# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_dm15781_0m
_database_code_depnum_ccdc_archive 'CCDC 1566071'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-09-13 downloaded from the CCDC.
;
_audit_creation_date             2015-10-20
_audit_creation_method           
;
Olex2 1.2
(compiled 2014.07.22 svn.r2960 for OlexSys, GUI svn.r4862)
;
_shelxl_version_number           2014-3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C34 H18 F2 O2, 0.5(C H2 Cl2)'
_chemical_formula_sum            'C34.50 H19 Cl F2 O2'
_chemical_formula_weight         538.95
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.558(3)
_cell_length_b                   16.573(5)
_cell_length_c                   13.868(4)
_cell_angle_alpha                90
_cell_angle_beta                 109.866(5)
_cell_angle_gamma                90
_cell_volume                     2498.4(12)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    2474
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.77
_cell_measurement_theta_min      2.24
_shelx_estimated_absorpt_T_max   0.961
_shelx_estimated_absorpt_T_min   0.942
_exptl_absorpt_coefficient_mu    0.201
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6586
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0548 before and 0.0433 after correction.
The Ratio of minimum to maximum transmission is 0.8827.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.433
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1108
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.2
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0531
_diffrn_reflns_av_unetI/netI     0.0633
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            25347
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         26.999
_diffrn_reflns_theta_min         1.987
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2688
_reflns_number_total             5459
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.307
_refine_diff_density_min         -0.199
_refine_diff_density_rms         0.036
_refine_ls_extinction_coef       0.0048(9)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     371
_refine_ls_number_reflns         5459
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1182
_refine_ls_R_factor_gt           0.0519
_refine_ls_restrained_S_all      1.040
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0828P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1358
_refine_ls_wR_factor_ref         0.1760
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Others
 Fixed Sof: Cl1(0.5) Cl2(0.5) C35(0.5) H35A(0.5) H35B(0.5)
3.a Riding coordinates:
 C35(H35A,H35B)
3.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C8(H8), C9(H9), C10(H10), C11(H11), C15(H15),
 C17(H17), C19(H19), C20(H20), C22(H22), C26(H26), C28(H28), C29(H29), C31(H31),
  C33(H33)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F -0.16956(16) 0.20713(10) 0.18377(15) 0.1047(7) Uani 1 1 d . . . . .
F2 F 0.87317(17) 0.20883(11) -0.17931(15) 0.1056(6) Uani 1 1 d . . . . .
O1 O 0.36781(19) 0.00978(9) 0.04138(13) 0.0836(6) Uani 1 1 d . . . . .
O2 O 0.35962(18) 0.44148(9) 0.01418(16) 0.0885(7) Uani 1 1 d . . . . .
C1 C 0.3014(2) 0.04324(13) -0.05090(17) 0.0525(6) Uani 1 1 d . . . . .
C2 C 0.2395(2) -0.01128(14) -0.1256(2) 0.0666(7) Uani 1 1 d . . . . .
H2 H 0.2453 -0.0662 -0.1111 0.080 Uiso 1 1 calc R . . . .
C3 C 0.1706(2) 0.01477(17) -0.2196(2) 0.0702(8) Uani 1 1 d . . . . .
H3 H 0.1272 -0.0219 -0.2697 0.084 Uiso 1 1 calc R . . . .
C4 C 0.1649(3) 0.09641(18) -0.2410(2) 0.0775(8) Uani 1 1 d . . . . .
H4 H 0.1187 0.1150 -0.3060 0.093 Uiso 1 1 calc R . . . .
C5 C 0.2274(2) 0.14979(15) -0.16616(18) 0.0674(7) Uani 1 1 d . . . . .
H5 H 0.2234 0.2046 -0.1815 0.081 Uiso 1 1 calc R . . . .
C6 C 0.29617(19) 0.12484(12) -0.06872(15) 0.0441(5) Uani 1 1 d . . . . .
C7 C 0.4375(2) 0.05888(13) 0.11834(16) 0.0510(6) Uani 1 1 d . . . . .
C8 C 0.5072(3) 0.01931(14) 0.20673(19) 0.0667(7) Uani 1 1 d . . . . .
H8 H 0.5043 -0.0366 0.2104 0.080 Uiso 1 1 calc R . . . .
C9 C 0.5798(2) 0.06234(16) 0.28812(19) 0.0642(7) Uani 1 1 d . . . . .
H9 H 0.6277 0.0361 0.3475 0.077 Uiso 1 1 calc R . . . .
C10 C 0.5818(2) 0.14460(16) 0.28206(18) 0.0713(8) Uani 1 1 d . . . . .
H10 H 0.6305 0.1744 0.3379 0.086 Uiso 1 1 calc R . . . .
C11 C 0.5128(2) 0.18321(14) 0.19461(17) 0.0664(7) Uani 1 1 d . . . . .
H11 H 0.5156 0.2392 0.1917 0.080 Uiso 1 1 calc R . . . .
C12 C 0.43889(19) 0.14096(12) 0.11028(15) 0.0419(5) Uani 1 1 d . . . . .
C13 C 0.36174(19) 0.18635(11) 0.01399(15) 0.0403(5) Uani 1 1 d . . . . .
C14 C 0.2659(2) 0.23650(12) 0.04137(15) 0.0430(5) Uani 1 1 d . . . . .
C15 C 0.1792(2) 0.19759(13) 0.07061(17) 0.0525(6) Uani 1 1 d . . . . .
H15 H 0.1802 0.1415 0.0731 0.063 Uiso 1 1 calc R . . . .
C16 C 0.0879(2) 0.23956(14) 0.09728(16) 0.0526(6) Uani 1 1 d . . . . .
C17 C -0.0004(2) 0.19964(15) 0.1293(2) 0.0669(7) Uani 1 1 d . . . . .
H17 H -0.0003 0.1437 0.1348 0.080 Uiso 1 1 calc R . . . .
C18 C -0.0853(2) 0.24468(18) 0.1519(2) 0.0715(8) Uani 1 1 d . . . . .
C19 C -0.0910(3) 0.32794(18) 0.1450(2) 0.0735(8) Uani 1 1 d . . . . .
H19 H -0.1519 0.3563 0.1603 0.088 Uiso 1 1 calc R . . . .
C20 C -0.0065(3) 0.36728(16) 0.11550(19) 0.0689(7) Uani 1 1 d . . . . .
H20 H -0.0094 0.4233 0.1108 0.083 Uiso 1 1 calc R . . . .
C21 C 0.0867(2) 0.32472(14) 0.09158(16) 0.0535(6) Uani 1 1 d . . . . .
C22 C 0.1776(2) 0.36378(13) 0.06462(17) 0.0549(6) Uani 1 1 d . . . . .
H22 H 0.1784 0.4199 0.0631 0.066 Uiso 1 1 calc R . . . .
C23 C 0.2667(2) 0.32172(12) 0.04006(15) 0.0460(5) Uani 1 1 d . . . . .
C24 C 0.3588(2) 0.36770(12) 0.01142(16) 0.0530(6) Uani 1 1 d . . . . .
C25 C 0.4485(2) 0.32266(12) -0.02114(15) 0.0458(5) Uani 1 1 d . . . . .
C26 C 0.5328(2) 0.36532(13) -0.05100(16) 0.0533(6) Uani 1 1 d . . . . .
H26 H 0.5316 0.4214 -0.0490 0.064 Uiso 1 1 calc R . . . .
C27 C 0.6199(2) 0.32694(14) -0.08413(17) 0.0548(6) Uani 1 1 d . . . . .
C28 C 0.7067(3) 0.36990(17) -0.11559(19) 0.0699(7) Uani 1 1 d . . . . .
H28 H 0.7064 0.4260 -0.1146 0.084 Uiso 1 1 calc R . . . .
C29 C 0.7901(3) 0.33066(19) -0.1471(2) 0.0777(8) Uani 1 1 d . . . . .
H29 H 0.8469 0.3591 -0.1679 0.093 Uiso 1 1 calc R . . . .
C30 C 0.7888(3) 0.24677(19) -0.1477(2) 0.0732(8) Uani 1 1 d . . . . .
C31 C 0.7091(2) 0.20127(16) -0.11895(19) 0.0654(7) Uani 1 1 d . . . . .
H31 H 0.7120 0.1452 -0.1209 0.079 Uiso 1 1 calc R . . . .
C32 C 0.6211(2) 0.24118(14) -0.08587(16) 0.0519(6) Uani 1 1 d . . . . .
C33 C 0.5343(2) 0.19845(13) -0.05453(16) 0.0505(6) Uani 1 1 d . . . . .
H33 H 0.5349 0.1424 -0.0556 0.061 Uiso 1 1 calc R . . . .
C34 C 0.4492(2) 0.23736(12) -0.02263(15) 0.0436(5) Uani 1 1 d . . . . .
Cl1 Cl 0.1512(2) -0.01024(11) 0.17649(15) 0.1211(7) Uani 0.5 1 d . . P . .
Cl2 Cl -0.0268(2) 0.01395(13) -0.02712(16) 0.0908(7) Uani 0.5 1 d . . P . .
C35 C 0.0373(7) -0.0550(4) 0.0757(6) 0.103(3) Uani 0.5 1 d . . P . .
H35A H -0.0266 -0.0739 0.0997 0.123 Uiso 0.5 1 d R . P . .
H35B H 0.0709 -0.1006 0.0517 0.123 Uiso 0.5 1 d R . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C18 1.350(3) . ?
F2 C30 1.353(3) . ?
O1 C1 1.366(3) . ?
O1 C7 1.366(3) . ?
O2 C24 1.223(2) . ?
C1 C2 1.377(3) . ?
C1 C6 1.372(3) . ?
C2 H2 0.9300 . ?
C2 C3 1.348(3) . ?
C3 H3 0.9300 . ?
C3 C4 1.382(4) . ?
C4 H4 0.9300 . ?
C4 C5 1.368(3) . ?
C5 H5 0.9300 . ?
C5 C6 1.378(3) . ?
C6 C13 1.529(3) . ?
C7 C8 1.382(3) . ?
C7 C12 1.365(3) . ?
C8 H8 0.9300 . ?
C8 C9 1.358(3) . ?
C9 H9 0.9300 . ?
C9 C10 1.367(3) . ?
C10 H10 0.9300 . ?
C10 C11 1.363(3) . ?
C11 H11 0.9300 . ?
C11 C12 1.382(3) . ?
C12 C13 1.528(3) . ?
C13 C14 1.533(3) . ?
C13 C34 1.531(3) . ?
C14 C15 1.364(3) . ?
C14 C23 1.413(3) . ?
C15 H15 0.9300 . ?
C15 C16 1.414(3) . ?
C16 C17 1.409(3) . ?
C16 C21 1.413(3) . ?
C17 H17 0.9300 . ?
C17 C18 1.352(3) . ?
C18 C19 1.383(4) . ?
C19 H19 0.9300 . ?
C19 C20 1.348(4) . ?
C20 H20 0.9300 . ?
C20 C21 1.418(3) . ?
C21 C22 1.389(3) . ?
C22 H22 0.9300 . ?
C22 C23 1.379(3) . ?
C23 C24 1.469(3) . ?
C24 C25 1.467(3) . ?
C25 C26 1.376(3) . ?
C25 C34 1.414(3) . ?
C26 H26 0.9300 . ?
C26 C27 1.395(3) . ?
C27 C28 1.415(3) . ?
C27 C32 1.422(3) . ?
C28 H28 0.9300 . ?
C28 C29 1.352(4) . ?
C29 H29 0.9300 . ?
C29 C30 1.390(4) . ?
C30 C31 1.351(3) . ?
C31 H31 0.9300 . ?
C31 C32 1.414(3) . ?
C32 C33 1.412(3) . ?
C33 H33 0.9300 . ?
C33 C34 1.369(3) . ?
Cl1 Cl2 2.083(3) 3 ?
Cl1 C35 1.728(8) . ?
Cl2 Cl1 2.083(3) 3 ?
Cl2 Cl2 0.920(4) 3 ?
Cl2 C35 1.781(8) . ?
Cl2 C35 0.936(7) 3 ?
C35 Cl2 0.936(7) 3 ?
C35 H35A 0.9600 . ?
C35 H35B 0.9599 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 O1 C7 118.98(17) . . ?
O1 C1 C2 114.9(2) . . ?
O1 C1 C6 123.03(19) . . ?
C6 C1 C2 122.1(2) . . ?
C1 C2 H2 119.9 . . ?
C3 C2 C1 120.2(2) . . ?
C3 C2 H2 119.9 . . ?
C2 C3 H3 120.3 . . ?
C2 C3 C4 119.4(2) . . ?
C4 C3 H3 120.3 . . ?
C3 C4 H4 120.1 . . ?
C5 C4 C3 119.7(3) . . ?
C5 C4 H4 120.1 . . ?
C4 C5 H5 119.0 . . ?
C4 C5 C6 122.0(2) . . ?
C6 C5 H5 119.0 . . ?
C1 C6 C5 116.6(2) . . ?
C1 C6 C13 122.78(19) . . ?
C5 C6 C13 120.61(19) . . ?
O1 C7 C8 114.9(2) . . ?
O1 C7 C12 123.4(2) . . ?
C12 C7 C8 121.7(2) . . ?
C7 C8 H8 120.1 . . ?
C9 C8 C7 119.8(2) . . ?
C9 C8 H8 120.1 . . ?
C8 C9 H9 120.3 . . ?
C8 C9 C10 119.4(2) . . ?
C10 C9 H9 120.3 . . ?
C9 C10 H10 119.8 . . ?
C11 C10 C9 120.4(2) . . ?
C11 C10 H10 119.8 . . ?
C10 C11 H11 119.3 . . ?
C10 C11 C12 121.4(2) . . ?
C12 C11 H11 119.3 . . ?
C7 C12 C11 117.2(2) . . ?
C7 C12 C13 122.84(19) . . ?
C11 C12 C13 119.97(18) . . ?
C6 C13 C14 109.37(16) . . ?
C6 C13 C34 109.52(16) . . ?
C12 C13 C6 108.70(16) . . ?
C12 C13 C14 107.86(15) . . ?
C12 C13 C34 107.86(16) . . ?
C34 C13 C14 113.40(16) . . ?
C15 C14 C13 118.89(18) . . ?
C15 C14 C23 119.1(2) . . ?
C23 C14 C13 122.02(19) . . ?
C14 C15 H15 118.9 . . ?
C14 C15 C16 122.3(2) . . ?
C16 C15 H15 118.9 . . ?
C17 C16 C15 122.4(2) . . ?
C17 C16 C21 119.5(2) . . ?
C21 C16 C15 118.1(2) . . ?
C16 C17 H17 120.8 . . ?
C18 C17 C16 118.3(2) . . ?
C18 C17 H17 120.8 . . ?
F1 C18 C17 118.8(3) . . ?
F1 C18 C19 117.4(3) . . ?
C17 C18 C19 123.7(3) . . ?
C18 C19 H19 120.6 . . ?
C20 C19 C18 118.8(3) . . ?
C20 C19 H19 120.6 . . ?
C19 C20 H20 119.5 . . ?
C19 C20 C21 121.1(3) . . ?
C21 C20 H20 119.5 . . ?
C16 C21 C20 118.5(2) . . ?
C22 C21 C16 119.1(2) . . ?
C22 C21 C20 122.4(2) . . ?
C21 C22 H22 119.1 . . ?
C23 C22 C21 121.9(2) . . ?
C23 C22 H22 119.1 . . ?
C14 C23 C24 122.1(2) . . ?
C22 C23 C14 119.5(2) . . ?
C22 C23 C24 118.37(19) . . ?
O2 C24 C23 120.6(2) . . ?
O2 C24 C25 121.3(2) . . ?
C25 C24 C23 118.14(18) . . ?
C26 C25 C24 118.5(2) . . ?
C26 C25 C34 120.1(2) . . ?
C34 C25 C24 121.4(2) . . ?
C25 C26 H26 119.0 . . ?
C25 C26 C27 122.0(2) . . ?
C27 C26 H26 119.0 . . ?
C26 C27 C28 122.6(2) . . ?
C26 C27 C32 118.3(2) . . ?
C28 C27 C32 119.1(2) . . ?
C27 C28 H28 119.5 . . ?
C29 C28 C27 121.0(3) . . ?
C29 C28 H28 119.5 . . ?
C28 C29 H29 120.8 . . ?
C28 C29 C30 118.4(3) . . ?
C30 C29 H29 120.8 . . ?
F2 C30 C29 117.3(3) . . ?
C31 C30 F2 118.4(3) . . ?
C31 C30 C29 124.3(3) . . ?
C30 C31 H31 120.9 . . ?
C30 C31 C32 118.2(3) . . ?
C32 C31 H31 120.9 . . ?
C31 C32 C27 119.1(2) . . ?
C33 C32 C27 118.9(2) . . ?
C33 C32 C31 122.0(2) . . ?
C32 C33 H33 119.1 . . ?
C34 C33 C32 121.8(2) . . ?
C34 C33 H33 119.1 . . ?
C25 C34 C13 122.65(19) . . ?
C33 C34 C13 118.36(18) . . ?
C33 C34 C25 118.9(2) . . ?
C35 Cl1 Cl2 26.4(2) . 3 ?
Cl2 Cl2 Cl1 147.5(3) 3 3 ?
Cl2 Cl2 C35 147.2(7) 3 3 ?
Cl2 Cl2 C35 16.5(4) 3 . ?
C35 Cl2 Cl1 55.2(5) 3 3 ?
C35 Cl2 Cl1 137.4(3) . 3 ?
C35 Cl2 C35 163.8(4) 3 . ?
Cl1 C35 Cl2 111.5(4) . . ?
Cl1 C35 H35A 108.9 . . ?
Cl1 C35 H35B 109.4 . . ?
Cl2 C35 Cl1 98.4(6) 3 . ?
Cl2 C35 Cl2 16.2(4) 3 . ?
Cl2 C35 H35A 109.1 . . ?
Cl2 C35 H35A 124.0 3 . ?
Cl2 C35 H35B 106.9 3 . ?
Cl2 C35 H35B 109.5 . . ?
H35A C35 H35B 108.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F1 C18 C19 C20 178.6(2) . . . . ?
F2 C30 C31 C32 179.9(2) . . . . ?
O1 C1 C2 C3 179.7(2) . . . . ?
O1 C1 C6 C5 178.8(2) . . . . ?
O1 C1 C6 C13 -1.5(3) . . . . ?
O1 C7 C8 C9 -179.9(2) . . . . ?
O1 C7 C12 C11 179.4(2) . . . . ?
O1 C7 C12 C13 0.3(3) . . . . ?
O2 C24 C25 C26 -1.4(3) . . . . ?
O2 C24 C25 C34 178.8(2) . . . . ?
C1 O1 C7 C8 -176.3(2) . . . . ?
C1 O1 C7 C12 4.1(3) . . . . ?
C1 C2 C3 C4 1.4(4) . . . . ?
C1 C6 C13 C12 5.2(3) . . . . ?
C1 C6 C13 C14 -112.4(2) . . . . ?
C1 C6 C13 C34 122.8(2) . . . . ?
C2 C1 C6 C5 -1.2(3) . . . . ?
C2 C1 C6 C13 178.5(2) . . . . ?
C2 C3 C4 C5 -1.1(4) . . . . ?
C3 C4 C5 C6 -0.4(4) . . . . ?
C4 C5 C6 C1 1.5(4) . . . . ?
C4 C5 C6 C13 -178.1(2) . . . . ?
C5 C6 C13 C12 -175.17(19) . . . . ?
C5 C6 C13 C14 67.3(2) . . . . ?
C5 C6 C13 C34 -57.6(3) . . . . ?
C6 C1 C2 C3 -0.3(4) . . . . ?
C6 C13 C14 C15 54.5(2) . . . . ?
C6 C13 C14 C23 -127.3(2) . . . . ?
C6 C13 C34 C25 128.4(2) . . . . ?
C6 C13 C34 C33 -54.0(2) . . . . ?
C7 O1 C1 C2 176.5(2) . . . . ?
C7 O1 C1 C6 -3.5(3) . . . . ?
C7 C8 C9 C10 0.9(4) . . . . ?
C7 C12 C13 C6 -4.6(3) . . . . ?
C7 C12 C13 C14 113.9(2) . . . . ?
C7 C12 C13 C34 -123.3(2) . . . . ?
C8 C7 C12 C11 -0.2(3) . . . . ?
C8 C7 C12 C13 -179.3(2) . . . . ?
C8 C9 C10 C11 -0.9(4) . . . . ?
C9 C10 C11 C12 0.3(4) . . . . ?
C10 C11 C12 C7 0.2(4) . . . . ?
C10 C11 C12 C13 179.3(2) . . . . ?
C11 C12 C13 C6 176.37(19) . . . . ?
C11 C12 C13 C14 -65.1(2) . . . . ?
C11 C12 C13 C34 57.7(2) . . . . ?
C12 C7 C8 C9 -0.3(4) . . . . ?
C12 C13 C14 C15 -63.5(2) . . . . ?
C12 C13 C14 C23 114.6(2) . . . . ?
C12 C13 C34 C25 -113.4(2) . . . . ?
C12 C13 C34 C33 64.2(2) . . . . ?
C13 C14 C15 C16 179.85(18) . . . . ?
C13 C14 C23 C22 179.50(18) . . . . ?
C13 C14 C23 C24 0.6(3) . . . . ?
C14 C13 C34 C25 6.0(3) . . . . ?
C14 C13 C34 C33 -176.46(18) . . . . ?
C14 C15 C16 C17 -178.8(2) . . . . ?
C14 C15 C16 C21 0.9(3) . . . . ?
C14 C23 C24 O2 -177.6(2) . . . . ?
C14 C23 C24 C25 2.8(3) . . . . ?
C15 C14 C23 C22 -2.4(3) . . . . ?
C15 C14 C23 C24 178.7(2) . . . . ?
C15 C16 C17 C18 -179.1(2) . . . . ?
C15 C16 C21 C20 178.3(2) . . . . ?
C15 C16 C21 C22 -2.8(3) . . . . ?
C16 C17 C18 F1 -179.3(2) . . . . ?
C16 C17 C18 C19 0.3(4) . . . . ?
C16 C21 C22 C23 2.1(3) . . . . ?
C17 C16 C21 C20 -1.9(3) . . . . ?
C17 C16 C21 C22 177.0(2) . . . . ?
C17 C18 C19 C20 -1.0(4) . . . . ?
C18 C19 C20 C21 0.2(4) . . . . ?
C19 C20 C21 C16 1.3(4) . . . . ?
C19 C20 C21 C22 -177.6(2) . . . . ?
C20 C21 C22 C23 -179.0(2) . . . . ?
C21 C16 C17 C18 1.2(3) . . . . ?
C21 C22 C23 C14 0.5(3) . . . . ?
C21 C22 C23 C24 179.41(19) . . . . ?
C22 C23 C24 O2 3.5(3) . . . . ?
C22 C23 C24 C25 -176.07(19) . . . . ?
C23 C14 C15 C16 1.6(3) . . . . ?
C23 C24 C25 C26 178.11(18) . . . . ?
C23 C24 C25 C34 -1.7(3) . . . . ?
C24 C25 C26 C27 -179.20(19) . . . . ?
C24 C25 C34 C13 -3.0(3) . . . . ?
C24 C25 C34 C33 179.46(19) . . . . ?
C25 C26 C27 C28 179.6(2) . . . . ?
C25 C26 C27 C32 -0.5(3) . . . . ?
C26 C25 C34 C13 177.27(18) . . . . ?
C26 C25 C34 C33 -0.3(3) . . . . ?
C26 C27 C28 C29 179.9(2) . . . . ?
C26 C27 C32 C31 -179.8(2) . . . . ?
C26 C27 C32 C33 0.2(3) . . . . ?
C27 C28 C29 C30 -0.1(4) . . . . ?
C27 C32 C33 C34 0.0(3) . . . . ?
C28 C27 C32 C31 0.0(3) . . . . ?
C28 C27 C32 C33 -179.9(2) . . . . ?
C28 C29 C30 F2 -179.9(2) . . . . ?
C28 C29 C30 C31 0.2(4) . . . . ?
C29 C30 C31 C32 -0.1(4) . . . . ?
C30 C31 C32 C27 0.0(3) . . . . ?
C30 C31 C32 C33 179.9(2) . . . . ?
C31 C32 C33 C34 -179.9(2) . . . . ?
C32 C27 C28 C29 0.1(4) . . . . ?
C32 C33 C34 C13 -177.65(18) . . . . ?
C32 C33 C34 C25 0.0(3) . . . . ?
C34 C13 C14 C15 177.09(18) . . . . ?
C34 C13 C14 C23 -4.8(3) . . . . ?
C34 C25 C26 C27 0.6(3) . . . . ?
Cl1 Cl2 C35 Cl1 173.5(2) 3 . . . ?
Cl1 Cl2 C35 Cl2 135.8(11) 3 . . 3 ?
Cl2 Cl1 C35 Cl2 -10.0(3) 3 . . . ?
Cl2 Cl2 C35 Cl1 37.7(10) 3 . . . ?
C35 Cl2 C35 Cl1 37.7(10) 3 . . . ?
C35 Cl2 C35 Cl2 -0.007(9) 3 . . 3 ?

_olex2_submission_special_instructions 'No special instructions were received'
