# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1557615'
_audit_update_record             
;
2017-09-25 deposited with the CCDC.
2017-09-29 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT417_1                   
;
PROBLEM: Short Inter D-H..H-D       H1WA   ..  H7      ..       1.70 Ang.
RESPONSE: The position of hydrogen atom H7 cannot be accurately calculated.
;
_vrf_PLAT417_1_2                 
;
PROBLEM: Short Inter D-H..H-D       H1WB   ..  H7      ..       2.07 Ang.
RESPONSE: The position of hydrogen atom H7 cannot be accurately calculated.
;
_vrf_PLAT420_1                   
;
PROBLEM: D-H Without Acceptor      *O2W    -- *H2WB   ...     Please Check
RESPONSE: The pointing direction of the calculated hydrogen atom H2WB of O2W cannot be fixed.
;
# Added during the CSD deposition process: Monday 25 September 2017 03:46 PM
# end Validation Reply Form

_audit_creation_date             2017-09-25
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(N O3), C204 H186 Ag8 P8, 8(C H4 O), 3(H2 O)'
_chemical_formula_sum            'C212 H224 Ag8 N2 O17 P8'
_chemical_formula_weight         4182.64
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   36.288(2)
_cell_length_b                   30.351(2)
_cell_length_c                   18.6689(12)
_cell_angle_alpha                90
_cell_angle_beta                 110.535(2)
_cell_angle_gamma                90
_cell_volume                     19255(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9677
_cell_measurement_temperature    173.15
_cell_measurement_theta_max      27.94
_cell_measurement_theta_min      2.40
_shelx_estimated_absorpt_T_max   0.769
_shelx_estimated_absorpt_T_min   0.655
_exptl_absorpt_coefficient_mu    0.925
_exptl_absorpt_correction_T_max  27.94
_exptl_absorpt_correction_T_min  2.40
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             8568
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1370
_diffrn_reflns_av_unetI/netI     0.0532
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       43
_diffrn_reflns_limit_h_min       -43
_diffrn_reflns_limit_k_max       36
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            212944
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.250
_diffrn_reflns_theta_min         1.777
_diffrn_ambient_temperature      173.15
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                14287
_reflns_number_total             17402
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.244
_refine_diff_density_min         -1.301
_refine_diff_density_rms         0.131
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1102
_refine_ls_number_reflns         17402
_refine_ls_number_restraints     44
_refine_ls_R_factor_all          0.0625
_refine_ls_R_factor_gt           0.0493
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0845P)²+59.6161P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1286
_refine_ls_wR_factor_ref         0.1433
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups, All O(H,H) groups
2. Restrained distances
 O2-N1
 1.43 with sigma of 0.02
 O3-N1
 1.43 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C103) \\sim Ueq, Uanis(C104) \\sim Ueq, Uanis(C106) \\sim Ueq, Uanis(O4)
\\sim Ueq, Uanis(O5) \\sim Ueq, Uanis(O6) \\sim Ueq, Uanis(O7) \\sim Ueq, :
with sigma of 0.01 and sigma for terminal atoms of 0.02
4. Others
 Fixed Sof: O2W(0.5) H2WA(0.5) H2WB(0.5)
5.a Free rotating group:
 O1W(H1WA,H1WB), O2W(H2WA,H2WB)
5.b Ternary CH refined with riding coordinates:
 C5(H5), C15(H15), C25(H25)
5.c Secondary CH2 refined with riding coordinates:
 C6(H6A,H6B), C7(H7A,H7B), C8(H8A,H8B), C9(H9A,H9B), C10(H10A,H10B), C16(H16A,
 H16B), C17(H17A,H17B), C18(H18A,H18B), C19(H19A,H19B), C20(H20A,H20B),
 C26(H26A,H26B), C27(H27A,H27B), C28(H28A,H28B), C29(H29A,H29B), C30(H30A,H30B)
5.d Aromatic/amide H refined with riding coordinates:
 C32(H32), C33(H33), C34(H34), C35(H35), C36(H36), C38(H38), C39(H39),
 C40(H40), C41(H41), C42(H42), C44(H44), C45(H45), C46(H46), C47(H47), C48(H48),
  C50(H50), C51(H51), C52(H52), C53(H53), C54(H54), C56(H56), C57(H57),
 C58(H58), C59(H59), C60(H60), C62(H62), C63(H63), C64(H64), C65(H65), C66(H66),
  C68(H68), C69(H69), C70(H70), C71(H71), C72(H72), C74(H74), C75(H75),
 C76(H76), C77(H77), C78(H78), C80(H80), C81(H81), C82(H82), C83(H83), C84(H84),
  C86(H86), C87(H87), C88(H88), C89(H89), C90(H90), C92(H92), C93(H93),
 C94(H94), C95(H95), C96(H96), C98(H98), C99(H99), C100(H100), C101(H101),
 C102(H102)
5.e Idealised Me refined as rotating group:
 C103(H10C,H10D,H10E), C104(H10F,H10G,H10H), C105(H10I,H10J,H10K), C106(H10L,
 H10M,H10N)
5.f Idealised tetrahedral OH refined as rotating group:
 O4(H4), O5(H5A), O6(H6), O7(H7)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.8224(3) 0.5320(3) 0.5348(5) 0.143(3) Uiso 1 1 d . . . . .
Ag1 Ag 1.00883(2) 0.78372(2) 0.17545(2) 0.02421(9) Uani 1 1 d . . . . .
Ag2 Ag 1.0000 0.69354(2) 0.2500 0.02504(11) Uani 1 2 d S T P . .
Ag3 Ag 1.07645(2) 0.75380(2) 0.32719(2) 0.02462(10) Uani 1 1 d . . . . .
Ag4 Ag 1.0000 0.88240(2) 0.2500 0.02548(12) Uani 1 2 d S T P . .
Ag5 Ag 1.01941(2) 0.69245(2) 0.07481(2) 0.02575(10) Uani 1 1 d . . . . .
P1 P 0.99674(4) 0.92956(4) 0.13796(6) 0.0267(2) Uani 1 1 d . . . . .
P2 P 1.14878(3) 0.75311(3) 0.39821(6) 0.0219(2) Uani 1 1 d . . . . .
P3 P 1.00788(3) 0.61101(3) 0.05012(6) 0.0219(2) Uani 1 1 d . . . . .
P4 P 1.04203(3) 0.73259(4) -0.01916(6) 0.0272(2) Uani 1 1 d . . . . .
C1 C 1.05066(12) 0.82312(13) 0.2539(2) 0.0241(9) Uani 1 1 d . . . . .
C2 C 1.07474(13) 0.84428(14) 0.3040(3) 0.0268(9) Uani 1 1 d . . . . .
C3 C 1.10292(14) 0.86800(15) 0.3596(3) 0.0324(10) Uani 1 1 d . . . . .
C4 C 1.12915(16) 0.88609(17) 0.4088(3) 0.0415(12) Uani 1 1 d . . . . .
C5 C 1.16170(16) 0.90681(18) 0.4704(3) 0.0420(12) Uani 1 1 d . . . . .
H5 H 1.1830 0.8844 0.4908 0.050 Uiso 1 1 calc R . . . .
C6 C 1.14868(19) 0.9212(2) 0.5355(3) 0.0543(15) Uani 1 1 d . . . . .
H6A H 1.1391 0.8953 0.5562 0.065 Uiso 1 1 calc R . . . .
H6B H 1.1267 0.9425 0.5162 0.065 Uiso 1 1 calc R . . . .
C7 C 1.1832(2) 0.9429(2) 0.5997(3) 0.0579(16) Uani 1 1 d . . . . .
H7A H 1.1739 0.9532 0.6407 0.069 Uiso 1 1 calc R . . . .
H7B H 1.2041 0.9208 0.6220 0.069 Uiso 1 1 calc R . . . .
C8 C 1.1995(3) 0.9807(3) 0.5698(4) 0.074(2) Uani 1 1 d . . . . .
H8A H 1.2222 0.9932 0.6116 0.089 Uiso 1 1 calc R . . . .
H8B H 1.1792 1.0040 0.5518 0.089 Uiso 1 1 calc R . . . .
C9 C 1.2125(2) 0.9667(2) 0.5049(4) 0.0683(19) Uani 1 1 d . . . . .
H9A H 1.2343 0.9453 0.5241 0.082 Uiso 1 1 calc R . . . .
H9B H 1.2224 0.9927 0.4853 0.082 Uiso 1 1 calc R . . . .
C10 C 1.17876(17) 0.94576(19) 0.4395(3) 0.0488(14) Uani 1 1 d . . . . .
H10A H 1.1886 0.9353 0.3993 0.059 Uiso 1 1 calc R . . . .
H10B H 1.1579 0.9679 0.4166 0.059 Uiso 1 1 calc R . . . .
C11 C 0.96724(13) 0.74571(14) 0.0946(2) 0.0251(9) Uani 1 1 d . . . . .
C12 C 0.94264(12) 0.72140(14) 0.0501(2) 0.0253(9) Uani 1 1 d . . . . .
C13 C 0.91510(14) 0.69410(15) 0.0012(3) 0.0314(10) Uani 1 1 d . . . . .
C14 C 0.88990(15) 0.67052(16) -0.0397(3) 0.0389(11) Uani 1 1 d . . . . .
C15 C 0.85748(16) 0.64371(18) -0.0893(3) 0.0453(13) Uani 1 1 d . . . . .
H15 H 0.8324 0.6580 -0.0909 0.054 Uiso 1 1 calc R . . . .
C16 C 0.85801(18) 0.5974(2) -0.0579(4) 0.0536(15) Uani 1 1 d . . . . .
H16A H 0.8570 0.5990 -0.0056 0.064 Uiso 1 1 calc R . . . .
H16B H 0.8827 0.5824 -0.0549 0.064 Uiso 1 1 calc R . . . .
C17 C 0.82291(19) 0.5715(2) -0.1095(4) 0.0615(18) Uani 1 1 d . . . . .
H17A H 0.8242 0.5410 -0.0899 0.074 Uiso 1 1 calc R . . . .
H17B H 0.7984 0.5850 -0.1081 0.074 Uiso 1 1 calc R . . . .
C18 C 0.8216(2) 0.5700(3) -0.1900(5) 0.078(2) Uani 1 1 d . . . . .
H18A H 0.7971 0.5549 -0.2220 0.094 Uiso 1 1 calc R . . . .
H18B H 0.8442 0.5527 -0.1925 0.094 Uiso 1 1 calc R . . . .
C19 C 0.8227(2) 0.6153(3) -0.2217(4) 0.074(2) Uani 1 1 d . . . . .
H19A H 0.7980 0.6309 -0.2271 0.089 Uiso 1 1 calc R . . . .
H19B H 0.8244 0.6126 -0.2733 0.089 Uiso 1 1 calc R . . . .
C20 C 0.85755(17) 0.6428(2) -0.1712(3) 0.0529(15) Uani 1 1 d . . . . .
H20A H 0.8825 0.6298 -0.1717 0.063 Uiso 1 1 calc R . . . .
H20B H 0.8555 0.6732 -0.1914 0.063 Uiso 1 1 calc R . . . .
C21 C 1.05144(13) 0.69491(14) 0.2252(2) 0.0267(9) Uani 1 1 d . . . . .
C22 C 1.08155(13) 0.69805(14) 0.2105(2) 0.0258(9) Uani 1 1 d . . . . .
C23 C 1.11641(14) 0.69949(15) 0.1964(3) 0.0300(10) Uani 1 1 d . . . . .
C24 C 1.14716(14) 0.70125(16) 0.1867(3) 0.0341(11) Uani 1 1 d . . . . .
C25 C 1.18462(15) 0.70244(18) 0.1732(3) 0.0388(11) Uani 1 1 d . . . . .
H25 H 1.2050 0.7138 0.2211 0.047 Uiso 1 1 calc R . . . .
C26 C 1.19722(16) 0.6556(2) 0.1596(4) 0.0477(13) Uani 1 1 d . . . . .
H26A H 1.2004 0.6371 0.2050 0.057 Uiso 1 1 calc R . . . .
H26B H 1.1765 0.6422 0.1152 0.057 Uiso 1 1 calc R . . . .
C27 C 1.23584(19) 0.6570(3) 0.1444(5) 0.069(2) Uani 1 1 d . . . . .
H27A H 1.2573 0.6663 0.1916 0.083 Uiso 1 1 calc R . . . .
H27B H 1.2421 0.6270 0.1311 0.083 Uiso 1 1 calc R . . . .
C28 C 1.2339(2) 0.6881(3) 0.0807(5) 0.078(2) Uani 1 1 d . . . . .
H28A H 1.2598 0.6890 0.0742 0.093 Uiso 1 1 calc R . . . .
H28B H 1.2142 0.6773 0.0323 0.093 Uiso 1 1 calc R . . . .
C29 C 1.22278(19) 0.7337(2) 0.0969(4) 0.0623(17) Uani 1 1 d . . . . .
H29A H 1.2210 0.7533 0.0534 0.075 Uiso 1 1 calc R . . . .
H29B H 1.2435 0.7454 0.1431 0.075 Uiso 1 1 calc R . . . .
C30 C 1.18334(17) 0.7338(2) 0.1096(3) 0.0508(14) Uani 1 1 d . . . . .
H30A H 1.1775 0.7639 0.1228 0.061 Uiso 1 1 calc R . . . .
H30B H 1.1621 0.7248 0.0618 0.061 Uiso 1 1 calc R . . . .
C31 C 0.97666(14) 0.98457(14) 0.1393(2) 0.0292(10) Uani 1 1 d . . . . .
C32 C 0.93696(16) 0.98807(17) 0.1311(3) 0.0411(12) Uani 1 1 d . . . . .
H32 H 0.9214 0.9622 0.1244 0.049 Uiso 1 1 calc R . . . .
C33 C 0.92005(19) 1.02913(18) 0.1328(3) 0.0478(13) Uani 1 1 d . . . . .
H33 H 0.8931 1.0312 0.1276 0.057 Uiso 1 1 calc R . . . .
C34 C 0.94266(19) 1.06660(17) 0.1422(3) 0.0499(14) Uani 1 1 d . . . . .
H34 H 0.9314 1.0947 0.1433 0.060 Uiso 1 1 calc R . . . .
C35 C 0.9816(2) 1.06323(17) 0.1499(3) 0.0502(14) Uani 1 1 d . . . . .
H35 H 0.9969 1.0893 0.1556 0.060 Uiso 1 1 calc R . . . .
C36 C 0.99902(17) 1.02253(16) 0.1494(3) 0.0390(11) Uani 1 1 d . . . . .
H36 H 1.0262 1.0208 0.1559 0.047 Uiso 1 1 calc R . . . .
C37 C 1.04611(14) 0.94017(14) 0.1374(3) 0.0295(10) Uani 1 1 d . . . . .
C38 C 1.05453(15) 0.94634(15) 0.0709(3) 0.0330(10) Uani 1 1 d . . . . .
H38 H 1.0341 0.9444 0.0224 0.040 Uiso 1 1 calc R . . . .
C39 C 1.09302(16) 0.95541(17) 0.0755(3) 0.0410(12) Uani 1 1 d . . . . .
H39 H 1.0987 0.9600 0.0301 0.049 Uiso 1 1 calc R . . . .
C40 C 1.12269(16) 0.95765(17) 0.1455(3) 0.0426(12) Uani 1 1 d . . . . .
H40 H 1.1489 0.9640 0.1486 0.051 Uiso 1 1 calc R . . . .
C41 C 1.11452(17) 0.95079(19) 0.2103(3) 0.0482(13) Uani 1 1 d . . . . .
H41 H 1.1352 0.9520 0.2586 0.058 Uiso 1 1 calc R . . . .
C42 C 1.07661(16) 0.94205(17) 0.2067(3) 0.0400(12) Uani 1 1 d . . . . .
H42 H 1.0715 0.9373 0.2526 0.048 Uiso 1 1 calc R . . . .
C43 C 0.96937(13) 0.91028(14) 0.0422(2) 0.0267(9) Uani 1 1 d . . . . .
C44 C 0.96553(15) 0.86498(15) 0.0283(3) 0.0358(11) Uani 1 1 d . . . . .
H44 H 0.9764 0.8449 0.0694 0.043 Uiso 1 1 calc R . . . .
C45 C 0.94624(16) 0.84920(17) -0.0437(3) 0.0413(12) Uani 1 1 d . . . . .
H45 H 0.9447 0.8183 -0.0525 0.050 Uiso 1 1 calc R . . . .
C46 C 0.92911(15) 0.87732(17) -0.1033(3) 0.0387(11) Uani 1 1 d . . . . .
H46 H 0.9154 0.8660 -0.1530 0.046 Uiso 1 1 calc R . . . .
C47 C 0.93182(15) 0.92226(17) -0.0911(3) 0.0367(11) Uani 1 1 d . . . . .
H47 H 0.9197 0.9420 -0.1321 0.044 Uiso 1 1 calc R . . . .
C48 C 0.95215(14) 0.93822(15) -0.0190(3) 0.0323(10) Uani 1 1 d . . . . .
H48 H 0.9544 0.9692 -0.0110 0.039 Uiso 1 1 calc R . . . .
C49 C 1.17698(12) 0.79485(14) 0.3690(3) 0.0243(9) Uani 1 1 d . . . . .
C50 C 1.16589(14) 0.80511(16) 0.2920(3) 0.0339(10) Uani 1 1 d . . . . .
H50 H 1.1438 0.7909 0.2559 0.041 Uiso 1 1 calc R . . . .
C51 C 1.18694(16) 0.83604(18) 0.2674(3) 0.0434(12) Uani 1 1 d . . . . .
H51 H 1.1799 0.8421 0.2143 0.052 Uiso 1 1 calc R . . . .
C52 C 1.21838(16) 0.85818(18) 0.3204(3) 0.0434(12) Uani 1 1 d . . . . .
H52 H 1.2324 0.8800 0.3038 0.052 Uiso 1 1 calc R . . . .
C53 C 1.22902(14) 0.84828(16) 0.3965(3) 0.0371(11) Uani 1 1 d . . . . .
H53 H 1.2506 0.8633 0.4326 0.045 Uiso 1 1 calc R . . . .
C54 C 1.20873(13) 0.81664(15) 0.4215(3) 0.0304(10) Uani 1 1 d . . . . .
H54 H 1.2165 0.8099 0.4745 0.037 Uiso 1 1 calc R . . . .
C55 C 1.16341(12) 0.76054(14) 0.5012(2) 0.0246(9) Uani 1 1 d . . . . .
C56 C 1.19478(13) 0.73765(15) 0.5526(3) 0.0298(10) Uani 1 1 d . . . . .
H56 H 1.2098 0.7180 0.5341 0.036 Uiso 1 1 calc R . . . .
C57 C 1.20438(15) 0.74323(17) 0.6309(3) 0.0370(11) Uani 1 1 d . . . . .
H57 H 1.2258 0.7273 0.6656 0.044 Uiso 1 1 calc R . . . .
C58 C 1.18298(16) 0.77177(19) 0.6583(3) 0.0435(12) Uani 1 1 d . . . . .
H58 H 1.1894 0.7756 0.7119 0.052 Uiso 1 1 calc R . . . .
C59 C 1.15217(17) 0.79481(19) 0.6074(3) 0.0449(13) Uani 1 1 d . . . . .
H59 H 1.1378 0.8151 0.6262 0.054 Uiso 1 1 calc R . . . .
C60 C 1.14180(15) 0.78884(16) 0.5293(3) 0.0348(11) Uani 1 1 d . . . . .
H60 H 1.1199 0.8042 0.4950 0.042 Uiso 1 1 calc R . . . .
C61 C 1.17265(13) 0.70182(14) 0.3887(2) 0.0248(9) Uani 1 1 d . . . . .
C62 C 1.15284(14) 0.66228(15) 0.3873(3) 0.0334(10) Uani 1 1 d . . . . .
H62 H 1.1275 0.6625 0.3917 0.040 Uiso 1 1 calc R . . . .
C63 C 1.16993(17) 0.62296(16) 0.3797(3) 0.0421(12) Uani 1 1 d . . . . .
H63 H 1.1564 0.5962 0.3795 0.051 Uiso 1 1 calc R . . . .
C64 C 1.20608(16) 0.62185(17) 0.3723(3) 0.0424(12) Uani 1 1 d . . . . .
H64 H 1.2173 0.5945 0.3662 0.051 Uiso 1 1 calc R . . . .
C65 C 1.22632(15) 0.66066(18) 0.3738(3) 0.0412(12) Uani 1 1 d . . . . .
H65 H 1.2515 0.6601 0.3689 0.049 Uiso 1 1 calc R . . . .
C66 C 1.20939(13) 0.70030(16) 0.3824(3) 0.0317(10) Uani 1 1 d . . . . .
H66 H 1.2234 0.7270 0.3840 0.038 Uiso 1 1 calc R . . . .
C67 C 0.98155(12) 0.59367(13) -0.0479(2) 0.0235(9) Uani 1 1 d . . . . .
C68 C 0.98925(15) 0.61527(16) -0.1066(3) 0.0364(11) Uani 1 1 d . . . . .
H68 H 1.0071 0.6394 -0.0949 0.044 Uiso 1 1 calc R . . . .
C69 C 0.97156(16) 0.60239(18) -0.1812(3) 0.0408(12) Uani 1 1 d . . . . .
H69 H 0.9779 0.6171 -0.2203 0.049 Uiso 1 1 calc R . . . .
C70 C 0.94473(15) 0.56848(17) -0.2002(3) 0.0354(11) Uani 1 1 d . . . . .
H70 H 0.9319 0.5604 -0.2522 0.043 Uiso 1 1 calc R . . . .
C71 C 0.93662(14) 0.54640(15) -0.1430(3) 0.0337(10) Uani 1 1 d . . . . .
H71 H 0.9185 0.5226 -0.1553 0.040 Uiso 1 1 calc R . . . .
C72 C 0.95493(13) 0.55898(14) -0.0673(2) 0.0264(9) Uani 1 1 d . . . . .
H72 H 0.9492 0.5436 -0.0281 0.032 Uiso 1 1 calc R . . . .
C73 C 0.98312(12) 0.58256(14) 0.1056(2) 0.0230(8) Uani 1 1 d . . . . .
C74 C 0.98726(14) 0.53749(14) 0.1203(3) 0.0309(10) Uani 1 1 d . . . . .
H74 H 1.0044 0.5207 0.1025 0.037 Uiso 1 1 calc R . . . .
C75 C 0.96671(16) 0.51729(16) 0.1604(3) 0.0379(11) Uani 1 1 d . . . . .
H75 H 0.9696 0.4865 0.1698 0.046 Uiso 1 1 calc R . . . .
C76 C 0.94183(15) 0.54118(17) 0.1871(3) 0.0374(11) Uani 1 1 d . . . . .
H76 H 0.9279 0.5270 0.2153 0.045 Uiso 1 1 calc R . . . .
C77 C 0.93729(14) 0.58574(17) 0.1725(3) 0.0350(11) Uani 1 1 d . . . . .
H77 H 0.9201 0.6023 0.1904 0.042 Uiso 1 1 calc R . . . .
C78 C 0.95766(13) 0.60637(14) 0.1319(2) 0.0265(9) Uani 1 1 d . . . . .
H78 H 0.9543 0.6371 0.1218 0.032 Uiso 1 1 calc R . . . .
C79 C 1.05475(13) 0.58244(14) 0.0738(3) 0.0255(9) Uani 1 1 d . . . . .
C80 C 1.08322(14) 0.59037(15) 0.1447(3) 0.0351(11) Uani 1 1 d . . . . .
H80 H 1.0772 0.6090 0.1800 0.042 Uiso 1 1 calc R . . . .
C81 C 1.12007(15) 0.57173(17) 0.1650(3) 0.0424(12) Uani 1 1 d . . . . .
H81 H 1.1390 0.5773 0.2142 0.051 Uiso 1 1 calc R . . . .
C82 C 1.12964(15) 0.54509(17) 0.1143(4) 0.0449(13) Uani 1 1 d . . . . .
H82 H 1.1552 0.5326 0.1281 0.054 Uiso 1 1 calc R . . . .
C83 C 1.10151(15) 0.53668(17) 0.0429(3) 0.0396(12) Uani 1 1 d . . . . .
H83 H 1.1079 0.5184 0.0076 0.048 Uiso 1 1 calc R . . . .
C84 C 1.06450(14) 0.55478(15) 0.0231(3) 0.0307(10) Uani 1 1 d . . . . .
H84 H 1.0453 0.5484 -0.0256 0.037 Uiso 1 1 calc R . . . .
C85 C 1.06726(13) 0.69637(15) -0.0653(3) 0.0289(10) Uani 1 1 d . . . . .
C86 C 1.09356(15) 0.66580(16) -0.0198(3) 0.0345(11) Uani 1 1 d . . . . .
H86 H 1.0971 0.6638 0.0329 0.041 Uiso 1 1 calc R . . . .
C87 C 1.11467(16) 0.63827(17) -0.0502(3) 0.0414(12) Uani 1 1 d . . . . .
H87 H 1.1327 0.6175 -0.0185 0.050 Uiso 1 1 calc R . . . .
C88 C 1.10928(18) 0.64132(18) -0.1274(3) 0.0460(13) Uani 1 1 d . . . . .
H88 H 1.1238 0.6227 -0.1487 0.055 Uiso 1 1 calc R . . . .
C89 C 1.08294(18) 0.67130(18) -0.1734(3) 0.0468(13) Uani 1 1 d . . . . .
H89 H 1.0793 0.6730 -0.2262 0.056 Uiso 1 1 calc R . . . .
C90 C 1.06189(17) 0.69886(17) -0.1434(3) 0.0389(11) Uani 1 1 d . . . . .
H90 H 1.0438 0.7195 -0.1754 0.047 Uiso 1 1 calc R . . . .
C91 C 1.00018(14) 0.75453(16) -0.0977(3) 0.0309(10) Uani 1 1 d . . . . .
C92 C 1.00212(16) 0.79186(18) -0.1391(3) 0.0404(12) Uani 1 1 d . . . . .
H92 H 1.0263 0.8072 -0.1273 0.048 Uiso 1 1 calc R . . . .
C93 C 0.96910(18) 0.8069(2) -0.1973(3) 0.0475(14) Uani 1 1 d . . . . .
H93 H 0.9708 0.8325 -0.2252 0.057 Uiso 1 1 calc R . . . .
C94 C 0.93399(18) 0.7853(2) -0.2152(3) 0.0506(15) Uani 1 1 d . . . . .
H94 H 0.9116 0.7954 -0.2560 0.061 Uiso 1 1 calc R . . . .
C95 C 0.93138(17) 0.74854(19) -0.1735(3) 0.0469(14) Uani 1 1 d . . . . .
H95 H 0.9069 0.7338 -0.1849 0.056 Uiso 1 1 calc R . . . .
C96 C 0.96411(15) 0.73313(18) -0.1155(3) 0.0377(11) Uani 1 1 d . . . . .
H96 H 0.9621 0.7077 -0.0874 0.045 Uiso 1 1 calc R . . . .
C97 C 1.07572(13) 0.77927(15) 0.0095(3) 0.0288(9) Uani 1 1 d . . . . .
C98 C 1.07704(14) 0.80311(16) 0.0740(3) 0.0336(10) Uani 1 1 d . . . . .
H98 H 1.0614 0.7942 0.1028 0.040 Uiso 1 1 calc R . . . .
C99 C 1.10096(16) 0.83961(17) 0.0963(3) 0.0399(12) Uani 1 1 d . . . . .
H99 H 1.1013 0.8561 0.1398 0.048 Uiso 1 1 calc R . . . .
C100 C 1.12421(16) 0.85200(17) 0.0555(3) 0.0425(12) Uani 1 1 d . . . . .
H100 H 1.1408 0.8771 0.0710 0.051 Uiso 1 1 calc R . . . .
C101 C 1.12359(16) 0.82821(17) -0.0077(3) 0.0417(12) Uani 1 1 d . . . . .
H101 H 1.1397 0.8369 -0.0358 0.050 Uiso 1 1 calc R . . . .
C102 C 1.09972(15) 0.79184(16) -0.0302(3) 0.0355(11) Uani 1 1 d . . . . .
H102 H 1.0997 0.7753 -0.0734 0.043 Uiso 1 1 calc R . . . .
C103 C 0.7347(3) 0.6460(4) 0.6043(7) 0.117(4) Uani 1 1 d . U . . .
H10C H 0.7374 0.6488 0.5541 0.176 Uiso 1 1 calc GR . . . .
H10D H 0.7599 0.6530 0.6444 0.176 Uiso 1 1 calc GR . . . .
H10E H 0.7145 0.6665 0.6076 0.176 Uiso 1 1 calc GR . . . .
C104 C 0.7285(3) 0.4955(4) 0.3077(7) 0.115(4) Uani 1 1 d . U . . .
H10F H 0.7256 0.4809 0.2592 0.172 Uiso 1 1 calc GR . . . .
H10G H 0.7040 0.5108 0.3031 0.172 Uiso 1 1 calc GR . . . .
H10H H 0.7344 0.4735 0.3485 0.172 Uiso 1 1 calc GR . . . .
C105 C 1.1707(3) 0.7477(4) 0.8727(6) 0.098(3) Uani 1 1 d . . . . .
H10I H 1.1732 0.7188 0.8515 0.148 Uiso 1 1 calc GR . . . .
H10J H 1.1494 0.7469 0.8935 0.148 Uiso 1 1 calc GR . . . .
H10K H 1.1954 0.7553 0.9135 0.148 Uiso 1 1 calc GR . . . .
C106 C 1.1602(3) 0.8915(4) -0.2185(7) 0.128(4) Uani 1 1 d . U . . .
H10L H 1.1590 0.8715 -0.2605 0.192 Uiso 1 1 calc GR . . . .
H10M H 1.1857 0.9066 -0.2007 0.192 Uiso 1 1 calc GR . . . .
H10N H 1.1390 0.9132 -0.2364 0.192 Uiso 1 1 calc GR . . . .
O4 O 0.7237(2) 0.6026(3) 0.6142(5) 0.117(2) Uani 1 1 d . U . . .
H4 H 0.7335 0.5851 0.5909 0.176 Uiso 1 1 calc GR . . . .
O5 O 0.7611(3) 0.5278(3) 0.3261(6) 0.138(3) Uani 1 1 d . U . . .
H5A H 0.7685 0.5342 0.3728 0.208 Uiso 1 1 calc GR . . . .
O6 O 1.1624(3) 0.7787(3) 0.8164(4) 0.127(3) Uani 1 1 d . U . . .
H6 H 1.1657 0.8039 0.8360 0.190 Uiso 1 1 calc GR . . . .
O7 O 1.1560(3) 0.8675(3) -0.1589(5) 0.136(3) Uani 1 1 d . U . . .
H7 H 1.1759 0.8711 -0.1193 0.204 Uiso 1 1 calc GR . . A 1
O1W O 0.6873(3) 0.5796(3) 0.4563(5) 0.133(3) Uiso 1 1 d . U . . .
H1WA H 0.6811 0.5749 0.4075 0.199 Uiso 1 1 d G . . . .
H1WB H 0.7109 0.5906 0.4708 0.199 Uiso 1 1 d G . . . .
O2W O 0.7945(3) 0.4730(3) 0.7057(5) 0.058(2) Uiso 0.5 1 d . . . . .
H2WA H 0.7855 0.4667 0.7419 0.087 Uiso 0.5 1 d G . . . .
H2WB H 0.8191 0.4798 0.7296 0.087 Uiso 0.5 1 d G . . . .
O2 O 0.7819(2) 0.5511(3) 0.5982(5) 0.119(2) Uiso 1 1 d D . . . .
O3 O 0.7638(2) 0.5612(3) 0.4661(5) 0.122(2) Uiso 1 1 d D . . . .
N1 N 0.7891(4) 0.5545(4) 0.5336(7) 0.155(4) Uiso 1 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 N1 1.381(13) . ?
Ag1 Ag1 3.0675(6) 2_755 ?
Ag1 Ag2 3.1375(5) . ?
Ag1 Ag3 3.1613(5) . ?
Ag1 Ag3 3.2087(5) 2_755 ?
Ag1 Ag4 3.3652(5) . ?
Ag1 C1 2.078(4) . ?
Ag1 C11 2.071(5) . ?
Ag2 Ag1 3.1375(5) 2_755 ?
Ag2 Ag3 3.2114(4) 2_755 ?
Ag2 Ag3 3.2115(4) . ?
Ag2 C21 2.075(4) . ?
Ag2 C21 2.075(4) 2_755 ?
Ag3 Ag1 3.2087(5) 2_755 ?
Ag3 P2 2.4913(11) . ?
Ag3 C1 2.505(4) . ?
Ag3 C11 2.516(4) 2_755 ?
Ag3 C21 2.536(4) . ?
Ag4 Ag1 3.3651(5) 2_755 ?
Ag4 P1 2.5027(11) 2_755 ?
Ag4 P1 2.5028(11) . ?
Ag4 C1 2.556(4) 2_755 ?
Ag4 C1 2.556(4) . ?
Ag5 P3 2.5221(11) . ?
Ag5 P4 2.4994(11) . ?
Ag5 C11 2.612(4) . ?
Ag5 C21 2.637(4) . ?
P1 C31 1.825(5) . ?
P1 C37 1.824(5) . ?
P1 C43 1.811(5) . ?
P2 C49 1.828(4) . ?
P2 C55 1.821(4) . ?
P2 C61 1.820(4) . ?
P3 C67 1.820(4) . ?
P3 C73 1.810(4) . ?
P3 C79 1.820(4) . ?
P4 C85 1.828(5) . ?
P4 C91 1.826(5) . ?
P4 C97 1.824(5) . ?
C1 C2 1.215(6) . ?
C2 C3 1.378(7) . ?
C3 C4 1.199(7) . ?
C4 C5 1.470(7) . ?
C5 H5 1.0000 . ?
C5 C6 1.514(8) . ?
C5 C10 1.538(8) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C6 C7 1.543(8) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C7 C8 1.488(10) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C8 C9 1.507(10) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C10 1.531(8) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 Ag3 2.516(4) 2_755 ?
C11 C12 1.229(6) . ?
C12 C13 1.370(6) . ?
C13 C14 1.201(7) . ?
C14 C15 1.463(7) . ?
C15 H15 1.0000 . ?
C15 C16 1.520(8) . ?
C15 C20 1.530(9) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C17 1.520(8) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C17 C18 1.486(11) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C18 C19 1.503(11) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C20 1.531(8) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.220(6) . ?
C22 C23 1.380(6) . ?
C23 C24 1.193(7) . ?
C24 C25 1.467(7) . ?
C25 H25 1.0000 . ?
C25 C26 1.542(8) . ?
C25 C30 1.510(8) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C26 C27 1.524(8) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C28 1.502(12) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C28 C29 1.502(11) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C29 C30 1.530(8) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.399(7) . ?
C31 C36 1.383(7) . ?
C32 H32 0.9500 . ?
C32 C33 1.395(7) . ?
C33 H33 0.9500 . ?
C33 C34 1.377(8) . ?
C34 H34 0.9500 . ?
C34 C35 1.372(9) . ?
C35 H35 0.9500 . ?
C35 C36 1.390(7) . ?
C36 H36 0.9500 . ?
C37 C38 1.390(6) . ?
C37 C42 1.378(7) . ?
C38 H38 0.9500 . ?
C38 C39 1.397(7) . ?
C39 H39 0.9500 . ?
C39 C40 1.373(8) . ?
C40 H40 0.9500 . ?
C40 C41 1.358(8) . ?
C41 H41 0.9500 . ?
C41 C42 1.380(8) . ?
C42 H42 0.9500 . ?
C43 C44 1.397(6) . ?
C43 C48 1.384(6) . ?
C44 H44 0.9500 . ?
C44 C45 1.366(7) . ?
C45 H45 0.9500 . ?
C45 C46 1.366(7) . ?
C46 H46 0.9500 . ?
C46 C47 1.381(7) . ?
C47 H47 0.9500 . ?
C47 C48 1.376(7) . ?
C48 H48 0.9500 . ?
C49 C50 1.387(7) . ?
C49 C54 1.390(6) . ?
C50 H50 0.9500 . ?
C50 C51 1.386(7) . ?
C51 H51 0.9500 . ?
C51 C52 1.393(8) . ?
C52 H52 0.9500 . ?
C52 C53 1.368(8) . ?
C53 H53 0.9500 . ?
C53 C54 1.387(7) . ?
C54 H54 0.9500 . ?
C55 C56 1.390(6) . ?
C55 C60 1.384(7) . ?
C56 H56 0.9500 . ?
C56 C57 1.389(7) . ?
C57 H57 0.9500 . ?
C57 C58 1.376(8) . ?
C58 H58 0.9500 . ?
C58 C59 1.377(8) . ?
C59 H59 0.9500 . ?
C59 C60 1.385(7) . ?
C60 H60 0.9500 . ?
C61 C62 1.395(6) . ?
C61 C66 1.380(6) . ?
C62 H62 0.9500 . ?
C62 C63 1.375(7) . ?
C63 H63 0.9500 . ?
C63 C64 1.366(8) . ?
C64 H64 0.9500 . ?
C64 C65 1.383(8) . ?
C65 H65 0.9500 . ?
C65 C66 1.385(7) . ?
C66 H66 0.9500 . ?
C67 C68 1.387(6) . ?
C67 C72 1.388(6) . ?
C68 H68 0.9500 . ?
C68 C69 1.369(7) . ?
C69 H69 0.9500 . ?
C69 C70 1.375(7) . ?
C70 H70 0.9500 . ?
C70 C71 1.378(7) . ?
C71 H71 0.9500 . ?
C71 C72 1.387(6) . ?
C72 H72 0.9500 . ?
C73 C74 1.393(6) . ?
C73 C78 1.391(6) . ?
C74 H74 0.9500 . ?
C74 C75 1.372(7) . ?
C75 H75 0.9500 . ?
C75 C76 1.381(7) . ?
C76 H76 0.9500 . ?
C76 C77 1.378(7) . ?
C77 H77 0.9500 . ?
C77 C78 1.381(6) . ?
C78 H78 0.9500 . ?
C79 C80 1.385(7) . ?
C79 C84 1.401(6) . ?
C80 H80 0.9500 . ?
C80 C81 1.377(7) . ?
C81 H81 0.9500 . ?
C81 C82 1.378(8) . ?
C82 H82 0.9500 . ?
C82 C83 1.390(8) . ?
C83 H83 0.9500 . ?
C83 C84 1.376(7) . ?
C84 H84 0.9500 . ?
C85 C86 1.387(7) . ?
C85 C90 1.404(7) . ?
C86 H86 0.9500 . ?
C86 C87 1.382(7) . ?
C87 H87 0.9500 . ?
C87 C88 1.389(8) . ?
C88 H88 0.9500 . ?
C88 C89 1.379(8) . ?
C89 H89 0.9500 . ?
C89 C90 1.376(8) . ?
C90 H90 0.9500 . ?
C91 C92 1.388(7) . ?
C91 C96 1.393(7) . ?
C92 H92 0.9500 . ?
C92 C93 1.382(8) . ?
C93 H93 0.9500 . ?
C93 C94 1.366(9) . ?
C94 H94 0.9500 . ?
C94 C95 1.382(9) . ?
C95 H95 0.9500 . ?
C95 C96 1.379(8) . ?
C96 H96 0.9500 . ?
C97 C98 1.390(7) . ?
C97 C102 1.382(6) . ?
C98 H98 0.9500 . ?
C98 C99 1.378(7) . ?
C99 H99 0.9500 . ?
C99 C100 1.373(7) . ?
C100 H100 0.9500 . ?
C100 C101 1.377(8) . ?
C101 H101 0.9500 . ?
C101 C102 1.375(7) . ?
C102 H102 0.9500 . ?
C103 H10C 0.9800 . ?
C103 H10D 0.9800 . ?
C103 H10E 0.9800 . ?
C103 O4 1.407(12) . ?
C104 H10F 0.9800 . ?
C104 H10G 0.9800 . ?
C104 H10H 0.9800 . ?
C104 O5 1.480(13) . ?
C105 H10I 0.9800 . ?
C105 H10J 0.9800 . ?
C105 H10K 0.9800 . ?
C105 O6 1.363(12) . ?
C106 H10L 0.9800 . ?
C106 H10M 0.9800 . ?
C106 H10N 0.9800 . ?
C106 O7 1.383(13) . ?
O4 H4 0.8400 . ?
O5 H5A 0.8400 . ?
O6 H6 0.8400 . ?
O7 H7 0.8400 . ?
O1W H1WA 0.8702 . ?
O1W H1WB 0.8695 . ?
O2W H2WA 0.8696 . ?
O2W H2WB 0.8699 . ?
O2 N1 1.326(11) . ?
O3 N1 1.289(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 Ag1 Ag2 60.735(7) 2_755 . ?
Ag1 Ag1 Ag3 61.992(12) 2_755 . ?
Ag1 Ag1 Ag3 60.438(11) 2_755 2_755 ?
Ag1 Ag1 Ag4 62.883(7) 2_755 . ?
Ag2 Ag1 Ag3 61.308(8) . . ?
Ag2 Ag1 Ag3 60.788(8) . 2_755 ?
Ag2 Ag1 Ag4 123.618(12) . . ?
Ag3 Ag1 Ag3 111.946(12) . 2_755 ?
Ag3 Ag1 Ag4 92.384(11) . . ?
Ag3 Ag1 Ag4 91.545(10) 2_755 . ?
C1 Ag1 Ag1 72.20(11) . 2_755 ?
C1 Ag1 Ag2 110.65(11) . . ?
C1 Ag1 Ag3 52.30(11) . . ?
C1 Ag1 Ag3 129.49(11) . 2_755 ?
C1 Ag1 Ag4 49.34(11) . . ?
C11 Ag1 Ag1 109.32(11) . 2_755 ?
C11 Ag1 Ag2 71.09(11) . . ?
C11 Ag1 Ag3 51.61(11) . 2_755 ?
C11 Ag1 Ag3 129.16(11) . . ?
C11 Ag1 Ag4 130.28(11) . . ?
C11 Ag1 C1 178.20(16) . . ?
Ag1 Ag2 Ag1 58.530(14) 2_755 . ?
Ag1 Ag2 Ag3 59.711(11) . . ?
Ag1 Ag2 Ag3 59.711(11) 2_755 2_755 ?
Ag1 Ag2 Ag3 60.702(11) . 2_755 ?
Ag1 Ag2 Ag3 60.701(11) 2_755 . ?
Ag3 Ag2 Ag3 110.562(18) 2_755 . ?
C21 Ag2 Ag1 69.14(12) 2_755 2_755 ?
C21 Ag2 Ag1 108.73(12) 2_755 . ?
C21 Ag2 Ag1 108.73(12) . 2_755 ?
C21 Ag2 Ag1 69.13(12) . . ?
C21 Ag2 Ag3 52.08(12) 2_755 2_755 ?
C21 Ag2 Ag3 126.27(12) 2_755 . ?
C21 Ag2 Ag3 126.27(12) . 2_755 ?
C21 Ag2 Ag3 52.08(12) . . ?
C21 Ag2 C21 177.7(2) 2_755 . ?
Ag1 Ag3 Ag1 57.568(12) . 2_755 ?
Ag1 Ag3 Ag2 58.981(10) . . ?
Ag1 Ag3 Ag2 58.509(10) 2_755 . ?
P2 Ag3 Ag1 145.19(3) . . ?
P2 Ag3 Ag1 147.25(3) . 2_755 ?
P2 Ag3 Ag2 144.79(3) . . ?
P2 Ag3 C1 114.82(10) . . ?
P2 Ag3 C11 116.81(10) . 2_755 ?
P2 Ag3 C21 115.23(10) . . ?
C1 Ag3 Ag1 41.01(10) . . ?
C1 Ag3 Ag1 65.21(9) . 2_755 ?
C1 Ag3 Ag2 97.75(10) . . ?
C1 Ag3 C11 102.04(14) . 2_755 ?
C1 Ag3 C21 102.41(14) . . ?
C11 Ag3 Ag1 95.69(10) 2_755 . ?
C11 Ag3 Ag1 40.18(10) 2_755 2_755 ?
C11 Ag3 Ag2 65.41(10) 2_755 . ?
C11 Ag3 C21 103.56(14) 2_755 . ?
C21 Ag3 Ag1 95.66(10) . 2_755 ?
C21 Ag3 Ag1 64.46(10) . . ?
C21 Ag3 Ag2 40.21(10) . . ?
Ag1 Ag4 Ag1 54.231(13) 2_755 . ?
P1 Ag4 Ag1 150.60(3) . 2_755 ?
P1 Ag4 Ag1 150.60(3) 2_755 . ?
P1 Ag4 Ag1 98.44(3) 2_755 2_755 ?
P1 Ag4 Ag1 98.44(3) . . ?
P1 Ag4 P1 110.24(5) 2_755 . ?
P1 Ag4 C1 104.41(10) . . ?
P1 Ag4 C1 104.41(10) 2_755 2_755 ?
P1 Ag4 C1 123.82(10) . 2_755 ?
P1 Ag4 C1 123.82(10) 2_755 . ?
C1 Ag4 Ag1 62.20(9) 2_755 . ?
C1 Ag4 Ag1 38.09(10) 2_755 2_755 ?
C1 Ag4 Ag1 62.19(9) . 2_755 ?
C1 Ag4 Ag1 38.09(10) . . ?
C1 Ag4 C1 90.48(18) 2_755 . ?
P3 Ag5 C11 123.39(10) . . ?
P3 Ag5 C21 101.85(9) . . ?
P4 Ag5 P3 115.07(4) . . ?
P4 Ag5 C11 103.30(9) . . ?
P4 Ag5 C21 127.09(10) . . ?
C11 Ag5 C21 84.42(13) . . ?
C31 P1 Ag4 114.46(14) . . ?
C37 P1 Ag4 110.33(15) . . ?
C37 P1 C31 103.7(2) . . ?
C43 P1 Ag4 119.28(14) . . ?
C43 P1 C31 103.0(2) . . ?
C43 P1 C37 104.5(2) . . ?
C49 P2 Ag3 115.54(14) . . ?
C55 P2 Ag3 115.05(14) . . ?
C55 P2 C49 104.04(19) . . ?
C61 P2 Ag3 113.82(14) . . ?
C61 P2 C49 103.2(2) . . ?
C61 P2 C55 103.7(2) . . ?
C67 P3 Ag5 117.52(14) . . ?
C67 P3 C79 102.87(19) . . ?
C73 P3 Ag5 116.53(14) . . ?
C73 P3 C67 104.26(19) . . ?
C73 P3 C79 104.1(2) . . ?
C79 P3 Ag5 109.97(14) . . ?
C85 P4 Ag5 112.31(15) . . ?
C91 P4 Ag5 110.83(15) . . ?
C91 P4 C85 104.7(2) . . ?
C97 P4 Ag5 121.58(15) . . ?
C97 P4 C85 102.2(2) . . ?
C97 P4 C91 103.6(2) . . ?
Ag1 C1 Ag3 86.69(14) . . ?
Ag1 C1 Ag4 92.57(16) . . ?
Ag3 C1 Ag4 137.20(17) . . ?
C2 C1 Ag1 175.2(4) . . ?
C2 C1 Ag3 89.6(3) . . ?
C2 C1 Ag4 88.0(3) . . ?
C1 C2 C3 178.1(5) . . ?
C4 C3 C2 175.4(5) . . ?
C3 C4 C5 178.1(6) . . ?
C4 C5 H5 107.9 . . ?
C4 C5 C6 111.1(5) . . ?
C4 C5 C10 110.7(5) . . ?
C6 C5 H5 107.9 . . ?
C6 C5 C10 111.0(5) . . ?
C10 C5 H5 107.9 . . ?
C5 C6 H6A 109.6 . . ?
C5 C6 H6B 109.6 . . ?
C5 C6 C7 110.5(5) . . ?
H6A C6 H6B 108.1 . . ?
C7 C6 H6A 109.6 . . ?
C7 C6 H6B 109.6 . . ?
C6 C7 H7A 109.4 . . ?
C6 C7 H7B 109.4 . . ?
H7A C7 H7B 108.0 . . ?
C8 C7 C6 111.1(5) . . ?
C8 C7 H7A 109.4 . . ?
C8 C7 H7B 109.4 . . ?
C7 C8 H8A 109.4 . . ?
C7 C8 H8B 109.4 . . ?
C7 C8 C9 111.2(6) . . ?
H8A C8 H8B 108.0 . . ?
C9 C8 H8A 109.4 . . ?
C9 C8 H8B 109.4 . . ?
C8 C9 H9A 109.3 . . ?
C8 C9 H9B 109.3 . . ?
C8 C9 C10 111.8(6) . . ?
H9A C9 H9B 107.9 . . ?
C10 C9 H9A 109.3 . . ?
C10 C9 H9B 109.3 . . ?
C5 C10 H10A 109.8 . . ?
C5 C10 H10B 109.8 . . ?
C9 C10 C5 109.5(5) . . ?
C9 C10 H10A 109.8 . . ?
C9 C10 H10B 109.8 . . ?
H10A C10 H10B 108.2 . . ?
Ag1 C11 Ag3 88.21(15) . 2_755 ?
Ag1 C11 Ag5 93.94(16) . . ?
Ag3 C11 Ag5 141.05(17) 2_755 . ?
C12 C11 Ag1 176.1(4) . . ?
C12 C11 Ag3 89.7(3) . 2_755 ?
C12 C11 Ag5 85.6(3) . . ?
C11 C12 C13 179.3(5) . . ?
C14 C13 C12 177.1(5) . . ?
C13 C14 C15 176.6(5) . . ?
C14 C15 H15 107.4 . . ?
C14 C15 C16 111.8(5) . . ?
C14 C15 C20 111.1(5) . . ?
C16 C15 H15 107.4 . . ?
C16 C15 C20 111.4(5) . . ?
C20 C15 H15 107.4 . . ?
C15 C16 H16A 109.7 . . ?
C15 C16 H16B 109.7 . . ?
C15 C16 C17 109.9(5) . . ?
H16A C16 H16B 108.2 . . ?
C17 C16 H16A 109.7 . . ?
C17 C16 H16B 109.7 . . ?
C16 C17 H17A 109.1 . . ?
C16 C17 H17B 109.1 . . ?
H17A C17 H17B 107.9 . . ?
C18 C17 C16 112.3(6) . . ?
C18 C17 H17A 109.1 . . ?
C18 C17 H17B 109.1 . . ?
C17 C18 H18A 109.2 . . ?
C17 C18 H18B 109.2 . . ?
C17 C18 C19 112.1(6) . . ?
H18A C18 H18B 107.9 . . ?
C19 C18 H18A 109.2 . . ?
C19 C18 H18B 109.2 . . ?
C18 C19 H19A 109.0 . . ?
C18 C19 H19B 109.0 . . ?
C18 C19 C20 112.7(6) . . ?
H19A C19 H19B 107.8 . . ?
C20 C19 H19A 109.0 . . ?
C20 C19 H19B 109.0 . . ?
C15 C20 C19 109.6(5) . . ?
C15 C20 H20A 109.8 . . ?
C15 C20 H20B 109.8 . . ?
C19 C20 H20A 109.8 . . ?
C19 C20 H20B 109.8 . . ?
H20A C20 H20B 108.2 . . ?
Ag2 C21 Ag3 87.71(15) . . ?
Ag2 C21 Ag5 98.15(17) . . ?
Ag3 C21 Ag5 136.67(17) . . ?
C22 C21 Ag2 176.7(4) . . ?
C22 C21 Ag3 90.1(3) . . ?
C22 C21 Ag5 81.8(3) . . ?
C21 C22 C23 176.7(5) . . ?
C24 C23 C22 177.8(5) . . ?
C23 C24 C25 178.4(5) . . ?
C24 C25 H25 107.2 . . ?
C24 C25 C26 110.6(4) . . ?
C24 C25 C30 112.1(5) . . ?
C26 C25 H25 107.2 . . ?
C30 C25 H25 107.2 . . ?
C30 C25 C26 112.3(5) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 108.1 . . ?
C27 C26 C25 110.6(5) . . ?
C27 C26 H26A 109.5 . . ?
C27 C26 H26B 109.5 . . ?
C26 C27 H27A 109.2 . . ?
C26 C27 H27B 109.2 . . ?
H27A C27 H27B 107.9 . . ?
C28 C27 C26 111.9(6) . . ?
C28 C27 H27A 109.2 . . ?
C28 C27 H27B 109.2 . . ?
C27 C28 H28A 109.4 . . ?
C27 C28 H28B 109.4 . . ?
H28A C28 H28B 108.0 . . ?
C29 C28 C27 111.2(6) . . ?
C29 C28 H28A 109.4 . . ?
C29 C28 H28B 109.4 . . ?
C28 C29 H29A 109.4 . . ?
C28 C29 H29B 109.4 . . ?
C28 C29 C30 111.4(5) . . ?
H29A C29 H29B 108.0 . . ?
C30 C29 H29A 109.4 . . ?
C30 C29 H29B 109.4 . . ?
C25 C30 C29 110.4(5) . . ?
C25 C30 H30A 109.6 . . ?
C25 C30 H30B 109.6 . . ?
C29 C30 H30A 109.6 . . ?
C29 C30 H30B 109.6 . . ?
H30A C30 H30B 108.1 . . ?
C32 C31 P1 117.9(4) . . ?
C36 C31 P1 123.1(4) . . ?
C36 C31 C32 119.0(4) . . ?
C31 C32 H32 119.7 . . ?
C33 C32 C31 120.7(5) . . ?
C33 C32 H32 119.7 . . ?
C32 C33 H33 120.2 . . ?
C34 C33 C32 119.6(6) . . ?
C34 C33 H33 120.2 . . ?
C33 C34 H34 120.1 . . ?
C35 C34 C33 119.8(5) . . ?
C35 C34 H34 120.1 . . ?
C34 C35 H35 119.3 . . ?
C34 C35 C36 121.3(5) . . ?
C36 C35 H35 119.3 . . ?
C31 C36 C35 119.6(5) . . ?
C31 C36 H36 120.2 . . ?
C35 C36 H36 120.2 . . ?
C38 C37 P1 123.6(4) . . ?
C42 C37 P1 117.9(4) . . ?
C42 C37 C38 118.5(5) . . ?
C37 C38 H38 120.0 . . ?
C37 C38 C39 120.0(5) . . ?
C39 C38 H38 120.0 . . ?
C38 C39 H39 120.0 . . ?
C40 C39 C38 120.1(5) . . ?
C40 C39 H39 120.0 . . ?
C39 C40 H40 120.1 . . ?
C41 C40 C39 119.8(5) . . ?
C41 C40 H40 120.1 . . ?
C40 C41 H41 119.6 . . ?
C40 C41 C42 120.8(5) . . ?
C42 C41 H41 119.6 . . ?
C37 C42 C41 120.8(5) . . ?
C37 C42 H42 119.6 . . ?
C41 C42 H42 119.6 . . ?
C44 C43 P1 119.1(3) . . ?
C48 C43 P1 123.3(3) . . ?
C48 C43 C44 117.6(4) . . ?
C43 C44 H44 119.6 . . ?
C45 C44 C43 120.7(4) . . ?
C45 C44 H44 119.6 . . ?
C44 C45 H45 119.6 . . ?
C46 C45 C44 120.8(5) . . ?
C46 C45 H45 119.6 . . ?
C45 C46 H46 120.1 . . ?
C45 C46 C47 119.8(5) . . ?
C47 C46 H46 120.1 . . ?
C46 C47 H47 120.3 . . ?
C48 C47 C46 119.5(5) . . ?
C48 C47 H47 120.3 . . ?
C43 C48 H48 119.2 . . ?
C47 C48 C43 121.6(4) . . ?
C47 C48 H48 119.2 . . ?
C50 C49 P2 118.4(3) . . ?
C50 C49 C54 119.5(4) . . ?
C54 C49 P2 122.1(3) . . ?
C49 C50 H50 119.9 . . ?
C51 C50 C49 120.2(4) . . ?
C51 C50 H50 119.9 . . ?
C50 C51 H51 120.0 . . ?
C50 C51 C52 120.0(5) . . ?
C52 C51 H51 120.0 . . ?
C51 C52 H52 120.2 . . ?
C53 C52 C51 119.6(5) . . ?
C53 C52 H52 120.2 . . ?
C52 C53 H53 119.6 . . ?
C52 C53 C54 120.8(5) . . ?
C54 C53 H53 119.6 . . ?
C49 C54 H54 120.1 . . ?
C53 C54 C49 119.9(4) . . ?
C53 C54 H54 120.1 . . ?
C56 C55 P2 122.1(3) . . ?
C60 C55 P2 118.9(3) . . ?
C60 C55 C56 119.0(4) . . ?
C55 C56 H56 119.7 . . ?
C57 C56 C55 120.5(4) . . ?
C57 C56 H56 119.7 . . ?
C56 C57 H57 119.9 . . ?
C58 C57 C56 120.1(5) . . ?
C58 C57 H57 119.9 . . ?
C57 C58 H58 120.3 . . ?
C59 C58 C57 119.4(5) . . ?
C59 C58 H58 120.3 . . ?
C58 C59 H59 119.5 . . ?
C58 C59 C60 121.0(5) . . ?
C60 C59 H59 119.5 . . ?
C55 C60 C59 120.0(5) . . ?
C55 C60 H60 120.0 . . ?
C59 C60 H60 120.0 . . ?
C62 C61 P2 118.5(3) . . ?
C66 C61 P2 123.0(3) . . ?
C66 C61 C62 118.5(4) . . ?
C61 C62 H62 120.0 . . ?
C63 C62 C61 120.0(4) . . ?
C63 C62 H62 120.0 . . ?
C62 C63 H63 119.5 . . ?
C64 C63 C62 121.0(5) . . ?
C64 C63 H63 119.5 . . ?
C63 C64 H64 120.0 . . ?
C63 C64 C65 119.9(5) . . ?
C65 C64 H64 120.0 . . ?
C64 C65 H65 120.4 . . ?
C64 C65 C66 119.2(5) . . ?
C66 C65 H65 120.4 . . ?
C61 C66 C65 121.3(5) . . ?
C61 C66 H66 119.3 . . ?
C65 C66 H66 119.3 . . ?
C68 C67 P3 118.5(3) . . ?
C68 C67 C72 117.9(4) . . ?
C72 C67 P3 123.6(3) . . ?
C67 C68 H68 119.5 . . ?
C69 C68 C67 121.0(5) . . ?
C69 C68 H68 119.5 . . ?
C68 C69 H69 119.6 . . ?
C68 C69 C70 120.9(5) . . ?
C70 C69 H69 119.6 . . ?
C69 C70 H70 120.4 . . ?
C69 C70 C71 119.2(4) . . ?
C71 C70 H70 120.4 . . ?
C70 C71 H71 120.0 . . ?
C70 C71 C72 120.0(5) . . ?
C72 C71 H71 120.0 . . ?
C67 C72 H72 119.5 . . ?
C71 C72 C67 121.0(4) . . ?
C71 C72 H72 119.5 . . ?
C74 C73 P3 122.7(3) . . ?
C78 C73 P3 118.6(3) . . ?
C78 C73 C74 118.7(4) . . ?
C73 C74 H74 119.8 . . ?
C75 C74 C73 120.3(4) . . ?
C75 C74 H74 119.8 . . ?
C74 C75 H75 119.6 . . ?
C74 C75 C76 120.8(4) . . ?
C76 C75 H75 119.6 . . ?
C75 C76 H76 120.3 . . ?
C77 C76 C75 119.4(4) . . ?
C77 C76 H76 120.3 . . ?
C76 C77 H77 119.9 . . ?
C76 C77 C78 120.3(4) . . ?
C78 C77 H77 119.9 . . ?
C73 C78 H78 119.7 . . ?
C77 C78 C73 120.5(4) . . ?
C77 C78 H78 119.7 . . ?
C80 C79 P3 118.0(3) . . ?
C80 C79 C84 118.0(4) . . ?
C84 C79 P3 123.9(3) . . ?
C79 C80 H80 119.4 . . ?
C81 C80 C79 121.2(5) . . ?
C81 C80 H80 119.4 . . ?
C80 C81 H81 119.8 . . ?
C80 C81 C82 120.5(5) . . ?
C82 C81 H81 119.8 . . ?
C81 C82 H82 120.3 . . ?
C81 C82 C83 119.3(5) . . ?
C83 C82 H82 120.3 . . ?
C82 C83 H83 119.9 . . ?
C84 C83 C82 120.2(5) . . ?
C84 C83 H83 119.9 . . ?
C79 C84 H84 119.6 . . ?
C83 C84 C79 120.8(5) . . ?
C83 C84 H84 119.6 . . ?
C86 C85 P4 117.7(3) . . ?
C86 C85 C90 119.1(4) . . ?
C90 C85 P4 123.2(4) . . ?
C85 C86 H86 119.5 . . ?
C87 C86 C85 121.0(5) . . ?
C87 C86 H86 119.5 . . ?
C86 C87 H87 120.4 . . ?
C86 C87 C88 119.2(5) . . ?
C88 C87 H87 120.4 . . ?
C87 C88 H88 119.9 . . ?
C89 C88 C87 120.3(5) . . ?
C89 C88 H88 119.9 . . ?
C88 C89 H89 119.6 . . ?
C90 C89 C88 120.7(5) . . ?
C90 C89 H89 119.6 . . ?
C85 C90 H90 120.2 . . ?
C89 C90 C85 119.6(5) . . ?
C89 C90 H90 120.2 . . ?
C92 C91 P4 123.7(4) . . ?
C92 C91 C96 118.3(5) . . ?
C96 C91 P4 117.9(4) . . ?
C91 C92 H92 119.7 . . ?
C93 C92 C91 120.5(5) . . ?
C93 C92 H92 119.7 . . ?
C92 C93 H93 119.6 . . ?
C94 C93 C92 120.8(6) . . ?
C94 C93 H93 119.6 . . ?
C93 C94 H94 120.3 . . ?
C93 C94 C95 119.4(5) . . ?
C95 C94 H94 120.3 . . ?
C94 C95 H95 119.8 . . ?
C96 C95 C94 120.4(5) . . ?
C96 C95 H95 119.8 . . ?
C91 C96 H96 119.7 . . ?
C95 C96 C91 120.5(5) . . ?
C95 C96 H96 119.7 . . ?
C98 C97 P4 118.3(3) . . ?
C102 C97 P4 122.7(4) . . ?
C102 C97 C98 119.0(4) . . ?
C97 C98 H98 119.8 . . ?
C99 C98 C97 120.5(4) . . ?
C99 C98 H98 119.8 . . ?
C98 C99 H99 120.1 . . ?
C100 C99 C98 119.8(5) . . ?
C100 C99 H99 120.1 . . ?
C99 C100 H100 119.9 . . ?
C99 C100 C101 120.2(5) . . ?
C101 C100 H100 119.9 . . ?
C100 C101 H101 119.9 . . ?
C102 C101 C100 120.1(5) . . ?
C102 C101 H101 119.9 . . ?
C97 C102 H102 119.8 . . ?
C101 C102 C97 120.4(5) . . ?
C101 C102 H102 119.8 . . ?
H10C C103 H10D 109.5 . . ?
H10C C103 H10E 109.5 . . ?
H10D C103 H10E 109.5 . . ?
O4 C103 H10C 109.5 . . ?
O4 C103 H10D 109.5 . . ?
O4 C103 H10E 109.5 . . ?
H10F C104 H10G 109.5 . . ?
H10F C104 H10H 109.5 . . ?
H10G C104 H10H 109.5 . . ?
O5 C104 H10F 109.5 . . ?
O5 C104 H10G 109.5 . . ?
O5 C104 H10H 109.5 . . ?
H10I C105 H10J 109.5 . . ?
H10I C105 H10K 109.5 . . ?
H10J C105 H10K 109.5 . . ?
O6 C105 H10I 109.5 . . ?
O6 C105 H10J 109.5 . . ?
O6 C105 H10K 109.5 . . ?
H10L C106 H10M 109.5 . . ?
H10L C106 H10N 109.5 . . ?
H10M C106 H10N 109.5 . . ?
O7 C106 H10L 109.5 . . ?
O7 C106 H10M 109.5 . . ?
O7 C106 H10N 109.5 . . ?
C103 O4 H4 109.5 . . ?
C104 O5 H5A 109.5 . . ?
C105 O6 H6 109.5 . . ?
C106 O7 H7 109.5 . . ?
H1WA O1W H1WB 104.5 . . ?
H2WA O2W H2WB 104.5 . . ?
O2 N1 O1 113.4(11) . . ?
O3 N1 O1 114.6(11) . . ?
O3 N1 O2 126.8(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag3 P2 C49 C50 -37.8(4) . . . . ?
Ag3 P2 C49 C54 141.7(3) . . . . ?
Ag3 P2 C55 C56 141.6(3) . . . . ?
Ag3 P2 C55 C60 -36.3(4) . . . . ?
Ag3 P2 C61 C62 -37.8(4) . . . . ?
Ag3 P2 C61 C66 142.0(4) . . . . ?
Ag4 P1 C31 C32 -66.9(4) . . . . ?
Ag4 P1 C31 C36 111.8(4) . . . . ?
Ag4 P1 C37 C38 149.0(3) . . . . ?
Ag4 P1 C37 C42 -30.9(4) . . . . ?
Ag4 P1 C43 C44 -28.1(4) . . . . ?
Ag4 P1 C43 C48 152.6(3) . . . . ?
Ag5 P3 C67 C68 39.0(4) . . . . ?
Ag5 P3 C67 C72 -143.1(3) . . . . ?
Ag5 P3 C73 C74 -155.6(3) . . . . ?
Ag5 P3 C73 C78 27.2(4) . . . . ?
Ag5 P3 C79 C80 50.7(4) . . . . ?
Ag5 P3 C79 C84 -125.7(4) . . . . ?
Ag5 P4 C85 C86 -42.2(4) . . . . ?
Ag5 P4 C85 C90 139.4(4) . . . . ?
Ag5 P4 C91 C92 151.8(4) . . . . ?
Ag5 P4 C91 C96 -26.5(4) . . . . ?
Ag5 P4 C97 C98 -24.6(5) . . . . ?
Ag5 P4 C97 C102 155.6(4) . . . . ?
P1 C31 C32 C33 179.0(4) . . . . ?
P1 C31 C36 C35 -179.8(4) . . . . ?
P1 C37 C38 C39 178.4(4) . . . . ?
P1 C37 C42 C41 -178.8(4) . . . . ?
P1 C43 C44 C45 -177.8(4) . . . . ?
P1 C43 C48 C47 179.5(4) . . . . ?
P2 C49 C50 C51 -178.9(4) . . . . ?
P2 C49 C54 C53 -179.6(4) . . . . ?
P2 C55 C56 C57 -178.1(4) . . . . ?
P2 C55 C60 C59 179.5(4) . . . . ?
P2 C61 C62 C63 179.6(4) . . . . ?
P2 C61 C66 C65 -178.8(4) . . . . ?
P3 C67 C68 C69 177.2(4) . . . . ?
P3 C67 C72 C71 -178.0(3) . . . . ?
P3 C73 C74 C75 -177.6(4) . . . . ?
P3 C73 C78 C77 178.1(4) . . . . ?
P3 C79 C80 C81 -176.6(4) . . . . ?
P3 C79 C84 C83 175.4(4) . . . . ?
P4 C85 C86 C87 -177.9(4) . . . . ?
P4 C85 C90 C89 177.9(4) . . . . ?
P4 C91 C92 C93 -179.3(4) . . . . ?
P4 C91 C96 C95 179.2(4) . . . . ?
P4 C97 C98 C99 -177.6(4) . . . . ?
P4 C97 C102 C101 177.7(4) . . . . ?
C4 C5 C6 C7 180.0(5) . . . . ?
C4 C5 C10 C9 179.9(5) . . . . ?
C5 C6 C7 C8 56.6(8) . . . . ?
C6 C5 C10 C9 55.9(7) . . . . ?
C6 C7 C8 C9 -56.7(9) . . . . ?
C7 C8 C9 C10 57.3(9) . . . . ?
C8 C9 C10 C5 -56.0(8) . . . . ?
C10 C5 C6 C7 -56.3(7) . . . . ?
C14 C15 C16 C17 177.7(5) . . . . ?
C14 C15 C20 C19 -178.7(5) . . . . ?
C15 C16 C17 C18 56.2(7) . . . . ?
C16 C15 C20 C19 55.9(7) . . . . ?
C16 C17 C18 C19 -54.3(8) . . . . ?
C17 C18 C19 C20 53.2(9) . . . . ?
C18 C19 C20 C15 -53.5(8) . . . . ?
C20 C15 C16 C17 -57.3(6) . . . . ?
C24 C25 C26 C27 179.2(5) . . . . ?
C24 C25 C30 C29 -179.5(5) . . . . ?
C25 C26 C27 C28 -53.7(7) . . . . ?
C26 C25 C30 C29 -54.2(6) . . . . ?
C26 C27 C28 C29 56.6(8) . . . . ?
C27 C28 C29 C30 -57.5(8) . . . . ?
C28 C29 C30 C25 56.3(7) . . . . ?
C30 C25 C26 C27 53.1(7) . . . . ?
C31 P1 C37 C38 -88.0(4) . . . . ?
C31 P1 C37 C42 92.1(4) . . . . ?
C31 P1 C43 C44 -156.2(4) . . . . ?
C31 P1 C43 C48 24.5(4) . . . . ?
C31 C32 C33 C34 0.4(8) . . . . ?
C32 C31 C36 C35 -1.1(7) . . . . ?
C32 C33 C34 C35 -0.1(9) . . . . ?
C33 C34 C35 C36 -0.8(9) . . . . ?
C34 C35 C36 C31 1.4(8) . . . . ?
C36 C31 C32 C33 0.2(7) . . . . ?
C37 P1 C31 C32 172.8(4) . . . . ?
C37 P1 C31 C36 -8.5(4) . . . . ?
C37 P1 C43 C44 95.8(4) . . . . ?
C37 P1 C43 C48 -83.6(4) . . . . ?
C37 C38 C39 C40 0.9(7) . . . . ?
C38 C37 C42 C41 1.3(8) . . . . ?
C38 C39 C40 C41 0.3(8) . . . . ?
C39 C40 C41 C42 -0.7(9) . . . . ?
C40 C41 C42 C37 -0.1(9) . . . . ?
C42 C37 C38 C39 -1.7(7) . . . . ?
C43 P1 C31 C32 64.1(4) . . . . ?
C43 P1 C31 C36 -117.2(4) . . . . ?
C43 P1 C37 C38 19.6(4) . . . . ?
C43 P1 C37 C42 -160.3(4) . . . . ?
C43 C44 C45 C46 -2.2(8) . . . . ?
C44 C43 C48 C47 0.2(7) . . . . ?
C44 C45 C46 C47 1.1(8) . . . . ?
C45 C46 C47 C48 0.7(8) . . . . ?
C46 C47 C48 C43 -1.3(8) . . . . ?
C48 C43 C44 C45 1.6(7) . . . . ?
C49 P2 C55 C56 -91.0(4) . . . . ?
C49 P2 C55 C60 91.1(4) . . . . ?
C49 P2 C61 C62 -163.8(4) . . . . ?
C49 P2 C61 C66 16.0(4) . . . . ?
C49 C50 C51 C52 -2.5(8) . . . . ?
C50 C49 C54 C53 -0.1(7) . . . . ?
C50 C51 C52 C53 1.9(9) . . . . ?
C51 C52 C53 C54 -0.4(8) . . . . ?
C52 C53 C54 C49 -0.5(7) . . . . ?
C54 C49 C50 C51 1.6(7) . . . . ?
C55 P2 C49 C50 -164.9(4) . . . . ?
C55 P2 C49 C54 14.6(4) . . . . ?
C55 P2 C61 C62 88.0(4) . . . . ?
C55 P2 C61 C66 -92.3(4) . . . . ?
C55 C56 C57 C58 -0.4(7) . . . . ?
C56 C55 C60 C59 1.6(7) . . . . ?
C56 C57 C58 C59 -0.3(8) . . . . ?
C57 C58 C59 C60 1.7(9) . . . . ?
C58 C59 C60 C55 -2.3(8) . . . . ?
C60 C55 C56 C57 -0.3(7) . . . . ?
C61 P2 C49 C50 87.1(4) . . . . ?
C61 P2 C49 C54 -93.4(4) . . . . ?
C61 P2 C55 C56 16.6(4) . . . . ?
C61 P2 C55 C60 -161.3(4) . . . . ?
C61 C62 C63 C64 -0.8(8) . . . . ?
C62 C61 C66 C65 1.0(7) . . . . ?
C62 C63 C64 C65 1.0(8) . . . . ?
C63 C64 C65 C66 -0.3(8) . . . . ?
C64 C65 C66 C61 -0.7(8) . . . . ?
C66 C61 C62 C63 -0.2(7) . . . . ?
C67 P3 C73 C74 73.2(4) . . . . ?
C67 P3 C73 C78 -104.1(3) . . . . ?
C67 P3 C79 C80 176.7(4) . . . . ?
C67 P3 C79 C84 0.2(4) . . . . ?
C67 C68 C69 C70 1.9(8) . . . . ?
C68 C67 C72 C71 -0.1(6) . . . . ?
C68 C69 C70 C71 -2.1(8) . . . . ?
C69 C70 C71 C72 1.1(7) . . . . ?
C70 C71 C72 C67 -0.1(7) . . . . ?
C72 C67 C68 C69 -0.8(7) . . . . ?
C73 P3 C67 C68 169.7(4) . . . . ?
C73 P3 C67 C72 -12.4(4) . . . . ?
C73 P3 C79 C80 -74.8(4) . . . . ?
C73 P3 C79 C84 108.8(4) . . . . ?
C73 C74 C75 C76 -0.4(8) . . . . ?
C74 C73 C78 C77 0.7(6) . . . . ?
C74 C75 C76 C77 0.8(8) . . . . ?
C75 C76 C77 C78 -0.4(8) . . . . ?
C76 C77 C78 C73 -0.3(7) . . . . ?
C78 C73 C74 C75 -0.4(7) . . . . ?
C79 P3 C67 C68 -82.0(4) . . . . ?
C79 P3 C67 C72 95.9(4) . . . . ?
C79 P3 C73 C74 -34.3(4) . . . . ?
C79 P3 C73 C78 148.4(3) . . . . ?
C79 C80 C81 C82 0.9(8) . . . . ?
C80 C79 C84 C83 -1.1(7) . . . . ?
C80 C81 C82 C83 -0.9(8) . . . . ?
C81 C82 C83 C84 -0.1(8) . . . . ?
C82 C83 C84 C79 1.1(7) . . . . ?
C84 C79 C80 C81 0.1(7) . . . . ?
C85 P4 C91 C92 -86.9(4) . . . . ?
C85 P4 C91 C96 94.8(4) . . . . ?
C85 P4 C97 C98 -150.6(4) . . . . ?
C85 P4 C97 C102 29.6(5) . . . . ?
C85 C86 C87 C88 -0.2(7) . . . . ?
C86 C85 C90 C89 -0.5(7) . . . . ?
C86 C87 C88 C89 -0.5(8) . . . . ?
C87 C88 C89 C90 0.6(8) . . . . ?
C88 C89 C90 C85 -0.1(8) . . . . ?
C90 C85 C86 C87 0.6(7) . . . . ?
C91 P4 C85 C86 -162.5(4) . . . . ?
C91 P4 C85 C90 19.0(4) . . . . ?
C91 P4 C97 C98 100.7(4) . . . . ?
C91 P4 C97 C102 -79.0(4) . . . . ?
C91 C92 C93 C94 0.0(8) . . . . ?
C92 C91 C96 C95 0.8(7) . . . . ?
C92 C93 C94 C95 1.3(8) . . . . ?
C93 C94 C95 C96 -1.5(8) . . . . ?
C94 C95 C96 C91 0.5(8) . . . . ?
C96 C91 C92 C93 -1.0(7) . . . . ?
C97 P4 C85 C86 89.7(4) . . . . ?
C97 P4 C85 C90 -88.8(4) . . . . ?
C97 P4 C91 C92 19.9(5) . . . . ?
C97 P4 C91 C96 -158.4(4) . . . . ?
C97 C98 C99 C100 -1.3(8) . . . . ?
C98 C97 C102 C101 -2.0(8) . . . . ?
C98 C99 C100 C101 0.2(8) . . . . ?
C99 C100 C101 C102 -0.1(9) . . . . ?
C100 C101 C102 C97 1.0(8) . . . . ?
C102 C97 C98 C99 2.1(7) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.134 0.466 0.303 17.0 4.5 ?
2 0.134 0.534 0.803 17.0 4.5 ?
3 0.366 0.034 0.697 17.0 4.5 ?
4 0.366 0.966 0.197 17.0 4.5 ?
5 0.634 0.034 0.803 17.0 4.5 ?
6 0.634 0.966 0.303 17.0 4.5 ?
7 0.866 0.466 0.197 17.0 4.5 ?
8 0.866 0.534 0.697 17.0 4.5 ?


_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1557617'
_audit_update_record             
;
2017-09-25 deposited with the CCDC.
2017-09-29 downloaded from the CCDC.
;
_audit_creation_date             2017-09-25
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C186 H148 Ag8 P8, 2(N O3), 2(O)'
_chemical_formula_sum            'C187 H153 Ag8 N2 O8 P8'
_chemical_formula_weight         3666.82
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   35.354(4)
_cell_length_b                   30.585(3)
_cell_length_c                   18.7881(19)
_cell_angle_alpha                90
_cell_angle_beta                 111.840(2)
_cell_angle_gamma                90
_cell_volume                     18858(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9386
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.76
_cell_measurement_theta_min      2.48
_shelx_estimated_absorpt_T_max   0.768
_shelx_estimated_absorpt_T_min   0.653
_exptl_absorpt_coefficient_mu    0.931
_exptl_absorpt_correction_T_max  0.7675
_exptl_absorpt_correction_T_min  0.6531
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.292
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             7396
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1054
_diffrn_reflns_av_unetI/netI     0.0519
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       42
_diffrn_reflns_limit_h_min       -42
_diffrn_reflns_limit_k_max       36
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            175586
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.249
_diffrn_reflns_theta_min         1.241
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                13013
_reflns_number_total             17015
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_refine_diff_density_max         1.693
_refine_diff_density_min         -0.675
_refine_diff_density_rms         0.139
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     943
_refine_ls_number_reflns         17015
_refine_ls_number_restraints     21
_refine_ls_R_factor_all          0.0732
_refine_ls_R_factor_gt           0.0525
_refine_ls_restrained_S_all      1.098
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0823P)²+68.4620P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1363
_refine_ls_wR_factor_ref         0.1595
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N1-O1 = N1-O2 = N1-O3
 1.4 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(C19) \\sim Ueq, Uanis(C19') \\sim Ueq, Uanis(C20) \\sim Ueq, : with sigma
of 0.01 and sigma for terminal atoms of 0.02
4. Others
 Fixed Sof: C19(0.6) C19'(0.4) C21(0.5) O4(0.5) O1W(0.5) C21'(0.5)
5.a Ternary CH refined with riding coordinates:
 C5(H5), C12(H12)
5.b Me refined with riding coordinates:
 C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C13(H13A,H13B,H13C), C14(H14A,H14B,H14C)
5.c Aromatic/amide H refined with riding coordinates:
 C23(H23), C24(H24), C25(H25), C26(H26), C27(H27), C29(H29), C30(H30),
 C31(H31), C32(H32), C33(H33), C35(H35), C36(H36), C37(H37), C38(H38), C39(H39),
  C41(H41), C42(H42), C43(H43), C44(H44), C45(H45), C47(H47), C48(H48),
 C49(H49), C50(H50), C51(H51), C53(H53), C54(H54), C55(H55), C56(H56), C57(H57),
  C59(H59), C60(H60), C61(H61), C62(H62), C63(H63), C65(H65), C66(H66),
 C67(H67), C68(H68), C69(H69), C71(H71), C72(H72), C73(H73), C74(H74), C75(H75),
  C77(H77), C78(H78), C79(H79), C80(H80), C81(H81), C83(H83), C84(H84),
 C85(H85), C86(H86), C87(H87), C89(H89), C90(H90), C91(H91), C92(H92), C93(H93)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.5000 0.80550(2) 0.7500 0.03466(14) Uani 1 2 d S T P . .
Ag2 Ag 0.49095(2) 0.71555(2) 0.82530(2) 0.03416(11) Uani 1 1 d . . . . .
Ag3 Ag 0.57472(2) 0.74527(2) 0.82617(2) 0.03528(11) Uani 1 1 d . . . . .
Ag4 Ag 0.48056(2) 0.80747(2) 0.92951(2) 0.03709(12) Uani 1 1 d . . . . .
Ag5 Ag 0.5000 0.61415(2) 0.7500 0.03601(14) Uani 1 2 d S T P . .
P1 P 0.64902(4) 0.74621(4) 0.89949(8) 0.0341(3) Uani 1 1 d . . . . .
P2 P 0.49089(4) 0.88885(4) 0.95086(7) 0.0356(3) Uani 1 1 d . . . . .
P3 P 0.45823(5) 0.76658(5) 1.02302(8) 0.0417(3) Uani 1 1 d . . . . .
P4 P 0.49903(5) 0.56827(5) 0.85952(8) 0.0408(3) Uani 1 1 d . . . . .
C1 C 0.53339(16) 0.75424(17) 0.9091(3) 0.0353(11) Uani 1 1 d . . . . .
C2 C 0.55798(16) 0.77895(17) 0.9536(3) 0.0348(11) Uani 1 1 d . . . . .
C3 C 0.58660(18) 0.80665(18) 1.0043(3) 0.0430(13) Uani 1 1 d . . . . .
C4 C 0.6108(2) 0.8312(2) 1.0464(4) 0.0592(17) Uani 1 1 d . . . . .
C5 C 0.6418(3) 0.8607(3) 1.0972(5) 0.095(3) Uani 1 1 d . . . . .
H5 H 0.6682 0.8462 1.1030 0.114 Uiso 1 1 calc R . . . .
C6 C 0.6440(3) 0.9029(3) 1.0634(6) 0.112(4) Uani 1 1 d . . . . .
H6A H 0.6653 0.9207 1.1007 0.169 Uiso 1 1 calc R . . . .
H6B H 0.6505 0.8987 1.0175 0.169 Uiso 1 1 calc R . . . .
H6C H 0.6177 0.9179 1.0493 0.169 Uiso 1 1 calc R . . . .
C7 C 0.6411(3) 0.8593(3) 1.1774(5) 0.104(3) Uani 1 1 d . . . . .
H7A H 0.6395 0.8289 1.1923 0.157 Uiso 1 1 calc R . . . .
H7B H 0.6659 0.8729 1.2135 0.157 Uiso 1 1 calc R . . . .
H7C H 0.6172 0.8754 1.1781 0.157 Uiso 1 1 calc R . . . .
C8 C 0.44845(16) 0.67550(17) 0.7436(3) 0.0371(12) Uani 1 1 d . . . . .
C9 C 0.42563(15) 0.65279(16) 0.6929(3) 0.0352(11) Uani 1 1 d . . . . .
C10 C 0.39807(19) 0.62651(18) 0.6367(3) 0.0465(13) Uani 1 1 d . . . . .
C11 C 0.3754(2) 0.6032(2) 0.5885(4) 0.0619(17) Uani 1 1 d . . . . .
C12 C 0.3498(3) 0.5722(3) 0.5308(5) 0.087(3) Uani 1 1 d . . . . .
H12 H 0.3690 0.5521 0.5191 0.104 Uiso 1 1 calc R . . . .
C13 C 0.3256(3) 0.5927(3) 0.4591(5) 0.091(3) Uani 1 1 d . . . . .
H13A H 0.3093 0.5704 0.4232 0.136 Uiso 1 1 calc R . . . .
H13B H 0.3074 0.6144 0.4680 0.136 Uiso 1 1 calc R . . . .
H13C H 0.3436 0.6071 0.4373 0.136 Uiso 1 1 calc R . . . .
C14 C 0.3258(3) 0.5435(3) 0.5676(5) 0.104(3) Uani 1 1 d . . . . .
H14A H 0.3447 0.5311 0.6158 0.156 Uiso 1 1 calc R . . . .
H14B H 0.3054 0.5615 0.5779 0.156 Uiso 1 1 calc R . . . .
H14C H 0.3120 0.5198 0.5324 0.156 Uiso 1 1 calc R . . . .
C15 C 0.44698(16) 0.80407(16) 0.7749(3) 0.0352(11) Uani 1 1 d . . . . .
C16 C 0.41756(16) 0.80103(17) 0.7933(3) 0.0362(11) Uani 1 1 d . . . . .
C17 C 0.38312(19) 0.7990(2) 0.8109(3) 0.0482(14) Uani 1 1 d . . . . .
C18 C 0.3540(2) 0.7960(2) 0.8282(5) 0.0686(19) Uani 1 1 d . . . . .
C19 C 0.3238(4) 0.7954(5) 0.8671(10) 0.074(4) Uani 0.6 1 d . U . . .
C19' C 0.3086(7) 0.7928(8) 0.8206(14) 0.075(6) Uani 0.4 1 d . U . . .
C20 C 0.2992(3) 0.8388(4) 0.8483(6) 0.104(3) Uani 1 1 d . U . . .
C21 C 0.2949(5) 0.7543(5) 0.8307(11) 0.072(4) Uiso 0.5 1 d . U . . .
C22 C 0.67324(15) 0.79686(17) 0.8882(3) 0.0350(11) Uani 1 1 d . . . . .
C23 C 0.65429(18) 0.83641(19) 0.8897(3) 0.0467(13) Uani 1 1 d . . . . .
H23 H 0.6291 0.8364 0.8968 0.056 Uiso 1 1 calc R . . . .
C24 C 0.6712(2) 0.8753(2) 0.8812(4) 0.0585(16) Uani 1 1 d . . . . .
H24 H 0.6578 0.9021 0.8824 0.070 Uiso 1 1 calc R . . . .
C25 C 0.7083(2) 0.8754(2) 0.8708(4) 0.0596(17) Uani 1 1 d . . . . .
H25 H 0.7205 0.9023 0.8663 0.072 Uiso 1 1 calc R . . . .
C26 C 0.72702(19) 0.8369(2) 0.8670(3) 0.0548(16) Uani 1 1 d . . . . .
H26 H 0.7517 0.8370 0.8580 0.066 Uiso 1 1 calc R . . . .
C27 C 0.70969(17) 0.79773(19) 0.8764(3) 0.0448(13) Uani 1 1 d . . . . .
H27 H 0.7230 0.7710 0.8747 0.054 Uiso 1 1 calc R . . . .
C28 C 0.67773(16) 0.70337(18) 0.8748(3) 0.0379(12) Uani 1 1 d . . . . .
C29 C 0.66683(18) 0.6914(2) 0.7979(3) 0.0498(14) Uani 1 1 d . . . . .
H29 H 0.6445 0.7053 0.7595 0.060 Uiso 1 1 calc R . . . .
C30 C 0.6885(2) 0.6593(2) 0.7775(4) 0.0646(18) Uani 1 1 d . . . . .
H30 H 0.6814 0.6521 0.7249 0.078 Uiso 1 1 calc R . . . .
C31 C 0.7201(2) 0.6376(2) 0.8324(4) 0.0609(17) Uani 1 1 d . . . . .
H31 H 0.7347 0.6155 0.8179 0.073 Uiso 1 1 calc R . . . .
C32 C 0.73031(19) 0.6481(2) 0.9088(4) 0.0559(16) Uani 1 1 d . . . . .
H32 H 0.7515 0.6327 0.9472 0.067 Uiso 1 1 calc R . . . .
C33 C 0.70947(16) 0.68131(18) 0.9292(3) 0.0413(12) Uani 1 1 d . . . . .
H33 H 0.7172 0.6890 0.9817 0.050 Uiso 1 1 calc R . . . .
C34 C 0.66416(16) 0.74083(17) 1.0034(3) 0.0363(11) Uani 1 1 d . . . . .
C35 C 0.69471(16) 0.76617(19) 1.0548(3) 0.0402(12) Uani 1 1 d . . . . .
H35 H 0.7087 0.7870 1.0362 0.048 Uiso 1 1 calc R . . . .
C36 C 0.70488(18) 0.7612(2) 1.1329(3) 0.0465(13) Uani 1 1 d . . . . .
H36 H 0.7259 0.7786 1.1677 0.056 Uiso 1 1 calc R . . . .
C37 C 0.68497(19) 0.7313(2) 1.1604(3) 0.0536(15) Uani 1 1 d . . . . .
H37 H 0.6922 0.7280 1.2141 0.064 Uiso 1 1 calc R . . . .
C38 C 0.6544(2) 0.7061(2) 1.1099(4) 0.0575(16) Uani 1 1 d . . . . .
H38 H 0.6406 0.6854 1.1291 0.069 Uiso 1 1 calc R . . . .
C39 C 0.64352(18) 0.71072(19) 1.0315(3) 0.0461(13) Uani 1 1 d . . . . .
H39 H 0.6222 0.6935 0.9971 0.055 Uiso 1 1 calc R . . . .
C40 C 0.44206(18) 0.91748(17) 0.9252(3) 0.0408(12) Uani 1 1 d . . . . .
C41 C 0.4130(2) 0.9098(2) 0.8532(4) 0.0533(15) Uani 1 1 d . . . . .
H41 H 0.4190 0.8913 0.8182 0.064 Uiso 1 1 calc R . . . .
C42 C 0.3748(2) 0.9294(2) 0.8319(4) 0.069(2) Uani 1 1 d . . . . .
H42 H 0.3550 0.9242 0.7821 0.083 Uiso 1 1 calc R . . . .
C43 C 0.3652(2) 0.9559(2) 0.8817(5) 0.070(2) Uani 1 1 d . . . . .
H43 H 0.3390 0.9688 0.8670 0.084 Uiso 1 1 calc R . . . .
C44 C 0.3942(2) 0.9635(2) 0.9528(4) 0.0623(18) Uani 1 1 d . . . . .
H44 H 0.3878 0.9817 0.9877 0.075 Uiso 1 1 calc R . . . .
C45 C 0.43233(19) 0.94516(18) 0.9748(4) 0.0482(14) Uani 1 1 d . . . . .
H45 H 0.4522 0.9514 1.0241 0.058 Uiso 1 1 calc R . . . .
C46 C 0.51867(17) 0.90709(18) 1.0491(3) 0.0403(12) Uani 1 1 d . . . . .
C47 C 0.54587(18) 0.94197(17) 1.0682(3) 0.0430(13) Uani 1 1 d . . . . .
H47 H 0.5517 0.9570 1.0292 0.052 Uiso 1 1 calc R . . . .
C48 C 0.5647(2) 0.95486(19) 1.1445(4) 0.0553(16) Uani 1 1 d . . . . .
H48 H 0.5836 0.9784 1.1571 0.066 Uiso 1 1 calc R . . . .
C49 C 0.5564(2) 0.9343(2) 1.2011(3) 0.0577(17) Uani 1 1 d . . . . .
H49 H 0.5692 0.9434 1.2529 0.069 Uiso 1 1 calc R . . . .
C50 C 0.5294(2) 0.9003(2) 1.1826(4) 0.0619(18) Uani 1 1 d . . . . .
H50 H 0.5233 0.8862 1.2221 0.074 Uiso 1 1 calc R . . . .
C51 C 0.5108(2) 0.8859(2) 1.1085(3) 0.0525(15) Uani 1 1 d . . . . .
H51 H 0.4926 0.8617 1.0974 0.063 Uiso 1 1 calc R . . . .
C52 C 0.51646(17) 0.91658(16) 0.8959(3) 0.0364(11) Uani 1 1 d . . . . .
C53 C 0.54126(17) 0.89227(18) 0.8685(3) 0.0399(12) Uani 1 1 d . . . . .
H53 H 0.5438 0.8616 0.8772 0.048 Uiso 1 1 calc R . . . .
C54 C 0.56225(19) 0.9122(2) 0.8287(3) 0.0477(14) Uani 1 1 d . . . . .
H54 H 0.5792 0.8952 0.8102 0.057 Uiso 1 1 calc R . . . .
C55 C 0.5589(2) 0.9566(2) 0.8155(4) 0.0587(17) Uani 1 1 d . . . . .
H55 H 0.5738 0.9704 0.7888 0.070 Uiso 1 1 calc R . . . .
C56 C 0.5339(2) 0.9808(2) 0.8411(4) 0.0559(16) Uani 1 1 d . . . . .
H56 H 0.5311 1.0113 0.8310 0.067 Uiso 1 1 calc R . . . .
C57 C 0.5127(2) 0.96145(18) 0.8812(3) 0.0471(14) Uani 1 1 d . . . . .
H57 H 0.4955 0.9786 0.8987 0.057 Uiso 1 1 calc R . . . .
C58 C 0.50163(19) 0.7434(2) 1.1015(3) 0.0479(14) Uani 1 1 d . . . . .
C59 C 0.53906(19) 0.7639(2) 1.1204(3) 0.0505(15) Uani 1 1 d . . . . .
H59 H 0.5412 0.7892 1.0927 0.061 Uiso 1 1 calc R . . . .
C60 C 0.5738(2) 0.7480(2) 1.1793(4) 0.0602(17) Uani 1 1 d . . . . .
H60 H 0.5993 0.7624 1.1923 0.072 Uiso 1 1 calc R . . . .
C61 C 0.5701(2) 0.7106(2) 1.2187(4) 0.0640(19) Uani 1 1 d . . . . .
H61 H 0.5932 0.6993 1.2591 0.077 Uiso 1 1 calc R . . . .
C62 C 0.5331(2) 0.6900(2) 1.1992(4) 0.0639(19) Uani 1 1 d . . . . .
H62 H 0.5310 0.6645 1.2264 0.077 Uiso 1 1 calc R . . . .
C63 C 0.4988(2) 0.7054(2) 1.1408(4) 0.0569(16) Uani 1 1 d . . . . .
H63 H 0.4736 0.6904 1.1274 0.068 Uiso 1 1 calc R . . . .
C64 C 0.42174(18) 0.72160(18) 0.9913(3) 0.0429(13) Uani 1 1 d . . . . .
C65 C 0.42255(18) 0.69560(18) 0.9313(3) 0.0453(13) Uani 1 1 d . . . . .
H65 H 0.4408 0.7022 0.9064 0.054 Uiso 1 1 calc R . . . .
C66 C 0.3969(2) 0.66029(19) 0.9079(4) 0.0517(15) Uani 1 1 d . . . . .
H66 H 0.3976 0.6427 0.8668 0.062 Uiso 1 1 calc R . . . .
C67 C 0.3704(2) 0.6501(2) 0.9430(4) 0.0621(17) Uani 1 1 d . . . . .
H67 H 0.3531 0.6253 0.9269 0.075 Uiso 1 1 calc R . . . .
C68 C 0.3690(2) 0.6758(3) 1.0013(5) 0.078(2) Uani 1 1 d . . . . .
H68 H 0.3500 0.6695 1.0246 0.094 Uiso 1 1 calc R . . . .
C69 C 0.3952(2) 0.7110(2) 1.0266(4) 0.069(2) Uani 1 1 d . . . . .
H69 H 0.3948 0.7280 1.0687 0.083 Uiso 1 1 calc R . . . .
C70 C 0.43395(18) 0.80263(18) 1.0707(3) 0.0433(13) Uani 1 1 d . . . . .
C71 C 0.4397(2) 0.7991(2) 1.1478(3) 0.0564(16) Uani 1 1 d . . . . .
H71 H 0.4578 0.7778 1.1795 0.068 Uiso 1 1 calc R . . . .
C72 C 0.4186(3) 0.8273(2) 1.1779(4) 0.072(2) Uani 1 1 d . . . . .
H72 H 0.4226 0.8251 1.2306 0.087 Uiso 1 1 calc R . . . .
C73 C 0.3924(3) 0.8579(2) 1.1338(4) 0.073(2) Uani 1 1 d . . . . .
H73 H 0.3781 0.8764 1.1558 0.088 Uiso 1 1 calc R . . . .
C74 C 0.3864(2) 0.8622(2) 1.0572(4) 0.0641(18) Uani 1 1 d . . . . .
H74 H 0.3683 0.8837 1.0263 0.077 Uiso 1 1 calc R . . . .
C75 C 0.40755(19) 0.8345(2) 1.0261(4) 0.0506(15) Uani 1 1 d . . . . .
H75 H 0.4039 0.8373 0.9736 0.061 Uiso 1 1 calc R . . . .
C76 C 0.51747(18) 0.51251(18) 0.8570(3) 0.0422(13) Uani 1 1 d . . . . .
C77 C 0.4949(2) 0.47563(18) 0.8553(3) 0.0514(15) Uani 1 1 d . . . . .
H77 H 0.4682 0.4786 0.8553 0.062 Uiso 1 1 calc R . . . .
C78 C 0.5104(2) 0.4346(2) 0.8536(4) 0.0631(18) Uani 1 1 d . . . . .
H78 H 0.4942 0.4095 0.8516 0.076 Uiso 1 1 calc R . . . .
C79 C 0.5494(3) 0.4299(2) 0.8549(4) 0.069(2) Uani 1 1 d . . . . .
H79 H 0.5604 0.4015 0.8556 0.082 Uiso 1 1 calc R . . . .
C80 C 0.5724(2) 0.4664(2) 0.8551(4) 0.0621(18) Uani 1 1 d . . . . .
H80 H 0.5990 0.4633 0.8545 0.074 Uiso 1 1 calc R . . . .
C81 C 0.5563(2) 0.5078(2) 0.8561(4) 0.0551(16) Uani 1 1 d . . . . .
H81 H 0.5720 0.5330 0.8562 0.066 Uiso 1 1 calc R . . . .
C82 C 0.44851(18) 0.56009(17) 0.8630(3) 0.0429(13) Uani 1 1 d . . . . .
C83 C 0.4152(2) 0.5589(2) 0.7948(4) 0.0546(15) Uani 1 1 d . . . . .
H83 H 0.4187 0.5644 0.7479 0.065 Uiso 1 1 calc R . . . .
C84 C 0.3767(2) 0.5499(2) 0.7944(4) 0.0652(18) Uani 1 1 d . . . . .
H84 H 0.3541 0.5478 0.7471 0.078 Uiso 1 1 calc R . . . .
C85 C 0.3711(2) 0.5438(2) 0.8629(4) 0.0630(18) Uani 1 1 d . . . . .
H85 H 0.3447 0.5380 0.8627 0.076 Uiso 1 1 calc R . . . .
C86 C 0.4038(2) 0.5462(2) 0.9306(4) 0.0579(17) Uani 1 1 d . . . . .
H86 H 0.3998 0.5425 0.9776 0.069 Uiso 1 1 calc R . . . .
C87 C 0.4425(2) 0.5541(2) 0.9316(4) 0.0522(15) Uani 1 1 d . . . . .
H87 H 0.4650 0.5554 0.9790 0.063 Uiso 1 1 calc R . . . .
C88 C 0.53009(17) 0.58739(17) 0.9545(3) 0.0388(12) Uani 1 1 d . . . . .
C89 C 0.55405(18) 0.55951(19) 1.0132(3) 0.0466(14) Uani 1 1 d . . . . .
H89 H 0.5543 0.5290 1.0040 0.056 Uiso 1 1 calc R . . . .
C90 C 0.5773(2) 0.5762(2) 1.0844(3) 0.0525(15) Uani 1 1 d . . . . .
H90 H 0.5936 0.5572 1.1239 0.063 Uiso 1 1 calc R . . . .
C91 C 0.5771(2) 0.6205(2) 1.0984(3) 0.0511(15) Uani 1 1 d . . . . .
H91 H 0.5929 0.6316 1.1477 0.061 Uiso 1 1 calc R . . . .
C92 C 0.5543(2) 0.6485(2) 1.0424(4) 0.0527(15) Uani 1 1 d . . . . .
H92 H 0.5546 0.6790 1.0522 0.063 Uiso 1 1 calc R . . . .
C93 C 0.5304(2) 0.63169(19) 0.9698(3) 0.0502(15) Uani 1 1 d . . . . .
H93 H 0.5143 0.6510 0.9307 0.060 Uiso 1 1 calc R . . . .
N1 N 0.3092(13) 0.7185(8) 1.122(2) 0.401(17) Uiso 1 1 d D U . . .
O1 O 0.3187(7) 0.7637(9) 1.1309(14) 0.357(11) Uiso 1 1 d D U . . .
O2 O 0.3209(8) 0.6783(9) 1.1618(14) 0.361(11) Uiso 1 1 d D U . . .
O3 O 0.2768(14) 0.7154(13) 1.049(2) 0.57(3) Uiso 1 1 d D U . . .
O4 O 0.2992(7) 0.5596(7) 0.9475(13) 0.182(8) Uiso 0.5 1 d . . . . .
O1W O 0.2504(10) 0.5370(11) 0.7707(19) 0.258(13) Uiso 0.5 1 d . . . . .
C21' C 0.3114(8) 0.7558(8) 0.8812(16) 0.117(7) Uiso 0.5 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.1639(6) . ?
Ag1 Ag2 3.1638(6) 2_656 ?
Ag1 Ag3 3.0996(5) . ?
Ag1 Ag3 3.0997(5) 2_656 ?
Ag1 C15 2.095(5) . ?
Ag1 C15 2.095(5) 2_656 ?
Ag2 Ag2 3.1248(8) 2_656 ?
Ag2 Ag3 3.0659(6) 2_656 ?
Ag2 Ag3 3.0925(6) . ?
Ag2 C1 2.091(5) . ?
Ag2 C8 2.097(6) . ?
Ag3 Ag2 3.0659(6) 2_656 ?
Ag3 P1 2.4711(14) . ?
Ag3 C1 2.516(5) . ?
Ag3 C8 2.479(5) 2_656 ?
Ag3 C15 2.519(5) 2_656 ?
Ag4 P2 2.5263(14) . ?
Ag4 P3 2.5109(14) . ?
Ag4 C1 2.611(5) . ?
Ag4 C15 2.700(5) . ?
Ag4 C16 2.704(5) . ?
Ag5 P4 2.5013(14) . ?
Ag5 P4 2.5013(14) 2_656 ?
Ag5 C8 2.587(5) . ?
Ag5 C8 2.587(5) 2_656 ?
P1 C22 1.821(5) . ?
P1 C28 1.820(5) . ?
P1 C34 1.830(5) . ?
P2 C40 1.833(6) . ?
P2 C46 1.825(5) . ?
P2 C52 1.816(5) . ?
P3 C58 1.831(7) . ?
P3 C64 1.828(6) . ?
P3 C70 1.824(6) . ?
P4 C76 1.833(6) . ?
P4 C82 1.828(6) . ?
P4 C88 1.809(6) . ?
C1 C2 1.219(7) . ?
C2 C3 1.390(8) . ?
C3 C4 1.190(8) . ?
C4 C5 1.466(10) . ?
C5 H5 1.0000 . ?
C5 C6 1.455(13) . ?
C5 C7 1.516(13) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 Ag3 2.479(5) 2_656 ?
C8 C9 1.212(7) . ?
C9 C10 1.394(8) . ?
C10 C11 1.197(8) . ?
C11 C12 1.470(10) . ?
C12 H12 1.0000 . ?
C12 C13 1.442(11) . ?
C12 C14 1.552(12) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 Ag3 2.519(5) 2_656 ?
C15 C16 1.215(7) . ?
C16 C17 1.377(8) . ?
C17 C18 1.193(9) . ?
C18 C19 1.502(15) . ?
C18 C19' 1.56(2) . ?
C19 C19' 0.84(2) . ?
C19 C20 1.553(18) . ?
C19 C21 1.60(2) . ?
C19 C21' 1.35(3) . ?
C19' C20 1.58(2) . ?
C19' C21 1.31(3) . ?
C19' C21' 1.58(3) . ?
C21 C21' 0.91(3) . ?
C22 C23 1.388(8) . ?
C22 C27 1.387(8) . ?
C23 H23 0.9500 . ?
C23 C24 1.367(8) . ?
C24 H24 0.9500 . ?
C24 C25 1.397(9) . ?
C25 H25 0.9500 . ?
C25 C26 1.365(9) . ?
C26 H26 0.9500 . ?
C26 C27 1.386(8) . ?
C27 H27 0.9500 . ?
C28 C29 1.398(8) . ?
C28 C33 1.381(8) . ?
C29 H29 0.9500 . ?
C29 C30 1.384(8) . ?
C30 H30 0.9500 . ?
C30 C31 1.376(10) . ?
C31 H31 0.9500 . ?
C31 C32 1.382(9) . ?
C32 H32 0.9500 . ?
C32 C33 1.389(8) . ?
C33 H33 0.9500 . ?
C34 C35 1.386(8) . ?
C34 C39 1.394(8) . ?
C35 H35 0.9500 . ?
C35 C36 1.384(8) . ?
C36 H36 0.9500 . ?
C36 C37 1.366(9) . ?
C37 H37 0.9500 . ?
C37 C38 1.379(9) . ?
C38 H38 0.9500 . ?
C38 C39 1.384(8) . ?
C39 H39 0.9500 . ?
C40 C41 1.382(8) . ?
C40 C45 1.394(8) . ?
C41 H41 0.9500 . ?
C41 C42 1.391(9) . ?
C42 H42 0.9500 . ?
C42 C43 1.372(10) . ?
C43 H43 0.9500 . ?
C43 C44 1.367(10) . ?
C44 H44 0.9500 . ?
C44 C45 1.374(9) . ?
C45 H45 0.9500 . ?
C46 C47 1.391(8) . ?
C46 C51 1.405(8) . ?
C47 H47 0.9500 . ?
C47 C48 1.395(8) . ?
C48 H48 0.9500 . ?
C48 C49 1.358(9) . ?
C49 H49 0.9500 . ?
C49 C50 1.366(10) . ?
C50 H50 0.9500 . ?
C50 C51 1.372(9) . ?
C51 H51 0.9500 . ?
C52 C53 1.387(7) . ?
C52 C57 1.397(7) . ?
C53 H53 0.9500 . ?
C53 C54 1.375(8) . ?
C54 H54 0.9500 . ?
C54 C55 1.380(9) . ?
C55 H55 0.9500 . ?
C55 C56 1.369(9) . ?
C56 H56 0.9500 . ?
C56 C57 1.379(8) . ?
C57 H57 0.9500 . ?
C58 C59 1.386(9) . ?
C58 C63 1.399(8) . ?
C59 H59 0.9500 . ?
C59 C60 1.399(9) . ?
C60 H60 0.9500 . ?
C60 C61 1.395(10) . ?
C61 H61 0.9500 . ?
C61 C62 1.375(11) . ?
C62 H62 0.9500 . ?
C62 C63 1.380(10) . ?
C63 H63 0.9500 . ?
C64 C65 1.388(8) . ?
C64 C69 1.375(8) . ?
C65 H65 0.9500 . ?
C65 C66 1.373(8) . ?
C66 H66 0.9500 . ?
C66 C67 1.368(9) . ?
C67 H67 0.9500 . ?
C67 C68 1.364(10) . ?
C68 H68 0.9500 . ?
C68 C69 1.384(10) . ?
C69 H69 0.9500 . ?
C70 C71 1.391(8) . ?
C70 C75 1.393(9) . ?
C71 H71 0.9500 . ?
C71 C72 1.389(9) . ?
C72 H72 0.9500 . ?
C72 C73 1.361(11) . ?
C73 H73 0.9500 . ?
C73 C74 1.381(10) . ?
C74 H74 0.9500 . ?
C74 C75 1.395(9) . ?
C75 H75 0.9500 . ?
C76 C77 1.375(8) . ?
C76 C81 1.386(9) . ?
C77 H77 0.9500 . ?
C77 C78 1.374(9) . ?
C78 H78 0.9500 . ?
C78 C79 1.378(11) . ?
C79 H79 0.9500 . ?
C79 C80 1.381(10) . ?
C80 H80 0.9500 . ?
C80 C81 1.389(9) . ?
C81 H81 0.9500 . ?
C82 C83 1.380(9) . ?
C82 C87 1.394(8) . ?
C83 H83 0.9500 . ?
C83 C84 1.387(10) . ?
C84 H84 0.9500 . ?
C84 C85 1.385(10) . ?
C85 H85 0.9500 . ?
C85 C86 1.366(10) . ?
C86 H86 0.9500 . ?
C86 C87 1.385(9) . ?
C87 H87 0.9500 . ?
C88 C89 1.402(8) . ?
C88 C93 1.384(8) . ?
C89 H89 0.9500 . ?
C89 C90 1.382(8) . ?
C90 H90 0.9500 . ?
C90 C91 1.379(8) . ?
C91 H91 0.9500 . ?
C91 C92 1.363(9) . ?
C92 H92 0.9500 . ?
C92 C93 1.407(9) . ?
C93 H93 0.9500 . ?
N1 O1 1.420(10) . ?
N1 O2 1.417(10) . ?
N1 O3 1.422(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag2 59.186(18) 2_656 . ?
Ag3 Ag1 Ag2 58.603(13) 2_656 . ?
Ag3 Ag1 Ag2 58.604(13) . 2_656 ?
Ag3 Ag1 Ag2 59.162(14) 2_656 2_656 ?
Ag3 Ag1 Ag2 59.162(14) . . ?
Ag3 Ag1 Ag3 107.07(2) . 2_656 ?
C15 Ag1 Ag2 109.24(13) . 2_656 ?
C15 Ag1 Ag2 68.54(14) . . ?
C15 Ag1 Ag2 68.54(14) 2_656 2_656 ?
C15 Ag1 Ag2 109.24(13) 2_656 . ?
C15 Ag1 Ag3 53.90(13) . 2_656 ?
C15 Ag1 Ag3 124.36(14) . . ?
C15 Ag1 Ag3 53.90(13) 2_656 . ?
C15 Ag1 Ag3 124.35(14) 2_656 2_656 ?
C15 Ag1 C15 177.6(3) 2_656 . ?
Ag2 Ag2 Ag1 60.406(9) 2_656 . ?
Ag3 Ag2 Ag1 59.652(11) 2_656 . ?
Ag3 Ag2 Ag1 59.383(10) . . ?
Ag3 Ag2 Ag2 59.089(13) . 2_656 ?
Ag3 Ag2 Ag2 59.929(15) 2_656 2_656 ?
Ag3 Ag2 Ag3 108.107(16) 2_656 . ?
C1 Ag2 Ag1 71.39(14) . . ?
C1 Ag2 Ag2 110.50(13) . 2_656 ?
C1 Ag2 Ag3 53.98(13) . . ?
C1 Ag2 Ag3 127.92(14) . 2_656 ?
C1 Ag2 C8 178.44(19) . . ?
C8 Ag2 Ag1 110.16(13) . . ?
C8 Ag2 Ag2 70.69(14) . 2_656 ?
C8 Ag2 Ag3 53.47(14) . 2_656 ?
C8 Ag2 Ag3 126.82(14) . . ?
Ag2 Ag3 Ag1 61.744(13) 2_656 . ?
Ag2 Ag3 Ag1 61.455(13) . . ?
Ag2 Ag3 Ag2 60.981(15) 2_656 . ?
P1 Ag3 Ag1 142.86(4) . . ?
P1 Ag3 Ag2 143.30(4) . 2_656 ?
P1 Ag3 Ag2 145.46(4) . . ?
P1 Ag3 C1 113.29(12) . . ?
P1 Ag3 C8 112.24(13) . 2_656 ?
P1 Ag3 C15 111.99(12) . 2_656 ?
C1 Ag3 Ag1 68.25(11) . . ?
C1 Ag3 Ag2 101.15(12) . 2_656 ?
C1 Ag3 Ag2 42.23(12) . . ?
C1 Ag3 C15 107.74(17) . 2_656 ?
C8 Ag3 Ag1 102.14(13) 2_656 . ?
C8 Ag3 Ag2 67.46(12) 2_656 . ?
C8 Ag3 Ag2 42.84(13) 2_656 2_656 ?
C8 Ag3 C1 105.50(17) 2_656 . ?
C8 Ag3 C15 105.54(17) 2_656 2_656 ?
C15 Ag3 Ag1 42.22(12) 2_656 . ?
C15 Ag3 Ag2 100.57(12) 2_656 . ?
C15 Ag3 Ag2 66.34(12) 2_656 2_656 ?
P2 Ag4 C1 124.65(12) . . ?
P2 Ag4 C15 100.86(11) . . ?
P2 Ag4 C16 103.98(12) . . ?
P3 Ag4 P2 116.36(5) . . ?
P3 Ag4 C1 102.75(12) . . ?
P3 Ag4 C15 127.34(12) . . ?
P3 Ag4 C16 105.27(12) . . ?
C1 Ag4 C15 82.54(15) . . ?
C1 Ag4 C16 101.41(16) . . ?
C15 Ag4 C16 25.99(15) . . ?
P4 Ag5 P4 111.75(7) . 2_656 ?
P4 Ag5 C8 102.72(11) . . ?
P4 Ag5 C8 102.72(11) 2_656 2_656 ?
P4 Ag5 C8 126.41(12) 2_656 . ?
P4 Ag5 C8 126.41(13) . 2_656 ?
C8 Ag5 C8 87.0(2) . 2_656 ?
C22 P1 Ag3 113.16(17) . . ?
C22 P1 C34 103.7(2) . . ?
C28 P1 Ag3 115.31(18) . . ?
C28 P1 C22 104.6(2) . . ?
C28 P1 C34 103.8(2) . . ?
C34 P1 Ag3 114.97(17) . . ?
C40 P2 Ag4 111.26(18) . . ?
C46 P2 Ag4 116.95(18) . . ?
C46 P2 C40 102.7(2) . . ?
C52 P2 Ag4 116.30(16) . . ?
C52 P2 C40 104.3(2) . . ?
C52 P2 C46 103.7(2) . . ?
C58 P3 Ag4 111.7(2) . . ?
C64 P3 Ag4 120.93(18) . . ?
C64 P3 C58 104.4(3) . . ?
C70 P3 Ag4 111.74(19) . . ?
C70 P3 C58 104.2(3) . . ?
C70 P3 C64 102.2(3) . . ?
C76 P4 Ag5 112.76(17) . . ?
C82 P4 Ag5 114.74(18) . . ?
C82 P4 C76 103.6(3) . . ?
C88 P4 Ag5 116.15(17) . . ?
C88 P4 C76 103.6(2) . . ?
C88 P4 C82 104.6(2) . . ?
Ag2 C1 Ag3 83.79(17) . . ?
Ag2 C1 Ag4 96.39(19) . . ?
Ag3 C1 Ag4 140.4(2) . . ?
C2 C1 Ag2 175.1(4) . . ?
C2 C1 Ag3 93.5(4) . . ?
C2 C1 Ag4 83.1(3) . . ?
C1 C2 C3 179.0(6) . . ?
C4 C3 C2 178.4(7) . . ?
C3 C4 C5 177.8(8) . . ?
C4 C5 H5 103.9 . . ?
C4 C5 C7 110.2(8) . . ?
C6 C5 C4 114.3(7) . . ?
C6 C5 H5 103.9 . . ?
C6 C5 C7 118.7(8) . . ?
C7 C5 H5 103.9 . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C5 C7 H7A 109.5 . . ?
C5 C7 H7B 109.5 . . ?
C5 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Ag2 C8 Ag3 83.69(18) . 2_656 ?
Ag2 C8 Ag5 95.12(19) . . ?
Ag3 C8 Ag5 137.5(2) 2_656 . ?
C9 C8 Ag2 175.0(4) . . ?
C9 C8 Ag3 94.9(4) . 2_656 ?
C9 C8 Ag5 82.7(3) . . ?
C8 C9 C10 177.0(6) . . ?
C11 C10 C9 178.0(7) . . ?
C10 C11 C12 175.9(8) . . ?
C11 C12 H12 106.1 . . ?
C11 C12 C14 108.9(7) . . ?
C13 C12 C11 113.4(7) . . ?
C13 C12 H12 106.1 . . ?
C13 C12 C14 115.4(8) . . ?
C14 C12 H12 106.1 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Ag1 C15 Ag3 83.88(16) . 2_656 ?
Ag1 C15 Ag4 99.65(19) . . ?
Ag3 C15 Ag4 136.6(2) 2_656 . ?
C16 C15 Ag1 175.4(5) . . ?
C16 C15 Ag3 96.1(4) . 2_656 ?
C16 C15 Ag4 77.2(3) . . ?
C15 C16 Ag4 76.9(3) . . ?
C15 C16 C17 177.0(6) . . ?
C17 C16 Ag4 105.5(4) . . ?
C18 C17 C16 177.6(8) . . ?
C17 C18 C19 167.3(10) . . ?
C17 C18 C19' 160.4(11) . . ?
C19 C18 C19' 31.9(8) . . ?
C18 C19 C20 108.5(11) . . ?
C18 C19 C21 104.9(11) . . ?
C19' C19 C18 78(2) . . ?
C19' C19 C20 76(2) . . ?
C19' C19 C21 55(2) . . ?
C19' C19 C21' 89(2) . . ?
C20 C19 C21 111.0(12) . . ?
C21' C19 C18 116.6(15) . . ?
C21' C19 C20 128.2(15) . . ?
C21' C19 C21 34.6(12) . . ?
C18 C19' C20 104.3(15) . . ?
C18 C19' C21' 101.0(17) . . ?
C19 C19' C18 70(2) . . ?
C19 C19' C20 73(2) . . ?
C19 C19' C21 94(2) . . ?
C19 C19' C21' 58(2) . . ?
C20 C19' C21' 111.4(17) . . ?
C21 C19' C18 117.7(18) . . ?
C21 C19' C20 128.1(17) . . ?
C21 C19' C21' 35.2(12) . . ?
C19 C20 C19' 31.2(8) . . ?
C19' C21 C19 31.7(11) . . ?
C21' C21 C19 57(2) . . ?
C21' C21 C19' 89(2) . . ?
C23 C22 P1 119.2(4) . . ?
C27 C22 P1 122.7(4) . . ?
C27 C22 C23 118.1(5) . . ?
C22 C23 H23 119.3 . . ?
C24 C23 C22 121.4(6) . . ?
C24 C23 H23 119.3 . . ?
C23 C24 H24 120.3 . . ?
C23 C24 C25 119.4(6) . . ?
C25 C24 H24 120.3 . . ?
C24 C25 H25 119.8 . . ?
C26 C25 C24 120.4(6) . . ?
C26 C25 H25 119.8 . . ?
C25 C26 H26 120.3 . . ?
C25 C26 C27 119.4(6) . . ?
C27 C26 H26 120.3 . . ?
C22 C27 H27 119.4 . . ?
C26 C27 C22 121.2(6) . . ?
C26 C27 H27 119.4 . . ?
C29 C28 P1 119.1(4) . . ?
C33 C28 P1 122.7(4) . . ?
C33 C28 C29 118.2(5) . . ?
C28 C29 H29 119.9 . . ?
C30 C29 C28 120.3(6) . . ?
C30 C29 H29 119.9 . . ?
C29 C30 H30 119.6 . . ?
C31 C30 C29 120.9(6) . . ?
C31 C30 H30 119.6 . . ?
C30 C31 H31 120.3 . . ?
C30 C31 C32 119.5(6) . . ?
C32 C31 H31 120.3 . . ?
C31 C32 H32 120.1 . . ?
C31 C32 C33 119.8(6) . . ?
C33 C32 H32 120.1 . . ?
C28 C33 C32 121.4(5) . . ?
C28 C33 H33 119.3 . . ?
C32 C33 H33 119.3 . . ?
C35 C34 P1 122.3(4) . . ?
C35 C34 C39 119.2(5) . . ?
C39 C34 P1 118.4(4) . . ?
C34 C35 H35 119.9 . . ?
C36 C35 C34 120.2(5) . . ?
C36 C35 H35 119.9 . . ?
C35 C36 H36 119.7 . . ?
C37 C36 C35 120.6(6) . . ?
C37 C36 H36 119.7 . . ?
C36 C37 H37 120.2 . . ?
C36 C37 C38 119.7(6) . . ?
C38 C37 H37 120.2 . . ?
C37 C38 H38 119.6 . . ?
C37 C38 C39 120.8(6) . . ?
C39 C38 H38 119.6 . . ?
C34 C39 H39 120.3 . . ?
C38 C39 C34 119.5(5) . . ?
C38 C39 H39 120.3 . . ?
C41 C40 P2 117.5(4) . . ?
C41 C40 C45 118.6(6) . . ?
C45 C40 P2 123.8(5) . . ?
C40 C41 H41 120.1 . . ?
C40 C41 C42 119.8(6) . . ?
C42 C41 H41 120.1 . . ?
C41 C42 H42 119.4 . . ?
C43 C42 C41 121.2(7) . . ?
C43 C42 H42 119.4 . . ?
C42 C43 H43 120.6 . . ?
C44 C43 C42 118.7(7) . . ?
C44 C43 H43 120.6 . . ?
C43 C44 H44 119.3 . . ?
C43 C44 C45 121.4(6) . . ?
C45 C44 H44 119.3 . . ?
C40 C45 H45 119.9 . . ?
C44 C45 C40 120.3(6) . . ?
C44 C45 H45 119.9 . . ?
C47 C46 P2 123.8(4) . . ?
C47 C46 C51 118.1(5) . . ?
C51 C46 P2 118.1(5) . . ?
C46 C47 H47 120.0 . . ?
C46 C47 C48 120.1(5) . . ?
C48 C47 H47 120.0 . . ?
C47 C48 H48 119.5 . . ?
C49 C48 C47 121.0(6) . . ?
C49 C48 H48 119.5 . . ?
C48 C49 H49 120.4 . . ?
C48 C49 C50 119.2(6) . . ?
C50 C49 H49 120.4 . . ?
C49 C50 H50 119.1 . . ?
C49 C50 C51 121.8(6) . . ?
C51 C50 H50 119.1 . . ?
C46 C51 H51 120.1 . . ?
C50 C51 C46 119.8(6) . . ?
C50 C51 H51 120.1 . . ?
C53 C52 P2 118.6(4) . . ?
C53 C52 C57 118.7(5) . . ?
C57 C52 P2 122.7(4) . . ?
C52 C53 H53 119.7 . . ?
C54 C53 C52 120.6(5) . . ?
C54 C53 H53 119.7 . . ?
C53 C54 H54 119.8 . . ?
C53 C54 C55 120.4(6) . . ?
C55 C54 H54 119.8 . . ?
C54 C55 H55 120.3 . . ?
C56 C55 C54 119.4(6) . . ?
C56 C55 H55 120.3 . . ?
C55 C56 H56 119.5 . . ?
C55 C56 C57 121.0(6) . . ?
C57 C56 H56 119.5 . . ?
C52 C57 H57 120.1 . . ?
C56 C57 C52 119.8(5) . . ?
C56 C57 H57 120.1 . . ?
C59 C58 P3 117.7(5) . . ?
C59 C58 C63 119.3(6) . . ?
C63 C58 P3 123.0(5) . . ?
C58 C59 H59 119.4 . . ?
C58 C59 C60 121.2(6) . . ?
C60 C59 H59 119.4 . . ?
C59 C60 H60 120.7 . . ?
C61 C60 C59 118.5(7) . . ?
C61 C60 H60 120.7 . . ?
C60 C61 H61 119.9 . . ?
C62 C61 C60 120.1(7) . . ?
C62 C61 H61 119.9 . . ?
C61 C62 H62 119.3 . . ?
C61 C62 C63 121.5(7) . . ?
C63 C62 H62 119.3 . . ?
C58 C63 H63 120.4 . . ?
C62 C63 C58 119.3(7) . . ?
C62 C63 H63 120.4 . . ?
C65 C64 P3 118.1(4) . . ?
C69 C64 P3 123.1(5) . . ?
C69 C64 C65 118.7(6) . . ?
C64 C65 H65 120.0 . . ?
C66 C65 C64 120.0(5) . . ?
C66 C65 H65 120.0 . . ?
C65 C66 H66 119.5 . . ?
C67 C66 C65 121.0(6) . . ?
C67 C66 H66 119.5 . . ?
C66 C67 H67 120.3 . . ?
C68 C67 C66 119.4(6) . . ?
C68 C67 H67 120.3 . . ?
C67 C68 H68 119.8 . . ?
C67 C68 C69 120.4(6) . . ?
C69 C68 H68 119.8 . . ?
C64 C69 C68 120.4(6) . . ?
C64 C69 H69 119.8 . . ?
C68 C69 H69 119.8 . . ?
C71 C70 P3 123.5(5) . . ?
C71 C70 C75 119.1(5) . . ?
C75 C70 P3 117.4(4) . . ?
C70 C71 H71 120.6 . . ?
C72 C71 C70 118.9(6) . . ?
C72 C71 H71 120.6 . . ?
C71 C72 H72 119.1 . . ?
C73 C72 C71 121.8(6) . . ?
C73 C72 H72 119.1 . . ?
C72 C73 H73 119.8 . . ?
C72 C73 C74 120.3(7) . . ?
C74 C73 H73 119.8 . . ?
C73 C74 H74 120.6 . . ?
C73 C74 C75 118.7(7) . . ?
C75 C74 H74 120.6 . . ?
C70 C75 C74 121.1(6) . . ?
C70 C75 H75 119.4 . . ?
C74 C75 H75 119.4 . . ?
C77 C76 P4 123.7(5) . . ?
C77 C76 C81 118.8(6) . . ?
C81 C76 P4 117.5(4) . . ?
C76 C77 H77 119.4 . . ?
C78 C77 C76 121.2(7) . . ?
C78 C77 H77 119.4 . . ?
C77 C78 H78 120.1 . . ?
C77 C78 C79 119.9(7) . . ?
C79 C78 H78 120.1 . . ?
C78 C79 H79 120.0 . . ?
C78 C79 C80 120.0(6) . . ?
C80 C79 H79 120.0 . . ?
C79 C80 H80 120.3 . . ?
C79 C80 C81 119.5(7) . . ?
C81 C80 H80 120.3 . . ?
C76 C81 C80 120.5(6) . . ?
C76 C81 H81 119.7 . . ?
C80 C81 H81 119.7 . . ?
C83 C82 P4 118.5(4) . . ?
C83 C82 C87 118.9(6) . . ?
C87 C82 P4 122.5(5) . . ?
C82 C83 H83 119.8 . . ?
C82 C83 C84 120.5(6) . . ?
C84 C83 H83 119.8 . . ?
C83 C84 H84 120.0 . . ?
C85 C84 C83 120.0(7) . . ?
C85 C84 H84 120.0 . . ?
C84 C85 H85 120.2 . . ?
C86 C85 C84 119.7(6) . . ?
C86 C85 H85 120.2 . . ?
C85 C86 H86 119.6 . . ?
C85 C86 C87 120.7(6) . . ?
C87 C86 H86 119.6 . . ?
C82 C87 H87 120.0 . . ?
C86 C87 C82 120.1(6) . . ?
C86 C87 H87 120.0 . . ?
C89 C88 P4 123.1(4) . . ?
C93 C88 P4 118.5(4) . . ?
C93 C88 C89 118.4(5) . . ?
C88 C89 H89 119.9 . . ?
C90 C89 C88 120.3(5) . . ?
C90 C89 H89 119.9 . . ?
C89 C90 H90 119.9 . . ?
C91 C90 C89 120.3(6) . . ?
C91 C90 H90 119.9 . . ?
C90 C91 H91 119.6 . . ?
C92 C91 C90 120.9(6) . . ?
C92 C91 H91 119.6 . . ?
C91 C92 H92 120.4 . . ?
C91 C92 C93 119.2(6) . . ?
C93 C92 H92 120.4 . . ?
C88 C93 C92 121.0(5) . . ?
C88 C93 H93 119.5 . . ?
C92 C93 H93 119.5 . . ?
O1 N1 O3 104(3) . . ?
O2 N1 O1 141(4) . . ?
O2 N1 O3 115(3) . . ?
C19 C21' C19' 32.2(11) . . ?
C21 C21' C19 88(2) . . ?
C21 C21' C19' 56(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag3 P1 C22 C23 42.6(5) . . . . ?
Ag3 P1 C22 C27 -136.0(4) . . . . ?
Ag3 P1 C28 C29 38.9(5) . . . . ?
Ag3 P1 C28 C33 -139.5(4) . . . . ?
Ag3 P1 C34 C35 -137.0(4) . . . . ?
Ag3 P1 C34 C39 41.7(5) . . . . ?
Ag3 C15 C16 Ag4 136.52(19) 2_656 . . . ?
Ag4 P2 C40 C41 -52.7(5) . . . . ?
Ag4 P2 C40 C45 125.1(5) . . . . ?
Ag4 P2 C46 C47 142.8(4) . . . . ?
Ag4 P2 C46 C51 -40.1(5) . . . . ?
Ag4 P2 C52 C53 -22.9(5) . . . . ?
Ag4 P2 C52 C57 158.1(4) . . . . ?
Ag4 P3 C58 C59 26.4(5) . . . . ?
Ag4 P3 C58 C63 -151.3(4) . . . . ?
Ag4 P3 C64 C65 33.4(6) . . . . ?
Ag4 P3 C64 C69 -150.2(5) . . . . ?
Ag4 P3 C70 C71 -140.9(5) . . . . ?
Ag4 P3 C70 C75 40.8(5) . . . . ?
Ag5 P4 C76 C77 -122.5(5) . . . . ?
Ag5 P4 C76 C81 57.0(5) . . . . ?
Ag5 P4 C82 C83 31.5(5) . . . . ?
Ag5 P4 C82 C87 -150.0(4) . . . . ?
Ag5 P4 C88 C89 -138.0(4) . . . . ?
Ag5 P4 C88 C93 41.6(5) . . . . ?
P1 C22 C23 C24 -179.8(5) . . . . ?
P1 C22 C27 C26 179.2(4) . . . . ?
P1 C28 C29 C30 179.3(5) . . . . ?
P1 C28 C33 C32 178.6(5) . . . . ?
P1 C34 C35 C36 179.5(4) . . . . ?
P1 C34 C39 C38 -179.9(5) . . . . ?
P2 C40 C41 C42 177.4(5) . . . . ?
P2 C40 C45 C44 -176.3(5) . . . . ?
P2 C46 C47 C48 177.5(4) . . . . ?
P2 C46 C51 C50 -176.4(5) . . . . ?
P2 C52 C53 C54 -177.9(4) . . . . ?
P2 C52 C57 C56 178.0(5) . . . . ?
P3 C58 C59 C60 -179.6(5) . . . . ?
P3 C58 C63 C62 179.7(5) . . . . ?
P3 C64 C65 C66 177.1(5) . . . . ?
P3 C64 C69 C68 -178.2(7) . . . . ?
P3 C70 C71 C72 -177.7(6) . . . . ?
P3 C70 C75 C74 177.4(5) . . . . ?
P4 C76 C77 C78 -179.9(5) . . . . ?
P4 C76 C81 C80 179.3(5) . . . . ?
P4 C82 C83 C84 175.6(5) . . . . ?
P4 C82 C87 C86 -177.3(5) . . . . ?
P4 C88 C89 C90 179.6(5) . . . . ?
P4 C88 C93 C92 -179.4(5) . . . . ?
C17 C18 C19 C19' 169(4) . . . . ?
C17 C18 C19 C20 98(4) . . . . ?
C17 C18 C19 C21 -143(4) . . . . ?
C17 C18 C19 C21' -108(4) . . . . ?
C17 C18 C19' C19 -173(3) . . . . ?
C17 C18 C19' C20 -108(3) . . . . ?
C17 C18 C19' C21 104(3) . . . . ?
C17 C18 C19' C21' 137(3) . . . . ?
C18 C19 C19' C20 -112.8(9) . . . . ?
C18 C19 C19' C21 118.2(15) . . . . ?
C18 C19 C19' C21' 117.4(14) . . . . ?
C18 C19 C20 C19' 72(2) . . . . ?
C18 C19 C21 C19' -63(2) . . . . ?
C18 C19 C21 C21' 115(2) . . . . ?
C18 C19 C21' C19' -76(2) . . . . ?
C18 C19 C21' C21 -77(3) . . . . ?
C18 C19' C20 C19 -63.5(19) . . . . ?
C18 C19' C21 C19 69(2) . . . . ?
C18 C19' C21 C21' 68(3) . . . . ?
C18 C19' C21' C19 58.3(19) . . . . ?
C18 C19' C21' C21 -123(2) . . . . ?
C19 C18 C19' C20 65(2) . . . . ?
C19 C18 C19' C21 -83(3) . . . . ?
C19 C18 C19' C21' -50.4(19) . . . . ?
C19 C19' C21 C21' -1(3) . . . . ?
C19 C19' C21' C21 179(3) . . . . ?
C19 C21 C21' C19' -0.8(18) . . . . ?
C19' C18 C19 C20 -71(2) . . . . ?
C19' C18 C19 C21 48(2) . . . . ?
C19' C18 C19 C21' 83(3) . . . . ?
C19' C19 C21 C21' 179(3) . . . . ?
C19' C19 C21' C21 -1(3) . . . . ?
C19' C21 C21' C19 0.8(18) . . . . ?
C20 C19 C19' C18 112.8(9) . . . . ?
C20 C19 C19' C21 -129.0(15) . . . . ?
C20 C19 C19' C21' -129.8(14) . . . . ?
C20 C19 C21 C19' 54(2) . . . . ?
C20 C19 C21 C21' -128(2) . . . . ?
C20 C19 C21' C19' 72(2) . . . . ?
C20 C19 C21' C21 70(3) . . . . ?
C20 C19' C21 C19 -71(2) . . . . ?
C20 C19' C21 C21' -72(3) . . . . ?
C20 C19' C21' C19 -52.0(19) . . . . ?
C20 C19' C21' C21 127(3) . . . . ?
C21 C19 C19' C18 -118.2(15) . . . . ?
C21 C19 C19' C20 129.0(15) . . . . ?
C21 C19 C19' C21' -0.8(19) . . . . ?
C21 C19 C20 C19' -42.9(19) . . . . ?
C21 C19 C21' C19' 1(3) . . . . ?
C21 C19' C20 C19 81(3) . . . . ?
C21 C19' C21' C19 -179(3) . . . . ?
C22 P1 C28 C29 -86.0(5) . . . . ?
C22 P1 C28 C33 95.5(5) . . . . ?
C22 P1 C34 C35 -12.9(5) . . . . ?
C22 P1 C34 C39 165.8(4) . . . . ?
C22 C23 C24 C25 0.0(10) . . . . ?
C23 C22 C27 C26 0.5(8) . . . . ?
C23 C24 C25 C26 1.8(10) . . . . ?
C24 C25 C26 C27 -2.4(10) . . . . ?
C25 C26 C27 C22 1.2(9) . . . . ?
C27 C22 C23 C24 -1.1(9) . . . . ?
C28 P1 C22 C23 168.8(4) . . . . ?
C28 P1 C22 C27 -9.8(5) . . . . ?
C28 P1 C34 C35 96.2(5) . . . . ?
C28 P1 C34 C39 -85.1(5) . . . . ?
C28 C29 C30 C31 2.2(11) . . . . ?
C29 C28 C33 C32 0.2(8) . . . . ?
C29 C30 C31 C32 -0.1(11) . . . . ?
C30 C31 C32 C33 -1.9(10) . . . . ?
C31 C32 C33 C28 1.9(9) . . . . ?
C33 C28 C29 C30 -2.2(9) . . . . ?
C34 P1 C22 C23 -82.7(5) . . . . ?
C34 P1 C22 C27 98.7(5) . . . . ?
C34 P1 C28 C29 165.6(5) . . . . ?
C34 P1 C28 C33 -12.9(5) . . . . ?
C34 C35 C36 C37 -0.1(9) . . . . ?
C35 C34 C39 C38 -1.2(9) . . . . ?
C35 C36 C37 C38 -0.2(10) . . . . ?
C36 C37 C38 C39 -0.1(10) . . . . ?
C37 C38 C39 C34 0.8(10) . . . . ?
C39 C34 C35 C36 0.8(8) . . . . ?
C40 P2 C46 C47 -95.1(5) . . . . ?
C40 P2 C46 C51 82.0(5) . . . . ?
C40 P2 C52 C53 -145.8(4) . . . . ?
C40 P2 C52 C57 35.2(5) . . . . ?
C40 C41 C42 C43 -0.7(11) . . . . ?
C41 C40 C45 C44 1.6(9) . . . . ?
C41 C42 C43 C44 0.8(12) . . . . ?
C42 C43 C44 C45 0.2(11) . . . . ?
C43 C44 C45 C40 -1.4(10) . . . . ?
C45 C40 C41 C42 -0.6(9) . . . . ?
C46 P2 C40 C41 -178.6(5) . . . . ?
C46 P2 C40 C45 -0.7(5) . . . . ?
C46 P2 C52 C53 107.0(4) . . . . ?
C46 P2 C52 C57 -72.0(5) . . . . ?
C46 C47 C48 C49 -1.1(9) . . . . ?
C47 C46 C51 C50 0.8(9) . . . . ?
C47 C48 C49 C50 0.5(10) . . . . ?
C48 C49 C50 C51 0.8(10) . . . . ?
C49 C50 C51 C46 -1.5(10) . . . . ?
C51 C46 C47 C48 0.4(8) . . . . ?
C52 P2 C40 C41 73.4(5) . . . . ?
C52 P2 C40 C45 -108.7(5) . . . . ?
C52 P2 C46 C47 13.3(5) . . . . ?
C52 P2 C46 C51 -169.6(5) . . . . ?
C52 C53 C54 C55 -0.1(9) . . . . ?
C53 C52 C57 C56 -1.0(9) . . . . ?
C53 C54 C55 C56 -1.2(10) . . . . ?
C54 C55 C56 C57 1.3(11) . . . . ?
C55 C56 C57 C52 -0.2(10) . . . . ?
C57 C52 C53 C54 1.2(8) . . . . ?
C58 P3 C64 C65 -93.4(5) . . . . ?
C58 P3 C64 C69 83.0(6) . . . . ?
C58 P3 C70 C71 -20.1(6) . . . . ?
C58 P3 C70 C75 161.5(5) . . . . ?
C58 C59 C60 C61 0.6(9) . . . . ?
C59 C58 C63 C62 2.1(9) . . . . ?
C59 C60 C61 C62 0.3(9) . . . . ?
C60 C61 C62 C63 0.0(10) . . . . ?
C61 C62 C63 C58 -1.2(10) . . . . ?
C63 C58 C59 C60 -1.8(9) . . . . ?
C64 P3 C58 C59 158.7(5) . . . . ?
C64 P3 C58 C63 -19.0(6) . . . . ?
C64 P3 C70 C71 88.4(6) . . . . ?
C64 P3 C70 C75 -90.0(5) . . . . ?
C64 C65 C66 C67 -0.1(10) . . . . ?
C65 C64 C69 C68 -1.9(11) . . . . ?
C65 C66 C67 C68 1.0(11) . . . . ?
C66 C67 C68 C69 -2.3(13) . . . . ?
C67 C68 C69 C64 2.8(13) . . . . ?
C69 C64 C65 C66 0.6(9) . . . . ?
C70 P3 C58 C59 -94.4(5) . . . . ?
C70 P3 C58 C63 87.9(5) . . . . ?
C70 P3 C64 C65 158.3(5) . . . . ?
C70 P3 C64 C69 -25.3(7) . . . . ?
C70 C71 C72 C73 0.4(12) . . . . ?
C71 C70 C75 C74 -1.1(9) . . . . ?
C71 C72 C73 C74 -0.9(12) . . . . ?
C72 C73 C74 C75 0.5(11) . . . . ?
C73 C74 C75 C70 0.5(10) . . . . ?
C75 C70 C71 C72 0.6(9) . . . . ?
C76 P4 C82 C83 -91.9(5) . . . . ?
C76 P4 C82 C87 86.7(5) . . . . ?
C76 P4 C88 C89 -13.8(5) . . . . ?
C76 P4 C88 C93 165.8(5) . . . . ?
C76 C77 C78 C79 1.1(10) . . . . ?
C77 C76 C81 C80 -1.2(9) . . . . ?
C77 C78 C79 C80 -2.3(11) . . . . ?
C78 C79 C80 C81 1.7(11) . . . . ?
C79 C80 C81 C76 0.1(10) . . . . ?
C81 C76 C77 C78 0.7(9) . . . . ?
C82 P4 C76 C77 2.2(5) . . . . ?
C82 P4 C76 C81 -178.4(5) . . . . ?
C82 P4 C88 C89 94.5(5) . . . . ?
C82 P4 C88 C93 -85.9(5) . . . . ?
C82 C83 C84 C85 2.8(10) . . . . ?
C83 C82 C87 C86 1.3(9) . . . . ?
C83 C84 C85 C86 -0.8(11) . . . . ?
C84 C85 C86 C87 -0.9(10) . . . . ?
C85 C86 C87 C82 0.7(10) . . . . ?
C87 C82 C83 C84 -3.0(9) . . . . ?
C88 P4 C76 C77 111.1(5) . . . . ?
C88 P4 C76 C81 -69.4(5) . . . . ?
C88 P4 C82 C83 159.9(5) . . . . ?
C88 P4 C82 C87 -21.5(5) . . . . ?
C88 C89 C90 C91 0.2(9) . . . . ?
C89 C88 C93 C92 0.2(9) . . . . ?
C89 C90 C91 C92 -0.7(10) . . . . ?
C90 C91 C92 C93 0.9(9) . . . . ?
C91 C92 C93 C88 -0.7(9) . . . . ?
C93 C88 C89 C90 0.0(9) . . . . ?
C21' C19 C19' C18 -117.4(14) . . . . ?
C21' C19 C19' C20 129.8(13) . . . . ?
C21' C19 C19' C21 0.8(19) . . . . ?
C21' C19 C20 C19' -78(3) . . . . ?
C21' C19 C21 C19' -179(3) . . . . ?
C21' C19' C20 C19 44.7(18) . . . . ?
C21' C19' C21 C19 1(3) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.258 0.000 -0.408 833.9 245.2 ?
2 0.242 0.500 -0.422 833.9 244.5 ?
3 0.758 0.500 0.149 833.9 245.2 ?
4 0.742 0.000 -0.022 833.9 244.5 ?


_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_8
_database_code_depnum_ccdc_archive 'CCDC 1557619'
_audit_update_record             
;
2017-09-25 deposited with the CCDC.
2017-09-29 downloaded from the CCDC.
;
_audit_creation_date             2017-09-25
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         '2(C112 H80 Ag4 P4), 3(C2 H3 N)'
_chemical_formula_sum            'C230 H169 Ag8 N3 P8'
_chemical_formula_weight         4085.39
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   16.3046(11)
_cell_length_b                   34.222(2)
_cell_length_c                   17.6558(11)
_cell_angle_alpha                90
_cell_angle_beta                 102.0690(10)
_cell_angle_gamma                90
_cell_volume                     9633.8(11)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9835
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.943
_cell_measurement_theta_min      2.362
_shelx_estimated_absorpt_T_max   0.770
_shelx_estimated_absorpt_T_min   0.657
_exptl_absorpt_coefficient_mu    0.917
_exptl_absorpt_correction_T_max  0.6082
_exptl_absorpt_correction_T_min  0.5028
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2008/1 (Bruker,2008) was used for absorption correction. wR2(int) was 0.1556 before and 0.1362 after correction. The Ratio of minimum to maximum transmission is 0.8267. The λ/2 correction factor is 0.0015.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.408
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4132
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1147
_diffrn_reflns_av_unetI/netI     0.0519
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       41
_diffrn_reflns_limit_k_min       -41
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            173520
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.249
_diffrn_reflns_theta_min         1.321
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                14051
_reflns_number_total             17458
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.34A (Bruker, 200?)'
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        'SAINT v7.34A (Bruker, 200?)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_refine_diff_density_max         1.216
_refine_diff_density_min         -0.902
_refine_diff_density_rms         0.121
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1146
_refine_ls_number_reflns         17458
_refine_ls_number_restraints     14
_refine_ls_R_factor_all          0.0711
_refine_ls_R_factor_gt           0.0536
_refine_ls_restrained_S_all      1.128
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0733P)²+16.5707P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1347
_refine_ls_wR_factor_ref         0.1493
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C115-C116
 1.43 with sigma of 0.01
 C11-C12
 1.2 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(C11) \\sim Ueq, Uanis(C12) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
4. Others
 Fixed Sof: Ag4(0.9) Ag4'(0.1) C115(0.5) C116(0.5) H11D(0.5) H11E(0.5)
 H11F(0.5) N2(0.5)
5.a Aromatic/amide H refined with riding coordinates:
 C6(H6), C7(H7), C8(H8), C9(H9), C10(H10), C16(H16), C17(H17), C18(H18),
 C19(H19), C20(H20), C26(H26), C27(H27), C28(H28), C29(H29), C30(H30), C36(H36),
  C37(H37), C38(H38), C39(H39), C40(H40), C42(H42), C43(H43), C44(H44),
 C45(H45), C46(H46), C48(H48), C49(H49), C50(H50), C51(H51), C52(H52), C54(H54),
  C55(H55), C56(H56), C57(H57), C58(H58), C60(H60), C61(H61), C62(H62),
 C63(H63), C64(H64), C66(H66), C67(H67), C68(H68), C69(H69), C70(H70), C72(H72),
  C73(H73), C74(H74), C75(H75), C76(H76), C78(H78), C79(H79), C80(H80),
 C81(H81), C82(H82), C84(H84), C85(H85), C86(H86), C87(H87), C88(H88), C90(H90),
  C91(H91), C92(H92), C93(H93), C94(H94), C96(H96), C97(H97), C98(H98),
 C99(H99), C100(H100), C102(H102), C103(H103), C104(H104), C105(H105),
 C106(H106), C108(H108), C109(H109), C110(H110), C111(H111), C112(H112)
5.b Idealised Me refined as rotating group:
 C114(H11A,H11B,H11C), C116(H11D,H11E,H11F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.80054(2) 0.37171(2) 1.29280(2) 0.03269(11) Uani 1 1 d . . . . .
Ag2 Ag 0.82663(2) 0.39841(2) 1.13248(2) 0.03310(11) Uani 1 1 d . . . . .
Ag3 Ag 0.81927(2) 0.35394(2) 0.98724(2) 0.02960(10) Uani 1 1 d . . . . .
Ag4 Ag 0.78451(4) 0.31528(2) 1.12847(4) 0.04702(15) Uani 0.9 1 d . . P . .
Ag4' Ag 0.8296(5) 0.31576(16) 1.1673(4) 0.0602(15) Uani 0.1 1 d . . P . .
P1 P 0.69688(8) 0.32768(4) 1.33515(7) 0.0310(3) Uani 1 1 d . . . . .
P2 P 0.88758(8) 0.42052(4) 1.37850(7) 0.0293(3) Uani 1 1 d . . . . .
P3 P 0.74767(8) 0.40608(3) 0.89877(7) 0.0310(3) Uani 1 1 d . . . . .
P4 P 0.90916(8) 0.30348(3) 0.94282(7) 0.0275(3) Uani 1 1 d . . . . .
C1 C 0.7257(3) 0.41148(15) 1.1809(3) 0.0352(11) Uani 1 1 d . . . . .
C2 C 0.6622(3) 0.42275(14) 1.1983(3) 0.0333(11) Uani 1 1 d . . . . .
C3 C 0.5904(3) 0.43559(15) 1.2214(3) 0.0386(12) Uani 1 1 d . . . . .
C4 C 0.5307(3) 0.44742(16) 1.2436(3) 0.0436(13) Uani 1 1 d . . . . .
C5 C 0.4599(4) 0.46062(17) 1.2727(4) 0.0511(15) Uani 1 1 d . . . . .
C6 C 0.4713(5) 0.4823(2) 1.3381(4) 0.073(2) Uani 1 1 d . . . . .
H6 H 0.5262 0.4896 1.3642 0.088 Uiso 1 1 calc R . . . .
C7 C 0.4006(8) 0.4940(3) 1.3675(6) 0.108(4) Uani 1 1 d . . . . .
H7 H 0.4074 0.5100 1.4124 0.130 Uiso 1 1 calc R . . . .
C8 C 0.3214(7) 0.4818(4) 1.3298(7) 0.110(4) Uani 1 1 d . . . . .
H8 H 0.2738 0.4886 1.3502 0.132 Uiso 1 1 calc R . . . .
C9 C 0.3118(6) 0.4606(4) 1.2653(7) 0.111(4) Uani 1 1 d . . . . .
H9 H 0.2572 0.4525 1.2400 0.133 Uiso 1 1 calc R . . . .
C10 C 0.3795(4) 0.4503(2) 1.2349(5) 0.076(2) Uani 1 1 d . . . . .
H10 H 0.3712 0.4361 1.1878 0.091 Uiso 1 1 calc R . . . .
C11 C 0.8708(5) 0.31771(18) 1.2322(4) 0.0593(17) Uani 1 1 d D U . . .
C12 C 0.9325(4) 0.32111(17) 1.2826(4) 0.0500(15) Uani 1 1 d D U . . .
C13 C 1.0050(5) 0.32307(17) 1.3370(4) 0.0569(17) Uani 1 1 d . . . . .
C14 C 1.0704(5) 0.32509(19) 1.3833(4) 0.0583(16) Uani 1 1 d . . . . .
C15 C 1.1495(5) 0.3280(2) 1.4349(5) 0.076(2) Uani 1 1 d . . . . .
C16 C 1.1805(7) 0.2975(3) 1.4853(5) 0.103(3) Uani 1 1 d . . . . .
H16 H 1.1456 0.2757 1.4894 0.123 Uiso 1 1 calc R . . . .
C17 C 1.2592(10) 0.2984(4) 1.5284(7) 0.148(6) Uani 1 1 d . . . . .
H17 H 1.2816 0.2764 1.5585 0.178 Uiso 1 1 calc R . . . .
C18 C 1.3060(8) 0.3312(6) 1.5284(9) 0.157(7) Uani 1 1 d . . . . .
H18 H 1.3602 0.3324 1.5611 0.189 Uiso 1 1 calc R . . . .
C19 C 1.2760(8) 0.3635(5) 1.4809(10) 0.151(6) Uani 1 1 d . . . . .
H19 H 1.3089 0.3864 1.4812 0.181 Uiso 1 1 calc R . . . .
C20 C 1.1982(6) 0.3605(3) 1.4346(7) 0.106(3) Uani 1 1 d . . . . .
H20 H 1.1772 0.3816 1.4012 0.127 Uiso 1 1 calc R . . . .
C21 C 0.9301(3) 0.38863(13) 1.0858(3) 0.0323(11) Uani 1 1 d . . . . .
C22 C 1.0032(3) 0.38500(14) 1.0827(3) 0.0347(11) Uani 1 1 d . . . . .
C23 C 1.0866(3) 0.38054(15) 1.0820(3) 0.0387(12) Uani 1 1 d . . . . .
C24 C 1.1608(4) 0.37709(16) 1.0833(4) 0.0470(14) Uani 1 1 d . . . . .
C25 C 1.2483(3) 0.37453(16) 1.0821(4) 0.0481(14) Uani 1 1 d . . . . .
C26 C 1.3059(4) 0.36021(18) 1.1449(4) 0.0621(18) Uani 1 1 d . . . . .
H26 H 1.2874 0.3516 1.1897 0.075 Uiso 1 1 calc R . . . .
C27 C 1.3896(4) 0.3583(2) 1.1430(5) 0.078(2) Uani 1 1 d . . . . .
H27 H 1.4285 0.3485 1.1866 0.094 Uiso 1 1 calc R . . . .
C28 C 1.4176(4) 0.3705(2) 1.0791(6) 0.079(2) Uani 1 1 d . . . . .
H28 H 1.4756 0.3693 1.0786 0.094 Uiso 1 1 calc R . . . .
C29 C 1.3622(4) 0.3844(2) 1.0163(5) 0.073(2) Uani 1 1 d . . . . .
H29 H 1.3816 0.3926 0.9717 0.088 Uiso 1 1 calc R . . . .
C30 C 1.2770(4) 0.3868(2) 1.0174(4) 0.0608(17) Uani 1 1 d . . . . .
H30 H 1.2385 0.3968 0.9737 0.073 Uiso 1 1 calc R . . . .
C31 C 0.7041(5) 0.31630(18) 1.0237(4) 0.0581(17) Uani 1 1 d . . . . .
C32 C 0.6399(5) 0.31774(19) 0.9712(4) 0.0598(18) Uani 1 1 d . . . . .
C33 C 0.5671(5) 0.3190(2) 0.9169(4) 0.0611(18) Uani 1 1 d . . . . .
C34 C 0.5032(6) 0.3205(2) 0.8695(5) 0.069(2) Uani 1 1 d . . . . .
C35 C 0.4258(5) 0.3232(2) 0.8170(4) 0.0666(19) Uani 1 1 d . . . . .
C36 C 0.3833(6) 0.3583(2) 0.8023(5) 0.080(2) Uani 1 1 d . . . . .
H36 H 0.4068 0.3814 0.8277 0.096 Uiso 1 1 calc R . . . .
C37 C 0.3069(6) 0.3599(3) 0.7508(6) 0.090(3) Uani 1 1 d . . . . .
H37 H 0.2781 0.3841 0.7398 0.108 Uiso 1 1 calc R . . . .
C38 C 0.2735(6) 0.3261(3) 0.7160(6) 0.095(3) Uani 1 1 d . . . . .
H38 H 0.2205 0.3268 0.6812 0.114 Uiso 1 1 calc R . . . .
C39 C 0.3154(6) 0.2912(3) 0.7307(5) 0.088(2) Uani 1 1 d . . . . .
H39 H 0.2909 0.2680 0.7061 0.105 Uiso 1 1 calc R . . . .
C40 C 0.3910(5) 0.2894(2) 0.7796(4) 0.070(2) Uani 1 1 d . . . . .
H40 H 0.4202 0.2653 0.7885 0.083 Uiso 1 1 calc R . . . .
C41 C 0.6145(3) 0.35272(15) 1.3712(3) 0.0378(12) Uani 1 1 d . . . . .
C42 C 0.6377(4) 0.38527(17) 1.4175(4) 0.0528(15) Uani 1 1 d . . . . .
H42 H 0.6943 0.3940 1.4284 0.063 Uiso 1 1 calc R . . . .
C43 C 0.5771(5) 0.4052(2) 1.4481(4) 0.069(2) Uani 1 1 d . . . . .
H43 H 0.5922 0.4277 1.4794 0.083 Uiso 1 1 calc R . . . .
C44 C 0.4959(5) 0.3922(2) 1.4330(4) 0.071(2) Uani 1 1 d . . . . .
H44 H 0.4555 0.4055 1.4552 0.085 Uiso 1 1 calc R . . . .
C45 C 0.4718(4) 0.3606(2) 1.3868(4) 0.0603(18) Uani 1 1 d . . . . .
H45 H 0.4148 0.3526 1.3753 0.072 Uiso 1 1 calc R . . . .
C46 C 0.5320(4) 0.34018(18) 1.3563(3) 0.0469(14) Uani 1 1 d . . . . .
H46 H 0.5161 0.3176 1.3252 0.056 Uiso 1 1 calc R . . . .
C47 C 0.6386(3) 0.29508(14) 1.2612(3) 0.0311(10) Uani 1 1 d . . . . .
C48 C 0.6258(4) 0.25622(16) 1.2742(3) 0.0435(13) Uani 1 1 d . . . . .
H48 H 0.6486 0.2451 1.3234 0.052 Uiso 1 1 calc R . . . .
C49 C 0.5796(4) 0.23312(16) 1.2158(4) 0.0492(14) Uani 1 1 d . . . . .
H49 H 0.5708 0.2063 1.2255 0.059 Uiso 1 1 calc R . . . .
C50 C 0.5466(3) 0.24867(17) 1.1444(3) 0.0463(13) Uani 1 1 d . . . . .
H50 H 0.5153 0.2328 1.1045 0.056 Uiso 1 1 calc R . . . .
C51 C 0.5596(3) 0.28794(16) 1.1311(3) 0.0414(12) Uani 1 1 d . . . . .
H51 H 0.5364 0.2990 1.0820 0.050 Uiso 1 1 calc R . . . .
C52 C 0.6059(3) 0.31096(15) 1.1885(3) 0.0356(11) Uani 1 1 d . . . . .
H52 H 0.6155 0.3377 1.1786 0.043 Uiso 1 1 calc R . . . .
C53 C 0.7413(3) 0.29433(14) 1.4133(3) 0.0333(11) Uani 1 1 d . . . . .
C54 C 0.8150(4) 0.27457(17) 1.4091(3) 0.0464(13) Uani 1 1 d . . . . .
H54 H 0.8422 0.2802 1.3677 0.056 Uiso 1 1 calc R . . . .
C55 C 0.8494(4) 0.24702(19) 1.4635(4) 0.0547(15) Uani 1 1 d . . . . .
H55 H 0.8991 0.2336 1.4590 0.066 Uiso 1 1 calc R . . . .
C56 C 0.8114(4) 0.23917(19) 1.5242(3) 0.0544(16) Uani 1 1 d . . . . .
H56 H 0.8346 0.2201 1.5617 0.065 Uiso 1 1 calc R . . . .
C57 C 0.7399(4) 0.25893(19) 1.5305(3) 0.0538(15) Uani 1 1 d . . . . .
H57 H 0.7141 0.2537 1.5730 0.065 Uiso 1 1 calc R . . . .
C58 C 0.7049(4) 0.28647(16) 1.4757(3) 0.0412(12) Uani 1 1 d . . . . .
H58 H 0.6555 0.3000 1.4809 0.049 Uiso 1 1 calc R . . . .
C59 C 0.8276(3) 0.45844(15) 1.4148(3) 0.0347(11) Uani 1 1 d . . . . .
C60 C 0.7635(4) 0.47617(18) 1.3633(4) 0.0531(15) Uani 1 1 d . . . . .
H60 H 0.7497 0.4674 1.3111 0.064 Uiso 1 1 calc R . . . .
C61 C 0.7188(4) 0.5067(2) 1.3865(4) 0.067(2) Uani 1 1 d . . . . .
H61 H 0.6747 0.5187 1.3504 0.080 Uiso 1 1 calc R . . . .
C62 C 0.7385(4) 0.5195(2) 1.4621(4) 0.0656(19) Uani 1 1 d . . . . .
H62 H 0.7068 0.5399 1.4788 0.079 Uiso 1 1 calc R . . . .
C63 C 0.8034(4) 0.5030(2) 1.5127(4) 0.0598(17) Uani 1 1 d . . . . .
H63 H 0.8186 0.5128 1.5641 0.072 Uiso 1 1 calc R . . . .
C64 C 0.8471(4) 0.47232(18) 1.4907(3) 0.0495(14) Uani 1 1 d . . . . .
H64 H 0.8910 0.4604 1.5274 0.059 Uiso 1 1 calc R . . . .
C65 C 0.9529(3) 0.40081(14) 1.4669(3) 0.0355(11) Uani 1 1 d . . . . .
C66 C 1.0308(4) 0.41597(19) 1.5000(3) 0.0474(14) Uani 1 1 d . . . . .
H66 H 1.0537 0.4367 1.4753 0.057 Uiso 1 1 calc R . . . .
C67 C 1.0753(4) 0.4008(2) 1.5692(4) 0.0639(19) Uani 1 1 d . . . . .
H67 H 1.1293 0.4109 1.5914 0.077 Uiso 1 1 calc R . . . .
C68 C 1.0419(5) 0.3715(2) 1.6057(4) 0.067(2) Uani 1 1 d . . . . .
H68 H 1.0720 0.3618 1.6540 0.080 Uiso 1 1 calc R . . . .
C69 C 0.9649(5) 0.3561(2) 1.5729(4) 0.0652(19) Uani 1 1 d . . . . .
H69 H 0.9424 0.3354 1.5980 0.078 Uiso 1 1 calc R . . . .
C70 C 0.9203(4) 0.37052(17) 1.5036(3) 0.0493(14) Uani 1 1 d . . . . .
H70 H 0.8671 0.3597 1.4810 0.059 Uiso 1 1 calc R . . . .
C71 C 0.9607(3) 0.44911(14) 1.3355(3) 0.0319(10) Uani 1 1 d . . . . .
C72 C 1.0063(3) 0.43001(16) 1.2893(3) 0.0389(12) Uani 1 1 d . . . . .
H72 H 0.9974 0.4029 1.2793 0.047 Uiso 1 1 calc R . . . .
C73 C 1.0645(4) 0.44955(18) 1.2572(3) 0.0489(14) Uani 1 1 d . . . . .
H73 H 1.0963 0.4359 1.2264 0.059 Uiso 1 1 calc R . . . .
C74 C 1.0766(4) 0.48916(19) 1.2700(3) 0.0507(15) Uani 1 1 d . . . . .
H74 H 1.1167 0.5028 1.2480 0.061 Uiso 1 1 calc R . . . .
C75 C 1.0309(4) 0.50870(17) 1.3144(3) 0.0486(14) Uani 1 1 d . . . . .
H75 H 1.0389 0.5360 1.3224 0.058 Uiso 1 1 calc R . . . .
C76 C 0.9729(3) 0.48909(15) 1.3481(3) 0.0403(12) Uani 1 1 d . . . . .
H76 H 0.9418 0.5029 1.3795 0.048 Uiso 1 1 calc R . . . .
C77 C 0.7419(3) 0.39309(13) 0.7978(3) 0.0328(11) Uani 1 1 d . . . . .
C78 C 0.7539(4) 0.41946(17) 0.7418(3) 0.0535(15) Uani 1 1 d . . . . .
H78 H 0.7617 0.4464 0.7543 0.064 Uiso 1 1 calc R . . . .
C79 C 0.7545(5) 0.4066(2) 0.6670(4) 0.070(2) Uani 1 1 d . . . . .
H79 H 0.7608 0.4250 0.6283 0.084 Uiso 1 1 calc R . . . .
C80 C 0.7461(4) 0.3676(2) 0.6487(4) 0.0617(18) Uani 1 1 d . . . . .
H80 H 0.7491 0.3589 0.5983 0.074 Uiso 1 1 calc R . . . .
C81 C 0.7334(4) 0.34126(17) 0.7039(3) 0.0489(14) Uani 1 1 d . . . . .
H81 H 0.7260 0.3144 0.6910 0.059 Uiso 1 1 calc R . . . .
C82 C 0.7312(3) 0.35354(14) 0.7777(3) 0.0379(12) Uani 1 1 d . . . . .
H82 H 0.7224 0.3350 0.8153 0.045 Uiso 1 1 calc R . . . .
C83 C 0.6440(3) 0.42376(14) 0.9048(3) 0.0371(11) Uani 1 1 d . . . . .
C84 C 0.5905(4) 0.44179(16) 0.8444(3) 0.0457(13) Uani 1 1 d . . . . .
H84 H 0.6053 0.4432 0.7952 0.055 Uiso 1 1 calc R . . . .
C85 C 0.5152(4) 0.45803(17) 0.8539(4) 0.0556(16) Uani 1 1 d . . . . .
H85 H 0.4782 0.4699 0.8114 0.067 Uiso 1 1 calc R . . . .
C86 C 0.4952(4) 0.45659(18) 0.9258(4) 0.0578(17) Uani 1 1 d . . . . .
H86 H 0.4442 0.4679 0.9331 0.069 Uiso 1 1 calc R . . . .
C87 C 0.5480(4) 0.43889(19) 0.9871(4) 0.0556(16) Uani 1 1 d . . . . .
H87 H 0.5338 0.4382 1.0366 0.067 Uiso 1 1 calc R . . . .
C88 C 0.6220(3) 0.42205(16) 0.9763(3) 0.0434(13) Uani 1 1 d . . . . .
H88 H 0.6579 0.4092 1.0183 0.052 Uiso 1 1 calc R . . . .
C89 C 0.8099(4) 0.45058(15) 0.9079(3) 0.0385(12) Uani 1 1 d . . . . .
C90 C 0.8943(4) 0.44660(17) 0.9120(3) 0.0467(14) Uani 1 1 d . . . . .
H90 H 0.9178 0.4213 0.9106 0.056 Uiso 1 1 calc R . . . .
C91 C 0.9454(5) 0.4792(2) 0.9180(4) 0.0609(18) Uani 1 1 d . . . . .
H91 H 1.0037 0.4761 0.9200 0.073 Uiso 1 1 calc R . . . .
C92 C 0.9129(6) 0.5154(2) 0.9212(4) 0.073(2) Uani 1 1 d . . . . .
H92 H 0.9482 0.5377 0.9254 0.088 Uiso 1 1 calc R . . . .
C93 C 0.8288(6) 0.51959(19) 0.9184(5) 0.078(2) Uani 1 1 d . . . . .
H93 H 0.8059 0.5450 0.9207 0.093 Uiso 1 1 calc R . . . .
C94 C 0.7770(5) 0.48744(16) 0.9124(4) 0.0591(17) Uani 1 1 d . . . . .
H94 H 0.7189 0.4906 0.9112 0.071 Uiso 1 1 calc R . . . .
C95 C 0.9612(3) 0.26994(14) 1.0173(3) 0.0305(10) Uani 1 1 d . . . . .
C96 C 0.9833(3) 0.28369(15) 1.0930(3) 0.0349(11) Uani 1 1 d . . . . .
H96 H 0.9698 0.3098 1.1044 0.042 Uiso 1 1 calc R . . . .
C97 C 1.0246(3) 0.25967(16) 1.1518(3) 0.0416(12) Uani 1 1 d . . . . .
H97 H 1.0399 0.2693 1.2033 0.050 Uiso 1 1 calc R . . . .
C98 C 1.0435(4) 0.22209(17) 1.1358(3) 0.0465(14) Uani 1 1 d . . . . .
H98 H 1.0718 0.2056 1.1762 0.056 Uiso 1 1 calc R . . . .
C99 C 1.0218(4) 0.20802(16) 1.0614(3) 0.0476(14) Uani 1 1 d . . . . .
H99 H 1.0350 0.1818 1.0507 0.057 Uiso 1 1 calc R . . . .
C100 C 0.9807(4) 0.23175(15) 1.0019(3) 0.0409(12) Uani 1 1 d . . . . .
H100 H 0.9660 0.2219 0.9506 0.049 Uiso 1 1 calc R . . . .
C101 C 0.8552(3) 0.27177(14) 0.8654(3) 0.0318(10) Uani 1 1 d . . . . .
C102 C 0.8903(4) 0.25906(16) 0.8043(3) 0.0435(13) Uani 1 1 d . . . . .
H102 H 0.9462 0.2662 0.8024 0.052 Uiso 1 1 calc R . . . .
C103 C 0.8443(5) 0.23603(18) 0.7463(3) 0.0559(16) Uani 1 1 d . . . . .
H103 H 0.8689 0.2272 0.7052 0.067 Uiso 1 1 calc R . . . .
C104 C 0.7645(4) 0.22590(17) 0.7476(3) 0.0536(16) Uani 1 1 d . . . . .
H104 H 0.7327 0.2110 0.7063 0.064 Uiso 1 1 calc R . . . .
C105 C 0.7292(4) 0.23711(16) 0.8085(3) 0.0472(14) Uani 1 1 d . . . . .
H105 H 0.6739 0.2290 0.8103 0.057 Uiso 1 1 calc R . . . .
C106 C 0.7744(3) 0.26018(14) 0.8673(3) 0.0367(11) Uani 1 1 d . . . . .
H106 H 0.7497 0.2681 0.9090 0.044 Uiso 1 1 calc R . . . .
C107 C 0.9936(3) 0.32412(14) 0.9026(3) 0.0332(11) Uani 1 1 d . . . . .
C108 C 0.9722(4) 0.35331(16) 0.8466(3) 0.0445(13) Uani 1 1 d . . . . .
H108 H 0.9152 0.3609 0.8298 0.053 Uiso 1 1 calc R . . . .
C109 C 1.0330(4) 0.37094(19) 0.8159(4) 0.0529(15) Uani 1 1 d . . . . .
H109 H 1.0177 0.3911 0.7787 0.063 Uiso 1 1 calc R . . . .
C110 C 1.1156(4) 0.36008(19) 0.8376(4) 0.0564(16) Uani 1 1 d . . . . .
H110 H 1.1573 0.3726 0.8159 0.068 Uiso 1 1 calc R . . . .
C111 C 1.1372(4) 0.33054(19) 0.8919(4) 0.0528(15) Uani 1 1 d . . . . .
H111 H 1.1939 0.3222 0.9066 0.063 Uiso 1 1 calc R . . . .
C112 C 1.0762(3) 0.31309(16) 0.9248(3) 0.0406(12) Uani 1 1 d . . . . .
H112 H 1.0916 0.2933 0.9629 0.049 Uiso 1 1 calc R . . . .
C113 C 0.4730(5) 0.4083(3) 1.6352(5) 0.080(2) Uani 1 1 d . . . . .
C114 C 0.5203(6) 0.3787(3) 1.6820(5) 0.098(3) Uani 1 1 d . . . . .
H11A H 0.5730 0.3743 1.6649 0.147 Uiso 1 1 calc GR . . . .
H11B H 0.4878 0.3544 1.6768 0.147 Uiso 1 1 calc GR . . . .
H11C H 0.5325 0.3871 1.7362 0.147 Uiso 1 1 calc GR . . . .
C115 C 0.7792(10) 0.5314(3) 1.1630(9) 0.075(5) Uani 0.5 1 d D . P . .
C116 C 0.8357(7) 0.5036(3) 1.1438(7) 0.051(3) Uani 0.5 1 d D . P . .
H11D H 0.8933 0.5132 1.1604 0.076 Uiso 0.5 1 calc GR . P . .
H11E H 0.8233 0.4994 1.0877 0.076 Uiso 0.5 1 calc GR . P . .
H11F H 0.8297 0.4788 1.1701 0.076 Uiso 0.5 1 calc GR . P . .
N1 N 0.4385(8) 0.4310(3) 1.5977(7) 0.169(5) Uani 1 1 d . . . . .
N2 N 0.7370(15) 0.5498(5) 1.1822(13) 0.142(8) Uani 0.5 1 d . . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.0873(5) . ?
Ag1 Ag4' 3.040(6) . ?
Ag1 P1 2.4929(12) . ?
Ag1 P2 2.4891(13) . ?
Ag1 C1 2.497(5) . ?
Ag1 C11 2.527(6) . ?
Ag2 Ag3 2.9627(5) . ?
Ag2 Ag4 2.9239(7) . ?
Ag2 Ag4' 2.893(6) . ?
Ag2 C1 2.056(5) . ?
Ag2 C21 2.054(5) . ?
Ag3 Ag4 2.9799(7) . ?
Ag3 P3 2.4948(13) . ?
Ag3 P4 2.4949(12) . ?
Ag3 C21 2.527(5) . ?
Ag3 C31 2.471(6) . ?
Ag4 Ag4' 0.894(9) . ?
Ag4 C11 2.064(8) . ?
Ag4 C31 2.032(8) . ?
Ag4' C11 1.202(10) . ?
Ag4' C12 2.360(11) . ?
P1 C41 1.817(5) . ?
P1 C47 1.826(5) . ?
P1 C53 1.820(5) . ?
P2 C59 1.820(5) . ?
P2 C65 1.825(5) . ?
P2 C71 1.825(5) . ?
P3 C77 1.821(5) . ?
P3 C83 1.819(5) . ?
P3 C89 1.818(5) . ?
P4 C95 1.816(5) . ?
P4 C101 1.822(5) . ?
P4 C107 1.819(5) . ?
C1 C2 1.203(7) . ?
C2 C3 1.390(7) . ?
C3 C4 1.194(7) . ?
C4 C5 1.431(8) . ?
C5 C6 1.353(10) . ?
C5 C10 1.387(10) . ?
C6 H6 0.9500 . ?
C6 C7 1.417(11) . ?
C7 H7 0.9500 . ?
C7 C8 1.387(15) . ?
C8 H8 0.9500 . ?
C8 C9 1.332(16) . ?
C9 H9 0.9500 . ?
C9 C10 1.370(11) . ?
C10 H10 0.9500 . ?
C11 C12 1.202(7) . ?
C12 C13 1.360(10) . ?
C13 C14 1.202(10) . ?
C14 C15 1.419(11) . ?
C15 C16 1.396(12) . ?
C15 C20 1.368(13) . ?
C16 H16 0.9500 . ?
C16 C17 1.348(15) . ?
C17 H17 0.9500 . ?
C17 C18 1.36(2) . ?
C18 H18 0.9500 . ?
C18 C19 1.41(2) . ?
C19 H19 0.9500 . ?
C19 C20 1.361(15) . ?
C20 H20 0.9500 . ?
C21 C22 1.211(7) . ?
C22 C23 1.371(7) . ?
C23 C24 1.212(8) . ?
C24 C25 1.433(8) . ?
C25 C26 1.385(9) . ?
C25 C30 1.386(9) . ?
C26 H26 0.9500 . ?
C26 C27 1.373(10) . ?
C27 H27 0.9500 . ?
C27 C28 1.367(12) . ?
C28 H28 0.9500 . ?
C28 C29 1.361(11) . ?
C29 H29 0.9500 . ?
C29 C30 1.397(9) . ?
C30 H30 0.9500 . ?
C31 C32 1.245(10) . ?
C32 C33 1.361(12) . ?
C33 C34 1.194(11) . ?
C34 C35 1.403(12) . ?
C35 C36 1.385(11) . ?
C35 C40 1.392(10) . ?
C36 H36 0.9500 . ?
C36 C37 1.380(13) . ?
C37 H37 0.9500 . ?
C37 C38 1.369(13) . ?
C38 H38 0.9500 . ?
C38 C39 1.374(13) . ?
C39 H39 0.9500 . ?
C39 C40 1.351(11) . ?
C40 H40 0.9500 . ?
C41 C42 1.387(8) . ?
C41 C46 1.384(8) . ?
C42 H42 0.9500 . ?
C42 C43 1.399(9) . ?
C43 H43 0.9500 . ?
C43 C44 1.369(11) . ?
C44 H44 0.9500 . ?
C44 C45 1.361(11) . ?
C45 H45 0.9500 . ?
C45 C46 1.402(8) . ?
C46 H46 0.9500 . ?
C47 C48 1.373(7) . ?
C47 C52 1.392(7) . ?
C48 H48 0.9500 . ?
C48 C49 1.390(8) . ?
C49 H49 0.9500 . ?
C49 C50 1.372(8) . ?
C50 H50 0.9500 . ?
C50 C51 1.388(8) . ?
C51 H51 0.9500 . ?
C51 C52 1.378(7) . ?
C52 H52 0.9500 . ?
C53 C54 1.395(8) . ?
C53 C58 1.382(7) . ?
C54 H54 0.9500 . ?
C54 C55 1.379(8) . ?
C55 H55 0.9500 . ?
C55 C56 1.371(9) . ?
C56 H56 0.9500 . ?
C56 C57 1.373(9) . ?
C57 H57 0.9500 . ?
C57 C58 1.386(8) . ?
C58 H58 0.9500 . ?
C59 C60 1.375(8) . ?
C59 C64 1.394(7) . ?
C60 H60 0.9500 . ?
C60 C61 1.382(8) . ?
C61 H61 0.9500 . ?
C61 C62 1.379(9) . ?
C62 H62 0.9500 . ?
C62 C63 1.357(9) . ?
C63 H63 0.9500 . ?
C63 C64 1.369(8) . ?
C64 H64 0.9500 . ?
C65 C66 1.383(8) . ?
C65 C70 1.387(8) . ?
C66 H66 0.9500 . ?
C66 C67 1.385(8) . ?
C67 H67 0.9500 . ?
C67 C68 1.366(10) . ?
C68 H68 0.9500 . ?
C68 C69 1.373(11) . ?
C69 H69 0.9500 . ?
C69 C70 1.377(9) . ?
C70 H70 0.9500 . ?
C71 C72 1.379(7) . ?
C71 C76 1.394(7) . ?
C72 H72 0.9500 . ?
C72 C73 1.376(7) . ?
C73 H73 0.9500 . ?
C73 C74 1.381(9) . ?
C74 H74 0.9500 . ?
C74 C75 1.364(9) . ?
C75 H75 0.9500 . ?
C75 C76 1.392(8) . ?
C76 H76 0.9500 . ?
C77 C78 1.382(7) . ?
C77 C82 1.401(7) . ?
C78 H78 0.9500 . ?
C78 C79 1.394(9) . ?
C79 H79 0.9500 . ?
C79 C80 1.375(10) . ?
C80 H80 0.9500 . ?
C80 C81 1.374(9) . ?
C81 H81 0.9500 . ?
C81 C82 1.377(8) . ?
C82 H82 0.9500 . ?
C83 C84 1.375(7) . ?
C83 C88 1.383(8) . ?
C84 H84 0.9500 . ?
C84 C85 1.389(8) . ?
C85 H85 0.9500 . ?
C85 C86 1.376(10) . ?
C86 H86 0.9500 . ?
C86 C87 1.375(9) . ?
C87 H87 0.9500 . ?
C87 C88 1.386(8) . ?
C88 H88 0.9500 . ?
C89 C90 1.369(8) . ?
C89 C94 1.380(8) . ?
C90 H90 0.9500 . ?
C90 C91 1.383(8) . ?
C91 H91 0.9500 . ?
C91 C92 1.353(11) . ?
C92 H92 0.9500 . ?
C92 C93 1.370(12) . ?
C93 H93 0.9500 . ?
C93 C94 1.377(9) . ?
C94 H94 0.9500 . ?
C95 C96 1.392(7) . ?
C95 C100 1.385(7) . ?
C96 H96 0.9500 . ?
C96 C97 1.384(7) . ?
C97 H97 0.9500 . ?
C97 C98 1.366(8) . ?
C98 H98 0.9500 . ?
C98 C99 1.374(8) . ?
C99 H99 0.9500 . ?
C99 C100 1.385(8) . ?
C100 H100 0.9500 . ?
C101 C102 1.394(7) . ?
C101 C106 1.382(7) . ?
C102 H102 0.9500 . ?
C102 C103 1.382(8) . ?
C103 H103 0.9500 . ?
C103 C104 1.350(9) . ?
C104 H104 0.9500 . ?
C104 C105 1.376(9) . ?
C105 H105 0.9500 . ?
C105 C106 1.387(7) . ?
C106 H106 0.9500 . ?
C107 C108 1.398(7) . ?
C107 C112 1.373(7) . ?
C108 H108 0.9500 . ?
C108 C109 1.365(8) . ?
C109 H109 0.9500 . ?
C109 C110 1.372(9) . ?
C110 H110 0.9500 . ?
C110 C111 1.387(9) . ?
C111 H111 0.9500 . ?
C111 C112 1.387(8) . ?
C112 H112 0.9500 . ?
C113 C114 1.428(12) . ?
C113 N1 1.096(12) . ?
C114 H11A 0.9800 . ?
C114 H11B 0.9800 . ?
C114 H11C 0.9800 . ?
C115 C116 1.415(9) . ?
C115 N2 1.041(17) . ?
C116 H11D 0.9800 . ?
C116 H11E 0.9800 . ?
C116 H11F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag4' Ag1 Ag2 56.33(10) . . ?
P1 Ag1 Ag2 133.30(3) . . ?
P1 Ag1 Ag4' 93.24(13) . . ?
P1 Ag1 C1 108.48(13) . . ?
P1 Ag1 C11 94.62(15) . . ?
P2 Ag1 Ag2 100.86(3) . . ?
P2 Ag1 Ag4' 135.24(16) . . ?
P2 Ag1 P1 124.02(4) . . ?
P2 Ag1 C1 103.72(12) . . ?
P2 Ag1 C11 119.81(18) . . ?
C1 Ag1 Ag2 41.54(12) . . ?
C1 Ag1 Ag4' 83.76(17) . . ?
C1 Ag1 C11 104.7(2) . . ?
C11 Ag1 Ag2 70.51(15) . . ?
C11 Ag1 Ag4' 22.6(2) . . ?
Ag3 Ag2 Ag1 130.781(16) . . ?
Ag4 Ag2 Ag1 69.978(16) . . ?
Ag4 Ag2 Ag3 60.821(16) . . ?
Ag4' Ag2 Ag1 61.00(11) . . ?
Ag4' Ag2 Ag3 71.18(13) . . ?
Ag4' Ag2 Ag4 17.67(17) . . ?
C1 Ag2 Ag1 53.66(14) . . ?
C1 Ag2 Ag3 125.49(14) . . ?
C1 Ag2 Ag4 91.00(14) . . ?
C1 Ag2 Ag4' 95.95(19) . . ?
C21 Ag2 Ag1 127.02(14) . . ?
C21 Ag2 Ag3 57.11(14) . . ?
C21 Ag2 Ag4 92.31(13) . . ?
C21 Ag2 Ag4' 87.00(18) . . ?
C21 Ag2 C1 176.6(2) . . ?
Ag2 Ag3 Ag4 58.945(15) . . ?
P3 Ag3 Ag2 95.94(3) . . ?
P3 Ag3 Ag4 134.07(3) . . ?
P3 Ag3 P4 121.79(4) . . ?
P3 Ag3 C21 105.58(11) . . ?
P4 Ag3 Ag2 135.02(3) . . ?
P4 Ag3 Ag4 100.53(3) . . ?
P4 Ag3 C21 99.14(12) . . ?
C21 Ag3 Ag2 43.05(11) . . ?
C21 Ag3 Ag4 82.32(11) . . ?
C31 Ag3 Ag2 86.44(15) . . ?
C31 Ag3 Ag4 42.52(19) . . ?
C31 Ag3 P3 104.73(19) . . ?
C31 Ag3 P4 104.45(15) . . ?
C31 Ag3 C21 122.6(2) . . ?
Ag2 Ag4 Ag3 60.234(15) . . ?
Ag4' Ag4 Ag2 79.2(4) . . ?
Ag4' Ag4 Ag3 111.3(4) . . ?
Ag4' Ag4 C11 11.7(4) . . ?
Ag4' Ag4 C31 165.5(4) . . ?
C11 Ag4 Ag2 80.00(17) . . ?
C11 Ag4 Ag3 120.72(17) . . ?
C31 Ag4 Ag2 96.25(17) . . ?
C31 Ag4 Ag3 55.23(16) . . ?
C31 Ag4 C11 175.7(2) . . ?
Ag2 Ag4' Ag1 62.66(11) . . ?
Ag4 Ag4' Ag1 110.0(4) . . ?
Ag4 Ag4' Ag2 83.1(4) . . ?
Ag4 Ag4' C11 159.6(7) . . ?
Ag4 Ag4' C12 170.2(5) . . ?
C11 Ag4' Ag1 54.0(4) . . ?
C11 Ag4' Ag2 97.4(4) . . ?
C11 Ag4' C12 11.1(4) . . ?
C12 Ag4' Ag1 60.9(2) . . ?
C12 Ag4' Ag2 94.9(3) . . ?
C41 P1 Ag1 114.65(17) . . ?
C41 P1 C47 103.1(2) . . ?
C41 P1 C53 103.7(2) . . ?
C47 P1 Ag1 116.02(15) . . ?
C53 P1 Ag1 114.80(17) . . ?
C53 P1 C47 103.0(2) . . ?
C59 P2 Ag1 114.36(17) . . ?
C59 P2 C65 102.9(2) . . ?
C59 P2 C71 102.1(2) . . ?
C65 P2 Ag1 115.36(17) . . ?
C65 P2 C71 103.8(2) . . ?
C71 P2 Ag1 116.49(16) . . ?
C77 P3 Ag3 111.12(16) . . ?
C83 P3 Ag3 121.33(17) . . ?
C83 P3 C77 106.3(2) . . ?
C89 P3 Ag3 111.34(18) . . ?
C89 P3 C77 101.9(2) . . ?
C89 P3 C83 102.9(2) . . ?
C95 P4 Ag3 115.20(15) . . ?
C95 P4 C101 104.2(2) . . ?
C95 P4 C107 104.5(2) . . ?
C101 P4 Ag3 115.13(16) . . ?
C107 P4 Ag3 113.36(16) . . ?
C107 P4 C101 103.0(2) . . ?
Ag2 C1 Ag1 84.79(17) . . ?
C2 C1 Ag1 106.1(4) . . ?
C2 C1 Ag2 169.1(4) . . ?
C1 C2 C3 177.8(5) . . ?
C4 C3 C2 177.4(6) . . ?
C3 C4 C5 177.8(6) . . ?
C6 C5 C4 120.2(7) . . ?
C6 C5 C10 119.8(6) . . ?
C10 C5 C4 120.0(6) . . ?
C5 C6 H6 120.3 . . ?
C5 C6 C7 119.4(9) . . ?
C7 C6 H6 120.3 . . ?
C6 C7 H7 120.5 . . ?
C8 C7 C6 119.1(10) . . ?
C8 C7 H7 120.5 . . ?
C7 C8 H8 119.8 . . ?
C9 C8 C7 120.4(8) . . ?
C9 C8 H8 119.8 . . ?
C8 C9 H9 119.5 . . ?
C8 C9 C10 120.9(11) . . ?
C10 C9 H9 119.5 . . ?
C5 C10 H10 119.8 . . ?
C9 C10 C5 120.3(9) . . ?
C9 C10 H10 119.8 . . ?
Ag4 C11 Ag1 96.9(3) . . ?
Ag4' C11 Ag1 103.4(5) . . ?
Ag4' C11 Ag4 8.7(3) . . ?
C12 C11 Ag1 89.9(5) . . ?
C12 C11 Ag4 166.1(5) . . ?
C12 C11 Ag4' 157.8(7) . . ?
C11 C12 Ag4' 11.1(4) . . ?
C11 C12 C13 176.0(7) . . ?
C13 C12 Ag4' 165.9(5) . . ?
C14 C13 C12 178.0(7) . . ?
C13 C14 C15 177.1(8) . . ?
C16 C15 C14 121.1(9) . . ?
C20 C15 C14 120.3(9) . . ?
C20 C15 C16 118.5(10) . . ?
C15 C16 H16 119.4 . . ?
C17 C16 C15 121.2(13) . . ?
C17 C16 H16 119.4 . . ?
C16 C17 H17 120.4 . . ?
C16 C17 C18 119.2(13) . . ?
C18 C17 H17 120.4 . . ?
C17 C18 H18 119.3 . . ?
C17 C18 C19 121.5(13) . . ?
C19 C18 H18 119.3 . . ?
C18 C19 H19 121.3 . . ?
C20 C19 C18 117.5(14) . . ?
C20 C19 H19 121.3 . . ?
C15 C20 H20 119.1 . . ?
C19 C20 C15 121.8(13) . . ?
C19 C20 H20 119.1 . . ?
Ag2 C21 Ag3 79.85(16) . . ?
C22 C21 Ag2 159.0(4) . . ?
C22 C21 Ag3 119.4(4) . . ?
C21 C22 C23 178.0(6) . . ?
C24 C23 C22 178.2(6) . . ?
C23 C24 C25 177.2(7) . . ?
C26 C25 C24 121.3(6) . . ?
C26 C25 C30 118.5(6) . . ?
C30 C25 C24 120.1(6) . . ?
C25 C26 H26 119.7 . . ?
C27 C26 C25 120.5(7) . . ?
C27 C26 H26 119.7 . . ?
C26 C27 H27 119.7 . . ?
C28 C27 C26 120.7(7) . . ?
C28 C27 H27 119.7 . . ?
C27 C28 H28 120.0 . . ?
C29 C28 C27 120.1(7) . . ?
C29 C28 H28 120.0 . . ?
C28 C29 H29 120.0 . . ?
C28 C29 C30 120.1(7) . . ?
C30 C29 H29 120.0 . . ?
C25 C30 C29 120.1(7) . . ?
C25 C30 H30 119.9 . . ?
C29 C30 H30 119.9 . . ?
Ag4 C31 Ag3 82.2(2) . . ?
C32 C31 Ag3 110.7(5) . . ?
C32 C31 Ag4 163.7(5) . . ?
C31 C32 C33 176.8(7) . . ?
C34 C33 C32 179.2(8) . . ?
C33 C34 C35 176.7(8) . . ?
C36 C35 C34 121.7(7) . . ?
C36 C35 C40 119.5(8) . . ?
C40 C35 C34 118.8(8) . . ?
C35 C36 H36 119.8 . . ?
C37 C36 C35 120.4(8) . . ?
C37 C36 H36 119.8 . . ?
C36 C37 H37 120.6 . . ?
C38 C37 C36 118.7(9) . . ?
C38 C37 H37 120.6 . . ?
C37 C38 H38 119.5 . . ?
C37 C38 C39 121.1(10) . . ?
C39 C38 H38 119.5 . . ?
C38 C39 H39 119.7 . . ?
C40 C39 C38 120.7(9) . . ?
C40 C39 H39 119.7 . . ?
C35 C40 H40 120.2 . . ?
C39 C40 C35 119.6(8) . . ?
C39 C40 H40 120.2 . . ?
C42 C41 P1 117.0(4) . . ?
C46 C41 P1 123.2(4) . . ?
C46 C41 C42 119.7(5) . . ?
C41 C42 H42 120.3 . . ?
C41 C42 C43 119.4(6) . . ?
C43 C42 H42 120.3 . . ?
C42 C43 H43 120.0 . . ?
C44 C43 C42 119.9(7) . . ?
C44 C43 H43 120.0 . . ?
C43 C44 H44 119.3 . . ?
C45 C44 C43 121.5(6) . . ?
C45 C44 H44 119.3 . . ?
C44 C45 H45 120.4 . . ?
C44 C45 C46 119.3(7) . . ?
C46 C45 H45 120.4 . . ?
C41 C46 C45 120.2(6) . . ?
C41 C46 H46 119.9 . . ?
C45 C46 H46 119.9 . . ?
C48 C47 P1 123.1(4) . . ?
C48 C47 C52 119.4(5) . . ?
C52 C47 P1 117.5(4) . . ?
C47 C48 H48 119.9 . . ?
C47 C48 C49 120.3(5) . . ?
C49 C48 H48 119.9 . . ?
C48 C49 H49 119.7 . . ?
C50 C49 C48 120.6(5) . . ?
C50 C49 H49 119.7 . . ?
C49 C50 H50 120.4 . . ?
C49 C50 C51 119.1(5) . . ?
C51 C50 H50 120.4 . . ?
C50 C51 H51 119.7 . . ?
C52 C51 C50 120.6(5) . . ?
C52 C51 H51 119.7 . . ?
C47 C52 H52 120.0 . . ?
C51 C52 C47 120.0(5) . . ?
C51 C52 H52 120.0 . . ?
C54 C53 P1 118.3(4) . . ?
C58 C53 P1 123.9(4) . . ?
C58 C53 C54 117.9(5) . . ?
C53 C54 H54 119.2 . . ?
C55 C54 C53 121.5(5) . . ?
C55 C54 H54 119.2 . . ?
C54 C55 H55 120.2 . . ?
C56 C55 C54 119.6(6) . . ?
C56 C55 H55 120.2 . . ?
C55 C56 H56 120.1 . . ?
C55 C56 C57 119.8(6) . . ?
C57 C56 H56 120.1 . . ?
C56 C57 H57 119.7 . . ?
C56 C57 C58 120.7(6) . . ?
C58 C57 H57 119.7 . . ?
C53 C58 C57 120.4(5) . . ?
C53 C58 H58 119.8 . . ?
C57 C58 H58 119.8 . . ?
C60 C59 P2 118.1(4) . . ?
C60 C59 C64 118.3(5) . . ?
C64 C59 P2 123.4(4) . . ?
C59 C60 H60 119.6 . . ?
C59 C60 C61 120.8(6) . . ?
C61 C60 H60 119.6 . . ?
C60 C61 H61 120.1 . . ?
C62 C61 C60 119.8(6) . . ?
C62 C61 H61 120.1 . . ?
C61 C62 H62 120.2 . . ?
C63 C62 C61 119.7(6) . . ?
C63 C62 H62 120.2 . . ?
C62 C63 H63 119.5 . . ?
C62 C63 C64 120.9(6) . . ?
C64 C63 H63 119.5 . . ?
C59 C64 H64 119.8 . . ?
C63 C64 C59 120.4(6) . . ?
C63 C64 H64 119.8 . . ?
C66 C65 P2 122.9(4) . . ?
C66 C65 C70 119.4(5) . . ?
C70 C65 P2 117.6(4) . . ?
C65 C66 H66 120.1 . . ?
C65 C66 C67 119.9(6) . . ?
C67 C66 H66 120.1 . . ?
C66 C67 H67 119.9 . . ?
C68 C67 C66 120.3(7) . . ?
C68 C67 H67 119.9 . . ?
C67 C68 H68 119.9 . . ?
C67 C68 C69 120.1(6) . . ?
C69 C68 H68 119.9 . . ?
C68 C69 H69 119.9 . . ?
C68 C69 C70 120.3(6) . . ?
C70 C69 H69 119.9 . . ?
C65 C70 H70 120.0 . . ?
C69 C70 C65 120.0(6) . . ?
C69 C70 H70 120.0 . . ?
C72 C71 P2 118.2(4) . . ?
C72 C71 C76 118.9(5) . . ?
C76 C71 P2 122.9(4) . . ?
C71 C72 H72 119.4 . . ?
C73 C72 C71 121.1(5) . . ?
C73 C72 H72 119.4 . . ?
C72 C73 H73 120.1 . . ?
C72 C73 C74 119.8(5) . . ?
C74 C73 H73 120.1 . . ?
C73 C74 H74 120.0 . . ?
C75 C74 C73 119.9(5) . . ?
C75 C74 H74 120.0 . . ?
C74 C75 H75 119.6 . . ?
C74 C75 C76 120.8(5) . . ?
C76 C75 H75 119.6 . . ?
C71 C76 H76 120.3 . . ?
C75 C76 C71 119.5(5) . . ?
C75 C76 H76 120.3 . . ?
C78 C77 P3 123.7(4) . . ?
C78 C77 C82 118.6(5) . . ?
C82 C77 P3 117.5(4) . . ?
C77 C78 H78 119.9 . . ?
C77 C78 C79 120.1(5) . . ?
C79 C78 H78 119.9 . . ?
C78 C79 H79 119.7 . . ?
C80 C79 C78 120.6(6) . . ?
C80 C79 H79 119.7 . . ?
C79 C80 H80 120.2 . . ?
C81 C80 C79 119.5(6) . . ?
C81 C80 H80 120.2 . . ?
C80 C81 H81 119.7 . . ?
C80 C81 C82 120.6(5) . . ?
C82 C81 H81 119.7 . . ?
C77 C82 H82 119.7 . . ?
C81 C82 C77 120.6(5) . . ?
C81 C82 H82 119.7 . . ?
C84 C83 P3 123.4(4) . . ?
C84 C83 C88 118.9(5) . . ?
C88 C83 P3 117.4(4) . . ?
C83 C84 H84 119.3 . . ?
C83 C84 C85 121.4(6) . . ?
C85 C84 H84 119.3 . . ?
C84 C85 H85 120.6 . . ?
C86 C85 C84 118.8(6) . . ?
C86 C85 H85 120.6 . . ?
C85 C86 H86 119.6 . . ?
C87 C86 C85 120.8(6) . . ?
C87 C86 H86 119.6 . . ?
C86 C87 H87 120.2 . . ?
C86 C87 C88 119.7(6) . . ?
C88 C87 H87 120.2 . . ?
C83 C88 C87 120.5(6) . . ?
C83 C88 H88 119.8 . . ?
C87 C88 H88 119.8 . . ?
C90 C89 P3 117.2(4) . . ?
C90 C89 C94 119.1(5) . . ?
C94 C89 P3 123.7(5) . . ?
C89 C90 H90 119.8 . . ?
C89 C90 C91 120.5(6) . . ?
C91 C90 H90 119.8 . . ?
C90 C91 H91 119.8 . . ?
C92 C91 C90 120.4(7) . . ?
C92 C91 H91 119.8 . . ?
C91 C92 H92 120.2 . . ?
C91 C92 C93 119.5(6) . . ?
C93 C92 H92 120.2 . . ?
C92 C93 H93 119.6 . . ?
C92 C93 C94 120.8(7) . . ?
C94 C93 H93 119.6 . . ?
C89 C94 H94 120.2 . . ?
C93 C94 C89 119.7(7) . . ?
C93 C94 H94 120.2 . . ?
C96 C95 P4 118.0(4) . . ?
C100 C95 P4 123.1(4) . . ?
C100 C95 C96 118.9(4) . . ?
C95 C96 H96 119.8 . . ?
C97 C96 C95 120.5(5) . . ?
C97 C96 H96 119.8 . . ?
C96 C97 H97 120.0 . . ?
C98 C97 C96 120.0(5) . . ?
C98 C97 H97 120.0 . . ?
C97 C98 H98 119.9 . . ?
C97 C98 C99 120.2(5) . . ?
C99 C98 H98 119.9 . . ?
C98 C99 H99 119.8 . . ?
C98 C99 C100 120.4(5) . . ?
C100 C99 H99 119.8 . . ?
C95 C100 H100 120.0 . . ?
C99 C100 C95 120.0(5) . . ?
C99 C100 H100 120.0 . . ?
C102 C101 P4 123.7(4) . . ?
C106 C101 P4 117.8(4) . . ?
C106 C101 C102 118.5(5) . . ?
C101 C102 H102 119.9 . . ?
C103 C102 C101 120.2(6) . . ?
C103 C102 H102 119.9 . . ?
C102 C103 H103 119.7 . . ?
C104 C103 C102 120.7(5) . . ?
C104 C103 H103 119.7 . . ?
C103 C104 H104 119.9 . . ?
C103 C104 C105 120.2(5) . . ?
C105 C104 H104 119.9 . . ?
C104 C105 H105 120.0 . . ?
C104 C105 C106 119.9(6) . . ?
C106 C105 H105 120.0 . . ?
C101 C106 C105 120.4(5) . . ?
C101 C106 H106 119.8 . . ?
C105 C106 H106 119.8 . . ?
C108 C107 P4 117.1(4) . . ?
C112 C107 P4 124.0(4) . . ?
C112 C107 C108 118.9(5) . . ?
C107 C108 H108 119.9 . . ?
C109 C108 C107 120.2(6) . . ?
C109 C108 H108 119.9 . . ?
C108 C109 H109 119.3 . . ?
C108 C109 C110 121.4(6) . . ?
C110 C109 H109 119.3 . . ?
C109 C110 H110 120.5 . . ?
C109 C110 C111 118.9(6) . . ?
C111 C110 H110 120.5 . . ?
C110 C111 H111 119.9 . . ?
C110 C111 C112 120.2(6) . . ?
C112 C111 H111 119.9 . . ?
C107 C112 C111 120.5(5) . . ?
C107 C112 H112 119.7 . . ?
C111 C112 H112 119.7 . . ?
N1 C113 C114 177.8(12) . . ?
C113 C114 H11A 109.5 . . ?
C113 C114 H11B 109.5 . . ?
C113 C114 H11C 109.5 . . ?
H11A C114 H11B 109.5 . . ?
H11A C114 H11C 109.5 . . ?
H11B C114 H11C 109.5 . . ?
N2 C115 C116 173.6(17) . . ?
C115 C116 H11D 109.5 . . ?
C115 C116 H11E 109.5 . . ?
C115 C116 H11F 109.5 . . ?
H11D C116 H11E 109.5 . . ?
H11D C116 H11F 109.5 . . ?
H11E C116 H11F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 Ag4' C11 Ag4 42(2) . . . . ?
Ag1 Ag4' C11 C12 -125(2) . . . . ?
Ag1 P1 C41 C42 -40.4(5) . . . . ?
Ag1 P1 C41 C46 141.5(4) . . . . ?
Ag1 P1 C47 C48 135.1(4) . . . . ?
Ag1 P1 C47 C52 -45.2(4) . . . . ?
Ag1 P1 C53 C54 -44.8(5) . . . . ?
Ag1 P1 C53 C58 137.3(4) . . . . ?
Ag1 P2 C59 C60 -45.9(5) . . . . ?
Ag1 P2 C59 C64 138.8(4) . . . . ?
Ag1 P2 C65 C66 146.5(4) . . . . ?
Ag1 P2 C65 C70 -36.7(5) . . . . ?
Ag1 P2 C71 C72 -42.8(5) . . . . ?
Ag1 P2 C71 C76 137.9(4) . . . . ?
Ag1 C11 C12 Ag4' -127.5(19) . . . . ?
Ag2 Ag4 Ag4' Ag1 57.6(2) . . . . ?
Ag2 Ag4 Ag4' C11 92.9(19) . . . . ?
Ag2 Ag4' C11 Ag1 48.1(3) . . . . ?
Ag2 Ag4' C11 Ag4 90.3(19) . . . . ?
Ag2 Ag4' C11 C12 -77.2(18) . . . . ?
Ag3 Ag4 Ag4' Ag1 109.5(2) . . . . ?
Ag3 Ag4 Ag4' Ag2 51.88(19) . . . . ?
Ag3 Ag4 Ag4' C11 144.8(18) . . . . ?
Ag3 P3 C77 C78 -140.3(5) . . . . ?
Ag3 P3 C77 C82 34.5(4) . . . . ?
Ag3 P3 C83 C84 -157.4(4) . . . . ?
Ag3 P3 C83 C88 28.8(5) . . . . ?
Ag3 P3 C89 C90 43.2(5) . . . . ?
Ag3 P3 C89 C94 -135.6(5) . . . . ?
Ag3 P4 C95 C96 -31.0(5) . . . . ?
Ag3 P4 C95 C100 150.0(4) . . . . ?
Ag3 P4 C101 C102 141.3(4) . . . . ?
Ag3 P4 C101 C106 -37.9(4) . . . . ?
Ag3 P4 C107 C108 -49.6(4) . . . . ?
Ag3 P4 C107 C112 129.5(4) . . . . ?
Ag4 Ag4' C11 Ag1 -42(2) . . . . ?
Ag4 Ag4' C11 C12 -167.5(16) . . . . ?
Ag4 C11 C12 Ag4' -7.8(10) . . . . ?
P1 C41 C42 C43 -178.7(5) . . . . ?
P1 C41 C46 C45 179.1(4) . . . . ?
P1 C47 C48 C49 178.9(4) . . . . ?
P1 C47 C52 C51 -178.4(4) . . . . ?
P1 C53 C54 C55 -175.8(5) . . . . ?
P1 C53 C58 C57 176.1(4) . . . . ?
P2 C59 C60 C61 -176.3(6) . . . . ?
P2 C59 C64 C63 175.0(5) . . . . ?
P2 C65 C66 C67 176.8(5) . . . . ?
P2 C65 C70 C69 -176.2(5) . . . . ?
P2 C71 C72 C73 -177.8(4) . . . . ?
P2 C71 C76 C75 178.8(4) . . . . ?
P3 C77 C78 C79 175.3(5) . . . . ?
P3 C77 C82 C81 -174.5(4) . . . . ?
P3 C83 C84 C85 -174.0(5) . . . . ?
P3 C83 C88 C87 172.9(5) . . . . ?
P3 C89 C90 C91 179.2(4) . . . . ?
P3 C89 C94 C93 -179.3(5) . . . . ?
P4 C95 C96 C97 -178.6(4) . . . . ?
P4 C95 C100 C99 178.9(4) . . . . ?
P4 C101 C102 C103 -177.9(4) . . . . ?
P4 C101 C106 C105 177.9(4) . . . . ?
P4 C107 C108 C109 177.8(4) . . . . ?
P4 C107 C112 C111 -179.3(4) . . . . ?
C4 C5 C6 C7 -177.9(7) . . . . ?
C4 C5 C10 C9 175.6(7) . . . . ?
C5 C6 C7 C8 2.1(13) . . . . ?
C6 C5 C10 C9 -2.7(11) . . . . ?
C6 C7 C8 C9 -2.5(15) . . . . ?
C7 C8 C9 C10 0.2(16) . . . . ?
C8 C9 C10 C5 2.4(15) . . . . ?
C10 C5 C6 C7 0.4(11) . . . . ?
C11 Ag4 Ag4' Ag1 -35.3(18) . . . . ?
C11 Ag4 Ag4' Ag2 -93(2) . . . . ?
C12 Ag4' C11 Ag1 125(2) . . . . ?
C12 Ag4' C11 Ag4 167.5(16) . . . . ?
C14 C15 C16 C17 172.9(9) . . . . ?
C14 C15 C20 C19 -177.0(9) . . . . ?
C15 C16 C17 C18 6.5(17) . . . . ?
C16 C15 C20 C19 1.2(14) . . . . ?
C16 C17 C18 C19 -4(2) . . . . ?
C17 C18 C19 C20 -0.3(19) . . . . ?
C18 C19 C20 C15 1.5(17) . . . . ?
C20 C15 C16 C17 -5.3(13) . . . . ?
C24 C25 C26 C27 -179.3(6) . . . . ?
C24 C25 C30 C29 179.7(6) . . . . ?
C25 C26 C27 C28 0.0(12) . . . . ?
C26 C25 C30 C29 0.2(10) . . . . ?
C26 C27 C28 C29 -0.5(13) . . . . ?
C27 C28 C29 C30 0.8(12) . . . . ?
C28 C29 C30 C25 -0.7(11) . . . . ?
C30 C25 C26 C27 0.1(10) . . . . ?
C31 Ag4 Ag4' Ag1 130.4(15) . . . . ?
C31 Ag4 Ag4' Ag2 72.8(16) . . . . ?
C31 Ag4 Ag4' C11 165.7(12) . . . . ?
C34 C35 C36 C37 -179.4(7) . . . . ?
C34 C35 C40 C39 178.0(7) . . . . ?
C35 C36 C37 C38 1.3(13) . . . . ?
C36 C35 C40 C39 -1.3(11) . . . . ?
C36 C37 C38 C39 -1.1(14) . . . . ?
C37 C38 C39 C40 -0.3(14) . . . . ?
C38 C39 C40 C35 1.5(13) . . . . ?
C40 C35 C36 C37 -0.1(11) . . . . ?
C41 P1 C47 C48 -98.8(5) . . . . ?
C41 P1 C47 C52 81.0(4) . . . . ?
C41 P1 C53 C54 -170.6(4) . . . . ?
C41 P1 C53 C58 11.5(5) . . . . ?
C41 C42 C43 C44 0.8(10) . . . . ?
C42 C41 C46 C45 1.1(8) . . . . ?
C42 C43 C44 C45 -1.7(11) . . . . ?
C43 C44 C45 C46 2.3(10) . . . . ?
C44 C45 C46 C41 -1.9(9) . . . . ?
C46 C41 C42 C43 -0.5(9) . . . . ?
C47 P1 C41 C42 -167.4(4) . . . . ?
C47 P1 C41 C46 14.5(5) . . . . ?
C47 P1 C53 C54 82.3(4) . . . . ?
C47 P1 C53 C58 -95.7(5) . . . . ?
C47 C48 C49 C50 0.3(9) . . . . ?
C48 C47 C52 C51 1.4(7) . . . . ?
C48 C49 C50 C51 -0.3(9) . . . . ?
C49 C50 C51 C52 0.8(8) . . . . ?
C50 C51 C52 C47 -1.4(8) . . . . ?
C52 C47 C48 C49 -0.9(8) . . . . ?
C53 P1 C41 C42 85.5(5) . . . . ?
C53 P1 C41 C46 -92.6(5) . . . . ?
C53 P1 C47 C48 8.8(5) . . . . ?
C53 P1 C47 C52 -171.4(4) . . . . ?
C53 C54 C55 C56 -1.2(10) . . . . ?
C54 C53 C58 C57 -1.8(8) . . . . ?
C54 C55 C56 C57 -0.4(10) . . . . ?
C55 C56 C57 C58 0.8(10) . . . . ?
C56 C57 C58 C53 0.4(9) . . . . ?
C58 C53 C54 C55 2.3(9) . . . . ?
C59 P2 C65 C66 -88.3(5) . . . . ?
C59 P2 C65 C70 88.5(4) . . . . ?
C59 P2 C71 C72 -168.1(4) . . . . ?
C59 P2 C71 C76 12.6(5) . . . . ?
C59 C60 C61 C62 -0.1(11) . . . . ?
C60 C59 C64 C63 -0.3(9) . . . . ?
C60 C61 C62 C63 2.1(12) . . . . ?
C61 C62 C63 C64 -3.2(12) . . . . ?
C62 C63 C64 C59 2.3(11) . . . . ?
C64 C59 C60 C61 -0.8(10) . . . . ?
C65 P2 C59 C60 -171.8(5) . . . . ?
C65 P2 C59 C64 12.9(5) . . . . ?
C65 P2 C71 C72 85.2(4) . . . . ?
C65 P2 C71 C76 -94.2(5) . . . . ?
C65 C66 C67 C68 -1.3(10) . . . . ?
C66 C65 C70 C69 0.7(9) . . . . ?
C66 C67 C68 C69 1.8(11) . . . . ?
C67 C68 C69 C70 -1.1(11) . . . . ?
C68 C69 C70 C65 -0.2(10) . . . . ?
C70 C65 C66 C67 0.0(8) . . . . ?
C71 P2 C59 C60 80.8(5) . . . . ?
C71 P2 C59 C64 -94.5(5) . . . . ?
C71 P2 C65 C66 17.8(5) . . . . ?
C71 P2 C65 C70 -165.4(4) . . . . ?
C71 C72 C73 C74 -1.4(9) . . . . ?
C72 C71 C76 C75 -0.5(8) . . . . ?
C72 C73 C74 C75 0.1(9) . . . . ?
C73 C74 C75 C76 1.0(9) . . . . ?
C74 C75 C76 C71 -0.8(8) . . . . ?
C76 C71 C72 C73 1.6(8) . . . . ?
C77 P3 C83 C84 -29.3(5) . . . . ?
C77 P3 C83 C88 156.9(4) . . . . ?
C77 P3 C89 C90 -75.3(5) . . . . ?
C77 P3 C89 C94 105.9(5) . . . . ?
C77 C78 C79 C80 -2.2(11) . . . . ?
C78 C77 C82 C81 0.5(8) . . . . ?
C78 C79 C80 C81 2.8(12) . . . . ?
C79 C80 C81 C82 -1.7(10) . . . . ?
C80 C81 C82 C77 0.0(9) . . . . ?
C82 C77 C78 C79 0.5(9) . . . . ?
C83 P3 C77 C78 85.8(5) . . . . ?
C83 P3 C77 C82 -99.4(4) . . . . ?
C83 P3 C89 C90 174.7(4) . . . . ?
C83 P3 C89 C94 -4.1(6) . . . . ?
C83 C84 C85 C86 1.3(9) . . . . ?
C84 C83 C88 C87 -1.2(8) . . . . ?
C84 C85 C86 C87 -1.0(10) . . . . ?
C85 C86 C87 C88 -0.5(10) . . . . ?
C86 C87 C88 C83 1.6(9) . . . . ?
C88 C83 C84 C85 -0.2(8) . . . . ?
C89 P3 C77 C78 -21.6(6) . . . . ?
C89 P3 C77 C82 153.1(4) . . . . ?
C89 P3 C83 C84 77.4(5) . . . . ?
C89 P3 C83 C88 -96.5(4) . . . . ?
C89 C90 C91 C92 1.0(9) . . . . ?
C90 C89 C94 C93 1.9(9) . . . . ?
C90 C91 C92 C93 0.0(10) . . . . ?
C91 C92 C93 C94 0.0(12) . . . . ?
C92 C93 C94 C89 -1.0(11) . . . . ?
C94 C89 C90 C91 -1.9(8) . . . . ?
C95 P4 C101 C102 -91.5(5) . . . . ?
C95 P4 C101 C106 89.3(4) . . . . ?
C95 P4 C107 C108 -175.9(4) . . . . ?
C95 P4 C107 C112 3.3(5) . . . . ?
C95 C96 C97 C98 -0.5(8) . . . . ?
C96 C95 C100 C99 -0.2(8) . . . . ?
C96 C97 C98 C99 0.2(9) . . . . ?
C97 C98 C99 C100 0.1(9) . . . . ?
C98 C99 C100 C95 -0.1(9) . . . . ?
C100 C95 C96 C97 0.5(8) . . . . ?
C101 P4 C95 C96 -158.1(4) . . . . ?
C101 P4 C95 C100 22.8(5) . . . . ?
C101 P4 C107 C108 75.4(4) . . . . ?
C101 P4 C107 C112 -105.5(4) . . . . ?
C101 C102 C103 C104 0.7(9) . . . . ?
C102 C101 C106 C105 -1.4(7) . . . . ?
C102 C103 C104 C105 -2.7(10) . . . . ?
C103 C104 C105 C106 2.6(9) . . . . ?
C104 C105 C106 C101 -0.5(8) . . . . ?
C106 C101 C102 C103 1.3(8) . . . . ?
C107 P4 C95 C96 94.1(4) . . . . ?
C107 P4 C95 C100 -85.0(5) . . . . ?
C107 P4 C101 C102 17.4(5) . . . . ?
C107 P4 C101 C106 -161.8(4) . . . . ?
C107 C108 C109 C110 1.4(9) . . . . ?
C108 C107 C112 C111 -0.2(8) . . . . ?
C108 C109 C110 C111 0.0(9) . . . . ?
C109 C110 C111 C112 -1.6(9) . . . . ?
C110 C111 C112 C107 1.6(8) . . . . ?
C112 C107 C108 C109 -1.3(8) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1557616'
_audit_update_record             
;
2017-09-25 deposited with the CCDC.
2017-09-29 downloaded from the CCDC.
;
_audit_creation_date             2017-09-25
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         
'C204 H186 Ag8 P8, 2(Cl O4), 2(C4 H10 O), 2(C H2 Cl2)'
_chemical_formula_sum            'C214 H210 Ag8 Cl6 O10 P8'
_chemical_formula_weight         4265.23
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   36.107(3)
_cell_length_b                   30.577(3)
_cell_length_c                   18.5765(16)
_cell_angle_alpha                90
_cell_angle_beta                 109.178(2)
_cell_angle_gamma                90
_cell_volume                     19371(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9887
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.845
_cell_measurement_theta_min      2.235
_shelx_estimated_absorpt_T_max   0.754
_shelx_estimated_absorpt_T_min   0.635
_exptl_absorpt_coefficient_mu    0.998
_exptl_absorpt_correction_T_max  0.7539
_exptl_absorpt_correction_T_min  0.6352
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.462
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             8688
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1127
_diffrn_reflns_av_unetI/netI     0.0434
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       43
_diffrn_reflns_limit_h_min       -43
_diffrn_reflns_limit_k_max       36
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            265544
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.250
_diffrn_reflns_theta_min         1.301
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                14687
_reflns_number_total             17573
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_refine_diff_density_max         1.870
_refine_diff_density_min         -1.245
_refine_diff_density_rms         0.140
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.132
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1084
_refine_ls_number_reflns         17573
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0677
_refine_ls_R_factor_gt           0.0539
_refine_ls_restrained_S_all      1.132
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0800P)²+142.8018P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1414
_refine_ls_wR_factor_ref         0.1638
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C5(H5), C15(H15), C25(H25)
2.b Secondary CH2 refined with riding coordinates:
 C6(H6A,H6B), C7(H7A,H7B), C8(H8A,H8B), C9(H9A,H9B), C10(H10A,H10B), C16(H16A,
 H16B), C17(H17A,H17B), C18(H18A,H18B), C19(H19A,H19B), C20(H20A,H20B),
 C26(H26A,H26B), C27(H27A,H27B), C28(H28A,H28B), C29(H29A,H29B), C30(H30A,H30B),
  C105(H10F,H10G), C106(H10H,H10I), C103(H10M,H10N)
2.c Me refined with riding coordinates:
 C104(H10C,H10D,H10E), C107(H10J,H10K,H10L)
2.d Aromatic/amide H refined with riding coordinates:
 C32(H32), C33(H33), C34(H34), C35(H35), C36(H36), C38(H38), C39(H39),
 C40(H40), C41(H41), C42(H42), C44(H44), C45(H45), C46(H46), C47(H47), C48(H48),
  C50(H50), C51(H51), C52(H52), C53(H53), C54(H54), C56(H56), C57(H57),
 C58(H58), C59(H59), C60(H60), C62(H62), C63(H63), C64(H64), C65(H65), C66(H66),
  C68(H68), C69(H69), C70(H70), C71(H71), C72(H72), C74(H74), C75(H75),
 C76(H76), C77(H77), C78(H78), C80(H80), C81(H81), C82(H82), C83(H83), C84(H84),
  C86(H86), C87(H87), C88(H88), C89(H89), C90(H90), C92(H92), C93(H93),
 C94(H94), C95(H95), C96(H96), C98(H98), C99(H99), C100(H100), C101(H101),
 C102(H102)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.50901(2) 0.28353(2) 0.17451(2) 0.02521(11) Uani 1 1 d . . . . .
Ag2 Ag 0.5000 0.19382(2) 0.2500 0.02997(14) Uani 1 2 d S T P . .
Ag3 Ag 0.57673(2) 0.25491(2) 0.32627(2) 0.02656(11) Uani 1 1 d . . . . .
Ag4 Ag 0.52024(2) 0.19405(2) 0.07412(2) 0.02782(11) Uani 1 1 d . . . . .
Ag5 Ag 0.5000 0.38382(2) 0.2500 0.02682(13) Uani 1 2 d S T P . .
P1 P 0.64863(4) 0.25316(4) 0.39723(7) 0.0229(3) Uani 1 1 d . . . . .
P2 P 0.50799(4) 0.11280(4) 0.04889(7) 0.0252(3) Uani 1 1 d . . . . .
P3 P 0.54295(4) 0.23431(4) -0.02159(8) 0.0287(3) Uani 1 1 d . . . . .
P4 P 0.49942(4) 0.43007(4) 0.13874(7) 0.0275(3) Uani 1 1 d . . . . .
Cl1 Cl 0.65365(6) 0.37867(10) -0.19216(12) 0.0861(8) Uani 1 1 d . . . . .
C1 C 0.55077(14) 0.32213(16) 0.2535(3) 0.0262(10) Uani 1 1 d . . . . .
C2 C 0.57360(14) 0.34466(15) 0.3029(3) 0.0263(10) Uani 1 1 d . . . . .
C3 C 0.59912(16) 0.37074(17) 0.3574(3) 0.0335(12) Uani 1 1 d . . . . .
C4 C 0.62009(19) 0.3950(2) 0.4052(4) 0.0460(15) Uani 1 1 d . . . . .
C5 C 0.64214(19) 0.4270(2) 0.4635(4) 0.0485(15) Uani 1 1 d . . . . .
H5 H 0.6229 0.4455 0.4780 0.058 Uiso 1 1 calc R . . . .
C6 C 0.6689(2) 0.4052(2) 0.5340(4) 0.0543(17) Uani 1 1 d . . . . .
H6A H 0.6877 0.3861 0.5204 0.065 Uiso 1 1 calc R . . . .
H6B H 0.6532 0.3869 0.5572 0.065 Uiso 1 1 calc R . . . .
C7 C 0.6912(2) 0.4397(3) 0.5911(4) 0.0582(18) Uani 1 1 d . . . . .
H7A H 0.6724 0.4563 0.6092 0.070 Uiso 1 1 calc R . . . .
H7B H 0.7099 0.4249 0.6357 0.070 Uiso 1 1 calc R . . . .
C8 C 0.7133(3) 0.4711(3) 0.5572(5) 0.074(2) Uani 1 1 d . . . . .
H8A H 0.7255 0.4940 0.5952 0.088 Uiso 1 1 calc R . . . .
H8B H 0.7347 0.4550 0.5461 0.088 Uiso 1 1 calc R . . . .
C9 C 0.6880(3) 0.4920(3) 0.4865(5) 0.071(2) Uani 1 1 d . . . . .
H9A H 0.7041 0.5104 0.4647 0.086 Uiso 1 1 calc R . . . .
H9B H 0.6685 0.5110 0.4983 0.086 Uiso 1 1 calc R . . . .
C10 C 0.6664(2) 0.4570(2) 0.4279(4) 0.0588(19) Uani 1 1 d . . . . .
H10A H 0.6857 0.4392 0.4132 0.071 Uiso 1 1 calc R . . . .
H10B H 0.6488 0.4714 0.3815 0.071 Uiso 1 1 calc R . . . .
C11 C 0.46747(14) 0.24521(16) 0.0944(3) 0.0257(10) Uani 1 1 d . . . . .
C12 C 0.44325(15) 0.22099(16) 0.0520(3) 0.0269(10) Uani 1 1 d . . . . .
C13 C 0.41520(15) 0.19343(17) 0.0042(3) 0.0299(11) Uani 1 1 d . . . . .
C14 C 0.39041(16) 0.17007(19) -0.0356(3) 0.0369(12) Uani 1 1 d . . . . .
C15 C 0.35856(16) 0.14234(18) -0.0848(4) 0.0385(13) Uani 1 1 d . . . . .
H15 H 0.3332 0.1559 -0.0859 0.046 Uiso 1 1 calc R . . . .
C16 C 0.35972(19) 0.0961(2) -0.0524(4) 0.0491(16) Uani 1 1 d . . . . .
H16A H 0.3583 0.0977 -0.0001 0.059 Uiso 1 1 calc R . . . .
H16B H 0.3847 0.0817 -0.0497 0.059 Uiso 1 1 calc R . . . .
C17 C 0.3251(2) 0.0693(2) -0.1033(5) 0.0570(19) Uani 1 1 d . . . . .
H17A H 0.3269 0.0390 -0.0835 0.068 Uiso 1 1 calc R . . . .
H17B H 0.3003 0.0821 -0.1016 0.068 Uiso 1 1 calc R . . . .
C18 C 0.3248(2) 0.0683(3) -0.1837(5) 0.068(2) Uani 1 1 d . . . . .
H18A H 0.3013 0.0521 -0.2152 0.081 Uiso 1 1 calc R . . . .
H18B H 0.3482 0.0523 -0.1859 0.081 Uiso 1 1 calc R . . . .
C19 C 0.3245(2) 0.1134(3) -0.2164(5) 0.068(2) Uani 1 1 d . . . . .
H19A H 0.2994 0.1280 -0.2207 0.082 Uiso 1 1 calc R . . . .
H19B H 0.3264 0.1110 -0.2682 0.082 Uiso 1 1 calc R . . . .
C20 C 0.3589(2) 0.1413(2) -0.1660(4) 0.0502(16) Uani 1 1 d . . . . .
H20A H 0.3841 0.1289 -0.1670 0.060 Uiso 1 1 calc R . . . .
H20B H 0.3567 0.1715 -0.1863 0.060 Uiso 1 1 calc R . . . .
C21 C 0.55185(16) 0.19532(16) 0.2243(3) 0.0324(12) Uani 1 1 d . . . . .
C22 C 0.58209(15) 0.19970(16) 0.2079(3) 0.0286(11) Uani 1 1 d . . . . .
C23 C 0.61693(17) 0.20299(19) 0.1925(3) 0.0378(13) Uani 1 1 d . . . . .
C24 C 0.6472(2) 0.2065(2) 0.1809(4) 0.0482(15) Uani 1 1 d . . . . .
C25 C 0.6856(2) 0.2113(3) 0.1695(5) 0.064(2) Uani 1 1 d . . . . .
H25 H 0.7046 0.2209 0.2195 0.076 Uiso 1 1 calc R . . . .
C26 C 0.6999(2) 0.1681(3) 0.1511(5) 0.069(2) Uani 1 1 d . . . . .
H26A H 0.6808 0.1562 0.1039 0.083 Uiso 1 1 calc R . . . .
H26B H 0.7020 0.1472 0.1930 0.083 Uiso 1 1 calc R . . . .
C27 C 0.7398(3) 0.1726(4) 0.1402(8) 0.108(4) Uani 1 1 d . . . . .
H27A H 0.7598 0.1799 0.1897 0.129 Uiso 1 1 calc R . . . .
H27B H 0.7472 0.1442 0.1230 0.129 Uiso 1 1 calc R . . . .
C28 C 0.7399(4) 0.2063(5) 0.0848(9) 0.139(6) Uani 1 1 d . . . . .
H28A H 0.7234 0.1963 0.0336 0.167 Uiso 1 1 calc R . . . .
H28B H 0.7669 0.2099 0.0839 0.167 Uiso 1 1 calc R . . . .
C29 C 0.7247(4) 0.2506(4) 0.1008(9) 0.112(4) Uani 1 1 d . . . . .
H29A H 0.7439 0.2638 0.1467 0.134 Uiso 1 1 calc R . . . .
H29B H 0.7218 0.2705 0.0572 0.134 Uiso 1 1 calc R . . . .
C30 C 0.6857(3) 0.2457(3) 0.1134(7) 0.096(4) Uani 1 1 d . . . . .
H30A H 0.6785 0.2739 0.1312 0.115 Uiso 1 1 calc R . . . .
H30B H 0.6654 0.2386 0.0641 0.115 Uiso 1 1 calc R . . . .
C31 C 0.66249(14) 0.25922(16) 0.5003(3) 0.0252(10) Uani 1 1 d . . . . .
C32 C 0.69298(15) 0.23591(17) 0.5514(3) 0.0300(11) Uani 1 1 d . . . . .
H32 H 0.7078 0.2159 0.5328 0.036 Uiso 1 1 calc R . . . .
C33 C 0.70190(17) 0.2417(2) 0.6293(3) 0.0390(13) Uani 1 1 d . . . . .
H33 H 0.7224 0.2251 0.6636 0.047 Uiso 1 1 calc R . . . .
C34 C 0.68166(19) 0.2710(2) 0.6573(3) 0.0451(14) Uani 1 1 d . . . . .
H34 H 0.6882 0.2750 0.7108 0.054 Uiso 1 1 calc R . . . .
C35 C 0.65157(19) 0.2949(2) 0.6075(4) 0.0460(15) Uani 1 1 d . . . . .
H35 H 0.6378 0.3157 0.6269 0.055 Uiso 1 1 calc R . . . .
C36 C 0.64134(17) 0.28868(18) 0.5298(3) 0.0347(12) Uani 1 1 d . . . . .
H36 H 0.6199 0.3044 0.4962 0.042 Uiso 1 1 calc R . . . .
C37 C 0.67723(14) 0.29583(16) 0.3706(3) 0.0260(10) Uani 1 1 d . . . . .
C38 C 0.70835(15) 0.31729(17) 0.4230(3) 0.0329(11) Uani 1 1 d . . . . .
H38 H 0.7157 0.3098 0.4755 0.040 Uiso 1 1 calc R . . . .
C39 C 0.72861(17) 0.34917(19) 0.3999(4) 0.0418(14) Uani 1 1 d . . . . .
H39 H 0.7500 0.3634 0.4365 0.050 Uiso 1 1 calc R . . . .
C40 C 0.71853(18) 0.3607(2) 0.3250(4) 0.0469(15) Uani 1 1 d . . . . .
H40 H 0.7326 0.3831 0.3096 0.056 Uiso 1 1 calc R . . . .
C41 C 0.6878(2) 0.3398(2) 0.2716(4) 0.0534(17) Uani 1 1 d . . . . .
H41 H 0.6812 0.3473 0.2193 0.064 Uiso 1 1 calc R . . . .
C42 C 0.66658(17) 0.30769(18) 0.2937(3) 0.0369(13) Uani 1 1 d . . . . .
H42 H 0.6450 0.2939 0.2569 0.044 Uiso 1 1 calc R . . . .
C43 C 0.67323(14) 0.20251(16) 0.3857(3) 0.0256(10) Uani 1 1 d . . . . .
C44 C 0.65249(16) 0.16333(17) 0.3812(3) 0.0343(12) Uani 1 1 d . . . . .
H44 H 0.6267 0.1636 0.3842 0.041 Uiso 1 1 calc R . . . .
C45 C 0.66969(19) 0.12446(19) 0.3723(4) 0.0452(15) Uani 1 1 d . . . . .
H45 H 0.6559 0.0978 0.3707 0.054 Uiso 1 1 calc R . . . .
C46 C 0.70673(19) 0.1237(2) 0.3659(4) 0.0473(15) Uani 1 1 d . . . . .
H46 H 0.7181 0.0967 0.3590 0.057 Uiso 1 1 calc R . . . .
C47 C 0.72701(17) 0.1620(2) 0.3694(4) 0.0442(14) Uani 1 1 d . . . . .
H47 H 0.7525 0.1617 0.3648 0.053 Uiso 1 1 calc R . . . .
C48 C 0.71010(16) 0.20122(18) 0.3797(3) 0.0344(12) Uani 1 1 d . . . . .
H48 H 0.7243 0.2277 0.3827 0.041 Uiso 1 1 calc R . . . .
C49 C 0.48316(15) 0.08387(16) 0.1056(3) 0.0273(10) Uani 1 1 d . . . . .
C50 C 0.45813(15) 0.10714(17) 0.1338(3) 0.0299(11) Uani 1 1 d . . . . .
H50 H 0.4548 0.1377 0.1243 0.036 Uiso 1 1 calc R . . . .
C51 C 0.43772(17) 0.0863(2) 0.1763(3) 0.0381(13) Uani 1 1 d . . . . .
H51 H 0.4208 0.1026 0.1960 0.046 Uiso 1 1 calc R . . . .
C52 C 0.44220(18) 0.0419(2) 0.1894(3) 0.0433(14) Uani 1 1 d . . . . .
H52 H 0.4282 0.0276 0.2179 0.052 Uiso 1 1 calc R . . . .
C53 C 0.46696(19) 0.01826(19) 0.1612(3) 0.0416(13) Uani 1 1 d . . . . .
H53 H 0.4700 -0.0123 0.1704 0.050 Uiso 1 1 calc R . . . .
C54 C 0.48739(17) 0.03887(17) 0.1197(3) 0.0341(12) Uani 1 1 d . . . . .
H54 H 0.5044 0.0224 0.1006 0.041 Uiso 1 1 calc R . . . .
C55 C 0.55466(15) 0.08372(16) 0.0695(3) 0.0286(11) Uani 1 1 d . . . . .
C56 C 0.58405(17) 0.09288(17) 0.1376(3) 0.0368(13) Uani 1 1 d . . . . .
H56 H 0.5791 0.1129 0.1725 0.044 Uiso 1 1 calc R . . . .
C57 C 0.62063(18) 0.0731(2) 0.1553(4) 0.0489(16) Uani 1 1 d . . . . .
H57 H 0.6405 0.0794 0.2023 0.059 Uiso 1 1 calc R . . . .
C58 C 0.62812(19) 0.0443(2) 0.1047(4) 0.0499(16) Uani 1 1 d . . . . .
H58 H 0.6531 0.0308 0.1170 0.060 Uiso 1 1 calc R . . . .
C59 C 0.59941(19) 0.0350(2) 0.0362(4) 0.0467(15) Uani 1 1 d . . . . .
H59 H 0.6047 0.0153 0.0012 0.056 Uiso 1 1 calc R . . . .
C60 C 0.56261(17) 0.05460(18) 0.0186(3) 0.0354(12) Uani 1 1 d . . . . .
H60 H 0.5428 0.0481 -0.0283 0.042 Uiso 1 1 calc R . . . .
C61 C 0.48125(15) 0.09550(16) -0.0491(3) 0.0277(10) Uani 1 1 d . . . . .
C62 C 0.45635(15) 0.05979(17) -0.0669(3) 0.0313(11) Uani 1 1 d . . . . .
H62 H 0.4514 0.0436 -0.0274 0.038 Uiso 1 1 calc R . . . .
C63 C 0.43838(16) 0.04744(19) -0.1432(3) 0.0376(13) Uani 1 1 d . . . . .
H63 H 0.4210 0.0232 -0.1550 0.045 Uiso 1 1 calc R . . . .
C64 C 0.44565(19) 0.0699(2) -0.2005(3) 0.0433(14) Uani 1 1 d . . . . .
H64 H 0.4335 0.0613 -0.2521 0.052 Uiso 1 1 calc R . . . .
C65 C 0.4709(2) 0.1054(2) -0.1831(3) 0.0485(16) Uani 1 1 d . . . . .
H65 H 0.4760 0.1210 -0.2230 0.058 Uiso 1 1 calc R . . . .
C66 C 0.48873(18) 0.1183(2) -0.1080(3) 0.0404(13) Uani 1 1 d . . . . .
H66 H 0.5060 0.1427 -0.0967 0.049 Uiso 1 1 calc R . . . .
C67 C 0.50083(16) 0.25577(18) -0.0985(3) 0.0325(11) Uani 1 1 d . . . . .
C68 C 0.5019(2) 0.2934(2) -0.1403(3) 0.0427(14) Uani 1 1 d . . . . .
H68 H 0.5257 0.3092 -0.1302 0.051 Uiso 1 1 calc R . . . .
C69 C 0.4682(2) 0.3078(2) -0.1966(4) 0.0491(16) Uani 1 1 d . . . . .
H69 H 0.4694 0.3330 -0.2258 0.059 Uiso 1 1 calc R . . . .
C70 C 0.4332(2) 0.2859(2) -0.2106(4) 0.0489(16) Uani 1 1 d . . . . .
H70 H 0.4102 0.2962 -0.2488 0.059 Uiso 1 1 calc R . . . .
C71 C 0.43128(19) 0.2491(2) -0.1692(4) 0.0441(14) Uani 1 1 d . . . . .
H71 H 0.4071 0.2340 -0.1785 0.053 Uiso 1 1 calc R . . . .
C72 C 0.46515(17) 0.23402(19) -0.1134(3) 0.0369(12) Uani 1 1 d . . . . .
H72 H 0.4639 0.2085 -0.0851 0.044 Uiso 1 1 calc R . . . .
C73 C 0.57708(16) 0.28035(17) 0.0058(3) 0.0313(11) Uani 1 1 d . . . . .
C74 C 0.60054(19) 0.2934(2) -0.0360(4) 0.0443(14) Uani 1 1 d . . . . .
H74 H 0.5997 0.2776 -0.0805 0.053 Uiso 1 1 calc R . . . .
C75 C 0.6253(2) 0.3292(2) -0.0138(4) 0.0530(17) Uani 1 1 d . . . . .
H75 H 0.6417 0.3376 -0.0423 0.064 Uiso 1 1 calc R . . . .
C76 C 0.6258(2) 0.3524(2) 0.0495(4) 0.0498(16) Uani 1 1 d . . . . .
H76 H 0.6420 0.3775 0.0639 0.060 Uiso 1 1 calc R . . . .
C77 C 0.60293(18) 0.33976(19) 0.0928(4) 0.0451(15) Uani 1 1 d . . . . .
H77 H 0.6039 0.3556 0.1374 0.054 Uiso 1 1 calc R . . . .
C78 C 0.57832(17) 0.30340(19) 0.0701(3) 0.0367(12) Uani 1 1 d . . . . .
H78 H 0.5624 0.2946 0.0993 0.044 Uiso 1 1 calc R . . . .
C79 C 0.56844(17) 0.19787(17) -0.0683(3) 0.0325(11) Uani 1 1 d . . . . .
C80 C 0.59369(18) 0.16749(19) -0.0232(3) 0.0394(13) Uani 1 1 d . . . . .
H80 H 0.5963 0.1653 0.0292 0.047 Uiso 1 1 calc R . . . .
C81 C 0.6154(2) 0.1400(2) -0.0534(4) 0.0536(17) Uani 1 1 d . . . . .
H81 H 0.6327 0.1192 -0.0218 0.064 Uiso 1 1 calc R . . . .
C82 C 0.6118(2) 0.1431(2) -0.1291(4) 0.0573(18) Uani 1 1 d . . . . .
H82 H 0.6269 0.1246 -0.1498 0.069 Uiso 1 1 calc R . . . .
C83 C 0.5859(2) 0.1732(2) -0.1753(4) 0.0559(18) Uani 1 1 d . . . . .
H83 H 0.5833 0.1751 -0.2278 0.067 Uiso 1 1 calc R . . . .
C84 C 0.5641(2) 0.2003(2) -0.1460(4) 0.0455(15) Uani 1 1 d . . . . .
H84 H 0.5461 0.2205 -0.1781 0.055 Uiso 1 1 calc R . . . .
C85 C 0.48193(15) 0.48565(17) 0.1432(3) 0.0300(11) Uani 1 1 d . . . . .
C86 C 0.50481(17) 0.52263(18) 0.1467(3) 0.0347(12) Uani 1 1 d . . . . .
H86 H 0.5310 0.5197 0.1469 0.042 Uiso 1 1 calc R . . . .
C87 C 0.4893(2) 0.56364(19) 0.1497(4) 0.0480(15) Uani 1 1 d . . . . .
H87 H 0.5050 0.5887 0.1507 0.058 Uiso 1 1 calc R . . . .
C88 C 0.4519(2) 0.5691(2) 0.1513(4) 0.0470(15) Uani 1 1 d . . . . .
H88 H 0.4418 0.5976 0.1537 0.056 Uiso 1 1 calc R . . . .
C89 C 0.42902(19) 0.5324(2) 0.1494(4) 0.0441(14) Uani 1 1 d . . . . .
H89 H 0.4031 0.5357 0.1508 0.053 Uiso 1 1 calc R . . . .
C90 C 0.44390(17) 0.49109(19) 0.1454(3) 0.0374(12) Uani 1 1 d . . . . .
H90 H 0.4280 0.4661 0.1441 0.045 Uiso 1 1 calc R . . . .
C91 C 0.54830(16) 0.43856(16) 0.1317(3) 0.0294(11) Uani 1 1 d . . . . .
C92 C 0.55491(17) 0.44510(18) 0.0634(3) 0.0368(12) Uani 1 1 d . . . . .
H92 H 0.5337 0.4434 0.0168 0.044 Uiso 1 1 calc R . . . .
C93 C 0.59232(18) 0.45413(19) 0.0625(4) 0.0414(14) Uani 1 1 d . . . . .
H93 H 0.5967 0.4585 0.0153 0.050 Uiso 1 1 calc R . . . .
C94 C 0.62356(18) 0.4569(2) 0.1302(4) 0.0428(14) Uani 1 1 d . . . . .
H94 H 0.6491 0.4640 0.1295 0.051 Uiso 1 1 calc R . . . .
C95 C 0.61721(18) 0.4492(2) 0.1984(4) 0.0458(15) Uani 1 1 d . . . . .
H95 H 0.6386 0.4504 0.2448 0.055 Uiso 1 1 calc R . . . .
C96 C 0.58021(18) 0.43994(19) 0.1997(3) 0.0399(13) Uani 1 1 d . . . . .
H96 H 0.5762 0.4344 0.2470 0.048 Uiso 1 1 calc R . . . .
C97 C 0.46988(15) 0.41116(16) 0.0449(3) 0.0270(10) Uani 1 1 d . . . . .
C98 C 0.44816(16) 0.43898(18) -0.0130(3) 0.0351(12) Uani 1 1 d . . . . .
H98 H 0.4488 0.4696 -0.0045 0.042 Uiso 1 1 calc R . . . .
C99 C 0.42577(17) 0.4222(2) -0.0827(3) 0.0383(13) Uani 1 1 d . . . . .
H99 H 0.4103 0.4413 -0.1212 0.046 Uiso 1 1 calc R . . . .
C100 C 0.42555(18) 0.3775(2) -0.0972(3) 0.0410(13) Uani 1 1 d . . . . .
H100 H 0.4107 0.3662 -0.1458 0.049 Uiso 1 1 calc R . . . .
C101 C 0.44712(19) 0.3500(2) -0.0402(3) 0.0417(13) Uani 1 1 d . . . . .
H101 H 0.4470 0.3195 -0.0497 0.050 Uiso 1 1 calc R . . . .
C102 C 0.46889(18) 0.36612(18) 0.0304(3) 0.0376(13) Uani 1 1 d . . . . .
H102 H 0.4833 0.3466 0.0693 0.045 Uiso 1 1 calc R . . . .
O1 O 0.6146(2) 0.3782(3) -0.2012(5) 0.117(3) Uani 1 1 d . . . . .
O2 O 0.6788(2) 0.3944(3) -0.1237(4) 0.115(3) Uani 1 1 d . . . . .
O3 O 0.6666(3) 0.3812(4) -0.2527(5) 0.135(4) Uani 1 1 d . . . . .
O4 O 0.6599(3) 0.3266(4) -0.1781(9) 0.180(5) Uani 1 1 d . . . . .
C104 C 0.3363(4) 0.0113(4) -0.3836(7) 0.109(4) Uiso 1 1 d . . . . .
H10C H 0.3504 -0.0090 -0.4061 0.163 Uiso 1 1 calc R . . . .
H10D H 0.3551 0.0304 -0.3470 0.163 Uiso 1 1 calc R . . . .
H10E H 0.3213 -0.0052 -0.3574 0.163 Uiso 1 1 calc R . . . .
C105 C 0.3114(4) 0.0360(4) -0.4394(7) 0.101(3) Uiso 1 1 d . . . . .
H10F H 0.2925 0.0168 -0.4767 0.121 Uiso 1 1 calc R . . . .
H10G H 0.3264 0.0526 -0.4664 0.121 Uiso 1 1 calc R . . . .
O5 O 0.2909(3) 0.0656(3) -0.4067(5) 0.113(3) Uiso 1 1 d . . . . .
C106 C 0.2638(4) 0.0939(4) -0.4617(7) 0.107(4) Uiso 1 1 d . . . . .
H10H H 0.2467 0.0761 -0.5042 0.128 Uiso 1 1 calc R . . . .
H10I H 0.2787 0.1145 -0.4830 0.128 Uiso 1 1 calc R . . . .
C107 C 0.2393(6) 0.1188(6) -0.4256(11) 0.175(7) Uiso 1 1 d . . . . .
H10J H 0.2212 0.1378 -0.4637 0.262 Uiso 1 1 calc R . . . .
H10K H 0.2243 0.0984 -0.4053 0.262 Uiso 1 1 calc R . . . .
H10L H 0.2562 0.1368 -0.3841 0.262 Uiso 1 1 calc R . . . .
C103 C 0.7259(4) 0.5344(4) 0.2986(6) 0.099(3) Uani 1 1 d . . . . .
H10M H 0.7241 0.5433 0.3486 0.119 Uiso 1 1 calc R . . . .
H10N H 0.7036 0.5480 0.2584 0.119 Uiso 1 1 calc R . . . .
Cl2 Cl 0.76882(10) 0.55355(13) 0.2906(3) 0.1557(19) Uani 1 1 d . . . . .
Cl3 Cl 0.72207(10) 0.48066(12) 0.2907(4) 0.185(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag1 3.0802(8) 2_655 ?
Ag1 Ag2 3.1457(6) . ?
Ag1 Ag3 3.2125(6) 2_655 ?
Ag1 Ag3 3.1881(5) . ?
Ag1 C1 2.090(5) . ?
Ag1 C11 2.090(5) . ?
Ag2 Ag1 3.1457(6) 2_655 ?
Ag2 Ag3 3.2546(5) . ?
Ag2 Ag3 3.2546(5) 2_655 ?
Ag2 C21 2.079(6) . ?
Ag2 C21 2.079(6) 2_655 ?
Ag3 Ag1 3.2125(6) 2_655 ?
Ag3 P1 2.4964(13) . ?
Ag3 C1 2.470(5) . ?
Ag3 C11 2.520(5) 2_655 ?
Ag3 C21 2.568(5) . ?
Ag4 P2 2.5399(13) . ?
Ag4 P3 2.5113(14) . ?
Ag4 C11 2.587(5) . ?
Ag4 C21 2.645(5) . ?
Ag5 P4 2.4987(13) 2_655 ?
Ag5 P4 2.4987(13) . ?
Ag5 C1 2.616(5) . ?
Ag5 C1 2.616(5) 2_655 ?
P1 C31 1.822(5) . ?
P1 C37 1.830(5) . ?
P1 C43 1.832(5) . ?
P2 C49 1.821(5) . ?
P2 C55 1.831(5) . ?
P2 C61 1.837(5) . ?
P3 C67 1.832(6) . ?
P3 C73 1.830(6) . ?
P3 C79 1.835(6) . ?
P4 C85 1.825(5) . ?
P4 C91 1.831(5) . ?
P4 C97 1.813(5) . ?
Cl1 O1 1.365(7) . ?
Cl1 O2 1.383(7) . ?
Cl1 O3 1.355(8) . ?
Cl1 O4 1.618(12) . ?
C1 C2 1.224(7) . ?
C2 C3 1.378(7) . ?
C3 C4 1.211(8) . ?
C4 C5 1.483(9) . ?
C5 H5 1.0000 . ?
C5 C6 1.504(10) . ?
C5 C10 1.558(9) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C6 C7 1.523(9) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C7 C8 1.513(11) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C8 C9 1.478(12) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C10 1.541(10) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 Ag3 2.520(5) 2_655 ?
C11 C12 1.218(7) . ?
C12 C13 1.390(7) . ?
C13 C14 1.193(8) . ?
C14 C15 1.479(8) . ?
C15 H15 1.0000 . ?
C15 C16 1.532(9) . ?
C15 C20 1.512(9) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C17 1.533(9) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C17 C18 1.489(12) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C18 C19 1.506(12) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C20 1.546(9) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.234(8) . ?
C22 C23 1.382(8) . ?
C23 C24 1.186(9) . ?
C24 C25 1.477(10) . ?
C25 H25 1.0000 . ?
C25 C26 1.499(11) . ?
C25 C30 1.480(12) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C26 C27 1.525(12) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C28 1.456(16) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C28 C29 1.528(16) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C29 C30 1.511(13) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.391(7) . ?
C31 C36 1.404(7) . ?
C32 H32 0.9500 . ?
C32 C33 1.387(8) . ?
C33 H33 0.9500 . ?
C33 C34 1.363(9) . ?
C34 H34 0.9500 . ?
C34 C35 1.381(9) . ?
C35 H35 0.9500 . ?
C35 C36 1.380(8) . ?
C36 H36 0.9500 . ?
C37 C38 1.386(7) . ?
C37 C42 1.400(8) . ?
C38 H38 0.9500 . ?
C38 C39 1.370(8) . ?
C39 H39 0.9500 . ?
C39 C40 1.365(9) . ?
C40 H40 0.9500 . ?
C40 C41 1.379(10) . ?
C41 H41 0.9500 . ?
C41 C42 1.388(8) . ?
C42 H42 0.9500 . ?
C43 C44 1.401(7) . ?
C43 C48 1.372(7) . ?
C44 H44 0.9500 . ?
C44 C45 1.376(8) . ?
C45 H45 0.9500 . ?
C45 C46 1.382(9) . ?
C46 H46 0.9500 . ?
C46 C47 1.371(9) . ?
C47 H47 0.9500 . ?
C47 C48 1.387(8) . ?
C48 H48 0.9500 . ?
C49 C50 1.382(7) . ?
C49 C54 1.400(7) . ?
C50 H50 0.9500 . ?
C50 C51 1.397(8) . ?
C51 H51 0.9500 . ?
C51 C52 1.379(9) . ?
C52 H52 0.9500 . ?
C52 C53 1.380(9) . ?
C53 H53 0.9500 . ?
C53 C54 1.382(8) . ?
C54 H54 0.9500 . ?
C55 C56 1.387(8) . ?
C55 C60 1.395(7) . ?
C56 H56 0.9500 . ?
C56 C57 1.391(8) . ?
C57 H57 0.9500 . ?
C57 C58 1.378(10) . ?
C58 H58 0.9500 . ?
C58 C59 1.381(10) . ?
C59 H59 0.9500 . ?
C59 C60 1.395(8) . ?
C60 H60 0.9500 . ?
C61 C62 1.383(7) . ?
C61 C66 1.397(8) . ?
C62 H62 0.9500 . ?
C62 C63 1.402(8) . ?
C63 H63 0.9500 . ?
C63 C64 1.364(9) . ?
C64 H64 0.9500 . ?
C64 C65 1.384(10) . ?
C65 H65 0.9500 . ?
C65 C66 1.389(9) . ?
C66 H66 0.9500 . ?
C67 C68 1.396(8) . ?
C67 C72 1.394(8) . ?
C68 H68 0.9500 . ?
C68 C69 1.390(9) . ?
C69 H69 0.9500 . ?
C69 C70 1.380(10) . ?
C70 H70 0.9500 . ?
C70 C71 1.378(10) . ?
C71 H71 0.9500 . ?
C71 C72 1.395(9) . ?
C72 H72 0.9500 . ?
C73 C74 1.383(8) . ?
C73 C78 1.375(8) . ?
C74 H74 0.9500 . ?
C74 C75 1.389(9) . ?
C75 H75 0.9500 . ?
C75 C76 1.367(10) . ?
C76 H76 0.9500 . ?
C76 C77 1.384(10) . ?
C77 H77 0.9500 . ?
C77 C78 1.399(8) . ?
C78 H78 0.9500 . ?
C79 C80 1.377(8) . ?
C79 C84 1.401(8) . ?
C80 H80 0.9500 . ?
C80 C81 1.386(9) . ?
C81 H81 0.9500 . ?
C81 C82 1.371(10) . ?
C82 H82 0.9500 . ?
C82 C83 1.390(10) . ?
C83 H83 0.9500 . ?
C83 C84 1.375(9) . ?
C84 H84 0.9500 . ?
C85 C86 1.389(8) . ?
C85 C90 1.396(8) . ?
C86 H86 0.9500 . ?
C86 C87 1.382(8) . ?
C87 H87 0.9500 . ?
C87 C88 1.373(10) . ?
C88 H88 0.9500 . ?
C88 C89 1.386(10) . ?
C89 H89 0.9500 . ?
C89 C90 1.385(8) . ?
C90 H90 0.9500 . ?
C91 C92 1.380(8) . ?
C91 C96 1.404(8) . ?
C92 H92 0.9500 . ?
C92 C93 1.384(8) . ?
C93 H93 0.9500 . ?
C93 C94 1.389(9) . ?
C94 H94 0.9500 . ?
C94 C95 1.380(9) . ?
C95 H95 0.9500 . ?
C95 C96 1.374(9) . ?
C96 H96 0.9500 . ?
C97 C98 1.393(7) . ?
C97 C102 1.402(8) . ?
C98 H98 0.9500 . ?
C98 C99 1.381(8) . ?
C99 H99 0.9500 . ?
C99 C100 1.391(9) . ?
C100 H100 0.9500 . ?
C100 C101 1.376(9) . ?
C101 H101 0.9500 . ?
C101 C102 1.380(8) . ?
C102 H102 0.9500 . ?
C104 H10C 0.9800 . ?
C104 H10D 0.9800 . ?
C104 H10E 0.9800 . ?
C104 C105 1.354(15) . ?
C105 H10F 0.9900 . ?
C105 H10G 0.9900 . ?
C105 O5 1.426(13) . ?
O5 C106 1.445(14) . ?
C106 H10H 0.9900 . ?
C106 H10I 0.9900 . ?
C106 C107 1.48(2) . ?
C107 H10J 0.9800 . ?
C107 H10K 0.9800 . ?
C107 H10L 0.9800 . ?
C103 H10M 0.9900 . ?
C103 H10N 0.9900 . ?
C103 Cl2 1.709(13) . ?
C103 Cl3 1.653(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 Ag1 Ag2 60.688(8) 2_655 . ?
Ag1 Ag1 Ag3 60.838(13) 2_655 2_655 ?
Ag1 Ag1 Ag3 61.633(14) 2_655 . ?
Ag2 Ag1 Ag3 61.567(10) . 2_655 ?
Ag2 Ag1 Ag3 61.838(10) . . ?
Ag3 Ag1 Ag3 112.786(15) . 2_655 ?
C1 Ag1 Ag1 71.34(14) . 2_655 ?
C1 Ag1 Ag2 109.63(13) . . ?
C1 Ag1 Ag3 50.74(13) . . ?
C1 Ag1 Ag3 128.98(14) . 2_655 ?
C1 Ag1 C11 179.3(2) . . ?
C11 Ag1 Ag1 109.36(14) . 2_655 ?
C11 Ag1 Ag2 70.95(13) . . ?
C11 Ag1 Ag3 129.65(13) . . ?
C11 Ag1 Ag3 51.63(14) . 2_655 ?
Ag1 Ag2 Ag1 58.626(17) . 2_655 ?
Ag1 Ag2 Ag3 59.723(12) 2_655 2_655 ?
Ag1 Ag2 Ag3 59.722(12) . . ?
Ag1 Ag2 Ag3 60.226(13) . 2_655 ?
Ag1 Ag2 Ag3 60.227(12) 2_655 . ?
Ag3 Ag2 Ag3 109.96(2) 2_655 . ?
C21 Ag2 Ag1 69.26(14) . . ?
C21 Ag2 Ag1 69.26(14) 2_655 2_655 ?
C21 Ag2 Ag1 108.41(14) 2_655 . ?
C21 Ag2 Ag1 108.41(14) . 2_655 ?
C21 Ag2 Ag3 52.06(14) . . ?
C21 Ag2 Ag3 126.13(14) . 2_655 ?
C21 Ag2 Ag3 126.13(15) 2_655 . ?
C21 Ag2 Ag3 52.06(14) 2_655 2_655 ?
C21 Ag2 C21 177.5(3) . 2_655 ?
Ag1 Ag3 Ag1 57.530(14) . 2_655 ?
Ag1 Ag3 Ag2 58.441(12) . . ?
Ag1 Ag3 Ag2 58.206(12) 2_655 . ?
P1 Ag3 Ag1 147.31(3) . 2_655 ?
P1 Ag3 Ag1 146.65(3) . . ?
P1 Ag3 Ag2 143.75(3) . . ?
P1 Ag3 C11 115.92(12) . 2_655 ?
P1 Ag3 C21 115.17(13) . . ?
C1 Ag3 Ag1 65.09(12) . 2_655 ?
C1 Ag3 Ag1 40.93(12) . . ?
C1 Ag3 Ag2 97.10(12) . . ?
C1 Ag3 P1 116.66(12) . . ?
C1 Ag3 C11 102.62(16) . 2_655 ?
C1 Ag3 C21 102.07(16) . . ?
C11 Ag3 Ag1 40.56(11) 2_655 2_655 ?
C11 Ag3 Ag1 95.75(11) 2_655 . ?
C11 Ag3 Ag2 64.85(11) 2_655 . ?
C11 Ag3 C21 102.26(17) 2_655 . ?
C21 Ag3 Ag1 64.01(12) . . ?
C21 Ag3 Ag1 94.98(13) . 2_655 ?
C21 Ag3 Ag2 39.67(13) . . ?
P2 Ag4 C11 121.76(11) . . ?
P2 Ag4 C21 101.40(11) . . ?
P3 Ag4 P2 115.24(4) . . ?
P3 Ag4 C11 103.53(11) . . ?
P3 Ag4 C21 127.70(13) . . ?
C11 Ag4 C21 85.45(16) . . ?
P4 Ag5 P4 111.06(6) 2_655 . ?
P4 Ag5 C1 104.13(11) 2_655 2_655 ?
P4 Ag5 C1 124.90(11) 2_655 . ?
P4 Ag5 C1 124.90(11) . 2_655 ?
P4 Ag5 C1 104.12(11) . . ?
C1 Ag5 C1 87.7(2) 2_655 . ?
C31 P1 Ag3 115.57(16) . . ?
C31 P1 C37 103.1(2) . . ?
C31 P1 C43 103.5(2) . . ?
C37 P1 Ag3 115.04(16) . . ?
C37 P1 C43 103.5(2) . . ?
C43 P1 Ag3 114.59(16) . . ?
C49 P2 Ag4 117.23(16) . . ?
C49 P2 C55 103.7(2) . . ?
C49 P2 C61 103.6(2) . . ?
C55 P2 Ag4 110.12(17) . . ?
C55 P2 C61 102.4(2) . . ?
C61 P2 Ag4 117.89(17) . . ?
C67 P3 Ag4 110.31(19) . . ?
C67 P3 C79 105.4(3) . . ?
C73 P3 Ag4 121.78(18) . . ?
C73 P3 C67 104.6(2) . . ?
C73 P3 C79 101.7(2) . . ?
C79 P3 Ag4 111.62(18) . . ?
C85 P4 Ag5 113.46(17) . . ?
C85 P4 C91 103.2(2) . . ?
C91 P4 Ag5 113.16(17) . . ?
C97 P4 Ag5 117.19(17) . . ?
C97 P4 C85 103.8(2) . . ?
C97 P4 C91 104.7(2) . . ?
O1 Cl1 O2 117.1(5) . . ?
O1 Cl1 O4 95.3(6) . . ?
O2 Cl1 O4 100.3(7) . . ?
O3 Cl1 O1 121.5(6) . . ?
O3 Cl1 O2 116.3(5) . . ?
O3 Cl1 O4 97.0(7) . . ?
Ag1 C1 Ag3 88.33(17) . . ?
Ag1 C1 Ag5 92.96(18) . . ?
Ag3 C1 Ag5 138.7(2) . . ?
C2 C1 Ag1 175.6(4) . . ?
C2 C1 Ag3 91.0(3) . . ?
C2 C1 Ag5 84.7(3) . . ?
C1 C2 C3 178.8(6) . . ?
C4 C3 C2 176.9(6) . . ?
C3 C4 C5 174.2(7) . . ?
C4 C5 H5 108.6 . . ?
C4 C5 C6 112.4(6) . . ?
C4 C5 C10 108.8(6) . . ?
C6 C5 H5 108.6 . . ?
C6 C5 C10 109.9(6) . . ?
C10 C5 H5 108.6 . . ?
C5 C6 H6A 109.7 . . ?
C5 C6 H6B 109.7 . . ?
C5 C6 C7 110.0(6) . . ?
H6A C6 H6B 108.2 . . ?
C7 C6 H6A 109.7 . . ?
C7 C6 H6B 109.7 . . ?
C6 C7 H7A 109.1 . . ?
C6 C7 H7B 109.1 . . ?
H7A C7 H7B 107.9 . . ?
C8 C7 C6 112.3(6) . . ?
C8 C7 H7A 109.1 . . ?
C8 C7 H7B 109.1 . . ?
C7 C8 H8A 109.1 . . ?
C7 C8 H8B 109.1 . . ?
H8A C8 H8B 107.8 . . ?
C9 C8 C7 112.7(7) . . ?
C9 C8 H8A 109.1 . . ?
C9 C8 H8B 109.1 . . ?
C8 C9 H9A 109.6 . . ?
C8 C9 H9B 109.6 . . ?
C8 C9 C10 110.5(7) . . ?
H9A C9 H9B 108.1 . . ?
C10 C9 H9A 109.6 . . ?
C10 C9 H9B 109.6 . . ?
C5 C10 H10A 109.8 . . ?
C5 C10 H10B 109.8 . . ?
C9 C10 C5 109.4(6) . . ?
C9 C10 H10A 109.8 . . ?
C9 C10 H10B 109.8 . . ?
H10A C10 H10B 108.2 . . ?
Ag1 C11 Ag3 87.82(17) . 2_655 ?
Ag1 C11 Ag4 92.99(18) . . ?
Ag3 C11 Ag4 142.6(2) 2_655 . ?
C12 C11 Ag1 175.4(4) . . ?
C12 C11 Ag3 89.6(4) . 2_655 ?
C12 C11 Ag4 86.8(3) . . ?
C11 C12 C13 179.1(6) . . ?
C14 C13 C12 178.1(6) . . ?
C13 C14 C15 177.9(6) . . ?
C14 C15 H15 107.2 . . ?
C14 C15 C16 111.7(5) . . ?
C14 C15 C20 111.6(5) . . ?
C16 C15 H15 107.2 . . ?
C20 C15 H15 107.2 . . ?
C20 C15 C16 111.4(5) . . ?
C15 C16 H16A 109.7 . . ?
C15 C16 H16B 109.7 . . ?
C15 C16 C17 109.9(6) . . ?
H16A C16 H16B 108.2 . . ?
C17 C16 H16A 109.7 . . ?
C17 C16 H16B 109.7 . . ?
C16 C17 H17A 109.3 . . ?
C16 C17 H17B 109.3 . . ?
H17A C17 H17B 108.0 . . ?
C18 C17 C16 111.5(6) . . ?
C18 C17 H17A 109.3 . . ?
C18 C17 H17B 109.3 . . ?
C17 C18 H18A 109.1 . . ?
C17 C18 H18B 109.1 . . ?
C17 C18 C19 112.5(6) . . ?
H18A C18 H18B 107.8 . . ?
C19 C18 H18A 109.1 . . ?
C19 C18 H18B 109.1 . . ?
C18 C19 H19A 109.3 . . ?
C18 C19 H19B 109.3 . . ?
C18 C19 C20 111.4(7) . . ?
H19A C19 H19B 108.0 . . ?
C20 C19 H19A 109.3 . . ?
C20 C19 H19B 109.3 . . ?
C15 C20 C19 110.3(6) . . ?
C15 C20 H20A 109.6 . . ?
C15 C20 H20B 109.6 . . ?
C19 C20 H20A 109.6 . . ?
C19 C20 H20B 109.6 . . ?
H20A C20 H20B 108.1 . . ?
Ag2 C21 Ag3 88.26(19) . . ?
Ag2 C21 Ag4 97.6(2) . . ?
Ag3 C21 Ag4 135.5(2) . . ?
C22 C21 Ag2 174.9(4) . . ?
C22 C21 Ag3 88.9(3) . . ?
C22 C21 Ag4 81.4(4) . . ?
C21 C22 C23 176.9(6) . . ?
C24 C23 C22 178.4(7) . . ?
C23 C24 C25 177.7(8) . . ?
C24 C25 H25 106.6 . . ?
C24 C25 C26 110.8(7) . . ?
C24 C25 C30 113.0(7) . . ?
C26 C25 H25 106.6 . . ?
C30 C25 H25 106.6 . . ?
C30 C25 C26 112.6(7) . . ?
C25 C26 H26A 109.4 . . ?
C25 C26 H26B 109.4 . . ?
C25 C26 C27 111.3(8) . . ?
H26A C26 H26B 108.0 . . ?
C27 C26 H26A 109.4 . . ?
C27 C26 H26B 109.4 . . ?
C26 C27 H27A 109.2 . . ?
C26 C27 H27B 109.2 . . ?
H27A C27 H27B 107.9 . . ?
C28 C27 C26 112.2(10) . . ?
C28 C27 H27A 109.2 . . ?
C28 C27 H27B 109.2 . . ?
C27 C28 H28A 108.8 . . ?
C27 C28 H28B 108.8 . . ?
C27 C28 C29 114.0(10) . . ?
H28A C28 H28B 107.7 . . ?
C29 C28 H28A 108.8 . . ?
C29 C28 H28B 108.8 . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 108.1 . . ?
C30 C29 C28 110.7(9) . . ?
C30 C29 H29A 109.5 . . ?
C30 C29 H29B 109.5 . . ?
C25 C30 C29 113.5(9) . . ?
C25 C30 H30A 108.9 . . ?
C25 C30 H30B 108.9 . . ?
C29 C30 H30A 108.9 . . ?
C29 C30 H30B 108.9 . . ?
H30A C30 H30B 107.7 . . ?
C32 C31 P1 123.2(4) . . ?
C32 C31 C36 118.2(5) . . ?
C36 C31 P1 118.6(4) . . ?
C31 C32 H32 119.8 . . ?
C33 C32 C31 120.5(5) . . ?
C33 C32 H32 119.8 . . ?
C32 C33 H33 119.6 . . ?
C34 C33 C32 120.9(6) . . ?
C34 C33 H33 119.6 . . ?
C33 C34 H34 120.2 . . ?
C33 C34 C35 119.5(6) . . ?
C35 C34 H34 120.2 . . ?
C34 C35 H35 119.7 . . ?
C36 C35 C34 120.7(6) . . ?
C36 C35 H35 119.7 . . ?
C31 C36 H36 119.9 . . ?
C35 C36 C31 120.2(5) . . ?
C35 C36 H36 119.9 . . ?
C38 C37 P1 123.1(4) . . ?
C38 C37 C42 118.8(5) . . ?
C42 C37 P1 118.1(4) . . ?
C37 C38 H38 119.7 . . ?
C39 C38 C37 120.6(5) . . ?
C39 C38 H38 119.7 . . ?
C38 C39 H39 119.6 . . ?
C40 C39 C38 120.9(6) . . ?
C40 C39 H39 119.6 . . ?
C39 C40 H40 120.2 . . ?
C39 C40 C41 119.7(6) . . ?
C41 C40 H40 120.2 . . ?
C40 C41 H41 119.7 . . ?
C40 C41 C42 120.5(6) . . ?
C42 C41 H41 119.7 . . ?
C37 C42 H42 120.3 . . ?
C41 C42 C37 119.5(5) . . ?
C41 C42 H42 120.3 . . ?
C44 C43 P1 117.4(4) . . ?
C48 C43 P1 123.6(4) . . ?
C48 C43 C44 119.0(5) . . ?
C43 C44 H44 120.2 . . ?
C45 C44 C43 119.5(5) . . ?
C45 C44 H44 120.2 . . ?
C44 C45 H45 119.6 . . ?
C44 C45 C46 120.8(6) . . ?
C46 C45 H45 119.6 . . ?
C45 C46 H46 120.0 . . ?
C47 C46 C45 120.0(5) . . ?
C47 C46 H46 120.0 . . ?
C46 C47 H47 120.3 . . ?
C46 C47 C48 119.5(6) . . ?
C48 C47 H47 120.3 . . ?
C43 C48 C47 121.3(5) . . ?
C43 C48 H48 119.4 . . ?
C47 C48 H48 119.4 . . ?
C50 C49 P2 118.5(4) . . ?
C50 C49 C54 118.6(5) . . ?
C54 C49 P2 122.8(4) . . ?
C49 C50 H50 119.6 . . ?
C49 C50 C51 120.8(5) . . ?
C51 C50 H50 119.6 . . ?
C50 C51 H51 120.1 . . ?
C52 C51 C50 119.7(5) . . ?
C52 C51 H51 120.1 . . ?
C51 C52 H52 119.9 . . ?
C51 C52 C53 120.1(6) . . ?
C53 C52 H52 119.9 . . ?
C52 C53 H53 119.9 . . ?
C52 C53 C54 120.2(5) . . ?
C54 C53 H53 119.9 . . ?
C49 C54 H54 119.7 . . ?
C53 C54 C49 120.5(5) . . ?
C53 C54 H54 119.7 . . ?
C56 C55 P2 117.9(4) . . ?
C56 C55 C60 118.7(5) . . ?
C60 C55 P2 123.3(4) . . ?
C55 C56 H56 119.7 . . ?
C55 C56 C57 120.7(5) . . ?
C57 C56 H56 119.7 . . ?
C56 C57 H57 120.0 . . ?
C58 C57 C56 120.1(6) . . ?
C58 C57 H57 120.0 . . ?
C57 C58 H58 119.9 . . ?
C57 C58 C59 120.2(6) . . ?
C59 C58 H58 119.9 . . ?
C58 C59 H59 120.1 . . ?
C58 C59 C60 119.8(6) . . ?
C60 C59 H59 120.1 . . ?
C55 C60 C59 120.5(6) . . ?
C55 C60 H60 119.7 . . ?
C59 C60 H60 119.7 . . ?
C62 C61 P2 123.6(4) . . ?
C62 C61 C66 119.0(5) . . ?
C66 C61 P2 117.3(4) . . ?
C61 C62 H62 119.9 . . ?
C61 C62 C63 120.2(5) . . ?
C63 C62 H62 119.9 . . ?
C62 C63 H63 119.7 . . ?
C64 C63 C62 120.6(6) . . ?
C64 C63 H63 119.7 . . ?
C63 C64 H64 120.2 . . ?
C63 C64 C65 119.5(5) . . ?
C65 C64 H64 120.2 . . ?
C64 C65 H65 119.6 . . ?
C64 C65 C66 120.8(6) . . ?
C66 C65 H65 119.6 . . ?
C61 C66 H66 120.1 . . ?
C65 C66 C61 119.9(6) . . ?
C65 C66 H66 120.1 . . ?
C68 C67 P3 124.2(5) . . ?
C72 C67 P3 117.4(4) . . ?
C72 C67 C68 118.4(5) . . ?
C67 C68 H68 119.9 . . ?
C69 C68 C67 120.2(6) . . ?
C69 C68 H68 119.9 . . ?
C68 C69 H69 119.7 . . ?
C70 C69 C68 120.6(6) . . ?
C70 C69 H69 119.7 . . ?
C69 C70 H70 119.9 . . ?
C71 C70 C69 120.2(6) . . ?
C71 C70 H70 119.9 . . ?
C70 C71 H71 120.3 . . ?
C70 C71 C72 119.5(6) . . ?
C72 C71 H71 120.3 . . ?
C67 C72 C71 121.2(6) . . ?
C67 C72 H72 119.4 . . ?
C71 C72 H72 119.4 . . ?
C74 C73 P3 123.1(4) . . ?
C78 C73 P3 117.6(4) . . ?
C78 C73 C74 119.3(5) . . ?
C73 C74 H74 119.5 . . ?
C73 C74 C75 121.0(6) . . ?
C75 C74 H74 119.5 . . ?
C74 C75 H75 120.4 . . ?
C76 C75 C74 119.2(6) . . ?
C76 C75 H75 120.4 . . ?
C75 C76 H76 119.5 . . ?
C75 C76 C77 121.0(6) . . ?
C77 C76 H76 119.5 . . ?
C76 C77 H77 120.4 . . ?
C76 C77 C78 119.1(6) . . ?
C78 C77 H77 120.4 . . ?
C73 C78 C77 120.4(6) . . ?
C73 C78 H78 119.8 . . ?
C77 C78 H78 119.8 . . ?
C80 C79 P3 117.2(4) . . ?
C80 C79 C84 119.4(5) . . ?
C84 C79 P3 123.4(5) . . ?
C79 C80 H80 119.6 . . ?
C79 C80 C81 120.7(6) . . ?
C81 C80 H80 119.6 . . ?
C80 C81 H81 120.0 . . ?
C82 C81 C80 119.9(6) . . ?
C82 C81 H81 120.0 . . ?
C81 C82 H82 120.1 . . ?
C81 C82 C83 119.7(6) . . ?
C83 C82 H82 120.1 . . ?
C82 C83 H83 119.6 . . ?
C84 C83 C82 120.7(6) . . ?
C84 C83 H83 119.6 . . ?
C79 C84 H84 120.3 . . ?
C83 C84 C79 119.5(6) . . ?
C83 C84 H84 120.3 . . ?
C86 C85 P4 123.4(4) . . ?
C86 C85 C90 118.5(5) . . ?
C90 C85 P4 118.1(4) . . ?
C85 C86 H86 120.1 . . ?
C87 C86 C85 119.9(6) . . ?
C87 C86 H86 120.1 . . ?
C86 C87 H87 119.1 . . ?
C88 C87 C86 121.7(6) . . ?
C88 C87 H87 119.1 . . ?
C87 C88 H88 120.6 . . ?
C87 C88 C89 118.9(6) . . ?
C89 C88 H88 120.6 . . ?
C88 C89 H89 119.9 . . ?
C90 C89 C88 120.1(6) . . ?
C90 C89 H89 119.9 . . ?
C85 C90 H90 119.6 . . ?
C89 C90 C85 120.8(6) . . ?
C89 C90 H90 119.6 . . ?
C92 C91 P4 123.3(4) . . ?
C92 C91 C96 119.0(5) . . ?
C96 C91 P4 117.7(4) . . ?
C91 C92 H92 119.9 . . ?
C91 C92 C93 120.2(6) . . ?
C93 C92 H92 119.9 . . ?
C92 C93 H93 119.7 . . ?
C92 C93 C94 120.5(6) . . ?
C94 C93 H93 119.7 . . ?
C93 C94 H94 120.3 . . ?
C95 C94 C93 119.3(6) . . ?
C95 C94 H94 120.3 . . ?
C94 C95 H95 119.7 . . ?
C96 C95 C94 120.5(6) . . ?
C96 C95 H95 119.7 . . ?
C91 C96 H96 119.8 . . ?
C95 C96 C91 120.3(6) . . ?
C95 C96 H96 119.8 . . ?
C98 C97 P4 123.5(4) . . ?
C98 C97 C102 118.6(5) . . ?
C102 C97 P4 117.9(4) . . ?
C97 C98 H98 119.8 . . ?
C99 C98 C97 120.3(5) . . ?
C99 C98 H98 119.8 . . ?
C98 C99 H99 119.6 . . ?
C98 C99 C100 120.8(5) . . ?
C100 C99 H99 119.6 . . ?
C99 C100 H100 120.5 . . ?
C101 C100 C99 119.0(5) . . ?
C101 C100 H100 120.5 . . ?
C100 C101 H101 119.5 . . ?
C100 C101 C102 121.0(6) . . ?
C102 C101 H101 119.5 . . ?
C97 C102 H102 119.9 . . ?
C101 C102 C97 120.3(5) . . ?
C101 C102 H102 119.9 . . ?
H10C C104 H10D 109.5 . . ?
H10C C104 H10E 109.5 . . ?
H10D C104 H10E 109.5 . . ?
C105 C104 H10C 109.5 . . ?
C105 C104 H10D 109.5 . . ?
C105 C104 H10E 109.5 . . ?
C104 C105 H10F 109.8 . . ?
C104 C105 H10G 109.8 . . ?
C104 C105 O5 109.6(11) . . ?
H10F C105 H10G 108.2 . . ?
O5 C105 H10F 109.8 . . ?
O5 C105 H10G 109.8 . . ?
C105 O5 C106 113.9(9) . . ?
O5 C106 H10H 109.5 . . ?
O5 C106 H10I 109.5 . . ?
O5 C106 C107 110.7(12) . . ?
H10H C106 H10I 108.1 . . ?
C107 C106 H10H 109.5 . . ?
C107 C106 H10I 109.5 . . ?
C106 C107 H10J 109.5 . . ?
C106 C107 H10K 109.5 . . ?
C106 C107 H10L 109.5 . . ?
H10J C107 H10K 109.5 . . ?
H10J C107 H10L 109.5 . . ?
H10K C107 H10L 109.5 . . ?
H10M C103 H10N 107.8 . . ?
Cl2 C103 H10M 109.1 . . ?
Cl2 C103 H10N 109.1 . . ?
Cl3 C103 H10M 109.1 . . ?
Cl3 C103 H10N 109.1 . . ?
Cl3 C103 Cl2 112.6(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag3 P1 C31 C32 141.1(4) . . . . ?
Ag3 P1 C31 C36 -38.6(4) . . . . ?
Ag3 P1 C37 C38 141.2(4) . . . . ?
Ag3 P1 C37 C42 -37.7(5) . . . . ?
Ag3 P1 C43 C44 -36.7(5) . . . . ?
Ag3 P1 C43 C48 141.9(4) . . . . ?
Ag4 P2 C49 C50 27.0(5) . . . . ?
Ag4 P2 C49 C54 -155.0(4) . . . . ?
Ag4 P2 C55 C56 47.4(5) . . . . ?
Ag4 P2 C55 C60 -129.4(4) . . . . ?
Ag4 P2 C61 C62 -147.0(4) . . . . ?
Ag4 P2 C61 C66 37.2(5) . . . . ?
Ag4 P3 C67 C68 150.9(5) . . . . ?
Ag4 P3 C67 C72 -26.0(5) . . . . ?
Ag4 P3 C73 C74 156.7(4) . . . . ?
Ag4 P3 C73 C78 -25.0(5) . . . . ?
Ag4 P3 C79 C80 -40.9(5) . . . . ?
Ag4 P3 C79 C84 140.6(5) . . . . ?
Ag5 P4 C85 C86 118.1(4) . . . . ?
Ag5 P4 C85 C90 -60.2(5) . . . . ?
Ag5 P4 C91 C92 150.6(4) . . . . ?
Ag5 P4 C91 C96 -31.7(5) . . . . ?
Ag5 P4 C97 C98 141.6(4) . . . . ?
Ag5 P4 C97 C102 -38.2(5) . . . . ?
P1 C31 C32 C33 -179.5(4) . . . . ?
P1 C31 C36 C35 -178.5(5) . . . . ?
P1 C37 C38 C39 -179.7(4) . . . . ?
P1 C37 C42 C41 -179.6(5) . . . . ?
P1 C43 C44 C45 179.9(5) . . . . ?
P1 C43 C48 C47 -178.6(5) . . . . ?
P2 C49 C50 C51 178.6(4) . . . . ?
P2 C49 C54 C53 -178.1(4) . . . . ?
P2 C55 C56 C57 -177.6(5) . . . . ?
P2 C55 C60 C59 177.0(5) . . . . ?
P2 C61 C62 C63 -177.0(4) . . . . ?
P2 C61 C66 C65 176.8(5) . . . . ?
P3 C67 C68 C69 -178.6(5) . . . . ?
P3 C67 C72 C71 177.7(4) . . . . ?
P3 C73 C74 C75 178.4(5) . . . . ?
P3 C73 C78 C77 -178.0(5) . . . . ?
P3 C79 C80 C81 -177.1(5) . . . . ?
P3 C79 C84 C83 176.5(5) . . . . ?
P4 C85 C86 C87 179.8(5) . . . . ?
P4 C85 C90 C89 179.5(5) . . . . ?
P4 C91 C92 C93 175.8(4) . . . . ?
P4 C91 C96 C95 -175.5(5) . . . . ?
P4 C97 C98 C99 -178.9(4) . . . . ?
P4 C97 C102 C101 -179.5(5) . . . . ?
C4 C5 C6 C7 179.0(6) . . . . ?
C4 C5 C10 C9 177.3(7) . . . . ?
C5 C6 C7 C8 -55.1(9) . . . . ?
C6 C5 C10 C9 -59.3(8) . . . . ?
C6 C7 C8 C9 54.3(10) . . . . ?
C7 C8 C9 C10 -55.1(11) . . . . ?
C8 C9 C10 C5 57.3(10) . . . . ?
C10 C5 C6 C7 57.8(8) . . . . ?
C14 C15 C16 C17 177.4(5) . . . . ?
C14 C15 C20 C19 -178.1(6) . . . . ?
C15 C16 C17 C18 56.0(8) . . . . ?
C16 C15 C20 C19 56.2(7) . . . . ?
C16 C17 C18 C19 -55.6(8) . . . . ?
C17 C18 C19 C20 54.5(9) . . . . ?
C18 C19 C20 C15 -54.3(9) . . . . ?
C20 C15 C16 C17 -56.9(7) . . . . ?
C24 C25 C26 C27 -179.3(8) . . . . ?
C24 C25 C30 C29 -179.5(10) . . . . ?
C25 C26 C27 C28 -53.0(15) . . . . ?
C26 C25 C30 C29 -53.0(13) . . . . ?
C26 C27 C28 C29 52.7(18) . . . . ?
C27 C28 C29 C30 -50.7(19) . . . . ?
C28 C29 C30 C25 50.2(16) . . . . ?
C30 C25 C26 C27 53.0(12) . . . . ?
C31 P1 C37 C38 14.5(5) . . . . ?
C31 P1 C37 C42 -164.4(4) . . . . ?
C31 P1 C43 C44 90.0(4) . . . . ?
C31 P1 C43 C48 -91.4(5) . . . . ?
C31 C32 C33 C34 -1.5(8) . . . . ?
C32 C31 C36 C35 1.8(8) . . . . ?
C32 C33 C34 C35 0.7(9) . . . . ?
C33 C34 C35 C36 1.3(10) . . . . ?
C34 C35 C36 C31 -2.6(9) . . . . ?
C36 C31 C32 C33 0.2(7) . . . . ?
C37 P1 C31 C32 -92.5(4) . . . . ?
C37 P1 C31 C36 87.8(4) . . . . ?
C37 P1 C43 C44 -162.7(4) . . . . ?
C37 P1 C43 C48 15.9(5) . . . . ?
C37 C38 C39 C40 0.4(9) . . . . ?
C38 C37 C42 C41 1.4(8) . . . . ?
C38 C39 C40 C41 -0.7(10) . . . . ?
C39 C40 C41 C42 1.4(11) . . . . ?
C40 C41 C42 C37 -1.7(10) . . . . ?
C42 C37 C38 C39 -0.7(8) . . . . ?
C43 P1 C31 C32 15.0(5) . . . . ?
C43 P1 C31 C36 -164.7(4) . . . . ?
C43 P1 C37 C38 -93.0(5) . . . . ?
C43 P1 C37 C42 88.1(4) . . . . ?
C43 C44 C45 C46 -1.7(10) . . . . ?
C44 C43 C48 C47 0.0(8) . . . . ?
C44 C45 C46 C47 1.0(10) . . . . ?
C45 C46 C47 C48 0.2(10) . . . . ?
C46 C47 C48 C43 -0.7(9) . . . . ?
C48 C43 C44 C45 1.2(8) . . . . ?
C49 P2 C55 C56 -78.8(5) . . . . ?
C49 P2 C55 C60 104.3(5) . . . . ?
C49 P2 C61 C62 -15.6(5) . . . . ?
C49 P2 C61 C66 168.5(4) . . . . ?
C49 C50 C51 C52 -0.7(8) . . . . ?
C50 C49 C54 C53 -0.1(8) . . . . ?
C50 C51 C52 C53 0.4(9) . . . . ?
C51 C52 C53 C54 0.0(9) . . . . ?
C52 C53 C54 C49 -0.2(9) . . . . ?
C54 C49 C50 C51 0.6(8) . . . . ?
C55 P2 C49 C50 148.6(4) . . . . ?
C55 P2 C49 C54 -33.4(5) . . . . ?
C55 P2 C61 C62 92.0(5) . . . . ?
C55 P2 C61 C66 -83.8(5) . . . . ?
C55 C56 C57 C58 0.5(10) . . . . ?
C56 C55 C60 C59 0.2(8) . . . . ?
C56 C57 C58 C59 0.1(11) . . . . ?
C57 C58 C59 C60 -0.5(10) . . . . ?
C58 C59 C60 C55 0.4(9) . . . . ?
C60 C55 C56 C57 -0.7(9) . . . . ?
C61 P2 C49 C50 -104.7(4) . . . . ?
C61 P2 C49 C54 73.3(5) . . . . ?
C61 P2 C55 C56 173.6(4) . . . . ?
C61 P2 C55 C60 -3.2(5) . . . . ?
C61 C62 C63 C64 1.1(8) . . . . ?
C62 C61 C66 C65 0.8(9) . . . . ?
C62 C63 C64 C65 -0.3(9) . . . . ?
C63 C64 C65 C66 -0.2(10) . . . . ?
C64 C65 C66 C61 -0.1(10) . . . . ?
C66 C61 C62 C63 -1.3(8) . . . . ?
C67 P3 C73 C74 -77.6(5) . . . . ?
C67 P3 C73 C78 100.7(5) . . . . ?
C67 P3 C79 C80 -160.7(5) . . . . ?
C67 P3 C79 C84 20.8(6) . . . . ?
C67 C68 C69 C70 1.8(10) . . . . ?
C68 C67 C72 C71 0.6(8) . . . . ?
C68 C69 C70 C71 -0.7(10) . . . . ?
C69 C70 C71 C72 -0.3(9) . . . . ?
C70 C71 C72 C67 0.4(9) . . . . ?
C72 C67 C68 C69 -1.6(9) . . . . ?
C73 P3 C67 C68 18.3(6) . . . . ?
C73 P3 C67 C72 -158.6(4) . . . . ?
C73 P3 C79 C80 90.4(5) . . . . ?
C73 P3 C79 C84 -88.1(5) . . . . ?
C73 C74 C75 C76 -1.3(10) . . . . ?
C74 C73 C78 C77 0.3(9) . . . . ?
C74 C75 C76 C77 2.0(11) . . . . ?
C75 C76 C77 C78 -1.6(10) . . . . ?
C76 C77 C78 C73 0.4(9) . . . . ?
C78 C73 C74 C75 0.2(9) . . . . ?
C79 P3 C67 C68 -88.4(5) . . . . ?
C79 P3 C67 C72 94.6(5) . . . . ?
C79 P3 C73 C74 31.9(5) . . . . ?
C79 P3 C73 C78 -149.8(4) . . . . ?
C79 C80 C81 C82 0.0(11) . . . . ?
C80 C79 C84 C83 -1.9(9) . . . . ?
C80 C81 C82 C83 -1.0(12) . . . . ?
C81 C82 C83 C84 0.5(12) . . . . ?
C82 C83 C84 C79 1.0(11) . . . . ?
C84 C79 C80 C81 1.4(9) . . . . ?
C85 P4 C91 C92 -86.4(5) . . . . ?
C85 P4 C91 C96 91.3(4) . . . . ?
C85 P4 C97 C98 15.7(5) . . . . ?
C85 P4 C97 C102 -164.1(4) . . . . ?
C85 C86 C87 C88 1.6(10) . . . . ?
C86 C85 C90 C89 1.2(8) . . . . ?
C86 C87 C88 C89 -0.4(10) . . . . ?
C87 C88 C89 C90 -0.4(10) . . . . ?
C88 C89 C90 C85 0.0(9) . . . . ?
C90 C85 C86 C87 -2.0(8) . . . . ?
C91 P4 C85 C86 -4.7(5) . . . . ?
C91 P4 C85 C90 177.0(4) . . . . ?
C91 P4 C97 C98 -92.1(5) . . . . ?
C91 P4 C97 C102 88.1(5) . . . . ?
C91 C92 C93 C94 -0.3(9) . . . . ?
C92 C91 C96 C95 2.3(9) . . . . ?
C92 C93 C94 C95 2.0(9) . . . . ?
C93 C94 C95 C96 -1.5(10) . . . . ?
C94 C95 C96 C91 -0.6(10) . . . . ?
C96 C91 C92 C93 -1.9(8) . . . . ?
C97 P4 C85 C86 -113.7(5) . . . . ?
C97 P4 C85 C90 68.1(5) . . . . ?
C97 P4 C91 C92 21.8(5) . . . . ?
C97 P4 C91 C96 -160.5(4) . . . . ?
C97 C98 C99 C100 -2.3(9) . . . . ?
C98 C97 C102 C101 0.7(8) . . . . ?
C98 C99 C100 C101 2.0(9) . . . . ?
C99 C100 C101 C102 -0.3(9) . . . . ?
C100 C101 C102 C97 -1.0(9) . . . . ?
C102 C97 C98 C99 0.9(8) . . . . ?
C104 C105 O5 C106 179.3(11) . . . . ?
C105 O5 C106 C107 171.4(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_7
_database_code_depnum_ccdc_archive 'CCDC 1557618'
_audit_update_record             
;
2017-09-26 deposited with the CCDC.
2017-09-29 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT430_7                   
;
PROBLEM: Short Inter D...A Contact  O1W    ..  O4W     ..       2.44 Ang.
RESPONSE: Positions of hydrogen atoms of O1W and O4W cannot be accurately calculated.
;
_vrf_PLAT430_7_2                 
;
PROBLEM: Short Inter D...A Contact  O4W    ..  O6W     ..       2.17 Ang.
RESPONSE: Positions of hydrogen atoms of O4W and O6W cannot be accurately calculated.
;
_vrf_PLAT430_7_3                 
;
PROBLEM: Short Inter D...A Contact  O5W    ..  O6W     ..       2.53 Ang.
RESPONSE: Positions of hydrogen atoms of O5W and O6W cannot be accurately calculated.
;
_vrf_PLAT430_7_4                 
;
PROBLEM: Short Inter D...A Contact  O6W    ..  O7W     ..       1.87 Ang.
RESPONSE: Positions of hydrogen atoms of O6W and O7W cannot be accurately calculated.
;
_vrf_PLAT220_7                   
;
PROBLEM: Non-Solvent Resd 1   C   Ueq(max)/Ueq(min) Range        6.3 Ratio
RESPONSE: No appropriate disorder components of carbon C10 is found.
;
_vrf_PLAT306_7                   
;
PROBLEM: Isolated Oxygen Atom (H-atoms Missing ?) .......        O1W Check
RESPONSE: Positions of hydrogen atoms of O1W cannot be accurately calculated.
;
_vrf_PLAT430_7_5                 
;
PROBLEM: Short Inter D...A Contact  O1W    ..  O2W     ..       2.82 Ang.
RESPONSE: Positions of hydrogen atoms of O1W and O2W cannot be accurately calculated.
;
# Added during the CSD deposition process: Tuesday 26 September 2017 03:17 AM
# end Validation Reply Form

_audit_creation_date             2017-09-26
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C120 H104 Ag4 P4, 10(O)'
_chemical_formula_sum            'C121 H107 Ag4 O9 P4'
_chemical_formula_weight         2260.42
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_H-M_alt        'P 1 2/n 1'
_space_group_name_Hall           '-P 2yac'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z-1/2'

_cell_length_a                   16.8050(19)
_cell_length_b                   21.229(3)
_cell_length_c                   16.9004(19)
_cell_angle_alpha                90
_cell_angle_beta                 101.531(2)
_cell_angle_gamma                90
_cell_volume                     5907.5(12)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9669
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.174
_cell_measurement_theta_min      2.283
_shelx_estimated_absorpt_T_max   0.804
_shelx_estimated_absorpt_T_min   0.703
_exptl_absorpt_coefficient_mu    0.759
_exptl_absorpt_correction_T_max  0.8042
_exptl_absorpt_correction_T_min  0.7026
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.271
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2306
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1258
_diffrn_reflns_av_unetI/netI     0.0583
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            119413
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.249
_diffrn_reflns_theta_min         1.911
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7772
_reflns_number_total             10655
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_refine_diff_density_max         1.522
_refine_diff_density_min         -0.819
_refine_diff_density_rms         0.141
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     613
_refine_ls_number_reflns         10655
_refine_ls_number_restraints     37
_refine_ls_R_factor_all          0.0913
_refine_ls_R_factor_gt           0.0649
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1133P)²+17.4564P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1763
_refine_ls_wR_factor_ref         0.2065
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Rigid bond restraints
 C9, C10
 with sigma for 1-2 distances of 0.0005 and sigma for 1-3 distances of 0.0005
3. Uiso/Uaniso restraints and constraints
Uanis(C10) \\sim Ueq, Uanis(C11) \\sim Ueq, Uanis(C21) \\sim Ueq, Uanis(O7W)
\\sim Ueq, Uanis(O3W') \\sim Ueq, Uanis(O5W) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
4. Others
 Sof(O3W')=1-FVAR(1)
 Sof(O3W)=FVAR(1)
 Fixed Sof: O6W(0.5) O7W(0.5) O4W(0.5) O5W(0.5)
5.a Free rotating group:
 Ag1(Ag2,P1,P2,C1,C2,C3,C4,C5,C6,C7)
5.b Ternary CH refined with riding coordinates:
 C7(H7), C19(H19)
5.c Secondary CH2 refined with riding coordinates:
 C8(H8A,H8B), C9(H9A,H9B), C10(H10A,H10B), C11(H11A,H11B), C12(H12A,H12B),
 C20(H20A,H20B), C21(H21A,H21B), C22(H22A,H22B), C23(H23A,H23B), C24(H24A,H24B)
5.d Aromatic/amide H refined with riding coordinates:
 C26(H26), C27(H27), C28(H28), C29(H29), C30(H30), C32(H32), C33(H33),
 C34(H34), C35(H35), C36(H36), C38(H38), C39(H39), C40(H40), C41(H41), C42(H42),
  C44(H44), C45(H45), C46(H46), C47(H47), C48(H48), C50(H50), C51(H51),
 C52(H52), C53(H53), C54(H54), C56(H56), C57(H57), C58(H58), C59(H59), C60(H60)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.78983(2) 0.29847(2) 0.09874(2) 0.03268(16) Uani 1 1 d . . . . .
Ag2 Ag 0.66646(2) 0.29749(2) 0.20722(2) 0.03743(16) Uani 1 1 d G . . . .
P1 P 0.88795(4) 0.37887(3) 0.06389(4) 0.0300(3) Uani 1 1 d G . . . .
P2 P 0.71940(5) 0.22424(4) -0.00878(4) 0.0367(4) Uani 1 1 d G . . . .
C1 C 0.68399(3) 0.36673(2) 0.12508(3) 0.0426(15) Uani 1 1 d G . . . .
C2 C 0.66626(5) 0.41497(3) 0.08661(5) 0.0428(15) Uani 1 1 d G . . . .
C3 C 0.64379(7) 0.47080(4) 0.04552(7) 0.0474(16) Uani 1 1 d G . . . .
C4 C 0.62134(8) 0.51933(5) 0.01092(9) 0.0529(18) Uani 1 1 d G . . . .
C5 C 0.59814(11) 0.57465(6) -0.02928(11) 0.0512(17) Uani 1 1 d G . . . .
C6 C 0.57767(12) 0.62256(7) -0.06541(13) 0.0555(18) Uani 1 1 d G . . . .
C7 C 0.54900(15) 0.67949(8) -0.11176(15) 0.071(2) Uani 1 1 d G . . . .
H7 H 0.4884 0.6769 -0.1233 0.086 Uiso 1 1 calc R . . . .
C8 C 0.5723(9) 0.6803(6) -0.1904(7) 0.106(4) Uani 1 1 d . . . . .
H8A H 0.5401 0.7121 -0.2258 0.127 Uiso 1 1 calc R . . . .
H8B H 0.5621 0.6385 -0.2166 0.127 Uiso 1 1 calc R . . . .
C9 C 0.6617(10) 0.6962(8) -0.1773(10) 0.134(4) Uani 1 1 d . U . . .
H9A H 0.6790 0.6973 -0.2299 0.161 Uiso 1 1 calc R . . . .
H9B H 0.6937 0.6632 -0.1436 0.161 Uiso 1 1 calc R . . . .
C10 C 0.6795(13) 0.7658(11) -0.1318(14) 0.190(7) Uani 1 1 d . U . . .
H10A H 0.7381 0.7762 -0.1214 0.228 Uiso 1 1 calc R . . . .
H10B H 0.6489 0.7997 -0.1650 0.228 Uiso 1 1 calc R . . . .
C11 C 0.6508(13) 0.7575(10) -0.0554(13) 0.175(7) Uani 1 1 d . U . . .
H11A H 0.6853 0.7256 -0.0221 0.209 Uiso 1 1 calc R . . . .
H11B H 0.6577 0.7977 -0.0252 0.209 Uiso 1 1 calc R . . . .
C12 C 0.5697(10) 0.7386(5) -0.0656(8) 0.117(4) Uani 1 1 d . . . . .
H12A H 0.5350 0.7728 -0.0936 0.141 Uiso 1 1 calc R . . . .
H12B H 0.5561 0.7334 -0.0117 0.141 Uiso 1 1 calc R . . . .
C13 C 0.6295(4) 0.2345(3) 0.2864(4) 0.0417(14) Uani 1 1 d . . . . .
C14 C 0.5935(4) 0.1972(3) 0.3210(4) 0.0425(15) Uani 1 1 d . . . . .
C15 C 0.5486(5) 0.1582(3) 0.3591(4) 0.058(2) Uani 1 1 d . . . . .
C16 C 0.5060(6) 0.1271(4) 0.3933(5) 0.072(3) Uani 1 1 d . . . . .
C17 C 0.4572(7) 0.0932(4) 0.4347(6) 0.086(3) Uani 1 1 d . . . . .
C18 C 0.4144(9) 0.0644(5) 0.4716(7) 0.111(5) Uani 1 1 d . . . . .
C19 C 0.3590(9) 0.0306(6) 0.5162(8) 0.113(5) Uani 1 1 d . . . . .
H19 H 0.3513 -0.0140 0.4972 0.136 Uiso 1 1 calc R . . . .
C20 C 0.3975(9) 0.0326(7) 0.6080(9) 0.131(5) Uani 1 1 d . . . . .
H20A H 0.4496 0.0093 0.6187 0.157 Uiso 1 1 calc R . . . .
H20B H 0.4082 0.0767 0.6260 0.157 Uiso 1 1 calc R . . . .
C21 C 0.3367(9) 0.0016(8) 0.6539(9) 0.134(5) Uani 1 1 d . U . . .
H21A H 0.3313 -0.0437 0.6398 0.161 Uiso 1 1 calc R . . . .
H21B H 0.3581 0.0049 0.7127 0.161 Uiso 1 1 calc R . . . .
C22 C 0.2549(8) 0.0321(6) 0.6339(8) 0.110(4) Uani 1 1 d . . . . .
H22A H 0.2171 0.0080 0.6604 0.132 Uiso 1 1 calc R . . . .
H22B H 0.2592 0.0751 0.6570 0.132 Uiso 1 1 calc R . . . .
C23 C 0.2208(8) 0.0364(10) 0.5497(9) 0.156(7) Uani 1 1 d . . . . .
H23A H 0.1705 0.0618 0.5425 0.187 Uiso 1 1 calc R . . . .
H23B H 0.2055 -0.0064 0.5288 0.187 Uiso 1 1 calc R . . . .
C24 C 0.2774(8) 0.0656(10) 0.4997(9) 0.167(8) Uani 1 1 d . . . . .
H24A H 0.2863 0.1106 0.5139 0.200 Uiso 1 1 calc R . . . .
H24B H 0.2524 0.0627 0.4415 0.200 Uiso 1 1 calc R . . . .
C25 C 0.9402(3) 0.4295(3) 0.1458(3) 0.0323(12) Uani 1 1 d . . . . .
C26 C 1.0160(4) 0.4572(3) 0.1444(4) 0.0396(14) Uani 1 1 d . . . . .
H26 H 1.0401 0.4512 0.0987 0.048 Uiso 1 1 calc R . . . .
C27 C 1.0555(4) 0.4925(3) 0.2077(4) 0.0464(16) Uani 1 1 d . . . . .
H27 H 1.1058 0.5118 0.2047 0.056 Uiso 1 1 calc R . . . .
C28 C 1.0232(5) 0.5006(4) 0.2759(4) 0.0525(18) Uani 1 1 d . . . . .
H28 H 1.0522 0.5235 0.3208 0.063 Uiso 1 1 calc R . . . .
C29 C 0.9475(5) 0.4746(3) 0.2781(4) 0.0542(19) Uani 1 1 d . . . . .
H29 H 0.9233 0.4819 0.3235 0.065 Uiso 1 1 calc R . . . .
C30 C 0.9072(4) 0.4382(3) 0.2143(4) 0.0486(16) Uani 1 1 d . . . . .
H30 H 0.8569 0.4190 0.2174 0.058 Uiso 1 1 calc R . . . .
C31 C 0.8362(3) 0.4335(3) -0.0136(3) 0.0302(12) Uani 1 1 d . . . . .
C32 C 0.8421(4) 0.4989(3) -0.0054(4) 0.0365(13) Uani 1 1 d . . . . .
H32 H 0.8755 0.5169 0.0411 0.044 Uiso 1 1 calc R . . . .
C33 C 0.7987(4) 0.5376(3) -0.0656(4) 0.0464(16) Uani 1 1 d . . . . .
H33 H 0.8035 0.5821 -0.0604 0.056 Uiso 1 1 calc R . . . .
C34 C 0.7487(4) 0.5118(3) -0.1331(4) 0.0474(16) Uani 1 1 d . . . . .
H34 H 0.7192 0.5384 -0.1738 0.057 Uiso 1 1 calc R . . . .
C35 C 0.7422(4) 0.4473(4) -0.1405(4) 0.0465(16) Uani 1 1 d . . . . .
H35 H 0.7077 0.4296 -0.1866 0.056 Uiso 1 1 calc R . . . .
C36 C 0.7855(4) 0.4076(3) -0.0814(4) 0.0394(14) Uani 1 1 d . . . . .
H36 H 0.7806 0.3632 -0.0873 0.047 Uiso 1 1 calc R . . . .
C37 C 0.9732(4) 0.3476(3) 0.0232(4) 0.0357(13) Uani 1 1 d . . . . .
C38 C 1.0192(4) 0.3004(3) 0.0666(5) 0.0535(18) Uani 1 1 d . . . . .
H38 H 1.0054 0.2855 0.1152 0.064 Uiso 1 1 calc R . . . .
C39 C 1.0856(5) 0.2744(4) 0.0403(6) 0.076(3) Uani 1 1 d . . . . .
H39 H 1.1159 0.2414 0.0701 0.091 Uiso 1 1 calc R . . . .
C40 C 1.1070(5) 0.2969(4) -0.0292(6) 0.071(2) Uani 1 1 d . . . . .
H40 H 1.1529 0.2799 -0.0467 0.085 Uiso 1 1 calc R . . . .
C41 C 1.0616(5) 0.3441(5) -0.0733(5) 0.065(2) Uani 1 1 d . . . . .
H41 H 1.0761 0.3588 -0.1217 0.078 Uiso 1 1 calc R . . . .
C42 C 0.9950(4) 0.3705(3) -0.0479(4) 0.0438(15) Uani 1 1 d . . . . .
H42 H 0.9648 0.4034 -0.0780 0.053 Uiso 1 1 calc R . . . .
C43 C 0.6510(4) 0.1674(3) 0.0236(4) 0.0450(15) Uani 1 1 d . . . . .
C44 C 0.6661(5) 0.1490(3) 0.1039(5) 0.0538(19) Uani 1 1 d . . . . .
H44 H 0.7111 0.1662 0.1407 0.065 Uiso 1 1 calc R . . . .
C45 C 0.6154(7) 0.1050(4) 0.1311(6) 0.084(3) Uani 1 1 d . . . . .
H45 H 0.6251 0.0923 0.1860 0.101 Uiso 1 1 calc R . . . .
C46 C 0.5487(7) 0.0799(4) 0.0741(9) 0.097(4) Uani 1 1 d . . . . .
H46 H 0.5130 0.0505 0.0914 0.116 Uiso 1 1 calc R . . . .
C47 C 0.5360(6) 0.0975(5) -0.0038(8) 0.088(3) Uani 1 1 d . . . . .
H47 H 0.4925 0.0787 -0.0410 0.105 Uiso 1 1 calc R . . . .
C48 C 0.5832(5) 0.1412(4) -0.0314(6) 0.066(2) Uani 1 1 d . . . . .
H48 H 0.5714 0.1540 -0.0864 0.079 Uiso 1 1 calc R . . . .
C49 C 0.6518(4) 0.2657(3) -0.0921(4) 0.0463(16) Uani 1 1 d . . . . .
C50 C 0.5935(5) 0.3059(3) -0.0701(5) 0.0538(18) Uani 1 1 d . . . . .
H50 H 0.5887 0.3090 -0.0152 0.065 Uiso 1 1 calc R . . . .
C51 C 0.5436(6) 0.3408(4) -0.1281(5) 0.077(3) Uani 1 1 d . . . . .
H51 H 0.5039 0.3678 -0.1133 0.092 Uiso 1 1 calc R . . . .
C52 C 0.5508(7) 0.3367(4) -0.2079(5) 0.085(3) Uani 1 1 d . . . . .
H52 H 0.5166 0.3614 -0.2476 0.103 Uiso 1 1 calc R . . . .
C53 C 0.6057(8) 0.2981(5) -0.2298(5) 0.088(3) Uani 1 1 d . . . . .
H53 H 0.6090 0.2951 -0.2852 0.105 Uiso 1 1 calc R . . . .
C54 C 0.6585(6) 0.2620(4) -0.1723(4) 0.065(2) Uani 1 1 d . . . . .
H54 H 0.6981 0.2355 -0.1882 0.078 Uiso 1 1 calc R . . . .
C55 C 0.7855(4) 0.1786(3) -0.0608(4) 0.0405(14) Uani 1 1 d . . . . .
C56 C 0.8619(5) 0.2024(4) -0.0613(5) 0.063(2) Uani 1 1 d . . . . .
H56 H 0.8791 0.2398 -0.0320 0.075 Uiso 1 1 calc R . . . .
C57 C 0.9141(6) 0.1728(5) -0.1037(6) 0.078(3) Uani 1 1 d . . . . .
H57 H 0.9661 0.1903 -0.1039 0.094 Uiso 1 1 calc R . . . .
C58 C 0.8906(6) 0.1181(5) -0.1454(5) 0.077(3) Uani 1 1 d . . . . .
H58 H 0.9255 0.0981 -0.1755 0.092 Uiso 1 1 calc R . . . .
C59 C 0.8156(6) 0.0928(4) -0.1430(6) 0.078(3) Uani 1 1 d . . . . .
H59 H 0.8000 0.0540 -0.1695 0.094 Uiso 1 1 calc R . . . .
C60 C 0.7630(5) 0.1229(4) -0.1026(5) 0.066(2) Uani 1 1 d . . . . .
H60 H 0.7108 0.1055 -0.1034 0.079 Uiso 1 1 calc R . . . .
O6W O 1.0733(11) 0.1426(8) -0.2784(10) 0.116(5) Uiso 0.5 1 d . . P . .
O1W O 0.6063(4) 0.0007(3) 0.8210(3) 0.082(2) Uani 1 1 d . . . . .
O7W O 1.1107(12) 0.2074(8) -0.2058(12) 0.126(6) Uani 0.5 1 d . U P . .
O2W O 0.7104(5) -0.0821(4) 0.7594(4) 0.106(2) Uani 1 1 d . . . . .
O3W O 1.260(2) 0.4268(17) -0.199(2) 0.062(15) Uiso 0.16(2) 1 d . U P A 1
O3W' O 1.2257(9) 0.3961(6) -0.1734(7) 0.147(5) Uani 0.84(2) 1 d . U P A 2
O4W O 0.4708(10) 0.0463(6) 0.7823(7) 0.095(4) Uani 0.5 1 d . . P . .
O5W O 1.1682(16) 0.1958(11) -0.3561(10) 0.156(8) Uani 0.5 1 d . U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 3.2142 2_655 ?
Ag1 Ag2 3.0298 . ?
Ag1 P1 2.5233 . ?
Ag1 P2 2.5152 . ?
Ag1 C1 2.4038 . ?
Ag1 C13 2.529(6) 2_655 ?
Ag2 Ag1 3.2142 2_655 ?
Ag2 Ag2 2.8900 2_655 ?
Ag2 C1 2.0828 . ?
Ag2 C13 2.072(7) . ?
P1 C25 1.833(6) . ?
P1 C31 1.833(5) . ?
P1 C37 1.833(6) . ?
P2 C43 1.824(6) . ?
P2 C49 1.846(7) . ?
P2 C55 1.827(6) . ?
C1 C2 1.2177 . ?
C2 C3 1.3873 . ?
C3 C4 1.2072 . ?
C4 C5 1.3736 . ?
C5 C6 1.2007 . ?
C6 C7 1.4682 . ?
C7 H7 1.0000 . ?
C7 C8 1.458(12) . ?
C7 C12 1.482(12) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C8 C9 1.512(19) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C10 1.67(2) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C10 C11 1.48(3) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C11 C12 1.40(2) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 Ag1 2.529(6) 2_655 ?
C13 C14 1.216(9) . ?
C14 C15 1.364(10) . ?
C15 C16 1.203(10) . ?
C16 C17 1.383(11) . ?
C17 C18 1.208(11) . ?
C18 C19 1.493(13) . ?
C19 H19 1.0000 . ?
C19 C20 1.56(2) . ?
C19 C24 1.53(2) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C20 C21 1.548(15) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C21 C22 1.496(18) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C23 1.426(18) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C23 C24 1.526(16) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.407(8) . ?
C25 C30 1.392(8) . ?
C26 H26 0.9500 . ?
C26 C27 1.364(9) . ?
C27 H27 0.9500 . ?
C27 C28 1.380(10) . ?
C28 H28 0.9500 . ?
C28 C29 1.394(10) . ?
C29 H29 0.9500 . ?
C29 C30 1.389(9) . ?
C30 H30 0.9500 . ?
C31 C32 1.396(8) . ?
C31 C36 1.397(8) . ?
C32 H32 0.9500 . ?
C32 C33 1.396(9) . ?
C33 H33 0.9500 . ?
C33 C34 1.386(10) . ?
C34 H34 0.9500 . ?
C34 C35 1.378(10) . ?
C35 H35 0.9500 . ?
C35 C36 1.395(9) . ?
C36 H36 0.9500 . ?
C37 C38 1.383(9) . ?
C37 C42 1.411(8) . ?
C38 H38 0.9500 . ?
C38 C39 1.394(11) . ?
C39 H39 0.9500 . ?
C39 C40 1.381(13) . ?
C40 H40 0.9500 . ?
C40 C41 1.385(13) . ?
C41 H41 0.9500 . ?
C41 C42 1.393(10) . ?
C42 H42 0.9500 . ?
C43 C44 1.387(10) . ?
C43 C48 1.431(11) . ?
C44 H44 0.9500 . ?
C44 C45 1.402(11) . ?
C45 H45 0.9500 . ?
C45 C46 1.427(16) . ?
C46 H46 0.9500 . ?
C46 C47 1.345(16) . ?
C47 H47 0.9500 . ?
C47 C48 1.363(12) . ?
C48 H48 0.9500 . ?
C49 C50 1.403(11) . ?
C49 C54 1.386(10) . ?
C50 H50 0.9500 . ?
C50 C51 1.373(11) . ?
C51 H51 0.9500 . ?
C51 C52 1.381(13) . ?
C52 H52 0.9500 . ?
C52 C53 1.340(15) . ?
C53 H53 0.9500 . ?
C53 C54 1.405(12) . ?
C54 H54 0.9500 . ?
C55 C56 1.381(10) . ?
C55 C60 1.390(10) . ?
C56 H56 0.9500 . ?
C56 C57 1.390(12) . ?
C57 H57 0.9500 . ?
C57 C58 1.374(13) . ?
C58 H58 0.9500 . ?
C58 C59 1.378(13) . ?
C59 H59 0.9500 . ?
C59 C60 1.377(12) . ?
C60 H60 0.9500 . ?
O2W O2W 1.428(15) 2_656 ?
O3W O3W 1.68(7) 2_754 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag2 55.0 . 2_655 ?
P1 Ag1 Ag2 134.8 . . ?
P1 Ag1 Ag2 102.5 . 2_655 ?
P1 Ag1 C13 105.50(15) . 2_655 ?
P2 Ag1 Ag2 135.4 . 2_655 ?
P2 Ag1 Ag2 98.8 . . ?
P2 Ag1 P1 119.4 . . ?
P2 Ag1 C13 108.72(16) . 2_655 ?
C1 Ag1 Ag2 80.9 . 2_655 ?
C1 Ag1 Ag2 43.2 . . ?
C1 Ag1 P1 100.2 . . ?
C1 Ag1 P2 104.6 . . ?
C1 Ag1 C13 118.96(15) . 2_655 ?
C13 Ag1 Ag2 81.85(14) 2_655 . ?
C13 Ag1 Ag2 40.11(15) 2_655 2_655 ?
Ag1 Ag2 Ag1 124.9 . 2_655 ?
Ag2 Ag2 Ag1 59.2 2_655 2_655 ?
Ag2 Ag2 Ag1 65.7 2_655 . ?
C1 Ag2 Ag1 52.2 . . ?
C1 Ag2 Ag1 129.9 . 2_655 ?
C1 Ag2 Ag2 94.6 . 2_655 ?
C13 Ag2 Ag1 51.84(17) . 2_655 ?
C13 Ag2 Ag1 136.44(18) . . ?
C13 Ag2 Ag2 93.63(18) . 2_655 ?
C13 Ag2 C1 170.44(18) . . ?
C25 P1 Ag1 117.21(17) . . ?
C25 P1 C31 104.8(3) . . ?
C25 P1 C37 101.7(3) . . ?
C31 P1 Ag1 110.84(17) . . ?
C31 P1 C37 104.8(2) . . ?
C37 P1 Ag1 116.04(19) . . ?
C43 P2 Ag1 115.5(2) . . ?
C43 P2 C49 102.5(3) . . ?
C43 P2 C55 105.9(3) . . ?
C49 P2 Ag1 112.4(2) . . ?
C55 P2 Ag1 115.9(2) . . ?
C55 P2 C49 103.1(3) . . ?
Ag2 C1 Ag1 84.6 . . ?
C2 C1 Ag1 121.3 . . ?
C2 C1 Ag2 153.8 . . ?
C1 C2 C3 177.2 . . ?
C4 C3 C2 177.3 . . ?
C3 C4 C5 178.1 . . ?
C6 C5 C4 179.1 . . ?
C5 C6 C7 177.1 . . ?
C6 C7 H7 105.8 . . ?
C6 C7 C12 113.5(6) . . ?
C8 C7 C6 112.1(5) . . ?
C8 C7 H7 105.8 . . ?
C8 C7 C12 113.1(7) . . ?
C12 C7 H7 105.8 . . ?
C7 C8 H8A 110.1 . . ?
C7 C8 H8B 110.1 . . ?
C7 C8 C9 108.0(10) . . ?
H8A C8 H8B 108.4 . . ?
C9 C8 H8A 110.1 . . ?
C9 C8 H8B 110.1 . . ?
C8 C9 H9A 109.6 . . ?
C8 C9 H9B 109.6 . . ?
C8 C9 C10 110.3(12) . . ?
H9A C9 H9B 108.1 . . ?
C10 C9 H9A 109.6 . . ?
C10 C9 H9B 109.6 . . ?
C9 C10 H10A 111.0 . . ?
C9 C10 H10B 111.0 . . ?
H10A C10 H10B 109.0 . . ?
C11 C10 C9 103.7(16) . . ?
C11 C10 H10A 111.0 . . ?
C11 C10 H10B 111.0 . . ?
C10 C11 H11A 108.8 . . ?
C10 C11 H11B 108.8 . . ?
H11A C11 H11B 107.7 . . ?
C12 C11 C10 114.0(18) . . ?
C12 C11 H11A 108.8 . . ?
C12 C11 H11B 108.8 . . ?
C7 C12 H12A 108.4 . . ?
C7 C12 H12B 108.4 . . ?
C11 C12 C7 115.4(13) . . ?
C11 C12 H12A 108.4 . . ?
C11 C12 H12B 108.4 . . ?
H12A C12 H12B 107.5 . . ?
Ag2 C13 Ag1 88.0(2) . 2_655 ?
C14 C13 Ag1 102.8(5) . 2_655 ?
C14 C13 Ag2 166.7(6) . . ?
C13 C14 C15 176.0(8) . . ?
C16 C15 C14 175.8(9) . . ?
C15 C16 C17 177.9(9) . . ?
C18 C17 C16 178.9(10) . . ?
C17 C18 C19 177.8(16) . . ?
C18 C19 H19 110.3 . . ?
C18 C19 C20 108.2(11) . . ?
C18 C19 C24 107.4(12) . . ?
C20 C19 H19 110.3 . . ?
C24 C19 H19 110.3 . . ?
C24 C19 C20 110.3(10) . . ?
C19 C20 H20A 110.2 . . ?
C19 C20 H20B 110.2 . . ?
H20A C20 H20B 108.5 . . ?
C21 C20 C19 107.6(12) . . ?
C21 C20 H20A 110.2 . . ?
C21 C20 H20B 110.2 . . ?
C20 C21 H21A 109.2 . . ?
C20 C21 H21B 109.2 . . ?
H21A C21 H21B 107.9 . . ?
C22 C21 C20 111.8(11) . . ?
C22 C21 H21A 109.2 . . ?
C22 C21 H21B 109.2 . . ?
C21 C22 H22A 108.5 . . ?
C21 C22 H22B 108.5 . . ?
H22A C22 H22B 107.5 . . ?
C23 C22 C21 114.9(12) . . ?
C23 C22 H22A 108.5 . . ?
C23 C22 H22B 108.5 . . ?
C22 C23 H23A 108.7 . . ?
C22 C23 H23B 108.7 . . ?
C22 C23 C24 114.0(11) . . ?
H23A C23 H23B 107.6 . . ?
C24 C23 H23A 108.7 . . ?
C24 C23 H23B 108.7 . . ?
C19 C24 H24A 109.7 . . ?
C19 C24 H24B 109.7 . . ?
C23 C24 C19 109.6(12) . . ?
C23 C24 H24A 109.7 . . ?
C23 C24 H24B 109.7 . . ?
H24A C24 H24B 108.2 . . ?
C26 C25 P1 122.1(4) . . ?
C30 C25 P1 119.7(4) . . ?
C30 C25 C26 118.1(5) . . ?
C25 C26 H26 119.5 . . ?
C27 C26 C25 121.1(6) . . ?
C27 C26 H26 119.5 . . ?
C26 C27 H27 119.6 . . ?
C26 C27 C28 120.8(6) . . ?
C28 C27 H27 119.6 . . ?
C27 C28 H28 120.4 . . ?
C27 C28 C29 119.2(6) . . ?
C29 C28 H28 120.4 . . ?
C28 C29 H29 119.8 . . ?
C30 C29 C28 120.3(6) . . ?
C30 C29 H29 119.8 . . ?
C25 C30 H30 119.8 . . ?
C29 C30 C25 120.4(6) . . ?
C29 C30 H30 119.8 . . ?
C32 C31 P1 122.9(4) . . ?
C32 C31 C36 119.5(5) . . ?
C36 C31 P1 117.5(4) . . ?
C31 C32 H32 120.1 . . ?
C33 C32 C31 119.8(6) . . ?
C33 C32 H32 120.1 . . ?
C32 C33 H33 119.7 . . ?
C34 C33 C32 120.6(6) . . ?
C34 C33 H33 119.7 . . ?
C33 C34 H34 120.3 . . ?
C35 C34 C33 119.5(6) . . ?
C35 C34 H34 120.3 . . ?
C34 C35 H35 119.5 . . ?
C34 C35 C36 120.9(6) . . ?
C36 C35 H35 119.5 . . ?
C31 C36 H36 120.1 . . ?
C35 C36 C31 119.7(6) . . ?
C35 C36 H36 120.1 . . ?
C38 C37 P1 117.3(5) . . ?
C38 C37 C42 119.2(6) . . ?
C42 C37 P1 123.4(5) . . ?
C37 C38 H38 119.5 . . ?
C37 C38 C39 121.0(7) . . ?
C39 C38 H38 119.5 . . ?
C38 C39 H39 120.1 . . ?
C40 C39 C38 119.7(8) . . ?
C40 C39 H39 120.1 . . ?
C39 C40 H40 120.0 . . ?
C39 C40 C41 120.0(8) . . ?
C41 C40 H40 120.0 . . ?
C40 C41 H41 119.5 . . ?
C40 C41 C42 121.0(8) . . ?
C42 C41 H41 119.5 . . ?
C37 C42 H42 120.5 . . ?
C41 C42 C37 119.1(7) . . ?
C41 C42 H42 120.5 . . ?
C44 C43 P2 118.5(5) . . ?
C44 C43 C48 119.5(7) . . ?
C48 C43 P2 122.0(6) . . ?
C43 C44 H44 119.9 . . ?
C43 C44 C45 120.2(8) . . ?
C45 C44 H44 119.9 . . ?
C44 C45 H45 120.8 . . ?
C44 C45 C46 118.4(9) . . ?
C46 C45 H45 120.8 . . ?
C45 C46 H46 119.8 . . ?
C47 C46 C45 120.4(8) . . ?
C47 C46 H46 119.8 . . ?
C46 C47 H47 118.8 . . ?
C46 C47 C48 122.3(10) . . ?
C48 C47 H47 118.8 . . ?
C43 C48 H48 120.5 . . ?
C47 C48 C43 119.0(9) . . ?
C47 C48 H48 120.5 . . ?
C50 C49 P2 116.3(5) . . ?
C54 C49 P2 124.1(6) . . ?
C54 C49 C50 119.4(7) . . ?
C49 C50 H50 120.0 . . ?
C51 C50 C49 119.9(8) . . ?
C51 C50 H50 120.0 . . ?
C50 C51 H51 119.9 . . ?
C50 C51 C52 120.1(9) . . ?
C52 C51 H51 119.9 . . ?
C51 C52 H52 119.7 . . ?
C53 C52 C51 120.6(8) . . ?
C53 C52 H52 119.7 . . ?
C52 C53 H53 119.4 . . ?
C52 C53 C54 121.1(9) . . ?
C54 C53 H53 119.4 . . ?
C49 C54 C53 118.8(9) . . ?
C49 C54 H54 120.6 . . ?
C53 C54 H54 120.6 . . ?
C56 C55 P2 117.6(5) . . ?
C56 C55 C60 117.9(7) . . ?
C60 C55 P2 124.4(6) . . ?
C55 C56 H56 119.3 . . ?
C55 C56 C57 121.4(8) . . ?
C57 C56 H56 119.3 . . ?
C56 C57 H57 120.0 . . ?
C58 C57 C56 120.0(9) . . ?
C58 C57 H57 120.0 . . ?
C57 C58 H58 120.5 . . ?
C57 C58 C59 119.0(8) . . ?
C59 C58 H58 120.5 . . ?
C58 C59 H59 119.5 . . ?
C60 C59 C58 121.0(8) . . ?
C60 C59 H59 119.5 . . ?
C55 C60 H60 119.7 . . ?
C59 C60 C55 120.7(8) . . ?
C59 C60 H60 119.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 P1 C25 C26 154.4(4) . . . . ?
Ag1 P1 C25 C30 -21.5(6) . . . . ?
Ag1 P1 C31 C32 128.9(4) . . . . ?
Ag1 P1 C31 C36 -47.7(5) . . . . ?
Ag1 P1 C37 C38 -51.8(6) . . . . ?
Ag1 P1 C37 C42 130.1(5) . . . . ?
Ag1 P2 C43 C44 -27.4(6) . . . . ?
Ag1 P2 C43 C48 153.2(5) . . . . ?
Ag1 P2 C49 C50 -53.9(6) . . . . ?
Ag1 P2 C49 C54 122.5(6) . . . . ?
Ag1 P2 C55 C56 -23.4(6) . . . . ?
Ag1 P2 C55 C60 159.3(6) . . . . ?
P1 C25 C26 C27 -177.1(5) . . . . ?
P1 C25 C30 C29 177.8(6) . . . . ?
P1 C31 C32 C33 -177.8(4) . . . . ?
P1 C31 C36 C35 177.4(5) . . . . ?
P1 C37 C38 C39 -179.5(7) . . . . ?
P1 C37 C42 C41 179.1(5) . . . . ?
P2 C43 C44 C45 -179.5(6) . . . . ?
P2 C43 C48 C47 178.0(7) . . . . ?
P2 C49 C50 C51 176.9(6) . . . . ?
P2 C49 C54 C53 -177.1(7) . . . . ?
P2 C55 C56 C57 -175.9(7) . . . . ?
P2 C55 C60 C59 177.3(7) . . . . ?
C6 C7 C8 C9 -75.5(9) . . . . ?
C6 C7 C12 C11 75.3(14) . . . . ?
C7 C8 C9 C10 -58.8(14) . . . . ?
C8 C7 C12 C11 -53.8(17) . . . . ?
C8 C9 C10 C11 59.0(19) . . . . ?
C9 C10 C11 C12 -57(2) . . . . ?
C10 C11 C12 C7 57(2) . . . . ?
C12 C7 C8 C9 54.4(12) . . . . ?
C18 C19 C20 C21 176.1(11) . . . . ?
C18 C19 C24 C23 -175.1(13) . . . . ?
C19 C20 C21 C22 -55.0(17) . . . . ?
C20 C19 C24 C23 -57.4(17) . . . . ?
C20 C21 C22 C23 52.8(19) . . . . ?
C21 C22 C23 C24 -51(2) . . . . ?
C22 C23 C24 C19 53(2) . . . . ?
C24 C19 C20 C21 58.8(15) . . . . ?
C25 P1 C31 C32 1.5(5) . . . . ?
C25 P1 C31 C36 -175.0(4) . . . . ?
C25 P1 C37 C38 76.6(6) . . . . ?
C25 P1 C37 C42 -101.5(6) . . . . ?
C25 C26 C27 C28 1.9(11) . . . . ?
C26 C25 C30 C29 1.7(10) . . . . ?
C26 C27 C28 C29 -3.0(12) . . . . ?
C27 C28 C29 C30 3.6(12) . . . . ?
C28 C29 C30 C25 -3.0(12) . . . . ?
C30 C25 C26 C27 -1.2(10) . . . . ?
C31 P1 C25 C26 -82.2(5) . . . . ?
C31 P1 C25 C30 101.9(5) . . . . ?
C31 P1 C37 C38 -174.5(5) . . . . ?
C31 P1 C37 C42 7.5(6) . . . . ?
C31 C32 C33 C34 1.1(9) . . . . ?
C32 C31 C36 C35 0.7(8) . . . . ?
C32 C33 C34 C35 -0.2(10) . . . . ?
C33 C34 C35 C36 -0.4(10) . . . . ?
C34 C35 C36 C31 0.1(9) . . . . ?
C36 C31 C32 C33 -1.3(8) . . . . ?
C37 P1 C25 C26 26.7(6) . . . . ?
C37 P1 C25 C30 -149.2(5) . . . . ?
C37 P1 C31 C32 -105.2(5) . . . . ?
C37 P1 C31 C36 78.3(5) . . . . ?
C37 C38 C39 C40 1.5(14) . . . . ?
C38 C37 C42 C41 1.1(10) . . . . ?
C38 C39 C40 C41 -1.4(14) . . . . ?
C39 C40 C41 C42 1.2(13) . . . . ?
C40 C41 C42 C37 -1.1(12) . . . . ?
C42 C37 C38 C39 -1.3(11) . . . . ?
C43 P2 C49 C50 70.8(6) . . . . ?
C43 P2 C49 C54 -112.9(7) . . . . ?
C43 P2 C55 C56 -153.0(6) . . . . ?
C43 P2 C55 C60 29.8(7) . . . . ?
C43 C44 C45 C46 0.3(12) . . . . ?
C44 C43 C48 C47 -1.4(12) . . . . ?
C44 C45 C46 C47 1.0(14) . . . . ?
C45 C46 C47 C48 -2.6(16) . . . . ?
C46 C47 C48 C43 2.8(14) . . . . ?
C48 C43 C44 C45 -0.1(11) . . . . ?
C49 P2 C43 C44 -149.9(5) . . . . ?
C49 P2 C43 C48 30.7(7) . . . . ?
C49 P2 C55 C56 99.8(6) . . . . ?
C49 P2 C55 C60 -77.5(7) . . . . ?
C49 C50 C51 C52 -0.4(13) . . . . ?
C50 C49 C54 C53 -0.9(12) . . . . ?
C50 C51 C52 C53 1.0(16) . . . . ?
C51 C52 C53 C54 -1.5(17) . . . . ?
C52 C53 C54 C49 1.5(15) . . . . ?
C54 C49 C50 C51 0.4(11) . . . . ?
C55 P2 C43 C44 102.3(6) . . . . ?
C55 P2 C43 C48 -77.0(7) . . . . ?
C55 P2 C49 C50 -179.4(5) . . . . ?
C55 P2 C49 C54 -3.0(7) . . . . ?
C55 C56 C57 C58 -0.9(15) . . . . ?
C56 C55 C60 C59 0.1(13) . . . . ?
C56 C57 C58 C59 -1.3(15) . . . . ?
C57 C58 C59 C60 3.0(15) . . . . ?
C58 C59 C60 C55 -2.4(15) . . . . ?
C60 C55 C56 C57 1.6(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
