# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_L(tBu)Eu
_database_code_depnum_ccdc_archive 'CCDC 1549492'
_audit_update_record             
;
2017-08-16 deposited with the CCDC.
2017-08-17 downloaded from the CCDC.
;
_audit_creation_date             2017-08-16
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5337)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C51 H75 Eu1 N4 O3'
_chemical_formula_sum            'C51 H75 Eu N4 O3'
_chemical_formula_weight         944.11
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      hexagonal
_space_group_IT_number           176
_space_group_name_H-M_alt        'P 63/m'
_space_group_name_Hall           '-P 6c'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'

_cell_length_a                   16.2194(7)
_cell_length_b                   16.2194(7)
_cell_length_c                   26.9621(15)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     6142.6(6)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9517
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      69.65
_cell_measurement_theta_min      3.15
_shelx_estimated_absorpt_T_max   0.778
_shelx_estimated_absorpt_T_min   0.549
_exptl_absorpt_coefficient_mu    7.569
_exptl_absorpt_correction_T_max  0.7533
_exptl_absorpt_correction_T_min  0.5563
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction. wR2(int) was 0.1688 before and 0.0758 after correction. The Ratio of minimum to maximum transmission is 0.7385. The λ/2 correction factor is 0.00150.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.021
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       Hexagonal
_exptl_crystal_F_000             1984
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.035
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0593
_diffrn_reflns_av_unetI/netI     0.0274
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.970
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            49515
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.970
_diffrn_reflns_theta_full        66.000
_diffrn_reflns_theta_max         70.074
_diffrn_reflns_theta_min         3.146
_diffrn_ambient_temperature      200.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3536
_reflns_number_total             3877
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       'APEX2 (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         0.887
_refine_diff_density_min         -1.170
_refine_diff_density_rms         0.073
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.146
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     200
_refine_ls_number_reflns         3877
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0526
_refine_ls_R_factor_gt           0.0482
_refine_ls_restrained_S_all      1.146
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0298P)²+15.2378P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1107
_refine_ls_wR_factor_ref         0.1126
_refine_special_details          'Olex2 solvent mask'
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C15) = Uanis(C15A)
Uanis(C16) = Uanis(C16A)
Uanis(C17) = Uanis(C17A)
Uanis(C14) = Uanis(C14A)
3. Same fragment restrains
{C14, C15, C16, C17} sigma for 1-2: 0.02, 1-3: 0.04
as
{C14A, C15A, C16A, C17A}
4. Others
 Sof(C14A)=Sof(C15A)=Sof(H15D)=Sof(H15E)=Sof(H15F)=Sof(C16A)=Sof(H16D)=
 Sof(H16E)=Sof(H16F)=Sof(C17A)=Sof(H17D)=Sof(H17E)=Sof(H17F)=1-FVAR(1)
 Sof(C14)=Sof(C15)=Sof(H15A)=Sof(H15B)=Sof(H15C)=Sof(C16)=Sof(H16A)=Sof(H16B)=
 Sof(H16C)=Sof(C17)=Sof(H17A)=Sof(H17B)=Sof(H17C)=FVAR(1)
5.a Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C2(H2A,H2B)
5.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C7(H7), C9(H9)
5.c Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C13(H13A,H13B,H13C), C15(H15A,H15B,
 H15C), C16(H16A,H16B,H16C), C17(H17A,H17B,H17C), C15A(H15D,H15E,H15F),
 C16A(H16D,H16E,H16F), C17A(H17D,H17E,H17F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 1.6667 1.3333 0.48363(2) 0.02681(13) Uani 1 3 d S T P . .
O1 O 1.53277(18) 1.25844(18) 0.43996(11) 0.0356(6) Uani 1 1 d . . . . .
N1 N 1.6667 1.3333 0.5875(2) 0.0382(13) Uani 1 3 d S T P . .
N2 N 1.5591(2) 1.1724(2) 0.52286(12) 0.0329(7) Uani 1 1 d . . . . .
C1 C 1.5976(3) 1.2360(3) 0.60536(16) 0.0413(10) Uani 1 1 d . . . . .
H1A H 1.5336 1.2292 0.6078 0.050 Uiso 1 1 calc R . . . .
H1B H 1.6165 1.2267 0.6389 0.050 Uiso 1 1 calc R . . . .
C2 C 1.5936(3) 1.1607(3) 0.57074(16) 0.0395(10) Uani 1 1 d . . . . .
H2A H 1.6577 1.1682 0.5671 0.047 Uiso 1 1 calc R . . . .
H2B H 1.5501 1.0965 0.5842 0.047 Uiso 1 1 calc R . . . .
C3 C 1.4792(3) 1.1022(3) 0.50693(15) 0.0348(9) Uani 1 1 d . . . . .
H3 H 1.4537 1.0449 0.5256 0.042 Uiso 1 1 calc R . . . .
C4 C 1.4241(3) 1.1002(3) 0.46429(15) 0.0323(8) Uani 1 1 d . . . . .
C5 C 1.4528(3) 1.1797(3) 0.43304(15) 0.0309(8) Uani 1 1 d . . . . .
C6 C 1.3889(3) 1.1726(3) 0.39437(15) 0.0317(8) Uani 1 1 d . . . . .
C7 C 1.3025(3) 1.0886(3) 0.39000(17) 0.0395(10) Uani 1 1 d . . . . .
H7 H 1.2609 1.0842 0.3640 0.047 Uiso 1 1 calc R . . . .
C8 C 1.2724(3) 1.0090(3) 0.42169(17) 0.0402(10) Uani 1 1 d . . . . .
C9 C 1.3357(3) 1.0168(3) 0.45797(16) 0.0387(10) Uani 1 1 d . . . . .
H9 H 1.3191 0.9642 0.4793 0.046 Uiso 1 1 calc R . . . .
C10 C 1.4158(3) 1.2571(3) 0.35931(16) 0.0360(9) Uani 1 1 d . . . . .
C11 C 1.4301(4) 1.3438(3) 0.38905(19) 0.0500(12) Uani 1 1 d . . . . .
H11A H 1.3719 1.3274 0.4076 0.075 Uiso 1 1 calc GR . . . .
H11B H 1.4445 1.3965 0.3663 0.075 Uiso 1 1 calc GR . . . .
H11C H 1.4832 1.3631 0.4123 0.075 Uiso 1 1 calc GR . . . .
C12 C 1.5075(3) 1.2816(4) 0.33068(19) 0.0523(12) Uani 1 1 d . . . . .
H12A H 1.5587 1.2949 0.3543 0.078 Uiso 1 1 calc GR . . . .
H12B H 1.5261 1.3378 0.3099 0.078 Uiso 1 1 calc GR . . . .
H12C H 1.4961 1.2277 0.3096 0.078 Uiso 1 1 calc GR . . . .
C13 C 1.3382(3) 1.2352(3) 0.32065(18) 0.0511(12) Uani 1 1 d . . . . .
H13A H 1.3324 1.1847 0.2985 0.077 Uiso 1 1 calc GR . . . .
H13B H 1.3553 1.2927 0.3013 0.077 Uiso 1 1 calc GR . . . .
H13C H 1.2774 1.2142 0.3375 0.077 Uiso 1 1 calc GR . . . .
C14 C 1.1788(7) 0.9189(7) 0.4118(3) 0.0458(19) Uani 0.717(6) 1 d D . . A 1
C15 C 1.1539(5) 0.8463(5) 0.4538(3) 0.060(2) Uani 0.717(6) 1 d D . . A 1
H15A H 1.2029 0.8279 0.4559 0.090 Uiso 0.717(6) 1 calc GR . . A 1
H15B H 1.0920 0.7899 0.4471 0.090 Uiso 0.717(6) 1 calc GR . . A 1
H15C H 1.1510 0.8749 0.4853 0.090 Uiso 0.717(6) 1 calc GR . . A 1
C16 C 1.1818(5) 0.8723(5) 0.3632(3) 0.0625(19) Uani 0.717(6) 1 d D . . A 1
H16A H 1.1960 0.9172 0.3358 0.094 Uiso 0.717(6) 1 calc GR . . A 1
H16B H 1.1200 0.8151 0.3574 0.094 Uiso 0.717(6) 1 calc GR . . A 1
H16C H 1.2315 0.8547 0.3650 0.094 Uiso 0.717(6) 1 calc GR . . A 1
C17 C 1.0983(5) 0.9435(6) 0.4096(4) 0.068(3) Uani 0.717(6) 1 d D . . A 1
H17A H 1.0944 0.9705 0.4414 0.102 Uiso 0.717(6) 1 calc GR . . A 1
H17B H 1.0376 0.8856 0.4028 0.102 Uiso 0.717(6) 1 calc GR . . A 1
H17C H 1.1119 0.9900 0.3831 0.102 Uiso 0.717(6) 1 calc GR . . A 1
C14A C 1.163(2) 0.9244(19) 0.4233(8) 0.0458(19) Uani 0.283(6) 1 d D . . A 2
C15A C 1.1097(11) 0.9252(11) 0.4700(7) 0.060(2) Uani 0.283(6) 1 d D . . A 2
H15D H 1.1391 0.9146 0.4992 0.090 Uiso 0.283(6) 1 calc GR . . A 2
H15E H 1.0430 0.8745 0.4677 0.090 Uiso 0.283(6) 1 calc GR . . A 2
H15F H 1.1128 0.9869 0.4729 0.090 Uiso 0.283(6) 1 calc GR . . A 2
C16A C 1.1685(12) 0.8338(12) 0.4157(9) 0.0625(19) Uani 0.283(6) 1 d D . . A 2
H16D H 1.2064 0.8407 0.3861 0.094 Uiso 0.283(6) 1 calc GR . . A 2
H16E H 1.1041 0.7793 0.4115 0.094 Uiso 0.283(6) 1 calc GR . . A 2
H16F H 1.1984 0.8232 0.4448 0.094 Uiso 0.283(6) 1 calc GR . . A 2
C17A C 1.1090(16) 0.9340(17) 0.3785(9) 0.068(3) Uani 0.283(6) 1 d D . . A 2
H17D H 1.0424 0.8828 0.3795 0.102 Uiso 0.283(6) 1 calc GR . . A 2
H17E H 1.1386 0.9296 0.3477 0.102 Uiso 0.283(6) 1 calc GR . . A 2
H17F H 1.1118 0.9957 0.3799 0.102 Uiso 0.283(6) 1 calc GR . . A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.223(3) 2_865 ?
Eu1 O1 2.223(3) . ?
Eu1 O1 2.223(3) 3_785 ?
Eu1 N1 2.800(6) . ?
Eu1 N2 2.534(3) . ?
Eu1 N2 2.534(3) 3_785 ?
Eu1 N2 2.534(3) 2_865 ?
O1 C5 1.301(4) . ?
N1 C1 1.487(5) . ?
N1 C1 1.487(5) 2_865 ?
N1 C1 1.487(4) 3_785 ?
N2 C2 1.456(5) . ?
N2 C3 1.299(5) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C1 C2 1.512(6) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 H3 0.9500 . ?
C3 C4 1.446(6) . ?
C4 C5 1.410(5) . ?
C4 C9 1.405(5) . ?
C5 C6 1.434(5) . ?
C6 C7 1.386(5) . ?
C6 C10 1.538(5) . ?
C7 H7 0.9500 . ?
C7 C8 1.416(6) . ?
C8 C9 1.377(6) . ?
C8 C14 1.514(11) . ?
C8 C14A 1.61(3) . ?
C9 H9 0.9500 . ?
C10 C11 1.533(6) . ?
C10 C12 1.541(6) . ?
C10 C13 1.532(6) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 C15 1.535(11) . ?
C14 C16 1.527(11) . ?
C14 C17 1.546(9) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C14A C15A 1.529(18) . ?
C14A C16A 1.531(19) . ?
C14A C17A 1.544(18) . ?
C15A H15D 0.9800 . ?
C15A H15E 0.9800 . ?
C15A H15F 0.9800 . ?
C16A H16D 0.9800 . ?
C16A H16E 0.9800 . ?
C16A H16F 0.9800 . ?
C17A H17D 0.9800 . ?
C17A H17E 0.9800 . ?
C17A H17F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O1 94.54(10) 2_865 . ?
O1 Eu1 O1 94.54(10) 2_865 3_785 ?
O1 Eu1 O1 94.54(10) . 3_785 ?
O1 Eu1 N1 121.99(7) 2_865 . ?
O1 Eu1 N1 121.98(7) . . ?
O1 Eu1 N1 121.99(7) 3_785 . ?
O1 Eu1 N2 164.99(11) 2_865 3_785 ?
O1 Eu1 N2 164.99(10) 3_785 . ?
O1 Eu1 N2 91.18(11) 3_785 2_865 ?
O1 Eu1 N2 91.18(11) . 3_785 ?
O1 Eu1 N2 164.99(10) . 2_865 ?
O1 Eu1 N2 71.15(10) . . ?
O1 Eu1 N2 71.15(10) 3_785 3_785 ?
O1 Eu1 N2 91.18(11) 2_865 . ?
O1 Eu1 N2 71.15(10) 2_865 2_865 ?
N2 Eu1 N1 65.33(7) . . ?
N2 Eu1 N1 65.33(7) 3_785 . ?
N2 Eu1 N1 65.33(7) 2_865 . ?
N2 Eu1 N2 103.80(9) . 3_785 ?
N2 Eu1 N2 103.81(9) 2_865 . ?
N2 Eu1 N2 103.81(9) 2_865 3_785 ?
C5 O1 Eu1 146.6(2) . . ?
C1 N1 Eu1 108.9(3) . . ?
C1 N1 Eu1 108.9(3) 2_865 . ?
C1 N1 Eu1 108.9(3) 3_785 . ?
C1 N1 C1 110.0(3) . 3_785 ?
C1 N1 C1 110.0(3) 2_865 3_785 ?
C1 N1 C1 110.0(3) 2_865 . ?
C2 N2 Eu1 113.1(2) . . ?
C3 N2 Eu1 129.5(3) . . ?
C3 N2 C2 117.3(3) . . ?
N1 C1 H1A 109.4 . . ?
N1 C1 H1B 109.4 . . ?
N1 C1 C2 111.3(4) . . ?
H1A C1 H1B 108.0 . . ?
C2 C1 H1A 109.4 . . ?
C2 C1 H1B 109.4 . . ?
N2 C2 C1 107.9(3) . . ?
N2 C2 H2A 110.1 . . ?
N2 C2 H2B 110.1 . . ?
C1 C2 H2A 110.1 . . ?
C1 C2 H2B 110.1 . . ?
H2A C2 H2B 108.4 . . ?
N2 C3 H3 116.0 . . ?
N2 C3 C4 128.1(4) . . ?
C4 C3 H3 116.0 . . ?
C5 C4 C3 122.5(3) . . ?
C9 C4 C3 116.1(4) . . ?
C9 C4 C5 121.3(4) . . ?
O1 C5 C4 121.6(4) . . ?
O1 C5 C6 120.6(3) . . ?
C4 C5 C6 117.8(3) . . ?
C5 C6 C10 120.3(3) . . ?
C7 C6 C5 118.4(4) . . ?
C7 C6 C10 121.3(4) . . ?
C6 C7 H7 117.9 . . ?
C6 C7 C8 124.3(4) . . ?
C8 C7 H7 117.9 . . ?
C7 C8 C14 119.8(5) . . ?
C7 C8 C14A 121.5(9) . . ?
C9 C8 C7 116.3(4) . . ?
C9 C8 C14 123.7(5) . . ?
C9 C8 C14A 120.8(9) . . ?
C4 C9 H9 119.0 . . ?
C8 C9 C4 121.9(4) . . ?
C8 C9 H9 119.0 . . ?
C6 C10 C12 110.2(3) . . ?
C11 C10 C6 110.0(4) . . ?
C11 C10 C12 110.0(4) . . ?
C13 C10 C6 112.2(3) . . ?
C13 C10 C11 107.4(4) . . ?
C13 C10 C12 107.1(4) . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C10 C13 H13A 109.5 . . ?
C10 C13 H13B 109.5 . . ?
C10 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C8 C14 C15 111.3(7) . . ?
C8 C14 C16 111.3(6) . . ?
C8 C14 C17 109.0(6) . . ?
C15 C14 C17 107.1(7) . . ?
C16 C14 C15 108.4(7) . . ?
C16 C14 C17 109.5(8) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C14 C17 H17A 109.5 . . ?
C14 C17 H17B 109.5 . . ?
C14 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15A C14A C8 113.7(16) . . ?
C15A C14A C17A 107.0(18) . . ?
C16A C14A C8 104.2(15) . . ?
C16A C14A C15A 114.9(18) . . ?
C16A C14A C17A 107.5(18) . . ?
C17A C14A C8 109.4(17) . . ?
C14A C15A H15D 109.5 . . ?
C14A C15A H15E 109.5 . . ?
C14A C15A H15F 109.5 . . ?
H15D C15A H15E 109.5 . . ?
H15D C15A H15F 109.5 . . ?
H15E C15A H15F 109.5 . . ?
C14A C16A H16D 109.5 . . ?
C14A C16A H16E 109.5 . . ?
C14A C16A H16F 109.5 . . ?
H16D C16A H16E 109.5 . . ?
H16D C16A H16F 109.5 . . ?
H16E C16A H16F 109.5 . . ?
C14A C17A H17D 109.5 . . ?
C14A C17A H17E 109.5 . . ?
C14A C17A H17F 109.5 . . ?
H17D C17A H17E 109.5 . . ?
H17D C17A H17F 109.5 . . ?
H17E C17A H17F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C5 C4 4.1(7) . . . . ?
Eu1 O1 C5 C6 -178.6(3) . . . . ?
Eu1 N1 C1 C2 33.5(4) . . . . ?
Eu1 N2 C2 C1 61.0(4) . . . . ?
Eu1 N2 C3 C4 -7.0(6) . . . . ?
O1 C5 C6 C7 -177.0(4) . . . . ?
O1 C5 C6 C10 2.2(6) . . . . ?
N1 C1 C2 N2 -63.0(4) . . . . ?
N2 C3 C4 C5 -0.1(7) . . . . ?
N2 C3 C4 C9 -174.8(4) . . . . ?
C1 N1 C1 C2 -85.8(6) 2_865 . . . ?
C1 N1 C1 C2 152.9(4) 3_785 . . . ?
C2 N2 C3 C4 171.5(4) . . . . ?
C3 N2 C2 C1 -117.7(4) . . . . ?
C3 C4 C5 O1 2.7(6) . . . . ?
C3 C4 C5 C6 -174.7(4) . . . . ?
C3 C4 C9 C8 173.8(4) . . . . ?
C4 C5 C6 C7 0.4(6) . . . . ?
C4 C5 C6 C10 179.6(4) . . . . ?
C5 C4 C9 C8 -1.0(7) . . . . ?
C5 C6 C7 C8 0.7(6) . . . . ?
C5 C6 C10 C11 -60.6(5) . . . . ?
C5 C6 C10 C12 60.8(5) . . . . ?
C5 C6 C10 C13 180.0(4) . . . . ?
C6 C7 C8 C9 -1.9(7) . . . . ?
C6 C7 C8 C14 -176.7(5) . . . . ?
C6 C7 C8 C14A 165.0(9) . . . . ?
C7 C6 C10 C11 118.5(4) . . . . ?
C7 C6 C10 C12 -120.1(4) . . . . ?
C7 C6 C10 C13 -0.9(6) . . . . ?
C7 C8 C9 C4 2.0(7) . . . . ?
C7 C8 C14 C15 -173.0(5) . . . . ?
C7 C8 C14 C16 65.9(8) . . . . ?
C7 C8 C14 C17 -55.0(9) . . . . ?
C7 C8 C14A C15A -106.2(15) . . . . ?
C7 C8 C14A C16A 127.9(12) . . . . ?
C7 C8 C14A C17A 13.3(18) . . . . ?
C9 C4 C5 O1 177.1(4) . . . . ?
C9 C4 C5 C6 -0.3(6) . . . . ?
C9 C8 C14 C15 12.5(8) . . . . ?
C9 C8 C14 C16 -108.6(7) . . . . ?
C9 C8 C14 C17 130.5(7) . . . . ?
C9 C8 C14A C15A 60.1(17) . . . . ?
C9 C8 C14A C16A -65.8(15) . . . . ?
C9 C8 C14A C17A 179.6(12) . . . . ?
C10 C6 C7 C8 -178.5(4) . . . . ?
C14 C8 C9 C4 176.6(5) . . . . ?
C14A C8 C9 C4 -165.0(9) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.230 -0.663 0.250 903.7 199.9 ?
2 -0.817 -0.647 0.750 903.7 191.0 ?


_olex2_submission_special_instructions 'No special instructions were received'
