# 1. SUBMISSION DETAILS
data_publication_text
_ccdc_journal_manuscript_code    'Inorg. Chem.'
_publ_requested_journal          'Inorganic Chemistry'
_publ_requested_category         FA
_publ_requested_coeditor_name    ?
_publ_contact_author_name        'Dr. Pavlo Solokha'
_publ_contact_author_address     
;Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
_publ_contact_author_email       'pavlo.solokha@unige.it'
_publ_contact_author_phone       '+39 010 3536159'
#
#=============================================================================

# 2. TITLE AY AUTHOR LIST

_publ_section_title              
;
A new glance on the R₂MGe₆ (R = rare earth metal, M=another metal)
compouYs. An experimental aY theoretical study of R₂PdGe₆ germanides.
;
# --------------------------------------------------------------------------
loop_
	_publ_author_name
        _publ_author_footnote
	_publ_author_address
'De Negri, Serena'
;
Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
'Freccero, Riccardo'
;
Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
'Proserpio, Davide Maria'
;
Università degli studi di Milano
Dipartimento di Chimica
Via Golgi 19
I-20133 Milano
Italy
;
;
Also at Samara Center for Theoretical Materials Science (SCTMS)
Samara State University
443011 Samara
Russian Federation
;
'Saccone, Adriana'
;
Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
#============================================================================= 
 
data_shelx
 
_audit_creation_method            'SHELXL-2014/7'
_chemical_name_systematic         ?
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          'Ge6 Lu2 Pd'
_chemical_formula_sum             'Ge6 Lu2 Pd' 
_chemical_formula_weight          891.88

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'Ge'  'Ge'   0.1547   1.8001
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pd'  'Pd'  -0.9988   1.0072
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Lu'  'Lu'  -0.4720   5.8584
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_space_group_crystal_system       orthorhombic
_space_group_IT_number            64
_space_group_name_H-M_alt         'C m c a'
_space_group_name_Hall            '-C 2bc 2'
 
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
 
loop_
 _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y+1/2, z+1/2'
 '-x, y+1/2, -z+1/2'
 'x, -y, -z'
 'x+1/2, y+1/2, z'
 '-x+1/2, -y+1, z+1/2'
 '-x+1/2, y+1, -z+1/2'
 'x+1/2, -y+1/2, -z'
 '-x, -y, -z'
 'x, y-1/2, -z-1/2'
 'x, -y-1/2, z-1/2'
 '-x, y, z'
 '-x+1/2, -y+1/2, -z'
 'x+1/2, y, -z-1/2'
 'x+1/2, -y, z-1/2'
 '-x+1/2, y+1/2, z'
 
_cell_length_a                    8.0725(8)
_cell_length_b                    7.9791(8)
_cell_length_c                    21.317(2)
_cell_angle_alpha                 90
_cell_angle_beta                  90
_cell_angle_gamma                 90
_cell_volume                      1373.0(2)
_cell_formula_units_Z             8
_cell_measurement_temperature     293(2)
_cell_measurement_reflns_used     874
_cell_measurement_theta_min       3.82
_cell_measurement_theta_max       31.21
 
_exptl_crystal_description        'irregularly shaped' 
_exptl_crystal_colour             'metallic grey'
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_density_diffrn     8.629          
_exptl_crystal_F_000              3040
_exptl_transmission_factor_min    0.3785
_exptl_transmission_factor_max    0.7463
_exptl_crystal_size_max           0.03
_exptl_crystal_size_mid           0.02
_exptl_crystal_size_min           0.01
_exptl_absorpt_coefficient_mu     56.774
_shelx_estimated_absorpt_T_min    ?
_shelx_estimated_absorpt_T_max    ?
_exptl_absorpt_correction_type    'multi-scan'
_exptl_absorpt_correction_T_min   ? 
_exptl_absorpt_correction_T_max   ? 
_exptl_absorpt_process_details    'Bruker SADABS'  
_diffrn_ambient_temperature       295(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'Bruker APEXII'
_diffrn_measurement_method        'ω scans'
_diffrn_detector_area_resol_mean  ?
_diffrn_reflns_number             18294
_diffrn_reflns_av_unetI/netI      0.0284
_diffrn_reflns_av_R_equivalents   0.0636
_diffrn_standards_number          0
_diffrn_standards_interval_count  0 
_diffrn_standards_interval_time   0
_diffrn_standards_decay_%         0
_diffrn_reflns_limit_h_min        -11
_diffrn_reflns_limit_h_max        11
_diffrn_reflns_limit_k_min        -11
_diffrn_reflns_limit_k_max        11
_diffrn_reflns_limit_l_min        -31
_diffrn_reflns_limit_l_max        31
_diffrn_reflns_theta_min          1.911
_diffrn_reflns_theta_max          31.772
_diffrn_reflns_theta_full         25.242
_diffrn_measured_fraction_theta_max   0.984
_diffrn_measured_fraction_theta_full  1.000
_diffrn_reflns_Laue_measured_fraction_max    0.984
_diffrn_reflns_Laue_measured_fraction_full   1.000
_diffrn_reflns_point_group_measured_fraction_max   0.984
_diffrn_reflns_point_group_measured_fraction_full  1.000
_reflns_number_total              1225
_reflns_number_gt                 874
_reflns_threshold_expression      'I > 2σ(I)'
_reflns_Friedel_coverage          0.000
_reflns_Friedel_fraction_max      .
_reflns_Friedel_fraction_full     .
 
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
 
_computing_data_collection        ?
_computing_cell_refinement        ?
_computing_data_reduction         ?
_computing_structure_solution     ?
_computing_structure_refinement 'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics     ?
_computing_publication_material   ?
_refine_special_details           ?
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0342P)²+18.7444P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      ?
_atom_sites_solution_secondary    ?
_atom_sites_solution_hydrogens    .
_refine_ls_hydrogen_treatment     undef
_refine_ls_extinction_method      'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef        0.000412(19)
_refine_ls_extinction_expression
 'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
_refine_ls_number_reflns          1225
_refine_ls_number_parameters      50
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0399
_refine_ls_R_factor_gt            0.0224
_refine_ls_wR_factor_ref          0.0634
_refine_ls_wR_factor_gt           0.0557
_refine_ls_goodness_of_fit_ref    0.912
_refine_ls_restrained_S_all       0.912
_refine_ls_shift/su_max           0.051
_refine_ls_shift/su_mean          0.006
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_site_symmetry_order  
 _atom_site_calc_flag
 _atom_site_refinement_flags_posn
 _atom_site_refinement_flags_adp
 _atom_site_refinement_flags_occupancy
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Lu Lu 0.25159(3) 0.37591(4) 0.08075(2) 0.00719(9) Uani 1 1 d . . . . .
Ge1 Ge 0.0000 0.13448(14) 0.02722(4) 0.00865(18) Uani 1 2 d S T P . .
Ge2 Ge 0.0000 0.11768(14) 0.45459(5) 0.00976(19) Uani 1 2 d S T P . .
Ge3 Ge 0.0000 0.40517(12) 0.19299(5) 0.00852(19) Uani 1 2 d S T P . .
Ge4 Ge 0.0000 0.34839(11) 0.30862(4) 0.00788(19) Uani 1 2 d S T P . .
Ge5 Ge 0.27669(8) 0.12673(9) 0.19238(3) 0.00820(14) Uani 1 1 d . . . . .
Pd Pd 0.0000 0.12825(9) 0.14062(3) 0.00677(14) Uani 1 2 d S T P . .
 
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Lu Ge2 2.9007(8) 10_566 ?
Lu Ge2 2.9722(9) 14_556 ?
Lu Ge1 3.0229(9) . ?
Lu Ge1 3.0952(9) 5 ?
Lu Ge5 3.1074(8) . ?
Lu Ge5 3.1177(8) 16 ?
Lu Ge4 3.1032(8) 14_556 ?
Lu Pd 3.1078(6) . ?
Lu Pd 3.1151(7) 5 ?
Lu Ge1 3.0536(8) 13 ?
Lu Ge3 3.1470(8) . ?
Lu Ge2 3.3704(9) 2_554 ?
Ge1 Ge1 2.440(2) 9 ?
Ge1 Pd 2.4179(11) . ?
Ge1 Ge2 2.5114(16) 2_554 ?
Ge1 Lu 3.0229(9) 12 ?
Ge1 Lu 3.0951(9) 5_445 ?
Ge1 Lu 3.0951(9) 16_545 ?
Ge1 Lu 3.0536(8) 8_455 ?
Ge1 Lu 3.0536(8) 13 ?
Ge2 Ge1 2.5114(16) 2 ?
Ge2 Ge2 2.697(2) 9_556 ?
Ge2 Lu 2.9007(8) 3_545 ?
Ge2 Lu 2.9007(8) 10_556 ?
Ge2 Lu 2.9721(9) 7_545 ?
Ge2 Lu 2.9721(9) 14_456 ?
Ge2 Lu 3.3704(9) 11_566 ?
Ge2 Lu 3.3704(9) 2 ?
Ge3 Ge4 2.5063(14) . ?
Ge3 Pd 2.4755(12) . ?
Ge3 Ge5 2.5249(10) 16 ?
Ge3 Ge5 2.5249(10) 5_455 ?
Ge3 Lu 3.1471(8) 12 ?
Ge4 Pd 2.4813(12) 10_566 ?
Ge4 Ge5 2.5255(10) 14_456 ?
Ge4 Ge5 2.5255(10) 7_545 ?
Ge4 Lu 3.1033(8) 7_545 ?
Ge4 Lu 3.1033(8) 14_456 ?
Ge5 Ge5 2.4942(14) 7_545 ?
Ge5 Pd 2.4912(7) . ?
Ge5 Ge3 2.5249(10) 5_545 ?
Ge5 Ge4 2.5255(10) 14_556 ?
Ge5 Lu 3.1177(8) 16_545 ?
Pd Ge4 2.4813(12) 10_556 ?
Pd Ge5 2.4912(7) 12 ?
Pd Lu 3.1078(6) 12 ?
Pd Lu 3.1152(7) 5_445 ?
Pd Lu 3.1152(7) 16_545 ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
Ge2 Lu Ge2 150.18(4) 10_566 14_556 ?
Ge2 Lu Ge1 81.68(2) 10_566 . ?
Ge2 Lu Ge1 85.17(3) 14_556 . ?
Ge2 Lu Ge1 85.10(2) 10_566 5 ?
Ge2 Lu Ge1 86.07(2) 14_556 5 ?
Ge1 Lu Ge1 136.13(3) . 5 ?
Ge2 Lu Ge5 132.07(2) 10_566 . ?
Ge2 Lu Ge5 72.94(2) 14_556 . ?
Ge1 Lu Ge5 85.71(2) . . ?
Ge1 Lu Ge5 131.804(19) 5 . ?
Ge2 Lu Ge5 73.74(3) 10_566 16 ?
Ge2 Lu Ge5 133.46(2) 14_556 16 ?
Ge1 Lu Ge5 130.39(2) . 16 ?
Ge1 Lu Ge5 84.32(2) 5 16 ?
Ge5 Lu Ge5 80.273(19) . 16 ?
Ge2 Lu Ge4 134.17(3) 10_566 14_556 ?
Ge2 Lu Ge4 73.00(2) 14_556 14_556 ?
Ge1 Lu Ge4 132.53(3) . 14_556 ?
Ge1 Lu Ge4 84.76(2) 5 14_556 ?
Ge5 Lu Ge4 47.99(2) . 14_556 ?
Ge5 Lu Ge4 60.84(2) 16 14_556 ?
Ge2 Lu Pd 94.126(19) 10_566 . ?
Ge2 Lu Pd 95.98(2) 14_556 . ?
Ge1 Lu Pd 46.43(2) . . ?
Ge1 Lu Pd 177.00(3) 5 . ?
Ge5 Lu Pd 47.260(16) . . ?
Ge5 Lu Pd 92.69(2) 16 . ?
Ge4 Lu Pd 93.742(19) 14_556 . ?
Ge2 Lu Pd 97.31(3) 10_566 5 ?
Ge2 Lu Pd 96.754(19) 14_556 5 ?
Ge1 Lu Pd 177.50(2) . 5 ?
Ge1 Lu Pd 45.83(2) 5 5 ?
Ge5 Lu Pd 93.32(2) . 5 ?
Ge5 Lu Pd 47.119(16) 16 5 ?
Ge4 Lu Pd 47.03(2) 14_556 5 ?
Pd Lu Pd 131.56(2) . 5 ?
Ge2 Lu Ge1 106.39(3) 10_566 13 ?
Ge2 Lu Ge1 49.24(3) 14_556 13 ?
Ge1 Lu Ge1 98.014(15) . 13 ?
Ge1 Lu Ge1 46.74(4) 5 13 ?
Ge5 Lu Ge1 121.13(2) . 13 ?
Ge5 Lu Ge1 129.85(2) 16 13 ?
Ge4 Lu Ge1 98.420(19) 14_556 13 ?
Pd Lu Ge1 136.17(3) . 13 ?
Pd Lu Ge1 84.47(2) 5 13 ?
Ge2 Lu Ge3 72.32(2) 10_566 . ?
Ge2 Lu Ge3 132.81(3) 14_556 . ?
Ge1 Lu Ge3 84.30(2) . . ?
Ge1 Lu Ge3 130.46(3) 5 . ?
Ge5 Lu Ge3 60.49(2) . . ?
Ge5 Lu Ge3 47.53(2) 16 . ?
Ge4 Lu Ge3 81.058(19) 14_556 . ?
Pd Lu Ge3 46.62(2) . . ?
Pd Lu Ge3 93.211(19) 5 . ?
Ge1 Lu Ge3 177.20(3) 13 . ?
Ge2 Lu Ge2 50.26(4) 10_566 2_554 ?
Ge2 Lu Ge2 102.407(16) 14_556 2_554 ?
Ge1 Lu Ge2 45.86(3) . 2_554 ?
Ge1 Lu Ge2 94.94(2) 5 2_554 ?
Ge5 Lu Ge2 131.30(2) . 2_554 ?
Ge5 Lu Ge2 123.72(2) 16 2_554 ?
Ge4 Lu Ge2 175.40(2) 14_556 2_554 ?
Pd Lu Ge2 86.762(19) . 2_554 ?
Pd Lu Ge2 134.83(2) 5 2_554 ?
Ge1 Lu Ge2 78.158(19) 13 2_554 ?
Ge3 Lu Ge2 102.509(19) . 2_554 ?
Ge1 Ge1 Pd 117.22(7) 9 . ?
Ge1 Ge1 Ge2 113.55(6) 9 2_554 ?
Pd Ge1 Ge2 129.23(6) . 2_554 ?
Ge1 Ge1 Lu 137.740(16) 9 12 ?
Pd Ge1 Lu 68.64(2) . 12 ?
Ge2 Ge1 Lu 74.39(4) 2_554 12 ?
Ge1 Ge1 Lu 137.741(16) 9 . ?
Pd Ge1 Lu 68.63(2) . . ?
Ge2 Ge1 Lu 74.39(4) 2_554 . ?
Lu Ge1 Lu 84.42(3) 12 . ?
Ge1 Ge1 Lu 65.73(4) 9 5_445 ?
Pd Ge1 Lu 67.52(2) . 5_445 ?
Ge2 Ge1 Lu 138.776(15) 2_554 5_445 ?
Lu Ge1 Lu 81.393(14) 12 5_445 ?
Lu Ge1 Lu 136.13(3) . 5_445 ?
Ge1 Ge1 Lu 65.73(4) 9 16_545 ?
Pd Ge1 Lu 67.52(2) . 16_545 ?
Ge2 Ge1 Lu 138.776(15) 2_554 16_545 ?
Lu Ge1 Lu 136.13(3) 12 16_545 ?
Lu Ge1 Lu 81.392(14) . 16_545 ?
Lu Ge1 Lu 80.76(3) 5_445 16_545 ?
Ge1 Ge1 Lu 67.52(3) 9 8_455 ?
Pd Ge1 Lu 138.847(13) . 8_455 ?
Ge2 Ge1 Lu 63.69(3) 2_554 8_455 ?
Lu Ge1 Lu 81.985(15) 12 8_455 ?
Lu Ge1 Lu 137.99(4) . 8_455 ?
Lu Ge1 Lu 80.463(17) 5_445 8_455 ?
Lu Ge1 Lu 133.25(4) 16_545 8_455 ?
Ge1 Ge1 Lu 67.52(3) 9 13 ?
Pd Ge1 Lu 138.847(13) . 13 ?
Ge2 Ge1 Lu 63.69(3) 2_554 13 ?
Lu Ge1 Lu 137.99(4) 12 13 ?
Lu Ge1 Lu 81.986(15) . 13 ?
Lu Ge1 Lu 133.25(4) 5_445 13 ?
Lu Ge1 Lu 80.463(17) 16_545 13 ?
Lu Ge1 Lu 82.10(3) 8_455 13 ?
Ge1 Ge2 Ge2 96.07(6) 2 9_556 ?
Ge1 Ge2 Lu 133.14(2) 2 3_545 ?
Ge2 Ge2 Lu 73.94(4) 9_556 3_545 ?
Ge1 Ge2 Lu 133.14(2) 2 10_556 ?
Ge2 Ge2 Lu 73.94(4) 9_556 10_556 ?
Lu Ge2 Lu 88.88(3) 3_545 10_556 ?
Ge1 Ge2 Lu 67.07(3) 2 7_545 ?
Ge2 Ge2 Lu 131.65(3) 9_556 7_545 ?
Lu Ge2 Lu 150.19(4) 3_545 7_545 ?
Lu Ge2 Lu 85.575(12) 10_556 7_545 ?
Ge1 Ge2 Lu 67.07(3) 2 14_456 ?
Ge2 Ge2 Lu 131.65(3) 9_556 14_456 ?
Lu Ge2 Lu 85.575(12) 3_545 14_456 ?
Lu Ge2 Lu 150.19(4) 10_556 14_456 ?
Lu Ge2 Lu 84.86(3) 7_545 14_456 ?
Ge1 Ge2 Lu 59.75(3) 2 11_566 ?
Ge2 Ge2 Lu 55.80(3) 9_556 11_566 ?
Lu Ge2 Lu 129.73(4) 3_545 11_566 ?
Lu Ge2 Lu 78.192(17) 10_556 11_566 ?
Lu Ge2 Lu 77.592(16) 7_545 11_566 ?
Lu Ge2 Lu 126.74(3) 14_456 11_566 ?
Ge1 Ge2 Lu 59.75(3) 2 2 ?
Ge2 Ge2 Lu 55.80(3) 9_556 2 ?
Lu Ge2 Lu 78.192(17) 3_545 2 ?
Lu Ge2 Lu 129.73(4) 10_556 2 ?
Lu Ge2 Lu 126.74(3) 7_545 2 ?
Lu Ge2 Lu 77.592(16) 14_456 2 ?
Lu Ge2 Lu 74.11(2) 11_566 2 ?
Ge4 Ge3 Pd 106.39(4) . . ?
Ge4 Ge3 Ge5 97.56(4) . 16 ?
Pd Ge3 Ge5 128.51(3) . 16 ?
Ge4 Ge3 Ge5 97.56(4) . 5_455 ?
Pd Ge3 Ge5 128.51(3) . 5_455 ?
Ge5 Ge3 Ge5 91.12(4) 16 5_455 ?
Ge4 Ge3 Lu 137.250(19) . . ?
Pd Ge3 Lu 65.86(2) . . ?
Ge5 Ge3 Lu 65.62(2) 16 . ?
Ge5 Ge3 Lu 120.58(4) 5_455 . ?
Ge4 Ge3 Lu 137.251(19) . 12 ?
Pd Ge3 Lu 65.85(2) . 12 ?
Ge5 Ge3 Lu 120.58(4) 16 12 ?
Ge5 Ge3 Lu 65.62(2) 5_455 12 ?
Lu Ge3 Lu 80.39(3) . 12 ?
Ge3 Ge4 Pd 105.44(4) . 10_566 ?
Ge3 Ge4 Ge5 96.79(4) . 14_456 ?
Pd Ge4 Ge5 129.34(3) 10_566 14_456 ?
Ge3 Ge4 Ge5 96.79(4) . 7_545 ?
Pd Ge4 Ge5 129.34(3) 10_566 7_545 ?
Ge5 Ge4 Ge5 91.09(4) 14_456 7_545 ?
Ge3 Ge4 Lu 137.274(18) . 7_545 ?
Pd Ge4 Lu 66.73(2) 10_566 7_545 ?
Ge5 Ge4 Lu 121.14(4) 14_456 7_545 ?
Ge5 Ge4 Lu 66.09(2) 7_545 7_545 ?
Ge3 Ge4 Lu 137.274(18) . 14_456 ?
Pd Ge4 Lu 66.73(2) 10_566 14_456 ?
Ge5 Ge4 Lu 66.09(2) 14_456 14_456 ?
Ge5 Ge4 Lu 121.14(4) 7_545 14_456 ?
Lu Ge4 Lu 80.51(3) 7_545 14_456 ?
Ge5 Ge5 Pd 106.34(4) 7_545 . ?
Ge5 Ge5 Ge3 96.79(4) 7_545 5_545 ?
Pd Ge5 Ge3 130.23(4) . 5_545 ?
Ge5 Ge5 Ge4 97.57(4) 7_545 14_556 ?
Pd Ge5 Ge4 129.26(4) . 14_556 ?
Ge3 Ge5 Ge4 88.90(3) 5_545 14_556 ?
Ge5 Ge5 Lu 137.985(18) 7_545 . ?
Pd Ge5 Lu 66.38(2) . . ?
Ge3 Ge5 Lu 119.90(3) 5_545 . ?
Ge4 Ge5 Lu 65.92(3) 14_556 . ?
Ge5 Ge5 Lu 137.657(18) 7_545 16_545 ?
Pd Ge5 Lu 66.39(2) . 16_545 ?
Ge3 Ge5 Lu 66.84(3) 5_545 16_545 ?
Ge4 Ge5 Lu 119.69(3) 14_556 16_545 ?
Lu Ge5 Lu 79.717(19) . 16_545 ?
Ge1 Pd Ge3 115.63(5) . . ?
Ge1 Pd Ge4 117.03(5) . 10_556 ?
Ge3 Pd Ge4 127.35(4) . 10_556 ?
Ge1 Pd Ge5 116.29(2) . . ?
Ge3 Pd Ge5 78.73(3) . . ?
Ge4 Pd Ge5 78.61(3) 10_556 . ?
Ge1 Pd Ge5 116.29(2) . 12 ?
Ge3 Pd Ge5 78.73(3) . 12 ?
Ge4 Pd Ge5 78.61(3) 10_556 12 ?
Ge5 Pd Ge5 127.42(4) . 12 ?
Ge1 Pd Lu 64.94(2) . . ?
Ge3 Pd Lu 67.52(2) . . ?
Ge4 Pd Lu 138.700(12) 10_556 . ?
Ge5 Pd Lu 66.36(2) . . ?
Ge5 Pd Lu 140.43(3) 12 . ?
Ge1 Pd Lu 64.93(2) . 12 ?
Ge3 Pd Lu 67.52(2) . 12 ?
Ge4 Pd Lu 138.700(12) 10_556 12 ?
Ge5 Pd Lu 140.43(3) . 12 ?
Ge5 Pd Lu 66.36(2) 12 12 ?
Lu Pd Lu 81.61(2) . 12 ?
Ge1 Pd Lu 66.65(2) . 5_445 ?
Ge3 Pd Lu 139.611(12) . 5_445 ?
Ge4 Pd Lu 66.23(2) 10_556 5_445 ?
Ge5 Pd Lu 139.06(3) . 5_445 ?
Ge5 Pd Lu 66.49(2) 12 5_445 ?
Lu Pd Lu 131.56(2) . 5_445 ?
Lu Pd Lu 79.749(11) 12 5_445 ?
Ge1 Pd Lu 66.65(2) . 16_545 ?
Ge3 Pd Lu 139.611(12) . 16_545 ?
Ge4 Pd Lu 66.23(2) 10_556 16_545 ?
Ge5 Pd Lu 66.49(2) . 16_545 ?
Ge5 Pd Lu 139.06(3) 12 16_545 ?
Lu Pd Lu 79.750(11) . 16_545 ?
Lu Pd Lu 131.56(2) 12 16_545 ?
Lu Pd Lu 80.14(2) 5_445 16_545 ?
 
_refine_diff_density_max    1.772
_refine_diff_density_min   -1.634
_refine_diff_density_rms    0.387



