# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Compound_1a
_database_code_depnum_ccdc_archive 'CCDC 1486160'
_audit_update_record             
;
2017-07-06 deposited with the CCDC.
2017-07-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H31 Eu N O8 P'
_chemical_formula_weight         860.61

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0047 0.0022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0089 0.0045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0150 0.0081 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1264 0.1222 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.0675 4.5357 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           54
_space_group_name_H-M_alt        'P c c a'
_space_group_name_Hall           '-P 2a 2ac'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z'
'-x, y, -z+1/2'
'x+1/2, -y, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z'
'x, -y, z-1/2'
'-x-1/2, y, z-1/2'

_cell_length_a                   36.202(7)
_cell_length_b                   15.391(3)
_cell_length_c                   29.655(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     16523(6)
_cell_formula_units_Z            8
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    45205
_cell_measurement_theta_min      1.793
_cell_measurement_theta_max      35.397

_exptl_crystal_description       plate
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    0.692
_exptl_crystal_F_000             3456
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.050
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.030
_exptl_absorpt_coefficient_mu    1.088
_shelx_estimated_absorpt_T_min   0.948
_shelx_estimated_absorpt_T_max   0.968
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     0.800
_diffrn_radiation_type           Synchrotron
_diffrn_source                   'SPring-8 BL38B1'
_diffrn_measurement_device_type  MX225HE
_diffrn_measurement_method       'phi scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            45205
_diffrn_reflns_av_unetI/netI     0.0493
_diffrn_reflns_av_R_equivalents  0.0474
_diffrn_reflns_limit_h_min       -52
_diffrn_reflns_limit_h_max       52
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_theta_min         1.793
_diffrn_reflns_theta_max         35.397
_diffrn_reflns_theta_full        28.685
_diffrn_measured_fraction_theta_max 0.900
_diffrn_measured_fraction_theta_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.900
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.900
_diffrn_reflns_point_group_measured_fraction_full 0.992
_reflns_number_total             23666
_reflns_number_gt                17139
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       HKL2000
_computing_cell_refinement       HKL2000
_computing_data_reduction        HKL2000
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'SHELXLE (Hübschle et al., 2011)'
_refine_special_details          ', SQUEEZE'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1712P)²+8.3150P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         23666
_refine_ls_number_parameters     478
_refine_ls_number_restraints     93
_refine_ls_R_factor_all          0.0661
_refine_ls_R_factor_gt           0.0515
_refine_ls_wR_factor_ref         0.1798
_refine_ls_wR_factor_gt          0.1599
_refine_ls_goodness_of_fit_ref   0.718
_refine_ls_restrained_S_all      0.719
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.87578(9) 0.9593(2) 0.96020(12) 0.0616(8) Uani 1 1 d . . . . .
C2 C 0.83745(8) 0.9268(3) 0.95089(12) 0.0676(8) Uani 1 1 d . . . . .
C3 C 0.82253(11) 0.9299(4) 0.90861(15) 0.0927(13) Uani 1 1 d . . . . .
H1 H 0.836933 0.949313 0.884670 0.111 Uiso 1 1 calc R U . . .
C4 C 0.78611(11) 0.9045(4) 0.90065(14) 0.0925(14) Uani 1 1 d . . . . .
H2 H 0.776302 0.909580 0.871780 0.111 Uiso 1 1 calc R U . . .
C5 C 0.76448(9) 0.8721(3) 0.93496(12) 0.0683(8) Uani 1 1 d . . . . .
C6 C 0.78007(13) 0.8659(5) 0.97731(16) 0.124(3) Uani 1 1 d . . . . .
H3 H 0.766344 0.843009 1.001014 0.149 Uiso 1 1 calc R U . . .
C7 C 0.81616(13) 0.8935(5) 0.98484(14) 0.114(2) Uani 1 1 d . . . . .
H4 H 0.826052 0.889224 1.013698 0.137 Uiso 1 1 calc R U . . .
C8 C 0.72504(8) 0.8470(2) 0.92694(11) 0.0646(8) Uani 1 1 d . . . . .
C9 C 0.71298(9) 0.8177(3) 0.88590(13) 0.0836(12) Uani 1 1 d . . . . .
H5 H 0.729835 0.810939 0.862498 0.100 Uiso 1 1 calc R U . . .
C10 C 0.67560(9) 0.7977(3) 0.87851(11) 0.0752(10) Uani 1 1 d . . . . .
H6 H 0.667858 0.777979 0.850412 0.090 Uiso 1 1 calc R U . . .
C11 C 0.65074(7) 0.80723(18) 0.91266(9) 0.0498(6) Uani 1 1 d . . . . .
C12 C 0.66270(9) 0.8361(3) 0.95462(11) 0.0731(10) Uani 1 1 d . . . . .
H7 H 0.645889 0.843371 0.978028 0.088 Uiso 1 1 calc R U . . .
C13 C 0.70002(10) 0.8541(3) 0.96142(12) 0.0835(12) Uani 1 1 d . . . . .
H8 H 0.708072 0.871266 0.989837 0.100 Uiso 1 1 calc R U . . .
O1 O 0.89681(6) 0.97704(17) 0.92837(8) 0.0668(6) Uani 1 1 d . . . . .
O2 O 0.88477(7) 0.9734(2) 1.00065(11) 0.0903(9) Uani 1 1 d . . . . .
C14 C 0.51990(8) 0.9684(2) 0.58342(9) 0.0540(6) Uani 1 1 d . . . . .
C15 C 0.53364(9) 0.9410(2) 0.62933(10) 0.0602(7) Uani 1 1 d . . . . .
C16 C 0.56577(12) 0.9724(4) 0.64659(14) 0.0933(15) Uani 1 1 d . . . . .
H9 H 0.579596 1.011596 0.629735 0.112 Uiso 1 1 calc R U . . .
C17 C 0.57842(12) 0.9471(3) 0.68883(14) 0.0917(14) Uani 1 1 d . . . . .
H10 H 0.600296 0.970129 0.700122 0.110 Uiso 1 1 calc R U . . .
C18 C 0.55854(8) 0.8879(3) 0.71410(11) 0.0651(8) Uani 1 1 d . . . . .
C19 C 0.52647(11) 0.8546(3) 0.69618(12) 0.0863(13) Uani 1 1 d . . . . .
H11 H 0.513221 0.813241 0.712358 0.104 Uiso 1 1 calc R U . . .
C20 C 0.51351(10) 0.8815(3) 0.65436(11) 0.0765(10) Uani 1 1 d . . . . .
H12 H 0.491369 0.859746 0.643191 0.092 Uiso 1 1 calc R U . . .
C21 C 0.57089(9) 0.8608(2) 0.75986(10) 0.0636(8) Uani 1 1 d . . . . .
C22 C 0.58599(13) 0.9211(3) 0.78965(13) 0.0880(13) Uani 1 1 d . . . . .
H13 H 0.589506 0.978126 0.780276 0.106 Uiso 1 1 calc R U . . .
C23 C 0.59582(11) 0.8973(2) 0.83288(11) 0.0781(11) Uani 1 1 d . . . . .
H14 H 0.605589 0.938598 0.852407 0.094 Uiso 1 1 calc R U . . .
C24 C 0.59128(7) 0.81234(19) 0.84749(9) 0.0508(6) Uani 1 1 d . . . . .
C25 C 0.57647(11) 0.7529(2) 0.81842(11) 0.0708(9) Uani 1 1 d . . . . .
H15 H 0.573147 0.695683 0.827650 0.085 Uiso 1 1 calc R U . . .
C26 C 0.56635(12) 0.7779(3) 0.77497(12) 0.0777(10) Uani 1 1 d . . . . .
H16 H 0.556187 0.736633 0.755679 0.093 Uiso 1 1 calc R U . . .
O3 O 0.48679(7) 0.95280(17) 0.57388(8) 0.0711(7) Uani 1 1 d . . . . .
O4 O 0.54228(7) 1.0070(2) 0.55862(7) 0.0769(7) Uani 1 1 d . . . . .
C27 C 0.51702(10) 0.1615(2) 0.98058(10) 0.0578(7) Uani 1 1 d . . . . .
C28 C 0.53065(9) 0.2499(2) 0.96600(11) 0.0609(7) Uani 1 1 d . . . . .
C29 C 0.50654(10) 0.3186(2) 0.96205(14) 0.0731(9) Uani 1 1 d . . . . .
H17 H 0.481453 0.309680 0.966941 0.088 Uiso 1 1 calc R U . . .
C30 C 0.51902(10) 0.4004(2) 0.95095(14) 0.0765(10) Uani 1 1 d . . . . .
H18 H 0.502124 0.445650 0.948217 0.092 Uiso 1 1 calc R U . . .
C31 C 0.55622(9) 0.4168(2) 0.94376(13) 0.0660(9) Uani 1 1 d . . . . .
C32 C 0.58033(10) 0.3470(2) 0.94605(16) 0.0820(11) Uani 1 1 d . . . . .
H19 H 0.605302 0.355590 0.940214 0.098 Uiso 1 1 calc R U . . .
C33 C 0.56767(11) 0.2640(2) 0.95697(15) 0.0777(11) Uani 1 1 d . . . . .
H20 H 0.584230 0.217860 0.958184 0.093 Uiso 1 1 calc R U . . .
C34 C 0.56899(10) 0.5060(2) 0.93359(12) 0.0627(7) Uani 1 1 d . . . . .
C35 C 0.54968(14) 0.5766(3) 0.95131(18) 0.0990(16) Uani 1 1 d . . . . .
H21 H 0.528879 0.566933 0.969007 0.119 Uiso 1 1 calc R U . . .
C36 C 0.56114(11) 0.6614(2) 0.94285(16) 0.0833(13) Uani 1 1 d . . . . .
H22 H 0.548426 0.707756 0.955621 0.100 Uiso 1 1 calc R U . . .
C37 C 0.59125(8) 0.67673(18) 0.91560(9) 0.0506(5) Uani 1 1 d . U . . .
C38 C 0.61055(10) 0.6081(2) 0.89809(14) 0.0742(10) Uani 1 1 d . U . . .
H23 H 0.631284 0.618160 0.880313 0.089 Uiso 1 1 calc R U . . .
C39 C 0.59911(10) 0.5228(2) 0.90690(14) 0.0753(10) Uani 1 1 d . U . . .
H24 H 0.612186 0.476685 0.894405 0.090 Uiso 1 1 calc R U . . .
O5 O 0.53883(9) 0.10047(17) 0.97859(10) 0.0844(8) Uani 1 1 d . . . . .
O6 O 0.48444(7) 0.15717(16) 0.99342(9) 0.0719(6) Uani 1 1 d . . . . .
P1 P 0.60203(2) 0.78922(4) 0.90552(2) 0.04450(14) Uani 1 1 d . U . . .
O7 O 0.58025(6) 0.84370(13) 0.93738(7) 0.0550(4) Uani 1 1 d . U . . .
C40 C 0.4182(3) 0.8162(6) 0.4340(3) 0.179(4) Uani 1 1 d . U . . .
H25 H 0.438752 0.840152 0.419841 0.215 Uiso 1 1 calc R U . . .
C41 C 0.3853(6) 0.6746(13) 0.4454(8) 0.402(12) Uani 1 1 d . U . . .
H26 H 0.377304 0.629080 0.425521 0.602 Uiso 1 1 calc R U . . .
H27 H 0.402437 0.651437 0.466977 0.602 Uiso 1 1 calc R U . . .
H28 H 0.364374 0.698537 0.460819 0.602 Uiso 1 1 calc R U . . .
C42 C 0.4232(7) 0.7095(17) 0.3741(6) 0.498(15) Uani 1 1 d . U . . .
H29 H 0.409480 0.658819 0.365300 0.747 Uiso 1 1 calc R U . . .
H30 H 0.422904 0.751056 0.349989 0.747 Uiso 1 1 calc R U . . .
H31 H 0.448194 0.693409 0.380751 0.747 Uiso 1 1 calc R U . . .
N1 N 0.4053(4) 0.7499(11) 0.4164(5) 0.341(7) Uani 1 1 d . U . . .
O8 O 0.40751(9) 0.8535(2) 0.46724(10) 0.0945(9) Uani 1 1 d . U . . .
Eu1 Eu 0.44281(2) 0.95519(2) 0.51612(2) 0.04394(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.243(4) . ?
C1 O2 1.262(5) . ?
C1 C2 1.501(4) . ?
C1 Eu1 2.848(3) 4_576 ?
C2 C3 1.366(5) . ?
C2 C7 1.367(5) . ?
C3 C4 1.395(5) . ?
C3 H1 0.9300 . ?
C4 C5 1.377(5) . ?
C4 H2 0.9300 . ?
C5 C6 1.380(6) . ?
C5 C8 1.499(4) . ?
C6 C7 1.392(6) . ?
C6 H3 0.9300 . ?
C7 H4 0.9300 . ?
C8 C9 1.369(5) . ?
C8 C13 1.370(5) . ?
C9 C10 1.405(4) . ?
C9 H5 0.9300 . ?
C10 C11 1.363(4) . ?
C10 H6 0.9300 . ?
C11 C12 1.390(4) . ?
C11 P1 1.797(3) . ?
C12 C13 1.394(4) . ?
C12 H7 0.9300 . ?
C13 H8 0.9300 . ?
O1 Eu1 2.564(2) 4_576 ?
O2 Eu1 2.423(3) 4_576 ?
C14 O4 1.245(4) . ?
C14 O3 1.255(4) . ?
C14 C15 1.510(4) . ?
C15 C16 1.360(5) . ?
C15 C20 1.385(5) . ?
C16 C17 1.389(5) . ?
C16 H9 0.9300 . ?
C17 C18 1.382(5) . ?
C17 H10 0.9300 . ?
C18 C19 1.376(5) . ?
C18 C21 1.488(4) . ?
C19 C20 1.389(4) . ?
C19 H11 0.9300 . ?
C20 H12 0.9300 . ?
C21 C26 1.363(5) . ?
C21 C22 1.392(5) . ?
C22 C23 1.380(4) . ?
C22 H13 0.9300 . ?
C23 C24 1.387(4) . ?
C23 H14 0.9300 . ?
C24 C25 1.367(4) . ?
C24 P1 1.800(3) . ?
C25 C26 1.394(5) . ?
C25 H15 0.9300 . ?
C26 H16 0.9300 . ?
O3 Eu1 2.339(2) . ?
O4 Eu1 2.354(2) 5_676 ?
C27 O5 1.229(4) . ?
C27 O6 1.241(4) . ?
C27 C28 1.510(4) . ?
C28 C29 1.376(5) . ?
C28 C33 1.384(5) . ?
C29 C30 1.378(4) . ?
C29 H17 0.9300 . ?
C30 C31 1.387(5) . ?
C30 H18 0.9300 . ?
C31 C32 1.386(5) . ?
C31 C34 1.479(4) . ?
C32 C33 1.395(5) . ?
C32 H19 0.9300 . ?
C33 H20 0.9300 . ?
C34 C39 1.372(4) . ?
C34 C35 1.395(6) . ?
C35 C36 1.392(5) . ?
C35 H21 0.9300 . ?
C36 C37 1.378(4) . ?
C36 H22 0.9300 . ?
C37 C38 1.368(5) . ?
C37 P1 1.800(3) . ?
C38 C39 1.402(4) . ?
C38 H23 0.9300 . ?
C39 H24 0.9300 . ?
O5 Eu1 2.338(3) 3_646 ?
O6 Eu1 2.391(2) 7_566 ?
P1 O7 1.489(2) . ?
O7 Eu1 2.355(2) 3_656 ?
C40 O8 1.205(8) . ?
C40 N1 1.238(12) . ?
C40 H25 0.9300 . ?
C41 N1 1.61(2) . ?
C41 H26 0.9600 . ?
C41 H27 0.9600 . ?
C41 H28 0.9600 . ?
C42 N1 1.540(19) . ?
C42 H29 0.9600 . ?
C42 H30 0.9600 . ?
C42 H31 0.9600 . ?
O8 Eu1 2.487(3) . ?
Eu1 Eu1 4.4680(8) 5_676 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 O2 121.8(3) . . ?
O1 C1 C2 120.0(3) . . ?
O2 C1 C2 118.1(3) . . ?
O1 C1 Eu1 64.16(15) . 4_576 ?
O2 C1 Eu1 57.75(16) . 4_576 ?
C2 C1 Eu1 170.8(3) . 4_576 ?
C3 C2 C7 117.8(3) . . ?
C3 C2 C1 121.5(3) . . ?
C7 C2 C1 120.7(3) . . ?
C2 C3 C4 121.3(4) . . ?
C2 C3 H1 119.4 . . ?
C4 C3 H1 119.4 . . ?
C5 C4 C3 120.9(4) . . ?
C5 C4 H2 119.6 . . ?
C3 C4 H2 119.6 . . ?
C4 C5 C6 117.7(3) . . ?
C4 C5 C8 121.2(3) . . ?
C6 C5 C8 121.1(3) . . ?
C5 C6 C7 120.6(4) . . ?
C5 C6 H3 119.7 . . ?
C7 C6 H3 119.7 . . ?
C2 C7 C6 121.7(4) . . ?
C2 C7 H4 119.2 . . ?
C6 C7 H4 119.2 . . ?
C9 C8 C13 118.6(3) . . ?
C9 C8 C5 122.0(3) . . ?
C13 C8 C5 119.4(3) . . ?
C8 C9 C10 121.2(3) . . ?
C8 C9 H5 119.4 . . ?
C10 C9 H5 119.4 . . ?
C11 C10 C9 119.8(3) . . ?
C11 C10 H6 120.1 . . ?
C9 C10 H6 120.1 . . ?
C10 C11 C12 119.6(3) . . ?
C10 C11 P1 122.9(2) . . ?
C12 C11 P1 117.4(2) . . ?
C11 C12 C13 119.7(3) . . ?
C11 C12 H7 120.2 . . ?
C13 C12 H7 120.2 . . ?
C8 C13 C12 121.1(3) . . ?
C8 C13 H8 119.4 . . ?
C12 C13 H8 119.4 . . ?
C1 O1 Eu1 89.97(19) . 4_576 ?
C1 O2 Eu1 96.1(2) . 4_576 ?
O4 C14 O3 125.4(3) . . ?
O4 C14 C15 116.9(3) . . ?
O3 C14 C15 117.7(3) . . ?
C16 C15 C20 118.9(3) . . ?
C16 C15 C14 121.5(3) . . ?
C20 C15 C14 119.7(3) . . ?
C15 C16 C17 121.5(4) . . ?
C15 C16 H9 119.3 . . ?
C17 C16 H9 119.3 . . ?
C18 C17 C16 120.1(4) . . ?
C18 C17 H10 119.9 . . ?
C16 C17 H10 119.9 . . ?
C19 C18 C17 118.4(3) . . ?
C19 C18 C21 120.1(3) . . ?
C17 C18 C21 121.5(3) . . ?
C18 C19 C20 121.2(3) . . ?
C18 C19 H11 119.4 . . ?
C20 C19 H11 119.4 . . ?
C15 C20 C19 119.9(3) . . ?
C15 C20 H12 120.1 . . ?
C19 C20 H12 120.1 . . ?
C26 C21 C22 117.6(3) . . ?
C26 C21 C18 121.7(3) . . ?
C22 C21 C18 120.7(3) . . ?
C23 C22 C21 120.9(3) . . ?
C23 C22 H13 119.5 . . ?
C21 C22 H13 119.5 . . ?
C22 C23 C24 120.6(3) . . ?
C22 C23 H14 119.7 . . ?
C24 C23 H14 119.7 . . ?
C25 C24 C23 118.7(3) . . ?
C25 C24 P1 123.8(2) . . ?
C23 C24 P1 117.3(2) . . ?
C24 C25 C26 120.1(3) . . ?
C24 C25 H15 119.9 . . ?
C26 C25 H15 119.9 . . ?
C21 C26 C25 122.0(3) . . ?
C21 C26 H16 119.0 . . ?
C25 C26 H16 119.0 . . ?
C14 O3 Eu1 144.3(2) . . ?
C14 O4 Eu1 145.4(2) . 5_676 ?
O5 C27 O6 125.7(3) . . ?
O5 C27 C28 117.7(3) . . ?
O6 C27 C28 116.6(3) . . ?
C29 C28 C33 118.5(3) . . ?
C29 C28 C27 120.6(3) . . ?
C33 C28 C27 120.9(3) . . ?
C28 C29 C30 121.0(3) . . ?
C28 C29 H17 119.5 . . ?
C30 C29 H17 119.5 . . ?
C29 C30 C31 121.4(3) . . ?
C29 C30 H18 119.3 . . ?
C31 C30 H18 119.3 . . ?
C32 C31 C30 117.6(3) . . ?
C32 C31 C34 122.2(3) . . ?
C30 C31 C34 120.2(3) . . ?
C31 C32 C33 121.0(3) . . ?
C31 C32 H19 119.5 . . ?
C33 C32 H19 119.5 . . ?
C28 C33 C32 120.4(3) . . ?
C28 C33 H20 119.8 . . ?
C32 C33 H20 119.8 . . ?
C39 C34 C35 117.9(3) . . ?
C39 C34 C31 122.8(3) . . ?
C35 C34 C31 119.3(3) . . ?
C36 C35 C34 120.9(3) . . ?
C36 C35 H21 119.6 . . ?
C34 C35 H21 119.6 . . ?
C37 C36 C35 120.2(3) . . ?
C37 C36 H22 119.9 . . ?
C35 C36 H22 119.9 . . ?
C38 C37 C36 119.6(3) . . ?
C38 C37 P1 124.6(2) . . ?
C36 C37 P1 115.7(2) . . ?
C37 C38 C39 120.1(3) . . ?
C37 C38 H23 120.0 . . ?
C39 C38 H23 120.0 . . ?
C34 C39 C38 121.3(3) . . ?
C34 C39 H24 119.4 . . ?
C38 C39 H24 119.4 . . ?
C27 O5 Eu1 155.6(3) . 3_646 ?
C27 O6 Eu1 136.4(2) . 7_566 ?
O7 P1 C11 110.97(13) . . ?
O7 P1 C37 108.76(13) . . ?
C11 P1 C37 109.97(13) . . ?
O7 P1 C24 112.38(13) . . ?
C11 P1 C24 107.11(12) . . ?
C37 P1 C24 107.58(13) . . ?
P1 O7 Eu1 165.88(12) . 3_656 ?
O8 C40 N1 128.1(10) . . ?
O8 C40 H25 116.0 . . ?
N1 C40 H25 116.0 . . ?
N1 C41 H26 109.5 . . ?
N1 C41 H27 109.5 . . ?
H26 C41 H27 109.5 . . ?
N1 C41 H28 109.5 . . ?
H26 C41 H28 109.5 . . ?
H27 C41 H28 109.5 . . ?
N1 C42 H29 109.5 . . ?
N1 C42 H30 109.5 . . ?
H29 C42 H30 109.5 . . ?
N1 C42 H31 109.5 . . ?
H29 C42 H31 109.5 . . ?
H30 C42 H31 109.5 . . ?
C40 N1 C42 121.2(15) . . ?
C40 N1 C41 122.4(13) . . ?
C42 N1 C41 109.4(17) . . ?
C40 O8 Eu1 127.7(5) . . ?
O5 Eu1 O3 76.83(10) 3_666 . ?
O5 Eu1 O4 76.22(11) 3_666 5_676 ?
O3 Eu1 O4 122.50(9) . 5_676 ?
O5 Eu1 O7 139.33(9) 3_666 3_656 ?
O3 Eu1 O7 78.52(8) . 3_656 ?
O4 Eu1 O7 144.37(10) 5_676 3_656 ?
O5 Eu1 O6 122.10(10) 3_666 7_565 ?
O3 Eu1 O6 76.45(10) . 7_565 ?
O4 Eu1 O6 76.65(10) 5_676 7_565 ?
O7 Eu1 O6 82.03(8) 3_656 7_565 ?
O5 Eu1 O2 80.02(12) 3_666 4_476 ?
O3 Eu1 O2 138.40(10) . 4_476 ?
O4 Eu1 O2 83.89(10) 5_676 4_476 ?
O7 Eu1 O2 98.24(10) 3_656 4_476 ?
O6 Eu1 O2 144.80(11) 7_565 4_476 ?
O5 Eu1 O8 141.94(12) 3_666 . ?
O3 Eu1 O8 140.06(11) . . ?
O4 Eu1 O8 74.02(11) 5_676 . ?
O7 Eu1 O8 72.57(10) 3_656 . ?
O6 Eu1 O8 72.81(11) 7_565 . ?
O2 Eu1 O8 73.76(12) 4_476 . ?
O5 Eu1 O1 75.67(10) 3_666 4_476 ?
O3 Eu1 O1 88.75(9) . 4_476 ?
O4 Eu1 O1 130.77(9) 5_676 4_476 ?
O7 Eu1 O1 71.94(8) 3_656 4_476 ?
O6 Eu1 O1 152.21(9) 7_565 4_476 ?
O2 Eu1 O1 51.97(9) 4_476 4_476 ?
O8 Eu1 O1 107.26(10) . 4_476 ?
O5 Eu1 C1 77.52(10) 3_666 4_476 ?
O3 Eu1 C1 113.99(10) . 4_476 ?
O4 Eu1 C1 108.27(10) 5_676 4_476 ?
O7 Eu1 C1 83.69(9) 3_656 4_476 ?
O6 Eu1 C1 160.17(10) 7_565 4_476 ?
O2 Eu1 C1 26.14(11) 4_476 4_476 ?
O8 Eu1 C1 89.82(11) . 4_476 ?
O1 Eu1 C1 25.87(9) 4_476 4_476 ?
O5 Eu1 Eu1 57.02(8) 3_666 5_676 ?
O3 Eu1 Eu1 62.01(7) . 5_676 ?
O4 Eu1 Eu1 60.65(7) 5_676 5_676 ?
O7 Eu1 Eu1 132.76(5) 3_656 5_676 ?
O6 Eu1 Eu1 65.09(7) 7_565 5_676 ?
O2 Eu1 Eu1 128.30(9) 4_476 5_676 ?
O8 Eu1 Eu1 123.08(7) . 5_676 ?
O1 Eu1 Eu1 127.87(6) 4_476 5_676 ?
C1 Eu1 Eu1 134.41(7) 4_476 5_676 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 -11.5(6) . . . . ?
O2 C1 C2 C3 163.9(4) . . . . ?
O1 C1 C2 C7 169.1(5) . . . . ?
O2 C1 C2 C7 -15.6(7) . . . . ?
C7 C2 C3 C4 3.5(8) . . . . ?
C1 C2 C3 C4 -176.0(5) . . . . ?
C2 C3 C4 C5 -2.7(9) . . . . ?
C3 C4 C5 C6 0.1(8) . . . . ?
C3 C4 C5 C8 178.3(5) . . . . ?
C4 C5 C6 C7 1.5(10) . . . . ?
C8 C5 C6 C7 -176.8(6) . . . . ?
C3 C2 C7 C6 -1.8(10) . . . . ?
C1 C2 C7 C6 177.6(6) . . . . ?
C5 C6 C7 C2 -0.6(12) . . . . ?
C4 C5 C8 C9 29.6(6) . . . . ?
C6 C5 C8 C9 -152.2(6) . . . . ?
C4 C5 C8 C13 -149.7(5) . . . . ?
C6 C5 C8 C13 28.4(7) . . . . ?
C13 C8 C9 C10 1.9(7) . . . . ?
C5 C8 C9 C10 -177.5(4) . . . . ?
C8 C9 C10 C11 -0.1(7) . . . . ?
C9 C10 C11 C12 -0.5(6) . . . . ?
C9 C10 C11 P1 176.3(3) . . . . ?
C10 C11 C12 C13 -0.6(6) . . . . ?
P1 C11 C12 C13 -177.7(3) . . . . ?
C9 C8 C13 C12 -3.1(7) . . . . ?
C5 C8 C13 C12 176.3(4) . . . . ?
C11 C12 C13 C8 2.5(7) . . . . ?
O2 C1 O1 Eu1 -4.4(4) . . . 4_576 ?
C2 C1 O1 Eu1 170.8(3) . . . 4_576 ?
O1 C1 O2 Eu1 4.7(4) . . . 4_576 ?
C2 C1 O2 Eu1 -170.6(3) . . . 4_576 ?
O4 C14 C15 C16 13.6(5) . . . . ?
O3 C14 C15 C16 -164.5(4) . . . . ?
O4 C14 C15 C20 -165.5(4) . . . . ?
O3 C14 C15 C20 16.5(5) . . . . ?
C20 C15 C16 C17 -1.0(8) . . . . ?
C14 C15 C16 C17 180.0(4) . . . . ?
C15 C16 C17 C18 0.9(8) . . . . ?
C16 C17 C18 C19 0.6(8) . . . . ?
C16 C17 C18 C21 -178.7(5) . . . . ?
C17 C18 C19 C20 -2.1(7) . . . . ?
C21 C18 C19 C20 177.2(4) . . . . ?
C16 C15 C20 C19 -0.5(7) . . . . ?
C14 C15 C20 C19 178.5(4) . . . . ?
C18 C19 C20 C15 2.1(7) . . . . ?
C19 C18 C21 C26 37.1(6) . . . . ?
C17 C18 C21 C26 -143.6(5) . . . . ?
C19 C18 C21 C22 -139.9(5) . . . . ?
C17 C18 C21 C22 39.5(6) . . . . ?
C26 C21 C22 C23 -0.2(7) . . . . ?
C18 C21 C22 C23 176.8(4) . . . . ?
C21 C22 C23 C24 0.8(7) . . . . ?
C22 C23 C24 C25 -0.8(6) . . . . ?
C22 C23 C24 P1 -176.0(4) . . . . ?
C23 C24 C25 C26 0.2(6) . . . . ?
P1 C24 C25 C26 175.1(3) . . . . ?
C22 C21 C26 C25 -0.3(6) . . . . ?
C18 C21 C26 C25 -177.3(4) . . . . ?
C24 C25 C26 C21 0.4(7) . . . . ?
O4 C14 O3 Eu1 9.9(6) . . . . ?
C15 C14 O3 Eu1 -172.3(3) . . . . ?
O3 C14 O4 Eu1 -23.8(7) . . . 5_676 ?
C15 C14 O4 Eu1 158.3(3) . . . 5_676 ?
O5 C27 C28 C29 171.9(4) . . . . ?
O6 C27 C28 C29 -7.8(5) . . . . ?
O5 C27 C28 C33 -9.1(5) . . . . ?
O6 C27 C28 C33 171.2(3) . . . . ?
C33 C28 C29 C30 -2.3(6) . . . . ?
C27 C28 C29 C30 176.7(4) . . . . ?
C28 C29 C30 C31 -0.6(7) . . . . ?
C29 C30 C31 C32 3.0(7) . . . . ?
C29 C30 C31 C34 -177.7(4) . . . . ?
C30 C31 C32 C33 -2.5(7) . . . . ?
C34 C31 C32 C33 178.2(4) . . . . ?
C29 C28 C33 C32 2.8(6) . . . . ?
C27 C28 C33 C32 -176.3(4) . . . . ?
C31 C32 C33 C28 -0.3(7) . . . . ?
C32 C31 C34 C39 30.4(6) . . . . ?
C30 C31 C34 C39 -148.9(4) . . . . ?
C32 C31 C34 C35 -150.2(5) . . . . ?
C30 C31 C34 C35 30.5(6) . . . . ?
C39 C34 C35 C36 -1.3(8) . . . . ?
C31 C34 C35 C36 179.3(5) . . . . ?
C34 C35 C36 C37 1.9(8) . . . . ?
C35 C36 C37 C38 -2.1(7) . . . . ?
C35 C36 C37 P1 177.6(4) . . . . ?
C36 C37 C38 C39 1.7(6) . . . . ?
P1 C37 C38 C39 -178.0(3) . . . . ?
C35 C34 C39 C38 0.9(7) . . . . ?
C31 C34 C39 C38 -179.7(4) . . . . ?
C37 C38 C39 C34 -1.1(7) . . . . ?
O6 C27 O5 Eu1 4.5(9) . . . 3_646 ?
C28 C27 O5 Eu1 -175.2(5) . . . 3_646 ?
O5 C27 O6 Eu1 -4.6(6) . . . 7_566 ?
C28 C27 O6 Eu1 175.1(2) . . . 7_566 ?
C10 C11 P1 O7 -151.3(3) . . . . ?
C12 C11 P1 O7 25.6(3) . . . . ?
C10 C11 P1 C37 88.3(3) . . . . ?
C12 C11 P1 C37 -94.8(3) . . . . ?
C10 C11 P1 C24 -28.3(3) . . . . ?
C12 C11 P1 C24 148.6(3) . . . . ?
C38 C37 P1 O7 -168.3(3) . . . . ?
C36 C37 P1 O7 12.1(3) . . . . ?
C38 C37 P1 C11 -46.6(3) . . . . ?
C36 C37 P1 C11 133.8(3) . . . . ?
C38 C37 P1 C24 69.7(3) . . . . ?
C36 C37 P1 C24 -109.9(3) . . . . ?
C25 C24 P1 O7 -117.8(3) . . . . ?
C23 C24 P1 O7 57.2(3) . . . . ?
C25 C24 P1 C11 120.1(3) . . . . ?
C23 C24 P1 C11 -64.9(3) . . . . ?
C25 C24 P1 C37 1.9(3) . . . . ?
C23 C24 P1 C37 176.9(3) . . . . ?
C11 P1 O7 Eu1 37.5(6) . . . 3_656 ?
C37 P1 O7 Eu1 158.6(5) . . . 3_656 ?
C24 P1 O7 Eu1 -82.4(5) . . . 3_656 ?
O8 C40 N1 C42 -178.7(16) . . . . ?
O8 C40 N1 C41 -31(3) . . . . ?
N1 C40 O8 Eu1 159.1(13) . . . . ?

_refine_diff_density_max         1.248
_refine_diff_density_min         -0.989
_refine_diff_density_rms         0.086



_exptl_crystal_preparation       ', Luminescent'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Compound_1b
_database_code_depnum_ccdc_archive 'CCDC 1486159'
_audit_update_record             
;
2017-07-06 deposited with the CCDC.
2017-07-06 downloaded from the CCDC.
;

# start Validation Reply Form
_vrf_PLAT029_1b                  
;
PROBLEM: _diffrn_measured_fraction_theta_full value Low 
.......      0.924
RESPONSE: Data were collected from an unstable crystal 
which was sealed in a cappilary glass.
Although repeated recrystallization and data collection 
were attempted, but this structure represents the best 
of the all.
;
# end Validation Reply Form

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C41.28 H29.31 Eu N0.76 O8 P'
_chemical_formula_weight         846.89

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0047 0.0022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0089 0.0045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0150 0.0081 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1264 0.1222 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.0675 4.5357 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           54
_space_group_name_H-M_alt        'P c c a'
_space_group_name_Hall           '-P 2a 2ac'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z'
'x+1/2, -y, -z+1/2'
'-x, y, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z'
'-x-1/2, y, z-1/2'
'x, -y, z-1/2'

_cell_length_a                   36.205(7)
_cell_length_b                   15.379(3)
_cell_length_c                   29.692(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     16532(6)
_cell_formula_units_Z            8
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    35578
_cell_measurement_theta_min      1.794
_cell_measurement_theta_max      32.038

_exptl_crystal_description       prismatic
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    0.681
_exptl_crystal_F_000             3394
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    1.087
_shelx_estimated_absorpt_T_min   0.812
_shelx_estimated_absorpt_T_max   0.948
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     0.800
_diffrn_radiation_type           Synchrotron
_diffrn_source                   'SPring-8 BL38B1'
_diffrn_measurement_device_type  MX225HE
_diffrn_measurement_method       'phi scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            35578
_diffrn_reflns_av_unetI/netI     0.0205
_diffrn_reflns_av_R_equivalents  0.0124
_diffrn_reflns_limit_h_min       -40
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_theta_min         1.794
_diffrn_reflns_theta_max         32.038
_diffrn_reflns_theta_full        28.685
_diffrn_measured_fraction_theta_max 0.909
_diffrn_measured_fraction_theta_full 0.924
_diffrn_reflns_Laue_measured_fraction_max 0.909
_diffrn_reflns_Laue_measured_fraction_full 0.924
_diffrn_reflns_point_group_measured_fraction_max 0.909
_diffrn_reflns_point_group_measured_fraction_full 0.924
_reflns_number_total             18374
_reflns_number_gt                14425
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       HKL2000
_computing_cell_refinement       HKL2000
_computing_data_reduction        HKL2000
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'SHELXLE (Hübschle et al., 2011)'
_refine_special_details          ', SQUEEZE'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0828P)²+4.4977P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         18374
_refine_ls_number_parameters     489
_refine_ls_number_restraints     33
_refine_ls_R_factor_all          0.0515
_refine_ls_R_factor_gt           0.0428
_refine_ls_wR_factor_ref         0.1378
_refine_ls_wR_factor_gt          0.1318
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_restrained_S_all      1.097
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.40937(8) 0.32204(16) 0.08465(9) 0.0473(6) Uani 1 1 d . . . . .
C2 C 0.38952(10) 0.39105(19) 0.10081(14) 0.0727(10) Uani 1 1 d . . . . .
H1 H 0.368409 0.381303 0.117921 0.087 Uiso 1 1 calc R U . . .
C3 C 0.40087(10) 0.4763(2) 0.09168(15) 0.0768(11) Uani 1 1 d . . . . .
H2 H 0.387281 0.522604 0.103076 0.092 Uiso 1 1 calc R U . . .
C4 C 0.43161(10) 0.49247(19) 0.06629(11) 0.0604(7) Uani 1 1 d . . . . .
C5 C 0.45103(13) 0.4223(2) 0.05040(18) 0.0957(15) Uani 1 1 d . . . . .
H3 H 0.472235 0.431913 0.033448 0.115 Uiso 1 1 calc R U . . .
C6 C 0.44004(11) 0.3377(2) 0.05883(17) 0.0855(14) Uani 1 1 d . . . . .
H4 H 0.453455 0.291479 0.046984 0.103 Uiso 1 1 calc R U . . .
C7 C 0.44467(9) 0.5827(2) 0.05626(13) 0.0628(8) Uani 1 1 d . . . . .
C8 C 0.42040(10) 0.6523(2) 0.05361(15) 0.0807(11) Uani 1 1 d . . . . .
H5 H 0.395392 0.643576 0.059165 0.097 Uiso 1 1 calc R U . . .
C9 C 0.43314(11) 0.7352(2) 0.04269(16) 0.0780(11) Uani 1 1 d . . . . .
H6 H 0.416653 0.781534 0.041715 0.094 Uiso 1 1 calc R U . . .
C10 C 0.46945(9) 0.74891(18) 0.03346(11) 0.0581(7) Uani 1 1 d . . . . .
C11 C 0.49415(10) 0.6808(2) 0.03797(14) 0.0732(10) Uani 1 1 d . . . . .
H7 H 0.519253 0.689985 0.033325 0.088 Uiso 1 1 calc R U . . .
C12 C 0.48125(10) 0.5990(2) 0.04944(14) 0.0762(10) Uani 1 1 d . . . . .
H8 H 0.498083 0.553695 0.052575 0.091 Uiso 1 1 calc R U . . .
C13 C 0.48321(10) 0.83763(18) 0.01949(10) 0.0563(7) Uani 1 1 d . . . . .
O1 O 0.46094(8) 0.89926(14) 0.02116(9) 0.0785(7) Uani 1 1 d . . . . .
O2 O 0.51603(7) 0.84278(14) 0.00645(9) 0.0722(7) Uani 1 1 d . . . . .
C14 C 0.34958(8) 0.19210(16) 0.08799(10) 0.0493(6) Uani 1 1 d . . . . .
C15 C 0.32418(9) 0.2008(2) 0.12222(12) 0.0683(8) Uani 1 1 d . . . . .
H9 H 0.331779 0.220506 0.150343 0.082 Uiso 1 1 calc R U . . .
C16 C 0.28741(10) 0.1804(3) 0.11505(13) 0.0758(10) Uani 1 1 d . . . . .
H10 H 0.270804 0.185447 0.138795 0.091 Uiso 1 1 calc R U . . .
C17 C 0.27484(9) 0.1529(2) 0.07405(12) 0.0605(7) Uani 1 1 d . . . . .
C18 C 0.30064(10) 0.1450(3) 0.03964(12) 0.0761(10) Uani 1 1 d . . . . .
H11 H 0.292796 0.126052 0.011473 0.091 Uiso 1 1 calc R U . . .
C19 C 0.33721(10) 0.1640(3) 0.04584(12) 0.0710(9) Uani 1 1 d . . . . .
H12 H 0.353769 0.158229 0.022086 0.085 Uiso 1 1 calc R U . . .
C20 C 0.23544(9) 0.1278(2) 0.06615(12) 0.0653(8) Uani 1 1 d . . . . .
C21 C 0.21377(11) 0.0941(3) 0.10002(14) 0.0817(11) Uani 1 1 d . . . . .
H13 H 0.223456 0.088965 0.128911 0.098 Uiso 1 1 calc R U . . .
C22 C 0.17778(11) 0.0678(3) 0.09184(14) 0.0785(10) Uani 1 1 d . . . . .
H14 H 0.163610 0.045935 0.115381 0.094 Uiso 1 1 calc R U . . .
C23 C 0.16275(9) 0.0736(2) 0.04955(12) 0.0640(8) Uani 1 1 d . . . . .
C24 C 0.18397(13) 0.1089(4) 0.01591(14) 0.0981(16) Uani 1 1 d . . . . .
H15 H 0.173900 0.115640 -0.012694 0.118 Uiso 1 1 calc R U . . .
C25 C 0.21998(12) 0.1347(4) 0.02362(15) 0.0989(16) Uani 1 1 d . . . . .
H16 H 0.233976 0.156944 0.000018 0.119 Uiso 1 1 calc R U . . .
C26 C 0.12452(9) 0.04101(18) 0.04061(12) 0.0578(7) Uani 1 1 d . . . . .
O3 O 0.10292(6) 0.02510(14) 0.07195(8) 0.0653(6) Uani 1 1 d . . . . .
O4 O 0.11565(7) 0.0258(2) -0.00022(10) 0.0834(8) Uani 1 1 d . . . . .
C27 C 0.40912(8) 0.18626(17) 0.15271(9) 0.0491(6) Uani 1 1 d . . . . .
C28 C 0.42330(11) 0.2473(2) 0.18205(11) 0.0676(8) Uani 1 1 d . . . . .
H17 H 0.426086 0.304743 0.172882 0.081 Uiso 1 1 calc R U . . .
C29 C 0.43343(11) 0.2226(2) 0.22543(12) 0.0719(9) Uani 1 1 d . . . . .
H18 H 0.443207 0.264127 0.244815 0.086 Uiso 1 1 calc R U . . .
C30 C 0.42943(9) 0.1390(2) 0.24037(10) 0.0618(7) Uani 1 1 d . . . . .
C31 C 0.41513(11) 0.0780(2) 0.21017(12) 0.0790(11) Uani 1 1 d . . . . .
H19 H 0.412299 0.020569 0.219375 0.095 Uiso 1 1 calc R U . . .
C32 C 0.40515(11) 0.1011(2) 0.16711(11) 0.0727(10) Uani 1 1 d . . . . .
H20 H 0.395711 0.059332 0.147577 0.087 Uiso 1 1 calc R U . . .
C33 C 0.44162(9) 0.1117(2) 0.28585(11) 0.0650(8) Uani 1 1 d . . . . .
C34 C 0.47387(11) 0.1450(3) 0.30396(12) 0.0803(11) Uani 1 1 d . . . . .
H21 H 0.487175 0.186362 0.287846 0.096 Uiso 1 1 calc R U . . .
C35 C 0.48682(10) 0.1179(3) 0.34588(11) 0.0742(10) Uani 1 1 d . . . . .
H22 H 0.509073 0.139353 0.356901 0.089 Uiso 1 1 calc R U . . .
C36 C 0.46661(9) 0.0591(2) 0.37109(10) 0.0574(7) Uani 1 1 d . . . . .
C37 C 0.43460(11) 0.0273(3) 0.35317(13) 0.0827(12) Uani 1 1 d . . . . .
H23 H 0.420751 -0.012328 0.369721 0.099 Uiso 1 1 calc R U . . .
C38 C 0.42226(12) 0.0524(3) 0.31129(13) 0.0869(13) Uani 1 1 d . . . . .
H24 H 0.400492 0.028808 0.299996 0.104 Uiso 1 1 calc R U . . .
C39 C 0.48032(10) 0.03107(19) 0.41657(10) 0.0573(7) Uani 1 1 d . . . . .
O5 O 0.51323(7) 0.04648(15) 0.42622(8) 0.0694(6) Uani 1 1 d . . . . .
O6 O 0.45717(7) -0.00689(19) 0.44169(7) 0.0740(6) Uani 1 1 d . . . . .
P1 P 0.39821(2) 0.20987(4) 0.09494(2) 0.04324(14) Uani 1 1 d . . . . .
O7 O 0.41975(5) 0.15434(12) 0.06316(7) 0.0531(5) Uani 1 1 d . . . . .
Eu1 Eu 0.55695(2) 0.04440(2) 0.48379(2) 0.04262(6) Uani 1 1 d . . . . .
C40 C 0.5820(3) 0.1888(6) 0.5640(3) 0.147(4) Uani 0.758(8) 1 d . U P A -1
H25 H 0.562429 0.162895 0.579267 0.177 Uiso 0.758(8) 1 calc R U P A -1
C41 C 0.6185(5) 0.3265(11) 0.5530(7) 0.323(11) Uani 0.758(8) 1 d . U P A -1
H26 H 0.623030 0.377110 0.571107 0.485 Uiso 0.758(8) 1 calc R U P A -1
H27 H 0.641522 0.298451 0.546222 0.485 Uiso 0.758(8) 1 calc R U P A -1
H28 H 0.606621 0.343526 0.525449 0.485 Uiso 0.758(8) 1 calc R U P A -1
C42 C 0.5770(6) 0.3012(14) 0.6207(6) 0.400(13) Uani 0.758(8) 1 d . U P A -1
H29 H 0.588943 0.355864 0.626434 0.600 Uiso 0.758(8) 1 calc R U P A -1
H30 H 0.551024 0.310543 0.616493 0.600 Uiso 0.758(8) 1 calc R U P A -1
H31 H 0.580860 0.262919 0.645745 0.600 Uiso 0.758(8) 1 calc R U P A -1
N1 N 0.5928(4) 0.2618(8) 0.5795(4) 0.260(6) Uani 0.758(8) 1 d . U P A -1
O8 O 0.5944(4) 0.1472(11) 0.5307(4) 0.089(3) Uani 0.758(8) 1 d . U P A -1
O9 O 0.5899(12) 0.133(3) 0.5395(13) 0.073(6) Uani 0.242(8) 1 d . . P A -2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.369(4) . ?
C1 C6 1.371(4) . ?
C1 P1 1.798(2) . ?
C2 C3 1.400(4) . ?
C2 H1 0.9300 . ?
C3 C4 1.367(5) . ?
C3 H2 0.9300 . ?
C4 C5 1.371(5) . ?
C4 C7 1.496(4) . ?
C5 C6 1.384(5) . ?
C5 H3 0.9300 . ?
C6 H4 0.9300 . ?
C7 C12 1.363(5) . ?
C7 C8 1.387(5) . ?
C8 C9 1.394(4) . ?
C8 H5 0.9300 . ?
C9 C10 1.359(5) . ?
C9 H6 0.9300 . ?
C10 C11 1.383(5) . ?
C10 C13 1.511(4) . ?
C11 C12 1.385(4) . ?
C11 H7 0.9300 . ?
C12 H8 0.9300 . ?
C13 O1 1.245(4) . ?
C13 O2 1.252(4) . ?
O1 Eu1 2.329(2) 4_665 ?
O2 Eu1 2.379(2) 8_565 ?
C14 C15 1.377(4) . ?
C14 C19 1.398(4) . ?
C14 P1 1.793(3) . ?
C15 C16 1.384(5) . ?
C15 H9 0.9300 . ?
C16 C17 1.366(5) . ?
C16 H10 0.9300 . ?
C17 C18 1.390(5) . ?
C17 C20 1.497(4) . ?
C18 C19 1.368(5) . ?
C18 H11 0.9300 . ?
C19 H12 0.9300 . ?
C20 C21 1.377(5) . ?
C20 C25 1.385(5) . ?
C21 C22 1.386(5) . ?
C21 H13 0.9300 . ?
C22 C23 1.371(5) . ?
C22 H14 0.9300 . ?
C23 C24 1.372(5) . ?
C23 C26 1.496(4) . ?
C24 C25 1.382(6) . ?
C24 H15 0.9300 . ?
C25 H16 0.9300 . ?
C26 O3 1.240(4) . ?
C26 O4 1.276(5) . ?
C26 Eu1 2.870(3) 3_455 ?
O3 Eu1 2.579(2) 3_455 ?
O4 Eu1 2.433(3) 3_455 ?
C27 C28 1.380(4) . ?
C27 C32 1.386(4) . ?
C27 P1 1.797(3) . ?
C28 C29 1.392(4) . ?
C28 H17 0.9300 . ?
C29 C30 1.368(4) . ?
C29 H18 0.9300 . ?
C30 C31 1.397(5) . ?
C30 C33 1.481(4) . ?
C31 C32 1.375(4) . ?
C31 H19 0.9300 . ?
C32 H20 0.9300 . ?
C33 C38 1.377(5) . ?
C33 C34 1.384(5) . ?
C34 C35 1.394(5) . ?
C34 H21 0.9300 . ?
C35 C36 1.383(4) . ?
C35 H22 0.9300 . ?
C36 C37 1.366(5) . ?
C36 C39 1.502(4) . ?
C37 C38 1.376(5) . ?
C37 H23 0.9300 . ?
C38 H24 0.9300 . ?
C39 O5 1.248(4) . ?
C39 O6 1.265(4) . ?
O5 Eu1 2.330(2) . ?
O6 Eu1 2.343(2) 5_656 ?
P1 O7 1.493(2) . ?
O7 Eu1 2.348(2) 4_655 ?
Eu1 O9 2.45(5) . ?
Eu1 O8 2.506(16) . ?
Eu1 Eu1 4.4492(8) 5_656 ?
C40 O8 1.259(17) . ?
C40 N1 1.274(11) . ?
C40 H25 0.9300 . ?
C41 N1 1.574(19) . ?
C41 H26 0.9600 . ?
C41 H27 0.9600 . ?
C41 H28 0.9600 . ?
C42 N1 1.479(17) . ?
C42 H29 0.9600 . ?
C42 H30 0.9600 . ?
C42 H31 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 119.0(3) . . ?
C2 C1 P1 124.5(2) . . ?
C6 C1 P1 116.5(2) . . ?
C1 C2 C3 120.3(3) . . ?
C1 C2 H1 119.9 . . ?
C3 C2 H1 119.9 . . ?
C4 C3 C2 121.1(3) . . ?
C4 C3 H2 119.4 . . ?
C2 C3 H2 119.4 . . ?
C3 C4 C5 117.6(3) . . ?
C3 C4 C7 122.4(3) . . ?
C5 C4 C7 120.0(3) . . ?
C4 C5 C6 122.0(3) . . ?
C4 C5 H3 119.0 . . ?
C6 C5 H3 119.0 . . ?
C1 C6 C5 120.0(3) . . ?
C1 C6 H4 120.0 . . ?
C5 C6 H4 120.0 . . ?
C12 C7 C8 117.8(3) . . ?
C12 C7 C4 120.5(3) . . ?
C8 C7 C4 121.8(3) . . ?
C7 C8 C9 120.6(3) . . ?
C7 C8 H5 119.7 . . ?
C9 C8 H5 119.7 . . ?
C10 C9 C8 120.6(3) . . ?
C10 C9 H6 119.7 . . ?
C8 C9 H6 119.7 . . ?
C9 C10 C11 119.2(3) . . ?
C9 C10 C13 121.0(3) . . ?
C11 C10 C13 119.8(3) . . ?
C10 C11 C12 119.6(3) . . ?
C10 C11 H7 120.2 . . ?
C12 C11 H7 120.2 . . ?
C7 C12 C11 122.1(3) . . ?
C7 C12 H8 119.0 . . ?
C11 C12 H8 119.0 . . ?
O1 C13 O2 125.3(3) . . ?
O1 C13 C10 117.6(3) . . ?
O2 C13 C10 117.1(3) . . ?
C13 O1 Eu1 155.1(2) . 4_665 ?
C13 O2 Eu1 136.4(2) . 8_565 ?
C15 C14 C19 118.5(3) . . ?
C15 C14 P1 123.8(2) . . ?
C19 C14 P1 117.7(2) . . ?
C14 C15 C16 120.4(3) . . ?
C14 C15 H9 119.8 . . ?
C16 C15 H9 119.8 . . ?
C17 C16 C15 121.8(3) . . ?
C17 C16 H10 119.1 . . ?
C15 C16 H10 119.1 . . ?
C16 C17 C18 117.3(3) . . ?
C16 C17 C20 122.5(3) . . ?
C18 C17 C20 120.2(3) . . ?
C19 C18 C17 122.2(3) . . ?
C19 C18 H11 118.9 . . ?
C17 C18 H11 118.9 . . ?
C18 C19 C14 119.8(3) . . ?
C18 C19 H12 120.1 . . ?
C14 C19 H12 120.1 . . ?
C21 C20 C25 117.7(3) . . ?
C21 C20 C17 121.7(3) . . ?
C25 C20 C17 120.5(3) . . ?
C20 C21 C22 121.2(4) . . ?
C20 C21 H13 119.4 . . ?
C22 C21 H13 119.4 . . ?
C23 C22 C21 121.0(4) . . ?
C23 C22 H14 119.5 . . ?
C21 C22 H14 119.5 . . ?
C22 C23 C24 118.0(3) . . ?
C22 C23 C26 120.5(3) . . ?
C24 C23 C26 121.4(3) . . ?
C23 C24 C25 121.4(4) . . ?
C23 C24 H15 119.3 . . ?
C25 C24 H15 119.3 . . ?
C24 C25 C20 120.7(4) . . ?
C24 C25 H16 119.7 . . ?
C20 C25 H16 119.7 . . ?
O3 C26 O4 121.2(3) . . ?
O3 C26 C23 121.1(3) . . ?
O4 C26 C23 117.6(3) . . ?
O3 C26 Eu1 64.00(16) . 3_455 ?
O4 C26 Eu1 57.42(16) . 3_455 ?
C23 C26 Eu1 170.7(2) . 3_455 ?
C26 O3 Eu1 90.40(19) . 3_455 ?
C26 O4 Eu1 96.4(2) . 3_455 ?
C28 C27 C32 119.2(3) . . ?
C28 C27 P1 123.2(2) . . ?
C32 C27 P1 117.5(2) . . ?
C27 C28 C29 119.8(3) . . ?
C27 C28 H17 120.1 . . ?
C29 C28 H17 120.1 . . ?
C30 C29 C28 121.9(3) . . ?
C30 C29 H18 119.0 . . ?
C28 C29 H18 119.0 . . ?
C29 C30 C31 117.5(3) . . ?
C29 C30 C33 122.0(3) . . ?
C31 C30 C33 120.4(3) . . ?
C32 C31 C30 121.4(3) . . ?
C32 C31 H19 119.3 . . ?
C30 C31 H19 119.3 . . ?
C31 C32 C27 120.2(3) . . ?
C31 C32 H20 119.9 . . ?
C27 C32 H20 119.9 . . ?
C38 C33 C34 117.5(3) . . ?
C38 C33 C30 122.4(3) . . ?
C34 C33 C30 120.1(3) . . ?
C33 C34 C35 121.3(3) . . ?
C33 C34 H21 119.3 . . ?
C35 C34 H21 119.3 . . ?
C36 C35 C34 120.1(3) . . ?
C36 C35 H22 120.0 . . ?
C34 C35 H22 120.0 . . ?
C37 C36 C35 118.2(3) . . ?
C37 C36 C39 121.9(3) . . ?
C35 C36 C39 120.0(3) . . ?
C36 C37 C38 121.8(3) . . ?
C36 C37 H23 119.1 . . ?
C38 C37 H23 119.1 . . ?
C37 C38 C33 121.1(3) . . ?
C37 C38 H24 119.5 . . ?
C33 C38 H24 119.5 . . ?
O5 C39 O6 125.8(3) . . ?
O5 C39 C36 117.9(3) . . ?
O6 C39 C36 116.3(3) . . ?
C39 O5 Eu1 144.5(2) . . ?
C39 O6 Eu1 144.6(2) . 5_656 ?
O7 P1 C14 110.67(12) . . ?
O7 P1 C27 111.90(13) . . ?
C14 P1 C27 107.15(13) . . ?
O7 P1 C1 108.90(12) . . ?
C14 P1 C1 110.32(12) . . ?
C27 P1 C1 107.86(13) . . ?
P1 O7 Eu1 167.16(12) . 4_655 ?
O1 Eu1 O5 77.17(9) 4_645 . ?
O1 Eu1 O6 76.29(10) 4_645 5_656 ?
O5 Eu1 O6 123.23(9) . 5_656 ?
O1 Eu1 O7 138.82(8) 4_645 4_655 ?
O5 Eu1 O7 78.39(8) . 4_655 ?
O6 Eu1 O7 144.71(9) 5_656 4_655 ?
O1 Eu1 O2 122.95(9) 4_645 8_566 ?
O5 Eu1 O2 76.96(10) . 8_566 ?
O6 Eu1 O2 77.09(9) 5_656 8_566 ?
O7 Eu1 O2 82.32(8) 4_655 8_566 ?
O1 Eu1 O4 80.23(11) 4_645 3 ?
O5 Eu1 O4 138.30(10) . 3 ?
O6 Eu1 O4 83.79(10) 5_656 3 ?
O7 Eu1 O4 97.16(9) 4_655 3 ?
O2 Eu1 O4 144.18(10) 8_566 3 ?
O1 Eu1 O9 135.2(10) 4_645 . ?
O5 Eu1 O9 144.9(12) . . ?
O6 Eu1 O9 66.7(6) 5_656 . ?
O7 Eu1 O9 80.0(7) 4_655 . ?
O2 Eu1 O9 73.0(12) 8_566 . ?
O4 Eu1 O9 71.6(12) 3 . ?
O1 Eu1 O8 142.2(4) 4_645 . ?
O5 Eu1 O8 140.1(4) . . ?
O6 Eu1 O8 75.4(2) 5_656 . ?
O7 Eu1 O8 71.4(3) 4_655 . ?
O2 Eu1 O8 73.7(4) 8_566 . ?
O4 Eu1 O8 72.3(4) 3 . ?
O1 Eu1 O3 75.03(9) 4_645 3 ?
O5 Eu1 O3 88.47(9) . 3 ?
O6 Eu1 O3 130.14(8) 5_656 3 ?
O7 Eu1 O3 71.68(7) 4_655 3 ?
O2 Eu1 O3 152.35(8) 8_566 3 ?
O4 Eu1 O3 51.77(9) 3 3 ?
O8 Eu1 O3 105.7(3) . 3 ?
O1 Eu1 C26 77.43(9) 4_645 3 ?
O5 Eu1 C26 113.60(10) . 3 ?
O6 Eu1 C26 108.15(9) 5_656 3 ?
O7 Eu1 C26 82.73(8) 4_655 3 ?
O2 Eu1 C26 159.43(9) 8_566 3 ?
O4 Eu1 C26 26.22(10) 3 3 ?
O8 Eu1 C26 88.2(4) . 3 ?
O3 Eu1 C26 25.60(8) 3 3 ?
O1 Eu1 Eu1 57.44(7) 4_645 5_656 ?
O5 Eu1 Eu1 62.18(7) . 5_656 ?
O6 Eu1 Eu1 61.18(7) 5_656 5_656 ?
O7 Eu1 Eu1 133.04(5) 4_655 5_656 ?
O2 Eu1 Eu1 65.51(6) 8_566 5_656 ?
O4 Eu1 Eu1 129.05(8) 3 5_656 ?
O8 Eu1 Eu1 125.0(3) . 5_656 ?
O3 Eu1 Eu1 127.57(6) 3 5_656 ?
C26 Eu1 Eu1 134.77(6) 3 5_656 ?
O8 C40 N1 128.4(11) . . ?
O8 C40 H25 115.8 . . ?
N1 C40 H25 115.8 . . ?
N1 C41 H26 109.5 . . ?
N1 C41 H27 109.5 . . ?
H26 C41 H27 109.5 . . ?
N1 C41 H28 109.5 . . ?
H26 C41 H28 109.5 . . ?
H27 C41 H28 109.5 . . ?
N1 C42 H29 109.5 . . ?
N1 C42 H30 109.5 . . ?
H29 C42 H30 109.5 . . ?
N1 C42 H31 109.5 . . ?
H29 C42 H31 109.5 . . ?
H30 C42 H31 109.5 . . ?
C40 N1 C42 122.8(15) . . ?
C40 N1 C41 123.9(12) . . ?
C42 N1 C41 112.4(13) . . ?
C40 O8 Eu1 124.4(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -1.1(6) . . . . ?
P1 C1 C2 C3 178.7(3) . . . . ?
C1 C2 C3 C4 0.6(6) . . . . ?
C2 C3 C4 C5 -0.5(6) . . . . ?
C2 C3 C4 C7 -179.4(4) . . . . ?
C3 C4 C5 C6 1.0(8) . . . . ?
C7 C4 C5 C6 180.0(5) . . . . ?
C2 C1 C6 C5 1.6(7) . . . . ?
P1 C1 C6 C5 -178.3(4) . . . . ?
C4 C5 C6 C1 -1.6(8) . . . . ?
C3 C4 C7 C12 150.7(4) . . . . ?
C5 C4 C7 C12 -28.2(6) . . . . ?
C3 C4 C7 C8 -29.2(6) . . . . ?
C5 C4 C7 C8 151.8(5) . . . . ?
C12 C7 C8 C9 2.3(7) . . . . ?
C4 C7 C8 C9 -177.8(4) . . . . ?
C7 C8 C9 C10 1.5(7) . . . . ?
C8 C9 C10 C11 -4.3(6) . . . . ?
C8 C9 C10 C13 177.1(4) . . . . ?
C9 C10 C11 C12 3.4(6) . . . . ?
C13 C10 C11 C12 -178.0(4) . . . . ?
C8 C7 C12 C11 -3.2(7) . . . . ?
C4 C7 C12 C11 176.8(4) . . . . ?
C10 C11 C12 C7 0.4(7) . . . . ?
C9 C10 C13 O1 7.1(5) . . . . ?
C11 C10 C13 O1 -171.4(3) . . . . ?
C9 C10 C13 O2 -171.8(4) . . . . ?
C11 C10 C13 O2 9.7(5) . . . . ?
O2 C13 O1 Eu1 -6.9(8) . . . 4_665 ?
C10 C13 O1 Eu1 174.3(4) . . . 4_665 ?
O1 C13 O2 Eu1 5.2(6) . . . 8_565 ?
C10 C13 O2 Eu1 -176.0(2) . . . 8_565 ?
C19 C14 C15 C16 1.3(5) . . . . ?
P1 C14 C15 C16 -175.7(3) . . . . ?
C14 C15 C16 C17 -1.4(6) . . . . ?
C15 C16 C17 C18 0.9(6) . . . . ?
C15 C16 C17 C20 177.9(4) . . . . ?
C16 C17 C18 C19 -0.4(6) . . . . ?
C20 C17 C18 C19 -177.4(4) . . . . ?
C17 C18 C19 C14 0.3(6) . . . . ?
C15 C14 C19 C18 -0.7(5) . . . . ?
P1 C14 C19 C18 176.4(3) . . . . ?
C16 C17 C20 C21 -29.0(6) . . . . ?
C18 C17 C20 C21 147.9(4) . . . . ?
C16 C17 C20 C25 153.5(4) . . . . ?
C18 C17 C20 C25 -29.6(6) . . . . ?
C25 C20 C21 C22 0.2(7) . . . . ?
C17 C20 C21 C22 -177.4(4) . . . . ?
C20 C21 C22 C23 0.8(7) . . . . ?
C21 C22 C23 C24 -2.2(7) . . . . ?
C21 C22 C23 C26 177.0(4) . . . . ?
C22 C23 C24 C25 2.7(8) . . . . ?
C26 C23 C24 C25 -176.5(5) . . . . ?
C23 C24 C25 C20 -1.8(9) . . . . ?
C21 C20 C25 C24 0.3(8) . . . . ?
C17 C20 C25 C24 177.9(5) . . . . ?
C22 C23 C26 O3 15.1(5) . . . . ?
C24 C23 C26 O3 -165.7(4) . . . . ?
C22 C23 C26 O4 -161.2(4) . . . . ?
C24 C23 C26 O4 17.9(6) . . . . ?
O4 C26 O3 Eu1 5.0(3) . . . 3_455 ?
C23 C26 O3 Eu1 -171.2(3) . . . 3_455 ?
O3 C26 O4 Eu1 -5.3(3) . . . 3_455 ?
C23 C26 O4 Eu1 171.0(2) . . . 3_455 ?
C32 C27 C28 C29 0.1(5) . . . . ?
P1 C27 C28 C29 -175.6(3) . . . . ?
C27 C28 C29 C30 -0.7(6) . . . . ?
C28 C29 C30 C31 0.8(6) . . . . ?
C28 C29 C30 C33 177.4(4) . . . . ?
C29 C30 C31 C32 -0.5(6) . . . . ?
C33 C30 C31 C32 -177.1(4) . . . . ?
C30 C31 C32 C27 -0.1(7) . . . . ?
C28 C27 C32 C31 0.2(6) . . . . ?
P1 C27 C32 C31 176.2(3) . . . . ?
C29 C30 C33 C38 142.9(4) . . . . ?
C31 C30 C33 C38 -40.6(6) . . . . ?
C29 C30 C33 C34 -38.2(6) . . . . ?
C31 C30 C33 C34 138.3(4) . . . . ?
C38 C33 C34 C35 1.6(7) . . . . ?
C30 C33 C34 C35 -177.3(4) . . . . ?
C33 C34 C35 C36 -2.6(7) . . . . ?
C34 C35 C36 C37 1.8(6) . . . . ?
C34 C35 C36 C39 -179.0(4) . . . . ?
C35 C36 C37 C38 -0.1(7) . . . . ?
C39 C36 C37 C38 -179.3(4) . . . . ?
C36 C37 C38 C33 -0.8(8) . . . . ?
C34 C33 C38 C37 0.1(7) . . . . ?
C30 C33 C38 C37 179.0(4) . . . . ?
C37 C36 C39 O5 163.7(4) . . . . ?
C35 C36 C39 O5 -15.5(5) . . . . ?
C37 C36 C39 O6 -15.8(5) . . . . ?
C35 C36 C39 O6 165.0(3) . . . . ?
O6 C39 O5 Eu1 -8.9(6) . . . . ?
C36 C39 O5 Eu1 171.5(2) . . . . ?
O5 C39 O6 Eu1 21.0(6) . . . 5_656 ?
C36 C39 O6 Eu1 -159.4(3) . . . 5_656 ?
C15 C14 P1 O7 150.2(3) . . . . ?
C19 C14 P1 O7 -26.8(3) . . . . ?
C15 C14 P1 C27 27.9(3) . . . . ?
C19 C14 P1 C27 -149.0(3) . . . . ?
C15 C14 P1 C1 -89.2(3) . . . . ?
C19 C14 P1 C1 93.8(3) . . . . ?
C28 C27 P1 O7 120.1(3) . . . . ?
C32 C27 P1 O7 -55.6(3) . . . . ?
C28 C27 P1 C14 -118.4(3) . . . . ?
C32 C27 P1 C14 65.8(3) . . . . ?
C28 C27 P1 C1 0.4(3) . . . . ?
C32 C27 P1 C1 -175.4(3) . . . . ?
C2 C1 P1 O7 165.9(3) . . . . ?
C6 C1 P1 O7 -14.3(3) . . . . ?
C2 C1 P1 C14 44.2(3) . . . . ?
C6 C1 P1 C14 -135.9(3) . . . . ?
C2 C1 P1 C27 -72.5(3) . . . . ?
C6 C1 P1 C27 107.4(3) . . . . ?
C14 P1 O7 Eu1 -35.4(6) . . . 4_655 ?
C27 P1 O7 Eu1 84.0(6) . . . 4_655 ?
C1 P1 O7 Eu1 -156.8(6) . . . 4_655 ?
O8 C40 N1 C42 -176.5(18) . . . . ?
O8 C40 N1 C41 15(3) . . . . ?
N1 C40 O8 Eu1 -152.1(12) . . . . ?

_refine_diff_density_max         0.975
_refine_diff_density_min         -1.071
_refine_diff_density_rms         0.064



_exptl_crystal_preparation       ', Luminescent'
