# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2a
_database_code_depnum_ccdc_archive 'CCDC 1535612'
_audit_update_record             
;
2017-03-02 deposited with the CCDC.
2017-05-19 downloaded from the CCDC.
;

#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C103 H84 Ag2 N10 Pt2'
_chemical_formula_moiety         'C103 H84 Ag2 N10 Pt2'
_chemical_formula_weight         2067.78
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_space_group_crystal_system      orthorhombic
_space_group_name_H-M_alt        'P b c n'
_space_group_name_Hall           '-P 2n 2ab'
_space_group_IT_number           60
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 1/2-X,1/2-Y,1/2+Z
3 1/2+X,1/2-Y,-Z
4 -X,+Y,1/2-Z
5 -X,-Y,-Z
6 -1/2+X,-1/2+Y,-1/2-Z
7 -1/2-X,-1/2+Y,+Z
8 +X,-Y,-1/2+Z
#------------------------------------------------------------------------------
_cell_length_a                   18.6158(16)
_cell_length_b                   18.2847(14)
_cell_length_c                   24.601(2)
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_volume                     8373.8(12)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    23945
_cell_measurement_theta_min      1.77
_cell_measurement_theta_max      27.49
_cell_measurement_temperature    273
#------------------------------------------------------------------------------
_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.130
_exptl_crystal_density_diffrn    1.640
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4088.00
_exptl_absorpt_coefficient_mu    3.833
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_correction_T_min  0.495
_exptl_absorpt_correction_T_max  0.608

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      273
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 29.257
_diffrn_reflns_number            66939
_diffrn_reflns_av_R_equivalents  0.0360
_diffrn_reflns_theta_max         27.490
_diffrn_reflns_theta_min         1.767
_diffrn_reflns_theta_full        27.490
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.000
_diffrn_reflns_Laue_measured_fraction_full 0.000
_diffrn_reflns_point_group_measured_fraction_max 0.000
_diffrn_reflns_point_group_measured_fraction_full 0.000
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       31
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_reflns_number_total             9581
_reflns_number_gt                8668
_reflns_threshold_expression     F²>2.0σ(F²)

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_all          0.0308
_refine_ls_R_factor_gt           0.0264
_refine_ls_wR_factor_ref         0.0552
_refine_ls_wR_factor_gt          0.0536
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_reflns         9581
_refine_ls_number_parameters     512
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0215P)²+11.8384P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.006
_refine_diff_density_max         1.80
_refine_diff_density_min         -0.86
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.875181(6) 0.453712(6) 0.740489(4) 0.01258(4) Uani 1 1 d . . .
Ag1 Ag 0.983593(11) 0.354147(11) 0.809363(8) 0.01581(5) Uani 1 1 d . . .
N11 N 0.89885(13) 0.56118(13) 0.74022(10) 0.0171(5) Uani 1 1 d . . .
C12 C 0.88134(15) 0.59782(16) 0.78688(12) 0.0190(6) Uani 1 1 d . . .
C13 C 0.88591(16) 0.67381(16) 0.78884(14) 0.0255(7) Uani 1 1 d . . .
H13 H 0.8732 0.6986 0.8204 0.031 Uiso 1 1 calc R . .
C14 C 0.90923(18) 0.71237(18) 0.74414(15) 0.0299(7) Uani 1 1 d . . .
H14 H 0.9114 0.7632 0.7451 0.036 Uiso 1 1 calc R . .
C15 C 0.92933(17) 0.67486(17) 0.69776(14) 0.0266(7) Uani 1 1 d . . .
H15 H 0.9462 0.6999 0.6674 0.032 Uiso 1 1 calc R . .
C16 C 0.92383(15) 0.59925(16) 0.69727(12) 0.0212(6) Uani 1 1 d . . .
H16 H 0.9379 0.5739 0.6662 0.025 Uiso 1 1 calc R . .
C121 C 0.85865(15) 0.54981(16) 0.83133(12) 0.0193(6) Uani 1 1 d . . .
C122 C 0.85706(14) 0.47456(16) 0.81875(11) 0.0161(6) Uani 1 1 d . . .
C123 C 0.83592(16) 0.42653(17) 0.85997(11) 0.0205(6) Uani 1 1 d . . .
H123 H 0.8355 0.3765 0.8532 0.025 Uiso 1 1 calc R . .
C124 C 0.81547(17) 0.45197(18) 0.91099(12) 0.0255(7) Uani 1 1 d . . .
H124 H 0.8012 0.4191 0.9377 0.031 Uiso 1 1 calc R . .
C125 C 0.81635(17) 0.52619(18) 0.92205(12) 0.0268(7) Uani 1 1 d . . .
H125 H 0.8021 0.5431 0.9560 0.032 Uiso 1 1 calc R . .
C126 C 0.83835(17) 0.57528(18) 0.88262(12) 0.0251(7) Uani 1 1 d . . .
H126 H 0.8396 0.6251 0.8902 0.030 Uiso 1 1 calc R . .
N21 N 0.84821(13) 0.34764(12) 0.74795(9) 0.0147(5) Uani 1 1 d . . .
N22 N 0.89480(12) 0.29981(12) 0.77243(9) 0.0139(5) Uani 1 1 d . . .
C23 C 0.86129(15) 0.23444(15) 0.77644(11) 0.0157(6) Uani 1 1 d . . .
C24 C 0.79328(16) 0.24027(16) 0.75329(12) 0.0213(6) Uani 1 1 d . . .
H24 H 0.7593 0.2033 0.7497 0.026 Uiso 1 1 calc R . .
C25 C 0.78650(15) 0.31250(16) 0.73664(11) 0.0172(6) Uani 1 1 d . . .
C231 C 0.89199(15) 0.17136(15) 0.80530(11) 0.0171(6) Uani 1 1 d . . .
C232 C 0.96519(15) 0.16367(16) 0.81550(12) 0.0197(6) Uani 1 1 d . . .
H232 H 0.9971 0.1983 0.8020 0.024 Uiso 1 1 calc R . .
C233 C 0.99138(17) 0.10509(17) 0.84555(13) 0.0254(7) Uani 1 1 d . . .
H233 H 1.0404 0.1009 0.8519 0.031 Uiso 1 1 calc R . .
C234 C 0.94446(18) 0.05282(16) 0.86606(13) 0.0256(7) Uani 1 1 d . . .
H234 H 0.9618 0.0140 0.8867 0.031 Uiso 1 1 calc R . .
C235 C 0.87162(17) 0.05903(17) 0.85552(14) 0.0266(7) Uani 1 1 d . . .
H235 H 0.8400 0.0237 0.8684 0.032 Uiso 1 1 calc R . .
C236 C 0.84584(16) 0.11776(16) 0.82578(13) 0.0232(6) Uani 1 1 d . . .
H236 H 0.7968 0.1216 0.8193 0.028 Uiso 1 1 calc R . .
C251 C 0.72181(15) 0.34965(15) 0.71498(13) 0.0211(6) Uani 1 1 d . . .
C252 C 0.69302(19) 0.32992(18) 0.66504(14) 0.0301(7) Uani 1 1 d . . .
H252 H 0.7166 0.2959 0.6433 0.036 Uiso 1 1 calc R . .
C253 C 0.6286(2) 0.3613(2) 0.64759(16) 0.0404(9) Uani 1 1 d . . .
H253 H 0.6095 0.3483 0.6140 0.048 Uiso 1 1 calc R . .
C254 C 0.59286(19) 0.41136(18) 0.67975(16) 0.0376(9) Uani 1 1 d . . .
H254 H 0.5497 0.4315 0.6680 0.045 Uiso 1 1 calc R . .
C255 C 0.62141(17) 0.43152(18) 0.72964(16) 0.0300(7) Uani 1 1 d . . .
H255 H 0.5976 0.4653 0.7514 0.036 Uiso 1 1 calc R . .
C256 C 0.68570(17) 0.40088(17) 0.74677(13) 0.0238(6) Uani 1 1 d . . .
H256 H 0.7050 0.4148 0.7801 0.029 Uiso 1 1 calc R . .
N31 N 0.88575(12) 0.44195(12) 0.65573(9) 0.0150(5) Uani 1 1 d . . .
N32 N 0.93821(12) 0.39611(12) 0.63722(9) 0.0157(5) Uani 1 1 d . . .
C33 C 0.93995(15) 0.40124(16) 0.58242(11) 0.0184(6) Uani 1 1 d . . .
C34 C 0.88823(16) 0.45111(16) 0.56556(12) 0.0205(6) Uani 1 1 d . . .
H34 H 0.8782 0.4653 0.5301 0.025 Uiso 1 1 calc R . .
C35 C 0.85438(15) 0.47557(16) 0.61269(11) 0.0164(6) Uani 1 1 d . . .
C331 C 0.98939(15) 0.35766(17) 0.54888(12) 0.0210(6) Uani 1 1 d . . .
C332 C 1.00937(17) 0.38343(19) 0.49741(12) 0.0263(7) Uani 1 1 d . . .
H332 H 0.9914 0.4278 0.4849 0.032 Uiso 1 1 calc R . .
C333 C 1.05551(19) 0.3433(2) 0.46518(14) 0.0353(8) Uani 1 1 d . . .
H333 H 1.0681 0.3607 0.4310 0.042 Uiso 1 1 calc R . .
C334 C 1.08292(18) 0.2780(2) 0.48316(14) 0.0353(8) Uani 1 1 d . . .
H334 H 1.1146 0.2517 0.4615 0.042 Uiso 1 1 calc R . .
C335 C 1.06319(18) 0.2513(2) 0.53386(13) 0.0318(8) Uani 1 1 d . . .
H335 H 1.0815 0.2069 0.5461 0.038 Uiso 1 1 calc R . .
C336 C 1.01623(17) 0.29079(18) 0.56627(12) 0.0249(7) Uani 1 1 d . . .
H336 H 1.0026 0.2723 0.5999 0.030 Uiso 1 1 calc R . .
C351 C 0.79709(15) 0.53097(16) 0.61647(12) 0.0198(6) Uani 1 1 d . . .
C352 C 0.78740(17) 0.57904(19) 0.57320(15) 0.0334(8) Uani 1 1 d . . .
H352 H 0.8161 0.5747 0.5424 0.040 Uiso 1 1 calc R . .
C353 C 0.73554(19) 0.6333(2) 0.57540(17) 0.0444(10) Uani 1 1 d . . .
H353 H 0.7295 0.6649 0.5461 0.053 Uiso 1 1 calc R . .
C354 C 0.69279(18) 0.64067(19) 0.62082(17) 0.0381(9) Uani 1 1 d . . .
H354 H 0.6591 0.6781 0.6228 0.046 Uiso 1 1 calc R . .
C355 C 0.70039(17) 0.59203(17) 0.66340(14) 0.0272(7) Uani 1 1 d . . .
H355 H 0.6706 0.5959 0.6936 0.033 Uiso 1 1 calc R . .
C356 C 0.75187(16) 0.53763(16) 0.66140(12) 0.0213(6) Uani 1 1 d . . .
H356 H 0.7564 0.5052 0.6903 0.026 Uiso 1 1 calc R . .
C41 C 0.63496(17) 0.29135(16) 0.91092(13) 0.0243(7) Uani 1 1 d . . .
C42 C 0.62031(18) 0.25549(17) 0.95963(14) 0.0284(7) Uani 1 1 d . . .
H42 H 0.5743 0.2576 0.9742 0.034 Uiso 1 1 calc R . .
C43 C 0.67347(18) 0.21667(17) 0.98674(13) 0.0278(7) Uani 1 1 d . . .
H43 H 0.6629 0.1930 1.0192 0.033 Uiso 1 1 calc R . .
C44 C 0.74237(18) 0.21325(18) 0.96527(13) 0.0293(7) Uani 1 1 d . . .
H44 H 0.7782 0.1872 0.9831 0.035 Uiso 1 1 calc R . .
C45 C 0.75728(18) 0.24921(19) 0.91683(14) 0.0316(7) Uani 1 1 d . . .
H45 H 0.8034 0.2475 0.9023 0.038 Uiso 1 1 calc R . .
C46 C 0.70422(18) 0.28735(18) 0.89032(13) 0.0279(7) Uani 1 1 d . . .
H46 H 0.7150 0.3110 0.8579 0.034 Uiso 1 1 calc R . .
C47 C 0.57701(19) 0.33242(19) 0.88089(15) 0.0358(8) Uani 1 1 d . . .
H47A H 0.5705 0.3112 0.8455 0.043 Uiso 1 1 calc R . .
H47B H 0.5908 0.3828 0.8771 0.043 Uiso 1 1 calc R . .
H47C H 0.5328 0.3294 0.9009 0.043 Uiso 1 1 calc R . .
C51 C 0.4882(3) 0.4293(3) 0.9916(2) 0.0302(15) Uiso 0.50 1 d PG A -1
H51 H 0.4705 0.3830 0.9836 0.036 Uiso 0.50 1 calc PR A -1
C52 C 0.5595(2) 0.4378(3) 1.0072(2) 0.0432(19) Uiso 0.50 1 d PG A -1
H52 H 0.5895 0.3973 1.0096 0.052 Uiso 0.50 1 calc PR A -1
C53 C 0.58597(19) 0.5071(3) 1.0193(2) 0.052(2) Uiso 0.50 1 d PG A -1
C54 C 0.5412(3) 0.5677(3) 1.0157(3) 0.056(2) Uiso 0.50 1 d PG A -1
H54 H 0.5589 0.6140 1.0238 0.068 Uiso 0.50 1 calc PR A -1
C55 C 0.4699(3) 0.5591(3) 1.0001(3) 0.047(2) Uiso 0.50 1 d PG A -1
H55 H 0.4399 0.5997 0.9978 0.056 Uiso 0.50 1 calc PR A -1
C56 C 0.44344(19) 0.4899(3) 0.9881(2) 0.0398(18) Uiso 0.50 1 d PG A -1
H56 H 0.3958 0.4842 0.9776 0.048 Uiso 0.50 1 calc PR A -1
C57 C 0.6406(5) 0.5221(6) 1.0265(4) 0.064(3) Uiso 0.50 1 d P A -1
H57A H 0.6711 0.4976 1.0009 0.077 Uiso 0.50 1 calc PR A -1
H57B H 0.6540 0.5081 1.0628 0.077 Uiso 0.50 1 calc PR A -1
H57C H 0.6458 0.5740 1.0225 0.077 Uiso 0.50 1 calc PR A -1


#==============================================================================
_computing_data_collection       'CrystalClear-SM Expert 2.0 r16 (Rigaku, 2014)'
_computing_cell_refinement       'CrystalClear-SM Expert 2.0 r16'
_computing_data_reduction        'CrystalClear-SM Expert 2.0 r16'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.2 (Rigaku, 2015)'
_computing_molecular_graphics    'CrystalStructure 4.2'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C122 1.991(3) . ?
Pt1 N21 2.012(2) . ?
Pt1 N11 2.014(2) . ?
Pt1 N31 2.105(2) . ?
Pt1 Ag1 3.2028(3) . ?
Ag1 N32 2.106(2) 4_756 ?
Ag1 N22 2.132(2) . ?
Ag1 Ag1 2.9839(5) 4_756 ?
N11 C16 1.348(4) . ?
N11 C12 1.368(4) . ?
C12 C13 1.393(4) . ?
C12 C121 1.465(4) . ?
C13 C14 1.377(5) . ?
C13 H13 0.9300 . ?
C14 C15 1.383(5) . ?
C14 H14 0.9300 . ?
C15 C16 1.386(4) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C121 C126 1.397(4) . ?
C121 C122 1.411(4) . ?
C122 C123 1.398(4) . ?
C123 C124 1.392(4) . ?
C123 H123 0.9300 . ?
C124 C125 1.384(4) . ?
C124 H124 0.9300 . ?
C125 C126 1.384(5) . ?
C125 H125 0.9300 . ?
C126 H126 0.9300 . ?
N21 C25 1.345(4) . ?
N21 N22 1.371(3) . ?
N22 C23 1.352(3) . ?
C23 C24 1.392(4) . ?
C23 C231 1.470(4) . ?
C24 C25 1.389(4) . ?
C24 H24 0.9300 . ?
C25 C251 1.482(4) . ?
C231 C232 1.393(4) . ?
C231 C236 1.397(4) . ?
C232 C233 1.390(4) . ?
C232 H232 0.9300 . ?
C233 C234 1.390(4) . ?
C233 H233 0.9300 . ?
C234 C235 1.385(4) . ?
C234 H234 0.9300 . ?
C235 C236 1.385(4) . ?
C235 H235 0.9300 . ?
C236 H236 0.9300 . ?
C251 C252 1.388(4) . ?
C251 C256 1.393(4) . ?
C252 C253 1.397(5) . ?
C252 H252 0.9300 . ?
C253 C254 1.381(5) . ?
C253 H253 0.9300 . ?
C254 C255 1.387(5) . ?
C254 H254 0.9300 . ?
C255 C256 1.387(4) . ?
C255 H255 0.9300 . ?
C256 H256 0.9300 . ?
N31 C35 1.356(3) . ?
N31 N32 1.365(3) . ?
N32 C33 1.352(3) . ?
N32 Ag1 2.106(2) 4_756 ?
C33 C34 1.389(4) . ?
C33 C331 1.471(4) . ?
C34 C35 1.393(4) . ?
C34 H34 0.9300 . ?
C35 C351 1.474(4) . ?
C331 C336 1.388(4) . ?
C331 C332 1.401(4) . ?
C332 C333 1.380(5) . ?
C332 H332 0.9300 . ?
C333 C334 1.371(5) . ?
C333 H333 0.9300 . ?
C334 C335 1.389(5) . ?
C334 H334 0.9300 . ?
C335 C336 1.386(4) . ?
C335 H335 0.9300 . ?
C336 H336 0.9300 . ?
C351 C352 1.392(4) . ?
C351 C356 1.395(4) . ?
C352 C353 1.385(5) . ?
C352 H352 0.9300 . ?
C353 C354 1.378(5) . ?
C353 H353 0.9300 . ?
C354 C355 1.381(5) . ?
C354 H354 0.9300 . ?
C355 C356 1.382(4) . ?
C355 H355 0.9300 . ?
C356 H356 0.9300 . ?
C41 C46 1.387(4) . ?
C41 C42 1.393(5) . ?
C41 C47 1.508(5) . ?
C42 C43 1.388(5) . ?
C42 H42 0.9300 . ?
C43 C44 1.388(5) . ?
C43 H43 0.9300 . ?
C44 C45 1.389(5) . ?
C44 H44 0.9300 . ?
C45 C46 1.374(5) . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
C51 C52 1.3900 . ?
C51 C56 1.3900 . ?
C51 H51 0.9300 . ?
C52 C53 1.3900 . ?
C52 H52 0.9300 . ?
C53 C57 1.068(10) . ?
C53 C54 1.3900 . ?
C54 C55 1.3900 . ?
C54 H54 0.9300 . ?
C55 C56 1.3900 . ?
C55 H55 0.9300 . ?
C56 H56 0.9300 . ?
C57 H57A 0.9600 . ?
C57 H57B 0.9600 . ?
C57 H57C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C122 Pt1 N21 93.10(10) . . ?
C122 Pt1 N11 81.57(11) . . ?
N21 Pt1 N11 174.62(9) . . ?
C122 Pt1 N31 173.14(10) . . ?
N21 Pt1 N31 90.87(9) . . ?
N11 Pt1 N31 94.35(9) . . ?
C122 Pt1 Ag1 72.79(8) . . ?
N21 Pt1 Ag1 63.96(7) . . ?
N11 Pt1 Ag1 114.74(7) . . ?
N31 Pt1 Ag1 114.02(6) . . ?
N32 Ag1 N22 166.34(9) 4_756 . ?
N32 Ag1 Ag1 117.99(6) 4_756 4_756 ?
N22 Ag1 Ag1 75.02(6) . 4_756 ?
N32 Ag1 Pt1 123.96(6) 4_756 . ?
N22 Ag1 Pt1 63.31(6) . . ?
Ag1 Ag1 Pt1 67.118(7) 4_756 . ?
C16 N11 C12 119.1(3) . . ?
C16 N11 Pt1 125.6(2) . . ?
C12 N11 Pt1 115.0(2) . . ?
N11 C12 C13 120.2(3) . . ?
N11 C12 C121 113.7(2) . . ?
C13 C12 C121 126.1(3) . . ?
C14 C13 C12 120.2(3) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C13 C14 C15 119.4(3) . . ?
C13 C14 H14 120.3 . . ?
C15 C14 H14 120.3 . . ?
C14 C15 C16 118.8(3) . . ?
C14 C15 H15 120.6 . . ?
C16 C15 H15 120.6 . . ?
N11 C16 C15 122.3(3) . . ?
N11 C16 H16 118.9 . . ?
C15 C16 H16 118.9 . . ?
C126 C121 C122 121.2(3) . . ?
C126 C121 C12 123.5(3) . . ?
C122 C121 C12 115.3(3) . . ?
C123 C122 C121 117.3(3) . . ?
C123 C122 Pt1 129.0(2) . . ?
C121 C122 Pt1 113.3(2) . . ?
C124 C123 C122 121.4(3) . . ?
C124 C123 H123 119.3 . . ?
C122 C123 H123 119.3 . . ?
C125 C124 C123 120.1(3) . . ?
C125 C124 H124 119.9 . . ?
C123 C124 H124 119.9 . . ?
C126 C125 C124 120.1(3) . . ?
C126 C125 H125 119.9 . . ?
C124 C125 H125 119.9 . . ?
C125 C126 C121 119.8(3) . . ?
C125 C126 H126 120.1 . . ?
C121 C126 H126 120.1 . . ?
C25 N21 N22 109.0(2) . . ?
C25 N21 Pt1 130.89(19) . . ?
N22 N21 Pt1 119.81(17) . . ?
C23 N22 N21 107.7(2) . . ?
C23 N22 Ag1 137.62(19) . . ?
N21 N22 Ag1 112.36(16) . . ?
N22 C23 C24 108.8(2) . . ?
N22 C23 C231 123.3(2) . . ?
C24 C23 C231 127.7(3) . . ?
C25 C24 C23 106.0(3) . . ?
C25 C24 H24 127.0 . . ?
C23 C24 H24 127.0 . . ?
N21 C25 C24 108.4(3) . . ?
N21 C25 C251 123.3(3) . . ?
C24 C25 C251 128.0(3) . . ?
C232 C231 C236 117.8(3) . . ?
C232 C231 C23 123.1(3) . . ?
C236 C231 C23 119.0(3) . . ?
C233 C232 C231 121.1(3) . . ?
C233 C232 H232 119.4 . . ?
C231 C232 H232 119.4 . . ?
C234 C233 C232 120.2(3) . . ?
C234 C233 H233 119.9 . . ?
C232 C233 H233 119.9 . . ?
C235 C234 C233 119.4(3) . . ?
C235 C234 H234 120.3 . . ?
C233 C234 H234 120.3 . . ?
C236 C235 C234 120.1(3) . . ?
C236 C235 H235 119.9 . . ?
C234 C235 H235 119.9 . . ?
C235 C236 C231 121.4(3) . . ?
C235 C236 H236 119.3 . . ?
C231 C236 H236 119.3 . . ?
C252 C251 C256 119.0(3) . . ?
C252 C251 C25 120.9(3) . . ?
C256 C251 C25 119.9(3) . . ?
C251 C252 C253 119.8(3) . . ?
C251 C252 H252 120.1 . . ?
C253 C252 H252 120.1 . . ?
C254 C253 C252 120.6(3) . . ?
C254 C253 H253 119.7 . . ?
C252 C253 H253 119.7 . . ?
C253 C254 C255 119.9(3) . . ?
C253 C254 H254 120.0 . . ?
C255 C254 H254 120.0 . . ?
C256 C255 C254 119.5(3) . . ?
C256 C255 H255 120.3 . . ?
C254 C255 H255 120.3 . . ?
C255 C256 C251 121.2(3) . . ?
C255 C256 H256 119.4 . . ?
C251 C256 H256 119.4 . . ?
C35 N31 N32 109.0(2) . . ?
C35 N31 Pt1 133.36(19) . . ?
N32 N31 Pt1 117.38(17) . . ?
C33 N32 N31 107.9(2) . . ?
C33 N32 Ag1 129.13(19) . 4_756 ?
N31 N32 Ag1 120.67(17) . 4_756 ?
N32 C33 C34 109.1(3) . . ?
N32 C33 C331 122.5(3) . . ?
C34 C33 C331 128.4(3) . . ?
C33 C34 C35 106.0(3) . . ?
C33 C34 H34 127.0 . . ?
C35 C34 H34 127.0 . . ?
N31 C35 C34 108.0(2) . . ?
N31 C35 C351 125.0(3) . . ?
C34 C35 C351 126.9(3) . . ?
C336 C331 C332 118.6(3) . . ?
C336 C331 C33 122.0(3) . . ?
C332 C331 C33 119.4(3) . . ?
C333 C332 C331 120.4(3) . . ?
C333 C332 H332 119.8 . . ?
C331 C332 H332 119.8 . . ?
C334 C333 C332 120.6(3) . . ?
C334 C333 H333 119.7 . . ?
C332 C333 H333 119.7 . . ?
C333 C334 C335 119.8(3) . . ?
C333 C334 H334 120.1 . . ?
C335 C334 H334 120.1 . . ?
C336 C335 C334 120.0(3) . . ?
C336 C335 H335 120.0 . . ?
C334 C335 H335 120.0 . . ?
C335 C336 C331 120.6(3) . . ?
C335 C336 H336 119.7 . . ?
C331 C336 H336 119.7 . . ?
C352 C351 C356 118.2(3) . . ?
C352 C351 C35 118.6(3) . . ?
C356 C351 C35 123.1(3) . . ?
C353 C352 C351 120.8(3) . . ?
C353 C352 H352 119.6 . . ?
C351 C352 H352 119.6 . . ?
C354 C353 C352 120.3(3) . . ?
C354 C353 H353 119.9 . . ?
C352 C353 H353 119.9 . . ?
C353 C354 C355 119.5(3) . . ?
C353 C354 H354 120.2 . . ?
C355 C354 H354 120.2 . . ?
C354 C355 C356 120.5(3) . . ?
C354 C355 H355 119.8 . . ?
C356 C355 H355 119.8 . . ?
C355 C356 C351 120.6(3) . . ?
C355 C356 H356 119.7 . . ?
C351 C356 H356 119.7 . . ?
C46 C41 C42 118.1(3) . . ?
C46 C41 C47 120.8(3) . . ?
C42 C41 C47 121.1(3) . . ?
C43 C42 C41 121.0(3) . . ?
C43 C42 H42 119.5 . . ?
C41 C42 H42 119.5 . . ?
C44 C43 C42 119.9(3) . . ?
C44 C43 H43 120.0 . . ?
C42 C43 H43 120.0 . . ?
C43 C44 C45 119.3(3) . . ?
C43 C44 H44 120.3 . . ?
C45 C44 H44 120.3 . . ?
C46 C45 C44 120.2(3) . . ?
C46 C45 H45 119.9 . . ?
C44 C45 H45 119.9 . . ?
C45 C46 C41 121.4(3) . . ?
C45 C46 H46 119.3 . . ?
C41 C46 H46 119.3 . . ?
C41 C47 H47A 109.5 . . ?
C41 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C41 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C52 C51 C56 120.0 . . ?
C52 C51 H51 120.0 . . ?
C56 C51 H51 120.0 . . ?
C53 C52 C51 120.0 . . ?
C53 C52 H52 120.0 . . ?
C51 C52 H52 120.0 . . ?
C57 C53 C52 127.4(7) . . ?
C57 C53 C54 112.1(7) . . ?
C52 C53 C54 120.0 . . ?
C55 C54 C53 120.0 . . ?
C55 C54 H54 120.0 . . ?
C53 C54 H54 120.0 . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C55 C56 C51 120.0 . . ?
C55 C56 H56 120.0 . . ?
C51 C56 H56 120.0 . . ?
C53 C57 H57A 109.5 . . ?
C53 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C53 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C122 Pt1 Ag1 N32 -60.46(11) . . . 4_756 ?
N21 Pt1 Ag1 N32 -162.84(11) . . . 4_756 ?
N11 Pt1 Ag1 N32 11.38(11) . . . 4_756 ?
N31 Pt1 Ag1 N32 118.65(10) . . . 4_756 ?
C122 Pt1 Ag1 N22 106.12(11) . . . . ?
N21 Pt1 Ag1 N22 3.74(10) . . . . ?
N11 Pt1 Ag1 N22 177.96(10) . . . . ?
N31 Pt1 Ag1 N22 -74.77(9) . . . . ?
C122 Pt1 Ag1 Ag1 -169.72(8) . . . 4_756 ?
N21 Pt1 Ag1 Ag1 87.90(7) . . . 4_756 ?
N11 Pt1 Ag1 Ag1 -97.88(8) . . . 4_756 ?
N31 Pt1 Ag1 Ag1 9.39(7) . . . 4_756 ?
C122 Pt1 N11 C16 176.1(2) . . . . ?
N21 Pt1 N11 C16 -175.6(9) . . . . ?
N31 Pt1 N11 C16 -9.4(2) . . . . ?
Ag1 Pt1 N11 C16 109.6(2) . . . . ?
C122 Pt1 N11 C12 -9.9(2) . . . . ?
N21 Pt1 N11 C12 -1.7(11) . . . . ?
N31 Pt1 N11 C12 164.5(2) . . . . ?
Ag1 Pt1 N11 C12 -76.5(2) . . . . ?
C16 N11 C12 C13 3.2(4) . . . . ?
Pt1 N11 C12 C13 -171.2(2) . . . . ?
C16 N11 C12 C121 -176.9(2) . . . . ?
Pt1 N11 C12 C121 8.8(3) . . . . ?
N11 C12 C13 C14 -1.1(5) . . . . ?
C121 C12 C13 C14 179.0(3) . . . . ?
C12 C13 C14 C15 -1.2(5) . . . . ?
C13 C14 C15 C16 1.4(5) . . . . ?
C12 N11 C16 C15 -3.1(4) . . . . ?
Pt1 N11 C16 C15 170.7(2) . . . . ?
C14 C15 C16 N11 0.7(5) . . . . ?
N11 C12 C121 C126 180.0(3) . . . . ?
C13 C12 C121 C126 -0.1(5) . . . . ?
N11 C12 C121 C122 -1.2(4) . . . . ?
C13 C12 C121 C122 178.7(3) . . . . ?
C126 C121 C122 C123 -1.4(4) . . . . ?
C12 C121 C122 C123 179.8(2) . . . . ?
C126 C121 C122 Pt1 171.9(2) . . . . ?
C12 C121 C122 Pt1 -6.8(3) . . . . ?
N21 Pt1 C122 C123 2.0(3) . . . . ?
N11 Pt1 C122 C123 -178.7(3) . . . . ?
N31 Pt1 C122 C123 127.3(8) . . . . ?
Ag1 Pt1 C122 C123 -59.5(2) . . . . ?
N21 Pt1 C122 C121 -170.3(2) . . . . ?
N11 Pt1 C122 C121 8.9(2) . . . . ?
N31 Pt1 C122 C121 -45.0(9) . . . . ?
Ag1 Pt1 C122 C121 128.2(2) . . . . ?
C121 C122 C123 C124 1.6(4) . . . . ?
Pt1 C122 C123 C124 -170.5(2) . . . . ?
C122 C123 C124 C125 -0.6(5) . . . . ?
C123 C124 C125 C126 -0.7(5) . . . . ?
C124 C125 C126 C121 1.0(5) . . . . ?
C122 C121 C126 C125 0.1(5) . . . . ?
C12 C121 C126 C125 178.8(3) . . . . ?
C122 Pt1 N21 C25 98.5(2) . . . . ?
N11 Pt1 N21 C25 90.3(10) . . . . ?
N31 Pt1 N21 C25 -75.9(2) . . . . ?
Ag1 Pt1 N21 C25 167.6(3) . . . . ?
C122 Pt1 N21 N22 -75.1(2) . . . . ?
N11 Pt1 N21 N22 -83.3(10) . . . . ?
N31 Pt1 N21 N22 110.46(19) . . . . ?
Ag1 Pt1 N21 N22 -6.00(16) . . . . ?
C25 N21 N22 C23 -0.2(3) . . . . ?
Pt1 N21 N22 C23 174.68(17) . . . . ?
C25 N21 N22 Ag1 -166.12(17) . . . . ?
Pt1 N21 N22 Ag1 8.8(2) . . . . ?
N32 Ag1 N22 C23 -39.8(5) 4_756 . . . ?
Ag1 Ag1 N22 C23 123.2(3) 4_756 . . . ?
Pt1 Ag1 N22 C23 -165.2(3) . . . . ?
N32 Ag1 N22 N21 120.0(4) 4_756 . . . ?
Ag1 Ag1 N22 N21 -76.92(16) 4_756 . . . ?
Pt1 Ag1 N22 N21 -5.34(14) . . . . ?
N21 N22 C23 C24 1.2(3) . . . . ?
Ag1 N22 C23 C24 161.7(2) . . . . ?
N21 N22 C23 C231 -173.9(2) . . . . ?
Ag1 N22 C23 C231 -13.4(4) . . . . ?
N22 C23 C24 C25 -1.7(3) . . . . ?
C231 C23 C24 C25 173.2(3) . . . . ?
N22 N21 C25 C24 -0.9(3) . . . . ?
Pt1 N21 C25 C24 -175.0(2) . . . . ?
N22 N21 C25 C251 173.8(3) . . . . ?
Pt1 N21 C25 C251 -0.3(4) . . . . ?
C23 C24 C25 N21 1.6(3) . . . . ?
C23 C24 C25 C251 -172.8(3) . . . . ?
N22 C23 C231 C232 -21.8(4) . . . . ?
C24 C23 C231 C232 164.0(3) . . . . ?
N22 C23 C231 C236 155.3(3) . . . . ?
C24 C23 C231 C236 -18.9(4) . . . . ?
C236 C231 C232 C233 -0.7(4) . . . . ?
C23 C231 C232 C233 176.4(3) . . . . ?
C231 C232 C233 C234 0.0(5) . . . . ?
C232 C233 C234 C235 1.0(5) . . . . ?
C233 C234 C235 C236 -1.4(5) . . . . ?
C234 C235 C236 C231 0.7(5) . . . . ?
C232 C231 C236 C235 0.4(5) . . . . ?
C23 C231 C236 C235 -176.9(3) . . . . ?
N21 C25 C251 C252 119.7(3) . . . . ?
C24 C25 C251 C252 -66.8(4) . . . . ?
N21 C25 C251 C256 -65.6(4) . . . . ?
C24 C25 C251 C256 108.0(4) . . . . ?
C256 C251 C252 C253 -0.2(5) . . . . ?
C25 C251 C252 C253 174.5(3) . . . . ?
C251 C252 C253 C254 -0.5(6) . . . . ?
C252 C253 C254 C255 0.7(6) . . . . ?
C253 C254 C255 C256 -0.2(5) . . . . ?
C254 C255 C256 C251 -0.6(5) . . . . ?
C252 C251 C256 C255 0.8(5) . . . . ?
C25 C251 C256 C255 -174.0(3) . . . . ?
C122 Pt1 N31 C35 -3.0(10) . . . . ?
N21 Pt1 N31 C35 122.5(3) . . . . ?
N11 Pt1 N31 C35 -56.3(3) . . . . ?
Ag1 Pt1 N31 C35 -175.8(2) . . . . ?
C122 Pt1 N31 N32 170.6(8) . . . . ?
N21 Pt1 N31 N32 -63.95(19) . . . . ?
N11 Pt1 N31 N32 117.34(19) . . . . ?
Ag1 Pt1 N31 N32 -2.2(2) . . . . ?
C35 N31 N32 C33 0.3(3) . . . . ?
Pt1 N31 N32 C33 -174.81(18) . . . . ?
C35 N31 N32 Ag1 164.50(18) . . . 4_756 ?
Pt1 N31 N32 Ag1 -10.6(2) . . . 4_756 ?
N31 N32 C33 C34 0.2(3) . . . . ?
Ag1 N32 C33 C34 -162.25(19) 4_756 . . . ?
N31 N32 C33 C331 -178.5(2) . . . . ?
Ag1 N32 C33 C331 19.0(4) 4_756 . . . ?
N32 C33 C34 C35 -0.6(3) . . . . ?
C331 C33 C34 C35 178.1(3) . . . . ?
N32 N31 C35 C34 -0.6(3) . . . . ?
Pt1 N31 C35 C34 173.3(2) . . . . ?
N32 N31 C35 C351 -177.8(2) . . . . ?
Pt1 N31 C35 C351 -3.8(4) . . . . ?
C33 C34 C35 N31 0.7(3) . . . . ?
C33 C34 C35 C351 177.8(3) . . . . ?
N32 C33 C331 C336 25.8(4) . . . . ?
C34 C33 C331 C336 -152.6(3) . . . . ?
N32 C33 C331 C332 -155.2(3) . . . . ?
C34 C33 C331 C332 26.3(5) . . . . ?
C336 C331 C332 C333 -0.8(5) . . . . ?
C33 C331 C332 C333 -179.8(3) . . . . ?
C331 C332 C333 C334 -0.5(5) . . . . ?
C332 C333 C334 C335 1.1(5) . . . . ?
C333 C334 C335 C336 -0.3(5) . . . . ?
C334 C335 C336 C331 -1.0(5) . . . . ?
C332 C331 C336 C335 1.6(4) . . . . ?
C33 C331 C336 C335 -179.5(3) . . . . ?
N31 C35 C351 C352 157.4(3) . . . . ?
C34 C35 C351 C352 -19.2(5) . . . . ?
N31 C35 C351 C356 -22.6(5) . . . . ?
C34 C35 C351 C356 160.8(3) . . . . ?
C356 C351 C352 C353 1.7(5) . . . . ?
C35 C351 C352 C353 -178.3(3) . . . . ?
C351 C352 C353 C354 0.3(6) . . . . ?
C352 C353 C354 C355 -2.2(6) . . . . ?
C353 C354 C355 C356 2.0(5) . . . . ?
C354 C355 C356 C351 0.1(5) . . . . ?
C352 C351 C356 C355 -1.9(4) . . . . ?
C35 C351 C356 C355 178.1(3) . . . . ?
C46 C41 C42 C43 -0.2(5) . . . . ?
C47 C41 C42 C43 178.9(3) . . . . ?
C41 C42 C43 C44 0.0(5) . . . . ?
C42 C43 C44 C45 0.3(5) . . . . ?
C43 C44 C45 C46 -0.4(5) . . . . ?
C44 C45 C46 C41 0.2(5) . . . . ?
C42 C41 C46 C45 0.1(5) . . . . ?
C47 C41 C46 C45 -179.0(3) . . . . ?
C56 C51 C52 C53 0.0 . . . . ?
C51 C52 C53 C57 -171.2(9) . . . . ?
C51 C52 C53 C54 0.0 . . . . ?
C57 C53 C54 C55 172.4(8) . . . . ?
C52 C53 C54 C55 0.0 . . . . ?
C53 C54 C55 C56 0.0 . . . . ?
C54 C55 C56 C51 0.0 . . . . ?
C52 C51 C56 C55 0.0 . . . . ?
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5a
_database_code_depnum_ccdc_archive 'CCDC 1535613'
_audit_update_record             
;
2017-03-02 deposited with the CCDC.
2017-05-19 downloaded from the CCDC.
;

#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C82 H56 Ag2 F4 N10 Pt2'
_chemical_formula_moiety         'C82 H56 Ag2 F4 N10 Pt2'
_chemical_formula_weight         1863.32
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_space_group_crystal_system      monoclinic
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
_space_group_IT_number           14
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-1/2-Y,-1/2+Z
#------------------------------------------------------------------------------
_cell_length_a                   23.523(5)
_cell_length_b                   14.927(3)
_cell_length_c                   19.897(5)
_cell_angle_alpha                90.0000
_cell_angle_beta                 109.989(3)
_cell_angle_gamma                90.0000
_cell_volume                     6565(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    13556
_cell_measurement_theta_min      1.75
_cell_measurement_theta_max      27.49
_cell_measurement_temperature    273
#------------------------------------------------------------------------------
_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.070
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.040
_exptl_crystal_density_diffrn    1.885
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3616.00
_exptl_absorpt_coefficient_mu    4.886
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_correction_T_min  0.748
_exptl_absorpt_correction_T_max  0.822

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      273
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 29.257
_diffrn_reflns_number            53578
_diffrn_reflns_av_R_equivalents  0.0885
_diffrn_reflns_theta_max         27.480
_diffrn_reflns_theta_min         1.646
_diffrn_reflns_theta_full        27.480
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measured_fraction_theta_full 0.978
_diffrn_reflns_Laue_measured_fraction_max 0.000
_diffrn_reflns_Laue_measured_fraction_full 0.000
_diffrn_reflns_point_group_measured_fraction_max 0.000
_diffrn_reflns_point_group_measured_fraction_full 0.000
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_reflns_number_total             14744
_reflns_number_gt                10814
_reflns_threshold_expression     F²>2.0σ(F²)

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_all          0.1125
_refine_ls_R_factor_gt           0.0810
_refine_ls_wR_factor_ref         0.1465
_refine_ls_wR_factor_gt          0.1308
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_reflns         14744
_refine_ls_number_parameters     901
_refine_ls_goodness_of_fit_ref   1.164
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0286P)²+46.0873P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.001
_refine_diff_density_max         1.23
_refine_diff_density_min         -1.84
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.322401(19) 0.57368(3) 0.18920(2) 0.02251(11) Uani 1 1 d . . .
Pt2 Pt 0.177196(19) 0.58559(3) 0.29561(2) 0.02277(11) Uani 1 1 d . . .
Ag1 Ag 0.20047(4) 0.45387(6) 0.17107(4) 0.0263(2) Uani 1 1 d . . .
Ag2 Ag 0.29626(4) 0.44210(6) 0.31348(4) 0.0264(2) Uani 1 1 d . . .
N11 N 0.3217(4) 0.7017(6) 0.2194(4) 0.024(2) Uani 1 1 d . . .
C12 C 0.2894(5) 0.7601(7) 0.1660(6) 0.026(2) Uani 1 1 d . . .
C13 C 0.2952(6) 0.8529(9) 0.1748(7) 0.045(3) Uani 1 1 d . . .
H13 H 0.2737 0.8919 0.1386 0.054 Uiso 1 1 calc R . .
C14 C 0.3348(6) 0.8849(8) 0.2409(7) 0.045(3) Uani 1 1 d . . .
H14 H 0.3411 0.9463 0.2474 0.054 Uiso 1 1 calc R . .
C15 C 0.3646(6) 0.8273(9) 0.2963(7) 0.041(3) Uani 1 1 d . . .
H15 H 0.3884 0.8486 0.3410 0.049 Uiso 1 1 calc R . .
C16 C 0.3573(5) 0.7365(8) 0.2821(6) 0.029(3) Uani 1 1 d . . .
H16 H 0.3782 0.6970 0.3182 0.035 Uiso 1 1 calc R . .
C121 C 0.2509(5) 0.7133(8) 0.1019(6) 0.029(3) Uani 1 1 d . . .
C122 C 0.2577(5) 0.6185(7) 0.1012(5) 0.022(2) Uani 1 1 d . . .
C123 C 0.2255(5) 0.5698(8) 0.0422(5) 0.027(3) Uani 1 1 d . . .
H123 H 0.2303 0.5081 0.0405 0.033 Uiso 1 1 calc R . .
C124 C 0.1852(5) 0.6164(9) -0.0155(6) 0.037(3) Uani 1 1 d . . .
F124 F 0.1524(3) 0.5682(5) -0.0746(3) 0.0436(18) Uani 1 1 d . . .
C125 C 0.1750(5) 0.7074(8) -0.0186(6) 0.031(3) Uani 1 1 d . . .
H125 H 0.1472 0.7361 -0.0576 0.038 Uiso 1 1 calc R . .
C126 C 0.2107(6) 0.7518(8) 0.0429(6) 0.031(3) Uani 1 1 d . . .
F126 F 0.2017(4) 0.8439(5) 0.0423(4) 0.054(2) Uani 1 1 d . . .
N21 N 0.3195(4) 0.4491(6) 0.1494(4) 0.027(2) Uani 1 1 d . . .
N22 N 0.2733(4) 0.3918(6) 0.1465(4) 0.0221(19) Uani 1 1 d . . .
C23 C 0.2810(5) 0.3182(8) 0.1120(6) 0.030(3) Uani 1 1 d . . .
C24 C 0.3311(5) 0.3295(8) 0.0913(6) 0.033(3) Uani 1 1 d . . .
H24 H 0.3458 0.2891 0.0657 0.039 Uiso 1 1 calc R . .
C25 C 0.3549(5) 0.4127(7) 0.1161(5) 0.024(2) Uani 1 1 d . . .
C231 C 0.2396(5) 0.2384(7) 0.0987(6) 0.027(3) Uani 1 1 d . . .
C232 C 0.1872(5) 0.2369(8) 0.1134(6) 0.031(3) Uani 1 1 d . . .
H232 H 0.1751 0.2880 0.1316 0.038 Uiso 1 1 calc R . .
C233 C 0.1514(6) 0.1600(8) 0.1016(7) 0.038(3) Uani 1 1 d . . .
H233 H 0.1158 0.1606 0.1121 0.046 Uiso 1 1 calc R . .
C234 C 0.1676(6) 0.0846(8) 0.0753(6) 0.036(3) Uani 1 1 d . . .
H234 H 0.1431 0.0340 0.0668 0.043 Uiso 1 1 calc R . .
C235 C 0.2213(7) 0.0840(8) 0.0611(7) 0.043(3) Uani 1 1 d . . .
H235 H 0.2328 0.0321 0.0432 0.052 Uiso 1 1 calc R . .
C236 C 0.2576(6) 0.1573(8) 0.0727(6) 0.039(3) Uani 1 1 d . . .
H236 H 0.2939 0.1550 0.0638 0.047 Uiso 1 1 calc R . .
C251 C 0.4064(5) 0.4612(7) 0.1078(6) 0.031(3) Uani 1 1 d . . .
C252 C 0.4002(6) 0.5210(9) 0.0544(7) 0.044(3) Uani 1 1 d . . .
H252 H 0.3615 0.5332 0.0229 0.053 Uiso 1 1 calc R . .
C253 C 0.4479(7) 0.5641(10) 0.0448(8) 0.051(4) Uani 1 1 d . . .
H253 H 0.4414 0.6038 0.0069 0.061 Uiso 1 1 calc R . .
C254 C 0.5057(6) 0.5488(10) 0.0911(8) 0.053(4) Uani 1 1 d . . .
H254 H 0.5383 0.5786 0.0850 0.064 Uiso 1 1 calc R . .
C255 C 0.5148(6) 0.4894(9) 0.1462(7) 0.042(3) Uani 1 1 d . . .
H255 H 0.5538 0.4791 0.1777 0.050 Uiso 1 1 calc R . .
C256 C 0.4655(5) 0.4435(8) 0.1560(7) 0.035(3) Uani 1 1 d . . .
H256 H 0.4718 0.4027 0.1931 0.042 Uiso 1 1 calc R . .
N31 N 0.3964(4) 0.5357(6) 0.2790(5) 0.027(2) Uani 1 1 d . . .
N32 N 0.3856(4) 0.4700(6) 0.3217(4) 0.0225(19) Uani 1 1 d . . .
C33 C 0.4393(5) 0.4455(8) 0.3715(6) 0.026(2) Uani 1 1 d . . .
C34 C 0.4855(6) 0.4952(7) 0.3599(6) 0.029(3) Uani 1 1 d . . .
H34 H 0.5268 0.4916 0.3855 0.035 Uiso 1 1 calc R . .
C35 C 0.4570(5) 0.5513(8) 0.3017(6) 0.026(2) Uani 1 1 d . . .
C331 C 0.4452(5) 0.3754(8) 0.4256(6) 0.028(3) Uani 1 1 d . . .
C332 C 0.4021(5) 0.3085(8) 0.4186(7) 0.038(3) Uani 1 1 d . . .
H332 H 0.3668 0.3082 0.3789 0.045 Uiso 1 1 calc R . .
C333 C 0.4116(6) 0.2432(8) 0.4697(7) 0.040(3) Uani 1 1 d . . .
H333 H 0.3826 0.1989 0.4644 0.049 Uiso 1 1 calc R . .
C334 C 0.4638(6) 0.2426(8) 0.5289(6) 0.036(3) Uani 1 1 d . . .
H334 H 0.4694 0.1986 0.5636 0.043 Uiso 1 1 calc R . .
C335 C 0.5068(7) 0.3058(9) 0.5366(6) 0.047(4) Uani 1 1 d . . .
H335 H 0.5427 0.3038 0.5754 0.056 Uiso 1 1 calc R . .
C336 C 0.4971(6) 0.3738(8) 0.4863(6) 0.037(3) Uani 1 1 d . . .
H336 H 0.5257 0.4190 0.4933 0.045 Uiso 1 1 calc R . .
C351 C 0.4871(5) 0.6187(7) 0.2712(6) 0.022(2) Uani 1 1 d . . .
C352 C 0.5500(5) 0.6295(8) 0.3063(6) 0.036(3) Uani 1 1 d . . .
H352 H 0.5707 0.5937 0.3452 0.044 Uiso 1 1 calc R . .
C353 C 0.5802(6) 0.6941(10) 0.2819(7) 0.046(4) Uani 1 1 d . . .
H353 H 0.6215 0.7016 0.3059 0.055 Uiso 1 1 calc R . .
C354 C 0.5526(6) 0.7476(9) 0.2244(7) 0.040(3) Uani 1 1 d . . .
H354 H 0.5744 0.7901 0.2093 0.048 Uiso 1 1 calc R . .
C355 C 0.4900(6) 0.7367(8) 0.1885(7) 0.039(3) Uani 1 1 d . . .
H355 H 0.4696 0.7731 0.1499 0.047 Uiso 1 1 calc R . .
C356 C 0.4591(5) 0.6706(8) 0.2115(6) 0.030(3) Uani 1 1 d . . .
H356 H 0.4183 0.6611 0.1860 0.036 Uiso 1 1 calc R . .
N41 N 0.1801(4) 0.7107(6) 0.2591(5) 0.025(2) Uani 1 1 d . . .
C42 C 0.2162(6) 0.7695(8) 0.3081(6) 0.032(3) Uani 1 1 d . . .
C43 C 0.2114(6) 0.8626(8) 0.2905(8) 0.044(3) Uani 1 1 d . . .
H43 H 0.2329 0.9045 0.3242 0.053 Uiso 1 1 calc R . .
C44 C 0.1749(7) 0.8905(9) 0.2237(7) 0.051(4) Uani 1 1 d . . .
H44 H 0.1724 0.9512 0.2124 0.061 Uiso 1 1 calc R . .
C45 C 0.1426(7) 0.8301(8) 0.1743(7) 0.045(3) Uani 1 1 d . . .
H45 H 0.1192 0.8490 0.1287 0.054 Uiso 1 1 calc R . .
C46 C 0.1447(5) 0.7393(8) 0.1927(6) 0.033(3) Uani 1 1 d . . .
H46 H 0.1218 0.6980 0.1594 0.040 Uiso 1 1 calc R . .
C421 C 0.2548(5) 0.7259(8) 0.3720(6) 0.031(3) Uani 1 1 d . . .
C422 C 0.2473(5) 0.6322(7) 0.3774(5) 0.022(2) Uani 1 1 d . . .
C423 C 0.2831(5) 0.5859(9) 0.4362(5) 0.032(3) Uani 1 1 d . . .
H423 H 0.2776 0.5247 0.4402 0.038 Uiso 1 1 calc R . .
C424 C 0.3270(5) 0.6309(9) 0.4890(6) 0.036(3) Uani 1 1 d . . .
F424 F 0.3621(4) 0.5869(6) 0.5469(4) 0.064(2) Uani 1 1 d . . .
C425 C 0.3361(6) 0.7217(10) 0.4868(6) 0.047(4) Uani 1 1 d . . .
H425 H 0.3652 0.7510 0.5242 0.056 Uiso 1 1 calc R . .
C426 C 0.3012(6) 0.7669(8) 0.4284(7) 0.034(3) Uani 1 1 d . . .
F426 F 0.3081(4) 0.8571(6) 0.4243(4) 0.064(2) Uani 1 1 d . . .
N51 N 0.1774(4) 0.4630(6) 0.3368(4) 0.0212(19) Uani 1 1 d . . .
N52 N 0.2167(4) 0.3980(6) 0.3282(5) 0.024(2) Uani 1 1 d . . .
C53 C 0.2027(5) 0.3187(7) 0.3528(5) 0.022(2) Uani 1 1 d . . .
C54 C 0.1546(5) 0.3327(7) 0.3764(6) 0.028(3) Uani 1 1 d . . .
H54 H 0.1358 0.2901 0.3958 0.033 Uiso 1 1 calc R . .
C55 C 0.1399(4) 0.4230(8) 0.3655(5) 0.023(2) Uani 1 1 d . . .
C531 C 0.2355(6) 0.2359(8) 0.3515(6) 0.032(3) Uani 1 1 d . . .
C532 C 0.2597(6) 0.2193(8) 0.2988(7) 0.037(3) Uani 1 1 d . . .
H532 H 0.2553 0.2616 0.2630 0.045 Uiso 1 1 calc R . .
C533 C 0.2911(7) 0.1389(8) 0.2984(8) 0.049(4) Uani 1 1 d . . .
H533 H 0.3090 0.1292 0.2640 0.059 Uiso 1 1 calc R . .
C534 C 0.2949(7) 0.0755(8) 0.3491(7) 0.046(3) Uani 1 1 d . . .
H534 H 0.3153 0.0221 0.3491 0.055 Uiso 1 1 calc R . .
C535 C 0.2684(6) 0.0903(8) 0.4012(7) 0.042(3) Uani 1 1 d . . .
H535 H 0.2700 0.0459 0.4346 0.050 Uiso 1 1 calc R . .
C536 C 0.2396(5) 0.1712(8) 0.4032(6) 0.035(3) Uani 1 1 d . . .
H536 H 0.2233 0.1818 0.4389 0.042 Uiso 1 1 calc R . .
C551 C 0.0935(5) 0.4749(8) 0.3845(6) 0.031(3) Uani 1 1 d . . .
C552 C 0.0359(6) 0.4408(8) 0.3714(6) 0.033(3) Uani 1 1 d . . .
H552 H 0.0252 0.3867 0.3471 0.039 Uiso 1 1 calc R . .
C553 C -0.0062(6) 0.4853(9) 0.3937(7) 0.043(3) Uani 1 1 d . . .
H553 H -0.0448 0.4620 0.3841 0.052 Uiso 1 1 calc R . .
C554 C 0.0105(6) 0.5653(9) 0.4307(6) 0.035(3) Uani 1 1 d . . .
H554 H -0.0169 0.5946 0.4474 0.042 Uiso 1 1 calc R . .
C555 C 0.0666(5) 0.6022(8) 0.4431(6) 0.031(3) Uani 1 1 d . . .
H555 H 0.0765 0.6571 0.4662 0.037 Uiso 1 1 calc R . .
C556 C 0.1084(5) 0.5563(8) 0.4205(6) 0.027(2) Uani 1 1 d . . .
H556 H 0.1468 0.5804 0.4296 0.032 Uiso 1 1 calc R . .
N61 N 0.0998(4) 0.5460(6) 0.2108(4) 0.0191(19) Uani 1 1 d . . .
N62 N 0.1115(4) 0.4896(6) 0.1623(4) 0.0225(19) Uani 1 1 d . . .
C63 C 0.0580(5) 0.4590(7) 0.1191(6) 0.025(2) Uani 1 1 d . . .
C64 C 0.0128(5) 0.4911(7) 0.1410(6) 0.027(3) Uani 1 1 d . . .
H64 H -0.0282 0.4780 0.1212 0.033 Uiso 1 1 calc R . .
C65 C 0.0400(5) 0.5465(8) 0.1978(5) 0.028(3) Uani 1 1 d . . .
C631 C 0.0524(5) 0.4013(8) 0.0554(6) 0.026(2) Uani 1 1 d . . .
C632 C 0.0934(6) 0.4124(8) 0.0191(5) 0.030(3) Uani 1 1 d . . .
H632 H 0.1245 0.4540 0.0350 0.036 Uiso 1 1 calc R . .
C633 C 0.0873(6) 0.3613(9) -0.0401(6) 0.039(3) Uani 1 1 d . . .
H633 H 0.1138 0.3699 -0.0650 0.047 Uiso 1 1 calc R . .
C634 C 0.0425(6) 0.2973(8) -0.0635(7) 0.036(3) Uani 1 1 d . . .
H634 H 0.0392 0.2624 -0.1034 0.043 Uiso 1 1 calc R . .
C635 C 0.0023(6) 0.2857(8) -0.0266(6) 0.039(3) Uani 1 1 d . . .
H635 H -0.0282 0.2431 -0.0421 0.047 Uiso 1 1 calc R . .
C636 C 0.0074(6) 0.3357(8) 0.0315(6) 0.035(3) Uani 1 1 d . . .
H636 H -0.0193 0.3265 0.0561 0.042 Uiso 1 1 calc R . .
C651 C 0.0088(5) 0.6070(8) 0.2324(5) 0.025(2) Uani 1 1 d . . .
C652 C -0.0516(6) 0.5902(8) 0.2267(6) 0.034(3) Uani 1 1 d . . .
H652 H -0.0697 0.5366 0.2065 0.041 Uiso 1 1 calc R . .
C653 C -0.0840(5) 0.6513(8) 0.2501(5) 0.027(3) Uani 1 1 d . . .
H653 H -0.1239 0.6381 0.2451 0.032 Uiso 1 1 calc R . .
C654 C -0.0598(6) 0.7313(9) 0.2808(6) 0.038(3) Uani 1 1 d . . .
H654 H -0.0830 0.7716 0.2960 0.045 Uiso 1 1 calc R . .
C655 C 0.0015(6) 0.7517(8) 0.2893(6) 0.037(3) Uani 1 1 d . . .
H655 H 0.0192 0.8053 0.3100 0.044 Uiso 1 1 calc R . .
C656 C 0.0337(5) 0.6893(8) 0.2655(5) 0.030(3) Uani 1 1 d . . .
H656 H 0.0738 0.7018 0.2715 0.036 Uiso 1 1 calc R . .


#==============================================================================
_computing_data_collection       'CrystalClear-SM Expert 2.0 r16 (Rigaku, 2014)'
_computing_cell_refinement       'CrystalClear-SM Expert 2.0 r16'
_computing_data_reduction        'CrystalClear-SM Expert 2.0 r16'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.2 (Rigaku, 2015)'
_computing_molecular_graphics    'CrystalStructure 4.2'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C122 2.001(11) . ?
Pt1 N11 2.005(9) . ?
Pt1 N21 2.013(9) . ?
Pt1 N31 2.102(9) . ?
Pt1 Ag1 3.2936(11) . ?
Pt2 C422 2.003(11) . ?
Pt2 N51 2.004(9) . ?
Pt2 N41 2.014(9) . ?
Pt2 N61 2.100(8) . ?
Ag1 N62 2.109(9) . ?
Ag1 N22 2.146(8) . ?
Ag1 Ag2 2.9619(13) . ?
Ag2 N32 2.095(8) . ?
Ag2 N52 2.098(9) . ?
N11 C16 1.348(12) . ?
N11 C12 1.384(13) . ?
C12 C13 1.396(16) . ?
C12 C121 1.464(15) . ?
C13 C14 1.409(18) . ?
C13 H13 0.9300 . ?
C14 C15 1.386(17) . ?
C14 H14 0.9300 . ?
C15 C16 1.382(16) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C121 C126 1.358(15) . ?
C121 C122 1.425(15) . ?
C122 C123 1.369(14) . ?
C123 C124 1.399(16) . ?
C123 H123 0.9300 . ?
C124 F124 1.370(13) . ?
C124 C125 1.377(17) . ?
C125 C126 1.393(16) . ?
C125 H125 0.9300 . ?
C126 F126 1.390(13) . ?
N21 C25 1.344(13) . ?
N21 N22 1.368(11) . ?
N22 C23 1.340(14) . ?
C23 C24 1.386(15) . ?
C23 C231 1.503(15) . ?
C24 C25 1.382(15) . ?
C24 H24 0.9300 . ?
C25 C251 1.468(15) . ?
C231 C232 1.360(14) . ?
C231 C236 1.436(15) . ?
C232 C233 1.396(15) . ?
C232 H232 0.9300 . ?
C233 C234 1.349(16) . ?
C233 H233 0.9300 . ?
C234 C235 1.386(17) . ?
C234 H234 0.9300 . ?
C235 C236 1.359(16) . ?
C235 H235 0.9300 . ?
C236 H236 0.9300 . ?
C251 C252 1.357(16) . ?
C251 C256 1.418(16) . ?
C252 C253 1.363(16) . ?
C252 H252 0.9300 . ?
C253 C254 1.38(2) . ?
C253 H253 0.9300 . ?
C254 C255 1.369(19) . ?
C254 H254 0.9300 . ?
C255 C256 1.415(16) . ?
C255 H255 0.9300 . ?
C256 H256 0.9300 . ?
N31 C35 1.361(13) . ?
N31 N32 1.376(11) . ?
N32 C33 1.362(13) . ?
C33 C34 1.400(14) . ?
C33 C331 1.473(15) . ?
C34 C35 1.400(15) . ?
C34 H34 0.9300 . ?
C35 C351 1.475(14) . ?
C331 C336 1.393(15) . ?
C331 C332 1.396(16) . ?
C332 C333 1.370(16) . ?
C332 H332 0.9300 . ?
C333 C334 1.380(16) . ?
C333 H333 0.9300 . ?
C334 C335 1.353(17) . ?
C334 H334 0.9300 . ?
C335 C336 1.387(16) . ?
C335 H335 0.9300 . ?
C336 H336 0.9300 . ?
C351 C356 1.382(15) . ?
C351 C352 1.411(14) . ?
C352 C353 1.382(16) . ?
C352 H352 0.9300 . ?
C353 C354 1.364(18) . ?
C353 H353 0.9300 . ?
C354 C355 1.408(17) . ?
C354 H354 0.9300 . ?
C355 C356 1.393(15) . ?
C355 H355 0.9300 . ?
C356 H356 0.9300 . ?
N41 C46 1.367(14) . ?
N41 C42 1.370(14) . ?
C42 C43 1.428(16) . ?
C42 C421 1.440(16) . ?
C43 C44 1.377(18) . ?
C43 H43 0.9300 . ?
C44 C45 1.359(17) . ?
C44 H44 0.9300 . ?
C45 C46 1.401(16) . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C421 C426 1.411(16) . ?
C421 C422 1.418(15) . ?
C422 C423 1.372(14) . ?
C423 C424 1.372(15) . ?
C423 H423 0.9300 . ?
C424 F424 1.338(14) . ?
C424 C425 1.375(18) . ?
C425 C426 1.352(17) . ?
C425 H425 0.9300 . ?
C426 F426 1.362(14) . ?
N51 C55 1.346(12) . ?
N51 N52 1.389(11) . ?
N52 C53 1.363(13) . ?
C53 C54 1.381(14) . ?
C53 C531 1.462(15) . ?
C54 C55 1.391(15) . ?
C54 H54 0.9300 . ?
C55 C551 1.488(15) . ?
C531 C532 1.377(15) . ?
C531 C536 1.389(16) . ?
C532 C533 1.411(16) . ?
C532 H532 0.9300 . ?
C533 C534 1.364(17) . ?
C533 H533 0.9300 . ?
C534 C535 1.397(16) . ?
C534 H534 0.9300 . ?
C535 C536 1.392(16) . ?
C535 H535 0.9300 . ?
C536 H536 0.9300 . ?
C551 C552 1.388(15) . ?
C551 C556 1.393(15) . ?
C552 C553 1.384(16) . ?
C552 H552 0.9300 . ?
C553 C554 1.387(17) . ?
C553 H553 0.9300 . ?
C554 C555 1.371(16) . ?
C554 H554 0.9300 . ?
C555 C556 1.393(14) . ?
C555 H555 0.9300 . ?
C556 H556 0.9300 . ?
N61 C65 1.342(13) . ?
N61 N62 1.377(11) . ?
N62 C63 1.339(13) . ?
C63 C64 1.365(14) . ?
C63 C631 1.501(15) . ?
C64 C65 1.370(15) . ?
C64 H64 0.9300 . ?
C65 C651 1.474(15) . ?
C631 C632 1.398(14) . ?
C631 C636 1.400(15) . ?
C632 C633 1.369(15) . ?
C632 H632 0.9300 . ?
C633 C634 1.380(17) . ?
C633 H633 0.9300 . ?
C634 C635 1.391(17) . ?
C634 H634 0.9300 . ?
C635 C636 1.346(15) . ?
C635 H635 0.9300 . ?
C636 H636 0.9300 . ?
C651 C652 1.406(15) . ?
C651 C656 1.422(15) . ?
C652 C653 1.370(14) . ?
C652 H652 0.9300 . ?
C653 C654 1.373(17) . ?
C653 H653 0.9300 . ?
C654 C655 1.426(17) . ?
C654 H654 0.9300 . ?
C655 C656 1.382(15) . ?
C655 H655 0.9300 . ?
C656 H656 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C122 Pt1 N11 82.1(4) . . ?
C122 Pt1 N21 92.9(4) . . ?
N11 Pt1 N21 174.6(3) . . ?
C122 Pt1 N31 174.1(4) . . ?
N11 Pt1 N31 95.3(3) . . ?
N21 Pt1 N31 89.5(4) . . ?
C122 Pt1 Ag1 73.3(3) . . ?
N11 Pt1 Ag1 117.0(3) . . ?
N21 Pt1 Ag1 62.8(3) . . ?
N31 Pt1 Ag1 112.6(2) . . ?
C422 Pt2 N51 95.7(4) . . ?
C422 Pt2 N41 81.4(4) . . ?
N51 Pt2 N41 177.0(4) . . ?
C422 Pt2 N61 175.3(4) . . ?
N51 Pt2 N61 87.3(3) . . ?
N41 Pt2 N61 95.6(3) . . ?
N62 Ag1 N22 159.7(3) . . ?
N62 Ag1 Ag2 120.2(2) . . ?
N22 Ag1 Ag2 77.7(2) . . ?
N62 Ag1 Pt1 132.4(2) . . ?
N22 Ag1 Pt1 61.7(2) . . ?
Ag2 Ag1 Pt1 65.05(3) . . ?
N32 Ag2 N52 166.4(3) . . ?
N32 Ag2 Ag1 118.5(2) . . ?
N52 Ag2 Ag1 74.3(2) . . ?
C16 N11 C12 118.2(10) . . ?
C16 N11 Pt1 125.4(8) . . ?
C12 N11 Pt1 115.4(7) . . ?
N11 C12 C13 121.6(11) . . ?
N11 C12 C121 112.4(10) . . ?
C13 C12 C121 126.0(11) . . ?
C12 C13 C14 117.3(12) . . ?
C12 C13 H13 121.3 . . ?
C14 C13 H13 121.3 . . ?
C15 C14 C13 121.6(12) . . ?
C15 C14 H14 119.2 . . ?
C13 C14 H14 119.2 . . ?
C16 C15 C14 116.9(12) . . ?
C16 C15 H15 121.5 . . ?
C14 C15 H15 121.5 . . ?
N11 C16 C15 124.2(12) . . ?
N11 C16 H16 117.9 . . ?
C15 C16 H16 117.9 . . ?
C126 C121 C122 117.4(11) . . ?
C126 C121 C12 126.2(11) . . ?
C122 C121 C12 116.4(10) . . ?
C123 C122 C121 120.3(10) . . ?
C123 C122 Pt1 127.3(8) . . ?
C121 C122 Pt1 112.2(8) . . ?
C122 C123 C124 117.5(11) . . ?
C122 C123 H123 121.3 . . ?
C124 C123 H123 121.3 . . ?
F124 C124 C125 116.2(11) . . ?
F124 C124 C123 117.9(12) . . ?
C125 C124 C123 125.9(11) . . ?
C124 C125 C126 112.7(11) . . ?
C124 C125 H125 123.7 . . ?
C126 C125 H125 123.7 . . ?
C121 C126 F126 119.0(11) . . ?
C121 C126 C125 126.2(12) . . ?
F126 C126 C125 114.8(10) . . ?
C25 N21 N22 110.1(9) . . ?
C25 N21 Pt1 128.5(8) . . ?
N22 N21 Pt1 121.0(6) . . ?
C23 N22 N21 106.9(8) . . ?
C23 N22 Ag1 136.8(7) . . ?
N21 N22 Ag1 113.8(6) . . ?
N22 C23 C24 109.2(10) . . ?
N22 C23 C231 123.1(9) . . ?
C24 C23 C231 127.6(11) . . ?
C25 C24 C23 106.6(10) . . ?
C25 C24 H24 126.7 . . ?
C23 C24 H24 126.7 . . ?
N21 C25 C24 107.2(10) . . ?
N21 C25 C251 122.1(10) . . ?
C24 C25 C251 130.7(10) . . ?
C232 C231 C236 117.6(11) . . ?
C232 C231 C23 123.8(10) . . ?
C236 C231 C23 118.5(10) . . ?
C231 C232 C233 121.2(11) . . ?
C231 C232 H232 119.4 . . ?
C233 C232 H232 119.4 . . ?
C234 C233 C232 121.1(12) . . ?
C234 C233 H233 119.5 . . ?
C232 C233 H233 119.5 . . ?
C233 C234 C235 118.9(11) . . ?
C233 C234 H234 120.6 . . ?
C235 C234 H234 120.6 . . ?
C236 C235 C234 121.6(12) . . ?
C236 C235 H235 119.2 . . ?
C234 C235 H235 119.2 . . ?
C235 C236 C231 119.6(12) . . ?
C235 C236 H236 120.2 . . ?
C231 C236 H236 120.2 . . ?
C252 C251 C256 118.0(11) . . ?
C252 C251 C25 122.6(11) . . ?
C256 C251 C25 119.3(11) . . ?
C251 C252 C253 123.1(14) . . ?
C251 C252 H252 118.4 . . ?
C253 C252 H252 118.4 . . ?
C252 C253 C254 120.0(14) . . ?
C252 C253 H253 120.0 . . ?
C254 C253 H253 120.0 . . ?
C255 C254 C253 119.5(12) . . ?
C255 C254 H254 120.2 . . ?
C253 C254 H254 120.2 . . ?
C254 C255 C256 120.8(12) . . ?
C254 C255 H255 119.6 . . ?
C256 C255 H255 119.6 . . ?
C255 C256 C251 118.5(12) . . ?
C255 C256 H256 120.7 . . ?
C251 C256 H256 120.7 . . ?
C35 N31 N32 108.0(9) . . ?
C35 N31 Pt1 134.9(7) . . ?
N32 N31 Pt1 116.3(7) . . ?
C33 N32 N31 108.7(9) . . ?
C33 N32 Ag2 131.2(7) . . ?
N31 N32 Ag2 119.0(6) . . ?
N32 C33 C34 108.4(10) . . ?
N32 C33 C331 123.7(10) . . ?
C34 C33 C331 127.8(10) . . ?
C35 C34 C33 105.9(11) . . ?
C35 C34 H34 127.0 . . ?
C33 C34 H34 127.0 . . ?
N31 C35 C34 108.9(10) . . ?
N31 C35 C351 125.2(10) . . ?
C34 C35 C351 125.9(10) . . ?
C336 C331 C332 117.8(11) . . ?
C336 C331 C33 118.8(10) . . ?
C332 C331 C33 123.4(10) . . ?
C333 C332 C331 120.3(11) . . ?
C333 C332 H332 119.8 . . ?
C331 C332 H332 119.8 . . ?
C332 C333 C334 120.7(12) . . ?
C332 C333 H333 119.7 . . ?
C334 C333 H333 119.7 . . ?
C335 C334 C333 120.3(12) . . ?
C335 C334 H334 119.9 . . ?
C333 C334 H334 119.9 . . ?
C334 C335 C336 119.7(12) . . ?
C334 C335 H335 120.1 . . ?
C336 C335 H335 120.1 . . ?
C335 C336 C331 121.1(12) . . ?
C335 C336 H336 119.4 . . ?
C331 C336 H336 119.4 . . ?
C356 C351 C352 118.2(10) . . ?
C356 C351 C35 125.5(10) . . ?
C352 C351 C35 116.3(10) . . ?
C353 C352 C351 118.9(11) . . ?
C353 C352 H352 120.5 . . ?
C351 C352 H352 120.5 . . ?
C354 C353 C352 123.3(12) . . ?
C354 C353 H353 118.4 . . ?
C352 C353 H353 118.4 . . ?
C353 C354 C355 118.3(11) . . ?
C353 C354 H354 120.9 . . ?
C355 C354 H354 120.9 . . ?
C356 C355 C354 119.2(12) . . ?
C356 C355 H355 120.4 . . ?
C354 C355 H355 120.4 . . ?
C351 C356 C355 122.0(11) . . ?
C351 C356 H356 119.0 . . ?
C355 C356 H356 119.0 . . ?
C46 N41 C42 120.8(10) . . ?
C46 N41 Pt2 123.6(8) . . ?
C42 N41 Pt2 115.3(7) . . ?
N41 C42 C43 118.1(12) . . ?
N41 C42 C421 112.8(10) . . ?
C43 C42 C421 129.1(12) . . ?
C44 C43 C42 120.1(13) . . ?
C44 C43 H43 119.9 . . ?
C42 C43 H43 119.9 . . ?
C45 C44 C43 120.5(13) . . ?
C45 C44 H44 119.7 . . ?
C43 C44 H44 119.7 . . ?
C44 C45 C46 119.4(13) . . ?
C44 C45 H45 120.3 . . ?
C46 C45 H45 120.3 . . ?
N41 C46 C45 120.7(12) . . ?
N41 C46 H46 119.7 . . ?
C45 C46 H46 119.7 . . ?
C426 C421 C422 116.8(11) . . ?
C426 C421 C42 126.0(11) . . ?
C422 C421 C42 117.1(11) . . ?
C423 C422 C421 120.3(11) . . ?
C423 C422 Pt2 127.8(9) . . ?
C421 C422 Pt2 111.7(8) . . ?
C424 C423 C422 119.3(12) . . ?
C424 C423 H423 120.4 . . ?
C422 C423 H423 120.4 . . ?
F424 C424 C423 120.1(12) . . ?
F424 C424 C425 117.0(11) . . ?
C423 C424 C425 122.9(12) . . ?
C426 C425 C424 117.6(11) . . ?
C426 C425 H425 121.2 . . ?
C424 C425 H425 121.2 . . ?
C425 C426 F426 119.7(12) . . ?
C425 C426 C421 123.0(12) . . ?
F426 C426 C421 117.2(11) . . ?
C55 N51 N52 107.6(9) . . ?
C55 N51 Pt2 131.9(7) . . ?
N52 N51 Pt2 119.8(6) . . ?
C53 N52 N51 108.1(8) . . ?
C53 N52 Ag2 131.2(7) . . ?
N51 N52 Ag2 117.4(7) . . ?
N52 C53 C54 108.5(10) . . ?
N52 C53 C531 122.4(10) . . ?
C54 C53 C531 129.1(10) . . ?
C53 C54 C55 106.4(10) . . ?
C53 C54 H54 126.8 . . ?
C55 C54 H54 126.8 . . ?
N51 C55 C54 109.3(10) . . ?
N51 C55 C551 121.5(10) . . ?
C54 C55 C551 129.1(10) . . ?
C532 C531 C536 119.7(11) . . ?
C532 C531 C53 121.5(11) . . ?
C536 C531 C53 118.7(10) . . ?
C531 C532 C533 120.7(12) . . ?
C531 C532 H532 119.6 . . ?
C533 C532 H532 119.6 . . ?
C534 C533 C532 119.2(12) . . ?
C534 C533 H533 120.4 . . ?
C532 C533 H533 120.4 . . ?
C533 C534 C535 120.4(12) . . ?
C533 C534 H534 119.8 . . ?
C535 C534 H534 119.8 . . ?
C536 C535 C534 120.2(12) . . ?
C536 C535 H535 119.9 . . ?
C534 C535 H535 119.9 . . ?
C531 C536 C535 119.6(11) . . ?
C531 C536 H536 120.2 . . ?
C535 C536 H536 120.2 . . ?
C552 C551 C556 118.4(11) . . ?
C552 C551 C55 121.0(11) . . ?
C556 C551 C55 120.5(10) . . ?
C553 C552 C551 121.5(12) . . ?
C553 C552 H552 119.2 . . ?
C551 C552 H552 119.2 . . ?
C552 C553 C554 118.7(12) . . ?
C552 C553 H553 120.7 . . ?
C554 C553 H553 120.7 . . ?
C555 C554 C553 121.4(11) . . ?
C555 C554 H554 119.3 . . ?
C553 C554 H554 119.3 . . ?
C554 C555 C556 119.1(12) . . ?
C554 C555 H555 120.4 . . ?
C556 C555 H555 120.4 . . ?
C551 C556 C555 120.9(11) . . ?
C551 C556 H556 119.6 . . ?
C555 C556 H556 119.6 . . ?
C65 N61 N62 108.4(8) . . ?
C65 N61 Pt2 135.8(7) . . ?
N62 N61 Pt2 114.2(6) . . ?
C63 N62 N61 106.8(8) . . ?
C63 N62 Ag1 131.0(7) . . ?
N61 N62 Ag1 121.8(6) . . ?
N62 C63 C64 109.8(10) . . ?
N62 C63 C631 122.0(10) . . ?
C64 C63 C631 128.1(10) . . ?
C63 C64 C65 106.3(10) . . ?
C63 C64 H64 126.9 . . ?
C65 C64 H64 126.9 . . ?
N61 C65 C64 108.5(9) . . ?
N61 C65 C651 124.8(10) . . ?
C64 C65 C651 126.1(11) . . ?
C632 C631 C636 118.8(10) . . ?
C632 C631 C63 119.5(10) . . ?
C636 C631 C63 121.7(10) . . ?
C633 C632 C631 119.4(12) . . ?
C633 C632 H632 120.3 . . ?
C631 C632 H632 120.3 . . ?
C632 C633 C634 121.3(12) . . ?
C632 C633 H633 119.3 . . ?
C634 C633 H633 119.3 . . ?
C633 C634 C635 119.0(11) . . ?
C633 C634 H634 120.5 . . ?
C635 C634 H634 120.5 . . ?
C636 C635 C634 120.5(12) . . ?
C636 C635 H635 119.8 . . ?
C634 C635 H635 119.8 . . ?
C635 C636 C631 121.0(11) . . ?
C635 C636 H636 119.5 . . ?
C631 C636 H636 119.5 . . ?
C652 C651 C656 115.9(10) . . ?
C652 C651 C65 120.2(10) . . ?
C656 C651 C65 123.6(10) . . ?
C653 C652 C651 121.2(11) . . ?
C653 C652 H652 119.4 . . ?
C651 C652 H652 119.4 . . ?
C652 C653 C654 122.4(11) . . ?
C652 C653 H653 118.8 . . ?
C654 C653 H653 118.8 . . ?
C653 C654 C655 119.2(11) . . ?
C653 C654 H654 120.4 . . ?
C655 C654 H654 120.4 . . ?
C656 C655 C654 117.7(12) . . ?
C656 C655 H655 121.1 . . ?
C654 C655 H655 121.1 . . ?
C655 C656 C651 123.6(12) . . ?
C655 C656 H656 118.2 . . ?
C651 C656 H656 118.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C122 Pt1 Ag1 N62 -55.6(4) . . . . ?
N11 Pt1 Ag1 N62 16.0(4) . . . . ?
N21 Pt1 Ag1 N62 -158.0(4) . . . . ?
N31 Pt1 Ag1 N62 124.9(4) . . . . ?
C122 Pt1 Ag1 N22 106.3(4) . . . . ?
N11 Pt1 Ag1 N22 177.9(4) . . . . ?
N21 Pt1 Ag1 N22 3.9(4) . . . . ?
N31 Pt1 Ag1 N22 -73.2(4) . . . . ?
C122 Pt1 Ag1 Ag2 -164.7(3) . . . . ?
N11 Pt1 Ag1 Ag2 -93.1(3) . . . . ?
N21 Pt1 Ag1 Ag2 93.0(3) . . . . ?
N31 Pt1 Ag1 Ag2 15.8(3) . . . . ?
N62 Ag1 Ag2 N32 -150.0(4) . . . . ?
N22 Ag1 Ag2 N32 40.5(4) . . . . ?
Pt1 Ag1 Ag2 N32 -23.8(3) . . . . ?
N62 Ag1 Ag2 N52 35.1(4) . . . . ?
N22 Ag1 Ag2 N52 -134.5(3) . . . . ?
Pt1 Ag1 Ag2 N52 161.2(3) . . . . ?
C122 Pt1 N11 C16 -179.9(9) . . . . ?
N21 Pt1 N11 C16 -159(3) . . . . ?
N31 Pt1 N11 C16 -5.2(9) . . . . ?
Ag1 Pt1 N11 C16 113.5(9) . . . . ?
C122 Pt1 N11 C12 -11.4(8) . . . . ?
N21 Pt1 N11 C12 9(4) . . . . ?
N31 Pt1 N11 C12 163.3(8) . . . . ?
Ag1 Pt1 N11 C12 -78.0(8) . . . . ?
C16 N11 C12 C13 3.1(16) . . . . ?
Pt1 N11 C12 C13 -166.3(9) . . . . ?
C16 N11 C12 C121 -177.8(9) . . . . ?
Pt1 N11 C12 C121 12.9(11) . . . . ?
N11 C12 C13 C14 -0.8(18) . . . . ?
C121 C12 C13 C14 -179.8(11) . . . . ?
C12 C13 C14 C15 -3(2) . . . . ?
C13 C14 C15 C16 5(2) . . . . ?
C12 N11 C16 C15 -1.4(17) . . . . ?
Pt1 N11 C16 C15 166.8(9) . . . . ?
C14 C15 C16 N11 -2.4(19) . . . . ?
N11 C12 C121 C126 174.7(11) . . . . ?
C13 C12 C121 C126 -6.2(19) . . . . ?
N11 C12 C121 C122 -6.8(14) . . . . ?
C13 C12 C121 C122 172.4(11) . . . . ?
C126 C121 C122 C123 1.5(15) . . . . ?
C12 C121 C122 C123 -177.2(10) . . . . ?
C126 C121 C122 Pt1 176.3(8) . . . . ?
C12 C121 C122 Pt1 -2.4(12) . . . . ?
N11 Pt1 C122 C123 -178.5(10) . . . . ?
N21 Pt1 C122 C123 3.4(10) . . . . ?
N31 Pt1 C122 C123 118(4) . . . . ?
Ag1 Pt1 C122 C123 -57.1(9) . . . . ?
N11 Pt1 C122 C121 7.2(7) . . . . ?
N21 Pt1 C122 C121 -170.9(7) . . . . ?
N31 Pt1 C122 C121 -56(4) . . . . ?
Ag1 Pt1 C122 C121 128.6(7) . . . . ?
C121 C122 C123 C124 -1.7(15) . . . . ?
Pt1 C122 C123 C124 -175.6(8) . . . . ?
C122 C123 C124 F124 -179.4(9) . . . . ?
C122 C123 C124 C125 0.2(18) . . . . ?
F124 C124 C125 C126 -179.1(9) . . . . ?
C123 C124 C125 C126 1.2(18) . . . . ?
C122 C121 C126 F126 178.4(9) . . . . ?
C12 C121 C126 F126 -3.0(18) . . . . ?
C122 C121 C126 C125 0.1(18) . . . . ?
C12 C121 C126 C125 178.6(11) . . . . ?
C124 C125 C126 C121 -1.4(18) . . . . ?
C124 C125 C126 F126 -179.8(10) . . . . ?
C122 Pt1 N21 C25 96.3(9) . . . . ?
N11 Pt1 N21 C25 76(4) . . . . ?
N31 Pt1 N21 C25 -78.4(9) . . . . ?
Ag1 Pt1 N21 C25 165.8(10) . . . . ?
C122 Pt1 N21 N22 -75.9(8) . . . . ?
N11 Pt1 N21 N22 -96(4) . . . . ?
N31 Pt1 N21 N22 109.5(8) . . . . ?
Ag1 Pt1 N21 N22 -6.4(6) . . . . ?
C25 N21 N22 C23 1.1(12) . . . . ?
Pt1 N21 N22 C23 174.6(7) . . . . ?
C25 N21 N22 Ag1 -164.0(7) . . . . ?
Pt1 N21 N22 Ag1 9.5(9) . . . . ?
N62 Ag1 N22 C23 -25.8(17) . . . . ?
Ag2 Ag1 N22 C23 127.4(11) . . . . ?
Pt1 Ag1 N22 C23 -164.5(12) . . . . ?
N62 Ag1 N22 N21 133.1(9) . . . . ?
Ag2 Ag1 N22 N21 -73.8(6) . . . . ?
Pt1 Ag1 N22 N21 -5.6(6) . . . . ?
N21 N22 C23 C24 -1.5(13) . . . . ?
Ag1 N22 C23 C24 158.4(9) . . . . ?
N21 N22 C23 C231 179.2(10) . . . . ?
Ag1 N22 C23 C231 -21.0(18) . . . . ?
N22 C23 C24 C25 1.3(13) . . . . ?
C231 C23 C24 C25 -179.3(11) . . . . ?
N22 N21 C25 C24 -0.3(12) . . . . ?
Pt1 N21 C25 C24 -173.1(8) . . . . ?
N22 N21 C25 C251 177.0(10) . . . . ?
Pt1 N21 C25 C251 4.2(16) . . . . ?
C23 C24 C25 N21 -0.6(13) . . . . ?
C23 C24 C25 C251 -177.6(12) . . . . ?
N22 C23 C231 C232 7.4(18) . . . . ?
C24 C23 C231 C232 -171.8(12) . . . . ?
N22 C23 C231 C236 -169.1(10) . . . . ?
C24 C23 C231 C236 11.6(18) . . . . ?
C236 C231 C232 C233 -1.8(18) . . . . ?
C23 C231 C232 C233 -178.3(11) . . . . ?
C231 C232 C233 C234 0(2) . . . . ?
C232 C233 C234 C235 1(2) . . . . ?
C233 C234 C235 C236 0(2) . . . . ?
C234 C235 C236 C231 -1(2) . . . . ?
C232 C231 C236 C235 2.5(18) . . . . ?
C23 C231 C236 C235 179.2(12) . . . . ?
N21 C25 C251 C252 -83.2(15) . . . . ?
C24 C25 C251 C252 93.4(17) . . . . ?
N21 C25 C251 C256 98.7(13) . . . . ?
C24 C25 C251 C256 -84.7(16) . . . . ?
C256 C251 C252 C253 1(2) . . . . ?
C25 C251 C252 C253 -177.7(12) . . . . ?
C251 C252 C253 C254 -1(2) . . . . ?
C252 C253 C254 C255 1(2) . . . . ?
C253 C254 C255 C256 0(2) . . . . ?
C254 C255 C256 C251 -0.7(18) . . . . ?
C252 C251 C256 C255 0.4(17) . . . . ?
C25 C251 C256 C255 178.6(10) . . . . ?
C122 Pt1 N31 C35 -10(4) . . . . ?
N11 Pt1 N31 C35 -72.4(11) . . . . ?
N21 Pt1 N31 C35 105.2(11) . . . . ?
Ag1 Pt1 N31 C35 165.4(10) . . . . ?
C122 Pt1 N31 N32 -178(3) . . . . ?
N11 Pt1 N31 N32 118.9(7) . . . . ?
N21 Pt1 N31 N32 -63.5(7) . . . . ?
Ag1 Pt1 N31 N32 -3.3(8) . . . . ?
C35 N31 N32 C33 0.7(11) . . . . ?
Pt1 N31 N32 C33 172.4(7) . . . . ?
C35 N31 N32 Ag2 170.4(7) . . . . ?
Pt1 N31 N32 Ag2 -18.0(9) . . . . ?
N52 Ag2 N32 C33 1(2) . . . . ?
Ag1 Ag2 N32 C33 -157.5(9) . . . . ?
N52 Ag2 N32 N31 -165.5(12) . . . . ?
Ag1 Ag2 N32 N31 35.6(8) . . . . ?
N31 N32 C33 C34 -1.0(12) . . . . ?
Ag2 N32 C33 C34 -169.0(7) . . . . ?
N31 N32 C33 C331 -178.9(10) . . . . ?
Ag2 N32 C33 C331 13.2(16) . . . . ?
N32 C33 C34 C35 0.9(12) . . . . ?
C331 C33 C34 C35 178.6(11) . . . . ?
N32 N31 C35 C34 -0.1(12) . . . . ?
Pt1 N31 C35 C34 -169.5(8) . . . . ?
N32 N31 C35 C351 -178.2(9) . . . . ?
Pt1 N31 C35 C351 12.4(17) . . . . ?
C33 C34 C35 N31 -0.5(12) . . . . ?
C33 C34 C35 C351 177.6(10) . . . . ?
N32 C33 C331 C336 -160.7(11) . . . . ?
C34 C33 C331 C336 21.9(18) . . . . ?
N32 C33 C331 C332 21.2(17) . . . . ?
C34 C33 C331 C332 -156.2(12) . . . . ?
C336 C331 C332 C333 -0.8(18) . . . . ?
C33 C331 C332 C333 177.4(11) . . . . ?
C331 C332 C333 C334 0.1(19) . . . . ?
C332 C333 C334 C335 -1(2) . . . . ?
C333 C334 C335 C336 3(2) . . . . ?
C334 C335 C336 C331 -4(2) . . . . ?
C332 C331 C336 C335 2.6(19) . . . . ?
C33 C331 C336 C335 -175.7(11) . . . . ?
N31 C35 C351 C356 -5.8(17) . . . . ?
C34 C35 C351 C356 176.5(11) . . . . ?
N31 C35 C351 C352 174.9(10) . . . . ?
C34 C35 C351 C352 -2.8(16) . . . . ?
C356 C351 C352 C353 3.1(17) . . . . ?
C35 C351 C352 C353 -177.5(11) . . . . ?
C351 C352 C353 C354 -1(2) . . . . ?
C352 C353 C354 C355 0(2) . . . . ?
C353 C354 C355 C356 -1.7(18) . . . . ?
C352 C351 C356 C355 -4.5(17) . . . . ?
C35 C351 C356 C355 176.2(10) . . . . ?
C354 C355 C356 C351 3.8(18) . . . . ?
C422 Pt2 N41 C46 174.1(9) . . . . ?
N51 Pt2 N41 C46 -177(34) . . . . ?
N61 Pt2 N41 C46 -9.6(9) . . . . ?
C422 Pt2 N41 C42 -12.0(8) . . . . ?
N51 Pt2 N41 C42 -3(7) . . . . ?
N61 Pt2 N41 C42 164.4(8) . . . . ?
C46 N41 C42 C43 6.2(16) . . . . ?
Pt2 N41 C42 C43 -168.0(9) . . . . ?
C46 N41 C42 C421 -173.8(10) . . . . ?
Pt2 N41 C42 C421 12.0(12) . . . . ?
N41 C42 C43 C44 -5.3(18) . . . . ?
C421 C42 C43 C44 174.7(13) . . . . ?
C42 C43 C44 C45 1(2) . . . . ?
C43 C44 C45 C46 3(2) . . . . ?
C42 N41 C46 C45 -2.8(17) . . . . ?
Pt2 N41 C46 C45 170.8(9) . . . . ?
C44 C45 C46 N41 -1.7(19) . . . . ?
N41 C42 C421 C426 172.9(11) . . . . ?
C43 C42 C421 C426 -7(2) . . . . ?
N41 C42 C421 C422 -4.2(15) . . . . ?
C43 C42 C421 C422 175.8(11) . . . . ?
C426 C421 C422 C423 1.6(15) . . . . ?
C42 C421 C422 C423 179.0(10) . . . . ?
C426 C421 C422 Pt2 177.2(8) . . . . ?
C42 C421 C422 Pt2 -5.4(12) . . . . ?
N51 Pt2 C422 C423 4.7(10) . . . . ?
N41 Pt2 C422 C423 -175.8(10) . . . . ?
N61 Pt2 C422 C423 134(4) . . . . ?
N51 Pt2 C422 C421 -170.5(7) . . . . ?
N41 Pt2 C422 C421 9.0(7) . . . . ?
N61 Pt2 C422 C421 -42(5) . . . . ?
C421 C422 C423 C424 -1.4(16) . . . . ?
Pt2 C422 C423 C424 -176.2(8) . . . . ?
C422 C423 C424 F424 179.7(10) . . . . ?
C422 C423 C424 C425 1.8(19) . . . . ?
F424 C424 C425 C426 179.6(11) . . . . ?
C423 C424 C425 C426 -2.5(19) . . . . ?
C424 C425 C426 F426 179.2(11) . . . . ?
C424 C425 C426 C421 2.8(19) . . . . ?
C422 C421 C426 C425 -2.4(17) . . . . ?
C42 C421 C426 C425 -179.5(12) . . . . ?
C422 C421 C426 F426 -178.9(10) . . . . ?
C42 C421 C426 F426 3.9(18) . . . . ?
C422 Pt2 N51 C55 107.3(9) . . . . ?
N41 Pt2 N51 C55 98(7) . . . . ?
N61 Pt2 N51 C55 -69.0(9) . . . . ?
C422 Pt2 N51 N52 -83.1(7) . . . . ?
N41 Pt2 N51 N52 -92(7) . . . . ?
N61 Pt2 N51 N52 100.5(7) . . . . ?
C55 N51 N52 C53 -0.7(11) . . . . ?
Pt2 N51 N52 C53 -172.5(7) . . . . ?
C55 N51 N52 Ag2 -162.4(6) . . . . ?
Pt2 N51 N52 Ag2 25.7(9) . . . . ?
N32 Ag2 N52 C53 -40(2) . . . . ?
Ag1 Ag2 N52 C53 121.3(9) . . . . ?
N32 Ag2 N52 N51 117.2(14) . . . . ?
Ag1 Ag2 N52 N51 -82.0(6) . . . . ?
N51 N52 C53 C54 0.5(12) . . . . ?
Ag2 N52 C53 C54 158.8(8) . . . . ?
N51 N52 C53 C531 179.9(9) . . . . ?
Ag2 N52 C53 C531 -21.8(15) . . . . ?
N52 C53 C54 C55 -0.1(12) . . . . ?
C531 C53 C54 C55 -179.5(11) . . . . ?
N52 N51 C55 C54 0.6(11) . . . . ?
Pt2 N51 C55 C54 171.1(7) . . . . ?
N52 N51 C55 C551 177.4(9) . . . . ?
Pt2 N51 C55 C551 -12.1(15) . . . . ?
C53 C54 C55 N51 -0.3(12) . . . . ?
C53 C54 C55 C551 -176.8(10) . . . . ?
N52 C53 C531 C532 -31.9(17) . . . . ?
C54 C53 C531 C532 147.4(12) . . . . ?
N52 C53 C531 C536 151.0(11) . . . . ?
C54 C53 C531 C536 -29.7(18) . . . . ?
C536 C531 C532 C533 -2.8(19) . . . . ?
C53 C531 C532 C533 -180.0(12) . . . . ?
C531 C532 C533 C534 3(2) . . . . ?
C532 C533 C534 C535 0(2) . . . . ?
C533 C534 C535 C536 -2(2) . . . . ?
C532 C531 C536 C535 0.2(18) . . . . ?
C53 C531 C536 C535 177.3(11) . . . . ?
C534 C535 C536 C531 2(2) . . . . ?
N51 C55 C551 C552 139.5(11) . . . . ?
C54 C55 C551 C552 -44.3(17) . . . . ?
N51 C55 C551 C556 -45.0(15) . . . . ?
C54 C55 C551 C556 131.2(12) . . . . ?
C556 C551 C552 C553 -0.5(18) . . . . ?
C55 C551 C552 C553 175.1(11) . . . . ?
C551 C552 C553 C554 -0.8(19) . . . . ?
C552 C553 C554 C555 2.3(19) . . . . ?
C553 C554 C555 C556 -2.6(18) . . . . ?
C552 C551 C556 C555 0.3(16) . . . . ?
C55 C551 C556 C555 -175.3(10) . . . . ?
C554 C555 C556 C551 1.2(17) . . . . ?
C422 Pt2 N61 C65 -41(5) . . . . ?
N51 Pt2 N61 C65 87.8(11) . . . . ?
N41 Pt2 N61 C65 -91.5(11) . . . . ?
C422 Pt2 N61 N62 155(4) . . . . ?
N51 Pt2 N61 N62 -75.6(7) . . . . ?
N41 Pt2 N61 N62 105.0(7) . . . . ?
C65 N61 N62 C63 1.9(11) . . . . ?
Pt2 N61 N62 C63 169.9(7) . . . . ?
C65 N61 N62 Ag1 -171.4(7) . . . . ?
Pt2 N61 N62 Ag1 -3.4(9) . . . . ?
N22 Ag1 N62 C63 8.7(16) . . . . ?
Ag2 Ag1 N62 C63 -140.6(9) . . . . ?
Pt1 Ag1 N62 C63 136.8(8) . . . . ?
N22 Ag1 N62 N61 -179.8(8) . . . . ?
Ag2 Ag1 N62 N61 30.9(8) . . . . ?
Pt1 Ag1 N62 N61 -51.7(8) . . . . ?
N61 N62 C63 C64 -2.8(12) . . . . ?
Ag1 N62 C63 C64 169.6(7) . . . . ?
N61 N62 C63 C631 174.8(9) . . . . ?
Ag1 N62 C63 C631 -12.7(16) . . . . ?
N62 C63 C64 C65 2.6(13) . . . . ?
C631 C63 C64 C65 -174.8(11) . . . . ?
N62 N61 C65 C64 -0.3(12) . . . . ?
Pt2 N61 C65 C64 -164.4(8) . . . . ?
N62 N61 C65 C651 -172.1(10) . . . . ?
Pt2 N61 C65 C651 23.8(17) . . . . ?
C63 C64 C65 N61 -1.4(13) . . . . ?
C63 C64 C65 C651 170.2(11) . . . . ?
N62 C63 C631 C632 -31.0(17) . . . . ?
C64 C63 C631 C632 146.1(12) . . . . ?
N62 C63 C631 C636 148.3(11) . . . . ?
C64 C63 C631 C636 -34.5(19) . . . . ?
C636 C631 C632 C633 2.3(18) . . . . ?
C63 C631 C632 C633 -178.3(11) . . . . ?
C631 C632 C633 C634 -1.9(19) . . . . ?
C632 C633 C634 C635 1.0(19) . . . . ?
C633 C634 C635 C636 -0.6(19) . . . . ?
C634 C635 C636 C631 1.1(19) . . . . ?
C632 C631 C636 C635 -2.0(18) . . . . ?
C63 C631 C636 C635 178.7(11) . . . . ?
N61 C65 C651 C652 -166.7(11) . . . . ?
C64 C65 C651 C652 23.0(17) . . . . ?
N61 C65 C651 C656 20.9(17) . . . . ?
C64 C65 C651 C656 -149.4(12) . . . . ?
C656 C651 C652 C653 1.6(16) . . . . ?
C65 C651 C652 C653 -171.4(10) . . . . ?
C651 C652 C653 C654 -0.5(17) . . . . ?
C652 C653 C654 C655 -0.4(17) . . . . ?
C653 C654 C655 C656 0.2(16) . . . . ?
C654 C655 C656 C651 0.9(16) . . . . ?
C652 C651 C656 C655 -1.8(16) . . . . ?
C65 C651 C656 C655 170.9(10) . . . . ?
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3a
_database_code_depnum_ccdc_archive 'CCDC 1535611'
_audit_update_record             
;
2017-03-02 deposited with the CCDC.
2017-05-19 downloaded from the CCDC.
;

#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C85.8 H67 Ag3 B Cl4.2 F4 N10 Pt2'
_chemical_formula_moiety         
'C82 H60 Ag3 B F4 N10 Pt2, 1.4(C H Cl3), 0.4(C6 H14)'
_chemical_formula_weight         2187.63
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_space_group_crystal_system      triclinic
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
_space_group_IT_number           2
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,-Y,-Z
#------------------------------------------------------------------------------
_cell_length_a                   14.001(2)
_cell_length_b                   16.562(3)
_cell_length_c                   20.395(4)
_cell_angle_alpha                101.594(2)
_cell_angle_beta                 101.990(2)
_cell_angle_gamma                100.392(2)
_cell_volume                     4408.4(14)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    11195
_cell_measurement_theta_min      1.62
_cell_measurement_theta_max      26.02
_cell_measurement_temperature    273
#------------------------------------------------------------------------------
_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.140
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.030
_exptl_crystal_density_diffrn    1.648
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2122.40
_exptl_absorpt_coefficient_mu    3.985
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_correction_T_min  0.755
_exptl_absorpt_correction_T_max  0.887

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      273
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 29.257
_diffrn_reflns_number            33257
_diffrn_reflns_av_R_equivalents  0.0364
_diffrn_reflns_theta_max         26.030
_diffrn_reflns_theta_min         1.622
_diffrn_reflns_theta_full        26.030
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measured_fraction_theta_full 0.976
_diffrn_reflns_Laue_measured_fraction_max 0.000
_diffrn_reflns_Laue_measured_fraction_full 0.000
_diffrn_reflns_point_group_measured_fraction_max 0.000
_diffrn_reflns_point_group_measured_fraction_full 0.000
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_reflns_number_total             16971
_reflns_number_gt                13406
_reflns_threshold_expression     F²>2.0σ(F²)

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_all          0.0862
_refine_ls_R_factor_gt           0.0698
_refine_ls_wR_factor_ref         0.1886
_refine_ls_wR_factor_gt          0.1741
_refine_ls_number_restraints     20
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_reflns         16971
_refine_ls_number_parameters     986
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0858P)²+63.3568P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.000
_refine_diff_density_max         3.45
_refine_diff_density_min         -2.33
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
B B 0.0013 0.0007
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.37799(3) 0.89575(3) 0.311155(19) 0.02226(12) Uani 1 1 d . . .
Pt2 Pt 0.55160(3) 0.65805(3) 0.22969(2) 0.02476(12) Uani 1 1 d . . .
Ag1 Ag 0.34423(6) 0.72140(5) 0.17863(4) 0.02390(18) Uani 1 1 d . . .
Ag2 Ag 0.55109(6) 0.86468(5) 0.22516(4) 0.02514(19) Uani 1 1 d . . .
Ag3 Ag 0.47700(6) 0.76329(5) 0.32226(4) 0.02671(19) Uani 1 1 d . . .
N11 N 0.5096(6) 0.9873(5) 0.3520(5) 0.0241(19) Uani 1 1 d . . .
C12 C 0.5647(8) 0.9811(8) 0.4144(5) 0.029(3) Uani 1 1 d . . .
C13 C 0.6558(8) 1.0383(8) 0.4456(6) 0.033(3) Uani 1 1 d . . .
H13 H 0.6950 1.0333 0.4868 0.040 Uiso 1 1 calc R . .
C14 C 0.6893(9) 1.1026(8) 0.4163(7) 0.038(3) Uani 1 1 d . . .
H14 H 0.7506 1.1410 0.4372 0.045 Uiso 1 1 calc R . .
C15 C 0.6301(9) 1.1086(8) 0.3555(6) 0.034(3) Uani 1 1 d . . .
H15 H 0.6512 1.1516 0.3349 0.041 Uiso 1 1 calc R . .
C16 C 0.5391(8) 1.0511(7) 0.3248(6) 0.027(2) Uani 1 1 d . . .
H16 H 0.4982 1.0570 0.2848 0.033 Uiso 1 1 calc R . .
C121 C 0.5178(8) 0.9129(7) 0.4414(6) 0.027(2) Uani 1 1 d . . .
C122 C 0.4231(8) 0.8646(7) 0.4006(5) 0.026(2) Uani 1 1 d . . .
C123 C 0.3756(8) 0.7983(7) 0.4246(5) 0.023(2) Uani 1 1 d . . .
H123 H 0.3132 0.7652 0.3985 0.028 Uiso 1 1 calc R . .
C124 C 0.4197(9) 0.7805(8) 0.4869(6) 0.033(3) Uani 1 1 d . . .
H124 H 0.3868 0.7364 0.5017 0.040 Uiso 1 1 calc R . .
C125 C 0.5147(8) 0.8306(8) 0.5267(6) 0.030(2) Uani 1 1 d . . .
H125 H 0.5451 0.8197 0.5681 0.036 Uiso 1 1 calc R . .
C126 C 0.5613(9) 0.8955(8) 0.5036(6) 0.034(3) Uani 1 1 d . . .
H126 H 0.6235 0.9287 0.5301 0.041 Uiso 1 1 calc R . .
N21 N 0.2461(6) 0.8086(5) 0.2821(4) 0.0188(17) Uani 1 1 d . . .
N22 N 0.2345(6) 0.7353(6) 0.2331(4) 0.0229(19) Uani 1 1 d . . .
C23 C 0.1437(8) 0.6853(7) 0.2292(5) 0.025(2) Uani 1 1 d . . .
C24 C 0.1000(8) 0.7292(8) 0.2766(6) 0.031(3) Uani 1 1 d . . .
H24 H 0.0380 0.7099 0.2848 0.037 Uiso 1 1 calc R . .
C25 C 0.1653(7) 0.8057(7) 0.3087(5) 0.022(2) Uani 1 1 d . . .
C231 C 0.1047(8) 0.6019(8) 0.1822(6) 0.031(3) Uani 1 1 d . . .
C232 C 0.0449(11) 0.5385(8) 0.2007(7) 0.044(3) Uani 1 1 d . . .
H232 H 0.0311 0.5508 0.2438 0.053 Uiso 1 1 calc R . .
C233 C 0.0051(12) 0.4584(9) 0.1585(8) 0.056(4) Uani 1 1 d . . .
H233 H -0.0345 0.4174 0.1729 0.067 Uiso 1 1 calc R . .
C234 C 0.0252(11) 0.4401(9) 0.0945(8) 0.057(4) Uani 1 1 d . . .
H234 H -0.0004 0.3860 0.0655 0.069 Uiso 1 1 calc R . .
C235 C 0.0838(10) 0.5023(9) 0.0726(7) 0.042(3) Uani 1 1 d . . .
H235 H 0.0954 0.4903 0.0288 0.051 Uiso 1 1 calc R . .
C236 C 0.1240(8) 0.5819(8) 0.1173(6) 0.036(3) Uani 1 1 d . . .
H236 H 0.1648 0.6229 0.1036 0.043 Uiso 1 1 calc R . .
C251 C 0.1533(8) 0.8757(7) 0.3629(5) 0.025(2) Uani 1 1 d . . .
C252 C 0.1106(8) 0.8544(8) 0.4134(6) 0.032(3) Uani 1 1 d . . .
H252 H 0.0931 0.7980 0.4147 0.039 Uiso 1 1 calc R . .
C253 C 0.0931(8) 0.9181(9) 0.4633(6) 0.036(3) Uani 1 1 d . . .
H253 H 0.0627 0.9038 0.4972 0.043 Uiso 1 1 calc R . .
C254 C 0.1209(9) 1.0013(9) 0.4620(6) 0.036(3) Uani 1 1 d . . .
H254 H 0.1104 1.0433 0.4957 0.043 Uiso 1 1 calc R . .
C255 C 0.1646(8) 1.0240(8) 0.4108(6) 0.034(3) Uani 1 1 d . . .
H255 H 0.1821 1.0804 0.4096 0.041 Uiso 1 1 calc R . .
C256 C 0.1816(8) 0.9602(7) 0.3616(5) 0.028(2) Uani 1 1 d . . .
H256 H 0.2120 0.9742 0.3277 0.034 Uiso 1 1 calc R . .
N31 N 0.3549(6) 0.9227(6) 0.2123(4) 0.0230(19) Uani 1 1 d . . .
N32 N 0.4369(7) 0.9190(6) 0.1856(4) 0.026(2) Uani 1 1 d . . .
C33 C 0.4336(8) 0.9644(7) 0.1368(5) 0.023(2) Uani 1 1 d . . .
C34 C 0.3486(8) 0.9979(7) 0.1331(6) 0.031(3) Uani 1 1 d . . .
H34 H 0.3277 1.0322 0.1046 0.037 Uiso 1 1 calc R . .
C35 C 0.3015(8) 0.9697(7) 0.1806(5) 0.024(2) Uani 1 1 d . . .
C331 C 0.5131(8) 0.9713(8) 0.1003(6) 0.030(2) Uani 1 1 d . . .
C332 C 0.5562(9) 0.9032(7) 0.0811(6) 0.030(2) Uani 1 1 d . . .
H332 H 0.5307 0.8502 0.0873 0.037 Uiso 1 1 calc R . .
C333 C 0.6373(9) 0.9158(9) 0.0526(7) 0.040(3) Uani 1 1 d . . .
H333 H 0.6656 0.8704 0.0394 0.048 Uiso 1 1 calc R . .
C334 C 0.6766(10) 0.9919(10) 0.0435(7) 0.048(4) Uani 1 1 d . . .
H334 H 0.7333 0.9992 0.0264 0.058 Uiso 1 1 calc R . .
C335 C 0.6317(10) 1.0607(9) 0.0598(7) 0.041(3) Uani 1 1 d . . .
H335 H 0.6566 1.1126 0.0515 0.050 Uiso 1 1 calc R . .
C336 C 0.5514(9) 1.0500(7) 0.0880(6) 0.034(3) Uani 1 1 d . . .
H336 H 0.5217 1.0951 0.0992 0.041 Uiso 1 1 calc R . .
C351 C 0.2044(7) 0.9834(7) 0.1920(6) 0.026(2) Uani 1 1 d . . .
C352 C 0.1902(10) 1.0659(9) 0.2134(8) 0.047(3) Uani 1 1 d . . .
H352 H 0.2423 1.1131 0.2211 0.056 Uiso 1 1 calc R . .
C353 C 0.0984(11) 1.0749(10) 0.2226(9) 0.058(4) Uani 1 1 d . . .
H353 H 0.0893 1.1292 0.2375 0.070 Uiso 1 1 calc R . .
C354 C 0.0195(11) 1.0074(10) 0.2108(7) 0.050(4) Uani 1 1 d . . .
H354 H -0.0426 1.0159 0.2163 0.060 Uiso 1 1 calc R . .
C355 C 0.0327(9) 0.9269(9) 0.1909(6) 0.037(3) Uani 1 1 d . . .
H355 H -0.0202 0.8806 0.1839 0.045 Uiso 1 1 calc R . .
C356 C 0.1249(9) 0.9139(8) 0.1812(6) 0.034(3) Uani 1 1 d . . .
H356 H 0.1333 0.8592 0.1675 0.041 Uiso 1 1 calc R . .
N41 N 0.4304(6) 0.5589(6) 0.2075(5) 0.027(2) Uani 1 1 d . . .
C42 C 0.4155(10) 0.5269(7) 0.2624(6) 0.033(3) Uani 1 1 d . . .
C43 C 0.3419(12) 0.4544(9) 0.2518(7) 0.050(4) Uani 1 1 d . . .
H43 H 0.3316 0.4334 0.2894 0.060 Uiso 1 1 calc R . .
C44 C 0.2848(11) 0.4136(9) 0.1876(8) 0.048(3) Uani 1 1 d . . .
H44 H 0.2346 0.3654 0.1811 0.058 Uiso 1 1 calc R . .
C45 C 0.3017(10) 0.4443(8) 0.1307(7) 0.042(3) Uani 1 1 d . . .
H45 H 0.2642 0.4169 0.0859 0.050 Uiso 1 1 calc R . .
C46 C 0.3759(9) 0.5165(7) 0.1438(6) 0.032(3) Uani 1 1 d . . .
H46 H 0.3889 0.5370 0.1065 0.039 Uiso 1 1 calc R . .
C421 C 0.4840(10) 0.5757(8) 0.3295(6) 0.035(3) Uani 1 1 d . . .
C422 C 0.5603(9) 0.6434(7) 0.3266(6) 0.029(2) Uani 1 1 d . . .
C423 C 0.6225(10) 0.6957(8) 0.3882(6) 0.036(3) Uani 1 1 d . . .
H423 H 0.6702 0.7421 0.3870 0.043 Uiso 1 1 calc R . .
C424 C 0.6147(10) 0.6802(9) 0.4515(7) 0.045(3) Uani 1 1 d . . .
H424 H 0.6565 0.7161 0.4924 0.054 Uiso 1 1 calc R . .
C425 C 0.5436(11) 0.6101(9) 0.4534(7) 0.046(3) Uani 1 1 d . . .
H425 H 0.5398 0.5979 0.4955 0.055 Uiso 1 1 calc R . .
C426 C 0.4785(12) 0.5587(9) 0.3919(7) 0.049(4) Uani 1 1 d . . .
H426 H 0.4308 0.5125 0.3932 0.059 Uiso 1 1 calc R . .
N51 N 0.6812(6) 0.7462(6) 0.2588(4) 0.0231(19) Uani 1 1 d . . .
N52 N 0.6838(7) 0.8280(6) 0.2583(4) 0.0257(19) Uani 1 1 d . . .
C53 C 0.7802(9) 0.8731(8) 0.2853(6) 0.033(3) Uani 1 1 d . . .
C54 C 0.8399(8) 0.8190(8) 0.3040(6) 0.032(3) Uani 1 1 d . . .
H54 H 0.9086 0.8332 0.3242 0.038 Uiso 1 1 calc R . .
C55 C 0.7750(9) 0.7384(8) 0.2861(6) 0.030(3) Uani 1 1 d . . .
C531 C 0.8086(9) 0.9651(8) 0.2901(6) 0.032(3) Uani 1 1 d . . .
C532 C 0.8863(9) 1.0162(9) 0.3435(6) 0.039(3) Uani 1 1 d . . .
H532 H 0.9195 0.9923 0.3764 0.047 Uiso 1 1 calc R . .
C533 C 0.9165(10) 1.1025(9) 0.3495(7) 0.045(3) Uani 1 1 d . . .
H533 H 0.9686 1.1362 0.3863 0.054 Uiso 1 1 calc R . .
C534 C 0.8684(10) 1.1373(9) 0.3007(7) 0.047(3) Uani 1 1 d . . .
H534 H 0.8877 1.1952 0.3047 0.056 Uiso 1 1 calc R . .
C535 C 0.7910(9) 1.0871(8) 0.2448(7) 0.038(3) Uani 1 1 d . . .
H535 H 0.7600 1.1112 0.2112 0.046 Uiso 1 1 calc R . .
C536 C 0.7608(8) 1.0022(9) 0.2397(6) 0.037(3) Uani 1 1 d . . .
H536 H 0.7086 0.9688 0.2028 0.045 Uiso 1 1 calc R . .
C551 C 0.8031(8) 0.6597(8) 0.2936(6) 0.032(3) Uani 1 1 d . . .
C552 C 0.7622(10) 0.5844(9) 0.2445(7) 0.045(3) Uani 1 1 d . . .
H552 H 0.7136 0.5835 0.2054 0.054 Uiso 1 1 calc R . .
C553 C 0.7899(12) 0.5110(10) 0.2507(8) 0.055(4) Uani 1 1 d . . .
H553 H 0.7603 0.4611 0.2166 0.065 Uiso 1 1 calc R . .
C554 C 0.8641(13) 0.5117(10) 0.3096(9) 0.058(4) Uani 1 1 d . . .
H554 H 0.8844 0.4623 0.3146 0.069 Uiso 1 1 calc R . .
C555 C 0.9054(11) 0.5858(11) 0.3589(7) 0.051(4) Uani 1 1 d . . .
H555 H 0.9542 0.5864 0.3978 0.062 Uiso 1 1 calc R . .
C556 C 0.8765(9) 0.6604(9) 0.3526(6) 0.037(3) Uani 1 1 d . . .
H556 H 0.9052 0.7102 0.3870 0.045 Uiso 1 1 calc R . .
N61 N 0.5196(6) 0.6750(6) 0.1283(5) 0.0239(19) Uani 1 1 d . . .
N62 N 0.4292(7) 0.6967(6) 0.1065(4) 0.0255(19) Uani 1 1 d . . .
C63 C 0.4159(8) 0.6953(7) 0.0383(5) 0.027(2) Uani 1 1 d . . .
C64 C 0.4971(8) 0.6726(7) 0.0164(6) 0.030(3) Uani 1 1 d . . .
H64 H 0.5064 0.6662 -0.0280 0.036 Uiso 1 1 calc R . .
C65 C 0.5626(8) 0.6609(7) 0.0747(5) 0.026(2) Uani 1 1 d . . .
C631 C 0.3293(7) 0.7185(7) -0.0017(5) 0.024(2) Uani 1 1 d . . .
C632 C 0.2730(8) 0.7680(7) 0.0310(6) 0.027(2) Uani 1 1 d . . .
H632 H 0.2912 0.7876 0.0790 0.032 Uiso 1 1 calc R . .
C633 C 0.1913(9) 0.7876(8) -0.0071(7) 0.038(3) Uani 1 1 d . . .
H633 H 0.1532 0.8190 0.0151 0.045 Uiso 1 1 calc R . .
C634 C 0.1654(10) 0.7600(9) -0.0800(7) 0.044(3) Uani 1 1 d . . .
H634 H 0.1106 0.7737 -0.1061 0.053 Uiso 1 1 calc R . .
C635 C 0.2221(10) 0.7126(8) -0.1120(6) 0.043(3) Uani 1 1 d . . .
H635 H 0.2056 0.6949 -0.1600 0.051 Uiso 1 1 calc R . .
C636 C 0.3027(9) 0.6913(8) -0.0738(6) 0.038(3) Uani 1 1 d . . .
H636 H 0.3395 0.6586 -0.0960 0.045 Uiso 1 1 calc R . .
C651 C 0.6589(8) 0.6363(8) 0.0795(5) 0.029(3) Uani 1 1 d . . .
C652 C 0.6645(8) 0.5553(7) 0.0514(5) 0.029(2) Uani 1 1 d . . .
H652 H 0.6057 0.5144 0.0287 0.034 Uiso 1 1 calc R . .
C653 C 0.7559(8) 0.5334(8) 0.0563(6) 0.034(3) Uani 1 1 d . . .
H653 H 0.7580 0.4779 0.0376 0.041 Uiso 1 1 calc R . .
C654 C 0.8430(9) 0.5927(8) 0.0883(6) 0.037(3) Uani 1 1 d . . .
H654 H 0.9045 0.5778 0.0915 0.044 Uiso 1 1 calc R . .
C655 C 0.8392(8) 0.6753(8) 0.1161(7) 0.039(3) Uani 1 1 d . . .
H655 H 0.8987 0.7161 0.1370 0.047 Uiso 1 1 calc R . .
C656 C 0.7486(9) 0.6981(9) 0.1132(6) 0.038(3) Uani 1 1 d . . .
H656 H 0.7467 0.7533 0.1331 0.046 Uiso 1 1 calc R . .
B1 B 0.122(2) 0.6796(17) 0.5407(13) 0.015(5) Uiso 0.40 1 d PU A 1
F1 F 0.1967(16) 0.6847(13) 0.5067(11) 0.056(5) Uiso 0.40 1 d PU A 1
F2 F 0.0678(10) 0.5950(9) 0.5088(7) 0.020(3) Uiso 0.40 1 d PU A 1
F3 F 0.0645(12) 0.7327(10) 0.5228(8) 0.030(3) Uiso 0.40 1 d PU A 1
F4 F 0.1481(16) 0.6860(13) 0.6058(11) 0.054(5) Uiso 0.40 1 d PU A 1
C1 C -0.498(2) 0.707(2) 0.7895(18) 0.068(8) Uiso 0.60 1 d P B 1
H1 H -0.4607 0.7062 0.7540 0.082 Uiso 0.60 1 calc PR B 1
Cl1 Cl -0.5572(7) 0.6034(6) 0.7876(5) 0.073(2) Uiso 0.60 1 d P B 1
Cl2 Cl -0.5981(7) 0.7629(6) 0.7710(5) 0.087(2) Uiso 0.60 1 d P B 1
Cl3 Cl -0.4198(6) 0.7603(5) 0.8694(4) 0.0697(19) Uiso 0.60 1 d P B 1
B2 B -0.3250(17) 0.7211(14) 0.6568(11) 0.030(4) Uiso 0.60 1 d PU C 2
F5 F -0.2764(11) 0.7270(9) 0.7221(7) 0.055(3) Uiso 0.60 1 d PU C 2
F6 F -0.3449(7) 0.6410(6) 0.6166(5) 0.025(2) Uiso 0.60 1 d PU C 2
F7 F -0.2763(8) 0.7745(7) 0.6247(5) 0.032(2) Uiso 0.60 1 d PU C 2
F8 F -0.4084(17) 0.7442(14) 0.6607(12) 0.108(7) Uiso 0.60 1 d PU C 2
C2 C -0.529(4) 0.690(3) 0.752(3) 0.066(12) Uiso 0.40 1 d P D 2
H2 H -0.4832 0.6769 0.7230 0.079 Uiso 0.40 1 calc PR D 2
Cl4 Cl -0.647(2) 0.6751(17) 0.6982(14) 0.168(9) Uiso 0.40 1 d P D 2
Cl5 Cl -0.4911(13) 0.8003(11) 0.7922(9) 0.105(5) Uiso 0.40 1 d P D 2
Cl6 Cl -0.5239(8) 0.6254(7) 0.8098(6) 0.052(2) Uiso 0.40 1 d P D 2
C3 C -0.160(2) 0.8457(18) 0.9349(14) 0.029(6) Uiso 0.40 1 d PU E 2
H3 H -0.1532 0.8894 0.9090 0.035 Uiso 0.40 1 calc PR E 2
Cl7 Cl -0.2753(8) 0.7952(7) 0.9144(6) 0.066(3) Uiso 0.40 1 d PU E 2
Cl8 Cl -0.0821(13) 0.7693(11) 0.9105(9) 0.108(5) Uiso 0.40 1 d P E 2
Cl9 Cl -0.1036(19) 0.8903(16) 1.0201(13) 0.161(8) Uiso 0.40 1 d P E 2
C4 C 0.087(4) 0.359(3) 0.331(3) 0.087(14) Uiso 0.40 1 d PDU F -1
H4A H 0.0243 0.3339 0.2976 0.104 Uiso 0.40 1 calc PR F -1
H4B H 0.0780 0.3614 0.3768 0.104 Uiso 0.40 1 calc PR F -1
H4C H 0.1345 0.3248 0.3231 0.104 Uiso 0.40 1 calc PR F -1
C5 C 0.127(4) 0.448(3) 0.3247(15) 0.121(13) Uiso 0.40 1 d PDU F -1
H5A H 0.1601 0.4437 0.2871 0.145 Uiso 0.40 1 calc PR F -1
H5B H 0.0707 0.4729 0.3122 0.145 Uiso 0.40 1 calc PR F -1
C6 C 0.201(3) 0.507(3) 0.3893(16) 0.078(10) Uiso 0.40 1 d PDU F -1
H6A H 0.2678 0.5029 0.3863 0.093 Uiso 0.40 1 calc PR F -1
H6B H 0.1958 0.5646 0.3883 0.093 Uiso 0.40 1 calc PR F -1
C7 C 0.189(2) 0.494(2) 0.4593(14) 0.052(7) Uiso 0.40 1 d PDU F -1
H7A H 0.1450 0.5271 0.4766 0.062 Uiso 0.40 1 calc PR F -1
H7B H 0.1638 0.4351 0.4567 0.062 Uiso 0.40 1 calc PR F -1
C8 C 0.296(2) 0.526(2) 0.5045(14) 0.050(8) Uiso 0.40 1 d PDU F -1
H8A H 0.3368 0.4890 0.4884 0.060 Uiso 0.40 1 calc PR F -1
H8B H 0.3232 0.5822 0.4998 0.060 Uiso 0.40 1 calc PR F -1
C9 C 0.302(3) 0.530(3) 0.5800(15) 0.057(9) Uiso 0.40 1 d PDU F -1
H9A H 0.2561 0.5619 0.5950 0.069 Uiso 0.40 1 calc PR F -1
H9B H 0.3692 0.5577 0.6070 0.069 Uiso 0.40 1 calc PR F -1
H9C H 0.2850 0.4739 0.5860 0.069 Uiso 0.40 1 calc PR F -1


#==============================================================================
_computing_data_collection       DTREK
_computing_cell_refinement       DTREK
_computing_data_reduction        DTREK
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.2 (Rigaku, 2015)'
_computing_molecular_graphics    'CrystalStructure 4.2'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C122 2.002(12) . ?
Pt1 N21 2.021(8) . ?
Pt1 N11 2.058(8) . ?
Pt1 N31 2.125(9) . ?
Pt1 Ag3 2.8199(10) . ?
Pt2 N51 2.006(9) . ?
Pt2 C422 2.020(11) . ?
Pt2 N41 2.039(9) . ?
Pt2 N61 2.109(9) . ?
Pt2 Ag3 2.8012(9) . ?
Pt2 Ag1 3.3012(10) . ?
Ag1 N22 2.094(8) . ?
Ag1 N62 2.100(9) . ?
Ag1 Ag3 2.9955(12) . ?
Ag1 Ag2 3.2240(12) . ?
Ag2 N32 2.072(10) . ?
Ag2 N52 2.080(9) . ?
Ag2 Ag3 3.0624(12) . ?
Ag3 C122 2.411(10) . ?
Ag3 C422 2.485(10) . ?
N11 C16 1.329(14) . ?
N11 C12 1.377(14) . ?
C12 C13 1.384(16) . ?
C12 C121 1.464(16) . ?
C13 C14 1.380(18) . ?
C13 H13 0.9300 . ?
C14 C15 1.373(17) . ?
C14 H14 0.9300 . ?
C15 C16 1.383(16) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C121 C126 1.399(16) . ?
C121 C122 1.408(14) . ?
C122 C123 1.406(15) . ?
C123 C124 1.403(16) . ?
C123 H123 0.9300 . ?
C124 C125 1.413(16) . ?
C124 H124 0.9300 . ?
C125 C126 1.371(17) . ?
C125 H125 0.9300 . ?
C126 H126 0.9300 . ?
N21 C25 1.350(12) . ?
N21 N22 1.368(11) . ?
N22 C23 1.364(14) . ?
C23 C24 1.400(14) . ?
C23 C231 1.450(15) . ?
C24 C25 1.367(16) . ?
C24 H24 0.9300 . ?
C25 C251 1.492(14) . ?
C231 C232 1.385(17) . ?
C231 C236 1.393(16) . ?
C232 C233 1.373(18) . ?
C232 H232 0.9300 . ?
C233 C234 1.38(2) . ?
C233 H233 0.9300 . ?
C234 C235 1.40(2) . ?
C234 H234 0.9300 . ?
C235 C236 1.387(17) . ?
C235 H235 0.9300 . ?
C236 H236 0.9300 . ?
C251 C252 1.367(15) . ?
C251 C256 1.392(16) . ?
C252 C253 1.404(16) . ?
C252 H252 0.9300 . ?
C253 C254 1.371(19) . ?
C253 H253 0.9300 . ?
C254 C255 1.394(17) . ?
C254 H254 0.9300 . ?
C255 C256 1.394(16) . ?
C255 H255 0.9300 . ?
C256 H256 0.9300 . ?
N31 C35 1.338(14) . ?
N31 N32 1.375(12) . ?
N32 C33 1.359(13) . ?
C33 C34 1.396(15) . ?
C33 C331 1.463(15) . ?
C34 C35 1.389(15) . ?
C34 H34 0.9300 . ?
C35 C351 1.475(14) . ?
C331 C332 1.399(16) . ?
C331 C336 1.409(16) . ?
C332 C333 1.381(16) . ?
C332 H332 0.9300 . ?
C333 C334 1.35(2) . ?
C333 H333 0.9300 . ?
C334 C335 1.41(2) . ?
C334 H334 0.9300 . ?
C335 C336 1.366(17) . ?
C335 H335 0.9300 . ?
C336 H336 0.9300 . ?
C351 C356 1.396(16) . ?
C351 C352 1.410(17) . ?
C352 C353 1.367(18) . ?
C352 H352 0.9300 . ?
C353 C354 1.37(2) . ?
C353 H353 0.9300 . ?
C354 C355 1.37(2) . ?
C354 H354 0.9300 . ?
C355 C356 1.393(17) . ?
C355 H355 0.9300 . ?
C356 H356 0.9300 . ?
N41 C46 1.338(14) . ?
N41 C42 1.369(15) . ?
C42 C43 1.380(18) . ?
C42 C421 1.476(17) . ?
C43 C44 1.352(19) . ?
C43 H43 0.9300 . ?
C44 C45 1.40(2) . ?
C44 H44 0.9300 . ?
C45 C46 1.374(18) . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C421 C426 1.373(17) . ?
C421 C422 1.422(18) . ?
C422 C423 1.387(16) . ?
C423 C424 1.389(17) . ?
C423 H423 0.9300 . ?
C424 C425 1.40(2) . ?
C424 H424 0.9300 . ?
C425 C426 1.395(19) . ?
C425 H425 0.9300 . ?
C426 H426 0.9300 . ?
N51 N52 1.351(12) . ?
N51 C55 1.355(14) . ?
N52 C53 1.358(14) . ?
C53 C54 1.387(17) . ?
C53 C531 1.481(17) . ?
C54 C55 1.404(17) . ?
C54 H54 0.9300 . ?
C55 C551 1.457(17) . ?
C531 C532 1.376(16) . ?
C531 C536 1.414(18) . ?
C532 C533 1.389(19) . ?
C532 H532 0.9300 . ?
C533 C534 1.37(2) . ?
C533 H533 0.9300 . ?
C534 C535 1.395(18) . ?
C534 H534 0.9300 . ?
C535 C536 1.370(18) . ?
C535 H535 0.9300 . ?
C536 H536 0.9300 . ?
C551 C552 1.374(18) . ?
C551 C556 1.407(16) . ?
C552 C553 1.361(19) . ?
C552 H552 0.9300 . ?
C553 C554 1.41(2) . ?
C553 H553 0.9300 . ?
C554 C555 1.36(2) . ?
C554 H554 0.9300 . ?
C555 C556 1.389(19) . ?
C555 H555 0.9300 . ?
C556 H556 0.9300 . ?
N61 C65 1.355(13) . ?
N61 N62 1.386(12) . ?
N62 C63 1.360(14) . ?
C63 C64 1.389(15) . ?
C63 C631 1.471(15) . ?
C64 C65 1.411(16) . ?
C64 H64 0.9300 . ?
C65 C651 1.467(15) . ?
C631 C636 1.395(15) . ?
C631 C632 1.404(15) . ?
C632 C633 1.373(16) . ?
C632 H632 0.9300 . ?
C633 C634 1.412(18) . ?
C633 H633 0.9300 . ?
C634 C635 1.382(19) . ?
C634 H634 0.9300 . ?
C635 C636 1.377(18) . ?
C635 H635 0.9300 . ?
C636 H636 0.9300 . ?
C651 C652 1.371(16) . ?
C651 C656 1.412(16) . ?
C652 C653 1.382(16) . ?
C652 H652 0.9300 . ?
C653 C654 1.363(17) . ?
C653 H653 0.9300 . ?
C654 C655 1.388(17) . ?
C654 H654 0.9300 . ?
C655 C656 1.380(16) . ?
C655 H655 0.9300 . ?
C656 H656 0.9300 . ?
B1 F4 1.28(3) . ?
B1 F3 1.35(3) . ?
B1 F1 1.36(3) . ?
B1 F2 1.42(3) . ?
C1 Cl3 1.72(3) . ?
C1 Cl1 1.76(3) . ?
C1 Cl2 1.82(3) . ?
C1 H1 0.9800 . ?
B2 F8 1.31(3) . ?
B2 F5 1.34(3) . ?
B2 F6 1.36(2) . ?
B2 F7 1.37(2) . ?
C2 Cl4 1.73(5) . ?
C2 Cl6 1.74(5) . ?
C2 Cl5 1.77(5) . ?
C2 H2 0.9800 . ?
C3 Cl7 1.60(3) . ?
C3 Cl9 1.70(4) . ?
C3 Cl8 1.87(3) . ?
C3 H3 0.9800 . ?
C4 C5 1.522(10) . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5 C6 1.520(10) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 C7 1.519(10) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.516(10) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C9 1.512(10) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C122 Pt1 N21 93.8(4) . . ?
C122 Pt1 N11 81.3(4) . . ?
N21 Pt1 N11 173.4(3) . . ?
C122 Pt1 N31 169.3(4) . . ?
N21 Pt1 N31 91.8(3) . . ?
N11 Pt1 N31 93.8(3) . . ?
C122 Pt1 Ag3 57.0(3) . . ?
N21 Pt1 Ag3 88.4(2) . . ?
N11 Pt1 Ag3 92.6(3) . . ?
N31 Pt1 Ag3 114.0(2) . . ?
N51 Pt2 C422 93.1(4) . . ?
N51 Pt2 N41 172.1(4) . . ?
C422 Pt2 N41 81.7(4) . . ?
N51 Pt2 N61 92.7(3) . . ?
C422 Pt2 N61 171.1(4) . . ?
N41 Pt2 N61 93.2(4) . . ?
N51 Pt2 Ag3 88.7(2) . . ?
C422 Pt2 Ag3 59.5(3) . . ?
N41 Pt2 Ag3 93.7(2) . . ?
N61 Pt2 Ag3 114.1(2) . . ?
N51 Pt2 Ag1 117.0(2) . . ?
C422 Pt2 Ag1 108.1(3) . . ?
N41 Pt2 Ag1 70.5(3) . . ?
N61 Pt2 Ag1 63.3(2) . . ?
Ag3 Pt2 Ag1 58.11(2) . . ?
N22 Ag1 N62 168.3(3) . . ?
N22 Ag1 Ag3 81.9(2) . . ?
N62 Ag1 Ag3 109.5(2) . . ?
N22 Ag1 Ag2 118.8(2) . . ?
N62 Ag1 Ag2 70.9(2) . . ?
Ag3 Ag1 Ag2 58.86(3) . . ?
N22 Ag1 Pt2 126.5(2) . . ?
N62 Ag1 Pt2 62.5(2) . . ?
Ag3 Ag1 Pt2 52.56(2) . . ?
Ag2 Ag1 Pt2 63.68(3) . . ?
N32 Ag2 N52 168.5(4) . . ?
N32 Ag2 Ag3 107.5(2) . . ?
N52 Ag2 Ag3 83.4(3) . . ?
N32 Ag2 Ag1 72.3(2) . . ?
N52 Ag2 Ag1 117.8(3) . . ?
Ag3 Ag2 Ag1 56.85(3) . . ?
C122 Ag3 C422 138.1(4) . . ?
C122 Ag3 Pt2 174.8(3) . . ?
C422 Ag3 Pt2 44.4(3) . . ?
C122 Ag3 Pt1 44.1(3) . . ?
C422 Ag3 Pt1 177.4(3) . . ?
Pt2 Ag3 Pt1 133.48(3) . . ?
C122 Ag3 Ag1 111.1(3) . . ?
C422 Ag3 Ag1 105.4(3) . . ?
Pt2 Ag3 Ag1 69.34(3) . . ?
Pt1 Ag3 Ag1 72.01(3) . . ?
C122 Ag3 Ag2 103.6(3) . . ?
C422 Ag3 Ag2 110.3(3) . . ?
Pt2 Ag3 Ag2 71.76(3) . . ?
Pt1 Ag3 Ag2 68.74(3) . . ?
Ag1 Ag3 Ag2 64.30(3) . . ?
C16 N11 C12 120.7(9) . . ?
C16 N11 Pt1 125.0(8) . . ?
C12 N11 Pt1 114.1(7) . . ?
N11 C12 C13 118.9(11) . . ?
N11 C12 C121 114.6(9) . . ?
C13 C12 C121 126.5(11) . . ?
C14 C13 C12 120.7(12) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C15 C14 C13 118.5(11) . . ?
C15 C14 H14 120.7 . . ?
C13 C14 H14 120.7 . . ?
C14 C15 C16 120.2(12) . . ?
C14 C15 H15 119.9 . . ?
C16 C15 H15 119.9 . . ?
N11 C16 C15 120.8(11) . . ?
N11 C16 H16 119.6 . . ?
C15 C16 H16 119.6 . . ?
C126 C121 C122 120.7(11) . . ?
C126 C121 C12 123.8(10) . . ?
C122 C121 C12 115.6(10) . . ?
C123 C122 C121 117.3(10) . . ?
C123 C122 Pt1 128.3(7) . . ?
C121 C122 Pt1 114.2(8) . . ?
C123 C122 Ag3 89.6(7) . . ?
C121 C122 Ag3 99.0(7) . . ?
Pt1 C122 Ag3 78.8(3) . . ?
C124 C123 C122 122.0(10) . . ?
C124 C123 H123 119.0 . . ?
C122 C123 H123 119.0 . . ?
C123 C124 C125 119.2(11) . . ?
C123 C124 H124 120.4 . . ?
C125 C124 H124 120.4 . . ?
C126 C125 C124 119.2(11) . . ?
C126 C125 H125 120.4 . . ?
C124 C125 H125 120.4 . . ?
C125 C126 C121 121.7(11) . . ?
C125 C126 H126 119.2 . . ?
C121 C126 H126 119.2 . . ?
C25 N21 N22 110.3(8) . . ?
C25 N21 Pt1 129.9(7) . . ?
N22 N21 Pt1 119.5(6) . . ?
C23 N22 N21 106.7(8) . . ?
C23 N22 Ag1 133.2(7) . . ?
N21 N22 Ag1 120.0(6) . . ?
N22 C23 C24 108.1(10) . . ?
N22 C23 C231 122.8(9) . . ?
C24 C23 C231 129.2(10) . . ?
C25 C24 C23 107.4(10) . . ?
C25 C24 H24 126.3 . . ?
C23 C24 H24 126.3 . . ?
N21 C25 C24 107.5(9) . . ?
N21 C25 C251 124.1(9) . . ?
C24 C25 C251 128.3(9) . . ?
C232 C231 C236 117.2(11) . . ?
C232 C231 C23 120.3(11) . . ?
C236 C231 C23 122.5(11) . . ?
C233 C232 C231 123.3(13) . . ?
C233 C232 H232 118.4 . . ?
C231 C232 H232 118.4 . . ?
C232 C233 C234 118.5(14) . . ?
C232 C233 H233 120.8 . . ?
C234 C233 H233 120.8 . . ?
C233 C234 C235 120.7(13) . . ?
C233 C234 H234 119.6 . . ?
C235 C234 H234 119.6 . . ?
C236 C235 C234 118.9(13) . . ?
C236 C235 H235 120.6 . . ?
C234 C235 H235 120.6 . . ?
C235 C236 C231 121.4(13) . . ?
C235 C236 H236 119.3 . . ?
C231 C236 H236 119.3 . . ?
C252 C251 C256 120.3(10) . . ?
C252 C251 C25 118.0(10) . . ?
C256 C251 C25 121.7(9) . . ?
C251 C252 C253 119.8(12) . . ?
C251 C252 H252 120.1 . . ?
C253 C252 H252 120.1 . . ?
C254 C253 C252 119.9(11) . . ?
C254 C253 H253 120.1 . . ?
C252 C253 H253 120.1 . . ?
C253 C254 C255 121.0(10) . . ?
C253 C254 H254 119.5 . . ?
C255 C254 H254 119.5 . . ?
C256 C255 C254 118.6(12) . . ?
C256 C255 H255 120.7 . . ?
C254 C255 H255 120.7 . . ?
C251 C256 C255 120.4(11) . . ?
C251 C256 H256 119.8 . . ?
C255 C256 H256 119.8 . . ?
C35 N31 N32 108.3(9) . . ?
C35 N31 Pt1 135.1(7) . . ?
N32 N31 Pt1 111.5(6) . . ?
C33 N32 N31 108.3(9) . . ?
C33 N32 Ag2 128.2(7) . . ?
N31 N32 Ag2 123.1(7) . . ?
N32 C33 C34 108.1(9) . . ?
N32 C33 C331 119.6(10) . . ?
C34 C33 C331 132.2(10) . . ?
C35 C34 C33 105.8(10) . . ?
C35 C34 H34 127.1 . . ?
C33 C34 H34 127.1 . . ?
N31 C35 C34 109.4(9) . . ?
N31 C35 C351 124.2(10) . . ?
C34 C35 C351 126.2(10) . . ?
C332 C331 C336 119.2(11) . . ?
C332 C331 C33 121.6(11) . . ?
C336 C331 C33 119.1(11) . . ?
C333 C332 C331 119.0(11) . . ?
C333 C332 H332 120.5 . . ?
C331 C332 H332 120.5 . . ?
C334 C333 C332 121.9(13) . . ?
C334 C333 H333 119.1 . . ?
C332 C333 H333 119.1 . . ?
C333 C334 C335 120.2(12) . . ?
C333 C334 H334 119.9 . . ?
C335 C334 H334 119.9 . . ?
C336 C335 C334 119.1(12) . . ?
C336 C335 H335 120.4 . . ?
C334 C335 H335 120.4 . . ?
C335 C336 C331 120.6(12) . . ?
C335 C336 H336 119.7 . . ?
C331 C336 H336 119.7 . . ?
C356 C351 C352 119.2(11) . . ?
C356 C351 C35 119.7(10) . . ?
C352 C351 C35 121.1(10) . . ?
C353 C352 C351 118.6(13) . . ?
C353 C352 H352 120.7 . . ?
C351 C352 H352 120.7 . . ?
C354 C353 C352 122.6(14) . . ?
C354 C353 H353 118.7 . . ?
C352 C353 H353 118.7 . . ?
C353 C354 C355 119.3(13) . . ?
C353 C354 H354 120.4 . . ?
C355 C354 H354 120.4 . . ?
C354 C355 C356 120.5(13) . . ?
C354 C355 H355 119.7 . . ?
C356 C355 H355 119.7 . . ?
C355 C356 C351 119.7(12) . . ?
C355 C356 H356 120.1 . . ?
C351 C356 H356 120.1 . . ?
C46 N41 C42 118.8(10) . . ?
C46 N41 Pt2 125.2(8) . . ?
C42 N41 Pt2 115.2(7) . . ?
N41 C42 C43 119.9(11) . . ?
N41 C42 C421 114.1(11) . . ?
C43 C42 C421 126.0(11) . . ?
C44 C43 C42 121.0(13) . . ?
C44 C43 H43 119.5 . . ?
C42 C43 H43 119.5 . . ?
C43 C44 C45 119.6(14) . . ?
C43 C44 H44 120.2 . . ?
C45 C44 H44 120.2 . . ?
C46 C45 C44 117.4(12) . . ?
C46 C45 H45 121.3 . . ?
C44 C45 H45 121.3 . . ?
N41 C46 C45 123.4(12) . . ?
N41 C46 H46 118.3 . . ?
C45 C46 H46 118.3 . . ?
C426 C421 C422 120.1(12) . . ?
C426 C421 C42 124.2(12) . . ?
C422 C421 C42 115.7(10) . . ?
C423 C422 C421 118.5(11) . . ?
C423 C422 Pt2 128.0(9) . . ?
C421 C422 Pt2 113.0(8) . . ?
C423 C422 Ag3 85.0(7) . . ?
C421 C422 Ag3 104.5(8) . . ?
Pt2 C422 Ag3 76.1(4) . . ?
C422 C423 C424 121.2(13) . . ?
C422 C423 H423 119.4 . . ?
C424 C423 H423 119.4 . . ?
C423 C424 C425 119.6(12) . . ?
C423 C424 H424 120.2 . . ?
C425 C424 H424 120.2 . . ?
C426 C425 C424 119.6(12) . . ?
C426 C425 H425 120.2 . . ?
C424 C425 H425 120.2 . . ?
C421 C426 C425 120.7(13) . . ?
C421 C426 H426 119.7 . . ?
C425 C426 H426 119.7 . . ?
N52 N51 C55 109.3(9) . . ?
N52 N51 Pt2 121.7(7) . . ?
C55 N51 Pt2 128.8(8) . . ?
N51 N52 C53 108.1(9) . . ?
N51 N52 Ag2 119.8(7) . . ?
C53 N52 Ag2 131.9(8) . . ?
N52 C53 C54 109.0(10) . . ?
N52 C53 C531 121.4(11) . . ?
C54 C53 C531 129.5(11) . . ?
C53 C54 C55 105.5(10) . . ?
C53 C54 H54 127.2 . . ?
C55 C54 H54 127.2 . . ?
N51 C55 C54 107.9(10) . . ?
N51 C55 C551 125.7(11) . . ?
C54 C55 C551 126.3(11) . . ?
C532 C531 C536 118.3(12) . . ?
C532 C531 C53 119.6(12) . . ?
C536 C531 C53 122.1(11) . . ?
C531 C532 C533 121.6(13) . . ?
C531 C532 H532 119.2 . . ?
C533 C532 H532 119.2 . . ?
C534 C533 C532 119.1(12) . . ?
C534 C533 H533 120.4 . . ?
C532 C533 H533 120.4 . . ?
C533 C534 C535 120.9(13) . . ?
C533 C534 H534 119.6 . . ?
C535 C534 H534 119.6 . . ?
C536 C535 C534 119.6(13) . . ?
C536 C535 H535 120.2 . . ?
C534 C535 H535 120.2 . . ?
C535 C536 C531 120.4(11) . . ?
C535 C536 H536 119.8 . . ?
C531 C536 H536 119.8 . . ?
C552 C551 C556 118.3(12) . . ?
C552 C551 C55 122.6(11) . . ?
C556 C551 C55 119.1(11) . . ?
C553 C552 C551 122.7(14) . . ?
C553 C552 H552 118.7 . . ?
C551 C552 H552 118.7 . . ?
C552 C553 C554 119.2(15) . . ?
C552 C553 H553 120.4 . . ?
C554 C553 H553 120.4 . . ?
C555 C554 C553 118.9(13) . . ?
C555 C554 H554 120.6 . . ?
C553 C554 H554 120.5 . . ?
C554 C555 C556 121.7(13) . . ?
C554 C555 H555 119.1 . . ?
C556 C555 H555 119.1 . . ?
C555 C556 C551 119.2(13) . . ?
C555 C556 H556 120.4 . . ?
C551 C556 H556 120.4 . . ?
C65 N61 N62 109.4(9) . . ?
C65 N61 Pt2 134.4(7) . . ?
N62 N61 Pt2 115.8(6) . . ?
C63 N62 N61 107.6(8) . . ?
C63 N62 Ag1 134.2(8) . . ?
N61 N62 Ag1 118.2(6) . . ?
N62 C63 C64 108.9(10) . . ?
N62 C63 C631 122.7(10) . . ?
C64 C63 C631 128.4(10) . . ?
C63 C64 C65 106.8(10) . . ?
C63 C64 H64 126.6 . . ?
C65 C64 H64 126.6 . . ?
N61 C65 C64 107.3(9) . . ?
N61 C65 C651 123.9(10) . . ?
C64 C65 C651 128.8(10) . . ?
C636 C631 C632 119.1(10) . . ?
C636 C631 C63 119.5(10) . . ?
C632 C631 C63 121.4(10) . . ?
C633 C632 C631 120.5(11) . . ?
C633 C632 H632 119.7 . . ?
C631 C632 H632 119.7 . . ?
C632 C633 C634 119.8(12) . . ?
C632 C633 H633 120.1 . . ?
C634 C633 H633 120.1 . . ?
C635 C634 C633 119.4(12) . . ?
C635 C634 H634 120.3 . . ?
C633 C634 H634 120.3 . . ?
C636 C635 C634 120.8(12) . . ?
C636 C635 H635 119.6 . . ?
C634 C635 H635 119.6 . . ?
C635 C636 C631 120.2(11) . . ?
C635 C636 H636 119.9 . . ?
C631 C636 H636 119.9 . . ?
C652 C651 C656 119.0(10) . . ?
C652 C651 C65 122.0(10) . . ?
C656 C651 C65 119.0(11) . . ?
C651 C652 C653 121.2(11) . . ?
C651 C652 H652 119.4 . . ?
C653 C652 H652 119.4 . . ?
C654 C653 C652 120.4(12) . . ?
C654 C653 H653 119.8 . . ?
C652 C653 H653 119.8 . . ?
C653 C654 C655 119.4(11) . . ?
C653 C654 H654 120.3 . . ?
C655 C654 H654 120.3 . . ?
C656 C655 C654 121.1(11) . . ?
C656 C655 H655 119.4 . . ?
C654 C655 H655 119.4 . . ?
C655 C656 C651 118.9(12) . . ?
C655 C656 H656 120.6 . . ?
C651 C656 H656 120.6 . . ?
F4 B1 F3 114(2) . . ?
F4 B1 F1 118(2) . . ?
F3 B1 F1 108(2) . . ?
F4 B1 F2 107(2) . . ?
F3 B1 F2 109(2) . . ?
F1 B1 F2 100.2(19) . . ?
Cl3 C1 Cl1 112.4(19) . . ?
Cl3 C1 Cl2 108.2(18) . . ?
Cl1 C1 Cl2 106.7(17) . . ?
Cl3 C1 H1 109.8 . . ?
Cl1 C1 H1 109.8 . . ?
Cl2 C1 H1 109.8 . . ?
F8 B2 F5 106(2) . . ?
F8 B2 F6 110(2) . . ?
F5 B2 F6 111.9(18) . . ?
F8 B2 F7 106.4(19) . . ?
F5 B2 F7 114.5(18) . . ?
F6 B2 F7 107.8(16) . . ?
Cl4 C2 Cl6 114(3) . . ?
Cl4 C2 Cl5 105(3) . . ?
Cl6 C2 Cl5 114(3) . . ?
Cl4 C2 H2 107.8 . . ?
Cl6 C2 H2 107.8 . . ?
Cl5 C2 H2 107.8 . . ?
Cl7 C3 Cl9 118.0(19) . . ?
Cl7 C3 Cl8 108.7(17) . . ?
Cl9 C3 Cl8 102.6(17) . . ?
Cl7 C3 H3 109.1 . . ?
Cl9 C3 H3 109.1 . . ?
Cl8 C3 H3 109.1 . . ?
C5 C4 H4A 109.5 . . ?
C5 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C5 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C6 C5 C4 115(3) . . ?
C6 C5 H5A 108.5 . . ?
C4 C5 H5A 108.5 . . ?
C6 C5 H5B 108.5 . . ?
C4 C5 H5B 108.5 . . ?
H5A C5 H5B 107.5 . . ?
C7 C6 C5 118.3(11) . . ?
C7 C6 H6A 107.7 . . ?
C5 C6 H6A 107.7 . . ?
C7 C6 H6B 107.7 . . ?
C5 C6 H6B 107.7 . . ?
H6A C6 H6B 107.1 . . ?
C8 C7 C6 103(2) . . ?
C8 C7 H7A 111.2 . . ?
C6 C7 H7A 111.2 . . ?
C8 C7 H7B 111.2 . . ?
C6 C7 H7B 111.2 . . ?
H7A C7 H7B 109.1 . . ?
C9 C8 C7 113(3) . . ?
C9 C8 H8A 109.0 . . ?
C7 C8 H8A 109.0 . . ?
C9 C8 H8B 109.0 . . ?
C7 C8 H8B 109.0 . . ?
H8A C8 H8B 107.8 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N51 Pt2 Ag1 N22 -107.6(4) . . . . ?
C422 Pt2 Ag1 N22 -4.3(4) . . . . ?
N41 Pt2 Ag1 N22 69.6(4) . . . . ?
N61 Pt2 Ag1 N22 173.7(4) . . . . ?
Ag3 Pt2 Ag1 N22 -38.0(3) . . . . ?
N51 Pt2 Ag1 N62 81.1(4) . . . . ?
C422 Pt2 Ag1 N62 -175.6(4) . . . . ?
N41 Pt2 Ag1 N62 -101.7(4) . . . . ?
N61 Pt2 Ag1 N62 2.5(4) . . . . ?
Ag3 Pt2 Ag1 N62 150.8(3) . . . . ?
N51 Pt2 Ag1 Ag3 -69.7(3) . . . . ?
C422 Pt2 Ag1 Ag3 33.7(3) . . . . ?
N41 Pt2 Ag1 Ag3 107.6(3) . . . . ?
N61 Pt2 Ag1 Ag3 -148.3(3) . . . . ?
N51 Pt2 Ag1 Ag2 0.0(3) . . . . ?
C422 Pt2 Ag1 Ag2 103.3(3) . . . . ?
N41 Pt2 Ag1 Ag2 177.2(3) . . . . ?
N61 Pt2 Ag1 Ag2 -78.7(3) . . . . ?
Ag3 Pt2 Ag1 Ag2 69.64(3) . . . . ?
N22 Ag1 Ag2 N32 -67.3(4) . . . . ?
N62 Ag1 Ag2 N32 105.6(4) . . . . ?
Ag3 Ag1 Ag2 N32 -125.9(2) . . . . ?
Pt2 Ag1 Ag2 N32 173.6(2) . . . . ?
N22 Ag1 Ag2 N52 118.7(4) . . . . ?
N62 Ag1 Ag2 N52 -68.4(4) . . . . ?
Ag3 Ag1 Ag2 N52 60.1(3) . . . . ?
Pt2 Ag1 Ag2 N52 -0.4(3) . . . . ?
N22 Ag1 Ag2 Ag3 58.6(3) . . . . ?
N62 Ag1 Ag2 Ag3 -128.5(3) . . . . ?
Pt2 Ag1 Ag2 Ag3 -60.42(2) . . . . ?
N51 Pt2 Ag3 C122 27(3) . . . . ?
C422 Pt2 Ag3 C122 122(3) . . . . ?
N41 Pt2 Ag3 C122 -160(3) . . . . ?
N61 Pt2 Ag3 C122 -65(3) . . . . ?
Ag1 Pt2 Ag3 C122 -96(3) . . . . ?
N51 Pt2 Ag3 C422 -94.4(5) . . . . ?
N41 Pt2 Ag3 C422 78.0(5) . . . . ?
N61 Pt2 Ag3 C422 173.2(5) . . . . ?
Ag1 Pt2 Ag3 C422 142.3(4) . . . . ?
N51 Pt2 Ag3 Pt1 87.6(3) . . . . ?
C422 Pt2 Ag3 Pt1 -177.9(4) . . . . ?
N41 Pt2 Ag3 Pt1 -99.9(3) . . . . ?
N61 Pt2 Ag3 Pt1 -4.7(3) . . . . ?
Ag1 Pt2 Ag3 Pt1 -35.66(4) . . . . ?
N51 Pt2 Ag3 Ag1 123.3(3) . . . . ?
C422 Pt2 Ag3 Ag1 -142.3(4) . . . . ?
N41 Pt2 Ag3 Ag1 -64.2(3) . . . . ?
N61 Pt2 Ag3 Ag1 30.9(3) . . . . ?
N51 Pt2 Ag3 Ag2 54.6(3) . . . . ?
C422 Pt2 Ag3 Ag2 149.1(4) . . . . ?
N41 Pt2 Ag3 Ag2 -132.9(3) . . . . ?
N61 Pt2 Ag3 Ag2 -37.7(3) . . . . ?
Ag1 Pt2 Ag3 Ag2 -68.67(3) . . . . ?
N21 Pt1 Ag3 C122 -95.5(4) . . . . ?
N11 Pt1 Ag3 C122 77.9(4) . . . . ?
N31 Pt1 Ag3 C122 173.2(4) . . . . ?
C122 Pt1 Ag3 C422 152(6) . . . . ?
N21 Pt1 Ag3 C422 56(6) . . . . ?
N11 Pt1 Ag3 C422 -130(6) . . . . ?
N31 Pt1 Ag3 C422 -35(6) . . . . ?
C122 Pt1 Ag3 Pt2 -173.5(3) . . . . ?
N21 Pt1 Ag3 Pt2 90.9(2) . . . . ?
N11 Pt1 Ag3 Pt2 -95.6(2) . . . . ?
N31 Pt1 Ag3 Pt2 -0.3(2) . . . . ?
C122 Pt1 Ag3 Ag1 151.5(3) . . . . ?
N21 Pt1 Ag3 Ag1 55.9(2) . . . . ?
N11 Pt1 Ag3 Ag1 -130.6(2) . . . . ?
N31 Pt1 Ag3 Ag1 -35.3(2) . . . . ?
C122 Pt1 Ag3 Ag2 -139.8(3) . . . . ?
N21 Pt1 Ag3 Ag2 124.6(2) . . . . ?
N11 Pt1 Ag3 Ag2 -61.9(2) . . . . ?
N31 Pt1 Ag3 Ag2 33.4(2) . . . . ?
N22 Ag1 Ag3 C122 -35.5(4) . . . . ?
N62 Ag1 Ag3 C122 147.1(4) . . . . ?
Ag2 Ag1 Ag3 C122 95.4(3) . . . . ?
Pt2 Ag1 Ag3 C122 174.5(3) . . . . ?
N22 Ag1 Ag3 C422 123.6(4) . . . . ?
N62 Ag1 Ag3 C422 -53.8(4) . . . . ?
Ag2 Ag1 Ag3 C422 -105.5(3) . . . . ?
Pt2 Ag1 Ag3 C422 -26.4(3) . . . . ?
N22 Ag1 Ag3 Pt2 150.0(3) . . . . ?
N62 Ag1 Ag3 Pt2 -27.4(3) . . . . ?
Ag2 Ag1 Ag3 Pt2 -79.07(3) . . . . ?
N22 Ag1 Ag3 Pt1 -56.4(3) . . . . ?
N62 Ag1 Ag3 Pt1 126.2(3) . . . . ?
Ag2 Ag1 Ag3 Pt1 74.53(3) . . . . ?
Pt2 Ag1 Ag3 Pt1 153.59(3) . . . . ?
N22 Ag1 Ag3 Ag2 -130.9(3) . . . . ?
N62 Ag1 Ag3 Ag2 51.7(3) . . . . ?
Pt2 Ag1 Ag3 Ag2 79.07(3) . . . . ?
N32 Ag2 Ag3 C122 -53.2(4) . . . . ?
N52 Ag2 Ag3 C122 123.4(3) . . . . ?
Ag1 Ag2 Ag3 C122 -107.1(3) . . . . ?
N32 Ag2 Ag3 C422 151.9(4) . . . . ?
N52 Ag2 Ag3 C422 -31.6(4) . . . . ?
Ag1 Ag2 Ag3 C422 97.9(3) . . . . ?
N32 Ag2 Ag3 Pt2 129.3(3) . . . . ?
N52 Ag2 Ag3 Pt2 -54.2(2) . . . . ?
Ag1 Ag2 Ag3 Pt2 75.30(3) . . . . ?
N32 Ag2 Ag3 Pt1 -25.6(3) . . . . ?
N52 Ag2 Ag3 Pt1 150.9(2) . . . . ?
Ag1 Ag2 Ag3 Pt1 -79.60(3) . . . . ?
N32 Ag2 Ag3 Ag1 54.0(3) . . . . ?
N52 Ag2 Ag3 Ag1 -129.5(2) . . . . ?
C122 Pt1 N11 C16 -172.5(9) . . . . ?
N21 Pt1 N11 C16 -131(3) . . . . ?
N31 Pt1 N11 C16 17.1(9) . . . . ?
Ag3 Pt1 N11 C16 131.4(8) . . . . ?
C122 Pt1 N11 C12 3.4(7) . . . . ?
N21 Pt1 N11 C12 45(3) . . . . ?
N31 Pt1 N11 C12 -167.0(7) . . . . ?
Ag3 Pt1 N11 C12 -52.7(7) . . . . ?
C16 N11 C12 C13 -5.5(16) . . . . ?
Pt1 N11 C12 C13 178.4(8) . . . . ?
C16 N11 C12 C121 173.9(10) . . . . ?
Pt1 N11 C12 C121 -2.2(12) . . . . ?
N11 C12 C13 C14 2.6(17) . . . . ?
C121 C12 C13 C14 -176.6(11) . . . . ?
C12 C13 C14 C15 0.1(18) . . . . ?
C13 C14 C15 C16 -0.1(18) . . . . ?
C12 N11 C16 C15 5.6(16) . . . . ?
Pt1 N11 C16 C15 -178.8(8) . . . . ?
C14 C15 C16 N11 -2.7(17) . . . . ?
N11 C12 C121 C126 179.6(10) . . . . ?
C13 C12 C121 C126 -1.1(18) . . . . ?
N11 C12 C121 C122 -1.0(14) . . . . ?
C13 C12 C121 C122 178.3(11) . . . . ?
C126 C121 C122 C123 -0.7(16) . . . . ?
C12 C121 C122 C123 179.8(9) . . . . ?
C126 C121 C122 Pt1 -176.8(8) . . . . ?
C12 C121 C122 Pt1 3.8(13) . . . . ?
C126 C121 C122 Ag3 -95.0(10) . . . . ?
C12 C121 C122 Ag3 85.5(10) . . . . ?
N21 Pt1 C122 C123 5.1(10) . . . . ?
N11 Pt1 C122 C123 -179.3(10) . . . . ?
N31 Pt1 C122 C123 -115.7(19) . . . . ?
Ag3 Pt1 C122 C123 -80.5(9) . . . . ?
N21 Pt1 C122 C121 -179.4(8) . . . . ?
N11 Pt1 C122 C121 -3.9(8) . . . . ?
N31 Pt1 C122 C121 60(2) . . . . ?
Ag3 Pt1 C122 C121 95.0(8) . . . . ?
N21 Pt1 C122 Ag3 85.6(3) . . . . ?
N11 Pt1 C122 Ag3 -98.8(3) . . . . ?
N31 Pt1 C122 Ag3 -35(2) . . . . ?
C422 Ag3 C122 C123 -48.9(9) . . . . ?
Pt2 Ag3 C122 C123 -166(3) . . . . ?
Pt1 Ag3 C122 C123 129.3(7) . . . . ?
Ag1 Ag3 C122 C123 100.2(6) . . . . ?
Ag2 Ag3 C122 C123 167.5(6) . . . . ?
C422 Ag3 C122 C121 68.7(9) . . . . ?
Pt2 Ag3 C122 C121 -48(3) . . . . ?
Pt1 Ag3 C122 C121 -113.1(8) . . . . ?
Ag1 Ag3 C122 C121 -142.2(7) . . . . ?
Ag2 Ag3 C122 C121 -74.8(7) . . . . ?
C422 Ag3 C122 Pt1 -178.2(4) . . . . ?
Pt2 Ag3 C122 Pt1 65(3) . . . . ?
Ag1 Ag3 C122 Pt1 -29.1(3) . . . . ?
Ag2 Ag3 C122 Pt1 38.2(3) . . . . ?
C121 C122 C123 C124 0.4(16) . . . . ?
Pt1 C122 C123 C124 175.7(8) . . . . ?
Ag3 C122 C123 C124 100.3(10) . . . . ?
C122 C123 C124 C125 -0.1(16) . . . . ?
C123 C124 C125 C126 0.2(16) . . . . ?
C124 C125 C126 C121 -0.6(17) . . . . ?
C122 C121 C126 C125 0.9(17) . . . . ?
C12 C121 C126 C125 -179.8(11) . . . . ?
C122 Pt1 N21 C25 68.9(9) . . . . ?
N11 Pt1 N21 C25 27(4) . . . . ?
N31 Pt1 N21 C25 -120.3(9) . . . . ?
Ag3 Pt1 N21 C25 125.7(9) . . . . ?
C122 Pt1 N21 N22 -103.4(8) . . . . ?
N11 Pt1 N21 N22 -145(3) . . . . ?
N31 Pt1 N21 N22 67.4(7) . . . . ?
Ag3 Pt1 N21 N22 -46.6(7) . . . . ?
C25 N21 N22 C23 -0.1(11) . . . . ?
Pt1 N21 N22 C23 173.7(7) . . . . ?
C25 N21 N22 Ag1 177.5(7) . . . . ?
Pt1 N21 N22 Ag1 -8.8(10) . . . . ?
N62 Ag1 N22 C23 40(2) . . . . ?
Ag3 Ag1 N22 C23 -128.2(10) . . . . ?
Ag2 Ag1 N22 C23 -175.8(9) . . . . ?
Pt2 Ag1 N22 C23 -98.7(10) . . . . ?
N62 Ag1 N22 N21 -137.2(16) . . . . ?
Ag3 Ag1 N22 N21 55.0(7) . . . . ?
Ag2 Ag1 N22 N21 7.4(8) . . . . ?
Pt2 Ag1 N22 N21 84.5(8) . . . . ?
N21 N22 C23 C24 0.0(12) . . . . ?
Ag1 N22 C23 C24 -177.1(8) . . . . ?
N21 N22 C23 C231 179.7(10) . . . . ?
Ag1 N22 C23 C231 2.6(16) . . . . ?
N22 C23 C24 C25 0.1(13) . . . . ?
C231 C23 C24 C25 -179.6(11) . . . . ?
N22 N21 C25 C24 0.1(12) . . . . ?
Pt1 N21 C25 C24 -172.8(8) . . . . ?
N22 N21 C25 C251 -179.5(9) . . . . ?
Pt1 N21 C25 C251 7.7(15) . . . . ?
C23 C24 C25 N21 -0.1(13) . . . . ?
C23 C24 C25 C251 179.4(10) . . . . ?
N22 C23 C231 C232 147.3(12) . . . . ?
C24 C23 C231 C232 -33.0(19) . . . . ?
N22 C23 C231 C236 -33.4(17) . . . . ?
C24 C23 C231 C236 146.2(12) . . . . ?
C236 C231 C232 C233 0(2) . . . . ?
C23 C231 C232 C233 179.5(13) . . . . ?
C231 C232 C233 C234 0(2) . . . . ?
C232 C233 C234 C235 -1(2) . . . . ?
C233 C234 C235 C236 2(2) . . . . ?
C234 C235 C236 C231 -2(2) . . . . ?
C232 C231 C236 C235 1.0(18) . . . . ?
C23 C231 C236 C235 -178.3(11) . . . . ?
N21 C25 C251 C252 -141.0(11) . . . . ?
C24 C25 C251 C252 39.5(17) . . . . ?
N21 C25 C251 C256 41.0(16) . . . . ?
C24 C25 C251 C256 -138.5(12) . . . . ?
C256 C251 C252 C253 1.4(17) . . . . ?
C25 C251 C252 C253 -176.7(10) . . . . ?
C251 C252 C253 C254 -1.4(17) . . . . ?
C252 C253 C254 C255 1.3(18) . . . . ?
C253 C254 C255 C256 -1.3(17) . . . . ?
C252 C251 C256 C255 -1.4(16) . . . . ?
C25 C251 C256 C255 176.6(10) . . . . ?
C254 C255 C256 C251 1.4(16) . . . . ?
C122 Pt1 N31 C35 -159.0(18) . . . . ?
N21 Pt1 N31 C35 80.0(10) . . . . ?
N11 Pt1 N31 C35 -96.5(10) . . . . ?
Ag3 Pt1 N31 C35 169.0(9) . . . . ?
C122 Pt1 N31 N32 -8(2) . . . . ?
N21 Pt1 N31 N32 -129.2(7) . . . . ?
N11 Pt1 N31 N32 54.4(7) . . . . ?
Ag3 Pt1 N31 N32 -40.2(7) . . . . ?
C35 N31 N32 C33 0.0(11) . . . . ?
Pt1 N31 N32 C33 -158.7(7) . . . . ?
C35 N31 N32 Ag2 173.1(7) . . . . ?
Pt1 N31 N32 Ag2 14.4(9) . . . . ?
N52 Ag2 N32 C33 23(2) . . . . ?
Ag3 Ag2 N32 C33 -175.0(8) . . . . ?
Ag1 Ag2 N32 C33 -129.6(9) . . . . ?
N52 Ag2 N32 N31 -149.1(14) . . . . ?
Ag3 Ag2 N32 N31 13.4(8) . . . . ?
Ag1 Ag2 N32 N31 58.7(7) . . . . ?
N31 N32 C33 C34 0.5(11) . . . . ?
Ag2 N32 C33 C34 -172.1(7) . . . . ?
N31 N32 C33 C331 179.6(9) . . . . ?
Ag2 N32 C33 C331 7.0(14) . . . . ?
N32 C33 C34 C35 -0.8(12) . . . . ?
C331 C33 C34 C35 -179.8(11) . . . . ?
N32 N31 C35 C34 -0.5(12) . . . . ?
Pt1 N31 C35 C34 150.9(8) . . . . ?
N32 N31 C35 C351 175.7(9) . . . . ?
Pt1 N31 C35 C351 -32.8(16) . . . . ?
C33 C34 C35 N31 0.8(12) . . . . ?
C33 C34 C35 C351 -175.3(10) . . . . ?
N32 C33 C331 C332 37.6(15) . . . . ?
C34 C33 C331 C332 -143.6(12) . . . . ?
N32 C33 C331 C336 -138.4(11) . . . . ?
C34 C33 C331 C336 40.5(18) . . . . ?
C336 C331 C332 C333 2.1(17) . . . . ?
C33 C331 C332 C333 -173.9(11) . . . . ?
C331 C332 C333 C334 0.7(19) . . . . ?
C332 C333 C334 C335 -3(2) . . . . ?
C333 C334 C335 C336 3(2) . . . . ?
C334 C335 C336 C331 -0.4(19) . . . . ?
C332 C331 C336 C335 -2.2(18) . . . . ?
C33 C331 C336 C335 173.9(11) . . . . ?
N31 C35 C351 C356 -56.6(15) . . . . ?
C34 C35 C351 C356 119.0(13) . . . . ?
N31 C35 C351 C352 123.7(13) . . . . ?
C34 C35 C351 C352 -60.7(16) . . . . ?
C356 C351 C352 C353 0(2) . . . . ?
C35 C351 C352 C353 179.4(13) . . . . ?
C351 C352 C353 C354 -1(3) . . . . ?
C352 C353 C354 C355 2(3) . . . . ?
C353 C354 C355 C356 -2(2) . . . . ?
C354 C355 C356 C351 0.2(19) . . . . ?
C352 C351 C356 C355 0.6(18) . . . . ?
C35 C351 C356 C355 -179.0(11) . . . . ?
N51 Pt2 N41 C46 -124(2) . . . . ?
C422 Pt2 N41 C46 -173.4(10) . . . . ?
N61 Pt2 N41 C46 13.8(9) . . . . ?
Ag3 Pt2 N41 C46 128.2(9) . . . . ?
Ag1 Pt2 N41 C46 74.0(9) . . . . ?
N51 Pt2 N41 C42 45(3) . . . . ?
C422 Pt2 N41 C42 -3.7(8) . . . . ?
N61 Pt2 N41 C42 -176.5(8) . . . . ?
Ag3 Pt2 N41 C42 -62.1(8) . . . . ?
Ag1 Pt2 N41 C42 -116.3(8) . . . . ?
C46 N41 C42 C43 -2.9(17) . . . . ?
Pt2 N41 C42 C43 -173.4(10) . . . . ?
C46 N41 C42 C421 176.3(10) . . . . ?
Pt2 N41 C42 C421 5.9(13) . . . . ?
N41 C42 C43 C44 1(2) . . . . ?
C421 C42 C43 C44 -178.3(13) . . . . ?
C42 C43 C44 C45 1(2) . . . . ?
C43 C44 C45 C46 -1(2) . . . . ?
C42 N41 C46 C45 3.3(18) . . . . ?
Pt2 N41 C46 C45 172.6(9) . . . . ?
C44 C45 C46 N41 -1(2) . . . . ?
N41 C42 C421 C426 175.6(12) . . . . ?
C43 C42 C421 C426 -5(2) . . . . ?
N41 C42 C421 C422 -5.3(15) . . . . ?
C43 C42 C421 C422 173.9(13) . . . . ?
C426 C421 C422 C423 -5.6(18) . . . . ?
C42 C421 C422 C423 175.2(10) . . . . ?
C426 C421 C422 Pt2 -178.6(10) . . . . ?
C42 C421 C422 Pt2 2.2(13) . . . . ?
C426 C421 C422 Ag3 -97.8(12) . . . . ?
C42 C421 C422 Ag3 83.0(10) . . . . ?
N51 Pt2 C422 C423 14.5(11) . . . . ?
N41 Pt2 C422 C423 -171.5(11) . . . . ?
N61 Pt2 C422 C423 -117(3) . . . . ?
Ag3 Pt2 C422 C423 -72.1(10) . . . . ?
Ag1 Pt2 C422 C423 -105.2(10) . . . . ?
N51 Pt2 C422 C421 -173.3(8) . . . . ?
N41 Pt2 C422 C421 0.7(8) . . . . ?
N61 Pt2 C422 C421 56(3) . . . . ?
Ag3 Pt2 C422 C421 100.1(8) . . . . ?
Ag1 Pt2 C422 C421 67.0(8) . . . . ?
N51 Pt2 C422 Ag3 86.6(3) . . . . ?
N41 Pt2 C422 Ag3 -99.4(3) . . . . ?
N61 Pt2 C422 Ag3 -45(3) . . . . ?
Ag1 Pt2 C422 Ag3 -33.1(3) . . . . ?
C122 Ag3 C422 C423 -42.2(10) . . . . ?
Pt2 Ag3 C422 C423 131.2(9) . . . . ?
Pt1 Ag3 C422 C423 167(6) . . . . ?
Ag1 Ag3 C422 C423 167.6(7) . . . . ?
Ag2 Ag3 C422 C423 99.8(7) . . . . ?
C122 Ag3 C422 C421 76.0(9) . . . . ?
Pt2 Ag3 C422 C421 -110.6(8) . . . . ?
Pt1 Ag3 C422 C421 -75(7) . . . . ?
Ag1 Ag3 C422 C421 -74.2(7) . . . . ?
Ag2 Ag3 C422 C421 -142.0(7) . . . . ?
C122 Ag3 C422 Pt2 -173.4(4) . . . . ?
Pt1 Ag3 C422 Pt2 36(7) . . . . ?
Ag1 Ag3 C422 Pt2 36.4(4) . . . . ?
Ag2 Ag3 C422 Pt2 -31.4(4) . . . . ?
C421 C422 C423 C424 3.5(18) . . . . ?
Pt2 C422 C423 C424 175.4(10) . . . . ?
Ag3 C422 C423 C424 107.4(12) . . . . ?
C422 C423 C424 C425 1(2) . . . . ?
C423 C424 C425 C426 -3(2) . . . . ?
C422 C421 C426 C425 4(2) . . . . ?
C42 C421 C426 C425 -177.3(13) . . . . ?
C424 C425 C426 C421 1(2) . . . . ?
C422 Pt2 N51 N52 -111.5(8) . . . . ?
N41 Pt2 N51 N52 -160(2) . . . . ?
N61 Pt2 N51 N52 61.9(8) . . . . ?
Ag3 Pt2 N51 N52 -52.1(7) . . . . ?
Ag1 Pt2 N51 N52 0.6(8) . . . . ?
C422 Pt2 N51 C55 62.9(9) . . . . ?
N41 Pt2 N51 C55 14(3) . . . . ?
N61 Pt2 N51 C55 -123.7(9) . . . . ?
Ag3 Pt2 N51 C55 122.3(8) . . . . ?
Ag1 Pt2 N51 C55 175.0(8) . . . . ?
C55 N51 N52 C53 0.2(11) . . . . ?
Pt2 N51 N52 C53 175.6(7) . . . . ?
C55 N51 N52 Ag2 -176.4(6) . . . . ?
Pt2 N51 N52 Ag2 -1.0(10) . . . . ?
N32 Ag2 N52 N51 -149.0(15) . . . . ?
Ag3 Ag2 N52 N51 47.9(7) . . . . ?
Ag1 Ag2 N52 N51 1.0(8) . . . . ?
N32 Ag2 N52 C53 35(2) . . . . ?
Ag3 Ag2 N52 C53 -127.8(10) . . . . ?
Ag1 Ag2 N52 C53 -174.7(9) . . . . ?
N51 N52 C53 C54 -0.7(12) . . . . ?
Ag2 N52 C53 C54 175.4(8) . . . . ?
N51 N52 C53 C531 178.3(9) . . . . ?
Ag2 N52 C53 C531 -5.6(16) . . . . ?
N52 C53 C54 C55 0.8(13) . . . . ?
C531 C53 C54 C55 -178.0(11) . . . . ?
N52 N51 C55 C54 0.3(11) . . . . ?
Pt2 N51 C55 C54 -174.7(7) . . . . ?
N52 N51 C55 C551 -178.2(10) . . . . ?
Pt2 N51 C55 C551 6.8(15) . . . . ?
C53 C54 C55 N51 -0.6(12) . . . . ?
C53 C54 C55 C551 177.8(11) . . . . ?
N52 C53 C531 C532 148.3(11) . . . . ?
C54 C53 C531 C532 -33.0(18) . . . . ?
N52 C53 C531 C536 -34.3(17) . . . . ?
C54 C53 C531 C536 144.4(13) . . . . ?
C536 C531 C532 C533 1.6(18) . . . . ?
C53 C531 C532 C533 179.1(11) . . . . ?
C531 C532 C533 C534 -0.8(19) . . . . ?
C532 C533 C534 C535 -1(2) . . . . ?
C533 C534 C535 C536 1.7(19) . . . . ?
C534 C535 C536 C531 -0.9(18) . . . . ?
C532 C531 C536 C535 -0.7(17) . . . . ?
C53 C531 C536 C535 -178.1(11) . . . . ?
N51 C55 C551 C552 38.4(18) . . . . ?
C54 C55 C551 C552 -139.8(13) . . . . ?
N51 C55 C551 C556 -142.9(11) . . . . ?
C54 C55 C551 C556 38.9(17) . . . . ?
C556 C551 C552 C553 0(2) . . . . ?
C55 C551 C552 C553 178.6(13) . . . . ?
C551 C552 C553 C554 0(2) . . . . ?
C552 C553 C554 C555 1(2) . . . . ?
C553 C554 C555 C556 0(2) . . . . ?
C554 C555 C556 C551 0(2) . . . . ?
C552 C551 C556 C555 0.5(18) . . . . ?
C55 C551 C556 C555 -178.2(11) . . . . ?
N51 Pt2 N61 C65 65.8(10) . . . . ?
C422 Pt2 N61 C65 -163(2) . . . . ?
N41 Pt2 N61 C65 -109.0(10) . . . . ?
Ag3 Pt2 N61 C65 155.5(9) . . . . ?
Ag1 Pt2 N61 C65 -175.3(11) . . . . ?
N51 Pt2 N61 N62 -122.7(7) . . . . ?
C422 Pt2 N61 N62 9(3) . . . . ?
N41 Pt2 N61 N62 62.6(7) . . . . ?
Ag3 Pt2 N61 N62 -32.9(7) . . . . ?
Ag1 Pt2 N61 N62 -3.7(6) . . . . ?
C65 N61 N62 C63 0.5(12) . . . . ?
Pt2 N61 N62 C63 -173.1(7) . . . . ?
C65 N61 N62 Ag1 179.5(7) . . . . ?
Pt2 N61 N62 Ag1 5.9(9) . . . . ?
N22 Ag1 N62 C63 32(2) . . . . ?
Ag3 Ag1 N62 C63 -160.8(9) . . . . ?
Ag2 Ag1 N62 C63 -115.5(10) . . . . ?
Pt2 Ag1 N62 C63 174.9(11) . . . . ?
N22 Ag1 N62 N61 -146.7(16) . . . . ?
Ag3 Ag1 N62 N61 20.5(8) . . . . ?
Ag2 Ag1 N62 N61 65.8(7) . . . . ?
Pt2 Ag1 N62 N61 -3.8(6) . . . . ?
N61 N62 C63 C64 0.2(12) . . . . ?
Ag1 N62 C63 C64 -178.6(8) . . . . ?
N61 N62 C63 C631 -177.5(9) . . . . ?
Ag1 N62 C63 C631 3.7(16) . . . . ?
N62 C63 C64 C65 -0.8(13) . . . . ?
C631 C63 C64 C65 176.7(11) . . . . ?
N62 N61 C65 C64 -1.0(12) . . . . ?
Pt2 N61 C65 C64 171.0(8) . . . . ?
N62 N61 C65 C651 -179.7(10) . . . . ?
Pt2 N61 C65 C651 -7.7(17) . . . . ?
C63 C64 C65 N61 1.1(13) . . . . ?
C63 C64 C65 C651 179.7(11) . . . . ?
N62 C63 C631 C636 -159.9(11) . . . . ?
C64 C63 C631 C636 22.8(18) . . . . ?
N62 C63 C631 C632 20.4(16) . . . . ?
C64 C63 C631 C632 -156.9(11) . . . . ?
C636 C631 C632 C633 1.6(17) . . . . ?
C63 C631 C632 C633 -178.7(10) . . . . ?
C631 C632 C633 C634 -1.9(17) . . . . ?
C632 C633 C634 C635 0.8(19) . . . . ?
C633 C634 C635 C636 1(2) . . . . ?
C634 C635 C636 C631 -1(2) . . . . ?
C632 C631 C636 C635 -0.1(18) . . . . ?
C63 C631 C636 C635 -179.8(11) . . . . ?
N61 C65 C651 C652 105.7(13) . . . . ?
C64 C65 C651 C652 -72.7(17) . . . . ?
N61 C65 C651 C656 -75.3(15) . . . . ?
C64 C65 C651 C656 106.3(14) . . . . ?
C656 C651 C652 C653 0.8(17) . . . . ?
C65 C651 C652 C653 179.7(11) . . . . ?
C651 C652 C653 C654 -1.2(18) . . . . ?
C652 C653 C654 C655 0.1(19) . . . . ?
C653 C654 C655 C656 1(2) . . . . ?
C654 C655 C656 C651 -2(2) . . . . ?
C652 C651 C656 C655 0.7(18) . . . . ?
C65 C651 C656 C655 -178.3(12) . . . . ?
C4 C5 C6 C7 -30(7) . . . . ?
C5 C6 C7 C8 151(4) . . . . ?
C6 C7 C8 C9 173(3) . . . . ?
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1a
_database_code_depnum_ccdc_archive 'CCDC 1535614'
_audit_update_record             
;
2017-03-02 deposited with the CCDC.
2017-05-19 downloaded from the CCDC.
;
#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C42 H34 Cl3 N5 Pt'
_chemical_formula_moiety         'C42 H34 Cl3 N5 Pt'
_chemical_formula_weight         910.21
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_space_group_crystal_system      monoclinic
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
_space_group_IT_number           14
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-1/2-Y,-1/2+Z
#------------------------------------------------------------------------------
_cell_length_a                   15.354(2)
_cell_length_b                   20.314(3)
_cell_length_c                   23.041(4)
_cell_angle_alpha                90.0000
_cell_angle_beta                 93.005(2)
_cell_angle_gamma                90.0000
_cell_volume                     7176.8(19)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    18827
_cell_measurement_theta_min      1.85
_cell_measurement_theta_max      29.13
_cell_measurement_temperature    273
#------------------------------------------------------------------------------
_exptl_crystal_description       platelet
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.110
_exptl_crystal_size_mid          0.090
_exptl_crystal_size_min          0.040
_exptl_crystal_density_diffrn    1.685
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3600.00
_exptl_absorpt_coefficient_mu    4.157
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_correction_T_min  0.675
_exptl_absorpt_correction_T_max  0.847

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      273
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 29.257
_diffrn_reflns_number            65554
_diffrn_reflns_av_R_equivalents  0.0697
_diffrn_reflns_theta_max         29.110
_diffrn_reflns_theta_min         1.852
_diffrn_reflns_theta_full        29.110
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measured_fraction_theta_full 0.983
_diffrn_reflns_Laue_measured_fraction_max 0.000
_diffrn_reflns_Laue_measured_fraction_full 0.000
_diffrn_reflns_point_group_measured_fraction_max 0.000
_diffrn_reflns_point_group_measured_fraction_full 0.000
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_limit_l_max       31
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_reflns_number_total             18939
_reflns_number_gt                14572
_reflns_threshold_expression     F²>2.0σ(F²)

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_all          0.0909
_refine_ls_R_factor_gt           0.0655
_refine_ls_wR_factor_ref         0.1340
_refine_ls_wR_factor_gt          0.1203
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_reflns         18939
_refine_ls_number_parameters     919
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0365P)²+40.9788P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.001
_refine_diff_density_max         2.84
_refine_diff_density_min         -2.04
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.642939(17) 0.687914(13) 0.265387(11) 0.01696(7) Uani 1 1 d . . .
Pt2 Pt 0.856689(17) 0.339507(13) 0.243834(11) 0.01845(7) Uani 1 1 d . . .
N11 N 0.7668(4) 0.6553(3) 0.2806(2) 0.0221(13) Uani 1 1 d . . .
C12 C 0.7908(4) 0.6057(3) 0.2452(3) 0.0203(14) Uani 1 1 d . . .
C13 C 0.8765(5) 0.5823(4) 0.2491(3) 0.0261(16) Uani 1 1 d . . .
H13 H 0.8930 0.5486 0.2247 0.031 Uiso 1 1 calc R . .
C14 C 0.9367(5) 0.6089(4) 0.2890(3) 0.0296(17) Uani 1 1 d . . .
H14 H 0.9937 0.5934 0.2919 0.035 Uiso 1 1 calc R . .
C15 C 0.9105(5) 0.6591(4) 0.3246(3) 0.0285(17) Uani 1 1 d . . .
H15 H 0.9500 0.6781 0.3516 0.034 Uiso 1 1 calc R . .
C16 C 0.8250(5) 0.6809(4) 0.3197(3) 0.0252(16) Uani 1 1 d . . .
H16 H 0.8075 0.7143 0.3442 0.030 Uiso 1 1 calc R . .
C121 C 0.7228(5) 0.5826(3) 0.2036(3) 0.0216(15) Uani 1 1 d . . .
C122 C 0.6444(4) 0.6181(3) 0.2046(3) 0.0178(13) Uani 1 1 d . . .
C123 C 0.5764(5) 0.6002(4) 0.1643(3) 0.0249(16) Uani 1 1 d . . .
H123 H 0.5237 0.6228 0.1641 0.030 Uiso 1 1 calc R . .
C124 C 0.5868(5) 0.5492(4) 0.1248(3) 0.0286(17) Uani 1 1 d . . .
H124 H 0.5416 0.5384 0.0981 0.034 Uiso 1 1 calc R . .
C125 C 0.6649(5) 0.5143(4) 0.1253(3) 0.0293(17) Uani 1 1 d . . .
H125 H 0.6717 0.4799 0.0993 0.035 Uiso 1 1 calc R . .
C126 C 0.7321(5) 0.5311(4) 0.1646(3) 0.0272(16) Uani 1 1 d . . .
H126 H 0.7842 0.5078 0.1650 0.033 Uiso 1 1 calc R . .
N21 N 0.5195(4) 0.7159(3) 0.2406(2) 0.0203(12) Uani 1 1 d . . .
N22 N 0.5049(4) 0.7595(3) 0.1957(2) 0.0182(12) Uani 1 1 d . . .
H22 H 0.5449 0.7816 0.1796 0.022 Uiso 1 1 calc R . .
C23 C 0.4192(4) 0.7630(3) 0.1802(3) 0.0197(14) Uani 1 1 d . . .
C24 C 0.3758(5) 0.7212(3) 0.2155(3) 0.0210(14) Uani 1 1 d . . .
H24 H 0.3161 0.7134 0.2151 0.025 Uiso 1 1 calc R . .
C25 C 0.4415(5) 0.6924(3) 0.2526(3) 0.0201(14) Uani 1 1 d . . .
C231 C 0.3855(5) 0.8065(3) 0.1333(3) 0.0205(14) Uani 1 1 d . . .
C232 C 0.4372(5) 0.8523(4) 0.1059(3) 0.0233(15) Uani 1 1 d . . .
H232 H 0.4958 0.8561 0.1177 0.028 Uiso 1 1 calc R . .
C233 C 0.4033(5) 0.8922(4) 0.0617(3) 0.0277(17) Uani 1 1 d . . .
H233 H 0.4391 0.9220 0.0436 0.033 Uiso 1 1 calc R . .
C234 C 0.3153(5) 0.8877(4) 0.0444(3) 0.0267(16) Uani 1 1 d . . .
H234 H 0.2922 0.9148 0.0150 0.032 Uiso 1 1 calc R . .
C235 C 0.2618(5) 0.8427(4) 0.0707(3) 0.0307(18) Uani 1 1 d . . .
H235 H 0.2030 0.8396 0.0591 0.037 Uiso 1 1 calc R . .
C236 C 0.2974(5) 0.8023(4) 0.1149(3) 0.0241(15) Uani 1 1 d . . .
H236 H 0.2618 0.7720 0.1325 0.029 Uiso 1 1 calc R . .
C251 C 0.4292(4) 0.6443(4) 0.3000(3) 0.0199(14) Uani 1 1 d . . .
C252 C 0.3899(5) 0.6651(4) 0.3499(3) 0.0300(17) Uani 1 1 d . . .
H252 H 0.3737 0.7089 0.3538 0.036 Uiso 1 1 calc R . .
C253 C 0.3747(6) 0.6206(5) 0.3937(4) 0.045(2) Uani 1 1 d . . .
H253 H 0.3503 0.6347 0.4276 0.054 Uiso 1 1 calc R . .
C254 C 0.3960(6) 0.5557(5) 0.3867(4) 0.052(3) Uani 1 1 d . . .
H254 H 0.3846 0.5259 0.4160 0.063 Uiso 1 1 calc R . .
C255 C 0.4345(6) 0.5329(4) 0.3367(4) 0.043(2) Uani 1 1 d . . .
H255 H 0.4475 0.4885 0.3323 0.051 Uiso 1 1 calc R . .
C256 C 0.4527(5) 0.5783(4) 0.2937(4) 0.0303(17) Uani 1 1 d . . .
H256 H 0.4805 0.5647 0.2609 0.036 Uiso 1 1 calc R . .
N31 N 0.6459(3) 0.7592(3) 0.3337(2) 0.0178(12) Uani 1 1 d . . .
N32 N 0.6466(4) 0.8238(3) 0.3208(2) 0.0195(12) Uani 1 1 d . . .
H32 H 0.6479 0.8392 0.2860 0.023 Uiso 1 1 calc R . .
C33 C 0.6449(4) 0.8619(3) 0.3694(3) 0.0197(14) Uani 1 1 d . . .
C34 C 0.6439(5) 0.8179(3) 0.4150(3) 0.0215(15) Uani 1 1 d . . .
H34 H 0.6426 0.8287 0.4542 0.026 Uiso 1 1 calc R . .
C35 C 0.6450(5) 0.7548(4) 0.3921(3) 0.0232(15) Uani 1 1 d . . .
C331 C 0.6481(5) 0.9338(4) 0.3708(3) 0.0237(15) Uani 1 1 d . . .
C332 C 0.6654(5) 0.9715(4) 0.3218(3) 0.0252(16) Uani 1 1 d . . .
H332 H 0.6709 0.9511 0.2861 0.030 Uiso 1 1 calc R . .
C333 C 0.6742(5) 1.0392(4) 0.3267(4) 0.0296(17) Uani 1 1 d . . .
H333 H 0.6855 1.0639 0.2939 0.036 Uiso 1 1 calc R . .
C334 C 0.6665(5) 1.0708(4) 0.3796(4) 0.0346(19) Uani 1 1 d . . .
H334 H 0.6735 1.1162 0.3825 0.042 Uiso 1 1 calc R . .
C335 C 0.6484(5) 1.0336(4) 0.4282(4) 0.0304(18) Uani 1 1 d . . .
H335 H 0.6429 1.0541 0.4638 0.037 Uiso 1 1 calc R . .
C336 C 0.6384(5) 0.9661(4) 0.4235(3) 0.0284(17) Uani 1 1 d . . .
H336 H 0.6251 0.9418 0.4561 0.034 Uiso 1 1 calc R . .
C351 C 0.6456(5) 0.6924(4) 0.4252(3) 0.0225(15) Uani 1 1 d . . .
C352 C 0.6708(6) 0.6955(5) 0.4846(3) 0.039(2) Uani 1 1 d . . .
H352 H 0.6880 0.7356 0.5011 0.047 Uiso 1 1 calc R . .
C353 C 0.6704(6) 0.6398(5) 0.5189(4) 0.045(2) Uani 1 1 d . . .
H353 H 0.6867 0.6427 0.5583 0.054 Uiso 1 1 calc R . .
C354 C 0.6456(7) 0.5795(5) 0.4948(4) 0.049(3) Uani 1 1 d . . .
H354 H 0.6474 0.5415 0.5174 0.059 Uiso 1 1 calc R . .
C355 C 0.6181(6) 0.5769(4) 0.4366(4) 0.039(2) Uani 1 1 d . . .
H355 H 0.5992 0.5371 0.4204 0.047 Uiso 1 1 calc R . .
C356 C 0.6185(5) 0.6330(4) 0.4024(4) 0.0299(17) Uani 1 1 d . . .
H356 H 0.6001 0.6303 0.3633 0.036 Uiso 1 1 calc R . .
N41 N 0.7325(4) 0.3706(3) 0.2295(3) 0.0237(13) Uani 1 1 d . . .
C42 C 0.7062(5) 0.4185(4) 0.2675(3) 0.0254(16) Uani 1 1 d . . .
C43 C 0.6194(5) 0.4391(4) 0.2642(4) 0.0328(19) Uani 1 1 d . . .
H43 H 0.6010 0.4708 0.2900 0.039 Uiso 1 1 calc R . .
C44 C 0.5603(5) 0.4129(4) 0.2232(4) 0.036(2) Uani 1 1 d . . .
H44 H 0.5025 0.4267 0.2214 0.043 Uiso 1 1 calc R . .
C45 C 0.5884(5) 0.3662(4) 0.1850(4) 0.034(2) Uani 1 1 d . . .
H45 H 0.5499 0.3486 0.1566 0.041 Uiso 1 1 calc R . .
C46 C 0.6751(5) 0.3457(4) 0.1894(3) 0.0273(17) Uani 1 1 d . . .
H46 H 0.6937 0.3139 0.1638 0.033 Uiso 1 1 calc R . .
C421 C 0.7738(5) 0.4397(4) 0.3089(3) 0.0254(16) Uani 1 1 d . . .
C422 C 0.8535(4) 0.4059(3) 0.3074(3) 0.0187(14) Uani 1 1 d . . .
C423 C 0.9183(5) 0.4227(4) 0.3489(3) 0.0264(16) Uani 1 1 d . . .
H423 H 0.9709 0.3998 0.3498 0.032 Uiso 1 1 calc R . .
C424 C 0.9076(5) 0.4717(4) 0.3888(3) 0.0308(18) Uani 1 1 d . . .
H424 H 0.9529 0.4818 0.4157 0.037 Uiso 1 1 calc R . .
C425 C 0.8300(6) 0.5064(4) 0.3894(4) 0.0343(19) Uani 1 1 d . . .
H425 H 0.8231 0.5399 0.4164 0.041 Uiso 1 1 calc R . .
C426 C 0.7624(6) 0.4904(4) 0.3492(4) 0.0331(19) Uani 1 1 d . . .
H426 H 0.7099 0.5133 0.3490 0.040 Uiso 1 1 calc R . .
N51 N 0.9819(4) 0.3115(3) 0.2664(2) 0.0182(12) Uani 1 1 d . . .
N52 N 0.9965(3) 0.2651(3) 0.3076(2) 0.0181(12) Uani 1 1 d . . .
H52 H 0.9563 0.2432 0.3237 0.022 Uiso 1 1 calc R . .
C53 C 1.0831(4) 0.2575(3) 0.3201(3) 0.0194(14) Uani 1 1 d . . .
C54 C 1.1252(4) 0.3014(4) 0.2858(3) 0.0212(15) Uani 1 1 d . . .
H54 H 1.1851 0.3080 0.2850 0.025 Uiso 1 1 calc R . .
C55 C 1.0591(5) 0.3345(3) 0.2522(3) 0.0197(14) Uani 1 1 d . . .
C531 C 1.1178(4) 0.2115(3) 0.3647(3) 0.0186(14) Uani 1 1 d . . .
C532 C 1.0645(5) 0.1704(4) 0.3961(3) 0.0248(16) Uani 1 1 d . . .
H532 H 1.0045 0.1707 0.3880 0.030 Uiso 1 1 calc R . .
C533 C 1.0996(5) 0.1293(3) 0.4388(3) 0.0237(15) Uani 1 1 d . . .
H533 H 1.0632 0.1026 0.4597 0.028 Uiso 1 1 calc R . .
C534 C 1.1885(5) 0.1277(4) 0.4507(3) 0.0267(16) Uani 1 1 d . . .
H534 H 1.2122 0.1000 0.4796 0.032 Uiso 1 1 calc R . .
C535 C 1.2424(5) 0.1673(4) 0.4197(3) 0.0270(17) Uani 1 1 d . . .
H535 H 1.3024 0.1654 0.4273 0.032 Uiso 1 1 calc R . .
C536 C 1.2088(5) 0.2097(3) 0.3775(3) 0.0217(15) Uani 1 1 d . . .
H536 H 1.2458 0.2370 0.3577 0.026 Uiso 1 1 calc R . .
C551 C 1.0700(4) 0.3882(4) 0.2101(3) 0.0211(14) Uani 1 1 d . . .
C552 C 1.1176(5) 0.3759(4) 0.1615(3) 0.0248(16) Uani 1 1 d . . .
H552 H 1.1388 0.3338 0.1548 0.030 Uiso 1 1 calc R . .
C553 C 1.1334(5) 0.4266(4) 0.1228(3) 0.0326(18) Uani 1 1 d . . .
H553 H 1.1631 0.4179 0.0895 0.039 Uiso 1 1 calc R . .
C554 C 1.1052(5) 0.4898(4) 0.1336(3) 0.0307(18) Uani 1 1 d . . .
H554 H 1.1175 0.5240 0.1084 0.037 Uiso 1 1 calc R . .
C555 C 1.0581(5) 0.5018(4) 0.1824(3) 0.0259(16) Uani 1 1 d . . .
H555 H 1.0386 0.5442 0.1898 0.031 Uiso 1 1 calc R . .
C556 C 1.0403(5) 0.4511(4) 0.2197(3) 0.0250(16) Uani 1 1 d . . .
H556 H 1.0077 0.4595 0.2518 0.030 Uiso 1 1 calc R . .
N61 N 0.8537(4) 0.2705(3) 0.1744(2) 0.0197(12) Uani 1 1 d . . .
N62 N 0.8486(4) 0.2058(3) 0.1865(3) 0.0222(13) Uani 1 1 d . . .
H62 H 0.8454 0.1903 0.2210 0.027 Uiso 1 1 calc R . .
C63 C 0.8490(5) 0.1680(4) 0.1382(3) 0.0242(15) Uani 1 1 d . . .
C64 C 0.8547(5) 0.2110(4) 0.0924(3) 0.0252(16) Uani 1 1 d . . .
H64 H 0.8563 0.1998 0.0533 0.030 Uiso 1 1 calc R . .
C65 C 0.8577(5) 0.2749(3) 0.1156(3) 0.0221(15) Uani 1 1 d . . .
C631 C 0.8420(5) 0.0957(3) 0.1375(3) 0.0223(15) Uani 1 1 d . . .
C632 C 0.8178(5) 0.0605(4) 0.1855(3) 0.0275(17) Uani 1 1 d . . .
H632 H 0.8085 0.0820 0.2202 0.033 Uiso 1 1 calc R . .
C633 C 0.8076(5) -0.0077(4) 0.1812(4) 0.0338(19) Uani 1 1 d . . .
H633 H 0.7912 -0.0315 0.2133 0.041 Uiso 1 1 calc R . .
C634 C 0.8214(5) -0.0402(4) 0.1298(4) 0.0333(19) Uani 1 1 d . . .
H634 H 0.8145 -0.0856 0.1276 0.040 Uiso 1 1 calc R . .
C635 C 0.8454(5) -0.0053(4) 0.0818(3) 0.0305(17) Uani 1 1 d . . .
H635 H 0.8541 -0.0271 0.0470 0.037 Uiso 1 1 calc R . .
C636 C 0.8567(5) 0.0629(4) 0.0857(3) 0.0284(17) Uani 1 1 d . . .
H636 H 0.8740 0.0865 0.0537 0.034 Uiso 1 1 calc R . .
C651 C 0.8639(5) 0.3362(4) 0.0828(3) 0.0252(16) Uani 1 1 d . . .
C652 C 0.8519(6) 0.3339(4) 0.0217(3) 0.0327(19) Uani 1 1 d . . .
H652 H 0.8398 0.2937 0.0037 0.039 Uiso 1 1 calc R . .
C653 C 0.8577(6) 0.3894(4) -0.0119(3) 0.0317(18) Uani 1 1 d . . .
H653 H 0.8480 0.3870 -0.0520 0.038 Uiso 1 1 calc R . .
C654 C 0.8781(6) 0.4495(4) 0.0147(4) 0.0353(19) Uani 1 1 d . . .
H654 H 0.8824 0.4873 -0.0077 0.042 Uiso 1 1 calc R . .
C655 C 0.8917(5) 0.4529(3) 0.0741(3) 0.0239(15) Uani 1 1 d . . .
H655 H 0.9056 0.4930 0.0917 0.029 Uiso 1 1 calc R . .
C656 C 0.8848(5) 0.3964(4) 0.1079(3) 0.0251(16) Uani 1 1 d . . .
H656 H 0.8945 0.3992 0.1480 0.030 Uiso 1 1 calc R . .
Cl1 Cl 0.84439(11) 0.16933(9) 0.31927(8) 0.0232(4) Uani 1 1 d . . .
Cl2 Cl 0.65393(11) 0.85801(9) 0.18897(7) 0.0227(3) Uani 1 1 d . . .
C1 C 0.4489(6) 0.7354(4) -0.0085(4) 0.039(2) Uani 1 1 d . . .
H1A H 0.4310 0.7767 0.0083 0.047 Uiso 1 1 calc R . .
H1B H 0.4872 0.7455 -0.0395 0.047 Uiso 1 1 calc R . .
Cl3 Cl 0.50749(14) 0.68873(12) 0.04554(9) 0.0395(5) Uani 1 1 d . . .
Cl4 Cl 0.3592(2) 0.69530(18) -0.03687(15) 0.0930(13) Uani 1 1 d . . .
C2 C 1.1058(8) 0.2010(5) 0.0040(5) 0.060(3) Uani 1 1 d . . .
H2A H 1.1434 0.1702 0.0255 0.072 Uiso 1 1 calc R . .
H2B H 1.1391 0.2202 -0.0264 0.072 Uiso 1 1 calc R . .
Cl5 Cl 1.07502(19) 0.26285(12) 0.05055(10) 0.0530(7) Uani 1 1 d . . .
Cl6 Cl 1.0161(2) 0.15805(18) -0.02822(16) 0.0863(12) Uani 1 1 d . . .


#==============================================================================
_computing_data_collection       DTREK
_computing_cell_refinement       DTREK
_computing_data_reduction        DTREK
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.2 (Rigaku, 2015)'
_computing_molecular_graphics    'CrystalStructure 4.2'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C122 1.994(7) . ?
Pt1 N11 2.027(6) . ?
Pt1 N21 2.032(6) . ?
Pt1 N31 2.138(6) . ?
Pt2 C422 1.993(7) . ?
Pt2 N41 2.019(6) . ?
Pt2 N51 2.046(5) . ?
Pt2 N61 2.127(6) . ?
N11 C16 1.340(9) . ?
N11 C12 1.360(9) . ?
C12 C13 1.398(9) . ?
C12 C121 1.456(10) . ?
C13 C14 1.378(10) . ?
C13 H13 0.9300 . ?
C14 C15 1.381(11) . ?
C14 H14 0.9300 . ?
C15 C16 1.385(10) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C121 C126 1.392(10) . ?
C121 C122 1.405(9) . ?
C122 C123 1.408(9) . ?
C123 C124 1.395(10) . ?
C123 H123 0.9300 . ?
C124 C125 1.392(11) . ?
C124 H124 0.9300 . ?
C125 C126 1.379(11) . ?
C125 H125 0.9300 . ?
C126 H126 0.9300 . ?
N21 C25 1.331(9) . ?
N21 N22 1.372(7) . ?
N22 C23 1.348(8) . ?
N22 H22 0.8600 . ?
C23 C24 1.371(9) . ?
C23 C231 1.470(9) . ?
C24 C25 1.414(9) . ?
C24 H24 0.9300 . ?
C25 C251 1.485(9) . ?
C231 C232 1.394(10) . ?
C231 C236 1.399(9) . ?
C232 C233 1.383(10) . ?
C232 H232 0.9300 . ?
C233 C234 1.391(10) . ?
C233 H233 0.9300 . ?
C234 C235 1.389(11) . ?
C234 H234 0.9300 . ?
C235 C236 1.398(10) . ?
C235 H235 0.9300 . ?
C236 H236 0.9300 . ?
C251 C252 1.391(10) . ?
C251 C256 1.399(10) . ?
C252 C253 1.383(11) . ?
C252 H252 0.9300 . ?
C253 C254 1.371(14) . ?
C253 H253 0.9300 . ?
C254 C255 1.400(14) . ?
C254 H254 0.9300 . ?
C255 C256 1.392(11) . ?
C255 H255 0.9300 . ?
C256 H256 0.9300 . ?
N31 N32 1.347(8) . ?
N31 C35 1.348(8) . ?
N32 C33 1.363(8) . ?
N32 H32 0.8600 . ?
C33 C34 1.379(10) . ?
C33 C331 1.462(10) . ?
C34 C35 1.387(10) . ?
C34 H34 0.9300 . ?
C35 C351 1.478(10) . ?
C331 C336 1.396(10) . ?
C331 C332 1.399(10) . ?
C332 C333 1.385(10) . ?
C332 H332 0.9300 . ?
C333 C334 1.388(11) . ?
C333 H333 0.9300 . ?
C334 C335 1.391(11) . ?
C334 H334 0.9300 . ?
C335 C336 1.384(10) . ?
C335 H335 0.9300 . ?
C336 H336 0.9300 . ?
C351 C356 1.372(11) . ?
C351 C352 1.406(10) . ?
C352 C353 1.380(12) . ?
C352 H352 0.9300 . ?
C353 C354 1.390(14) . ?
C353 H353 0.9300 . ?
C354 C355 1.385(12) . ?
C354 H354 0.9300 . ?
C355 C356 1.387(11) . ?
C355 H355 0.9300 . ?
C356 H356 0.9300 . ?
N41 C46 1.341(9) . ?
N41 C42 1.383(9) . ?
C42 C43 1.395(10) . ?
C42 C421 1.439(10) . ?
C43 C44 1.381(11) . ?
C43 H43 0.9300 . ?
C44 C45 1.379(12) . ?
C44 H44 0.9300 . ?
C45 C46 1.394(10) . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C421 C422 1.405(9) . ?
C421 C426 1.405(11) . ?
C422 C423 1.387(10) . ?
C423 C424 1.371(10) . ?
C423 H423 0.9300 . ?
C424 C425 1.385(11) . ?
C424 H424 0.9300 . ?
C425 C426 1.393(12) . ?
C425 H425 0.9300 . ?
C426 H426 0.9300 . ?
N51 C55 1.330(8) . ?
N51 N52 1.348(7) . ?
N52 C53 1.354(8) . ?
N52 H52 0.8600 . ?
C53 C54 1.375(9) . ?
C53 C531 1.467(9) . ?
C54 C55 1.415(9) . ?
C54 H54 0.9300 . ?
C55 C551 1.475(9) . ?
C531 C532 1.398(10) . ?
C531 C536 1.414(9) . ?
C532 C533 1.379(10) . ?
C532 H532 0.9300 . ?
C533 C534 1.380(10) . ?
C533 H533 0.9300 . ?
C534 C535 1.380(10) . ?
C534 H534 0.9300 . ?
C535 C536 1.377(10) . ?
C535 H535 0.9300 . ?
C536 H536 0.9300 . ?
C551 C556 1.380(10) . ?
C551 C552 1.391(9) . ?
C552 C553 1.392(10) . ?
C552 H552 0.9300 . ?
C553 C554 1.383(11) . ?
C553 H553 0.9300 . ?
C554 C555 1.389(10) . ?
C554 H554 0.9300 . ?
C555 C556 1.379(10) . ?
C555 H555 0.9300 . ?
C556 H556 0.9300 . ?
N61 N62 1.346(8) . ?
N61 C65 1.362(9) . ?
N62 C63 1.351(9) . ?
N62 H62 0.8600 . ?
C63 C64 1.378(10) . ?
C63 C631 1.473(10) . ?
C64 C65 1.402(10) . ?
C64 H64 0.9300 . ?
C65 C651 1.462(10) . ?
C631 C632 1.382(10) . ?
C631 C636 1.396(10) . ?
C632 C633 1.396(11) . ?
C632 H632 0.9300 . ?
C633 C634 1.380(12) . ?
C633 H633 0.9300 . ?
C634 C635 1.380(11) . ?
C634 H634 0.9300 . ?
C635 C636 1.399(11) . ?
C635 H635 0.9300 . ?
C636 H636 0.9300 . ?
C651 C656 1.383(10) . ?
C651 C652 1.411(10) . ?
C652 C653 1.374(10) . ?
C652 H652 0.9300 . ?
C653 C654 1.395(11) . ?
C653 H653 0.9300 . ?
C654 C655 1.374(10) . ?
C654 H654 0.9300 . ?
C655 C656 1.396(9) . ?
C655 H655 0.9300 . ?
C656 H656 0.9300 . ?
C1 Cl4 1.701(9) . ?
C1 Cl3 1.771(8) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 Cl5 1.734(11) . ?
C2 Cl6 1.761(11) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C122 Pt1 N11 81.1(3) . . ?
C122 Pt1 N21 92.6(2) . . ?
N11 Pt1 N21 173.2(2) . . ?
C122 Pt1 N31 176.7(2) . . ?
N11 Pt1 N31 96.3(2) . . ?
N21 Pt1 N31 90.0(2) . . ?
C422 Pt2 N41 81.3(3) . . ?
C422 Pt2 N51 93.5(3) . . ?
N41 Pt2 N51 174.4(2) . . ?
C422 Pt2 N61 177.1(2) . . ?
N41 Pt2 N61 95.7(2) . . ?
N51 Pt2 N61 89.5(2) . . ?
C16 N11 C12 120.0(6) . . ?
C16 N11 Pt1 125.2(5) . . ?
C12 N11 Pt1 114.8(5) . . ?
N11 C12 C13 119.8(7) . . ?
N11 C12 C121 115.2(6) . . ?
C13 C12 C121 124.9(6) . . ?
C14 C13 C12 120.4(7) . . ?
C14 C13 H13 119.8 . . ?
C12 C13 H13 119.8 . . ?
C13 C14 C15 118.6(7) . . ?
C13 C14 H14 120.7 . . ?
C15 C14 H14 120.7 . . ?
C14 C15 C16 119.5(7) . . ?
C14 C15 H15 120.2 . . ?
C16 C15 H15 120.2 . . ?
N11 C16 C15 121.7(7) . . ?
N11 C16 H16 119.2 . . ?
C15 C16 H16 119.2 . . ?
C126 C121 C122 120.8(7) . . ?
C126 C121 C12 125.0(7) . . ?
C122 C121 C12 114.2(6) . . ?
C121 C122 C123 117.6(6) . . ?
C121 C122 Pt1 114.7(5) . . ?
C123 C122 Pt1 127.7(5) . . ?
C124 C123 C122 121.1(7) . . ?
C124 C123 H123 119.4 . . ?
C122 C123 H123 119.4 . . ?
C125 C124 C123 120.0(7) . . ?
C125 C124 H124 120.0 . . ?
C123 C124 H124 120.0 . . ?
C126 C125 C124 119.6(7) . . ?
C126 C125 H125 120.2 . . ?
C124 C125 H125 120.2 . . ?
C125 C126 C121 120.8(7) . . ?
C125 C126 H126 119.6 . . ?
C121 C126 H126 119.6 . . ?
C25 N21 N22 106.0(5) . . ?
C25 N21 Pt1 132.6(5) . . ?
N22 N21 Pt1 120.4(4) . . ?
C23 N22 N21 110.6(6) . . ?
C23 N22 H22 124.7 . . ?
N21 N22 H22 124.7 . . ?
N22 C23 C24 108.0(6) . . ?
N22 C23 C231 121.8(6) . . ?
C24 C23 C231 130.2(7) . . ?
C23 C24 C25 105.1(6) . . ?
C23 C24 H24 127.4 . . ?
C25 C24 H24 127.4 . . ?
N21 C25 C24 110.3(6) . . ?
N21 C25 C251 122.6(6) . . ?
C24 C25 C251 127.0(6) . . ?
C232 C231 C236 118.0(7) . . ?
C232 C231 C23 123.2(6) . . ?
C236 C231 C23 118.8(7) . . ?
C233 C232 C231 121.6(7) . . ?
C233 C232 H232 119.2 . . ?
C231 C232 H232 119.2 . . ?
C232 C233 C234 119.6(7) . . ?
C232 C233 H233 120.2 . . ?
C234 C233 H233 120.2 . . ?
C235 C234 C233 120.4(7) . . ?
C235 C234 H234 119.8 . . ?
C233 C234 H234 119.8 . . ?
C234 C235 C236 119.2(7) . . ?
C234 C235 H235 120.4 . . ?
C236 C235 H235 120.4 . . ?
C235 C236 C231 121.3(7) . . ?
C235 C236 H236 119.4 . . ?
C231 C236 H236 119.4 . . ?
C252 C251 C256 120.1(7) . . ?
C252 C251 C25 119.1(7) . . ?
C256 C251 C25 120.7(6) . . ?
C253 C252 C251 120.1(8) . . ?
C253 C252 H252 119.9 . . ?
C251 C252 H252 119.9 . . ?
C254 C253 C252 119.5(9) . . ?
C254 C253 H253 120.2 . . ?
C252 C253 H253 120.2 . . ?
C253 C254 C255 121.9(8) . . ?
C253 C254 H254 119.1 . . ?
C255 C254 H254 119.1 . . ?
C256 C255 C254 118.4(9) . . ?
C256 C255 H255 120.8 . . ?
C254 C255 H255 120.8 . . ?
C255 C256 C251 120.0(8) . . ?
C255 C256 H256 120.0 . . ?
C251 C256 H256 120.0 . . ?
N32 N31 C35 106.7(6) . . ?
N32 N31 Pt1 119.8(4) . . ?
C35 N31 Pt1 133.5(5) . . ?
N31 N32 C33 111.7(6) . . ?
N31 N32 H32 124.2 . . ?
C33 N32 H32 124.2 . . ?
N32 C33 C34 105.1(6) . . ?
N32 C33 C331 125.6(6) . . ?
C34 C33 C331 129.3(6) . . ?
C33 C34 C35 108.0(6) . . ?
C33 C34 H34 126.0 . . ?
C35 C34 H34 126.0 . . ?
N31 C35 C34 108.6(6) . . ?
N31 C35 C351 124.8(7) . . ?
C34 C35 C351 126.6(6) . . ?
C336 C331 C332 118.6(7) . . ?
C336 C331 C33 118.8(7) . . ?
C332 C331 C33 122.5(7) . . ?
C333 C332 C331 120.0(7) . . ?
C333 C332 H332 120.0 . . ?
C331 C332 H332 120.0 . . ?
C332 C333 C334 121.2(8) . . ?
C332 C333 H333 119.4 . . ?
C334 C333 H333 119.4 . . ?
C333 C334 C335 119.0(8) . . ?
C333 C334 H334 120.5 . . ?
C335 C334 H334 120.5 . . ?
C336 C335 C334 120.2(7) . . ?
C336 C335 H335 119.9 . . ?
C334 C335 H335 119.9 . . ?
C335 C336 C331 121.1(7) . . ?
C335 C336 H336 119.5 . . ?
C331 C336 H336 119.5 . . ?
C356 C351 C352 118.4(7) . . ?
C356 C351 C35 124.3(7) . . ?
C352 C351 C35 117.3(7) . . ?
C353 C352 C351 120.8(9) . . ?
C353 C352 H352 119.6 . . ?
C351 C352 H352 119.6 . . ?
C352 C353 C354 120.2(8) . . ?
C352 C353 H353 119.9 . . ?
C354 C353 H353 119.9 . . ?
C355 C354 C353 118.9(8) . . ?
C355 C354 H354 120.5 . . ?
C353 C354 H354 120.5 . . ?
C354 C355 C356 120.6(9) . . ?
C354 C355 H355 119.7 . . ?
C356 C355 H355 119.7 . . ?
C351 C356 C355 121.1(8) . . ?
C351 C356 H356 119.5 . . ?
C355 C356 H356 119.5 . . ?
C46 N41 C42 119.8(6) . . ?
C46 N41 Pt2 125.2(5) . . ?
C42 N41 Pt2 114.9(5) . . ?
N41 C42 C43 119.1(7) . . ?
N41 C42 C421 113.9(6) . . ?
C43 C42 C421 126.9(7) . . ?
C44 C43 C42 120.8(8) . . ?
C44 C43 H43 119.6 . . ?
C42 C43 H43 119.6 . . ?
C45 C44 C43 119.1(7) . . ?
C45 C44 H44 120.5 . . ?
C43 C44 H44 120.5 . . ?
C44 C45 C46 119.2(7) . . ?
C44 C45 H45 120.4 . . ?
C46 C45 H45 120.4 . . ?
N41 C46 C45 121.9(8) . . ?
N41 C46 H46 119.0 . . ?
C45 C46 H46 119.0 . . ?
C422 C421 C426 120.9(7) . . ?
C422 C421 C42 115.9(7) . . ?
C426 C421 C42 123.2(7) . . ?
C423 C422 C421 117.2(7) . . ?
C423 C422 Pt2 129.0(5) . . ?
C421 C422 Pt2 113.8(5) . . ?
C424 C423 C422 122.3(7) . . ?
C424 C423 H423 118.9 . . ?
C422 C423 H423 118.9 . . ?
C423 C424 C425 120.7(8) . . ?
C423 C424 H424 119.6 . . ?
C425 C424 H424 119.6 . . ?
C424 C425 C426 119.0(7) . . ?
C424 C425 H425 120.5 . . ?
C426 C425 H425 120.5 . . ?
C425 C426 C421 119.8(7) . . ?
C425 C426 H426 120.1 . . ?
C421 C426 H426 120.1 . . ?
C55 N51 N52 107.5(5) . . ?
C55 N51 Pt2 132.6(5) . . ?
N52 N51 Pt2 119.6(4) . . ?
N51 N52 C53 110.8(5) . . ?
N51 N52 H52 124.6 . . ?
C53 N52 H52 124.6 . . ?
N52 C53 C54 106.8(6) . . ?
N52 C53 C531 122.5(6) . . ?
C54 C53 C531 130.6(6) . . ?
C53 C54 C55 106.1(6) . . ?
C53 C54 H54 127.0 . . ?
C55 C54 H54 127.0 . . ?
N51 C55 C54 108.7(6) . . ?
N51 C55 C551 123.7(6) . . ?
C54 C55 C551 127.5(6) . . ?
C532 C531 C536 118.3(6) . . ?
C532 C531 C53 122.8(6) . . ?
C536 C531 C53 118.8(6) . . ?
C533 C532 C531 121.0(7) . . ?
C533 C532 H532 119.5 . . ?
C531 C532 H532 119.5 . . ?
C532 C533 C534 120.1(7) . . ?
C532 C533 H533 120.0 . . ?
C534 C533 H533 120.0 . . ?
C533 C534 C535 119.8(7) . . ?
C533 C534 H534 120.1 . . ?
C535 C534 H534 120.1 . . ?
C536 C535 C534 121.2(7) . . ?
C536 C535 H535 119.4 . . ?
C534 C535 H535 119.4 . . ?
C535 C536 C531 119.6(7) . . ?
C535 C536 H536 120.2 . . ?
C531 C536 H536 120.2 . . ?
C556 C551 C552 119.2(7) . . ?
C556 C551 C55 121.9(6) . . ?
C552 C551 C55 118.7(7) . . ?
C551 C552 C553 120.0(7) . . ?
C551 C552 H552 120.0 . . ?
C553 C552 H552 120.0 . . ?
C554 C553 C552 120.4(7) . . ?
C554 C553 H553 119.8 . . ?
C552 C553 H553 119.8 . . ?
C553 C554 C555 119.3(7) . . ?
C553 C554 H554 120.4 . . ?
C555 C554 H554 120.4 . . ?
C556 C555 C554 120.2(7) . . ?
C556 C555 H555 119.9 . . ?
C554 C555 H555 119.9 . . ?
C555 C556 C551 120.9(7) . . ?
C555 C556 H556 119.6 . . ?
C551 C556 H556 119.6 . . ?
N62 N61 C65 106.0(5) . . ?
N62 N61 Pt2 119.1(4) . . ?
C65 N61 Pt2 134.8(5) . . ?
N61 N62 C63 112.4(6) . . ?
N61 N62 H62 123.8 . . ?
C63 N62 H62 123.8 . . ?
N62 C63 C64 105.9(6) . . ?
N62 C63 C631 124.9(7) . . ?
C64 C63 C631 129.2(7) . . ?
C63 C64 C65 107.2(7) . . ?
C63 C64 H64 126.4 . . ?
C65 C64 H64 126.4 . . ?
N61 C65 C64 108.4(6) . . ?
N61 C65 C651 125.2(6) . . ?
C64 C65 C651 126.4(7) . . ?
C632 C631 C636 119.9(7) . . ?
C632 C631 C63 122.0(7) . . ?
C636 C631 C63 118.1(6) . . ?
C631 C632 C633 119.3(8) . . ?
C631 C632 H632 120.3 . . ?
C633 C632 H632 120.3 . . ?
C634 C633 C632 120.9(8) . . ?
C634 C633 H633 119.6 . . ?
C632 C633 H633 119.6 . . ?
C635 C634 C633 120.1(8) . . ?
C635 C634 H634 120.0 . . ?
C633 C634 H634 120.0 . . ?
C634 C635 C636 119.6(7) . . ?
C634 C635 H635 120.2 . . ?
C636 C635 H635 120.2 . . ?
C631 C636 C635 120.2(7) . . ?
C631 C636 H636 119.9 . . ?
C635 C636 H636 119.9 . . ?
C656 C651 C652 117.6(7) . . ?
C656 C651 C65 123.8(7) . . ?
C652 C651 C65 118.5(7) . . ?
C653 C652 C651 121.7(7) . . ?
C653 C652 H652 119.1 . . ?
C651 C652 H652 119.1 . . ?
C652 C653 C654 119.4(7) . . ?
C652 C653 H653 120.3 . . ?
C654 C653 H653 120.3 . . ?
C655 C654 C653 120.0(7) . . ?
C655 C654 H654 120.0 . . ?
C653 C654 H654 120.0 . . ?
C654 C655 C656 120.1(7) . . ?
C654 C655 H655 119.9 . . ?
C656 C655 H655 119.9 . . ?
C651 C656 C655 121.1(7) . . ?
C651 C656 H656 119.4 . . ?
C655 C656 H656 119.4 . . ?
Cl4 C1 Cl3 112.6(5) . . ?
Cl4 C1 H1A 109.1 . . ?
Cl3 C1 H1A 109.1 . . ?
Cl4 C1 H1B 109.1 . . ?
Cl3 C1 H1B 109.1 . . ?
H1A C1 H1B 107.8 . . ?
Cl5 C2 Cl6 112.8(6) . . ?
Cl5 C2 H2A 109.0 . . ?
Cl6 C2 H2A 109.0 . . ?
Cl5 C2 H2B 109.0 . . ?
Cl6 C2 H2B 109.0 . . ?
H2A C2 H2B 107.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C122 Pt1 N11 C16 176.8(6) . . . . ?
N21 Pt1 N11 C16 155.3(18) . . . . ?
N31 Pt1 N11 C16 -5.2(6) . . . . ?
C122 Pt1 N11 C12 0.2(5) . . . . ?
N21 Pt1 N11 C12 -21(2) . . . . ?
N31 Pt1 N11 C12 178.2(5) . . . . ?
C16 N11 C12 C13 -1.1(10) . . . . ?
Pt1 N11 C12 C13 175.7(5) . . . . ?
C16 N11 C12 C121 -178.8(6) . . . . ?
Pt1 N11 C12 C121 -2.0(8) . . . . ?
N11 C12 C13 C14 0.5(11) . . . . ?
C121 C12 C13 C14 178.0(7) . . . . ?
C12 C13 C14 C15 -0.3(12) . . . . ?
C13 C14 C15 C16 0.5(12) . . . . ?
C12 N11 C16 C15 1.3(11) . . . . ?
Pt1 N11 C16 C15 -175.1(6) . . . . ?
C14 C15 C16 N11 -1.1(12) . . . . ?
N11 C12 C121 C126 -177.9(7) . . . . ?
C13 C12 C121 C126 4.5(12) . . . . ?
N11 C12 C121 C122 3.3(9) . . . . ?
C13 C12 C121 C122 -174.2(7) . . . . ?
C126 C121 C122 C123 -0.9(10) . . . . ?
C12 C121 C122 C123 178.0(6) . . . . ?
C126 C121 C122 Pt1 178.1(5) . . . . ?
C12 C121 C122 Pt1 -3.1(8) . . . . ?
N11 Pt1 C122 C121 1.6(5) . . . . ?
N21 Pt1 C122 C121 179.2(5) . . . . ?
N31 Pt1 C122 C121 -36(5) . . . . ?
N11 Pt1 C122 C123 -179.6(7) . . . . ?
N21 Pt1 C122 C123 -2.0(6) . . . . ?
N31 Pt1 C122 C123 143(4) . . . . ?
C121 C122 C123 C124 -0.2(10) . . . . ?
Pt1 C122 C123 C124 -178.9(5) . . . . ?
C122 C123 C124 C125 1.0(11) . . . . ?
C123 C124 C125 C126 -0.8(11) . . . . ?
C124 C125 C126 C121 -0.2(12) . . . . ?
C122 C121 C126 C125 1.0(11) . . . . ?
C12 C121 C126 C125 -177.6(7) . . . . ?
C122 Pt1 N21 C25 82.4(7) . . . . ?
N11 Pt1 N21 C25 104(2) . . . . ?
N31 Pt1 N21 C25 -95.8(6) . . . . ?
C122 Pt1 N21 N22 -84.3(5) . . . . ?
N11 Pt1 N21 N22 -63(2) . . . . ?
N31 Pt1 N21 N22 97.6(5) . . . . ?
C25 N21 N22 C23 0.1(7) . . . . ?
Pt1 N21 N22 C23 169.9(4) . . . . ?
N21 N22 C23 C24 0.2(8) . . . . ?
N21 N22 C23 C231 179.6(6) . . . . ?
N22 C23 C24 C25 -0.4(8) . . . . ?
C231 C23 C24 C25 -179.7(7) . . . . ?
N22 N21 C25 C24 -0.4(8) . . . . ?
Pt1 N21 C25 C24 -168.4(5) . . . . ?
N22 N21 C25 C251 -178.6(6) . . . . ?
Pt1 N21 C25 C251 13.4(10) . . . . ?
C23 C24 C25 N21 0.5(8) . . . . ?
C23 C24 C25 C251 178.7(7) . . . . ?
N22 C23 C231 C232 -7.3(10) . . . . ?
C24 C23 C231 C232 171.9(7) . . . . ?
N22 C23 C231 C236 172.8(6) . . . . ?
C24 C23 C231 C236 -8.0(11) . . . . ?
C236 C231 C232 C233 -0.4(11) . . . . ?
C23 C231 C232 C233 179.6(7) . . . . ?
C231 C232 C233 C234 1.0(11) . . . . ?
C232 C233 C234 C235 -0.8(11) . . . . ?
C233 C234 C235 C236 0.1(11) . . . . ?
C234 C235 C236 C231 0.4(11) . . . . ?
C232 C231 C236 C235 -0.3(10) . . . . ?
C23 C231 C236 C235 179.7(6) . . . . ?
N21 C25 C251 C252 108.5(8) . . . . ?
C24 C25 C251 C252 -69.4(10) . . . . ?
N21 C25 C251 C256 -74.5(9) . . . . ?
C24 C25 C251 C256 107.5(9) . . . . ?
C256 C251 C252 C253 0.6(12) . . . . ?
C25 C251 C252 C253 177.6(7) . . . . ?
C251 C252 C253 C254 -2.2(13) . . . . ?
C252 C253 C254 C255 1.3(15) . . . . ?
C253 C254 C255 C256 1.2(15) . . . . ?
C254 C255 C256 C251 -2.8(13) . . . . ?
C252 C251 C256 C255 1.9(11) . . . . ?
C25 C251 C256 C255 -175.0(7) . . . . ?
C122 Pt1 N31 N32 146(4) . . . . ?
N11 Pt1 N31 N32 109.2(5) . . . . ?
N21 Pt1 N31 N32 -68.6(5) . . . . ?
C122 Pt1 N31 C35 -36(5) . . . . ?
N11 Pt1 N31 C35 -72.9(6) . . . . ?
N21 Pt1 N31 C35 109.4(6) . . . . ?
C35 N31 N32 C33 -0.9(7) . . . . ?
Pt1 N31 N32 C33 177.6(4) . . . . ?
N31 N32 C33 C34 0.5(7) . . . . ?
N31 N32 C33 C331 177.8(6) . . . . ?
N32 C33 C34 C35 0.1(8) . . . . ?
C331 C33 C34 C35 -177.1(7) . . . . ?
N32 N31 C35 C34 0.9(7) . . . . ?
Pt1 N31 C35 C34 -177.2(5) . . . . ?
N32 N31 C35 C351 -178.9(6) . . . . ?
Pt1 N31 C35 C351 2.9(11) . . . . ?
C33 C34 C35 N31 -0.6(8) . . . . ?
C33 C34 C35 C351 179.2(7) . . . . ?
N32 C33 C331 C336 174.6(7) . . . . ?
C34 C33 C331 C336 -8.7(11) . . . . ?
N32 C33 C331 C332 -9.1(11) . . . . ?
C34 C33 C331 C332 167.6(7) . . . . ?
C336 C331 C332 C333 1.3(11) . . . . ?
C33 C331 C332 C333 -175.1(7) . . . . ?
C331 C332 C333 C334 0.2(11) . . . . ?
C332 C333 C334 C335 -1.0(12) . . . . ?
C333 C334 C335 C336 0.2(12) . . . . ?
C334 C335 C336 C331 1.4(12) . . . . ?
C332 C331 C336 C335 -2.1(11) . . . . ?
C33 C331 C336 C335 174.4(7) . . . . ?
N31 C35 C351 C356 -22.6(12) . . . . ?
C34 C35 C351 C356 157.6(8) . . . . ?
N31 C35 C351 C352 161.2(7) . . . . ?
C34 C35 C351 C352 -18.5(11) . . . . ?
C356 C351 C352 C353 1.5(13) . . . . ?
C35 C351 C352 C353 177.9(8) . . . . ?
C351 C352 C353 C354 0.6(14) . . . . ?
C352 C353 C354 C355 -2.6(15) . . . . ?
C353 C354 C355 C356 2.5(14) . . . . ?
C352 C351 C356 C355 -1.6(12) . . . . ?
C35 C351 C356 C355 -177.8(7) . . . . ?
C354 C355 C356 C351 -0.4(13) . . . . ?
C422 Pt2 N41 C46 -176.3(6) . . . . ?
N51 Pt2 N41 C46 -155(2) . . . . ?
N61 Pt2 N41 C46 4.1(6) . . . . ?
C422 Pt2 N41 C42 -0.5(5) . . . . ?
N51 Pt2 N41 C42 21(3) . . . . ?
N61 Pt2 N41 C42 179.9(5) . . . . ?
C46 N41 C42 C43 1.4(10) . . . . ?
Pt2 N41 C42 C43 -174.6(6) . . . . ?
C46 N41 C42 C421 178.8(7) . . . . ?
Pt2 N41 C42 C421 2.8(8) . . . . ?
N41 C42 C43 C44 -0.9(12) . . . . ?
C421 C42 C43 C44 -177.9(8) . . . . ?
C42 C43 C44 C45 -0.4(13) . . . . ?
C43 C44 C45 C46 1.1(12) . . . . ?
C42 N41 C46 C45 -0.7(11) . . . . ?
Pt2 N41 C46 C45 174.9(6) . . . . ?
C44 C45 C46 N41 -0.6(12) . . . . ?
N41 C42 C421 C422 -4.4(10) . . . . ?
C43 C42 C421 C422 172.7(7) . . . . ?
N41 C42 C421 C426 176.3(7) . . . . ?
C43 C42 C421 C426 -6.6(13) . . . . ?
C426 C421 C422 C423 2.9(11) . . . . ?
C42 C421 C422 C423 -176.4(7) . . . . ?
C426 C421 C422 Pt2 -176.7(6) . . . . ?
C42 C421 C422 Pt2 4.0(8) . . . . ?
N41 Pt2 C422 C423 178.5(7) . . . . ?
N51 Pt2 C422 C423 0.5(7) . . . . ?
N61 Pt2 C422 C423 -173(5) . . . . ?
N41 Pt2 C422 C421 -1.9(5) . . . . ?
N51 Pt2 C422 C421 -179.9(5) . . . . ?
N61 Pt2 C422 C421 7(5) . . . . ?
C421 C422 C423 C424 -2.4(11) . . . . ?
Pt2 C422 C423 C424 177.2(6) . . . . ?
C422 C423 C424 C425 0.8(12) . . . . ?
C423 C424 C425 C426 0.4(12) . . . . ?
C424 C425 C426 C421 0.1(12) . . . . ?
C422 C421 C426 C425 -1.8(12) . . . . ?
C42 C421 C426 C425 177.4(7) . . . . ?
C422 Pt2 N51 C55 -86.8(7) . . . . ?
N41 Pt2 N51 C55 -108(2) . . . . ?
N61 Pt2 N51 C55 92.8(7) . . . . ?
C422 Pt2 N51 N52 85.8(5) . . . . ?
N41 Pt2 N51 N52 65(2) . . . . ?
N61 Pt2 N51 N52 -94.5(5) . . . . ?
C55 N51 N52 C53 -0.2(8) . . . . ?
Pt2 N51 N52 C53 -174.6(4) . . . . ?
N51 N52 C53 C54 0.5(8) . . . . ?
N51 N52 C53 C531 178.2(6) . . . . ?
N52 C53 C54 C55 -0.6(8) . . . . ?
C531 C53 C54 C55 -178.0(7) . . . . ?
N52 N51 C55 C54 -0.2(8) . . . . ?
Pt2 N51 C55 C54 173.1(5) . . . . ?
N52 N51 C55 C551 -177.4(6) . . . . ?
Pt2 N51 C55 C551 -4.1(11) . . . . ?
C53 C54 C55 N51 0.5(8) . . . . ?
C53 C54 C55 C551 177.6(7) . . . . ?
N52 C53 C531 C532 2.4(11) . . . . ?
C54 C53 C531 C532 179.4(7) . . . . ?
N52 C53 C531 C536 -176.0(6) . . . . ?
C54 C53 C531 C536 1.0(11) . . . . ?
C536 C531 C532 C533 0.4(11) . . . . ?
C53 C531 C532 C533 -178.0(7) . . . . ?
C531 C532 C533 C534 -0.8(11) . . . . ?
C532 C533 C534 C535 0.0(11) . . . . ?
C533 C534 C535 C536 1.3(11) . . . . ?
C534 C535 C536 C531 -1.7(11) . . . . ?
C532 C531 C536 C535 0.8(10) . . . . ?
C53 C531 C536 C535 179.3(6) . . . . ?
N51 C55 C551 C556 63.5(10) . . . . ?
C54 C55 C551 C556 -113.2(8) . . . . ?
N51 C55 C551 C552 -121.4(8) . . . . ?
C54 C55 C551 C552 61.8(10) . . . . ?
C556 C551 C552 C553 -1.0(11) . . . . ?
C55 C551 C552 C553 -176.2(7) . . . . ?
C551 C552 C553 C554 2.6(12) . . . . ?
C552 C553 C554 C555 -2.3(12) . . . . ?
C553 C554 C555 C556 0.3(12) . . . . ?
C554 C555 C556 C551 1.3(12) . . . . ?
C552 C551 C556 C555 -0.9(11) . . . . ?
C55 C551 C556 C555 174.1(7) . . . . ?
C422 Pt2 N61 N62 -114(5) . . . . ?
N41 Pt2 N61 N62 -105.0(5) . . . . ?
N51 Pt2 N61 N62 73.0(5) . . . . ?
C422 Pt2 N61 C65 68(5) . . . . ?
N41 Pt2 N61 C65 76.6(7) . . . . ?
N51 Pt2 N61 C65 -105.3(7) . . . . ?
C65 N61 N62 C63 0.0(8) . . . . ?
Pt2 N61 N62 C63 -178.8(5) . . . . ?
N61 N62 C63 C64 0.0(8) . . . . ?
N61 N62 C63 C631 -178.5(6) . . . . ?
N62 C63 C64 C65 0.0(8) . . . . ?
C631 C63 C64 C65 178.4(7) . . . . ?
N62 N61 C65 C64 0.1(8) . . . . ?
Pt2 N61 C65 C64 178.6(5) . . . . ?
N62 N61 C65 C651 180.0(7) . . . . ?
Pt2 N61 C65 C651 -1.5(11) . . . . ?
C63 C64 C65 N61 -0.1(8) . . . . ?
C63 C64 C65 C651 -180.0(7) . . . . ?
N62 C63 C631 C632 12.5(11) . . . . ?
C64 C63 C631 C632 -165.6(8) . . . . ?
N62 C63 C631 C636 -170.4(7) . . . . ?
C64 C63 C631 C636 11.5(12) . . . . ?
C636 C631 C632 C633 -0.6(11) . . . . ?
C63 C631 C632 C633 176.4(7) . . . . ?
C631 C632 C633 C634 0.1(12) . . . . ?
C632 C633 C634 C635 -0.2(12) . . . . ?
C633 C634 C635 C636 0.8(12) . . . . ?
C632 C631 C636 C635 1.2(11) . . . . ?
C63 C631 C636 C635 -175.9(7) . . . . ?
C634 C635 C636 C631 -1.3(12) . . . . ?
N61 C65 C651 C656 14.2(12) . . . . ?
C64 C65 C651 C656 -165.9(8) . . . . ?
N61 C65 C651 C652 -168.9(7) . . . . ?
C64 C65 C651 C652 11.0(12) . . . . ?
C656 C651 C652 C653 -2.3(12) . . . . ?
C65 C651 C652 C653 -179.4(8) . . . . ?
C651 C652 C653 C654 1.7(13) . . . . ?
C652 C653 C654 C655 -0.4(13) . . . . ?
C653 C654 C655 C656 -0.3(13) . . . . ?
C652 C651 C656 C655 1.6(11) . . . . ?
C65 C651 C656 C655 178.5(7) . . . . ?
C654 C655 C656 C651 -0.3(12) . . . . ?

#==============================================================================
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DA
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N22 H22 Cl2 . . . 3.049(6) 0.860 2.284 148.3 no
N32 H32 Cl2 . . . 3.123(6) 0.860 2.276 168.3 no
N52 H52 Cl1 . . . 3.062(6) 0.860 2.280 151.3 no
N62 H62 Cl1 . . . 3.152(6) 0.860 2.304 168.8 no
