# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_BiR1
_database_code_depnum_ccdc_archive 'CCDC 1530802'
_audit_update_record             
;
2017-02-03 deposited with the CCDC.
2017-09-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        
N-(7-(dimethylamino)-5-phenyl-10-(o-tolyl)dibenzo[b,e]bismin-3(5H)-ylidene)-N-methylmethanaminium
_chemical_name_common            BiR
_chemical_melting_point          unknown
_chemical_formula_moiety         C30H30BiN2
_chemical_formula_sum            'C32 H33 Bi F6 N3 P'
_chemical_formula_weight         813.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.7064(18)
_cell_length_b                   11.8965(17)
_cell_length_c                   14.505(2)
_cell_angle_alpha                66.593(6)
_cell_angle_beta                 77.962(6)
_cell_angle_gamma                70.259(6)
_cell_volume                     1589.9(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    4697
_cell_measurement_theta_min      3.0721
_cell_measurement_theta_max      27.4662

_exptl_crystal_description       Prism
_exptl_crystal_colour            Green
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.699
_exptl_crystal_F_000             796
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.330
_exptl_crystal_size_mid          0.310
_exptl_crystal_size_min          0.280
_exptl_absorpt_coefficient_mu    5.657
_shelx_estimated_absorpt_T_min   0.397
_shelx_estimated_absorpt_T_max   0.397
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'AFC7R Mercury CCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            12952
_diffrn_reflns_av_unetI/netI     0.0451
_diffrn_reflns_av_R_equivalents  0.0300
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         3.072
_diffrn_reflns_theta_max         27.482
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measured_fraction_theta_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_point_group_measured_fraction_full 0.992
_reflns_number_total             7179
_reflns_number_gt                6291
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0550P)²+0.5008P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7179
_refine_ls_number_parameters     394
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0458
_refine_ls_R_factor_gt           0.0391
_refine_ls_wR_factor_ref         0.1065
_refine_ls_wR_factor_gt          0.0997
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.79203(2) 0.93996(2) 0.54720(2) 0.05089(9) Uani 1 1 d . . . . .
C1 C 0.9810(5) 0.7819(5) 0.5663(3) 0.0444(10) Uani 1 1 d . . . . .
C2 C 1.0021(5) 0.6966(5) 0.6641(4) 0.0503(11) Uani 1 1 d . . . . .
H2 H 0.9394 0.7110 0.7163 0.060 Uiso 1 1 calc R U . . .
C3 C 1.1148(5) 0.5889(5) 0.6877(4) 0.0518(11) Uani 1 1 d . . . . .
C4 C 1.2092(6) 0.5741(6) 0.6068(4) 0.0605(14) Uani 1 1 d . . . . .
H4 H 1.2865 0.5061 0.6189 0.073 Uiso 1 1 calc R U . . .
C5 C 1.1888(6) 0.6581(6) 0.5110(4) 0.0573(13) Uani 1 1 d . . . . .
H5 H 1.2537 0.6447 0.4598 0.069 Uiso 1 1 calc R U . . .
C6 C 1.0758(5) 0.7638(5) 0.4846(4) 0.0458(10) Uani 1 1 d . . . . .
C7 C 1.0644(5) 0.8407(5) 0.3801(3) 0.0432(10) Uani 1 1 d . . . . .
C8 C 0.8575(5) 1.0256(5) 0.3841(4) 0.0476(11) Uani 1 1 d . . . . .
C9 C 0.9690(5) 0.9579(5) 0.3347(4) 0.0471(11) Uani 1 1 d . . . . .
C10 C 0.9833(6) 1.0220(6) 0.2264(4) 0.0630(14) Uani 1 1 d . . . . .
H10 H 1.0550 0.9837 0.1898 0.076 Uiso 1 1 calc R U . . .
C11 C 0.8999(6) 1.1325(6) 0.1763(4) 0.0641(14) Uani 1 1 d . . . . .
H11 H 0.9148 1.1676 0.1065 0.077 Uiso 1 1 calc R U . . .
C12 C 0.7895(6) 1.1979(5) 0.2260(4) 0.0555(12) Uani 1 1 d . . . . .
C13 C 0.7736(6) 1.1394(5) 0.3326(4) 0.0538(12) Uani 1 1 d . . . . .
H13 H 0.7035 1.1805 0.3685 0.065 Uiso 1 1 calc R U . . .
C14 C 0.5850(8) 1.3677(7) 0.2269(7) 0.092(2) Uani 1 1 d . . . . .
H14 H 0.5261 1.3145 0.2514 0.137 Uiso 1 1 calc R U . . .
H14A H 0.5414 1.4494 0.1804 0.137 Uiso 1 1 calc R U . . .
H14B H 0.6081 1.3789 0.2826 0.137 Uiso 1 1 calc R U . . .
C15 C 0.7215(9) 1.3648(7) 0.0647(5) 0.091(2) Uani 1 1 d . . . . .
H15 H 0.8104 1.3724 0.0439 0.136 Uiso 1 1 calc R U . . .
H15A H 0.6587 1.4478 0.0420 0.136 Uiso 1 1 calc R U . . .
H15B H 0.7065 1.3109 0.0359 0.136 Uiso 1 1 calc R U . . .
C16 C 1.0318(8) 0.5164(8) 0.8652(4) 0.081(2) Uani 1 1 d . . . . .
H16 H 1.0206 0.5959 0.8727 0.122 Uiso 1 1 calc R U . . .
H16A H 1.0605 0.4471 0.9263 0.122 Uiso 1 1 calc R U . . .
H16B H 0.9486 0.5148 0.8515 0.122 Uiso 1 1 calc R U . . .
C17 C 1.2422(7) 0.3868(6) 0.8029(5) 0.0786(18) Uani 1 1 d . . . . .
H17 H 1.2397 0.3396 0.7632 0.118 Uiso 1 1 calc R U . . .
H17A H 1.2351 0.3355 0.8732 0.118 Uiso 1 1 calc R U . . .
H17B H 1.3247 0.4086 0.7860 0.118 Uiso 1 1 calc R U . . .
C18 C 1.1673(5) 0.7876(5) 0.3082(3) 0.0455(10) Uani 1 1 d . . . . .
C19 C 1.2750(5) 0.8373(6) 0.2654(4) 0.0573(12) Uani 1 1 d . . . . .
H19 H 1.2828 0.9024 0.2820 0.069 Uiso 1 1 calc R U . . .
C20 C 1.3704(6) 0.7917(6) 0.1987(4) 0.0673(15) Uani 1 1 d . . . . .
H20 H 1.4427 0.8247 0.1713 0.081 Uiso 1 1 calc R U . . .
C21 C 1.3570(7) 0.6976(6) 0.1736(4) 0.0689(16) Uani 1 1 d . . . . .
H21 H 1.4205 0.6667 0.1284 0.083 Uiso 1 1 calc R U . . .
C22 C 1.2512(7) 0.6480(6) 0.2141(4) 0.0690(16) Uani 1 1 d . . . . .
H22 H 1.2441 0.5841 0.1957 0.083 Uiso 1 1 calc R U . . .
C23 C 1.1529(6) 0.6917(5) 0.2829(4) 0.0576(13) Uani 1 1 d . . . . .
C24 C 1.0383(8) 0.6363(7) 0.3274(6) 0.085(2) Uani 1 1 d . . . . .
H24 H 1.0350 0.6057 0.3996 0.128 Uiso 1 1 calc R U . . .
H24A H 1.0495 0.5668 0.3057 0.128 Uiso 1 1 calc R U . . .
H24B H 0.9569 0.7009 0.3054 0.128 Uiso 1 1 calc R U . . .
C25 C 0.6856(5) 0.8310(5) 0.5065(4) 0.0510(11) Uani 1 1 d . . . . .
C26 C 0.6851(7) 0.7092(6) 0.5687(5) 0.0710(16) Uani 1 1 d . . . . .
H26 H 0.7305 0.6698 0.6266 0.085 Uiso 1 1 calc R U . . .
C27 C 0.6167(8) 0.6445(7) 0.5454(6) 0.086(2) Uani 1 1 d . . . . .
H27 H 0.6166 0.5617 0.5875 0.103 Uiso 1 1 calc R U . . .
C28 C 0.5494(7) 0.7032(8) 0.4598(6) 0.085(2) Uani 1 1 d . . . . .
H28 H 0.5027 0.6609 0.4441 0.103 Uiso 1 1 calc R U . . .
C29 C 0.5517(8) 0.8233(9) 0.3988(7) 0.086(2) Uani 1 1 d . . . . .
H29 H 0.5085 0.8616 0.3399 0.103 Uiso 1 1 calc R U . . .
C30 C 0.6168(7) 0.8909(7) 0.4216(5) 0.0713(16) Uani 1 1 d . . . . .
H30 H 0.6140 0.9747 0.3804 0.086 Uiso 1 1 calc R U . . .
C31 C 0.8695(11) 0.8985(10) 0.0613(7) 0.097(2) Uani 1 1 d . . . . .
C32 C 0.7417(13) 0.9898(11) 0.0554(10) 0.144(4) Uani 1 1 d . . . . .
H32 H 0.7094 0.9965 0.1204 0.215 Uiso 1 1 calc R U . . .
H32A H 0.6810 0.9629 0.0341 0.215 Uiso 1 1 calc R U . . .
H32B H 0.7486 1.0714 0.0075 0.215 Uiso 1 1 calc R U . . .
N1 N 1.1313(5) 0.5032(5) 0.7822(3) 0.0597(11) Uani 1 1 d . . . . .
N2 N 0.7042(5) 1.3079(4) 0.1764(4) 0.0647(12) Uani 1 1 d . . . . .
N3 N 0.9717(10) 0.8268(10) 0.0672(7) 0.133(3) Uani 1 1 d . . . . .
P1 P 0.36103(19) 0.21842(18) 0.12133(12) 0.0678(4) Uani 1 1 d . . . . .
F1 F 0.4756(11) 0.1509(11) 0.1832(9) 0.271(7) Uani 1 1 d . . . . .
F2 F 0.3099(7) 0.3114(10) 0.1782(7) 0.204(4) Uani 1 1 d . . . . .
F3 F 0.2567(12) 0.1570(9) 0.1870(9) 0.252(5) Uani 1 1 d . . . . .
F4 F 0.4059(8) 0.1260(9) 0.0686(9) 0.237(5) Uani 1 1 d . . . . .
F5 F 0.4551(12) 0.2878(12) 0.0566(9) 0.272(6) Uani 1 1 d . . . . .
F6 F 0.2478(9) 0.3010(11) 0.0545(6) 0.219(5) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Bi1 C1 2.226(5) . ?
Bi1 C8 2.237(5) . ?
Bi1 C25 2.284(5) . ?
C1 C2 1.389(7) . ?
C1 C6 1.426(6) . ?
C2 C3 1.412(7) . ?
C2 H2 0.9300 . ?
C3 N1 1.349(6) . ?
C3 C4 1.407(8) . ?
C4 C5 1.361(8) . ?
C4 H4 0.9300 . ?
C5 C6 1.405(7) . ?
C5 H5 0.9300 . ?
C6 C7 1.431(7) . ?
C7 C9 1.418(7) . ?
C7 C18 1.508(6) . ?
C8 C13 1.361(7) . ?
C8 C9 1.428(7) . ?
C9 C10 1.448(7) . ?
C10 C11 1.332(8) . ?
C10 H10 0.9300 . ?
C11 C12 1.411(8) . ?
C11 H11 0.9300 . ?
C12 N2 1.335(7) . ?
C12 C13 1.422(8) . ?
C13 H13 0.9300 . ?
C14 N2 1.444(9) . ?
C14 H14 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C15 N2 1.485(9) . ?
C15 H15 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C16 N1 1.453(8) . ?
C16 H16 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C17 N1 1.457(8) . ?
C17 H17 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C18 C23 1.391(7) . ?
C18 C19 1.391(7) . ?
C19 C20 1.380(8) . ?
C19 H19 0.9300 . ?
C20 C21 1.364(9) . ?
C20 H20 0.9300 . ?
C21 C22 1.369(10) . ?
C21 H21 0.9300 . ?
C22 C23 1.406(8) . ?
C22 H22 0.9300 . ?
C23 C24 1.495(9) . ?
C24 H24 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C25 C26 1.370(8) . ?
C25 C30 1.376(8) . ?
C26 C27 1.391(9) . ?
C26 H26 0.9300 . ?
C27 C28 1.375(11) . ?
C27 H27 0.9300 . ?
C28 C29 1.355(11) . ?
C28 H28 0.9300 . ?
C29 C30 1.388(9) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 N3 1.133(12) . ?
C31 C32 1.425(17) . ?
C32 H32 0.9600 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
P1 F5 1.459(8) . ?
P1 F1 1.476(7) . ?
P1 F4 1.477(6) . ?
P1 F3 1.498(8) . ?
P1 F6 1.517(7) . ?
P1 F2 1.527(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Bi1 C8 89.77(18) . . ?
C1 Bi1 C25 92.37(17) . . ?
C8 Bi1 C25 89.59(18) . . ?
C2 C1 C6 120.2(5) . . ?
C2 C1 Bi1 116.1(3) . . ?
C6 C1 Bi1 123.7(3) . . ?
C1 C2 C3 122.7(5) . . ?
C1 C2 H2 118.7 . . ?
C3 C2 H2 118.7 . . ?
N1 C3 C4 121.2(5) . . ?
N1 C3 C2 122.3(5) . . ?
C4 C3 C2 116.5(5) . . ?
C5 C4 C3 120.7(5) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
C4 C5 C6 124.2(5) . . ?
C4 C5 H5 117.9 . . ?
C6 C5 H5 117.9 . . ?
C5 C6 C1 115.6(4) . . ?
C5 C6 C7 118.2(4) . . ?
C1 C6 C7 126.2(5) . . ?
C9 C7 C6 129.4(4) . . ?
C9 C7 C18 115.6(4) . . ?
C6 C7 C18 115.0(4) . . ?
C13 C8 C9 122.2(5) . . ?
C13 C8 Bi1 115.0(4) . . ?
C9 C8 Bi1 122.3(4) . . ?
C7 C9 C8 127.3(4) . . ?
C7 C9 C10 119.0(5) . . ?
C8 C9 C10 113.7(5) . . ?
C11 C10 C9 123.8(6) . . ?
C11 C10 H10 118.1 . . ?
C9 C10 H10 118.1 . . ?
C10 C11 C12 121.8(5) . . ?
C10 C11 H11 119.1 . . ?
C12 C11 H11 119.1 . . ?
N2 C12 C11 122.3(5) . . ?
N2 C12 C13 121.6(5) . . ?
C11 C12 C13 116.0(5) . . ?
C8 C13 C12 122.3(5) . . ?
C8 C13 H13 118.8 . . ?
C12 C13 H13 118.8 . . ?
N2 C14 H14 109.5 . . ?
N2 C14 H14A 109.5 . . ?
H14 C14 H14A 109.5 . . ?
N2 C14 H14B 109.5 . . ?
H14 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
N2 C15 H15 109.5 . . ?
N2 C15 H15A 109.5 . . ?
H15 C15 H15A 109.5 . . ?
N2 C15 H15B 109.5 . . ?
H15 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
N1 C16 H16 109.5 . . ?
N1 C16 H16A 109.5 . . ?
H16 C16 H16A 109.5 . . ?
N1 C16 H16B 109.5 . . ?
H16 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
N1 C17 H17 109.5 . . ?
N1 C17 H17A 109.5 . . ?
H17 C17 H17A 109.5 . . ?
N1 C17 H17B 109.5 . . ?
H17 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C23 C18 C19 120.1(5) . . ?
C23 C18 C7 120.3(5) . . ?
C19 C18 C7 119.6(4) . . ?
C20 C19 C18 121.1(5) . . ?
C20 C19 H19 119.4 . . ?
C18 C19 H19 119.4 . . ?
C21 C20 C19 119.0(6) . . ?
C21 C20 H20 120.5 . . ?
C19 C20 H20 120.5 . . ?
C20 C21 C22 120.9(5) . . ?
C20 C21 H21 119.6 . . ?
C22 C21 H21 119.6 . . ?
C21 C22 C23 121.5(5) . . ?
C21 C22 H22 119.3 . . ?
C23 C22 H22 119.3 . . ?
C18 C23 C22 117.4(5) . . ?
C18 C23 C24 121.5(5) . . ?
C22 C23 C24 121.1(5) . . ?
C23 C24 H24 109.5 . . ?
C23 C24 H24A 109.5 . . ?
H24 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C26 C25 C30 120.4(5) . . ?
C26 C25 Bi1 120.1(4) . . ?
C30 C25 Bi1 119.4(4) . . ?
C25 C26 C27 120.1(6) . . ?
C25 C26 H26 120.0 . . ?
C27 C26 H26 120.0 . . ?
C28 C27 C26 119.8(7) . . ?
C28 C27 H27 120.1 . . ?
C26 C27 H27 120.1 . . ?
C29 C28 C27 119.4(7) . . ?
C29 C28 H28 120.3 . . ?
C27 C28 H28 120.3 . . ?
C28 C29 C30 121.9(7) . . ?
C28 C29 H29 119.1 . . ?
C30 C29 H29 119.1 . . ?
C25 C30 C29 118.4(7) . . ?
C25 C30 H30 120.8 . . ?
C29 C30 H30 120.8 . . ?
N3 C31 C32 178.8(12) . . ?
C31 C32 H32 109.5 . . ?
C31 C32 H32A 109.5 . . ?
H32 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C3 N1 C16 121.2(5) . . ?
C3 N1 C17 121.2(5) . . ?
C16 N1 C17 117.3(5) . . ?
C12 N2 C14 121.8(6) . . ?
C12 N2 C15 120.3(6) . . ?
C14 N2 C15 117.5(6) . . ?
F5 P1 F1 80.9(8) . . ?
F5 P1 F4 91.1(6) . . ?
F1 P1 F4 91.4(5) . . ?
F5 P1 F3 175.6(7) . . ?
F1 P1 F3 101.9(8) . . ?
F4 P1 F3 92.3(6) . . ?
F5 P1 F6 94.0(8) . . ?
F1 P1 F6 173.7(8) . . ?
F4 P1 F6 92.3(5) . . ?
F3 P1 F6 83.0(7) . . ?
F5 P1 F2 91.3(6) . . ?
F1 P1 F2 89.3(5) . . ?
F4 P1 F2 177.6(6) . . ?
F3 P1 F2 85.3(5) . . ?
F6 P1 F2 87.2(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -0.8(7) . . . . ?
Bi1 C1 C2 C3 177.6(4) . . . . ?
C1 C2 C3 N1 -176.7(5) . . . . ?
C1 C2 C3 C4 2.4(7) . . . . ?
N1 C3 C4 C5 177.1(5) . . . . ?
C2 C3 C4 C5 -2.0(8) . . . . ?
C3 C4 C5 C6 0.0(10) . . . . ?
C4 C5 C6 C1 1.6(8) . . . . ?
C4 C5 C6 C7 -177.1(5) . . . . ?
C2 C1 C6 C5 -1.2(7) . . . . ?
Bi1 C1 C6 C5 -179.5(4) . . . . ?
C2 C1 C6 C7 177.3(4) . . . . ?
Bi1 C1 C6 C7 -1.0(7) . . . . ?
C5 C6 C7 C9 -173.0(5) . . . . ?
C1 C6 C7 C9 8.5(8) . . . . ?
C5 C6 C7 C18 8.4(7) . . . . ?
C1 C6 C7 C18 -170.1(4) . . . . ?
C6 C7 C9 C8 -2.0(8) . . . . ?
C18 C7 C9 C8 176.5(5) . . . . ?
C6 C7 C9 C10 176.3(5) . . . . ?
C18 C7 C9 C10 -5.2(7) . . . . ?
C13 C8 C9 C7 178.5(5) . . . . ?
Bi1 C8 C9 C7 -10.1(7) . . . . ?
C13 C8 C9 C10 0.1(7) . . . . ?
Bi1 C8 C9 C10 171.5(4) . . . . ?
C7 C9 C10 C11 -179.7(6) . . . . ?
C8 C9 C10 C11 -1.1(9) . . . . ?
C9 C10 C11 C12 0.8(10) . . . . ?
C10 C11 C12 N2 -179.1(6) . . . . ?
C10 C11 C12 C13 0.6(9) . . . . ?
C9 C8 C13 C12 1.3(8) . . . . ?
Bi1 C8 C13 C12 -170.6(4) . . . . ?
N2 C12 C13 C8 178.1(5) . . . . ?
C11 C12 C13 C8 -1.7(8) . . . . ?
C9 C7 C18 C23 -99.2(6) . . . . ?
C6 C7 C18 C23 79.5(6) . . . . ?
C9 C7 C18 C19 79.2(6) . . . . ?
C6 C7 C18 C19 -102.1(5) . . . . ?
C23 C18 C19 C20 -1.1(8) . . . . ?
C7 C18 C19 C20 -179.5(5) . . . . ?
C18 C19 C20 C21 1.0(9) . . . . ?
C19 C20 C21 C22 -0.4(9) . . . . ?
C20 C21 C22 C23 -0.2(10) . . . . ?
C19 C18 C23 C22 0.5(8) . . . . ?
C7 C18 C23 C22 178.9(5) . . . . ?
C19 C18 C23 C24 -179.9(6) . . . . ?
C7 C18 C23 C24 -1.5(8) . . . . ?
C21 C22 C23 C18 0.1(9) . . . . ?
C21 C22 C23 C24 -179.5(6) . . . . ?
C30 C25 C26 C27 1.1(10) . . . . ?
Bi1 C25 C26 C27 178.0(5) . . . . ?
C25 C26 C27 C28 -0.2(11) . . . . ?
C26 C27 C28 C29 0.7(12) . . . . ?
C27 C28 C29 C30 -2.1(12) . . . . ?
C26 C25 C30 C29 -2.4(10) . . . . ?
Bi1 C25 C30 C29 -179.4(5) . . . . ?
C28 C29 C30 C25 2.9(12) . . . . ?
C4 C3 N1 C16 -178.1(6) . . . . ?
C2 C3 N1 C16 1.0(8) . . . . ?
C4 C3 N1 C17 -4.9(8) . . . . ?
C2 C3 N1 C17 174.2(5) . . . . ?
C11 C12 N2 C14 174.1(6) . . . . ?
C13 C12 N2 C14 -5.6(9) . . . . ?
C11 C12 N2 C15 1.4(9) . . . . ?
C13 C12 N2 C15 -178.4(5) . . . . ?

_refine_diff_density_max         1.414
_refine_diff_density_min         -1.047
_refine_diff_density_rms         0.103






_chemical_compound_source        n.a.
_chemical_properties_physical    ', Photo-sensitive'
_exptl_crystal_preparation       ', Luminescent'
