# 1. SUBMISSION DETAILS
data_publication_text
_ccdc_journal_manuscript_code    'Inorg. Chem.'
_publ_requested_journal          'Inorganic Chemistry'
_publ_requested_category         FA
_publ_requested_coeditor_name    ?
_publ_contact_author_name        'Dr. Pavlo Solokha'
_publ_contact_author_address     
;Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
_publ_contact_author_email       'pavlo.solokha@unige.it'
_publ_contact_author_phone       '+39 010 3536159'
#
#=============================================================================

# 2. TITLE AY AUTHOR LIST

_publ_section_title              
;
A new glance on the R₂MGe₆ (R = rare earth metal, M=another metal)
compouYs. An experimental aY theoretical study of R₂PdGe₆ germanides.
;
# --------------------------------------------------------------------------
loop_
	_publ_author_name
        _publ_author_footnote
	_publ_author_address
'De Negri, Serena'
;
Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
'Freccero, Riccardo'
;
Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
'Proserpio, Davide Maria'
;
Università degli studi di Milano
Dipartimento di Chimica
Via Golgi 19
I-20133 Milano
Italy
;
;
Also at Samara Center for Theoretical Materials Science (SCTMS)
Samara State University
443011 Samara
Russian Federation
;
'Saccone, Adriana'
;
Dipartimento di Chimica e Chimica IYustriale
Sezione di Chimica Inorganica e Metallurgia
Università di Genova
Via Dodecaneso 31
I-16146 Genova
Italy
;
#============================================================================= 
  
data_shelx
 
_audit_creation_method            'SHELXL-2014/7'
_chemical_name_systematic         ?
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          'Ge6 Pd Pr2'
_chemical_formula_sum             'Ge6 Pd Pr2' 
_chemical_formula_weight          823.76

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'Ge'  'Ge'   0.1547   1.8001
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pd'  'Pd'  -0.9988   1.0072
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pr'  'Pr'  -0.2180   2.8214
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_space_group_crystal_system       orthorhombic
_space_group_IT_number            64
_space_group_name_H-M_alt         'C m c a'
_space_group_name_Hall            '-C 2bc 2'
 
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
 
loop_
 _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y+1/2, z+1/2'
 '-x, y+1/2, -z+1/2'
 'x, -y, -z'
 'x+1/2, y+1/2, z'
 '-x+1/2, -y+1, z+1/2'
 '-x+1/2, y+1, -z+1/2'
 'x+1/2, -y+1/2, -z'
 '-x, -y, -z'
 'x, y-1/2, -z-1/2'
 'x, -y-1/2, z-1/2'
 '-x, y, z'
 '-x+1/2, -y+1/2, -z'
 'x+1/2, y, -z-1/2'
 'x+1/2, -y, z-1/2'
 '-x+1/2, y+1/2, z'
 
_cell_length_a                    8.3129(5)
_cell_length_b                    8.1540(5)
_cell_length_c                    21.9959(13)
_cell_angle_alpha                 90
_cell_angle_beta                  90
_cell_angle_gamma                 90
_cell_volume                      1490.96(16)
_cell_formula_units_Z             8
_cell_measurement_temperature     295(2)
_cell_measurement_reflns_used     870
_cell_measurement_theta_min       3.63
_cell_measurement_theta_max       30.60
 
_exptl_crystal_description        'irregularly shaped' 
_exptl_crystal_colour             'metallic grey'
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_density_diffrn     7.340          
_exptl_crystal_F_000              2848
_exptl_transmission_factor_min    0.3534
_exptl_transmission_factor_max    0.7463
_exptl_crystal_size_max           0.04
_exptl_crystal_size_mid           0.03
_exptl_crystal_size_min           0.02
_exptl_absorpt_coefficient_mu     38.869
_shelx_estimated_absorpt_T_min    ?
_shelx_estimated_absorpt_T_max    ?
_exptl_absorpt_correction_type    'multi-scan'
_exptl_absorpt_correction_T_min   ? 
_exptl_absorpt_correction_T_max   ? 
_exptl_absorpt_process_details    'Bruker SADABS'  
_diffrn_ambient_temperature       295(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'Bruker APEXII'
_diffrn_measurement_method        'ω scans'
_diffrn_detector_area_resol_mean  ?
_diffrn_reflns_number             16918
_diffrn_reflns_av_unetI/netI      0.0270
_diffrn_reflns_av_R_equivalents   0.0636
_diffrn_standards_number          0
_diffrn_standards_interval_count  0 
_diffrn_standards_interval_time   0
_diffrn_standards_decay_%         0
_diffrn_reflns_limit_h_min        -12
_diffrn_reflns_limit_h_max        12
_diffrn_reflns_limit_k_min        -11
_diffrn_reflns_limit_k_max        11
_diffrn_reflns_limit_l_min        -32
_diffrn_reflns_limit_l_max        32
_diffrn_reflns_theta_min          1.852
_diffrn_reflns_theta_max          31.486
_diffrn_reflns_theta_full         25.242
_diffrn_measured_fraction_theta_max   0.979
_diffrn_measured_fraction_theta_full  1.000
_diffrn_reflns_Laue_measured_fraction_max    0.979
_diffrn_reflns_Laue_measured_fraction_full   1.000
_diffrn_reflns_point_group_measured_fraction_max   0.979
_diffrn_reflns_point_group_measured_fraction_full  1.000
_reflns_number_total              1296
_reflns_number_gt                 870
_reflns_threshold_expression      'I > 2σ(I)'
_reflns_Friedel_coverage          0.000
_reflns_Friedel_fraction_max      .
_reflns_Friedel_fraction_full     .
 
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
 
_computing_data_collection        ?
_computing_cell_refinement        ?
_computing_data_reduction         ?
_computing_structure_solution     ?
_computing_structure_refinement 'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics     ?
_computing_publication_material   ?
_refine_special_details           ?
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0102P)²+2.2693P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      ?
_atom_sites_solution_secondary    ?
_atom_sites_solution_hydrogens    .
_refine_ls_hydrogen_treatment     undef
_refine_ls_extinction_method      'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef        0.000308(13)
_refine_ls_extinction_expression
 'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
_refine_ls_number_reflns          1296
_refine_ls_number_parameters      50
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0366
_refine_ls_R_factor_gt            0.0197
_refine_ls_wR_factor_ref          0.0421
_refine_ls_wR_factor_gt           0.0372
_refine_ls_goodness_of_fit_ref    1.059
_refine_ls_restrained_S_all       1.059
_refine_ls_shift/su_max           0.014
_refine_ls_shift/su_mean          0.002
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_site_symmetry_order  
 _atom_site_calc_flag
 _atom_site_refinement_flags_posn
 _atom_site_refinement_flags_adp
 _atom_site_refinement_flags_occupancy
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Pr Pr 0.25041(2) 0.37528(10) 0.08254(2) 0.00671(6) Uani 1 1 d . . . . .
Ge1 Ge 0.0000 0.1286(2) 0.03042(3) 0.00837(12) Uani 1 2 d S T P . .
Ge2 Ge 0.0000 0.1213(2) 0.46216(3) 0.00887(12) Uani 1 2 d S T P . .
Ge3 Ge 0.0000 0.40475(8) 0.19441(3) 0.00889(16) Uani 1 2 d S T P . .
Ge4 Ge 0.0000 0.34608(8) 0.30572(3) 0.00855(16) Uani 1 2 d S T P . .
Ge5 Ge 0.27735(4) 0.12541(13) 0.19442(2) 0.00863(9) Uani 1 1 d . . . . .
Pd Pd 0.0000 0.12555(6) 0.14496(2) 0.00765(9) Uani 1 2 d S T P . .
 
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Pr Ge2 3.0535(13) 10_566 ?
Pr Ge2 3.0921(14) 14_556 ?
Pr Ge1 3.1133(13) . ?
Pr Ge1 3.1443(14) 5 ?
Pr Ge5 3.2027(10) . ?
Pr Ge5 3.2045(10) 16 ?
Pr Pd 3.2194(7) . ?
Pr Pd 3.2178(7) 5 ?
Pr Ge4 3.2253(5) 14_556 ?
Pr Ge1 3.2372(5) 13 ?
Pr Ge3 3.2319(6) . ?
Pr Ge2 3.3682(5) 2_554 ?
Ge1 Ge1 2.488(3) 9 ?
Ge1 Pd 2.5195(7) . ?
Ge1 Ge2 2.532(3) 2_554 ?
Ge1 Pr 3.1132(13) 12 ?
Ge1 Pr 3.1443(14) 5_445 ?
Ge1 Pr 3.1443(14) 16_545 ?
Ge1 Pr 3.2372(5) 8_455 ?
Ge1 Pr 3.2372(5) 13 ?
Ge2 Ge1 2.532(3) 2 ?
Ge2 Ge2 2.585(3) 9_556 ?
Ge2 Pr 3.0535(13) 3_545 ?
Ge2 Pr 3.0534(13) 10_556 ?
Ge2 Pr 3.0921(14) 7_545 ?
Ge2 Pr 3.0921(14) 14_456 ?
Ge2 Pr 3.3682(5) 11_566 ?
Ge2 Pr 3.3682(5) 2 ?
Ge3 Ge4 2.4947(8) . ?
Ge3 Pd 2.5231(8) . ?
Ge3 Ge5 2.5813(9) 16 ?
Ge3 Ge5 2.5813(9) 5_455 ?
Ge3 Pr 3.2320(6) 12 ?
Ge4 Pd 2.5239(8) 10_566 ?
Ge4 Ge5 2.5814(9) 14_456 ?
Ge4 Ge5 2.5814(9) 7_545 ?
Ge4 Pr 3.2254(5) 7_545 ?
Ge4 Pr 3.2254(5) 14_456 ?
Ge5 Ge5 2.4871(8) 7_545 ?
Ge5 Pd 2.5493(4) . ?
Ge5 Ge3 2.5813(9) 5_545 ?
Ge5 Ge4 2.5814(9) 14_556 ?
Ge5 Pr 3.2045(10) 16_545 ?
Pd Ge4 2.5238(8) 10_556 ?
Pd Ge5 2.5494(4) 12 ?
Pd Pr 3.2194(7) 12 ?
Pd Pr 3.2178(7) 5_445 ?
Pd Pr 3.2178(7) 16_545 ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
Ge2 Pr Ge2 142.66(2) 10_566 14_556 ?
Ge2 Pr Ge1 81.373(14) 10_566 . ?
Ge2 Pr Ge1 84.20(4) 14_556 . ?
Ge2 Pr Ge1 84.31(4) 10_566 5 ?
Ge2 Pr Ge1 83.184(14) 14_556 5 ?
Ge1 Pr Ge1 137.00(2) . 5 ?
Ge2 Pr Ge5 135.482(16) 10_566 . ?
Ge2 Pr Ge5 76.78(3) 14_556 . ?
Ge1 Pr Ge5 85.34(3) . . ?
Ge1 Pr Ge5 130.691(16) 5 . ?
Ge2 Pr Ge5 77.30(3) 10_566 16 ?
Ge2 Pr Ge5 135.956(16) 14_556 16 ?
Ge1 Pr Ge5 130.227(16) . 16 ?
Ge1 Pr Ge5 84.80(3) 5 16 ?
Ge5 Pr Ge5 79.623(11) . 16 ?
Ge2 Pr Pd 96.43(2) 10_566 . ?
Ge2 Pr Pd 98.39(3) 14_556 . ?
Ge1 Pr Pd 46.851(17) . . ?
Ge1 Pr Pd 176.11(2) 5 . ?
Ge5 Pr Pd 46.777(13) . . ?
Ge5 Pr Pd 91.635(16) 16 . ?
Ge2 Pr Pd 99.23(4) 10_566 5 ?
Ge2 Pr Pd 97.34(2) 14_556 5 ?
Ge1 Pr Pd 176.322(16) . 5 ?
Ge1 Pr Pd 46.641(17) 5 5 ?
Ge5 Pr Pd 91.750(17) . 5 ?
Ge5 Pr Pd 46.775(13) 16 5 ?
Pd Pr Pd 129.502(15) . 5 ?
Ge2 Pr Ge4 137.09(3) 10_566 14_556 ?
Ge2 Pr Ge4 76.186(16) 14_556 14_556 ?
Ge1 Pr Ge4 131.53(4) . 14_556 ?
Ge1 Pr Ge4 84.367(16) 5 14_556 ?
Ge5 Pr Ge4 47.354(15) . 14_556 ?
Ge5 Pr Ge4 60.534(16) 16 14_556 ?
Pd Pr Ge4 92.539(16) . 14_556 ?
Pd Pr Ge4 46.122(14) 5 14_556 ?
Ge2 Pr Ge1 101.32(2) 10_566 13 ?
Ge2 Pr Ge1 47.10(5) 14_556 13 ?
Ge1 Pr Ge1 98.02(2) . 13 ?
Ge1 Pr Ge1 45.87(5) 5 13 ?
Ge5 Pr Ge1 122.59(3) . 13 ?
Ge5 Pr Ge1 129.93(4) 16 13 ?
Pd Pr Ge1 137.35(4) . 13 ?
Pd Pr Ge1 85.44(2) 5 13 ?
Ge4 Pr Ge1 99.895(12) 14_556 13 ?
Ge2 Pr Ge3 75.951(16) 10_566 . ?
Ge2 Pr Ge3 136.39(3) 14_556 . ?
Ge1 Pr Ge3 84.130(16) . . ?
Ge1 Pr Ge3 130.83(4) 5 . ?
Ge5 Pr Ge3 60.485(16) . . ?
Ge5 Pr Ge3 47.285(15) 16 . ?
Pd Pr Ge3 46.044(14) . . ?
Pd Pr Ge3 92.483(16) 5 . ?
Ge4 Pr Ge3 80.773(11) 14_556 . ?
Ge1 Pr Ge3 176.28(4) 13 . ?
Ge2 Pr Ge2 47.16(5) 10_566 2_554 ?
Ge2 Pr Ge2 99.80(2) 14_556 2_554 ?
Ge1 Pr Ge2 45.79(5) . 2_554 ?
Ge1 Pr Ge2 96.64(2) 5 2_554 ?
Ge5 Pr Ge2 130.73(4) . 2_554 ?
Ge5 Pr Ge2 123.63(3) 16 2_554 ?
Pd Pr Ge2 86.61(2) . 2_554 ?
Pd Pr Ge2 136.77(4) 5 2_554 ?
Ge4 Pr Ge2 175.75(4) 14_556 2_554 ?
Ge1 Pr Ge2 78.043(11) 13 2_554 ?
Ge3 Pr Ge2 101.527(12) . 2_554 ?
Ge1 Ge1 Pd 121.97(9) 9 . ?
Ge1 Ge1 Ge2 111.10(4) 9 2_554 ?
Pd Ge1 Ge2 126.93(9) . 2_554 ?
Ge1 Ge1 Pr 137.959(19) 9 12 ?
Pd Ge1 Pr 68.79(2) . 12 ?
Ge2 Ge1 Pr 72.43(6) 2_554 12 ?
Ge1 Ge1 Pr 137.960(19) 9 . ?
Pd Ge1 Pr 68.79(2) . . ?
Ge2 Ge1 Pr 72.43(6) 2_554 . ?
Pr Ge1 Pr 83.92(4) 12 . ?
Ge1 Ge1 Pr 69.04(6) 9 5_445 ?
Pd Ge1 Pr 68.22(2) . 5_445 ?
Ge2 Ge1 Pr 138.178(14) 2_554 5_445 ?
Pr Ge1 Pr 81.314(8) 12 5_445 ?
Pr Ge1 Pr 137.00(2) . 5_445 ?
Ge1 Ge1 Pr 69.04(6) 9 16_545 ?
Pd Ge1 Pr 68.22(2) . 16_545 ?
Ge2 Ge1 Pr 138.178(14) 2_554 16_545 ?
Pr Ge1 Pr 137.00(2) 12 16_545 ?
Pr Ge1 Pr 81.313(8) . 16_545 ?
Pr Ge1 Pr 82.58(4) 5_445 16_545 ?
Ge1 Ge1 Pr 65.10(2) 9 8_455 ?
Pd Ge1 Pr 140.120(8) . 8_455 ?
Ge2 Ge1 Pr 63.44(2) 2_554 8_455 ?
Pr Ge1 Pr 81.98(2) 12 8_455 ?
Pr Ge1 Pr 135.85(5) . 8_455 ?
Pr Ge1 Pr 81.40(2) 5_445 8_455 ?
Pr Ge1 Pr 134.13(5) 16_545 8_455 ?
Ge1 Ge1 Pr 65.10(2) 9 13 ?
Pd Ge1 Pr 140.120(8) . 13 ?
Ge2 Ge1 Pr 63.44(2) 2_554 13 ?
Pr Ge1 Pr 135.85(5) 12 13 ?
Pr Ge1 Pr 81.98(2) . 13 ?
Pr Ge1 Pr 134.13(5) 5_445 13 ?
Pr Ge1 Pr 81.40(2) 16_545 13 ?
Pr Ge1 Pr 79.724(15) 8_455 13 ?
Ge1 Ge2 Ge2 103.55(4) 2 9_556 ?
Ge1 Ge2 Pr 136.049(13) 2 3_545 ?
Ge2 Ge2 Pr 72.82(6) 9_556 3_545 ?
Ge1 Ge2 Pr 136.049(13) 2 10_556 ?
Ge2 Ge2 Pr 72.82(6) 9_556 10_556 ?
Pr Ge2 Pr 85.96(5) 3_545 10_556 ?
Ge1 Ge2 Pr 69.46(6) 2 7_545 ?
Ge2 Ge2 Pr 135.824(14) 9_556 7_545 ?
Pr Ge2 Pr 142.66(2) 3_545 7_545 ?
Pr Ge2 Pr 83.119(8) 10_556 7_545 ?
Ge1 Ge2 Pr 69.46(6) 2 14_456 ?
Ge2 Ge2 Pr 135.824(14) 9_556 14_456 ?
Pr Ge2 Pr 83.119(8) 3_545 14_456 ?
Pr Ge2 Pr 142.66(2) 10_556 14_456 ?
Pr Ge2 Pr 84.29(5) 7_545 14_456 ?
Ge1 Ge2 Pr 61.79(2) 2 11_566 ?
Ge2 Ge2 Pr 60.01(2) 9_556 11_566 ?
Pr Ge2 Pr 132.84(5) 3_545 11_566 ?
Pr Ge2 Pr 80.63(2) 10_556 11_566 ?
Pr Ge2 Pr 80.19(2) 7_545 11_566 ?
Pr Ge2 Pr 131.23(5) 14_456 11_566 ?
Ge1 Ge2 Pr 61.79(2) 2 2 ?
Ge2 Ge2 Pr 60.01(2) 9_556 2 ?
Pr Ge2 Pr 80.63(2) 3_545 2 ?
Pr Ge2 Pr 132.84(5) 10_556 2 ?
Pr Ge2 Pr 131.23(5) 7_545 2 ?
Pr Ge2 Pr 80.19(2) 14_456 2 ?
Pr Ge2 Pr 76.343(15) 11_566 2 ?
Ge4 Ge3 Pd 104.48(3) . . ?
Ge4 Ge3 Ge5 97.67(2) . 16 ?
Pd Ge3 Ge5 128.98(2) . 16 ?
Ge4 Ge3 Ge5 97.67(2) . 5_455 ?
Pd Ge3 Ge5 128.98(2) . 5_455 ?
Ge5 Ge3 Ge5 91.62(4) 16 5_455 ?
Ge4 Ge3 Pr 137.135(13) . . ?
Pd Ge3 Pr 66.72(2) . . ?
Ge5 Ge3 Pr 65.80(2) 16 . ?
Ge5 Ge3 Pr 120.91(3) 5_455 . ?
Ge4 Ge3 Pr 137.135(13) . 12 ?
Pd Ge3 Pr 66.72(2) . 12 ?
Ge5 Ge3 Pr 120.91(3) 16 12 ?
Ge5 Ge3 Pr 65.80(2) 5_455 12 ?
Pr Ge3 Pr 80.193(17) . 12 ?
Ge3 Ge4 Pd 104.41(3) . 10_566 ?
Ge3 Ge4 Ge5 97.62(2) . 14_456 ?
Pd Ge4 Ge5 129.04(2) 10_566 14_456 ?
Ge3 Ge4 Ge5 97.62(2) . 7_545 ?
Pd Ge4 Ge5 129.04(2) 10_566 7_545 ?
Ge5 Ge4 Ge5 91.62(4) 14_456 7_545 ?
Ge3 Ge4 Pr 137.203(13) . 7_545 ?
Pd Ge4 Pr 66.78(2) 10_566 7_545 ?
Ge5 Ge4 Pr 120.90(3) 14_456 7_545 ?
Ge5 Ge4 Pr 65.86(2) 7_545 7_545 ?
Ge3 Ge4 Pr 137.203(12) . 14_456 ?
Pd Ge4 Pr 66.78(2) 10_566 14_456 ?
Ge5 Ge4 Pr 65.86(2) 14_456 14_456 ?
Ge5 Ge4 Pr 120.90(3) 7_545 14_456 ?
Pr Ge4 Pr 80.074(17) 7_545 14_456 ?
Ge5 Ge5 Pd 104.73(2) 7_545 . ?
Ge5 Ge5 Ge3 97.54(2) 7_545 5_545 ?
Pd Ge5 Ge3 130.45(4) . 5_545 ?
Ge5 Ge5 Ge4 97.60(2) 7_545 14_556 ?
Pd Ge5 Ge4 130.36(4) . 14_556 ?
Ge3 Ge5 Ge4 88.382(17) 5_545 14_556 ?
Ge5 Ge5 Pr 137.96(2) 7_545 . ?
Pd Ge5 Pr 66.957(18) . . ?
Ge3 Ge5 Pr 119.57(2) 5_545 . ?
Ge4 Ge5 Pr 66.78(3) 14_556 . ?
Ge5 Ge5 Pr 137.89(2) 7_545 16_545 ?
Pd Ge5 Pr 66.888(18) . 16_545 ?
Ge3 Ge5 Pr 66.92(3) 5_545 16_545 ?
Ge4 Ge5 Pr 119.63(2) 14_556 16_545 ?
Pr Ge5 Pr 79.036(11) . 16_545 ?
Ge1 Pd Ge3 114.97(5) . . ?
Ge1 Pd Ge4 116.03(5) . 10_556 ?
Ge3 Pd Ge4 129.00(3) . 10_556 ?
Ge1 Pd Ge5 115.260(12) . . ?
Ge3 Pd Ge5 79.42(3) . . ?
Ge4 Pd Ge5 79.41(3) 10_556 . ?
Ge1 Pd Ge5 115.261(12) . 12 ?
Ge3 Pd Ge5 79.42(3) . 12 ?
Ge4 Pd Ge5 79.41(3) 10_556 12 ?
Ge5 Pd Ge5 129.48(2) . 12 ?
Ge1 Pd Pr 64.36(3) . . ?
Ge3 Pd Pr 67.240(19) . . ?
Ge4 Pd Pr 138.973(13) 10_556 . ?
Ge5 Pd Pr 66.27(2) . . ?
Ge5 Pd Pr 140.09(3) 12 . ?
Ge1 Pd Pr 64.36(3) . 12 ?
Ge3 Pd Pr 67.241(19) . 12 ?
Ge4 Pd Pr 138.973(13) 10_556 12 ?
Ge5 Pd Pr 140.09(3) . 12 ?
Ge5 Pd Pr 66.27(2) 12 12 ?
Pr Pd Pr 80.57(2) . 12 ?
Ge1 Pd Pr 65.14(3) . 5_445 ?
Ge3 Pd Pr 139.128(12) . 5_445 ?
Ge4 Pd Pr 67.096(19) 10_556 5_445 ?
Ge5 Pd Pr 139.90(3) . 5_445 ?
Ge5 Pd Pr 66.34(2) 12 5_445 ?
Pr Pd Pr 129.500(15) . 5_445 ?
Pr Pd Pr 78.595(7) 12 5_445 ?
Ge1 Pd Pr 65.14(3) . 16_545 ?
Ge3 Pd Pr 139.128(13) . 16_545 ?
Ge4 Pd Pr 67.096(19) 10_556 16_545 ?
Ge5 Pd Pr 66.34(2) . 16_545 ?
Ge5 Pd Pr 139.90(3) 12 16_545 ?
Pr Pd Pr 78.595(7) . 16_545 ?
Pr Pd Pr 129.499(15) 12 16_545 ?
Pr Pd Pr 80.30(2) 5_445 16_545 ?
 
_refine_diff_density_max    1.005
_refine_diff_density_min   -1.679
_refine_diff_density_rms    0.307



