B H 0.133597 0.209066 0.238165 0.049 Uiso 1 1 calc R U . . .
H23C H 0.268455 0.181550 0.234766 0.049 Uiso 1 1 calc R U . . .
C24 C 0.0951(6) 0.1875(2) 0.3485(3) 0.0305(15) Uani 1 1 d . . . . .
H24 H 0.099326 0.162368 0.317320 0.037 Uiso 1 1 calc R U . . .
C25 C 0.0684(6) 0.1588(3) 0.4014(3) 0.0401(18) Uani 1 1 d . . . . .
H25A H -0.008992 0.138519 0.395310 0.060 Uiso 1 1 calc R U . . .
H25B H 0.056613 0.182849 0.431905 0.060 Uiso 1 1 calc R U . . .
H25C H 0.140090 0.136375 0.411171 0.060 Uiso 1 1 calc R U . . .
C26 C -0.0124(6) 0.2247(2) 0.3334(3) 0.0367(17) Uani 1 1 d . . . . .
H26A H 0.003095 0.240720 0.297410 0.055 Uiso 1 1 calc R U . . .
H26B H -0.015735 0.250825 0.362478 0.055 Uiso 1 1 calc R U . . .
H26C H -0.093497 0.206475 0.330828 0.055 Uiso 1 1 calc R U . . .
C27 C -0.2744(6) 0.4915(2) 0.3304(3) 0.0228(14) Uani 1 1 d . . . . .
C28 C -0.2005(6) 0.5293(2) 0.3062(3) 0.0224(14) Uani 1 1 d . . . . .
C29 C -0.2610(6) 0.5763(2) 0.2950(3) 0.0212(13) Uani 1 1 d . . . . .
H29 H -0.216651 0.602295 0.276545 0.025 Uiso 1 1 calc R U . . .
C30 C -0.3842(6) 0.5848(2) 0.3108(3) 0.0242(14) Uani 1 1 d . . . . .
H30 H -0.421406 0.617000 0.303339 0.029 Uiso 1 1 calc R U . . .
C31 C -0.4558(5) 0.5482(2) 0.3370(3) 0.0239(14) Uani 1 1 d . . . . .
C32 C -0.3986(6) 0.5012(2) 0.3453(3) 0.0240(14) Uani 1 1 d . . . . .
H32 H -0.445824 0.474764 0.361654 0.029 Uiso 1 1 calc R U . . .
C33 C 0.1030(6) 0.5421(2) 0.2386(3) 0.0225(14) Uani 1 1 d . . . . .
C34 C 0.0110(5) 0.5548(2) 0.2770(2) 0.0198(13) Uani 1 1 d . . . . .
C35 C 0.0188(6) 0.6041(2) 0.3010(3) 0.0244(14) Uani 1 1 d . . . . .
H35 H -0.040184 0.613994 0.327926 0.029 Uiso 1 1 calc R U . . .
C36 C 0.1117(6) 0.6376(2) 0.2855(3) 0.0257(14) Uani 1 1 d . . . . .
H36 H 0.113687 0.670451 0.301651 0.031 Uiso 1 1 calc R U . . .
C37 C 0.2023(6) 0.6254(2) 0.2472(3) 0.0240(14) Uani 1 1 d . . . . .
C38 C 0.1959(6) 0.5771(2) 0.2240(3) 0.0242(14) Uani 1 1 d . . . . .
H38 H 0.256181 0.567529 0.197521 0.029 Uiso 1 1 calc R U . . .
C39 C -0.5873(6) 0.5593(2) 0.3563(3) 0.0286(15) Uani 1 1 d . . . . .
H39A H -0.632902 0.580648 0.328562 0.043 Uiso 1 1 calc R U . . .
H39B H -0.581044 0.577063 0.392292 0.043 Uiso 1 1 calc R U . . .
H39C H -0.633613 0.527434 0.360605 0.043 Uiso 1 1 calc R U . . .
C40 C 0.3070(6) 0.6623(2) 0.2335(3) 0.0314(16) Uani 1 1 d . . . . .
H40A H 0.383560 0.654665 0.256688 0.047 Uiso 1 1 calc R U . . .
H40B H 0.279052 0.696950 0.241082 0.047 Uiso 1 1 calc R U . . .
H40C H 0.325837 0.659124 0.193914 0.047 Uiso 1 1 calc R U . . .
C41 C -0.1743(6) 0.4258(2) 0.4198(3) 0.0289(15) Uani 1 1 d . . . . .
H41 H -0.111483 0.398131 0.428243 0.035 Uiso 1 1 calc R U . . .
C42 C -0.2966(6) 0.4125(3) 0.4489(3) 0.0374(17) Uani 1 1 d . . . . .
H42A H -0.361022 0.438461 0.440448 0.056 Uiso 1 1 calc R U . . .
H42B H -0.279030 0.410917 0.489436 0.056 Uiso 1 1 calc R U . . .
H42C H -0.327968 0.379492 0.435515 0.056 Uiso 1 1 calc R U . . .
C43 C -0.1193(6) 0.4748(3) 0.4451(3) 0.0381(17) Uani 1 1 d . . . . .
H43A H -0.044846 0.485077 0.424635 0.057 Uiso 1 1 calc R U . . .
H43B H -0.094134 0.469125 0.484479 0.057 Uiso 1 1 calc R U . . .
H43C H -0.183744 0.501574 0.442295 0.057 Uiso 1 1 calc R U . . .
C44 C -0.3059(6) 0.3817(2) 0.3197(3) 0.0289(15) Uani 1 1 d . . . . .
H44 H -0.385555 0.386664 0.340333 0.035 Uiso 1 1 calc R U . . .
C45 C -0.2529(6) 0.3290(2) 0.3347(3) 0.0382(18) Uani 1 1 d . . . . .
H45A H -0.316931 0.303210 0.324847 0.057 Uiso 1 1 calc R U . . .
H45B H -0.231731 0.327442 0.374988 0.057 Uiso 1 1 calc R U . . .
H45C H -0.176251 0.322727 0.313982 0.057 Uiso 1 1 calc R U . . .
C46 C -0.3401(6) 0.3853(2) 0.2576(3) 0.0346(17) Uani 1 1 d . . . . .
H46A H -0.268594 0.373175 0.236315 0.052 Uiso 1 1 calc R U . . .
H46B H -0.358666 0.420587 0.247624 0.052 Uiso 1 1 calc R U . . .
H46C H -0.415074 0.364310 0.248671 0.052 Uiso 1 1 calc R U . . .
C47 C 0.2513(6) 0.4561(2) 0.1961(3) 0.0275(15) Uani 1 1 d . . . . .
H47 H 0.287331 0.481827 0.170437 0.033 Uiso 1 1 calc R U . . .
C48 C 0.3399(6) 0.4524(2) 0.2478(3) 0.0320(16) Uani 1 1 d . . . . .
H48A H 0.427341 0.447594 0.236379 0.048 Uiso 1 1 calc R U . . .
H48B H 0.314780 0.423631 0.270645 0.048 Uiso 1 1 calc R U . . .
H48C H 0.334672 0.483730 0.269610 0.048 Uiso 1 1 calc R U . . .
C49 C 0.2436(6) 0.4053(2) 0.1648(3) 0.0338(17) Uani 1 1 d . . . . .
H49A H 0.188141 0.408853 0.131091 0.051 Uiso 1 1 calc R U . . .
H49B H 0.208961 0.379335 0.189184 0.051 Uiso 1 1 calc R U . . .
H49C H 0.328848 0.395193 0.154195 0.051 Uiso 1 1 calc R U . . .
C51 C 0.0032(6) 0.4824(2) 0.1457(3) 0.0292(15) Uani 1 1 d . . . . .
H51 H -0.013160 0.447085 0.132093 0.035 Uiso 1 1 calc R U . . .
C52 C 0.0769(6) 0.5098(3) 0.1007(3) 0.0354(16) Uani 1 1 d . . . . .
H52A H 0.156152 0.491581 0.094523 0.053 Uiso 1 1 calc R U . . .
H52B H 0.096475 0.544432 0.113041 0.053 Uiso 1 1 calc R U . . .
H52C H 0.025036 0.510891 0.065673 0.053 Uiso 1 1 calc R U . . .
C53 C -0.1260(6) 0.5079(3) 0.1514(3) 0.0368(17) Uani 1 1 d . . . . .
H53A H -0.173797 0.506733 0.115369 0.055 Uiso 1 1 calc R U . . .
H53B H -0.113350 0.543245 0.162822 0.055 Uiso 1 1 calc R U . . .
H53C H -0.173514 0.489994 0.179657 0.055 Uiso 1 1 calc R U . . .
C55 C 0.1436(11) 0.6085(4) 0.9785(4) 0.085(3) Uani 1 1 d . . . . .
H55A H 0.061087 0.621874 0.964855 0.127 Uiso 1 1 calc R U . . .
H55B H 0.171666 0.626664 1.012563 0.127 Uiso 1 1 calc R U . . .
H55C H 0.135411 0.572352 0.986781 0.127 Uiso 1 1 calc R U . . .
C56 C 0.2407(12) 0.6159(4) 0.9338(5) 0.094(4) Uani 1 1 d . . . . .
H56A H 0.326297 0.615049 0.952653 0.112 Uiso 1 1 calc R U . . .
H56B H 0.234817 0.586305 0.908421 0.112 Uiso 1 1 calc R U . . .
C57 C 0.2324(12) 0.6634(4) 0.8981(5) 0.088(3) Uani 1 1 d . . . . .
H57A H 0.246695 0.692949 0.922997 0.106 Uiso 1 1 calc R U . . .
H57B H 0.303331 0.662542 0.872201 0.106 Uiso 1 1 calc R U . . .
C58 C 0.1165(11) 0.6720(4) 0.8653(6) 0.100(4) Uani 1 1 d . . . . .
H58A H 0.045570 0.676673 0.890586 0.120 Uiso 1 1 calc R U . . .
H58B H 0.097384 0.641852 0.841722 0.120 Uiso 1 1 calc R U . . .
C59 C 0.1259(15) 0.7166(4) 0.8294(5) 0.123(6) Uani 1 1 d . . . . .
H59A H 0.213890 0.720580 0.818274 0.184 Uiso 1 1 calc R U . . .
H59B H 0.100299 0.746811 0.849906 0.184 Uiso 1 1 calc R U . . .
H59C H 0.069952 0.712379 0.795922 0.184 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N1 2.038(5) . ?
Rh1 P1 2.3050(17) . ?
Rh1 P2 2.3104(16) . ?
Rh1 Cl1 2.4403(14) . ?
Rh1 Cl2 2.6114(15) . ?
Rh2 N2 2.023(4) . ?
Rh2 P4 2.3141(16) . ?
Rh2 P3 2.3160(16) . ?
Rh2 Cl3 2.4287(14) . ?
Rh2 Cl4 2.6102(16) . ?
Zn1 Cl4 2.2385(15) . ?
Zn1 Cl2 2.2585(16) . ?
Zn1 Cl1 2.3045(16) . ?
Zn1 Cl3 2.3151(17) . ?
P1 C6 1.808(6) . ?
P1 C18 1.846(6) . ?
P1 C15 1.866(6) . ?
P2 C12 1.817(6) . ?
P2 C24 1.851(6) . ?
P2 C21 1.855(6) . ?
P3 C27 1.818(6) . ?
P3 C44 1.847(6) . ?
P3 C41 1.855(7) . ?
P4 C33 1.804(6) . ?
P4 C51 1.845(7) . ?
P4 C47 1.848(6) . ?
N1 C7 1.385(8) . ?
N1 C1 1.404(8) . ?
N2 C34 1.390(7) . ?
N2 C28 1.396(8) . ?
C1 C6 1.406(9) . ?
C1 C2 1.412(8) . ?
C2 C3 1.378(9) . ?
C2 H2 0.9500 . ?
C3 C4 1.376(9) . ?
C3 H3 0.9500 . ?
C4 C5 1.377(9) . ?
C4 C13 1.526(9) . ?
C5 C6 1.397(9) . ?
C5 H5 0.9500 . ?
C7 C12 1.405(9) . ?
C7 C8 1.406(8) . ?
C8 C9 1.381(9) . ?
C8 H8 0.9500 . ?
C9 C10 1.388(9) . ?
C9 H9 0.9500 . ?
C10 C11 1.385(8) . ?
C10 C14 1.506(8) . ?
C11 C12 1.403(8) . ?
C11 H11 0.9500 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.487(10) . ?
C15 C17 1.542(10) . ?
C15 H15 1.0000 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C19 1.533(9) . ?
C18 C20 1.535(8) . ?
C18 H18 1.0000 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.517(9) . ?
C21 C23 1.531(9) . ?
C21 H21 1.0000 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 C25 1.512(9) . ?
C24 C26 1.530(9) . ?
C24 H24 1.0000 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C32 1.394(8) . ?
C27 C28 1.406(8) . ?
C28 C29 1.415(8) . ?
C29 C30 1.384(8) . ?
C29 H29 0.9500 . ?
C30 C31 1.390(8) . ?
C30 H30 0.9500 . ?
C31 C32 1.391(8) . ?
C31 C39 1.508(8) . ?
C32 H32 0.9500 . ?
C33 C38 1.400(8) . ?
C33 C34 1.404(8) . ?
C34 C35 1.422(8) . ?
C35 C36 1.382(8) . ?
C35 H35 0.9500 . ?
C36 C37 1.388(9) . ?
C36 H36 0.9500 . ?
C37 C38 1.391(8) . ?
C37 C40 1.518(8) . ?
C38 H38 0.9500 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C43 1.531(9) . ?
C41 C42 1.532(9) . ?
C41 H41 1.0000 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 C46 1.517(9) . ?
C44 C45 1.536(8) . ?
C44 H44 1.0000 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 C48 1.520(9) . ?
C47 C49 1.538(9) . ?
C47 H47 1.0000 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C51 C53 1.529(9) . ?
C51 C52 1.535(9) . ?
C51 H51 1.0000 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C55 C56 1.523(14) . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 C57 1.519(14) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C57 C58 1.441(14) . ?
C57 H57A 0.9900 . ?
C57 H57B 0.9900 . ?
C58 C59 1.464(15) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Rh1 P1 81.77(15) . . ?
N1 Rh1 P2 82.46(15) . . ?
P1 Rh1 P2 159.45(6) . . ?
N1 Rh1 Cl1 176.71(14) . . ?
P1 Rh1 Cl1 96.09(5) . . ?
P2 Rh1 Cl1 100.18(5) . . ?
N1 Rh1 Cl2 92.97(14) . . ?
P1 Rh1 Cl2 97.32(5) . . ?
P2 Rh1 Cl2 96.58(5) . . ?
Cl1 Rh1 Cl2 84.81(5) . . ?
N2 Rh2 P4 81.00(14) . . ?
N2 Rh2 P3 83.17(14) . . ?
P4 Rh2 P3 157.98(6) . . ?
N2 Rh2 Cl3 176.04(15) . . ?
P4 Rh2 Cl3 97.71(5) . . ?
P3 Rh2 Cl3 99.04(5) . . ?
N2 Rh2 Cl4 91.26(15) . . ?
P4 Rh2 Cl4 98.18(5) . . ?
P3 Rh2 Cl4 97.37(5) . . ?
Cl3 Rh2 Cl4 85.21(5) . . ?
Cl4 Zn1 Cl2 114.29(6) . . ?
Cl4 Zn1 Cl1 123.46(6) . . ?
Cl2 Zn1 Cl1 96.67(6) . . ?
Cl4 Zn1 Cl3 97.11(6) . . ?
Cl2 Zn1 Cl3 120.67(6) . . ?
Cl1 Zn1 Cl3 106.25(6) . . ?
Zn1 Cl1 Rh1 89.15(5) . . ?
Zn1 Cl2 Rh1 86.00(5) . . ?
Zn1 Cl3 Rh2 89.12(5) . . ?
Zn1 Cl4 Rh2 86.37(5) . . ?
C6 P1 C18 106.6(3) . . ?
C6 P1 C15 104.0(3) . . ?
C18 P1 C15 103.8(3) . . ?
C6 P1 Rh1 98.4(2) . . ?
C18 P1 Rh1 126.7(2) . . ?
C15 P1 Rh1 114.8(2) . . ?
C12 P2 C24 106.7(3) . . ?
C12 P2 C21 106.3(3) . . ?
C24 P2 C21 106.1(3) . . ?
C12 P2 Rh1 98.5(2) . . ?
C24 P2 Rh1 118.9(2) . . ?
C21 P2 Rh1 118.9(2) . . ?
C27 P3 C44 106.0(3) . . ?
C27 P3 C41 105.0(3) . . ?
C44 P3 C41 105.8(3) . . ?
C27 P3 Rh2 98.7(2) . . ?
C44 P3 Rh2 116.6(2) . . ?
C41 P3 Rh2 122.6(2) . . ?
C33 P4 C51 104.6(3) . . ?
C33 P4 C47 108.3(3) . . ?
C51 P4 C47 104.2(3) . . ?
C33 P4 Rh2 97.7(2) . . ?
C51 P4 Rh2 116.0(2) . . ?
C47 P4 Rh2 124.1(2) . . ?
C7 N1 C1 123.7(5) . . ?
C7 N1 Rh1 118.5(4) . . ?
C1 N1 Rh1 117.2(4) . . ?
C34 N2 C28 123.8(5) . . ?
C34 N2 Rh2 116.9(4) . . ?
C28 N2 Rh2 119.2(4) . . ?
N1 C1 C6 118.9(5) . . ?
N1 C1 C2 123.1(6) . . ?
C6 C1 C2 117.9(6) . . ?
C3 C2 C1 119.8(6) . . ?
C3 C2 H2 120.1 . . ?
C1 C2 H2 120.1 . . ?
C4 C3 C2 122.5(6) . . ?
C4 C3 H3 118.8 . . ?
C2 C3 H3 118.8 . . ?
C3 C4 C5 118.3(6) . . ?
C3 C4 C13 120.6(6) . . ?
C5 C4 C13 121.0(6) . . ?
C4 C5 C6 121.3(6) . . ?
C4 C5 H5 119.4 . . ?
C6 C5 H5 119.4 . . ?
C5 C6 C1 120.2(6) . . ?
C5 C6 P1 125.9(5) . . ?
C1 C6 P1 113.9(5) . . ?
N1 C7 C12 119.1(5) . . ?
N1 C7 C8 124.6(6) . . ?
C12 C7 C8 116.3(5) . . ?
C9 C8 C7 121.5(6) . . ?
C9 C8 H8 119.2 . . ?
C7 C8 H8 119.2 . . ?
C8 C9 C10 122.3(6) . . ?
C8 C9 H9 118.8 . . ?
C10 C9 H9 118.8 . . ?
C11 C10 C9 116.9(6) . . ?
C11 C10 C14 121.4(6) . . ?
C9 C10 C14 121.7(6) . . ?
C10 C11 C12 121.7(6) . . ?
C10 C11 H11 119.1 . . ?
C12 C11 H11 119.1 . . ?
C11 C12 C7 121.1(5) . . ?
C11 C12 P2 124.1(5) . . ?
C7 C12 P2 114.8(4) . . ?
C4 C13 H13A 109.5 . . ?
C4 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C4 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C10 C14 H14A 109.5 . . ?
C10 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C10 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 C17 108.4(6) . . ?
C16 C15 P1 112.2(5) . . ?
C17 C15 P1 112.0(5) . . ?
C16 C15 H15 108.0 . . ?
C17 C15 H15 108.0 . . ?
P1 C15 H15 108.0 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C18 C20 110.0(5) . . ?
C19 C18 P1 111.9(4) . . ?
C20 C18 P1 112.1(4) . . ?
C19 C18 H18 107.5 . . ?
C20 C18 H18 107.5 . . ?
P1 C18 H18 107.5 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 C23 109.7(5) . . ?
C22 C21 P2 110.0(5) . . ?
C23 C21 P2 115.6(4) . . ?
C22 C21 H21 107.0 . . ?
C23 C21 H21 107.0 . . ?
P2 C21 H21 107.0 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C25 C24 C26 110.8(6) . . ?
C25 C24 P2 111.8(5) . . ?
C26 C24 P2 110.4(4) . . ?
C25 C24 H24 107.9 . . ?
C26 C24 H24 107.9 . . ?
P2 C24 H24 107.9 . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C32 C27 C28 121.2(5) . . ?
C32 C27 P3 124.3(4) . . ?
C28 C27 P3 114.5(4) . . ?
N2 C28 C27 119.8(5) . . ?
N2 C28 C29 123.5(5) . . ?
C27 C28 C29 116.6(5) . . ?
C30 C29 C28 120.7(5) . . ?
C30 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
C29 C30 C31 122.9(5) . . ?
C29 C30 H30 118.5 . . ?
C31 C30 H30 118.5 . . ?
C30 C31 C32 116.4(5) . . ?
C30 C31 C39 121.8(5) . . ?
C32 C31 C39 121.8(5) . . ?
C31 C32 C27 122.2(5) . . ?
C31 C32 H32 118.9 . . ?
C27 C32 H32 118.9 . . ?
C38 C33 C34 121.0(5) . . ?
C38 C33 P4 125.4(5) . . ?
C34 C33 P4 113.6(4) . . ?
N2 C34 C33 118.6(5) . . ?
N2 C34 C35 124.3(5) . . ?
C33 C34 C35 117.0(5) . . ?
C36 C35 C34 120.3(6) . . ?
C36 C35 H35 119.8 . . ?
C34 C35 H35 119.8 . . ?
C35 C36 C37 122.9(5) . . ?
C35 C36 H36 118.5 . . ?
C37 C36 H36 118.5 . . ?
C36 C37 C38 116.9(5) . . ?
C36 C37 C40 121.3(5) . . ?
C38 C37 C40 121.7(5) . . ?
C37 C38 C33 121.8(6) . . ?
C37 C38 H38 119.1 . . ?
C33 C38 H38 119.1 . . ?
C31 C39 H39A 109.5 . . ?
C31 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C31 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C37 C40 H40A 109.5 . . ?
C37 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C37 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C43 C41 C42 109.0(5) . . ?
C43 C41 P3 110.1(4) . . ?
C42 C41 P3 114.8(5) . . ?
C43 C41 H41 107.5 . . ?
C42 C41 H41 107.5 . . ?
P3 C41 H41 107.5 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C46 C44 C45 110.7(6) . . ?
C46 C44 P3 111.7(4) . . ?
C45 C44 P3 110.7(5) . . ?
C46 C44 H44 107.9 . . ?
C45 C44 H44 107.9 . . ?
P3 C44 H44 107.9 . . ?
C44 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C44 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C44 C46 H46A 109.5 . . ?
C44 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C44 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C48 C47 C49 111.0(5) . . ?
C48 C47 P4 111.5(4) . . ?
C49 C47 P4 110.6(4) . . ?
C48 C47 H47 107.9 . . ?
C49 C47 H47 107.9 . . ?
P4 C47 H47 107.9 . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C47 C49 H49A 109.5 . . ?
C47 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C47 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C53 C51 C52 109.5(5) . . ?
C53 C51 P4 111.4(5) . . ?
C52 C51 P4 113.8(5) . . ?
C53 C51 H51 107.3 . . ?
C52 C51 H51 107.3 . . ?
P4 C51 H51 107.3 . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C51 C53 H53A 109.5 . . ?
C51 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C51 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C56 C55 H55A 109.5 . . ?
C56 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C56 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
C57 C56 C55 118.5(11) . . ?
C57 C56 H56A 107.7 . . ?
C55 C56 H56A 107.7 . . ?
C57 C56 H56B 107.7 . . ?
C55 C56 H56B 107.7 . . ?
H56A C56 H56B 107.1 . . ?
C58 C57 C56 117.7(11) . . ?
C58 C57 H57A 107.9 . . ?
C56 C57 H57A 107.9 . . ?
C58 C57 H57B 107.9 . . ?
C56 C57 H57B 107.9 . . ?
H57A C57 H57B 107.2 . . ?
C57 C58 C59 111.7(12) . . ?
C57 C58 H58A 109.3 . . ?
C59 C58 H58A 109.3 . . ?
C57 C58 H58B 109.3 . . ?
C59 C58 H58B 109.3 . . ?
H58A C58 H58B 107.9 . . ?
C58 C59 H59A 109.5 . . ?
C58 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C58 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 N1 C1 C6 -146.9(6) . . . . ?
Rh1 N1 C1 C6 23.6(7) . . . . ?
C7 N1 C1 C2 36.8(9) . . . . ?
Rh1 N1 C1 C2 -152.7(5) . . . . ?
N1 C1 C2 C3 177.4(5) . . . . ?
C6 C1 C2 C3 1.1(9) . . . . ?
C1 C2 C3 C4 -0.6(9) . . . . ?
C2 C3 C4 C5 0.5(9) . . . . ?
C2 C3 C4 C13 -176.5(6) . . . . ?
C3 C4 C5 C6 -0.8(9) . . . . ?
C13 C4 C5 C6 176.2(6) . . . . ?
C4 C5 C6 C1 1.3(9) . . . . ?
C4 C5 C6 P1 -178.2(5) . . . . ?
N1 C1 C6 C5 -177.9(5) . . . . ?
C2 C1 C6 C5 -1.4(9) . . . . ?
N1 C1 C6 P1 1.7(7) . . . . ?
C2 C1 C6 P1 178.1(4) . . . . ?
C18 P1 C6 C5 26.4(6) . . . . ?
C15 P1 C6 C5 -82.9(6) . . . . ?
Rh1 P1 C6 C5 158.8(5) . . . . ?
C18 P1 C6 C1 -153.2(4) . . . . ?
C15 P1 C6 C1 97.6(5) . . . . ?
Rh1 P1 C6 C1 -20.7(5) . . . . ?
C1 N1 C7 C12 -168.0(6) . . . . ?
Rh1 N1 C7 C12 21.7(7) . . . . ?
C1 N1 C7 C8 14.5(9) . . . . ?
Rh1 N1 C7 C8 -155.8(5) . . . . ?
N1 C7 C8 C9 179.9(6) . . . . ?
C12 C7 C8 C9 2.3(9) . . . . ?
C7 C8 C9 C10 -0.9(9) . . . . ?
C8 C9 C10 C11 -1.4(9) . . . . ?
C8 C9 C10 C14 179.1(6) . . . . ?
C9 C10 C11 C12 2.3(9) . . . . ?
C14 C10 C11 C12 -178.2(6) . . . . ?
C10 C11 C12 C7 -0.9(9) . . . . ?
C10 C11 C12 P2 -178.8(5) . . . . ?
N1 C7 C12 C11 -179.1(5) . . . . ?
C8 C7 C12 C11 -1.4(9) . . . . ?
N1 C7 C12 P2 -1.0(7) . . . . ?
C8 C7 C12 P2 176.6(4) . . . . ?
C24 P2 C12 C11 38.9(6) . . . . ?
C21 P2 C12 C11 -74.0(6) . . . . ?
Rh1 P2 C12 C11 162.5(5) . . . . ?
C24 P2 C12 C7 -139.1(5) . . . . ?
C21 P2 C12 C7 108.0(5) . . . . ?
Rh1 P2 C12 C7 -15.5(5) . . . . ?
C6 P1 C15 C16 -36.6(7) . . . . ?
C18 P1 C15 C16 -147.9(6) . . . . ?
Rh1 P1 C15 C16 69.7(6) . . . . ?
C6 P1 C15 C17 -158.8(5) . . . . ?
C18 P1 C15 C17 89.9(5) . . . . ?
Rh1 P1 C15 C17 -52.5(6) . . . . ?
C6 P1 C18 C19 65.7(5) . . . . ?
C15 P1 C18 C19 175.1(5) . . . . ?
Rh1 P1 C18 C19 -48.7(5) . . . . ?
C6 P1 C18 C20 -170.2(5) . . . . ?
C15 P1 C18 C20 -60.8(5) . . . . ?
Rh1 P1 C18 C20 75.4(5) . . . . ?
C12 P2 C21 C22 -44.4(5) . . . . ?
C24 P2 C21 C22 -157.7(4) . . . . ?
Rh1 P2 C21 C22 65.2(4) . . . . ?
C12 P2 C21 C23 80.5(5) . . . . ?
C24 P2 C21 C23 -32.8(5) . . . . ?
Rh1 P2 C21 C23 -169.9(4) . . . . ?
C12 P2 C24 C25 59.4(5) . . . . ?
C21 P2 C24 C25 172.4(4) . . . . ?
Rh1 P2 C24 C25 -50.5(5) . . . . ?
C12 P2 C24 C26 -176.7(5) . . . . ?
C21 P2 C24 C26 -63.7(5) . . . . ?
Rh1 P2 C24 C26 73.4(5) . . . . ?
C44 P3 C27 C32 46.0(6) . . . . ?
C41 P3 C27 C32 -65.7(6) . . . . ?
Rh2 P3 C27 C32 167.0(5) . . . . ?
C44 P3 C27 C28 -136.3(5) . . . . ?
C41 P3 C27 C28 111.9(5) . . . . ?
Rh2 P3 C27 C28 -15.4(5) . . . . ?
C34 N2 C28 C27 -167.4(6) . . . . ?
Rh2 N2 C28 C27 15.0(8) . . . . ?
C34 N2 C28 C29 16.9(9) . . . . ?
Rh2 N2 C28 C29 -160.7(5) . . . . ?
C32 C27 C28 N2 -179.4(6) . . . . ?
P3 C27 C28 N2 2.9(8) . . . . ?
C32 C27 C28 C29 -3.3(9) . . . . ?
P3 C27 C28 C29 179.0(5) . . . . ?
N2 C28 C29 C30 179.8(6) . . . . ?
C27 C28 C29 C30 3.9(9) . . . . ?
C28 C29 C30 C31 -1.2(10) . . . . ?
C29 C30 C31 C32 -2.1(9) . . . . ?
C29 C30 C31 C39 176.9(6) . . . . ?
C30 C31 C32 C27 2.6(9) . . . . ?
C39 C31 C32 C27 -176.3(6) . . . . ?
C28 C27 C32 C31 0.1(10) . . . . ?
P3 C27 C32 C31 177.6(5) . . . . ?
C51 P4 C33 C38 -84.0(6) . . . . ?
C47 P4 C33 C38 26.6(7) . . . . ?
Rh2 P4 C33 C38 156.5(5) . . . . ?
C51 P4 C33 C34 98.4(5) . . . . ?
C47 P4 C33 C34 -150.9(5) . . . . ?
Rh2 P4 C33 C34 -21.1(5) . . . . ?
C28 N2 C34 C33 -149.4(6) . . . . ?
Rh2 N2 C34 C33 28.2(7) . . . . ?
C28 N2 C34 C35 33.9(9) . . . . ?
Rh2 N2 C34 C35 -148.5(5) . . . . ?
C38 C33 C34 N2 -178.2(6) . . . . ?
P4 C33 C34 N2 -0.5(7) . . . . ?
C38 C33 C34 C35 -1.3(9) . . . . ?
P4 C33 C34 C35 176.4(4) . . . . ?
N2 C34 C35 C36 178.2(6) . . . . ?
C33 C34 C35 C36 1.5(9) . . . . ?
C34 C35 C36 C37 -1.2(10) . . . . ?
C35 C36 C37 C38 0.5(10) . . . . ?
C35 C36 C37 C40 -176.8(6) . . . . ?
C36 C37 C38 C33 -0.3(9) . . . . ?
C40 C37 C38 C33 177.0(6) . . . . ?
C34 C33 C38 C37 0.8(10) . . . . ?
P4 C33 C38 C37 -176.6(5) . . . . ?
C27 P3 C41 C43 -49.4(5) . . . . ?
C44 P3 C41 C43 -161.2(4) . . . . ?
Rh2 P3 C41 C43 61.6(5) . . . . ?
C27 P3 C41 C42 74.1(5) . . . . ?
C44 P3 C41 C42 -37.8(5) . . . . ?
Rh2 P3 C41 C42 -175.0(4) . . . . ?
C27 P3 C44 C46 63.2(5) . . . . ?
C41 P3 C44 C46 174.4(4) . . . . ?
Rh2 P3 C44 C46 -45.4(5) . . . . ?
C27 P3 C44 C45 -173.0(5) . . . . ?
C41 P3 C44 C45 -61.8(5) . . . . ?
Rh2 P3 C44 C45 78.4(5) . . . . ?
C33 P4 C47 C48 66.4(5) . . . . ?
C51 P4 C47 C48 177.3(4) . . . . ?
Rh2 P4 C47 C48 -46.9(5) . . . . ?
C33 P4 C47 C49 -169.7(4) . . . . ?
C51 P4 C47 C49 -58.7(5) . . . . ?
Rh2 P4 C47 C49 77.1(5) . . . . ?
C33 P4 C51 C53 -57.4(5) . . . . ?
C47 P4 C51 C53 -171.0(4) . . . . ?
Rh2 P4 C51 C53 49.0(5) . . . . ?
C33 P4 C51 C52 67.0(5) . . . . ?
C47 P4 C51 C52 -46.6(5) . . . . ?
Rh2 P4 C51 C52 173.4(4) . . . . ?
C55 C56 C57 C58 -59.3(14) . . . . ?
C56 C57 C58 C59 -175.1(10) . . . . ?

_refine_diff_density_max         0.942
_refine_diff_density_min         -0.614
_refine_diff_density_rms         0.100



_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Diethyl ether, pentane'
_chemical_properties_physical    ', Air-sensitive'
