# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_aa1_0m
_database_code_depnum_ccdc_archive 'CCDC 1588756'
_audit_update_record             
;
2017-12-02 deposited with the CCDC.
2018-02-15 downloaded from the CCDC.
;
_audit_creation_date             2017-07-31
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2017.06.29 svn.r3433 for OlexSys, GUI svn.r5370)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C22 H22 As Cl2 Cu5 N11 O31 W9, 0.75(H2 O)'
_chemical_formula_sum            'C22 H23.50 As Cl2 Cu5 N11 O31.75 W9'
_chemical_formula_weight         3068.15
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0500 2.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1480 0.1590 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3200 1.2650 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8720 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   27.5445(19)
_cell_length_b                   14.3006(10)
_cell_length_c                   27.9545(19)
_cell_angle_alpha                90
_cell_angle_beta                 110.0750(10)
_cell_angle_gamma                90
_cell_volume                     10342.3(12)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9904
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.43
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    22.772
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.2720
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.1728 before and 0.0663 after correction.
The Ratio of minimum to maximum transmission is 0.3648.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   
'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.'
_exptl_crystal_colour            blue
_exptl_crystal_colour_primary    blue
_exptl_crystal_density_diffrn    3.941
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             10912
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0561
_diffrn_reflns_av_unetI/netI     0.0557
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            36483
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.500
_diffrn_reflns_theta_min         2.428
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7788
_reflns_number_total             9614
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.18C (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.18C (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.897
_refine_diff_density_min         -2.623
_refine_diff_density_rms         0.434
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     715
_refine_ls_number_reflns         9614
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0566
_refine_ls_R_factor_gt           0.0429
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0776P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1158
_refine_ls_wR_factor_ref         0.1232
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(O8) \\sim Ueq, Uanis(O9) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(C17) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O8) = Uanis(O13)
Uanis(O1) = Uanis(O17)
Uanis(O9) = Uanis(O2)
Uanis(O14) = Uanis(O24)
3. Others
 Fixed Sof: O32(0.75) H32A(0.75) H32B(0.75)
4.a Riding coordinates:
 O32(H32A,H32B)
4.b Aromatic/amide H refined with riding coordinates:
 C5(H5), C3(H3), C8(H8), C1(H1), C7(H7), C4(H4), C9(H9), C17(H17), C2(H2),
 C6(H6), C15(H15), C22(H22), C21(H21), C16(H16), C11(H11), C10(H10), C12(H12),
 C13(H13), C14(H14), C19(H19), C20(H20), C18(H18)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W8 W 0.38359(2) 0.53668(3) 0.61424(2) 0.01819(13) Uani 1 1 d . . . . .
W6 W 0.47854(2) 0.53372(3) 0.88398(2) 0.01888(13) Uani 1 1 d . . . . .
W9 W 0.54940(2) 0.30654(3) 0.68713(2) 0.01812(13) Uani 1 1 d . . . . .
W2 W 0.31840(2) 0.38642(3) 0.74558(2) 0.01801(13) Uani 1 1 d . . . . .
W7 W 0.41111(2) 0.30786(3) 0.68507(2) 0.01684(13) Uani 1 1 d . . . . .
W1 W 0.34055(2) 0.58670(3) 0.81330(2) 0.01709(13) Uani 1 1 d . . . . .
W4 W 0.40799(2) 0.73987(3) 0.67758(2) 0.02185(14) Uani 1 1 d . . . . .
W5 W 0.45476(2) 0.73597(3) 0.82029(2) 0.02236(14) Uani 1 1 d . . . . .
W3 W 0.29518(2) 0.59439(3) 0.68381(2) 0.01887(13) Uani 1 1 d . . . . .
As1 As 0.42880(4) 0.52654(7) 0.74879(4) 0.0086(2) Uani 1 1 d . . . . .
Cu5 Cu 0.28961(6) 1.02575(10) 1.00496(6) 0.0333(4) Uani 1 1 d . . . . .
Cu1 Cu 0.45434(6) 0.99457(11) 0.85878(7) 0.0358(4) Uani 1 1 d . . . . .
Cu3 Cu 0.32819(6) 1.56440(11) 0.94546(7) 0.0389(4) Uani 1 1 d . . . . .
Cu2 Cu 0.46570(7) 1.16207(12) 0.94501(7) 0.0431(5) Uani 1 1 d . . . . .
Cu4 Cu 0.22836(6) 0.65067(11) 0.85114(6) 0.0361(4) Uani 1 1 d . . . . .
Cl1 Cl 0.42447(14) 1.0259(2) 0.92955(13) 0.0365(8) Uani 1 1 d . . . . .
Cl2 Cl 0.24240(11) 1.5359(2) 0.92377(12) 0.0282(7) Uani 1 1 d . . . . .
O20 O 0.4785(3) 0.2962(5) 0.6849(3) 0.0180(18) Uani 1 1 d . . . . .
O28 O 0.2374(3) 0.6370(6) 0.6448(3) 0.0263(19) Uani 1 1 d . . . . .
O22 O 0.5290(3) 0.4118(5) 0.6436(3) 0.0198(18) Uani 1 1 d . . . . .
O9 O 0.4022(3) 0.5372(5) 0.8578(3) 0.0173(12) Uani 1 1 d . U . . .
O21 O 0.5708(3) 0.2429(5) 0.7508(3) 0.0144(17) Uani 1 1 d . . . . .
O24 O 0.3832(3) 0.2200(5) 0.6437(3) 0.0190(12) Uani 1 1 d . . . . .
O14 O 0.3474(3) 0.3444(5) 0.6994(3) 0.0190(12) Uani 1 1 d . . . . .
O13 O 0.4475(3) 0.4147(5) 0.7491(3) 0.0116(11) Uani 1 1 d . . . . .
O11 O 0.5493(3) 0.5382(5) 0.8915(3) 0.0167(17) Uani 1 1 d . . . . .
O26 O 0.4748(3) 0.7480(5) 0.6738(3) 0.0161(17) Uani 1 1 d . . . . .
O17 O 0.4279(3) 0.5837(5) 0.6958(3) 0.0129(11) Uani 1 1 d . . . . .
O16 O 0.3255(3) 0.5417(5) 0.6390(3) 0.0178(17) Uani 1 1 d . . . . .
O2 O 0.3085(3) 0.4684(5) 0.7975(3) 0.0173(12) Uani 1 1 d . . . . .
O1 O 0.3670(3) 0.5247(5) 0.7489(3) 0.0129(11) Uani 1 1 d . . . . .
O5 O 0.3416(3) 0.6983(5) 0.6871(3) 0.0174(17) Uani 1 1 d . . . . .
O7 O 0.3832(3) 0.6945(5) 0.8083(3) 0.0215(18) Uani 1 1 d . . . . .
O6 O 0.4338(3) 0.7568(5) 0.7493(2) 0.0138(17) Uani 1 1 d . . . . .
O10 O 0.4745(3) 0.6674(5) 0.8827(3) 0.0170(17) Uani 1 1 d . . . . .
O31 O 0.3118(3) 0.6291(5) 0.8533(3) 0.0264(19) Uani 1 1 d . . . . .
O19 O 0.3487(3) 0.5143(5) 0.5520(3) 0.0214(18) Uani 1 1 d . . . . .
O18 O 0.3833(3) 0.6699(5) 0.6150(3) 0.0196(17) Uani 1 1 d . . . . .
O27 O 0.3863(3) 0.8494(5) 0.6563(3) 0.027(2) Uani 1 1 d . . . . .
O25 O 0.4461(3) 0.8437(5) 0.8431(3) 0.0254(19) Uani 1 1 d . . . . .
O12 O 0.4840(3) 0.5130(6) 0.9461(3) 0.027(2) Uani 1 1 d . . . . .
O30 O 0.2732(3) 0.3031(5) 0.7435(3) 0.0259(19) Uani 1 1 d . . . . .
O3 O 0.2745(3) 0.4726(5) 0.6969(3) 0.0208(18) Uani 1 1 d . . . . .
O15 O 0.3976(3) 0.4128(5) 0.6409(3) 0.0181(17) Uani 1 1 d . . . . .
O4 O 0.2937(3) 0.6321(5) 0.7485(3) 0.0174(17) Uani 1 1 d . . . . .
O23 O 0.5468(3) 0.2174(5) 0.6454(3) 0.0205(18) Uani 1 1 d . . . . .
O8 O 0.4647(3) 0.5843(5) 0.8017(3) 0.0116(11) Uani 1 1 d . U . . .
O29 O 0.3797(3) 0.3410(5) 0.7971(3) 0.0168(16) Uani 1 1 d . . . . .
N1 N 0.4168(4) 1.2698(7) 0.9506(4) 0.033(3) Uani 1 1 d . . . . .
N2 N 0.3627(4) 1.4378(7) 0.9454(4) 0.027(2) Uani 1 1 d . . . . .
N6 N 0.5299(4) 0.9845(6) 0.8931(4) 0.025(2) Uani 1 1 d . . . . .
N5 N 0.3983(4) 1.0292(7) 0.7959(4) 0.025(2) Uani 1 1 d . . . . .
N3 N 0.5367(4) 1.2170(7) 0.9770(4) 0.032(3) Uani 1 1 d . . . . .
N4 N 0.6221(4) 1.3338(7) 1.0245(4) 0.029(3) Uani 1 1 d . . . . .
N10 N 0.3664(4) 1.0234(6) 1.0479(4) 0.024(2) Uani 1 1 d . . . . .
N11 N 0.2661(4) 1.1562(6) 1.0015(4) 0.027(2) Uani 1 1 d . . . . .
N8 N 0.2461(4) 0.7673(6) 0.8916(4) 0.025(2) Uani 1 1 d . . . . .
N9 N 0.2702(4) 0.9230(6) 0.9547(4) 0.024(2) Uani 1 1 d . . . . .
N7 N 0.1794(4) 0.5912(7) 0.7916(4) 0.026(2) Uani 1 1 d . . . . .
C5 C 0.5605(5) 1.2196(9) 1.0281(5) 0.032(3) Uani 1 1 d . . . . .
H5 H 0.548734 1.180318 1.048293 0.038 Uiso 1 1 calc R . . . .
C3 C 0.3435(6) 1.3687(9) 0.9110(5) 0.040(4) Uani 1 1 d . . . . .
H3 H 0.311996 1.377004 0.884895 0.048 Uiso 1 1 calc R . . . .
C8 C 0.5577(5) 1.2690(8) 0.9509(5) 0.032(3) Uani 1 1 d . . . . .
H8 H 0.543199 1.267506 0.915577 0.038 Uiso 1 1 calc R . . . .
C1 C 0.4352(5) 1.3383(9) 0.9840(5) 0.036(3) Uani 1 1 d . . . . .
H1 H 0.467171 1.331154 1.009517 0.043 Uiso 1 1 calc R . . . .
C7 C 0.5997(5) 1.3258(9) 0.9725(5) 0.034(3) Uani 1 1 d . . . . .
H7 H 0.613340 1.359439 0.951591 0.041 Uiso 1 1 calc R . . . .
C4 C 0.3703(5) 1.2861(9) 0.9143(5) 0.039(4) Uani 1 1 d . . . . .
H4 H 0.355678 1.239454 0.890573 0.047 Uiso 1 1 calc R . . . .
C9 C 0.3581(5) 1.0796(8) 0.7989(5) 0.028(3) Uani 1 1 d . . . . .
H9 H 0.356129 1.093404 0.830661 0.034 Uiso 1 1 calc R . . . .
C17 C 0.3857(5) 0.9557(9) 1.0812(5) 0.032(3) Uani 1 1 d . U . . .
H17 H 0.363667 0.909761 1.085559 0.039 Uiso 1 1 calc R . . . .
C2 C 0.4074(5) 1.4207(9) 0.9814(5) 0.029(3) Uani 1 1 d . . . . .
H2 H 0.421109 1.465942 1.006296 0.035 Uiso 1 1 calc R . . . .
C6 C 0.6019(5) 1.2789(9) 1.0515(5) 0.031(3) Uani 1 1 d . . . . .
H6 H 0.615777 1.280420 1.086907 0.037 Uiso 1 1 calc R . . . .
C15 C 0.2798(5) 0.8308(8) 0.8875(5) 0.029(3) Uani 1 1 d . . . . .
H15 H 0.295719 0.822521 0.863413 0.035 Uiso 1 1 calc R . . . .
C22 C 0.2248(5) 0.7813(8) 0.9275(5) 0.026(3) Uani 1 1 d . . . . .
H22 H 0.201658 0.737695 0.931867 0.031 Uiso 1 1 calc R . . . .
C21 C 0.2368(4) 0.8594(8) 0.9579(4) 0.027(3) Uani 1 1 d . . . . .
H21 H 0.220616 0.867760 0.981872 0.033 Uiso 1 1 calc R . . . .
C16 C 0.2915(5) 0.9084(8) 0.9183(5) 0.032(3) Uani 1 1 d . . . . .
H16 H 0.314622 0.952177 0.914042 0.038 Uiso 1 1 calc R . . . .
C11 C 0.3977(5) 1.0080(9) 0.7489(5) 0.030(3) Uani 1 1 d . . . . .
H11 H 0.424344 0.972253 0.745069 0.036 Uiso 1 1 calc R . . . .
C10 C 0.3197(4) 1.1111(8) 0.7554(5) 0.025(3) Uani 1 1 d . . . . .
H10 H 0.292748 1.146739 0.758553 0.030 Uiso 1 1 calc R . . . .
C12 C 0.5496(5) 0.9126(10) 0.9257(5) 0.040(4) Uani 1 1 d . . . . .
H12 H 0.528132 0.864447 0.928781 0.048 Uiso 1 1 calc R . . . .
C13 C 0.5620(5) 1.0487(9) 0.8901(6) 0.040(4) Uani 1 1 d . . . . .
H13 H 0.549660 1.099016 0.868181 0.048 Uiso 1 1 calc R . . . .
C14 C 0.1410(5) 0.5375(8) 0.7930(5) 0.034(3) Uani 1 1 d . . . . .
H14 H 0.140428 0.518977 0.824717 0.040 Uiso 1 1 calc R . . . .
C19 C 0.2387(6) 1.1980(9) 0.9582(5) 0.042(4) Uani 1 1 d . . . . .
H19 H 0.229338 1.164329 0.927949 0.050 Uiso 1 1 calc R . . . .
C20 C 0.2766(6) 1.2081(9) 1.0428(5) 0.049(5) Uani 1 1 d . . . . .
H20 H 0.294961 1.181307 1.074081 0.059 Uiso 1 1 calc R . . . .
C18 C 0.3994(5) 1.0885(9) 1.0464(5) 0.034(3) Uani 1 1 d . . . . .
H18 H 0.386886 1.138957 1.024673 0.041 Uiso 1 1 calc R . . . .
O32 O 0.3203(7) 0.8453(12) 0.7497(9) 0.110(8) Uani 0.75 1 d . . P . .
H32A H 0.334190 0.792077 0.750113 0.166 Uiso 0.75 1 d R . P . .
H32B H 0.287640 0.839108 0.739843 0.166 Uiso 0.75 1 d R . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W8 O11 1.910(8) 2_656 ?
W8 O17 2.287(7) . ?
W8 O16 1.951(8) . ?
W8 O19 1.704(7) . ?
W8 O18 1.906(7) . ?
W8 O15 1.908(7) . ?
W6 O22 1.888(7) 2_656 ?
W6 O9 1.977(7) . ?
W6 O11 1.888(8) . ?
W6 O10 1.914(7) . ?
W6 O12 1.717(8) . ?
W6 O8 2.316(7) . ?
W9 O20 1.938(7) . ?
W9 O22 1.896(7) . ?
W9 O21 1.903(7) . ?
W9 O13 2.340(7) 2_656 ?
W9 O23 1.713(7) . ?
W9 O29 1.912(7) 2_656 ?
W2 O14 1.838(8) . ?
W2 O2 1.956(8) . ?
W2 O1 2.372(7) . ?
W2 O30 1.711(7) . ?
W2 O3 1.925(7) . ?
W2 O29 1.919(7) . ?
W7 O20 1.865(7) . ?
W7 O21 1.927(7) 2_656 ?
W7 O24 1.701(7) . ?
W7 O14 1.998(8) . ?
W7 O13 2.304(7) . ?
W7 O15 1.898(7) . ?
W1 O9 1.865(7) . ?
W1 O2 1.890(7) . ?
W1 O1 2.337(7) . ?
W1 O7 1.972(8) . ?
W1 O31 1.690(8) . ?
W1 O4 1.940(7) . ?
W4 O26 1.884(7) . ?
W4 O17 2.315(7) . ?
W4 O5 2.026(8) . ?
W4 O6 1.898(6) . ?
W4 O18 1.925(7) . ?
W4 O27 1.709(8) . ?
W5 O26 1.897(7) 2_656 ?
W5 O7 1.974(7) . ?
W5 O6 1.891(6) . ?
W5 O10 1.911(7) . ?
W5 O25 1.715(8) . ?
W5 O8 2.269(7) . ?
W3 O28 1.704(7) . ?
W3 O16 1.885(8) . ?
W3 O1 2.398(6) . ?
W3 O5 1.941(7) . ?
W3 O3 1.907(8) . ?
W3 O4 1.901(7) . ?
As1 O13 1.679(7) . ?
As1 O17 1.684(7) . ?
As1 O1 1.703(7) . ?
As1 O8 1.686(7) . ?
Cu5 Cl2 2.594(4) 7_577 ?
Cu5 N10 2.042(9) . ?
Cu5 N11 1.966(9) . ?
Cu5 N9 1.975(9) . ?
Cu1 Cu2 3.336(2) . ?
Cu1 Cl1 2.431(4) . ?
Cu1 O25 2.198(8) . ?
Cu1 N6 1.976(10) . ?
Cu1 N5 1.965(9) . ?
Cu3 Cu4 3.325(2) 1_565 ?
Cu3 Cl2 2.266(3) . ?
Cu3 O31 2.627(9) 1_565 ?
Cu3 N2 2.044(10) . ?
Cu3 N4 1.977(9) 5_687 ?
Cu2 Cl1 2.221(3) . ?
Cu2 O23 2.556(8) 2_666 ?
Cu2 N1 2.087(11) . ?
Cu2 N3 2.010(10) . ?
Cu4 Cl2 2.535(3) 1_545 ?
Cu4 O31 2.298(8) . ?
Cu4 N8 1.981(9) . ?
Cu4 N7 1.942(10) . ?
N1 C1 1.327(15) . ?
N1 C4 1.354(16) . ?
N2 C3 1.353(15) . ?
N2 C2 1.320(14) . ?
N6 C12 1.357(16) . ?
N6 C13 1.296(17) . ?
N5 C9 1.346(16) . ?
N5 C11 1.343(16) . ?
N3 C5 1.352(16) . ?
N3 C8 1.306(16) . ?
N4 C7 1.376(15) . ?
N4 C6 1.336(16) . ?
N10 C17 1.322(15) . ?
N10 C18 1.313(16) . ?
N11 C19 1.329(16) . ?
N11 C20 1.317(16) . ?
N8 C15 1.330(16) . ?
N8 C22 1.340(16) . ?
N9 C21 1.320(16) . ?
N9 C16 1.352(17) . ?
N7 C10 1.352(15) 4_546 ?
N7 C14 1.319(16) . ?
C5 H5 0.9300 . ?
C5 C6 1.391(17) . ?
C3 H3 0.9300 . ?
C3 C4 1.378(18) . ?
C8 H8 0.9300 . ?
C8 C7 1.374(17) . ?
C1 H1 0.9300 . ?
C1 C2 1.394(18) . ?
C7 H7 0.9300 . ?
C4 H4 0.9300 . ?
C9 H9 0.9300 . ?
C9 C10 1.384(16) . ?
C17 H17 0.9300 . ?
C17 C13 1.389(16) 5_677 ?
C2 H2 0.9300 . ?
C6 H6 0.9300 . ?
C15 H15 0.9300 . ?
C15 C16 1.373(16) . ?
C22 H22 0.9300 . ?
C22 C21 1.373(15) . ?
C21 H21 0.9300 . ?
C16 H16 0.9300 . ?
C11 H11 0.9300 . ?
C11 C14 1.352(17) 4_556 ?
C10 H10 0.9300 . ?
C12 H12 0.9300 . ?
C12 C18 1.353(17) 5_677 ?
C13 H13 0.9300 . ?
C14 H14 0.9300 . ?
C19 H19 0.9300 . ?
C19 C20 1.404(18) 7_577 ?
C20 H20 0.9300 . ?
C18 H18 0.9300 . ?
O32 H32A 0.8499 . ?
O32 H32B 0.8502 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 W8 O17 83.1(3) 2_656 . ?
O11 W8 O16 164.8(3) 2_656 . ?
O16 W8 O17 81.8(3) . . ?
O19 W8 O11 98.0(4) . 2_656 ?
O19 W8 O17 173.6(3) . . ?
O19 W8 O16 97.2(4) . . ?
O19 W8 O18 101.3(3) . . ?
O19 W8 O15 101.0(3) . . ?
O18 W8 O11 89.9(3) . 2_656 ?
O18 W8 O17 72.4(3) . . ?
O18 W8 O16 87.3(3) . . ?
O18 W8 O15 157.6(3) . . ?
O15 W8 O11 88.4(3) . 2_656 ?
O15 W8 O17 85.2(3) . . ?
O15 W8 O16 88.6(3) . . ?
O22 W6 O9 85.3(3) 2_656 . ?
O22 W6 O10 156.4(3) 2_656 . ?
O22 W6 O8 85.7(3) 2_656 . ?
O9 W6 O8 80.4(3) . . ?
O11 W6 O22 92.4(3) . 2_656 ?
O11 W6 O9 165.2(3) . . ?
O11 W6 O10 91.1(3) . . ?
O11 W6 O8 84.9(3) . . ?
O10 W6 O9 85.4(3) . . ?
O10 W6 O8 71.4(3) . . ?
O12 W6 O22 102.3(3) . 2_656 ?
O12 W6 O9 95.3(3) . . ?
O12 W6 O11 99.5(4) . . ?
O12 W6 O10 100.1(3) . . ?
O12 W6 O8 170.6(3) . . ?
O20 W9 O13 81.2(3) . 2_656 ?
O22 W9 O20 88.1(3) . . ?
O22 W9 O21 155.3(3) . . ?
O22 W9 O13 83.7(3) . 2_656 ?
O22 W9 O29 89.8(3) . 2_656 ?
O21 W9 O20 88.8(3) . . ?
O21 W9 O13 71.6(3) . 2_656 ?
O21 W9 O29 86.8(3) . 2_656 ?
O23 W9 O20 96.6(3) . . ?
O23 W9 O22 102.7(3) . . ?
O23 W9 O21 102.1(3) . . ?
O23 W9 O13 173.3(3) . 2_656 ?
O23 W9 O29 98.6(3) . 2_656 ?
O29 W9 O20 164.7(3) 2_656 . ?
O29 W9 O13 83.5(3) 2_656 2_656 ?
O14 W2 O2 157.3(3) . . ?
O14 W2 O1 85.6(3) . . ?
O14 W2 O3 91.8(3) . . ?
O14 W2 O29 86.2(3) . . ?
O2 W2 O1 72.1(3) . . ?
O30 W2 O14 103.7(4) . . ?
O30 W2 O2 99.0(4) . . ?
O30 W2 O1 167.7(3) . . ?
O30 W2 O3 98.5(3) . . ?
O30 W2 O29 103.5(3) . . ?
O3 W2 O2 85.8(3) . . ?
O3 W2 O1 72.7(3) . . ?
O29 W2 O2 87.5(3) . . ?
O29 W2 O1 85.0(3) . . ?
O29 W2 O3 157.8(3) . . ?
O20 W7 O21 91.1(3) . 2_656 ?
O20 W7 O14 165.2(3) . . ?
O20 W7 O13 83.9(3) . . ?
O20 W7 O15 92.4(3) . . ?
O21 W7 O14 84.5(3) 2_656 . ?
O21 W7 O13 72.1(3) 2_656 . ?
O24 W7 O20 98.6(3) . . ?
O24 W7 O21 100.9(3) . 2_656 ?
O24 W7 O14 96.1(3) . . ?
O24 W7 O13 172.6(3) . . ?
O24 W7 O15 101.5(3) . . ?
O14 W7 O13 81.3(3) . . ?
O15 W7 O21 156.5(3) . 2_656 ?
O15 W7 O14 86.2(3) . . ?
O15 W7 O13 85.2(3) . . ?
O9 W1 O2 93.5(3) . . ?
O9 W1 O1 85.2(3) . . ?
O9 W1 O7 85.2(3) . . ?
O9 W1 O4 155.6(3) . . ?
O2 W1 O1 74.0(3) . . ?
O2 W1 O7 157.8(3) . . ?
O2 W1 O4 88.5(3) . . ?
O7 W1 O1 83.8(3) . . ?
O31 W1 O9 102.8(3) . . ?
O31 W1 O2 100.9(4) . . ?
O31 W1 O1 170.9(3) . . ?
O31 W1 O7 101.0(4) . . ?
O31 W1 O4 100.7(3) . . ?
O4 W1 O1 72.0(3) . . ?
O4 W1 O7 83.9(3) . . ?
O26 W4 O17 84.8(3) . . ?
O26 W4 O5 165.8(3) . . ?
O26 W4 O6 91.9(3) . . ?
O26 W4 O18 91.6(3) . . ?
O5 W4 O17 81.1(3) . . ?
O6 W4 O17 85.2(3) . . ?
O6 W4 O5 85.8(3) . . ?
O6 W4 O18 155.9(3) . . ?
O18 W4 O17 71.5(3) . . ?
O18 W4 O5 85.0(3) . . ?
O27 W4 O26 99.0(4) . . ?
O27 W4 O17 171.6(3) . . ?
O27 W4 O5 95.2(4) . . ?
O27 W4 O6 102.2(3) . . ?
O27 W4 O18 100.8(3) . . ?
O26 W5 O7 166.9(3) 2_656 . ?
O26 W5 O10 90.3(3) 2_656 . ?
O26 W5 O8 84.6(3) 2_656 . ?
O7 W5 O8 82.3(3) . . ?
O6 W5 O26 90.7(3) . 2_656 ?
O6 W5 O7 86.7(3) . . ?
O6 W5 O10 158.1(3) . . ?
O6 W5 O8 85.8(3) . . ?
O10 W5 O7 87.4(3) . . ?
O10 W5 O8 72.5(3) . . ?
O25 W5 O26 98.9(4) . 2_656 ?
O25 W5 O7 94.3(3) . . ?
O25 W5 O6 102.6(3) . . ?
O25 W5 O10 98.8(3) . . ?
O25 W5 O8 170.8(3) . . ?
O28 W3 O16 104.3(3) . . ?
O28 W3 O1 168.8(3) . . ?
O28 W3 O5 102.2(3) . . ?
O28 W3 O3 100.0(4) . . ?
O28 W3 O4 100.8(3) . . ?
O16 W3 O1 84.3(3) . . ?
O16 W3 O5 84.4(3) . . ?
O16 W3 O3 89.6(3) . . ?
O16 W3 O4 154.8(3) . . ?
O5 W3 O1 85.7(3) . . ?
O3 W3 O1 72.4(3) . . ?
O3 W3 O5 157.8(3) . . ?
O4 W3 O1 71.2(3) . . ?
O4 W3 O5 88.1(3) . . ?
O4 W3 O3 88.3(3) . . ?
O13 As1 O17 112.2(3) . . ?
O13 As1 O1 106.9(3) . . ?
O13 As1 O8 112.1(3) . . ?
O17 As1 O1 107.2(3) . . ?
O17 As1 O8 111.1(3) . . ?
O8 As1 O1 107.0(3) . . ?
N10 Cu5 Cl2 95.7(3) . 7_577 ?
N11 Cu5 Cl2 99.6(3) . 7_577 ?
N11 Cu5 N10 107.5(4) . . ?
N11 Cu5 N9 131.9(4) . . ?
N9 Cu5 Cl2 102.3(3) . 7_577 ?
N9 Cu5 N10 112.2(4) . . ?
Cl1 Cu1 Cu2 41.72(8) . . ?
O25 Cu1 Cu2 145.8(2) . . ?
O25 Cu1 Cl1 107.6(3) . . ?
N6 Cu1 Cu2 83.1(3) . . ?
N6 Cu1 Cl1 102.3(3) . . ?
N6 Cu1 O25 92.6(3) . . ?
N5 Cu1 Cu2 108.4(3) . . ?
N5 Cu1 Cl1 107.5(3) . . ?
N5 Cu1 O25 94.2(3) . . ?
N5 Cu1 N6 145.8(5) . . ?
Cl2 Cu3 Cu4 49.59(9) . 1_565 ?
Cl2 Cu3 O31 89.3(2) . 1_565 ?
O31 Cu3 Cu4 43.48(18) 1_565 1_565 ?
N2 Cu3 Cu4 125.8(3) . 1_565 ?
N2 Cu3 Cl2 106.4(3) . . ?
N2 Cu3 O31 103.6(3) . 1_565 ?
N4 Cu3 Cu4 109.1(3) 5_687 1_565 ?
N4 Cu3 Cl2 138.8(3) 5_687 . ?
N4 Cu3 O31 91.0(4) 5_687 1_565 ?
N4 Cu3 N2 113.5(4) 5_687 . ?
Cl1 Cu2 Cu1 46.75(11) . . ?
Cl1 Cu2 O23 101.1(2) . 2_666 ?
O23 Cu2 Cu1 63.94(18) 2_666 . ?
N1 Cu2 Cu1 132.9(3) . . ?
N1 Cu2 Cl1 111.2(3) . . ?
N1 Cu2 O23 88.5(4) . 2_666 ?
N3 Cu2 Cu1 115.9(3) . . ?
N3 Cu2 Cl1 141.6(3) . . ?
N3 Cu2 O23 95.7(4) . 2_666 ?
N3 Cu2 N1 103.4(4) . . ?
Cl2 Cu4 Cu3 42.90(8) 1_545 1_545 ?
O31 Cu4 Cu3 51.9(2) . 1_545 ?
O31 Cu4 Cl2 90.9(2) . 1_545 ?
N8 Cu4 Cu3 83.4(3) . 1_545 ?
N8 Cu4 Cl2 98.5(3) . 1_545 ?
N8 Cu4 O31 92.8(4) . . ?
N7 Cu4 Cu3 131.2(3) . 1_545 ?
N7 Cu4 Cl2 105.9(3) . 1_545 ?
N7 Cu4 O31 111.0(4) . . ?
N7 Cu4 N8 145.2(4) . . ?
Cu2 Cl1 Cu1 91.53(14) . . ?
Cu3 Cl2 Cu5 116.98(13) . 7_577 ?
Cu3 Cl2 Cu4 87.51(12) . 1_565 ?
Cu4 Cl2 Cu5 146.79(14) 1_565 7_577 ?
W7 O20 W9 170.3(4) . . ?
W6 O22 W9 164.2(4) 2_656 . ?
W1 O9 W6 150.0(4) . . ?
W9 O21 W7 122.5(4) . 2_656 ?
W2 O14 W7 148.2(4) . . ?
W7 O13 W9 92.6(2) . 2_656 ?
As1 O13 W9 124.3(4) . 2_656 ?
As1 O13 W7 125.2(3) . . ?
W6 O11 W8 169.2(4) . 2_656 ?
W4 O26 W5 168.3(4) . 2_656 ?
W8 O17 W4 93.4(2) . . ?
As1 O17 W8 125.1(4) . . ?
As1 O17 W4 126.4(4) . . ?
W3 O16 W8 148.7(4) . . ?
W1 O2 W2 122.5(4) . . ?
W2 O1 W3 90.5(2) . . ?
W1 O1 W2 91.4(3) . . ?
W1 O1 W3 91.9(2) . . ?
As1 O1 W2 124.3(3) . . ?
As1 O1 W1 124.9(3) . . ?
As1 O1 W3 123.9(4) . . ?
W3 O5 W4 145.8(4) . . ?
W1 O7 W5 143.8(4) . . ?
W5 O6 W4 163.2(4) . . ?
W5 O10 W6 121.8(4) . . ?
W1 O31 Cu3 124.1(4) . 1_545 ?
W1 O31 Cu4 136.2(4) . . ?
Cu4 O31 Cu3 84.7(3) . 1_545 ?
W8 O18 W4 121.9(4) . . ?
W5 O25 Cu1 159.7(5) . . ?
W3 O3 W2 124.3(4) . . ?
W7 O15 W8 162.9(4) . . ?
W3 O4 W1 124.7(4) . . ?
W9 O23 Cu2 149.8(4) . 2_646 ?
W5 O8 W6 93.6(2) . . ?
As1 O8 W6 124.4(3) . . ?
As1 O8 W5 126.1(4) . . ?
W9 O29 W2 145.7(4) 2_656 . ?
C1 N1 Cu2 119.8(9) . . ?
C1 N1 C4 115.7(11) . . ?
C4 N1 Cu2 122.8(9) . . ?
C3 N2 Cu3 125.4(9) . . ?
C2 N2 Cu3 118.4(8) . . ?
C2 N2 C3 116.2(11) . . ?
C12 N6 Cu1 119.4(9) . . ?
C13 N6 Cu1 123.0(8) . . ?
C13 N6 C12 117.2(11) . . ?
C9 N5 Cu1 119.3(9) . . ?
C11 N5 Cu1 124.1(9) . . ?
C11 N5 C9 116.6(10) . . ?
C5 N3 Cu2 121.7(9) . . ?
C8 N3 Cu2 121.6(8) . . ?
C8 N3 C5 115.3(10) . . ?
C7 N4 Cu3 120.2(8) . 5_687 ?
C6 N4 Cu3 123.8(9) . 5_687 ?
C6 N4 C7 115.2(10) . . ?
C17 N10 Cu5 120.8(8) . . ?
C18 N10 Cu5 124.0(8) . . ?
C18 N10 C17 115.2(10) . . ?
C19 N11 Cu5 123.1(8) . . ?
C20 N11 Cu5 121.5(8) . . ?
C20 N11 C19 115.4(10) . . ?
C15 N8 Cu4 124.7(9) . . ?
C15 N8 C22 117.3(10) . . ?
C22 N8 Cu4 117.9(8) . . ?
C21 N9 Cu5 119.3(9) . . ?
C21 N9 C16 115.9(10) . . ?
C16 N9 Cu5 124.7(8) . . ?
C10 N7 Cu4 120.1(8) 4_546 . ?
C14 N7 Cu4 123.8(9) . . ?
C14 N7 C10 115.7(10) . 4_546 ?
N3 C5 H5 118.8 . . ?
N3 C5 C6 122.4(12) . . ?
C6 C5 H5 118.8 . . ?
N2 C3 H3 119.7 . . ?
N2 C3 C4 120.6(12) . . ?
C4 C3 H3 119.7 . . ?
N3 C8 H8 118.0 . . ?
N3 C8 C7 124.0(11) . . ?
C7 C8 H8 118.0 . . ?
N1 C1 H1 119.4 . . ?
N1 C1 C2 121.2(11) . . ?
C2 C1 H1 119.4 . . ?
N4 C7 H7 119.4 . . ?
C8 C7 N4 121.2(12) . . ?
C8 C7 H7 119.4 . . ?
N1 C4 C3 123.1(12) . . ?
N1 C4 H4 118.5 . . ?
C3 C4 H4 118.5 . . ?
N5 C9 H9 119.5 . . ?
N5 C9 C10 121.0(12) . . ?
C10 C9 H9 119.5 . . ?
N10 C17 H17 119.1 . . ?
N10 C17 C13 121.8(12) . 5_677 ?
C13 C17 H17 119.1 5_677 . ?
N2 C2 C1 123.3(11) . . ?
N2 C2 H2 118.4 . . ?
C1 C2 H2 118.4 . . ?
N4 C6 C5 121.7(12) . . ?
N4 C6 H6 119.2 . . ?
C5 C6 H6 119.2 . . ?
N8 C15 H15 119.4 . . ?
N8 C15 C16 121.2(13) . . ?
C16 C15 H15 119.4 . . ?
N8 C22 H22 119.6 . . ?
N8 C22 C21 120.8(12) . . ?
C21 C22 H22 119.6 . . ?
N9 C21 C22 122.9(12) . . ?
N9 C21 H21 118.6 . . ?
C22 C21 H21 118.6 . . ?
N9 C16 C15 121.8(13) . . ?
N9 C16 H16 119.1 . . ?
C15 C16 H16 119.1 . . ?
N5 C11 H11 119.4 . . ?
N5 C11 C14 121.2(12) . 4_556 ?
C14 C11 H11 119.4 4_556 . ?
N7 C10 C9 121.4(11) 4_556 . ?
N7 C10 H10 119.3 4_556 . ?
C9 C10 H10 119.3 . . ?
N6 C12 H12 120.3 . . ?
C18 C12 N6 119.4(12) 5_677 . ?
C18 C12 H12 120.3 5_677 . ?
N6 C13 C17 121.7(12) . 5_677 ?
N6 C13 H13 119.2 . . ?
C17 C13 H13 119.2 5_677 . ?
N7 C14 C11 123.9(13) . 4_546 ?
N7 C14 H14 118.1 . . ?
C11 C14 H14 118.1 4_546 . ?
N11 C19 H19 119.3 . . ?
N11 C19 C20 121.4(11) . 7_577 ?
C20 C19 H19 119.3 7_577 . ?
N11 C20 C19 123.2(11) . 7_577 ?
N11 C20 H20 118.4 . . ?
C19 C20 H20 118.4 7_577 . ?
N10 C18 C12 124.6(12) . 5_677 ?
N10 C18 H18 117.7 . . ?
C12 C18 H18 117.7 5_677 . ?
H32A O32 H32B 109.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cu5 N10 C17 C13 178.3(11) . . . 5_677 ?
Cu5 N10 C18 C12 -179.4(12) . . . 5_677 ?
Cu5 N11 C19 C20 -178.8(12) . . . 7_577 ?
Cu5 N11 C20 C19 178.7(13) . . . 7_577 ?
Cu5 N9 C21 C22 -174.0(9) . . . . ?
Cu5 N9 C16 C15 173.9(9) . . . . ?
Cu1 N6 C12 C18 -172.4(11) . . . 5_677 ?
Cu1 N6 C13 C17 173.2(11) . . . 5_677 ?
Cu1 N5 C9 C10 175.3(9) . . . . ?
Cu1 N5 C11 C14 -176.9(10) . . . 4_556 ?
Cu3 N2 C3 C4 179.5(11) . . . . ?
Cu3 N2 C2 C1 -177.7(11) . . . . ?
Cu3 N4 C7 C8 -166.3(11) 5_687 . . . ?
Cu3 N4 C6 C5 168.4(9) 5_687 . . . ?
Cu2 N1 C1 C2 166.0(10) . . . . ?
Cu2 N1 C4 C3 -163.6(12) . . . . ?
Cu2 N3 C5 C6 -161.4(10) . . . . ?
Cu2 N3 C8 C7 164.0(11) . . . . ?
Cu4 N8 C15 C16 -177.6(8) . . . . ?
Cu4 N8 C22 C21 178.0(8) . . . . ?
Cu4 N7 C14 C11 169.3(10) . . . 4_546 ?
O20 W9 O22 W6 116.2(18) . . . 2_656 ?
O20 W9 O23 Cu2 96.1(8) . . . 2_646 ?
O20 W7 O15 W8 -111.9(15) . . . . ?
O28 W3 O16 W8 123.2(8) . . . . ?
O22 W6 O11 W8 54(2) 2_656 . . 2_656 ?
O22 W9 O23 Cu2 6.6(9) . . . 2_646 ?
O9 W6 O11 W8 -27(3) . . . 2_656 ?
O9 W1 O2 W2 -83.6(5) . . . . ?
O9 W1 O31 Cu3 -26.5(5) . . . 1_545 ?
O9 W1 O31 Cu4 -149.5(6) . . . . ?
O21 W9 O22 W6 33(2) . . . 2_656 ?
O21 W9 O23 Cu2 -173.8(8) . . . 2_646 ?
O21 W7 O15 W8 -13(2) 2_656 . . . ?
O24 W7 O15 W8 148.8(15) . . . . ?
O14 W7 O15 W8 53.4(15) . . . . ?
O13 W9 O22 W6 34.8(17) 2_656 . . 2_656 ?
O13 W7 O15 W8 -28.2(15) . . . . ?
O13 As1 O17 W8 54.9(5) . . . . ?
O13 As1 O17 W4 -177.7(4) . . . . ?
O13 As1 O1 W2 -2.9(5) . . . . ?
O13 As1 O1 W1 118.0(4) . . . . ?
O13 As1 O1 W3 -121.0(4) . . . . ?
O13 As1 O8 W6 -53.0(5) . . . . ?
O13 As1 O8 W5 -179.3(4) . . . . ?
O26 W4 O6 W5 -107.0(15) . . . . ?
O26 W5 O6 W4 108.6(15) 2_656 . . . ?
O26 W5 O25 Cu1 34.1(13) 2_656 . . . ?
O17 W4 O26 W5 -29(2) . . . 2_656 ?
O17 W4 O6 W5 -22.3(15) . . . . ?
O17 As1 O13 W9 -176.9(3) . . . 2_656 ?
O17 As1 O13 W7 -53.5(5) . . . . ?
O17 As1 O1 W2 117.6(4) . . . . ?
O17 As1 O1 W1 -121.5(4) . . . . ?
O17 As1 O1 W3 -0.5(5) . . . . ?
O17 As1 O8 W6 -179.4(4) . . . . ?
O17 As1 O8 W5 54.3(5) . . . . ?
O2 W2 O14 W7 52.9(13) . . . . ?
O2 W1 O9 W6 136.7(8) . . . . ?
O2 W1 O31 Cu3 69.7(5) . . . 1_545 ?
O2 W1 O31 Cu4 -53.3(7) . . . . ?
O1 W2 O14 W7 63.8(8) . . . . ?
O1 W1 O9 W6 63.1(9) . . . . ?
O1 W1 O2 W2 0.3(4) . . . . ?
O1 W3 O16 W8 -64.2(7) . . . . ?
O1 As1 O13 W9 -59.6(5) . . . 2_656 ?
O1 As1 O13 W7 63.8(5) . . . . ?
O1 As1 O17 W8 -62.1(5) . . . . ?
O1 As1 O17 W4 65.3(5) . . . . ?
O1 As1 O8 W6 63.8(5) . . . . ?
O1 As1 O8 W5 -62.5(5) . . . . ?
O5 W4 O26 W5 -24(3) . . . 2_656 ?
O5 W4 O6 W5 59.0(15) . . . . ?
O5 W3 O16 W8 22.0(7) . . . . ?
O7 W1 O9 W6 -21.0(9) . . . . ?
O7 W1 O2 W2 2.3(11) . . . . ?
O7 W1 O31 Cu3 -114.0(4) . . . 1_545 ?
O7 W1 O31 Cu4 122.9(6) . . . . ?
O7 W5 O6 W4 -58.5(15) . . . . ?
O7 W5 O25 Cu1 -146.2(12) . . . . ?
O6 W4 O26 W5 56(2) . . . 2_656 ?
O6 W5 O25 Cu1 -58.7(13) . . . . ?
O10 W6 O11 W8 -103(2) . . . 2_656 ?
O10 W5 O6 W4 16(2) . . . . ?
O10 W5 O25 Cu1 125.8(12) . . . . ?
O31 W1 O9 W6 -121.2(9) . . . . ?
O31 W1 O2 W2 172.6(4) . . . . ?
O18 W4 O26 W5 -100(2) . . . 2_656 ?
O18 W4 O6 W5 -9(2) . . . . ?
O27 W4 O26 W5 159(2) . . . 2_656 ?
O27 W4 O6 W5 153.4(15) . . . . ?
O25 W5 O6 W4 -152.1(15) . . . . ?
O12 W6 O11 W8 157(2) . . . 2_656 ?
O30 W2 O14 W7 -124.4(8) . . . . ?
O3 W2 O14 W7 136.4(8) . . . . ?
O3 W3 O16 W8 -136.6(8) . . . . ?
O4 W1 O9 W6 42.6(13) . . . . ?
O4 W1 O2 W2 72.0(4) . . . . ?
O4 W1 O31 Cu3 160.2(4) . . . 1_545 ?
O4 W1 O31 Cu4 37.2(7) . . . . ?
O4 W3 O16 W8 -51.4(12) . . . . ?
O23 W9 O22 W6 -147.5(17) . . . 2_656 ?
O8 W6 O11 W8 -32(2) . . . 2_656 ?
O8 W5 O6 W4 24.1(15) . . . . ?
O8 As1 O13 W9 57.3(5) . . . 2_656 ?
O8 As1 O13 W7 -179.3(4) . . . . ?
O8 As1 O17 W8 -178.7(4) . . . . ?
O8 As1 O17 W4 -51.3(5) . . . . ?
O8 As1 O1 W2 -123.1(4) . . . . ?
O8 As1 O1 W1 -2.3(5) . . . . ?
O8 As1 O1 W3 118.8(4) . . . . ?
O29 W9 O22 W6 -48.7(18) 2_656 . . 2_656 ?
O29 W9 O23 Cu2 -85.2(8) 2_656 . . 2_646 ?
O29 W2 O14 W7 -21.4(8) . . . . ?
N1 C1 C2 N2 -2(2) . . . . ?
N2 C3 C4 N1 -1(2) . . . . ?
N5 C9 C10 N7 1.2(19) . . . 4_556 ?
N3 C5 C6 N4 -3(2) . . . . ?
N3 C8 C7 N4 -2(2) . . . . ?
N8 C15 C16 N9 1.3(18) . . . . ?
N8 C22 C21 N9 -1.7(18) . . . . ?
C5 N3 C8 C7 -2(2) . . . . ?
C3 N2 C2 C1 2(2) . . . . ?
C8 N3 C5 C6 4.8(19) . . . . ?
C1 N1 C4 C3 1(2) . . . . ?
C7 N4 C6 C5 -1.2(18) . . . . ?
C4 N1 C1 C2 1(2) . . . . ?
C9 N5 C11 C14 1.2(19) . . . 4_556 ?
C17 N10 C18 C12 3(2) . . . 5_677 ?
C2 N2 C3 C4 0(2) . . . . ?
C6 N4 C7 C8 3.7(19) . . . . ?
C15 N8 C22 C21 1.3(16) . . . . ?
C22 N8 C15 C16 -1.2(16) . . . . ?
C21 N9 C16 C15 -1.6(17) . . . . ?
C16 N9 C21 C22 1.7(17) . . . . ?
C11 N5 C9 C10 -2.9(18) . . . . ?
C10 N7 C14 C11 -4.2(19) 4_546 . . 4_546 ?
C12 N6 C13 C17 0(2) . . . 5_677 ?
C13 N6 C12 C18 1(2) . . . 5_677 ?
C19 N11 C20 C19 -2(3) . . . 7_577 ?
C20 N11 C19 C20 2(3) . . . 7_577 ?
C18 N10 C17 C13 -4(2) . . . 5_677 ?

_olex2_submission_special_instructions 'No special instructions were received'
