# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1539552'
_audit_update_record             
;
2017-03-22 deposited with the CCDC.
2017-05-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C36 H36 K Mo N6 O18 Sb'
_chemical_formula_weight         1097.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   18.241(13)
_cell_length_b                   15.645(10)
_cell_length_c                   14.448(11)
_cell_angle_alpha                90.00
_cell_angle_beta                 114.629(13)
_cell_angle_gamma                90.00
_cell_volume                     3748(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    18901
_cell_measurement_theta_min      2.0241
_cell_measurement_theta_max      27.4045

_exptl_crystal_description       plate
_exptl_crystal_colour            black
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    0.972
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1100
_exptl_absorpt_coefficient_mu    0.630
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.6078
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_detector_area_resol_mean 28.571
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            30433
_diffrn_reflns_av_R_equivalents  0.0554
_diffrn_reflns_av_sigmaI/netI    0.0972
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.00
_diffrn_reflns_theta_max         27.36
_reflns_number_total             8366
_reflns_number_gt                3096
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    Diamond
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8366
_refine_ls_number_parameters     393
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1259
_refine_ls_R_factor_gt           0.0485
_refine_ls_wR_factor_ref         0.1703
_refine_ls_wR_factor_gt          0.1184
_refine_ls_goodness_of_fit_ref   0.679
_refine_ls_restrained_S_all      0.679
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.07408(4) 0.88226(4) 0.57559(4) 0.0824(2) Uani 1 1 d . . .
Sb2 Sb 0.12906(4) 1.04460(4) 0.58634(4) 0.0881(2) Uani 1 1 d . . .
Sb3 Sb 0.03162(8) 0.94462(10) 0.26921(9) 0.0930(4) Uani 0.50 1 d P . .
Sb4 Sb 0.05849(8) 1.09488(9) 0.37773(12) 0.0861(4) Uani 0.50 1 d P . .
Sb5 Sb -0.02747(7) 0.84939(8) 0.38067(8) 0.0753(3) Uani 0.50 1 d P . .
Mo1 Mo 0.02771(7) 0.98292(8) 0.37759(8) 0.0554(3) Uani 0.50 1 d P . .
K1 K -0.5000 1.0000 -0.5000 0.0960(9) Uani 1 2 d S . .
K2 K -0.20092(17) 1.02802(15) 0.1081(3) 0.1316(10) Uani 1 1 d . . .
C1 C 0.0981(10) 0.8998(11) 0.3567(9) 0.074(5) Uani 0.50 1 d P . .
O1 O 0.1423(7) 0.8573(7) 0.3391(8) 0.082(3) Uani 0.50 1 d P . .
C2 C -0.0435(8) 0.9478(16) 0.2547(15) 0.112(8) Uani 0.50 1 d P . .
O2 O -0.0846(8) 0.9072(9) 0.1654(8) 0.111(5) Uani 0.50 1 d P . .
C3 C 0.0596(18) 1.0695(18) 0.3173(19) 0.142(13) Uani 0.50 1 d P . .
O3 O 0.0936(8) 1.1339(8) 0.2943(9) 0.100(4) Uani 0.50 1 d P . .
O4 O -0.4042(4) 1.0969(4) -0.5740(5) 0.0946(18) Uani 1 1 d . . .
O5 O -0.3355(4) 0.9666(4) -0.4220(5) 0.0976(18) Uani 1 1 d . . .
O6 O -0.4368(4) 0.8489(4) -0.3859(5) 0.0974(18) Uani 1 1 d . . .
O7 O -0.1421(5) 1.1883(5) 0.0573(6) 0.122(3) Uani 1 1 d . . .
O8 O -0.2383(6) 1.1848(5) 0.1630(6) 0.131(3) Uani 1 1 d . . .
O9 O -0.1243(5) 1.0368(5) -0.0308(6) 0.117(2) Uani 1 1 d . . .
O10 O -0.2367(5) 0.9033(4) -0.0612(6) 0.114(2) Uani 1 1 d . . .
O11 O -0.3242(5) 0.8993(5) 0.0619(6) 0.115(2) Uani 1 1 d . . .
O12 O -0.3551(5) 1.0569(6) 0.1265(6) 0.116(2) Uani 1 1 d . . .
C4 C -0.4314(8) 1.1825(7) -0.5993(8) 0.111(3) Uani 1 1 d . . .
H1A H -0.4015 1.2103 -0.6328 0.134 Uiso 1 1 calc R . .
H1B H -0.4227 1.2143 -0.5379 0.134 Uiso 1 1 calc R . .
C5 C -0.3205(7) 1.0917(8) -0.5123(8) 0.108(3) Uani 1 1 d . . .
H2A H -0.3074 1.1259 -0.4515 0.130 Uiso 1 1 calc R . .
H2B H -0.2911 1.1148 -0.5492 0.130 Uiso 1 1 calc R . .
C6 C -0.2953(6) 1.0017(8) -0.4828(9) 0.112(3) Uani 1 1 d . . .
H3A H -0.3087 0.9674 -0.5436 0.134 Uiso 1 1 calc R . .
H3B H -0.2373 0.9994 -0.4437 0.134 Uiso 1 1 calc R . .
C7 C -0.3111(7) 0.8818(7) -0.3882(9) 0.118(4) Uani 1 1 d . . .
H4A H -0.2531 0.8804 -0.3488 0.142 Uiso 1 1 calc R . .
H4B H -0.3242 0.8445 -0.4466 0.142 Uiso 1 1 calc R . .
C8 C -0.3513(8) 0.8509(7) -0.3254(8) 0.116(4) Uani 1 1 d . . .
H5A H -0.3321 0.7941 -0.3002 0.140 Uiso 1 1 calc R . .
H5B H -0.3390 0.8885 -0.2675 0.140 Uiso 1 1 calc R . .
C9 C -0.4804(8) 0.8188(7) -0.3311(8) 0.113(3) Uani 1 1 d . . .
H6A H -0.4709 0.8559 -0.2735 0.136 Uiso 1 1 calc R . .
H6B H -0.4624 0.7616 -0.3056 0.136 Uiso 1 1 calc R . .
C10 C -0.3379(10) 1.1175(10) 0.2025(10) 0.155(6) Uani 1 1 d . . .
H7A H -0.2963 1.0959 0.2654 0.186 Uiso 1 1 calc R . .
H7B H -0.3858 1.1285 0.2139 0.186 Uiso 1 1 calc R . .
C11 C -0.3103(12) 1.1974(10) 0.1738(11) 0.170(7) Uani 1 1 d . . .
H8A H -0.3515 1.2182 0.1101 0.204 Uiso 1 1 calc R . .
H8B H -0.3021 1.2404 0.2256 0.204 Uiso 1 1 calc R . .
C12 C -0.2004(12) 1.2594(8) 0.1512(10) 0.158(6) Uani 1 1 d . . .
H9A H -0.1896 1.2969 0.2090 0.190 Uiso 1 1 calc R . .
H9B H -0.2362 1.2893 0.0903 0.190 Uiso 1 1 calc R . .
C13 C -0.1260(9) 1.2403(9) 0.1437(10) 0.147(6) Uani 1 1 d . . .
H10A H -0.1002 1.2929 0.1377 0.177 Uiso 1 1 calc R . .
H10B H -0.0898 1.2107 0.2046 0.177 Uiso 1 1 calc R . .
C14 C -0.0709(10) 1.1704(9) 0.0430(9) 0.145(5) Uani 1 1 d . . .
H11A H -0.0318 1.1418 0.1027 0.174 Uiso 1 1 calc R . .
H11B H -0.0472 1.2234 0.0337 0.174 Uiso 1 1 calc R . .
C15 C -0.0916(7) 1.1146(7) -0.0487(9) 0.115(3) Uani 1 1 d . . .
H12A H -0.1307 1.1429 -0.1086 0.138 Uiso 1 1 calc R . .
H12B H -0.0436 1.1030 -0.0598 0.138 Uiso 1 1 calc R . .
C16 C -0.1455(8) 0.9788(9) -0.1098(11) 0.132(4) Uani 1 1 d . . .
H13A H -0.1009 0.9709 -0.1289 0.158 Uiso 1 1 calc R . .
H13B H -0.1913 1.0004 -0.1686 0.158 Uiso 1 1 calc R . .
C17 C -0.1669(9) 0.8953(8) -0.0771(11) 0.143(5) Uani 1 1 d . . .
H14A H -0.1751 0.8525 -0.1291 0.172 Uiso 1 1 calc R . .
H14B H -0.1228 0.8765 -0.0148 0.172 Uiso 1 1 calc R . .
C18 C -0.2582(9) 0.8280(7) -0.0256(10) 0.134(4) Uani 1 1 d . . .
H15A H -0.2173 0.8143 0.0416 0.160 Uiso 1 1 calc R . .
H15B H -0.2613 0.7809 -0.0708 0.160 Uiso 1 1 calc R . .
C19 C -0.3372(8) 0.8390(8) -0.0207(10) 0.132(4) Uani 1 1 d . . .
H16A H -0.3768 0.8613 -0.0847 0.158 Uiso 1 1 calc R . .
H16B H -0.3565 0.7847 -0.0071 0.158 Uiso 1 1 calc R . .
C20 C -0.3948(8) 0.9151(10) 0.0720(10) 0.135(4) Uani 1 1 d . . .
H5C H -0.4150 0.8623 0.0875 0.162 Uiso 1 1 calc R . .
H5D H -0.4350 0.9371 0.0083 0.162 Uiso 1 1 calc R . .
C21 C -0.3480(13) 1.1402(14) -0.1339(15) 0.209(8) Uiso 1 1 d . . .
H20A H -0.3152 1.0901 -0.1046 0.251 Uiso 1 1 calc R . .
H20B H -0.3153 1.1909 -0.1076 0.251 Uiso 1 1 calc R . .
N1 N -0.4433(11) 1.0762(12) -0.2940(14) 0.243(7) Uani 1 1 d . . .
N2 N -0.4146(13) 1.1416(15) -0.1121(12) 0.331(14) Uani 1 1 d . . .
C22 C -0.3809(8) 0.9781(10) 0.1544(10) 0.134(5) Uani 1 1 d . . .
H18A H -0.4303 0.9870 0.1631 0.161 Uiso 1 1 calc R . .
H18B H -0.3399 0.9571 0.2181 0.161 Uiso 1 1 calc R . .
C23 C -0.3835(14) 1.1377(15) -0.2541(17) 0.255(10) Uiso 1 1 d . . .
H19A H -0.4057 1.1933 -0.2811 0.306 Uiso 1 1 calc R . .
H19B H -0.3405 1.1253 -0.2749 0.306 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Sb5 2.698(2) . ?
Sb1 Sb2 2.7111(17) . ?
Sb1 Sb4 2.791(2) 3_576 ?
Sb1 Mo1 3.060(2) . ?
Sb1 Mo1 3.0661(18) 3_576 ?
Sb2 Sb5 2.6735(17) 3_576 ?
Sb2 Sb4 2.851(3) . ?
Sb2 Mo1 2.966(2) . ?
Sb2 Mo1 3.143(2) 3_576 ?
Sb3 C2 1.298(13) . ?
Sb3 C1 1.511(13) . ?
Sb3 Mo1 1.7057(19) . ?
Sb3 C3 2.06(3) . ?
Sb3 O2 2.107(13) . ?
Sb3 O1 2.294(11) . ?
Sb3 Sb5 2.724(2) . ?
Sb3 Sb4 2.754(3) . ?
Sb3 K2 4.109(4) . ?
Sb4 C3 0.97(3) . ?
Sb4 O3 1.697(11) . ?
Sb4 Mo1 1.839(2) . ?
Sb4 Sb1 2.791(2) 3_576 ?
Sb5 C2 2.307(16) . ?
Sb5 Mo1 2.327(2) . ?
Sb5 C1 2.579(19) . ?
Sb5 Sb2 2.6735(17) 3_576 ?
Mo1 C2 1.79(2) . ?
Mo1 C3 1.83(3) . ?
Mo1 C1 1.938(15) . ?
Mo1 Sb1 3.0661(19) 3_576 ?
Mo1 Sb2 3.143(2) 3_576 ?
K1 O5 2.780(7) 3_474 ?
K1 O5 2.780(7) . ?
K1 O6 2.837(7) . ?
K1 O6 2.837(7) 3_474 ?
K1 O4 2.837(6) . ?
K1 O4 2.837(6) 3_474 ?
K1 N1 2.963(18) . ?
K1 N1 2.963(18) 3_474 ?
K2 O2 2.701(14) . ?
K2 O8 2.750(9) . ?
K2 O11 2.883(8) . ?
K2 O9 2.888(9) . ?
K2 O7 2.939(8) . ?
K2 O12 2.968(8) . ?
K2 O10 2.981(8) . ?
K2 C2 3.040(14) . ?
C1 O1 1.151(16) . ?
C2 O2 1.35(2) . ?
C3 O3 1.30(3) . ?
O4 C5 1.414(12) . ?
O4 C4 1.422(12) . ?
O5 C7 1.419(11) . ?
O5 C6 1.467(11) . ?
O6 C9 1.415(11) . ?
O6 C8 1.436(12) . ?
O7 C13 1.414(15) . ?
O7 C14 1.425(16) . ?
O8 C11 1.400(17) . ?
O8 C12 1.403(15) . ?
O9 C16 1.381(14) . ?
O9 C15 1.425(11) . ?
O10 C17 1.391(14) . ?
O10 C18 1.405(12) . ?
O11 C20 1.376(13) . ?
O11 C19 1.461(13) . ?
O12 C10 1.383(14) . ?
O12 C22 1.437(14) . ?
C4 C9 1.501(13) 3_474 ?
C5 C6 1.488(14) . ?
C7 C8 1.466(14) . ?
C9 C4 1.501(13) 3_474 ?
C10 C11 1.470(18) . ?
C12 C13 1.438(18) . ?
C14 C15 1.497(15) . ?
C16 C17 1.495(16) . ?
C18 C19 1.483(16) . ?
C20 C22 1.484(16) . ?
C21 N2 1.38(3) . ?
C21 C23 1.58(2) . ?
N1 C23 1.39(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Sb5 Sb1 Sb2 108.36(4) . . ?
Sb5 Sb1 Sb4 89.40(7) . 3_576 ?
Sb2 Sb1 Sb4 101.72(4) . 3_576 ?
Sb5 Sb1 Mo1 47.17(5) . . ?
Sb2 Sb1 Mo1 61.51(4) . . ?
Sb4 Sb1 Mo1 103.31(5) 3_576 . ?
Sb5 Sb1 Mo1 98.39(5) . 3_576 ?
Sb2 Sb1 Mo1 65.58(5) . 3_576 ?
Sb4 Sb1 Mo1 36.22(4) 3_576 3_576 ?
Mo1 Sb1 Mo1 84.00(5) . 3_576 ?
Sb5 Sb2 Sb1 108.91(6) 3_576 . ?
Sb5 Sb2 Sb4 88.63(6) 3_576 . ?
Sb1 Sb2 Sb4 101.81(4) . . ?
Sb5 Sb2 Mo1 101.45(5) 3_576 . ?
Sb1 Sb2 Mo1 65.04(4) . . ?
Sb4 Sb2 Mo1 36.79(5) . . ?
Sb5 Sb2 Mo1 46.31(5) 3_576 3_576 ?
Sb1 Sb2 Mo1 62.66(3) . 3_576 ?
Sb4 Sb2 Mo1 99.90(5) . 3_576 ?
Mo1 Sb2 Mo1 84.23(6) . 3_576 ?
C2 Sb3 C1 125.3(10) . . ?
C2 Sb3 Mo1 71.9(11) . . ?
C1 Sb3 Mo1 73.8(5) . . ?
C2 Sb3 C3 96.6(14) . . ?
C1 Sb3 C3 99.1(9) . . ?
Mo1 Sb3 C3 57.2(6) . . ?
C2 Sb3 O2 38.2(12) . . ?
C1 Sb3 O2 133.3(8) . . ?
Mo1 Sb3 O2 109.7(4) . . ?
C3 Sb3 O2 122.5(8) . . ?
C2 Sb3 O1 140.3(9) . . ?
C1 Sb3 O1 26.2(6) . . ?
Mo1 Sb3 O1 99.8(3) . . ?
C3 Sb3 O1 111.5(8) . . ?
O2 Sb3 O1 126.0(5) . . ?
C2 Sb3 Sb5 57.7(7) . . ?
C1 Sb3 Sb5 68.2(7) . . ?
Mo1 Sb3 Sb5 58.07(7) . . ?
C3 Sb3 Sb5 114.9(6) . . ?
O2 Sb3 Sb5 74.9(4) . . ?
O1 Sb3 Sb5 84.6(3) . . ?
C2 Sb3 Sb4 89.1(12) . . ?
C1 Sb3 Sb4 91.7(6) . . ?
Mo1 Sb3 Sb4 40.80(6) . . ?
C3 Sb3 Sb4 16.4(6) . . ?
O2 Sb3 Sb4 122.0(4) . . ?
O1 Sb3 Sb4 110.0(3) . . ?
Sb5 Sb3 Sb4 98.66(7) . . ?
C2 Sb3 K2 29.0(7) . . ?
C1 Sb3 K2 154.2(7) . . ?
Mo1 Sb3 K2 88.88(9) . . ?
C3 Sb3 K2 86.7(7) . . ?
O2 Sb3 K2 35.9(4) . . ?
O1 Sb3 K2 161.8(3) . . ?
Sb5 Sb3 K2 86.52(7) . . ?
Sb4 Sb3 K2 87.04(6) . . ?
C3 Sb4 O3 49.5(19) . . ?
C3 Sb4 Mo1 74.3(17) . . ?
O3 Sb4 Mo1 123.2(4) . . ?
C3 Sb4 Sb3 37.0(17) . . ?
O3 Sb4 Sb3 86.2(4) . . ?
Mo1 Sb4 Sb3 37.31(6) . . ?
C3 Sb4 Sb1 128.1(19) . 3_576 ?
O3 Sb4 Sb1 138.3(4) . 3_576 ?
Mo1 Sb4 Sb1 80.07(6) . 3_576 ?
Sb3 Sb4 Sb1 106.29(6) . 3_576 ?
C3 Sb4 Sb2 132.1(11) . . ?
O3 Sb4 Sb2 135.4(5) . . ?
Mo1 Sb4 Sb2 75.02(6) . . ?
Sb3 Sb4 Sb2 105.15(7) . . ?
Sb1 Sb4 Sb2 80.49(6) 3_576 . ?
C2 Sb5 Mo1 45.6(6) . . ?
C2 Sb5 C1 61.2(4) . . ?
Mo1 Sb5 C1 46.2(4) . . ?
C2 Sb5 Sb2 81.8(5) . 3_576 ?
Mo1 Sb5 Sb2 77.53(6) . 3_576 ?
C1 Sb5 Sb2 123.7(4) . 3_576 ?
C2 Sb5 Sb1 120.2(6) . . ?
Mo1 Sb5 Sb1 74.61(5) . . ?
C1 Sb5 Sb1 79.6(3) . . ?
Sb2 Sb5 Sb1 85.47(5) 3_576 . ?
C2 Sb5 Sb3 28.4(3) . . ?
Mo1 Sb5 Sb3 38.46(5) . . ?
C1 Sb5 Sb3 33.0(3) . . ?
Sb2 Sb5 Sb3 103.92(7) 3_576 . ?
Sb1 Sb5 Sb3 104.13(7) . . ?
Sb3 Mo1 C2 43.4(5) . . ?
Sb3 Mo1 C3 71.3(9) . . ?
C2 Mo1 C3 89.9(12) . . ?
Sb3 Mo1 Sb4 101.89(9) . . ?
C2 Mo1 Sb4 112.8(6) . . ?
C3 Mo1 Sb4 30.6(9) . . ?
Sb3 Mo1 C1 48.5(4) . . ?
C2 Mo1 C1 83.9(7) . . ?
C3 Mo1 C1 93.4(9) . . ?
Sb4 Mo1 C1 114.7(6) . . ?
Sb3 Mo1 Sb5 83.47(8) . . ?
C2 Mo1 Sb5 66.6(6) . . ?
C3 Mo1 Sb5 154.0(10) . . ?
Sb4 Mo1 Sb5 171.54(9) . . ?
C1 Mo1 Sb5 73.8(6) . . ?
Sb3 Mo1 Sb2 143.22(9) . . ?
C2 Mo1 Sb2 173.3(5) . . ?
C3 Mo1 Sb2 93.2(10) . . ?
Sb4 Mo1 Sb2 68.18(6) . . ?
C1 Mo1 Sb2 101.8(4) . . ?
Sb5 Mo1 Sb2 111.33(6) . . ?
Sb3 Mo1 Sb1 125.21(9) . . ?
C2 Mo1 Sb1 124.9(6) . . ?
C3 Mo1 Sb1 143.7(10) . . ?
Sb4 Mo1 Sb1 121.59(7) . . ?
C1 Mo1 Sb1 81.8(4) . . ?
Sb5 Mo1 Sb1 58.23(5) . . ?
Sb2 Mo1 Sb1 53.45(5) . . ?
Sb3 Mo1 Sb1 134.83(8) . 3_576 ?
C2 Mo1 Sb1 100.0(6) . 3_576 ?
C3 Mo1 Sb1 86.5(7) . 3_576 ?
Sb4 Mo1 Sb1 63.72(7) . 3_576 ?
C1 Mo1 Sb1 176.1(4) . 3_576 ?
Sb5 Mo1 Sb1 107.86(7) . 3_576 ?
Sb2 Mo1 Sb1 74.34(5) . 3_576 ?
Sb1 Mo1 Sb1 96.00(5) . 3_576 ?
Sb3 Mo1 Sb2 119.55(8) . 3_576 ?
C2 Mo1 Sb2 77.8(5) . 3_576 ?
C3 Mo1 Sb2 132.2(7) . 3_576 ?
Sb4 Mo1 Sb2 115.39(7) . 3_576 ?
C1 Mo1 Sb2 129.9(6) . 3_576 ?
Sb5 Mo1 Sb2 56.16(4) . 3_576 ?
Sb2 Mo1 Sb2 95.77(6) . 3_576 ?
Sb1 Mo1 Sb2 71.97(4) . 3_576 ?
Sb1 Mo1 Sb2 51.76(4) 3_576 3_576 ?
O5 K1 O5 180.0 3_474 . ?
O5 K1 O6 120.1(2) 3_474 . ?
O5 K1 O6 59.9(2) . . ?
O5 K1 O6 59.9(2) 3_474 3_474 ?
O5 K1 O6 120.1(2) . 3_474 ?
O6 K1 O6 180.0 . 3_474 ?
O5 K1 O4 118.5(2) 3_474 . ?
O5 K1 O4 61.5(2) . . ?
O6 K1 O4 120.0(2) . . ?
O6 K1 O4 60.0(2) 3_474 . ?
O5 K1 O4 61.5(2) 3_474 3_474 ?
O5 K1 O4 118.5(2) . 3_474 ?
O6 K1 O4 60.0(2) . 3_474 ?
O6 K1 O4 120.0(2) 3_474 3_474 ?
O4 K1 O4 180.000(1) . 3_474 ?
O5 K1 N1 101.4(4) 3_474 . ?
O5 K1 N1 78.6(4) . . ?
O6 K1 N1 82.2(4) . . ?
O6 K1 N1 97.8(4) 3_474 . ?
O4 K1 N1 98.7(4) . . ?
O4 K1 N1 81.3(4) 3_474 . ?
O5 K1 N1 78.6(4) 3_474 3_474 ?
O5 K1 N1 101.4(4) . 3_474 ?
O6 K1 N1 97.8(4) . 3_474 ?
O6 K1 N1 82.2(4) 3_474 3_474 ?
O4 K1 N1 81.3(4) . 3_474 ?
O4 K1 N1 98.7(4) 3_474 3_474 ?
N1 K1 N1 180.0(4) . 3_474 ?
O2 K2 O8 142.5(4) . . ?
O2 K2 O11 91.1(4) . . ?
O8 K2 O11 115.2(3) . . ?
O2 K2 O9 72.6(3) . . ?
O8 K2 O9 114.1(3) . . ?
O11 K2 O9 115.4(3) . . ?
O2 K2 O7 110.6(4) . . ?
O8 K2 O7 58.1(3) . . ?
O11 K2 O7 150.4(2) . . ?
O9 K2 O7 56.8(3) . . ?
O2 K2 O12 137.0(4) . . ?
O8 K2 O12 58.7(3) . . ?
O11 K2 O12 56.6(3) . . ?
O9 K2 O12 143.7(2) . . ?
O7 K2 O12 110.5(3) . . ?
O2 K2 O10 70.6(3) . . ?
O8 K2 O10 145.6(2) . . ?
O11 K2 O10 58.0(2) . . ?
O9 K2 O10 57.7(2) . . ?
O7 K2 O10 109.4(3) . . ?
O12 K2 O10 106.4(2) . . ?
O2 K2 C2 26.4(5) . . ?
O8 K2 C2 116.3(6) . . ?
O11 K2 C2 107.0(5) . . ?
O9 K2 C2 85.1(4) . . ?
O7 K2 C2 100.9(4) . . ?
O12 K2 C2 131.0(3) . . ?
O10 K2 C2 97.0(5) . . ?
O2 K2 Sb3 27.2(3) . . ?
O8 K2 Sb3 116.2(2) . . ?
O11 K2 Sb3 115.53(18) . . ?
O9 K2 Sb3 74.00(17) . . ?
O7 K2 Sb3 90.81(19) . . ?
O12 K2 Sb3 142.24(17) . . ?
O10 K2 Sb3 94.49(16) . . ?
C2 K2 Sb3 11.9(3) . . ?
O1 C1 Sb3 118.4(11) . . ?
O1 C1 Mo1 172.7(16) . . ?
Sb3 C1 Mo1 57.7(5) . . ?
O1 C1 Sb5 126.5(14) . . ?
Sb3 C1 Sb5 78.8(7) . . ?
Mo1 C1 Sb5 60.0(5) . . ?
C1 O1 Sb3 35.4(7) . . ?
Sb3 C2 O2 105.4(16) . . ?
Sb3 C2 Mo1 64.6(8) . . ?
O2 C2 Mo1 167.0(15) . . ?
Sb3 C2 Sb5 94.0(8) . . ?
O2 C2 Sb5 106.1(15) . . ?
Mo1 C2 Sb5 67.8(5) . . ?
Sb3 C2 K2 139.1(9) . . ?
O2 C2 K2 62.7(7) . . ?
Mo1 C2 K2 130.3(11) . . ?
Sb5 C2 K2 126.7(6) . . ?
C2 O2 Sb3 36.4(7) . . ?
C2 O2 K2 90.9(10) . . ?
Sb3 O2 K2 116.9(6) . . ?
Sb4 C3 O3 96(3) . . ?
Sb4 C3 Mo1 75.2(14) . . ?
O3 C3 Mo1 168(2) . . ?
Sb4 C3 Sb3 127(2) . . ?
O3 C3 Sb3 136.6(16) . . ?
Mo1 C3 Sb3 51.5(8) . . ?
C3 O3 Sb4 34.5(12) . . ?
C5 O4 C4 112.7(9) . . ?
C5 O4 K1 113.9(6) . . ?
C4 O4 K1 113.4(6) . . ?
C7 O5 C6 113.1(8) . . ?
C7 O5 K1 116.5(6) . . ?
C6 O5 K1 114.3(6) . . ?
C9 O6 C8 112.8(8) . . ?
C9 O6 K1 114.6(6) . . ?
C8 O6 K1 114.2(6) . . ?
C13 O7 C14 112.0(11) . . ?
C13 O7 K2 103.5(7) . . ?
C14 O7 K2 108.5(7) . . ?
C11 O8 C12 115.4(12) . . ?
C11 O8 K2 121.0(9) . . ?
C12 O8 K2 120.9(9) . . ?
C16 O9 C15 114.0(9) . . ?
C16 O9 K2 119.5(7) . . ?
C15 O9 K2 121.8(7) . . ?
C17 O10 C18 113.6(10) . . ?
C17 O10 K2 107.0(7) . . ?
C18 O10 K2 104.4(7) . . ?
C20 O11 C19 111.3(10) . . ?
C20 O11 K2 121.5(8) . . ?
C19 O11 K2 119.0(7) . . ?
C10 O12 C22 111.0(10) . . ?
C10 O12 K2 105.4(8) . . ?
C22 O12 K2 109.1(7) . . ?
O4 C4 C9 108.7(9) . 3_474 ?
O4 C5 C6 111.0(9) . . ?
O5 C6 C5 110.7(8) . . ?
O5 C7 C8 110.7(9) . . ?
O6 C8 C7 109.2(9) . . ?
O6 C9 C4 108.9(8) . 3_474 ?
O12 C10 C11 110.5(11) . . ?
O8 C11 C10 111.0(12) . . ?
O8 C12 C13 111.3(13) . . ?
O7 C13 C12 109.4(12) . . ?
O7 C14 C15 109.5(11) . . ?
O9 C15 C14 107.9(9) . . ?
O9 C16 C17 109.5(11) . . ?
O10 C17 C16 110.6(10) . . ?
O10 C18 C19 110.2(10) . . ?
O11 C19 C18 106.5(10) . . ?
O11 C20 C22 110.5(11) . . ?
N2 C21 C23 104.8(18) . . ?
C23 N1 K1 125.6(16) . . ?
O12 C22 C20 108.1(10) . . ?
N1 C23 C21 111(2) . . ?

_diffrn_measured_fraction_theta_max 0.984
_diffrn_reflns_theta_full        27.36
_diffrn_measured_fraction_theta_full 0.984
_refine_diff_density_max         0.849
_refine_diff_density_min         -0.865
_refine_diff_density_rms         0.093
_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
