# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_dyma_lt_mo
_database_code_depnum_ccdc_archive 'CCDC 1528215'
_audit_update_record             
;
2017-01-18 deposited with the CCDC.
2017-05-30 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C11 H18 Dy N3 O9'
_chemical_formula_sum            'C11 H18 Dy N3 O9'
_chemical_formula_weight         498.78

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/c'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.8534(6)
_cell_length_b                   11.8871(3)
_cell_length_c                   12.5771(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 104.182(4)
_cell_angle_gamma                90.00
_cell_volume                     1718.14(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    4210
_cell_measurement_theta_min      2.39
_cell_measurement_theta_max      28.17

_exptl_crystal_description       block
_exptl_crystal_colour            white
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.928
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             972.0
_exptl_absorpt_coefficient_mu    4.398
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_correction_T_min  0.291
_exptl_absorpt_correction_T_max  0.415
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            5570
_diffrn_reflns_av_R_equivalents  0.0291
_diffrn_reflns_av_sigmaI/netI    0.0570
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.39
_diffrn_reflns_theta_max         28.17
_reflns_number_total             4210
_reflns_number_gt                2964
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SMART'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0288P)²+17.2557P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       ?
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         4210
_refine_ls_number_parameters     223
_refine_ls_number_restraints     3
_refine_ls_R_factor_all          0.0706
_refine_ls_R_factor_gt           0.0552
_refine_ls_wR_factor_ref         0.1235
_refine_ls_wR_factor_gt          0.1119
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_restrained_S_all      1.060
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.84575(4) 0.57199(3) 0.46070(3) 0.03853(17) Uani 1 1 d . . .
O5 O 1.0217(6) 0.5858(5) 0.4222(4) 0.0401(14) Uani 1 1 d . . .
O3 O 0.7950(6) 0.4295(5) 0.5793(5) 0.0506(17) Uani 1 1 d . . .
O6 O 0.7789(6) 0.6130(5) 0.2587(5) 0.0452(15) Uani 1 1 d . . .
O1 O 0.8540(5) 0.7707(4) 0.4282(4) 0.0357(13) Uani 1 1 d . . .
O4 O 0.8558(7) 0.4089(5) 0.3589(5) 0.061(2) Uani 1 1 d . . .
O9 O 0.9601(8) 0.6462(5) 0.6269(5) 0.054(2) Uani 1 1 d . . .
N3 N 0.6802(8) 0.5688(7) 0.2473(7) 0.057(2) Uani 1 1 d . . .
N1 N 0.8465(9) 0.9562(6) 0.4605(6) 0.058(3) Uani 1 1 d . . .
O8 O 0.6520(7) 0.5406(8) 0.3348(6) 0.075(2) Uani 1 1 d . . .
O7 O 0.6129(7) 0.5561(7) 0.1570(6) 0.079(3) Uani 1 1 d . . .
O2 O 0.7029(7) 0.6527(6) 0.5348(6) 0.066(2) Uani 1 1 d . . .
N2 N 0.5756(7) 0.6684(7) 0.6418(7) 0.052(2) Uani 1 1 d . . .
C7 C 0.8928(10) 0.3828(6) 0.6125(6) 0.043(2) Uani 1 1 d . . .
C4 C 0.6807(9) 0.6604(8) 0.6250(10) 0.054(3) Uani 1 1 d . . .
H4 H 0.7432 0.6606 0.6864 0.065 Uiso 1 1 calc R . .
C1 C 0.8387(8) 0.8488(7) 0.4880(7) 0.041(2) Uani 1 1 d . . .
H1 H 0.8210 0.8320 0.5543 0.049 Uiso 1 1 calc R . .
C5 C 0.5583(9) 0.6787(11) 0.7529(9) 0.064(3) Uani 1 1 d . . .
H5A H 0.5122 0.6167 0.7672 0.096 Uiso 1 1 calc R . .
H5B H 0.5189 0.7481 0.7590 0.096 Uiso 1 1 calc R . .
H5C H 0.6325 0.6781 0.8051 0.096 Uiso 1 1 calc R . .
C3 C 0.8696(12) 0.9899(8) 0.3574(8) 0.070(4) Uani 1 1 d . . .
H3C H 0.9004 0.9271 0.3256 0.105 Uiso 1 1 calc R . .
H3B H 0.9251 1.0503 0.3698 0.105 Uiso 1 1 calc R . .
H3A H 0.7986 1.0147 0.3083 0.105 Uiso 1 1 calc R . .
C6 C 0.4730(10) 0.6735(15) 0.5522(10) 0.094(5) Uani 1 1 d . . .
H6B H 0.4372 0.7461 0.5511 0.141 Uiso 1 1 calc R . .
H6A H 0.4190 0.6163 0.5616 0.141 Uiso 1 1 calc R . .
H6C H 0.4943 0.6614 0.4842 0.141 Uiso 1 1 calc R . .
C2 C 0.8204(17) 1.0477(10) 0.5305(11) 0.106(6) Uani 1 1 d . . .
H2A H 0.7404 1.0698 0.5046 0.159 Uiso 1 1 calc R . .
H2B H 0.8698 1.1109 0.5275 0.159 Uiso 1 1 calc R . .
H2C H 0.8338 1.0216 0.6048 0.159 Uiso 1 1 calc R . .
C8 C 0.9325(14) 0.2941(8) 0.7002(8) 0.081(4) Uani 1 1 d D . .
H8 H 1.0120 0.2796 0.7220 0.097 Uiso 1 1 calc R . .
C9 C 0.8650(11) 0.2361(8) 0.7477(8) 0.074(4) Uani 1 1 d D . .
C10 C 0.7332(7) 0.2524(8) 0.7148(8) 0.047(2) Uani 1 1 d D . .
H10A H 0.7148 0.3187 0.6703 0.071 Uiso 1 1 calc R . .
H10B H 0.7046 0.2606 0.7794 0.071 Uiso 1 1 calc R . .
H10C H 0.6974 0.1881 0.6739 0.071 Uiso 1 1 calc R . .
C11 C 0.9301(14) 0.3504(8) 0.3338(7) 0.064(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O5 2.260(7) . ?
Dy1 O2 2.330(7) . ?
Dy1 O4 2.342(7) . ?
Dy1 O9 2.366(7) . ?
Dy1 O1 2.403(5) . ?
Dy1 O3 2.428(6) . ?
Dy1 O8 2.478(8) . ?
Dy1 O6 2.517(6) . ?
Dy1 O5 2.650(5) 3_766 ?
Dy1 N3 2.911(8) . ?
Dy1 C7 2.914(8) . ?
Dy1 Dy1 3.9378(9) 3_766 ?
O5 C7 1.254(11) 3_766 ?
O5 Dy1 2.650(5) 3_766 ?
O3 C7 1.261(12) . ?
O6 N3 1.258(10) . ?
O1 C1 1.236(10) . ?
O4 C11 1.223(15) . ?
O9 C11 1.275(15) 3_766 ?
N3 O7 1.227(10) . ?
N3 O8 1.270(11) . ?
N1 C1 1.332(10) . ?
N1 C3 1.446(11) . ?
N1 C2 1.479(12) . ?
O2 C4 1.229(12) . ?
N2 C4 1.317(12) . ?
N2 C6 1.443(13) . ?
N2 C5 1.466(12) . ?
C7 O5 1.254(11) 3_766 ?
C7 C8 1.515(13) . ?
C4 H4 0.9300 . ?
C1 H1 0.9300 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C3 H3C 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6A 0.9600 . ?
C6 H6C 0.9600 . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C8 C9 1.307(11) . ?
C8 H8 0.9300 . ?
C9 C10 1.528(12) . ?
C9 C11 1.554(14) 4_566 ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 O9 1.275(15) 3_766 ?
C11 C9 1.554(14) 4_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 O2 148.8(2) . . ?
O5 Dy1 O4 76.7(3) . . ?
O2 Dy1 O4 134.3(3) . . ?
O5 Dy1 O9 78.7(2) . . ?
O2 Dy1 O9 78.9(3) . . ?
O4 Dy1 O9 134.2(2) . . ?
O5 Dy1 O1 79.3(2) . . ?
O2 Dy1 O1 74.2(2) . . ?
O4 Dy1 O1 135.3(2) . . ?
O9 Dy1 O1 75.25(19) . . ?
O5 Dy1 O3 124.3(2) . . ?
O2 Dy1 O3 74.2(2) . . ?
O4 Dy1 O3 79.2(2) . . ?
O9 Dy1 O3 83.8(2) . . ?
O1 Dy1 O3 144.8(2) . . ?
O5 Dy1 O8 129.3(2) . . ?
O2 Dy1 O8 70.5(3) . . ?
O4 Dy1 O8 71.9(3) . . ?
O9 Dy1 O8 149.5(3) . . ?
O1 Dy1 O8 96.3(2) . . ?
O3 Dy1 O8 87.5(3) . . ?
O5 Dy1 O6 81.3(2) . . ?
O2 Dy1 O6 104.1(3) . . ?
O4 Dy1 O6 69.8(2) . . ?
O9 Dy1 O6 142.2(2) . . ?
O1 Dy1 O6 69.74(19) . . ?
O3 Dy1 O6 133.7(2) . . ?
O8 Dy1 O6 51.0(2) . . ?
O5 Dy1 O5 73.6(2) . 3_766 ?
O2 Dy1 O5 117.3(2) . 3_766 ?
O4 Dy1 O5 67.38(18) . 3_766 ?
O9 Dy1 O5 68.88(18) . 3_766 ?
O1 Dy1 O5 138.3(2) . 3_766 ?
O3 Dy1 O5 50.7(2) . 3_766 ?
O8 Dy1 O5 125.4(2) . 3_766 ?
O6 Dy1 O5 134.07(19) . 3_766 ?
O5 Dy1 N3 104.6(2) . . ?
O2 Dy1 N3 89.0(3) . . ?
O4 Dy1 N3 66.3(2) . . ?
O9 Dy1 N3 158.5(2) . . ?
O1 Dy1 N3 84.4(2) . . ?
O3 Dy1 N3 110.2(2) . . ?
O8 Dy1 N3 25.7(2) . . ?
O6 Dy1 N3 25.5(2) . . ?
O5 Dy1 N3 132.6(2) 3_766 . ?
O5 Dy1 C7 99.1(3) . . ?
O2 Dy1 C7 95.5(3) . . ?
O4 Dy1 C7 72.1(2) . . ?
O9 Dy1 C7 74.5(2) . . ?
O1 Dy1 C7 149.4(2) . . ?
O3 Dy1 C7 25.3(3) . . ?
O8 Dy1 C7 107.5(3) . . ?
O6 Dy1 C7 140.7(2) . . ?
O5 Dy1 C7 25.5(2) 3_766 . ?
N3 Dy1 C7 124.9(3) . . ?
O5 Dy1 Dy1 40.22(14) . 3_766 ?
O2 Dy1 Dy1 143.1(2) . 3_766 ?
O4 Dy1 Dy1 66.98(18) . 3_766 ?
O9 Dy1 Dy1 69.18(17) . 3_766 ?
O1 Dy1 Dy1 113.32(14) . 3_766 ?
O3 Dy1 Dy1 84.11(17) . 3_766 ?
O8 Dy1 Dy1 138.9(2) . 3_766 ?
O6 Dy1 Dy1 112.41(16) . 3_766 ?
O5 Dy1 Dy1 33.41(15) 3_766 3_766 ?
N3 Dy1 Dy1 126.92(19) . 3_766 ?
C7 Dy1 Dy1 58.9(2) . 3_766 ?
C7 O5 Dy1 164.4(6) 3_766 . ?
C7 O5 Dy1 89.1(5) 3_766 3_766 ?
Dy1 O5 Dy1 106.4(2) . 3_766 ?
C7 O3 Dy1 99.5(5) . . ?
N3 O6 Dy1 95.0(5) . . ?
C1 O1 Dy1 128.1(5) . . ?
C11 O4 Dy1 138.4(7) . . ?
C11 O9 Dy1 131.6(6) 3_766 . ?
O7 N3 O6 122.1(9) . . ?
O7 N3 O8 121.3(10) . . ?
O6 N3 O8 116.5(8) . . ?
O7 N3 Dy1 173.5(7) . . ?
O6 N3 Dy1 59.5(4) . . ?
O8 N3 Dy1 57.7(5) . . ?
C1 N1 C3 122.6(8) . . ?
C1 N1 C2 120.8(8) . . ?
C3 N1 C2 116.3(8) . . ?
N3 O8 Dy1 96.6(6) . . ?
C4 O2 Dy1 137.8(7) . . ?
C4 N2 C6 121.8(10) . . ?
C4 N2 C5 121.2(9) . . ?
C6 N2 C5 116.9(9) . . ?
O5 C7 O3 120.6(7) 3_766 . ?
O5 C7 C8 109.0(10) 3_766 . ?
O3 C7 C8 130.1(10) . . ?
O5 C7 Dy1 65.4(4) 3_766 . ?
O3 C7 Dy1 55.3(4) . . ?
C8 C7 Dy1 171.7(8) . . ?
O2 C4 N2 125.3(11) . . ?
O2 C4 H4 117.3 . . ?
N2 C4 H4 117.3 . . ?
O1 C1 N1 122.2(8) . . ?
O1 C1 H1 118.9 . . ?
N1 C1 H1 118.9 . . ?
N2 C5 H5A 109.5 . . ?
N2 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
N2 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
N1 C3 H3C 109.5 . . ?
N1 C3 H3B 109.5 . . ?
H3C C3 H3B 109.5 . . ?
N1 C3 H3A 109.5 . . ?
H3C C3 H3A 109.5 . . ?
H3B C3 H3A 109.5 . . ?
N2 C6 H6B 109.5 . . ?
N2 C6 H6A 109.5 . . ?
H6B C6 H6A 109.5 . . ?
N2 C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
N1 C2 H2A 109.5 . . ?
N1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
N1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C9 C8 C7 125.8(13) . . ?
C9 C8 H8 117.1 . . ?
C7 C8 H8 117.1 . . ?
C8 C9 C10 120.6(11) . . ?
C8 C9 C11 114.4(12) . 4_566 ?
C10 C9 C11 125.0(10) . 4_566 ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O4 C11 O9 127.9(9) . 3_766 ?
O4 C11 C9 106.9(12) . 4_565 ?
O9 C11 C9 125.2(11) 3_766 4_565 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 Dy1 O5 C7 -56(2) . . . 3_766 ?
O4 Dy1 O5 C7 118(2) . . . 3_766 ?
O9 Dy1 O5 C7 -101(2) . . . 3_766 ?
O1 Dy1 O5 C7 -24(2) . . . 3_766 ?
O3 Dy1 O5 C7 -175.1(19) . . . 3_766 ?
O8 Dy1 O5 C7 65(2) . . . 3_766 ?
O6 Dy1 O5 C7 47(2) . . . 3_766 ?
O5 Dy1 O5 C7 -172(2) 3_766 . . 3_766 ?
N3 Dy1 O5 C7 57(2) . . . 3_766 ?
C7 Dy1 O5 C7 -172.9(19) . . . 3_766 ?
Dy1 Dy1 O5 C7 -172(2) 3_766 . . 3_766 ?
O2 Dy1 O5 Dy1 116.0(4) . . . 3_766 ?
O4 Dy1 O5 Dy1 -70.0(2) . . . 3_766 ?
O9 Dy1 O5 Dy1 71.1(2) . . . 3_766 ?
O1 Dy1 O5 Dy1 148.0(2) . . . 3_766 ?
O3 Dy1 O5 Dy1 -3.2(3) . . . 3_766 ?
O8 Dy1 O5 Dy1 -122.6(3) . . . 3_766 ?
O6 Dy1 O5 Dy1 -141.1(2) . . . 3_766 ?
O5 Dy1 O5 Dy1 0.0 3_766 . . 3_766 ?
N3 Dy1 O5 Dy1 -130.8(2) . . . 3_766 ?
C7 Dy1 O5 Dy1 -0.9(2) . . . 3_766 ?
O5 Dy1 O3 C7 5.3(6) . . . . ?
O2 Dy1 O3 C7 -146.6(6) . . . . ?
O4 Dy1 O3 C7 70.8(5) . . . . ?
O9 Dy1 O3 C7 -66.4(5) . . . . ?
O1 Dy1 O3 C7 -119.7(5) . . . . ?
O8 Dy1 O3 C7 142.9(6) . . . . ?
O6 Dy1 O3 C7 118.8(5) . . . . ?
O5 Dy1 O3 C7 1.3(5) 3_766 . . . ?
N3 Dy1 O3 C7 130.5(5) . . . . ?
Dy1 Dy1 O3 C7 3.2(5) 3_766 . . . ?
O5 Dy1 O6 N3 156.2(6) . . . . ?
O2 Dy1 O6 N3 -55.2(6) . . . . ?
O4 Dy1 O6 N3 77.2(6) . . . . ?
O9 Dy1 O6 N3 -145.3(5) . . . . ?
O1 Dy1 O6 N3 -122.1(6) . . . . ?
O3 Dy1 O6 N3 26.2(7) . . . . ?
O8 Dy1 O6 N3 -5.4(5) . . . . ?
O5 Dy1 O6 N3 99.2(6) 3_766 . . . ?
C7 Dy1 O6 N3 62.4(7) . . . . ?
Dy1 Dy1 O6 N3 130.2(5) 3_766 . . . ?
O5 Dy1 O1 C1 -127.6(8) . . . . ?
O2 Dy1 O1 C1 35.8(8) . . . . ?
O4 Dy1 O1 C1 174.1(7) . . . . ?
O9 Dy1 O1 C1 -46.6(8) . . . . ?
O3 Dy1 O1 C1 8.9(9) . . . . ?
O8 Dy1 O1 C1 103.5(8) . . . . ?
O6 Dy1 O1 C1 147.8(8) . . . . ?
O5 Dy1 O1 C1 -77.7(8) 3_766 . . . ?
N3 Dy1 O1 C1 126.3(8) . . . . ?
C7 Dy1 O1 C1 -37.8(10) . . . . ?
Dy1 Dy1 O1 C1 -105.7(7) 3_766 . . . ?
O5 Dy1 O4 C11 21.1(9) . . . . ?
O2 Dy1 O4 C11 -163.3(8) . . . . ?
O9 Dy1 O4 C11 -38.2(10) . . . . ?
O1 Dy1 O4 C11 80.3(9) . . . . ?
O3 Dy1 O4 C11 -108.3(9) . . . . ?
O8 Dy1 O4 C11 160.7(10) . . . . ?
O6 Dy1 O4 C11 106.5(9) . . . . ?
O5 Dy1 O4 C11 -56.5(9) 3_766 . . . ?
N3 Dy1 O4 C11 133.8(10) . . . . ?
C7 Dy1 O4 C11 -83.3(9) . . . . ?
Dy1 Dy1 O4 C11 -20.2(8) 3_766 . . . ?
O5 Dy1 O9 C11 -18.1(7) . . . 3_766 ?
O2 Dy1 O9 C11 -176.2(8) . . . 3_766 ?
O4 Dy1 O9 C11 40.4(9) . . . 3_766 ?
O1 Dy1 O9 C11 -99.8(8) . . . 3_766 ?
O3 Dy1 O9 C11 108.8(8) . . . 3_766 ?
O8 Dy1 O9 C11 -176.9(7) . . . 3_766 ?
O6 Dy1 O9 C11 -77.4(8) . . . 3_766 ?
O5 Dy1 O9 C11 58.6(7) 3_766 . . 3_766 ?
N3 Dy1 O9 C11 -119.2(9) . . . 3_766 ?
C7 Dy1 O9 C11 84.8(8) . . . 3_766 ?
Dy1 Dy1 O9 C11 22.7(7) 3_766 . . 3_766 ?
Dy1 O6 N3 O7 -172.6(9) . . . . ?
Dy1 O6 N3 O8 9.3(9) . . . . ?
O5 Dy1 N3 O7 82(7) . . . . ?
O2 Dy1 N3 O7 -127(7) . . . . ?
O4 Dy1 N3 O7 14(7) . . . . ?
O9 Dy1 N3 O7 178(7) . . . . ?
O1 Dy1 N3 O7 159(7) . . . . ?
O3 Dy1 N3 O7 -54(7) . . . . ?
O8 Dy1 N3 O7 -83(7) . . . . ?
O6 Dy1 N3 O7 106(7) . . . . ?
O5 Dy1 N3 O7 1(7) 3_766 . . . ?
C7 Dy1 N3 O7 -30(7) . . . . ?
Dy1 Dy1 N3 O7 44(7) 3_766 . . . ?
O5 Dy1 N3 O6 -24.4(6) . . . . ?
O2 Dy1 N3 O6 127.2(5) . . . . ?
O4 Dy1 N3 O6 -92.4(6) . . . . ?
O9 Dy1 N3 O6 71.8(9) . . . . ?
O1 Dy1 N3 O6 53.0(5) . . . . ?
O3 Dy1 N3 O6 -160.1(5) . . . . ?
O8 Dy1 N3 O6 170.2(10) . . . . ?
O5 Dy1 N3 O6 -105.4(5) 3_766 . . . ?
C7 Dy1 N3 O6 -136.8(5) . . . . ?
Dy1 Dy1 N3 O6 -62.1(6) 3_766 . . . ?
O5 Dy1 N3 O8 165.4(6) . . . . ?
O2 Dy1 N3 O8 -43.0(7) . . . . ?
O4 Dy1 N3 O8 97.4(7) . . . . ?
O9 Dy1 N3 O8 -98.4(9) . . . . ?
O1 Dy1 N3 O8 -117.2(7) . . . . ?
O3 Dy1 N3 O8 29.7(7) . . . . ?
O6 Dy1 N3 O8 -170.2(10) . . . . ?
O5 Dy1 N3 O8 84.4(7) 3_766 . . . ?
C7 Dy1 N3 O8 53.0(7) . . . . ?
Dy1 Dy1 N3 O8 127.7(6) 3_766 . . . ?
O7 N3 O8 Dy1 172.4(8) . . . . ?
O6 N3 O8 Dy1 -9.4(9) . . . . ?
O5 Dy1 O8 N3 -18.3(8) . . . . ?
O2 Dy1 O8 N3 133.6(7) . . . . ?
O4 Dy1 O8 N3 -72.9(6) . . . . ?
O9 Dy1 O8 N3 134.4(6) . . . . ?
O1 Dy1 O8 N3 62.9(6) . . . . ?
O3 Dy1 O8 N3 -152.3(6) . . . . ?
O6 Dy1 O8 N3 5.4(5) . . . . ?
O5 Dy1 O8 N3 -116.1(6) 3_766 . . . ?
C7 Dy1 O8 N3 -136.6(6) . . . . ?
Dy1 Dy1 O8 N3 -74.1(7) 3_766 . . . ?
O5 Dy1 O2 C4 -86.1(11) . . . . ?
O4 Dy1 O2 C4 102.0(11) . . . . ?
O9 Dy1 O2 C4 -41.3(10) . . . . ?
O1 Dy1 O2 C4 -118.9(11) . . . . ?
O3 Dy1 O2 C4 45.3(10) . . . . ?
O8 Dy1 O2 C4 138.4(11) . . . . ?
O6 Dy1 O2 C4 177.4(10) . . . . ?
O5 Dy1 O2 C4 17.8(11) 3_766 . . . ?
N3 Dy1 O2 C4 156.6(11) . . . . ?
C7 Dy1 O2 C4 31.7(11) . . . . ?
Dy1 Dy1 O2 C4 -11.0(12) 3_766 . . . ?
Dy1 O3 C7 O5 -2.5(9) . . . 3_766 ?
Dy1 O3 C7 C8 172.1(8) . . . . ?
O5 Dy1 C7 O5 2.1(5) . . . 3_766 ?
O2 Dy1 C7 O5 -150.2(5) . . . 3_766 ?
O4 Dy1 C7 O5 74.8(5) . . . 3_766 ?
O9 Dy1 C7 O5 -73.3(5) . . . 3_766 ?
O1 Dy1 C7 O5 -82.2(6) . . . 3_766 ?
O3 Dy1 C7 O5 177.7(8) . . . 3_766 ?
O8 Dy1 C7 O5 138.5(5) . . . 3_766 ?
O6 Dy1 C7 O5 89.4(6) . . . 3_766 ?
N3 Dy1 C7 O5 117.2(5) . . . 3_766 ?
Dy1 Dy1 C7 O5 1.4(4) 3_766 . . 3_766 ?
O5 Dy1 C7 O3 -175.6(5) . . . . ?
O2 Dy1 C7 O3 32.1(6) . . . . ?
O4 Dy1 C7 O3 -102.8(6) . . . . ?
O9 Dy1 C7 O3 109.0(5) . . . . ?
O1 Dy1 C7 O3 100.2(7) . . . . ?
O8 Dy1 C7 O3 -39.2(6) . . . . ?
O6 Dy1 C7 O3 -88.2(6) . . . . ?
O5 Dy1 C7 O3 -177.7(8) 3_766 . . . ?
N3 Dy1 C7 O3 -60.5(6) . . . . ?
Dy1 Dy1 C7 O3 -176.3(6) 3_766 . . . ?
O5 Dy1 C7 C8 52(5) . . . . ?
O2 Dy1 C7 C8 -101(5) . . . . ?
O4 Dy1 C7 C8 124(5) . . . . ?
O9 Dy1 C7 C8 -24(5) . . . . ?
O1 Dy1 C7 C8 -33(5) . . . . ?
O3 Dy1 C7 C8 -133(5) . . . . ?
O8 Dy1 C7 C8 -172(5) . . . . ?
O6 Dy1 C7 C8 139(4) . . . . ?
O5 Dy1 C7 C8 49(5) 3_766 . . . ?
N3 Dy1 C7 C8 167(5) . . . . ?
Dy1 Dy1 C7 C8 51(5) 3_766 . . . ?
Dy1 O2 C4 N2 -149.9(9) . . . . ?
C6 N2 C4 O2 -2.6(17) . . . . ?
C5 N2 C4 O2 -179.2(10) . . . . ?
Dy1 O1 C1 N1 179.6(7) . . . . ?
C3 N1 C1 O1 2.2(17) . . . . ?
C2 N1 C1 O1 176.1(11) . . . . ?
O5 C7 C8 C9 -174.0(9) 3_766 . . . ?
O3 C7 C8 C9 11.0(16) . . . . ?
Dy1 C7 C8 C9 139(4) . . . . ?
C7 C8 C9 C10 1.5(15) . . . . ?
C7 C8 C9 C11 179.3(8) . . . 4_566 ?
Dy1 O4 C11 O9 11.5(16) . . . 3_766 ?
Dy1 O4 C11 C9 -171.7(6) . . . 4_565 ?

_diffrn_measured_fraction_theta_max 0.976
_diffrn_reflns_theta_full        28.17
_diffrn_measured_fraction_theta_full 0.976
_refine_diff_density_max         2.457
_refine_diff_density_min         -2.261
_refine_diff_density_rms         0.175
