# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
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data_yts57_0m
_database_code_depnum_ccdc_archive 'CCDC 1559824'
_audit_update_record             
;
2017-07-03 deposited with the CCDC.
2017-08-14 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        Eu11Bi8.07(2)Sn1.93
_chemical_name_common            .
_chemical_melting_point          .
_chemical_formula_moiety         'Bi8.07 Eu11 Sn1.93'
_chemical_formula_sum            'Bi8.07 Eu11 Sn1.93'
_chemical_formula_weight         3587.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      tetragonal
_space_group_IT_number           139
_space_group_name_H-M_alt        'I 4/m m m'
_space_group_name_Hall           '-I 4 2'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'-x, y, -z'
'x, -y, -z'
'y, x, -z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'x, -y, z'
'-x, y, z'
'-y, -x, z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'y+1/2, x+1/2, z+1/2'

_cell_length_a                   12.5369(18)
_cell_length_b                   12.5369(18)
_cell_length_c                   18.124(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2848.6(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    878
_cell_measurement_theta_min      3.21
_cell_measurement_theta_max      26.37

_exptl_crystal_description       block
_exptl_crystal_colour            silver
_exptl_crystal_density_meas      8.364
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    8.364
_exptl_crystal_F_000             5837
_exptl_transmission_factor_min   .
_exptl_transmission_factor_max   .
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_exptl_absorpt_coefficient_mu    75.076
_shelx_estimated_absorpt_T_min   .
_shelx_estimated_absorpt_T_max   .
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.3385
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_process_details   .

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            9514
_diffrn_reflns_av_unetI/netI     0.0380
_diffrn_reflns_av_R_equivalents  0.0871
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.215
_diffrn_reflns_theta_max         26.366
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             878
_reflns_number_gt                750
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+43.6939P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000058(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         878
_refine_ls_number_parameters     41
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0372
_refine_ls_R_factor_gt           0.0274
_refine_ls_wR_factor_ref         0.0432
_refine_ls_wR_factor_gt          0.0411
_refine_ls_goodness_of_fit_ref   1.093
_refine_ls_restrained_S_all      1.093
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 0.25149(6) 0.31101(5) 0.0131(2) Uani 1 2 d S T P . .
Eu2 Eu 0.0000 0.33341(6) 0.10147(4) 0.01022(19) Uani 1 2 d S T P . .
Eu3 Eu 0.32598(8) 0.32598(8) 0.0000 0.0245(3) Uani 1 4 d S T P . .
Eu4 Eu 0.0000 0.0000 0.16552(9) 0.0142(4) Uani 1 8 d S T P . .
Bi1 Bi 0.20554(3) 0.20554(3) 0.17296(4) 0.01220(16) Uani 1 2 d S T P . .
Bi2 Bi 0.14843(7) 0.5000 0.0000 0.0100(2) Uani 1 4 d S T P . .
Bi3 Bi 0.11994(9) 0.11994(9) 0.0000 0.0156(6) Uani 0.035(10) 4 d S T P . .
Sn1 Sn 0.11994(9) 0.11994(9) 0.0000 0.0156(6) Uani 0.965(10) 4 d S T P . .
Bi4 Bi 0.0000 0.0000 0.37750(7) 0.0123(3) Uani 1 8 d S T P . .
Bi5 Bi 0.0000 0.5000 0.2500 0.0077(3) Uani 1 8 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Bi5 3.3060(9) . ?
Eu1 Bi4 3.3753(10) . ?
Eu1 Bi1 3.6376(9) 3 ?
Eu1 Bi1 3.6376(9) . ?
Eu1 Bi2 3.6478(10) 27_455 ?
Eu1 Bi1 3.7421(7) 25 ?
Eu1 Bi1 3.7421(7) 27_455 ?
Eu1 Eu2 3.9341(13) . ?
Eu1 Eu2 4.0724(10) 28 ?
Eu1 Eu2 4.0724(10) 27_455 ?
Eu1 Eu4 4.1102(14) . ?
Eu1 Eu3 4.1756(9) 25 ?
Eu2 Bi1 3.2998(7) . ?
Eu2 Bi1 3.2998(7) 3 ?
Eu2 Bi2 3.3477(9) . ?
Eu2 Bi2 3.3477(9) 17_565 ?
Eu2 Bi5 3.4071(8) . ?
Eu2 Sn1 3.5785(9) 3 ?
Eu2 Bi3 3.5785(9) 3 ?
Eu2 Bi3 3.5785(9) . ?
Eu2 Eu2 3.6781(16) 18 ?
Eu2 Eu1 4.0724(10) 28 ?
Eu3 Bi2 3.1168(7) 3_655 ?
Eu3 Bi2 3.1168(7) . ?
Eu3 Bi3 3.653(2) . ?
Eu3 Bi1 3.7929(11) . ?
Eu3 Bi1 3.7929(11) 18 ?
Eu3 Bi4 3.8011(14) 25 ?
Eu3 Bi4 3.8011(14) 9_554 ?
Eu3 Eu1 4.1755(9) 25 ?
Eu3 Eu1 4.1755(9) 28 ?
Eu3 Eu1 4.1755(9) 10_554 ?
Eu3 Eu1 4.1755(9) 11_554 ?
Eu4 Bi1 3.6466(8) 2 ?
Eu4 Bi1 3.6466(8) 4 ?
Eu4 Bi1 3.6466(8) 3 ?
Eu4 Bi1 3.6466(8) . ?
Eu4 Bi3 3.6771(17) . ?
Eu4 Sn1 3.6771(17) 17 ?
Eu4 Bi3 3.6771(17) 17 ?
Eu4 Sn1 3.6771(17) 19 ?
Eu4 Sn1 3.6771(17) 3 ?
Eu4 Bi3 3.6771(17) 19 ?
Eu4 Bi3 3.6771(17) 3 ?
Bi1 Bi1 3.2070(13) 25 ?
Bi1 Eu2 3.2998(7) 4 ?
Bi1 Bi3 3.4827(10) . ?
Bi1 Eu1 3.6376(9) 4 ?
Bi1 Eu1 3.7421(7) 28 ?
Bi1 Eu1 3.7421(7) 25 ?
Bi2 Eu3 3.1168(7) 19_565 ?
Bi2 Eu2 3.3476(9) 18 ?
Bi2 Eu2 3.3476(9) 2_565 ?
Bi2 Eu2 3.3476(9) 17_565 ?
Bi2 Eu1 3.6478(10) 28 ?
Bi2 Eu1 3.6478(10) 11_554 ?
Bi3 Sn1 3.007(2) 19 ?
Bi3 Sn1 3.007(2) 3 ?
Bi3 Bi3 3.007(2) 19 ?
Bi3 Bi3 3.007(2) 3 ?
Bi3 Bi1 3.4828(10) 18 ?
Bi3 Eu2 3.5785(9) 4 ?
Bi3 Eu2 3.5785(9) 18 ?
Bi3 Eu2 3.5785(9) 19 ?
Bi4 Eu1 3.3753(10) 3 ?
Bi4 Eu1 3.3753(10) 2 ?
Bi4 Eu1 3.3753(10) 4 ?
Bi4 Eu3 3.8012(14) 25 ?
Bi4 Eu3 3.8012(14) 27_455 ?
Bi4 Eu3 3.8012(14) 11_545 ?
Bi4 Eu3 3.8012(14) 9_445 ?
Bi5 Eu1 3.3060(9) 27_455 ?
Bi5 Eu1 3.3060(9) 2_565 ?
Bi5 Eu1 3.3060(9) 28 ?
Bi5 Eu2 3.4071(9) 28 ?
Bi5 Eu2 3.4071(9) 27_455 ?
Bi5 Eu2 3.4071(8) 2_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Bi5 Eu1 Bi4 178.62(4) . . ?
Bi5 Eu1 Bi1 85.365(18) . 3 ?
Bi4 Eu1 Bi1 95.60(2) . 3 ?
Bi5 Eu1 Bi1 85.364(18) . . ?
Bi4 Eu1 Bi1 95.60(2) . . ?
Bi1 Eu1 Bi1 90.21(3) 3 . ?
Bi5 Eu1 Bi2 89.42(2) . 27_455 ?
Bi4 Eu1 Bi2 89.20(3) . 27_455 ?
Bi1 Eu1 Bi2 134.454(15) 3 27_455 ?
Bi1 Eu1 Bi2 134.454(15) . 27_455 ?
Bi5 Eu1 Bi1 83.701(13) . 25 ?
Bi4 Eu1 Bi1 96.129(14) . 25 ?
Bi1 Eu1 Bi1 140.81(2) 3 25 ?
Bi1 Eu1 Bi1 51.492(19) . 25 ?
Bi2 Eu1 Bi1 82.968(16) 27_455 25 ?
Bi5 Eu1 Bi1 83.701(13) . 27_455 ?
Bi4 Eu1 Bi1 96.129(14) . 27_455 ?
Bi1 Eu1 Bi1 51.491(19) 3 27_455 ?
Bi1 Eu1 Bi1 140.81(2) . 27_455 ?
Bi2 Eu1 Bi1 82.968(15) 27_455 27_455 ?
Bi1 Eu1 Bi1 161.17(3) 25 27_455 ?
Bi5 Eu1 Eu2 55.326(17) . . ?
Bi4 Eu1 Eu2 126.05(3) . . ?
Bi1 Eu1 Eu2 51.491(15) 3 . ?
Bi1 Eu1 Eu2 51.490(15) . . ?
Bi2 Eu1 Eu2 144.75(3) 27_455 . ?
Bi1 Eu1 Eu2 92.141(16) 25 . ?
Bi1 Eu1 Eu2 92.141(16) 27_455 . ?
Bi5 Eu1 Eu2 53.793(15) . 28 ?
Bi4 Eu1 Eu2 125.14(3) . 28 ?
Bi1 Eu1 Eu2 138.79(2) 3 28 ?
Bi1 Eu1 Eu2 91.478(18) . 28 ?
Bi2 Eu1 Eu2 51.033(17) 27_455 28 ?
Bi1 Eu1 Eu2 49.735(13) 25 28 ?
Bi1 Eu1 Eu2 111.44(2) 27_455 28 ?
Eu2 Eu1 Eu2 100.15(2) . 28 ?
Bi5 Eu1 Eu2 53.793(15) . 27_455 ?
Bi4 Eu1 Eu2 125.14(3) . 27_455 ?
Bi1 Eu1 Eu2 91.478(18) 3 27_455 ?
Bi1 Eu1 Eu2 138.79(2) . 27_455 ?
Bi2 Eu1 Eu2 51.033(17) 27_455 27_455 ?
Bi1 Eu1 Eu2 111.44(2) 25 27_455 ?
Bi1 Eu1 Eu2 49.735(13) 27_455 27_455 ?
Eu2 Eu1 Eu2 100.15(2) . 27_455 ?
Eu2 Eu1 Eu2 61.71(2) 28 27_455 ?
Bi5 Eu1 Eu4 120.55(3) . . ?
Bi4 Eu1 Eu4 60.83(3) . . ?
Bi1 Eu1 Eu4 55.753(18) 3 . ?
Bi1 Eu1 Eu4 55.753(18) . . ?
Bi2 Eu1 Eu4 150.03(3) 27_455 . ?
Bi1 Eu1 Eu4 99.222(14) 25 . ?
Bi1 Eu1 Eu4 99.222(14) 27_455 . ?
Eu2 Eu1 Eu4 65.23(3) . . ?
Eu2 Eu1 Eu4 146.796(16) 28 . ?
Eu2 Eu1 Eu4 146.796(16) 27_455 . ?
Bi5 Eu1 Eu3 119.57(3) . 25 ?
Bi4 Eu1 Eu3 59.33(3) . 25 ?
Bi1 Eu1 Eu3 153.84(3) 3 25 ?
Bi1 Eu1 Eu3 99.049(18) . 25 ?
Bi2 Eu1 Eu3 46.350(15) 27_455 25 ?
Bi1 Eu1 Eu3 56.93(2) 25 25 ?
Bi1 Eu1 Eu3 119.03(2) 27_455 25 ?
Eu2 Eu1 Eu3 148.493(16) . 25 ?
Eu2 Eu1 Eu3 65.82(2) 28 25 ?
Eu2 Eu1 Eu3 97.26(2) 27_455 25 ?
Eu4 Eu1 Eu3 110.36(3) . 25 ?
Bi1 Eu2 Bi1 102.69(3) . 3 ?
Bi1 Eu2 Bi2 94.860(17) . . ?
Bi1 Eu2 Bi2 162.34(2) 3 . ?
Bi1 Eu2 Bi2 162.34(2) . 17_565 ?
Bi1 Eu2 Bi2 94.860(17) 3 17_565 ?
Bi2 Eu2 Bi2 67.54(3) . 17_565 ?
Bi1 Eu2 Bi5 89.29(2) . . ?
Bi1 Eu2 Bi5 89.29(2) 3 . ?
Bi2 Eu2 Bi5 92.96(2) . . ?
Bi2 Eu2 Bi5 92.96(2) 17_565 . ?
Bi1 Eu2 Sn1 99.59(3) . 3 ?
Bi1 Eu2 Sn1 60.680(18) 3 3 ?
Bi2 Eu2 Sn1 114.70(2) . 3 ?
Bi2 Eu2 Sn1 87.17(3) 17_565 3 ?
Bi5 Eu2 Sn1 149.824(19) . 3 ?
Bi1 Eu2 Bi3 99.59(3) . 3 ?
Bi1 Eu2 Bi3 60.680(18) 3 3 ?
Bi2 Eu2 Bi3 114.70(2) . 3 ?
Bi2 Eu2 Bi3 87.17(3) 17_565 3 ?
Bi5 Eu2 Bi3 149.824(19) . 3 ?
Sn1 Eu2 Bi3 0.000(9) 3 3 ?
Bi1 Eu2 Bi3 60.680(18) . . ?
Bi1 Eu2 Bi3 99.59(3) 3 . ?
Bi2 Eu2 Bi3 87.17(3) . . ?
Bi2 Eu2 Bi3 114.70(2) 17_565 . ?
Bi5 Eu2 Bi3 149.824(19) . . ?
Sn1 Eu2 Bi3 49.69(5) 3 . ?
Bi3 Eu2 Bi3 49.69(5) 3 . ?
Bi1 Eu2 Eu2 113.119(17) . 18 ?
Bi1 Eu2 Eu2 113.119(17) 3 18 ?
Bi2 Eu2 Eu2 56.676(15) . 18 ?
Bi2 Eu2 Eu2 56.677(15) 17_565 18 ?
Bi5 Eu2 Eu2 142.193(14) . 18 ?
Sn1 Eu2 Eu2 59.075(13) 3 18 ?
Bi3 Eu2 Eu2 59.075(13) 3 18 ?
Bi3 Eu2 Eu2 59.075(13) . 18 ?
Bi1 Eu2 Eu1 59.612(17) . . ?
Bi1 Eu2 Eu1 59.612(17) 3 . ?
Bi2 Eu2 Eu1 133.88(2) . . ?
Bi2 Eu2 Eu1 133.88(2) 17_565 . ?
Bi5 Eu2 Eu1 52.939(18) . . ?
Sn1 Eu2 Eu1 107.51(2) 3 . ?
Bi3 Eu2 Eu1 107.51(2) 3 . ?
Bi3 Eu2 Eu1 107.51(2) . . ?
Eu2 Eu2 Eu1 164.868(16) 18 . ?
Bi1 Eu2 Eu1 59.921(13) . 28 ?
Bi1 Eu2 Eu1 133.92(3) 3 28 ?
Bi2 Eu2 Eu1 57.911(18) . 28 ?
Bi2 Eu2 Eu1 108.62(2) 17_565 28 ?
Bi5 Eu2 Eu1 51.530(14) . 28 ?
Sn1 Eu2 Eu1 154.85(3) 3 28 ?
Bi3 Eu2 Eu1 154.85(3) 3 28 ?
Bi3 Eu2 Eu1 105.20(2) . 28 ?
Eu2 Eu2 Eu1 112.922(16) 18 28 ?
Eu1 Eu2 Eu1 75.990(18) . 28 ?
Bi2 Eu3 Bi2 178.85(6) 3_655 . ?
Bi2 Eu3 Bi3 89.43(3) 3_655 . ?
Bi2 Eu3 Bi3 89.43(3) . . ?
Bi2 Eu3 Bi1 89.677(16) 3_655 . ?
Bi2 Eu3 Bi1 89.676(16) . . ?
Bi3 Eu3 Bi1 55.74(2) . . ?
Bi2 Eu3 Bi1 89.677(16) 3_655 18 ?
Bi2 Eu3 Bi1 89.676(16) . 18 ?
Bi3 Eu3 Bi1 55.74(2) . 18 ?
Bi1 Eu3 Bi1 111.47(4) . 18 ?
Bi2 Eu3 Bi4 90.47(2) 3_655 25 ?
Bi2 Eu3 Bi4 90.47(2) . 25 ?
Bi3 Eu3 Bi4 144.26(2) . 25 ?
Bi1 Eu3 Bi4 88.53(2) . 25 ?
Bi1 Eu3 Bi4 160.00(4) 18 25 ?
Bi2 Eu3 Bi4 90.47(2) 3_655 9_554 ?
Bi2 Eu3 Bi4 90.47(2) . 9_554 ?
Bi3 Eu3 Bi4 144.26(2) . 9_554 ?
Bi1 Eu3 Bi4 160.00(4) . 9_554 ?
Bi1 Eu3 Bi4 88.53(2) 18 9_554 ?
Bi4 Eu3 Bi4 71.47(4) 25 9_554 ?
Bi2 Eu3 Eu1 57.870(12) 3_655 25 ?
Bi2 Eu3 Eu1 122.409(14) . 25 ?
Bi3 Eu3 Eu1 101.83(2) . 25 ?
Bi1 Eu3 Eu1 55.769(13) . 25 ?
Bi1 Eu3 Eu1 142.50(3) 18 25 ?
Bi4 Eu3 Eu1 49.796(18) 25 25 ?
Bi4 Eu3 Eu1 108.22(3) 9_554 25 ?
Bi2 Eu3 Eu1 122.409(14) 3_655 28 ?
Bi2 Eu3 Eu1 57.870(12) . 28 ?
Bi3 Eu3 Eu1 101.83(2) . 28 ?
Bi1 Eu3 Eu1 55.769(13) . 28 ?
Bi1 Eu3 Eu1 142.50(3) 18 28 ?
Bi4 Eu3 Eu1 49.796(18) 25 28 ?
Bi4 Eu3 Eu1 108.22(3) 9_554 28 ?
Eu1 Eu3 Eu1 64.54(2) 25 28 ?
Bi2 Eu3 Eu1 57.870(12) 3_655 10_554 ?
Bi2 Eu3 Eu1 122.409(14) . 10_554 ?
Bi3 Eu3 Eu1 101.83(2) . 10_554 ?
Bi1 Eu3 Eu1 142.50(3) . 10_554 ?
Bi1 Eu3 Eu1 55.769(13) 18 10_554 ?
Bi4 Eu3 Eu1 108.22(3) 25 10_554 ?
Bi4 Eu3 Eu1 49.796(18) 9_554 10_554 ?
Eu1 Eu3 Eu1 110.23(2) 25 10_554 ?
Eu1 Eu3 Eu1 156.34(4) 28 10_554 ?
Bi2 Eu3 Eu1 122.409(14) 3_655 11_554 ?
Bi2 Eu3 Eu1 57.870(12) . 11_554 ?
Bi3 Eu3 Eu1 101.83(2) . 11_554 ?
Bi1 Eu3 Eu1 142.50(3) . 11_554 ?
Bi1 Eu3 Eu1 55.769(13) 18 11_554 ?
Bi4 Eu3 Eu1 108.22(3) 25 11_554 ?
Bi4 Eu3 Eu1 49.796(18) 9_554 11_554 ?
Eu1 Eu3 Eu1 156.34(4) 25 11_554 ?
Eu1 Eu3 Eu1 110.23(2) 28 11_554 ?
Eu1 Eu3 Eu1 64.54(2) 10_554 11_554 ?
Bi1 Eu4 Bi1 89.922(2) 2 4 ?
Bi1 Eu4 Bi1 89.922(2) 2 3 ?
Bi1 Eu4 Bi1 175.76(6) 4 3 ?
Bi1 Eu4 Bi1 175.76(6) 2 . ?
Bi1 Eu4 Bi1 89.922(2) 4 . ?
Bi1 Eu4 Bi1 89.922(2) 3 . ?
Bi1 Eu4 Bi3 127.45(5) 2 . ?
Bi1 Eu4 Bi3 91.73(2) 4 . ?
Bi1 Eu4 Bi3 91.73(2) 3 . ?
Bi1 Eu4 Bi3 56.79(3) . . ?
Bi1 Eu4 Sn1 56.79(3) 2 17 ?
Bi1 Eu4 Sn1 91.73(2) 4 17 ?
Bi1 Eu4 Sn1 91.73(2) 3 17 ?
Bi1 Eu4 Sn1 127.45(5) . 17 ?
Bi3 Eu4 Sn1 70.66(5) . 17 ?
Bi1 Eu4 Bi3 56.79(3) 2 17 ?
Bi1 Eu4 Bi3 91.73(2) 4 17 ?
Bi1 Eu4 Bi3 91.73(2) 3 17 ?
Bi1 Eu4 Bi3 127.45(5) . 17 ?
Bi3 Eu4 Bi3 70.66(5) . 17 ?
Sn1 Eu4 Bi3 0.00(6) 17 17 ?
Bi1 Eu4 Sn1 91.73(2) 2 19 ?
Bi1 Eu4 Sn1 56.79(3) 4 19 ?
Bi1 Eu4 Sn1 127.45(5) 3 19 ?
Bi1 Eu4 Sn1 91.73(2) . 19 ?
Bi3 Eu4 Sn1 48.28(3) . 19 ?
Sn1 Eu4 Sn1 48.28(3) 17 19 ?
Bi3 Eu4 Sn1 48.28(3) 17 19 ?
Bi1 Eu4 Sn1 91.73(2) 2 3 ?
Bi1 Eu4 Sn1 127.45(5) 4 3 ?
Bi1 Eu4 Sn1 56.79(3) 3 3 ?
Bi1 Eu4 Sn1 91.73(2) . 3 ?
Bi3 Eu4 Sn1 48.28(3) . 3 ?
Sn1 Eu4 Sn1 48.28(3) 17 3 ?
Bi3 Eu4 Sn1 48.28(3) 17 3 ?
Sn1 Eu4 Sn1 70.66(5) 19 3 ?
Bi1 Eu4 Bi3 91.73(2) 2 19 ?
Bi1 Eu4 Bi3 56.79(3) 4 19 ?
Bi1 Eu4 Bi3 127.45(5) 3 19 ?
Bi1 Eu4 Bi3 91.73(2) . 19 ?
Bi3 Eu4 Bi3 48.28(3) . 19 ?
Sn1 Eu4 Bi3 48.28(3) 17 19 ?
Bi3 Eu4 Bi3 48.28(3) 17 19 ?
Sn1 Eu4 Bi3 0.00(6) 19 19 ?
Sn1 Eu4 Bi3 70.66(5) 3 19 ?
Bi1 Eu4 Bi3 91.73(2) 2 3 ?
Bi1 Eu4 Bi3 127.45(5) 4 3 ?
Bi1 Eu4 Bi3 56.79(3) 3 3 ?
Bi1 Eu4 Bi3 91.73(2) . 3 ?
Bi3 Eu4 Bi3 48.28(3) . 3 ?
Sn1 Eu4 Bi3 48.28(3) 17 3 ?
Bi3 Eu4 Bi3 48.28(3) 17 3 ?
Sn1 Eu4 Bi3 70.66(5) 19 3 ?
Sn1 Eu4 Bi3 0.00(6) 3 3 ?
Bi3 Eu4 Bi3 70.66(5) 19 3 ?
Bi1 Bi1 Eu2 116.390(17) 25 . ?
Bi1 Bi1 Eu2 116.390(17) 25 4 ?
Eu2 Bi1 Eu2 127.20(3) . 4 ?
Bi1 Bi1 Bi3 176.39(4) 25 . ?
Eu2 Bi1 Bi3 63.621(17) . . ?
Eu2 Bi1 Bi3 63.621(17) 4 . ?
Bi1 Bi1 Eu1 65.94(2) 25 . ?
Eu2 Bi1 Eu1 68.90(2) . . ?
Eu2 Bi1 Eu1 137.55(2) 4 . ?
Bi3 Bi1 Eu1 116.72(3) . . ?
Bi1 Bi1 Eu1 65.93(2) 25 4 ?
Eu2 Bi1 Eu1 137.55(2) . 4 ?
Eu2 Bi1 Eu1 68.90(2) 4 4 ?
Bi3 Bi1 Eu1 116.72(3) . 4 ?
Eu1 Bi1 Eu1 75.60(3) . 4 ?
Bi1 Bi1 Eu4 121.57(4) 25 . ?
Eu2 Bi1 Eu4 77.113(19) . . ?
Eu2 Bi1 Eu4 77.114(19) 4 . ?
Bi3 Bi1 Eu4 62.05(4) . . ?
Eu1 Bi1 Eu4 68.70(3) . . ?
Eu1 Bi1 Eu4 68.70(3) 4 . ?
Bi1 Bi1 Eu1 62.57(2) 25 28 ?
Eu2 Bi1 Eu1 70.344(18) . 28 ?
Eu2 Bi1 Eu1 136.96(2) 4 28 ?
Bi3 Bi1 Eu1 114.72(3) . 28 ?
Eu1 Bi1 Eu1 83.82(2) . 28 ?
Eu1 Bi1 Eu1 128.508(19) 4 28 ?
Eu4 Bi1 Eu1 143.294(13) . 28 ?
Bi1 Bi1 Eu1 62.57(2) 25 25 ?
Eu2 Bi1 Eu1 136.96(2) . 25 ?
Eu2 Bi1 Eu1 70.344(18) 4 25 ?
Bi3 Bi1 Eu1 114.72(3) . 25 ?
Eu1 Bi1 Eu1 128.508(19) . 25 ?
Eu1 Bi1 Eu1 83.82(2) 4 25 ?
Eu4 Bi1 Eu1 143.294(13) . 25 ?
Eu1 Bi1 Eu1 73.14(3) 28 25 ?
Bi1 Bi1 Eu3 116.29(3) 25 . ?
Eu2 Bi1 Eu3 78.052(19) . . ?
Eu2 Bi1 Eu3 78.051(19) 4 . ?
Bi3 Bi1 Eu3 60.10(3) . . ?
Eu1 Bi1 Eu3 141.946(14) . . ?
Eu1 Bi1 Eu3 141.946(14) 4 . ?
Eu4 Bi1 Eu3 122.14(4) . . ?
Eu1 Bi1 Eu3 67.30(2) 28 . ?
Eu1 Bi1 Eu3 67.30(2) 25 . ?
Eu3 Bi2 Eu3 88.85(6) 19_565 . ?
Eu3 Bi2 Eu2 146.478(16) 19_565 18 ?
Eu3 Bi2 Eu2 87.72(2) . 18 ?
Eu3 Bi2 Eu2 87.72(2) 19_565 2_565 ?
Eu3 Bi2 Eu2 146.478(16) . 2_565 ?
Eu2 Bi2 Eu2 112.46(3) 18 2_565 ?
Eu3 Bi2 Eu2 87.72(2) 19_565 17_565 ?
Eu3 Bi2 Eu2 146.478(15) . 17_565 ?
Eu2 Bi2 Eu2 77.20(3) 18 17_565 ?
Eu2 Bi2 Eu2 66.65(3) 2_565 17_565 ?
Eu3 Bi2 Eu2 146.478(16) 19_565 . ?
Eu3 Bi2 Eu2 87.72(2) . . ?
Eu2 Bi2 Eu2 66.65(3) 18 . ?
Eu2 Bi2 Eu2 77.20(3) 2_565 . ?
Eu2 Bi2 Eu2 112.46(3) 17_565 . ?
Eu3 Bi2 Eu1 75.780(16) 19_565 28 ?
Eu3 Bi2 Eu1 75.780(16) . 28 ?
Eu2 Bi2 Eu1 134.995(16) 18 28 ?
Eu2 Bi2 Eu1 71.056(17) 2_565 28 ?
Eu2 Bi2 Eu1 134.995(16) 17_565 28 ?
Eu2 Bi2 Eu1 71.056(16) . 28 ?
Eu3 Bi2 Eu1 75.780(16) 19_565 11_554 ?
Eu3 Bi2 Eu1 75.780(16) . 11_554 ?
Eu2 Bi2 Eu1 71.056(17) 18 11_554 ?
Eu2 Bi2 Eu1 134.995(16) 2_565 11_554 ?
Eu2 Bi2 Eu1 71.056(17) 17_565 11_554 ?
Eu2 Bi2 Eu1 134.995(16) . 11_554 ?
Eu1 Bi2 Eu1 139.76(4) 28 11_554 ?
Sn1 Bi3 Sn1 90.0 19 3 ?
Sn1 Bi3 Bi3 0.0 19 19 ?
Sn1 Bi3 Bi3 90.0 3 19 ?
Sn1 Bi3 Bi3 90.0 19 3 ?
Sn1 Bi3 Bi3 0.00(4) 3 3 ?
Bi3 Bi3 Bi3 90.0 19 3 ?
Sn1 Bi3 Bi1 107.947(17) 19 . ?
Sn1 Bi3 Bi1 107.947(17) 3 . ?
Bi3 Bi3 Bi1 107.947(17) 19 . ?
Bi3 Bi3 Bi1 107.947(17) 3 . ?
Sn1 Bi3 Bi1 107.946(17) 19 18 ?
Sn1 Bi3 Bi1 107.946(17) 3 18 ?
Bi3 Bi3 Bi1 107.946(17) 19 18 ?
Bi3 Bi3 Bi1 107.946(17) 3 18 ?
Bi1 Bi3 Bi1 128.33(5) . 18 ?
Sn1 Bi3 Eu2 138.41(2) 19 . ?
Sn1 Bi3 Eu2 65.15(2) 3 . ?
Bi3 Bi3 Eu2 138.41(2) 19 . ?
Bi3 Bi3 Eu2 65.15(2) 3 . ?
Bi1 Bi3 Eu2 55.700(14) . . ?
Bi1 Bi3 Eu2 111.20(3) 18 . ?
Sn1 Bi3 Eu2 65.15(2) 19 4 ?
Sn1 Bi3 Eu2 138.41(2) 3 4 ?
Bi3 Bi3 Eu2 65.15(2) 19 4 ?
Bi3 Bi3 Eu2 138.41(2) 3 4 ?
Bi1 Bi3 Eu2 55.700(14) . 4 ?
Bi1 Bi3 Eu2 111.20(3) 18 4 ?
Eu2 Bi3 Eu2 111.37(3) . 4 ?
Sn1 Bi3 Eu2 138.41(2) 19 18 ?
Sn1 Bi3 Eu2 65.15(2) 3 18 ?
Bi3 Bi3 Eu2 138.41(2) 19 18 ?
Bi3 Bi3 Eu2 65.15(2) 3 18 ?
Bi1 Bi3 Eu2 111.20(3) . 18 ?
Bi1 Bi3 Eu2 55.700(14) 18 18 ?
Eu2 Bi3 Eu2 61.85(3) . 18 ?
Eu2 Bi3 Eu2 153.20(5) 4 18 ?
Sn1 Bi3 Eu2 65.15(2) 19 19 ?
Sn1 Bi3 Eu2 138.41(2) 3 19 ?
Bi3 Bi3 Eu2 65.15(2) 19 19 ?
Bi3 Bi3 Eu2 138.41(2) 3 19 ?
Bi1 Bi3 Eu2 111.20(3) . 19 ?
Bi1 Bi3 Eu2 55.700(14) 18 19 ?
Eu2 Bi3 Eu2 153.20(5) . 19 ?
Eu2 Bi3 Eu2 61.85(3) 4 19 ?
Eu2 Bi3 Eu2 111.37(3) 18 19 ?
Sn1 Bi3 Eu3 135.0 19 . ?
Sn1 Bi3 Eu3 135.0 3 . ?
Bi3 Bi3 Eu3 135.0 19 . ?
Bi3 Bi3 Eu3 135.0 3 . ?
Bi1 Bi3 Eu3 64.17(3) . . ?
Bi1 Bi3 Eu3 64.17(3) 18 . ?
Eu2 Bi3 Eu3 76.60(3) . . ?
Eu2 Bi3 Eu3 76.60(3) 4 . ?
Eu2 Bi3 Eu3 76.60(3) 18 . ?
Eu2 Bi3 Eu3 76.60(3) 19 . ?
Sn1 Bi3 Eu4 65.863(16) 19 . ?
Sn1 Bi3 Eu4 65.863(16) 3 . ?
Bi3 Bi3 Eu4 65.863(16) 19 . ?
Bi3 Bi3 Eu4 65.863(16) 3 . ?
Bi1 Bi3 Eu4 61.17(2) . . ?
Bi1 Bi3 Eu4 170.50(5) 18 . ?
Eu2 Bi3 Eu4 73.425(17) . . ?
Eu2 Bi3 Eu4 73.426(17) 4 . ?
Eu2 Bi3 Eu4 123.591(19) 18 . ?
Eu2 Bi3 Eu4 123.591(19) 19 . ?
Eu3 Bi3 Eu4 125.33(3) . . ?
Eu1 Bi4 Eu1 82.676(17) . 3 ?
Eu1 Bi4 Eu1 138.16(5) . 2 ?
Eu1 Bi4 Eu1 82.676(17) 3 2 ?
Eu1 Bi4 Eu1 82.676(17) . 4 ?
Eu1 Bi4 Eu1 138.16(5) 3 4 ?
Eu1 Bi4 Eu1 82.677(17) 2 4 ?
Eu1 Bi4 Eu3 70.877(17) . 25 ?
Eu1 Bi4 Eu3 138.130(15) 3 25 ?
Eu1 Bi4 Eu3 138.130(15) 2 25 ?
Eu1 Bi4 Eu3 70.876(17) 4 25 ?
Eu1 Bi4 Eu3 70.877(17) . 27_455 ?
Eu1 Bi4 Eu3 70.876(17) 3 27_455 ?
Eu1 Bi4 Eu3 138.130(15) 2 27_455 ?
Eu1 Bi4 Eu3 138.130(15) 4 27_455 ?
Eu3 Bi4 Eu3 70.05(2) 25 27_455 ?
Eu1 Bi4 Eu3 138.131(15) . 11_545 ?
Eu1 Bi4 Eu3 138.130(15) 3 11_545 ?
Eu1 Bi4 Eu3 70.876(17) 2 11_545 ?
Eu1 Bi4 Eu3 70.876(17) 4 11_545 ?
Eu3 Bi4 Eu3 70.05(2) 25 11_545 ?
Eu3 Bi4 Eu3 108.53(4) 27_455 11_545 ?
Eu1 Bi4 Eu3 138.131(15) . 9_445 ?
Eu1 Bi4 Eu3 70.876(17) 3 9_445 ?
Eu1 Bi4 Eu3 70.876(17) 2 9_445 ?
Eu1 Bi4 Eu3 138.130(15) 4 9_445 ?
Eu3 Bi4 Eu3 108.53(4) 25 9_445 ?
Eu3 Bi4 Eu3 70.05(2) 27_455 9_445 ?
Eu3 Bi4 Eu3 70.05(2) 11_545 9_445 ?
Eu1 Bi4 Eu4 69.08(3) . . ?
Eu1 Bi4 Eu4 69.08(3) 3 . ?
Eu1 Bi4 Eu4 69.08(3) 2 . ?
Eu1 Bi4 Eu4 69.08(3) 4 . ?
Eu3 Bi4 Eu4 125.74(2) 25 . ?
Eu3 Bi4 Eu4 125.74(2) 27_455 . ?
Eu3 Bi4 Eu4 125.74(2) 11_545 . ?
Eu3 Bi4 Eu4 125.74(2) 9_445 . ?
Eu1 Bi5 Eu1 96.424(10) 27_455 2_565 ?
Eu1 Bi5 Eu1 140.92(3) 27_455 28 ?
Eu1 Bi5 Eu1 96.424(10) 2_565 28 ?
Eu1 Bi5 Eu1 96.423(10) 27_455 . ?
Eu1 Bi5 Eu1 140.92(3) 2_565 . ?
Eu1 Bi5 Eu1 96.423(9) 28 . ?
Eu1 Bi5 Eu2 147.35(2) 27_455 28 ?
Eu1 Bi5 Eu2 74.676(12) 2_565 28 ?
Eu1 Bi5 Eu2 71.74(2) 28 28 ?
Eu1 Bi5 Eu2 74.677(12) . 28 ?
Eu1 Bi5 Eu2 71.74(2) 27_455 27_455 ?
Eu1 Bi5 Eu2 74.676(12) 2_565 27_455 ?
Eu1 Bi5 Eu2 147.35(2) 28 27_455 ?
Eu1 Bi5 Eu2 74.677(12) . 27_455 ?
Eu2 Bi5 Eu2 75.61(3) 28 27_455 ?
Eu1 Bi5 Eu2 74.676(12) 27_455 2_565 ?
Eu1 Bi5 Eu2 71.74(2) 2_565 2_565 ?
Eu1 Bi5 Eu2 74.676(12) 28 2_565 ?
Eu1 Bi5 Eu2 147.35(2) . 2_565 ?
Eu2 Bi5 Eu2 128.628(18) 28 2_565 ?
Eu2 Bi5 Eu2 128.628(17) 27_455 2_565 ?
Eu1 Bi5 Eu2 74.676(12) 27_455 . ?
Eu1 Bi5 Eu2 147.35(2) 2_565 . ?
Eu1 Bi5 Eu2 74.676(12) 28 . ?
Eu1 Bi5 Eu2 71.73(2) . . ?
Eu2 Bi5 Eu2 128.627(17) 28 . ?
Eu2 Bi5 Eu2 128.627(18) 27_455 . ?
Eu2 Bi5 Eu2 75.61(3) 2_565 . ?

_refine_diff_density_max         1.934
_refine_diff_density_min         -2.102
_refine_diff_density_rms         0.424

_shelxl_version_number           2013-3


_exptl_crystal_recrystallization_method 'From the Melt'
_exptl_crystal_preparation       ', electrical conductivity'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_N0588A_0m
_database_code_depnum_ccdc_archive 'CCDC 1559830'
_audit_update_record             
;
2017-07-03 deposited with the CCDC.
2017-08-14 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT971_N0588A_0m           
;
PROBLEM: Check Calcd Residual Density  2.20A From     Bi4       3.75 eA-3
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT971_N0588A_0m_2         
;
PROBLEM: Check Calcd Residual Density  0.59A From     Bi3       3.70 eA-3
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT971_N0588A_0m_3         
;
PROBLEM: Check Calcd Residual Density  1.08A From     Eu3       3.61 eA-3
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT972_N0588A_0m           
;
PROBLEM: Check Calcd Residual Density  0.71A From     Bi3      -4.53 eA-3
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT220_N0588A_0m           
;
PROBLEM: Non-Solvent Resd 1  Bi   Ueq(max)/Ueq(min) Range        7.2 Ratio
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT919_N0588A_0m           
;
PROBLEM: Reflection # Likely Affected by the Beamstop ...          1 Check
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT971_N0588A_0m_4         
;
PROBLEM: Check Calcd Residual Density  0.40A From     Bi3       2.82 eA-3
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT972_N0588A_0m_2         
;
PROBLEM: Check Calcd Residual Density  0.61A From     Bi2      -3.35 eA-3
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
_vrf_PLAT972_N0588A_0m_3         
;
PROBLEM: Check Calcd Residual Density  0.25A From     Bi3      -2.78 eA-3
RESPONSE: An intrinsic structural feature which is historically known for this structure type
;
# Added during the CSD deposition process: Monday 03 July 2017 11:07 AM
# end Validation Reply Form


_audit_creation_method           SHELXL-2013
_chemical_name_systematic        Eu10.74K0.26Bi9.14Sn0.86
_chemical_name_common            .
_chemical_melting_point          .
_chemical_formula_moiety         'Eu10.74 K0.26 Bi9.14 Sn0.86'
_chemical_formula_sum            'Bi9.14 Eu10.74 K0.26 Sn0.86'
_chemical_formula_weight         3654.14

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      tetragonal
_space_group_IT_number           139
_space_group_name_H-M_alt        'I 4/m m m'
_space_group_name_Hall           '-I 4 2'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'-x, y, -z'
'x, -y, -z'
'y, x, -z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'x, -y, z'
'-x, y, z'
'-y, -x, z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'y+1/2, x+1/2, z+1/2'

_cell_length_a                   12.5414(3)
_cell_length_b                   12.5414(3)
_cell_length_c                   18.1027(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2847.31(16)
_cell_formula_units_Z            4
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    1189
_cell_measurement_theta_min      1.98
_cell_measurement_theta_max      29.59

_exptl_crystal_description       block
_exptl_crystal_colour            silver
_exptl_crystal_density_meas      8.524
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    8.524
_exptl_crystal_F_000             5932
_exptl_transmission_factor_min   .
_exptl_transmission_factor_max   .
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_exptl_absorpt_coefficient_mu    80.239
_shelx_estimated_absorpt_T_min   .
_shelx_estimated_absorpt_T_max   .
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.3240
_exptl_absorpt_correction_T_max  0.7459
_exptl_absorpt_process_details   .

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            18801
_diffrn_reflns_av_unetI/netI     0.0353
_diffrn_reflns_av_R_equivalents  0.0995
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         1.975
_diffrn_reflns_theta_max         29.590
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             1189
_reflns_number_gt                1026
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+159.1530P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         1189
_refine_ls_number_parameters     41
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0360
_refine_ls_R_factor_gt           0.0263
_refine_ls_wR_factor_ref         0.0545
_refine_ls_wR_factor_gt          0.0513
_refine_ls_goodness_of_fit_ref   1.146
_refine_ls_restrained_S_all      1.146
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 0.25054(5) 0.31033(4) 0.00765(14) Uani 1 2 d S T P . .
Eu2 Eu 0.0000 0.33522(5) 0.10217(4) 0.00774(14) Uani 1 2 d S T P . .
Eu3 Eu 0.32985(7) 0.32985(7) 0.0000 0.0177(2) Uani 1 4 d S T P . .
Eu4 Eu 0.0000 0.0000 0.16163(10) 0.0095(6) Uani 0.739(9) 8 d S T P . .
K4 K 0.0000 0.0000 0.16163(10) 0.0095(6) Uani 0.261(9) 8 d S T P . .
Bi1 Bi 0.20745(3) 0.20745(3) 0.17288(3) 0.00899(11) Uani 1 2 d S T P . .
Bi2 Bi 0.14852(5) 0.5000 0.0000 0.00910(15) Uani 1 4 d S T P . .
Bi3 Bi 0.12698(8) 0.12698(8) 0.0000 0.0297(4) Uani 0.569(11) 4 d S T P . .
Sn1 Sn 0.12698(8) 0.12698(8) 0.0000 0.0297(4) Uani 0.431(11) 4 d S T P . .
Bi4 Bi 0.0000 0.0000 0.37865(6) 0.00741(19) Uani 1 8 d S T P . .
Bi5 Bi 0.0000 0.5000 0.2500 0.00409(17) Uani 1 8 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Bi5 3.3137(6) . ?
Eu1 Bi4 3.3768(7) . ?
Eu1 Bi1 3.6403(6) 3 ?
Eu1 Bi1 3.6403(6) . ?
Eu1 Bi2 3.6595(7) 27_455 ?
Eu1 Bi1 3.7192(4) 25 ?
Eu1 Bi1 3.7192(4) 27_455 ?
Eu1 Eu2 3.9150(9) . ?
Eu1 Eu2 4.0703(7) 28 ?
Eu1 Eu2 4.0703(7) 27_455 ?
Eu1 Eu4 4.1375(13) . ?
Eu2 Bi1 3.3129(5) 3 ?
Eu2 Bi1 3.3129(5) . ?
Eu2 Bi2 3.3408(7) 17_565 ?
Eu2 Bi2 3.3408(7) . ?
Eu2 Bi5 3.3811(7) . ?
Eu2 Sn1 3.5746(7) 3 ?
Eu2 Bi3 3.5746(7) 3 ?
Eu2 Bi3 3.5746(7) . ?
Eu2 Eu2 3.6992(13) 18 ?
Eu2 Eu1 4.0703(7) 28 ?
Eu3 Bi2 3.1185(5) . ?
Eu3 Bi2 3.1185(5) 3_655 ?
Eu3 Bi3 3.5981(18) . ?
Eu3 Bi4 3.7326(12) 25 ?
Eu3 Bi4 3.7326(12) 9_554 ?
Eu3 Bi1 3.8089(9) . ?
Eu3 Bi1 3.8089(9) 18 ?
Eu3 Eu1 4.1664(6) 25 ?
Eu3 Eu1 4.1664(6) 28 ?
Eu3 Eu1 4.1664(6) 10_554 ?
Eu3 Eu1 4.1664(6) 11_554 ?
Eu4 Bi1 3.6849(5) 2 ?
Eu4 Bi1 3.6849(5) 4 ?
Eu4 Bi1 3.6849(5) 3 ?
Eu4 Bi1 3.6849(5) . ?
Eu4 Sn1 3.6924(16) 17 ?
Eu4 Bi3 3.6924(16) 17 ?
Eu4 Sn1 3.6924(16) 19 ?
Eu4 Sn1 3.6924(16) 3 ?
Eu4 Bi3 3.6924(16) 19 ?
Eu4 Bi3 3.6924(16) 3 ?
Eu4 Bi3 3.6924(16) . ?
Bi1 Bi1 3.1740(10) 25 ?
Bi1 Eu2 3.3129(5) 4 ?
Bi1 Bi3 3.4397(7) . ?
Bi1 Eu1 3.6403(6) 4 ?
Bi1 Eu1 3.7191(4) 28 ?
Bi1 Eu1 3.7191(4) 25 ?
Bi2 Eu3 3.1185(5) 19_565 ?
Bi2 Eu2 3.3409(7) 18 ?
Bi2 Eu2 3.3409(7) 2_565 ?
Bi2 Eu2 3.3409(7) 17_565 ?
Bi2 Eu1 3.6594(7) 28 ?
Bi2 Eu1 3.6594(7) 11_554 ?
Bi3 Sn1 3.1851(19) 19 ?
Bi3 Sn1 3.1851(19) 3 ?
Bi3 Bi3 3.1851(19) 19 ?
Bi3 Bi3 3.1851(19) 3 ?
Bi3 Bi1 3.4396(7) 18 ?
Bi3 Eu2 3.5746(7) 4 ?
Bi3 Eu2 3.5746(7) 18 ?
Bi3 Eu2 3.5746(7) 19 ?
Bi3 K4 3.6924(16) 17 ?
Bi4 Eu1 3.3768(7) 3 ?
Bi4 Eu1 3.3768(7) 2 ?
Bi4 Eu1 3.3768(7) 4 ?
Bi4 Eu3 3.7327(12) 25 ?
Bi4 Eu3 3.7327(12) 27_455 ?
Bi4 Eu3 3.7327(12) 11_545 ?
Bi4 Eu3 3.7327(12) 9_445 ?
Bi5 Eu1 3.3137(6) 27_455 ?
Bi5 Eu1 3.3137(6) 2_565 ?
Bi5 Eu1 3.3137(6) 28 ?
Bi5 Eu2 3.3811(7) 28 ?
Bi5 Eu2 3.3811(7) 2_565 ?
Bi5 Eu2 3.3811(7) 27_455 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Bi5 Eu1 Bi4 177.76(3) . . ?
Bi5 Eu1 Bi1 85.119(14) . 3 ?
Bi4 Eu1 Bi1 96.442(18) . 3 ?
Bi5 Eu1 Bi1 85.118(14) . . ?
Bi4 Eu1 Bi1 96.442(18) . . ?
Bi1 Eu1 Bi1 91.23(2) 3 . ?
Bi5 Eu1 Bi2 89.005(18) . 27_455 ?
Bi4 Eu1 Bi2 88.75(2) . 27_455 ?
Bi1 Eu1 Bi2 133.842(11) 3 27_455 ?
Bi1 Eu1 Bi2 133.841(11) . 27_455 ?
Bi5 Eu1 Bi1 83.867(11) . 25 ?
Bi4 Eu1 Bi1 95.849(11) . 25 ?
Bi1 Eu1 Bi1 141.439(19) 3 25 ?
Bi1 Eu1 Bi1 51.084(14) . 25 ?
Bi2 Eu1 Bi1 82.780(12) 27_455 25 ?
Bi5 Eu1 Bi1 83.867(11) . 27_455 ?
Bi4 Eu1 Bi1 95.849(11) . 27_455 ?
Bi1 Eu1 Bi1 51.085(14) 3 27_455 ?
Bi1 Eu1 Bi1 141.439(18) . 27_455 ?
Bi2 Eu1 Bi1 82.780(12) 27_455 27_455 ?
Bi1 Eu1 Bi1 161.17(2) 25 27_455 ?
Bi5 Eu1 Eu2 55.017(14) . . ?
Bi4 Eu1 Eu2 127.23(3) . . ?
Bi1 Eu1 Eu2 51.859(11) 3 . ?
Bi1 Eu1 Eu2 51.859(11) . . ?
Bi2 Eu1 Eu2 144.02(2) 27_455 . ?
Bi1 Eu1 Eu2 92.305(13) 25 . ?
Bi1 Eu1 Eu2 92.305(13) 27_455 . ?
Bi5 Eu1 Eu2 53.314(11) . 28 ?
Bi4 Eu1 Eu2 124.94(2) . 28 ?
Bi1 Eu1 Eu2 137.98(2) 3 28 ?
Bi1 Eu1 Eu2 90.988(14) . 28 ?
Bi2 Eu1 Eu2 50.875(14) 27_455 28 ?
Bi1 Eu1 Eu2 50.090(11) 25 28 ?
Bi1 Eu1 Eu2 111.111(17) 27_455 28 ?
Eu2 Eu1 Eu2 99.557(18) . 28 ?
Bi5 Eu1 Eu2 53.314(11) . 27_455 ?
Bi4 Eu1 Eu2 124.94(2) . 27_455 ?
Bi1 Eu1 Eu2 90.988(14) 3 27_455 ?
Bi1 Eu1 Eu2 137.98(2) . 27_455 ?
Bi2 Eu1 Eu2 50.875(14) 27_455 27_455 ?
Bi1 Eu1 Eu2 111.111(17) 25 27_455 ?
Bi1 Eu1 Eu2 50.090(11) 27_455 27_455 ?
Eu2 Eu1 Eu2 99.557(18) . 27_455 ?
Eu2 Eu1 Eu2 61.024(19) 28 27_455 ?
Bi5 Eu1 Eu4 120.17(3) . . ?
Bi4 Eu1 Eu4 62.07(3) . . ?
Bi1 Eu1 Eu4 56.121(15) 3 . ?
Bi1 Eu1 Eu4 56.122(15) . . ?
Bi2 Eu1 Eu4 150.83(3) 27_455 . ?
Bi1 Eu1 Eu4 99.251(11) 25 . ?
Bi1 Eu1 Eu4 99.251(11) 27_455 . ?
Eu2 Eu1 Eu4 65.15(2) . . ?
Eu2 Eu1 Eu4 146.813(14) 28 . ?
Eu2 Eu1 Eu4 146.813(14) 27_455 . ?
Bi1 Eu2 Bi1 103.50(3) 3 . ?
Bi1 Eu2 Bi2 94.318(14) 3 17_565 ?
Bi1 Eu2 Bi2 161.99(2) . 17_565 ?
Bi1 Eu2 Bi2 161.99(2) 3 . ?
Bi1 Eu2 Bi2 94.317(14) . . ?
Bi2 Eu2 Bi2 67.77(2) 17_565 . ?
Bi1 Eu2 Bi5 89.418(15) 3 . ?
Bi1 Eu2 Bi5 89.417(15) . . ?
Bi2 Eu2 Bi5 93.447(15) 17_565 . ?
Bi2 Eu2 Bi5 93.447(15) . . ?
Bi1 Eu2 Sn1 59.777(14) 3 3 ?
Bi1 Eu2 Sn1 101.33(3) . 3 ?
Bi2 Eu2 Sn1 85.24(2) 17_565 3 ?
Bi2 Eu2 Sn1 114.448(18) . 3 ?
Bi5 Eu2 Sn1 148.878(16) . 3 ?
Bi1 Eu2 Bi3 59.777(14) 3 3 ?
Bi1 Eu2 Bi3 101.33(3) . 3 ?
Bi2 Eu2 Bi3 85.24(2) 17_565 3 ?
Bi2 Eu2 Bi3 114.448(18) . 3 ?
Bi5 Eu2 Bi3 148.878(16) . 3 ?
Sn1 Eu2 Bi3 0.000(6) 3 3 ?
Bi1 Eu2 Bi3 101.33(3) 3 . ?
Bi1 Eu2 Bi3 59.778(14) . . ?
Bi2 Eu2 Bi3 114.448(18) 17_565 . ?
Bi2 Eu2 Bi3 85.24(2) . . ?
Bi5 Eu2 Bi3 148.878(16) . . ?
Sn1 Eu2 Bi3 52.91(4) 3 . ?
Bi3 Eu2 Bi3 52.91(4) 3 . ?
Bi1 Eu2 Eu2 112.730(13) 3 18 ?
Bi1 Eu2 Eu2 112.730(13) . 18 ?
Bi2 Eu2 Eu2 56.384(11) 17_565 18 ?
Bi2 Eu2 Eu2 56.384(11) . 18 ?
Bi5 Eu2 Eu2 142.325(11) . 18 ?
Sn1 Eu2 Eu2 58.840(10) 3 18 ?
Bi3 Eu2 Eu2 58.840(10) 3 18 ?
Bi3 Eu2 Eu2 58.840(10) . 18 ?
Bi1 Eu2 Eu1 59.793(14) 3 . ?
Bi1 Eu2 Eu1 59.793(14) . . ?
Bi2 Eu2 Eu1 134.481(16) 17_565 . ?
Bi2 Eu2 Eu1 134.481(16) . . ?
Bi5 Eu2 Eu1 53.416(13) . . ?
Sn1 Eu2 Eu1 107.447(18) 3 . ?
Bi3 Eu2 Eu1 107.447(18) 3 . ?
Bi3 Eu2 Eu1 107.447(18) . . ?
Eu2 Eu2 Eu1 164.259(14) 18 . ?
Bi1 Eu2 Eu1 134.33(2) 3 28 ?
Bi1 Eu2 Eu1 59.443(11) . 28 ?
Bi2 Eu2 Eu1 109.265(19) 17_565 28 ?
Bi2 Eu2 Eu1 58.185(13) . 28 ?
Bi5 Eu2 Eu1 51.807(11) . 28 ?
Sn1 Eu2 Eu1 156.17(2) 3 28 ?
Bi3 Eu2 Eu1 156.17(2) 3 28 ?
Bi3 Eu2 Eu1 103.29(2) . 28 ?
Eu2 Eu2 Eu1 112.901(13) 18 28 ?
Eu1 Eu2 Eu1 76.301(14) . 28 ?
Bi2 Eu3 Bi2 176.36(5) . 3_655 ?
Bi2 Eu3 Bi3 88.18(2) . . ?
Bi2 Eu3 Bi3 88.18(2) 3_655 . ?
Bi2 Eu3 Bi4 91.47(2) . 25 ?
Bi2 Eu3 Bi4 91.47(2) 3_655 25 ?
Bi3 Eu3 Bi4 143.949(17) . 25 ?
Bi2 Eu3 Bi4 91.47(2) . 9_554 ?
Bi2 Eu3 Bi4 91.47(2) 3_655 9_554 ?
Bi3 Eu3 Bi4 143.949(17) . 9_554 ?
Bi4 Eu3 Bi4 72.10(3) 25 9_554 ?
Bi2 Eu3 Bi1 88.962(14) . . ?
Bi2 Eu3 Bi1 88.962(14) 3_655 . ?
Bi3 Eu3 Bi1 55.251(17) . . ?
Bi4 Eu3 Bi1 88.697(15) 25 . ?
Bi4 Eu3 Bi1 160.80(3) 9_554 . ?
Bi2 Eu3 Bi1 88.962(14) . 18 ?
Bi2 Eu3 Bi1 88.962(14) 3_655 18 ?
Bi3 Eu3 Bi1 55.251(17) . 18 ?
Bi4 Eu3 Bi1 160.80(3) 25 18 ?
Bi4 Eu3 Bi1 88.698(15) 9_554 18 ?
Bi1 Eu3 Bi1 110.50(3) . 18 ?
Bi2 Eu3 Eu1 122.621(10) . 25 ?
Bi2 Eu3 Eu1 58.202(9) 3_655 25 ?
Bi3 Eu3 Eu1 101.014(18) . 25 ?
Bi4 Eu3 Eu1 50.250(14) 25 25 ?
Bi4 Eu3 Eu1 109.30(3) 9_554 25 ?
Bi1 Eu3 Eu1 55.373(8) . 25 ?
Bi1 Eu3 Eu1 141.81(2) 18 25 ?
Bi2 Eu3 Eu1 58.202(9) . 28 ?
Bi2 Eu3 Eu1 122.621(10) 3_655 28 ?
Bi3 Eu3 Eu1 101.014(18) . 28 ?
Bi4 Eu3 Eu1 50.250(14) 25 28 ?
Bi4 Eu3 Eu1 109.30(3) 9_554 28 ?
Bi1 Eu3 Eu1 55.373(8) . 28 ?
Bi1 Eu3 Eu1 141.81(2) 18 28 ?
Eu1 Eu3 Eu1 64.454(16) 25 28 ?
Bi2 Eu3 Eu1 122.621(10) . 10_554 ?
Bi2 Eu3 Eu1 58.202(9) 3_655 10_554 ?
Bi3 Eu3 Eu1 101.014(18) . 10_554 ?
Bi4 Eu3 Eu1 109.30(3) 25 10_554 ?
Bi4 Eu3 Eu1 50.250(14) 9_554 10_554 ?
Bi1 Eu3 Eu1 141.81(2) . 10_554 ?
Bi1 Eu3 Eu1 55.374(8) 18 10_554 ?
Eu1 Eu3 Eu1 110.992(15) 25 10_554 ?
Eu1 Eu3 Eu1 157.97(4) 28 10_554 ?
Bi2 Eu3 Eu1 58.202(9) . 11_554 ?
Bi2 Eu3 Eu1 122.621(10) 3_655 11_554 ?
Bi3 Eu3 Eu1 101.014(18) . 11_554 ?
Bi4 Eu3 Eu1 109.30(3) 25 11_554 ?
Bi4 Eu3 Eu1 50.250(14) 9_554 11_554 ?
Bi1 Eu3 Eu1 141.81(2) . 11_554 ?
Bi1 Eu3 Eu1 55.374(8) 18 11_554 ?
Eu1 Eu3 Eu1 157.97(4) 25 11_554 ?
Eu1 Eu3 Eu1 110.992(15) 28 11_554 ?
Eu1 Eu3 Eu1 64.454(16) 10_554 11_554 ?
Bi1 Eu4 Bi1 89.825(3) 2 4 ?
Bi1 Eu4 Bi1 89.825(3) 2 3 ?
Bi1 Eu4 Bi1 173.66(6) 4 3 ?
Bi1 Eu4 Bi1 173.66(6) 2 . ?
Bi1 Eu4 Bi1 89.825(3) 4 . ?
Bi1 Eu4 Bi1 89.825(3) 3 . ?
Bi1 Eu4 Sn1 55.58(2) 2 17 ?
Bi1 Eu4 Sn1 92.51(2) 4 17 ?
Bi1 Eu4 Sn1 92.51(2) 3 17 ?
Bi1 Eu4 Sn1 130.76(5) . 17 ?
Bi1 Eu4 Bi3 55.58(2) 2 17 ?
Bi1 Eu4 Bi3 92.51(2) 4 17 ?
Bi1 Eu4 Bi3 92.51(2) 3 17 ?
Bi1 Eu4 Bi3 130.76(5) . 17 ?
Sn1 Eu4 Bi3 0.00(3) 17 17 ?
Bi1 Eu4 Sn1 92.51(2) 2 19 ?
Bi1 Eu4 Sn1 55.58(2) 4 19 ?
Bi1 Eu4 Sn1 130.75(5) 3 19 ?
Bi1 Eu4 Sn1 92.51(2) . 19 ?
Sn1 Eu4 Sn1 51.10(3) 17 19 ?
Bi3 Eu4 Sn1 51.10(3) 17 19 ?
Bi1 Eu4 Sn1 92.51(2) 2 3 ?
Bi1 Eu4 Sn1 130.75(5) 4 3 ?
Bi1 Eu4 Sn1 55.58(2) 3 3 ?
Bi1 Eu4 Sn1 92.51(2) . 3 ?
Sn1 Eu4 Sn1 51.10(3) 17 3 ?
Bi3 Eu4 Sn1 51.10(3) 17 3 ?
Sn1 Eu4 Sn1 75.17(5) 19 3 ?
Bi1 Eu4 Bi3 92.51(2) 2 19 ?
Bi1 Eu4 Bi3 55.58(2) 4 19 ?
Bi1 Eu4 Bi3 130.75(5) 3 19 ?
Bi1 Eu4 Bi3 92.51(2) . 19 ?
Sn1 Eu4 Bi3 51.10(3) 17 19 ?
Bi3 Eu4 Bi3 51.10(3) 17 19 ?
Sn1 Eu4 Bi3 0.00(5) 19 19 ?
Sn1 Eu4 Bi3 75.17(5) 3 19 ?
Bi1 Eu4 Bi3 92.51(2) 2 3 ?
Bi1 Eu4 Bi3 130.75(5) 4 3 ?
Bi1 Eu4 Bi3 55.58(2) 3 3 ?
Bi1 Eu4 Bi3 92.51(2) . 3 ?
Sn1 Eu4 Bi3 51.10(3) 17 3 ?
Bi3 Eu4 Bi3 51.10(3) 17 3 ?
Sn1 Eu4 Bi3 75.17(5) 19 3 ?
Sn1 Eu4 Bi3 0.00(5) 3 3 ?
Bi3 Eu4 Bi3 75.17(5) 19 3 ?
Bi1 Eu4 Bi3 130.75(5) 2 . ?
Bi1 Eu4 Bi3 92.51(2) 4 . ?
Bi1 Eu4 Bi3 92.51(2) 3 . ?
Bi1 Eu4 Bi3 55.58(2) . . ?
Sn1 Eu4 Bi3 75.17(5) 17 . ?
Bi3 Eu4 Bi3 75.17(5) 17 . ?
Sn1 Eu4 Bi3 51.10(3) 19 . ?
Sn1 Eu4 Bi3 51.10(3) 3 . ?
Bi3 Eu4 Bi3 51.10(3) 19 . ?
Bi3 Eu4 Bi3 51.10(3) 3 . ?
Bi1 Bi1 Eu2 116.188(14) 25 4 ?
Bi1 Bi1 Eu2 116.188(14) 25 . ?
Eu2 Bi1 Eu2 127.62(3) 4 . ?
Bi1 Bi1 Bi3 176.11(3) 25 . ?
Eu2 Bi1 Bi3 63.893(14) 4 . ?
Eu2 Bi1 Bi3 63.893(14) . . ?
Bi1 Bi1 Eu1 65.742(16) 25 . ?
Eu2 Bi1 Eu1 136.58(2) 4 . ?
Eu2 Bi1 Eu1 68.348(14) . . ?
Bi3 Bi1 Eu1 117.12(2) . . ?
Bi1 Bi1 Eu1 65.742(16) 25 4 ?
Eu2 Bi1 Eu1 68.348(14) 4 4 ?
Eu2 Bi1 Eu1 136.59(2) . 4 ?
Bi3 Bi1 Eu1 117.12(2) . 4 ?
Eu1 Bi1 Eu1 75.23(2) . 4 ?
Bi1 Bi1 Eu4 121.57(4) 25 . ?
Eu2 Bi1 Eu4 76.449(17) 4 . ?
Eu2 Bi1 Eu4 76.450(17) . . ?
Bi3 Bi1 Eu4 62.32(3) . . ?
Eu1 Bi1 Eu4 68.78(2) . . ?
Eu1 Bi1 Eu4 68.78(2) 4 . ?
Bi1 Bi1 Eu1 63.174(16) 25 28 ?
Eu2 Bi1 Eu1 137.54(2) 4 28 ?
Eu2 Bi1 Eu1 70.465(15) . 28 ?
Bi3 Bi1 Eu1 113.91(2) . 28 ?
Eu1 Bi1 Eu1 84.200(19) . 28 ?
Eu1 Bi1 Eu1 128.916(14) 4 28 ?
Eu4 Bi1 Eu1 143.231(11) . 28 ?
Bi1 Bi1 Eu1 63.174(16) 25 25 ?
Eu2 Bi1 Eu1 70.466(15) 4 25 ?
Eu2 Bi1 Eu1 137.54(2) . 25 ?
Bi3 Bi1 Eu1 113.91(2) . 25 ?
Eu1 Bi1 Eu1 128.917(14) . 25 ?
Eu1 Bi1 Eu1 84.200(19) 4 25 ?
Eu4 Bi1 Eu1 143.231(11) . 25 ?
Eu1 Bi1 Eu1 73.37(2) 28 25 ?
Bi1 Bi1 Eu3 116.85(3) 25 . ?
Eu2 Bi1 Eu3 78.702(15) 4 . ?
Eu2 Bi1 Eu3 78.701(15) . . ?
Bi3 Bi1 Eu3 59.26(3) . . ?
Eu1 Bi1 Eu3 142.169(11) . . ?
Eu1 Bi1 Eu3 142.169(11) 4 . ?
Eu4 Bi1 Eu3 121.58(3) . . ?
Eu1 Bi1 Eu3 67.196(18) 28 . ?
Eu1 Bi1 Eu3 67.196(18) 25 . ?
Eu3 Bi2 Eu3 86.36(5) 19_565 . ?
Eu3 Bi2 Eu2 146.084(12) 19_565 . ?
Eu3 Bi2 Eu2 89.04(2) . . ?
Eu3 Bi2 Eu2 146.084(12) 19_565 18 ?
Eu3 Bi2 Eu2 89.04(2) . 18 ?
Eu2 Bi2 Eu2 67.23(2) . 18 ?
Eu3 Bi2 Eu2 89.04(2) 19_565 2_565 ?
Eu3 Bi2 Eu2 146.083(12) . 2_565 ?
Eu2 Bi2 Eu2 76.42(2) . 2_565 ?
Eu2 Bi2 Eu2 112.23(2) 18 2_565 ?
Eu3 Bi2 Eu2 89.04(2) 19_565 17_565 ?
Eu3 Bi2 Eu2 146.083(12) . 17_565 ?
Eu2 Bi2 Eu2 112.23(2) . 17_565 ?
Eu2 Bi2 Eu2 76.42(2) 18 17_565 ?
Eu2 Bi2 Eu2 67.23(2) 2_565 17_565 ?
Eu3 Bi2 Eu1 75.389(13) 19_565 28 ?
Eu3 Bi2 Eu1 75.389(13) . 28 ?
Eu2 Bi2 Eu1 70.939(12) . 28 ?
Eu2 Bi2 Eu1 135.424(14) 18 28 ?
Eu2 Bi2 Eu1 70.938(12) 2_565 28 ?
Eu2 Bi2 Eu1 135.424(14) 17_565 28 ?
Eu3 Bi2 Eu1 75.389(13) 19_565 11_554 ?
Eu3 Bi2 Eu1 75.389(13) . 11_554 ?
Eu2 Bi2 Eu1 135.424(14) . 11_554 ?
Eu2 Bi2 Eu1 70.938(12) 18 11_554 ?
Eu2 Bi2 Eu1 135.424(14) 2_565 11_554 ?
Eu2 Bi2 Eu1 70.938(12) 17_565 11_554 ?
Eu1 Bi2 Eu1 139.52(3) 28 11_554 ?
Sn1 Bi3 Sn1 90.0 19 3 ?
Sn1 Bi3 Bi3 0.0 19 19 ?
Sn1 Bi3 Bi3 90.0 3 19 ?
Sn1 Bi3 Bi3 90.0 19 3 ?
Sn1 Bi3 Bi3 0.00(3) 3 3 ?
Bi3 Bi3 Bi3 90.0 19 3 ?
Sn1 Bi3 Bi1 107.060(15) 19 18 ?
Sn1 Bi3 Bi1 107.060(15) 3 18 ?
Bi3 Bi3 Bi1 107.060(15) 19 18 ?
Bi3 Bi3 Bi1 107.060(15) 3 18 ?
Sn1 Bi3 Bi1 107.060(15) 19 . ?
Sn1 Bi3 Bi1 107.060(15) 3 . ?
Bi3 Bi3 Bi1 107.060(15) 19 . ?
Bi3 Bi3 Bi1 107.060(15) 3 . ?
Bi1 Bi3 Bi1 130.98(4) 18 . ?
Sn1 Bi3 Eu2 63.543(19) 19 4 ?
Sn1 Bi3 Eu2 136.94(2) 3 4 ?
Bi3 Bi3 Eu2 63.543(19) 19 4 ?
Bi3 Bi3 Eu2 136.94(2) 3 4 ?
Bi1 Bi3 Eu2 112.78(2) 18 4 ?
Bi1 Bi3 Eu2 56.329(11) . 4 ?
Sn1 Bi3 Eu2 136.94(2) 19 18 ?
Sn1 Bi3 Eu2 63.54(2) 3 18 ?
Bi3 Bi3 Eu2 136.94(2) 19 18 ?
Bi3 Bi3 Eu2 63.54(2) 3 18 ?
Bi1 Bi3 Eu2 56.329(11) 18 18 ?
Bi1 Bi3 Eu2 112.78(2) . 18 ?
Eu2 Bi3 Eu2 156.74(4) 4 18 ?
Sn1 Bi3 Eu2 63.54(2) 19 19 ?
Sn1 Bi3 Eu2 136.94(2) 3 19 ?
Bi3 Bi3 Eu2 63.54(2) 19 19 ?
Bi3 Bi3 Eu2 136.94(2) 3 19 ?
Bi1 Bi3 Eu2 56.328(11) 18 19 ?
Bi1 Bi3 Eu2 112.78(2) . 19 ?
Eu2 Bi3 Eu2 62.32(2) 4 19 ?
Eu2 Bi3 Eu2 112.54(2) 18 19 ?
Sn1 Bi3 Eu2 136.94(2) 19 . ?
Sn1 Bi3 Eu2 63.543(19) 3 . ?
Bi3 Bi3 Eu2 136.94(2) 19 . ?
Bi3 Bi3 Eu2 63.543(19) 3 . ?
Bi1 Bi3 Eu2 112.78(2) 18 . ?
Bi1 Bi3 Eu2 56.329(11) . . ?
Eu2 Bi3 Eu2 112.54(2) 4 . ?
Eu2 Bi3 Eu2 62.32(2) 18 . ?
Eu2 Bi3 Eu2 156.74(4) 19 . ?
Sn1 Bi3 Eu3 135.0 19 . ?
Sn1 Bi3 Eu3 135.0 3 . ?
Bi3 Bi3 Eu3 135.0 19 . ?
Bi3 Bi3 Eu3 135.0 3 . ?
Bi1 Bi3 Eu3 65.49(2) 18 . ?
Bi1 Bi3 Eu3 65.49(2) . . ?
Eu2 Bi3 Eu3 78.37(2) 4 . ?
Eu2 Bi3 Eu3 78.37(2) 18 . ?
Eu2 Bi3 Eu3 78.37(2) 19 . ?
Eu2 Bi3 Eu3 78.37(2) . . ?
Sn1 Bi3 K4 64.449(15) 19 17 ?
Sn1 Bi3 K4 64.449(15) 3 17 ?
Bi3 Bi3 K4 64.449(15) 19 17 ?
Bi3 Bi3 K4 64.449(15) 3 17 ?
Bi1 Bi3 K4 62.099(19) 18 17 ?
Bi1 Bi3 K4 166.93(4) . 17 ?
Eu2 Bi3 K4 122.207(17) 4 17 ?
Eu2 Bi3 K4 73.317(14) 18 17 ?
Eu2 Bi3 K4 73.317(14) 19 17 ?
Eu2 Bi3 K4 122.207(17) . 17 ?
Eu3 Bi3 K4 127.59(2) . 17 ?
Eu1 Bi4 Eu1 82.291(14) . 3 ?
Eu1 Bi4 Eu1 137.03(4) . 2 ?
Eu1 Bi4 Eu1 82.291(14) 3 2 ?
Eu1 Bi4 Eu1 82.291(14) . 4 ?
Eu1 Bi4 Eu1 137.03(4) 3 4 ?
Eu1 Bi4 Eu1 82.291(14) 2 4 ?
Eu1 Bi4 Eu3 71.554(13) . 25 ?
Eu1 Bi4 Eu3 138.375(12) 3 25 ?
Eu1 Bi4 Eu3 138.375(12) 2 25 ?
Eu1 Bi4 Eu3 71.553(13) 4 25 ?
Eu1 Bi4 Eu3 71.554(13) . 27_455 ?
Eu1 Bi4 Eu3 71.553(13) 3 27_455 ?
Eu1 Bi4 Eu3 138.375(12) 2 27_455 ?
Eu1 Bi4 Eu3 138.375(12) 4 27_455 ?
Eu3 Bi4 Eu3 69.736(18) 25 27_455 ?
Eu1 Bi4 Eu3 138.375(12) . 11_545 ?
Eu1 Bi4 Eu3 138.375(12) 3 11_545 ?
Eu1 Bi4 Eu3 71.553(13) 2 11_545 ?
Eu1 Bi4 Eu3 71.553(13) 4 11_545 ?
Eu3 Bi4 Eu3 69.736(17) 25 11_545 ?
Eu3 Bi4 Eu3 107.90(3) 27_455 11_545 ?
Eu1 Bi4 Eu3 138.375(12) . 9_445 ?
Eu1 Bi4 Eu3 71.553(13) 3 9_445 ?
Eu1 Bi4 Eu3 71.553(13) 2 9_445 ?
Eu1 Bi4 Eu3 138.375(12) 4 9_445 ?
Eu3 Bi4 Eu3 107.90(3) 25 9_445 ?
Eu3 Bi4 Eu3 69.736(17) 27_455 9_445 ?
Eu3 Bi4 Eu3 69.736(17) 11_545 9_445 ?
Eu1 Bi4 Eu4 68.51(2) . . ?
Eu1 Bi4 Eu4 68.52(2) 3 . ?
Eu1 Bi4 Eu4 68.52(2) 2 . ?
Eu1 Bi4 Eu4 68.52(2) 4 . ?
Eu3 Bi4 Eu4 126.052(17) 25 . ?
Eu3 Bi4 Eu4 126.052(17) 27_455 . ?
Eu3 Bi4 Eu4 126.052(17) 11_545 . ?
Eu3 Bi4 Eu4 126.052(17) 9_445 . ?
Eu1 Bi5 Eu1 96.237(7) 27_455 2_565 ?
Eu1 Bi5 Eu1 141.51(2) 27_455 28 ?
Eu1 Bi5 Eu1 96.237(7) 2_565 28 ?
Eu1 Bi5 Eu1 96.236(7) 27_455 . ?
Eu1 Bi5 Eu1 141.51(2) 2_565 . ?
Eu1 Bi5 Eu1 96.236(7) 28 . ?
Eu1 Bi5 Eu2 74.878(9) 27_455 . ?
Eu1 Bi5 Eu2 146.920(16) 2_565 . ?
Eu1 Bi5 Eu2 74.878(9) 28 . ?
Eu1 Bi5 Eu2 71.567(16) . . ?
Eu1 Bi5 Eu2 146.921(16) 27_455 28 ?
Eu1 Bi5 Eu2 74.879(9) 2_565 28 ?
Eu1 Bi5 Eu2 71.567(16) 28 28 ?
Eu1 Bi5 Eu2 74.879(9) . 28 ?
Eu2 Bi5 Eu2 128.788(14) . 28 ?
Eu1 Bi5 Eu2 74.879(9) 27_455 2_565 ?
Eu1 Bi5 Eu2 71.567(16) 2_565 2_565 ?
Eu1 Bi5 Eu2 74.879(9) 28 2_565 ?
Eu1 Bi5 Eu2 146.920(16) . 2_565 ?
Eu2 Bi5 Eu2 75.35(2) . 2_565 ?
Eu2 Bi5 Eu2 128.787(14) 28 2_565 ?
Eu1 Bi5 Eu2 71.567(16) 27_455 27_455 ?
Eu1 Bi5 Eu2 74.879(9) 2_565 27_455 ?
Eu1 Bi5 Eu2 146.921(16) 28 27_455 ?
Eu1 Bi5 Eu2 74.879(9) . 27_455 ?
Eu2 Bi5 Eu2 128.788(14) . 27_455 ?
Eu2 Bi5 Eu2 75.35(2) 28 27_455 ?
Eu2 Bi5 Eu2 128.787(14) 2_565 27_455 ?

_refine_diff_density_max         3.965
_refine_diff_density_min         -4.977
_refine_diff_density_rms         0.453

_shelxl_version_number           2013-3


_exptl_crystal_recrystallization_method 'From the Melt'
_chemical_properties_physical    ', Air-sensitive,Oxygen-sensitive'
