# Electronic Supplementary Material (ESI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_1_sqd
_database_code_depnum_ccdc_archive 'CCDC 1576513'
_audit_update_record             
;
2017-09-26 deposited with the CCDC.
2017-12-01 downloaded from the CCDC.
;
_audit_creation_date             2017-08-14
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5375)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '0.33(C312 H272 Ag30 Cl8 N8 P24)'
_chemical_formula_sum            'C100 H100 Ag15 Cl4 N4 O10 P12'
_chemical_formula_weight         3649.32
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0040 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0070 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0120 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1070 0.0990 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1520 0.1640 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8500 1.1240 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           20
_space_group_name_H-M_alt        'C 2 2 21'
_space_group_name_Hall           'C 2c 2'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'x, -y, -z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z+1/2'

_cell_length_a                   18.702(4)
_cell_length_b                   36.975(7)
_cell_length_c                   28.652(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     19813(7)
_cell_formula_units_Z            6
_cell_measurement_reflns_used    ?
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      ?
_cell_measurement_theta_min      ?
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.514
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.835
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       ?
_exptl_crystal_F_000             10566
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0738
_diffrn_reflns_av_unetI/netI     0.0669
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       43
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            30936
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.057
_diffrn_reflns_theta_max         25.057
_diffrn_reflns_theta_min         2.469
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           ?
_diffrn_radiation_wavelength     0.720
_diffrn_source                   ?
_reflns_Friedel_coverage         0.859
_reflns_Friedel_fraction_full    0.989
_reflns_Friedel_fraction_max     0.989
_reflns_number_gt                13666
_reflns_number_total             16793
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    ?
_refine_diff_density_max         7.458
_refine_diff_density_min         -3.979
_refine_diff_density_rms         0.497
_refine_ls_abs_structure_details 
;
 Flack x determined using 4558 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.48(5)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   3.608
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     730
_refine_ls_number_reflns         16793
_refine_ls_number_restraints     1140
_refine_ls_R_factor_all          0.1828
_refine_ls_R_factor_gt           0.1632
_refine_ls_restrained_S_all      3.526
_refine_ls_shift/su_max          1.423
_refine_ls_shift/su_mean         0.026
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.4575
_refine_ls_wR_factor_ref         0.4802
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Uiso/Uaniso restraints and constraints
All non-hydrogen atoms have similar U: within 2A with sigma of 0.04 and sigma
for terminal atoms of 0.08
All non-hydrogen atoms restrained to be isotropic: with sigma of 0.1 and sigma
for terminal atoms of 0.2
3.a Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C40(H40A,H40B), C53(H53A,H53B), C66(H66A,H66B)
3.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C7(H7), C9(H9), C10(H10), C11(H11), C12(H12),
 C13(H13), C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), C22(H22), C23(H23),
  C24(H24), C25(H25), C26(H26), C29(H29), C30(H30), C31(H31), C32(H32),
 C33(H33), C35(H35), C36(H36), C37(H37), C38(H38), C39(H39), C42(H42), C43(H43),
  C44(H44), C45(H45), C46(H46), C48(H48), C49(H49), C50(H50), C51(H51),
 C52(H52), C55(H55), C56(H56), C57(H57), C58(H58), C59(H59), C61(H61), C62(H62),
  C63(H63), C64(H64), C65(H65), C68(H68), C69(H69), C70(H70), C71(H71),
 C72(H72), C74(H74), C75(H75), C76(H76), C77(H77), C78(H78)
3.c Fitted hexagon refined as free rotating group:
 C2(C3,C4,C5,C6,C7), C8(C9,C10,C11,C12,C13), C15(C16,C17,C18,C19,C20), C21(C22,
 C23,C24,C25,C26), C28(C29,C30,C31,C32,C33), C34(C35,C36,C37,C38,C39), C41(C42,
 C43,C44,C45,C46), C47(C48,C49,C50,C51,C52), C60(C61,C62,C63,C64,C65), C67(C68,
 C69,C70,C71,C72), C73(C74,C75,C76,C77,C78)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.75342(16) 0.5000 0.5000 0.0301(7) Uani 1 2 d S TU P . .
Ag2 Ag 0.68161(11) 0.55949(5) 0.50010(12) 0.0331(6) Uani 1 1 d . U . . .
Ag3 Ag 0.84222(11) 0.55787(5) 0.50015(11) 0.0298(6) Uani 1 1 d . U . . .
Ag4 Ag 0.83797(11) 0.49999(10) 0.57126(6) 0.0328(6) Uani 1 1 d . U . . .
Ag5 Ag 0.67790(12) 0.49993(10) 0.42070(6) 0.0338(6) Uani 1 1 d . U . . .
Ag6 Ag 0.58249(16) 0.5000 0.5000 0.0316(7) Uani 1 2 d S TU P . .
Ag7 Ag 0.7599(2) 0.56649(8) 0.58448(8) 0.0347(8) Uani 1 1 d . U . . .
Ag8 Ag 0.94860(15) 0.5000 0.5000 0.0309(7) Uani 1 2 d S TU P . .
Ag9 Ag 0.75821(19) 0.56648(8) 0.41471(8) 0.0335(8) Uani 1 1 d . U . . .
Cl1 Cl 0.9260(13) 0.6118(4) 0.4838(7) 0.133(8) Uani 1 1 d . U . . .
Cl2 Cl 0.6022(16) 0.4970(13) 0.3451(8) 0.255(18) Uani 1 1 d . U . . .
P1 P 0.5049(4) 0.5564(2) 0.5005(4) 0.0332(16) Uani 1 1 d . U . . .
P2 P 0.6833(7) 0.6230(3) 0.5833(4) 0.042(3) Uani 1 1 d . U . . .
P3 P 0.6866(8) 0.6244(3) 0.4159(3) 0.038(3) Uani 1 1 d . U . . .
P4 P 0.8396(8) 0.5663(3) 0.6554(3) 0.046(3) Uani 1 1 d . U . . .
P5 P 1.0203(4) 0.4996(5) 0.5740(2) 0.043(2) Uani 1 1 d . U . . .
P6 P 0.8345(8) 0.5650(3) 0.3444(3) 0.041(3) Uani 1 1 d . U . . .
N1 N 0.6116(14) 0.6092(7) 0.4990(13) 0.040(6) Uani 1 1 d . U . . .
N2 N 0.9056(14) 0.4980(11) 0.6359(7) 0.038(6) Uani 1 1 d . U . . .
C1 C 0.542(2) 0.6022(8) 0.5191(12) 0.038(8) Uani 1 1 d . U . . .
H1A H 0.5096 0.6211 0.5096 0.045 Uiso 1 1 calc R . . . .
H1B H 0.5462 0.6029 0.5528 0.045 Uiso 1 1 calc R . . . .
C2 C 0.4383(15) 0.5518(9) 0.5445(8) 0.054(9) Uani 1 1 d . U . . .
C3 C 0.4546(16) 0.5518(10) 0.5919(9) 0.077(13) Uani 1 1 d G U . . .
H3 H 0.5006 0.5575 0.6017 0.092 Uiso 1 1 calc R . . . .
C4 C 0.402(2) 0.5430(10) 0.6244(7) 0.102(16) Uani 1 1 d G U . . .
H4 H 0.4133 0.5430 0.6561 0.122 Uiso 1 1 calc R . . . .
C5 C 0.3336(18) 0.5344(10) 0.6097(11) 0.097(16) Uani 1 1 d G U . . .
H5 H 0.2986 0.5286 0.6314 0.116 Uiso 1 1 calc R . . . .
C6 C 0.3172(14) 0.5345(11) 0.5623(13) 0.105(16) Uani 1 1 d G U . . .
H6 H 0.2712 0.5287 0.5525 0.126 Uiso 1 1 calc R . . . .
C7 C 0.3695(16) 0.5432(11) 0.5298(8) 0.103(15) Uani 1 1 d G U . . .
H7 H 0.3586 0.5433 0.4981 0.124 Uiso 1 1 calc R . . . .
C8 C 0.4601(19) 0.5694(10) 0.4439(9) 0.069(11) Uani 1 1 d . U . . .
C9 C 0.423(2) 0.6018(10) 0.4391(11) 0.134(19) Uani 1 1 d G U . . .
H9 H 0.4213 0.6181 0.4638 0.161 Uiso 1 1 calc R . . . .
C10 C 0.389(2) 0.6099(9) 0.3974(13) 0.105(16) Uani 1 1 d G U . . .
H10 H 0.3640 0.6316 0.3942 0.126 Uiso 1 1 calc R . . . .
C11 C 0.3913(19) 0.5856(11) 0.3604(10) 0.097(15) Uani 1 1 d G U . . .
H11 H 0.3684 0.5910 0.3325 0.116 Uiso 1 1 calc R . . . .
C12 C 0.428(2) 0.5532(9) 0.3652(10) 0.083(14) Uani 1 1 d G U . . .
H12 H 0.4301 0.5370 0.3404 0.100 Uiso 1 1 calc R . . . .
C13 C 0.4627(18) 0.5451(7) 0.4069(11) 0.063(12) Uani 1 1 d G U . . .
H13 H 0.4874 0.5235 0.4101 0.075 Uiso 1 1 calc R . . . .
C14 C 0.646(2) 0.6352(10) 0.5179(11) 0.045(9) Uani 1 1 d . U . . .
C15 C 0.6154(15) 0.6365(9) 0.6212(9) 0.074(11) Uani 1 1 d . U . . .
C16 C 0.6134(17) 0.6122(8) 0.6582(9) 0.067(12) Uani 1 1 d G U . . .
H16 H 0.6488 0.5947 0.6612 0.081 Uiso 1 1 calc R . . . .
C17 C 0.559(2) 0.6142(9) 0.6908(9) 0.093(15) Uani 1 1 d G U . . .
H17 H 0.5572 0.5979 0.7156 0.111 Uiso 1 1 calc R . . . .
C18 C 0.5056(17) 0.6403(10) 0.6864(11) 0.099(15) Uani 1 1 d G U . . .
H18 H 0.4689 0.6416 0.7082 0.119 Uiso 1 1 calc R . . . .
C19 C 0.5076(16) 0.6646(8) 0.6494(11) 0.086(14) Uani 1 1 d G U . . .
H19 H 0.4722 0.6821 0.6464 0.104 Uiso 1 1 calc R . . . .
C20 C 0.5625(18) 0.6627(8) 0.6168(9) 0.076(13) Uani 1 1 d G U . . .
H20 H 0.5638 0.6789 0.5920 0.091 Uiso 1 1 calc R . . . .
C21 C 0.7508(18) 0.6608(8) 0.5929(12) 0.091(14) Uani 1 1 d . U . . .
C22 C 0.746(2) 0.6805(11) 0.6341(12) 0.138(19) Uani 1 1 d G U . . .
H22 H 0.7135 0.6737 0.6571 0.166 Uiso 1 1 calc R . . . .
C23 C 0.790(3) 0.7104(11) 0.6410(12) 0.16(2) Uani 1 1 d G U . . .
H23 H 0.7867 0.7235 0.6686 0.189 Uiso 1 1 calc R . . . .
C24 C 0.839(2) 0.7205(10) 0.6068(14) 0.128(19) Uani 1 1 d G U . . .
H24 H 0.8679 0.7405 0.6114 0.154 Uiso 1 1 calc R . . . .
C25 C 0.8433(18) 0.7008(8) 0.5656(11) 0.083(14) Uani 1 1 d G U . . .
H25 H 0.8758 0.7076 0.5427 0.100 Uiso 1 1 calc R . . . .
C26 C 0.7995(16) 0.6709(6) 0.5587(9) 0.041(8) Uani 1 1 d G U . . .
H26 H 0.8027 0.6577 0.5311 0.049 Uiso 1 1 calc R . . . .
C27 C 0.601(3) 0.6248(11) 0.4539(15) 0.070(12) Uani 1 1 d . U . . .
C28 C 0.642(2) 0.6265(8) 0.3574(8) 0.066(11) Uani 1 1 d . U . . .
C29 C 0.598(2) 0.5988(8) 0.3421(10) 0.080(14) Uani 1 1 d G U . . .
H29 H 0.5835 0.5808 0.3628 0.096 Uiso 1 1 calc R . . . .
C30 C 0.575(2) 0.5979(10) 0.2959(11) 0.118(18) Uani 1 1 d G U . . .
H30 H 0.5456 0.5793 0.2857 0.141 Uiso 1 1 calc R . . . .
C31 C 0.597(2) 0.6247(11) 0.2650(8) 0.109(17) Uani 1 1 d G U . . .
H31 H 0.5817 0.6241 0.2341 0.130 Uiso 1 1 calc R . . . .
C32 C 0.641(3) 0.6525(9) 0.2803(9) 0.112(17) Uani 1 1 d G U . . .
H32 H 0.6557 0.6704 0.2596 0.134 Uiso 1 1 calc R . . . .
C33 C 0.664(2) 0.6534(7) 0.3265(11) 0.096(15) Uani 1 1 d G U . . .
H33 H 0.6936 0.6719 0.3367 0.115 Uiso 1 1 calc R . . . .
C34 C 0.7370(15) 0.6584(5) 0.4220(9) 0.044(9) Uani 1 1 d . U . . .
C35 C 0.7029(14) 0.6915(6) 0.4276(10) 0.055(10) Uani 1 1 d G U . . .
H35 H 0.6535 0.6931 0.4244 0.066 Uiso 1 1 calc R . . . .
C36 C 0.7427(19) 0.7222(4) 0.4380(12) 0.086(14) Uani 1 1 d G U . . .
H36 H 0.7199 0.7444 0.4418 0.103 Uiso 1 1 calc R . . . .
C37 C 0.8165(18) 0.7198(6) 0.4428(12) 0.102(16) Uani 1 1 d G U . . .
H37 H 0.8431 0.7404 0.4497 0.122 Uiso 1 1 calc R . . . .
C38 C 0.8506(14) 0.6867(8) 0.4372(11) 0.080(14) Uani 1 1 d G U . . .
H38 H 0.8999 0.6851 0.4403 0.096 Uiso 1 1 calc R . . . .
C39 C 0.8108(15) 0.6560(6) 0.4268(10) 0.075(13) Uani 1 1 d G U . . .
H39 H 0.8336 0.6338 0.4230 0.090 Uiso 1 1 calc R . . . .
C40 C 0.9230(19) 0.5383(9) 0.6502(11) 0.036(7) Uani 1 1 d . U . . .
H40A H 0.9543 0.5489 0.6270 0.043 Uiso 1 1 calc R . . . .
H40B H 0.9481 0.5383 0.6799 0.043 Uiso 1 1 calc R . . . .
C41 C 0.7721(17) 0.5770(8) 0.7052(8) 0.052(9) Uani 1 1 d . U . . .
C42 C 0.7708(18) 0.6085(7) 0.7318(11) 0.080(13) Uani 1 1 d G U . . .
H42 H 0.8009 0.6276 0.7243 0.096 Uiso 1 1 calc R . . . .
C43 C 0.725(2) 0.6112(9) 0.7696(11) 0.103(16) Uani 1 1 d G U . . .
H43 H 0.7238 0.6323 0.7875 0.124 Uiso 1 1 calc R . . . .
C44 C 0.680(2) 0.5826(12) 0.7808(10) 0.119(18) Uani 1 1 d G U . . .
H44 H 0.6487 0.5844 0.8061 0.143 Uiso 1 1 calc R . . . .
C45 C 0.681(2) 0.5512(10) 0.7542(11) 0.123(18) Uani 1 1 d G U . . .
H45 H 0.6507 0.5320 0.7617 0.147 Uiso 1 1 calc R . . . .
C46 C 0.727(2) 0.5484(7) 0.7164(9) 0.060(11) Uani 1 1 d G U . . .
H46 H 0.7279 0.5274 0.6985 0.072 Uiso 1 1 calc R . . . .
C47 C 0.9018(18) 0.5971(8) 0.6597(9) 0.050(9) Uani 1 1 d . U . . .
C48 C 0.916(2) 0.6212(10) 0.6235(9) 0.107(16) Uani 1 1 d G U . . .
H48 H 0.8930 0.6183 0.5949 0.129 Uiso 1 1 calc R . . . .
C49 C 0.963(2) 0.6496(9) 0.6302(14) 0.099(16) Uani 1 1 d G U . . .
H49 H 0.9724 0.6657 0.6060 0.119 Uiso 1 1 calc R . . . .
C50 C 0.997(2) 0.6539(10) 0.6730(16) 0.114(18) Uani 1 1 d G U . . .
H50 H 1.0288 0.6729 0.6775 0.137 Uiso 1 1 calc R . . . .
C51 C 0.983(2) 0.6299(12) 0.7092(12) 0.136(19) Uani 1 1 d G U . . .
H51 H 1.0058 0.6328 0.7379 0.164 Uiso 1 1 calc R . . . .
C52 C 0.936(2) 0.6015(10) 0.7025(8) 0.100(16) Uani 1 1 d G U . . .
H52 H 0.9264 0.5854 0.7267 0.120 Uiso 1 1 calc R . . . .
C53 C 0.971(2) 0.4778(10) 0.6268(12) 0.043(8) Uani 1 1 d . U . . .
H53A H 0.9595 0.4528 0.6199 0.051 Uiso 1 1 calc R . . . .
H53B H 1.0015 0.4783 0.6542 0.051 Uiso 1 1 calc R . . . .
C54 C 1.071(3) 0.5345(12) 0.5915(15) 0.058(10) Uani 1 1 d . U . . .
C55 C 1.084(2) 0.5605(13) 0.5617(11) 0.054(11) Uani 1 1 d . U . . .
H55 H 1.0559 0.5641 0.5352 0.065 Uiso 1 1 calc R . . . .
C56 C 1.137(4) 0.5806(16) 0.571(2) 0.096(15) Uani 1 1 d . U . . .
H56 H 1.1651 0.5887 0.5468 0.116 Uiso 1 1 calc R . . . .
C57 C 1.155(3) 0.5911(13) 0.6155(13) 0.073(13) Uani 1 1 d . U . . .
H57 H 1.1728 0.6139 0.6228 0.087 Uiso 1 1 calc R . . . .
C58 C 1.146(3) 0.5650(13) 0.6468(14) 0.066(11) Uani 1 1 d . U . . .
H58 H 1.1664 0.5669 0.6762 0.079 Uiso 1 1 calc R . . . .
C59 C 1.106(2) 0.5362(12) 0.6362(13) 0.055(10) Uani 1 1 d . U . . .
H59 H 1.1007 0.5173 0.6575 0.066 Uiso 1 1 calc R . . . .
C60 C 1.0865(17) 0.4616(7) 0.5691(13) 0.077(12) Uani 1 1 d . U . . .
C61 C 1.1591(19) 0.4697(6) 0.5684(12) 0.095(15) Uani 1 1 d G U . . .
H61 H 1.1742 0.4936 0.5708 0.114 Uiso 1 1 calc R . . . .
C62 C 1.2091(15) 0.4420(9) 0.5642(12) 0.089(14) Uani 1 1 d G U . . .
H62 H 1.2577 0.4475 0.5637 0.106 Uiso 1 1 calc R . . . .
C63 C 1.1865(18) 0.4063(8) 0.5606(11) 0.075(13) Uani 1 1 d G U . . .
H63 H 1.2200 0.3879 0.5578 0.090 Uiso 1 1 calc R . . . .
C64 C 1.1140(19) 0.3982(6) 0.5613(11) 0.066(12) Uani 1 1 d G U . . .
H64 H 1.0989 0.3744 0.5589 0.079 Uiso 1 1 calc R . . . .
C65 C 1.0640(15) 0.4259(8) 0.5655(13) 0.096(16) Uani 1 1 d G U . . .
H65 H 1.0154 0.4204 0.5660 0.115 Uiso 1 1 calc R . . . .
C66 C 0.868(3) 0.4797(10) 0.6739(10) 0.048(10) Uani 1 1 d . U . . .
H66A H 0.8276 0.4945 0.6838 0.057 Uiso 1 1 calc R . . . .
H66B H 0.8996 0.4768 0.7003 0.057 Uiso 1 1 calc R . . . .
C67 C 0.8061(17) 0.5656(12) 0.2848(7) 0.093(13) Uani 1 1 d . U . . .
C68 C 0.7323(16) 0.5650(14) 0.2794(9) 0.137(18) Uani 1 1 d G U . . .
H68 H 0.7027 0.5693 0.3049 0.164 Uiso 1 1 calc R . . . .
C69 C 0.7026(14) 0.5578(14) 0.2359(11) 0.128(18) Uani 1 1 d G U . . .
H69 H 0.6532 0.5574 0.2323 0.154 Uiso 1 1 calc R . . . .
C70 C 0.7468(18) 0.5513(14) 0.1978(8) 0.131(18) Uani 1 1 d G U . . .
H70 H 0.7269 0.5465 0.1687 0.157 Uiso 1 1 calc R . . . .
C71 C 0.8206(17) 0.5520(12) 0.2032(8) 0.093(14) Uani 1 1 d G U . . .
H71 H 0.8502 0.5476 0.1777 0.112 Uiso 1 1 calc R . . . .
C72 C 0.8503(14) 0.5591(11) 0.2467(9) 0.079(13) Uani 1 1 d G U . . .
H72 H 0.8997 0.5596 0.2503 0.095 Uiso 1 1 calc R . . . .
C73 C 0.8990(18) 0.6080(5) 0.3313(11) 0.077(14) Uani 1 1 d . U . . .
C74 C 0.8598(17) 0.6350(8) 0.3091(9) 0.081(13) Uani 1 1 d G U . . .
H74 H 0.8152 0.6297 0.2965 0.098 Uiso 1 1 calc R . . . .
C75 C 0.887(2) 0.6698(6) 0.3057(12) 0.099(15) Uani 1 1 d G U . . .
H75 H 0.8612 0.6878 0.2908 0.118 Uiso 1 1 calc R . . . .
C76 C 0.954(2) 0.6777(5) 0.3245(13) 0.122(18) Uani 1 1 d G U . . .
H76 H 0.9725 0.7010 0.3222 0.146 Uiso 1 1 calc R . . . .
C77 C 0.9933(19) 0.6508(7) 0.3467(12) 0.091(15) Uani 1 1 d G U . . .
H77 H 1.0379 0.6560 0.3593 0.109 Uiso 1 1 calc R . . . .
C78 C 0.9657(18) 0.6159(6) 0.3501(11) 0.079(13) Uani 1 1 d G U . . .
H78 H 0.9919 0.5979 0.3649 0.095 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag2 2.577(3) . ?
Ag1 Ag2 2.577(3) 3_566 ?
Ag1 Ag3 2.709(3) 3_566 ?
Ag1 Ag3 2.709(3) . ?
Ag1 Ag4 2.583(3) . ?
Ag1 Ag4 2.583(3) 3_566 ?
Ag1 Ag5 2.675(2) . ?
Ag1 Ag5 2.675(2) 3_566 ?
Ag1 Ag6 3.197(4) . ?
Ag2 Ag3 3.004(3) . ?
Ag2 Ag5 3.167(4) . ?
Ag2 Ag5 3.159(4) 3_566 ?
Ag2 Ag6 2.876(3) . ?
Ag2 Ag7 2.838(4) . ?
Ag2 Ag9 2.847(4) . ?
Ag2 N1 2.26(3) . ?
Ag3 Ag4 2.961(4) 3_566 ?
Ag3 Ag4 2.956(4) . ?
Ag3 Ag7 2.883(4) . ?
Ag3 Ag8 2.922(3) . ?
Ag3 Ag9 2.926(4) . ?
Ag3 Cl1 2.58(2) . ?
Ag4 Ag3 2.961(4) 3_566 ?
Ag4 Ag5 3.002(3) 3_566 ?
Ag4 Ag7 2.885(4) . ?
Ag4 Ag8 2.907(3) . ?
Ag4 Ag9 2.903(4) 3_566 ?
Ag4 N2 2.24(2) . ?
Ag5 Ag2 3.159(4) 3_566 ?
Ag5 Ag4 3.003(3) 3_566 ?
Ag5 Ag6 2.889(3) . ?
Ag5 Ag7 2.899(4) 3_566 ?
Ag5 Ag9 2.888(5) . ?
Ag5 Cl2 2.59(2) . ?
Ag6 Ag2 2.877(3) 3_566 ?
Ag6 Ag5 2.889(3) 3_566 ?
Ag6 P1 2.540(7) 3_566 ?
Ag6 P1 2.540(7) . ?
Ag7 Ag5 2.899(4) 3_566 ?
Ag7 P2 2.534(12) . ?
Ag7 P4 2.520(11) . ?
Ag8 Ag3 2.922(3) 3_566 ?
Ag8 Ag4 2.907(3) 3_566 ?
Ag8 P5 2.508(7) . ?
Ag8 P5 2.508(7) 3_566 ?
Ag9 Ag4 2.903(4) 3_566 ?
Ag9 P3 2.526(11) . ?
Ag9 P6 2.468(11) . ?
P1 C1 1.91(3) . ?
P1 C2 1.78(2) . ?
P1 C8 1.89(2) . ?
P2 C14 2.05(3) . ?
P2 C15 1.74(2) . ?
P2 C21 1.90(3) . ?
P3 C27 1.94(5) . ?
P3 C28 1.87(2) . ?
P3 C34 1.58(2) . ?
P4 C40 1.88(4) . ?
P4 C41 1.95(2) . ?
P4 C47 1.63(3) . ?
P5 C53 1.95(4) . ?
P5 C54 1.67(4) . ?
P5 C60 1.88(3) . ?
P6 C66 1.84(4) 3_566 ?
P6 C67 1.79(2) . ?
P6 C73 2.03(3) . ?
N1 C1 1.44(5) . ?
N1 C14 1.28(4) . ?
N1 C27 1.43(5) . ?
N2 C40 1.58(5) . ?
N2 C53 1.46(5) . ?
N2 C66 1.47(4) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 C3 1.3900 . ?
C2 C7 1.3900 . ?
C3 H3 0.9300 . ?
C3 C4 1.3900 . ?
C4 H4 0.9300 . ?
C4 C5 1.3900 . ?
C5 H5 0.9300 . ?
C5 C6 1.3900 . ?
C6 H6 0.9300 . ?
C6 C7 1.3900 . ?
C7 H7 0.9300 . ?
C8 C9 1.3900 . ?
C8 C13 1.3900 . ?
C9 H9 0.9300 . ?
C9 C10 1.3900 . ?
C10 H10 0.9300 . ?
C10 C11 1.3900 . ?
C11 H11 0.9300 . ?
C11 C12 1.3900 . ?
C12 H12 0.9300 . ?
C12 C13 1.3900 . ?
C13 H13 0.9300 . ?
C14 C27 2.06(6) . ?
C15 C16 1.3900 . ?
C15 C20 1.3900 . ?
C16 H16 0.9300 . ?
C16 C17 1.3900 . ?
C17 H17 0.9300 . ?
C17 C18 1.3900 . ?
C18 H18 0.9300 . ?
C18 C19 1.3900 . ?
C19 H19 0.9300 . ?
C19 C20 1.3900 . ?
C20 H20 0.9300 . ?
C21 C22 1.3900 . ?
C21 C26 1.3900 . ?
C22 H22 0.9300 . ?
C22 C23 1.3900 . ?
C23 H23 0.9300 . ?
C23 C24 1.3900 . ?
C24 H24 0.9300 . ?
C24 C25 1.3900 . ?
C25 H25 0.9300 . ?
C25 C26 1.3900 . ?
C26 H26 0.9300 . ?
C28 C29 1.3900 . ?
C28 C33 1.3900 . ?
C29 H29 0.9300 . ?
C29 C30 1.3900 . ?
C30 H30 0.9300 . ?
C30 C31 1.3900 . ?
C31 H31 0.9300 . ?
C31 C32 1.3900 . ?
C32 H32 0.9300 . ?
C32 C33 1.3900 . ?
C33 H33 0.9300 . ?
C34 C35 1.3900 . ?
C34 C39 1.3900 . ?
C35 H35 0.9300 . ?
C35 C36 1.3900 . ?
C36 H36 0.9300 . ?
C36 C37 1.3900 . ?
C37 H37 0.9300 . ?
C37 C38 1.3900 . ?
C38 H38 0.9300 . ?
C38 C39 1.3900 . ?
C39 H39 0.9300 . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C41 C42 1.3900 . ?
C41 C46 1.3900 . ?
C42 H42 0.9300 . ?
C42 C43 1.3900 . ?
C43 H43 0.9300 . ?
C43 C44 1.3900 . ?
C44 H44 0.9300 . ?
C44 C45 1.3900 . ?
C45 H45 0.9300 . ?
C45 C46 1.3900 . ?
C46 H46 0.9300 . ?
C47 C48 1.3900 . ?
C47 C52 1.3900 . ?
C48 H48 0.9300 . ?
C48 C49 1.3900 . ?
C49 H49 0.9300 . ?
C49 C50 1.3900 . ?
C50 H50 0.9300 . ?
C50 C51 1.3900 . ?
C51 H51 0.9300 . ?
C51 C52 1.3900 . ?
C52 H52 0.9300 . ?
C53 H53A 0.9700 . ?
C53 H53B 0.9700 . ?
C54 C55 1.31(6) . ?
C54 C59 1.44(6) . ?
C55 H55 0.9300 . ?
C55 C56 1.27(7) . ?
C56 H56 0.9300 . ?
C56 C57 1.37(7) . ?
C57 H57 0.9300 . ?
C57 C58 1.33(6) . ?
C58 H58 0.9300 . ?
C58 C59 1.34(5) . ?
C59 H59 0.9300 . ?
C60 C61 1.3900 . ?
C60 C65 1.3900 . ?
C61 H61 0.9300 . ?
C61 C62 1.3900 . ?
C62 H62 0.9300 . ?
C62 C63 1.3900 . ?
C63 H63 0.9300 . ?
C63 C64 1.3900 . ?
C64 H64 0.9300 . ?
C64 C65 1.3900 . ?
C65 H65 0.9300 . ?
C66 P6 1.84(4) 3_566 ?
C66 H66A 0.9700 . ?
C66 H66B 0.9700 . ?
C67 C68 1.3900 . ?
C67 C72 1.3900 . ?
C68 H68 0.9300 . ?
C68 C69 1.3900 . ?
C69 H69 0.9300 . ?
C69 C70 1.3900 . ?
C70 H70 0.9300 . ?
C70 C71 1.3900 . ?
C71 H71 0.9300 . ?
C71 C72 1.3900 . ?
C72 H72 0.9300 . ?
C73 C74 1.3900 . ?
C73 C78 1.3900 . ?
C74 H74 0.9300 . ?
C74 C75 1.3900 . ?
C75 H75 0.9300 . ?
C75 C76 1.3900 . ?
C76 H76 0.9300 . ?
C76 C77 1.3900 . ?
C77 H77 0.9300 . ?
C77 C78 1.3900 . ?
C78 H78 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ag1 Ag2 117.19(15) . 3_566 ?
Ag2 Ag1 Ag3 173.58(12) 3_566 . ?
Ag2 Ag1 Ag3 69.22(7) 3_566 3_566 ?
Ag2 Ag1 Ag3 69.23(7) . . ?
Ag2 Ag1 Ag3 173.59(12) . 3_566 ?
Ag2 Ag1 Ag4 108.56(10) 3_566 3_566 ?
Ag2 Ag1 Ag4 108.65(10) . 3_566 ?
Ag2 Ag1 Ag4 108.65(10) 3_566 . ?
Ag2 Ag1 Ag4 108.56(10) . . ?
Ag2 Ag1 Ag5 73.93(12) . 3_566 ?
Ag2 Ag1 Ag5 73.93(12) 3_566 . ?
Ag2 Ag1 Ag5 74.14(12) 3_566 3_566 ?
Ag2 Ag1 Ag5 74.14(12) . . ?
Ag2 Ag1 Ag6 58.60(7) 3_566 . ?
Ag2 Ag1 Ag6 58.59(7) . . ?
Ag3 Ag1 Ag3 104.36(13) . 3_566 ?
Ag3 Ag1 Ag6 127.82(6) 3_566 . ?
Ag3 Ag1 Ag6 127.82(6) . . ?
Ag4 Ag1 Ag3 67.87(11) 3_566 3_566 ?
Ag4 Ag1 Ag3 68.02(11) . 3_566 ?
Ag4 Ag1 Ag3 68.02(11) 3_566 . ?
Ag4 Ag1 Ag3 67.88(11) . . ?
Ag4 Ag1 Ag4 104.49(13) . 3_566 ?
Ag4 Ag1 Ag5 69.62(7) 3_566 . ?
Ag4 Ag1 Ag5 174.11(12) . . ?
Ag4 Ag1 Ag5 69.62(7) . 3_566 ?
Ag4 Ag1 Ag5 174.11(12) 3_566 3_566 ?
Ag4 Ag1 Ag6 127.76(7) 3_566 . ?
Ag4 Ag1 Ag6 127.76(7) . . ?
Ag5 Ag1 Ag3 108.76(9) . 3_566 ?
Ag5 Ag1 Ag3 109.02(10) 3_566 3_566 ?
Ag5 Ag1 Ag3 109.01(10) . . ?
Ag5 Ag1 Ag3 108.76(9) 3_566 . ?
Ag5 Ag1 Ag5 116.27(14) . 3_566 ?
Ag5 Ag1 Ag6 58.14(7) . . ?
Ag5 Ag1 Ag6 58.14(7) 3_566 . ?
Ag1 Ag2 Ag3 57.45(8) . . ?
Ag1 Ag2 Ag5 54.46(7) . 3_566 ?
Ag1 Ag2 Ag5 54.35(7) . . ?
Ag1 Ag2 Ag6 71.53(9) . . ?
Ag1 Ag2 Ag7 79.05(10) . . ?
Ag1 Ag2 Ag9 79.30(9) . . ?
Ag3 Ag2 Ag5 90.44(10) . 3_566 ?
Ag3 Ag2 Ag5 90.48(10) . . ?
Ag5 Ag2 Ag5 91.83(7) 3_566 . ?
Ag6 Ag2 Ag3 128.98(9) . . ?
Ag6 Ag2 Ag5 56.87(7) . . ?
Ag6 Ag2 Ag5 56.96(7) . 3_566 ?
Ag7 Ag2 Ag3 59.04(10) . . ?
Ag7 Ag2 Ag5 57.52(10) . 3_566 ?
Ag7 Ag2 Ag5 133.37(11) . . ?
Ag7 Ag2 Ag6 113.77(12) . . ?
Ag7 Ag2 Ag9 117.65(9) . . ?
Ag9 Ag2 Ag3 59.94(10) . . ?
Ag9 Ag2 Ag5 133.75(10) . 3_566 ?
Ag9 Ag2 Ag5 57.10(10) . . ?
Ag9 Ag2 Ag6 113.13(12) . . ?
N1 Ag2 Ag1 175.8(7) . . ?
N1 Ag2 Ag3 126.6(7) . . ?
N1 Ag2 Ag5 122.9(9) . . ?
N1 Ag2 Ag5 124.3(9) . 3_566 ?
N1 Ag2 Ag6 104.4(7) . . ?
N1 Ag2 Ag7 103.7(9) . . ?
N1 Ag2 Ag9 101.9(9) . . ?
Ag1 Ag3 Ag2 53.32(7) . . ?
Ag1 Ag3 Ag4 54.04(7) . . ?
Ag1 Ag3 Ag4 53.97(7) . 3_566 ?
Ag1 Ag3 Ag7 76.19(9) . . ?
Ag1 Ag3 Ag8 80.74(9) . . ?
Ag1 Ag3 Ag9 75.84(9) . . ?
Ag4 Ag3 Ag2 89.27(9) 3_566 . ?
Ag4 Ag3 Ag2 89.31(10) . . ?
Ag4 Ag3 Ag4 87.28(7) . 3_566 ?
Ag7 Ag3 Ag2 57.61(10) . . ?
Ag7 Ag3 Ag4 130.15(10) . 3_566 ?
Ag7 Ag3 Ag4 59.20(9) . . ?
Ag7 Ag3 Ag8 116.48(12) . . ?
Ag7 Ag3 Ag9 113.73(9) . . ?
Ag8 Ag3 Ag2 134.06(9) . . ?
Ag8 Ag3 Ag4 59.28(7) . . ?
Ag8 Ag3 Ag4 59.22(7) . 3_566 ?
Ag8 Ag3 Ag9 116.37(11) . . ?
Ag9 Ag3 Ag2 57.36(10) . . ?
Ag9 Ag3 Ag4 59.08(9) . 3_566 ?
Ag9 Ag3 Ag4 129.87(10) . . ?
Cl1 Ag3 Ag1 169.4(5) . . ?
Cl1 Ag3 Ag2 126.3(5) . . ?
Cl1 Ag3 Ag4 116.7(5) . 3_566 ?
Cl1 Ag3 Ag4 134.5(4) . . ?
Cl1 Ag3 Ag7 113.0(5) . . ?
Cl1 Ag3 Ag8 98.8(5) . . ?
Cl1 Ag3 Ag9 95.2(4) . . ?
Ag1 Ag4 Ag3 58.01(7) . 3_566 ?
Ag1 Ag4 Ag3 58.09(7) . . ?
Ag1 Ag4 Ag5 56.64(7) . 3_566 ?
Ag1 Ag4 Ag7 78.10(10) . . ?
Ag1 Ag4 Ag8 83.14(9) . . ?
Ag1 Ag4 Ag9 78.17(9) . 3_566 ?
Ag3 Ag4 Ag3 92.63(7) . 3_566 ?
Ag3 Ag4 Ag5 94.53(11) . 3_566 ?
Ag3 Ag4 Ag5 94.61(11) 3_566 3_566 ?
Ag7 Ag4 Ag3 59.14(10) . . ?
Ag7 Ag4 Ag3 136.06(10) . 3_566 ?
Ag7 Ag4 Ag5 58.97(12) . 3_566 ?
Ag7 Ag4 Ag8 116.90(13) . . ?
Ag7 Ag4 Ag9 116.32(9) . 3_566 ?
Ag8 Ag4 Ag3 59.71(6) . 3_566 ?
Ag8 Ag4 Ag3 59.77(7) . . ?
Ag8 Ag4 Ag5 139.78(9) . 3_566 ?
Ag9 Ag4 Ag3 59.86(9) 3_566 3_566 ?
Ag9 Ag4 Ag3 136.23(10) 3_566 . ?
Ag9 Ag4 Ag5 58.52(11) 3_566 3_566 ?
Ag9 Ag4 Ag8 117.59(12) 3_566 . ?
N2 Ag4 Ag1 176.1(8) . . ?
N2 Ag4 Ag3 125.2(10) . . ?
N2 Ag4 Ag3 122.1(9) . 3_566 ?
N2 Ag4 Ag5 119.9(6) . 3_566 ?
N2 Ag4 Ag7 101.8(9) . . ?
N2 Ag4 Ag8 100.3(6) . . ?
N2 Ag4 Ag9 98.5(10) . 3_566 ?
Ag1 Ag5 Ag2 51.61(7) . 3_566 ?
Ag1 Ag5 Ag2 51.51(7) . . ?
Ag1 Ag5 Ag4 53.74(7) . 3_566 ?
Ag1 Ag5 Ag6 70.01(8) . . ?
Ag1 Ag5 Ag7 76.41(9) . 3_566 ?
Ag1 Ag5 Ag9 77.01(9) . . ?
Ag2 Ag5 Ag2 88.11(7) 3_566 . ?
Ag4 Ag5 Ag2 85.55(10) 3_566 . ?
Ag4 Ag5 Ag2 85.62(10) 3_566 3_566 ?
Ag6 Ag5 Ag2 56.58(7) . 3_566 ?
Ag6 Ag5 Ag2 56.50(7) . . ?
Ag6 Ag5 Ag4 123.75(9) . 3_566 ?
Ag6 Ag5 Ag7 111.58(12) . 3_566 ?
Ag7 Ag5 Ag2 55.67(9) 3_566 3_566 ?
Ag7 Ag5 Ag2 127.89(10) 3_566 . ?
Ag7 Ag5 Ag4 58.49(12) 3_566 3_566 ?
Ag9 Ag5 Ag2 128.60(10) . 3_566 ?
Ag9 Ag5 Ag2 55.87(9) . . ?
Ag9 Ag5 Ag4 59.02(12) . 3_566 ?
Ag9 Ag5 Ag6 111.55(12) . . ?
Ag9 Ag5 Ag7 116.34(10) . 3_566 ?
Cl2 Ag5 Ag1 177.3(10) . . ?
Cl2 Ag5 Ag2 129.9(10) . . ?
Cl2 Ag5 Ag2 125.7(10) . 3_566 ?
Cl2 Ag5 Ag4 127.5(7) . 3_566 ?
Cl2 Ag5 Ag6 108.7(7) . . ?
Cl2 Ag5 Ag7 102.2(10) . 3_566 ?
Cl2 Ag5 Ag9 105.7(10) . . ?
Ag2 Ag6 Ag1 49.87(6) . . ?
Ag2 Ag6 Ag1 49.88(6) 3_566 . ?
Ag2 Ag6 Ag2 99.75(12) . 3_566 ?
Ag2 Ag6 Ag5 66.64(10) 3_566 3_566 ?
Ag2 Ag6 Ag5 66.45(11) . 3_566 ?
Ag2 Ag6 Ag5 66.63(10) . . ?
Ag2 Ag6 Ag5 66.45(11) 3_566 . ?
Ag5 Ag6 Ag1 51.86(6) 3_566 . ?
Ag5 Ag6 Ag1 51.86(6) . . ?
Ag5 Ag6 Ag5 103.71(12) . 3_566 ?
P1 Ag6 Ag1 124.84(17) . . ?
P1 Ag6 Ag1 124.84(17) 3_566 . ?
P1 Ag6 Ag2 74.97(17) 3_566 3_566 ?
P1 Ag6 Ag2 174.7(2) . 3_566 ?
P1 Ag6 Ag2 174.7(2) 3_566 . ?
P1 Ag6 Ag2 74.97(17) . . ?
P1 Ag6 Ag5 111.0(2) 3_566 3_566 ?
P1 Ag6 Ag5 110.3(3) . 3_566 ?
P1 Ag6 Ag5 111.0(2) . . ?
P1 Ag6 Ag5 110.3(3) 3_566 . ?
P1 Ag6 P1 110.3(3) 3_566 . ?
Ag2 Ag7 Ag3 63.35(8) . . ?
Ag2 Ag7 Ag4 94.10(9) . . ?
Ag2 Ag7 Ag5 66.81(9) . 3_566 ?
Ag3 Ag7 Ag4 61.66(9) . . ?
Ag3 Ag7 Ag5 98.39(9) . 3_566 ?
Ag4 Ag7 Ag5 62.55(9) . 3_566 ?
P2 Ag7 Ag2 76.8(2) . . ?
P2 Ag7 Ag3 112.5(3) . . ?
P2 Ag7 Ag4 170.9(2) . . ?
P2 Ag7 Ag5 113.5(3) . 3_566 ?
P4 Ag7 Ag2 172.6(3) . . ?
P4 Ag7 Ag3 111.1(3) . . ?
P4 Ag7 Ag4 78.7(3) . . ?
P4 Ag7 Ag5 110.6(3) . 3_566 ?
P4 Ag7 P2 110.3(4) . . ?
Ag3 Ag8 Ag3 94.16(12) . 3_566 ?
Ag4 Ag8 Ag3 60.94(10) . . ?
Ag4 Ag8 Ag3 61.07(10) . 3_566 ?
Ag4 Ag8 Ag3 60.94(10) 3_566 3_566 ?
Ag4 Ag8 Ag3 61.07(10) 3_566 . ?
Ag4 Ag8 Ag4 89.24(12) . 3_566 ?
P5 Ag8 Ag3 111.2(3) . 3_566 ?
P5 Ag8 Ag3 111.2(3) 3_566 . ?
P5 Ag8 Ag3 111.5(3) . . ?
P5 Ag8 Ag3 111.5(3) 3_566 3_566 ?
P5 Ag8 Ag4 77.70(17) 3_566 3_566 ?
P5 Ag8 Ag4 166.9(2) . 3_566 ?
P5 Ag8 Ag4 77.70(17) . . ?
P5 Ag8 Ag4 166.9(2) 3_566 . ?
P5 Ag8 P5 115.4(4) . 3_566 ?
Ag2 Ag9 Ag3 62.70(8) . . ?
Ag2 Ag9 Ag4 93.59(10) . 3_566 ?
Ag2 Ag9 Ag5 67.03(10) . . ?
Ag4 Ag9 Ag3 61.06(9) 3_566 . ?
Ag5 Ag9 Ag3 97.86(10) . . ?
Ag5 Ag9 Ag4 62.46(9) . 3_566 ?
P3 Ag9 Ag2 78.4(3) . . ?
P3 Ag9 Ag3 111.5(3) . . ?
P3 Ag9 Ag4 171.3(2) . 3_566 ?
P3 Ag9 Ag5 116.5(3) . . ?
P6 Ag9 Ag2 171.9(3) . . ?
P6 Ag9 Ag3 111.7(3) . . ?
P6 Ag9 Ag4 78.3(2) . 3_566 ?
P6 Ag9 Ag5 109.3(3) . . ?
P6 Ag9 P3 109.6(3) . . ?
C1 P1 Ag6 121.3(12) . . ?
C2 P1 Ag6 109.1(12) . . ?
C2 P1 C1 98.3(16) . . ?
C2 P1 C8 108.8(15) . . ?
C8 P1 Ag6 117.3(12) . . ?
C8 P1 C1 100.1(16) . . ?
C14 P2 Ag7 112.5(12) . . ?
C15 P2 Ag7 129.8(12) . . ?
C15 P2 C14 105.2(17) . . ?
C15 P2 C21 100.6(16) . . ?
C21 P2 Ag7 103.2(13) . . ?
C21 P2 C14 101.3(17) . . ?
C27 P3 Ag9 116.9(11) . . ?
C28 P3 Ag9 105.0(12) . . ?
C28 P3 C27 98(2) . . ?
C34 P3 Ag9 111.0(12) . . ?
C34 P3 C27 115.1(19) . . ?
C34 P3 C28 109.3(14) . . ?
C40 P4 Ag7 115.4(10) . . ?
C40 P4 C41 135.1(15) . . ?
C41 P4 Ag7 101.9(11) . . ?
C47 P4 Ag7 118.8(11) . . ?
C47 P4 C40 78.4(17) . . ?
C47 P4 C41 105.4(15) . . ?
C53 P5 Ag8 114.0(12) . . ?
C54 P5 Ag8 123.4(18) . . ?
C54 P5 C53 110.6(19) . . ?
C54 P5 C60 103.2(19) . . ?
C60 P5 Ag8 107.1(12) . . ?
C60 P5 C53 93.4(17) . . ?
C66 P6 Ag9 116.5(12) 3_566 . ?
C66 P6 C73 116.7(18) 3_566 . ?
C67 P6 Ag9 127.4(13) . . ?
C67 P6 C66 80.7(17) . 3_566 ?
C67 P6 C73 89.4(16) . . ?
C73 P6 Ag9 118.5(10) . . ?
C1 N1 Ag2 111.7(19) . . ?
C14 N1 Ag2 108(2) . . ?
C14 N1 C1 115(3) . . ?
C14 N1 C27 99(3) . . ?
C27 N1 Ag2 115(3) . . ?
C27 N1 C1 108(3) . . ?
C40 N2 Ag4 107(2) . . ?
C53 N2 Ag4 110.0(19) . . ?
C53 N2 C40 111(3) . . ?
C53 N2 C66 108(3) . . ?
C66 N2 Ag4 111(2) . . ?
C66 N2 C40 110(2) . . ?
P1 C1 H1A 109.2 . . ?
P1 C1 H1B 109.2 . . ?
N1 C1 P1 112(2) . . ?
N1 C1 H1A 109.2 . . ?
N1 C1 H1B 109.1 . . ?
H1A C1 H1B 107.9 . . ?
C3 C2 P1 122.5(16) . . ?
C3 C2 C7 120.0 . . ?
C7 C2 P1 117.0(16) . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 C3 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 120.0 . . ?
C4 C5 C6 120.0 . . ?
C6 C5 H5 120.0 . . ?
C5 C6 H6 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C2 C7 H7 120.0 . . ?
C6 C7 C2 120.0 . . ?
C6 C7 H7 120.0 . . ?
C9 C8 P1 122(2) . . ?
C9 C8 C13 120.0 . . ?
C13 C8 P1 118(2) . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 120.0 . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 120.0 . . ?
C9 C10 C11 120.0 . . ?
C11 C10 H10 120.0 . . ?
C10 C11 H11 120.0 . . ?
C10 C11 C12 120.0 . . ?
C12 C11 H11 120.0 . . ?
C11 C12 H12 120.0 . . ?
C13 C12 C11 120.0 . . ?
C13 C12 H12 120.0 . . ?
C8 C13 H13 120.0 . . ?
C12 C13 C8 120.0 . . ?
C12 C13 H13 120.0 . . ?
N1 C14 P2 113(3) . . ?
N1 C14 C27 43(2) . . ?
C27 C14 P2 156(2) . . ?
C16 C15 P2 108.1(18) . . ?
C16 C15 C20 120.0 . . ?
C20 C15 P2 131.4(17) . . ?
C15 C16 H16 120.0 . . ?
C15 C16 C17 120.0 . . ?
C17 C16 H16 120.0 . . ?
C16 C17 H17 120.0 . . ?
C18 C17 C16 120.0 . . ?
C18 C17 H17 120.0 . . ?
C17 C18 H18 120.0 . . ?
C19 C18 C17 120.0 . . ?
C19 C18 H18 120.0 . . ?
C18 C19 H19 120.0 . . ?
C18 C19 C20 120.0 . . ?
C20 C19 H19 120.0 . . ?
C15 C20 H20 120.0 . . ?
C19 C20 C15 120.0 . . ?
C19 C20 H20 120.0 . . ?
C22 C21 P2 117.7(17) . . ?
C22 C21 C26 120.0 . . ?
C26 C21 P2 122.0(17) . . ?
C21 C22 H22 120.0 . . ?
C21 C22 C23 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 120.0 . . ?
C24 C23 C22 120.0 . . ?
C24 C23 H23 120.0 . . ?
C23 C24 H24 120.0 . . ?
C23 C24 C25 120.0 . . ?
C25 C24 H24 120.0 . . ?
C24 C25 H25 120.0 . . ?
C26 C25 C24 120.0 . . ?
C26 C25 H25 120.0 . . ?
C21 C26 H26 120.0 . . ?
C25 C26 C21 120.0 . . ?
C25 C26 H26 120.0 . . ?
P3 C27 C14 99(3) . . ?
N1 C27 P3 113(3) . . ?
N1 C27 C14 38(2) . . ?
C29 C28 P3 121.0(16) . . ?
C29 C28 C33 120.0 . . ?
C33 C28 P3 118.2(17) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 C28 120.0 . . ?
C30 C29 H29 120.0 . . ?
C29 C30 H30 120.0 . . ?
C29 C30 C31 120.0 . . ?
C31 C30 H30 120.0 . . ?
C30 C31 H31 120.0 . . ?
C32 C31 C30 120.0 . . ?
C32 C31 H31 120.0 . . ?
C31 C32 H32 120.0 . . ?
C31 C32 C33 120.0 . . ?
C33 C32 H32 120.0 . . ?
C28 C33 H33 120.0 . . ?
C32 C33 C28 120.0 . . ?
C32 C33 H33 120.0 . . ?
C35 C34 P3 116.1(17) . . ?
C35 C34 C39 120.0 . . ?
C39 C34 P3 123.6(17) . . ?
C34 C35 H35 120.0 . . ?
C36 C35 C34 120.0 . . ?
C36 C35 H35 120.0 . . ?
C35 C36 H36 120.0 . . ?
C37 C36 C35 120.0 . . ?
C37 C36 H36 120.0 . . ?
C36 C37 H37 120.0 . . ?
C36 C37 C38 120.0 . . ?
C38 C37 H37 120.0 . . ?
C37 C38 H38 120.0 . . ?
C39 C38 C37 120.0 . . ?
C39 C38 H38 120.0 . . ?
C34 C39 H39 120.0 . . ?
C38 C39 C34 120.0 . . ?
C38 C39 H39 120.0 . . ?
P4 C40 H40A 109.3 . . ?
P4 C40 H40B 109.3 . . ?
N2 C40 P4 112(2) . . ?
N2 C40 H40A 109.3 . . ?
N2 C40 H40B 109.2 . . ?
H40A C40 H40B 107.9 . . ?
C42 C41 P4 125.7(18) . . ?
C42 C41 C46 120.0 . . ?
C46 C41 P4 114.0(18) . . ?
C41 C42 H42 120.0 . . ?
C43 C42 C41 120.0 . . ?
C43 C42 H42 120.0 . . ?
C42 C43 H43 120.0 . . ?
C44 C43 C42 120.0 . . ?
C44 C43 H43 120.0 . . ?
C43 C44 H44 120.0 . . ?
C43 C44 C45 120.0 . . ?
C45 C44 H44 120.0 . . ?
C44 C45 H45 120.0 . . ?
C46 C45 C44 120.0 . . ?
C46 C45 H45 120.0 . . ?
C41 C46 H46 120.0 . . ?
C45 C46 C41 120.0 . . ?
C45 C46 H46 120.0 . . ?
C48 C47 P4 121.5(18) . . ?
C48 C47 C52 120.0 . . ?
C52 C47 P4 118.1(18) . . ?
C47 C48 H48 120.0 . . ?
C47 C48 C49 120.0 . . ?
C49 C48 H48 120.0 . . ?
C48 C49 H49 120.0 . . ?
C50 C49 C48 120.0 . . ?
C50 C49 H49 120.0 . . ?
C49 C50 H50 120.0 . . ?
C51 C50 C49 120.0 . . ?
C51 C50 H50 120.0 . . ?
C50 C51 H51 120.0 . . ?
C50 C51 C52 120.0 . . ?
C52 C51 H51 120.0 . . ?
C47 C52 H52 120.0 . . ?
C51 C52 C47 120.0 . . ?
C51 C52 H52 120.0 . . ?
P5 C53 H53A 110.0 . . ?
P5 C53 H53B 109.9 . . ?
N2 C53 P5 109(2) . . ?
N2 C53 H53A 109.9 . . ?
N2 C53 H53B 109.8 . . ?
H53A C53 H53B 108.3 . . ?
C55 C54 P5 118(3) . . ?
C55 C54 C59 118(4) . . ?
C59 C54 P5 124(4) . . ?
C54 C55 H55 122.0 . . ?
C54 C55 C56 116(5) . . ?
C56 C55 H55 122.5 . . ?
C55 C56 H56 117.6 . . ?
C55 C56 C57 125(5) . . ?
C57 C56 H56 117.9 . . ?
C56 C57 H57 123.9 . . ?
C58 C57 C56 113(4) . . ?
C58 C57 H57 123.6 . . ?
C57 C58 H58 120.0 . . ?
C57 C58 C59 120(4) . . ?
C59 C58 H58 119.9 . . ?
C54 C59 H59 120.4 . . ?
C58 C59 C54 119(4) . . ?
C58 C59 H59 120.3 . . ?
C61 C60 P5 119(2) . . ?
C61 C60 C65 120.0 . . ?
C65 C60 P5 121(2) . . ?
C60 C61 H61 120.0 . . ?
C60 C61 C62 120.0 . . ?
C62 C61 H61 120.0 . . ?
C61 C62 H62 120.0 . . ?
C63 C62 C61 120.0 . . ?
C63 C62 H62 120.0 . . ?
C62 C63 H63 120.0 . . ?
C62 C63 C64 120.0 . . ?
C64 C63 H63 120.0 . . ?
C63 C64 H64 120.0 . . ?
C63 C64 C65 120.0 . . ?
C65 C64 H64 120.0 . . ?
C60 C65 H65 120.0 . . ?
C64 C65 C60 120.0 . . ?
C64 C65 H65 120.0 . . ?
P6 C66 H66A 109.3 3_566 . ?
P6 C66 H66B 109.3 3_566 . ?
N2 C66 P6 112(2) . 3_566 ?
N2 C66 H66A 109.4 . . ?
N2 C66 H66B 109.3 . . ?
H66A C66 H66B 107.9 . . ?
C68 C67 P6 113.6(18) . . ?
C68 C67 C72 120.0 . . ?
C72 C67 P6 124.9(18) . . ?
C67 C68 H68 120.0 . . ?
C69 C68 C67 120.0 . . ?
C69 C68 H68 120.0 . . ?
C68 C69 H69 120.0 . . ?
C68 C69 C70 120.0 . . ?
C70 C69 H69 120.0 . . ?
C69 C70 H70 120.0 . . ?
C71 C70 C69 120.0 . . ?
C71 C70 H70 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 C70 120.0 . . ?
C72 C71 H71 120.0 . . ?
C67 C72 H72 120.0 . . ?
C71 C72 C67 120.0 . . ?
C71 C72 H72 120.0 . . ?
C74 C73 P6 109.4(15) . . ?
C74 C73 C78 120.0 . . ?
C78 C73 P6 128.8(14) . . ?
C73 C74 H74 120.0 . . ?
C75 C74 C73 120.0 . . ?
C75 C74 H74 120.0 . . ?
C74 C75 H75 120.0 . . ?
C74 C75 C76 120.0 . . ?
C76 C75 H75 120.0 . . ?
C75 C76 H76 120.0 . . ?
C77 C76 C75 120.0 . . ?
C77 C76 H76 120.0 . . ?
C76 C77 H77 120.0 . . ?
C76 C77 C78 120.0 . . ?
C78 C77 H77 120.0 . . ?
C73 C78 H78 120.0 . . ?
C77 C78 C73 120.0 . . ?
C77 C78 H78 120.0 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
