# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1529050'
_audit_update_record             
;
2017-01-23 deposited with the CCDC.
2017-05-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H53 Ag4 Mo12 O48 P S8'
_chemical_formula_weight         2979.87

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   16.9657(8)
_cell_length_b                   17.2724(8)
_cell_length_c                   25.7174(12)
_cell_angle_alpha                90.00
_cell_angle_beta                 106.578(5)
_cell_angle_gamma                90.00
_cell_volume                     7222.9(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6373
_cell_measurement_theta_min      3.2880
_cell_measurement_theta_max      28.2170

_exptl_crystal_description       block
_exptl_crystal_colour            'dark yellow'
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.740
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5664
_exptl_absorpt_coefficient_mu    3.410
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.76251
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14762
_diffrn_reflns_av_R_equivalents  0.0281
_diffrn_reflns_av_sigmaI/netI    0.0402
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         2.88
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6351
_reflns_number_gt                5702
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+2384.2620P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00010(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         6351
_refine_ls_number_parameters     468
_refine_ls_number_restraints     348
_refine_ls_R_factor_all          0.1743
_refine_ls_R_factor_gt           0.1655
_refine_ls_wR_factor_ref         0.3140
_refine_ls_wR_factor_gt          0.3103
_refine_ls_goodness_of_fit_ref   1.127
_refine_ls_restrained_S_all      1.144
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.3641(2) 0.4470(2) 0.24429(14) 0.0719(9) Uani 1 1 d U . 4
Ag2 Ag 0.47930(18) 0.50941(17) 0.19112(12) 0.0574(8) Uani 1 1 d U . 4
C1 C 0.5000 0.418(2) 0.2500 0.038(9) Uani 1 2 d SU . 4
C2 C 0.5000 0.350(2) 0.2500 0.027(8) Uani 0.50 1 d PU A 4
C3 C 0.5000 0.265(3) 0.2500 0.044(10) Uani 1 2 d SU . 4
C4 C 0.5510(19) 0.2278(19) 0.2279(13) 0.044(7) Uani 1 1 d U B 4
H4 H 0.5855 0.2568 0.2131 0.053 Uiso 1 1 calc R B 4
C5 C 0.555(2) 0.145(2) 0.2260(14) 0.053(8) Uani 1 1 d U B 4
H5 H 0.5908 0.1204 0.2101 0.064 Uiso 1 1 calc R B 4
C6 C 0.5000 0.102(3) 0.2500 0.056(12) Uani 1 2 d SU . 4
H6 H 0.5000 0.0478 0.2500 0.068 Uiso 1 2 calc SR . 4
C7 C 0.365(3) 0.427(3) 0.017(2) 0.093(14) Uani 1 1 d U C 4
H7A H 0.3296 0.4535 0.0343 0.140 Uiso 1 1 calc R C 4
H7B H 0.3361 0.3847 -0.0041 0.140 Uiso 1 1 calc R C 4
H7C H 0.3837 0.4621 -0.0057 0.140 Uiso 1 1 calc R C 4
C8 C 0.391(3) 0.330(3) 0.096(2) 0.104(15) Uani 1 1 d U C 4
H8A H 0.4284 0.2955 0.1203 0.157 Uiso 1 1 calc R C 4
H8B H 0.3523 0.3005 0.0687 0.157 Uiso 1 1 calc R C 4
H8C H 0.3621 0.3602 0.1161 0.157 Uiso 1 1 calc R C 4
C9 C 0.448(4) 0.655(4) 0.062(2) 0.120(18) Uani 1 1 d U D 4
H9A H 0.4600 0.7090 0.0690 0.181 Uiso 1 1 calc R D 4
H9B H 0.4212 0.6470 0.0246 0.181 Uiso 1 1 calc R D 4
H9C H 0.4987 0.6261 0.0726 0.181 Uiso 1 1 calc R D 4
C10 C 0.327(3) 0.710(3) 0.099(2) 0.093(14) Uani 1 1 d U D 4
H10A H 0.2783 0.6949 0.1077 0.140 Uiso 1 1 calc R D 4
H10B H 0.3131 0.7338 0.0638 0.140 Uiso 1 1 calc R D 4
H10C H 0.3582 0.7456 0.1256 0.140 Uiso 1 1 calc R D 4
C11 C 0.391(3) 0.706(3) 0.257(2) 0.088(13) Uani 1 1 d U E 4
H11A H 0.4375 0.6952 0.2880 0.131 Uiso 1 1 calc R E 4
H11B H 0.3746 0.7588 0.2584 0.131 Uiso 1 1 calc R E 4
H11C H 0.4066 0.6973 0.2244 0.131 Uiso 1 1 calc R E 4
C12 C 0.285(4) 0.698(4) 0.310(2) 0.124(18) Uani 1 1 d U E 4
H12A H 0.2946 0.6656 0.3420 0.187 Uiso 1 1 calc R E 4
H12B H 0.2271 0.7106 0.2979 0.187 Uiso 1 1 calc R E 4
H12C H 0.3162 0.7446 0.3193 0.187 Uiso 1 1 calc R E 4
C13 C 0.175(2) 0.456(2) 0.2886(15) 0.058(9) Uani 1 1 d U F 4
H13A H 0.2008 0.4909 0.2690 0.088 Uiso 1 1 calc R F 4
H13B H 0.1604 0.4843 0.3166 0.088 Uiso 1 1 calc R F 4
H13C H 0.1271 0.4340 0.2641 0.088 Uiso 1 1 calc R F 4
C14 C 0.313(2) 0.433(2) 0.3662(16) 0.065(10) Uani 1 1 d U F 4
H14A H 0.3473 0.3979 0.3916 0.098 Uiso 1 1 calc R F 4
H14B H 0.2850 0.4667 0.3849 0.098 Uiso 1 1 calc R F 4
H14C H 0.3469 0.4642 0.3498 0.098 Uiso 1 1 calc R F 4
Mo1 Mo 0.18370(17) 0.50376(18) 0.10925(11) 0.0446(7) Uani 1 1 d U . 4
Mo2 Mo 0.11362(17) 0.32712(16) 0.04070(11) 0.0413(7) Uani 1 1 d U G 4
Mo3 Mo 0.00624(17) 0.41278(17) 0.12607(11) 0.0410(7) Uani 1 1 d U G 4
Mo4 Mo -0.17771(17) 0.41248(18) 0.01820(12) 0.0448(7) Uani 1 1 d U G 4
Mo5 Mo -0.07251(18) 0.32257(17) -0.06626(12) 0.0441(7) Uani 1 1 d U . 4
Mo6 Mo -0.10482(16) 0.58811(16) 0.08602(11) 0.0381(6) Uani 1 1 d U . 4
O1 O 0.4766(17) 0.4574(17) 0.1024(11) 0.071(7) Uani 1 1 d U C 4
O2 O 0.4425(16) 0.6199(16) 0.1554(11) 0.064(7) Uani 1 1 d U D 4
O3 O 0.3563(18) 0.5740(17) 0.2836(12) 0.077(8) Uani 1 1 d U E 4
O4 O 0.2857(17) 0.3657(17) 0.2755(12) 0.075(8) Uani 1 1 d U F 4
O5 O 0.2706(12) 0.5057(13) 0.1593(8) 0.043(5) Uani 1 1 d U H 4
O6 O 0.1859(18) 0.4023(18) 0.0833(12) 0.081(8) Uani 1 1 d U G 4
O7 O 0.1082(17) 0.4672(17) 0.1438(12) 0.075(8) Uani 1 1 d U G 4
O8 O 0.0772(19) 0.5499(19) 0.0271(13) 0.021(7) Uani 0.50 1 d PU . 1
O8' O 0.028(2) 0.425(2) -0.0170(15) 0.034(8) Uani 0.50 1 d PU . 2
O10 O -0.0479(18) 0.4851(18) 0.0415(12) 0.018(6) Uani 0.50 1 d PU . 1
O10' O -0.051(2) 0.546(2) -0.0492(15) 0.034(8) Uani 0.50 1 d PU . 2
O12 O 0.1471(14) 0.3555(14) -0.0191(9) 0.054(6) Uani 1 1 d U . .
O13 O 0.1668(15) 0.2451(15) 0.0600(10) 0.061(6) Uani 1 1 d U . .
O14 O 0.0564(17) 0.3355(17) 0.0949(11) 0.072(7) Uani 1 1 d U . .
O15 O 0.0163(13) 0.2883(13) -0.0067(9) 0.049(5) Uani 1 1 d U . .
O16 O 0.0071(15) 0.3730(15) 0.1855(10) 0.058(6) Uani 1 1 d U . .
O17 O -0.0971(16) 0.3790(15) 0.0822(10) 0.062(6) Uani 1 1 d U . .
O18 O -0.0440(15) 0.5110(15) 0.1314(10) 0.063(7) Uani 1 1 d U . .
O19 O -0.1550(16) 0.6258(16) 0.1249(11) 0.068(7) Uani 1 1 d U . .
O20 O -0.1793(16) 0.5069(16) 0.0510(11) 0.068(7) Uani 1 1 d U . .
O21 O -0.0106(13) 0.6494(13) 0.0995(9) 0.046(5) Uani 1 1 d U . .
O22 O -0.2627(15) 0.3711(15) 0.0260(10) 0.057(6) Uani 1 1 d U . .
O23 O -0.2202(18) 0.4603(18) -0.0506(12) 0.082(8) Uani 1 1 d U . .
O24 O -0.1388(19) 0.3313(19) -0.0192(13) 0.085(9) Uani 1 1 d U . .
O25 O -0.145(2) 0.395(2) -0.1150(14) 0.095(10) Uani 1 1 d U . .
O9 O -0.1050(16) 0.2405(16) -0.0988(11) 0.066(7) Uani 1 1 d U . .
P1 P 0.0000 0.5000 0.0000 0.0180(17) Uani 1 2 d SU . .
S1 S 0.4465(8) 0.3923(8) 0.0649(5) 0.086(3) Uani 1 1 d U . .
S2 S 0.3887(7) 0.6257(7) 0.0980(5) 0.073(3) Uani 1 1 d U . .
S3 S 0.3137(8) 0.6475(8) 0.2582(5) 0.084(3) Uani 1 1 d U . .
S4 S 0.2438(6) 0.3834(6) 0.3175(4) 0.064(3) Uani 1 1 d U . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O4 2.24(3) . ?
Ag1 C1 2.323(10) . ?
Ag1 O3 2.44(3) . ?
Ag1 O5 2.52(2) . ?
Ag1 Ag2 2.894(4) . ?
Ag1 Ag2 2.908(5) 2_655 ?
Ag2 O2 2.13(3) . ?
Ag2 C1 2.15(3) . ?
Ag2 O1 2.44(3) . ?
Ag2 Ag1 2.908(5) 2_655 ?
Ag2 Ag2 2.907(6) 2_655 ?
C1 C2 1.18(6) . ?
C1 Ag2 2.15(3) 2_655 ?
C1 Ag1 2.323(10) 2_655 ?
C2 C3 1.47(6) . ?
C3 C4 1.32(4) . ?
C3 C4 1.32(4) 2_655 ?
C4 C5 1.43(5) . ?
C5 C6 1.47(4) . ?
C6 C5 1.47(4) 2_655 ?
C7 S1 1.67(5) . ?
C8 S1 1.76(5) . ?
C9 S2 1.63(6) . ?
C10 S2 1.79(5) . ?
C11 S3 1.67(5) . ?
C12 S3 1.78(6) . ?
C13 S4 1.73(4) . ?
C14 S4 1.69(4) . ?
Mo1 O5 1.66(2) . ?
Mo1 O6 1.88(3) . ?
Mo1 O25 1.88(3) 5_565 ?
Mo1 O7 1.86(3) . ?
Mo1 O23 1.89(3) 5_565 ?
Mo2 O13 1.68(3) . ?
Mo2 O15 1.87(2) . ?
Mo2 O12 1.85(2) . ?
Mo2 O6 1.90(3) . ?
Mo2 O14 1.92(3) . ?
Mo3 O16 1.67(2) . ?
Mo3 O14 1.88(3) . ?
Mo3 O7 1.91(3) . ?
Mo3 O17 1.89(3) . ?
Mo3 O18 1.92(3) . ?
Mo4 O22 1.67(2) . ?
Mo4 O20 1.84(3) . ?
Mo4 O23 1.90(3) . ?
Mo4 O17 1.91(3) . ?
Mo4 O24 1.92(3) . ?
Mo5 O9 1.66(3) . ?
Mo5 O24 1.88(3) . ?
Mo5 O21 1.91(2) 5_565 ?
Mo5 O25 1.95(3) . ?
Mo5 O15 1.91(2) . ?
Mo6 O19 1.62(3) . ?
Mo6 O21 1.87(2) . ?
Mo6 O18 1.88(3) . ?
Mo6 O12 1.93(2) 5_565 ?
Mo6 O20 1.93(3) . ?
O1 S1 1.48(3) . ?
O2 S2 1.50(3) . ?
O3 S3 1.51(3) . ?
O4 S4 1.48(3) . ?
O8 P1 1.56(3) . ?
O8 O10 1.80(4) 5_565 ?
O8' P1 1.49(4) . ?
O8' O10' 1.71(5) 5_565 ?
O10 P1 1.54(3) . ?
O10 O8 1.80(4) 5_565 ?
O10' P1 1.54(4) . ?
O10' O8' 1.71(5) 5_565 ?
O12 Mo6 1.93(2) 5_565 ?
O21 Mo5 1.91(2) 5_565 ?
O23 Mo1 1.89(3) 5_565 ?
O25 Mo1 1.88(3) 5_565 ?
P1 O10' 1.54(4) 5_565 ?
P1 O8' 1.49(4) 5_565 ?
P1 O10 1.54(3) 5_565 ?
P1 O8 1.56(3) 5_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Ag1 C1 121.5(12) . . ?
O4 Ag1 O3 107.9(10) . . ?
C1 Ag1 O3 109.9(12) . . ?
O4 Ag1 O5 105.8(9) . . ?
C1 Ag1 O5 120.7(6) . . ?
O3 Ag1 O5 84.4(8) . . ?
O4 Ag1 Ag2 162.8(8) . . ?
C1 Ag1 Ag2 47.1(8) . . ?
O3 Ag1 Ag2 89.1(7) . . ?
O5 Ag1 Ag2 77.5(5) . . ?
O4 Ag1 Ag2 124.6(7) . 2_655 ?
C1 Ag1 Ag2 46.9(8) . 2_655 ?
O3 Ag1 Ag2 65.0(7) . 2_655 ?
O5 Ag1 Ag2 126.4(5) . 2_655 ?
Ag2 Ag1 Ag2 60.13(12) . 2_655 ?
O2 Ag2 C1 158.6(10) . . ?
O2 Ag2 O1 90.1(10) . . ?
C1 Ag2 O1 110.1(10) . . ?
O2 Ag2 Ag1 112.5(7) . . ?
C1 Ag2 Ag1 52.35(15) . . ?
O1 Ag2 Ag1 118.0(7) . . ?
O2 Ag2 Ag1 133.2(7) . 2_655 ?
C1 Ag2 Ag1 52.09(15) . 2_655 ?
O1 Ag2 Ag1 99.7(7) . 2_655 ?
Ag1 Ag2 Ag1 102.81(14) . 2_655 ?
O2 Ag2 Ag2 113.7(7) . 2_655 ?
C1 Ag2 Ag2 47.4(8) . 2_655 ?
O1 Ag2 Ag2 155.3(7) . 2_655 ?
Ag1 Ag2 Ag2 60.18(12) . 2_655 ?
Ag1 Ag2 Ag2 59.69(12) 2_655 2_655 ?
C2 C1 Ag2 137.4(8) . . ?
C2 C1 Ag2 137.4(8) . 2_655 ?
Ag2 C1 Ag2 85.2(16) . 2_655 ?
C2 C1 Ag1 102.5(10) . . ?
Ag2 C1 Ag1 80.6(9) . . ?
Ag2 C1 Ag1 81.1(9) 2_655 . ?
C2 C1 Ag1 102.5(10) . 2_655 ?
Ag2 C1 Ag1 81.1(9) . 2_655 ?
Ag2 C1 Ag1 80.6(9) 2_655 2_655 ?
Ag1 C1 Ag1 155(2) . 2_655 ?
C1 C2 C3 180.000(12) . . ?
C4 C3 C4 123(5) . 2_655 ?
C4 C3 C2 119(2) . . ?
C4 C3 C2 119(2) 2_655 . ?
C3 C4 C5 122(3) . . ?
C4 C5 C6 117(4) . . ?
C5 C6 C5 118(5) 2_655 . ?
O5 Mo1 O6 101.1(12) . . ?
O5 Mo1 O25 99.9(13) . 5_565 ?
O6 Mo1 O25 159.0(14) . 5_565 ?
O5 Mo1 O7 102.5(11) . . ?
O6 Mo1 O7 86.5(13) . . ?
O25 Mo1 O7 88.6(14) 5_565 . ?
O5 Mo1 O23 101.1(12) . 5_565 ?
O6 Mo1 O23 88.7(13) . 5_565 ?
O25 Mo1 O23 87.7(14) 5_565 5_565 ?
O7 Mo1 O23 156.4(13) . 5_565 ?
O13 Mo2 O15 100.9(11) . . ?
O13 Mo2 O12 101.7(11) . . ?
O15 Mo2 O12 88.6(10) . . ?
O13 Mo2 O6 101.7(13) . . ?
O15 Mo2 O6 157.2(12) . . ?
O12 Mo2 O6 89.9(12) . . ?
O13 Mo2 O14 100.9(12) . . ?
O15 Mo2 O14 88.0(11) . . ?
O12 Mo2 O14 157.3(11) . . ?
O6 Mo2 O14 84.7(12) . . ?
O16 Mo3 O14 102.2(12) . . ?
O16 Mo3 O7 102.3(12) . . ?
O14 Mo3 O7 87.8(12) . . ?
O16 Mo3 O17 100.6(11) . . ?
O14 Mo3 O17 89.0(12) . . ?
O7 Mo3 O17 157.1(12) . . ?
O16 Mo3 O18 100.7(11) . . ?
O14 Mo3 O18 157.1(12) . . ?
O7 Mo3 O18 86.5(12) . . ?
O17 Mo3 O18 87.7(11) . . ?
O22 Mo4 O20 101.4(12) . . ?
O22 Mo4 O23 100.8(13) . . ?
O20 Mo4 O23 89.4(13) . . ?
O22 Mo4 O17 101.4(11) . . ?
O20 Mo4 O17 88.5(11) . . ?
O23 Mo4 O17 157.7(12) . . ?
O22 Mo4 O24 100.3(13) . . ?
O20 Mo4 O24 158.3(13) . . ?
O23 Mo4 O24 86.8(13) . . ?
O17 Mo4 O24 86.9(12) . . ?
O9 Mo5 O24 102.7(13) . . ?
O9 Mo5 O21 99.9(11) . 5_565 ?
O24 Mo5 O21 157.4(12) . 5_565 ?
O9 Mo5 O25 99.7(14) . . ?
O24 Mo5 O25 88.7(14) . . ?
O21 Mo5 O25 87.7(12) 5_565 . ?
O9 Mo5 O15 102.2(12) . . ?
O24 Mo5 O15 89.4(12) . . ?
O21 Mo5 O15 85.6(9) 5_565 . ?
O25 Mo5 O15 157.9(12) . . ?
O19 Mo6 O21 103.3(12) . . ?
O19 Mo6 O18 101.1(13) . . ?
O21 Mo6 O18 89.9(10) . . ?
O19 Mo6 O12 102.7(12) . 5_565 ?
O21 Mo6 O12 87.7(10) . 5_565 ?
O18 Mo6 O12 155.9(11) . 5_565 ?
O19 Mo6 O20 101.0(13) . . ?
O21 Mo6 O20 155.7(10) . . ?
O18 Mo6 O20 86.8(11) . . ?
O12 Mo6 O20 85.6(11) 5_565 . ?
S1 O1 Ag2 143.4(18) . . ?
S2 O2 Ag2 120.3(16) . . ?
S3 O3 Ag1 130.7(17) . . ?
S4 O4 Ag1 126.1(18) . . ?
Mo1 O5 Ag1 150.0(12) . . ?
Mo1 O6 Mo2 140.0(17) . . ?
Mo1 O7 Mo3 138.8(16) . . ?
P1 O8 O10 54.0(14) . 5_565 ?
P1 O8' O10' 56.9(18) . 5_565 ?
P1 O10 O8 55.0(14) . 5_565 ?
P1 O10' O8' 54.3(18) . 5_565 ?
Mo2 O12 Mo6 138.7(13) . 5_565 ?
Mo3 O14 Mo2 138.4(16) . . ?
Mo2 O15 Mo5 139.2(13) . . ?
Mo4 O17 Mo3 137.6(15) . . ?
Mo6 O18 Mo3 139.4(14) . . ?
Mo4 O20 Mo6 139.9(15) . . ?
Mo6 O21 Mo5 139.8(12) . 5_565 ?
Mo1 O23 Mo4 139.7(17) 5_565 . ?
Mo5 O24 Mo4 137.3(18) . . ?
Mo1 O25 Mo5 135.8(19) 5_565 . ?
O10' P1 O10' 180(3) . 5_565 ?
O10' P1 O8' 111(2) . . ?
O10' P1 O8' 69(2) 5_565 . ?
O10' P1 O8' 69(2) . 5_565 ?
O10' P1 O8' 111(2) 5_565 5_565 ?
O8' P1 O8' 180.0(14) . 5_565 ?
O10' P1 O10 68.3(17) . 5_565 ?
O10' P1 O10 111.7(17) 5_565 5_565 ?
O8' P1 O10 70.2(18) . 5_565 ?
O8' P1 O10 109.8(18) 5_565 5_565 ?
O10' P1 O10 111.7(17) . . ?
O10' P1 O10 68.3(17) 5_565 . ?
O8' P1 O10 109.8(18) . . ?
O8' P1 O10 70.2(18) 5_565 . ?
O10 P1 O10 179.998(5) 5_565 . ?
O10' P1 O8 73.1(18) . 5_565 ?
O10' P1 O8 106.9(18) 5_565 5_565 ?
O8' P1 O8 71.9(18) . 5_565 ?
O8' P1 O8 108.1(18) 5_565 5_565 ?
O10 P1 O8 109.0(16) 5_565 5_565 ?
O10 P1 O8 71.0(16) . 5_565 ?
O10' P1 O8 106.9(18) . . ?
O10' P1 O8 73.1(18) 5_565 . ?
O8' P1 O8 108.1(18) . . ?
O8' P1 O8 71.9(18) 5_565 . ?
O10 P1 O8 71.0(16) 5_565 . ?
O10 P1 O8 109.0(16) . . ?
O8 P1 O8 180(2) 5_565 . ?
O1 S1 C7 105(2) . . ?
O1 S1 C8 107(2) . . ?
C7 S1 C8 97(3) . . ?
O2 S2 C9 106(2) . . ?
O2 S2 C10 104(2) . . ?
C9 S2 C10 102(3) . . ?
O3 S3 C11 103(2) . . ?
O3 S3 C12 107(2) . . ?
C11 S3 C12 96(3) . . ?
O4 S4 C14 105.4(19) . . ?
O4 S4 C13 103.8(18) . . ?
C14 S4 C13 101(2) . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         5.349
_refine_diff_density_min         -4.101
_refine_diff_density_rms         0.414
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1529049'
_audit_update_record             
;
2017-01-23 deposited with the CCDC.
2017-05-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H53 Ag4 O48 P S8 W12'
_chemical_formula_weight         4034.79

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   17.0815(6)
_cell_length_b                   17.3104(5)
_cell_length_c                   25.7879(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 106.596(4)
_cell_angle_gamma                90.00
_cell_volume                     7307.5(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    7197
_cell_measurement_theta_min      2.9990
_cell_measurement_theta_max      28.6050

_exptl_crystal_description       block
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.667
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             7200
_exptl_absorpt_coefficient_mu    20.186
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1956
_exptl_absorpt_correction_T_max  0.4990
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            20072
_diffrn_reflns_av_R_equivalents  0.0553
_diffrn_reflns_av_sigmaI/netI    0.0626
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         2.87
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6438
_reflns_number_gt                5619
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+3350.9080P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000109(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         6438
_refine_ls_number_parameters     470
_refine_ls_number_restraints     102
_refine_ls_R_factor_all          0.1125
_refine_ls_R_factor_gt           0.1027
_refine_ls_wR_factor_ref         0.2217
_refine_ls_wR_factor_gt          0.2183
_refine_ls_goodness_of_fit_ref   1.219
_refine_ls_restrained_S_all      1.211
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.6353(2) 0.0534(3) 0.75653(17) 0.0723(13) Uani 1 1 d . . 1
Ag2 Ag 0.5195(2) -0.0089(2) 0.80867(15) 0.0566(10) Uani 1 1 d . . 1
C1 C 0.824(3) 0.048(3) 0.712(2) 0.067(16) Uani 1 1 d . . 1
H1A H 0.8695 0.0706 0.7390 0.100 Uiso 1 1 calc R . 1
H1B H 0.8439 0.0228 0.6851 0.100 Uiso 1 1 calc R . 1
H1C H 0.7983 0.0102 0.7292 0.100 Uiso 1 1 calc R . 1
C2 C 0.687(3) 0.066(3) 0.6336(18) 0.056(13) Uani 1 1 d . . 1
H2A H 0.6691 0.0219 0.6499 0.084 Uiso 1 1 calc R . 1
H2B H 0.7124 0.0491 0.6070 0.084 Uiso 1 1 calc R . 1
H2C H 0.6402 0.0976 0.6165 0.084 Uiso 1 1 calc R . 1
C3 C 0.663(4) -0.210(4) 0.901(3) 0.10(2) Uani 1 1 d U . 1
H3A H 0.6249 -0.2509 0.8889 0.149 Uiso 1 1 calc R . 1
H3B H 0.6977 -0.2212 0.9367 0.149 Uiso 1 1 calc R . 1
H3C H 0.6961 -0.2037 0.8768 0.149 Uiso 1 1 calc R . 1
C4 C 0.549(6) -0.161(4) 0.937(3) 0.15(4) Uani 1 1 d . . 1
H4A H 0.5354 -0.1212 0.9591 0.224 Uiso 1 1 calc R . 1
H4B H 0.5771 -0.2020 0.9598 0.224 Uiso 1 1 calc R . 1
H4C H 0.5003 -0.1801 0.9120 0.224 Uiso 1 1 calc R . 1
C5 C 0.609(4) 0.170(4) 0.901(3) 0.11(3) Uani 1 1 d . . 1
H5A H 0.6387 0.1387 0.8824 0.160 Uiso 1 1 calc R . 1
H5B H 0.6471 0.2010 0.9277 0.160 Uiso 1 1 calc R . 1
H5C H 0.5718 0.2029 0.8759 0.160 Uiso 1 1 calc R . 1
C6 C 0.632(3) 0.074(3) 0.979(2) 0.076(16) Uani 1 1 d U . 1
H6A H 0.6719 0.0582 0.9618 0.113 Uiso 1 1 calc R . 1
H6B H 0.6151 0.0306 0.9963 0.113 Uiso 1 1 calc R . 1
H6C H 0.6543 0.1131 1.0055 0.113 Uiso 1 1 calc R . 1
C7 C 0.5000 0.152(3) 0.7500 0.018(9) Uani 0.50 1 d P A 1
C8 C 0.5000 0.081(3) 0.7500 0.038(13) Uani 1 2 d S . 1
C9 C 0.5000 0.238(3) 0.7500 0.032(12) Uani 1 2 d SU . 1
C10 C 0.447(3) 0.276(3) 0.7717(14) 0.046(11) Uani 1 1 d . B 1
H10 H 0.4112 0.2489 0.7857 0.055 Uiso 1 1 calc R B 1
C11 C 0.448(3) 0.355(2) 0.7729(16) 0.048(12) Uani 1 1 d . B 1
H11 H 0.4140 0.3810 0.7891 0.057 Uiso 1 1 calc R B 1
C12 C 0.5000 0.396(4) 0.7500 0.055(17) Uani 1 2 d SU . 1
H12 H 0.5000 0.4496 0.7500 0.065 Uiso 1 2 calc SR . 1
C13 C 0.604(4) -0.207(4) 0.742(3) 0.09(2) Uani 1 1 d U . 1
H13A H 0.5897 -0.1997 0.7754 0.139 Uiso 1 1 calc R . 1
H13B H 0.6206 -0.2598 0.7402 0.139 Uiso 1 1 calc R . 1
H13C H 0.5577 -0.1959 0.7121 0.139 Uiso 1 1 calc R . 1
C14 C 0.712(6) -0.198(4) 0.690(3) 0.13(4) Uani 1 1 d . . 1
H14A H 0.6633 -0.2151 0.6641 0.201 Uiso 1 1 calc R . 1
H14B H 0.7442 -0.2421 0.7063 0.201 Uiso 1 1 calc R . 1
H14C H 0.7433 -0.1661 0.6732 0.201 Uiso 1 1 calc R . 1
O1 O 0.7281(17) -0.0054(18) 0.8402(11) 0.050(8) Uani 1 1 d . C 1
O2 O 0.894(2) 0.032(2) 0.8570(15) 0.070(10) Uani 1 1 d U C 1
O3 O 0.995(2) 0.1288(16) 0.8151(11) 0.048(8) Uani 1 1 d . C 1
O4 O 1.044(2) -0.0131(17) 0.8692(15) 0.075(12) Uani 1 1 d . . 1
O5 O 0.819(2) 0.093(2) 0.9223(15) 0.068(9) Uani 1 1 d U C 1
O6 O 0.9444(19) 0.1603(19) 0.9061(13) 0.055(8) Uani 1 1 d U C 1
O7 O 0.8358(19) 0.254(2) 0.9408(15) 0.064(10) Uani 1 1 d . C 1
O8 O 0.9867(19) 0.2106(17) 1.0090(11) 0.051(8) Uani 1 1 d . C 1
O9 O 0.8553(17) 0.1455(19) 1.0205(11) 0.053(8) Uani 1 1 d . C 1
O10 O 1.2605(16) 0.1292(18) 0.9750(11) 0.046(7) Uani 1 1 d . C 1
O11 O 1.0956(18) 0.1214(16) 0.9189(12) 0.049(7) Uani 1 1 d U C 1
O12 O 1.137(2) 0.162(2) 1.0204(15) 0.078(11) Uani 1 1 d U C 1
O13 O 1.108(2) 0.2569(18) 1.1015(12) 0.060(9) Uani 1 1 d . C 1
O14 O 1.141(2) 0.103(2) 1.1115(14) 0.066(9) Uani 1 1 d U . 1
O15 O 0.9886(17) 0.1480(18) 1.1003(11) 0.050(8) Uani 1 1 d . C 1
O16 O 0.8437(18) 0.126(2) 1.1242(12) 0.063(10) Uani 1 1 d . C 1
O17 O 0.822(2) 0.004(2) 1.0494(16) 0.075(10) Uani 1 1 d U . 1
O18 O 0.781(3) -0.040(3) 0.9490(15) 0.099(16) Uani 1 1 d . . 1
O19 O 1.074(3) 0.049(3) 1.0266(18) 0.025(10) Uani 0.50 1 d PU C 1
O20 O 0.973(2) 0.073(2) 1.0151(17) 0.019(9) Uani 0.50 1 d PU C 1
O21 O 0.714(2) 0.1366(18) 0.7248(14) 0.060(9) Uani 1 1 d . . .
O22 O 0.557(2) -0.117(2) 0.8447(12) 0.065(10) Uani 1 1 d . . .
O23 O 0.523(2) 0.045(2) 0.8974(13) 0.079(13) Uani 1 1 d . . .
O24 O 0.645(2) -0.0732(18) 0.7174(15) 0.070(10) Uani 1 1 d . . .
O19' O 1.057(3) -0.047(3) 1.0485(19) 0.027(10) Uani 0.50 1 d PU . 2
O20' O 0.950(2) -0.015(2) 1.0403(15) 0.013(8) Uani 0.50 1 d PU . 2
P1 P 1.0000 0.0000 1.0000 0.013(2) Uani 1 2 d SU . .
S1 S 0.7548(9) 0.1188(7) 0.6825(5) 0.058(3) Uani 1 1 d . . .
S2 S 0.6099(9) -0.1235(8) 0.9030(6) 0.076(5) Uani 1 1 d . . .
S3 S 0.5536(11) 0.1088(10) 0.9343(7) 0.089(5) Uani 1 1 d . . .
S4 S 0.6859(11) -0.1445(10) 0.7414(6) 0.079(4) Uani 1 1 d . . .
W1 W 0.89435(9) 0.08731(9) 1.08591(6) 0.0282(4) Uani 1 1 d . . .
W2 W 0.99343(10) 0.08683(10) 0.87347(6) 0.0339(4) Uani 1 1 d . . .
W3 W 0.88846(9) 0.17364(9) 0.95961(6) 0.0302(4) Uani 1 1 d . . .
W4 W 1.17678(9) 0.08936(10) 0.98195(7) 0.0368(4) Uani 1 1 d . . .
W5 W 1.07264(10) 0.17652(9) 1.06804(6) 0.0325(4) Uani 1 1 d . . .
W6 W 0.81612(9) -0.00236(11) 0.89130(6) 0.0367(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O21 2.27(3) . ?
Ag1 C8 2.320(13) . ?
Ag1 O24 2.44(3) . ?
Ag1 O1 2.50(3) . ?
Ag1 Ag2 2.898(6) . ?
Ag1 Ag2 2.905(6) 2_656 ?
Ag2 O22 2.11(3) . ?
Ag2 C8 2.13(4) . ?
Ag2 O23 2.45(3) . ?
Ag2 Ag1 2.905(6) 2_656 ?
Ag2 Ag2 2.907(7) 2_656 ?
C1 S1 1.73(5) . ?
C2 S1 1.71(5) . ?
C3 S2 1.75(7) . ?
C4 S2 1.67(7) . ?
C5 S3 1.79(7) . ?
C6 S3 1.61(6) . ?
C7 C8 1.22(7) . ?
C7 C9 1.50(7) . ?
C8 Ag2 2.13(4) 2_656 ?
C8 Ag1 2.320(13) 2_656 ?
C9 C10 1.36(5) 2_656 ?
C9 C10 1.36(5) . ?
C10 C11 1.36(6) . ?
C11 C12 1.39(6) . ?
C12 C11 1.39(6) 2_656 ?
C13 S4 1.78(7) . ?
C14 S4 1.77(6) . ?
O1 W6 1.69(3) . ?
O2 W2 1.89(4) . ?
O2 W6 1.89(4) . ?
O3 W2 1.68(3) . ?
O4 W1 1.84(3) 5_757 ?
O4 W2 1.95(3) . ?
O5 W6 1.82(4) . ?
O5 W3 1.91(4) . ?
O6 W2 1.85(3) . ?
O6 W3 1.90(3) . ?
O7 W3 1.65(3) . ?
O8 W5 1.88(3) . ?
O8 W3 1.90(3) . ?
O9 W3 1.88(3) . ?
O9 W1 1.91(3) . ?
O10 W4 1.64(3) . ?
O11 W4 1.89(3) . ?
O11 W2 1.90(3) . ?
O12 W4 1.85(4) . ?
O12 W5 1.88(4) . ?
O13 W5 1.66(3) . ?
O14 W5 1.87(3) . ?
O14 W6 1.90(4) 5_757 ?
O15 W1 1.87(3) . ?
O15 W5 1.92(3) . ?
O16 W1 1.63(3) . ?
O17 W4 1.81(4) 5_757 ?
O17 W1 1.95(4) . ?
O18 W6 1.88(4) . ?
O18 W4 1.92(4) 5_757 ?
O19 P1 1.51(5) . ?
O19 O20 1.72(6) . ?
O19 W5 2.46(5) . ?
O19 W4 2.47(4) . ?
O20 P1 1.44(4) . ?
O20 W3 2.45(4) . ?
O21 S1 1.49(3) . ?
O22 S2 1.52(3) . ?
O23 S3 1.46(4) . ?
O24 S4 1.46(4) . ?
O19' P1 1.57(5) . ?
O19' W3 2.42(5) 5_757 ?
O19' W6 2.43(5) 5_757 ?
O19' W2 2.50(5) 5_757 ?
O20' P1 1.55(4) . ?
O20' W4 2.44(4) 5_757 ?
O20' W2 2.49(4) 5_757 ?
O20' W1 2.47(4) . ?
P1 O20 1.44(4) 5_757 ?
P1 O19 1.51(5) 5_757 ?
P1 O20' 1.55(4) 5_757 ?
P1 O19' 1.57(5) 5_757 ?
W1 O4 1.84(3) 5_757 ?
W2 O20' 2.49(4) 5_757 ?
W2 O19' 2.50(5) 5_757 ?
W3 O19' 2.42(5) 5_757 ?
W4 O17 1.81(4) 5_757 ?
W4 O18 1.92(4) 5_757 ?
W4 O20' 2.44(4) 5_757 ?
W6 O14 1.90(4) 5_757 ?
W6 O19' 2.43(5) 5_757 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O21 Ag1 C8 121.3(15) . . ?
O21 Ag1 O24 107.7(12) . . ?
C8 Ag1 O24 110.0(15) . . ?
O21 Ag1 O1 105.9(12) . . ?
C8 Ag1 O1 121.4(8) . . ?
O24 Ag1 O1 83.7(11) . . ?
O21 Ag1 Ag2 162.4(7) . . ?
C8 Ag1 Ag2 46.7(10) . . ?
O24 Ag1 Ag2 89.6(9) . . ?
O1 Ag1 Ag2 78.3(8) . . ?
O21 Ag1 Ag2 124.0(9) . 2_656 ?
C8 Ag1 Ag2 46.6(10) . 2_656 ?
O24 Ag1 Ag2 65.5(9) . 2_656 ?
O1 Ag1 Ag2 126.6(8) . 2_656 ?
Ag2 Ag1 Ag2 60.12(16) . 2_656 ?
O22 Ag2 C8 158.4(13) . . ?
O22 Ag2 O23 90.0(14) . . ?
C8 Ag2 O23 110.0(15) . . ?
O22 Ag2 Ag1 111.9(10) . . ?
C8 Ag2 Ag1 52.25(19) . . ?
O23 Ag2 Ag1 116.9(11) . . ?
O22 Ag2 Ag1 134.3(10) . 2_656 ?
C8 Ag2 Ag1 52.1(2) . 2_656 ?
O23 Ag2 Ag1 100.2(8) . 2_656 ?
Ag1 Ag2 Ag1 102.84(16) . 2_656 ?
O22 Ag2 Ag2 114.2(9) . 2_656 ?
C8 Ag2 Ag2 47.1(11) . 2_656 ?
O23 Ag2 Ag2 155.3(9) . 2_656 ?
Ag1 Ag2 Ag2 60.05(15) . 2_656 ?
Ag1 Ag2 Ag2 59.83(15) 2_656 2_656 ?
C8 C7 C9 180.00(3) . . ?
C7 C8 Ag2 137.1(11) . 2_656 ?
C7 C8 Ag2 137.1(11) . . ?
Ag2 C8 Ag2 86(2) 2_656 . ?
C7 C8 Ag1 102.1(14) . 2_656 ?
Ag2 C8 Ag1 81.1(12) 2_656 2_656 ?
Ag2 C8 Ag1 81.3(12) . 2_656 ?
C7 C8 Ag1 102.1(14) . . ?
Ag2 C8 Ag1 81.3(12) 2_656 . ?
Ag2 C8 Ag1 81.1(12) . . ?
Ag1 C8 Ag1 156(3) 2_656 . ?
C10 C9 C10 122(6) 2_656 . ?
C10 C9 C7 119(3) 2_656 . ?
C10 C9 C7 119(3) . . ?
C11 C10 C9 119(5) . . ?
C10 C11 C12 120(5) . . ?
C11 C12 C11 118(6) . 2_656 ?
W6 O1 Ag1 149.6(19) . . ?
W2 O2 W6 140(2) . . ?
W1 O4 W2 140(2) 5_757 . ?
W6 O5 W3 145(2) . . ?
W2 O6 W3 143.0(19) . . ?
W5 O8 W3 140.4(16) . . ?
W3 O9 W1 139.5(17) . . ?
W4 O11 W2 139.1(16) . . ?
W4 O12 W5 145(2) . . ?
W5 O14 W6 142(2) . 5_757 ?
W1 O15 W5 140.1(16) . . ?
W4 O17 W1 142(2) 5_757 . ?
W6 O18 W4 140(2) . 5_757 ?
P1 O19 O20 52(2) . . ?
P1 O19 W5 126(2) . . ?
O20 O19 W5 74(2) . . ?
P1 O19 W4 124(2) . . ?
O20 O19 W4 132(3) . . ?
W5 O19 W4 92.3(15) . . ?
P1 O20 O19 56(2) . . ?
P1 O20 W3 130(2) . . ?
O19 O20 W3 132(3) . . ?
S1 O21 Ag1 125.6(19) . . ?
S2 O22 Ag2 122(2) . . ?
S3 O23 Ag2 144(3) . . ?
S4 O24 Ag1 132(2) . . ?
P1 O19' W3 124(2) . 5_757 ?
P1 O19' W6 124(3) . 5_757 ?
W3 O19' W6 94.3(16) 5_757 5_757 ?
P1 O19' W2 121(2) . 5_757 ?
W3 O19' W2 92.6(16) 5_757 5_757 ?
W6 O19' W2 91.8(15) 5_757 5_757 ?
P1 O20' W4 124(2) . 5_757 ?
P1 O20' W2 123(2) . 5_757 ?
W4 O20' W2 92.4(12) 5_757 5_757 ?
P1 O20' W1 124(2) . . ?
W4 O20' W1 93.1(13) 5_757 . ?
W2 O20' W1 92.1(13) 5_757 . ?
O20 P1 O20 179.997(18) . 5_757 ?
O20 P1 O19 109(2) . 5_757 ?
O20 P1 O19 71(2) 5_757 5_757 ?
O20 P1 O19 71(2) . . ?
O20 P1 O19 109(2) 5_757 . ?
O19 P1 O19 180(2) 5_757 . ?
O20 P1 O20' 109(2) . 5_757 ?
O20 P1 O20' 71(2) 5_757 5_757 ?
O19 P1 O20' 110(2) 5_757 5_757 ?
O19 P1 O20' 70(2) . 5_757 ?
O20 P1 O20' 71(2) . . ?
O20 P1 O20' 109(2) 5_757 . ?
O19 P1 O20' 70(2) 5_757 . ?
O19 P1 O20' 110(2) . . ?
O20' P1 O20' 179.998(14) 5_757 . ?
O20 P1 O19' 66(2) . 5_757 ?
O20 P1 O19' 114(2) 5_757 5_757 ?
O19 P1 O19' 71(2) 5_757 5_757 ?
O19 P1 O19' 109(2) . 5_757 ?
O20' P1 O19' 73(2) 5_757 5_757 ?
O20' P1 O19' 107(2) . 5_757 ?
O20 P1 O19' 114(2) . . ?
O20 P1 O19' 66(2) 5_757 . ?
O19 P1 O19' 109(2) 5_757 . ?
O19 P1 O19' 71(2) . . ?
O20' P1 O19' 107(2) 5_757 . ?
O20' P1 O19' 73(2) . . ?
O19' P1 O19' 180.00(2) 5_757 . ?
O21 S1 C2 107(2) . . ?
O21 S1 C1 103(2) . . ?
C2 S1 C1 101(3) . . ?
O22 S2 C4 105(3) . . ?
O22 S2 C3 102(3) . . ?
C4 S2 C3 95(4) . . ?
O23 S3 C6 105(3) . . ?
O23 S3 C5 106(3) . . ?
C6 S3 C5 97(3) . . ?
O24 S4 C13 104(3) . . ?
O24 S4 C14 109(3) . . ?
C13 S4 C14 93(3) . . ?
O16 W1 O4 102.0(19) . 5_757 ?
O16 W1 O15 103.2(15) . . ?
O4 W1 O15 87.9(14) 5_757 . ?
O16 W1 O9 102.0(17) . . ?
O4 W1 O9 156.0(17) 5_757 . ?
O15 W1 O9 86.7(12) . . ?
O16 W1 O17 102.8(16) . . ?
O4 W1 O17 87.5(14) 5_757 . ?
O15 W1 O17 154.0(15) . . ?
O9 W1 O17 87.1(14) . . ?
O16 W1 O20' 157.8(16) . . ?
O4 W1 O20' 64.5(15) 5_757 . ?
O15 W1 O20' 94.2(13) . . ?
O9 W1 O20' 92.5(13) . . ?
O17 W1 O20' 60.9(14) . . ?
O3 W2 O6 103.8(15) . . ?
O3 W2 O2 105.3(16) . . ?
O6 W2 O2 87.4(14) . . ?
O3 W2 O11 99.6(14) . . ?
O6 W2 O11 87.6(13) . . ?
O2 W2 O11 155.1(15) . . ?
O3 W2 O4 102.0(16) . . ?
O6 W2 O4 154.2(16) . . ?
O2 W2 O4 85.7(15) . . ?
O11 W2 O4 88.2(12) . . ?
O3 W2 O20' 156.0(14) . 5_757 ?
O6 W2 O20' 92.7(14) . 5_757 ?
O2 W2 O20' 92.6(14) . 5_757 ?
O11 W2 O20' 63.3(12) . 5_757 ?
O4 W2 O20' 62.9(14) . 5_757 ?
O3 W2 O19' 160.2(15) . 5_757 ?
O6 W2 O19' 61.5(15) . 5_757 ?
O2 W2 O19' 63.0(15) . 5_757 ?
O11 W2 O19' 93.3(14) . 5_757 ?
O4 W2 O19' 93.4(16) . 5_757 ?
O20' W2 O19' 43.7(13) 5_757 5_757 ?
O7 W3 O9 101.2(15) . . ?
O7 W3 O8 102.4(16) . . ?
O9 W3 O8 87.0(12) . . ?
O7 W3 O5 105.2(17) . . ?
O9 W3 O5 86.5(14) . . ?
O8 W3 O5 152.4(15) . . ?
O7 W3 O6 103.5(15) . . ?
O9 W3 O6 155.2(14) . . ?
O8 W3 O6 89.8(13) . . ?
O5 W3 O6 85.1(14) . . ?
O7 W3 O19' 158.5(17) . 5_757 ?
O9 W3 O19' 93.0(15) . 5_757 ?
O8 W3 O19' 94.3(15) . 5_757 ?
O5 W3 O19' 59.4(15) . 5_757 ?
O6 W3 O19' 62.7(15) . 5_757 ?
O7 W3 O20 162.1(17) . . ?
O9 W3 O20 66.0(14) . . ?
O8 W3 O20 65.8(13) . . ?
O5 W3 O20 87.0(15) . . ?
O6 W3 O20 90.3(14) . . ?
O19' W3 O20 39.3(14) 5_757 . ?
O10 W4 O17 102.0(16) . 5_757 ?
O10 W4 O12 103.9(17) . . ?
O17 W4 O12 154.0(18) 5_757 . ?
O10 W4 O18 100.2(18) . 5_757 ?
O17 W4 O18 88.1(18) 5_757 5_757 ?
O12 W4 O18 84.6(16) . 5_757 ?
O10 W4 O11 103.3(14) . . ?
O17 W4 O11 88.6(15) 5_757 . ?
O12 W4 O11 88.3(15) . . ?
O18 W4 O11 156.5(17) 5_757 . ?
O10 W4 O20' 159.5(13) . 5_757 ?
O17 W4 O20' 63.0(15) 5_757 5_757 ?
O12 W4 O20' 92.6(16) . 5_757 ?
O18 W4 O20' 93.5(18) 5_757 5_757 ?
O11 W4 O20' 64.4(13) . 5_757 ?
O10 W4 O19 158.6(14) . . ?
O17 W4 O19 92.9(17) 5_757 . ?
O12 W4 O19 61.4(16) . . ?
O18 W4 O19 64.7(17) 5_757 . ?
O11 W4 O19 92.2(14) . . ?
O20' W4 O19 41.9(14) 5_757 . ?
O13 W5 O14 100.8(16) . . ?
O13 W5 O12 105.2(18) . . ?
O14 W5 O12 85.2(16) . . ?
O13 W5 O8 103.9(15) . . ?
O14 W5 O8 155.3(14) . . ?
O12 W5 O8 88.8(16) . . ?
O13 W5 O15 101.1(15) . . ?
O14 W5 O15 89.1(14) . . ?
O12 W5 O15 153.7(16) . . ?
O8 W5 O15 85.7(13) . . ?
O13 W5 O19 159.4(17) . . ?
O14 W5 O19 64.4(15) . . ?
O12 W5 O19 61.2(17) . . ?
O8 W5 O19 91.8(14) . . ?
O15 W5 O19 93.2(14) . . ?
O1 W6 O5 105.9(15) . . ?
O1 W6 O18 100.9(19) . . ?
O5 W6 O18 86.5(18) . . ?
O1 W6 O2 103.5(16) . . ?
O5 W6 O2 89.4(16) . . ?
O18 W6 O2 155.5(19) . . ?
O1 W6 O14 101.9(14) . 5_757 ?
O5 W6 O14 152.0(16) . 5_757 ?
O18 W6 O14 85.7(16) . 5_757 ?
O2 W6 O14 86.6(16) . 5_757 ?
O1 W6 O19' 160.0(16) . 5_757 ?
O5 W6 O19' 60.0(16) . 5_757 ?
O18 W6 O19' 93(2) . 5_757 ?
O2 W6 O19' 64.6(16) . 5_757 ?
O14 W6 O19' 93.6(15) 5_757 5_757 ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         2.644
_refine_diff_density_min         -3.071
_refine_diff_density_rms         0.477
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_6
_database_code_depnum_ccdc_archive 'CCDC 1529053'
_audit_update_record             
;
2017-01-23 deposited with the CCDC.
2017-05-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C144 H132 Ag19 O50 P S8 W12'
_chemical_formula_weight         7205.68

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.6613(15)
_cell_length_b                   18.0152(9)
_cell_length_c                   18.7774(6)
_cell_angle_alpha                93.702(3)
_cell_angle_beta                 101.547(6)
_cell_angle_gamma                101.388(7)
_cell_volume                     4412.5(6)
_cell_formula_units_Z            1
_cell_measurement_temperature    173
_cell_measurement_reflns_used    9926
_cell_measurement_theta_min      3.33
_cell_measurement_theta_max      25.43

_exptl_crystal_description       block
_exptl_crystal_colour            dark-yellow
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.14
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.712
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3320
_exptl_absorpt_coefficient_mu    10.009
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5728
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   'SADABS (Bruker, 2012)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            42160
_diffrn_reflns_av_R_equivalents  0.0475
_diffrn_reflns_av_sigmaI/netI    0.0551
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.04
_diffrn_reflns_theta_max         25.00
_reflns_number_total             15225
_reflns_number_gt                10780
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0333P)²+20.3828P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         15225
_refine_ls_number_parameters     1074
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0712
_refine_ls_R_factor_gt           0.0364
_refine_ls_wR_factor_ref         0.0783
_refine_ls_wR_factor_gt          0.0707
_refine_ls_goodness_of_fit_ref   0.956
_refine_ls_restrained_S_all      0.956
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.33504(6) 0.88660(6) 0.53236(5) 0.0346(2) Uani 0.95 1 d P . .
Ag1' Ag 0.3660(14) 0.8598(10) 0.5067(9) 0.037(4) Uani 0.05 1 d PU . .
Ag2 Ag 0.55836(7) 0.85857(5) 0.55840(6) 0.0427(2) Uani 0.95 1 d P . .
Ag2' Ag 0.5847(10) 0.8886(10) 0.5999(8) 0.026(4) Uani 0.05 1 d P . .
Ag3 Ag 0.49024(7) 0.98261(4) 0.64764(4) 0.03051(19) Uani 0.95 1 d P . .
Ag3' Ag 0.4270(13) 0.9820(8) 0.6281(9) 0.030(4) Uani 0.05 1 d PU . .
Ag4 Ag 0.5000 1.0000 0.5000 0.0245(2) Uani 1 2 d S . .
Ag5 Ag 0.78040(6) 0.92395(4) 0.64479(4) 0.03500(19) Uani 1 1 d . . .
Ag6 Ag 0.70977(5) 1.07004(4) 0.62815(4) 0.03291(18) Uani 1 1 d . . .
Ag7 Ag 0.73042(5) 0.93742(4) 0.48484(3) 0.02711(17) Uani 1 1 d . . .
Ag8 Ag 0.95158(5) 0.92629(4) 0.54857(4) 0.02763(16) Uani 1 1 d . . .
Ag9 Ag 0.88861(5) 0.93926(4) 0.38863(4) 0.02992(17) Uani 1 1 d . . .
Ag10 Ag 0.89302(5) 1.08460(4) 0.55412(4) 0.0393(2) Uani 1 1 d . . .
W1 W 0.11386(3) 0.68711(2) -0.025689(18) 0.02494(10) Uani 1 1 d . . .
W2 W 0.00218(3) 0.44827(2) 0.179693(19) 0.02939(10) Uani 1 1 d . . .
W3 W -0.11605(3) 0.66388(2) 0.039303(19) 0.02820(10) Uani 1 1 d . . .
W4 W 0.11354(3) 0.63612(2) 0.153963(19) 0.02865(10) Uani 1 1 d . . .
W5 W 0.22822(3) 0.52307(2) -0.06652(2) 0.03064(10) Uani 1 1 d . . .
W6 W -0.23132(3) 0.52686(2) -0.11375(2) 0.03336(11) Uani 1 1 d . . .
P1 P 0.0000 0.5000 0.0000 0.0075(6) Uani 1 2 d S . .
S1 S 0.79236(19) 0.84641(16) 0.21460(14) 0.0427(7) Uani 1 1 d . . .
S2 S 0.8070(3) 0.8351(2) 0.79908(19) 0.0481(9) Uani 0.80 1 d P . .
S2' S 0.8443(15) 0.7734(11) 0.7667(12) 0.080(6) Uani 0.20 1 d P . .
S3 S 0.3871(4) 0.8065(3) 0.1435(4) 0.127(2) Uani 1 1 d . . .
S4 S 0.5903(5) 0.7057(4) 0.9653(3) 0.081(2) Uani 0.60 1 d P . .
S4' S 0.4909(11) 0.6795(10) 1.0024(13) 0.199(10) Uani 0.40 1 d P . .
C1 C 0.4396(7) 0.8536(5) 0.6243(5) 0.032(2) Uani 1 1 d . . .
C2 C 0.4322(6) 0.7914(5) 0.6471(5) 0.027(2) Uani 1 1 d . . .
C3 C 0.4211(7) 0.7189(5) 0.6772(5) 0.034(2) Uani 1 1 d . . .
C4 C 0.3515(9) 0.7031(6) 0.7193(6) 0.057(3) Uani 1 1 d . . .
H4A H 0.3132 0.7381 0.7296 0.068 Uiso 1 1 calc R . .
C5 C 0.3392(11) 0.6322(8) 0.7467(8) 0.083(5) Uani 1 1 d . . .
H5A H 0.2902 0.6199 0.7745 0.100 Uiso 1 1 calc R . .
C6 C 0.3980(11) 0.5785(7) 0.7339(8) 0.072(4) Uani 1 1 d . . .
H6A H 0.3898 0.5333 0.7555 0.087 Uiso 1 1 calc R . .
C7 C 0.4668(10) 0.5921(7) 0.6901(7) 0.068(4) Uani 1 1 d . . .
H7A H 0.5043 0.5567 0.6794 0.081 Uiso 1 1 calc R . .
C8 C 0.4772(9) 0.6622(6) 0.6628(6) 0.056(3) Uani 1 1 d . . .
H8A H 0.5238 0.6733 0.6330 0.067 Uiso 1 1 calc R . .
C9 C 0.7113(6) 0.8383(5) 0.5395(5) 0.023(2) Uani 1 1 d . . .
C10 C 0.7013(6) 0.7702(6) 0.5478(5) 0.028(2) Uani 1 1 d . . .
C11 C 0.6972(5) 0.6882(3) 0.5558(4) 0.037(3) Uani 1 1 d G . .
C12 C 0.7611(6) 0.6659(4) 0.6140(4) 0.063(4) Uani 1 1 d G . .
H12A H 0.8075 0.7024 0.6482 0.076 Uiso 1 1 calc R . .
C13 C 0.7557(7) 0.5890(4) 0.6211(5) 0.092(5) Uani 1 1 d G . .
H13A H 0.7985 0.5740 0.6600 0.110 Uiso 1 1 calc R . .
C14 C 0.6863(7) 0.5343(3) 0.5700(5) 0.086(5) Uani 1 1 d G . .
H14A H 0.6827 0.4829 0.5747 0.103 Uiso 1 1 calc R . .
C15 C 0.6224(6) 0.5567(3) 0.5118(4) 0.065(4) Uani 1 1 d G . .
H15A H 0.5760 0.5202 0.4776 0.078 Uiso 1 1 calc R . .
C16 C 0.6278(5) 0.6336(4) 0.5047(3) 0.044(3) Uani 1 1 d G . .
H16A H 0.5850 0.6486 0.4658 0.053 Uiso 1 1 calc R . .
C17 C 0.6768(6) 0.9919(5) 0.7031(5) 0.030(2) Uani 1 1 d . . .
C18 C 0.6518(7) 0.9755(6) 0.7572(5) 0.040(3) Uani 1 1 d . . .
C19 C 0.6308(5) 0.9586(5) 0.8280(3) 0.052(3) Uani 1 1 d G . .
C20 C 0.5323(4) 0.9265(6) 0.8347(3) 0.072(4) Uani 1 1 d G . .
H20A H 0.4791 0.9146 0.7935 0.086 Uiso 1 1 calc R . .
C21 C 0.5132(5) 0.9123(6) 0.9031(4) 0.105(6) Uani 1 1 d G . .
H21A H 0.4472 0.8909 0.9076 0.126 Uiso 1 1 calc R . .
C22 C 0.5926(7) 0.9301(7) 0.9648(3) 0.130(8) Uani 1 1 d G . .
H22A H 0.5799 0.9206 1.0105 0.156 Uiso 1 1 calc R . .
C23 C 0.6912(6) 0.9622(7) 0.9580(3) 0.126(8) Uani 1 1 d G . .
H23A H 0.7443 0.9741 0.9993 0.151 Uiso 1 1 calc R . .
C24 C 0.7102(4) 0.9764(6) 0.8896(4) 0.084(5) Uani 1 1 d G . .
H24A H 0.7762 0.9979 0.8851 0.101 Uiso 1 1 calc R . .
C25 C 0.5046(6) 0.9091(5) 0.4251(5) 0.023(2) Uani 1 1 d . . .
C26 C 0.4993(6) 0.8444(5) 0.3948(4) 0.026(2) Uani 1 1 d . . .
C27 C 0.4931(7) 0.7667(5) 0.3608(4) 0.026(2) Uani 1 1 d . . .
C28 C 0.4004(8) 0.7184(5) 0.3455(5) 0.039(3) Uani 1 1 d . . .
H28A H 0.3431 0.7334 0.3560 0.046 Uiso 1 1 calc R . .
C29 C 0.3939(8) 0.6435(6) 0.3124(6) 0.045(3) Uani 1 1 d . . .
H29A H 0.3304 0.6101 0.3015 0.054 Uiso 1 1 calc R . .
C30 C 0.4751(9) 0.6176(6) 0.2958(5) 0.046(3) Uani 1 1 d . . .
H30A H 0.4661 0.5685 0.2733 0.055 Uiso 1 1 calc R . .
C31 C 0.5683(8) 0.6647(6) 0.3126(6) 0.044(3) Uani 1 1 d . . .
H31A H 0.6253 0.6482 0.3031 0.053 Uiso 1 1 calc R . .
C32 C 0.5777(8) 0.7383(6) 0.3444(5) 0.039(3) Uani 1 1 d . . .
H32A H 0.6420 0.7707 0.3554 0.047 Uiso 1 1 calc R . .
C33 C 0.9557(6) 0.9971(5) 0.6438(5) 0.027(2) Uani 1 1 d . . .
C34 C 0.9564(7) 1.0186(5) 0.7074(5) 0.032(2) Uani 1 1 d . . .
C35 C 0.9652(7) 1.0433(6) 0.7832(5) 0.032(2) Uani 1 1 d . . .
C36 C 1.0109(8) 1.0043(7) 0.8364(5) 0.055(3) Uani 1 1 d . . .
H36A H 1.0355 0.9619 0.8235 0.066 Uiso 1 1 calc R . .
C37 C 1.0198(10) 1.0291(8) 0.9094(6) 0.069(4) Uani 1 1 d . . .
H37A H 1.0496 1.0031 0.9462 0.083 Uiso 1 1 calc R . .
C38 C 0.9827(12) 1.0948(9) 0.9269(6) 0.086(6) Uani 1 1 d . . .
H38A H 0.9919 1.1126 0.9759 0.103 Uiso 1 1 calc R . .
C39 C 0.9346(11) 1.1329(7) 0.8755(6) 0.073(4) Uani 1 1 d . . .
H39A H 0.9086 1.1743 0.8891 0.088 Uiso 1 1 calc R . .
C40 C 0.9251(9) 1.1092(6) 0.8036(5) 0.047(3) Uani 1 1 d . . .
H40A H 0.8931 1.1348 0.7676 0.056 Uiso 1 1 calc R . .
C41 C 0.7709(7) 1.1602(5) 0.5774(4) 0.028(2) Uani 1 1 d . . .
C42 C 0.7946(7) 1.2237(5) 0.5590(5) 0.030(2) Uani 1 1 d . . .
C43 C 0.8241(5) 1.3022(3) 0.5438(3) 0.028(2) Uani 1 1 d G . .
C44 C 0.8097(5) 1.3205(3) 0.4722(3) 0.046(3) Uani 1 1 d G . .
H44A H 0.7792 1.2826 0.4336 0.055 Uiso 1 1 calc R . .
C45 C 0.8409(6) 1.3953(4) 0.4581(3) 0.065(4) Uani 1 1 d G . .
H45A H 0.8312 1.4075 0.4102 0.079 Uiso 1 1 calc R . .
C46 C 0.8864(6) 1.4519(3) 0.5156(4) 0.061(4) Uani 1 1 d G . .
H46A H 0.9073 1.5019 0.5062 0.073 Uiso 1 1 calc R . .
C47 C 0.9009(5) 1.4336(3) 0.5873(3) 0.049(3) Uani 1 1 d G . .
H47A H 0.9314 1.4715 0.6258 0.059 Uiso 1 1 calc R . .
C48 C 0.8697(5) 1.3588(3) 0.6013(2) 0.034(2) Uani 1 1 d G . .
H48A H 0.8794 1.3466 0.6492 0.041 Uiso 1 1 calc R . .
C49 C 0.7757(6) 1.0256(5) 0.4244(4) 0.025(2) Uani 1 1 d . . .
C50 C 0.7987(6) 1.0683(5) 0.3796(5) 0.024(2) Uani 1 1 d . . .
C51 C 0.8251(7) 1.1202(5) 0.3290(5) 0.030(2) Uani 1 1 d . . .
C52 C 0.7783(9) 1.1042(7) 0.2556(6) 0.052(3) Uani 1 1 d . . .
H52A H 0.7295 1.0594 0.2390 0.062 Uiso 1 1 calc R . .
C53 C 0.8045(9) 1.1550(7) 0.2073(6) 0.058(3) Uani 1 1 d . . .
H53A H 0.7752 1.1436 0.1577 0.070 Uiso 1 1 calc R . .
C54 C 0.8728(10) 1.2216(8) 0.2319(8) 0.067(4) Uani 1 1 d . . .
H54A H 0.8882 1.2565 0.1993 0.081 Uiso 1 1 calc R . .
C55 C 0.9193(9) 1.2377(7) 0.3043(8) 0.067(4) Uani 1 1 d . . .
H55A H 0.9682 1.2825 0.3207 0.081 Uiso 1 1 calc R . .
C56 C 0.8929(8) 1.1868(6) 0.3528(6) 0.050(3) Uani 1 1 d . . .
H56A H 0.9222 1.1985 0.4024 0.059 Uiso 1 1 calc R . .
C57 C 0.9529(6) 0.8470(5) 0.4609(5) 0.026(2) Uani 1 1 d . . .
C58 C 0.9272(6) 0.7867(5) 0.4222(5) 0.026(2) Uani 1 1 d . . .
C59 C 0.8941(7) 0.7109(5) 0.3797(4) 0.027(2) Uani 1 1 d . . .
C60 C 0.8440(7) 0.6522(5) 0.4096(5) 0.035(2) Uani 1 1 d . . .
H60A H 0.8321 0.6596 0.4564 0.043 Uiso 1 1 calc R . .
C61 C 0.8108(8) 0.5812(6) 0.3695(5) 0.046(3) Uani 1 1 d . . .
H61A H 0.7758 0.5410 0.3895 0.055 Uiso 1 1 calc R . .
C62 C 0.8287(8) 0.5689(6) 0.2998(6) 0.046(3) Uani 1 1 d . . .
H62A H 0.8064 0.5209 0.2736 0.056 Uiso 1 1 calc R . .
C63 C 0.8790(8) 0.6274(6) 0.2707(6) 0.045(3) Uani 1 1 d . . .
H63A H 0.8919 0.6199 0.2243 0.054 Uiso 1 1 calc R . .
C64 C 0.9110(7) 0.6983(5) 0.3101(5) 0.034(2) Uani 1 1 d . . .
H64A H 0.9448 0.7385 0.2895 0.041 Uiso 1 1 calc R . .
C65 C 0.7361(9) 0.8935(7) 0.1403(5) 0.061(4) Uani 1 1 d . . .
H65A H 0.7762 0.9442 0.1428 0.092 Uiso 1 1 calc R . .
H65B H 0.6677 0.8960 0.1439 0.092 Uiso 1 1 calc R . .
H65C H 0.7345 0.8655 0.0947 0.092 Uiso 1 1 calc R . .
C66 C 0.7051(8) 0.7591(6) 0.1948(6) 0.059(3) Uani 1 1 d . . .
H66A H 0.7246 0.7255 0.2302 0.089 Uiso 1 1 calc R . .
H66B H 0.7046 0.7369 0.1469 0.089 Uiso 1 1 calc R . .
H66C H 0.6379 0.7667 0.1966 0.089 Uiso 1 1 calc R . .
C67 C 0.8957(13) 0.7833(10) 0.8514(8) 0.106(6) Uani 1 1 d . . .
C68 C 0.6944(12) 0.7685(11) 0.7893(11) 0.131(8) Uani 1 1 d . . .
C69 C 0.3944(13) 0.8425(12) 0.0710(11) 0.135(8) Uani 1 1 d . . .
H69A H 0.3860 0.8941 0.0762 0.203 Uiso 1 1 calc R . .
H69B H 0.3416 0.8137 0.0318 0.203 Uiso 1 1 calc R . .
H69C H 0.4601 0.8419 0.0603 0.203 Uiso 1 1 calc R . .
C70 C 0.4051(14) 0.7109(9) 0.1224(9) 0.125(7) Uani 1 1 d . . .
H70A H 0.4024 0.6833 0.1642 0.188 Uiso 1 1 calc R . .
H70B H 0.4705 0.7139 0.1099 0.188 Uiso 1 1 calc R . .
H70C H 0.3520 0.6852 0.0818 0.188 Uiso 1 1 calc R . .
C71 C 0.482(2) 0.7012(18) 0.8980(18) 0.229(13) Uiso 1 1 d . . .
C72 C 0.5578(17) 0.6104(13) 0.9939(12) 0.144(8) Uiso 1 1 d . . .
O1 O 0.1663(5) 0.6998(4) 0.2262(3) 0.0433(18) Uani 1 1 d . . .
O2 O -0.0134(5) 0.6676(5) 0.1241(3) 0.059(2) Uani 1 1 d . . .
O3 O 0.0493(6) 0.5556(4) 0.1974(6) 0.078(3) Uani 1 1 d . . .
O4 O 0.1552(5) 0.6855(5) 0.0760(4) 0.057(2) Uani 1 1 d . . .
O5 O 0.0031(6) 0.4230(4) 0.2636(3) 0.0442(19) Uani 1 1 d . . .
O6 O -0.1304(6) 0.4730(4) 0.1504(4) 0.059(2) Uani 1 1 d . . .
O7 O -0.0464(6) 0.3530(4) 0.1216(4) 0.055(2) Uani 1 1 d . . .
O8 O 0.1339(6) 0.4363(4) 0.1674(6) 0.078(3) Uani 1 1 d . . .
O9 O -0.1916(7) 0.5857(4) 0.0784(4) 0.075(3) Uani 1 1 d . . .
O10 O -0.1919(7) 0.6219(4) -0.0534(3) 0.071(3) Uani 1 1 d . . .
O11 O -0.1697(6) 0.7409(4) 0.0579(4) 0.0492(19) Uani 1 1 d . . .
O12 O -0.0137(5) 0.7050(5) -0.0073(3) 0.057(2) Uani 1 1 d . . .
O13 O 0.1649(5) 0.7754(4) -0.0379(4) 0.056(2) Uani 1 1 d . . .
O14 O 0.2149(6) 0.6269(4) -0.0387(4) 0.061(2) Uani 1 1 d . . .
O15 O 0.2758(7) 0.5152(4) 0.0338(3) 0.072(3) Uani 1 1 d . . .
O16 O -0.3389(5) 0.5401(4) -0.1672(4) 0.048(2) Uani 1 1 d . . .
O17 O -0.2155(6) 0.4269(4) -0.1485(5) 0.069(3) Uani 1 1 d . . .
O18 O 0.3351(5) 0.5333(4) -0.0987(4) 0.053(2) Uani 1 1 d . . .
O19 O -0.0602(8) 0.4541(6) 0.0462(6) 0.023(3) Uani 0.50 1 d P . .
O20 O 0.1021(8) 0.4697(6) -0.0001(5) 0.022(3) Uani 0.50 1 d P . .
O21 O 0.0616(8) 0.5105(6) 0.0801(5) 0.018(3) Uani 0.50 1 d PU . .
O22 O 0.0193(8) 0.5843(6) 0.0278(5) 0.020(3) Uani 0.50 1 d P . .
O23 O 0.7694(5) 0.8886(4) 0.2832(4) 0.0475(19) Uani 1 1 d . . .
O24 O 0.8342(6) 0.8365(4) 0.7273(4) 0.061(2) Uani 1 1 d . . .
O25 O 0.4903(9) 0.8453(8) 0.1895(9) 0.184(8) Uani 1 1 d . . .
O26 O 0.5739(9) 0.7592(6) 1.0295(6) 0.117(4) Uani 1 1 d . . .
O1W O 0.4100(5) 1.0413(4) 0.7316(4) 0.0478(19) Uani 1 1 d . . .
H1WA H 0.4164 1.0894 0.7363 0.057 Uiso 1 1 d R . .
H1WB H 0.3854 1.0160 0.7630 0.057 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag1' 0.88(2) . ?
Ag1 C1 2.203(9) . ?
Ag1 C41 2.270(8) 2_676 ?
Ag1 Ag3' 2.368(17) . ?
Ag1 C49 2.592(9) 2_676 ?
Ag1 C42 2.643(9) 2_676 ?
Ag1 Ag3 2.8988(12) . ?
Ag1 Ag4 2.9175(9) . ?
Ag1 Ag6 3.1342(11) 2_676 ?
Ag1 Ag2 3.1377(13) . ?
Ag1 Ag10 3.3668(12) 2_676 ?
Ag1' C41 2.145(18) 2_676 ?
Ag1' C1 2.255(18) . ?
Ag1' C42 2.444(18) 2_676 ?
Ag1' Ag2 2.617(19) . ?
Ag1' Ag4 2.838(15) . ?
Ag1' Ag3' 2.93(3) . ?
Ag1' Ag6 2.994(15) 2_676 ?
Ag1' Ag2' 3.07(2) . ?
Ag1' Ag3 3.278(17) . ?
Ag2 Ag2' 0.887(16) . ?
Ag2 C1 2.220(10) . ?
Ag2 C9 2.281(8) . ?
Ag2 Ag4 3.0238(9) . ?
Ag2 Ag5 3.0971(13) . ?
Ag2 Ag3 3.1032(14) . ?
Ag2 Ag7 3.1121(11) . ?
Ag2' C1 2.107(16) . ?
Ag2' C9 2.524(18) . ?
Ag2' C17 2.536(19) . ?
Ag2' Ag3 2.542(17) . ?
Ag2' Ag5 2.573(13) . ?
Ag2' Ag4 3.068(15) . ?
Ag2' Ag3' 3.09(2) . ?
Ag2' Ag7 3.268(14) . ?
Ag2' Ag6 3.330(17) . ?
Ag3 Ag3' 0.867(17) . ?
Ag3 C1 2.278(9) . ?
Ag3 O1W 2.396(7) . ?
Ag3 C25 2.450(8) 2_676 ?
Ag3 C17 2.521(9) . ?
Ag3 Ag4 2.8364(7) . ?
Ag3 Ag6 3.2028(11) . ?
Ag3' O1W 2.232(17) . ?
Ag3' C1 2.353(17) . ?
Ag3' C25 2.370(17) 2_676 ?
Ag3' Ag4 2.796(15) . ?
Ag3' Ag7 3.321(17) 2_676 ?
Ag4 C25 2.108(9) . ?
Ag4 C25 2.108(9) 2_676 ?
Ag4 Ag3' 2.796(16) 2_676 ?
Ag4 Ag3 2.8364(7) 2_676 ?
Ag4 Ag1' 2.838(15) 2_676 ?
Ag4 Ag1 2.9175(9) 2_676 ?
Ag4 Ag2 3.0238(9) 2_676 ?
Ag5 C9 2.337(9) . ?
Ag5 O24 2.395(7) . ?
Ag5 C17 2.415(10) . ?
Ag5 C33 2.499(9) . ?
Ag5 C34 2.656(8) . ?
Ag5 Ag7 2.9805(9) . ?
Ag5 Ag6 2.9906(11) . ?
Ag5 Ag8 3.2245(11) . ?
Ag6 C41 2.056(9) . ?
Ag6 C17 2.103(9) . ?
Ag6 Ag1' 2.994(15) 2_676 ?
Ag6 Ag10 3.0739(11) . ?
Ag6 Ag1 3.1342(11) 2_676 ?
Ag7 C49 2.078(9) . ?
Ag7 C9 2.114(8) . ?
Ag7 Ag8 3.0698(10) . ?
Ag7 Ag9 3.0786(10) . ?
Ag7 Ag10 3.1192(10) . ?
Ag7 Ag3' 3.321(17) 2_676 ?
Ag8 C57 2.114(9) . ?
Ag8 C33 2.114(9) . ?
Ag8 Ag9 2.9216(10) 2_776 ?
Ag8 Ag9 2.9916(9) . ?
Ag8 Ag10 3.1114(11) . ?
Ag8 Ag10 3.1650(11) 2_776 ?
Ag9 O23 2.300(6) . ?
Ag9 C57 2.401(9) . ?
Ag9 C33 2.420(9) 2_776 ?
Ag9 C49 2.545(9) . ?
Ag9 Ag8 2.9216(10) 2_776 ?
Ag9 Ag10 3.0858(10) 2_776 ?
Ag10 C57 2.299(8) 2_776 ?
Ag10 C41 2.438(10) . ?
Ag10 C33 2.520(9) . ?
Ag10 C49 2.657(8) . ?
Ag10 Ag9 3.0858(10) 2_776 ?
Ag10 Ag8 3.1651(11) 2_776 ?
Ag10 Ag1 3.3667(12) 2_676 ?
W1 O13 1.655(6) . ?
W1 O7 1.877(6) 2_565 ?
W1 O4 1.883(6) . ?
W1 O12 1.925(7) . ?
W1 O14 1.958(8) . ?
W1 O22 2.433(10) . ?
W1 O19 2.486(10) 2_565 ?
W2 O5 1.666(6) . ?
W2 O7 1.895(7) . ?
W2 O3 1.898(7) . ?
W2 O8 1.911(8) . ?
W2 O6 1.932(7) . ?
W2 O21 2.435(9) . ?
W2 O19 2.496(10) . ?
W3 O11 1.740(7) . ?
W3 O12 1.853(7) . ?
W3 O9 1.857(7) . ?
W3 O10 1.864(6) . ?
W3 O2 1.887(6) . ?
W3 O20 2.526(11) 2_565 ?
W4 O1 1.660(6) . ?
W4 O3 1.865(7) . ?
W4 O4 1.887(7) . ?
W4 O2 1.919(7) . ?
W4 O17 1.976(8) 2_565 ?
W4 O21 2.473(11) . ?
W4 O22 2.482(10) . ?
W5 O18 1.670(7) . ?
W5 O6 1.865(7) 2_565 ?
W5 O15 1.890(6) . ?
W5 O9 1.912(7) 2_565 ?
W5 O14 1.962(7) . ?
W5 O20 2.411(10) . ?
W5 O19 2.507(12) 2_565 ?
W6 O16 1.675(6) . ?
W6 O8 1.871(8) 2_565 ?
W6 O15 1.878(7) 2_565 ?
W6 O10 1.910(7) . ?
W6 O17 1.943(7) . ?
W6 O20 2.474(10) 2_565 ?
W6 O21 2.512(11) 2_565 ?
P1 O19 1.491(10) 2_565 ?
P1 O19 1.491(10) . ?
P1 O22 1.528(10) 2_565 ?
P1 O22 1.528(10) . ?
P1 O21 1.550(9) . ?
P1 O21 1.550(9) 2_565 ?
P1 O20 1.594(12) 2_565 ?
P1 O20 1.595(12) . ?
S1 O23 1.571(7) . ?
S1 C66 1.744(10) . ?
S1 C65 1.799(11) . ?
S2 S2' 1.46(2) . ?
S2 O24 1.468(8) . ?
S2 C68 1.724(14) . ?
S2 C67 1.841(14) . ?
S2' O24 1.41(2) . ?
S2' C67 1.59(2) . ?
S2' C68 2.16(3) . ?
S3 O25 1.507(11) . ?
S3 C69 1.56(2) . ?
S3 C70 1.816(18) . ?
S4 O26 1.575(13) . ?
S4 S4' 1.65(2) . ?
S4 C71 1.73(3) . ?
S4 C72 1.83(2) . ?
S4' O26 1.624(17) . ?
S4' C72 1.70(3) . ?
S4' C71 2.01(4) . ?
C1 C2 1.218(12) . ?
C2 C3 1.449(12) . ?
C3 C4 1.353(14) . ?
C3 C8 1.435(15) . ?
C4 C5 1.400(15) . ?
C5 C6 1.412(18) . ?
C6 C7 1.365(17) . ?
C7 C8 1.386(14) . ?
C9 C10 1.232(12) . ?
C10 C11 1.484(11) . ?
C11 C12 1.3900 . ?
C11 C16 1.3900 . ?
C12 C13 1.3900 . ?
C13 C14 1.3900 . ?
C14 C15 1.3900 . ?
C15 C16 1.3900 . ?
C17 C18 1.173(12) . ?
C18 C19 1.453(11) . ?
C19 C20 1.3900 . ?
C19 C24 1.3900 . ?
C20 C21 1.3900 . ?
C21 C22 1.3900 . ?
C22 C23 1.3900 . ?
C23 C24 1.3900 . ?
C25 C26 1.245(12) . ?
C25 Ag3' 2.370(17) 2_676 ?
C25 Ag3 2.450(8) 2_676 ?
C26 C27 1.481(12) . ?
C27 C28 1.352(12) . ?
C27 C32 1.432(13) . ?
C28 C29 1.427(13) . ?
C29 C30 1.367(15) . ?
C30 C31 1.349(14) . ?
C31 C32 1.390(13) . ?
C33 C34 1.227(12) . ?
C33 Ag9 2.420(8) 2_776 ?
C34 C35 1.438(13) . ?
C35 C36 1.376(14) . ?
C35 C40 1.462(15) . ?
C36 C37 1.388(15) . ?
C37 C38 1.42(2) . ?
C38 C39 1.358(19) . ?
C39 C40 1.362(14) . ?
C41 C42 1.217(12) . ?
C41 Ag1' 2.145(18) 2_676 ?
C41 Ag1 2.270(8) 2_676 ?
C42 C43 1.456(10) . ?
C42 Ag1' 2.444(18) 2_676 ?
C42 Ag1 2.643(9) 2_676 ?
C43 C44 1.3900 . ?
C43 C48 1.3900 . ?
C44 C45 1.3900 . ?
C45 C46 1.3900 . ?
C46 C47 1.3900 . ?
C47 C48 1.3900 . ?
C49 C50 1.223(11) . ?
C49 Ag1 2.592(9) 2_676 ?
C50 C51 1.423(12) . ?
C51 C56 1.350(13) . ?
C51 C52 1.384(13) . ?
C52 C53 1.377(14) . ?
C53 C54 1.355(16) . ?
C54 C55 1.366(17) . ?
C55 C56 1.382(14) . ?
C57 C58 1.215(12) . ?
C57 Ag10 2.299(8) 2_776 ?
C58 C59 1.475(12) . ?
C59 C60 1.359(12) . ?
C59 C64 1.384(12) . ?
C60 C61 1.386(13) . ?
C61 C62 1.390(14) . ?
C62 C63 1.348(14) . ?
C63 C64 1.378(13) . ?
O6 W5 1.865(7) 2_565 ?
O7 W1 1.877(6) 2_565 ?
O8 W6 1.871(8) 2_565 ?
O9 W5 1.912(7) 2_565 ?
O15 W6 1.878(7) 2_565 ?
O17 W4 1.976(8) 2_565 ?
O19 O21 1.741(14) . ?
O19 O22 1.751(16) 2_565 ?
O19 O20 1.796(15) 2_565 ?
O19 W1 2.486(10) 2_565 ?
O19 W5 2.507(12) 2_565 ?
O20 O22 1.709(14) 2_565 ?
O20 O19 1.796(15) 2_565 ?
O20 W6 2.474(10) 2_565 ?
O20 W3 2.526(11) 2_565 ?
O21 W6 2.512(11) 2_565 ?
O22 O20 1.709(14) 2_565 ?
O22 O19 1.751(16) 2_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1' Ag1 C1 81.9(11) . . ?
Ag1' Ag1 C41 70.6(11) . 2_676 ?
C1 Ag1 C41 142.2(3) . 2_676 ?
Ag1' Ag1 Ag3' 122.2(11) . . ?
C1 Ag1 Ag3' 61.8(5) . . ?
C41 Ag1 Ag3' 155.9(4) 2_676 . ?
Ag1' Ag1 C49 165.5(10) . 2_676 ?
C1 Ag1 C49 112.5(3) . 2_676 ?
C41 Ag1 C49 97.3(3) 2_676 2_676 ?
Ag3' Ag1 C49 66.3(4) . 2_676 ?
Ag1' Ag1 C42 67.4(11) . 2_676 ?
C1 Ag1 C42 117.6(3) . 2_676 ?
C41 Ag1 C42 27.4(3) 2_676 2_676 ?
Ag3' Ag1 C42 168.9(4) . 2_676 ?
C49 Ag1 C42 105.7(3) 2_676 2_676 ?
Ag1' Ag1 Ag3 107.8(10) . . ?
C1 Ag1 Ag3 50.8(2) . . ?
C41 Ag1 Ag3 162.9(2) 2_676 . ?
Ag3' Ag1 Ag3 15.0(4) . . ?
C49 Ag1 Ag3 81.29(18) 2_676 . ?
C42 Ag1 Ag3 168.4(2) 2_676 . ?
Ag1' Ag1 Ag4 76.1(10) . . ?
C1 Ag1 Ag4 91.9(2) . . ?
C41 Ag1 Ag4 105.6(2) 2_676 . ?
Ag3' Ag1 Ag4 62.9(4) . . ?
C49 Ag1 Ag4 100.3(2) 2_676 . ?
C42 Ag1 Ag4 127.6(2) 2_676 . ?
Ag3 Ag1 Ag4 58.37(2) . . ?
Ag1' Ag1 Ag6 72.7(10) . 2_676 ?
C1 Ag1 Ag6 149.7(3) . 2_676 ?
C41 Ag1 Ag6 40.9(2) 2_676 2_676 ?
Ag3' Ag1 Ag6 119.1(4) . 2_676 ?
C49 Ag1 Ag6 92.85(18) 2_676 2_676 ?
C42 Ag1 Ag6 67.6(2) 2_676 2_676 ?
Ag3 Ag1 Ag6 122.02(3) . 2_676 ?
Ag4 Ag1 Ag6 66.40(2) . 2_676 ?
Ag1' Ag1 Ag2 47.0(10) . . ?
C1 Ag1 Ag2 45.0(3) . . ?
C41 Ag1 Ag2 117.4(2) 2_676 . ?
Ag3' Ag1 Ag2 76.7(4) . . ?
C49 Ag1 Ag2 142.96(18) 2_676 . ?
C42 Ag1 Ag2 111.1(2) 2_676 . ?
Ag3 Ag1 Ag2 61.72(3) . . ?
Ag4 Ag1 Ag2 59.78(2) . . ?
Ag6 Ag1 Ag2 104.67(4) 2_676 . ?
Ag1' Ag1 Ag10 116.5(10) . 2_676 ?
C1 Ag1 Ag10 153.8(2) . 2_676 ?
C41 Ag1 Ag10 46.4(2) 2_676 2_676 ?
Ag3' Ag1 Ag10 114.9(4) . 2_676 ?
C49 Ag1 Ag10 50.95(17) 2_676 2_676 ?
C42 Ag1 Ag10 60.1(2) 2_676 2_676 ?
Ag3 Ag1 Ag10 129.66(4) . 2_676 ?
Ag4 Ag1 Ag10 110.01(3) . 2_676 ?
Ag6 Ag1 Ag10 56.30(2) 2_676 2_676 ?
Ag2 Ag1 Ag10 160.49(4) . 2_676 ?
Ag1 Ag1' C41 86.6(13) . 2_676 ?
Ag1 Ag1' C1 75.3(11) . . ?
C41 Ag1' C1 148.2(10) 2_676 . ?
Ag1 Ag1' C42 93.1(13) . 2_676 ?
C41 Ag1' C42 29.9(4) 2_676 2_676 ?
C1 Ag1' C42 124.1(7) . 2_676 ?
Ag1 Ag1' Ag2 118.7(12) . . ?
C41 Ag1' Ag2 154.1(11) 2_676 . ?
C1 Ag1' Ag2 53.6(4) . . ?
C42 Ag1' Ag2 141.3(9) 2_676 . ?
Ag1 Ag1' Ag4 86.3(11) . . ?
C41 Ag1' Ag4 112.1(6) 2_676 . ?
C1 Ag1' Ag4 92.9(6) . . ?
C42 Ag1' Ag4 141.6(7) 2_676 . ?
Ag2 Ag1' Ag4 67.2(4) . . ?
Ag1 Ag1' Ag3' 43.1(9) . . ?
C41 Ag1' Ag3' 125.8(10) 2_676 . ?
C1 Ag1' Ag3' 51.9(5) . . ?
C42 Ag1' Ag3' 135.9(10) 2_676 . ?
Ag2 Ag1' Ag3' 77.1(5) . . ?
Ag4 Ag1' Ag3' 57.9(4) . . ?
Ag1 Ag1' Ag6 90.9(11) . 2_676 ?
C41 Ag1' Ag6 43.4(4) 2_676 2_676 ?
C1 Ag1' Ag6 158.4(8) . 2_676 ?
C42 Ag1' Ag6 72.3(4) 2_676 2_676 ?
Ag2 Ag1' Ag6 124.3(7) . 2_676 ?
Ag4 Ag1' Ag6 69.3(3) . 2_676 ?
Ag3' Ag1' Ag6 106.8(7) . 2_676 ?
Ag1 Ag1' Ag2' 103.2(12) . . ?
C41 Ag1' Ag2' 167.9(10) 2_676 . ?
C1 Ag1' Ag2' 43.3(5) . . ?
C42 Ag1' Ag2' 152.7(9) 2_676 . ?
Ag2 Ag1' Ag2' 15.4(3) . . ?
Ag4 Ag1' Ag2' 62.4(4) . . ?
Ag3' Ag1' Ag2' 61.8(6) . . ?
Ag6 Ag1' Ag2' 128.2(6) 2_676 . ?
Ag1 Ag1' Ag3 57.3(9) . . ?
C41 Ag1' Ag3 140.1(10) 2_676 . ?
C1 Ag1' Ag3 44.0(4) . . ?
C42 Ag1' Ag3 148.6(9) 2_676 . ?
Ag2 Ag1' Ag3 62.3(3) . . ?
Ag4 Ag1' Ag3 54.7(3) . . ?
Ag3' Ag1' Ag3 14.7(3) . . ?
Ag6 Ag1' Ag3 114.5(5) 2_676 . ?
Ag2' Ag1' Ag3 47.1(4) . . ?
Ag2' Ag2 C1 71.1(9) . . ?
Ag2' Ag2 C9 95.4(10) . . ?
C1 Ag2 C9 152.2(3) . . ?
Ag2' Ag2 Ag1' 112.7(11) . . ?
C1 Ag2 Ag1' 54.8(5) . . ?
C9 Ag2 Ag1' 149.7(5) . . ?
Ag2' Ag2 Ag4 84.5(11) . . ?
C1 Ag2 Ag4 88.8(2) . . ?
C9 Ag2 Ag4 114.7(2) . . ?
Ag1' Ag2 Ag4 59.9(3) . . ?
Ag2' Ag2 Ag5 46.9(9) . . ?
C1 Ag2 Ag5 114.9(2) . . ?
C9 Ag2 Ag5 48.7(2) . . ?
Ag1' Ag2 Ag5 156.0(4) . . ?
Ag4 Ag2 Ag5 101.05(3) . . ?
Ag2' Ag2 Ag3 44.1(10) . . ?
C1 Ag2 Ag3 47.1(2) . . ?
C9 Ag2 Ag3 135.1(2) . . ?
Ag1' Ag2 Ag3 69.3(5) . . ?
Ag4 Ag2 Ag3 55.13(2) . . ?
Ag5 Ag2 Ag3 88.04(4) . . ?
Ag2' Ag2 Ag7 92.2(9) . . ?
C1 Ag2 Ag7 155.8(2) . . ?
C9 Ag2 Ag7 42.8(2) . . ?
Ag1' Ag2 Ag7 121.5(4) . . ?
Ag4 Ag2 Ag7 71.89(2) . . ?
Ag5 Ag2 Ag7 57.37(2) . . ?
Ag3 Ag2 Ag7 108.75(3) . . ?
Ag2' Ag2 Ag1 98.5(10) . . ?
C1 Ag2 Ag1 44.6(2) . . ?
C9 Ag2 Ag1 162.5(2) . . ?
Ag1' Ag2 Ag1 14.3(5) . . ?
Ag4 Ag2 Ag1 56.49(2) . . ?
Ag5 Ag2 Ag1 143.13(4) . . ?
Ag3 Ag2 Ag1 55.35(3) . . ?
Ag7 Ag2 Ag1 125.57(4) . . ?
Ag2 Ag2' C1 85.4(10) . . ?
Ag2 Ag2' C9 64.1(9) . . ?
C1 Ag2' C9 141.1(9) . . ?
Ag2 Ag2' C17 168.8(13) . . ?
C1 Ag2' C17 103.2(7) . . ?
C9 Ag2' C17 110.6(6) . . ?
Ag2 Ag2' Ag3 121.9(11) . . ?
C1 Ag2' Ag3 57.8(5) . . ?
C9 Ag2' Ag3 159.7(7) . . ?
C17 Ag2' Ag3 59.5(5) . . ?
Ag2 Ag2' Ag5 118.6(12) . . ?
C1 Ag2' Ag5 148.6(7) . . ?
C9 Ag2' Ag5 54.6(3) . . ?
C17 Ag2' Ag5 56.4(4) . . ?
Ag3 Ag2' Ag5 114.8(6) . . ?
Ag2 Ag2' Ag4 78.8(10) . . ?
C1 Ag2' Ag4 89.7(5) . . ?
C9 Ag2' Ag4 106.2(5) . . ?
C17 Ag2' Ag4 94.0(6) . . ?
Ag3 Ag2' Ag4 59.9(3) . . ?
Ag5 Ag2' Ag4 113.5(5) . . ?
Ag2 Ag2' Ag1' 51.8(9) . . ?
C1 Ag2' Ag1' 47.3(5) . . ?
C9 Ag2' Ag1' 115.0(7) . . ?
C17 Ag2' Ag1' 130.1(8) . . ?
Ag3 Ag2' Ag1' 70.8(5) . . ?
Ag5 Ag2' Ag1' 164.1(6) . . ?
Ag4 Ag2' Ag1' 55.1(4) . . ?
Ag2 Ag2' Ag3' 108.2(11) . . ?
C1 Ag2' Ag3' 49.6(5) . . ?
C9 Ag2' Ag3' 160.2(7) . . ?
C17 Ag2' Ag3' 73.3(6) . . ?
Ag3 Ag2' Ag3' 13.8(3) . . ?
Ag5 Ag2' Ag3' 128.1(7) . . ?
Ag4 Ag2' Ag3' 54.0(4) . . ?
Ag1' Ag2' Ag3' 56.9(6) . . ?
Ag2 Ag2' Ag7 72.1(8) . . ?
C1 Ag2' Ag7 151.5(7) . . ?
C9 Ag2' Ag7 40.3(3) . . ?
C17 Ag2' Ag7 97.4(5) . . ?
Ag3 Ag2' Ag7 120.3(6) . . ?
Ag5 Ag2' Ag7 60.0(3) . . ?
Ag4 Ag2' Ag7 69.2(3) . . ?
Ag1' Ag2' Ag7 104.2(5) . . ?
Ag3' Ag2' Ag7 120.9(6) . . ?
Ag2 Ag2' Ag6 129.9(11) . . ?
C1 Ag2' Ag6 122.2(8) . . ?
C9 Ag2' Ag6 96.4(5) . . ?
C17 Ag2' Ag6 39.2(3) . . ?
Ag3 Ag2' Ag6 64.5(4) . . ?
Ag5 Ag2' Ag6 59.2(3) . . ?
Ag4 Ag2' Ag6 62.3(3) . . ?
Ag1' Ag2' Ag6 115.0(6) . . ?
Ag3' Ag2' Ag6 74.2(5) . . ?
Ag7 Ag2' Ag6 65.6(3) . . ?
Ag3' Ag3 C1 84.1(10) . . ?
Ag3' Ag3 O1W 68.7(11) . . ?
C1 Ag3 O1W 115.7(3) . . ?
Ag3' Ag3 C25 74.5(10) . 2_676 ?
C1 Ag3 C25 136.1(3) . 2_676 ?
O1W Ag3 C25 91.8(3) . 2_676 ?
Ag3' Ag3 C17 176.8(10) . . ?
C1 Ag3 C17 98.9(3) . . ?
O1W Ag3 C17 110.7(3) . . ?
C25 Ag3 C17 102.5(3) 2_676 . ?
Ag3' Ag3 Ag2' 121.6(11) . . ?
C1 Ag3 Ag2' 51.5(4) . . ?
O1W Ag3 Ag2' 157.4(4) . . ?
C25 Ag3 Ag2' 110.0(4) 2_676 . ?
C17 Ag3 Ag2' 60.1(4) . . ?
Ag3' Ag3 Ag4 78.5(10) . . ?
C1 Ag3 Ag4 92.5(2) . . ?
O1W Ag3 Ag4 133.05(16) . . ?
C25 Ag3 Ag4 46.3(2) 2_676 . ?
C17 Ag3 Ag4 100.2(2) . . ?
Ag2' Ag3 Ag4 69.3(3) . . ?
Ag3' Ag3 Ag1 45.1(10) . . ?
C1 Ag3 Ag1 48.6(2) . . ?
O1W Ag3 Ag1 109.62(17) . . ?
C25 Ag3 Ag1 91.3(2) 2_676 . ?
C17 Ag3 Ag1 136.7(2) . . ?
Ag2' Ag3 Ag1 76.6(3) . . ?
Ag4 Ag3 Ag1 61.14(2) . . ?
Ag3' Ag3 Ag2 107.8(10) . . ?
C1 Ag3 Ag2 45.6(2) . . ?
O1W Ag3 Ag2 160.85(17) . . ?
C25 Ag3 Ag2 105.6(2) 2_676 . ?
C17 Ag3 Ag2 73.8(2) . . ?
Ag2' Ag3 Ag2 14.0(3) . . ?
Ag4 Ag3 Ag2 61.01(2) . . ?
Ag1 Ag3 Ag2 62.93(3) . . ?
Ag3' Ag3 Ag6 136.2(10) . . ?
C1 Ag3 Ag6 121.2(2) . . ?
O1W Ag3 Ag6 118.36(17) . . ?
C25 Ag3 Ag6 62.56(19) 2_676 . ?
C17 Ag3 Ag6 41.0(2) . . ?
Ag2' Ag3 Ag6 69.8(3) . . ?
Ag4 Ag3 Ag6 66.35(2) . . ?
Ag1 Ag3 Ag6 124.69(4) . . ?
Ag2 Ag3 Ag6 77.74(3) . . ?
Ag3' Ag3 Ag1' 59.5(11) . . ?
C1 Ag3 Ag1' 43.4(4) . . ?
O1W Ag3 Ag1' 124.2(4) . . ?
C25 Ag3 Ag1' 93.0(3) 2_676 . ?
C17 Ag3 Ag1' 122.2(5) . . ?
Ag2' Ag3 Ag1' 62.2(5) . . ?
Ag4 Ag3 Ag1' 54.7(3) . . ?
Ag1 Ag3 Ag1' 14.9(4) . . ?
Ag2 Ag3 Ag1' 48.3(4) . . ?
Ag6 Ag3 Ag1' 112.9(4) . . ?
Ag3 Ag3' O1W 90.1(12) . . ?
Ag3 Ag3' C1 74.4(10) . . ?
O1W Ag3' C1 119.3(7) . . ?
Ag3 Ag3' Ag1 119.9(12) . . ?
O1W Ag3' Ag1 141.0(8) . . ?
C1 Ag3' Ag1 55.6(4) . . ?
Ag3 Ag3' C25 84.9(11) . 2_676 ?
O1W Ag3' C25 98.2(6) . 2_676 ?
C1 Ag3' C25 136.4(8) . 2_676 ?
Ag1 Ag3' C25 108.1(7) . 2_676 ?
Ag3 Ag3' Ag4 83.8(10) . . ?
O1W Ag3' Ag4 145.3(7) . . ?
C1 Ag3' Ag4 91.9(5) . . ?
Ag1 Ag3' Ag4 68.2(4) . . ?
C25 Ag3' Ag4 47.3(4) 2_676 . ?
Ag3 Ag3' Ag1' 105.8(12) . . ?
O1W Ag3' Ag1' 153.6(8) . . ?
C1 Ag3' Ag1' 49.0(5) . . ?
Ag1 Ag3' Ag1' 14.8(4) . . ?
C25 Ag3' Ag1' 104.0(7) 2_676 . ?
Ag4 Ag3' Ag1' 59.3(5) . . ?
Ag3 Ag3' Ag2' 44.5(9) . . ?
O1W Ag3' Ag2' 130.5(8) . . ?
C1 Ag3' Ag2' 43.0(4) . . ?
Ag1 Ag3' Ag2' 75.4(5) . . ?
C25 Ag3' Ag2' 96.2(6) 2_676 . ?
Ag4 Ag3' Ag2' 62.7(4) . . ?
Ag1' Ag3' Ag2' 61.3(6) . . ?
Ag3 Ag3' Ag7 145.6(12) . 2_676 ?
O1W Ag3' Ag7 96.6(5) . 2_676 ?
C1 Ag3' Ag7 128.6(7) . 2_676 ?
Ag1 Ag3' Ag7 73.2(4) . 2_676 ?
C25 Ag3' Ag7 60.8(4) 2_676 2_676 ?
Ag4 Ag3' Ag7 71.6(4) . 2_676 ?
Ag1' Ag3' Ag7 82.3(5) . 2_676 ?
Ag2' Ag3' Ag7 131.4(6) . 2_676 ?
C25 Ag4 C25 180.0(4) . 2_676 ?
C25 Ag4 Ag3' 55.7(4) . 2_676 ?
C25 Ag4 Ag3' 124.3(4) 2_676 2_676 ?
C25 Ag4 Ag3' 124.3(4) . . ?
C25 Ag4 Ag3' 55.7(4) 2_676 . ?
Ag3' Ag4 Ag3' 179.999(5) 2_676 . ?
C25 Ag4 Ag3 57.2(2) . 2_676 ?
C25 Ag4 Ag3 122.8(2) 2_676 2_676 ?
Ag3' Ag4 Ag3 17.7(4) 2_676 2_676 ?
Ag3' Ag4 Ag3 162.3(4) . 2_676 ?
C25 Ag4 Ag3 122.8(2) . . ?
C25 Ag4 Ag3 57.2(2) 2_676 . ?
Ag3' Ag4 Ag3 162.3(4) 2_676 . ?
Ag3' Ag4 Ag3 17.7(4) . . ?
Ag3 Ag4 Ag3 179.999(3) 2_676 . ?
C25 Ag4 Ag1' 115.3(5) . 2_676 ?
C25 Ag4 Ag1' 64.7(5) 2_676 2_676 ?
Ag3' Ag4 Ag1' 62.8(5) 2_676 2_676 ?
Ag3' Ag4 Ag1' 117.2(5) . 2_676 ?
Ag3 Ag4 Ag1' 70.6(4) 2_676 2_676 ?
Ag3 Ag4 Ag1' 109.4(4) . 2_676 ?
C25 Ag4 Ag1' 64.7(5) . . ?
C25 Ag4 Ag1' 115.3(5) 2_676 . ?
Ag3' Ag4 Ag1' 117.2(5) 2_676 . ?
Ag3' Ag4 Ag1' 62.8(5) . . ?
Ag3 Ag4 Ag1' 109.4(4) 2_676 . ?
Ag3 Ag4 Ag1' 70.6(4) . . ?
Ag1' Ag4 Ag1' 180.0(7) 2_676 . ?
C25 Ag4 Ag1 81.8(2) . . ?
C25 Ag4 Ag1 98.2(2) 2_676 . ?
Ag3' Ag4 Ag1 131.1(3) 2_676 . ?
Ag3' Ag4 Ag1 48.9(3) . . ?
Ag3 Ag4 Ag1 119.52(2) 2_676 . ?
Ag3 Ag4 Ag1 60.48(2) . . ?
Ag1' Ag4 Ag1 162.4(5) 2_676 . ?
Ag1' Ag4 Ag1 17.6(5) . . ?
C25 Ag4 Ag1 98.2(2) . 2_676 ?
C25 Ag4 Ag1 81.8(2) 2_676 2_676 ?
Ag3' Ag4 Ag1 48.9(3) 2_676 2_676 ?
Ag3' Ag4 Ag1 131.1(3) . 2_676 ?
Ag3 Ag4 Ag1 60.48(2) 2_676 2_676 ?
Ag3 Ag4 Ag1 119.51(2) . 2_676 ?
Ag1' Ag4 Ag1 17.6(5) 2_676 2_676 ?
Ag1' Ag4 Ag1 162.4(5) . 2_676 ?
Ag1 Ag4 Ag1 179.999(1) . 2_676 ?
C25 Ag4 Ag2 118.7(2) . 2_676 ?
C25 Ag4 Ag2 61.3(2) 2_676 2_676 ?
Ag3' Ag4 Ag2 73.0(3) 2_676 2_676 ?
Ag3' Ag4 Ag2 107.0(3) . 2_676 ?
Ag3 Ag4 Ag2 63.85(3) 2_676 2_676 ?
Ag3 Ag4 Ag2 116.15(3) . 2_676 ?
Ag1' Ag4 Ag2 52.9(4) 2_676 2_676 ?
Ag1' Ag4 Ag2 127.1(4) . 2_676 ?
Ag1 Ag4 Ag2 116.27(3) . 2_676 ?
Ag1 Ag4 Ag2 63.73(3) 2_676 2_676 ?
C25 Ag4 Ag2 61.3(2) . . ?
C25 Ag4 Ag2 118.7(2) 2_676 . ?
Ag3' Ag4 Ag2 107.0(3) 2_676 . ?
Ag3' Ag4 Ag2 73.0(3) . . ?
Ag3 Ag4 Ag2 116.15(3) 2_676 . ?
Ag3 Ag4 Ag2 63.85(3) . . ?
Ag1' Ag4 Ag2 127.1(4) 2_676 . ?
Ag1' Ag4 Ag2 52.9(4) . . ?
Ag1 Ag4 Ag2 63.73(3) . . ?
Ag1 Ag4 Ag2 116.27(3) 2_676 . ?
Ag2 Ag4 Ag2 179.998(14) 2_676 . ?
C9 Ag5 O24 98.8(3) . . ?
C9 Ag5 C17 122.2(3) . . ?
O24 Ag5 C17 106.3(3) . . ?
C9 Ag5 C33 111.9(3) . . ?
O24 Ag5 C33 96.4(3) . . ?
C17 Ag5 C33 115.8(3) . . ?
C9 Ag5 Ag2' 61.6(4) . . ?
O24 Ag5 Ag2' 109.7(4) . . ?
C17 Ag5 Ag2' 61.0(4) . . ?
C33 Ag5 Ag2' 153.7(4) . . ?
C9 Ag5 C34 138.7(3) . . ?
O24 Ag5 C34 86.1(3) . . ?
C17 Ag5 C34 94.9(3) . . ?
C33 Ag5 C34 27.3(3) . . ?
Ag2' Ag5 C34 153.6(5) . . ?
C9 Ag5 Ag7 44.9(2) . . ?
O24 Ag5 Ag7 139.9(2) . . ?
C17 Ag5 Ag7 108.4(2) . . ?
C33 Ag5 Ag7 86.2(2) . . ?
Ag2' Ag5 Ag7 71.7(3) . . ?
C34 Ag5 Ag7 110.1(2) . . ?
C9 Ag5 Ag6 110.7(2) . . ?
O24 Ag5 Ag6 146.4(2) . . ?
C17 Ag5 Ag6 44.2(2) . . ?
C33 Ag5 Ag6 87.3(2) . . ?
Ag2' Ag5 Ag6 73.1(4) . . ?
C34 Ag5 Ag6 82.1(2) . . ?
Ag7 Ag5 Ag6 73.51(3) . . ?
C9 Ag5 Ag2 47.1(2) . . ?
O24 Ag5 Ag2 109.9(2) . . ?
C17 Ag5 Ag2 75.3(2) . . ?
C33 Ag5 Ag2 147.6(2) . . ?
Ag2' Ag5 Ag2 14.6(4) . . ?
C34 Ag5 Ag2 162.9(2) . . ?
Ag7 Ag5 Ag2 61.57(3) . . ?
Ag6 Ag5 Ag2 81.09(3) . . ?
C9 Ag5 Ag8 71.2(2) . . ?
O24 Ag5 Ag8 98.0(2) . . ?
C17 Ag5 Ag8 149.0(2) . . ?
C33 Ag5 Ag8 40.9(2) . . ?
Ag2' Ag5 Ag8 127.8(3) . . ?
C34 Ag5 Ag8 67.5(2) . . ?
Ag7 Ag5 Ag8 59.15(2) . . ?
Ag6 Ag5 Ag8 106.15(3) . . ?
Ag2 Ag5 Ag8 114.33(3) . . ?
C41 Ag6 C17 165.3(3) . . ?
C41 Ag6 Ag5 127.1(3) . . ?
C17 Ag6 Ag5 53.2(3) . . ?
C41 Ag6 Ag1' 45.8(4) . 2_676 ?
C17 Ag6 Ag1' 147.9(4) . 2_676 ?
Ag5 Ag6 Ag1' 130.4(4) . 2_676 ?
C41 Ag6 Ag10 52.3(3) . . ?
C17 Ag6 Ag10 125.1(3) . . ?
Ag5 Ag6 Ag10 74.79(3) . . ?
Ag1' Ag6 Ag10 78.6(4) 2_676 . ?
C41 Ag6 Ag1 46.3(2) . 2_676 ?
C17 Ag6 Ag1 148.3(2) . 2_676 ?
Ag5 Ag6 Ag1 115.01(3) . 2_676 ?
Ag1' Ag6 Ag1 16.4(4) 2_676 2_676 ?
Ag10 Ag6 Ag1 65.67(3) . 2_676 ?
C41 Ag6 Ag3 138.8(3) . . ?
C17 Ag6 Ag3 51.8(2) . . ?
Ag5 Ag6 Ag3 88.10(3) . . ?
Ag1' Ag6 Ag3 96.7(4) 2_676 . ?
Ag10 Ag6 Ag3 151.62(3) . . ?
Ag1 Ag6 Ag3 103.33(3) 2_676 . ?
C41 Ag6 Ag4 98.4(2) . . ?
C17 Ag6 Ag4 96.1(2) . . ?
Ag5 Ag6 Ag4 96.85(2) . . ?
Ag1' Ag6 Ag4 53.1(3) 2_676 . ?
Ag10 Ag6 Ag4 107.41(3) . . ?
Ag1 Ag6 Ag4 53.667(19) 2_676 . ?
Ag3 Ag6 Ag4 51.523(18) . . ?
C41 Ag6 Ag2' 143.8(3) . . ?
C17 Ag6 Ag2' 49.6(3) . . ?
Ag5 Ag6 Ag2' 47.7(3) . . ?
Ag1' Ag6 Ag2' 105.9(4) 2_676 . ?
Ag10 Ag6 Ag2' 108.2(3) . . ?
Ag1 Ag6 Ag2' 99.6(2) 2_676 . ?
Ag3 Ag6 Ag2' 45.7(3) . . ?
Ag4 Ag6 Ag2' 55.0(2) . . ?
C49 Ag7 C9 167.2(3) . . ?
C49 Ag7 Ag5 131.4(2) . . ?
C9 Ag7 Ag5 51.2(2) . . ?
C49 Ag7 Ag8 93.0(2) . . ?
C9 Ag7 Ag8 77.1(2) . . ?
Ag5 Ag7 Ag8 64.39(2) . . ?
C49 Ag7 Ag9 55.1(3) . . ?
C9 Ag7 Ag9 112.3(2) . . ?
Ag5 Ag7 Ag9 122.62(3) . . ?
Ag8 Ag7 Ag9 58.23(2) . . ?
C49 Ag7 Ag2 145.3(2) . . ?
C9 Ag7 Ag2 47.1(2) . . ?
Ag5 Ag7 Ag2 61.06(3) . . ?
Ag8 Ag7 Ag2 118.47(3) . . ?
Ag9 Ag7 Ag2 154.08(4) . . ?
C49 Ag7 Ag10 57.4(2) . . ?
C9 Ag7 Ag10 121.8(2) . . ?
Ag5 Ag7 Ag10 74.26(2) . . ?
Ag8 Ag7 Ag10 60.36(2) . . ?
Ag9 Ag7 Ag10 78.35(3) . . ?
Ag2 Ag7 Ag10 124.20(3) . . ?
C49 Ag7 Ag2' 142.0(4) . . ?
C9 Ag7 Ag2' 50.5(4) . . ?
Ag5 Ag7 Ag2' 48.4(2) . . ?
Ag8 Ag7 Ag2' 110.7(2) . . ?
Ag9 Ag7 Ag2' 162.8(3) . . ?
Ag2 Ag7 Ag2' 15.7(3) . . ?
Ag10 Ag7 Ag2' 108.6(3) . . ?
C49 Ag7 Ag3' 54.8(4) . 2_676 ?
C9 Ag7 Ag3' 134.2(4) . 2_676 ?
Ag5 Ag7 Ag3' 136.8(3) . 2_676 ?
Ag8 Ag7 Ag3' 147.7(3) . 2_676 ?
Ag9 Ag7 Ag3' 95.9(3) . 2_676 ?
Ag2 Ag7 Ag3' 93.3(3) . 2_676 ?
Ag10 Ag7 Ag3' 98.1(3) . 2_676 ?
Ag2' Ag7 Ag3' 98.6(4) . 2_676 ?
C57 Ag8 C33 173.8(3) . . ?
C57 Ag8 Ag9 126.5(2) . 2_776 ?
C33 Ag8 Ag9 54.6(2) . 2_776 ?
C57 Ag8 Ag9 52.8(2) . . ?
C33 Ag8 Ag9 133.4(2) . . ?
Ag9 Ag8 Ag9 107.14(3) 2_776 . ?
C57 Ag8 Ag7 92.7(2) . . ?
C33 Ag8 Ag7 91.1(2) . . ?
Ag9 Ag8 Ag7 122.02(3) 2_776 . ?
Ag9 Ag8 Ag7 61.03(2) . . ?
C57 Ag8 Ag10 132.5(2) . . ?
C33 Ag8 Ag10 53.6(2) . . ?
Ag9 Ag8 Ag10 61.43(2) 2_776 . ?
Ag9 Ag8 Ag10 79.78(3) . . ?
Ag7 Ag8 Ag10 60.61(2) . . ?
C57 Ag8 Ag10 46.6(2) . 2_776 ?
C33 Ag8 Ag10 134.3(2) . 2_776 ?
Ag9 Ag8 Ag10 79.95(3) 2_776 2_776 ?
Ag9 Ag8 Ag10 60.08(2) . 2_776 ?
Ag7 Ag8 Ag10 120.94(3) . 2_776 ?
Ag10 Ag8 Ag10 111.96(3) . 2_776 ?
C57 Ag8 Ag5 128.4(2) . . ?
C33 Ag8 Ag5 50.8(2) . . ?
Ag9 Ag8 Ag5 105.12(3) 2_776 . ?
Ag9 Ag8 Ag5 117.49(3) . . ?
Ag7 Ag8 Ag5 56.46(2) . . ?
Ag10 Ag8 Ag5 71.07(3) . . ?
Ag10 Ag8 Ag5 174.92(3) 2_776 . ?
O23 Ag9 C57 114.8(3) . . ?
O23 Ag9 C33 108.8(3) . 2_776 ?
C57 Ag9 C33 99.9(3) . 2_776 ?
O23 Ag9 C49 91.7(3) . . ?
C57 Ag9 C49 125.7(3) . . ?
C33 Ag9 C49 115.8(3) 2_776 . ?
O23 Ag9 Ag8 142.03(19) . 2_776 ?
C57 Ag9 Ag8 99.0(2) . 2_776 ?
C33 Ag9 Ag8 45.4(2) 2_776 2_776 ?
C49 Ag9 Ag8 81.45(19) . 2_776 ?
O23 Ag9 Ag8 144.26(18) . . ?
C57 Ag9 Ag8 44.5(2) . . ?
C33 Ag9 Ag8 104.1(2) 2_776 . ?
C49 Ag9 Ag8 86.13(18) . . ?
Ag8 Ag9 Ag8 72.86(3) 2_776 . ?
O23 Ag9 Ag7 94.78(18) . . ?
C57 Ag9 Ag7 87.1(2) . . ?
C33 Ag9 Ag7 149.2(2) 2_776 . ?
C49 Ag9 Ag7 42.0(2) . . ?
Ag8 Ag9 Ag7 104.02(3) 2_776 . ?
Ag8 Ag9 Ag7 60.74(2) . . ?
O23 Ag9 Ag10 130.97(18) . 2_776 ?
C57 Ag9 Ag10 47.6(2) . 2_776 ?
C33 Ag9 Ag10 52.8(2) 2_776 2_776 ?
C49 Ag9 Ag10 137.10(18) . 2_776 ?
Ag8 Ag9 Ag10 62.31(2) 2_776 2_776 ?
Ag8 Ag9 Ag10 62.75(2) . 2_776 ?
Ag7 Ag9 Ag10 123.30(3) . 2_776 ?
C57 Ag10 C41 115.4(3) 2_776 . ?
C57 Ag10 C33 99.9(3) 2_776 . ?
C41 Ag10 C33 121.4(3) . . ?
C57 Ag10 C49 109.7(3) 2_776 . ?
C41 Ag10 C49 91.7(3) . . ?
C33 Ag10 C49 119.4(3) . . ?
C57 Ag10 Ag6 149.8(2) 2_776 . ?
C41 Ag10 Ag6 41.8(2) . . ?
C33 Ag10 Ag6 85.2(2) . . ?
C49 Ag10 Ag6 92.96(19) . . ?
C57 Ag10 Ag9 50.4(2) 2_776 2_776 ?
C41 Ag10 Ag9 143.2(2) . 2_776 ?
C33 Ag10 Ag9 49.9(2) . 2_776 ?
C49 Ag10 Ag9 124.5(2) . 2_776 ?
Ag6 Ag10 Ag9 130.45(3) . 2_776 ?
C57 Ag10 Ag8 96.1(2) 2_776 . ?
C41 Ag10 Ag8 148.0(2) . . ?
C33 Ag10 Ag8 42.5(2) . . ?
C49 Ag10 Ag8 81.86(19) . . ?
Ag6 Ag10 Ag8 106.95(3) . . ?
Ag9 Ag10 Ag8 56.25(2) 2_776 . ?
C57 Ag10 Ag7 139.5(2) 2_776 . ?
C41 Ag10 Ag7 96.0(2) . . ?
C33 Ag10 Ag7 82.9(2) . . ?
C49 Ag10 Ag7 41.19(19) . . ?
Ag6 Ag10 Ag7 70.47(3) . . ?
Ag9 Ag10 Ag7 115.27(3) 2_776 . ?
Ag8 Ag10 Ag7 59.04(2) . . ?
C57 Ag10 Ag8 41.9(2) 2_776 2_776 ?
C41 Ag10 Ag8 140.4(2) . 2_776 ?
C33 Ag10 Ag8 97.1(2) . 2_776 ?
C49 Ag10 Ag8 75.3(2) . 2_776 ?
Ag6 Ag10 Ag8 167.60(3) . 2_776 ?
Ag9 Ag10 Ag8 57.17(2) 2_776 2_776 ?
Ag8 Ag10 Ag8 68.04(3) . 2_776 ?
Ag7 Ag10 Ag8 97.64(3) . 2_776 ?
C57 Ag10 Ag1 123.5(2) 2_776 2_676 ?
C41 Ag10 Ag1 42.39(19) . 2_676 ?
C33 Ag10 Ag1 136.64(19) . 2_676 ?
C49 Ag10 Ag1 49.3(2) . 2_676 ?
Ag6 Ag10 Ag1 58.03(2) . 2_676 ?
Ag9 Ag10 Ag1 171.47(4) 2_776 2_676 ?
Ag8 Ag10 Ag1 123.23(3) . 2_676 ?
Ag7 Ag10 Ag1 64.71(3) . 2_676 ?
Ag8 Ag10 Ag1 114.34(3) 2_776 2_676 ?
O13 W1 O7 101.3(3) . 2_565 ?
O13 W1 O4 103.0(4) . . ?
O7 W1 O4 155.7(4) 2_565 . ?
O13 W1 O12 97.9(4) . . ?
O7 W1 O12 89.2(3) 2_565 . ?
O4 W1 O12 86.7(3) . . ?
O13 W1 O14 105.8(4) . . ?
O7 W1 O14 85.8(3) 2_565 . ?
O4 W1 O14 88.3(3) . . ?
O12 W1 O14 156.3(3) . . ?
O13 W1 O22 158.4(4) . . ?
O7 W1 O22 93.1(3) 2_565 . ?
O4 W1 O22 63.4(3) . . ?
O12 W1 O22 66.0(4) . . ?
O14 W1 O22 91.1(4) . . ?
O13 W1 O19 159.9(4) . 2_565 ?
O7 W1 O19 64.7(3) 2_565 2_565 ?
O4 W1 O19 92.0(3) . 2_565 ?
O12 W1 O19 96.3(4) . 2_565 ?
O14 W1 O19 60.7(4) . 2_565 ?
O22 W1 O19 41.7(4) . 2_565 ?
O5 W2 O7 101.8(3) . . ?
O5 W2 O3 102.5(4) . . ?
O7 W2 O3 155.7(4) . . ?
O5 W2 O8 101.5(4) . . ?
O7 W2 O8 84.8(3) . . ?
O3 W2 O8 90.8(3) . . ?
O5 W2 O6 103.4(4) . . ?
O7 W2 O6 90.2(3) . . ?
O3 W2 O6 83.8(3) . . ?
O8 W2 O6 155.2(4) . . ?
O5 W2 O21 159.3(3) . . ?
O7 W2 O21 92.5(4) . . ?
O3 W2 O21 64.2(4) . . ?
O8 W2 O21 64.7(4) . . ?
O6 W2 O21 91.3(4) . . ?
O5 W2 O19 159.4(3) . . ?
O7 W2 O19 64.3(3) . . ?
O3 W2 O19 92.1(4) . . ?
O8 W2 O19 92.7(4) . . ?
O6 W2 O19 63.5(4) . . ?
O21 W2 O19 41.3(3) . . ?
O11 W3 O12 103.3(3) . . ?
O11 W3 O9 102.8(4) . . ?
O12 W3 O9 153.9(4) . . ?
O11 W3 O10 103.1(4) . . ?
O12 W3 O10 86.4(3) . . ?
O9 W3 O10 88.6(3) . . ?
O11 W3 O2 103.4(4) . . ?
O12 W3 O2 88.0(3) . . ?
O9 W3 O2 85.2(3) . . ?
O10 W3 O2 153.5(4) . . ?
O11 W3 O20 160.4(3) . 2_565 ?
O12 W3 O20 91.2(4) . 2_565 ?
O9 W3 O20 63.7(4) . 2_565 ?
O10 W3 O20 64.3(4) . 2_565 ?
O2 W3 O20 90.0(4) . 2_565 ?
O1 W4 O3 101.1(4) . . ?
O1 W4 O4 103.4(3) . . ?
O3 W4 O4 155.5(4) . . ?
O1 W4 O2 99.1(4) . . ?
O3 W4 O2 90.9(3) . . ?
O4 W4 O2 86.5(3) . . ?
O1 W4 O17 105.0(4) . 2_565 ?
O3 W4 O17 84.6(3) . 2_565 ?
O4 W4 O17 87.9(3) . 2_565 ?
O2 W4 O17 155.9(4) . 2_565 ?
O1 W4 O21 158.2(3) . . ?
O3 W4 O21 63.7(4) . . ?
O4 W4 O21 92.4(3) . . ?
O2 W4 O21 96.8(4) . . ?
O17 W4 O21 60.0(3) 2_565 . ?
O1 W4 O22 158.7(3) . . ?
O3 W4 O22 94.5(4) . . ?
O4 W4 O22 62.3(3) . . ?
O2 W4 O22 65.9(4) . . ?
O17 W4 O22 90.8(4) 2_565 . ?
O21 W4 O22 43.1(3) . . ?
O18 W5 O6 101.8(4) . 2_565 ?
O18 W5 O15 102.8(4) . . ?
O6 W5 O15 155.4(4) 2_565 . ?
O18 W5 O9 98.0(4) . 2_565 ?
O6 W5 O9 90.8(3) 2_565 2_565 ?
O15 W5 O9 86.4(3) . 2_565 ?
O18 W5 O14 105.5(4) . . ?
O6 W5 O14 85.0(3) 2_565 . ?
O15 W5 O14 87.9(3) . . ?
O9 W5 O14 156.5(4) 2_565 . ?
O18 W5 O20 157.9(4) . . ?
O6 W5 O20 93.5(4) 2_565 . ?
O15 W5 O20 63.2(4) . . ?
O9 W5 O20 65.7(4) 2_565 . ?
O14 W5 O20 91.5(4) . . ?
O18 W5 O19 159.3(4) . 2_565 ?
O6 W5 O19 63.9(3) 2_565 2_565 ?
O15 W5 O19 92.2(4) . 2_565 ?
O9 W5 O19 97.2(4) 2_565 2_565 ?
O14 W5 O19 60.2(3) . 2_565 ?
O20 W5 O19 42.8(4) . 2_565 ?
O16 W6 O8 101.6(4) . 2_565 ?
O16 W6 O15 103.6(4) . 2_565 ?
O8 W6 O15 154.9(4) 2_565 2_565 ?
O16 W6 O10 99.2(4) . . ?
O8 W6 O10 89.0(4) 2_565 . ?
O15 W6 O10 86.4(3) 2_565 . ?
O16 W6 O17 105.7(4) . . ?
O8 W6 O17 84.9(3) 2_565 . ?
O15 W6 O17 88.9(4) 2_565 . ?
O10 W6 O17 155.0(4) . . ?
O16 W6 O20 157.9(4) . 2_565 ?
O8 W6 O20 93.9(4) 2_565 2_565 ?
O15 W6 O20 61.9(3) 2_565 2_565 ?
O10 W6 O20 64.9(4) . 2_565 ?
O17 W6 O20 91.3(4) . 2_565 ?
O16 W6 O21 158.3(4) . 2_565 ?
O8 W6 O21 63.4(3) 2_565 2_565 ?
O15 W6 O21 92.5(4) 2_565 2_565 ?
O10 W6 O21 96.2(4) . 2_565 ?
O17 W6 O21 59.5(3) . 2_565 ?
O20 W6 O21 43.8(4) 2_565 2_565 ?
O19 P1 O19 179.998(2) 2_565 . ?
O19 P1 O22 109.1(6) 2_565 2_565 ?
O19 P1 O22 70.9(6) . 2_565 ?
O19 P1 O22 70.9(6) 2_565 . ?
O19 P1 O22 109.1(6) . . ?
O22 P1 O22 179.999(2) 2_565 . ?
O19 P1 O21 110.2(5) 2_565 . ?
O19 P1 O21 69.8(5) . . ?
O22 P1 O21 107.5(5) 2_565 . ?
O22 P1 O21 72.5(5) . . ?
O19 P1 O21 69.8(5) 2_565 2_565 ?
O19 P1 O21 110.2(5) . 2_565 ?
O22 P1 O21 72.5(5) 2_565 2_565 ?
O22 P1 O21 107.5(5) . 2_565 ?
O21 P1 O21 179.999(1) . 2_565 ?
O19 P1 O20 108.9(6) 2_565 2_565 ?
O19 P1 O20 71.1(6) . 2_565 ?
O22 P1 O20 113.7(6) 2_565 2_565 ?
O22 P1 O20 66.3(6) . 2_565 ?
O21 P1 O20 107.4(5) . 2_565 ?
O21 P1 O20 72.6(5) 2_565 2_565 ?
O19 P1 O20 71.1(6) 2_565 . ?
O19 P1 O20 108.9(6) . . ?
O22 P1 O20 66.3(6) 2_565 . ?
O22 P1 O20 113.7(6) . . ?
O21 P1 O20 72.6(5) . . ?
O21 P1 O20 107.4(5) 2_565 . ?
O20 P1 O20 180.0(7) 2_565 . ?
O23 S1 C66 106.7(5) . . ?
O23 S1 C65 103.0(5) . . ?
C66 S1 C65 98.3(5) . . ?
S2' S2 O24 57.7(9) . . ?
S2' S2 C68 85.1(11) . . ?
O24 S2 C68 107.6(8) . . ?
S2' S2 C67 56.1(10) . . ?
O24 S2 C67 104.3(7) . . ?
C68 S2 C67 99.3(9) . . ?
O24 S2' S2 61.6(9) . . ?
O24 S2' C67 121.9(14) . . ?
S2 S2' C67 74.3(11) . . ?
O24 S2' C68 90.0(12) . . ?
S2 S2' C68 52.7(9) . . ?
C67 S2' C68 91.7(13) . . ?
O25 S3 C69 99.4(11) . . ?
O25 S3 C70 102.0(8) . . ?
C69 S3 C70 102.4(10) . . ?
O26 S4 S4' 60.4(7) . . ?
O26 S4 C71 103.0(13) . . ?
S4' S4 C71 73.0(13) . . ?
O26 S4 C72 103.4(9) . . ?
S4' S4 C72 58.3(9) . . ?
C71 S4 C72 98.8(13) . . ?
O26 S4' S4 57.5(8) . . ?
O26 S4' C72 107.1(12) . . ?
S4 S4' C72 66.2(10) . . ?
O26 S4' C71 90.0(15) . . ?
S4 S4' C71 55.2(13) . . ?
C72 S4' C71 93.0(16) . . ?
C2 C1 Ag2' 110.1(9) . . ?
C2 C1 Ag1 127.1(7) . . ?
Ag2' C1 Ag1 103.4(5) . . ?
C2 C1 Ag2 104.8(7) . . ?
Ag2' C1 Ag2 23.5(4) . . ?
Ag1 C1 Ag2 90.4(3) . . ?
C2 C1 Ag1' 118.5(8) . . ?
Ag2' C1 Ag1' 89.4(7) . . ?
Ag1 C1 Ag1' 22.8(6) . . ?
Ag2 C1 Ag1' 71.6(6) . . ?
C2 C1 Ag3 148.7(8) . . ?
Ag2' C1 Ag3 70.7(6) . . ?
Ag1 C1 Ag3 80.6(3) . . ?
Ag2 C1 Ag3 87.2(3) . . ?
Ag1' C1 Ag3 92.6(6) . . ?
C2 C1 Ag3' 154.2(9) . . ?
Ag2' C1 Ag3' 87.4(7) . . ?
Ag1 C1 Ag3' 62.5(5) . . ?
Ag2 C1 Ag3' 98.6(5) . . ?
Ag1' C1 Ag3' 79.1(7) . . ?
Ag3 C1 Ag3' 21.5(4) . . ?
C1 C2 C3 177.0(10) . . ?
C4 C3 C8 118.5(9) . . ?
C4 C3 C2 117.9(9) . . ?
C8 C3 C2 123.6(9) . . ?
C3 C4 C5 117.7(11) . . ?
C4 C5 C6 122.7(12) . . ?
C7 C6 C5 120.8(11) . . ?
C6 C7 C8 115.6(12) . . ?
C7 C8 C3 124.6(11) . . ?
C10 C9 Ag7 157.7(8) . . ?
C10 C9 Ag2 100.4(6) . . ?
Ag7 C9 Ag2 90.1(3) . . ?
C10 C9 Ag5 116.4(6) . . ?
Ag7 C9 Ag5 83.9(3) . . ?
Ag2 C9 Ag5 84.2(3) . . ?
C10 C9 Ag2' 107.4(7) . . ?
Ag7 C9 Ag2' 89.1(5) . . ?
Ag2 C9 Ag2' 20.5(3) . . ?
Ag5 C9 Ag2' 63.8(4) . . ?
C9 C10 C11 175.4(9) . . ?
C12 C11 C16 120.0 . . ?
C12 C11 C10 120.7(5) . . ?
C16 C11 C10 119.3(5) . . ?
C13 C12 C11 120.0 . . ?
C12 C13 C14 120.0 . . ?
C13 C14 C15 120.0 . . ?
C14 C15 C16 120.0 . . ?
C15 C16 C11 120.0 . . ?
C18 C17 Ag6 152.4(9) . . ?
C18 C17 Ag5 122.9(8) . . ?
Ag6 C17 Ag5 82.6(3) . . ?
C18 C17 Ag3 87.3(7) . . ?
Ag6 C17 Ag3 87.2(3) . . ?
Ag5 C17 Ag3 121.6(4) . . ?
C18 C17 Ag2' 109.3(8) . . ?
Ag6 C17 Ag2' 91.3(5) . . ?
Ag5 C17 Ag2' 62.6(4) . . ?
Ag3 C17 Ag2' 60.4(4) . . ?
C17 C18 C19 174.5(10) . . ?
C20 C19 C24 120.0 . . ?
C20 C19 C18 120.8(6) . . ?
C24 C19 C18 119.2(6) . . ?
C21 C20 C19 120.0 . . ?
C20 C21 C22 120.0 . . ?
C21 C22 C23 120.0 . . ?
C24 C23 C22 120.0 . . ?
C23 C24 C19 120.0 . . ?
C26 C25 Ag4 163.4(7) . . ?
C26 C25 Ag3' 119.5(8) . 2_676 ?
Ag4 C25 Ag3' 77.0(5) . 2_676 ?
C26 C25 Ag3 119.5(6) . 2_676 ?
Ag4 C25 Ag3 76.6(3) . 2_676 ?
Ag3' C25 Ag3 20.6(4) 2_676 2_676 ?
C25 C26 C27 178.4(9) . . ?
C28 C27 C32 117.6(9) . . ?
C28 C27 C26 117.3(9) . . ?
C32 C27 C26 125.1(8) . . ?
C27 C28 C29 117.4(10) . . ?
C30 C29 C28 124.3(10) . . ?
C31 C30 C29 118.7(10) . . ?
C30 C31 C32 118.7(10) . . ?
C31 C32 C27 123.2(9) . . ?
C34 C33 Ag8 161.5(8) . . ?
C34 C33 Ag9 109.8(6) . 2_776 ?
Ag8 C33 Ag9 79.9(3) . 2_776 ?
C34 C33 Ag5 83.5(6) . . ?
Ag8 C33 Ag5 88.3(3) . . ?
Ag9 C33 Ag5 166.2(4) 2_776 . ?
C34 C33 Ag10 113.2(7) . . ?
Ag8 C33 Ag10 83.9(3) . . ?
Ag9 C33 Ag10 77.3(2) 2_776 . ?
Ag5 C33 Ag10 94.4(3) . . ?
C33 C34 C35 175.7(10) . . ?
C33 C34 Ag5 69.2(5) . . ?
C35 C34 Ag5 114.2(6) . . ?
C36 C35 C34 119.7(10) . . ?
C36 C35 C40 120.2(9) . . ?
C34 C35 C40 120.2(9) . . ?
C35 C36 C37 119.2(13) . . ?
C36 C37 C38 118.8(12) . . ?
C39 C38 C37 123.2(11) . . ?
C38 C39 C40 118.6(14) . . ?
C39 C40 C35 120.0(12) . . ?
C42 C41 Ag6 162.8(9) . . ?
C42 C41 Ag1' 88.8(7) . 2_676 ?
Ag6 C41 Ag1' 90.9(5) . 2_676 ?
C42 C41 Ag1 93.6(6) . 2_676 ?
Ag6 C41 Ag1 92.7(3) . 2_676 ?
Ag1' C41 Ag1 22.8(6) 2_676 2_676 ?
C42 C41 Ag10 109.9(7) . . ?
Ag6 C41 Ag10 85.9(3) . . ?
Ag1' C41 Ag10 113.8(7) 2_676 . ?
Ag1 C41 Ag10 91.2(3) 2_676 . ?
C41 C42 C43 175.0(9) . . ?
C41 C42 Ag1' 61.3(6) . 2_676 ?
C43 C42 Ag1' 121.7(6) . 2_676 ?
C41 C42 Ag1 59.0(5) . 2_676 ?
C43 C42 Ag1 125.3(5) . 2_676 ?
Ag1' C42 Ag1 19.5(6) 2_676 2_676 ?
C44 C43 C48 120.0 . . ?
C44 C43 C42 120.5(5) . . ?
C48 C43 C42 119.5(5) . . ?
C43 C44 C45 120.0 . . ?
C46 C45 C44 120.0 . . ?
C47 C46 C45 120.0 . . ?
C46 C47 C48 120.0 . . ?
C47 C48 C43 120.0 . . ?
C50 C49 Ag7 169.5(8) . . ?
C50 C49 Ag9 90.6(6) . . ?
Ag7 C49 Ag9 82.9(3) . . ?
C50 C49 Ag1 91.3(6) . 2_676 ?
Ag7 C49 Ag1 95.6(3) . 2_676 ?
Ag9 C49 Ag1 177.2(3) . 2_676 ?
C50 C49 Ag10 107.6(6) . . ?
Ag7 C49 Ag10 81.4(3) . . ?
Ag9 C49 Ag10 97.6(3) . . ?
Ag1 C49 Ag10 79.8(2) 2_676 . ?
C49 C50 C51 178.0(10) . . ?
C56 C51 C52 119.6(9) . . ?
C56 C51 C50 120.2(9) . . ?
C52 C51 C50 120.2(9) . . ?
C53 C52 C51 119.5(11) . . ?
C54 C53 C52 120.2(11) . . ?
C53 C54 C55 120.5(10) . . ?
C54 C55 C56 119.3(11) . . ?
C51 C56 C55 120.8(11) . . ?
C58 C57 Ag8 156.2(7) . . ?
C58 C57 Ag10 111.2(7) . 2_776 ?
Ag8 C57 Ag10 91.6(3) . 2_776 ?
C58 C57 Ag9 106.4(7) . . ?
Ag8 C57 Ag9 82.7(3) . . ?
Ag10 C57 Ag9 82.0(3) 2_776 . ?
C57 C58 C59 175.9(9) . . ?
C60 C59 C64 119.3(8) . . ?
C60 C59 C58 118.7(8) . . ?
C64 C59 C58 122.0(8) . . ?
C59 C60 C61 119.1(9) . . ?
C60 C61 C62 121.3(9) . . ?
C63 C62 C61 119.2(10) . . ?
C62 C63 C64 119.6(10) . . ?
C63 C64 C59 121.5(9) . . ?
S2' C67 S2 49.6(8) . . ?
S2 C68 S2' 42.2(6) . . ?
S4 C71 S4' 51.8(10) . . ?
S4' C72 S4 55.6(10) . . ?
W3 O2 W4 139.8(4) . . ?
W4 O3 W2 139.6(6) . . ?
W1 O4 W4 141.0(4) . . ?
W5 O6 W2 140.7(4) 2_565 . ?
W1 O7 W2 139.9(4) 2_565 . ?
W6 O8 W2 139.7(5) 2_565 . ?
W3 O9 W5 138.9(5) . 2_565 ?
W3 O10 W6 139.9(5) . . ?
W3 O12 W1 140.0(4) . . ?
W1 O14 W5 142.4(4) . . ?
W6 O15 W5 141.1(4) 2_565 . ?
W6 O17 W4 143.4(4) . 2_565 ?
P1 O19 O21 56.7(5) . . ?
P1 O19 O22 55.5(5) . 2_565 ?
O21 O19 O22 90.6(7) . 2_565 ?
P1 O19 O20 57.1(5) . 2_565 ?
O21 O19 O20 91.5(7) . 2_565 ?
O22 O19 O20 95.0(7) 2_565 2_565 ?
P1 O19 W1 123.1(6) . 2_565 ?
O21 O19 W1 128.8(7) . 2_565 ?
O22 O19 W1 67.5(5) 2_565 2_565 ?
O20 O19 W1 134.1(6) 2_565 2_565 ?
P1 O19 W2 124.1(6) . . ?
O21 O19 W2 67.5(4) . . ?
O22 O19 W2 128.9(7) 2_565 . ?
O20 O19 W2 129.3(6) 2_565 . ?
W1 O19 W2 90.6(3) 2_565 . ?
P1 O19 W5 122.9(6) . 2_565 ?
O21 O19 W5 128.4(7) . 2_565 ?
O22 O19 W5 134.6(6) 2_565 2_565 ?
O20 O19 W5 65.8(5) 2_565 2_565 ?
W1 O19 W5 96.0(4) 2_565 2_565 ?
W2 O19 W5 91.3(4) . 2_565 ?
P1 O20 O22 55.0(5) . 2_565 ?
P1 O20 O19 51.8(5) . 2_565 ?
O22 O20 O19 89.1(7) 2_565 2_565 ?
P1 O20 W5 123.2(5) . . ?
O22 O20 W5 132.4(6) 2_565 . ?
O19 O20 W5 71.5(5) 2_565 . ?
P1 O20 W6 121.8(5) . 2_565 ?
O22 O20 W6 129.9(6) 2_565 2_565 ?
O19 O20 W6 130.5(6) 2_565 2_565 ?
W5 O20 W6 93.3(4) . 2_565 ?
P1 O20 W3 127.3(5) . 2_565 ?
O22 O20 W3 72.4(5) 2_565 2_565 ?
O19 O20 W3 135.2(6) 2_565 2_565 ?
W5 O20 W3 91.2(4) . 2_565 ?
W6 O20 W3 90.3(4) 2_565 2_565 ?
P1 O21 O19 53.5(5) . . ?
P1 O21 W2 124.7(5) . . ?
O19 O21 W2 71.2(5) . . ?
P1 O21 W4 121.9(5) . . ?
O19 O21 W4 129.5(7) . . ?
W2 O21 W4 92.0(4) . . ?
P1 O21 W6 121.8(6) . 2_565 ?
O19 O21 W6 130.0(7) . 2_565 ?
W2 O21 W6 91.7(3) . 2_565 ?
W4 O21 W6 96.6(3) . 2_565 ?
P1 O22 O20 58.7(5) . 2_565 ?
P1 O22 O19 53.6(5) . 2_565 ?
O20 O22 O19 93.1(7) 2_565 2_565 ?
P1 O22 W1 124.4(6) . . ?
O20 O22 W1 131.8(6) 2_565 . ?
O19 O22 W1 70.8(5) 2_565 . ?
P1 O22 W4 122.4(5) . . ?
O20 O22 W4 128.2(6) 2_565 . ?
O19 O22 W4 131.2(7) 2_565 . ?
W1 O22 W4 92.6(3) . . ?
S1 O23 Ag9 125.1(4) . . ?
S2' O24 S2 60.8(9) . . ?
S2' O24 Ag5 166.4(9) . . ?
S2 O24 Ag5 120.8(5) . . ?
S4 O26 S4' 62.1(9) . . ?
Ag3' O1W Ag3 21.2(4) . . ?

_diffrn_measured_fraction_theta_max 0.979
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.979
_refine_diff_density_max         2.282
_refine_diff_density_min         -1.663
_refine_diff_density_rms         0.201
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1529048'
_audit_update_record             
;
2017-01-23 deposited with the CCDC.
2017-05-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C37 H32 Ag5 F3 O5 S3'
_chemical_formula_weight         1249.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   33.174(4)
_cell_length_b                   8.3649(5)
_cell_length_c                   32.717(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 114.198(14)
_cell_angle_gamma                90.00
_cell_volume                     8281.1(15)
_cell_formula_units_Z            8
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    2102
_cell_measurement_theta_min      3.1790
_cell_measurement_theta_max      23.6370

_exptl_crystal_description       needle-like
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.004
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4832
_exptl_absorpt_coefficient_mu    2.527
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.54037
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            15821
_diffrn_reflns_av_R_equivalents  0.0489
_diffrn_reflns_av_sigmaI/netI    0.0852
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       39
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         2.73
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7273
_reflns_number_gt                4323
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000010(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         7273
_refine_ls_number_parameters     467
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1155
_refine_ls_R_factor_gt           0.0606
_refine_ls_wR_factor_ref         0.0735
_refine_ls_wR_factor_gt          0.0651
_refine_ls_goodness_of_fit_ref   1.193
_refine_ls_restrained_S_all      1.193
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.27294(2) 0.85069(6) 0.96908(2) 0.0501(2) Uani 1 1 d . . 1
Ag3 Ag 0.20986(2) 1.14551(6) 0.95799(2) 0.0504(2) Uani 1 1 d . . 1
Ag2 Ag 0.30606(2) 1.18515(7) 0.97118(2) 0.0577(2) Uani 1 1 d . . 1
Ag4 Ag 0.17544(2) 0.81188(7) 0.94444(2) 0.0570(2) Uani 1 1 d . . 1
Ag5 Ag 0.24141(3) 0.49453(7) 0.95120(3) 0.0846(3) Uani 1 1 d . . 1
C17 C 0.1773(3) 1.0394(8) 0.9938(3) 0.046(2) Uani 1 1 d . . 1
C18 C 0.1470(3) 0.9886(8) 0.9999(3) 0.047(2) Uani 1 1 d . A 1
C19 C 0.10714(16) 0.9333(6) 1.0026(2) 0.048(2) Uani 1 1 d G A 1
C24 C 0.0764(2) 0.8469(7) 0.96723(18) 0.070(3) Uani 1 1 d G A 1
H24 H 0.0810 0.8296 0.9414 0.084 Uiso 1 1 calc R A 1
C23 C 0.03883(19) 0.7864(6) 0.9705(2) 0.087(3) Uani 1 1 d G A 1
H23 H 0.0183 0.7286 0.9469 0.104 Uiso 1 1 calc R A 1
C22 C 0.03197(18) 0.8122(7) 1.0091(3) 0.098(4) Uani 1 1 d G A 1
H22 H 0.0068 0.7717 1.0113 0.117 Uiso 1 1 calc R A 1
C21 C 0.0627(3) 0.8986(8) 1.0445(2) 0.106(4) Uani 1 1 d G A 1
H21 H 0.0581 0.9158 1.0703 0.127 Uiso 1 1 calc R A 1
C20 C 0.1003(2) 0.9591(6) 1.04121(19) 0.078(3) Uani 1 1 d G A 1
H20 H 0.1208 1.0169 1.0649 0.093 Uiso 1 1 calc R A 1
C1 C 0.3249(3) 0.9592(8) 1.0213(3) 0.046(2) Uani 1 1 d . . 1
C2 C 0.3615(3) 1.0011(8) 1.0450(3) 0.046(2) Uani 1 1 d . B 1
C3 C 0.40645(17) 1.0472(7) 1.0710(2) 0.051(2) Uani 1 1 d G B 1
C4 C 0.4309(3) 0.9672(6) 1.1108(2) 0.078(3) Uani 1 1 d G B 1
H4 H 0.4180 0.8850 1.1204 0.094 Uiso 1 1 calc R B 1
C5 C 0.4746(2) 1.0101(8) 1.13616(18) 0.097(4) Uani 1 1 d G B 1
H5 H 0.4909 0.9565 1.1628 0.116 Uiso 1 1 calc R B 1
C6 C 0.49383(17) 1.1330(9) 1.1218(3) 0.100(4) Uani 1 1 d G B 1
H6 H 0.5231 1.1617 1.1388 0.120 Uiso 1 1 calc R B 1
C7 C 0.4694(2) 1.2130(7) 1.0820(3) 0.108(4) Uani 1 1 d G B 1
H7 H 0.4823 1.2952 1.0724 0.129 Uiso 1 1 calc R B 1
C8 C 0.4257(2) 1.1701(7) 1.05666(19) 0.075(3) Uani 1 1 d G B 1
H8 H 0.4093 1.2236 1.0301 0.090 Uiso 1 1 calc R B 1
C9 C 0.2351(3) 1.2432(8) 0.9154(3) 0.048(2) Uani 1 1 d . . 1
C10 C 0.2425(3) 1.2846(8) 0.8837(3) 0.048(2) Uani 1 1 d . . 1
C11 C 0.2513(2) 1.3292(7) 0.8464(2) 0.052(2) Uani 1 1 d G . 1
C16 C 0.28701(19) 1.4287(7) 0.8529(2) 0.082(3) Uani 1 1 d G . 1
H16 H 0.3049 1.4649 0.8816 0.099 Uiso 1 1 calc R . 1
C15 C 0.2960(2) 1.4741(6) 0.8167(3) 0.101(4) Uani 1 1 d G . 1
H15 H 0.3199 1.5408 0.8210 0.121 Uiso 1 1 calc R . 1
C14 C 0.2693(3) 1.4200(8) 0.7739(3) 0.119(6) Uani 1 1 d G . 1
H14 H 0.2754 1.4504 0.7496 0.143 Uiso 1 1 calc R . 1
C13 C 0.2337(3) 1.3205(7) 0.76735(19) 0.102(4) Uani 1 1 d G . 1
H13 H 0.2158 1.2843 0.7387 0.122 Uiso 1 1 calc R . 1
C12 C 0.22467(18) 1.2750(6) 0.8036(3) 0.073(3) Uani 1 1 d G . 1
H12 H 0.2008 1.2084 0.7993 0.088 Uiso 1 1 calc R . 1
C25 C 0.2269(3) 0.7402(8) 0.9139(3) 0.049(2) Uani 1 1 d . C 1
C26 C 0.2035(3) 0.6880(8) 0.8775(3) 0.045(2) Uani 1 1 d . C 1
C27 C 0.17672(18) 0.6325(7) 0.83347(17) 0.051(2) Uani 1 1 d G C 1
C28 C 0.18368(18) 0.6914(6) 0.7972(2) 0.069(3) Uani 1 1 d G C 1
H28 H 0.2063 0.7642 0.8018 0.082 Uiso 1 1 calc R C 1
C29 C 0.1568(3) 0.6417(8) 0.75398(19) 0.091(4) Uani 1 1 d G C 1
H29 H 0.1614 0.6811 0.7297 0.110 Uiso 1 1 calc R C 1
C30 C 0.1229(2) 0.5330(8) 0.74711(18) 0.089(4) Uani 1 1 d G C 1
H30 H 0.1049 0.4997 0.7182 0.106 Uiso 1 1 calc R C 1
C31 C 0.11596(17) 0.4740(6) 0.7834(3) 0.091(4) Uani 1 1 d G C 1
H31 H 0.0933 0.4013 0.7788 0.109 Uiso 1 1 calc R C 1
C32 C 0.1429(2) 0.5238(7) 0.8266(2) 0.074(3) Uani 1 1 d G C 1
H32 H 0.1382 0.4844 0.8509 0.089 Uiso 1 1 calc R C 1
C60 C 0.9338(5) -0.0666(13) 0.8315(4) 0.104(4) Uani 1 1 d . D 1
C33 C 0.4129(5) 1.0293(14) 0.9117(5) 0.173(7) Uani 1 1 d . E 1
C34 C 0.3255(6) 0.951(2) 0.8689(6) 0.224(9) Uani 1 1 d . E 1
C35 C 0.0620(10) 0.892(3) 0.7980(8) 0.130(11) Uani 0.50 1 d P F 1
C36 C 0.1343(7) 1.042(2) 0.8275(6) 0.077(6) Uani 0.50 1 d P F 1
C35' C 0.0496(8) 1.031(5) 0.8188(9) 0.127(10) Uani 0.50 1 d P F 1
C36' C 0.0859(19) 1.149(3) 0.8426(12) 0.28(3) Uani 0.50 1 d P F 1
F1 F 0.9432(2) -0.1716(7) 0.8054(3) 0.141(3) Uani 1 1 d . D 1
F2 F 0.9086(3) -0.1478(7) 0.8468(2) 0.156(3) Uani 1 1 d . D 1
F3 F 0.9717(2) -0.0386(7) 0.8657(2) 0.130(3) Uani 1 1 d . D 1
O3 O 0.9398(2) 0.1650(7) 0.7864(2) 0.093(2) Uani 1 1 d . D 1
O5 O 0.8681(2) 0.0474(7) 0.7684(2) 0.098(2) Uani 1 1 d . D 1
O4 O 0.9028(2) 0.1983(7) 0.8365(2) 0.105(2) Uani 1 1 d . D 1
O1 O 0.3531(2) 1.1515(6) 0.9354(2) 0.083(2) Uani 1 1 d . E 1
O2 O 0.1114(2) 0.8853(7) 0.8842(2) 0.083(2) Uani 1 1 d . F 1
S3 S 0.90757(10) 0.1059(3) 0.80195(10) 0.0757(8) Uani 1 1 d . D 1
S1 S 0.3645(2) 0.9876(5) 0.9230(2) 0.085(2) Uani 0.70 1 d P E 1
S2 S 0.1065(3) 0.9443(8) 0.8394(3) 0.087(3) Uani 0.50 1 d P F 1
S1' S 0.3607(7) 1.065(2) 0.8999(8) 0.163(8) Uani 0.30 1 d P E 1
S2' S 0.1014(3) 1.0364(12) 0.8560(3) 0.115(3) Uani 0.50 1 d P F 1


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C25 2.045(8) . ?
Ag1 C1 2.074(8) . ?
Ag1 Ag4 2.9693(10) 7_567 ?
Ag1 Ag2 2.9962(8) . ?
Ag1 Ag4 3.0131(11) . ?
Ag1 Ag5 3.1181(10) 7_567 ?
Ag1 Ag5 3.1322(9) . ?
Ag1 Ag3 3.1575(8) . ?
Ag3 C9 2.066(8) . ?
Ag3 C17 2.091(8) . ?
Ag3 Ag2 2.9428(9) 7_577 ?
Ag3 Ag4 2.9789(8) . ?
Ag3 Ag5 2.9792(11) 7_567 ?
Ag3 Ag2 3.0580(11) . ?
Ag3 Ag5 3.1397(9) 1_565 ?
Ag2 O1 2.318(6) . ?
Ag2 C9 2.364(9) . ?
Ag2 C1 2.412(7) . ?
Ag2 C17 2.531(7) 7_577 ?
Ag2 Ag3 2.9429(9) 7_577 ?
Ag2 Ag5 3.2521(10) 1_565 ?
Ag4 O2 2.311(6) . ?
Ag4 C25 2.380(8) . ?
Ag4 C17 2.481(7) . ?
Ag4 C1 2.531(7) 7_567 ?
Ag4 Ag1 2.9692(10) 7_567 ?
Ag5 C25 2.337(7) . ?
Ag5 C9 2.374(7) 1_545 ?
Ag5 C17 2.572(9) 7_567 ?
Ag5 Ag3 2.9792(11) 7_567 ?
Ag5 Ag1 3.1180(10) 7_567 ?
Ag5 Ag3 3.1398(9) 1_545 ?
Ag5 Ag2 3.2521(10) 1_545 ?
C17 C18 1.181(9) . ?
C17 Ag2 2.531(7) 7_577 ?
C17 Ag5 2.572(9) 7_567 ?
C18 C19 1.436(9) . ?
C19 C24 1.3900 . ?
C19 C20 1.3900 . ?
C24 C23 1.3900 . ?
C23 C22 1.3900 . ?
C22 C21 1.3900 . ?
C21 C20 1.3900 . ?
C1 C2 1.194(10) . ?
C1 Ag4 2.531(7) 7_567 ?
C2 C3 1.435(9) . ?
C3 C4 1.3900 . ?
C3 C8 1.3900 . ?
C4 C5 1.3900 . ?
C5 C6 1.3900 . ?
C6 C7 1.3900 . ?
C7 C8 1.3900 . ?
C9 C10 1.210(9) . ?
C9 Ag5 2.374(7) 1_565 ?
C10 C11 1.416(9) . ?
C11 C16 1.3900 . ?
C11 C12 1.3900 . ?
C16 C15 1.3900 . ?
C15 C14 1.3900 . ?
C14 C13 1.3900 . ?
C13 C12 1.3900 . ?
C25 C26 1.208(10) . ?
C26 C27 1.424(9) . ?
C27 C28 1.3900 . ?
C27 C32 1.3900 . ?
C28 C29 1.3900 . ?
C29 C30 1.3900 . ?
C30 C31 1.3900 . ?
C31 C32 1.3900 . ?
C60 F3 1.317(13) . ?
C60 F2 1.326(13) . ?
C60 F1 1.345(13) . ?
C60 S3 1.756(12) . ?
C33 S1' 1.64(2) . ?
C33 S1 1.824(14) . ?
C34 S1' 1.53(2) . ?
C34 S1 1.739(17) . ?
C35 C35' 1.49(3) . ?
C35 S2 1.60(2) . ?
C35 S2' 2.17(2) . ?
C36 S2 1.403(18) . ?
C36 S2' 1.703(18) . ?
C35' C36' 1.51(5) . ?
C35' S2' 1.65(3) . ?
C35' S2 1.87(3) . ?
C36' S2' 1.08(3) . ?
C36' S2 1.87(3) . ?
O3 S3 1.447(6) . ?
O5 S3 1.408(6) . ?
O4 S3 1.431(6) . ?
O1 S1' 1.475(18) . ?
O1 S1 1.521(8) . ?
O2 S2 1.489(8) . ?
O2 S2' 1.519(9) . ?
S1 S1' 0.97(2) . ?
S2 S2' 0.995(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C25 Ag1 C1 173.1(3) . . ?
C25 Ag1 Ag4 124.3(2) . 7_567 ?
C1 Ag1 Ag4 57.0(2) . 7_567 ?
C25 Ag1 Ag2 125.2(2) . . ?
C1 Ag1 Ag2 53.1(2) . . ?
Ag4 Ag1 Ag2 110.06(3) 7_567 . ?
C25 Ag1 Ag4 51.9(2) . . ?
C1 Ag1 Ag4 134.9(2) . . ?
Ag4 Ag1 Ag4 110.00(3) 7_567 . ?
Ag2 Ag1 Ag4 116.75(3) . . ?
C25 Ag1 Ag5 127.6(2) . 7_567 ?
C1 Ag1 Ag5 59.2(2) . 7_567 ?
Ag4 Ag1 Ag5 67.61(2) 7_567 7_567 ?
Ag2 Ag1 Ag5 76.90(2) . 7_567 ?
Ag4 Ag1 Ag5 75.73(3) . 7_567 ?
C25 Ag1 Ag5 48.2(2) . . ?
C1 Ag1 Ag5 132.2(2) . . ?
Ag4 Ag1 Ag5 76.13(2) 7_567 . ?
Ag2 Ag1 Ag5 169.64(3) . . ?
Ag4 Ag1 Ag5 66.91(2) . . ?
Ag5 Ag1 Ag5 113.41(2) 7_567 . ?
C25 Ag1 Ag3 91.8(2) . . ?
C1 Ag1 Ag3 92.3(2) . . ?
Ag4 Ag1 Ag3 124.29(3) 7_567 . ?
Ag2 Ag1 Ag3 59.53(2) . . ?
Ag4 Ag1 Ag3 57.67(2) . . ?
Ag5 Ag1 Ag3 56.68(2) 7_567 . ?
Ag5 Ag1 Ag3 124.51(3) . . ?
C9 Ag3 C17 172.8(3) . . ?
C9 Ag3 Ag2 126.46(19) . 7_577 ?
C17 Ag3 Ag2 57.42(19) . 7_577 ?
C9 Ag3 Ag4 120.4(2) . . ?
C17 Ag3 Ag4 55.32(19) . . ?
Ag2 Ag3 Ag4 112.74(3) 7_577 . ?
C9 Ag3 Ag5 128.6(2) . 7_567 ?
C17 Ag3 Ag5 57.8(2) . 7_567 ?
Ag2 Ag3 Ag5 66.62(2) 7_577 7_567 ?
Ag4 Ag3 Ag5 78.36(2) . 7_567 ?
C9 Ag3 Ag2 50.5(2) . . ?
C17 Ag3 Ag2 135.8(2) . . ?
Ag2 Ag3 Ag2 110.52(3) 7_577 . ?
Ag4 Ag3 Ag2 115.90(3) . . ?
Ag5 Ag3 Ag2 78.09(3) 7_567 . ?
C9 Ag3 Ag5 49.13(19) . 1_565 ?
C17 Ag3 Ag5 134.29(19) . 1_565 ?
Ag2 Ag3 Ag5 77.33(2) 7_577 1_565 ?
Ag4 Ag3 Ag5 168.27(3) . 1_565 ?
Ag5 Ag3 Ag5 112.07(3) 7_567 1_565 ?
Ag2 Ag3 Ag5 63.28(2) . 1_565 ?
C9 Ag3 Ag1 87.3(2) . . ?
C17 Ag3 Ag1 94.3(2) . . ?
Ag2 Ag3 Ag1 127.58(3) 7_577 . ?
Ag4 Ag3 Ag1 58.73(2) . . ?
Ag5 Ag3 Ag1 61.00(2) 7_567 . ?
Ag2 Ag3 Ag1 57.612(19) . . ?
Ag5 Ag3 Ag1 120.66(3) 1_565 . ?
O1 Ag2 C9 107.3(3) . . ?
O1 Ag2 C1 102.0(2) . . ?
C9 Ag2 C1 125.8(3) . . ?
O1 Ag2 C17 105.7(2) . 7_577 ?
C9 Ag2 C17 97.2(3) . 7_577 ?
C1 Ag2 C17 117.3(3) . 7_577 ?
O1 Ag2 Ag3 146.18(16) . 7_577 ?
C9 Ag2 Ag3 93.78(19) . 7_577 ?
C1 Ag2 Ag3 85.48(18) . 7_577 ?
C17 Ag2 Ag3 44.12(17) 7_577 7_577 ?
O1 Ag2 Ag1 101.03(14) . . ?
C9 Ag2 Ag1 86.23(17) . . ?
C1 Ag2 Ag1 43.44(19) . . ?
C17 Ag2 Ag1 150.52(17) 7_577 . ?
Ag3 Ag2 Ag1 106.56(3) 7_577 . ?
O1 Ag2 Ag3 142.61(17) . . ?
C9 Ag2 Ag3 42.4(2) . . ?
C1 Ag2 Ag3 88.6(2) . . ?
C17 Ag2 Ag3 100.63(19) 7_577 . ?
Ag3 Ag2 Ag3 69.48(3) 7_577 . ?
Ag1 Ag2 Ag3 62.86(2) . . ?
O1 Ag2 Ag5 121.32(14) . 1_565 ?
C9 Ag2 Ag5 46.79(17) . 1_565 ?
C1 Ag2 Ag5 136.53(19) . 1_565 ?
C17 Ag2 Ag5 51.0(2) 7_577 1_565 ?
Ag3 Ag2 Ag5 57.23(2) 7_577 1_565 ?
Ag1 Ag2 Ag5 122.21(3) . 1_565 ?
Ag3 Ag2 Ag5 59.58(2) . 1_565 ?
O2 Ag4 C25 106.0(3) . . ?
O2 Ag4 C17 96.9(3) . . ?
C25 Ag4 C17 129.5(3) . . ?
O2 Ag4 C1 116.5(2) . 7_567 ?
C25 Ag4 C1 95.4(2) . 7_567 ?
C17 Ag4 C1 113.7(2) . 7_567 ?
O2 Ag4 Ag1 154.70(14) . 7_567 ?
C25 Ag4 Ag1 93.0(2) . 7_567 ?
C17 Ag4 Ag1 83.11(19) . 7_567 ?
C1 Ag4 Ag1 43.39(19) 7_567 7_567 ?
O2 Ag4 Ag3 92.30(15) . . ?
C25 Ag4 Ag3 90.07(18) . . ?
C17 Ag4 Ag3 43.87(17) . . ?
C1 Ag4 Ag3 147.60(19) 7_567 . ?
Ag1 Ag4 Ag3 104.54(3) 7_567 . ?
O2 Ag4 Ag1 135.20(14) . . ?
C25 Ag4 Ag1 42.6(2) . . ?
C17 Ag4 Ag1 90.4(2) . . ?
C1 Ag4 Ag1 100.18(19) 7_567 . ?
Ag1 Ag4 Ag1 69.99(3) 7_567 . ?
Ag3 Ag4 Ag1 63.60(2) . . ?
C25 Ag5 C9 124.3(3) . 1_545 ?
C25 Ag5 C17 113.2(3) . 7_567 ?
C9 Ag5 C17 95.9(3) 1_545 7_567 ?
C25 Ag5 Ag3 141.0(2) . 7_567 ?
C9 Ag5 Ag3 92.6(2) 1_545 7_567 ?
C17 Ag5 Ag3 43.49(17) 7_567 7_567 ?
C25 Ag5 Ag1 90.1(2) . 7_567 ?
C9 Ag5 Ag1 140.2(2) 1_545 7_567 ?
C17 Ag5 Ag1 86.39(17) 7_567 7_567 ?
Ag3 Ag5 Ag1 62.32(2) 7_567 7_567 ?
C25 Ag5 Ag1 40.8(2) . . ?
C9 Ag5 Ag1 152.8(2) 1_545 . ?
C17 Ag5 Ag1 78.47(15) 7_567 . ?
Ag3 Ag5 Ag1 100.64(3) 7_567 . ?
Ag1 Ag5 Ag1 66.59(2) 7_567 . ?
C25 Ag5 Ag3 148.4(2) . 1_545 ?
C9 Ag5 Ag3 41.1(2) 1_545 1_545 ?
C17 Ag5 Ag3 97.61(15) 7_567 1_545 ?
Ag3 Ag5 Ag3 67.93(2) 7_567 1_545 ?
Ag1 Ag5 Ag3 99.06(3) 7_567 1_545 ?
Ag1 Ag5 Ag3 165.18(3) . 1_545 ?
C25 Ag5 Ag2 141.5(2) . 1_545 ?
C9 Ag5 Ag2 46.5(2) 1_545 1_545 ?
C17 Ag5 Ag2 49.86(15) 7_567 1_545 ?
Ag3 Ag5 Ag2 56.16(2) 7_567 1_545 ?
Ag1 Ag5 Ag2 118.46(3) 7_567 1_545 ?
Ag1 Ag5 Ag2 125.25(3) . 1_545 ?
Ag3 Ag5 Ag2 57.13(2) 1_545 1_545 ?
C18 C17 Ag3 156.7(8) . . ?
C18 C17 Ag4 92.2(5) . . ?
Ag3 C17 Ag4 80.8(2) . . ?
C18 C17 Ag2 107.2(6) . 7_577 ?
Ag3 C17 Ag2 78.5(2) . 7_577 ?
Ag4 C17 Ag2 159.3(3) . 7_577 ?
C18 C17 Ag5 124.3(7) . 7_567 ?
Ag3 C17 Ag5 78.7(3) . 7_567 ?
Ag4 C17 Ag5 96.3(3) . 7_567 ?
Ag2 C17 Ag5 79.2(2) 7_577 7_567 ?
C17 C18 C19 173.8(9) . . ?
C24 C19 C20 120.0 . . ?
C24 C19 C18 119.7(6) . . ?
C20 C19 C18 120.2(6) . . ?
C19 C24 C23 120.0 . . ?
C22 C23 C24 120.0 . . ?
C23 C22 C21 120.0 . . ?
C22 C21 C20 120.0 . . ?
C21 C20 C19 120.0 . . ?
C2 C1 Ag1 160.7(8) . . ?
C2 C1 Ag2 97.0(6) . . ?
Ag1 C1 Ag2 83.5(3) . . ?
C2 C1 Ag4 99.4(6) . 7_567 ?
Ag1 C1 Ag4 79.6(2) . 7_567 ?
Ag2 C1 Ag4 163.0(4) . 7_567 ?
C1 C2 C3 175.8(10) . . ?
C4 C3 C8 120.0 . . ?
C4 C3 C2 119.4(6) . . ?
C8 C3 C2 120.6(6) . . ?
C5 C4 C3 120.0 . . ?
C4 C5 C6 120.0 . . ?
C7 C6 C5 120.0 . . ?
C6 C7 C8 120.0 . . ?
C7 C8 C3 120.0 . . ?
C10 C9 Ag3 166.4(8) . . ?
C10 C9 Ag2 103.5(7) . . ?
Ag3 C9 Ag2 87.0(3) . . ?
C10 C9 Ag5 99.3(5) . 1_565 ?
Ag3 C9 Ag5 89.7(3) . 1_565 ?
Ag2 C9 Ag5 86.7(3) . 1_565 ?
C9 C10 C11 178.6(8) . . ?
C16 C11 C12 120.0 . . ?
C16 C11 C10 119.3(7) . . ?
C12 C11 C10 120.7(7) . . ?
C11 C16 C15 120.0 . . ?
C16 C15 C14 120.0 . . ?
C13 C14 C15 120.0 . . ?
C14 C13 C12 120.0 . . ?
C13 C12 C11 120.0 . . ?
C26 C25 Ag1 168.6(8) . . ?
C26 C25 Ag5 96.2(6) . . ?
Ag1 C25 Ag5 91.0(3) . . ?
C26 C25 Ag4 103.0(6) . . ?
Ag1 C25 Ag4 85.5(3) . . ?
Ag5 C25 Ag4 91.9(3) . . ?
C25 C26 C27 177.1(9) . . ?
C28 C27 C32 120.0 . . ?
C28 C27 C26 119.7(6) . . ?
C32 C27 C26 120.3(6) . . ?
C29 C28 C27 120.0 . . ?
C28 C29 C30 120.0 . . ?
C29 C30 C31 120.0 . . ?
C32 C31 C30 120.0 . . ?
C31 C32 C27 120.0 . . ?
F3 C60 F2 107.5(11) . . ?
F3 C60 F1 105.4(13) . . ?
F2 C60 F1 104.5(9) . . ?
F3 C60 S3 114.0(8) . . ?
F2 C60 S3 112.4(11) . . ?
F1 C60 S3 112.3(9) . . ?
S1' C33 S1 31.8(8) . . ?
S1' C34 S1 33.6(9) . . ?
C35' C35 S2 74.5(14) . . ?
C35' C35 S2' 49.3(12) . . ?
S2 C35 S2' 25.2(5) . . ?
S2 C36 S2' 35.8(6) . . ?
C35 C35' C36' 116(3) . . ?
C35 C35' S2' 87.6(18) . . ?
C36' C35' S2' 39.7(13) . . ?
C35 C35' S2 55.6(13) . . ?
C36' C35' S2 66.1(18) . . ?
S2' C35' S2 32.0(6) . . ?
S2' C36' C35' 77(2) . . ?
S2' C36' S2 24.8(10) . . ?
C35' C36' S2 66.4(14) . . ?
S1' O1 S1 37.6(8) . . ?
S1' O1 Ag2 145.6(8) . . ?
S1 O1 Ag2 122.4(4) . . ?
S2 O2 S2' 38.6(3) . . ?
S2 O2 Ag4 128.2(5) . . ?
S2' O2 Ag4 129.4(5) . . ?
O5 S3 O4 115.7(5) . . ?
O5 S3 O3 115.6(5) . . ?
O4 S3 O3 115.5(4) . . ?
O5 S3 C60 103.6(5) . . ?
O4 S3 C60 101.6(6) . . ?
O3 S3 C60 101.7(6) . . ?
S1' S1 O1 68.6(12) . . ?
S1' S1 C34 61.1(15) . . ?
O1 S1 C34 105.5(6) . . ?
S1' S1 C33 63.5(13) . . ?
O1 S1 C33 102.6(5) . . ?
C34 S1 C33 100.1(8) . . ?
S2' S2 C36 88.7(11) . . ?
S2' S2 O2 72.3(7) . . ?
C36 S2 O2 130.4(11) . . ?
S2' S2 C35 111.5(15) . . ?
C36 S2 C35 114.0(13) . . ?
O2 S2 C35 115.6(11) . . ?
S2' S2 C36' 27.1(13) . . ?
C36 S2 C36' 77.1(18) . . ?
O2 S2 C36' 98.4(12) . . ?
C35 S2 C36' 93.7(17) . . ?
S2' S2 C35' 61.6(14) . . ?
C36 S2 C35' 110.7(13) . . ?
O2 S2 C35' 99.8(9) . . ?
C35 S2 C35' 49.9(11) . . ?
C36' S2 C35' 47.5(16) . . ?
S1 S1' O1 73.8(15) . . ?
S1 S1' C34 85.2(16) . . ?
O1 S1' C34 119.8(14) . . ?
S1 S1' C33 84.7(18) . . ?
O1 S1' C33 114.3(16) . . ?
C34 S1' C33 119.1(13) . . ?
S2 S2' C36' 128(2) . . ?
S2 S2' O2 69.0(7) . . ?
C36' S2' O2 158(3) . . ?
S2 S2' C35' 86.4(17) . . ?
C36' S2' C35' 63(2) . . ?
O2 S2' C35' 109.1(15) . . ?
S2 S2' C36 55.5(9) . . ?
C36' S2' C36 93(3) . . ?
O2 S2' C36 109.1(9) . . ?
C35' S2' C36 107.7(13) . . ?
S2 S2' C35 43.3(12) . . ?
C36' S2' C35 97(2) . . ?
O2 S2' C35 88.4(9) . . ?
C35' S2' C35 43.1(12) . . ?
C36 S2' C35 80.2(12) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.705
_refine_diff_density_min         -1.460
_refine_diff_density_rms         0.129
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5
_database_code_depnum_ccdc_archive 'CCDC 1529052'
_audit_update_record             
;
2017-01-23 deposited with the CCDC.
2017-05-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C84 H100 Ag12 O50 S10 Si W12'
_chemical_formula_weight         5758.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   20.6616(12)
_cell_length_b                   22.0358(12)
_cell_length_c                   30.4391(18)
_cell_angle_alpha                90.00
_cell_angle_beta                 105.960(6)
_cell_angle_gamma                90.00
_cell_volume                     13324.6(13)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5119
_cell_measurement_theta_min      2.9790
_cell_measurement_theta_max      25.4820

_exptl_crystal_description       needle-like
_exptl_crystal_colour            kelly-green
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.871
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             10520
_exptl_absorpt_coefficient_mu    12.266
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.58096
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            23962
_diffrn_reflns_av_R_equivalents  0.0551
_diffrn_reflns_av_sigmaI/netI    0.0936
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         2.73
_diffrn_reflns_theta_max         25.00
_reflns_number_total             11713
_reflns_number_gt                7275
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11713
_refine_ls_number_parameters     771
_refine_ls_number_restraints     9
_refine_ls_R_factor_all          0.1079
_refine_ls_R_factor_gt           0.0569
_refine_ls_wR_factor_ref         0.0891
_refine_ls_wR_factor_gt          0.0805
_refine_ls_goodness_of_fit_ref   1.204
_refine_ls_restrained_S_all      1.204
_refine_ls_shift/su_max          0.102
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.0000 0.66376(8) 0.7500 0.0691(6) Uani 1 2 d S . .
Ag2 Ag 0.03009(6) 0.58014(6) 0.83133(4) 0.0610(4) Uani 1 1 d . . .
Ag3 Ag 0.10844(7) 0.58086(6) 0.74964(4) 0.0654(4) Uani 1 1 d . . .
Ag4 Ag 0.14483(6) 0.48132(5) 0.81988(4) 0.0519(3) Uani 1 1 d . . .
Ag5 Ag 0.03638(6) 0.40761(6) 0.83674(5) 0.0671(4) Uani 1 1 d . . .
Ag6 Ag 0.0000 0.48630(7) 0.7500 0.0433(4) Uani 1 2 d S . .
Ag7 Ag -0.12063(7) 0.40765(6) 0.76440(4) 0.0777(5) Uani 1 1 d . . .
C1 C 0.1448(7) 0.5752(7) 0.8277(5) 0.051(4) Uani 1 1 d . . .
C2 C 0.1577(8) 0.6216(7) 0.8472(5) 0.052(4) Uani 1 1 d . . .
C3 C 0.1814(5) 0.6772(4) 0.8724(3) 0.044(4) Uani 1 1 d G . .
C4 C 0.1391(4) 0.7271(5) 0.8691(3) 0.065(5) Uani 1 1 d G . .
H4 H 0.0960 0.7261 0.8490 0.078 Uiso 1 1 calc R . .
C5 C 0.1611(6) 0.7783(4) 0.8956(4) 0.091(7) Uani 1 1 d G . .
H5 H 0.1328 0.8116 0.8934 0.110 Uiso 1 1 calc R . .
C6 C 0.2254(7) 0.7797(4) 0.9255(4) 0.093(7) Uani 1 1 d G . .
H6 H 0.2402 0.8139 0.9433 0.111 Uiso 1 1 calc R . .
C7 C 0.2678(5) 0.7298(6) 0.9289(4) 0.077(6) Uani 1 1 d G . .
H7 H 0.3108 0.7307 0.9489 0.092 Uiso 1 1 calc R . .
C8 C 0.2457(5) 0.6786(4) 0.9024(4) 0.061(5) Uani 1 1 d G . .
H8 H 0.2741 0.6453 0.9046 0.073 Uiso 1 1 calc R . .
C9 C -0.0555(9) 0.6541(8) 0.8012(6) 0.067(6) Uani 1 1 d . . .
C10 C -0.0826(8) 0.6688(7) 0.8291(6) 0.056(5) Uani 1 1 d . . .
C11 C -0.1172(6) 0.6831(5) 0.8622(3) 0.056(5) Uani 1 1 d G . .
C12 C -0.1631(6) 0.6444(4) 0.8737(4) 0.078(6) Uani 1 1 d G . .
H12 H -0.1727 0.6069 0.8594 0.093 Uiso 1 1 calc R . .
C13 C -0.1944(5) 0.6616(7) 0.9067(5) 0.098(7) Uani 1 1 d G . .
H13 H -0.2251 0.6356 0.9145 0.118 Uiso 1 1 calc R . .
C14 C -0.1800(6) 0.7176(8) 0.9282(4) 0.111(8) Uani 1 1 d G . .
H14 H -0.2010 0.7291 0.9503 0.133 Uiso 1 1 calc R . .
C15 C -0.1342(7) 0.7564(5) 0.9167(4) 0.081(6) Uani 1 1 d G . .
H15 H -0.1245 0.7938 0.9311 0.097 Uiso 1 1 calc R . .
C16 C -0.1028(5) 0.7391(5) 0.8837(4) 0.057(5) Uani 1 1 d G . .
H16 H -0.0721 0.7651 0.8760 0.069 Uiso 1 1 calc R . .
C17 C -0.0452(7) 0.4868(7) 0.8043(5) 0.042(4) Uani 1 1 d . . .
C18 C -0.0739(7) 0.4833(6) 0.8332(5) 0.043(4) Uani 1 1 d . . .
C19 C -0.1071(5) 0.4838(4) 0.8688(3) 0.044(4) Uani 1 1 d G . .
C20 C -0.1758(5) 0.4719(5) 0.8576(3) 0.065(5) Uani 1 1 d G . .
H20 H -0.1994 0.4644 0.8273 0.078 Uiso 1 1 calc R . .
C21 C -0.2092(4) 0.4713(5) 0.8915(4) 0.088(6) Uani 1 1 d G . .
H21 H -0.2551 0.4633 0.8839 0.106 Uiso 1 1 calc R . .
C22 C -0.1739(6) 0.4825(5) 0.9366(4) 0.078(6) Uani 1 1 d G . .
H22 H -0.1962 0.4821 0.9593 0.094 Uiso 1 1 calc R . .
C23 C -0.1052(6) 0.4944(5) 0.9479(3) 0.073(6) Uani 1 1 d G . .
H23 H -0.0816 0.5020 0.9781 0.087 Uiso 1 1 calc R . .
C24 C -0.0718(4) 0.4951(4) 0.9140(4) 0.060(5) Uani 1 1 d G . .
H24 H -0.0259 0.5031 0.9215 0.072 Uiso 1 1 calc R . .
C25 C 0.1299(8) 0.3876(7) 0.8114(5) 0.058(5) Uani 1 1 d . . .
C26 C 0.1250(8) 0.3348(8) 0.8105(5) 0.057(5) Uani 1 1 d . . .
C27 C 0.1191(7) 0.2682(5) 0.8084(6) 0.072(6) Uani 1 1 d G . .
C28 C 0.1475(8) 0.2340(8) 0.8473(5) 0.174(13) Uani 1 1 d G . .
H28 H 0.1727 0.2529 0.8738 0.209 Uiso 1 1 calc R . .
C29 C 0.1382(9) 0.1715(8) 0.8465(6) 0.156(12) Uani 1 1 d G . .
H29 H 0.1572 0.1486 0.8725 0.187 Uiso 1 1 calc R . .
C30 C 0.1006(9) 0.1432(5) 0.8069(8) 0.131(10) Uani 1 1 d G . .
H30 H 0.0944 0.1014 0.8064 0.157 Uiso 1 1 calc R . .
C31 C 0.0722(10) 0.1775(8) 0.7680(6) 0.237(19) Uani 1 1 d G . .
H31 H 0.0470 0.1586 0.7415 0.285 Uiso 1 1 calc R . .
C32 C 0.0815(9) 0.2400(8) 0.7688(5) 0.215(17) Uani 1 1 d G . .
H32 H 0.0625 0.2629 0.7428 0.258 Uiso 1 1 calc R . .
C33 C 0.1656(8) 0.4648(8) 0.9430(6) 0.098(7) Uani 1 1 d . . .
H33A H 0.1351 0.4978 0.9322 0.147 Uiso 1 1 calc R . .
H33B H 0.1873 0.4538 0.9201 0.147 Uiso 1 1 calc R . .
H33C H 0.1989 0.4769 0.9704 0.147 Uiso 1 1 calc R . .
C34 C 0.1770(10) 0.3424(9) 0.9466(7) 0.170(13) Uani 1 1 d . . .
H34A H 0.1526 0.3054 0.9369 0.255 Uiso 1 1 calc R . .
H34B H 0.2112 0.3354 0.9747 0.255 Uiso 1 1 calc R . .
H34C H 0.1975 0.3555 0.9235 0.255 Uiso 1 1 calc R . .
C35 C 0.1250(7) 0.6555(8) 0.9792(5) 0.081(6) Uani 1 1 d . . .
H35A H 0.1321 0.6204 0.9985 0.122 Uiso 1 1 calc R . .
H35B H 0.1230 0.6910 0.9970 0.122 Uiso 1 1 calc R . .
H35C H 0.1615 0.6595 0.9655 0.122 Uiso 1 1 calc R . .
C36 C -0.0041(7) 0.6361(6) 0.9728(5) 0.068(5) Uani 1 1 d . . .
H36A H -0.0478 0.6221 0.9559 0.102 Uiso 1 1 calc R . .
H36B H -0.0085 0.6737 0.9877 0.102 Uiso 1 1 calc R . .
H36C H 0.0166 0.6064 0.9954 0.102 Uiso 1 1 calc R . .
C37 C -0.3074(13) 0.2844(11) 0.7786(10) 0.210(15) Uani 1 1 d . . .
H37A H -0.2894 0.2502 0.7663 0.315 Uiso 1 1 calc R . .
H37B H -0.3556 0.2836 0.7681 0.315 Uiso 1 1 calc R . .
H37C H -0.2934 0.2824 0.8114 0.315 Uiso 1 1 calc R . .
C38 C -0.3069(11) 0.3454(9) 0.6993(7) 0.154(11) Uani 1 1 d . . .
H38A H -0.2844 0.3765 0.6869 0.231 Uiso 1 1 calc R . .
H38B H -0.3547 0.3519 0.6891 0.231 Uiso 1 1 calc R . .
H38C H -0.2964 0.3064 0.6890 0.231 Uiso 1 1 calc R . .
C39 C 0.0052(17) 0.2504(11) 0.8745(10) 0.145(13) Uani 0.70 1 d PU . .
H39A H 0.0004 0.2252 0.8991 0.218 Uiso 0.70 1 calc PR . .
H39B H 0.0417 0.2783 0.8856 0.218 Uiso 0.70 1 calc PR . .
H39C H 0.0142 0.2254 0.8510 0.218 Uiso 0.70 1 calc PR . .
C40 C -0.094(2) 0.2565(17) 0.8428(14) 0.157(11) Uani 0.70 1 d PU . .
H40A H -0.1228 0.2644 0.8127 0.236 Uiso 0.70 1 calc PR . .
H40B H -0.1214 0.2493 0.8633 0.236 Uiso 0.70 1 calc PR . .
H40C H -0.0671 0.2214 0.8420 0.236 Uiso 0.70 1 calc PR . .
C41 C -0.1029(12) 0.3285(10) 0.8930(8) 0.048(7) Uani 0.60 1 d P . .
C42 C 0.3298(12) 0.5221(12) 0.7574(11) 0.216(16) Uani 1 1 d U . .
H42A H 0.3128 0.5191 0.7248 0.324 Uiso 1 1 calc R . .
H42B H 0.3475 0.4835 0.7697 0.324 Uiso 1 1 calc R . .
H42C H 0.3648 0.5521 0.7650 0.324 Uiso 1 1 calc R . .
C43 C 0.2899(11) 0.6236(10) 0.7855(11) 0.214(16) Uani 1 1 d . . .
H43A H 0.3378 0.6290 0.7962 0.321 Uiso 1 1 calc R . .
H43B H 0.2690 0.6406 0.8072 0.321 Uiso 1 1 calc R . .
H43C H 0.2732 0.6436 0.7566 0.321 Uiso 1 1 calc R . .
O1 O 0.0571(5) 0.3953(5) 0.9160(4) 0.083(4) Uani 1 1 d . . .
O2 O 0.0506(5) 0.5865(4) 0.9129(3) 0.063(3) Uani 1 1 d . . .
O3 O -0.2166(8) 0.3646(7) 0.7767(4) 0.128(6) Uani 1 1 d . . .
O4 O -0.0524(6) 0.3343(5) 0.8190(4) 0.080(4) Uani 1 1 d . . .
O5 O 0.2047(7) 0.5441(8) 0.7365(5) 0.155(7) Uani 1 1 d . . .
O6 O 0.5311(8) 0.4395(7) 0.9849(5) 0.036(5) Uani 0.50 1 d P . .
O7 O 0.4896(7) 0.4416(6) 1.0278(5) 0.025(4) Uani 0.50 1 d P . .
O8 O 0.5324(8) 0.5080(7) 1.0543(5) 0.032(4) Uani 0.50 1 d P . .
O9 O 0.5821(8) 0.5147(7) 1.0095(5) 0.034(5) Uani 0.50 1 d P . .
O10 O 0.6161(5) 0.3723(5) 1.0128(3) 0.084(4) Uani 1 1 d . . .
O11 O 0.5021(5) 0.3485(5) 0.9512(4) 0.085(4) Uani 1 1 d . . .
O12 O 0.5459(5) 0.2694(4) 1.0229(4) 0.083(4) Uani 1 1 d . . .
O13 O 0.5006(5) 0.3626(4) 0.8611(3) 0.074(3) Uani 1 1 d . . .
O14 O 0.5939(5) 0.4201(5) 0.9320(4) 0.095(4) Uani 1 1 d . . .
O15 O 0.4073(5) 0.4135(4) 0.9008(4) 0.064(3) Uani 1 1 d . . .
O16 O 0.3201(7) 0.5308(4) 0.9500(3) 0.097(5) Uani 1 1 d . . .
O17 O 0.3424(7) 0.4128(4) 0.9603(3) 0.094(5) Uani 1 1 d . . .
O18 O 0.2765(5) 0.4570(4) 0.8754(3) 0.053(3) Uani 1 1 d . . .
O19 O 0.3842(5) 0.5355(4) 0.8885(4) 0.075(4) Uani 1 1 d . . .
O20 O 0.4570(5) 0.5959(5) 0.8380(3) 0.084(4) Uani 1 1 d . . .
O21 O 0.5025(6) 0.4874(4) 0.8799(4) 0.086(4) Uani 1 1 d . . .
O22 O 0.4478(5) 0.6312(5) 0.9237(4) 0.082(4) Uani 1 1 d . . .
O23 O 0.5634(5) 0.5849(5) 0.9169(4) 0.080(4) Uani 1 1 d . . .
O24 O 0.5610(5) 0.6512(5) 0.9860(3) 0.073(3) Uani 1 1 d . . .
O25 O 0.6600(7) 0.5195(5) 0.9688(3) 0.108(5) Uani 1 1 d . . .
O26 O 0.6794(5) 0.6416(4) 0.9651(3) 0.066(3) Uani 1 1 d . . .
O27 O 0.7242(5) 0.4098(4) 0.9846(3) 0.061(3) Uani 1 1 d . . .
S1 S 0.1194(3) 0.4004(3) 0.95530(16) 0.0871(17) Uani 1 1 d . . .
S2 S 0.0469(2) 0.64750(19) 0.93492(14) 0.0588(12) Uani 1 1 d . . .
S3 S -0.2790(9) 0.3483(9) 0.7614(6) 0.127(6) Uani 0.50 1 d P . .
S4 S -0.0667(5) 0.2895(3) 0.8528(4) 0.172(4) Uani 1 1 d U . .
S5 S 0.2702(5) 0.5413(5) 0.7786(4) 0.114(4) Uani 0.60 1 d PU . .
S3' S -0.2524(7) 0.3166(6) 0.7474(5) 0.080(4) Uani 0.50 1 d P . .
S5' S 0.2718(7) 0.5693(7) 0.7411(5) 0.082(4) Uani 0.40 1 d P . .
Si1 Si 0.5000 0.5000 1.0000 0.0183(11) Uani 1 2 d S . .
W1 W 0.49931(3) 0.40744(3) 0.90538(2) 0.0492(2) Uani 1 1 d . . .
W2 W 0.62253(3) 0.59632(3) 0.97595(2) 0.04630(19) Uani 1 1 d . . .
W3 W 0.47193(3) 0.56452(3) 0.89061(2) 0.04596(19) Uani 1 1 d . . .
W4 W 0.34798(3) 0.47113(3) 0.91507(2) 0.04684(19) Uani 1 1 d . . .
W5 W 0.53138(3) 0.34345(3) 1.01513(2) 0.04652(19) Uani 1 1 d . . .
W6 W 0.65217(3) 0.43913(3) 0.98913(2) 0.0528(2) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C9 2.18(2) . ?
Ag1 C9 2.19(2) 2_556 ?
Ag1 Ag3 2.8933(18) 2_556 ?
Ag1 Ag3 2.8934(18) . ?
Ag1 Ag2 3.0106(17) 2_556 ?
Ag1 Ag2 3.0107(17) . ?
Ag2 C9 2.394(17) . ?
Ag2 O2 2.406(10) . ?
Ag2 C1 2.406(15) . ?
Ag2 C17 2.574(14) . ?
Ag2 Ag6 3.1536(16) . ?
Ag2 Ag3 3.2231(17) 2_556 ?
Ag2 Ag4 3.3073(18) . ?
Ag2 Ag3 3.3195(19) . ?
Ag3 O5 2.282(14) . ?
Ag3 C1 2.289(15) . ?
Ag3 C9 2.294(15) 2_556 ?
Ag3 Ag4 3.0106(17) . ?
Ag3 Ag6 3.0620(17) . ?
Ag3 Ag2 3.2230(17) 2_556 ?
Ag4 C1 2.082(15) . ?
Ag4 C25 2.094(17) . ?
Ag4 Ag5 2.9248(18) . ?
Ag4 Ag7 2.9598(17) 2_556 ?
Ag4 Ag6 3.1607(12) . ?
Ag5 C25 2.312(17) . ?
Ag5 O1 2.347(11) . ?
Ag5 O4 2.391(10) . ?
Ag5 C17 2.438(14) . ?
Ag5 Ag6 3.0742(15) . ?
Ag6 C17 2.110(15) . ?
Ag6 C17 2.110(15) 2_556 ?
Ag6 Ag3 3.0620(17) 2_556 ?
Ag6 Ag5 3.0741(15) 2_556 ?
Ag6 Ag2 3.1536(16) 2_556 ?
Ag6 Ag4 3.1606(12) 2_556 ?
Ag6 Ag7 3.1635(16) . ?
Ag6 Ag7 3.1636(16) 2_556 ?
Ag7 C25 2.306(15) 2_556 ?
Ag7 O3 2.319(14) . ?
Ag7 C17 2.429(14) . ?
Ag7 O4 2.465(10) . ?
Ag7 C18 2.642(15) . ?
Ag7 Ag4 2.9597(17) 2_556 ?
C1 C2 1.177(17) . ?
C2 C3 1.458(16) . ?
C3 C4 1.3900 . ?
C3 C8 1.3900 . ?
C4 C5 1.3900 . ?
C5 C6 1.3900 . ?
C6 C7 1.3900 . ?
C7 C8 1.3900 . ?
C9 C10 1.18(2) . ?
C9 Ag3 2.294(15) 2_556 ?
C10 C11 1.42(2) . ?
C11 C12 1.3900 . ?
C11 C16 1.3900 . ?
C12 C13 1.3900 . ?
C13 C14 1.3900 . ?
C14 C15 1.3900 . ?
C15 C16 1.3900 . ?
C17 C18 1.191(18) . ?
C18 C19 1.434(17) . ?
C19 C20 1.3900 . ?
C19 C24 1.3900 . ?
C20 C21 1.3900 . ?
C21 C22 1.3900 . ?
C22 C23 1.3900 . ?
C23 C24 1.3900 . ?
C25 C26 1.166(18) . ?
C25 Ag7 2.306(15) 2_556 ?
C26 C27 1.473(18) . ?
C27 C28 1.3900 . ?
C27 C32 1.3900 . ?
C28 C29 1.3900 . ?
C29 C30 1.3900 . ?
C30 C31 1.3900 . ?
C31 C32 1.3900 . ?
C33 S1 1.805(17) . ?
C34 S1 1.816(19) . ?
C35 S2 1.804(13) . ?
C36 S2 1.781(15) . ?
C37 S3 1.66(3) . ?
C38 S3 1.82(3) . ?
C39 S4 1.69(3) . ?
C40 S4 0.92(3) . ?
C41 S4 1.82(2) . ?
C42 S5 1.60(2) . ?
C43 S5 1.86(2) . ?
O1 S1 1.502(10) . ?
O2 S2 1.513(9) . ?
O3 S3 1.297(19) . ?
O3 S3' 1.449(18) . ?
O4 S4 1.512(12) . ?
O5 S5' 1.465(19) . ?
O5 S5 1.589(16) . ?
O6 Si1 1.600(17) . ?
O6 O7 1.75(2) . ?
O6 W5 2.308(15) . ?
O6 W1 2.433(16) . ?
O6 W6 2.470(17) . ?
O7 Si1 1.587(14) . ?
O7 O8 1.78(2) . ?
O7 W5 2.399(15) . ?
O7 W3 2.394(15) 5_667 ?
O7 W2 2.437(15) 5_667 ?
O8 Si1 1.613(16) . ?
O8 W3 2.336(15) 5_667 ?
O8 W1 2.420(16) 5_667 ?
O8 W4 2.433(16) 5_667 ?
O9 Si1 1.672(17) . ?
O9 W2 2.332(15) . ?
O9 W4 2.374(16) 5_667 ?
O9 W6 2.397(17) . ?
O10 W6 1.881(11) . ?
O10 W5 1.881(10) . ?
O11 W5 1.876(10) . ?
O11 W1 1.895(10) . ?
O12 W5 1.663(9) . ?
O13 W1 1.676(9) . ?
O14 W6 1.870(11) . ?
O14 W1 1.918(11) . ?
O15 W1 1.873(9) . ?
O15 W4 1.896(9) . ?
O16 W6 1.903(10) 5_667 ?
O16 W4 1.877(11) . ?
O17 W2 1.885(10) 5_667 ?
O17 W4 1.911(10) . ?
O18 W4 1.660(8) . ?
O19 W4 1.887(10) . ?
O19 W3 1.907(9) . ?
O20 W3 1.692(9) . ?
O21 W3 1.874(9) . ?
O21 W1 1.933(10) . ?
O22 W5 1.877(10) 5_667 ?
O22 W3 1.923(11) . ?
O23 W3 1.893(10) . ?
O23 W2 1.891(9) . ?
O24 W2 1.840(11) . ?
O24 W5 1.902(10) 5_667 ?
O25 W6 1.898(11) . ?
O25 W2 1.898(11) . ?
O26 W2 1.642(10) . ?
O27 W6 1.662(9) . ?
S3 S3' 1.048(18) . ?
S5 S5' 1.306(15) . ?
Si1 O7 1.587(14) 5_667 ?
Si1 O6 1.600(17) 5_667 ?
Si1 O8 1.613(16) 5_667 ?
Si1 O9 1.672(17) 5_667 ?
W1 O8 2.420(16) 5_667 ?
W2 O17 1.885(10) 5_667 ?
W2 O7 2.437(15) 5_667 ?
W3 O8 2.336(15) 5_667 ?
W3 O7 2.394(15) 5_667 ?
W4 O9 2.374(16) 5_667 ?
W4 O8 2.433(16) 5_667 ?
W5 O22 1.877(10) 5_667 ?
W5 O24 1.902(10) 5_667 ?
W6 O16 1.903(10) 5_667 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C9 Ag1 C9 168.8(9) . 2_556 ?
C9 Ag1 Ag3 51.4(4) . 2_556 ?
C9 Ag1 Ag3 120.0(5) 2_556 2_556 ?
C9 Ag1 Ag3 120.0(4) . . ?
C9 Ag1 Ag3 51.4(4) 2_556 . ?
Ag3 Ag1 Ag3 101.69(8) 2_556 . ?
C9 Ag1 Ag2 119.8(4) . 2_556 ?
C9 Ag1 Ag2 52.0(4) 2_556 2_556 ?
Ag3 Ag1 Ag2 68.39(5) 2_556 2_556 ?
Ag3 Ag1 Ag2 66.14(4) . 2_556 ?
C9 Ag1 Ag2 52.0(4) . . ?
C9 Ag1 Ag2 119.8(4) 2_556 . ?
Ag3 Ag1 Ag2 66.14(4) 2_556 . ?
Ag3 Ag1 Ag2 68.39(5) . . ?
Ag2 Ag1 Ag2 104.53(7) 2_556 . ?
C9 Ag2 O2 104.9(5) . . ?
C9 Ag2 C1 130.3(6) . . ?
O2 Ag2 C1 98.9(4) . . ?
C9 Ag2 C17 95.9(5) . . ?
O2 Ag2 C17 107.2(4) . . ?
C1 Ag2 C17 117.7(5) . . ?
C9 Ag2 Ag1 46.0(5) . . ?
O2 Ag2 Ag1 138.7(2) . . ?
C1 Ag2 Ag1 88.4(4) . . ?
C17 Ag2 Ag1 104.8(3) . . ?
C9 Ag2 Ag6 100.4(4) . . ?
O2 Ag2 Ag6 142.1(2) . . ?
C1 Ag2 Ag6 85.3(4) . . ?
C17 Ag2 Ag6 41.7(3) . . ?
Ag1 Ag2 Ag6 78.71(4) . . ?
C9 Ag2 Ag3 45.3(4) . 2_556 ?
O2 Ag2 Ag3 131.0(3) . 2_556 ?
C1 Ag2 Ag3 130.1(4) . 2_556 ?
C17 Ag2 Ag3 55.1(3) . 2_556 ?
Ag1 Ag2 Ag3 55.18(4) . 2_556 ?
Ag6 Ag2 Ag3 57.38(3) . 2_556 ?
C9 Ag2 Ag4 152.0(4) . . ?
O2 Ag2 Ag4 102.7(2) . . ?
C1 Ag2 Ag4 38.9(4) . . ?
C17 Ag2 Ag4 80.1(3) . . ?
Ag1 Ag2 Ag4 107.95(5) . . ?
Ag6 Ag2 Ag4 58.52(3) . . ?
Ag3 Ag2 Ag4 115.73(5) 2_556 . ?
C9 Ag2 Ag3 99.8(5) . . ?
O2 Ag2 Ag3 142.1(3) . . ?
C1 Ag2 Ag3 43.6(4) . . ?
C17 Ag2 Ag3 98.1(3) . . ?
Ag1 Ag2 Ag3 54.13(3) . . ?
Ag6 Ag2 Ag3 56.39(3) . . ?
Ag3 Ag2 Ag3 86.60(5) 2_556 . ?
Ag4 Ag2 Ag3 54.04(4) . . ?
O5 Ag3 C1 96.3(6) . . ?
O5 Ag3 C9 114.1(7) . 2_556 ?
C1 Ag3 C9 134.3(6) . 2_556 ?
O5 Ag3 Ag1 159.7(5) . . ?
C1 Ag3 Ag1 93.7(4) . . ?
C9 Ag3 Ag1 48.1(5) 2_556 . ?
O5 Ag3 Ag4 78.8(5) . . ?
C1 Ag3 Ag4 43.7(4) . . ?
C9 Ag3 Ag4 166.2(5) 2_556 . ?
Ag1 Ag3 Ag4 119.98(6) . . ?
O5 Ag3 Ag6 115.6(4) . . ?
C1 Ag3 Ag6 89.5(4) . . ?
C9 Ag3 Ag6 105.5(4) 2_556 . ?
Ag1 Ag3 Ag6 82.03(5) . . ?
Ag4 Ag3 Ag6 62.72(4) . . ?
O5 Ag3 Ag2 119.8(4) . 2_556 ?
C1 Ag3 Ag2 139.7(4) . 2_556 ?
C9 Ag3 Ag2 47.9(4) 2_556 2_556 ?
Ag1 Ag3 Ag2 58.68(4) . 2_556 ?
Ag4 Ag3 Ag2 122.37(5) . 2_556 ?
Ag6 Ag3 Ag2 60.17(3) . 2_556 ?
O5 Ag3 Ag2 139.3(5) . . ?
C1 Ag3 Ag2 46.4(4) . . ?
C9 Ag3 Ag2 105.6(5) 2_556 . ?
Ag1 Ag3 Ag2 57.48(4) . . ?
Ag4 Ag3 Ag2 62.77(4) . . ?
Ag6 Ag3 Ag2 59.07(3) . . ?
Ag2 Ag3 Ag2 93.40(5) 2_556 . ?
C1 Ag4 C25 171.7(6) . . ?
C1 Ag4 Ag5 120.5(4) . . ?
C25 Ag4 Ag5 51.7(5) . . ?
C1 Ag4 Ag7 129.7(4) . 2_556 ?
C25 Ag4 Ag7 50.8(4) . 2_556 ?
Ag5 Ag4 Ag7 83.83(5) . 2_556 ?
C1 Ag4 Ag3 49.4(4) . . ?
C25 Ag4 Ag3 129.2(4) . . ?
Ag5 Ag4 Ag3 118.39(5) . . ?
Ag7 Ag4 Ag3 80.47(5) 2_556 . ?
C1 Ag4 Ag6 90.7(4) . . ?
C25 Ag4 Ag6 82.6(4) . . ?
Ag5 Ag4 Ag6 60.54(4) . . ?
Ag7 Ag4 Ag6 62.14(4) 2_556 . ?
Ag3 Ag4 Ag6 59.43(4) . . ?
C1 Ag4 Ag2 46.5(4) . . ?
C25 Ag4 Ag2 125.2(5) . . ?
Ag5 Ag4 Ag2 75.00(4) . . ?
Ag7 Ag4 Ag2 119.82(5) 2_556 . ?
Ag3 Ag4 Ag2 63.19(4) . . ?
Ag6 Ag4 Ag2 58.31(4) . . ?
C25 Ag5 O1 112.8(5) . . ?
C25 Ag5 O4 117.1(5) . . ?
O1 Ag5 O4 93.7(4) . . ?
C25 Ag5 C17 123.4(5) . . ?
O1 Ag5 C17 114.2(5) . . ?
O4 Ag5 C17 89.4(4) . . ?
C25 Ag5 Ag4 45.3(4) . . ?
O1 Ag5 Ag4 108.2(3) . . ?
O4 Ag5 Ag4 155.8(3) . . ?
C17 Ag5 Ag4 90.5(3) . . ?
C25 Ag5 Ag6 81.4(4) . . ?
O1 Ag5 Ag6 151.7(3) . . ?
O4 Ag5 Ag6 101.3(2) . . ?
C17 Ag5 Ag6 43.1(4) . . ?
Ag4 Ag5 Ag6 63.53(4) . . ?
C17 Ag6 C17 179.4(8) . 2_556 ?
C17 Ag6 Ag3 60.8(4) . 2_556 ?
C17 Ag6 Ag3 118.8(4) 2_556 2_556 ?
C17 Ag6 Ag3 118.8(4) . . ?
C17 Ag6 Ag3 60.8(4) 2_556 . ?
Ag3 Ag6 Ag3 94.24(7) 2_556 . ?
C17 Ag6 Ag5 128.2(4) . 2_556 ?
C17 Ag6 Ag5 52.2(4) 2_556 2_556 ?
Ag3 Ag6 Ag5 112.37(3) 2_556 2_556 ?
Ag3 Ag6 Ag5 112.77(4) . 2_556 ?
C17 Ag6 Ag5 52.2(4) . . ?
C17 Ag6 Ag5 128.2(4) 2_556 . ?
Ag3 Ag6 Ag5 112.77(4) 2_556 . ?
Ag3 Ag6 Ag5 112.37(3) . . ?
Ag5 Ag6 Ag5 111.33(7) 2_556 . ?
C17 Ag6 Ag2 54.3(4) . . ?
C17 Ag6 Ag2 125.3(4) 2_556 . ?
Ag3 Ag6 Ag2 62.45(4) 2_556 . ?
Ag3 Ag6 Ag2 64.54(4) . . ?
Ag5 Ag6 Ag2 173.18(5) 2_556 . ?
Ag5 Ag6 Ag2 75.33(4) . . ?
C17 Ag6 Ag2 125.3(4) . 2_556 ?
C17 Ag6 Ag2 54.3(4) 2_556 2_556 ?
Ag3 Ag6 Ag2 64.54(4) 2_556 2_556 ?
Ag3 Ag6 Ag2 62.45(4) . 2_556 ?
Ag5 Ag6 Ag2 75.33(4) 2_556 2_556 ?
Ag5 Ag6 Ag2 173.17(5) . 2_556 ?
Ag2 Ag6 Ag2 98.05(6) . 2_556 ?
C17 Ag6 Ag4 89.2(3) . 2_556 ?
C17 Ag6 Ag4 90.8(3) 2_556 2_556 ?
Ag3 Ag6 Ag4 57.84(3) 2_556 2_556 ?
Ag3 Ag6 Ag4 125.42(5) . 2_556 ?
Ag5 Ag6 Ag4 55.93(3) 2_556 2_556 ?
Ag5 Ag6 Ag4 121.40(4) . 2_556 ?
Ag2 Ag6 Ag4 119.79(4) . 2_556 ?
Ag2 Ag6 Ag4 63.17(3) 2_556 2_556 ?
C17 Ag6 Ag4 90.8(3) . . ?
C17 Ag6 Ag4 89.2(3) 2_556 . ?
Ag3 Ag6 Ag4 125.42(5) 2_556 . ?
Ag3 Ag6 Ag4 57.84(3) . . ?
Ag5 Ag6 Ag4 121.40(4) 2_556 . ?
Ag5 Ag6 Ag4 55.93(3) . . ?
Ag2 Ag6 Ag4 63.17(3) . . ?
Ag2 Ag6 Ag4 119.79(4) 2_556 . ?
Ag4 Ag6 Ag4 176.02(7) 2_556 . ?
C17 Ag6 Ag7 50.1(4) . . ?
C17 Ag6 Ag7 130.3(4) 2_556 . ?
Ag3 Ag6 Ag7 76.53(4) 2_556 . ?
Ag3 Ag6 Ag7 168.08(5) . . ?
Ag5 Ag6 Ag7 78.12(4) 2_556 . ?
Ag5 Ag6 Ag7 65.66(4) . . ?
Ag2 Ag6 Ag7 104.08(4) . . ?
Ag2 Ag6 Ag7 118.37(3) 2_556 . ?
Ag4 Ag6 Ag7 55.81(3) 2_556 . ?
Ag4 Ag6 Ag7 121.59(4) . . ?
C17 Ag6 Ag7 130.3(4) . 2_556 ?
C17 Ag6 Ag7 50.1(4) 2_556 2_556 ?
Ag3 Ag6 Ag7 168.08(5) 2_556 2_556 ?
Ag3 Ag6 Ag7 76.53(4) . 2_556 ?
Ag5 Ag6 Ag7 65.67(4) 2_556 2_556 ?
Ag5 Ag6 Ag7 78.12(4) . 2_556 ?
Ag2 Ag6 Ag7 118.37(3) . 2_556 ?
Ag2 Ag6 Ag7 104.08(4) 2_556 2_556 ?
Ag4 Ag6 Ag7 121.60(4) 2_556 2_556 ?
Ag4 Ag6 Ag7 55.81(3) . 2_556 ?
Ag7 Ag6 Ag7 113.57(7) . 2_556 ?
C25 Ag7 O3 104.1(5) 2_556 . ?
C25 Ag7 C17 120.2(5) 2_556 . ?
O3 Ag7 C17 132.2(5) . . ?
C25 Ag7 O4 115.1(5) 2_556 . ?
O3 Ag7 O4 88.8(5) . . ?
C17 Ag7 O4 87.9(4) . . ?
C25 Ag7 C18 145.7(5) 2_556 . ?
O3 Ag7 C18 105.8(5) . . ?
C17 Ag7 C18 26.7(4) . . ?
O4 Ag7 C18 82.1(4) . . ?
C25 Ag7 Ag4 44.8(4) 2_556 2_556 ?
O3 Ag7 Ag4 114.6(4) . 2_556 ?
C17 Ag7 Ag4 88.4(3) . 2_556 ?
O4 Ag7 Ag4 150.8(3) . 2_556 ?
C18 Ag7 Ag4 106.2(3) . 2_556 ?
C25 Ag7 Ag6 79.5(4) 2_556 . ?
O3 Ag7 Ag6 170.9(4) . . ?
C17 Ag7 Ag6 41.8(4) . . ?
O4 Ag7 Ag6 97.2(3) . . ?
C18 Ag7 Ag6 68.6(4) . . ?
Ag4 Ag7 Ag6 62.04(4) 2_556 . ?
C2 C1 Ag4 156.1(14) . . ?
C2 C1 Ag3 116.1(13) . . ?
Ag4 C1 Ag3 86.9(5) . . ?
C2 C1 Ag2 91.5(12) . . ?
Ag4 C1 Ag2 94.7(6) . . ?
Ag3 C1 Ag2 90.0(5) . . ?
C1 C2 C3 173.7(17) . . ?
C4 C3 C8 120.0 . . ?
C4 C3 C2 120.8(10) . . ?
C8 C3 C2 119.1(10) . . ?
C5 C4 C3 120.0 . . ?
C6 C5 C4 120.0 . . ?
C5 C6 C7 120.0 . . ?
C6 C7 C8 120.0 . . ?
C7 C8 C3 120.0 . . ?
C10 C9 Ag1 158.4(17) . . ?
C10 C9 Ag3 116.4(15) . 2_556 ?
Ag1 C9 Ag3 80.4(6) . 2_556 ?
C10 C9 Ag2 111.0(15) . . ?
Ag1 C9 Ag2 82.1(6) . . ?
Ag3 C9 Ag2 86.8(6) 2_556 . ?
C9 C10 C11 176.6(19) . . ?
C12 C11 C16 120.0 . . ?
C12 C11 C10 123.5(11) . . ?
C16 C11 C10 116.5(11) . . ?
C13 C12 C11 120.0 . . ?
C14 C13 C12 120.0 . . ?
C15 C14 C13 120.0 . . ?
C14 C15 C16 120.0 . . ?
C15 C16 C11 120.0 . . ?
C18 C17 Ag6 174.7(14) . . ?
C18 C17 Ag7 86.6(11) . . ?
Ag6 C17 Ag7 88.1(5) . . ?
C18 C17 Ag5 94.8(11) . . ?
Ag6 C17 Ag5 84.7(5) . . ?
Ag7 C17 Ag5 88.1(5) . . ?
C18 C17 Ag2 101.3(11) . . ?
Ag6 C17 Ag2 84.0(5) . . ?
Ag7 C17 Ag2 169.0(7) . . ?
Ag5 C17 Ag2 98.8(4) . . ?
C17 C18 C19 175.6(16) . . ?
C17 C18 Ag7 66.6(10) . . ?
C19 C18 Ag7 117.3(8) . . ?
C20 C19 C24 120.0 . . ?
C20 C19 C18 118.7(9) . . ?
C24 C19 C18 121.3(9) . . ?
C19 C20 C21 120.0 . . ?
C22 C21 C20 120.0 . . ?
C23 C22 C21 120.0 . . ?
C22 C23 C24 120.0 . . ?
C23 C24 C19 120.0 . . ?
C26 C25 Ag4 174.2(15) . . ?
C26 C25 Ag7 100.6(13) . 2_556 ?
Ag4 C25 Ag7 84.4(5) . 2_556 ?
C26 C25 Ag5 97.1(14) . . ?
Ag4 C25 Ag5 83.0(6) . . ?
Ag7 C25 Ag5 116.7(6) 2_556 . ?
C25 C26 C27 178.9(18) . . ?
C28 C27 C32 120.0 . . ?
C28 C27 C26 119.6(13) . . ?
C32 C27 C26 120.2(13) . . ?
C27 C28 C29 120.0 . . ?
C30 C29 C28 120.0 . . ?
C31 C30 C29 120.0 . . ?
C30 C31 C32 120.0 . . ?
C31 C32 C27 120.0 . . ?
S1 O1 Ag5 133.2(7) . . ?
S2 O2 Ag2 119.5(6) . . ?
S3 O3 S3' 44.5(9) . . ?
S3 O3 Ag7 150.1(12) . . ?
S3' O3 Ag7 121.0(11) . . ?
S4 O4 Ag5 124.6(7) . . ?
S4 O4 Ag7 134.8(8) . . ?
Ag5 O4 Ag7 88.3(3) . . ?
S5' O5 S5 50.4(7) . . ?
S5' O5 Ag3 134.1(11) . . ?
S5 O5 Ag3 117.6(9) . . ?
Si1 O6 O7 56.4(7) . . ?
Si1 O6 W5 127.4(9) . . ?
O7 O6 W5 71.0(7) . . ?
Si1 O6 W1 120.5(8) . . ?
O7 O6 W1 134.2(10) . . ?
W5 O6 W1 95.7(6) . . ?
Si1 O6 W6 118.0(8) . . ?
O7 O6 W6 131.2(9) . . ?
W5 O6 W6 94.8(6) . . ?
W1 O6 W6 92.4(6) . . ?
Si1 O7 O6 57.1(7) . . ?
Si1 O7 O8 56.8(7) . . ?
O6 O7 O8 94.3(10) . . ?
Si1 O7 W5 122.6(9) . . ?
O6 O7 W5 65.5(7) . . ?
O8 O7 W5 131.1(9) . . ?
Si1 O7 W3 123.0(7) . 5_667 ?
O6 O7 W3 133.0(9) . 5_667 ?
O8 O7 W3 66.1(7) . 5_667 ?
W5 O7 W3 94.9(5) . 5_667 ?
Si1 O7 W2 121.3(8) . 5_667 ?
O6 O7 W2 127.7(9) . 5_667 ?
O8 O7 W2 130.5(10) . 5_667 ?
W5 O7 W2 93.6(5) . 5_667 ?
W3 O7 W2 94.0(6) 5_667 5_667 ?
Si1 O8 O7 55.4(7) . . ?
Si1 O8 W3 125.0(8) . 5_667 ?
O7 O8 W3 69.6(7) . 5_667 ?
Si1 O8 W1 120.6(8) . 5_667 ?
O7 O8 W1 133.7(10) . 5_667 ?
W3 O8 W1 95.3(6) 5_667 5_667 ?
Si1 O8 W4 120.4(9) . 5_667 ?
O7 O8 W4 130.8(9) . 5_667 ?
W3 O8 W4 95.1(5) 5_667 5_667 ?
W1 O8 W4 92.8(5) 5_667 5_667 ?
Si1 O9 W2 122.9(8) . . ?
Si1 O9 W4 120.7(8) . 5_667 ?
W2 O9 W4 97.2(6) . 5_667 ?
Si1 O9 W6 118.5(8) . . ?
W2 O9 W6 96.2(6) . . ?
W4 O9 W6 95.2(6) 5_667 . ?
W6 O10 W5 138.6(6) . . ?
W5 O11 W1 137.7(6) . . ?
W6 O14 W1 138.3(7) . . ?
W1 O15 W4 137.5(5) . . ?
W6 O16 W4 137.6(6) 5_667 . ?
W2 O17 W4 137.0(6) 5_667 . ?
W4 O19 W3 136.3(5) . . ?
W3 O21 W1 134.9(7) . . ?
W5 O22 W3 136.5(6) 5_667 . ?
W3 O23 W2 138.0(7) . . ?
W2 O24 W5 140.7(6) . 5_667 ?
W6 O25 W2 136.1(8) . . ?
O1 S1 C33 106.3(7) . . ?
O1 S1 C34 106.4(8) . . ?
C33 S1 C34 96.8(11) . . ?
O2 S2 C36 105.8(6) . . ?
O2 S2 C35 105.9(7) . . ?
C36 S2 C35 95.5(7) . . ?
S3' S3 O3 75.5(17) . . ?
S3' S3 C37 80(2) . . ?
O3 S3 C37 121.6(17) . . ?
S3' S3 C38 66.8(17) . . ?
O3 S3 C38 112.4(16) . . ?
C37 S3 C38 105.0(16) . . ?
C40 S4 O4 121(3) . . ?
C40 S4 C39 97(3) . . ?
O4 S4 C39 106.5(13) . . ?
C40 S4 C41 105(3) . . ?
O4 S4 C41 110.1(10) . . ?
C39 S4 C41 117.4(15) . . ?
S5' S5 O5 59.9(9) . . ?
S5' S5 C42 64.2(14) . . ?
O5 S5 C42 105.4(15) . . ?
S5' S5 C43 65.2(13) . . ?
O5 S5 C43 99.5(12) . . ?
C42 S5 C43 97.8(14) . . ?
S3 S3' O3 60.0(14) . . ?
S5 S5' O5 69.7(11) . . ?
O7 Si1 O7 180.0(9) . 5_667 ?
O7 Si1 O6 66.5(8) . . ?
O7 Si1 O6 113.5(8) 5_667 . ?
O7 Si1 O6 113.5(8) . 5_667 ?
O7 Si1 O6 66.5(8) 5_667 5_667 ?
O6 Si1 O6 179.996(8) . 5_667 ?
O7 Si1 O8 67.7(7) . . ?
O7 Si1 O8 112.3(8) 5_667 . ?
O6 Si1 O8 107.3(8) . . ?
O6 Si1 O8 72.7(8) 5_667 . ?
O7 Si1 O8 112.3(8) . 5_667 ?
O7 Si1 O8 67.7(7) 5_667 5_667 ?
O6 Si1 O8 72.7(8) . 5_667 ?
O6 Si1 O8 107.3(8) 5_667 5_667 ?
O8 Si1 O8 180.0(12) . 5_667 ?
O7 Si1 O9 69.8(7) . 5_667 ?
O7 Si1 O9 110.2(7) 5_667 5_667 ?
O6 Si1 O9 104.9(8) . 5_667 ?
O6 Si1 O9 75.1(8) 5_667 5_667 ?
O8 Si1 O9 108.3(8) . 5_667 ?
O8 Si1 O9 71.7(8) 5_667 5_667 ?
O7 Si1 O9 110.2(7) . . ?
O7 Si1 O9 69.8(7) 5_667 . ?
O6 Si1 O9 75.1(8) . . ?
O6 Si1 O9 104.9(8) 5_667 . ?
O8 Si1 O9 71.7(8) . . ?
O8 Si1 O9 108.3(8) 5_667 . ?
O9 Si1 O9 179.999(4) 5_667 . ?
O13 W1 O15 102.8(5) . . ?
O13 W1 O11 100.6(5) . . ?
O15 W1 O11 85.9(4) . . ?
O13 W1 O14 100.7(5) . . ?
O15 W1 O14 156.4(5) . . ?
O11 W1 O14 88.1(4) . . ?
O13 W1 O21 101.8(5) . . ?
O15 W1 O21 92.9(4) . . ?
O11 W1 O21 157.3(5) . . ?
O14 W1 O21 83.9(5) . . ?
O13 W1 O6 155.7(5) . . ?
O15 W1 O6 92.5(5) . . ?
O11 W1 O6 61.4(5) . . ?
O14 W1 O6 64.7(5) . . ?
O21 W1 O6 96.1(5) . . ?
O13 W1 O8 158.1(5) . 5_667 ?
O15 W1 O8 64.6(5) . 5_667 ?
O11 W1 O8 96.4(5) . 5_667 ?
O14 W1 O8 93.4(5) . 5_667 ?
O21 W1 O8 63.0(5) . 5_667 ?
O6 W1 O8 46.2(5) . 5_667 ?
O26 W2 O24 101.5(5) . . ?
O26 W2 O17 100.2(5) . 5_667 ?
O24 W2 O17 89.2(5) . 5_667 ?
O26 W2 O23 101.6(5) . . ?
O24 W2 O23 87.1(4) . . ?
O17 W2 O23 158.1(5) 5_667 . ?
O26 W2 O25 100.5(6) . . ?
O24 W2 O25 157.9(6) . . ?
O17 W2 O25 88.3(4) 5_667 . ?
O23 W2 O25 87.1(5) . . ?
O26 W2 O9 156.7(5) . . ?
O24 W2 O9 95.0(6) . . ?
O17 W2 O9 63.3(5) 5_667 . ?
O23 W2 O9 95.6(5) . . ?
O25 W2 O9 64.5(6) . . ?
O26 W2 O7 157.3(5) . 5_667 ?
O24 W2 O7 62.7(5) . 5_667 ?
O17 W2 O7 95.9(6) 5_667 5_667 ?
O23 W2 O7 63.4(5) . 5_667 ?
O25 W2 O7 95.8(6) . 5_667 ?
O9 W2 O7 46.0(5) . 5_667 ?
O20 W3 O21 100.8(6) . . ?
O20 W3 O23 101.8(5) . . ?
O21 W3 O23 86.8(5) . . ?
O20 W3 O19 100.4(5) . . ?
O21 W3 O19 93.1(5) . . ?
O23 W3 O19 157.4(5) . . ?
O20 W3 O22 100.2(5) . . ?
O21 W3 O22 158.9(5) . . ?
O23 W3 O22 88.3(4) . . ?
O19 W3 O22 83.8(5) . . ?
O20 W3 O8 157.7(6) . 5_667 ?
O21 W3 O8 65.6(5) . 5_667 ?
O23 W3 O8 95.1(5) . 5_667 ?
O19 W3 O8 64.6(5) . 5_667 ?
O22 W3 O8 94.6(5) . 5_667 ?
O20 W3 O7 157.9(5) . 5_667 ?
O21 W3 O7 95.7(5) . 5_667 ?
O23 W3 O7 64.3(5) . 5_667 ?
O19 W3 O7 93.3(5) . 5_667 ?
O22 W3 O7 63.8(5) . 5_667 ?
O8 W3 O7 44.3(5) 5_667 5_667 ?
O18 W4 O16 101.2(5) . . ?
O18 W4 O19 101.9(4) . . ?
O16 W4 O19 86.3(5) . . ?
O18 W4 O15 102.0(5) . . ?
O16 W4 O15 156.5(5) . . ?
O19 W4 O15 92.7(4) . . ?
O18 W4 O17 100.4(5) . . ?
O16 W4 O17 88.5(4) . . ?
O19 W4 O17 157.6(5) . . ?
O15 W4 O17 83.4(5) . . ?
O18 W4 O9 155.8(5) . 5_667 ?
O16 W4 O9 63.9(5) . 5_667 ?
O19 W4 O9 96.3(5) . 5_667 ?
O15 W4 O9 92.9(5) . 5_667 ?
O17 W4 O9 62.1(5) . 5_667 ?
O18 W4 O8 157.0(5) . 5_667 ?
O16 W4 O8 95.1(6) . 5_667 ?
O19 W4 O8 62.7(5) . 5_667 ?
O15 W4 O8 64.1(5) . 5_667 ?
O17 W4 O8 96.1(5) . 5_667 ?
O9 W4 O8 47.2(5) 5_667 5_667 ?
O12 W5 O22 99.7(5) . 5_667 ?
O12 W5 O11 101.5(5) . . ?
O22 W5 O11 158.7(5) 5_667 . ?
O12 W5 O10 101.7(5) . . ?
O22 W5 O10 88.6(5) 5_667 . ?
O11 W5 O10 88.8(4) . . ?
O12 W5 O24 101.8(5) . 5_667 ?
O22 W5 O24 87.4(4) 5_667 5_667 ?
O11 W5 O24 86.7(4) . 5_667 ?
O10 W5 O24 156.5(5) . 5_667 ?
O12 W5 O6 159.5(6) . . ?
O22 W5 O6 95.5(5) 5_667 . ?
O11 W5 O6 64.4(5) . . ?
O10 W5 O6 64.9(5) . . ?
O24 W5 O6 92.4(5) 5_667 . ?
O12 W5 O7 156.9(6) . . ?
O22 W5 O7 64.3(5) 5_667 . ?
O11 W5 O7 94.9(5) . . ?
O10 W5 O7 94.6(5) . . ?
O24 W5 O7 62.8(5) 5_667 . ?
O6 W5 O7 43.5(5) . . ?
O27 W6 O25 100.2(6) . . ?
O27 W6 O14 101.5(5) . . ?
O25 W6 O14 89.8(5) . . ?
O27 W6 O10 100.7(5) . . ?
O25 W6 O10 159.0(6) . . ?
O14 W6 O10 87.6(5) . . ?
O27 W6 O16 100.3(5) . 5_667 ?
O25 W6 O16 87.9(4) . 5_667 ?
O14 W6 O16 158.1(6) . 5_667 ?
O10 W6 O16 86.8(5) . 5_667 ?
O27 W6 O9 155.4(5) . . ?
O25 W6 O9 63.1(5) . . ?
O14 W6 O9 96.6(5) . . ?
O10 W6 O9 96.5(5) . . ?
O16 W6 O9 63.1(5) 5_667 . ?
O27 W6 O6 156.1(5) . . ?
O25 W6 O6 98.9(6) . . ?
O14 W6 O6 64.4(5) . . ?
O10 W6 O6 61.3(5) . . ?
O16 W6 O6 94.5(6) 5_667 . ?
O9 W6 O6 48.4(5) . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.755
_refine_diff_density_min         -1.853
_refine_diff_density_rms         0.235
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 1529051'
_audit_update_record             
;
2017-01-23 deposited with the CCDC.
2017-05-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H65 Ag5 O50 S10 Si W12'
_chemical_formula_weight         4296.04

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.5633(6)
_cell_length_b                   15.5962(6)
_cell_length_c                   18.8084(9)
_cell_angle_alpha                86.273(4)
_cell_angle_beta                 85.954(4)
_cell_angle_gamma                85.935(4)
_cell_volume                     3951.5(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    8338
_cell_measurement_theta_min      3.3130
_cell_measurement_theta_max      28.5490

_exptl_crystal_description       sheet-like
_exptl_crystal_colour            pale-green
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.611
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3860
_exptl_absorpt_coefficient_mu    18.961
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.07580
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            27649
_diffrn_reflns_av_R_equivalents  0.0767
_diffrn_reflns_av_sigmaI/netI    0.1365
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         2.77
_diffrn_reflns_theta_max         25.00
_reflns_number_total             13878
_reflns_number_gt                8789
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000167(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         13878
_refine_ls_number_parameters     1021
_refine_ls_number_restraints     96
_refine_ls_R_factor_all          0.1172
_refine_ls_R_factor_gt           0.0726
_refine_ls_wR_factor_ref         0.0820
_refine_ls_wR_factor_gt          0.0767
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_restrained_S_all      1.088
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.72832(13) 0.70733(15) 0.74770(8) 0.0597(6) Uani 1 1 d . . .
Ag2 Ag 0.51080(12) 0.69620(13) 0.65099(8) 0.0509(5) Uani 1 1 d . . .
Ag3 Ag 0.47050(10) 0.73754(13) 0.80444(7) 0.0447(5) Uani 1 1 d . . .
Ag4 Ag 0.43874(14) 0.91775(17) 0.79800(9) 0.0805(7) Uani 1 1 d . . .
Ag5 Ag 0.31114(10) 0.81827(16) 0.72486(8) 0.0652(7) Uani 1 1 d . . .
C1 C 0.4758(12) 0.8264(15) 0.7106(9) 0.035(6) Uani 1 1 d . . .
C2 C 0.5175(11) 0.8489(16) 0.6547(9) 0.038(7) Uani 1 1 d . . .
C3 C 0.5637(12) 0.8930(15) 0.5932(9) 0.032(5) Uani 1 1 d . . .
C4 C 0.5952(11) 0.8512(14) 0.5327(8) 0.031(5) Uani 1 1 d . . .
H4 H 0.5891 0.7923 0.5321 0.037 Uiso 1 1 calc R . .
C5 C 0.6354(13) 0.8946(17) 0.4737(10) 0.042(6) Uani 1 1 d . . .
H5 H 0.6565 0.8658 0.4331 0.050 Uiso 1 1 calc R . .
C6 C 0.6440(13) 0.9800(18) 0.4753(11) 0.047(7) Uani 1 1 d . . .
H6 H 0.6695 1.0101 0.4346 0.056 Uiso 1 1 calc R . .
C7 C 0.6157(14) 1.0244(17) 0.5364(12) 0.054(7) Uani 1 1 d . . .
H7 H 0.6238 1.0830 0.5376 0.065 Uiso 1 1 calc R . .
C8 C 0.5768(12) 0.9797(15) 0.5928(9) 0.034(5) Uani 1 1 d . . .
H8 H 0.5575 1.0083 0.6338 0.040 Uiso 1 1 calc R . .
C9 C 0.8236(14) 0.912(2) 0.6364(10) 0.078(10) Uani 1 1 d . . .
H9A H 0.8848 0.9205 0.6089 0.116 Uiso 1 1 calc R . .
H9B H 0.7788 0.9616 0.6301 0.116 Uiso 1 1 calc R . .
H9C H 0.7947 0.8623 0.6208 0.116 Uiso 1 1 calc R . .
C10 C 0.7304(12) 0.9364(16) 0.7639(9) 0.049(6) Uani 1 1 d U . .
H10A H 0.6788 0.9047 0.7480 0.074 Uiso 1 1 calc R . .
H10B H 0.7203 0.9959 0.7480 0.074 Uiso 1 1 calc R . .
H10C H 0.7291 0.9314 0.8151 0.074 Uiso 1 1 calc R . .
C11 C 0.8877(11) 0.6376(16) 0.6066(8) 0.047(7) Uani 1 1 d . . .
H11A H 0.8815 0.6332 0.6578 0.071 Uiso 1 1 calc R . .
H11B H 0.9423 0.6714 0.5906 0.071 Uiso 1 1 calc R . .
H11C H 0.8990 0.5810 0.5890 0.071 Uiso 1 1 calc R . .
C12 C 0.7559(12) 0.6284(16) 0.5098(8) 0.052(6) Uani 1 1 d U . .
H12A H 0.7344 0.5737 0.5288 0.077 Uiso 1 1 calc R . .
H12B H 0.8140 0.6196 0.4782 0.077 Uiso 1 1 calc R . .
H12C H 0.7041 0.6584 0.4838 0.077 Uiso 1 1 calc R . .
C13 C 0.7860(11) 0.6686(17) 0.9292(9) 0.049(7) Uani 1 1 d . . .
H13A H 0.8180 0.6172 0.9105 0.073 Uiso 1 1 calc R . .
H13B H 0.7991 0.6704 0.9786 0.073 Uiso 1 1 calc R . .
H13C H 0.8110 0.7181 0.9028 0.073 Uiso 1 1 calc R . .
C14 C 0.6180(14) 0.746(2) 0.9810(11) 0.089(11) Uani 1 1 d . . .
H14A H 0.6508 0.7976 0.9680 0.134 Uiso 1 1 calc R . .
H14B H 0.6336 0.7250 1.0283 0.134 Uiso 1 1 calc R . .
H14C H 0.5477 0.7575 0.9797 0.134 Uiso 1 1 calc R . .
C15 C 0.595(2) 0.442(2) 0.6873(11) 0.115(12) Uani 1 1 d . . .
H15A H 0.6225 0.3875 0.7059 0.173 Uiso 1 1 calc R . .
H15B H 0.6397 0.4654 0.6504 0.173 Uiso 1 1 calc R . .
H15C H 0.5327 0.4344 0.6678 0.173 Uiso 1 1 calc R . .
C16 C 0.5205(16) 0.442(2) 0.8196(12) 0.100(12) Uani 1 1 d . . .
H16A H 0.4910 0.4720 0.8594 0.149 Uiso 1 1 calc R . .
H16B H 0.5698 0.3990 0.8360 0.149 Uiso 1 1 calc R . .
H16C H 0.4703 0.4137 0.7980 0.149 Uiso 1 1 calc R . .
C17 C 0.3986(14) 0.7167(17) 0.4689(10) 0.064(8) Uani 1 1 d . . .
H17A H 0.3827 0.7513 0.5091 0.096 Uiso 1 1 calc R . .
H17B H 0.3409 0.7146 0.4425 0.096 Uiso 1 1 calc R . .
H17C H 0.4504 0.7414 0.4386 0.096 Uiso 1 1 calc R . .
C18 C 0.3334(16) 0.580(2) 0.5470(13) 0.110(12) Uani 1 1 d . . .
H18A H 0.3507 0.5332 0.5807 0.165 Uiso 1 1 calc R . .
H18B H 0.2884 0.5610 0.5149 0.165 Uiso 1 1 calc R . .
H18C H 0.3022 0.6273 0.5720 0.165 Uiso 1 1 calc R . .
C19 C 0.3626(14) 0.5667(18) 1.0054(9) 0.072(9) Uani 1 1 d . . .
H19A H 0.3903 0.5198 0.9780 0.108 Uiso 1 1 calc R . .
H19B H 0.3022 0.5506 1.0309 0.108 Uiso 1 1 calc R . .
H19C H 0.4089 0.5799 1.0387 0.108 Uiso 1 1 calc R . .
C20 C 0.2565(13) 0.6132(18) 0.8964(11) 0.070(9) Uani 1 1 d . . .
H20A H 0.2906 0.5663 0.8722 0.105 Uiso 1 1 calc R . .
H20B H 0.2311 0.6557 0.8618 0.105 Uiso 1 1 calc R . .
H20C H 0.2026 0.5922 0.9269 0.105 Uiso 1 1 calc R . .
C21 C 0.5491(13) 1.201(2) 0.7441(10) 0.079(11) Uani 1 1 d . . .
H21A H 0.5881 1.2127 0.7826 0.118 Uiso 1 1 calc R . .
H21B H 0.5096 1.2522 0.7303 0.118 Uiso 1 1 calc R . .
H21C H 0.5921 1.1838 0.7041 0.118 Uiso 1 1 calc R . .
C22 C 0.4423(13) 1.1545(17) 0.8595(9) 0.061(8) Uani 1 1 d . . .
H22A H 0.3724 1.1557 0.8722 0.091 Uiso 1 1 calc R . .
H22B H 0.4642 1.2117 0.8589 0.091 Uiso 1 1 calc R . .
H22C H 0.4770 1.1180 0.8940 0.091 Uiso 1 1 calc R . .
C23 C 0.3475(14) 0.969(2) 1.0413(10) 0.087(11) Uani 1 1 d . . .
H23A H 0.4090 0.9921 1.0506 0.130 Uiso 1 1 calc R . .
H23B H 0.3209 0.9396 1.0838 0.130 Uiso 1 1 calc R . .
H23C H 0.3014 1.0159 1.0270 0.130 Uiso 1 1 calc R . .
C24 C 0.2432(13) 0.8943(17) 0.9520(10) 0.058(7) Uani 1 1 d . . .
H24A H 0.2120 0.9515 0.9488 0.087 Uiso 1 1 calc R . .
H24B H 0.2083 0.8600 0.9884 0.087 Uiso 1 1 calc R . .
H24C H 0.2420 0.8689 0.9069 0.087 Uiso 1 1 calc R . .
C25 C 0.1115(18) 0.931(2) 0.5683(19) 0.144(15) Uani 1 1 d . . .
H25A H 0.1181 0.9796 0.5955 0.217 Uiso 1 1 calc R . .
H25B H 0.0445 0.9306 0.5549 0.217 Uiso 1 1 calc R . .
H25C H 0.1556 0.9336 0.5261 0.217 Uiso 1 1 calc R . .
C26 C 0.0954(17) 0.764(2) 0.5827(13) 0.095(10) Uani 1 1 d . . .
H26A H 0.0419 0.7843 0.5538 0.142 Uiso 1 1 calc R . .
H26B H 0.0715 0.7255 0.6207 0.142 Uiso 1 1 calc R . .
H26C H 0.1467 0.7349 0.5539 0.142 Uiso 1 1 calc R . .
C27 C 0.0404(12) 0.6880(16) 0.7951(10) 0.052(7) Uani 1 1 d . . .
H27A H 0.0686 0.6644 0.7517 0.078 Uiso 1 1 calc R . .
H27B H -0.0305 0.6874 0.7966 0.078 Uiso 1 1 calc R . .
H27C H 0.0647 0.6540 0.8353 0.078 Uiso 1 1 calc R . .
C28 C 0.0230(11) 0.8213(17) 0.8836(9) 0.049(7) Uani 1 1 d . . .
H28A H 0.0455 0.7774 0.9180 0.073 Uiso 1 1 calc R . .
H28B H -0.0479 0.8234 0.8839 0.073 Uiso 1 1 calc R . .
H28C H 0.0432 0.8761 0.8955 0.073 Uiso 1 1 calc R . .
O1 O 1.1264(6) 0.3303(8) 0.7535(4) 0.017(3) Uani 1 1 d . . .
O2 O 1.0587(7) 0.1842(9) 0.8066(5) 0.024(3) Uani 1 1 d . . .
O3 O 0.9834(6) 0.2578(8) 0.6914(5) 0.017(3) Uani 1 1 d U . .
O4 O 0.9440(6) 0.3260(8) 0.8165(5) 0.016(3) Uani 1 1 d U . .
O5 O 0.9446(7) 0.1417(10) 0.6112(5) 0.034(4) Uani 1 1 d . . .
O6 O 0.8997(7) 0.1031(9) 0.7487(5) 0.030(4) Uani 1 1 d . . .
O7 O 0.7861(7) 0.2452(9) 0.7577(5) 0.025(3) Uani 1 1 d . . .
O8 O 0.8283(7) 0.2873(8) 0.6199(5) 0.021(3) Uani 1 1 d U . .
O9 O 0.7466(7) 0.1322(10) 0.6554(5) 0.041(4) Uani 1 1 d . . .
O10 O 0.8620(7) 0.1722(10) 0.8716(5) 0.035(4) Uani 1 1 d . . .
O11 O 0.8430(7) 0.3181(9) 0.9359(5) 0.024(3) Uani 1 1 d . . .
O12 O 0.7677(7) 0.3957(9) 0.8193(5) 0.025(3) Uani 1 1 d . . .
O13 O 0.6745(7) 0.2581(9) 0.8862(5) 0.030(3) Uani 1 1 d . . .
O14 O 0.9093(7) 0.4668(9) 0.8828(5) 0.025(3) Uani 1 1 d U . .
O15 O 1.0298(7) 0.2538(9) 0.9440(5) 0.026(3) Uani 1 1 d U . .
O16 O 1.0966(7) 0.3970(9) 0.8929(5) 0.024(3) Uani 1 1 d . . .
O17 O 0.9676(8) 0.4028(9) 1.0155(5) 0.032(3) Uani 1 1 d . . .
O18 O 1.2067(7) 0.2597(9) 0.8809(5) 0.026(3) Uani 1 1 d . . .
O19 O 1.3126(6) 0.3248(8) 0.7699(5) 0.024(3) Uani 1 1 d . . .
O20 O 1.1984(7) 0.4718(9) 0.7800(5) 0.025(3) Uani 1 1 d . . .
O21 O 1.2992(7) 0.4062(10) 0.8974(5) 0.039(4) Uani 1 1 d . . .
O22 O 1.2526(7) 0.1774(9) 0.7324(5) 0.026(3) Uani 1 1 d . . .
O23 O 1.1788(7) 0.2512(8) 0.6203(5) 0.021(3) Uani 1 1 d U . .
O24 O 1.2373(7) 0.4001(9) 0.6547(5) 0.026(3) Uani 1 1 d . . .
O25 O 1.3780(7) 0.2725(9) 0.6370(5) 0.029(4) Uani 1 1 d . . .
O26 O 1.1159(7) 0.1052(9) 0.6724(5) 0.028(4) Uani 1 1 d . . .
O27 O 1.0118(7) 0.2885(9) 0.5575(5) 0.028(4) Uani 1 1 d . . .
O28 O 1.1182(8) 0.1374(10) 0.5244(5) 0.037(4) Uani 1 1 d . . .
O29 O 1.0647(7) 0.0174(9) 0.7951(5) 0.028(3) Uani 1 1 d U . .
O30 O 1.2060(7) 0.0908(9) 0.8566(5) 0.029(4) Uani 1 1 d . . .
O31 O 1.2596(7) -0.0030(10) 0.7398(5) 0.039(3) Uani 1 1 d U . .
O32 O 1.0247(7) 0.0879(10) 0.9208(5) 0.038(4) Uani 1 1 d . . .
O33 O 1.1801(7) 0.1383(10) 0.9961(5) 0.037(4) Uani 1 1 d . . .
O34 O 0.8839(8) -0.0095(9) 0.8703(5) 0.037(4) Uani 1 1 d . . .
O35 O 0.8662(7) 0.4207(8) 0.6942(5) 0.020(3) Uani 1 1 d . . .
O36 O 1.0049(7) 0.4880(9) 0.7545(5) 0.023(3) Uani 1 1 d . . .
O37 O 0.8129(7) 0.5601(10) 0.7758(5) 0.040(4) Uani 1 1 d . . .
O38 O 1.0438(7) 0.4241(8) 0.6319(5) 0.023(3) Uani 1 1 d U . .
O39 O 1.1407(7) 0.5706(9) 0.6599(5) 0.031(3) Uani 1 1 d . . .
O40 O 0.8834(8) 0.4361(10) 0.5451(5) 0.045(5) Uani 1 1 d . . .
O41 O 0.8536(9) 0.7996(12) 0.7463(8) 0.072(5) Uani 1 1 d . . .
O42 O 0.7007(8) 0.6738(11) 0.6370(5) 0.046(5) Uani 1 1 d . . .
O43 O 0.6364(8) 0.7115(12) 0.8500(6) 0.064(6) Uani 1 1 d . . .
O44 O 0.4951(12) 0.5810(16) 0.7387(8) 0.094(6) Uani 1 1 d U . .
O45 O 0.5150(8) 0.6235(11) 0.5509(6) 0.049(5) Uani 1 1 d . . .
O46 O 0.4337(9) 0.6663(13) 0.9051(7) 0.078(7) Uani 1 1 d . . .
O47 O 0.5141(16) 1.0418(17) 0.7720(12) 0.129(9) Uani 1 1 d . . .
O48 O 0.4218(10) 0.9397(13) 0.9138(6) 0.078(6) Uani 1 1 d . . .
O49 O 0.2559(9) 0.8299(12) 0.6110(7) 0.074(6) Uani 1 1 d . . .
O50 O 0.1847(8) 0.7931(10) 0.8060(6) 0.042(4) Uani 1 1 d . . .
S1 S 0.8470(3) 0.8943(5) 0.7278(3) 0.0480(18) Uani 1 1 d . . .
S2 S 0.7815(17) 0.686(2) 0.5751(13) 0.039(7) Uani 0.20 1 d PU . .
S3 S 0.6575(3) 0.6687(5) 0.9216(3) 0.0456(17) Uani 1 1 d . . .
S4 S 0.5756(5) 0.5140(6) 0.7569(4) 0.052(2) Uani 0.80 1 d P . .
S5 S 0.4384(4) 0.6117(5) 0.4993(3) 0.0510(18) Uani 1 1 d . . .
S6 S 0.3372(5) 0.6590(6) 0.9468(3) 0.042(2) Uani 0.80 1 d P . .
S6' S 0.377(2) 0.601(3) 0.9159(15) 0.052(8) Uani 0.20 1 d PU . .
S7 S 0.4670(9) 1.1137(13) 0.7736(7) 0.054(5) Uani 0.45 1 d P . .
S8 S 0.3676(5) 0.8989(6) 0.9738(3) 0.078(3) Uani 1 1 d . . .
S9 S 0.1387(10) 0.8441(14) 0.6155(8) 0.055(5) Uani 0.40 1 d P . .
S10 S 0.0748(3) 0.7976(4) 0.7981(2) 0.0397(16) Uani 1 1 d . . .
S2' S 0.7659(4) 0.6041(5) 0.6026(3) 0.038(2) Uani 0.80 1 d P . .
S4' S 0.470(3) 0.495(4) 0.742(2) 0.119(16) Uani 0.20 1 d PU . .
S7' S 0.5424(7) 1.1122(8) 0.7991(5) 0.039(3) Uani 0.55 1 d P . .
S9' S 0.1790(7) 0.8354(8) 0.5554(5) 0.050(3) Uani 0.60 1 d P . .
Si1 Si 1.0287(3) 0.2744(4) 0.7670(2) 0.0116(12) Uani 1 1 d . . .
W1 W 1.07202(5) 0.18618(6) 0.59949(3) 0.0242(2) Uani 1 1 d . . .
W2 W 0.94946(5) 0.07577(6) 0.84045(4) 0.0267(2) Uani 1 1 d . . .
W3 W 1.12431(5) 0.46789(6) 0.69638(3) 0.0231(2) Uani 1 1 d . . .
W4 W 0.96915(5) 0.36755(6) 0.93225(3) 0.0233(2) Uani 1 1 d . . .
W5 W 0.84446(5) 0.18275(6) 0.67925(4) 0.0258(2) Uani 1 1 d . . .
W6 W 1.21924(5) 0.37100(6) 0.84270(3) 0.0245(2) Uani 1 1 d . . .
W7 W 0.92800(5) 0.36913(6) 0.61043(3) 0.0247(2) Uani 1 1 d . . .
W8 W 1.26844(5) 0.28610(6) 0.68428(3) 0.0233(2) Uani 1 1 d . . .
W9 W 1.12636(5) 0.16570(6) 0.91861(3) 0.0255(2) Uani 1 1 d . . .
W10 W 0.87422(5) 0.46320(6) 0.78574(3) 0.0220(2) Uani 1 1 d . . .
W11 W 0.79074(5) 0.27683(6) 0.85386(4) 0.0239(2) Uani 1 1 d . . .
W12 W 1.17784(5) 0.07967(6) 0.76020(4) 0.0258(2) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O43 2.220(11) . ?
Ag1 O42 2.242(10) . ?
Ag1 O41 2.301(16) . ?
Ag1 O37 2.534(14) . ?
Ag2 O45 2.256(12) . ?
Ag2 O44 2.37(2) . ?
Ag2 C1 2.38(2) . ?
Ag2 C2 2.39(2) . ?
Ag2 O42 2.572(11) . ?
Ag2 Ag3 3.002(2) . ?
Ag3 C1 2.173(19) . ?
Ag3 O46 2.177(13) . ?
Ag3 O43 2.462(11) . ?
Ag3 Ag4 2.809(3) . ?
Ag3 Ag5 2.885(2) . ?
Ag4 O48 2.219(12) . ?
Ag4 C1 2.25(2) . ?
Ag4 O47 2.26(2) . ?
Ag4 Ag5 2.879(3) . ?
Ag5 C1 2.242(16) . ?
Ag5 O50 2.253(10) . ?
Ag5 O49 2.310(13) . ?
C1 C2 1.20(2) . ?
C2 C3 1.44(2) . ?
C3 C8 1.37(3) . ?
C3 C4 1.38(2) . ?
C4 C5 1.36(2) . ?
C5 C6 1.35(3) . ?
C6 C7 1.40(3) . ?
C7 C8 1.33(2) . ?
C9 S1 1.768(18) . ?
C10 S1 1.775(16) . ?
C11 S2 1.70(3) . ?
C12 S2 1.64(3) . ?
C13 S3 1.758(15) . ?
C14 S3 1.73(2) . ?
C15 S4 1.77(2) . ?
C16 S4 1.75(2) . ?
C17 S5 1.76(2) . ?
C18 S5 1.72(2) . ?
C19 S6 1.78(2) . ?
C20 S6 1.72(2) . ?
C21 S7 1.85(3) . ?
C22 S7 1.78(2) . ?
C23 S8 1.73(2) . ?
C24 S8 1.772(17) . ?
C25 S9 1.60(4) . ?
C26 S9 1.59(3) . ?
C27 S10 1.81(2) . ?
C28 S10 1.761(16) . ?
O1 Si1 1.633(11) . ?
O1 W6 2.313(9) . ?
O1 W3 2.336(12) . ?
O1 W8 2.336(9) . ?
O2 Si1 1.590(13) . ?
O2 W9 2.350(9) . ?
O2 W2 2.354(12) . ?
O2 W12 2.375(12) . ?
O3 Si1 1.630(10) . ?
O3 W5 2.320(10) . ?
O3 W1 2.334(10) . ?
O3 W7 2.352(11) . ?
O4 Si1 1.628(11) . ?
O4 W11 2.313(9) . ?
O4 W10 2.332(12) . ?
O4 W4 2.366(9) . ?
O5 W5 1.905(10) . ?
O5 W1 1.901(10) . ?
O6 W5 1.898(11) . ?
O6 W2 1.910(10) . ?
O7 W11 1.911(10) . ?
O7 W5 1.915(11) . ?
O8 W7 1.916(11) . ?
O8 W5 1.924(12) . ?
O9 W5 1.693(11) . ?
O10 W11 1.860(13) . ?
O10 W2 1.943(13) . ?
O11 W11 1.908(10) . ?
O11 W4 1.922(10) . ?
O12 W10 1.896(11) . ?
O12 W11 1.936(13) . ?
O13 W11 1.687(10) . ?
O14 W4 1.913(12) . ?
O14 W10 1.925(9) . ?
O15 W9 1.890(12) . ?
O15 W4 1.909(13) . ?
O16 W6 1.885(9) . ?
O16 W4 1.907(9) . ?
O17 W4 1.691(10) . ?
O18 W6 1.849(13) . ?
O18 W9 1.955(12) . ?
O19 W8 1.905(10) . ?
O19 W6 1.937(10) . ?
O20 W6 1.919(13) . ?
O20 W3 1.932(9) . ?
O21 W6 1.689(11) . ?
O22 W8 1.888(13) . ?
O22 W12 1.915(12) . ?
O23 W8 1.901(10) . ?
O23 W1 1.901(11) . ?
O24 W8 1.857(13) . ?
O24 W3 1.947(11) . ?
O25 W8 1.685(9) . ?
O26 W1 1.901(11) . ?
O26 W12 1.911(9) . ?
O27 W1 1.892(13) . ?
O27 W7 1.915(12) . ?
O28 W1 1.707(11) . ?
O29 W2 1.926(11) . ?
O29 W12 1.928(11) . ?
O30 W12 1.900(10) . ?
O30 W9 1.927(11) . ?
O31 W12 1.685(13) . ?
O32 W9 1.897(12) . ?
O32 W2 1.909(10) . ?
O33 W9 1.692(10) . ?
O34 W2 1.696(12) . ?
O35 W10 1.898(10) . ?
O35 W7 1.927(10) . ?
O36 W10 1.887(9) . ?
O36 W3 1.907(9) . ?
O37 W10 1.679(14) . ?
O38 W3 1.879(10) . ?
O38 W7 1.921(11) . ?
O39 W3 1.724(13) . ?
O40 W7 1.678(12) . ?
O41 S1 1.493(18) . ?
O42 S2' 1.501(14) . ?
O42 S2 1.55(3) . ?
O43 S3 1.501(13) . ?
O44 S4' 1.40(6) . ?
O44 S4 1.50(2) . ?
O45 S5 1.499(11) . ?
O46 S6' 1.32(4) . ?
O46 S6 1.486(13) . ?
O47 S7 1.25(3) . ?
O47 S7' 1.33(2) . ?
O48 S8 1.440(15) . ?
O49 S9' 1.521(14) . ?
O49 S9 1.585(17) . ?
O50 S10 1.504(11) . ?
S2 S2' 1.37(3) . ?
S4 S4' 1.54(4) . ?
S6 S6' 1.19(4) . ?
S7 S7' 1.158(13) . ?
S9 S9' 1.231(15) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O43 Ag1 O42 134.2(5) . . ?
O43 Ag1 O41 110.4(6) . . ?
O42 Ag1 O41 111.3(5) . . ?
O43 Ag1 O37 95.4(5) . . ?
O42 Ag1 O37 92.0(5) . . ?
O41 Ag1 O37 104.1(5) . . ?
O45 Ag2 O44 100.1(6) . . ?
O45 Ag2 C1 149.9(6) . . ?
O44 Ag2 C1 107.0(6) . . ?
O45 Ag2 C2 125.4(6) . . ?
O44 Ag2 C2 134.5(6) . . ?
C1 Ag2 C2 29.1(5) . . ?
O45 Ag2 O42 84.6(4) . . ?
O44 Ag2 O42 93.6(5) . . ?
C1 Ag2 O42 106.0(5) . . ?
C2 Ag2 O42 92.0(5) . . ?
O45 Ag2 Ag3 159.9(4) . . ?
O44 Ag2 Ag3 61.4(5) . . ?
C1 Ag2 Ag3 45.8(4) . . ?
C2 Ag2 Ag3 73.3(4) . . ?
O42 Ag2 Ag3 103.5(2) . . ?
C1 Ag3 O46 166.7(6) . . ?
C1 Ag3 O43 110.2(6) . . ?
O46 Ag3 O43 79.8(5) . . ?
C1 Ag3 Ag4 51.9(6) . . ?
O46 Ag3 Ag4 118.3(5) . . ?
O43 Ag3 Ag4 103.7(4) . . ?
C1 Ag3 Ag5 50.2(4) . . ?
O46 Ag3 Ag5 118.6(4) . . ?
O43 Ag3 Ag5 159.5(4) . . ?
Ag4 Ag3 Ag5 60.73(7) . . ?
C1 Ag3 Ag2 51.9(6) . . ?
O46 Ag3 Ag2 136.4(5) . . ?
O43 Ag3 Ag2 101.6(3) . . ?
Ag4 Ag3 Ag2 103.78(7) . . ?
Ag5 Ag3 Ag2 71.95(6) . . ?
O48 Ag4 C1 148.9(7) . . ?
O48 Ag4 O47 92.5(7) . . ?
C1 Ag4 O47 110.3(7) . . ?
O48 Ag4 Ag3 99.9(5) . . ?
C1 Ag4 Ag3 49.4(5) . . ?
O47 Ag4 Ag3 143.5(6) . . ?
O48 Ag4 Ag5 124.7(4) . . ?
C1 Ag4 Ag5 50.0(4) . . ?
O47 Ag4 Ag5 135.1(7) . . ?
Ag3 Ag4 Ag5 60.94(7) . . ?
C1 Ag5 O50 143.8(5) . . ?
C1 Ag5 O49 105.7(6) . . ?
O50 Ag5 O49 110.3(5) . . ?
C1 Ag5 Ag4 50.3(5) . . ?
O50 Ag5 Ag4 104.0(3) . . ?
O49 Ag5 Ag4 133.2(4) . . ?
C1 Ag5 Ag3 48.2(5) . . ?
O50 Ag5 Ag3 98.4(3) . . ?
O49 Ag5 Ag3 140.9(4) . . ?
Ag4 Ag5 Ag3 58.33(7) . . ?
C2 C1 Ag3 148.6(17) . . ?
C2 C1 Ag5 122.8(14) . . ?
Ag3 C1 Ag5 81.6(6) . . ?
C2 C1 Ag4 121.8(18) . . ?
Ag3 C1 Ag4 78.8(6) . . ?
Ag5 C1 Ag4 79.7(6) . . ?
C2 C1 Ag2 75.9(15) . . ?
Ag3 C1 Ag2 82.3(7) . . ?
Ag5 C1 Ag2 96.8(8) . . ?
Ag4 C1 Ag2 161.0(9) . . ?
C1 C2 C3 168(2) . . ?
C1 C2 Ag2 75.0(16) . . ?
C3 C2 Ag2 116.8(14) . . ?
C8 C3 C4 117.7(18) . . ?
C8 C3 C2 120.6(19) . . ?
C4 C3 C2 122(2) . . ?
C5 C4 C3 121(2) . . ?
C6 C5 C4 119(2) . . ?
C5 C6 C7 121.7(19) . . ?
C8 C7 C6 117(2) . . ?
C7 C8 C3 123(2) . . ?
Si1 O1 W6 124.8(5) . . ?
Si1 O1 W3 123.6(5) . . ?
W6 O1 W3 92.1(4) . . ?
Si1 O1 W8 123.7(7) . . ?
W6 O1 W8 92.0(3) . . ?
W3 O1 W8 91.2(3) . . ?
Si1 O2 W9 125.2(7) . . ?
Si1 O2 W2 125.1(5) . . ?
W9 O2 W2 90.3(4) . . ?
Si1 O2 W12 124.8(5) . . ?
W9 O2 W12 90.5(4) . . ?
W2 O2 W12 90.3(5) . . ?
Si1 O3 W5 125.2(5) . . ?
Si1 O3 W1 123.9(5) . . ?
W5 O3 W1 91.6(4) . . ?
Si1 O3 W7 123.6(7) . . ?
W5 O3 W7 91.4(3) . . ?
W1 O3 W7 91.3(3) . . ?
Si1 O4 W11 125.1(7) . . ?
Si1 O4 W10 124.0(5) . . ?
W11 O4 W10 91.9(3) . . ?
Si1 O4 W4 123.4(5) . . ?
W11 O4 W4 91.8(3) . . ?
W10 O4 W4 90.7(4) . . ?
W5 O5 W1 122.5(7) . . ?
W5 O6 W2 151.4(8) . . ?
W11 O7 W5 149.2(6) . . ?
W7 O8 W5 121.1(5) . . ?
W11 O10 W2 151.7(6) . . ?
W11 O11 W4 122.6(5) . . ?
W10 O12 W11 121.3(5) . . ?
W4 O14 W10 121.1(6) . . ?
W9 O15 W4 152.3(6) . . ?
W6 O16 W4 152.2(8) . . ?
W6 O18 W9 151.6(6) . . ?
W8 O19 W6 121.0(4) . . ?
W6 O20 W3 120.7(6) . . ?
W8 O22 W12 152.3(6) . . ?
W8 O23 W1 151.5(6) . . ?
W8 O24 W3 122.7(5) . . ?
W1 O26 W12 150.3(8) . . ?
W1 O27 W7 123.4(5) . . ?
W2 O29 W12 120.8(7) . . ?
W12 O30 W9 122.5(5) . . ?
W9 O32 W2 122.5(6) . . ?
W10 O35 W7 150.7(5) . . ?
W10 O36 W3 152.0(7) . . ?
W10 O37 Ag1 174.1(6) . . ?
W3 O38 W7 151.9(5) . . ?
S1 O41 Ag1 127.2(8) . . ?
S2' O42 S2 53.1(13) . . ?
S2' O42 Ag1 119.1(7) . . ?
S2 O42 Ag1 120.3(11) . . ?
S2' O42 Ag2 130.4(8) . . ?
S2 O42 Ag2 135.8(11) . . ?
Ag1 O42 Ag2 96.3(4) . . ?
S3 O43 Ag1 128.9(7) . . ?
S3 O43 Ag3 124.9(7) . . ?
Ag1 O43 Ag3 100.0(4) . . ?
S4' O44 S4 64(2) . . ?
S4' O44 Ag2 138(2) . . ?
S4 O44 Ag2 125.4(10) . . ?
S5 O45 Ag2 132.5(8) . . ?
S6' O46 S6 49.7(15) . . ?
S6' O46 Ag3 127.6(16) . . ?
S6 O46 Ag3 130.5(9) . . ?
S7 O47 S7' 53.1(12) . . ?
S7 O47 Ag4 121.8(16) . . ?
S7' O47 Ag4 144.6(14) . . ?
S8 O48 Ag4 133.6(11) . . ?
S9' O49 S9 46.6(6) . . ?
S9' O49 Ag5 155.8(10) . . ?
S9 O49 Ag5 109.6(9) . . ?
S10 O50 Ag5 130.5(7) . . ?
O41 S1 C9 108.5(13) . . ?
O41 S1 C10 107.3(10) . . ?
C9 S1 C10 97.7(9) . . ?
S2' S2 O42 61.6(13) . . ?
S2' S2 C12 71.9(18) . . ?
O42 S2 C12 108.3(18) . . ?
S2' S2 C11 69.8(15) . . ?
O42 S2 C11 105.5(16) . . ?
C12 S2 C11 106(2) . . ?
O43 S3 C14 104.0(11) . . ?
O43 S3 C13 107.0(8) . . ?
C14 S3 C13 99.2(10) . . ?
S4' S4 O44 55(2) . . ?
S4' S4 C16 65.7(19) . . ?
O44 S4 C16 105.6(11) . . ?
S4' S4 C15 77(2) . . ?
O44 S4 C15 109.1(12) . . ?
C16 S4 C15 96.2(15) . . ?
O45 S5 C18 108.4(10) . . ?
O45 S5 C17 105.0(11) . . ?
C18 S5 C17 100.8(13) . . ?
S6' S6 O46 57.9(18) . . ?
S6' S6 C20 68.7(17) . . ?
O46 S6 C20 109.3(10) . . ?
S6' S6 C19 68.0(17) . . ?
O46 S6 C19 101.9(10) . . ?
C20 S6 C19 97.0(12) . . ?
S6 S6' O46 72(2) . . ?
S7' S7 O47 67.0(13) . . ?
S7' S7 C22 73.5(11) . . ?
O47 S7 C22 115.7(18) . . ?
S7' S7 C21 62.9(11) . . ?
O47 S7 C21 110.7(15) . . ?
C22 S7 C21 92.2(14) . . ?
O48 S8 C23 109.5(13) . . ?
O48 S8 C24 108.3(9) . . ?
C23 S8 C24 98.4(10) . . ?
S9' S9 C26 71.5(13) . . ?
S9' S9 O49 64.0(9) . . ?
C26 S9 O49 108.2(16) . . ?
S9' S9 C25 73.0(15) . . ?
C26 S9 C25 110.0(16) . . ?
O49 S9 C25 107.1(15) . . ?
O50 S10 C28 103.8(7) . . ?
O50 S10 C27 106.9(8) . . ?
C28 S10 C27 100.0(11) . . ?
S2 S2' O42 65.4(13) . . ?
O44 S4' S4 61(2) . . ?
S7 S7' O47 59.9(13) . . ?
S9 S9' O49 69.4(9) . . ?
O2 Si1 O4 109.1(6) . . ?
O2 Si1 O3 109.0(7) . . ?
O4 Si1 O3 108.8(5) . . ?
O2 Si1 O1 109.2(6) . . ?
O4 Si1 O1 109.9(6) . . ?
O3 Si1 O1 110.7(5) . . ?
O28 W1 O27 99.9(5) . . ?
O28 W1 O26 101.5(6) . . ?
O27 W1 O26 158.6(5) . . ?
O28 W1 O5 100.1(5) . . ?
O27 W1 O5 88.1(5) . . ?
O26 W1 O5 89.4(5) . . ?
O28 W1 O23 102.2(5) . . ?
O27 W1 O23 88.2(5) . . ?
O26 W1 O23 86.1(5) . . ?
O5 W1 O23 157.7(4) . . ?
O28 W1 O3 169.9(4) . . ?
O27 W1 O3 73.1(4) . . ?
O26 W1 O3 85.9(4) . . ?
O5 W1 O3 72.8(4) . . ?
O23 W1 O3 85.1(4) . . ?
O34 W2 O32 100.6(5) . . ?
O34 W2 O6 101.6(5) . . ?
O32 W2 O6 157.7(6) . . ?
O34 W2 O29 100.4(6) . . ?
O32 W2 O29 88.5(5) . . ?
O6 W2 O29 89.3(4) . . ?
O34 W2 O10 101.9(6) . . ?
O32 W2 O10 88.1(5) . . ?
O6 W2 O10 85.6(5) . . ?
O29 W2 O10 157.7(5) . . ?
O34 W2 O2 172.2(5) . . ?
O32 W2 O2 73.4(4) . . ?
O6 W2 O2 84.6(4) . . ?
O29 W2 O2 74.7(5) . . ?
O10 W2 O2 83.2(5) . . ?
O39 W3 O38 102.5(5) . . ?
O39 W3 O36 100.3(5) . . ?
O38 W3 O36 85.8(4) . . ?
O39 W3 O20 98.8(5) . . ?
O38 W3 O20 158.7(5) . . ?
O36 W3 O20 89.1(4) . . ?
O39 W3 O24 103.4(5) . . ?
O38 W3 O24 89.2(4) . . ?
O36 W3 O24 156.3(5) . . ?
O20 W3 O24 87.3(4) . . ?
O39 W3 O1 170.9(4) . . ?
O38 W3 O1 85.6(4) . . ?
O36 W3 O1 84.2(4) . . ?
O20 W3 O1 73.2(5) . . ?
O24 W3 O1 72.3(4) . . ?
O17 W4 O16 101.9(5) . . ?
O17 W4 O15 102.4(5) . . ?
O16 W4 O15 84.8(5) . . ?
O17 W4 O14 100.4(5) . . ?
O16 W4 O14 90.2(5) . . ?
O15 W4 O14 157.1(4) . . ?
O17 W4 O11 100.9(5) . . ?
O16 W4 O11 157.2(4) . . ?
O15 W4 O11 88.4(5) . . ?
O14 W4 O11 87.7(5) . . ?
O17 W4 O4 170.8(4) . . ?
O16 W4 O4 85.5(4) . . ?
O15 W4 O4 83.6(4) . . ?
O14 W4 O4 73.8(4) . . ?
O11 W4 O4 72.0(4) . . ?
O9 W5 O6 102.6(6) . . ?
O9 W5 O5 100.3(5) . . ?
O6 W5 O5 88.5(5) . . ?
O9 W5 O7 101.5(5) . . ?
O6 W5 O7 86.6(5) . . ?
O5 W5 O7 158.2(5) . . ?
O9 W5 O8 99.1(5) . . ?
O6 W5 O8 158.3(5) . . ?
O5 W5 O8 88.8(5) . . ?
O7 W5 O8 88.0(5) . . ?
O9 W5 O3 170.3(4) . . ?
O6 W5 O3 84.6(4) . . ?
O5 W5 O3 73.0(4) . . ?
O7 W5 O3 85.4(4) . . ?
O8 W5 O3 74.1(4) . . ?
O21 W6 O18 100.8(6) . . ?
O21 W6 O16 101.4(5) . . ?
O18 W6 O16 85.5(5) . . ?
O21 W6 O20 100.6(6) . . ?
O18 W6 O20 158.6(4) . . ?
O16 W6 O20 90.2(5) . . ?
O21 W6 O19 99.6(5) . . ?
O18 W6 O19 88.3(5) . . ?
O16 W6 O19 158.8(4) . . ?
O20 W6 O19 88.2(4) . . ?
O21 W6 O1 171.1(4) . . ?
O18 W6 O1 84.8(4) . . ?
O16 W6 O1 85.8(4) . . ?
O20 W6 O1 74.0(4) . . ?
O19 W6 O1 73.5(4) . . ?
O40 W7 O8 99.9(6) . . ?
O40 W7 O27 101.9(5) . . ?
O8 W7 O27 88.6(5) . . ?
O40 W7 O38 101.9(6) . . ?
O8 W7 O38 158.0(4) . . ?
O27 W7 O38 89.0(5) . . ?
O40 W7 O35 101.3(5) . . ?
O8 W7 O35 88.4(4) . . ?
O27 W7 O35 156.7(4) . . ?
O38 W7 O35 85.3(4) . . ?
O40 W7 O3 171.0(6) . . ?
O8 W7 O3 73.4(4) . . ?
O27 W7 O3 72.3(4) . . ?
O38 W7 O3 85.0(4) . . ?
O35 W7 O3 84.8(4) . . ?
O25 W8 O24 98.1(5) . . ?
O25 W8 O22 103.5(6) . . ?
O24 W8 O22 158.3(4) . . ?
O25 W8 O23 101.9(5) . . ?
O24 W8 O23 89.3(5) . . ?
O22 W8 O23 85.3(5) . . ?
O25 W8 O19 99.7(5) . . ?
O24 W8 O19 88.8(5) . . ?
O22 W8 O19 88.5(5) . . ?
O23 W8 O19 158.3(4) . . ?
O25 W8 O1 169.3(6) . . ?
O24 W8 O1 73.8(4) . . ?
O22 W8 O1 84.8(4) . . ?
O23 W8 O1 85.3(4) . . ?
O19 W8 O1 73.5(4) . . ?
O33 W9 O15 103.2(5) . . ?
O33 W9 O32 102.7(5) . . ?
O15 W9 O32 89.2(5) . . ?
O33 W9 O30 99.4(5) . . ?
O15 W9 O30 157.3(4) . . ?
O32 W9 O30 88.3(5) . . ?
O33 W9 O18 100.3(5) . . ?
O15 W9 O18 85.3(5) . . ?
O32 W9 O18 157.1(4) . . ?
O30 W9 O18 88.3(5) . . ?
O33 W9 O2 172.0(6) . . ?
O15 W9 O2 84.0(4) . . ?
O32 W9 O2 73.7(4) . . ?
O30 W9 O2 73.5(4) . . ?
O18 W9 O2 83.6(4) . . ?
O37 W10 O36 102.1(6) . . ?
O37 W10 O35 101.2(5) . . ?
O36 W10 O35 86.0(4) . . ?
O37 W10 O12 99.8(5) . . ?
O36 W10 O12 158.0(5) . . ?
O35 W10 O12 88.3(4) . . ?
O37 W10 O14 99.6(5) . . ?
O36 W10 O14 89.0(4) . . ?
O35 W10 O14 159.2(5) . . ?
O12 W10 O14 88.8(4) . . ?
O37 W10 O4 170.9(4) . . ?
O36 W10 O4 84.9(4) . . ?
O35 W10 O4 85.0(4) . . ?
O12 W10 O4 73.5(4) . . ?
O14 W10 O4 74.4(4) . . ?
O13 W11 O10 103.8(6) . . ?
O13 W11 O7 100.5(5) . . ?
O10 W11 O7 87.2(5) . . ?
O13 W11 O11 100.7(4) . . ?
O10 W11 O11 88.7(5) . . ?
O7 W11 O11 158.8(4) . . ?
O13 W11 O12 98.8(5) . . ?
O10 W11 O12 157.4(4) . . ?
O7 W11 O12 88.0(5) . . ?
O11 W11 O12 87.8(5) . . ?
O13 W11 O4 170.1(5) . . ?
O10 W11 O4 84.3(4) . . ?
O7 W11 O4 85.4(4) . . ?
O11 W11 O4 73.5(4) . . ?
O12 W11 O4 73.3(4) . . ?
O31 W12 O30 99.7(5) . . ?
O31 W12 O26 102.2(5) . . ?
O30 W12 O26 158.0(5) . . ?
O31 W12 O22 102.0(5) . . ?
O30 W12 O22 89.3(5) . . ?
O26 W12 O22 85.4(5) . . ?
O31 W12 O29 100.2(6) . . ?
O30 W12 O29 88.4(4) . . ?
O26 W12 O29 88.5(4) . . ?
O22 W12 O29 157.7(5) . . ?
O31 W12 O2 171.0(5) . . ?
O30 W12 O2 73.4(4) . . ?
O26 W12 O2 84.8(4) . . ?
O22 W12 O2 83.9(4) . . ?
O29 W12 O2 74.2(5) . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         3.094
_refine_diff_density_min         -2.999
_refine_diff_density_rms         0.511
