# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
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data_cd17277
_database_code_depnum_ccdc_archive 'CCDC 1550234'
_audit_update_record             
;
2017-05-16 deposited with the CCDC.
2017-10-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C22 H26 N2 O6 Pd2'
_chemical_formula_weight         627.25

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.837(2)
_cell_length_b                   15.910(3)
_cell_length_c                   12.607(2)
_cell_angle_alpha                90
_cell_angle_beta                 98.114(4)
_cell_angle_gamma                90
_cell_volume                     2350.5(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3792
_cell_measurement_theta_min      5.093
_cell_measurement_theta_max      49.465

_exptl_crystal_description       prismatic
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.772
_exptl_crystal_F_000             1248
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.120
_exptl_absorpt_coefficient_mu    1.570
_shelx_estimated_absorpt_T_min   0.744
_shelx_estimated_absorpt_T_max   0.834
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5728
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            13336
_diffrn_reflns_av_unetI/netI     0.0407
_diffrn_reflns_av_R_equivalents  0.0385
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.074
_diffrn_reflns_theta_max         25.496
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             4382
_reflns_number_gt                3633
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 ? 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0468P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4382
_refine_ls_number_parameters     295
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0428
_refine_ls_R_factor_gt           0.0338
_refine_ls_wR_factor_ref         0.0847
_refine_ls_wR_factor_gt          0.0793
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_restrained_S_all      1.007
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.24673(2) 0.34374(2) 0.32983(2) 0.04227(11) Uani 1 1 d . . . . .
Pd2 Pd 0.37328(2) 0.24663(2) 0.50077(2) 0.04271(11) Uani 1 1 d . . . . .
N1 N 0.1122(2) 0.26665(19) 0.3129(3) 0.0461(7) Uani 1 1 d . . . . .
N2 N 0.4544(3) 0.16094(18) 0.4223(3) 0.0462(7) Uani 1 1 d . . . . .
O1 O 0.0181(2) 0.27329(18) 0.3681(2) 0.0585(7) Uani 1 1 d . . . . .
O2 O 0.5455(2) 0.17706(19) 0.3654(2) 0.0649(8) Uani 1 1 d . . . . .
O3 O 0.2015(2) 0.41152(16) 0.4651(2) 0.0580(7) Uani 1 1 d . . . . .
O4 O 0.2805(2) 0.32037(17) 0.5900(2) 0.0572(7) Uani 1 1 d . . . . .
O5 O 0.3925(2) 0.41296(15) 0.3317(2) 0.0528(6) Uani 1 1 d . . . . .
O6 O 0.4811(2) 0.35119(14) 0.4784(2) 0.0519(7) Uani 1 1 d . . . . .
C1 C 0.2877(3) 0.2681(2) 0.2194(3) 0.0441(8) Uani 1 1 d . . . . .
C2 C 0.3800(3) 0.2737(3) 0.1629(3) 0.0549(10) Uani 1 1 d . . . . .
H2 H 0.4249 0.3219 0.1681 0.066 Uiso 1 1 calc R U . . .
C3 C 0.4051(4) 0.2074(3) 0.0988(3) 0.0685(12) Uani 1 1 d . . . . .
H3 H 0.4658 0.2122 0.0597 0.082 Uiso 1 1 calc R U . . .
C4 C 0.3417(4) 0.1349(3) 0.0920(4) 0.0689(12) Uani 1 1 d . . . . .
H4 H 0.3614 0.0903 0.0506 0.083 Uiso 1 1 calc R U . . .
C5 C 0.2493(4) 0.1279(3) 0.1463(3) 0.0586(11) Uani 1 1 d . . . . .
H5 H 0.2063 0.0787 0.1415 0.070 Uiso 1 1 calc R U . . .
C6 C 0.2206(3) 0.1945(2) 0.2081(3) 0.0434(8) Uani 1 1 d . . . . .
C7 C 0.1207(3) 0.1963(2) 0.2636(3) 0.0453(9) Uani 1 1 d . . . . .
C8 C 0.0376(4) 0.1264(3) 0.2631(4) 0.0669(12) Uani 1 1 d . . . . .
H8A H 0.0148 0.1211 0.3329 0.100 Uiso 1 1 calc R U . . .
H8B H 0.0725 0.0749 0.2448 0.100 Uiso 1 1 calc R U . . .
H8C H -0.0281 0.1379 0.2114 0.100 Uiso 1 1 calc R U . . .
C9 C -0.0491(4) 0.3419(3) 0.3245(4) 0.0854(16) Uani 1 1 d . . . . .
H9A H -0.0089 0.3935 0.3429 0.128 Uiso 1 1 calc R U . . .
H9B H -0.1201 0.3424 0.3532 0.128 Uiso 1 1 calc R U . . .
H9C H -0.0640 0.3365 0.2480 0.128 Uiso 1 1 calc R U . . .
C10 C 0.2815(3) 0.1463(2) 0.5196(3) 0.0449(9) Uani 1 1 d . . . . .
C11 C 0.1928(4) 0.1396(3) 0.5800(3) 0.0562(10) Uani 1 1 d . . . . .
H11 H 0.1728 0.1854 0.6191 0.067 Uiso 1 1 calc R U . . .
C12 C 0.1341(4) 0.0645(3) 0.5820(4) 0.0682(12) Uani 1 1 d . . . . .
H12 H 0.0760 0.0597 0.6243 0.082 Uiso 1 1 calc R U . . .
C13 C 0.1607(4) -0.0028(3) 0.5223(4) 0.0703(13) Uani 1 1 d . . . . .
H13 H 0.1194 -0.0525 0.5231 0.084 Uiso 1 1 calc R U . . .
C14 C 0.2485(4) 0.0027(3) 0.4609(4) 0.0619(11) Uani 1 1 d . . . . .
H14 H 0.2658 -0.0428 0.4196 0.074 Uiso 1 1 calc R U . . .
C15 C 0.3103(3) 0.0767(2) 0.4616(3) 0.0475(9) Uani 1 1 d . . . . .
C16 C 0.4092(3) 0.0876(2) 0.4057(3) 0.0456(9) Uani 1 1 d . . . . .
C17 C 0.4535(4) 0.0204(3) 0.3405(3) 0.0628(11) Uani 1 1 d . . . . .
H17A H 0.4036 0.0143 0.2740 0.094 Uiso 1 1 calc R U . . .
H17B H 0.4569 -0.0318 0.3791 0.094 Uiso 1 1 calc R U . . .
H17C H 0.5285 0.0352 0.3263 0.094 Uiso 1 1 calc R U . . .
C18 C 0.6436(4) 0.2048(3) 0.4338(5) 0.0796(14) Uani 1 1 d . . . . .
H18A H 0.6231 0.2497 0.4783 0.119 Uiso 1 1 calc R U . . .
H18B H 0.6996 0.2245 0.3915 0.119 Uiso 1 1 calc R U . . .
H18C H 0.6748 0.1590 0.4782 0.119 Uiso 1 1 calc R U . . .
C19 C 0.2207(3) 0.3837(3) 0.5576(4) 0.0534(10) Uani 1 1 d . . . . .
C20 C 0.1689(4) 0.4292(3) 0.6450(4) 0.0753(14) Uani 1 1 d . . . . .
H20A H 0.1119 0.4680 0.6130 0.113 Uiso 1 1 calc R U . . .
H20B H 0.2275 0.4594 0.6899 0.113 Uiso 1 1 calc R U . . .
H20C H 0.1344 0.3891 0.6874 0.113 Uiso 1 1 calc R U . . .
C21 C 0.4771(3) 0.4005(2) 0.4015(3) 0.0441(8) Uani 1 1 d . . . . .
C22 C 0.5844(3) 0.4492(2) 0.3917(4) 0.0603(11) Uani 1 1 d . . . . .
H22A H 0.5845 0.4654 0.3184 0.091 Uiso 1 1 calc R U . . .
H22B H 0.6498 0.4147 0.4147 0.091 Uiso 1 1 calc R U . . .
H22C H 0.5872 0.4986 0.4358 0.091 Uiso 1 1 calc R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 C1 1.952(4) . ?
Pd1 N1 1.997(3) . ?
Pd1 O5 2.044(2) . ?
Pd1 O3 2.149(3) . ?
Pd1 Pd2 2.8922(5) . ?
Pd2 C10 1.963(3) . ?
Pd2 N2 2.007(3) . ?
Pd2 O4 2.048(3) . ?
Pd2 O6 2.140(2) . ?
N1 C7 1.291(5) . ?
N1 O1 1.398(4) . ?
N2 C16 1.289(4) . ?
N2 O2 1.400(4) . ?
O1 C9 1.416(5) . ?
O2 C18 1.416(5) . ?
O3 C19 1.238(5) . ?
O4 C19 1.266(5) . ?
O5 C21 1.252(5) . ?
O6 C21 1.242(4) . ?
C1 C2 1.388(5) . ?
C1 C6 1.412(5) . ?
C2 C3 1.387(6) . ?
C2 H2 0.9300 . ?
C3 C4 1.373(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.373(6) . ?
C4 H4 0.9300 . ?
C5 C6 1.386(5) . ?
C5 H5 0.9300 . ?
C6 C7 1.456(5) . ?
C7 C8 1.485(5) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 C11 1.385(5) . ?
C10 C15 1.396(5) . ?
C11 C12 1.384(5) . ?
C11 H11 0.9300 . ?
C12 C13 1.371(6) . ?
C12 H12 0.9300 . ?
C13 C14 1.384(6) . ?
C13 H13 0.9300 . ?
C14 C15 1.386(5) . ?
C14 H14 0.9300 . ?
C15 C16 1.459(5) . ?
C16 C17 1.489(5) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.519(5) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 C22 1.508(5) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pd1 N1 79.62(14) . . ?
C1 Pd1 O5 92.63(13) . . ?
N1 Pd1 O5 172.25(12) . . ?
C1 Pd1 O3 171.97(13) . . ?
N1 Pd1 O3 96.26(11) . . ?
O5 Pd1 O3 91.42(11) . . ?
C1 Pd1 Pd2 92.73(11) . . ?
N1 Pd1 Pd2 94.18(9) . . ?
O5 Pd1 Pd2 86.08(8) . . ?
O3 Pd1 Pd2 80.64(8) . . ?
C10 Pd2 N2 79.58(14) . . ?
C10 Pd2 O4 92.90(13) . . ?
N2 Pd2 O4 172.17(11) . . ?
C10 Pd2 O6 176.67(13) . . ?
N2 Pd2 O6 97.30(11) . . ?
O4 Pd2 O6 90.17(10) . . ?
C10 Pd2 Pd1 106.70(11) . . ?
N2 Pd2 Pd1 103.25(9) . . ?
O4 Pd2 Pd1 80.88(8) . . ?
O6 Pd2 Pd1 75.06(8) . . ?
C7 N1 O1 115.3(3) . . ?
C7 N1 Pd1 117.9(2) . . ?
O1 N1 Pd1 125.4(2) . . ?
C16 N2 O2 114.6(3) . . ?
C16 N2 Pd2 118.5(2) . . ?
O2 N2 Pd2 125.8(2) . . ?
N1 O1 C9 108.0(3) . . ?
N2 O2 C18 111.7(3) . . ?
C19 O3 Pd1 122.4(3) . . ?
C19 O4 Pd2 126.7(3) . . ?
C21 O5 Pd1 120.8(2) . . ?
C21 O6 Pd2 129.5(3) . . ?
C2 C1 C6 118.3(3) . . ?
C2 C1 Pd1 128.2(3) . . ?
C6 C1 Pd1 113.0(3) . . ?
C3 C2 C1 120.0(4) . . ?
C3 C2 H2 120.0 . . ?
C1 C2 H2 120.0 . . ?
C4 C3 C2 121.0(4) . . ?
C4 C3 H3 119.5 . . ?
C2 C3 H3 119.5 . . ?
C3 C4 C5 120.3(4) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
C4 C5 C6 119.6(4) . . ?
C4 C5 H5 120.2 . . ?
C6 C5 H5 120.2 . . ?
C5 C6 C1 120.8(4) . . ?
C5 C6 C7 124.4(4) . . ?
C1 C6 C7 114.7(3) . . ?
N1 C7 C6 111.9(3) . . ?
N1 C7 C8 123.7(4) . . ?
C6 C7 C8 124.4(4) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O1 C9 H9A 109.5 . . ?
O1 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
O1 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C11 C10 C15 119.1(3) . . ?
C11 C10 Pd2 127.2(3) . . ?
C15 C10 Pd2 113.7(3) . . ?
C12 C11 C10 120.0(4) . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C13 C12 C11 120.5(4) . . ?
C13 C12 H12 119.7 . . ?
C11 C12 H12 119.7 . . ?
C12 C13 C14 120.5(4) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
C13 C14 C15 119.1(4) . . ?
C13 C14 H14 120.4 . . ?
C15 C14 H14 120.4 . . ?
C14 C15 C10 120.7(3) . . ?
C14 C15 C16 123.8(4) . . ?
C10 C15 C16 115.5(3) . . ?
N2 C16 C15 111.9(3) . . ?
N2 C16 C17 124.7(3) . . ?
C15 C16 C17 123.4(3) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O2 C18 H18A 109.5 . . ?
O2 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
O2 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
O3 C19 O4 127.4(4) . . ?
O3 C19 C20 118.3(4) . . ?
O4 C19 C20 114.3(4) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
O6 C21 O5 126.0(3) . . ?
O6 C21 C22 116.6(4) . . ?
O5 C21 C22 117.4(3) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 N1 O1 C9 -119.9(4) . . . . ?
Pd1 N1 O1 C9 73.9(4) . . . . ?
C16 N2 O2 C18 -127.4(4) . . . . ?
Pd2 N2 O2 C18 64.9(4) . . . . ?
C6 C1 C2 C3 -0.9(6) . . . . ?
Pd1 C1 C2 C3 170.3(3) . . . . ?
C1 C2 C3 C4 -1.7(7) . . . . ?
C2 C3 C4 C5 2.3(7) . . . . ?
C3 C4 C5 C6 -0.2(7) . . . . ?
C4 C5 C6 C1 -2.4(6) . . . . ?
C4 C5 C6 C7 176.0(4) . . . . ?
C2 C1 C6 C5 3.0(5) . . . . ?
Pd1 C1 C6 C5 -169.6(3) . . . . ?
C2 C1 C6 C7 -175.6(3) . . . . ?
Pd1 C1 C6 C7 11.8(4) . . . . ?
O1 N1 C7 C6 179.9(3) . . . . ?
Pd1 N1 C7 C6 -12.7(4) . . . . ?
O1 N1 C7 C8 0.5(5) . . . . ?
Pd1 N1 C7 C8 167.8(3) . . . . ?
C5 C6 C7 N1 -178.1(4) . . . . ?
C1 C6 C7 N1 0.4(4) . . . . ?
C5 C6 C7 C8 1.3(6) . . . . ?
C1 C6 C7 C8 179.8(4) . . . . ?
C15 C10 C11 C12 -0.1(6) . . . . ?
Pd2 C10 C11 C12 177.9(3) . . . . ?
C10 C11 C12 C13 -1.9(7) . . . . ?
C11 C12 C13 C14 1.5(7) . . . . ?
C12 C13 C14 C15 0.9(7) . . . . ?
C13 C14 C15 C10 -2.9(6) . . . . ?
C13 C14 C15 C16 175.8(4) . . . . ?
C11 C10 C15 C14 2.5(6) . . . . ?
Pd2 C10 C15 C14 -175.7(3) . . . . ?
C11 C10 C15 C16 -176.3(3) . . . . ?
Pd2 C10 C15 C16 5.5(4) . . . . ?
O2 N2 C16 C15 -176.3(3) . . . . ?
Pd2 N2 C16 C15 -7.7(4) . . . . ?
O2 N2 C16 C17 5.6(5) . . . . ?
Pd2 N2 C16 C17 174.2(3) . . . . ?
C14 C15 C16 N2 -177.4(4) . . . . ?
C10 C15 C16 N2 1.3(5) . . . . ?
C14 C15 C16 C17 0.8(6) . . . . ?
C10 C15 C16 C17 179.5(4) . . . . ?
Pd1 O3 C19 O4 10.1(6) . . . . ?
Pd1 O3 C19 C20 -170.3(3) . . . . ?
Pd2 O4 C19 O3 3.8(6) . . . . ?
Pd2 O4 C19 C20 -175.7(3) . . . . ?
Pd2 O6 C21 O5 19.2(5) . . . . ?
Pd2 O6 C21 C22 -160.5(3) . . . . ?
Pd1 O5 C21 O6 -4.7(5) . . . . ?
Pd1 O5 C21 C22 175.0(2) . . . . ?

_refine_diff_density_max         0.734
_refine_diff_density_min         -0.332
_refine_diff_density_rms         0.097

_shelxl_version_number           2013-4

