# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1527507'
_audit_update_record             
;
2017-01-14 deposited with the CCDC.
2017-02-08 downloaded from the CCDC.
;
_audit_creation_date             2016-12-21
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.11.30 svn.r3356 for OlexSys, GUI svn.r5269)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C62 H44 Ag3 Gd3 N10 O31'
_chemical_formula_sum            'C62 H44 Ag3 Gd3 N10 O31'
_chemical_formula_weight         2220.43
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'

_cell_length_a                   12.694(3)
_cell_length_b                   12.948(3)
_cell_length_c                   23.498(6)
_cell_angle_alpha                103.967(4)
_cell_angle_beta                 101.905(5)
_cell_angle_gamma                91.809(3)
_cell_volume                     3653.7(14)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    6210
_cell_measurement_temperature    113
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_exptl_absorpt_coefficient_mu    3.565
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.508
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            'metallic light colourless'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.018
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    "'not measured'"
_exptl_crystal_description       needle
_exptl_crystal_F_000             2134
_exptl_crystal_preparation       Fiber
_exptl_crystal_recrystallization_method ?
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_special_details           
;
 ?
;
_diffrn_reflns_av_R_equivalents  0.0658
_diffrn_reflns_av_unetI/netI     0.0828
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            29820
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         3.02
_diffrn_ambient_temperature      113
_diffrn_detector                 PILT
_diffrn_detector_area_resol_mean 5.8140
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_details      
;
scan:
	Number of images: 360
	           Slice: -105.0000 - 75.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 0.0000
	             XTD: 44.9726
	          2theta: -15.0629
scan:
	Number of images: 300
	           Slice: -105.0000 - 45.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 90.0000
	             XTD: 44.9726
	          2theta: -15.0629
scan:
	Number of images: 200
	           Slice: -105.0000 - -5.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 180.0000
	             XTD: 44.9726
	          2theta: -15.0629
;
_diffrn_measurement_device       
;
AFC10: Fixed Chi 2 circle
;
_diffrn_measurement_device_type  'Rigaku Pilatus 200K'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_measurement_specimen_support Fiber
_diffrn_orient_matrix_type       d*Trek
_diffrn_orient_matrix_UB_11      0.066459
_diffrn_orient_matrix_UB_12      -0.008718
_diffrn_orient_matrix_UB_13      -0.045136
_diffrn_orient_matrix_UB_21      0.034070
_diffrn_orient_matrix_UB_22      0.067858
_diffrn_orient_matrix_UB_23      0.024806
_diffrn_orient_matrix_UB_31      0.030774
_diffrn_orient_matrix_UB_32      -0.013031
_diffrn_orient_matrix_UB_33      0.030077
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating Anode'
_diffrn_source_current           24.0
_diffrn_source_power             1.2
_diffrn_source_voltage           50.0
_diffrn_special_details          
;
 ?
;
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                9648
_reflns_number_total             12465
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_collection       
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_reduction        
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_refine_diff_density_max         2.863
_refine_diff_density_min         -1.845
_refine_diff_density_rms         0.215
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     987
_refine_ls_number_reflns         12465
_refine_ls_number_restraints     49
_refine_ls_R_factor_all          0.0638
_refine_ls_R_factor_gt           0.0471
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0576P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1114
_refine_ls_wR_factor_ref         0.1187
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Restrained distances
 O12_$1-O1
 3 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C7) \\sim Ueq, Uanis(C12) \\sim Ueq, Uanis(C59) \\sim Ueq, Uanis(O28)
\\sim Ueq, Uanis(O18) \\sim Ueq, Uanis(O3) \\sim Ueq, Uanis(O4) \\sim Ueq: with
sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C18) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
4.a Riding coordinates:
 O29(H29A,H29B), O28(H28A,H28B)
4.b Rotating group:
 O25(H25A,H25B), O31(H31A,H31B), O27(H27A,H27B), O26(H26A,H26B), O30(H30A,H30B)
4.c Aromatic/amide H refined with riding coordinates:
 C58(H58), C13(H13), C44(H44), C38(H38), C14(H14), C37(H37), C50(H50),
 C10(H10), C57(H57), C27(H27), C46(H46), C56(H56), C25(H25), C26(H26), C8(H8),
 C32(H32), C49(H49), C15(H15), C9(H9), C45(H45), C2(H2), C39(H39), C33(H33),
 C22(H22), C51(H51), C3(H3), C34(H34), C21(H21), C20(H20), C1(H1)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Gd1 Gd 1.16726(3) -0.10913(3) 1.088250(15) 0.01251(11) Uani 1 d . . . .
Gd3 Gd -0.04332(3) 0.25961(3) 0.484998(16) 0.01285(10) Uani 1 d . . . .
Gd2 Gd 0.79684(3) -0.38904(3) 0.891343(18) 0.01997(12) Uani 1 d . . . .
Ag2 Ag 0.33415(5) 0.32054(5) 0.68789(2) 0.01555(14) Uani 1 d . . . .
Ag3 Ag 0.42954(5) 0.06565(5) 0.73170(2) 0.01692(14) Uani 1 d . . . .
Ag1 Ag 0.32621(5) 0.73713(5) 0.72648(3) 0.02476(16) Uani 1 d . . . .
O12 O 0.6438(4) 0.1544(4) 0.9088(2) 0.0200(12) Uani 1 d . . D .
O7 O 0.1215(4) 0.3628(4) 0.5426(2) 0.0168(12) Uani 1 d . . . .
O1 O 0.1820(4) 0.7901(5) 0.9877(2) 0.0231(13) Uani 1 d . . D .
O25 O 0.0718(5) 0.1911(5) 0.4175(2) 0.0248(13) Uani 1 d . . . .
H25A H 0.0875 0.1274 0.4198 0.037 Uiso 1 d . . GR .
H25B H 0.1313 0.2321 0.4271 0.037 Uiso 1 d . . GR .
O31 O 1.0634(4) -0.1316(4) 1.1609(2) 0.0186(12) Uani 1 d . . . .
H31A H 1.0005 -0.1040 1.1545 0.028 Uiso 1 d . . GR .
H31B H 1.0985 -0.0996 1.1980 0.028 Uiso 1 d . . GR .
O9 O 0.7857(5) 0.4896(5) 0.7898(3) 0.0381(16) Uani 1 d . . . .
O11 O 0.7295(4) 0.2326(4) 0.8556(2) 0.0188(12) Uani 1 d . . . .
O29 O 1.2243(4) 0.0163(4) 1.0365(2) 0.0170(12) Uani 1 d . . . .
H29A H 1.2304 -0.0175 1.0014 0.025 Uiso 1 d . . R .
H29B H 1.2854 0.0490 1.0563 0.025 Uiso 1 d . . R .
O28 O 0.8217(6) -0.5654(5) 0.9040(4) 0.065(2) Uani 1 d . . . U
H28A H 0.8661 -0.5984 0.8820 0.098 Uiso 1 d . . R .
H28B H 0.7591 -0.6054 0.8925 0.098 Uiso 1 d . . R .
O27 O 0.7126(5) -0.4005(5) 0.9737(3) 0.0408(17) Uani 1 d . . . .
H27A H 0.7278 -0.4470 0.9975 0.061 Uiso 1 d . . GR .
H27B H 0.6603 -0.3589 0.9860 0.061 Uiso 1 d . . GR .
O17 O 0.8044(5) 0.0041(5) 0.7450(3) 0.0313(15) Uani 1 d . . . .
O6 O 0.0052(4) 0.6048(4) 0.5636(2) 0.0153(11) Uani 1 d . . . .
O21 O 0.8521(4) -0.2141(4) 0.9594(2) 0.0186(12) Uani 1 d . . . .
O8 O 0.2298(4) 0.3400(5) 0.4775(2) 0.0227(13) Uani 1 d . . . .
O26 O -0.1088(4) 0.4141(4) 0.5358(2) 0.0205(12) Uani 1 d . . . .
H26A H -0.1775 0.4046 0.5308 0.031 Uiso 1 d . . GR .
H26B H -0.0934 0.4667 0.5219 0.031 Uiso 1 d . . GR .
O23 O 1.0651(4) -0.2902(4) 1.0544(2) 0.0178(12) Uani 1 d . . . .
O14 O -0.0393(4) 0.2081(5) 0.5788(2) 0.0278(14) Uani 1 d . . . .
O18 O 0.7265(4) -0.0058(4) 0.8212(2) 0.0175(12) Uani 1 d . . . U
O2 O 0.1536(5) 0.8894(4) 0.9222(2) 0.0231(13) Uani 1 d . . . .
O5 O 0.1673(4) 0.6884(4) 0.6052(2) 0.0200(12) Uani 1 d . . . .
O20 O 0.6595(5) -0.2790(5) 0.8808(3) 0.0368(16) Uani 1 d . . . .
O22 O 0.9486(4) -0.3900(4) 0.9739(2) 0.0179(12) Uani 1 d . . . .
O10 O 0.6433(4) 0.4804(4) 0.8284(2) 0.0174(12) Uani 1 d . . . .
O15 O 0.2312(4) -0.1831(4) 0.5186(2) 0.0196(12) Uani 1 d . . . .
O16 O 0.1288(4) -0.0878(4) 0.5741(2) 0.0171(12) Uani 1 d . . . .
O30 O 1.0737(4) 0.0558(4) 1.1119(2) 0.0186(12) Uani 1 d . . . .
H30A H 1.1195 0.1101 1.1210 0.028 Uiso 1 d . . GR .
H30B H 1.0446 0.0560 1.1415 0.028 Uiso 1 d . . GR .
O13 O 0.0876(4) 0.1421(4) 0.5343(2) 0.0182(12) Uani 1 d . . . .
N2 N 0.1753(5) 0.7983(5) 0.7575(3) 0.0184(15) Uani 1 d . . . .
N10 N 0.4591(5) -0.1914(6) 0.6954(3) 0.0199(15) Uani 1 d . . . .
O24 O 0.9894(4) -0.1133(4) 1.0263(2) 0.0181(12) Uani 1 d . . . .
O19 O 0.6412(5) -0.2847(5) 0.7829(3) 0.0422(17) Uani 1 d . . . .
N8 N 0.2540(5) 0.0822(5) 0.6986(3) 0.0148(14) Uani 1 d . . . .
N7 N 0.3392(5) 0.1879(5) 0.6090(3) 0.0141(14) Uani 1 d . . . .
O3 O 0.0368(7) 0.6112(6) 0.8542(3) 0.056(2) Uani 1 d . . . U
N9 N 0.4586(5) -0.0202(5) 0.8057(3) 0.0144(14) Uani 1 d . . . .
C58 C 0.4683(7) -0.2200(7) 0.6377(3) 0.0205(18) Uani 1 d . . . .
H58 H 0.4096 -0.2586 0.6091 0.025 Uiso 1 calc . . R .
C13 C 0.1101(7) 0.4170(7) 0.7198(3) 0.0207(18) Uani 1 d . . . .
H13 H 0.1122 0.3706 0.7446 0.025 Uiso 1 calc . . R .
N3 N 0.1918(5) 0.4233(5) 0.6930(3) 0.0176(14) Uani 1 d . . . .
C42 C 0.5839(6) 0.2673(6) 0.7524(3) 0.0132(16) Uani 1 d . . . .
N5 N 0.4243(5) 0.3346(5) 0.7827(3) 0.0148(14) Uani 1 d . . . .
C12 C -0.0124(9) 0.6839(9) 0.8380(4) 0.040(2) Uani 1 d . . . U
C30 C 0.2056(6) 0.1054(6) 0.6470(3) 0.0139(16) Uani 1 d . . . .
N6 N 0.5598(5) 0.1687(5) 0.7156(3) 0.0162(14) Uani 1 d . . . .
C11 C 0.1897(7) 0.8104(6) 0.9394(3) 0.0190(18) Uani 1 d . . . .
N1 N 0.3009(6) 0.6600(6) 0.8072(3) 0.0261(17) Uani 1 d . . . .
C44 C 0.7115(7) 0.3065(7) 0.6970(4) 0.0248(19) Uani 1 d . . . .
H44 H 0.7629 0.3530 0.6909 0.030 Uiso 1 calc . . R .
C38 C 0.3817(7) 0.3346(7) 0.8768(3) 0.0207(18) Uani 1 d . . . .
H38 H 0.3347 0.3515 0.9026 0.025 Uiso 1 calc . . R .
C14 C 0.0217(6) 0.4770(6) 0.7123(3) 0.0169(17) Uani 1 d . . . .
H14 H -0.0333 0.4720 0.7324 0.020 Uiso 1 calc . . R .
C47 C 0.6447(6) 0.2129(6) 0.8739(3) 0.0148(17) Uani 1 d . . . .
C16 C 0.1023(6) 0.5521(6) 0.6471(3) 0.0144(16) Uani 1 d . . . .
N4 N 0.3740(5) 0.5517(5) 0.6769(3) 0.0208(15) Uani 1 d . . . .
C60 C 0.7330(7) -0.0274(6) 0.7666(4) 0.0192(18) Uani 1 d . . . .
C37 C 0.3615(6) 0.3583(7) 0.8226(3) 0.0191(18) Uani 1 d . . . .
H37 H 0.3001 0.3932 0.8124 0.023 Uiso 1 calc . . R .
C50 C 0.4487(6) -0.0429(6) 0.9026(3) 0.0174(17) Uani 1 d . . . .
H50 H 0.4224 -0.0222 0.9374 0.021 Uiso 1 calc . . R .
C10 C 0.1052(7) 0.8401(7) 0.7224(3) 0.0230(19) Uani 1 d . . . .
H10 H 0.1287 0.8679 0.6937 0.028 Uiso 1 calc . . R .
C5 C 0.2334(7) 0.7159(6) 0.8381(3) 0.0197(18) Uani 1 d . . . .
C57 C 0.5589(7) -0.1956(7) 0.6186(4) 0.0234(19) Uani 1 d . . . .
H57 H 0.5626 -0.2181 0.5784 0.028 Uiso 1 calc . . R .
C53 C 0.5220(6) -0.1020(6) 0.7980(3) 0.0150(16) Uani 1 d . . . .
C27 C 0.3525(6) 0.0049(6) 0.5215(4) 0.0211(18) Uani 1 d . . . .
H27 H 0.3582 -0.0566 0.4926 0.025 Uiso 1 calc . . R .
C7 C 0.0336(6) 0.7479(6) 0.8015(3) 0.0178(17) Uani 1 d . . . U
C43 C 0.6616(6) 0.3383(6) 0.7449(3) 0.0177(17) Uani 1 d . . . .
C4 C 0.2504(7) 0.7349(6) 0.9006(3) 0.0206(18) Uani 1 d . . . .
C40 C 0.5451(6) 0.2651(6) 0.8550(3) 0.0139(16) Uani 1 d . . . .
C46 C 0.6104(6) 0.1404(7) 0.6701(3) 0.0189(18) Uani 1 d . . . .
H46 H 0.5937 0.0720 0.6449 0.023 Uiso 1 calc . . R .
C56 C 0.6453(7) -0.1357(7) 0.6619(3) 0.0223(19) Uani 1 d . . . .
H56 H 0.7084 -0.1188 0.6505 0.027 Uiso 1 calc . . R .
C31 C 0.1026(6) 0.1401(6) 0.6372(3) 0.0147(16) Uani 1 d . . . .
C41 C 0.5181(6) 0.2932(6) 0.8001(3) 0.0133(16) Uani 1 d . . . .
C25 C 0.4042(6) 0.1872(6) 0.5708(3) 0.0171(17) Uani 1 d . . . .
H25 H 0.4460 0.2498 0.5745 0.021 Uiso 1 calc . . R .
C62 C 0.9891(6) -0.3019(6) 1.0103(3) 0.0151(17) Uani 1 d . . . .
C61 C 0.9394(6) -0.2016(6) 0.9974(3) 0.0167(17) Uani 1 d . . . .
C26 C 0.4124(7) 0.0986(6) 0.5261(4) 0.0218(18) Uani 1 d . . . .
H26 H 0.4571 0.1019 0.4997 0.026 Uiso 1 calc . . R .
C36 C 0.0470(6) 0.1646(6) 0.5793(3) 0.0167(17) Uani 1 d . . . .
C29 C 0.2768(6) 0.0977(6) 0.6020(3) 0.0120(16) Uani 1 d . . . .
C18 C 0.2890(6) 0.4976(6) 0.6336(3) 0.0133(16) Uani 1 d . . . U
C23 C 0.0936(6) 0.6192(6) 0.6029(3) 0.0160(17) Uani 1 d . . . .
C48 C 0.6979(7) 0.4444(6) 0.7905(3) 0.0188(18) Uani 1 d . . . .
C8 C -0.0361(7) 0.7966(7) 0.7653(4) 0.029(2) Uani 1 d . . . .
H8 H -0.1083 0.7968 0.7678 0.034 Uiso 1 calc . . R .
C32 C 0.0473(7) 0.1501(7) 0.6832(4) 0.0242(19) Uani 1 d . . . .
H32 H -0.0211 0.1749 0.6786 0.029 Uiso 1 calc . . R .
C49 C 0.4237(6) 0.0083(6) 0.8572(3) 0.0161(17) Uani 1 d . . . .
H49 H 0.3807 0.0652 0.8623 0.019 Uiso 1 calc . . R .
C15 C 0.0169(6) 0.5441(6) 0.6745(3) 0.0146(17) Uani 1 d . . . .
H15 H -0.0425 0.5832 0.6676 0.017 Uiso 1 calc . . R .
C17 C 0.1894(6) 0.4926(6) 0.6570(3) 0.0142(16) Uani 1 d . . . .
C6 C 0.1440(7) 0.7554(6) 0.7992(3) 0.0190(18) Uani 1 d . . . .
C54 C 0.5434(7) -0.1328(6) 0.7364(3) 0.0179(18) Uani 1 d . . . .
C9 C -0.0020(7) 0.8450(7) 0.7256(4) 0.030(2) Uani 1 d . . . .
H9 H -0.0490 0.8796 0.7020 0.035 Uiso 1 calc . . R .
C45 C 0.6851(7) 0.2064(7) 0.6587(3) 0.026(2) Uani 1 d . . . .
H45 H 0.7171 0.1843 0.6260 0.031 Uiso 1 calc . . R .
C59 C 0.6240(7) -0.2471(7) 0.8338(4) 0.027(2) Uani 1 d . . . U
C2 C 0.4029(7) 0.6303(7) 0.8982(4) 0.028(2) Uani 1 d . . . .
H2 H 0.4599 0.5988 0.9174 0.034 Uiso 1 calc . . R .
C39 C 0.4734(7) 0.2850(7) 0.8925(3) 0.0216(19) Uani 1 d . . . .
H39 H 0.4872 0.2648 0.9286 0.026 Uiso 1 calc . . R .
C33 C 0.0935(7) 0.1237(7) 0.7353(4) 0.027(2) Uani 1 d . . . .
H33 H 0.0562 0.1285 0.7659 0.032 Uiso 1 calc . . R .
C24 C 0.2089(6) 0.3774(6) 0.5282(3) 0.0148(17) Uani 1 d . . . .
C22 C 0.4707(7) 0.5544(7) 0.6632(4) 0.0241(19) Uani 1 d . . . .
H22 H 0.5295 0.5888 0.6933 0.029 Uiso 1 calc . . R .
C51 C 0.5135(6) -0.1251(7) 0.8949(3) 0.0222(19) Uani 1 d . . . .
H51 H 0.5324 -0.1604 0.9251 0.027 Uiso 1 calc . . R .
C55 C 0.6389(6) -0.1008(6) 0.7214(3) 0.0171(17) Uani 1 d . . . .
C3 C 0.3360(7) 0.6896(7) 0.9309(4) 0.0243(19) Uani 1 d . . . .
H3 H 0.3479 0.6992 0.9723 0.029 Uiso 1 calc . . R .
C34 C 0.1950(7) 0.0901(7) 0.7416(4) 0.0226(19) Uani 1 d . . . .
H34 H 0.2255 0.0718 0.7769 0.027 Uiso 1 calc . . R .
C28 C 0.2839(6) 0.0025(6) 0.5600(3) 0.0163(17) Uani 1 d . . . .
C21 C 0.4885(6) 0.5086(7) 0.6061(4) 0.0245(19) Uani 1 d . . . .
H21 H 0.5566 0.5143 0.5977 0.029 Uiso 1 calc . . R .
C35 C 0.2108(6) -0.0957(6) 0.5515(3) 0.0162(17) Uani 1 d . . . .
C52 C 0.5513(6) -0.1567(7) 0.8431(3) 0.0184(18) Uani 1 d . . . .
C20 C 0.4007(7) 0.4545(6) 0.5627(3) 0.0210(18) Uani 1 d . . . .
H20 H 0.4096 0.4233 0.5241 0.025 Uiso 1 calc . . R .
C1 C 0.3836(8) 0.6187(7) 0.8369(4) 0.030(2) Uani 1 d . . . .
H1 H 0.4299 0.5807 0.8154 0.036 Uiso 1 calc . . R .
C19 C 0.3009(6) 0.4463(6) 0.5757(3) 0.0166(17) Uani 1 d . . . .
O4 O -0.1024(6) 0.7120(6) 0.8495(3) 0.056(2) Uani 1 d . . . U


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Gd1 O12 2.478(5) 2_757 ?
Gd1 O1 2.455(5) 1_645 ?
Gd1 O31 2.426(5) . ?
Gd1 O11 2.540(5) 2_757 ?
Gd1 O29 2.425(5) . ?
Gd1 O23 2.508(5) . ?
Gd1 O18 2.392(5) 2_757 ?
Gd1 O30 2.478(5) . ?
Gd1 O24 2.412(5) . ?
Gd1 C47 2.863(7) 2_757 ?
Gd3 O7 2.404(5) . ?
Gd3 O25 2.407(5) . ?
Gd3 O6 2.401(5) 2_566 ?
Gd3 O26 2.341(5) . ?
Gd3 O14 2.442(5) . ?
Gd3 O5 2.607(5) 2_566 ?
Gd3 O15 2.531(5) 2_556 ?
Gd3 O16 2.406(5) 2_556 ?
Gd3 O13 2.576(5) . ?
Gd3 C36 2.846(7) . ?
Gd3 C23 2.866(8) 2_566 ?
Gd3 C35 2.800(8) 2_556 ?
Gd2 O9 2.493(6) 1_545 ?
Gd2 O28 2.394(7) . ?
Gd2 O27 2.428(6) . ?
Gd2 O21 2.423(5) . ?
Gd2 O20 2.297(6) . ?
Gd2 O22 2.438(5) . ?
Gd2 O10 2.498(5) 1_545 ?
Gd2 C48 2.825(8) 1_545 ?
Gd2 O4 2.312(7) 1_645 ?
Ag2 N7 2.215(6) . ?
Ag2 N3 2.283(6) . ?
Ag2 N5 2.246(6) . ?
Ag3 N8 2.238(6) . ?
Ag3 N9 2.256(6) . ?
Ag3 N6 2.240(7) . ?
Ag1 N2 2.285(7) . ?
Ag1 N10 2.230(7) 1_565 ?
Ag1 N1 2.418(7) . ?
Ag1 N4 2.555(6) . ?
O12 Gd1 2.478(5) 2_757 ?
O12 C47 1.246(9) . ?
O7 C24 1.246(9) . ?
O1 Gd1 2.455(5) 1_465 ?
O1 C11 1.247(9) . ?
O25 H25A 0.8662 . ?
O25 H25B 0.8654 . ?
O31 H31A 0.8844 . ?
O31 H31B 0.8842 . ?
O9 Gd2 2.493(6) 1_565 ?
O9 C48 1.247(10) . ?
O11 Gd1 2.540(5) 2_757 ?
O11 C47 1.278(9) . ?
O29 H29A 0.8551 . ?
O29 H29B 0.8554 . ?
O28 H28A 0.8918 . ?
O28 H28B 0.8892 . ?
O27 H27A 0.9161 . ?
O27 H27B 0.9159 . ?
O17 C60 1.228(9) . ?
O6 Gd3 2.401(5) 2_566 ?
O6 C23 1.274(9) . ?
O21 C61 1.250(9) . ?
O8 C24 1.258(9) . ?
O26 H26A 0.8568 . ?
O26 H26B 0.8568 . ?
O23 C62 1.236(9) . ?
O14 C36 1.247(9) . ?
O18 Gd1 2.392(5) 2_757 ?
O18 C60 1.267(9) . ?
O2 C11 1.255(9) . ?
O5 Gd3 2.607(5) 2_566 ?
O5 C23 1.259(9) . ?
O20 C59 1.274(10) . ?
O22 C62 1.269(9) . ?
O10 Gd2 2.498(5) 1_565 ?
O10 C48 1.251(9) . ?
O15 Gd3 2.531(5) 2_556 ?
O15 C35 1.274(9) . ?
O16 Gd3 2.406(5) 2_556 ?
O16 C35 1.258(9) . ?
O30 H30A 0.8526 . ?
O30 H30B 0.8529 . ?
O13 C36 1.247(9) . ?
N2 C10 1.307(10) . ?
N2 C6 1.357(10) . ?
N10 Ag1 2.230(7) 1_545 ?
N10 C58 1.347(9) . ?
N10 C54 1.348(10) . ?
O24 C61 1.254(9) . ?
O19 C59 1.244(10) . ?
N8 C30 1.347(9) . ?
N8 C34 1.364(10) . ?
N7 C25 1.338(9) . ?
N7 C29 1.346(10) . ?
O3 C12 1.238(13) . ?
N9 C53 1.351(9) . ?
N9 C49 1.345(9) . ?
C58 H58 0.9300 . ?
C58 C57 1.373(11) . ?
C13 H13 0.9300 . ?
C13 N3 1.330(10) . ?
C13 C14 1.390(11) . ?
N3 C17 1.372(10) . ?
C42 N6 1.343(10) . ?
C42 C43 1.393(11) . ?
C42 C41 1.514(10) . ?
N5 C37 1.339(9) . ?
N5 C41 1.348(9) . ?
C12 C7 1.512(13) . ?
C12 O4 1.271(12) . ?
C30 C31 1.389(10) . ?
C30 C29 1.514(10) . ?
N6 C46 1.341(9) . ?
C11 C4 1.512(11) . ?
N1 C5 1.351(10) . ?
N1 C1 1.337(11) . ?
C44 H44 0.9300 . ?
C44 C43 1.388(11) . ?
C44 C45 1.375(12) . ?
C38 H38 0.9300 . ?
C38 C37 1.358(11) . ?
C38 C39 1.374(11) . ?
C14 H14 0.9300 . ?
C14 C15 1.378(11) . ?
C47 Gd1 2.863(7) 2_757 ?
C47 C40 1.490(10) . ?
C16 C23 1.498(11) . ?
C16 C15 1.383(10) . ?
C16 C17 1.379(10) . ?
N4 C18 1.358(10) . ?
N4 C22 1.333(10) . ?
C60 C55 1.541(11) . ?
C37 H37 0.9300 . ?
C50 H50 0.9300 . ?
C50 C49 1.377(11) . ?
C50 C51 1.367(11) . ?
C10 H10 0.9300 . ?
C10 C9 1.382(12) . ?
C5 C4 1.398(11) . ?
C5 C6 1.489(11) . ?
C57 H57 0.9300 . ?
C57 C56 1.394(12) . ?
C53 C54 1.490(10) . ?
C53 C52 1.406(11) . ?
C27 H27 0.9300 . ?
C27 C26 1.381(11) . ?
C27 C28 1.383(11) . ?
C7 C8 1.373(12) . ?
C7 C6 1.413(11) . ?
C43 C48 1.514(11) . ?
C4 C3 1.397(11) . ?
C40 C41 1.401(10) . ?
C40 C39 1.383(11) . ?
C46 H46 0.9300 . ?
C46 C45 1.366(12) . ?
C56 H56 0.9300 . ?
C56 C55 1.382(10) . ?
C31 C36 1.508(11) . ?
C31 C32 1.387(11) . ?
C25 H25 0.9300 . ?
C25 C26 1.378(11) . ?
C62 C61 1.530(10) . ?
C26 H26 0.9300 . ?
C29 C28 1.399(10) . ?
C18 C17 1.485(10) . ?
C18 C19 1.402(10) . ?
C23 Gd3 2.866(7) 2_566 ?
C48 Gd2 2.825(8) 1_565 ?
C8 H8 0.9300 . ?
C8 C9 1.372(13) . ?
C32 H32 0.9300 . ?
C32 C33 1.372(12) . ?
C49 H49 0.9300 . ?
C15 H15 0.9300 . ?
C54 C55 1.407(11) . ?
C9 H9 0.9300 . ?
C45 H45 0.9300 . ?
C59 C52 1.516(11) . ?
C2 H2 0.9300 . ?
C2 C3 1.388(11) . ?
C2 C1 1.380(12) . ?
C39 H39 0.9300 . ?
C33 H33 0.9300 . ?
C33 C34 1.363(12) . ?
C24 C19 1.524(11) . ?
C22 H22 0.9300 . ?
C22 C21 1.397(11) . ?
C51 H51 0.9300 . ?
C51 C52 1.374(11) . ?
C3 H3 0.9300 . ?
C34 H34 0.9300 . ?
C28 C35 1.499(11) . ?
C21 H21 0.9300 . ?
C21 C20 1.383(12) . ?
C35 Gd3 2.800(8) 2_556 ?
C20 H20 0.9300 . ?
C20 C19 1.371(11) . ?
C1 H1 0.9300 . ?
O4 Gd2 2.312(7) 1_465 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O12 Gd1 O11 52.20(17) 2_757 2_757 ?
O12 Gd1 O23 102.07(18) 2_757 . ?
O12 Gd1 O30 136.56(18) 2_757 . ?
O12 Gd1 C47 25.7(2) 2_757 2_757 ?
O1 Gd1 O12 70.74(17) 1_645 2_757 ?
O1 Gd1 O11 95.80(17) 1_645 2_757 ?
O1 Gd1 O23 66.38(18) 1_645 . ?
O1 Gd1 O30 126.15(17) 1_645 . ?
O1 Gd1 C47 83.07(19) 1_645 2_757 ?
O31 Gd1 O12 125.12(17) . 2_757 ?
O31 Gd1 O1 136.09(19) . 1_645 ?
O31 Gd1 O11 75.11(17) . 2_757 ?
O31 Gd1 O23 70.08(17) . . ?
O31 Gd1 O30 73.59(18) . . ?
O31 Gd1 C47 100.4(2) . 2_757 ?
O11 Gd1 C47 26.51(19) 2_757 2_757 ?
O29 Gd1 O12 80.56(17) . 2_757 ?
O29 Gd1 O1 71.88(18) . 1_645 ?
O29 Gd1 O31 144.16(17) . . ?
O29 Gd1 O11 132.17(17) . 2_757 ?
O29 Gd1 O23 134.20(17) . . ?
O29 Gd1 O30 70.81(17) . . ?
O29 Gd1 C47 105.9(2) . 2_757 ?
O23 Gd1 O11 71.36(17) . 2_757 ?
O23 Gd1 C47 87.3(2) . 2_757 ?
O18 Gd1 O12 74.10(17) 2_757 2_757 ?
O18 Gd1 O1 141.20(18) 2_757 1_645 ?
O18 Gd1 O31 78.69(18) 2_757 . ?
O18 Gd1 O11 74.67(17) 2_757 2_757 ?
O18 Gd1 O29 86.77(18) 2_757 . ?
O18 Gd1 O23 138.44(17) 2_757 . ?
O18 Gd1 O30 72.37(17) 2_757 . ?
O18 Gd1 O24 136.24(17) 2_757 . ?
O18 Gd1 C47 71.88(19) 2_757 2_757 ?
O30 Gd1 O11 138.04(17) . 2_757 ?
O30 Gd1 O23 121.33(18) . . ?
O30 Gd1 C47 144.23(19) . 2_757 ?
O24 Gd1 O12 146.31(17) . 2_757 ?
O24 Gd1 O1 75.70(17) . 1_645 ?
O24 Gd1 O31 82.12(18) . . ?
O24 Gd1 O11 136.48(18) . 2_757 ?
O24 Gd1 O29 86.37(17) . . ?
O24 Gd1 O23 66.13(17) . . ?
O24 Gd1 O30 64.56(17) . . ?
O24 Gd1 C47 150.9(2) . 2_757 ?
O7 Gd3 O25 82.02(18) . . ?
O7 Gd3 O14 82.36(19) . . ?
O7 Gd3 O5 123.10(17) . 2_566 ?
O7 Gd3 O15 148.95(17) . 2_556 ?
O7 Gd3 O16 147.05(17) . 2_556 ?
O7 Gd3 O13 69.17(17) . . ?
O7 Gd3 C36 71.3(2) . . ?
O7 Gd3 C23 97.4(2) . 2_566 ?
O7 Gd3 C35 159.0(2) . 2_556 ?
O25 Gd3 O14 123.26(18) . . ?
O25 Gd3 O5 87.13(18) . 2_566 ?
O25 Gd3 O15 126.75(18) . 2_556 ?
O25 Gd3 O13 71.98(18) . . ?
O25 Gd3 C36 98.0(2) . . ?
O25 Gd3 C23 78.0(2) . 2_566 ?
O25 Gd3 C35 100.8(2) . 2_556 ?
O6 Gd3 O7 71.50(17) 2_566 . ?
O6 Gd3 O25 71.61(19) 2_566 . ?
O6 Gd3 O14 148.1(2) 2_566 . ?
O6 Gd3 O5 52.17(17) 2_566 2_566 ?
O6 Gd3 O15 124.49(17) 2_566 2_556 ?
O6 Gd3 O16 120.03(17) 2_566 2_556 ?
O6 Gd3 O13 129.01(17) 2_566 . ?
O6 Gd3 C36 142.4(2) 2_566 . ?
O6 Gd3 C23 26.1(2) 2_566 2_566 ?
O6 Gd3 C35 129.33(19) 2_566 2_556 ?
O26 Gd3 O7 78.41(18) . . ?
O26 Gd3 O25 144.9(2) . . ?
O26 Gd3 O6 74.62(18) . 2_566 ?
O26 Gd3 O14 82.68(19) . . ?
O26 Gd3 O5 79.68(17) . 2_566 ?
O26 Gd3 O15 81.03(18) . 2_556 ?
O26 Gd3 O16 133.20(18) . 2_556 ?
O26 Gd3 O13 125.67(17) . . ?
O26 Gd3 C36 102.9(2) . . ?
O26 Gd3 C23 75.94(19) . 2_566 ?
O26 Gd3 C35 108.0(2) . 2_556 ?
O14 Gd3 O5 144.62(17) . 2_566 ?
O14 Gd3 O15 72.10(18) . 2_556 ?
O14 Gd3 O13 51.48(17) . . ?
O14 Gd3 C36 25.9(2) . . ?
O14 Gd3 C23 158.18(19) . 2_566 ?
O14 Gd3 C35 78.7(2) . 2_556 ?
O5 Gd3 C36 165.5(2) 2_566 . ?
O5 Gd3 C23 26.06(19) 2_566 2_566 ?
O5 Gd3 C35 77.95(19) 2_566 2_556 ?
O15 Gd3 O5 75.00(17) 2_556 2_566 ?
O15 Gd3 O13 105.79(17) 2_556 . ?
O15 Gd3 C36 91.2(2) 2_556 . ?
O15 Gd3 C23 99.9(2) 2_556 2_566 ?
O15 Gd3 C35 27.06(19) 2_556 2_556 ?
O16 Gd3 O25 74.20(19) 2_556 . ?
O16 Gd3 O14 91.8(2) 2_556 . ?
O16 Gd3 O5 78.68(17) 2_556 2_566 ?
O16 Gd3 O15 53.42(17) 2_556 2_556 ?
O16 Gd3 O13 81.82(17) 2_556 . ?
O16 Gd3 C36 89.6(2) 2_556 . ?
O16 Gd3 C23 99.6(2) 2_556 2_566 ?
O16 Gd3 C35 26.62(19) 2_556 2_556 ?
O13 Gd3 O5 154.64(16) . 2_566 ?
O13 Gd3 C36 25.99(19) . . ?
O13 Gd3 C23 148.40(19) . 2_566 ?
O13 Gd3 C35 91.7(2) . 2_556 ?
C36 Gd3 C23 168.5(2) . 2_566 ?
C35 Gd3 C36 87.7(2) 2_556 . ?
C35 Gd3 C23 103.6(2) 2_556 2_566 ?
O9 Gd2 O10 52.15(19) 1_545 1_545 ?
O9 Gd2 C48 26.2(2) 1_545 1_545 ?
O28 Gd2 O9 72.4(3) . 1_545 ?
O28 Gd2 O27 74.9(3) . . ?
O28 Gd2 O21 131.9(2) . . ?
O28 Gd2 O22 68.1(2) . . ?
O28 Gd2 O10 68.4(2) . 1_545 ?
O28 Gd2 C48 65.2(2) . 1_545 ?
O27 Gd2 O9 132.7(2) . 1_545 ?
O27 Gd2 O22 75.94(19) . . ?
O27 Gd2 O10 84.4(2) . 1_545 ?
O27 Gd2 C48 107.8(2) . 1_545 ?
O21 Gd2 O9 148.1(2) . 1_545 ?
O21 Gd2 O27 78.6(2) . . ?
O21 Gd2 O22 66.91(17) . . ?
O21 Gd2 O10 146.87(17) . 1_545 ?
O21 Gd2 C48 162.72(19) . 1_545 ?
O20 Gd2 O9 106.4(2) . 1_545 ?
O20 Gd2 O28 138.7(3) . . ?
O20 Gd2 O27 77.8(2) . . ?
O20 Gd2 O21 70.06(19) . . ?
O20 Gd2 O22 132.9(2) . . ?
O20 Gd2 O10 78.69(19) . 1_545 ?
O20 Gd2 C48 95.2(2) . 1_545 ?
O20 Gd2 O4 89.8(3) . 1_645 ?
O22 Gd2 O9 120.1(2) . 1_545 ?
O22 Gd2 O10 135.52(17) . 1_545 ?
O22 Gd2 C48 129.8(2) . 1_545 ?
O10 Gd2 C48 26.27(19) 1_545 1_545 ?
O4 Gd2 O9 78.4(2) 1_645 1_545 ?
O4 Gd2 O28 128.5(3) 1_645 . ?
O4 Gd2 O27 148.5(2) 1_645 . ?
O4 Gd2 O21 70.0(2) 1_645 . ?
O4 Gd2 O22 92.8(2) 1_645 . ?
O4 Gd2 O10 121.8(2) 1_645 1_545 ?
O4 Gd2 C48 102.0(2) 1_645 1_545 ?
N7 Ag2 N3 123.2(2) . . ?
N7 Ag2 N5 125.5(2) . . ?
N5 Ag2 N3 107.2(2) . . ?
N8 Ag3 N9 112.5(2) . . ?
N8 Ag3 N6 122.0(2) . . ?
N6 Ag3 N9 122.5(2) . . ?
N2 Ag1 N1 71.4(2) . . ?
N2 Ag1 N4 133.0(2) . . ?
N10 Ag1 N2 134.7(2) 1_565 . ?
N10 Ag1 N1 139.4(2) 1_565 . ?
N10 Ag1 N4 89.0(2) 1_565 . ?
N1 Ag1 N4 85.4(2) . . ?
C47 O12 Gd1 94.7(5) . 2_757 ?
C24 O7 Gd3 130.4(5) . . ?
C11 O1 Gd1 137.1(5) . 1_465 ?
Gd3 O25 H25A 110.4 . . ?
Gd3 O25 H25B 109.7 . . ?
H25A O25 H25B 108.6 . . ?
Gd1 O31 H31A 111.3 . . ?
Gd1 O31 H31B 111.0 . . ?
H31A O31 H31B 107.7 . . ?
C48 O9 Gd2 91.9(5) . 1_565 ?
C47 O11 Gd1 91.0(4) . 2_757 ?
Gd1 O29 H29A 109.4 . . ?
Gd1 O29 H29B 109.8 . . ?
H29A O29 H29B 109.2 . . ?
Gd2 O28 H28A 111.8 . . ?
Gd2 O28 H28B 110.8 . . ?
H28A O28 H28B 107.2 . . ?
Gd2 O27 H27A 125.6 . . ?
Gd2 O27 H27B 125.4 . . ?
H27A O27 H27B 109.0 . . ?
C23 O6 Gd3 97.8(5) . 2_566 ?
C61 O21 Gd2 118.5(5) . . ?
Gd3 O26 H26A 109.8 . . ?
Gd3 O26 H26B 109.6 . . ?
H26A O26 H26B 109.1 . . ?
C62 O23 Gd1 114.8(5) . . ?
C36 O14 Gd3 95.5(4) . . ?
C60 O18 Gd1 133.9(5) . 2_757 ?
C23 O5 Gd3 88.5(4) . 2_566 ?
C59 O20 Gd2 124.9(6) . . ?
C62 O22 Gd2 118.8(5) . . ?
C48 O10 Gd2 91.6(5) . 1_565 ?
C35 O15 Gd3 88.3(4) . 2_556 ?
C35 O16 Gd3 94.4(4) . 2_556 ?
Gd1 O30 H30A 109.3 . . ?
Gd1 O30 H30B 109.6 . . ?
H30A O30 H30B 109.3 . . ?
C36 O13 Gd3 89.2(4) . . ?
C10 N2 Ag1 119.2(5) . . ?
C10 N2 C6 120.2(7) . . ?
C6 N2 Ag1 116.3(5) . . ?
C58 N10 Ag1 121.9(6) . 1_545 ?
C58 N10 C54 117.6(7) . . ?
C54 N10 Ag1 119.4(5) . 1_545 ?
C61 O24 Gd1 119.4(5) . . ?
C30 N8 Ag3 128.2(5) . . ?
C30 N8 C34 116.7(6) . . ?
C34 N8 Ag3 113.7(5) . . ?
C25 N7 Ag2 125.7(5) . . ?
C25 N7 C29 117.7(6) . . ?
C29 N7 Ag2 116.4(5) . . ?
C53 N9 Ag3 115.7(5) . . ?
C49 N9 Ag3 125.1(5) . . ?
C49 N9 C53 119.0(6) . . ?
N10 C58 H58 118.0 . . ?
N10 C58 C57 124.0(8) . . ?
C57 C58 H58 118.0 . . ?
N3 C13 H13 118.7 . . ?
N3 C13 C14 122.7(7) . . ?
C14 C13 H13 118.7 . . ?
C13 N3 Ag2 129.7(5) . . ?
C13 N3 C17 118.7(6) . . ?
C17 N3 Ag2 111.2(5) . . ?
N6 C42 C43 121.3(7) . . ?
N6 C42 C41 114.2(7) . . ?
C43 C42 C41 124.4(7) . . ?
C37 N5 Ag2 112.7(5) . . ?
C37 N5 C41 117.3(6) . . ?
C41 N5 Ag2 126.8(5) . . ?
O3 C12 C7 120.5(9) . . ?
O3 C12 O4 125.3(10) . . ?
O4 C12 C7 114.3(10) . . ?
N8 C30 C31 123.4(6) . . ?
N8 C30 C29 113.8(6) . . ?
C31 C30 C29 122.6(6) . . ?
C42 N6 Ag3 117.1(5) . . ?
C46 N6 Ag3 124.4(5) . . ?
C46 N6 C42 118.4(7) . . ?
O1 C11 O2 124.7(7) . . ?
O1 C11 C4 116.5(7) . . ?
O2 C11 C4 118.8(7) . . ?
C5 N1 Ag1 110.3(5) . . ?
C1 N1 Ag1 119.6(6) . . ?
C1 N1 C5 119.2(7) . . ?
C43 C44 H44 120.0 . . ?
C45 C44 H44 120.0 . . ?
C45 C44 C43 120.1(8) . . ?
C37 C38 H38 120.9 . . ?
C37 C38 C39 118.2(7) . . ?
C39 C38 H38 120.9 . . ?
C13 C14 H14 120.5 . . ?
C15 C14 C13 119.0(7) . . ?
C15 C14 H14 120.5 . . ?
O12 C47 Gd1 59.6(4) . 2_757 ?
O12 C47 O11 122.0(7) . . ?
O12 C47 C40 118.9(7) . . ?
O11 C47 Gd1 62.5(4) . 2_757 ?
O11 C47 C40 119.1(6) . . ?
C40 C47 Gd1 178.4(6) . 2_757 ?
C15 C16 C23 118.5(6) . . ?
C17 C16 C23 121.0(7) . . ?
C17 C16 C15 120.3(7) . . ?
C18 N4 Ag1 110.7(4) . . ?
C22 N4 Ag1 112.1(5) . . ?
C22 N4 C18 118.1(7) . . ?
O17 C60 O18 128.0(8) . . ?
O17 C60 C55 116.0(7) . . ?
O18 C60 C55 116.0(7) . . ?
N5 C37 C38 124.1(7) . . ?
N5 C37 H37 117.9 . . ?
C38 C37 H37 117.9 . . ?
C49 C50 H50 121.1 . . ?
C51 C50 H50 121.1 . . ?
C51 C50 C49 117.7(7) . . ?
N2 C10 H10 118.3 . . ?
N2 C10 C9 123.4(8) . . ?
C9 C10 H10 118.3 . . ?
N1 C5 C4 121.5(7) . . ?
N1 C5 C6 113.4(7) . . ?
C4 C5 C6 125.1(7) . . ?
C58 C57 H57 121.4 . . ?
C58 C57 C56 117.3(7) . . ?
C56 C57 H57 121.4 . . ?
N9 C53 C54 112.9(6) . . ?
N9 C53 C52 120.5(7) . . ?
C52 C53 C54 126.1(7) . . ?
C26 C27 H27 120.0 . . ?
C26 C27 C28 120.0(7) . . ?
C28 C27 H27 120.0 . . ?
C8 C7 C12 118.5(8) . . ?
C8 C7 C6 117.5(7) . . ?
C6 C7 C12 123.8(8) . . ?
C42 C43 C48 121.2(7) . . ?
C44 C43 C42 118.5(7) . . ?
C44 C43 C48 120.1(8) . . ?
C5 C4 C11 124.8(7) . . ?
C3 C4 C11 116.3(7) . . ?
C3 C4 C5 118.6(7) . . ?
C41 C40 C47 123.6(6) . . ?
C39 C40 C47 118.8(6) . . ?
C39 C40 C41 117.5(7) . . ?
N6 C46 H46 118.1 . . ?
N6 C46 C45 123.8(8) . . ?
C45 C46 H46 118.1 . . ?
C57 C56 H56 119.4 . . ?
C55 C56 C57 121.2(8) . . ?
C55 C56 H56 119.4 . . ?
C30 C31 C36 123.8(6) . . ?
C32 C31 C30 117.5(7) . . ?
C32 C31 C36 118.6(7) . . ?
N5 C41 C42 114.1(6) . . ?
N5 C41 C40 122.3(6) . . ?
C40 C41 C42 123.2(6) . . ?
N7 C25 H25 118.3 . . ?
N7 C25 C26 123.4(8) . . ?
C26 C25 H25 118.3 . . ?
O23 C62 O22 126.0(7) . . ?
O23 C62 C61 117.8(7) . . ?
O22 C62 C61 116.2(7) . . ?
O21 C61 O24 125.4(7) . . ?
O21 C61 C62 117.5(7) . . ?
O24 C61 C62 117.1(7) . . ?
C27 C26 H26 120.8 . . ?
C25 C26 C27 118.3(7) . . ?
C25 C26 H26 120.8 . . ?
O14 C36 Gd3 58.7(4) . . ?
O14 C36 O13 122.2(7) . . ?
O14 C36 C31 117.5(7) . . ?
O13 C36 Gd3 64.8(4) . . ?
O13 C36 C31 120.3(7) . . ?
C31 C36 Gd3 167.0(5) . . ?
N7 C29 C30 114.3(6) . . ?
N7 C29 C28 122.7(7) . . ?
C28 C29 C30 122.8(7) . . ?
N4 C18 C17 111.9(6) . . ?
N4 C18 C19 121.8(7) . . ?
C19 C18 C17 126.1(7) . . ?
O6 C23 Gd3 56.1(4) . 2_566 ?
O6 C23 C16 116.0(7) . . ?
O5 C23 Gd3 65.4(4) . 2_566 ?
O5 C23 O6 121.5(7) . . ?
O5 C23 C16 122.5(7) . . ?
C16 C23 Gd3 171.6(5) . 2_566 ?
O9 C48 Gd2 61.9(4) . 1_565 ?
O9 C48 O10 122.9(8) . . ?
O9 C48 C43 116.9(7) . . ?
O10 C48 Gd2 62.1(4) . 1_565 ?
O10 C48 C43 120.1(7) . . ?
C43 C48 Gd2 165.9(5) . 1_565 ?
C7 C8 H8 119.2 . . ?
C9 C8 C7 121.6(8) . . ?
C9 C8 H8 119.2 . . ?
C31 C32 H32 119.9 . . ?
C33 C32 C31 120.1(7) . . ?
C33 C32 H32 119.9 . . ?
N9 C49 C50 123.1(7) . . ?
N9 C49 H49 118.5 . . ?
C50 C49 H49 118.5 . . ?
C14 C15 C16 118.6(7) . . ?
C14 C15 H15 120.7 . . ?
C16 C15 H15 120.7 . . ?
N3 C17 C16 120.7(7) . . ?
N3 C17 C18 113.1(6) . . ?
C16 C17 C18 126.2(7) . . ?
N2 C6 C5 114.2(7) . . ?
N2 C6 C7 119.8(7) . . ?
C7 C6 C5 125.9(7) . . ?
N10 C54 C53 112.8(7) . . ?
N10 C54 C55 123.0(7) . . ?
C55 C54 C53 124.1(7) . . ?
C10 C9 H9 121.5 . . ?
C8 C9 C10 117.0(8) . . ?
C8 C9 H9 121.5 . . ?
C44 C45 H45 121.1 . . ?
C46 C45 C44 117.8(8) . . ?
C46 C45 H45 121.1 . . ?
O20 C59 C52 114.0(8) . . ?
O19 C59 O20 126.4(8) . . ?
O19 C59 C52 119.6(8) . . ?
C3 C2 H2 120.5 . . ?
C1 C2 H2 120.5 . . ?
C1 C2 C3 119.0(8) . . ?
C38 C39 C40 120.2(7) . . ?
C38 C39 H39 119.9 . . ?
C40 C39 H39 119.9 . . ?
C32 C33 H33 120.6 . . ?
C34 C33 C32 118.8(7) . . ?
C34 C33 H33 120.6 . . ?
O7 C24 O8 126.2(7) . . ?
O7 C24 C19 118.1(6) . . ?
O8 C24 C19 115.7(7) . . ?
N4 C22 H22 118.2 . . ?
N4 C22 C21 123.6(8) . . ?
C21 C22 H22 118.2 . . ?
C50 C51 H51 119.4 . . ?
C50 C51 C52 121.2(7) . . ?
C52 C51 H51 119.4 . . ?
C56 C55 C60 119.1(7) . . ?
C56 C55 C54 116.8(7) . . ?
C54 C55 C60 124.0(7) . . ?
C4 C3 H3 120.5 . . ?
C2 C3 C4 119.0(8) . . ?
C2 C3 H3 120.5 . . ?
N8 C34 H34 118.3 . . ?
C33 C34 N8 123.3(7) . . ?
C33 C34 H34 118.3 . . ?
C27 C28 C29 117.7(7) . . ?
C27 C28 C35 120.2(7) . . ?
C29 C28 C35 121.7(7) . . ?
C22 C21 H21 121.4 . . ?
C20 C21 C22 117.2(8) . . ?
C20 C21 H21 121.4 . . ?
O15 C35 Gd3 64.6(4) . 2_556 ?
O15 C35 C28 118.1(7) . . ?
O16 C35 Gd3 59.0(4) . 2_556 ?
O16 C35 O15 122.7(7) . . ?
O16 C35 C28 119.1(7) . . ?
C28 C35 Gd3 166.4(5) . 2_556 ?
C53 C52 C59 119.5(7) . . ?
C51 C52 C53 118.4(7) . . ?
C51 C52 C59 122.1(7) . . ?
C21 C20 H20 119.6 . . ?
C19 C20 C21 120.8(7) . . ?
C19 C20 H20 119.6 . . ?
N1 C1 C2 122.7(7) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C18 C19 C24 122.6(7) . . ?
C20 C19 C18 118.4(7) . . ?
C20 C19 C24 119.0(7) . . ?
C12 O4 Gd2 121.2(8) . 1_465 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Gd1 O12 C47 O11 -2.9(7) 2_757 . . . ?
Gd1 O12 C47 C40 179.7(6) 2_757 . . . ?
Gd1 O1 C11 O2 -27.7(13) 1_465 . . . ?
Gd1 O1 C11 C4 150.3(6) 1_465 . . . ?
Gd1 O11 C47 O12 2.8(7) 2_757 . . . ?
Gd1 O11 C47 C40 -179.8(6) 2_757 . . . ?
Gd1 O23 C62 O22 156.1(6) . . . . ?
Gd1 O23 C62 C61 -23.0(8) . . . . ?
Gd1 O18 C60 O17 4.2(12) 2_757 . . . ?
Gd1 O18 C60 C55 -174.8(5) 2_757 . . . ?
Gd1 O24 C61 O21 -172.5(6) . . . . ?
Gd1 O24 C61 C62 8.2(8) . . . . ?
Gd1 C47 C40 C41 -142(20) 2_757 . . . ?
Gd1 C47 C40 C39 37(20) 2_757 . . . ?
Gd3 O7 C24 O8 1.0(11) . . . . ?
Gd3 O7 C24 C19 -178.8(4) . . . . ?
Gd3 O6 C23 O5 -1.1(7) 2_566 . . . ?
Gd3 O6 C23 C16 176.7(5) 2_566 . . . ?
Gd3 O14 C36 O13 -13.9(8) . . . . ?
Gd3 O14 C36 C31 165.7(6) . . . . ?
Gd3 O5 C23 O6 1.0(7) 2_566 . . . ?
Gd3 O5 C23 C16 -176.6(6) 2_566 . . . ?
Gd3 O15 C35 O16 10.9(7) 2_556 . . . ?
Gd3 O15 C35 C28 -165.0(6) 2_556 . . . ?
Gd3 O16 C35 O15 -11.5(7) 2_556 . . . ?
Gd3 O16 C35 C28 164.4(6) 2_556 . . . ?
Gd3 O13 C36 O14 13.1(8) . . . . ?
Gd3 O13 C36 C31 -166.5(6) . . . . ?
Gd2 O9 C48 O10 12.4(8) 1_565 . . . ?
Gd2 O9 C48 C43 -164.2(6) 1_565 . . . ?
Gd2 O21 C61 O24 163.8(6) . . . . ?
Gd2 O21 C61 C62 -16.9(8) . . . . ?
Gd2 O20 C59 O19 14.9(13) . . . . ?
Gd2 O20 C59 C52 -167.1(5) . . . . ?
Gd2 O22 C62 O23 179.3(6) . . . . ?
Gd2 O22 C62 C61 -1.7(8) . . . . ?
Gd2 O10 C48 O9 -12.4(8) 1_565 . . . ?
Gd2 O10 C48 C43 164.1(6) 1_565 . . . ?
Ag2 N7 C25 C26 173.0(6) . . . . ?
Ag2 N7 C29 C30 4.8(7) . . . . ?
Ag2 N7 C29 C28 -170.0(5) . . . . ?
Ag2 N3 C17 C16 171.4(6) . . . . ?
Ag2 N3 C17 C18 -10.7(7) . . . . ?
Ag2 N5 C37 C38 155.3(7) . . . . ?
Ag2 N5 C41 C42 20.9(9) . . . . ?
Ag2 N5 C41 C40 -151.9(6) . . . . ?
Ag3 N8 C30 C31 -163.2(6) . . . . ?
Ag3 N8 C30 C29 12.8(9) . . . . ?
Ag3 N8 C34 C33 165.2(7) . . . . ?
Ag3 N9 C53 C54 -11.1(9) . . . . ?
Ag3 N9 C53 C52 175.9(6) . . . . ?
Ag3 N9 C49 C50 -176.1(6) . . . . ?
Ag3 N6 C46 C45 175.9(6) . . . . ?
Ag1 N2 C10 C9 156.7(6) . . . . ?
Ag1 N2 C6 C5 26.6(8) . . . . ?
Ag1 N2 C6 C7 -151.2(5) . . . . ?
Ag1 N10 C58 C57 -166.2(6) 1_545 . . . ?
Ag1 N10 C54 C53 -14.2(8) 1_545 . . . ?
Ag1 N10 C54 C55 168.5(6) 1_545 . . . ?
Ag1 N1 C5 C4 -141.7(7) . . . . ?
Ag1 N1 C5 C6 37.0(8) . . . . ?
Ag1 N1 C1 C2 141.1(7) . . . . ?
Ag1 N4 C18 C17 -54.3(7) . . . . ?
Ag1 N4 C18 C19 130.7(6) . . . . ?
Ag1 N4 C22 C21 -127.8(7) . . . . ?
O12 Gd1 O23 C62 -127.4(5) 2_757 . . . ?
O12 Gd1 O24 C61 61.8(7) 2_757 . . . ?
O12 C47 C40 C41 -152.0(7) . . . . ?
O12 C47 C40 C39 26.4(11) . . . . ?
O7 Gd3 O14 C36 -62.2(5) . . . . ?
O7 Gd3 O13 C36 89.8(5) . . . . ?
O7 Gd3 C36 O14 112.2(5) . . . . ?
O7 Gd3 C36 O13 -80.7(4) . . . . ?
O7 Gd3 C36 C31 35(2) . . . . ?
O7 C24 C19 C18 -3.1(11) . . . . ?
O7 C24 C19 C20 173.5(7) . . . . ?
O1 Gd1 O23 C62 -64.9(5) 1_645 . . . ?
O1 Gd1 O24 C61 56.5(5) 1_645 . . . ?
O1 C11 C4 C5 153.3(8) . . . . ?
O1 C11 C4 C3 -33.0(11) . . . . ?
O25 Gd3 O7 C24 12.7(6) . . . . ?
O25 Gd3 O14 C36 13.0(6) . . . . ?
O25 Gd3 O13 C36 177.9(5) . . . . ?
O25 Gd3 C36 O14 -169.0(5) . . . . ?
O25 Gd3 C36 O13 -2.0(5) . . . . ?
O25 Gd3 C36 C31 114(2) . . . . ?
O31 Gd1 O23 C62 109.3(5) . . . . ?
O31 Gd1 O24 C61 -85.3(5) . . . . ?
O9 Gd2 O21 C61 -98.7(6) 1_545 . . . ?
O9 Gd2 O20 C59 -32.4(7) 1_545 . . . ?
O9 Gd2 O22 C62 140.6(5) 1_545 . . . ?
O11 Gd1 O23 C62 -170.2(5) 2_757 . . . ?
O11 Gd1 O24 C61 -26.8(6) 2_757 . . . ?
O11 C47 C40 C41 30.5(11) . . . . ?
O11 C47 C40 C39 -151.2(7) . . . . ?
O29 Gd1 O23 C62 -38.9(6) . . . . ?
O29 Gd1 O24 C61 128.7(5) . . . . ?
O28 Gd2 O21 C61 33.6(7) . . . . ?
O28 Gd2 O20 C59 -114.2(7) . . . . ?
O28 Gd2 O22 C62 -166.9(6) . . . . ?
O27 Gd2 O21 C61 91.0(6) . . . . ?
O27 Gd2 O20 C59 -163.6(7) . . . . ?
O27 Gd2 O22 C62 -87.8(5) . . . . ?
O17 C60 C55 C56 6.9(11) . . . . ?
O17 C60 C55 C54 -171.0(7) . . . . ?
O6 Gd3 O7 C24 -60.5(6) 2_566 . . . ?
O6 Gd3 O14 C36 -96.9(6) 2_566 . . . ?
O6 Gd3 O13 C36 131.6(4) 2_566 . . . ?
O6 Gd3 C36 O14 120.9(5) 2_566 . . . ?
O6 Gd3 C36 O13 -72.1(5) 2_566 . . . ?
O6 Gd3 C36 C31 44(3) 2_566 . . . ?
O21 Gd2 O20 C59 114.2(7) . . . . ?
O21 Gd2 O22 C62 -4.4(5) . . . . ?
O8 C24 C19 C18 177.1(7) . . . . ?
O8 C24 C19 C20 -6.3(10) . . . . ?
O26 Gd3 O7 C24 -138.0(6) . . . . ?
O26 Gd3 O14 C36 -141.4(5) . . . . ?
O26 Gd3 O13 C36 32.3(5) . . . . ?
O26 Gd3 C36 O14 39.4(5) . . . . ?
O26 Gd3 C36 O13 -153.6(4) . . . . ?
O26 Gd3 C36 C31 -37(2) . . . . ?
O23 Gd1 O24 C61 -13.7(5) . . . . ?
O23 C62 C61 O21 -168.4(7) . . . . ?
O23 C62 C61 O24 11.0(10) . . . . ?
O14 Gd3 O7 C24 138.0(6) . . . . ?
O14 Gd3 O13 C36 -7.2(4) . . . . ?
O14 Gd3 C36 O13 167.0(8) . . . . ?
O14 Gd3 C36 C31 -77(2) . . . . ?
O18 Gd1 O23 C62 153.0(5) 2_757 . . . ?
O18 Gd1 O24 C61 -149.8(5) 2_757 . . . ?
O18 C60 C55 C56 -174.0(7) . . . . ?
O18 C60 C55 C54 8.0(11) . . . . ?
O2 C11 C4 C5 -28.6(13) . . . . ?
O2 C11 C4 C3 145.1(8) . . . . ?
O5 Gd3 O7 C24 -68.6(6) 2_566 . . . ?
O5 Gd3 O14 C36 158.1(4) 2_566 . . . ?
O5 Gd3 O13 C36 -146.1(5) 2_566 . . . ?
O5 Gd3 C36 O14 -59.3(10) 2_566 . . . ?
O5 Gd3 C36 O13 107.7(8) 2_566 . . . ?
O5 Gd3 C36 C31 -136(2) 2_566 . . . ?
O20 Gd2 O21 C61 172.0(6) . . . . ?
O20 Gd2 O22 C62 -29.9(6) . . . . ?
O20 C59 C52 C53 169.0(7) . . . . ?
O20 C59 C52 C51 -10.2(12) . . . . ?
O22 Gd2 O21 C61 11.6(5) . . . . ?
O22 Gd2 O20 C59 139.1(6) . . . . ?
O22 C62 C61 O21 12.5(10) . . . . ?
O22 C62 C61 O24 -168.1(7) . . . . ?
O10 Gd2 O21 C61 151.6(5) 1_545 . . . ?
O10 Gd2 O20 C59 -77.0(7) 1_545 . . . ?
O10 Gd2 O22 C62 -154.3(5) 1_545 . . . ?
O15 Gd3 O7 C24 172.5(5) 2_556 . . . ?
O15 Gd3 O14 C36 135.7(5) 2_556 . . . ?
O15 Gd3 O13 C36 -57.9(5) 2_556 . . . ?
O15 Gd3 C36 O14 -41.6(5) 2_556 . . . ?
O15 Gd3 C36 O13 125.4(4) 2_556 . . . ?
O15 Gd3 C36 C31 -118(2) 2_556 . . . ?
O16 Gd3 O7 C24 56.5(7) 2_556 . . . ?
O16 Gd3 O14 C36 85.3(5) 2_556 . . . ?
O16 Gd3 O13 C36 -106.1(5) 2_556 . . . ?
O16 Gd3 C36 O14 -95.0(5) 2_556 . . . ?
O16 Gd3 C36 O13 72.0(4) 2_556 . . . ?
O16 Gd3 C36 C31 -172(2) 2_556 . . . ?
O30 Gd1 O23 C62 54.3(5) . . . . ?
O30 Gd1 O24 C61 -160.8(6) . . . . ?
O13 Gd3 O7 C24 86.4(6) . . . . ?
O13 Gd3 O14 C36 7.2(4) . . . . ?
O13 Gd3 C36 O14 -167.0(8) . . . . ?
O13 Gd3 C36 C31 116(3) . . . . ?
N2 Ag1 N1 C5 -17.6(6) . . . . ?
N2 Ag1 N1 C1 -161.5(7) . . . . ?
N2 Ag1 N4 C18 41.9(6) . . . . ?
N2 Ag1 N4 C22 176.2(5) . . . . ?
N2 C10 C9 C8 -4.5(12) . . . . ?
N10 Ag1 N2 C10 55.3(7) 1_565 . . . ?
N10 Ag1 N2 C6 -148.1(5) 1_565 . . . ?
N10 Ag1 N1 C5 120.8(6) 1_565 . . . ?
N10 Ag1 N1 C1 -23.1(8) 1_565 . . . ?
N10 Ag1 N4 C18 -119.1(5) 1_565 . . . ?
N10 Ag1 N4 C22 15.1(6) 1_565 . . . ?
N10 C58 C57 C56 -1.4(12) . . . . ?
N10 C54 C55 C60 175.6(7) . . . . ?
N10 C54 C55 C56 -2.4(11) . . . . ?
O24 Gd1 O23 C62 19.3(5) . . . . ?
O19 C59 C52 C53 -12.8(12) . . . . ?
O19 C59 C52 C51 167.9(8) . . . . ?
N8 Ag3 N9 C53 129.5(5) . . . . ?
N8 Ag3 N9 C49 -54.9(7) . . . . ?
N8 Ag3 N6 C42 80.5(5) . . . . ?
N8 Ag3 N6 C46 -95.8(6) . . . . ?
N8 C30 C31 C36 -179.0(7) . . . . ?
N8 C30 C31 C32 -0.5(11) . . . . ?
N8 C30 C29 N7 -87.2(8) . . . . ?
N8 C30 C29 C28 87.6(9) . . . . ?
N7 Ag2 N3 C13 99.1(7) . . . . ?
N7 Ag2 N3 C17 -73.6(5) . . . . ?
N7 Ag2 N5 C37 -131.8(5) . . . . ?
N7 Ag2 N5 C41 27.4(7) . . . . ?
N7 C25 C26 C27 -1.7(12) . . . . ?
N7 C29 C28 C27 -5.0(11) . . . . ?
N7 C29 C28 C35 -177.8(6) . . . . ?
O3 C12 C7 C8 155.2(9) . . . . ?
O3 C12 C7 C6 -20.6(13) . . . . ?
O3 C12 O4 Gd2 -10.0(13) . . . 1_465 ?
N9 Ag3 N8 C30 -163.1(6) . . . . ?
N9 Ag3 N8 C34 30.9(6) . . . . ?
N9 Ag3 N6 C42 -78.5(5) . . . . ?
N9 Ag3 N6 C46 105.2(6) . . . . ?
N9 C53 C54 N10 -77.5(9) . . . . ?
N9 C53 C54 C55 99.8(9) . . . . ?
N9 C53 C52 C59 -179.1(7) . . . . ?
N9 C53 C52 C51 0.2(12) . . . . ?
C58 N10 C54 C53 177.4(7) . . . . ?
C58 N10 C54 C55 0.1(11) . . . . ?
C58 C57 C56 C55 -1.1(12) . . . . ?
C13 N3 C17 C16 -2.2(11) . . . . ?
C13 N3 C17 C18 175.7(7) . . . . ?
C13 C14 C15 C16 -2.3(11) . . . . ?
N3 Ag2 N7 C25 110.7(6) . . . . ?
N3 Ag2 N7 C29 -74.4(5) . . . . ?
N3 Ag2 N5 C37 26.0(6) . . . . ?
N3 Ag2 N5 C41 -174.8(6) . . . . ?
N3 C13 C14 C15 1.5(12) . . . . ?
C42 N6 C46 C45 -0.3(11) . . . . ?
C42 C43 C48 Gd2 80(2) . . . 1_565 ?
C42 C43 C48 O9 161.1(7) . . . . ?
C42 C43 C48 O10 -15.5(11) . . . . ?
N5 Ag2 N7 C25 -94.9(6) . . . . ?
N5 Ag2 N7 C29 80.1(6) . . . . ?
N5 Ag2 N3 C13 -59.3(7) . . . . ?
N5 Ag2 N3 C17 128.0(5) . . . . ?
C12 C7 C8 C9 -172.0(8) . . . . ?
C12 C7 C6 N2 168.3(7) . . . . ?
C12 C7 C6 C5 -9.3(12) . . . . ?
C30 N8 C34 C33 -2.5(12) . . . . ?
C30 C31 C36 Gd3 -101(2) . . . . ?
C30 C31 C36 O14 -170.9(8) . . . . ?
C30 C31 C36 O13 8.7(11) . . . . ?
C30 C31 C32 C33 -1.6(12) . . . . ?
C30 C29 C28 C27 -179.4(7) . . . . ?
C30 C29 C28 C35 7.8(11) . . . . ?
N6 Ag3 N8 C30 36.0(7) . . . . ?
N6 Ag3 N8 C34 -130.0(5) . . . . ?
N6 Ag3 N9 C53 -69.7(6) . . . . ?
N6 Ag3 N9 C49 105.9(6) . . . . ?
N6 C42 C43 C44 2.3(10) . . . . ?
N6 C42 C43 C48 -172.8(6) . . . . ?
N6 C42 C41 N5 -88.5(8) . . . . ?
N6 C42 C41 C40 84.3(9) . . . . ?
N6 C46 C45 C44 1.6(12) . . . . ?
C11 C4 C3 C2 -172.2(8) . . . . ?
N1 Ag1 N2 C10 -162.1(7) . . . . ?
N1 Ag1 N2 C6 -5.6(5) . . . . ?
N1 Ag1 N4 C18 101.1(5) . . . . ?
N1 Ag1 N4 C22 -124.7(6) . . . . ?
N1 C5 C4 C11 170.0(8) . . . . ?
N1 C5 C4 C3 -3.5(12) . . . . ?
N1 C5 C6 N2 -44.1(10) . . . . ?
N1 C5 C6 C7 133.6(8) . . . . ?
C44 C43 C48 Gd2 -95(2) . . . 1_565 ?
C44 C43 C48 O9 -13.9(11) . . . . ?
C44 C43 C48 O10 169.5(7) . . . . ?
C14 C13 N3 Ag2 -171.4(6) . . . . ?
C14 C13 N3 C17 0.8(11) . . . . ?
C47 Gd1 O23 C62 -148.6(5) 2_757 . . . ?
C47 Gd1 O24 C61 12.0(8) 2_757 . . . ?
C47 C40 C41 C42 3.9(12) . . . . ?
C47 C40 C41 N5 176.1(7) . . . . ?
C47 C40 C39 C38 178.9(8) . . . . ?
N4 Ag1 N2 C10 -97.6(6) . . . . ?
N4 Ag1 N2 C6 59.0(6) . . . . ?
N4 Ag1 N1 C5 -156.1(6) . . . . ?
N4 Ag1 N1 C1 60.0(6) . . . . ?
N4 C18 C17 N3 -73.6(8) . . . . ?
N4 C18 C17 C16 104.2(8) . . . . ?
N4 C18 C19 C24 174.6(7) . . . . ?
N4 C18 C19 C20 -2.0(11) . . . . ?
N4 C22 C21 C20 -2.4(13) . . . . ?
C37 N5 C41 C42 179.3(7) . . . . ?
C37 N5 C41 C40 6.5(11) . . . . ?
C37 C38 C39 C40 3.2(13) . . . . ?
C50 C51 C52 C53 0.3(13) . . . . ?
C50 C51 C52 C59 179.5(8) . . . . ?
C10 N2 C6 C5 -177.0(7) . . . . ?
C10 N2 C6 C7 5.2(11) . . . . ?
C5 N1 C1 C2 0.4(13) . . . . ?
C5 C4 C3 C2 1.9(13) . . . . ?
C57 C56 C55 C60 -175.2(7) . . . . ?
C57 C56 C55 C54 2.9(12) . . . . ?
C53 N9 C49 C50 -0.7(12) . . . . ?
C53 C54 C55 C60 -1.4(12) . . . . ?
C53 C54 C55 C56 -179.4(7) . . . . ?
C27 C28 C35 Gd3 -81(2) . . . 2_556 ?
C27 C28 C35 O15 16.8(10) . . . . ?
C27 C28 C35 O16 -159.3(7) . . . . ?
C7 C12 O4 Gd2 170.2(5) . . . 1_465 ?
C7 C8 C9 C10 1.7(12) . . . . ?
C43 C42 N6 Ag3 -178.2(5) . . . . ?
C43 C42 N6 C46 -1.7(10) . . . . ?
C43 C42 C41 N5 90.1(9) . . . . ?
C43 C42 C41 C40 -97.1(9) . . . . ?
C43 C44 C45 C46 -1.0(12) . . . . ?
C4 C5 C6 N2 134.5(8) . . . . ?
C4 C5 C6 C7 -47.8(12) . . . . ?
C31 C30 C29 N7 88.8(9) . . . . ?
C31 C30 C29 C28 -96.4(9) . . . . ?
C31 C32 C33 C34 1.6(13) . . . . ?
C41 C42 N6 Ag3 0.4(7) . . . . ?
C41 C42 N6 C46 176.9(6) . . . . ?
C41 C42 C43 C44 -176.2(7) . . . . ?
C41 C42 C43 C48 8.7(11) . . . . ?
C41 N5 C37 C38 -6.0(12) . . . . ?
C41 C40 C39 C38 -2.6(12) . . . . ?
C25 N7 C29 C30 -179.8(6) . . . . ?
C25 N7 C29 C28 5.3(10) . . . . ?
C26 C27 C28 C29 1.2(11) . . . . ?
C26 C27 C28 C35 174.1(7) . . . . ?
C36 Gd3 O7 C24 114.0(6) . . . . ?
C36 C31 C32 C33 177.0(8) . . . . ?
C29 N7 C25 C26 -1.9(11) . . . . ?
C29 C30 C31 C36 5.3(11) . . . . ?
C29 C30 C31 C32 -176.1(7) . . . . ?
C29 C28 C35 Gd3 91(2) . . . 2_556 ?
C29 C28 C35 O15 -170.6(7) . . . . ?
C29 C28 C35 O16 13.3(11) . . . . ?
C18 N4 C22 C21 2.8(12) . . . . ?
C23 Gd3 O7 C24 -64.0(6) 2_566 . . . ?
C23 Gd3 O14 C36 -153.0(6) 2_566 . . . ?
C23 Gd3 O13 C36 158.9(5) 2_566 . . . ?
C23 Gd3 C36 O14 122.3(10) 2_566 . . . ?
C23 Gd3 C36 O13 -70.7(12) 2_566 . . . ?
C23 Gd3 C36 C31 46(3) 2_566 . . . ?
C23 C16 C15 C14 175.9(7) . . . . ?
C23 C16 C17 N3 -173.5(7) . . . . ?
C23 C16 C17 C18 8.9(11) . . . . ?
C48 Gd2 O21 C61 -155.1(7) 1_545 . . . ?
C48 Gd2 O20 C59 -56.5(7) 1_545 . . . ?
C48 Gd2 O22 C62 170.5(5) 1_545 . . . ?
C8 C7 C6 N2 -7.6(11) . . . . ?
C8 C7 C6 C5 174.9(7) . . . . ?
C32 C31 C36 Gd3 80(3) . . . . ?
C32 C31 C36 O14 10.6(11) . . . . ?
C32 C31 C36 O13 -169.8(7) . . . . ?
C32 C33 C34 N8 0.5(13) . . . . ?
C49 N9 C53 C54 173.1(7) . . . . ?
C49 N9 C53 C52 0.1(11) . . . . ?
C49 C50 C51 C52 -0.9(12) . . . . ?
C15 C16 C23 Gd3 -28(4) . . . 2_566 ?
C15 C16 C23 O6 -47.0(9) . . . . ?
C15 C16 C23 O5 130.8(8) . . . . ?
C15 C16 C17 N3 1.3(11) . . . . ?
C15 C16 C17 C18 -176.3(7) . . . . ?
C17 C16 C23 Gd3 147(3) . . . 2_566 ?
C17 C16 C23 O6 127.9(7) . . . . ?
C17 C16 C23 O5 -54.3(10) . . . . ?
C17 C16 C15 C14 1.0(11) . . . . ?
C17 C18 C19 C24 0.4(12) . . . . ?
C17 C18 C19 C20 -176.3(7) . . . . ?
C6 N2 C10 C9 1.0(12) . . . . ?
C6 C5 C4 C11 -8.5(13) . . . . ?
C6 C5 C4 C3 178.0(8) . . . . ?
C6 C7 C8 C9 4.1(12) . . . . ?
C54 N10 C58 C57 1.9(12) . . . . ?
C54 C53 C52 C59 8.8(12) . . . . ?
C54 C53 C52 C51 -171.9(8) . . . . ?
C45 C44 C43 C42 -0.9(11) . . . . ?
C45 C44 C43 C48 174.3(7) . . . . ?
C39 C38 C37 N5 1.3(13) . . . . ?
C39 C40 C41 C42 -174.5(7) . . . . ?
C39 C40 C41 N5 -2.3(11) . . . . ?
C22 N4 C18 C17 174.5(7) . . . . ?
C22 N4 C18 C19 -0.5(11) . . . . ?
C22 C21 C20 C19 -0.3(12) . . . . ?
C51 C50 C49 N9 1.1(12) . . . . ?
C3 C2 C1 N1 -1.9(14) . . . . ?
C34 N8 C30 C31 2.5(11) . . . . ?
C34 N8 C30 C29 178.5(6) . . . . ?
C28 C27 C26 C25 2.0(12) . . . . ?
C21 C20 C19 C18 2.4(11) . . . . ?
C21 C20 C19 C24 -174.4(7) . . . . ?
C35 Gd3 O7 C24 112.0(7) 2_556 . . . ?
C35 Gd3 O14 C36 108.6(5) 2_556 . . . ?
C35 Gd3 O13 C36 -81.3(5) 2_556 . . . ?
C35 Gd3 C36 O14 -68.5(5) 2_556 . . . ?
C35 Gd3 C36 O13 98.5(5) 2_556 . . . ?
C35 Gd3 C36 C31 -145(2) 2_556 . . . ?
C52 C53 C54 N10 95.1(9) . . . . ?
C52 C53 C54 C55 -87.6(11) . . . . ?
C1 N1 C5 C4 2.4(13) . . . . ?
C1 N1 C5 C6 -178.9(8) . . . . ?
C1 C2 C3 C4 0.7(13) . . . . ?
C19 C18 C17 N3 101.2(9) . . . . ?
C19 C18 C17 C16 -81.1(11) . . . . ?
O4 Gd2 O21 C61 -90.6(6) 1_645 . . . ?
O4 Gd2 O20 C59 45.5(7) 1_645 . . . ?
O4 Gd2 O22 C62 62.4(5) 1_645 . . . ?
O4 C12 C7 C8 -25.0(11) . . . . ?
O4 C12 C7 C6 159.2(8) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1527506'
_audit_update_record             
;
2017-02-07 deposited with the CCDC.
2017-02-08 downloaded from the CCDC.
;
_audit_creation_date             2016-07-26
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C62 H44 Ag3 N10 O31 Tb3'
_chemical_formula_sum            'C62 H44 Ag3 N10 O31 Tb3'
_chemical_formula_weight         2225.44
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8970 1.1010 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1720 4.1540 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'

_cell_length_a                   12.6918(4)
_cell_length_b                   12.9749(4)
_cell_length_c                   23.5138(7)
_cell_angle_alpha                103.9950(10)
_cell_angle_beta                 102.1540(10)
_cell_angle_gamma                91.6670(10)
_cell_volume                     3659.89(19)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9935
_cell_measurement_temperature    120
_cell_measurement_theta_max      27.535
_cell_measurement_theta_min      3.248
_exptl_absorpt_coefficient_mu    3.739
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5880
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0973 before and 0.0715 after correction.
The Ratio of minimum to maximum transmission is 0.7886.
The λ/2 correction factor is 0.00150.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.019
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2140
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.18
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0759
_diffrn_reflns_av_unetI/netI     0.0636
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            56163
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.82
_diffrn_ambient_temperature      120
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                9578
_reflns_number_total             12867
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_refine_diff_density_max         1.654
_refine_diff_density_min         -1.265
_refine_diff_density_rms         0.158
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     989
_refine_ls_number_reflns         12867
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0644
_refine_ls_R_factor_gt           0.0412
_refine_ls_restrained_S_all      1.043
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0383P)²+2.4810P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0858
_refine_ls_wR_factor_ref         0.0925
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2.a Rotating group:
 O31(H31A,H31B), O25(H25A,H25B), O30(H30A,H30B), O27(H27A,H27B), O29(H29A,
 H29B), O26(H26A,H26B), O28(H28A,H28B)
2.b Aromatic/amide H refined with riding coordinates:
 C34(H34), C20(H20), C40(H40), C56(H56), C53(H53), C16(H16), C3(H3), C57(H57),
 C52(H52), C21(H21), C22(H22), C9(H9), C32(H32), C28(H28), C45(H45), C29(H29),
 C46(H46), C27(H27), C58(H58), C4(H4), C51(H51), C33(H33), C44(H44), C39(H39),
 C41(H41), C17(H17), C5(H5), C10(H10), C15(H15), C8(H8)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_refinement_flags_posn
Tb1 Tb 0.33425(3) 0.61005(3) 0.411727(15) 0.01960(9) Uani 1 d . . .
Tb3 Tb -0.45654(3) 1.24027(3) 0.014722(16) 0.02002(9) Uani 1 d . . .
Tb2 Tb 0.29563(3) 1.11162(3) 0.389041(18) 0.02776(10) Uani 1 d . . .
Ag3 Ag -0.16724(4) 0.81944(4) 0.18707(2) 0.01863(13) Uani 1 d . . .
Ag2 Ag -0.06870(4) 0.56582(4) 0.23174(2) 0.02061(13) Uani 1 d . . .
Ag1 Ag 0.17366(5) 0.76352(5) 0.77252(3) 0.02842(15) Uani 1 d . . .
O12 O 0.2824(4) 0.9930(4) 0.2862(3) 0.0364(14) Uani 1 d . . .
O2 O 0.4716(7) 0.8860(6) 0.6465(3) 0.068(3) Uani 1 d . . .
O24 O 0.6497(4) 0.7148(4) 0.5415(2) 0.0228(11) Uani 1 d . . .
O31 O -0.5747(4) 1.3095(4) 0.0811(2) 0.0264(12) Uani 1 d . . .
H31A H -0.5870 1.3750 0.0794 0.040 Uiso 1 d . . GR
H31B H -0.5440 1.3097 0.1182 0.040 Uiso 1 d . . GR
O5 O 0.1545(5) 0.2223(4) 0.3839(3) 0.053(2) Uani 1 d . . .
O1 O 0.6070(6) 0.7826(5) 0.6531(3) 0.074(3) Uani 1 d . . .
O25 O 0.2766(4) 0.4857(4) 0.4643(2) 0.0217(11) Uani 1 d . . .
H25A H 0.3094 0.4264 0.4563 0.033 Uiso 1 d . . GR
H25B H 0.2059 0.4696 0.4525 0.033 Uiso 1 d . . GR
O18 O -0.3780(4) 0.8634(4) 0.0436(2) 0.0184(11) Uani 1 d . . .
O30 O -0.3900(4) 1.0836(4) -0.0351(2) 0.0255(12) Uani 1 d . . .
H30A H -0.3432 1.1002 -0.0547 0.038 Uiso 1 d . . GR
H30B H -0.4436 1.0419 -0.0606 0.038 Uiso 1 d . . GR
O3 O 0.3472(4) 0.6101(4) 0.5787(2) 0.0298(13) Uani 1 d . . .
O27 O 0.4386(4) 0.6307(4) 0.3380(2) 0.0224(11) Uani 1 d . . .
H27A H 0.4419 0.6993 0.3343 0.034 Uiso 1 d . . GR
H27B H 0.4082 0.5878 0.3008 0.034 Uiso 1 d . . GR
O19 O -0.4950(4) 1.1051(4) 0.0642(2) 0.0208(11) Uani 1 d . . .
O4 O 0.3218(4) 0.7113(4) 0.5131(2) 0.0278(12) Uani 1 d . . .
O11 O 0.1418(4) 0.9805(4) 0.3264(2) 0.0241(12) Uani 1 d . . .
O23 O 0.5529(4) 0.8902(4) 0.5264(2) 0.0205(11) Uani 1 d . . .
O10 O 0.2301(4) 0.7337(4) 0.3549(2) 0.0204(11) Uani 1 d . . .
O6 O 0.1432(6) 0.2164(5) 0.2866(4) 0.065(2) Uani 1 d . . .
O14 O -0.3696(4) 0.4112(4) 0.0744(2) 0.0209(11) Uani 1 d . . .
O13 O -0.2690(4) 0.3165(4) 0.0186(2) 0.0213(11) Uani 1 d . . .
O20 O -0.3314(4) 1.1870(4) 0.1050(2) 0.0214(11) Uani 1 d . . .
O21 O 0.5137(4) 0.6140(4) 0.4726(2) 0.0217(11) Uani 1 d . . .
O8 O 0.3027(4) 0.5036(4) 0.2450(2) 0.0352(14) Uani 1 d . . .
O29 O 0.2099(5) 1.0940(5) 0.4711(3) 0.0445(16) Uani 1 d . . .
H29A H 0.2208 1.0385 0.4928 0.067 Uiso 1 d . . GR
H29B H 0.1590 1.1412 0.4874 0.067 Uiso 1 d . . GR
O15 O -0.5393(4) 0.7083(5) 0.0793(2) 0.0303(13) Uani 1 d . . .
O17 O -0.2695(4) 0.8385(4) -0.0214(2) 0.0265(12) Uani 1 d . . .
O9 O 0.1449(4) 0.6580(4) 0.4094(2) 0.0259(12) Uani 1 d . . .
O26 O 0.4265(4) 0.4453(4) 0.3870(2) 0.0225(11) Uani 1 d . . .
H26A H 0.3811 0.3882 0.3809 0.034 Uiso 1 d . . GR
H26B H 0.4820 0.4445 0.4170 0.034 Uiso 1 d . . GR
O7 O 0.2273(4) 0.4939(4) 0.3215(2) 0.0227(11) Uani 1 d . . .
O22 O 0.4372(4) 0.7909(4) 0.4453(2) 0.0222(11) Uani 1 d . . .
O28 O 0.3273(5) 0.9338(5) 0.3977(4) 0.063(2) Uani 1 d . . .
H28A H 0.3550 0.9344 0.4359 0.095 Uiso 1 d . . GR
H28B H 0.3737 0.9064 0.3757 0.095 Uiso 1 d . . GR
O16 O -0.4124(4) 0.6416(4) 0.0345(2) 0.0203(11) Uani 1 d . . .
N4 N -0.0401(5) 0.3076(5) 0.1969(3) 0.0231(14) Uani 1 d . . .
N7 N -0.2461(4) 0.5813(4) 0.1984(2) 0.0146(12) Uani 1 d . . .
N3 N -0.0400(4) 0.4823(5) 0.3061(2) 0.0177(13) Uani 1 d . . .
N6 N -0.0749(5) 0.8357(5) 0.2819(2) 0.0209(14) Uani 1 d . . .
N8 N -0.1618(5) 0.6866(5) 0.1084(3) 0.0195(13) Uani 1 d . . .
N5 N 0.0600(5) 0.6688(5) 0.2152(3) 0.0211(14) Uani 1 d . . .
N2 N 0.2010(5) 0.8398(5) 0.6924(3) 0.0288(15) Uani 1 d . . .
N10 N -0.1270(5) 1.0503(5) 0.1782(3) 0.0234(14) Uani 1 d . . .
N1 N 0.3240(5) 0.7020(5) 0.7424(3) 0.0232(14) Uani 1 d . . .
N9 N -0.3088(5) 0.9228(4) 0.1926(3) 0.0203(13) Uani 1 d . . .
C12 C 0.3138(6) 0.6903(6) 0.5617(3) 0.0231(17) Uani 1 d . . .
C55 C -0.2101(6) 0.9975(5) 0.1345(3) 0.0187(15) Uani 1 d . . .
C25 C 0.1473(6) 0.7154(5) 0.3739(3) 0.0198(16) Uani 1 d . . .
C34 C 0.2087(6) 0.8092(6) 0.1960(3) 0.0256(17) Uani 1 d . . .
H34 H 0.2592 0.8576 0.1891 0.031 Uiso 1 calc . . R
C20 C -0.0336(6) 0.2784(6) 0.1389(3) 0.0273(18) Uani 1 d . . .
H20 H -0.0942 0.2393 0.1098 0.033 Uiso 1 calc . . R
C18 C 0.0217(6) 0.3983(5) 0.2997(3) 0.0188(16) Uani 1 d . . .
C7 C 0.2684(6) 0.7840(6) 0.6625(4) 0.0259(17) Uani 1 d . . .
C43 C -0.2930(5) 0.6038(5) 0.1466(3) 0.0150(14) Uani 1 d . . .
C40 C -0.0898(6) 0.5982(6) 0.0255(3) 0.0238(17) Uani 1 d . . .
H40 H -0.0450 0.6019 -0.0017 0.029 Uiso 1 calc . . R
C56 C -0.0287(6) 1.0524(6) 0.1647(4) 0.0286(19) Uani 1 d . . .
H56 H 0.0314 1.0875 0.1956 0.034 Uiso 1 calc . . R
C53 C -0.3918(6) 0.9161(6) 0.2192(3) 0.0229(16) Uani 1 d . . .
H53 H -0.3902 0.8680 0.2440 0.028 Uiso 1 calc . . R
C16 C -0.0520(6) 0.4615(6) 0.4027(3) 0.0263(18) Uani 1 d . . .
H16 H -0.0805 0.4835 0.4376 0.032 Uiso 1 calc . . R
C3 C 0.5376(7) 0.7010(6) 0.7363(3) 0.0302(19) Uani 1 d . . .
H3 H 0.6116 0.7002 0.7343 0.036 Uiso 1 calc . . R
C49 C -0.4056(6) 1.1200(5) 0.1034(3) 0.0193(16) Uani 1 d . . .
C57 C -0.0109(6) 1.0060(6) 0.1084(4) 0.0286(18) Uani 1 d . . .
H57 H 0.0591 1.0112 0.1005 0.034 Uiso 1 calc . . R
C52 C -0.4788(6) 0.9760(6) 0.2120(3) 0.0223(16) Uani 1 d . . .
H52 H -0.5352 0.9711 0.2324 0.027 Uiso 1 calc . . R
C21 C 0.0581(6) 0.3030(6) 0.1201(4) 0.0291(19) Uani 1 d . . .
H21 H 0.0619 0.2786 0.0791 0.035 Uiso 1 calc . . R
C50 C -0.3977(5) 1.0532(5) 0.1473(3) 0.0169(15) Uani 1 d . . .
C19 C 0.0438(6) 0.3652(5) 0.2377(3) 0.0209(16) Uani 1 d . . .
C35 C 0.1585(6) 0.8396(6) 0.2436(3) 0.0213(16) Uani 1 d . . .
C22 C 0.1454(6) 0.3649(6) 0.1628(4) 0.0291(19) Uani 1 d . . .
H22 H 0.2091 0.3831 0.1510 0.035 Uiso 1 calc . . R
C9 C 0.0989(7) 0.8687(6) 0.6010(4) 0.034(2) Uani 1 d . . .
H9 H 0.0413 0.9013 0.5811 0.041 Uiso 1 calc . . R
C6 C 0.3585(6) 0.7438(5) 0.7010(3) 0.0233(17) Uani 1 d . . .
C62 C 0.5129(6) 0.8030(6) 0.4908(3) 0.0203(16) Uani 1 d . . .
C47 C -0.3974(6) 0.6393(5) 0.1373(3) 0.0174(15) Uani 1 d . . .
C32 C 0.1105(6) 0.6397(6) 0.1697(3) 0.0247(17) Uani 1 d . . .
H32 H 0.0940 0.5696 0.1442 0.030 Uiso 1 calc . . R
C28 C -0.1163(6) 0.8365(6) 0.3771(3) 0.0244(17) Uani 1 d . . .
H28 H -0.1635 0.8539 0.4039 0.029 Uiso 1 calc . . R
C45 C -0.4050(6) 0.6235(6) 0.2354(4) 0.0299(19) Uani 1 d . . .
H45 H -0.4423 0.6281 0.2668 0.036 Uiso 1 calc . . R
C29 C -0.1389(6) 0.8591(6) 0.3221(3) 0.0239(17) Uani 1 d . . .
H29 H -0.2028 0.8931 0.3115 0.029 Uiso 1 calc . . R
C46 C -0.4533(6) 0.6505(6) 0.1832(3) 0.0279(18) Uani 1 d . . .
H46 H -0.5231 0.6762 0.1787 0.033 Uiso 1 calc . . R
C13 C 0.1225(7) 0.2537(6) 0.3357(5) 0.037(2) Uani 1 d . . .
C27 C -0.0246(6) 0.7883(6) 0.3925(3) 0.0234(17) Uani 1 d . . .
H27 H -0.0084 0.7692 0.4298 0.028 Uiso 1 calc . . R
C54 C -0.3127(6) 0.9907(5) 0.1575(3) 0.0186(16) Uani 1 d . . .
C58 C -0.0969(6) 0.9525(6) 0.0645(3) 0.0236(17) Uani 1 d . . .
H58 H -0.0866 0.9196 0.0255 0.028 Uiso 1 calc . . R
C4 C 0.5022(6) 0.6540(7) 0.7756(3) 0.0312(19) Uani 1 d . . .
H4 H 0.5496 0.6186 0.8001 0.037 Uiso 1 calc . . R
C42 C -0.2237(5) 0.5966(6) 0.1025(3) 0.0182(15) Uani 1 d . . .
C38 C -0.2169(6) 0.5027(5) 0.0597(3) 0.0203(16) Uani 1 d . . .
C51 C -0.4824(6) 1.0438(6) 0.1742(3) 0.0205(16) Uani 1 d . . .
H51 H -0.5433 1.0836 0.1670 0.025 Uiso 1 calc . . R
C33 C 0.1842(6) 0.7061(6) 0.1583(3) 0.0279(18) Uani 1 d . . .
H33 H 0.2181 0.6829 0.1255 0.033 Uiso 1 calc . . R
C44 C -0.3011(6) 0.5895(6) 0.2415(3) 0.0242(17) Uani 1 d . . .
H44 H -0.2683 0.5715 0.2777 0.029 Uiso 1 calc . . R
C24 C 0.2316(6) 0.4703(6) 0.2669(4) 0.0263(18) Uani 1 d . . .
C11 C 0.2498(6) 0.7651(6) 0.5994(3) 0.0266(18) Uani 1 d . . .
C39 C -0.1481(6) 0.5049(6) 0.0207(3) 0.0227(17) Uani 1 d . . .
H39 H -0.1419 0.4424 -0.0089 0.027 Uiso 1 calc . . R
C61 C 0.5629(6) 0.7023(6) 0.5028(3) 0.0185(15) Uani 1 d . . .
C37 C -0.2883(5) 0.4040(5) 0.0517(3) 0.0170(15) Uani 1 d . . .
C1 C 0.5163(9) 0.8137(8) 0.6632(4) 0.049(3) Uani 1 d . . .
C41 C -0.0967(6) 0.6871(6) 0.0705(3) 0.0203(16) Uani 1 d . . .
H41 H -0.0537 0.7507 0.0746 0.024 Uiso 1 calc . . R
C31 C 0.0836(5) 0.7674(6) 0.2514(3) 0.0178(15) Uani 1 d . . .
C30 C 0.0182(6) 0.7921(5) 0.2988(3) 0.0187(16) Uani 1 d . . .
C17 C -0.0744(5) 0.5116(6) 0.3567(3) 0.0193(16) Uani 1 d . . .
H17 H -0.1172 0.5706 0.3614 0.023 Uiso 1 calc . . R
C36 C 0.1938(6) 0.9451(6) 0.2875(3) 0.0265(18) Uani 1 d . . .
C26 C 0.0450(6) 0.7671(5) 0.3540(3) 0.0189(16) Uani 1 d . . .
C5 C 0.3944(7) 0.6597(6) 0.7785(3) 0.0302(19) Uani 1 d . . .
H5 H 0.3700 0.6320 0.8078 0.036 Uiso 1 calc . . R
C2 C 0.4679(7) 0.7499(6) 0.6993(4) 0.029(2) Uani 1 d . . .
C48 C -0.4520(6) 0.6643(6) 0.0797(3) 0.0226(17) Uani 1 d . . .
C60 C -0.2902(6) 0.8780(5) 0.0292(3) 0.0202(16) Uani 1 d . . .
C23 C 0.1383(6) 0.3991(6) 0.2221(3) 0.0230(17) Uani 1 d . . .
C10 C 0.1660(6) 0.8083(6) 0.5694(4) 0.0275(18) Uani 1 d . . .
H10 H 0.1536 0.7970 0.5270 0.033 Uiso 1 calc . . R
C59 C -0.2000(6) 0.9460(6) 0.0767(3) 0.0211(16) Uani 1 d . . .
C14 C 0.0497(5) 0.3438(6) 0.3435(3) 0.0218(17) Uani 1 d . . .
C15 C 0.0139(6) 0.3778(6) 0.3963(3) 0.0265(18) Uani 1 d . . .
H15 H 0.0344 0.3439 0.4280 0.032 Uiso 1 calc . . R
C8 C 0.1182(7) 0.8803(7) 0.6625(4) 0.037(2) Uani 1 d . . .
H8 H 0.0704 0.9187 0.6843 0.045 Uiso 1 calc . . R


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Tb1 O25 2.438(5) . ?
Tb1 O27 2.449(5) . ?
Tb1 O4 2.467(5) . ?
Tb1 O10 2.555(5) . ?
Tb1 O21 2.413(5) . ?
Tb1 O9 2.492(5) . ?
Tb1 O26 2.471(5) . ?
Tb1 O7 2.395(5) . ?
Tb1 O22 2.516(5) . ?
Tb1 C25 2.859(7) . ?
Tb3 O31 2.424(5) . ?
Tb3 O18 2.415(4) 2_475 ?
Tb3 O30 2.363(5) . ?
Tb3 O19 2.417(5) . ?
Tb3 O14 2.409(4) 1_565 ?
Tb3 O13 2.526(5) 1_565 ?
Tb3 O20 2.620(5) . ?
Tb3 O15 2.451(5) 2_475 ?
Tb3 O16 2.578(5) 2_475 ?
Tb3 C49 2.875(7) . ?
Tb3 C37 2.808(7) 1_565 ?
Tb3 C48 2.853(7) 2_475 ?
Tb2 O12 2.501(5) . ?
Tb2 O24 2.423(5) 2_676 ?
Tb2 O5 2.330(6) 1_565 ?
Tb2 O1 2.337(6) 2_676 ?
Tb2 O11 2.502(5) . ?
Tb2 O23 2.462(5) 2_676 ?
Tb2 O29 2.457(6) . ?
Tb2 O28 2.402(6) . ?
Tb2 C36 2.843(7) . ?
Ag3 N6 2.246(6) . ?
Ag3 N8 2.217(6) . ?
Ag3 N9 2.280(6) . ?
Ag2 N7 2.255(6) . ?
Ag2 N3 2.243(6) . ?
Ag2 N5 2.235(6) . ?
Ag1 N4 2.233(6) 2_566 ?
Ag1 N2 2.409(6) . ?
Ag1 N10 2.558(6) 2_576 ?
Ag1 N1 2.272(6) . ?
O12 C36 1.279(9) . ?
O2 C1 1.214(13) . ?
O24 Tb2 2.423(5) 2_676 ?
O24 C61 1.251(8) . ?
O31 H31A 0.8767 . ?
O31 H31B 0.8767 . ?
O5 Tb2 2.330(6) 1_545 ?
O5 C13 1.287(11) . ?
O1 Tb2 2.337(6) 2_676 ?
O1 C1 1.281(13) . ?
O25 H25A 0.8846 . ?
O25 H25B 0.8849 . ?
O18 Tb3 2.415(4) 2_475 ?
O18 C60 1.253(8) . ?
O30 H30A 0.8752 . ?
O30 H30B 0.8750 . ?
O3 C12 1.255(9) . ?
O27 H27A 0.9147 . ?
O27 H27B 0.9135 . ?
O19 C49 1.279(8) . ?
O4 C12 1.261(8) . ?
O11 C36 1.246(9) . ?
O23 Tb2 2.462(5) 2_676 ?
O23 C62 1.252(8) . ?
O10 C25 1.262(8) . ?
O6 C13 1.225(11) . ?
O14 Tb3 2.409(4) 1_545 ?
O14 C37 1.254(8) . ?
O13 Tb3 2.526(5) 1_545 ?
O13 C37 1.274(8) . ?
O20 C49 1.251(8) . ?
O21 C61 1.259(8) . ?
O8 C24 1.243(9) . ?
O29 H29A 0.9761 . ?
O29 H29B 0.9767 . ?
O15 Tb3 2.451(5) 2_475 ?
O15 C48 1.260(9) . ?
O17 C60 1.262(8) . ?
O9 C25 1.250(9) . ?
O26 H26A 0.8899 . ?
O26 H26B 0.8898 . ?
O7 C24 1.260(9) . ?
O22 C62 1.253(8) . ?
O28 H28A 0.8910 . ?
O28 H28B 0.8903 . ?
O16 Tb3 2.578(5) 2_475 ?
O16 C48 1.246(9) . ?
N4 Ag1 2.233(6) 2_566 ?
N4 C20 1.345(9) . ?
N4 C19 1.337(9) . ?
N7 C43 1.342(8) . ?
N7 C44 1.333(9) . ?
N3 C18 1.358(9) . ?
N3 C17 1.327(9) . ?
N6 C29 1.359(9) . ?
N6 C30 1.351(9) . ?
N8 C42 1.350(9) . ?
N8 C41 1.338(9) . ?
N5 C32 1.343(9) . ?
N5 C31 1.339(9) . ?
N2 C7 1.340(10) . ?
N2 C8 1.332(11) . ?
N10 Ag1 2.558(6) 2_576 ?
N10 C55 1.340(9) . ?
N10 C56 1.352(9) . ?
N1 C6 1.362(9) . ?
N1 C5 1.325(10) . ?
N9 C53 1.345(9) . ?
N9 C54 1.340(9) . ?
C12 C11 1.524(10) . ?
C55 C54 1.519(9) . ?
C55 C59 1.397(10) . ?
C25 C26 1.518(10) . ?
C34 H34 0.9500 . ?
C34 C35 1.383(10) . ?
C34 C33 1.400(10) . ?
C20 H20 0.9500 . ?
C20 C21 1.386(11) . ?
C18 C19 1.505(10) . ?
C18 C14 1.379(10) . ?
C7 C6 1.492(11) . ?
C7 C11 1.411(11) . ?
C43 C47 1.407(10) . ?
C43 C42 1.483(9) . ?
C40 H40 0.9500 . ?
C40 C39 1.368(10) . ?
C40 C41 1.382(10) . ?
C56 H56 0.9500 . ?
C56 C57 1.383(11) . ?
C53 H53 0.9500 . ?
C53 C52 1.373(10) . ?
C16 H16 0.9500 . ?
C16 C17 1.377(10) . ?
C16 C15 1.388(11) . ?
C3 H3 0.9500 . ?
C3 C4 1.363(11) . ?
C3 C2 1.385(12) . ?
C49 C50 1.490(10) . ?
C57 H57 0.9500 . ?
C57 C58 1.370(10) . ?
C52 H52 0.9500 . ?
C52 C51 1.390(10) . ?
C21 H21 0.9500 . ?
C21 C22 1.404(10) . ?
C50 C54 1.384(10) . ?
C50 C51 1.373(10) . ?
C19 C23 1.414(10) . ?
C35 C31 1.386(10) . ?
C35 C36 1.492(10) . ?
C22 H22 0.9500 . ?
C22 C23 1.380(10) . ?
C9 H9 0.9500 . ?
C9 C10 1.384(11) . ?
C9 C8 1.386(12) . ?
C6 C2 1.397(11) . ?
C62 C61 1.529(10) . ?
C47 C46 1.393(10) . ?
C47 C48 1.499(10) . ?
C32 H32 0.9500 . ?
C32 C33 1.364(10) . ?
C28 H28 0.9500 . ?
C28 C29 1.370(10) . ?
C28 C27 1.361(10) . ?
C45 H45 0.9500 . ?
C45 C46 1.382(11) . ?
C45 C44 1.392(11) . ?
C29 H29 0.9500 . ?
C46 H46 0.9500 . ?
C13 C14 1.512(11) . ?
C27 H27 0.9500 . ?
C27 C26 1.380(10) . ?
C58 H58 0.9500 . ?
C58 C59 1.402(10) . ?
C4 H4 0.9500 . ?
C4 C5 1.387(11) . ?
C42 C38 1.397(10) . ?
C38 C39 1.399(10) . ?
C38 C37 1.497(9) . ?
C51 H51 0.9500 . ?
C33 H33 0.9500 . ?
C44 H44 0.9500 . ?
C24 C23 1.517(10) . ?
C11 C10 1.360(11) . ?
C39 H39 0.9500 . ?
C37 Tb3 2.808(7) 1_545 ?
C1 C2 1.521(12) . ?
C41 H41 0.9500 . ?
C31 C30 1.505(10) . ?
C30 C26 1.390(10) . ?
C17 H17 0.9500 . ?
C5 H5 0.9500 . ?
C48 Tb3 2.853(7) 2_475 ?
C60 C59 1.504(10) . ?
C10 H10 0.9500 . ?
C14 C15 1.388(11) . ?
C15 H15 0.9500 . ?
C8 H8 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O25 Tb1 O27 144.22(16) . . ?
O25 Tb1 O4 71.53(16) . . ?
O25 Tb1 O10 131.98(16) . . ?
O25 Tb1 O9 80.58(17) . . ?
O25 Tb1 O26 71.62(16) . . ?
O25 Tb1 O22 134.09(16) . . ?
O25 Tb1 C25 106.06(19) . . ?
O27 Tb1 O4 136.20(17) . . ?
O27 Tb1 O10 75.23(16) . . ?
O27 Tb1 O9 125.21(16) . . ?
O27 Tb1 O26 72.80(16) . . ?
O27 Tb1 O22 70.27(16) . . ?
O27 Tb1 C25 100.30(19) . . ?
O4 Tb1 O10 96.30(16) . . ?
O4 Tb1 O9 70.80(17) . . ?
O4 Tb1 O26 126.49(17) . . ?
O4 Tb1 O22 66.37(17) . . ?
O4 Tb1 C25 83.45(18) . . ?
O10 Tb1 C25 26.20(18) . . ?
O21 Tb1 O25 87.08(16) . . ?
O21 Tb1 O27 81.35(16) . . ?
O21 Tb1 O4 75.88(17) . . ?
O21 Tb1 O10 136.16(15) . . ?
O21 Tb1 O9 146.61(16) . . ?
O21 Tb1 O26 64.83(16) . . ?
O21 Tb1 O22 65.94(16) . . ?
O21 Tb1 C25 150.64(17) . . ?
O9 Tb1 O10 52.04(16) . . ?
O9 Tb1 O22 101.56(17) . . ?
O9 Tb1 C25 25.86(18) . . ?
O26 Tb1 O10 137.20(16) . . ?
O26 Tb1 O9 136.97(16) . . ?
O26 Tb1 O22 121.41(16) . . ?
O26 Tb1 C25 143.95(17) . . ?
O7 Tb1 O25 86.50(16) . . ?
O7 Tb1 O27 78.74(16) . . ?
O7 Tb1 O4 141.48(17) . . ?
O7 Tb1 O10 75.01(16) . . ?
O7 Tb1 O21 135.60(16) . . ?
O7 Tb1 O9 74.73(16) . . ?
O7 Tb1 O26 71.46(16) . . ?
O7 Tb1 O22 138.82(16) . . ?
O7 Tb1 C25 72.49(18) . . ?
O22 Tb1 O10 71.40(15) . . ?
O22 Tb1 C25 86.83(18) . . ?
O31 Tb3 O13 127.23(15) . 1_565 ?
O31 Tb3 O20 88.31(17) . . ?
O31 Tb3 O15 122.50(18) . 2_475 ?
O31 Tb3 O16 71.03(17) . 2_475 ?
O31 Tb3 C49 78.59(19) . . ?
O31 Tb3 C37 101.16(18) . 1_565 ?
O31 Tb3 C48 96.9(2) . 2_475 ?
O18 Tb3 O31 81.55(16) 2_475 . ?
O18 Tb3 O19 71.67(16) 2_475 . ?
O18 Tb3 O13 148.75(15) 2_475 1_565 ?
O18 Tb3 O20 122.92(15) 2_475 . ?
O18 Tb3 O15 82.31(16) 2_475 2_475 ?
O18 Tb3 O16 69.45(15) 2_475 2_475 ?
O18 Tb3 C49 97.59(18) 2_475 . ?
O18 Tb3 C37 159.01(18) 2_475 1_565 ?
O18 Tb3 C48 71.22(18) 2_475 2_475 ?
O30 Tb3 O31 144.42(17) . . ?
O30 Tb3 O18 78.41(16) . 2_475 ?
O30 Tb3 O19 74.25(17) . . ?
O30 Tb3 O14 132.81(16) . 1_565 ?
O30 Tb3 O13 81.27(16) . 1_565 ?
O30 Tb3 O20 78.54(16) . . ?
O30 Tb3 O15 83.53(18) . 2_475 ?
O30 Tb3 O16 126.68(16) . 2_475 ?
O30 Tb3 C49 75.32(18) . . ?
O30 Tb3 C37 108.06(19) . 1_565 ?
O30 Tb3 C48 104.0(2) . 2_475 ?
O19 Tb3 O31 71.66(17) . . ?
O19 Tb3 O13 124.65(16) . 1_565 ?
O19 Tb3 O20 51.97(15) . . ?
O19 Tb3 O15 148.49(17) . 2_475 ?
O19 Tb3 O16 128.93(16) . 2_475 ?
O19 Tb3 C49 26.19(17) . . ?
O19 Tb3 C37 129.10(18) . 1_565 ?
O19 Tb3 C48 142.38(18) . 2_475 ?
O14 Tb3 O31 74.76(16) 1_565 . ?
O14 Tb3 O18 147.64(16) 1_565 2_475 ?
O14 Tb3 O19 119.45(16) 1_565 . ?
O14 Tb3 O13 53.12(15) 1_565 1_565 ?
O14 Tb3 O20 78.55(16) 1_565 . ?
O14 Tb3 O15 92.04(17) 1_565 2_475 ?
O14 Tb3 O16 82.05(16) 1_565 2_475 ?
O14 Tb3 C49 98.94(18) 1_565 . ?
O14 Tb3 C37 26.42(18) 1_565 1_565 ?
O14 Tb3 C48 89.88(18) 1_565 2_475 ?
O13 Tb3 O20 75.10(15) 1_565 . ?
O13 Tb3 O16 105.59(16) 1_565 2_475 ?
O13 Tb3 C49 99.92(19) 1_565 . ?
O13 Tb3 C37 26.98(17) 1_565 1_565 ?
O13 Tb3 C48 91.20(19) 1_565 2_475 ?
O20 Tb3 C49 25.79(17) . . ?
O20 Tb3 C37 78.06(17) . 1_565 ?
O20 Tb3 C48 165.65(17) . 2_475 ?
O15 Tb3 O13 71.99(17) 2_475 1_565 ?
O15 Tb3 O20 144.45(16) 2_475 . ?
O15 Tb3 O16 51.62(16) 2_475 2_475 ?
O15 Tb3 C49 158.38(18) 2_475 . ?
O15 Tb3 C37 78.73(19) 2_475 1_565 ?
O15 Tb3 C48 26.10(19) 2_475 2_475 ?
O16 Tb3 O20 154.77(15) 2_475 . ?
O16 Tb3 C49 148.25(18) 2_475 . ?
O16 Tb3 C37 91.55(18) 2_475 1_565 ?
O16 Tb3 C48 25.90(18) 2_475 2_475 ?
C37 Tb3 C49 103.4(2) 1_565 . ?
C37 Tb3 C48 87.8(2) 1_565 2_475 ?
C48 Tb3 C49 168.6(2) 2_475 . ?
O12 Tb2 O11 52.37(16) . . ?
O12 Tb2 C36 26.7(2) . . ?
O24 Tb2 O12 148.22(17) 2_676 . ?
O24 Tb2 O11 146.71(16) 2_676 . ?
O24 Tb2 O23 66.51(16) 2_676 2_676 ?
O24 Tb2 O29 79.47(19) 2_676 . ?
O24 Tb2 C36 162.9(2) 2_676 . ?
O5 Tb2 O12 108.1(2) 1_565 . ?
O5 Tb2 O24 69.11(18) 1_565 2_676 ?
O5 Tb2 O1 90.6(3) 1_565 2_676 ?
O5 Tb2 O11 79.29(18) 1_565 . ?
O5 Tb2 O23 130.1(2) 1_565 2_676 ?
O5 Tb2 O29 75.4(2) 1_565 . ?
O5 Tb2 O28 139.3(2) 1_565 . ?
O5 Tb2 C36 96.3(2) 1_565 . ?
O1 Tb2 O12 78.51(19) 2_676 . ?
O1 Tb2 O24 69.98(19) 2_676 2_676 ?
O1 Tb2 O11 121.9(2) 2_676 . ?
O1 Tb2 O23 94.8(2) 2_676 2_676 ?
O1 Tb2 O29 149.3(2) 2_676 . ?
O1 Tb2 O28 127.2(3) 2_676 . ?
O1 Tb2 C36 102.5(2) 2_676 . ?
O11 Tb2 C36 25.97(19) . . ?
O23 Tb2 O12 121.65(18) 2_676 . ?
O23 Tb2 O11 134.59(16) 2_676 . ?
O23 Tb2 C36 130.32(19) 2_676 . ?
O29 Tb2 O12 131.60(19) . . ?
O29 Tb2 O11 82.76(19) . . ?
O29 Tb2 O23 75.12(18) . 2_676 ?
O29 Tb2 C36 106.0(2) . . ?
O28 Tb2 O12 71.2(2) . . ?
O28 Tb2 O24 132.5(2) . 2_676 ?
O28 Tb2 O11 68.52(18) . . ?
O28 Tb2 O23 67.98(18) . 2_676 ?
O28 Tb2 O29 76.5(3) . . ?
O28 Tb2 C36 64.4(2) . . ?
N6 Ag3 N9 106.9(2) . . ?
N8 Ag3 N6 125.6(2) . . ?
N8 Ag3 N9 123.8(2) . . ?
N3 Ag2 N7 111.9(2) . . ?
N5 Ag2 N7 122.0(2) . . ?
N5 Ag2 N3 123.0(2) . . ?
N4 Ag1 N2 139.9(2) 2_566 . ?
N4 Ag1 N10 89.5(2) 2_566 2_576 ?
N4 Ag1 N1 134.5(2) 2_566 . ?
N2 Ag1 N10 85.4(2) . 2_576 ?
N1 Ag1 N2 71.1(2) . . ?
N1 Ag1 N10 132.7(2) . 2_576 ?
C36 O12 Tb2 91.7(4) . . ?
C61 O24 Tb2 119.0(4) . 2_676 ?
Tb3 O31 H31A 109.3 . . ?
Tb3 O31 H31B 110.0 . . ?
H31A O31 H31B 109.0 . . ?
C13 O5 Tb2 119.0(6) . 1_545 ?
C1 O1 Tb2 117.0(7) . 2_676 ?
Tb1 O25 H25A 109.8 . . ?
Tb1 O25 H25B 110.3 . . ?
H25A O25 H25B 108.6 . . ?
C60 O18 Tb3 130.2(4) . 2_475 ?
Tb3 O30 H30A 109.7 . . ?
Tb3 O30 H30B 109.5 . . ?
H30A O30 H30B 109.2 . . ?
Tb1 O27 H27A 111.7 . . ?
Tb1 O27 H27B 111.3 . . ?
H27A O27 H27B 107.2 . . ?
C49 O19 Tb3 97.3(4) . . ?
C12 O4 Tb1 136.7(5) . . ?
C36 O11 Tb2 92.5(4) . . ?
C62 O23 Tb2 118.3(5) . 2_676 ?
C25 O10 Tb1 90.5(4) . . ?
C37 O14 Tb3 94.8(4) . 1_545 ?
C37 O13 Tb3 89.0(4) . 1_545 ?
C49 O20 Tb3 88.6(4) . . ?
C61 O21 Tb1 119.3(4) . . ?
Tb2 O29 H29A 125.8 . . ?
Tb2 O29 H29B 125.8 . . ?
H29A O29 H29B 108.4 . . ?
C48 O15 Tb3 95.1(4) . 2_475 ?
C25 O9 Tb1 93.7(4) . . ?
Tb1 O26 H26A 110.5 . . ?
Tb1 O26 H26B 110.1 . . ?
H26A O26 H26B 108.4 . . ?
C24 O7 Tb1 135.0(4) . . ?
C62 O22 Tb1 114.4(4) . . ?
Tb2 O28 H28A 110.2 . . ?
Tb2 O28 H28B 110.3 . . ?
H28A O28 H28B 108.4 . . ?
C48 O16 Tb3 89.4(4) . 2_475 ?
C20 N4 Ag1 120.5(5) . 2_566 ?
C19 N4 Ag1 119.6(5) . 2_566 ?
C19 N4 C20 118.9(6) . . ?
C43 N7 Ag2 126.9(4) . . ?
C44 N7 Ag2 112.4(4) . . ?
C44 N7 C43 119.3(6) . . ?
C18 N3 Ag2 117.0(4) . . ?
C17 N3 Ag2 125.1(5) . . ?
C17 N3 C18 117.8(6) . . ?
C29 N6 Ag3 112.2(5) . . ?
C30 N6 Ag3 126.3(5) . . ?
C30 N6 C29 117.4(6) . . ?
C42 N8 Ag3 115.6(5) . . ?
C41 N8 Ag3 125.0(5) . . ?
C41 N8 C42 119.1(6) . . ?
C32 N5 Ag2 124.1(5) . . ?
C31 N5 Ag2 117.3(5) . . ?
C31 N5 C32 118.6(6) . . ?
C7 N2 Ag1 110.2(5) . . ?
C8 N2 Ag1 118.8(5) . . ?
C8 N2 C7 119.7(7) . . ?
C55 N10 Ag1 111.2(4) . 2_576 ?
C55 N10 C56 117.2(6) . . ?
C56 N10 Ag1 112.0(4) . 2_576 ?
C6 N1 Ag1 117.6(5) . . ?
C5 N1 Ag1 118.9(5) . . ?
C5 N1 C6 119.0(7) . . ?
C53 N9 Ag3 129.7(5) . . ?
C54 N9 Ag3 111.9(5) . . ?
C54 N9 C53 117.8(6) . . ?
O3 C12 O4 125.5(7) . . ?
O3 C12 C11 118.7(6) . . ?
O4 C12 C11 115.6(7) . . ?
N10 C55 C54 111.8(6) . . ?
N10 C55 C59 123.6(6) . . ?
C59 C55 C54 124.3(6) . . ?
O10 C25 Tb1 63.3(4) . . ?
O10 C25 C26 118.9(6) . . ?
O9 C25 Tb1 60.4(4) . . ?
O9 C25 O10 123.7(7) . . ?
O9 C25 C26 117.4(6) . . ?
C26 C25 Tb1 177.4(5) . . ?
C35 C34 H34 120.4 . . ?
C35 C34 C33 119.2(7) . . ?
C33 C34 H34 120.4 . . ?
N4 C20 H20 118.8 . . ?
N4 C20 C21 122.4(7) . . ?
C21 C20 H20 118.8 . . ?
N3 C18 C19 112.3(6) . . ?
N3 C18 C14 122.6(7) . . ?
C14 C18 C19 124.8(6) . . ?
N2 C7 C6 114.6(7) . . ?
N2 C7 C11 120.2(7) . . ?
C11 C7 C6 125.2(7) . . ?
N7 C43 C47 121.7(6) . . ?
N7 C43 C42 115.1(6) . . ?
C47 C43 C42 123.0(6) . . ?
C39 C40 H40 120.4 . . ?
C39 C40 C41 119.3(7) . . ?
C41 C40 H40 120.4 . . ?
N10 C56 H56 118.3 . . ?
N10 C56 C57 123.5(7) . . ?
C57 C56 H56 118.3 . . ?
N9 C53 H53 118.6 . . ?
N9 C53 C52 122.7(7) . . ?
C52 C53 H53 118.6 . . ?
C17 C16 H16 121.2 . . ?
C17 C16 C15 117.5(7) . . ?
C15 C16 H16 121.2 . . ?
C4 C3 H3 119.4 . . ?
C4 C3 C2 121.3(8) . . ?
C2 C3 H3 119.4 . . ?
O19 C49 Tb3 56.5(3) . . ?
O19 C49 C50 115.0(6) . . ?
O20 C49 Tb3 65.6(4) . . ?
O20 C49 O19 122.1(7) . . ?
O20 C49 C50 122.9(6) . . ?
C50 C49 Tb3 171.1(5) . . ?
C56 C57 H57 120.9 . . ?
C58 C57 C56 118.3(7) . . ?
C58 C57 H57 120.9 . . ?
C53 C52 H52 120.8 . . ?
C53 C52 C51 118.4(7) . . ?
C51 C52 H52 120.8 . . ?
C20 C21 H21 120.8 . . ?
C20 C21 C22 118.5(7) . . ?
C22 C21 H21 120.8 . . ?
C54 C50 C49 122.3(6) . . ?
C51 C50 C49 119.5(6) . . ?
C51 C50 C54 117.9(6) . . ?
N4 C19 C18 112.8(6) . . ?
N4 C19 C23 122.7(7) . . ?
C23 C19 C18 124.3(6) . . ?
C34 C35 C31 118.6(7) . . ?
C34 C35 C36 118.8(6) . . ?
C31 C35 C36 122.4(6) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 C21 119.8(7) . . ?
C23 C22 H22 120.1 . . ?
C10 C9 H9 121.0 . . ?
C10 C9 C8 118.0(8) . . ?
C8 C9 H9 121.0 . . ?
N1 C6 C7 112.1(7) . . ?
N1 C6 C2 121.0(8) . . ?
C2 C6 C7 126.8(7) . . ?
O23 C62 O22 125.8(7) . . ?
O23 C62 C61 117.2(6) . . ?
O22 C62 C61 116.9(6) . . ?
C43 C47 C48 122.9(6) . . ?
C46 C47 C43 118.7(7) . . ?
C46 C47 C48 118.5(7) . . ?
N5 C32 H32 118.5 . . ?
N5 C32 C33 123.1(7) . . ?
C33 C32 H32 118.5 . . ?
C29 C28 H28 120.8 . . ?
C27 C28 H28 120.8 . . ?
C27 C28 C29 118.3(7) . . ?
C46 C45 H45 120.3 . . ?
C46 C45 C44 119.4(7) . . ?
C44 C45 H45 120.3 . . ?
N6 C29 C28 123.6(7) . . ?
N6 C29 H29 118.2 . . ?
C28 C29 H29 118.2 . . ?
C47 C46 H46 120.7 . . ?
C45 C46 C47 118.6(7) . . ?
C45 C46 H46 120.7 . . ?
O5 C13 C14 113.1(9) . . ?
O6 C13 O5 126.7(9) . . ?
O6 C13 C14 120.2(8) . . ?
C28 C27 H27 120.0 . . ?
C28 C27 C26 120.0(7) . . ?
C26 C27 H27 120.0 . . ?
N9 C54 C55 112.5(6) . . ?
N9 C54 C50 123.3(6) . . ?
C50 C54 C55 124.0(6) . . ?
C57 C58 H58 119.8 . . ?
C57 C58 C59 120.3(7) . . ?
C59 C58 H58 119.8 . . ?
C3 C4 H4 121.2 . . ?
C3 C4 C5 117.6(8) . . ?
C5 C4 H4 121.2 . . ?
N8 C42 C43 115.2(6) . . ?
N8 C42 C38 121.3(6) . . ?
C38 C42 C43 123.4(6) . . ?
C42 C38 C39 118.5(6) . . ?
C42 C38 C37 121.4(6) . . ?
C39 C38 C37 120.0(6) . . ?
C52 C51 H51 120.1 . . ?
C50 C51 C52 119.9(7) . . ?
C50 C51 H51 120.1 . . ?
C34 C33 H33 120.8 . . ?
C32 C33 C34 118.3(7) . . ?
C32 C33 H33 120.8 . . ?
N7 C44 C45 122.2(7) . . ?
N7 C44 H44 118.9 . . ?
C45 C44 H44 118.9 . . ?
O8 C24 O7 126.5(7) . . ?
O8 C24 C23 115.7(7) . . ?
O7 C24 C23 117.7(6) . . ?
C7 C11 C12 122.9(7) . . ?
C10 C11 C12 117.3(7) . . ?
C10 C11 C7 119.6(8) . . ?
C40 C39 C38 119.3(6) . . ?
C40 C39 H39 120.4 . . ?
C38 C39 H39 120.4 . . ?
O24 C61 O21 125.6(7) . . ?
O24 C61 C62 117.1(6) . . ?
O21 C61 C62 117.3(6) . . ?
O14 C37 Tb3 58.7(3) . 1_545 ?
O14 C37 O13 121.8(6) . . ?
O14 C37 C38 119.0(6) . . ?
O13 C37 Tb3 64.1(3) . 1_545 ?
O13 C37 C38 119.1(6) . . ?
C38 C37 Tb3 165.4(5) . 1_545 ?
O2 C1 O1 125.1(9) . . ?
O2 C1 C2 122.0(10) . . ?
O1 C1 C2 112.9(10) . . ?
N8 C41 C40 122.4(6) . . ?
N8 C41 H41 118.8 . . ?
C40 C41 H41 118.8 . . ?
N5 C31 C35 122.2(6) . . ?
N5 C31 C30 113.6(6) . . ?
C35 C31 C30 124.2(6) . . ?
N6 C30 C31 114.1(6) . . ?
N6 C30 C26 121.3(7) . . ?
C26 C30 C31 124.5(6) . . ?
N3 C17 C16 124.0(7) . . ?
N3 C17 H17 118.0 . . ?
C16 C17 H17 118.0 . . ?
O12 C36 Tb2 61.6(4) . . ?
O12 C36 C35 117.6(7) . . ?
O11 C36 Tb2 61.5(4) . . ?
O11 C36 O12 121.9(7) . . ?
O11 C36 C35 120.3(7) . . ?
C35 C36 Tb2 164.4(5) . . ?
C27 C26 C25 117.9(6) . . ?
C27 C26 C30 119.3(7) . . ?
C30 C26 C25 122.8(6) . . ?
N1 C5 C4 123.1(8) . . ?
N1 C5 H5 118.5 . . ?
C4 C5 H5 118.5 . . ?
C3 C2 C6 117.6(7) . . ?
C3 C2 C1 117.9(8) . . ?
C6 C2 C1 124.3(9) . . ?
O15 C48 Tb3 58.8(4) . 2_475 ?
O15 C48 C47 117.0(7) . . ?
O16 C48 Tb3 64.7(4) . 2_475 ?
O16 C48 O15 122.1(7) . . ?
O16 C48 C47 120.9(7) . . ?
C47 C48 Tb3 167.3(5) . 2_475 ?
O18 C60 O17 125.8(6) . . ?
O18 C60 C59 117.5(6) . . ?
O17 C60 C59 116.7(6) . . ?
C19 C23 C24 123.7(7) . . ?
C22 C23 C19 117.6(6) . . ?
C22 C23 C24 118.7(6) . . ?
C9 C10 H10 120.1 . . ?
C11 C10 C9 119.7(8) . . ?
C11 C10 H10 120.1 . . ?
C55 C59 C58 117.0(7) . . ?
C55 C59 C60 124.0(6) . . ?
C58 C59 C60 118.8(6) . . ?
C18 C14 C13 120.8(7) . . ?
C18 C14 C15 118.0(7) . . ?
C15 C14 C13 121.0(7) . . ?
C16 C15 H15 120.0 . . ?
C14 C15 C16 120.0(7) . . ?
C14 C15 H15 120.0 . . ?
N2 C8 C9 122.7(8) . . ?
N2 C8 H8 118.7 . . ?
C9 C8 H8 118.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Tb1 O4 C12 O3 27.0(12) . . . . ?
Tb1 O4 C12 C11 -147.7(5) . . . . ?
Tb1 O10 C25 O9 2.7(7) . . . . ?
Tb1 O10 C25 C26 -178.5(5) . . . . ?
Tb1 O21 C61 O24 170.8(5) . . . . ?
Tb1 O21 C61 C62 -10.0(8) . . . . ?
Tb1 O9 C25 O10 -2.8(7) . . . . ?
Tb1 O9 C25 C26 178.4(5) . . . . ?
Tb1 O7 C24 O8 2.5(13) . . . . ?
Tb1 O7 C24 C23 -173.8(5) . . . . ?
Tb1 O22 C62 O23 -156.5(6) . . . . ?
Tb1 O22 C62 C61 25.4(7) . . . . ?
Tb1 C25 C26 C27 59(11) . . . . ?
Tb1 C25 C26 C30 -120(11) . . . . ?
Tb3 O18 C60 O17 -0.6(10) 2_475 . . . ?
Tb3 O18 C60 C59 -178.7(4) 2_475 . . . ?
Tb3 O19 C49 O20 -2.1(7) . . . . ?
Tb3 O19 C49 C50 176.9(5) . . . . ?
Tb3 O14 C37 O13 -11.9(7) 1_545 . . . ?
Tb3 O14 C37 C38 163.3(5) 1_545 . . . ?
Tb3 O13 C37 O14 11.3(7) 1_545 . . . ?
Tb3 O13 C37 C38 -163.9(6) 1_545 . . . ?
Tb3 O20 C49 O19 1.9(6) . . . . ?
Tb3 O20 C49 C50 -177.0(6) . . . . ?
Tb3 O15 C48 O16 -14.2(7) 2_475 . . . ?
Tb3 O15 C48 C47 166.2(5) 2_475 . . . ?
Tb3 O16 C48 O15 13.5(7) 2_475 . . . ?
Tb3 O16 C48 C47 -167.0(6) 2_475 . . . ?
Tb3 C49 C50 C54 144(3) . . . . ?
Tb3 C49 C50 C51 -29(3) . . . . ?
Tb2 O12 C36 O11 12.6(8) . . . . ?
Tb2 O12 C36 C35 -162.3(6) . . . . ?
Tb2 O24 C61 O21 -164.5(5) 2_676 . . . ?
Tb2 O24 C61 C62 16.2(8) 2_676 . . . ?
Tb2 O5 C13 O6 15.2(11) 1_545 . . . ?
Tb2 O5 C13 C14 -166.7(4) 1_545 . . . ?
Tb2 O1 C1 O2 8.9(12) 2_676 . . . ?
Tb2 O1 C1 C2 -171.0(5) 2_676 . . . ?
Tb2 O11 C36 O12 -12.6(8) . . . . ?
Tb2 O11 C36 C35 162.2(6) . . . . ?
Tb2 O23 C62 O22 -178.6(5) 2_676 . . . ?
Tb2 O23 C62 C61 -0.5(8) 2_676 . . . ?
Ag3 N6 C29 C28 155.7(6) . . . . ?
Ag3 N6 C30 C31 23.8(8) . . . . ?
Ag3 N6 C30 C26 -152.2(5) . . . . ?
Ag3 N8 C42 C43 5.2(7) . . . . ?
Ag3 N8 C42 C38 -171.5(5) . . . . ?
Ag3 N8 C41 C40 173.9(5) . . . . ?
Ag3 N9 C53 C52 -171.3(5) . . . . ?
Ag3 N9 C54 C55 -12.3(7) . . . . ?
Ag3 N9 C54 C50 172.1(5) . . . . ?
Ag2 N7 C43 C47 -162.7(5) . . . . ?
Ag2 N7 C43 C42 12.8(8) . . . . ?
Ag2 N7 C44 C45 165.2(6) . . . . ?
Ag2 N3 C18 C19 -9.9(7) . . . . ?
Ag2 N3 C18 C14 176.6(5) . . . . ?
Ag2 N3 C17 C16 -177.2(5) . . . . ?
Ag2 N5 C32 C33 176.0(6) . . . . ?
Ag2 N5 C31 C35 -177.1(5) . . . . ?
Ag2 N5 C31 C30 0.7(7) . . . . ?
Ag1 N4 C20 C21 -166.6(6) 2_566 . . . ?
Ag1 N4 C19 C18 -15.4(8) 2_566 . . . ?
Ag1 N4 C19 C23 170.3(5) 2_566 . . . ?
Ag1 N2 C7 C6 -37.3(7) . . . . ?
Ag1 N2 C7 C11 141.1(6) . . . . ?
Ag1 N2 C8 C9 -141.2(7) . . . . ?
Ag1 N10 C55 C54 -55.9(6) 2_576 . . . ?
Ag1 N10 C55 C59 130.2(6) 2_576 . . . ?
Ag1 N10 C56 C57 -128.2(7) 2_576 . . . ?
Ag1 N1 C6 C7 -26.2(7) . . . . ?
Ag1 N1 C6 C2 151.1(5) . . . . ?
Ag1 N1 C5 C4 -157.0(6) . . . . ?
O12 Tb2 O11 C36 6.9(4) . . . . ?
O12 Tb2 C36 O11 -167.8(8) . . . . ?
O12 Tb2 C36 C35 91(2) . . . . ?
O2 C1 C2 C3 -154.6(8) . . . . ?
O2 C1 C2 C6 20.5(12) . . . . ?
O24 Tb2 O12 C36 -146.1(4) 2_676 . . . ?
O24 Tb2 O11 C36 148.3(4) 2_676 . . . ?
O24 Tb2 C36 O12 88.3(8) 2_676 . . . ?
O24 Tb2 C36 O11 -79.5(8) 2_676 . . . ?
O24 Tb2 C36 C35 179.5(16) 2_676 . . . ?
O31 Tb3 O19 C49 -101.6(4) . . . . ?
O31 Tb3 O20 C49 66.8(4) . . . . ?
O31 Tb3 C49 O19 71.5(4) . . . . ?
O31 Tb3 C49 O20 -110.4(4) . . . . ?
O31 Tb3 C49 C50 53(3) . . . . ?
O5 Tb2 O12 C36 -66.8(5) 1_565 . . . ?
O5 Tb2 O11 C36 129.9(5) 1_565 . . . ?
O5 Tb2 C36 O12 118.5(5) 1_565 . . . ?
O5 Tb2 C36 O11 -49.3(5) 1_565 . . . ?
O5 Tb2 C36 C35 -150(2) 1_565 . . . ?
O5 C13 C14 C18 169.9(6) . . . . ?
O5 C13 C14 C15 -6.7(10) . . . . ?
O1 Tb2 O12 C36 -153.7(5) 2_676 . . . ?
O1 Tb2 O11 C36 45.9(5) 2_676 . . . ?
O1 Tb2 C36 O12 26.5(5) 2_676 . . . ?
O1 Tb2 C36 O11 -141.4(5) 2_676 . . . ?
O1 Tb2 C36 C35 118(2) 2_676 . . . ?
O1 C1 C2 C3 25.4(10) . . . . ?
O1 C1 C2 C6 -159.6(7) . . . . ?
O25 Tb1 O4 C12 14.0(7) . . . . ?
O25 Tb1 O10 C25 9.7(5) . . . . ?
O25 Tb1 O21 C61 -125.9(5) . . . . ?
O25 Tb1 O9 C25 -170.2(4) . . . . ?
O25 Tb1 O7 C24 -150.8(7) . . . . ?
O25 Tb1 O22 C62 37.6(6) . . . . ?
O25 Tb1 C25 O10 -172.5(4) . . . . ?
O25 Tb1 C25 O9 10.1(4) . . . . ?
O25 Tb1 C25 C26 -22(11) . . . . ?
O18 Tb3 O19 C49 171.4(4) 2_475 . . . ?
O18 Tb3 O20 C49 -12.0(4) 2_475 . . . ?
O18 Tb3 C49 O19 -8.2(4) 2_475 . . . ?
O18 Tb3 C49 O20 169.9(4) 2_475 . . . ?
O18 Tb3 C49 C50 -27(3) 2_475 . . . ?
O18 C60 C59 C55 -3.1(10) . . . . ?
O18 C60 C59 C58 171.8(7) . . . . ?
O30 Tb3 O19 C49 88.7(4) . . . . ?
O30 Tb3 O20 C49 -79.9(4) . . . . ?
O30 Tb3 C49 O19 -84.1(4) . . . . ?
O30 Tb3 C49 O20 94.0(4) . . . . ?
O30 Tb3 C49 C50 -102(3) . . . . ?
O3 C12 C11 C7 32.3(11) . . . . ?
O3 C12 C11 C10 -142.6(8) . . . . ?
O27 Tb1 O4 C12 -138.6(7) . . . . ?
O27 Tb1 O10 C25 162.7(4) . . . . ?
O27 Tb1 O21 C61 88.1(5) . . . . ?
O27 Tb1 O9 C25 -17.4(5) . . . . ?
O27 Tb1 O7 C24 -3.6(7) . . . . ?
O27 Tb1 O22 C62 -110.9(5) . . . . ?
O27 Tb1 C25 O10 -17.0(4) . . . . ?
O27 Tb1 C25 O9 165.6(4) . . . . ?
O27 Tb1 C25 C26 133(11) . . . . ?
O19 Tb3 O20 C49 -1.1(4) . . . . ?
O19 Tb3 C49 O20 178.1(6) . . . . ?
O19 Tb3 C49 C50 -18(3) . . . . ?
O19 C49 C50 C54 126.8(7) . . . . ?
O19 C49 C50 C51 -46.2(9) . . . . ?
O4 Tb1 O10 C25 -61.0(4) . . . . ?
O4 Tb1 O21 C61 -54.2(5) . . . . ?
O4 Tb1 O9 C25 116.2(4) . . . . ?
O4 Tb1 O7 C24 155.1(6) . . . . ?
O4 Tb1 O22 C62 62.8(5) . . . . ?
O4 Tb1 C25 O10 118.9(4) . . . . ?
O4 Tb1 C25 O9 -58.5(4) . . . . ?
O4 Tb1 C25 C26 -91(11) . . . . ?
O4 C12 C11 C7 -152.5(7) . . . . ?
O4 C12 C11 C10 32.6(10) . . . . ?
O11 Tb2 O12 C36 -6.7(4) . . . . ?
O11 Tb2 C36 O12 167.8(8) . . . . ?
O11 Tb2 C36 C35 -101(2) . . . . ?
O23 Tb2 O12 C36 117.8(5) 2_676 . . . ?
O23 Tb2 O11 C36 -92.9(5) 2_676 . . . ?
O23 Tb2 C36 O12 -81.1(5) 2_676 . . . ?
O23 Tb2 C36 O11 111.1(4) 2_676 . . . ?
O23 Tb2 C36 C35 10(2) 2_676 . . . ?
O23 C62 C61 O24 -10.5(9) . . . . ?
O23 C62 C61 O21 170.2(6) . . . . ?
O10 Tb1 O4 C12 146.2(7) . . . . ?
O10 Tb1 O21 C61 30.1(6) . . . . ?
O10 Tb1 O9 C25 1.4(4) . . . . ?
O10 Tb1 O7 C24 74.0(7) . . . . ?
O10 Tb1 O22 C62 168.6(5) . . . . ?
O10 Tb1 C25 O9 -177.4(7) . . . . ?
O10 Tb1 C25 C26 150(11) . . . . ?
O10 C25 C26 C27 -151.2(6) . . . . ?
O10 C25 C26 C30 29.9(10) . . . . ?
O6 C13 C14 C18 -12.0(11) . . . . ?
O6 C13 C14 C15 171.5(7) . . . . ?
O14 Tb3 O19 C49 -42.0(4) 1_565 . . . ?
O14 Tb3 O20 C49 141.6(4) 1_565 . . . ?
O14 Tb3 C49 O19 143.9(4) 1_565 . . . ?
O14 Tb3 C49 O20 -38.0(4) 1_565 . . . ?
O14 Tb3 C49 C50 126(3) 1_565 . . . ?
O13 Tb3 O19 C49 21.4(4) 1_565 . . . ?
O13 Tb3 O20 C49 -163.8(4) 1_565 . . . ?
O13 Tb3 C49 O19 -162.2(4) 1_565 . . . ?
O13 Tb3 C49 O20 15.9(4) 1_565 . . . ?
O13 Tb3 C49 C50 179(100) 1_565 . . . ?
O20 Tb3 O19 C49 1.1(4) . . . . ?
O20 Tb3 C49 O19 -178.1(6) . . . . ?
O20 Tb3 C49 C50 164(3) . . . . ?
O20 C49 C50 C54 -54.2(9) . . . . ?
O20 C49 C50 C51 132.8(7) . . . . ?
O21 Tb1 O4 C12 -77.7(7) . . . . ?
O21 Tb1 O10 C25 -137.2(4) . . . . ?
O21 Tb1 O9 C25 120.1(4) . . . . ?
O21 Tb1 O7 C24 -68.6(7) . . . . ?
O21 Tb1 O22 C62 -21.7(5) . . . . ?
O21 Tb1 C25 O10 73.7(5) . . . . ?
O21 Tb1 C25 O9 -103.7(5) . . . . ?
O21 Tb1 C25 C26 -136(11) . . . . ?
O8 C24 C23 C19 -171.5(7) . . . . ?
O8 C24 C23 C22 8.6(11) . . . . ?
O29 Tb2 O12 C36 19.5(6) . . . . ?
O29 Tb2 O11 C36 -153.7(5) . . . . ?
O29 Tb2 C36 O12 -164.9(4) . . . . ?
O29 Tb2 C36 O11 27.3(5) . . . . ?
O29 Tb2 C36 C35 -74(2) . . . . ?
O15 Tb3 O19 C49 135.5(4) 2_475 . . . ?
O15 Tb3 O20 C49 -141.2(4) 2_475 . . . ?
O15 Tb3 C49 O19 -96.5(6) 2_475 . . . ?
O15 Tb3 C49 O20 81.6(6) 2_475 . . . ?
O15 Tb3 C49 C50 -115(3) 2_475 . . . ?
O17 C60 C59 C55 178.5(7) . . . . ?
O17 C60 C59 C58 -6.5(10) . . . . ?
O9 Tb1 O4 C12 100.2(7) . . . . ?
O9 Tb1 O10 C25 -1.4(4) . . . . ?
O9 Tb1 O21 C61 -57.9(6) . . . . ?
O9 Tb1 O7 C24 128.0(7) . . . . ?
O9 Tb1 O22 C62 125.6(5) . . . . ?
O9 Tb1 C25 O10 177.4(7) . . . . ?
O9 Tb1 C25 C26 -32(11) . . . . ?
O9 C25 C26 C27 27.7(9) . . . . ?
O9 C25 C26 C30 -151.3(7) . . . . ?
O26 Tb1 O4 C12 -34.7(8) . . . . ?
O26 Tb1 O10 C25 120.0(4) . . . . ?
O26 Tb1 O21 C61 163.1(5) . . . . ?
O26 Tb1 O9 C25 -120.4(4) . . . . ?
O26 Tb1 O7 C24 -79.0(7) . . . . ?
O26 Tb1 O22 C62 -56.8(5) . . . . ?
O26 Tb1 C25 O10 -91.8(5) . . . . ?
O26 Tb1 C25 O9 90.8(5) . . . . ?
O26 Tb1 C25 C26 58(11) . . . . ?
O7 Tb1 O4 C12 72.4(8) . . . . ?
O7 Tb1 O10 C25 80.7(4) . . . . ?
O7 Tb1 O21 C61 152.1(5) . . . . ?
O7 Tb1 O9 C25 -81.3(4) . . . . ?
O7 Tb1 O22 C62 -154.4(4) . . . . ?
O7 Tb1 C25 O10 -91.6(4) . . . . ?
O7 Tb1 C25 O9 91.0(4) . . . . ?
O7 Tb1 C25 C26 59(11) . . . . ?
O7 C24 C23 C19 5.2(11) . . . . ?
O7 C24 C23 C22 -174.7(7) . . . . ?
O22 Tb1 O4 C12 -147.3(7) . . . . ?
O22 Tb1 O10 C25 -123.5(4) . . . . ?
O22 Tb1 O21 C61 15.9(5) . . . . ?
O22 Tb1 O9 C25 56.5(4) . . . . ?
O22 Tb1 O7 C24 37.8(8) . . . . ?
O22 Tb1 C25 O10 52.3(4) . . . . ?
O22 Tb1 C25 O9 -125.1(4) . . . . ?
O22 Tb1 C25 C26 -157(11) . . . . ?
O22 C62 C61 O24 167.8(6) . . . . ?
O22 C62 C61 O21 -11.6(9) . . . . ?
O28 Tb2 O12 C36 70.2(5) . . . . ?
O28 Tb2 O11 C36 -75.4(5) . . . . ?
O28 Tb2 C36 O12 -99.0(5) . . . . ?
O28 Tb2 C36 O11 93.2(5) . . . . ?
O28 Tb2 C36 C35 -8(2) . . . . ?
O16 Tb3 O19 C49 -146.6(4) 2_475 . . . ?
O16 Tb3 O20 C49 101.2(5) 2_475 . . . ?
O16 Tb3 C49 O19 54.5(5) 2_475 . . . ?
O16 Tb3 C49 O20 -127.4(4) 2_475 . . . ?
O16 Tb3 C49 C50 36(3) 2_475 . . . ?
N4 Ag1 N2 C7 -120.6(5) 2_566 . . . ?
N4 Ag1 N2 C8 23.0(8) 2_566 . . . ?
N4 Ag1 N1 C6 148.7(5) 2_566 . . . ?
N4 Ag1 N1 C5 -55.2(6) 2_566 . . . ?
N4 C20 C21 C22 -2.9(12) . . . . ?
N4 C19 C23 C22 -4.1(11) . . . . ?
N4 C19 C23 C24 176.0(7) . . . . ?
N7 Ag2 N3 C18 128.1(5) . . . . ?
N7 Ag2 N3 C17 -55.0(6) . . . . ?
N7 Ag2 N5 C32 -96.2(6) . . . . ?
N7 Ag2 N5 C31 80.2(5) . . . . ?
N7 C43 C47 C46 -0.4(10) . . . . ?
N7 C43 C47 C48 -179.5(6) . . . . ?
N7 C43 C42 N8 -87.9(7) . . . . ?
N7 C43 C42 C38 88.7(8) . . . . ?
N3 Ag2 N7 C43 -163.5(5) . . . . ?
N3 Ag2 N7 C44 30.8(5) . . . . ?
N3 Ag2 N5 C32 105.5(6) . . . . ?
N3 Ag2 N5 C31 -78.1(5) . . . . ?
N3 C18 C19 N4 -78.3(7) . . . . ?
N3 C18 C19 C23 95.9(8) . . . . ?
N3 C18 C14 C13 -177.3(6) . . . . ?
N3 C18 C14 C15 -0.7(10) . . . . ?
N6 Ag3 N8 C42 80.3(5) . . . . ?
N6 Ag3 N8 C41 -94.1(6) . . . . ?
N6 Ag3 N9 C53 -61.3(6) . . . . ?
N6 Ag3 N9 C54 127.3(4) . . . . ?
N6 C30 C26 C25 178.3(6) . . . . ?
N6 C30 C26 C27 -0.6(10) . . . . ?
N8 Ag3 N6 C29 -131.7(5) . . . . ?
N8 Ag3 N6 C30 24.8(7) . . . . ?
N8 Ag3 N9 C53 98.2(6) . . . . ?
N8 Ag3 N9 C54 -73.3(5) . . . . ?
N8 C42 C38 C39 -3.1(10) . . . . ?
N8 C42 C38 C37 -177.7(6) . . . . ?
N5 Ag2 N7 C43 36.0(6) . . . . ?
N5 Ag2 N7 C44 -129.7(5) . . . . ?
N5 Ag2 N3 C18 -71.6(5) . . . . ?
N5 Ag2 N3 C17 105.2(5) . . . . ?
N5 C32 C33 C34 0.3(12) . . . . ?
N5 C31 C30 N6 -90.7(7) . . . . ?
N5 C31 C30 C26 85.2(8) . . . . ?
N2 Ag1 N1 C6 5.8(5) . . . . ?
N2 Ag1 N1 C5 161.9(6) . . . . ?
N2 C7 C6 N1 43.7(9) . . . . ?
N2 C7 C6 C2 -133.5(8) . . . . ?
N2 C7 C11 C12 -171.6(7) . . . . ?
N2 C7 C11 C10 3.2(11) . . . . ?
N10 Ag1 N2 C7 155.8(5) 2_576 . . . ?
N10 Ag1 N2 C8 -60.7(6) 2_576 . . . ?
N10 Ag1 N1 C6 -58.6(6) 2_576 . . . ?
N10 Ag1 N1 C5 97.5(6) 2_576 . . . ?
N10 C55 C54 N9 -72.5(7) . . . . ?
N10 C55 C54 C50 103.0(8) . . . . ?
N10 C55 C59 C58 -1.0(11) . . . . ?
N10 C55 C59 C60 174.0(7) . . . . ?
N10 C56 C57 C58 -2.0(12) . . . . ?
N1 Ag1 N2 C7 17.4(5) . . . . ?
N1 Ag1 N2 C8 161.0(6) . . . . ?
N1 C6 C2 C3 7.3(11) . . . . ?
N1 C6 C2 C1 -167.7(7) . . . . ?
N9 Ag3 N6 C29 27.3(5) . . . . ?
N9 Ag3 N6 C30 -176.2(5) . . . . ?
N9 Ag3 N8 C42 -75.2(5) . . . . ?
N9 Ag3 N8 C41 110.3(6) . . . . ?
N9 C53 C52 C51 1.9(10) . . . . ?
C12 C11 C10 C9 174.0(7) . . . . ?
C55 N10 C56 C57 2.0(11) . . . . ?
C25 Tb1 O4 C12 123.4(7) . . . . ?
C25 Tb1 O21 C61 -7.6(7) . . . . ?
C25 Tb1 O7 C24 101.1(7) . . . . ?
C25 Tb1 O22 C62 147.0(5) . . . . ?
C34 C35 C31 N5 1.4(11) . . . . ?
C34 C35 C31 C30 -176.2(7) . . . . ?
C34 C35 C36 Tb2 -96(2) . . . . ?
C34 C35 C36 O12 -13.7(11) . . . . ?
C34 C35 C36 O11 171.3(7) . . . . ?
C20 N4 C19 C18 176.0(6) . . . . ?
C20 N4 C19 C23 1.7(11) . . . . ?
C20 C21 C22 C23 0.3(12) . . . . ?
C18 N3 C17 C16 -0.4(10) . . . . ?
C18 C19 C23 C22 -177.8(7) . . . . ?
C18 C19 C23 C24 2.3(12) . . . . ?
C18 C14 C15 C16 2.7(10) . . . . ?
C7 N2 C8 C9 -1.0(12) . . . . ?
C7 C6 C2 C3 -175.7(7) . . . . ?
C7 C6 C2 C1 9.2(12) . . . . ?
C7 C11 C10 C9 -1.1(12) . . . . ?
C43 N7 C44 C45 -1.7(10) . . . . ?
C43 C47 C46 C45 -1.8(10) . . . . ?
C43 C47 C48 Tb3 -104(2) . . . 2_475 ?
C43 C47 C48 O15 -171.1(6) . . . . ?
C43 C47 C48 O16 9.3(10) . . . . ?
C43 C42 C38 C39 -179.5(6) . . . . ?
C43 C42 C38 C37 5.8(10) . . . . ?
C56 N10 C55 C54 173.5(6) . . . . ?
C56 N10 C55 C59 -0.4(11) . . . . ?
C56 C57 C58 C59 0.4(11) . . . . ?
C53 N9 C54 C55 175.1(6) . . . . ?
C53 N9 C54 C50 -0.4(10) . . . . ?
C53 C52 C51 C50 -2.9(10) . . . . ?
C3 C4 C5 N1 4.6(12) . . . . ?
C49 C50 C54 N9 -173.7(6) . . . . ?
C49 C50 C54 C55 11.3(10) . . . . ?
C49 C50 C51 C52 175.6(6) . . . . ?
C57 C58 C59 C55 1.0(11) . . . . ?
C57 C58 C59 C60 -174.3(7) . . . . ?
C21 C22 C23 C19 3.0(11) . . . . ?
C21 C22 C23 C24 -177.1(7) . . . . ?
C19 N4 C20 C21 1.9(11) . . . . ?
C19 C18 C14 C13 10.0(10) . . . . ?
C19 C18 C14 C15 -173.3(6) . . . . ?
C35 C34 C33 C32 0.6(12) . . . . ?
C35 C31 C30 N6 87.0(8) . . . . ?
C35 C31 C30 C26 -97.1(9) . . . . ?
C6 N1 C5 C4 -1.2(11) . . . . ?
C6 C7 C11 C12 6.7(12) . . . . ?
C6 C7 C11 C10 -178.5(7) . . . . ?
C47 C43 C42 N8 87.5(8) . . . . ?
C47 C43 C42 C38 -95.9(9) . . . . ?
C32 N5 C31 C35 -0.5(10) . . . . ?
C32 N5 C31 C30 177.3(6) . . . . ?
C28 C27 C26 C25 178.7(7) . . . . ?
C28 C27 C26 C30 -2.3(11) . . . . ?
C29 N6 C30 C31 179.3(6) . . . . ?
C29 N6 C30 C26 3.2(10) . . . . ?
C29 C28 C27 C26 2.4(11) . . . . ?
C46 C47 C48 Tb3 77(2) . . . 2_475 ?
C46 C47 C48 O15 9.7(10) . . . . ?
C46 C47 C48 O16 -169.9(6) . . . . ?
C46 C45 C44 N7 -0.4(12) . . . . ?
C13 C14 C15 C16 179.3(7) . . . . ?
C27 C28 C29 N6 0.3(11) . . . . ?
C54 N9 C53 C52 -0.3(10) . . . . ?
C54 C55 C59 C58 -174.2(7) . . . . ?
C54 C55 C59 C60 0.8(11) . . . . ?
C54 C50 C51 C52 2.3(10) . . . . ?
C4 C3 C2 C6 -3.8(11) . . . . ?
C4 C3 C2 C1 171.6(7) . . . . ?
C42 N8 C41 C40 -0.4(10) . . . . ?
C42 C43 C47 C46 -175.5(6) . . . . ?
C42 C43 C47 C48 5.3(10) . . . . ?
C42 C38 C39 C40 0.1(11) . . . . ?
C42 C38 C37 Tb3 92(2) . . . 1_545 ?
C42 C38 C37 O14 14.8(10) . . . . ?
C42 C38 C37 O13 -169.9(6) . . . . ?
C51 C50 C54 N9 -0.6(10) . . . . ?
C51 C50 C54 C55 -175.6(6) . . . . ?
C33 C34 C35 C31 -1.4(11) . . . . ?
C33 C34 C35 C36 173.4(7) . . . . ?
C44 N7 C43 C47 2.1(10) . . . . ?
C44 N7 C43 C42 177.6(6) . . . . ?
C44 C45 C46 C47 2.2(11) . . . . ?
C11 C7 C6 N1 -134.7(7) . . . . ?
C11 C7 C6 C2 48.1(11) . . . . ?
C39 C40 C41 N8 -2.6(11) . . . . ?
C39 C38 C37 Tb3 -83(2) . . . 1_545 ?
C39 C38 C37 O14 -159.8(7) . . . . ?
C39 C38 C37 O13 15.5(10) . . . . ?
C37 Tb3 O19 C49 -12.0(5) 1_565 . . . ?
C37 Tb3 O20 C49 168.6(4) 1_565 . . . ?
C37 Tb3 C49 O19 170.4(4) 1_565 . . . ?
C37 Tb3 C49 O20 -11.5(4) 1_565 . . . ?
C37 Tb3 C49 C50 152(3) 1_565 . . . ?
C37 C38 C39 C40 174.8(7) . . . . ?
C41 N8 C42 C43 180.0(6) . . . . ?
C41 N8 C42 C38 3.3(10) . . . . ?
C41 C40 C39 C38 2.7(11) . . . . ?
C31 N5 C32 C33 -0.4(11) . . . . ?
C31 C35 C36 Tb2 78(2) . . . . ?
C31 C35 C36 O12 161.0(7) . . . . ?
C31 C35 C36 O11 -14.1(11) . . . . ?
C31 C30 C26 C25 2.7(10) . . . . ?
C31 C30 C26 C27 -176.3(6) . . . . ?
C30 N6 C29 C28 -3.1(10) . . . . ?
C17 N3 C18 C19 173.0(6) . . . . ?
C17 N3 C18 C14 -0.5(10) . . . . ?
C17 C16 C15 C14 -3.4(10) . . . . ?
C36 C35 C31 N5 -173.2(7) . . . . ?
C36 C35 C31 C30 9.2(11) . . . . ?
C5 N1 C6 C7 177.7(6) . . . . ?
C5 N1 C6 C2 -5.0(10) . . . . ?
C2 C3 C4 C5 -1.9(12) . . . . ?
C48 Tb3 O19 C49 -178.8(4) 2_475 . . . ?
C48 Tb3 O20 C49 178.5(7) 2_475 . . . ?
C48 Tb3 C49 O19 3.8(12) 2_475 . . . ?
C48 Tb3 C49 O20 -178.1(9) 2_475 . . . ?
C48 Tb3 C49 C50 -15(4) 2_475 . . . ?
C48 C47 C46 C45 177.4(7) . . . . ?
C10 C9 C8 N2 3.0(12) . . . . ?
C59 C55 C54 N9 101.4(8) . . . . ?
C59 C55 C54 C50 -83.1(9) . . . . ?
C14 C18 C19 N4 95.0(8) . . . . ?
C14 C18 C19 C23 -90.8(9) . . . . ?
C15 C16 C17 N3 2.4(11) . . . . ?
C8 N2 C7 C6 179.4(7) . . . . ?
C8 N2 C7 C11 -2.1(11) . . . . ?
C8 C9 C10 C11 -1.9(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
