# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ge4
_database_code_depnum_ccdc_archive 'CCDC 1505261'
_audit_update_record             
;
2016-09-20 deposited with the CCDC.
2018-01-15 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        tetragermacyclobutadiene
_chemical_name_common            'Ge CBD'
_chemical_melting_point          616-618
_chemical_formula_moiety         'C96 H148 Ge4, 0.5(C6 H14)'
_chemical_formula_sum            'C99 H155 Ge4'
_chemical_formula_weight         1635.58

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.3376(1)
_cell_length_b                   17.8421(2)
_cell_length_c                   25.5819(3)
_cell_angle_alpha                84.4742(5)
_cell_angle_beta                 83.1749(6)
_cell_angle_gamma                87.3583(8)
_cell_volume                     4660.37(9)
_cell_formula_units_Z            2
_cell_measurement_temperature    90
_cell_measurement_reflns_used    264421
_cell_measurement_theta_min      1.340
_cell_measurement_theta_max      33.371

_exptl_crystal_description       plate
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.166
_exptl_crystal_F_000             1754
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.05
_exptl_absorpt_coefficient_mu    1.320
_shelx_estimated_absorpt_T_min   0.837
_shelx_estimated_absorpt_T_max   0.937
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.83842
_exptl_absorpt_correction_T_max  0.93689
_exptl_absorpt_process_details   
;
 Analytical Absorption Correction Program
 N.W. Alcock (1970). Cryst. Computing, 271
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      90
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'Fine-focus rotating anode'
_diffrn_measurement_device_type  'Rigaku AFC-8 with Saturn70 CCD'
_diffrn_measurement_method       ω-scan
_diffrn_detector_area_resol_mean 7.31
_diffrn_reflns_number            264416
_diffrn_reflns_av_unetI/netI     0.0408
_diffrn_reflns_av_R_equivalents  0.0655
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_theta_min         1.340
_diffrn_reflns_theta_max         33.371
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             35880
_reflns_number_gt                23868
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       CrystalClear
_computing_cell_refinement       HKL2000
_computing_data_reduction        HKL2000
_computing_structure_solution    SIR2004
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    SV
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0452P)²+0.9394P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         35880
_refine_ls_number_parameters     967
_refine_ls_number_restraints     54
_refine_ls_R_factor_all          0.0699
_refine_ls_R_factor_gt           0.0377
_refine_ls_wR_factor_ref         0.1037
_refine_ls_wR_factor_gt          0.0925
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.26279(2) 0.42473(2) 0.25490(2) 0.02291(4) Uani 1 1 d . . . . .
Ge2 Ge 0.16892(2) 0.33544(2) 0.32529(2) 0.03038(4) Uani 1 1 d . . . . .
Ge3 Ge 0.29111(2) 0.25504(2) 0.26579(2) 0.02575(4) Uani 1 1 d . . . . .
Ge4 Ge 0.39215(2) 0.34194(2) 0.19540(2) 0.03110(4) Uani 1 1 d . . . . .
C1 C 0.24073(13) 0.53681(7) 0.24830(5) 0.0210(2) Uani 1 1 d . . . . .
C2 C 0.11637(13) 0.57323(8) 0.25669(5) 0.0220(3) Uani 1 1 d . . . . .
C3 C -0.01745(13) 0.53962(8) 0.27490(6) 0.0260(3) Uani 1 1 d . . . . .
C4 C -0.11325(14) 0.60762(9) 0.26498(7) 0.0314(3) Uani 1 1 d . . . . .
H4A H -0.1535 0.6031 0.2322 0.038 Uiso 1 1 calc R U . . .
H4B H -0.1836 0.6084 0.2948 0.038 Uiso 1 1 calc R U . . .
C5 C -0.03743(14) 0.68123(8) 0.25959(6) 0.0261(3) Uani 1 1 d . . . . .
C6 C 0.10259(13) 0.65183(8) 0.25045(6) 0.0249(3) Uani 1 1 d . . . . .
C7 C 0.20989(14) 0.69654(8) 0.23814(6) 0.0278(3) Uani 1 1 d . . . . .
H7 H 0.1996 0.7499 0.2346 0.033 Uiso 1 1 calc R U . . .
C8 C 0.33260(14) 0.66193(8) 0.23108(6) 0.0250(3) Uani 1 1 d . . . . .
C9 C 0.45958(14) 0.70304(8) 0.21925(6) 0.0275(3) Uani 1 1 d . . . . .
C10 C 0.56127(14) 0.63750(9) 0.22345(7) 0.0323(3) Uani 1 1 d . . . . .
H10A H 0.6001 0.6371 0.2570 0.039 Uiso 1 1 calc R U . . .
H10B H 0.6319 0.6440 0.1938 0.039 Uiso 1 1 calc R U . . .
C11 C 0.49403(13) 0.56209(8) 0.22151(6) 0.0262(3) Uani 1 1 d . . . . .
C12 C 0.34894(13) 0.58349(8) 0.23497(5) 0.0222(3) Uani 1 1 d . . . . .
C13 C -0.04953(15) 0.47591(9) 0.24292(7) 0.0344(3) Uani 1 1 d . . . . .
H13A H -0.0431 0.4940 0.2053 0.052 Uiso 1 1 calc R U . . .
H13B H -0.1383 0.4597 0.2549 0.052 Uiso 1 1 calc R U . . .
H13C H 0.0123 0.4333 0.2481 0.052 Uiso 1 1 calc R U . . .
C14 C -0.02926(16) 0.51286(9) 0.33401(6) 0.0341(3) Uani 1 1 d . . . . .
H14A H -0.1173 0.4950 0.3455 0.051 Uiso 1 1 calc R U . . .
H14B H -0.0128 0.5548 0.3541 0.051 Uiso 1 1 calc R U . . .
H14C H 0.0347 0.4717 0.3402 0.051 Uiso 1 1 calc R U . . .
C15 C -0.05580(15) 0.72195(9) 0.31086(6) 0.0313(3) Uani 1 1 d . . . . .
H15A H -0.0373 0.6851 0.3408 0.038 Uiso 1 1 calc R U . . .
H15B H 0.0095 0.7615 0.3077 0.038 Uiso 1 1 calc R U . . .
C16 C -0.19076(18) 0.75837(11) 0.32418(8) 0.0431(4) Uani 1 1 d . . . . .
H16A H -0.2058 0.7997 0.2972 0.065 Uiso 1 1 calc R U . . .
H16B H -0.1959 0.7781 0.3588 0.065 Uiso 1 1 calc R U . . .
H16C H -0.2572 0.7207 0.3250 0.065 Uiso 1 1 calc R U . . .
C17 C -0.07280(16) 0.73625(10) 0.21269(7) 0.0351(3) Uani 1 1 d . . . . .
H17A H -0.1679 0.7474 0.2175 0.042 Uiso 1 1 calc R U . . .
H17B H -0.0288 0.7841 0.2138 0.042 Uiso 1 1 calc R U . . .
C18 C -0.0368(2) 0.70867(14) 0.15822(8) 0.0565(6) Uani 1 1 d . . . . .
H18A H 0.0577 0.6991 0.1522 0.085 Uiso 1 1 calc R U . . .
H18B H -0.0634 0.7471 0.1312 0.085 Uiso 1 1 calc R U . . .
H18C H -0.0815 0.6620 0.1561 0.085 Uiso 1 1 calc R U . . .
C19 C 0.47062(17) 0.75965(9) 0.26030(7) 0.0354(3) Uani 1 1 d . . . . .
H19A H 0.5612 0.7770 0.2559 0.042 Uiso 1 1 calc R U . . .
H19B H 0.4128 0.8041 0.2524 0.042 Uiso 1 1 calc R U . . .
C20 C 0.4362(2) 0.72991(13) 0.31773(8) 0.0545(5) Uani 1 1 d . . . . .
H20A H 0.3438 0.7178 0.3238 0.082 Uiso 1 1 calc R U . . .
H20B H 0.4529 0.7684 0.3408 0.082 Uiso 1 1 calc R U . . .
H20C H 0.4896 0.6844 0.3257 0.082 Uiso 1 1 calc R U . . .
C21 C 0.46699(16) 0.74457(10) 0.16311(7) 0.0349(3) Uani 1 1 d . . . . .
H21A H 0.4628 0.7069 0.1374 0.042 Uiso 1 1 calc R U . . .
H21B H 0.3894 0.7789 0.1612 0.042 Uiso 1 1 calc R U . . .
C22 C 0.5890(2) 0.79036(13) 0.14613(8) 0.0530(5) Uani 1 1 d . . . . .
H22A H 0.5913 0.8303 0.1697 0.079 Uiso 1 1 calc R U . . .
H22B H 0.5869 0.8129 0.1097 0.079 Uiso 1 1 calc R U . . .
H22C H 0.6668 0.7572 0.1481 0.079 Uiso 1 1 calc R U . . .
C23 C 0.51917(16) 0.53604(10) 0.16559(7) 0.0364(4) Uani 1 1 d . . . . .
H23A H 0.6126 0.5250 0.1570 0.055 Uiso 1 1 calc R U . . .
H23B H 0.4903 0.5760 0.1401 0.055 Uiso 1 1 calc R U . . .
H23C H 0.4707 0.4905 0.1641 0.055 Uiso 1 1 calc R U . . .
C24 C 0.54796(15) 0.50263(9) 0.26116(7) 0.0336(3) Uani 1 1 d . . . . .
H24A H 0.5302 0.5192 0.2968 0.050 Uiso 1 1 calc R U . . .
H24B H 0.6423 0.4958 0.2520 0.050 Uiso 1 1 calc R U . . .
H24C H 0.5059 0.4548 0.2601 0.050 Uiso 1 1 calc R U . . .
C25 C 0.17433(14) 0.32376(8) 0.40450(6) 0.0256(3) Uani 1 1 d . . . . .
C26 C 0.07876(15) 0.27705(9) 0.43361(6) 0.0291(3) Uani 1 1 d . . . . .
C27 C -0.03374(17) 0.23677(11) 0.41475(7) 0.0392(4) Uani 1 1 d . . . . .
C28 C -0.1121(2) 0.20637(14) 0.46725(8) 0.0549(6) Uani 1 1 d . . . . .
H28A H -0.1924 0.2380 0.4742 0.066 Uiso 1 1 calc R U . . .
H28B H -0.1379 0.1542 0.4646 0.066 Uiso 1 1 calc R U . . .
C29 C -0.02843(18) 0.20742(11) 0.51263(7) 0.0409(4) Uani 1 1 d D . . . .
C30 C 0.07694(15) 0.26072(9) 0.48843(6) 0.0317(3) Uani 1 1 d . . . . .
C31 C 0.16459(16) 0.29260(10) 0.51590(6) 0.0331(3) Uani 1 1 d . . . . .
H31 H 0.1634 0.2809 0.5530 0.040 Uiso 1 1 calc R U . . .
C32 C 0.25397(14) 0.34181(9) 0.48865(6) 0.0280(3) Uani 1 1 d . . . . .
C33 C 0.34771(16) 0.38522(10) 0.51428(6) 0.0320(3) Uani 1 1 d . . . . .
C34 C 0.42280(17) 0.43006(10) 0.46631(6) 0.0350(4) Uani 1 1 d . . . . .
H34A H 0.5168 0.4157 0.4644 0.042 Uiso 1 1 calc R U . . .
H34B H 0.4126 0.4847 0.4705 0.042 Uiso 1 1 calc R U . . .
C35 C 0.36922(15) 0.41304(9) 0.41459(6) 0.0275(3) Uani 1 1 d . . . . .
C36 C 0.26102(14) 0.35708(8) 0.43386(6) 0.0261(3) Uani 1 1 d . . . . .
C37 C 0.0155(2) 0.17179(12) 0.38192(8) 0.0554(6) Uani 1 1 d . . . . .
H37A H -0.0588 0.1439 0.3746 0.083 Uiso 1 1 calc R U . . .
H37B H 0.0736 0.1379 0.4016 0.083 Uiso 1 1 calc R U . . .
H37C H 0.0633 0.1919 0.3485 0.083 Uiso 1 1 calc R U . . .
C38 C -0.1244(2) 0.29075(15) 0.38377(10) 0.0659(7) Uani 1 1 d . . . . .
H38A H -0.0817 0.3037 0.3479 0.099 Uiso 1 1 calc R U . . .
H38B H -0.1427 0.3367 0.4018 0.099 Uiso 1 1 calc R U . . .
H38C H -0.2062 0.2661 0.3818 0.099 Uiso 1 1 calc R U . . .
C39 C -0.1075(2) 0.23577(13) 0.56259(8) 0.0530(5) Uani 1 1 d . . . . .
H39A H -0.1840 0.2039 0.5724 0.064 Uiso 1 1 calc R U . . .
H39B H -0.0525 0.2282 0.5920 0.064 Uiso 1 1 calc R U . . .
C40 C -0.1553(2) 0.31769(15) 0.55788(11) 0.0729(8) Uani 1 1 d . . . . .
H40A H -0.0804 0.3504 0.5523 0.109 Uiso 1 1 calc R U . . .
H40B H -0.2100 0.3287 0.5904 0.109 Uiso 1 1 calc R U . . .
H40C H -0.2065 0.3268 0.5279 0.109 Uiso 1 1 calc R U . . .
C41A C 0.0352(5) 0.12852(17) 0.52337(14) 0.0544(9) Uani 0.705(4) 1 d D . P A 1
H41A H 0.0804 0.1125 0.4897 0.065 Uiso 0.705(4) 1 calc R U P A 1
H41B H 0.1019 0.1317 0.5478 0.065 Uiso 0.705(4) 1 calc R U P A 1
C42A C -0.0608(5) 0.0689(2) 0.5471(2) 0.1037(15) Uani 0.705(4) 1 d D . P A 1
H42A H -0.1061 0.0842 0.5805 0.156 Uiso 0.705(4) 1 calc R U P A 1
H42B H -0.0136 0.0206 0.5537 0.156 Uiso 0.705(4) 1 calc R U P A 1
H42C H -0.1246 0.0634 0.5224 0.156 Uiso 0.705(4) 1 calc R U P A 1
C41B C 0.0249(13) 0.1352(4) 0.5419(3) 0.0544(9) Uani 0.295(4) 1 d D . P A 2
H41C H 0.0595 0.1488 0.5741 0.065 Uiso 0.295(4) 1 calc R U P A 2
H41D H -0.0481 0.1012 0.5533 0.065 Uiso 0.295(4) 1 calc R U P A 2
C42B C 0.1316(9) 0.0929(4) 0.5094(4) 0.1037(15) Uani 0.295(4) 1 d D . P A 2
H42D H 0.0927 0.0651 0.4843 0.156 Uiso 0.295(4) 1 calc R U P A 2
H42E H 0.1780 0.0574 0.5329 0.156 Uiso 0.295(4) 1 calc R U P A 2
H42F H 0.1929 0.1288 0.4899 0.156 Uiso 0.295(4) 1 calc R U P A 2
C43 C 0.27148(19) 0.43739(11) 0.55330(7) 0.0426(4) Uani 1 1 d . . . . .
H43A H 0.2242 0.4054 0.5825 0.051 Uiso 1 1 calc R U . . .
H43B H 0.3351 0.4659 0.5688 0.051 Uiso 1 1 calc R U . . .
C44 C 0.1747(3) 0.49284(14) 0.52969(9) 0.0627(6) Uani 1 1 d . . . . .
H44A H 0.2211 0.5279 0.5028 0.094 Uiso 1 1 calc R U . . .
H44B H 0.1281 0.5211 0.5576 0.094 Uiso 1 1 calc R U . . .
H44C H 0.1122 0.4655 0.5134 0.094 Uiso 1 1 calc R U . . .
C45 C 0.43870(18) 0.33226(12) 0.54612(7) 0.0428(4) Uani 1 1 d . . . . .
H45A H 0.5033 0.3632 0.5590 0.051 Uiso 1 1 calc R U . . .
H45B H 0.3859 0.3082 0.5775 0.051 Uiso 1 1 calc R U . . .
C46 C 0.5120(2) 0.27067(14) 0.51622(9) 0.0575(6) Uani 1 1 d . . . . .
H46A H 0.4494 0.2388 0.5038 0.086 Uiso 1 1 calc R U . . .
H46B H 0.5658 0.2399 0.5397 0.086 Uiso 1 1 calc R U . . .
H46C H 0.5680 0.2936 0.4858 0.086 Uiso 1 1 calc R U . . .
C47 C 0.47897(16) 0.37796(10) 0.37773(6) 0.0331(3) Uani 1 1 d . . . . .
H47A H 0.4452 0.3675 0.3451 0.050 Uiso 1 1 calc R U . . .
H47B H 0.5116 0.3308 0.3953 0.050 Uiso 1 1 calc R U . . .
H47C H 0.5501 0.4131 0.3693 0.050 Uiso 1 1 calc R U . . .
C48 C 0.31474(17) 0.48624(9) 0.38740(6) 0.0336(3) Uani 1 1 d . . . . .
H48A H 0.2809 0.4754 0.3548 0.050 Uiso 1 1 calc R U . . .
H48B H 0.3843 0.5224 0.3788 0.050 Uiso 1 1 calc R U . . .
H48C H 0.2442 0.5076 0.4112 0.050 Uiso 1 1 calc R U . . .
C49 C 0.30545(14) 0.14344(8) 0.27385(6) 0.0265(3) Uani 1 1 d . . . . .
C50 C 0.22540(15) 0.09944(8) 0.24864(6) 0.0293(3) Uani 1 1 d . . . . .
C51 C 0.12501(16) 0.12485(9) 0.21053(7) 0.0331(3) Uani 1 1 d . . . . .
C52 C 0.06411(19) 0.04972(9) 0.20104(8) 0.0418(4) Uani 1 1 d . . . . .
H52A H -0.0290 0.0499 0.2157 0.050 Uiso 1 1 calc R U . . .
H52B H 0.0695 0.0448 0.1626 0.050 Uiso 1 1 calc R U . . .
C53 C 0.13791(19) -0.01720(9) 0.22801(8) 0.0436(4) Uani 1 1 d . . . . .
C54 C 0.23532(16) 0.02072(9) 0.25588(7) 0.0354(4) Uani 1 1 d . . . . .
C55 C 0.32415(17) -0.01578(9) 0.28653(8) 0.0399(4) Uani 1 1 d . . . . .
H55 H 0.3297 -0.0693 0.2911 0.048 Uiso 1 1 calc R U . . .
C56 C 0.40523(16) 0.02648(9) 0.31053(7) 0.0351(4) Uani 1 1 d . . . . .
C57 C 0.51131(18) -0.00447(10) 0.34370(8) 0.0423(4) Uani 1 1 d D . . . .
C58 C 0.5778(2) 0.06804(10) 0.35339(9) 0.0499(5) Uani 1 1 d . . . . .
H58A H 0.5922 0.0666 0.3911 0.060 Uiso 1 1 calc R U . . .
H58B H 0.6636 0.0715 0.3317 0.060 Uiso 1 1 calc R U . . .
C59 C 0.48995(17) 0.13740(9) 0.33850(7) 0.0347(3) Uani 1 1 d . . . . .
C60 C 0.39559(15) 0.10538(8) 0.30506(6) 0.0294(3) Uani 1 1 d . . . . .
C61 C 0.01855(17) 0.17964(10) 0.23282(8) 0.0414(4) Uani 1 1 d . . . . .
H61A H 0.0582 0.2260 0.2397 0.062 Uiso 1 1 calc R U . . .
H61B H -0.0263 0.1563 0.2659 0.062 Uiso 1 1 calc R U . . .
H61C H -0.0443 0.1916 0.2072 0.062 Uiso 1 1 calc R U . . .
C62 C 0.1938(2) 0.16144(11) 0.15820(7) 0.0441(4) Uani 1 1 d . . . . .
H62A H 0.2319 0.2085 0.1646 0.066 Uiso 1 1 calc R U . . .
H62B H 0.1303 0.1722 0.1327 0.066 Uiso 1 1 calc R U . . .
H62C H 0.2628 0.1269 0.1441 0.066 Uiso 1 1 calc R U . . .
C63 C 0.0461(2) -0.06433(12) 0.26934(11) 0.0650(7) Uani 1 1 d . . . . .
H63A H -0.0217 -0.0846 0.2509 0.078 Uiso 1 1 calc R U . . .
H63B H 0.0973 -0.1079 0.2842 0.078 Uiso 1 1 calc R U . . .
C64 C -0.0209(3) -0.02332(18) 0.31470(11) 0.0807(9) Uani 1 1 d . . . . .
H64A H 0.0449 -0.0045 0.3343 0.121 Uiso 1 1 calc R U . . .
H64B H -0.0766 -0.0580 0.3384 0.121 Uiso 1 1 calc R U . . .
H64C H -0.0743 0.0191 0.3008 0.121 Uiso 1 1 calc R U . . .
C65 C 0.2057(3) -0.07075(12) 0.18898(11) 0.0679(7) Uani 1 1 d . . . . .
H65A H 0.2485 -0.1126 0.2096 0.082 Uiso 1 1 calc R U . . .
H65B H 0.1376 -0.0928 0.1717 0.082 Uiso 1 1 calc R U . . .
C66 C 0.3043(3) -0.03848(16) 0.14697(13) 0.0862(9) Uani 1 1 d . . . . .
H66A H 0.2624 0.0001 0.1241 0.129 Uiso 1 1 calc R U . . .
H66B H 0.3433 -0.0785 0.1259 0.129 Uiso 1 1 calc R U . . .
H66C H 0.3724 -0.0158 0.1632 0.129 Uiso 1 1 calc R U . . .
C67 C 0.6067(2) -0.05855(11) 0.31347(10) 0.0582(6) Uani 1 1 d . . . . .
H67A H 0.6824 -0.0699 0.3336 0.070 Uiso 1 1 calc R U . . .
H67B H 0.5627 -0.1065 0.3126 0.070 Uiso 1 1 calc R U . . .
C68 C 0.6567(3) -0.03026(19) 0.25737(12) 0.0816(9) Uani 1 1 d . . . . .
H68A H 0.5836 -0.0227 0.2361 0.122 Uiso 1 1 calc R U . . .
H68B H 0.7195 -0.0674 0.2422 0.122 Uiso 1 1 calc R U . . .
H68C H 0.6994 0.0176 0.2574 0.122 Uiso 1 1 calc R U . . .
C69A C 0.4471(6) -0.0411(2) 0.39714(15) 0.0598(10) Uani 0.701(4) 1 d D . P B 3
H69A H 0.3875 -0.0032 0.4141 0.072 Uiso 0.701(4) 1 calc R U P B 3
H69B H 0.3936 -0.0828 0.3901 0.072 Uiso 0.701(4) 1 calc R U P B 3
C70A C 0.5422(5) -0.0720(3) 0.43615(18) 0.1010(15) Uani 0.701(4) 1 d D . P B 3
H70A H 0.6005 -0.1106 0.4203 0.151 Uiso 0.701(4) 1 calc R U P B 3
H70B H 0.4931 -0.0943 0.4686 0.151 Uiso 0.701(4) 1 calc R U P B 3
H70C H 0.5937 -0.0310 0.4445 0.151 Uiso 0.701(4) 1 calc R U P B 3
C69B C 0.4607(17) -0.0628(3) 0.3893(4) 0.0598(10) Uani 0.299(4) 1 d D . P B 4
H69C H 0.4257 -0.1054 0.3739 0.072 Uiso 0.299(4) 1 calc R U P B 4
H69D H 0.5354 -0.0829 0.4079 0.072 Uiso 0.299(4) 1 calc R U P B 4
C70B C 0.3550(8) -0.0330(5) 0.4299(3) 0.1010(15) Uani 0.299(4) 1 d D . P B 4
H70D H 0.3876 0.0099 0.4451 0.151 Uiso 0.299(4) 1 calc R U P B 4
H70E H 0.3323 -0.0729 0.4582 0.151 Uiso 0.299(4) 1 calc R U P B 4
H70F H 0.2775 -0.0168 0.4126 0.151 Uiso 0.299(4) 1 calc R U P B 4
C71 C 0.4140(2) 0.16656(11) 0.38813(7) 0.0470(5) Uani 1 1 d . . . . .
H71A H 0.4754 0.1805 0.4117 0.071 Uiso 1 1 calc R U . . .
H71B H 0.3582 0.1270 0.4065 0.071 Uiso 1 1 calc R U . . .
H71C H 0.3598 0.2108 0.3779 0.071 Uiso 1 1 calc R U . . .
C72 C 0.57457(19) 0.19987(11) 0.30920(8) 0.0454(4) Uani 1 1 d . . . . .
H72A H 0.6255 0.1808 0.2781 0.068 Uiso 1 1 calc R U . . .
H72B H 0.6338 0.2161 0.3328 0.068 Uiso 1 1 calc R U . . .
H72C H 0.5186 0.2428 0.2979 0.068 Uiso 1 1 calc R U . . .
C73 C 0.38153(15) 0.32533(9) 0.11839(6) 0.0290(3) Uani 1 1 d . . . . .
C74 C 0.28626(15) 0.35370(9) 0.08517(6) 0.0303(3) Uani 1 1 d . . . . .
C75 C 0.16331(16) 0.40369(10) 0.09783(6) 0.0330(3) Uani 1 1 d . . . . .
C76 C 0.10389(19) 0.41634(12) 0.04417(7) 0.0448(4) Uani 1 1 d . . . . .
H76A H 0.0143 0.3974 0.0487 0.054 Uiso 1 1 calc R U . . .
H76B H 0.0993 0.4709 0.0325 0.054 Uiso 1 1 calc R U . . .
C77 C 0.19006(18) 0.37402(12) 0.00202(7) 0.0413(4) Uani 1 1 d . . . . .
C78 C 0.29582(16) 0.33713(10) 0.03252(6) 0.0345(3) Uani 1 1 d . . . . .
C79 C 0.39537(18) 0.29047(11) 0.01161(7) 0.0420(4) Uani 1 1 d . . . . .
H79 H 0.3991 0.2781 -0.0238 0.050 Uiso 1 1 calc R U . . .
C80 C 0.48897(17) 0.26224(11) 0.04299(7) 0.0392(4) Uani 1 1 d . . . . .
C81 C 0.6021(2) 0.20840(14) 0.02641(8) 0.0546(5) Uani 1 1 d D . . . .
C82 C 0.6874(2) 0.21146(16) 0.07085(8) 0.0630(7) Uani 1 1 d . . . . .
H82A H 0.7632 0.2429 0.0581 0.076 Uiso 1 1 calc R U . . .
H82B H 0.7206 0.1600 0.0817 0.076 Uiso 1 1 calc R U . . .
C83 C 0.60794(17) 0.24497(12) 0.11902(7) 0.0431(4) Uani 1 1 d . . . . .
C84 C 0.48635(16) 0.28049(10) 0.09529(6) 0.0332(3) Uani 1 1 d . . . . .
C85 C 0.19627(19) 0.48010(10) 0.11505(7) 0.0398(4) Uani 1 1 d . . . . .
H85A H 0.1167 0.5120 0.1193 0.060 Uiso 1 1 calc R U . . .
H85B H 0.2597 0.5048 0.0881 0.060 Uiso 1 1 calc R U . . .
H85C H 0.2334 0.4722 0.1487 0.060 Uiso 1 1 calc R U . . .
C86 C 0.06599(16) 0.36304(10) 0.13952(7) 0.0368(4) Uani 1 1 d . . . . .
H86A H 0.1036 0.3546 0.1731 0.055 Uiso 1 1 calc R U . . .
H86B H 0.0466 0.3145 0.1278 0.055 Uiso 1 1 calc R U . . .
H86C H -0.0146 0.3940 0.1444 0.055 Uiso 1 1 calc R U . . .
C87 C 0.1142(2) 0.31502(15) -0.02170(9) 0.0583(6) Uani 1 1 d . . . . .
H87A H 0.0403 0.3414 -0.0379 0.070 Uiso 1 1 calc R U . . .
H87B H 0.1726 0.2934 -0.0504 0.070 Uiso 1 1 calc R U . . .
C88 C 0.0613(3) 0.25094(16) 0.01683(11) 0.0747(7) Uani 1 1 d . . . . .
H88A H 0.1335 0.2234 0.0326 0.112 Uiso 1 1 calc R U . . .
H88B H 0.0159 0.2167 -0.0019 0.112 Uiso 1 1 calc R U . . .
H88C H 0.0003 0.2712 0.0448 0.112 Uiso 1 1 calc R U . . .
C89 C 0.2472(2) 0.42860(14) -0.04471(8) 0.0586(6) Uani 1 1 d . . . . .
H89A H 0.2998 0.3987 -0.0707 0.070 Uiso 1 1 calc R U . . .
H89B H 0.1741 0.4534 -0.0622 0.070 Uiso 1 1 calc R U . . .
C90 C 0.3312(3) 0.48896(17) -0.03057(11) 0.0853(9) Uani 1 1 d . . . . .
H90A H 0.2777 0.5232 -0.0084 0.128 Uiso 1 1 calc R U . . .
H90B H 0.3694 0.5174 -0.0630 0.128 Uiso 1 1 calc R U . . .
H90C H 0.4010 0.4655 -0.0112 0.128 Uiso 1 1 calc R U . . .
C91A C 0.5536(4) 0.12434(19) 0.03579(15) 0.0697(11) Uani 0.674(4) 1 d D . P C 5
H91A H 0.6287 0.0899 0.0263 0.084 Uiso 0.674(4) 1 calc R U P C 5
H91B H 0.5256 0.1131 0.0740 0.084 Uiso 0.674(4) 1 calc R U P C 5
C92A C 0.4435(5) 0.1067(2) 0.0057(2) 0.0902(13) Uani 0.674(4) 1 d D . P C 5
H92A H 0.3635 0.1336 0.0192 0.135 Uiso 0.674(4) 1 calc R U P C 5
H92B H 0.4299 0.0524 0.0103 0.135 Uiso 0.674(4) 1 calc R U P C 5
H92C H 0.4654 0.1227 -0.0319 0.135 Uiso 0.674(4) 1 calc R U P C 5
C91B C 0.5521(8) 0.1342(3) 0.0065(2) 0.0697(11) Uani 0.326(4) 1 d D . P C 6
H91C H 0.5063 0.1490 -0.0250 0.084 Uiso 0.326(4) 1 calc R U P C 6
H91D H 0.6289 0.1021 -0.0049 0.084 Uiso 0.326(4) 1 calc R U P C 6
C92B C 0.4619(9) 0.0877(4) 0.0464(4) 0.0902(13) Uani 0.326(4) 1 d D . P C 6
H92D H 0.5005 0.0786 0.0797 0.135 Uiso 0.326(4) 1 calc R U P C 6
H92E H 0.4490 0.0393 0.0328 0.135 Uiso 0.326(4) 1 calc R U P C 6
H92F H 0.3777 0.1148 0.0525 0.135 Uiso 0.326(4) 1 calc R U P C 6
C93A C 0.6692(8) 0.2286(4) -0.02929(15) 0.0777(13) Uani 0.765(13) 1 d D . P C 7
H93A H 0.7476 0.1950 -0.0350 0.093 Uiso 0.765(13) 1 calc R U P C 7
H93B H 0.6095 0.2181 -0.0550 0.093 Uiso 0.765(13) 1 calc R U P C 7
C94A C 0.7102(5) 0.3100(3) -0.0410(3) 0.0919(19) Uani 0.765(13) 1 d D . P C 7
H94A H 0.7648 0.3223 -0.0144 0.138 Uiso 0.765(13) 1 calc R U P C 7
H94B H 0.6325 0.3437 -0.0400 0.138 Uiso 0.765(13) 1 calc R U P C 7
H94C H 0.7598 0.3165 -0.0762 0.138 Uiso 0.765(13) 1 calc R U P C 7
C93B C 0.685(3) 0.2441(10) -0.0221(6) 0.0777(13) Uani 0.235(13) 1 d D . P C 8
H93C H 0.7614 0.2099 -0.0306 0.093 Uiso 0.235(13) 1 calc R U P C 8
H93D H 0.6333 0.2481 -0.0525 0.093 Uiso 0.235(13) 1 calc R U P C 8
C94B C 0.7344(15) 0.3219(7) -0.0165(8) 0.0919(19) Uani 0.235(13) 1 d D . P C 8
H94D H 0.6600 0.3567 -0.0087 0.138 Uiso 0.235(13) 1 calc R U P C 8
H94E H 0.7854 0.3405 -0.0496 0.138 Uiso 0.235(13) 1 calc R U P C 8
H94F H 0.7895 0.3185 0.0123 0.138 Uiso 0.235(13) 1 calc R U P C 8
C95 C 0.6912(2) 0.30295(16) 0.13886(11) 0.0679(7) Uani 1 1 d . . . . .
H95A H 0.6442 0.3228 0.1704 0.102 Uiso 1 1 calc R U . . .
H95B H 0.7086 0.3443 0.1112 0.102 Uiso 1 1 calc R U . . .
H95C H 0.7738 0.2787 0.1476 0.102 Uiso 1 1 calc R U . . .
C96 C 0.5747(2) 0.18255(12) 0.16316(8) 0.0538(5) Uani 1 1 d . . . . .
H96A H 0.6554 0.1578 0.1737 0.081 Uiso 1 1 calc R U . . .
H96B H 0.5217 0.1455 0.1505 0.081 Uiso 1 1 calc R U . . .
H96C H 0.5257 0.2043 0.1936 0.081 Uiso 1 1 calc R U . . .
C97A C -0.1589(11) -0.0608(7) 0.1067(4) 0.179(4) Uani 0.621(8) 1 d D U P D 7
H97A H -0.2353 -0.0365 0.0921 0.268 Uiso 0.621(8) 1 calc R U P D 7
H97B H -0.1463 -0.0387 0.1393 0.268 Uiso 0.621(8) 1 calc R U P D 7
H97C H -0.1725 -0.1149 0.1146 0.268 Uiso 0.621(8) 1 calc R U P D 7
C98A C -0.0395(10) -0.0489(7) 0.0670(4) 0.191(4) Uani 0.621(8) 1 d D U P D 7
H98A H 0.0249 -0.0211 0.0825 0.230 Uiso 0.621(8) 1 calc R U P D 7
H98B H 0.0009 -0.0985 0.0589 0.230 Uiso 0.621(8) 1 calc R U P D 7
C99A C -0.0733(10) -0.0055(7) 0.0166(4) 0.184(4) Uani 0.621(8) 1 d D U P D 7
H99A H -0.1174 0.0436 0.0234 0.221 Uiso 0.621(8) 1 calc R U P D 7
H99B H -0.1290 -0.0346 -0.0024 0.221 Uiso 0.621(8) 1 calc R U P D 7
C97B C -0.1874(18) -0.0212(11) 0.1036(7) 0.179(4) Uani 0.379(8) 1 d D U P D 8
H97D H -0.1383 -0.0444 0.1318 0.268 Uiso 0.379(8) 1 calc R U P D 8
H97E H -0.2788 -0.0352 0.1111 0.268 Uiso 0.379(8) 1 calc R U P D 8
H97F H -0.1824 0.0338 0.1018 0.268 Uiso 0.379(8) 1 calc R U P D 8
C98B C -0.1297(18) -0.0486(10) 0.0512(7) 0.191(4) Uani 0.379(8) 1 d D U P D 8
H98C H -0.0958 -0.1013 0.0567 0.230 Uiso 0.379(8) 1 calc R U P D 8
H98D H -0.1975 -0.0471 0.0268 0.230 Uiso 0.379(8) 1 calc R U P D 8
C99B C -0.0201(19) 0.0024(12) 0.0279(6) 0.184(4) Uani 0.379(8) 1 d D U P D 8
H99C H -0.0481 0.0551 0.0334 0.221 Uiso 0.379(8) 1 calc R U P D 8
H99D H 0.0562 -0.0103 0.0475 0.221 Uiso 0.379(8) 1 calc R U P D 8


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C1 1.9953(13) . ?
Ge1 Ge2 2.4283(2) . ?
Ge1 Ge4 2.4606(2) . ?
Ge2 C25 2.0241(14) . ?
Ge2 Ge3 2.4014(2) . ?
Ge3 C49 1.9825(14) . ?
Ge3 Ge4 2.4294(2) . ?
Ge4 C73 2.0368(15) . ?
C1 C12 1.4149(19) . ?
C1 C2 1.4160(19) . ?
C2 C6 1.3988(19) . ?
C2 C3 1.5362(19) . ?
C3 C13 1.533(2) . ?
C3 C14 1.534(2) . ?
C3 C4 1.551(2) . ?
C4 C5 1.547(2) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.5159(19) . ?
C5 C17 1.543(2) . ?
C5 C15 1.548(2) . ?
C6 C7 1.384(2) . ?
C7 C8 1.385(2) . ?
C7 H7 0.9500 . ?
C8 C12 1.3975(19) . ?
C8 C9 1.518(2) . ?
C9 C10 1.541(2) . ?
C9 C19 1.543(2) . ?
C9 C21 1.546(2) . ?
C10 C11 1.550(2) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C24 1.529(2) . ?
C11 C23 1.536(2) . ?
C11 C12 1.5374(19) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.527(2) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.521(3) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.520(3) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.531(2) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C26 1.416(2) . ?
C25 C36 1.420(2) . ?
C26 C30 1.403(2) . ?
C26 C27 1.542(2) . ?
C27 C37 1.530(3) . ?
C27 C38 1.542(3) . ?
C27 C28 1.548(3) . ?
C28 C29 1.530(3) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.515(2) . ?
C29 C41B 1.539(3) . ?
C29 C41A 1.541(3) . ?
C29 C39 1.547(3) . ?
C30 C31 1.384(2) . ?
C31 C32 1.384(2) . ?
C31 H31 0.9500 . ?
C32 C36 1.396(2) . ?
C32 C33 1.512(2) . ?
C33 C34 1.546(2) . ?
C33 C45 1.547(2) . ?
C33 C43 1.552(2) . ?
C34 C35 1.555(2) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C48 1.535(2) . ?
C35 C47 1.537(2) . ?
C35 C36 1.539(2) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.520(3) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41A C42A 1.522(6) . ?
C41A H41A 0.9900 . ?
C41A H41B 0.9900 . ?
C42A H42A 0.9800 . ?
C42A H42B 0.9800 . ?
C42A H42C 0.9800 . ?
C41B C42B 1.518(6) . ?
C41B H41C 0.9900 . ?
C41B H41D 0.9900 . ?
C42B H42D 0.9800 . ?
C42B H42E 0.9800 . ?
C42B H42F 0.9800 . ?
C43 C44 1.510(3) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C46 1.521(3) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 C60 1.408(2) . ?
C49 C50 1.415(2) . ?
C50 C54 1.400(2) . ?
C50 C51 1.531(2) . ?
C51 C61 1.533(2) . ?
C51 C62 1.540(3) . ?
C51 C52 1.559(2) . ?
C52 C53 1.538(2) . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C53 C54 1.519(2) . ?
C53 C65 1.535(3) . ?
C53 C63 1.546(3) . ?
C54 C55 1.378(2) . ?
C55 C56 1.385(2) . ?
C55 H55 0.9500 . ?
C56 C60 1.401(2) . ?
C56 C57 1.517(2) . ?
C57 C67 1.541(3) . ?
C57 C69A 1.546(3) . ?
C57 C69B 1.546(4) . ?
C57 C58 1.547(3) . ?
C58 C59 1.546(2) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C59 C72 1.531(3) . ?
C59 C71 1.533(3) . ?
C59 C60 1.534(2) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 C64 1.513(4) . ?
C63 H63A 0.9900 . ?
C63 H63B 0.9900 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 C66 1.484(4) . ?
C65 H65A 0.9900 . ?
C65 H65B 0.9900 . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C67 C68 1.513(4) . ?
C67 H67A 0.9900 . ?
C67 H67B 0.9900 . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69A C70A 1.531(7) . ?
C69A H69A 0.9900 . ?
C69A H69B 0.9900 . ?
C70A H70A 0.9800 . ?
C70A H70B 0.9800 . ?
C70A H70C 0.9800 . ?
C69B C70B 1.531(7) . ?
C69B H69C 0.9900 . ?
C69B H69D 0.9900 . ?
C70B H70D 0.9800 . ?
C70B H70E 0.9800 . ?
C70B H70F 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 C74 1.421(2) . ?
C73 C84 1.422(2) . ?
C74 C78 1.398(2) . ?
C74 C75 1.539(2) . ?
C75 C86 1.529(2) . ?
C75 C85 1.537(2) . ?
C75 C76 1.562(2) . ?
C76 C77 1.547(3) . ?
C76 H76A 0.9900 . ?
C76 H76B 0.9900 . ?
C77 C78 1.508(2) . ?
C77 C89 1.545(3) . ?
C77 C87 1.551(3) . ?
C78 C79 1.383(2) . ?
C79 C80 1.377(3) . ?
C79 H79 0.9500 . ?
C80 C84 1.404(2) . ?
C80 C81 1.525(3) . ?
C81 C82 1.526(3) . ?
C81 C93B 1.527(4) . ?
C81 C93A 1.527(3) . ?
C81 C91A 1.591(4) . ?
C81 C91B 1.592(4) . ?
C82 C83 1.552(3) . ?
C82 H82A 0.9900 . ?
C82 H82B 0.9900 . ?
C83 C96 1.528(3) . ?
C83 C95 1.535(3) . ?
C83 C84 1.544(2) . ?
C85 H85A 0.9800 . ?
C85 H85B 0.9800 . ?
C85 H85C 0.9800 . ?
C86 H86A 0.9800 . ?
C86 H86B 0.9800 . ?
C86 H86C 0.9800 . ?
C87 C88 1.513(4) . ?
C87 H87A 0.9900 . ?
C87 H87B 0.9900 . ?
C88 H88A 0.9800 . ?
C88 H88B 0.9800 . ?
C88 H88C 0.9800 . ?
C89 C90 1.510(4) . ?
C89 H89A 0.9900 . ?
C89 H89B 0.9900 . ?
C90 H90A 0.9800 . ?
C90 H90B 0.9800 . ?
C90 H90C 0.9800 . ?
C91A C92A 1.508(5) . ?
C91A H91A 0.9900 . ?
C91A H91B 0.9900 . ?
C92A H92A 0.9800 . ?
C92A H92B 0.9800 . ?
C92A H92C 0.9800 . ?
C91B C92B 1.511(5) . ?
C91B H91C 0.9900 . ?
C91B H91D 0.9900 . ?
C92B H92D 0.9800 . ?
C92B H92E 0.9800 . ?
C92B H92F 0.9800 . ?
C93A C94A 1.525(5) . ?
C93A H93A 0.9900 . ?
C93A H93B 0.9900 . ?
C94A H94A 0.9800 . ?
C94A H94B 0.9800 . ?
C94A H94C 0.9800 . ?
C93B C94B 1.524(6) . ?
C93B H93C 0.9900 . ?
C93B H93D 0.9900 . ?
C94B H94D 0.9800 . ?
C94B H94E 0.9800 . ?
C94B H94F 0.9800 . ?
C95 H95A 0.9800 . ?
C95 H95B 0.9800 . ?
C95 H95C 0.9800 . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
C97A C98A 1.512(4) . ?
C97A H97A 0.9800 . ?
C97A H97B 0.9800 . ?
C97A H97C 0.9800 . ?
C98A C99A 1.509(4) . ?
C98A H98A 0.9900 . ?
C98A H98B 0.9900 . ?
C99A C99A 1.66(2) 2 ?
C99A H99A 0.9900 . ?
C99A H99B 0.9900 . ?
C97B C98B 1.518(4) . ?
C97B H97D 0.9800 . ?
C97B H97E 0.9800 . ?
C97B H97F 0.9800 . ?
C98B C99B 1.516(4) . ?
C98B H98C 0.9900 . ?
C98B H98D 0.9900 . ?
C99B C99B 1.45(3) 2 ?
C99B H99C 0.9900 . ?
C99B H99D 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ge1 Ge2 128.22(4) . . ?
C1 Ge1 Ge4 129.42(4) . . ?
Ge2 Ge1 Ge4 102.354(8) . . ?
C25 Ge2 Ge3 123.54(4) . . ?
C25 Ge2 Ge1 133.17(4) . . ?
Ge3 Ge2 Ge1 77.329(7) . . ?
C49 Ge3 Ge2 127.10(4) . . ?
C49 Ge3 Ge4 128.82(4) . . ?
Ge2 Ge3 Ge4 104.083(8) . . ?
C73 Ge4 Ge3 120.18(4) . . ?
C73 Ge4 Ge1 131.33(5) . . ?
Ge3 Ge4 Ge1 76.202(7) . . ?
C12 C1 C2 117.00(12) . . ?
C12 C1 Ge1 121.37(10) . . ?
C2 C1 Ge1 121.63(10) . . ?
C6 C2 C1 120.75(12) . . ?
C6 C2 C3 109.38(12) . . ?
C1 C2 C3 129.82(12) . . ?
C13 C3 C14 110.31(13) . . ?
C13 C3 C2 113.88(12) . . ?
C14 C3 C2 110.61(12) . . ?
C13 C3 C4 108.93(12) . . ?
C14 C3 C4 109.98(12) . . ?
C2 C3 C4 102.85(11) . . ?
C5 C4 C3 108.98(11) . . ?
C5 C4 H4A 109.9 . . ?
C3 C4 H4A 109.9 . . ?
C5 C4 H4B 109.9 . . ?
C3 C4 H4B 109.9 . . ?
H4A C4 H4B 108.3 . . ?
C6 C5 C17 111.22(13) . . ?
C6 C5 C4 101.77(11) . . ?
C17 C5 C4 112.43(13) . . ?
C6 C5 C15 108.94(12) . . ?
C17 C5 C15 109.62(12) . . ?
C4 C5 C15 112.62(13) . . ?
C7 C6 C2 121.33(13) . . ?
C7 C6 C5 124.88(13) . . ?
C2 C6 C5 113.77(12) . . ?
C6 C7 C8 118.68(13) . . ?
C6 C7 H7 120.7 . . ?
C8 C7 H7 120.7 . . ?
C7 C8 C12 121.24(13) . . ?
C7 C8 C9 124.94(13) . . ?
C12 C8 C9 113.81(12) . . ?
C8 C9 C10 101.72(11) . . ?
C8 C9 C19 111.07(13) . . ?
C10 C9 C19 111.75(13) . . ?
C8 C9 C21 109.31(12) . . ?
C10 C9 C21 112.65(14) . . ?
C19 C9 C21 110.06(13) . . ?
C9 C10 C11 109.22(12) . . ?
C9 C10 H10A 109.8 . . ?
C11 C10 H10A 109.8 . . ?
C9 C10 H10B 109.8 . . ?
C11 C10 H10B 109.8 . . ?
H10A C10 H10B 108.3 . . ?
C24 C11 C23 109.94(13) . . ?
C24 C11 C12 114.23(12) . . ?
C23 C11 C12 110.46(12) . . ?
C24 C11 C10 109.10(13) . . ?
C23 C11 C10 110.11(13) . . ?
C12 C11 C10 102.76(11) . . ?
C8 C12 C1 120.92(12) . . ?
C8 C12 C11 109.23(12) . . ?
C1 C12 C11 129.84(12) . . ?
C3 C13 H13A 109.5 . . ?
C3 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C3 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C3 C14 H14A 109.5 . . ?
C3 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C3 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 C5 115.37(14) . . ?
C16 C15 H15A 108.4 . . ?
C5 C15 H15A 108.4 . . ?
C16 C15 H15B 108.4 . . ?
C5 C15 H15B 108.4 . . ?
H15A C15 H15B 107.5 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C5 115.50(15) . . ?
C18 C17 H17A 108.4 . . ?
C5 C17 H17A 108.4 . . ?
C18 C17 H17B 108.4 . . ?
C5 C17 H17B 108.4 . . ?
H17A C17 H17B 107.5 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 C9 115.56(15) . . ?
C20 C19 H19A 108.4 . . ?
C9 C19 H19A 108.4 . . ?
C20 C19 H19B 108.4 . . ?
C9 C19 H19B 108.4 . . ?
H19A C19 H19B 107.5 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 C9 115.21(14) . . ?
C22 C21 H21A 108.5 . . ?
C9 C21 H21A 108.5 . . ?
C22 C21 H21B 108.5 . . ?
C9 C21 H21B 108.5 . . ?
H21A C21 H21B 107.5 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C11 C23 H23A 109.5 . . ?
C11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C11 C24 H24A 109.5 . . ?
C11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 C36 116.88(13) . . ?
C26 C25 Ge2 115.28(10) . . ?
C36 C25 Ge2 127.84(11) . . ?
C30 C26 C25 120.89(14) . . ?
C30 C26 C27 109.02(13) . . ?
C25 C26 C27 130.09(14) . . ?
C37 C27 C26 112.17(15) . . ?
C37 C27 C38 109.80(17) . . ?
C26 C27 C38 113.07(16) . . ?
C37 C27 C28 110.38(17) . . ?
C26 C27 C28 102.91(13) . . ?
C38 C27 C28 108.25(17) . . ?
C29 C28 C27 109.59(14) . . ?
C29 C28 H28A 109.8 . . ?
C27 C28 H28A 109.8 . . ?
C29 C28 H28B 109.8 . . ?
C27 C28 H28B 109.8 . . ?
H28A C28 H28B 108.2 . . ?
C30 C29 C28 101.74(14) . . ?
C30 C29 C41B 113.4(5) . . ?
C28 C29 C41B 122.9(5) . . ?
C30 C29 C41A 108.4(2) . . ?
C28 C29 C41A 109.0(2) . . ?
C30 C29 C39 112.53(15) . . ?
C28 C29 C39 111.91(17) . . ?
C41B C29 C39 94.7(3) . . ?
C41A C29 C39 112.62(19) . . ?
C31 C30 C26 120.90(14) . . ?
C31 C30 C29 125.44(15) . . ?
C26 C30 C29 113.66(14) . . ?
C32 C31 C30 119.09(14) . . ?
C32 C31 H31 120.5 . . ?
C30 C31 H31 120.5 . . ?
C31 C32 C36 121.24(14) . . ?
C31 C32 C33 124.51(13) . . ?
C36 C32 C33 114.21(13) . . ?
C32 C33 C34 102.57(12) . . ?
C32 C33 C45 111.92(14) . . ?
C34 C33 C45 112.42(14) . . ?
C32 C33 C43 110.24(13) . . ?
C34 C33 C43 112.39(14) . . ?
C45 C33 C43 107.35(13) . . ?
C33 C34 C35 109.75(12) . . ?
C33 C34 H34A 109.7 . . ?
C35 C34 H34A 109.7 . . ?
C33 C34 H34B 109.7 . . ?
C35 C34 H34B 109.7 . . ?
H34A C34 H34B 108.2 . . ?
C48 C35 C47 110.42(13) . . ?
C48 C35 C36 111.61(13) . . ?
C47 C35 C36 111.74(12) . . ?
C48 C35 C34 109.55(13) . . ?
C47 C35 C34 109.58(13) . . ?
C36 C35 C34 103.73(12) . . ?
C32 C36 C25 120.83(13) . . ?
C32 C36 C35 109.69(12) . . ?
C25 C36 C35 129.47(13) . . ?
C27 C37 H37A 109.5 . . ?
C27 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C27 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C27 C38 H38A 109.5 . . ?
C27 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C27 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 C29 116.07(18) . . ?
C40 C39 H39A 108.3 . . ?
C29 C39 H39A 108.3 . . ?
C40 C39 H39B 108.3 . . ?
C29 C39 H39B 108.3 . . ?
H39A C39 H39B 107.4 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C42A C41A C29 113.9(3) . . ?
C42A C41A H41A 108.8 . . ?
C29 C41A H41A 108.8 . . ?
C42A C41A H41B 108.8 . . ?
C29 C41A H41B 108.8 . . ?
H41A C41A H41B 107.7 . . ?
C41A C42A H42A 109.5 . . ?
C41A C42A H42B 109.5 . . ?
H42A C42A H42B 109.5 . . ?
C41A C42A H42C 109.5 . . ?
H42A C42A H42C 109.5 . . ?
H42B C42A H42C 109.5 . . ?
C42B C41B C29 114.5(4) . . ?
C42B C41B H41C 108.6 . . ?
C29 C41B H41C 108.6 . . ?
C42B C41B H41D 108.6 . . ?
C29 C41B H41D 108.6 . . ?
H41C C41B H41D 107.6 . . ?
C41B C42B H42D 109.5 . . ?
C41B C42B H42E 109.5 . . ?
H42D C42B H42E 109.5 . . ?
C41B C42B H42F 109.5 . . ?
H42D C42B H42F 109.5 . . ?
H42E C42B H42F 109.5 . . ?
C44 C43 C33 115.43(15) . . ?
C44 C43 H43A 108.4 . . ?
C33 C43 H43A 108.4 . . ?
C44 C43 H43B 108.4 . . ?
C33 C43 H43B 108.4 . . ?
H43A C43 H43B 107.5 . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C46 C45 C33 115.65(15) . . ?
C46 C45 H45A 108.4 . . ?
C33 C45 H45A 108.4 . . ?
C46 C45 H45B 108.4 . . ?
C33 C45 H45B 108.4 . . ?
H45A C45 H45B 107.4 . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C35 C47 H47A 109.5 . . ?
C35 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C35 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C35 C48 H48A 109.5 . . ?
C35 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C35 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C60 C49 C50 117.81(13) . . ?
C60 C49 Ge3 120.95(11) . . ?
C50 C49 Ge3 121.24(11) . . ?
C54 C50 C49 120.18(14) . . ?
C54 C50 C51 110.46(13) . . ?
C49 C50 C51 129.33(13) . . ?
C50 C51 C61 113.86(14) . . ?
C50 C51 C62 110.09(14) . . ?
C61 C51 C62 109.17(15) . . ?
C50 C51 C52 103.36(13) . . ?
C61 C51 C52 110.16(14) . . ?
C62 C51 C52 110.06(14) . . ?
C53 C52 C51 109.63(14) . . ?
C53 C52 H52A 109.7 . . ?
C51 C52 H52A 109.7 . . ?
C53 C52 H52B 109.7 . . ?
C51 C52 H52B 109.7 . . ?
H52A C52 H52B 108.2 . . ?
C54 C53 C65 111.81(17) . . ?
C54 C53 C52 103.14(13) . . ?
C65 C53 C52 113.26(18) . . ?
C54 C53 C63 109.47(17) . . ?
C65 C53 C63 107.61(18) . . ?
C52 C53 C63 111.54(17) . . ?
C55 C54 C50 121.35(15) . . ?
C55 C54 C53 125.64(15) . . ?
C50 C54 C53 113.00(14) . . ?
C54 C55 C56 119.17(15) . . ?
C54 C55 H55 120.4 . . ?
C56 C55 H55 120.4 . . ?
C55 C56 C60 120.84(15) . . ?
C55 C56 C57 125.96(15) . . ?
C60 C56 C57 113.20(14) . . ?
C56 C57 C67 111.18(16) . . ?
C56 C57 C69A 109.0(3) . . ?
C67 C57 C69A 113.2(2) . . ?
C56 C57 C69B 112.7(7) . . ?
C67 C57 C69B 96.8(3) . . ?
C56 C57 C58 102.10(13) . . ?
C67 C57 C58 111.85(17) . . ?
C69A C57 C58 109.0(3) . . ?
C69B C57 C58 122.4(6) . . ?
C59 C58 C57 109.33(14) . . ?
C59 C58 H58A 109.8 . . ?
C57 C58 H58A 109.8 . . ?
C59 C58 H58B 109.8 . . ?
C57 C58 H58B 109.8 . . ?
H58A C58 H58B 108.3 . . ?
C72 C59 C71 109.34(15) . . ?
C72 C59 C60 114.52(14) . . ?
C71 C59 C60 109.89(14) . . ?
C72 C59 C58 109.37(15) . . ?
C71 C59 C58 110.70(15) . . ?
C60 C59 C58 102.88(13) . . ?
C56 C60 C49 120.62(14) . . ?
C56 C60 C59 109.85(13) . . ?
C49 C60 C59 129.49(13) . . ?
C51 C61 H61A 109.5 . . ?
C51 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C51 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C51 C62 H62A 109.5 . . ?
C51 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C51 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C64 C63 C53 116.03(18) . . ?
C64 C63 H63A 108.3 . . ?
C53 C63 H63A 108.3 . . ?
C64 C63 H63B 108.3 . . ?
C53 C63 H63B 108.3 . . ?
H63A C63 H63B 107.4 . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C66 C65 C53 117.28(19) . . ?
C66 C65 H65A 108.0 . . ?
C53 C65 H65A 108.0 . . ?
C66 C65 H65B 108.0 . . ?
C53 C65 H65B 108.0 . . ?
H65A C65 H65B 107.2 . . ?
C65 C66 H66A 109.5 . . ?
C65 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C65 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
C68 C67 C57 115.73(18) . . ?
C68 C67 H67A 108.3 . . ?
C57 C67 H67A 108.3 . . ?
C68 C67 H67B 108.3 . . ?
C57 C67 H67B 108.3 . . ?
H67A C67 H67B 107.4 . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C70A C69A C57 115.2(4) . . ?
C70A C69A H69A 108.5 . . ?
C57 C69A H69A 108.5 . . ?
C70A C69A H69B 108.5 . . ?
C57 C69A H69B 108.5 . . ?
H69A C69A H69B 107.5 . . ?
C69A C70A H70A 109.5 . . ?
C69A C70A H70B 109.5 . . ?
H70A C70A H70B 109.5 . . ?
C69A C70A H70C 109.5 . . ?
H70A C70A H70C 109.5 . . ?
H70B C70A H70C 109.5 . . ?
C70B C69B C57 115.2(5) . . ?
C70B C69B H69C 108.5 . . ?
C57 C69B H69C 108.5 . . ?
C70B C69B H69D 108.5 . . ?
C57 C69B H69D 108.5 . . ?
H69C C69B H69D 107.5 . . ?
C69B C70B H70D 109.5 . . ?
C69B C70B H70E 109.5 . . ?
H70D C70B H70E 109.5 . . ?
C69B C70B H70F 109.5 . . ?
H70D C70B H70F 109.5 . . ?
H70E C70B H70F 109.5 . . ?
C59 C71 H71A 109.5 . . ?
C59 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C59 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C59 C72 H72A 109.5 . . ?
C59 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C59 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C74 C73 C84 116.83(14) . . ?
C74 C73 Ge4 128.80(11) . . ?
C84 C73 Ge4 114.35(11) . . ?
C78 C74 C73 120.89(14) . . ?
C78 C74 C75 109.60(14) . . ?
C73 C74 C75 129.51(14) . . ?
C86 C75 C85 110.84(13) . . ?
C86 C75 C74 111.10(14) . . ?
C85 C75 C74 112.00(14) . . ?
C86 C75 C76 109.43(14) . . ?
C85 C75 C76 109.45(15) . . ?
C74 C75 C76 103.76(13) . . ?
C77 C76 C75 109.41(14) . . ?
C77 C76 H76A 109.8 . . ?
C75 C76 H76A 109.8 . . ?
C77 C76 H76B 109.8 . . ?
C75 C76 H76B 109.8 . . ?
H76A C76 H76B 108.2 . . ?
C78 C77 C89 111.35(16) . . ?
C78 C77 C76 102.85(13) . . ?
C89 C77 C76 111.68(17) . . ?
C78 C77 C87 111.56(17) . . ?
C89 C77 C87 106.84(16) . . ?
C76 C77 C87 112.66(16) . . ?
C79 C78 C74 121.23(16) . . ?
C79 C78 C77 124.43(15) . . ?
C74 C78 C77 114.34(14) . . ?
C80 C79 C78 118.99(16) . . ?
C80 C79 H79 120.5 . . ?
C78 C79 H79 120.5 . . ?
C79 C80 C84 121.50(16) . . ?
C79 C80 C81 125.31(16) . . ?
C84 C80 C81 113.18(16) . . ?
C80 C81 C82 101.58(16) . . ?
C80 C81 C93B 109.8(11) . . ?
C82 C81 C93B 103.4(11) . . ?
C80 C81 C93A 113.9(3) . . ?
C82 C81 C93A 115.3(4) . . ?
C80 C81 C91A 109.1(2) . . ?
C82 C81 C91A 102.3(2) . . ?
C80 C81 C91B 111.5(4) . . ?
C82 C81 C91B 126.2(4) . . ?
C81 C82 C83 110.29(16) . . ?
C81 C82 H82A 109.6 . . ?
C83 C82 H82A 109.6 . . ?
C81 C82 H82B 109.6 . . ?
C83 C82 H82B 109.6 . . ?
H82A C82 H82B 108.1 . . ?
C96 C83 C95 109.50(18) . . ?
C96 C83 C84 112.82(16) . . ?
C95 C83 C84 113.28(17) . . ?
C96 C83 C82 110.05(18) . . ?
C95 C83 C82 108.36(18) . . ?
C84 C83 C82 102.54(15) . . ?
C80 C84 C73 120.41(15) . . ?
C80 C84 C83 109.59(14) . . ?
C73 C84 C83 130.00(15) . . ?
C75 C85 H85A 109.5 . . ?
C75 C85 H85B 109.5 . . ?
H85A C85 H85B 109.5 . . ?
C75 C85 H85C 109.5 . . ?
H85A C85 H85C 109.5 . . ?
H85B C85 H85C 109.5 . . ?
C75 C86 H86A 109.5 . . ?
C75 C86 H86B 109.5 . . ?
H86A C86 H86B 109.5 . . ?
C75 C86 H86C 109.5 . . ?
H86A C86 H86C 109.5 . . ?
H86B C86 H86C 109.5 . . ?
C88 C87 C77 115.68(18) . . ?
C88 C87 H87A 108.4 . . ?
C77 C87 H87A 108.4 . . ?
C88 C87 H87B 108.4 . . ?
C77 C87 H87B 108.4 . . ?
H87A C87 H87B 107.4 . . ?
C87 C88 H88A 109.5 . . ?
C87 C88 H88B 109.5 . . ?
H88A C88 H88B 109.5 . . ?
C87 C88 H88C 109.5 . . ?
H88A C88 H88C 109.5 . . ?
H88B C88 H88C 109.5 . . ?
C90 C89 C77 115.63(18) . . ?
C90 C89 H89A 108.4 . . ?
C77 C89 H89A 108.4 . . ?
C90 C89 H89B 108.4 . . ?
C77 C89 H89B 108.4 . . ?
H89A C89 H89B 107.4 . . ?
C89 C90 H90A 109.5 . . ?
C89 C90 H90B 109.5 . . ?
H90A C90 H90B 109.5 . . ?
C89 C90 H90C 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
C92A C91A C81 116.2(3) . . ?
C92A C91A H91A 108.2 . . ?
C81 C91A H91A 108.2 . . ?
C92A C91A H91B 108.2 . . ?
C81 C91A H91B 108.2 . . ?
H91A C91A H91B 107.4 . . ?
C91A C92A H92A 109.5 . . ?
C91A C92A H92B 109.5 . . ?
H92A C92A H92B 109.5 . . ?
C91A C92A H92C 109.5 . . ?
H92A C92A H92C 109.5 . . ?
H92B C92A H92C 109.5 . . ?
C92B C91B C81 115.7(3) . . ?
C92B C91B H91C 108.4 . . ?
C81 C91B H91C 108.4 . . ?
C92B C91B H91D 108.4 . . ?
C81 C91B H91D 108.4 . . ?
H91C C91B H91D 107.4 . . ?
C91B C92B H92D 109.5 . . ?
C91B C92B H92E 109.5 . . ?
H92D C92B H92E 109.5 . . ?
C91B C92B H92F 109.5 . . ?
H92D C92B H92F 109.5 . . ?
H92E C92B H92F 109.5 . . ?
C94A C93A C81 115.2(3) . . ?
C94A C93A H93A 108.5 . . ?
C81 C93A H93A 108.5 . . ?
C94A C93A H93B 108.5 . . ?
C81 C93A H93B 108.5 . . ?
H93A C93A H93B 107.5 . . ?
C93A C94A H94A 109.5 . . ?
C93A C94A H94B 109.5 . . ?
H94A C94A H94B 109.5 . . ?
C93A C94A H94C 109.5 . . ?
H94A C94A H94C 109.5 . . ?
H94B C94A H94C 109.5 . . ?
C94B C93B C81 115.3(3) . . ?
C94B C93B H93C 108.4 . . ?
C81 C93B H93C 108.4 . . ?
C94B C93B H93D 108.4 . . ?
C81 C93B H93D 108.4 . . ?
H93C C93B H93D 107.5 . . ?
C93B C94B H94D 109.5 . . ?
C93B C94B H94E 109.5 . . ?
H94D C94B H94E 109.5 . . ?
C93B C94B H94F 109.5 . . ?
H94D C94B H94F 109.5 . . ?
H94E C94B H94F 109.5 . . ?
C83 C95 H95A 109.5 . . ?
C83 C95 H95B 109.5 . . ?
H95A C95 H95B 109.5 . . ?
C83 C95 H95C 109.5 . . ?
H95A C95 H95C 109.5 . . ?
H95B C95 H95C 109.5 . . ?
C83 C96 H96A 109.5 . . ?
C83 C96 H96B 109.5 . . ?
H96A C96 H96B 109.5 . . ?
C83 C96 H96C 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
C98A C97A H97A 109.5 . . ?
C98A C97A H97B 109.5 . . ?
H97A C97A H97B 109.5 . . ?
C98A C97A H97C 109.5 . . ?
H97A C97A H97C 109.5 . . ?
H97B C97A H97C 109.5 . . ?
C99A C98A C97A 111.5(7) . . ?
C99A C98A H98A 109.3 . . ?
C97A C98A H98A 109.3 . . ?
C99A C98A H98B 109.3 . . ?
C97A C98A H98B 109.3 . . ?
H98A C98A H98B 108.0 . . ?
C98A C99A C99A 101.1(9) . 2 ?
C98A C99A H99A 111.5 . . ?
C99A C99A H99A 111.5 2 . ?
C98A C99A H99B 111.5 . . ?
C99A C99A H99B 111.5 2 . ?
H99A C99A H99B 109.4 . . ?
C98B C97B H97D 109.5 . . ?
C98B C97B H97E 109.5 . . ?
H97D C97B H97E 109.5 . . ?
C98B C97B H97F 109.5 . . ?
H97D C97B H97F 109.5 . . ?
H97E C97B H97F 109.5 . . ?
C99B C98B C97B 108.2(9) . . ?
C99B C98B H98C 110.1 . . ?
C97B C98B H98C 110.1 . . ?
C99B C98B H98D 110.1 . . ?
C97B C98B H98D 110.1 . . ?
H98C C98B H98D 108.4 . . ?
C99B C99B C98B 114.7(19) 2 . ?
C99B C99B H99C 108.6 2 . ?
C98B C99B H99C 108.6 . . ?
C99B C99B H99D 108.6 2 . ?
C98B C99B H99D 108.6 . . ?
H99C C99B H99D 107.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C12 C1 C2 C6 1.7(2) . . . . ?
Ge1 C1 C2 C6 -178.24(10) . . . . ?
C12 C1 C2 C3 -175.58(13) . . . . ?
Ge1 C1 C2 C3 4.5(2) . . . . ?
C6 C2 C3 C13 131.08(14) . . . . ?
C1 C2 C3 C13 -51.4(2) . . . . ?
C6 C2 C3 C14 -104.03(14) . . . . ?
C1 C2 C3 C14 73.50(18) . . . . ?
C6 C2 C3 C4 13.37(15) . . . . ?
C1 C2 C3 C4 -169.09(14) . . . . ?
C13 C3 C4 C5 -139.40(13) . . . . ?
C14 C3 C4 C5 99.60(15) . . . . ?
C2 C3 C4 C5 -18.25(16) . . . . ?
C3 C4 C5 C6 16.05(16) . . . . ?
C3 C4 C5 C17 135.13(13) . . . . ?
C3 C4 C5 C15 -100.44(14) . . . . ?
C1 C2 C6 C7 -2.7(2) . . . . ?
C3 C2 C6 C7 175.05(14) . . . . ?
C1 C2 C6 C5 178.52(12) . . . . ?
C3 C2 C6 C5 -3.69(17) . . . . ?
C17 C5 C6 C7 53.7(2) . . . . ?
C4 C5 C6 C7 173.59(15) . . . . ?
C15 C5 C6 C7 -67.27(19) . . . . ?
C17 C5 C6 C2 -127.66(14) . . . . ?
C4 C5 C6 C2 -7.73(16) . . . . ?
C15 C5 C6 C2 111.41(14) . . . . ?
C2 C6 C7 C8 1.1(2) . . . . ?
C5 C6 C7 C8 179.69(14) . . . . ?
C6 C7 C8 C12 1.5(2) . . . . ?
C6 C7 C8 C9 -177.92(14) . . . . ?
C7 C8 C9 C10 172.35(15) . . . . ?
C12 C8 C9 C10 -7.12(17) . . . . ?
C7 C8 C9 C19 53.3(2) . . . . ?
C12 C8 C9 C19 -126.17(14) . . . . ?
C7 C8 C9 C21 -68.35(19) . . . . ?
C12 C8 C9 C21 112.18(15) . . . . ?
C8 C9 C10 C11 15.79(16) . . . . ?
C19 C9 C10 C11 134.36(14) . . . . ?
C21 C9 C10 C11 -101.12(15) . . . . ?
C9 C10 C11 C24 -139.96(14) . . . . ?
C9 C10 C11 C23 99.31(15) . . . . ?
C9 C10 C11 C12 -18.37(16) . . . . ?
C7 C8 C12 C1 -2.5(2) . . . . ?
C9 C8 C12 C1 176.99(13) . . . . ?
C7 C8 C12 C11 176.13(14) . . . . ?
C9 C8 C12 C11 -4.38(17) . . . . ?
C2 C1 C12 C8 0.8(2) . . . . ?
Ge1 C1 C12 C8 -179.20(10) . . . . ?
C2 C1 C12 C11 -177.47(14) . . . . ?
Ge1 C1 C12 C11 2.5(2) . . . . ?
C24 C11 C12 C8 131.83(14) . . . . ?
C23 C11 C12 C8 -103.64(14) . . . . ?
C10 C11 C12 C8 13.80(16) . . . . ?
C24 C11 C12 C1 -49.7(2) . . . . ?
C23 C11 C12 C1 74.83(19) . . . . ?
C10 C11 C12 C1 -167.73(14) . . . . ?
C6 C5 C15 C16 177.09(14) . . . . ?
C17 C5 C15 C16 55.18(19) . . . . ?
C4 C5 C15 C16 -70.79(18) . . . . ?
C6 C5 C17 C18 49.1(2) . . . . ?
C4 C5 C17 C18 -64.34(19) . . . . ?
C15 C5 C17 C18 169.58(16) . . . . ?
C8 C9 C19 C20 46.3(2) . . . . ?
C10 C9 C19 C20 -66.58(19) . . . . ?
C21 C9 C19 C20 167.47(16) . . . . ?
C8 C9 C21 C22 178.56(15) . . . . ?
C10 C9 C21 C22 -69.1(2) . . . . ?
C19 C9 C21 C22 56.3(2) . . . . ?
C36 C25 C26 C30 -4.4(2) . . . . ?
Ge2 C25 C26 C30 176.14(12) . . . . ?
C36 C25 C26 C27 175.90(16) . . . . ?
Ge2 C25 C26 C27 -3.6(2) . . . . ?
C30 C26 C27 C37 -109.84(17) . . . . ?
C25 C26 C27 C37 69.9(2) . . . . ?
C30 C26 C27 C38 125.33(18) . . . . ?
C25 C26 C27 C38 -54.9(2) . . . . ?
C30 C26 C27 C28 8.8(2) . . . . ?
C25 C26 C27 C28 -171.47(18) . . . . ?
C37 C27 C28 C29 103.3(2) . . . . ?
C26 C27 C28 C29 -16.6(2) . . . . ?
C38 C27 C28 C29 -136.48(19) . . . . ?
C27 C28 C29 C30 17.4(2) . . . . ?
C27 C28 C29 C41B -110.7(5) . . . . ?
C27 C28 C29 C41A -97.0(2) . . . . ?
C27 C28 C29 C39 137.79(18) . . . . ?
C25 C26 C30 C31 3.1(3) . . . . ?
C27 C26 C30 C31 -177.18(16) . . . . ?
C25 C26 C30 C29 -177.63(15) . . . . ?
C27 C26 C30 C29 2.1(2) . . . . ?
C28 C29 C30 C31 167.13(18) . . . . ?
C41B C29 C30 C31 -58.8(4) . . . . ?
C41A C29 C30 C31 -78.0(3) . . . . ?
C39 C29 C30 C31 47.2(3) . . . . ?
C28 C29 C30 C26 -12.1(2) . . . . ?
C41B C29 C30 C26 121.9(4) . . . . ?
C41A C29 C30 C26 102.7(2) . . . . ?
C39 C29 C30 C26 -132.07(17) . . . . ?
C26 C30 C31 C32 0.7(3) . . . . ?
C29 C30 C31 C32 -178.55(17) . . . . ?
C30 C31 C32 C36 -2.9(3) . . . . ?
C30 C31 C32 C33 174.91(16) . . . . ?
C31 C32 C33 C34 179.86(16) . . . . ?
C36 C32 C33 C34 -2.17(18) . . . . ?
C31 C32 C33 C45 59.1(2) . . . . ?
C36 C32 C33 C45 -122.90(15) . . . . ?
C31 C32 C33 C43 -60.3(2) . . . . ?
C36 C32 C33 C43 117.71(15) . . . . ?
C32 C33 C34 C35 1.21(18) . . . . ?
C45 C33 C34 C35 121.58(15) . . . . ?
C43 C33 C34 C35 -117.17(15) . . . . ?
C33 C34 C35 C48 119.26(15) . . . . ?
C33 C34 C35 C47 -119.46(15) . . . . ?
C33 C34 C35 C36 -0.02(18) . . . . ?
C31 C32 C36 C25 1.4(2) . . . . ?
C33 C32 C36 C25 -176.59(14) . . . . ?
C31 C32 C36 C35 -179.67(14) . . . . ?
C33 C32 C36 C35 2.29(19) . . . . ?
C26 C25 C36 C32 2.2(2) . . . . ?
Ge2 C25 C36 C32 -178.42(12) . . . . ?
C26 C25 C36 C35 -176.46(15) . . . . ?
Ge2 C25 C36 C35 2.9(2) . . . . ?
C48 C35 C36 C32 -119.18(14) . . . . ?
C47 C35 C36 C32 116.63(14) . . . . ?
C34 C35 C36 C32 -1.32(17) . . . . ?
C48 C35 C36 C25 59.6(2) . . . . ?
C47 C35 C36 C25 -64.6(2) . . . . ?
C34 C35 C36 C25 177.43(15) . . . . ?
C30 C29 C39 C40 47.6(3) . . . . ?
C28 C29 C39 C40 -66.2(2) . . . . ?
C41B C29 C39 C40 165.4(6) . . . . ?
C41A C29 C39 C40 170.6(3) . . . . ?
C30 C29 C41A C42A -179.1(3) . . . . ?
C28 C29 C41A C42A -69.2(4) . . . . ?
C39 C29 C41A C42A 55.7(4) . . . . ?
C30 C29 C41B C42B -52.6(11) . . . . ?
C28 C29 C41B C42B 70.3(12) . . . . ?
C39 C29 C41B C42B -169.7(9) . . . . ?
C32 C33 C43 C44 -56.8(2) . . . . ?
C34 C33 C43 C44 56.9(2) . . . . ?
C45 C33 C43 C44 -178.94(17) . . . . ?
C32 C33 C45 C46 52.6(2) . . . . ?
C34 C33 C45 C46 -62.2(2) . . . . ?
C43 C33 C45 C46 173.71(16) . . . . ?
C60 C49 C50 C54 1.2(2) . . . . ?
Ge3 C49 C50 C54 -178.58(13) . . . . ?
C60 C49 C50 C51 -176.49(16) . . . . ?
Ge3 C49 C50 C51 3.7(2) . . . . ?
C54 C50 C51 C61 125.90(16) . . . . ?
C49 C50 C51 C61 -56.2(2) . . . . ?
C54 C50 C51 C62 -111.14(16) . . . . ?
C49 C50 C51 C62 66.8(2) . . . . ?
C54 C50 C51 C52 6.39(19) . . . . ?
C49 C50 C51 C52 -175.71(17) . . . . ?
C50 C51 C52 C53 -6.0(2) . . . . ?
C61 C51 C52 C53 -128.02(17) . . . . ?
C62 C51 C52 C53 111.55(18) . . . . ?
C51 C52 C53 C54 3.6(2) . . . . ?
C51 C52 C53 C65 -117.47(18) . . . . ?
C51 C52 C53 C63 120.95(18) . . . . ?
C49 C50 C54 C55 -1.3(3) . . . . ?
C51 C50 C54 C55 176.79(17) . . . . ?
C49 C50 C54 C53 177.31(16) . . . . ?
C51 C50 C54 C53 -4.6(2) . . . . ?
C65 C53 C54 C55 -58.9(3) . . . . ?
C52 C53 C54 C55 179.14(19) . . . . ?
C63 C53 C54 C55 60.3(3) . . . . ?
C65 C53 C54 C50 122.58(19) . . . . ?
C52 C53 C54 C50 0.6(2) . . . . ?
C63 C53 C54 C50 -118.28(18) . . . . ?
C50 C54 C55 C56 -0.1(3) . . . . ?
C53 C54 C55 C56 -178.57(18) . . . . ?
C54 C55 C56 C60 1.6(3) . . . . ?
C54 C55 C56 C57 -177.57(18) . . . . ?
C55 C56 C57 C67 53.9(3) . . . . ?
C60 C56 C57 C67 -125.36(18) . . . . ?
C55 C56 C57 C69A -71.6(3) . . . . ?
C60 C56 C57 C69A 109.2(2) . . . . ?
C55 C56 C57 C69B -53.6(4) . . . . ?
C60 C56 C57 C69B 127.2(4) . . . . ?
C55 C56 C57 C58 173.29(19) . . . . ?
C60 C56 C57 C58 -5.9(2) . . . . ?
C56 C57 C58 C59 14.0(2) . . . . ?
C67 C57 C58 C59 132.99(18) . . . . ?
C69A C57 C58 C59 -101.1(3) . . . . ?
C69B C57 C58 C59 -113.1(7) . . . . ?
C57 C58 C59 C72 -138.69(17) . . . . ?
C57 C58 C59 C71 100.77(19) . . . . ?
C57 C58 C59 C60 -16.6(2) . . . . ?
C55 C56 C60 C49 -1.7(3) . . . . ?
C57 C56 C60 C49 177.59(16) . . . . ?
C55 C56 C60 C59 176.23(17) . . . . ?
C57 C56 C60 C59 -4.5(2) . . . . ?
C50 C49 C60 C56 0.2(2) . . . . ?
Ge3 C49 C60 C56 -179.95(13) . . . . ?
C50 C49 C60 C59 -177.22(16) . . . . ?
Ge3 C49 C60 C59 2.6(2) . . . . ?
C72 C59 C60 C56 131.41(16) . . . . ?
C71 C59 C60 C56 -105.08(16) . . . . ?
C58 C59 C60 C56 12.8(2) . . . . ?
C72 C59 C60 C49 -50.9(2) . . . . ?
C71 C59 C60 C49 72.6(2) . . . . ?
C58 C59 C60 C49 -169.48(18) . . . . ?
C54 C53 C63 C64 52.7(2) . . . . ?
C65 C53 C63 C64 174.4(2) . . . . ?
C52 C53 C63 C64 -60.8(2) . . . . ?
C54 C53 C65 C66 -56.7(3) . . . . ?
C52 C53 C65 C66 59.3(3) . . . . ?
C63 C53 C65 C66 -177.0(2) . . . . ?
C56 C57 C67 C68 47.8(2) . . . . ?
C69A C57 C67 C68 170.9(3) . . . . ?
C69B C57 C67 C68 165.4(7) . . . . ?
C58 C57 C67 C68 -65.6(2) . . . . ?
C56 C57 C69A C70A -177.4(3) . . . . ?
C67 C57 C69A C70A 58.3(4) . . . . ?
C58 C57 C69A C70A -66.8(4) . . . . ?
C56 C57 C69B C70B -61.6(13) . . . . ?
C67 C57 C69B C70B -178.0(11) . . . . ?
C58 C57 C69B C70B 60.7(15) . . . . ?
C84 C73 C74 C78 0.7(2) . . . . ?
Ge4 C73 C74 C78 179.05(13) . . . . ?
C84 C73 C74 C75 -179.51(16) . . . . ?
Ge4 C73 C74 C75 -1.1(3) . . . . ?
C78 C74 C75 C86 115.74(16) . . . . ?
C73 C74 C75 C86 -64.1(2) . . . . ?
C78 C74 C75 C85 -119.70(16) . . . . ?
C73 C74 C75 C85 60.4(2) . . . . ?
C78 C74 C75 C76 -1.75(19) . . . . ?
C73 C74 C75 C76 178.40(17) . . . . ?
C86 C75 C76 C77 -118.14(17) . . . . ?
C85 C75 C76 C77 120.22(17) . . . . ?
C74 C75 C76 C77 0.5(2) . . . . ?
C75 C76 C77 C78 0.8(2) . . . . ?
C75 C76 C77 C89 -118.72(18) . . . . ?
C75 C76 C77 C87 121.03(18) . . . . ?
C73 C74 C78 C79 2.4(3) . . . . ?
C75 C74 C78 C79 -177.47(16) . . . . ?
C73 C74 C78 C77 -177.67(15) . . . . ?
C75 C74 C78 C77 2.5(2) . . . . ?
C89 C77 C78 C79 -62.3(2) . . . . ?
C76 C77 C78 C79 177.92(18) . . . . ?
C87 C77 C78 C79 56.9(2) . . . . ?
C89 C77 C78 C74 117.71(18) . . . . ?
C76 C77 C78 C74 -2.0(2) . . . . ?
C87 C77 C78 C74 -123.02(18) . . . . ?
C74 C78 C79 C80 -2.3(3) . . . . ?
C77 C78 C79 C80 177.72(18) . . . . ?
C78 C79 C80 C84 -0.8(3) . . . . ?
C78 C79 C80 C81 178.0(2) . . . . ?
C79 C80 C81 C82 167.6(2) . . . . ?
C84 C80 C81 C82 -13.5(2) . . . . ?
C79 C80 C81 C93B 58.7(10) . . . . ?
C84 C80 C81 C93B -122.5(10) . . . . ?
C79 C80 C81 C93A 43.1(4) . . . . ?
C84 C80 C81 C93A -138.0(3) . . . . ?
C79 C80 C81 C91A -84.8(3) . . . . ?
C84 C80 C81 C91A 94.1(2) . . . . ?
C79 C80 C81 C91B -55.6(4) . . . . ?
C84 C80 C81 C91B 123.3(3) . . . . ?
C80 C81 C82 C83 17.0(3) . . . . ?
C93B C81 C82 C83 130.8(9) . . . . ?
C93A C81 C82 C83 140.7(3) . . . . ?
C91A C81 C82 C83 -95.7(3) . . . . ?
C91B C81 C82 C83 -110.9(4) . . . . ?
C81 C82 C83 C96 105.6(2) . . . . ?
C81 C82 C83 C95 -134.7(2) . . . . ?
C81 C82 C83 C84 -14.7(2) . . . . ?
C79 C80 C84 C73 3.9(3) . . . . ?
C81 C80 C84 C73 -175.06(16) . . . . ?
C79 C80 C84 C83 -176.26(18) . . . . ?
C81 C80 C84 C83 4.8(2) . . . . ?
C74 C73 C84 C80 -3.7(2) . . . . ?
Ge4 C73 C84 C80 177.68(14) . . . . ?
C74 C73 C84 C83 176.48(17) . . . . ?
Ge4 C73 C84 C83 -2.2(2) . . . . ?
C96 C83 C84 C80 -112.35(18) . . . . ?
C95 C83 C84 C80 122.53(19) . . . . ?
C82 C83 C84 C80 6.0(2) . . . . ?
C96 C83 C84 C73 67.5(2) . . . . ?
C95 C83 C84 C73 -57.6(3) . . . . ?
C82 C83 C84 C73 -174.16(19) . . . . ?
C78 C77 C87 C88 52.1(2) . . . . ?
C89 C77 C87 C88 174.0(2) . . . . ?
C76 C77 C87 C88 -63.0(2) . . . . ?
C78 C77 C89 C90 -55.1(3) . . . . ?
C76 C77 C89 C90 59.3(3) . . . . ?
C87 C77 C89 C90 -177.1(2) . . . . ?
C80 C81 C91A C92A 60.3(4) . . . . ?
C82 C81 C91A C92A 167.3(3) . . . . ?
C80 C81 C91B C92B -60.0(8) . . . . ?
C82 C81 C91B C92B 63.8(9) . . . . ?
C80 C81 C93A C94A 51.1(6) . . . . ?
C82 C81 C93A C94A -65.8(6) . . . . ?
C80 C81 C93B C94B 54(2) . . . . ?
C82 C81 C93B C94B -54(2) . . . . ?
C97A C98A C99A C99A 175.2(12) . . . 2 ?
C97B C98B C99B C99B -163(2) . . . 2 ?

_refine_diff_density_max         0.994
_refine_diff_density_min         -0.567
_refine_diff_density_rms         0.058


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: hexane and toluene'
_chemical_properties_physical    
', Air-sensitive,Moisture-sensitive,Oxygen-sensitive'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_EMind2Ge2Cl2
_database_code_depnum_ccdc_archive 'CCDC 1580780'
_audit_update_record             
;
2017-10-19 deposited with the CCDC.
2018-01-15 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        dichlorodigermene
_chemical_name_common            (EMind)ClGe=GeCl(EMind)
_chemical_melting_point          ?
_chemical_formula_moiety         'C48 H74 Cl2 Ge2'
_chemical_formula_sum            'C48 H74 Cl2 Ge2'
_chemical_formula_weight         867.15

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.9924(4)
_cell_length_b                   11.3428(4)
_cell_length_c                   11.8084(5)
_cell_angle_alpha                118.544(4)
_cell_angle_beta                 92.150(3)
_cell_angle_gamma                113.282(3)
_cell_volume                     1140.33(9)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    8311
_cell_measurement_theta_min      3.7020
_cell_measurement_theta_max      30.9590

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.263
_exptl_crystal_F_000             460
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.184
_exptl_crystal_size_mid          0.123
_exptl_crystal_size_min          0.111
_exptl_absorpt_coefficient_mu    1.466
_shelx_estimated_absorpt_T_min   0.774
_shelx_estimated_absorpt_T_max   0.854
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.78275
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.7e (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_measurement_device_type  'XtaLAB Pro: Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 5.811
_diffrn_reflns_number            18211
_diffrn_reflns_av_unetI/netI     0.0432
_diffrn_reflns_av_R_equivalents  0.0370
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         3.626
_diffrn_reflns_theta_max         27.489
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             5213
_reflns_number_gt                4378
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.39.7e (Rigaku OD, 2015)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.7e (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.39.7e (Rigaku OD, 2015)'
_computing_structure_solution    SIR2008
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_molecular_graphics    SHELXLE
_computing_publication_material  'SHELXL-2017/1 (Sheldrick, 2017)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0293P)²+2.1871P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5213
_refine_ls_number_parameters     258
_refine_ls_number_restraints     21
_refine_ls_R_factor_all          0.0552
_refine_ls_R_factor_gt           0.0438
_refine_ls_wR_factor_ref         0.1150
_refine_ls_wR_factor_gt          0.1116
_refine_ls_goodness_of_fit_ref   1.133
_refine_ls_restrained_S_all      1.141
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.10887(4) 0.57260(4) 0.08221(4) 0.02512(11) Uani 0.9565(8) 1 d D . P A
1
Cl1 Cl 0.06647(15) 0.52799(19) 0.24211(18) 0.0419(4) Uani 0.9565(8) 1 d D . P A
1
Ge1B Ge 0.0444(8) 0.6096(8) 0.1129(8) 0.02512(11) Uani 0.0435(8) 1 d D . P A 2
Cl1B Cl 0.034(5) 0.502(5) 0.228(5) 0.0419(4) Uani 0.0435(8) 1 d D . P A 2
C1 C 0.2254(3) 0.7948(3) 0.1691(3) 0.0223(6) Uani 1 1 d . . . . .
C2 C 0.1847(3) 0.9096(3) 0.2262(3) 0.0207(6) Uani 1 1 d . . . . .
C3 C 0.0409(3) 0.8962(3) 0.2332(3) 0.0239(6) Uani 1 1 d . . . . .
C4 C 0.0779(3) 1.0642(3) 0.3364(3) 0.0272(7) Uani 1 1 d . . . . .
H4A H 0.007184 1.087312 0.311256 0.033 Uiso 1 1 calc R U . . .
H4B H 0.080228 1.080836 0.426911 0.033 Uiso 1 1 calc R U . . .
C5 C 0.2201(3) 1.1694(3) 0.3379(3) 0.0235(6) Uani 1 1 d . . . . .
C6 C 0.2827(3) 1.0621(3) 0.2850(3) 0.0215(6) Uani 1 1 d . . . . .
C7 C 0.4208(3) 1.1031(3) 0.2912(3) 0.0240(6) Uani 1 1 d . . . . .
H7 H 0.487076 1.207269 0.334266 0.029 Uiso 1 1 calc R U . . .
C8 C 0.4613(3) 0.9907(3) 0.2341(3) 0.0241(6) Uani 1 1 d . . . . .
C9 C 0.6078(3) 1.0170(4) 0.2321(3) 0.0292(7) Uani 1 1 d D . . . .
C10 C 0.5907(4) 0.8546(4) 0.1580(5) 0.0540(12) Uani 1 1 d . . . . .
H10A H 0.643420 0.843290 0.218596 0.065 Uiso 1 1 calc DR U . . .
H10B H 0.627302 0.835304 0.079174 0.065 Uiso 1 1 calc R U . . .
C11 C 0.4339(4) 0.7368(4) 0.1110(4) 0.0328(8) Uani 1 1 d . . . . .
C12 C 0.3645(3) 0.8377(3) 0.1717(3) 0.0243(6) Uani 1 1 d . . . . .
C13 C -0.0475(3) 0.8366(4) 0.0954(3) 0.0282(7) Uani 1 1 d . . . . .
H13A H -0.062481 0.733528 0.030997 0.034 Uiso 1 1 calc R U . . .
H13B H 0.000261 0.903656 0.063953 0.034 Uiso 1 1 calc R U . . .
H13C H -0.136640 0.834535 0.103203 0.034 Uiso 1 1 calc R U . . .
C14 C -0.0390(4) 0.7976(4) 0.2864(4) 0.0322(7) Uani 1 1 d . . . . .
H14A H 0.021330 0.826314 0.368250 0.039 Uiso 1 1 calc R U . . .
H14B H -0.070555 0.690215 0.218234 0.039 Uiso 1 1 calc R U . . .
H14C H -0.118961 0.813352 0.306807 0.039 Uiso 1 1 calc R U . . .
C15 C 0.3059(4) 1.3060(4) 0.4813(3) 0.0333(7) Uani 1 1 d . . . . .
H15A H 0.314327 1.267244 0.539012 0.040 Uiso 1 1 calc R U . . .
H15B H 0.399898 1.363120 0.478845 0.040 Uiso 1 1 calc R U . . .
C16 C 0.2461(4) 1.4158(4) 0.5457(4) 0.0460(10) Uani 1 1 d . . . . .
H16A H 0.254206 1.470341 0.499973 0.055 Uiso 1 1 calc R U . . .
H16B H 0.297207 1.489014 0.640858 0.055 Uiso 1 1 calc R U . . .
H16C H 0.148695 1.358467 0.537375 0.055 Uiso 1 1 calc R U . . .
C17 C 0.2030(3) 1.2216(4) 0.2413(3) 0.0292(7) Uani 1 1 d . . . . .
H17A H 0.149007 1.129775 0.150665 0.035 Uiso 1 1 calc R U . . .
H17B H 0.147789 1.276181 0.271223 0.035 Uiso 1 1 calc R U . . .
C18 C 0.3343(4) 1.3229(4) 0.2293(4) 0.0393(8) Uani 1 1 d . . . . .
H18A H 0.311427 1.345074 0.163136 0.047 Uiso 1 1 calc R U . . .
H18B H 0.390879 1.271184 0.200400 0.047 Uiso 1 1 calc R U . . .
H18C H 0.385839 1.418226 0.316732 0.047 Uiso 1 1 calc R U . . .
C19 C 0.7114(4) 1.1267(5) 0.3740(4) 0.0435(13) Uani 0.835(7) 1 d D . P B 1
H19A H 0.801999 1.129901 0.367082 0.052 Uiso 0.835(7) 1 calc R U P B 1
H19B H 0.723623 1.230434 0.408750 0.052 Uiso 0.835(7) 1 calc R U P B 1
C20 C 0.6660(6) 1.0815(8) 0.4741(5) 0.0686(18) Uani 0.835(7) 1 d D U P B 1
H20A H 0.578849 1.083441 0.485318 0.103 Uiso 0.835(7) 1 calc R U P B 1
H20B H 0.736875 1.153223 0.560796 0.103 Uiso 0.835(7) 1 calc R U P B 1
H20C H 0.653235 0.978651 0.440284 0.103 Uiso 0.835(7) 1 calc R U P B 1
C19B C 0.6790(15) 1.0608(12) 0.3714(6) 0.0435(13) Uani 0.165(7) 1 d D . P B 2
H19C H 0.620267 0.984769 0.391297 0.052 Uiso 0.165(7) 1 calc DR U P B 2
H19D H 0.768005 1.058445 0.369724 0.052 Uiso 0.165(7) 1 calc DR U P B 2
C20B C 0.705(3) 1.2188(19) 0.4827(12) 0.0686(18) Uani 0.165(7) 1 d D U P B 2
H20D H 0.717184 1.282336 0.445581 0.103 Uiso 0.165(7) 1 calc R U P B 2
H20E H 0.788666 1.265456 0.553691 0.103 Uiso 0.165(7) 1 calc R U P B 2
H20F H 0.626214 1.209803 0.520178 0.103 Uiso 0.165(7) 1 calc R U P B 2
C21 C 0.6590(4) 1.0949(5) 0.1545(5) 0.0433(9) Uani 1 1 d . . . . .
H21A H 0.593598 1.030010 0.063579 0.052 Uiso 1 1 calc R U . . .
H21B H 0.655559 1.192388 0.200149 0.052 Uiso 1 1 calc R U . . .
C22 C 0.8042(4) 1.1276(5) 0.1394(5) 0.0527(11) Uani 1 1 d . . . . .
H22A H 0.811177 1.033084 0.098494 0.063 Uiso 1 1 calc R U . . .
H22B H 0.871755 1.201635 0.228055 0.063 Uiso 1 1 calc R U . . .
H22C H 0.822969 1.168989 0.082040 0.063 Uiso 1 1 calc R U . . .
C23 C 0.4184(4) 0.6347(5) 0.1635(5) 0.0436(9) Uani 1 1 d . . . . .
H23A H 0.479267 0.588613 0.134329 0.052 Uiso 1 1 calc R U . . .
H23B H 0.322514 0.554420 0.128399 0.052 Uiso 1 1 calc R U . . .
H23C H 0.443552 0.695001 0.261892 0.052 Uiso 1 1 calc R U . . .
C24 C 0.3823(4) 0.6421(5) -0.0412(4) 0.0447(9) Uani 1 1 d . . . . .
H24A H 0.282004 0.578712 -0.069299 0.054 Uiso 1 1 calc R U . . .
H24B H 0.426312 0.576898 -0.077366 0.054 Uiso 1 1 calc R U . . .
H24C H 0.405211 0.709610 -0.075259 0.054 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C1 1.981(3) . ?
Ge1 Cl1 2.1980(13) . ?
Ge1 Ge1 2.3853(7) 2_565 ?
Ge1B C1 2.019(8) . ?
Ge1B Cl1B 2.198(4) . ?
Ge1B Ge1B 2.407(15) 2_565 ?
C1 C12 1.403(4) . ?
C1 C2 1.412(4) . ?
C2 C6 1.400(4) . ?
C2 C3 1.537(4) . ?
C3 C14 1.534(4) . ?
C3 C13 1.536(4) . ?
C3 C4 1.553(4) . ?
C4 C5 1.539(4) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.520(4) . ?
C5 C15 1.541(4) . ?
C5 C17 1.552(4) . ?
C6 C7 1.388(4) . ?
C7 C8 1.389(4) . ?
C7 H7 0.9500 . ?
C8 C12 1.395(4) . ?
C8 C9 1.520(4) . ?
C9 C21 1.534(5) . ?
C9 C10 1.539(5) . ?
C9 C19B 1.543(5) . ?
C9 C19 1.548(4) . ?
C10 C11 1.569(5) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C23 1.515(5) . ?
C11 C24 1.517(6) . ?
C11 C12 1.534(4) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.529(5) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.511(5) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.526(4) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C19B C20B 1.528(5) . ?
C19B H19C 0.9900 . ?
C19B H19D 0.9900 . ?
C20B H20D 0.9800 . ?
C20B H20E 0.9800 . ?
C20B H20F 0.9800 . ?
C21 C22 1.528(5) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ge1 Cl1 107.57(10) . . ?
C1 Ge1 Ge1 124.24(9) . 2_565 ?
Cl1 Ge1 Ge1 104.89(4) . 2_565 ?
C1 Ge1B Cl1B 115.5(13) . . ?
C1 Ge1B Ge1B 120.7(5) . 2_565 ?
Cl1B Ge1B Ge1B 100.5(15) . 2_565 ?
C12 C1 C2 118.4(3) . . ?
C12 C1 Ge1 113.6(2) . . ?
C2 C1 Ge1 128.0(2) . . ?
C12 C1 Ge1B 141.1(3) . . ?
C2 C1 Ge1B 100.4(3) . . ?
C6 C2 C1 120.0(3) . . ?
C6 C2 C3 110.2(2) . . ?
C1 C2 C3 129.9(3) . . ?
C14 C3 C13 109.2(3) . . ?
C14 C3 C2 114.8(3) . . ?
C13 C3 C2 110.8(2) . . ?
C14 C3 C4 108.9(3) . . ?
C13 C3 C4 111.7(2) . . ?
C2 C3 C4 101.3(2) . . ?
C5 C4 C3 109.0(2) . . ?
C5 C4 H4A 109.9 . . ?
C3 C4 H4A 109.9 . . ?
C5 C4 H4B 109.9 . . ?
C3 C4 H4B 109.9 . . ?
H4A C4 H4B 108.3 . . ?
C6 C5 C4 100.9(2) . . ?
C6 C5 C15 111.0(2) . . ?
C4 C5 C15 111.6(3) . . ?
C6 C5 C17 111.1(2) . . ?
C4 C5 C17 110.3(3) . . ?
C15 C5 C17 111.6(3) . . ?
C7 C6 C2 120.9(3) . . ?
C7 C6 C5 126.4(3) . . ?
C2 C6 C5 112.7(3) . . ?
C6 C7 C8 119.5(3) . . ?
C6 C7 H7 120.3 . . ?
C8 C7 H7 120.3 . . ?
C7 C8 C12 120.4(3) . . ?
C7 C8 C9 125.8(3) . . ?
C12 C8 C9 113.8(3) . . ?
C8 C9 C21 109.0(2) . . ?
C8 C9 C10 102.8(3) . . ?
C21 C9 C10 111.9(3) . . ?
C8 C9 C19B 105.7(6) . . ?
C21 C9 C19B 129.2(6) . . ?
C10 C9 C19B 94.9(4) . . ?
C8 C9 C19 112.8(3) . . ?
C21 C9 C19 105.4(3) . . ?
C10 C9 C19 115.0(3) . . ?
C9 C10 C11 109.6(3) . . ?
C9 C10 H10A 109.7 . . ?
C11 C10 H10A 109.7 . . ?
C9 C10 H10B 109.7 . . ?
C11 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
C23 C11 C24 109.9(3) . . ?
C23 C11 C12 113.9(3) . . ?
C24 C11 C12 111.1(3) . . ?
C23 C11 C10 108.2(3) . . ?
C24 C11 C10 110.1(3) . . ?
C12 C11 C10 103.3(3) . . ?
C8 C12 C1 120.8(3) . . ?
C8 C12 C11 110.2(3) . . ?
C1 C12 C11 129.0(3) . . ?
C3 C13 H13A 109.5 . . ?
C3 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C3 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C3 C14 H14A 109.5 . . ?
C3 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C3 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 C5 114.6(3) . . ?
C16 C15 H15A 108.6 . . ?
C5 C15 H15A 108.6 . . ?
C16 C15 H15B 108.6 . . ?
C5 C15 H15B 108.6 . . ?
H15A C15 H15B 107.6 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C5 116.5(3) . . ?
C18 C17 H17A 108.2 . . ?
C5 C17 H17A 108.2 . . ?
C18 C17 H17B 108.2 . . ?
C5 C17 H17B 108.2 . . ?
H17A C17 H17B 107.3 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 C9 113.4(3) . . ?
C20 C19 H19A 108.9 . . ?
C9 C19 H19A 108.9 . . ?
C20 C19 H19B 108.9 . . ?
C9 C19 H19B 108.9 . . ?
H19A C19 H19B 107.7 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C20B C19B C9 112.1(7) . . ?
C20B C19B H19C 109.2 . . ?
C9 C19B H19C 109.2 . . ?
C20B C19B H19D 109.2 . . ?
C9 C19B H19D 109.2 . . ?
H19C C19B H19D 107.9 . . ?
C19B C20B H20D 109.5 . . ?
C19B C20B H20E 109.5 . . ?
H20D C20B H20E 109.5 . . ?
C19B C20B H20F 109.5 . . ?
H20D C20B H20F 109.5 . . ?
H20E C20B H20F 109.5 . . ?
C22 C21 C9 116.5(3) . . ?
C22 C21 H21A 108.2 . . ?
C9 C21 H21A 108.2 . . ?
C22 C21 H21B 108.2 . . ?
C9 C21 H21B 108.2 . . ?
H21A C21 H21B 107.3 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C11 C23 H23A 109.5 . . ?
C11 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C11 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C11 C24 H24A 109.5 . . ?
C11 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C11 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C12 C1 C2 C6 -0.7(4) . . . . ?
Ge1 C1 C2 C6 179.3(2) . . . . ?
Ge1B C1 C2 C6 177.2(3) . . . . ?
C12 C1 C2 C3 177.6(3) . . . . ?
Ge1 C1 C2 C3 -2.5(5) . . . . ?
Ge1B C1 C2 C3 -4.5(4) . . . . ?
C6 C2 C3 C14 -131.3(3) . . . . ?
C1 C2 C3 C14 50.3(4) . . . . ?
C6 C2 C3 C13 104.4(3) . . . . ?
C1 C2 C3 C13 -74.0(4) . . . . ?
C6 C2 C3 C4 -14.2(3) . . . . ?
C1 C2 C3 C4 167.4(3) . . . . ?
C14 C3 C4 C5 144.8(3) . . . . ?
C13 C3 C4 C5 -94.5(3) . . . . ?
C2 C3 C4 C5 23.5(3) . . . . ?
C3 C4 C5 C6 -23.3(3) . . . . ?
C3 C4 C5 C15 -141.2(3) . . . . ?
C3 C4 C5 C17 94.2(3) . . . . ?
C1 C2 C6 C7 -1.7(4) . . . . ?
C3 C2 C6 C7 179.7(3) . . . . ?
C1 C2 C6 C5 178.5(3) . . . . ?
C3 C2 C6 C5 -0.1(3) . . . . ?
C4 C5 C6 C7 -165.3(3) . . . . ?
C15 C5 C6 C7 -47.0(4) . . . . ?
C17 C5 C6 C7 77.8(4) . . . . ?
C4 C5 C6 C2 14.5(3) . . . . ?
C15 C5 C6 C2 132.8(3) . . . . ?
C17 C5 C6 C2 -102.5(3) . . . . ?
C2 C6 C7 C8 2.3(4) . . . . ?
C5 C6 C7 C8 -177.9(3) . . . . ?
C6 C7 C8 C12 -0.5(5) . . . . ?
C6 C7 C8 C9 179.7(3) . . . . ?
C7 C8 C9 C21 -61.6(4) . . . . ?
C12 C8 C9 C21 118.7(3) . . . . ?
C7 C8 C9 C10 179.5(3) . . . . ?
C12 C8 C9 C10 -0.2(4) . . . . ?
C7 C8 C9 C19B 80.7(5) . . . . ?
C12 C8 C9 C19B -99.1(5) . . . . ?
C7 C8 C9 C19 55.1(4) . . . . ?
C12 C8 C9 C19 -124.7(3) . . . . ?
C8 C9 C10 C11 3.3(4) . . . . ?
C21 C9 C10 C11 -113.5(4) . . . . ?
C19B C9 C10 C11 110.6(7) . . . . ?
C19 C9 C10 C11 126.4(4) . . . . ?
C9 C10 C11 C23 -126.1(4) . . . . ?
C9 C10 C11 C24 113.8(4) . . . . ?
C9 C10 C11 C12 -5.0(4) . . . . ?
C7 C8 C12 C1 -1.9(5) . . . . ?
C9 C8 C12 C1 177.9(3) . . . . ?
C7 C8 C12 C11 177.2(3) . . . . ?
C9 C8 C12 C11 -3.1(4) . . . . ?
C2 C1 C12 C8 2.5(4) . . . . ?
Ge1 C1 C12 C8 -177.5(2) . . . . ?
Ge1B C1 C12 C8 -174.3(4) . . . . ?
C2 C1 C12 C11 -176.4(3) . . . . ?
Ge1 C1 C12 C11 3.6(4) . . . . ?
Ge1B C1 C12 C11 6.9(7) . . . . ?
C23 C11 C12 C8 122.0(3) . . . . ?
C24 C11 C12 C8 -113.2(3) . . . . ?
C10 C11 C12 C8 4.8(4) . . . . ?
C23 C11 C12 C1 -59.0(5) . . . . ?
C24 C11 C12 C1 65.7(4) . . . . ?
C10 C11 C12 C1 -176.2(3) . . . . ?
C6 C5 C15 C16 -176.9(3) . . . . ?
C4 C5 C15 C16 -65.2(4) . . . . ?
C17 C5 C15 C16 58.6(4) . . . . ?
C6 C5 C17 C18 -67.5(4) . . . . ?
C4 C5 C17 C18 -178.6(3) . . . . ?
C15 C5 C17 C18 56.8(4) . . . . ?
C8 C9 C19 C20 52.2(5) . . . . ?
C21 C9 C19 C20 171.0(4) . . . . ?
C10 C9 C19 C20 -65.3(5) . . . . ?
C8 C9 C19B C20B -70.5(16) . . . . ?
C21 C9 C19B C20B 61.1(18) . . . . ?
C10 C9 C19B C20B -175.3(16) . . . . ?
C8 C9 C21 C22 -178.8(3) . . . . ?
C10 C9 C21 C22 -65.7(5) . . . . ?
C19B C9 C21 C22 50.8(8) . . . . ?
C19 C9 C21 C22 59.9(5) . . . . ?

_refine_diff_density_max         0.783
_refine_diff_density_min         -0.468
_refine_diff_density_rms         0.076


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: THF and pentane'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Heat-sensitive,Oxygen-sensitive
