# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_g141215a
_audit_block_doi                 10.5517/ccdc.csd.cc1mgxff
_database_code_depnum_ccdc_archive 'CCDC 1503885'
_audit_update_record             
;
2016-09-12 deposited with the CCDC.
2017-06-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        BS-Pt
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H22 Cl N3 Pt'
_chemical_formula_weight         631.03

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.2191(3)
_cell_length_b                   8.2286(3)
_cell_length_c                   28.0195(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 94.450(3)
_cell_angle_gamma                90.00
_cell_volume                     2349.04(15)
_cell_formula_units_Z            4
_cell_measurement_temperature    223(2)
_cell_measurement_reflns_used    3761
_cell_measurement_theta_min      4.3400
_cell_measurement_theta_max      73.2220

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.784
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1224
_exptl_absorpt_coefficient_mu    12.378
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2274
_exptl_absorpt_correction_T_max  0.7077
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      223(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            10001
_diffrn_reflns_av_R_equivalents  0.0452
_diffrn_reflns_av_sigmaI/netI    0.0593
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         3.16
_diffrn_reflns_theta_max         73.50
_reflns_number_total             4607
_reflns_number_gt                3585
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0257P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4607
_refine_ls_number_parameters     298
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0507
_refine_ls_R_factor_gt           0.0326
_refine_ls_wR_factor_ref         0.0773
_refine_ls_wR_factor_gt          0.0690
_refine_ls_goodness_of_fit_ref   0.987
_refine_ls_restrained_S_all      0.987
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.31732(2) 0.33111(3) 0.319448(8) 0.03053(7) Uani 1 1 d . . .
Cl1 Cl 0.33631(16) 0.44543(19) 0.24147(5) 0.0427(3) Uani 1 1 d . . .
N1 N 0.3898(5) 0.5257(6) 0.35703(16) 0.0335(11) Uani 1 1 d . . .
N2 N 0.1569(5) -0.0808(7) 0.45554(17) 0.0400(12) Uani 1 1 d . . .
N3 N 0.2493(5) 0.1262(6) 0.28550(16) 0.0348(11) Uani 1 1 d . . .
C1 C 0.4415(6) 0.6574(8) 0.3379(2) 0.0411(14) Uani 1 1 d . . .
H1 H 0.4426 0.6636 0.3044 0.049 Uiso 1 1 calc R . .
C2 C 0.4933(7) 0.7844(9) 0.3653(2) 0.0498(17) Uani 1 1 d . . .
H2 H 0.5292 0.8755 0.3508 0.060 Uiso 1 1 calc R . .
C3 C 0.4912(7) 0.7747(8) 0.4144(3) 0.0483(16) Uani 1 1 d . . .
H3 H 0.5253 0.8598 0.4340 0.058 Uiso 1 1 calc R . .
C4 C 0.4387(6) 0.6392(8) 0.4342(2) 0.0428(15) Uani 1 1 d . . .
H4 H 0.4372 0.6318 0.4677 0.051 Uiso 1 1 calc R . .
C5 C 0.3881(5) 0.5139(8) 0.4058(2) 0.0337(12) Uani 1 1 d . . .
C6 C 0.3275(6) 0.3651(7) 0.4217(2) 0.0351(13) Uani 1 1 d . . .
C7 C 0.3027(6) 0.3332(8) 0.4690(2) 0.0386(13) Uani 1 1 d . . .
H7 H 0.3238 0.4110 0.4930 0.046 Uiso 1 1 calc R . .
C8 C 0.2466(6) 0.1859(8) 0.4806(2) 0.0384(14) Uani 1 1 d . . .
H8 H 0.2289 0.1652 0.5125 0.046 Uiso 1 1 calc R . .
C9 C 0.2162(6) 0.0680(7) 0.4455(2) 0.0340(13) Uani 1 1 d . . .
C10 C 0.2417(6) 0.1044(8) 0.3982(2) 0.0369(13) Uani 1 1 d . . .
H10 H 0.2236 0.0252 0.3744 0.044 Uiso 1 1 calc R . .
C11 C 0.2925(6) 0.2526(7) 0.38515(18) 0.0316(12) Uani 1 1 d . . .
C12 C 0.1897(6) -0.1716(8) 0.4978(2) 0.0348(12) Uani 1 1 d . . .
C13 C 0.3093(6) -0.1504(9) 0.5251(2) 0.0450(15) Uani 1 1 d . . .
H13 H 0.3713 -0.0761 0.5149 0.054 Uiso 1 1 calc R . .
C14 C 0.3369(8) -0.2373(10) 0.5665(2) 0.057(2) Uani 1 1 d . . .
H14 H 0.4160 -0.2186 0.5851 0.068 Uiso 1 1 calc R . .
C15 C 0.2501(10) -0.3514(9) 0.5812(3) 0.064(2) Uani 1 1 d . . .
H15 H 0.2703 -0.4124 0.6092 0.077 Uiso 1 1 calc R . .
C16 C 0.1330(9) -0.3748(9) 0.5542(3) 0.063(2) Uani 1 1 d . . .
H16 H 0.0729 -0.4519 0.5641 0.076 Uiso 1 1 calc R . .
C17 C 0.1027(7) -0.2877(8) 0.5131(2) 0.0446(16) Uani 1 1 d . . .
H17 H 0.0226 -0.3063 0.4951 0.054 Uiso 1 1 calc R . .
C18 C 0.0639(6) -0.1464(8) 0.4194(2) 0.0355(13) Uani 1 1 d . . .
C19 C 0.0841(7) -0.2936(8) 0.3976(2) 0.0465(16) Uani 1 1 d . . .
H19 H 0.1584 -0.3566 0.4071 0.056 Uiso 1 1 calc R . .
C20 C -0.0069(8) -0.3482(9) 0.3615(2) 0.0559(19) Uani 1 1 d . . .
H20 H 0.0077 -0.4479 0.3465 0.067 Uiso 1 1 calc R . .
C21 C -0.1158(7) -0.2614(9) 0.3476(2) 0.0492(17) Uani 1 1 d . . .
H21 H -0.1768 -0.3015 0.3236 0.059 Uiso 1 1 calc R . .
C22 C -0.1359(6) -0.1139(9) 0.3689(2) 0.0475(16) Uani 1 1 d . . .
H22 H -0.2109 -0.0528 0.3590 0.057 Uiso 1 1 calc R . .
C23 C -0.0480(6) -0.0535(8) 0.4046(2) 0.0422(15) Uani 1 1 d . . .
H23 H -0.0626 0.0478 0.4187 0.051 Uiso 1 1 calc R . .
C24 C 0.1248(6) 0.0736(8) 0.2858(2) 0.0395(14) Uani 1 1 d . . .
H24 H 0.0662 0.1327 0.3034 0.047 Uiso 1 1 calc R . .
C25 C 0.0797(7) -0.0623(9) 0.2616(2) 0.0500(17) Uani 1 1 d . . .
H25 H -0.0088 -0.0937 0.2615 0.060 Uiso 1 1 calc R . .
C26 C 0.1679(8) -0.1524(9) 0.2373(3) 0.0560(18) Uani 1 1 d . . .
H26 H 0.1400 -0.2479 0.2212 0.067 Uiso 1 1 calc R . .
C27 C 0.2952(8) -0.1024(8) 0.2367(2) 0.0489(17) Uani 1 1 d . . .
H27 H 0.3558 -0.1628 0.2203 0.059 Uiso 1 1 calc R . .
C28 C 0.3333(6) 0.0392(7) 0.2606(2) 0.0377(13) Uani 1 1 d . . .
H28 H 0.4202 0.0758 0.2596 0.045 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C11 1.986(5) . ?
Pt1 N1 2.025(5) . ?
Pt1 N3 2.032(5) . ?
Pt1 Cl1 2.4006(15) . ?
N1 C1 1.336(8) . ?
N1 C5 1.372(7) . ?
N2 C9 1.404(8) . ?
N2 C12 1.417(7) . ?
N2 C18 1.439(7) . ?
N3 C24 1.344(8) . ?
N3 C28 1.353(8) . ?
C1 C2 1.378(9) . ?
C1 H1 0.9400 . ?
C2 C3 1.379(10) . ?
C2 H2 0.9400 . ?
C3 C4 1.374(9) . ?
C3 H3 0.9400 . ?
C4 C5 1.378(8) . ?
C4 H4 0.9400 . ?
C5 C6 1.458(9) . ?
C6 C7 1.394(8) . ?
C6 C11 1.406(8) . ?
C7 C8 1.390(9) . ?
C7 H7 0.9400 . ?
C8 C9 1.400(8) . ?
C8 H8 0.9400 . ?
C9 C10 1.402(8) . ?
C10 C11 1.385(9) . ?
C10 H10 0.9400 . ?
C12 C17 1.395(9) . ?
C12 C13 1.402(8) . ?
C13 C14 1.374(10) . ?
C13 H13 0.9400 . ?
C14 C15 1.376(12) . ?
C14 H14 0.9400 . ?
C15 C16 1.379(12) . ?
C15 H15 0.9400 . ?
C16 C17 1.372(9) . ?
C16 H16 0.9400 . ?
C17 H17 0.9400 . ?
C18 C19 1.379(9) . ?
C18 C23 1.411(9) . ?
C19 C20 1.394(9) . ?
C19 H19 0.9400 . ?
C20 C21 1.354(11) . ?
C20 H20 0.9400 . ?
C21 C22 1.375(10) . ?
C21 H21 0.9400 . ?
C22 C23 1.384(9) . ?
C22 H22 0.9400 . ?
C23 H23 0.9400 . ?
C24 C25 1.369(9) . ?
C24 H24 0.9400 . ?
C25 C26 1.386(11) . ?
C25 H25 0.9400 . ?
C26 C27 1.366(11) . ?
C26 H26 0.9400 . ?
C27 C28 1.385(9) . ?
C27 H27 0.9400 . ?
C28 H28 0.9400 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Pt1 N1 81.0(2) . . ?
C11 Pt1 N3 95.8(2) . . ?
N1 Pt1 N3 176.12(19) . . ?
C11 Pt1 Cl1 175.20(18) . . ?
N1 Pt1 Cl1 96.40(14) . . ?
N3 Pt1 Cl1 87.02(14) . . ?
C1 N1 C5 119.5(5) . . ?
C1 N1 Pt1 124.9(4) . . ?
C5 N1 Pt1 115.5(4) . . ?
C9 N2 C12 123.4(5) . . ?
C9 N2 C18 117.2(5) . . ?
C12 N2 C18 119.3(5) . . ?
C24 N3 C28 118.1(5) . . ?
C24 N3 Pt1 123.6(4) . . ?
C28 N3 Pt1 118.2(4) . . ?
N1 C1 C2 122.6(6) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C1 C2 C3 118.4(6) . . ?
C1 C2 H2 120.8 . . ?
C3 C2 H2 120.8 . . ?
C4 C3 C2 119.2(6) . . ?
C4 C3 H3 120.4 . . ?
C2 C3 H3 120.4 . . ?
C3 C4 C5 120.9(6) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 H4 119.6 . . ?
N1 C5 C4 119.3(6) . . ?
N1 C5 C6 113.7(5) . . ?
C4 C5 C6 127.0(6) . . ?
C7 C6 C11 120.9(6) . . ?
C7 C6 C5 124.1(5) . . ?
C11 C6 C5 114.9(5) . . ?
C8 C7 C6 119.7(5) . . ?
C8 C7 H7 120.2 . . ?
C6 C7 H7 120.2 . . ?
C7 C8 C9 120.9(5) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 H8 119.6 . . ?
C8 C9 N2 122.6(5) . . ?
C8 C9 C10 118.0(6) . . ?
N2 C9 C10 119.4(5) . . ?
C11 C10 C9 122.6(5) . . ?
C11 C10 H10 118.7 . . ?
C9 C10 H10 118.7 . . ?
C10 C11 C6 117.8(5) . . ?
C10 C11 Pt1 127.5(4) . . ?
C6 C11 Pt1 114.7(4) . . ?
C17 C12 C13 117.8(6) . . ?
C17 C12 N2 120.2(5) . . ?
C13 C12 N2 122.0(6) . . ?
C14 C13 C12 120.6(7) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C13 C14 C15 120.9(7) . . ?
C13 C14 H14 119.5 . . ?
C15 C14 H14 119.5 . . ?
C16 C15 C14 118.8(7) . . ?
C16 C15 H15 120.6 . . ?
C14 C15 H15 120.6 . . ?
C17 C16 C15 121.2(8) . . ?
C17 C16 H16 119.4 . . ?
C15 C16 H16 119.4 . . ?
C16 C17 C12 120.5(7) . . ?
C16 C17 H17 119.7 . . ?
C12 C17 H17 119.7 . . ?
C19 C18 C23 119.4(6) . . ?
C19 C18 N2 121.8(6) . . ?
C23 C18 N2 118.7(6) . . ?
C18 C19 C20 119.3(7) . . ?
C18 C19 H19 120.4 . . ?
C20 C19 H19 120.4 . . ?
C21 C20 C19 121.8(7) . . ?
C21 C20 H20 119.1 . . ?
C19 C20 H20 119.1 . . ?
C20 C21 C22 119.2(6) . . ?
C20 C21 H21 120.4 . . ?
C22 C21 H21 120.4 . . ?
C21 C22 C23 121.3(7) . . ?
C21 C22 H22 119.3 . . ?
C23 C22 H22 119.3 . . ?
C22 C23 C18 119.0(6) . . ?
C22 C23 H23 120.5 . . ?
C18 C23 H23 120.5 . . ?
N3 C24 C25 122.8(6) . . ?
N3 C24 H24 118.6 . . ?
C25 C24 H24 118.6 . . ?
C24 C25 C26 118.3(7) . . ?
C24 C25 H25 120.9 . . ?
C26 C25 H25 120.9 . . ?
C27 C26 C25 120.1(7) . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C26 C27 C28 118.6(7) . . ?
C26 C27 H27 120.7 . . ?
C28 C27 H27 120.7 . . ?
N3 C28 C27 122.0(6) . . ?
N3 C28 H28 119.0 . . ?
C27 C28 H28 119.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C11 Pt1 N1 C1 177.5(5) . . . . ?
N3 Pt1 N1 C1 145(3) . . . . ?
Cl1 Pt1 N1 C1 -6.6(5) . . . . ?
C11 Pt1 N1 C5 0.0(4) . . . . ?
N3 Pt1 N1 C5 -32(3) . . . . ?
Cl1 Pt1 N1 C5 175.9(4) . . . . ?
C11 Pt1 N3 C24 64.6(5) . . . . ?
N1 Pt1 N3 C24 97(3) . . . . ?
Cl1 Pt1 N3 C24 -111.5(5) . . . . ?
C11 Pt1 N3 C28 -116.4(4) . . . . ?
N1 Pt1 N3 C28 -84(3) . . . . ?
Cl1 Pt1 N3 C28 67.5(4) . . . . ?
C5 N1 C1 C2 -0.5(10) . . . . ?
Pt1 N1 C1 C2 -177.9(5) . . . . ?
N1 C1 C2 C3 -0.1(11) . . . . ?
C1 C2 C3 C4 0.4(11) . . . . ?
C2 C3 C4 C5 -0.2(11) . . . . ?
C1 N1 C5 C4 0.7(9) . . . . ?
Pt1 N1 C5 C4 178.4(4) . . . . ?
C1 N1 C5 C6 179.3(5) . . . . ?
Pt1 N1 C5 C6 -3.0(6) . . . . ?
C3 C4 C5 N1 -0.4(10) . . . . ?
C3 C4 C5 C6 -178.8(6) . . . . ?
N1 C5 C6 C7 -173.3(6) . . . . ?
C4 C5 C6 C7 5.2(10) . . . . ?
N1 C5 C6 C11 5.7(8) . . . . ?
C4 C5 C6 C11 -175.8(6) . . . . ?
C11 C6 C7 C8 2.2(9) . . . . ?
C5 C6 C7 C8 -178.8(6) . . . . ?
C6 C7 C8 C9 0.8(9) . . . . ?
C7 C8 C9 N2 -178.6(6) . . . . ?
C7 C8 C9 C10 -1.2(9) . . . . ?
C12 N2 C9 C8 -39.5(9) . . . . ?
C18 N2 C9 C8 144.2(6) . . . . ?
C12 N2 C9 C10 143.1(6) . . . . ?
C18 N2 C9 C10 -33.2(8) . . . . ?
C8 C9 C10 C11 -1.5(9) . . . . ?
N2 C9 C10 C11 176.0(6) . . . . ?
C9 C10 C11 C6 4.4(9) . . . . ?
C9 C10 C11 Pt1 -173.3(5) . . . . ?
C7 C6 C11 C10 -4.7(9) . . . . ?
C5 C6 C11 C10 176.2(5) . . . . ?
C7 C6 C11 Pt1 173.3(5) . . . . ?
C5 C6 C11 Pt1 -5.8(7) . . . . ?
N1 Pt1 C11 C10 -179.0(6) . . . . ?
N3 Pt1 C11 C10 -1.1(6) . . . . ?
Cl1 Pt1 C11 C10 124.0(19) . . . . ?
N1 Pt1 C11 C6 3.2(4) . . . . ?
N3 Pt1 C11 C6 -178.9(4) . . . . ?
Cl1 Pt1 C11 C6 -54(2) . . . . ?
C9 N2 C12 C17 159.8(6) . . . . ?
C18 N2 C12 C17 -23.9(9) . . . . ?
C9 N2 C12 C13 -21.1(9) . . . . ?
C18 N2 C12 C13 155.2(6) . . . . ?
C17 C12 C13 C14 -2.5(10) . . . . ?
N2 C12 C13 C14 178.3(6) . . . . ?
C12 C13 C14 C15 2.5(11) . . . . ?
C13 C14 C15 C16 -1.5(12) . . . . ?
C14 C15 C16 C17 0.5(13) . . . . ?
C15 C16 C17 C12 -0.6(13) . . . . ?
C13 C12 C17 C16 1.5(10) . . . . ?
N2 C12 C17 C16 -179.3(7) . . . . ?
C9 N2 C18 C19 118.0(7) . . . . ?
C12 N2 C18 C19 -58.5(8) . . . . ?
C9 N2 C18 C23 -59.3(8) . . . . ?
C12 N2 C18 C23 124.2(6) . . . . ?
C23 C18 C19 C20 -0.3(10) . . . . ?
N2 C18 C19 C20 -177.5(6) . . . . ?
C18 C19 C20 C21 -0.8(12) . . . . ?
C19 C20 C21 C22 1.3(12) . . . . ?
C20 C21 C22 C23 -0.7(11) . . . . ?
C21 C22 C23 C18 -0.4(10) . . . . ?
C19 C18 C23 C22 0.9(10) . . . . ?
N2 C18 C23 C22 178.2(6) . . . . ?
C28 N3 C24 C25 -0.9(9) . . . . ?
Pt1 N3 C24 C25 178.1(5) . . . . ?
N3 C24 C25 C26 2.5(11) . . . . ?
C24 C25 C26 C27 -1.9(11) . . . . ?
C25 C26 C27 C28 -0.1(11) . . . . ?
C24 N3 C28 C27 -1.3(9) . . . . ?
Pt1 N3 C28 C27 179.7(5) . . . . ?
C26 C27 C28 N3 1.8(10) . . . . ?

_diffrn_measured_fraction_theta_max 0.971
_diffrn_reflns_theta_full        73.50
_diffrn_measured_fraction_theta_full 0.971
_refine_diff_density_max         1.195
_refine_diff_density_min         -0.651
_refine_diff_density_rms         0.120
