# Electronic Supplementary Material (ESI) for Polymer Chemistry.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AT667
_database_code_depnum_ccdc_archive 'CCDC 1561720'

_audit_update_record             
;
2017-07-12 deposited with the CCDC.
2017-11-20 downloaded from the CCDC.
;
_publcif_datablock.id            {85c898e5-ee29-4528-b679-46ea93ebb3f7}
# publcif _publ_body_element loop end

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H38 Ge O3'
_chemical_formula_sum            'C32 H38 Ge O3'
_chemical_formula_weight         543.21

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   14.4530(6)
_cell_length_b                   24.1484(10)
_cell_length_c                   24.5040(10)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     8552.3(6)
_cell_formula_units_Z            12
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9135
_cell_measurement_theta_min      2.20
_cell_measurement_theta_max      30.02
_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.266
_exptl_crystal_F_000             3432
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.090
_exptl_absorpt_coefficient_mu    1.104
_shelx_estimated_absorpt_T_min   0.852
_shelx_estimated_absorpt_T_max   0.907
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.652
_exptl_absorpt_correction_T_max  0.741
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Incoatec microfocus sealed tube'
_diffrn_radiation_monochromator  'multilayer monochromator'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            424078
_diffrn_reflns_av_unetI/netI     0.0459
_diffrn_reflns_av_R_equivalents  0.0883
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -37
_diffrn_reflns_limit_k_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_theta_min         1.636
_diffrn_reflns_theta_max         33.184
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             32647
_reflns_number_gt                27060
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.866
_reflns_Friedel_fraction_max     0.999
_reflns_Friedel_fraction_full    1.000

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT v8.37A (Bruker, 2015)'
_computing_data_reduction        'Bruker SAINT v8.37A (Bruker, 2015)'
_computing_structure_solution    SHELXT-2014/5
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0404P)²+6.1022P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.068(6)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         32647
_refine_ls_number_parameters     1003
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0629
_refine_ls_R_factor_gt           0.0443
_refine_ls_wR_factor_ref         0.1051
_refine_ls_wR_factor_gt          0.0962
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_restrained_S_all      1.025
_refine_ls_shift/su_max          0.026
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.53566(2) 0.60418(2) 0.94209(2) 0.01915(6) Uani 1 1 d . . . . .
C1 C 0.4234(2) 0.65186(13) 0.92517(11) 0.0196(5) Uani 1 1 d . . . . .
O1 O 0.35596(17) 0.62562(10) 0.91065(11) 0.0324(5) Uani 1 1 d . . . . .
Ge2 Ge 0.49366(2) 0.60730(2) 0.61926(2) 0.02196(7) Uani 1 1 d . . . . .
C2 C 0.5330(2) 0.57754(13) 1.02066(14) 0.0260(6) Uani 1 1 d . . . . .
O2 O 0.5508(2) 0.61058(11) 1.05641(11) 0.0438(7) Uani 1 1 d . . . . .
Ge3 Ge 0.47844(2) 0.60728(2) 0.28395(2) 0.01625(6) Uani 1 1 d . . . . .
C3 C 0.66293(19) 0.63913(12) 0.93508(11) 0.0176(5) Uani 1 1 d . . . . .
O3 O 0.72825(14) 0.60860(10) 0.94315(9) 0.0280(4) Uani 1 1 d . . . . .
O4 O 0.67372(17) 0.63710(11) 0.59266(12) 0.0353(6) Uani 1 1 d . . . . .
C4 C 0.42101(18) 0.71368(12) 0.92798(11) 0.0179(5) Uani 1 1 d . . . . .
O5 O 0.3083(2) 0.59349(15) 0.59999(18) 0.0738(13) Uani 1 1 d . . . . .
C5 C 0.43848(19) 0.74454(12) 0.88072(12) 0.0192(5) Uani 1 1 d . . . . .
O6 O 0.5022(2) 0.62539(11) 0.73543(11) 0.0461(8) Uani 1 1 d . . . . .
C6 C 0.4338(2) 0.80238(13) 0.88396(13) 0.0237(6) Uani 1 1 d . . . . .
H6 H 0.4460 0.8237 0.8522 0.028 Uiso 1 1 calc R U . . .
O7 O 0.30012(15) 0.64721(10) 0.27190(11) 0.0281(5) Uani 1 1 d . . . . .
C7 C 0.4117(2) 0.82942(13) 0.93221(14) 0.0265(6) Uani 1 1 d . . . . .
O8 O 0.46489(19) 0.62370(9) 0.39933(9) 0.0285(5) Uani 1 1 d . . . . .
C8 C 0.3933(2) 0.79740(14) 0.97851(13) 0.0260(6) Uani 1 1 d . . . . .
H8 H 0.3771 0.8154 1.0116 0.031 Uiso 1 1 calc R U . . .
O9 O 0.65614(18) 0.58250(11) 0.25269(12) 0.0378(6) Uani 1 1 d . . . . .
C9 C 0.3980(2) 0.73996(14) 0.97725(12) 0.0214(6) Uani 1 1 d . . . . .
C10 C 0.4604(2) 0.71672(14) 0.82731(12) 0.0249(6) Uani 1 1 d . . . . .
H10A H 0.4978 0.7416 0.8047 0.037 Uiso 1 1 calc R U . . .
H10B H 0.4027 0.7079 0.8082 0.037 Uiso 1 1 calc R U . . .
H10C H 0.4950 0.6825 0.8342 0.037 Uiso 1 1 calc R U . . .
C12 C 0.3789(2) 0.70639(16) 1.02768(13) 0.0295(7) Uani 1 1 d . . . . .
H12A H 0.3587 0.7310 1.0571 0.044 Uiso 1 1 calc R U . . .
H12B H 0.4355 0.6870 1.0388 0.044 Uiso 1 1 calc R U . . .
H12C H 0.3302 0.6793 1.0200 0.044 Uiso 1 1 calc R U . . .
C11 C 0.4078(3) 0.89197(15) 0.93488(17) 0.0410(8) Uani 1 1 d . . . . .
H11A H 0.3545 0.9034 0.9569 0.062 Uiso 1 1 calc R U . . .
H11B H 0.4017 0.9070 0.8979 0.062 Uiso 1 1 calc R U . . .
H11C H 0.4648 0.9060 0.9516 0.062 Uiso 1 1 calc R U . . .
C13 C 0.5112(2) 0.51841(13) 1.03484(13) 0.0239(6) Uani 1 1 d . . . . .
C14 C 0.5839(2) 0.48293(13) 1.05015(13) 0.0245(6) Uani 1 1 d . . . . .
C15 C 0.5614(2) 0.42943(14) 1.06769(13) 0.0263(6) Uani 1 1 d . . . . .
H15 H 0.6098 0.4045 1.0767 0.032 Uiso 1 1 calc R U . . .
C16 C 0.4704(2) 0.41181(13) 1.07223(12) 0.0246(6) Uani 1 1 d . . . . .
C17 C 0.4000(2) 0.44826(13) 1.05705(13) 0.0245(6) Uani 1 1 d . . . . .
H17 H 0.3374 0.4366 1.0601 0.029 Uiso 1 1 calc R U . . .
C18 C 0.4191(2) 0.50129(13) 1.03759(13) 0.0247(6) Uani 1 1 d . . . . .
C19 C 0.6837(2) 0.50153(16) 1.04852(18) 0.0357(8) Uani 1 1 d . . . . .
H19A H 0.7244 0.4692 1.0519 0.054 Uiso 1 1 calc R U . . .
H19B H 0.6956 0.5271 1.0788 0.054 Uiso 1 1 calc R U . . .
H19C H 0.6960 0.5204 1.0138 0.054 Uiso 1 1 calc R U . . .
C20 C 0.4463(3) 0.35559(14) 1.09464(14) 0.0320(7) Uani 1 1 d . . . . .
H20A H 0.3919 0.3411 1.0755 0.048 Uiso 1 1 calc R U . . .
H20B H 0.4327 0.3587 1.1337 0.048 Uiso 1 1 calc R U . . .
H20C H 0.4987 0.3304 1.0893 0.048 Uiso 1 1 calc R U . . .
C22 C 0.67258(18) 0.69777(12) 0.91629(11) 0.0166(5) Uani 1 1 d . . . . .
C21 C 0.3411(2) 0.53982(16) 1.0226(2) 0.0407(9) Uani 1 1 d . . . . .
H21A H 0.2820 0.5201 1.0256 0.061 Uiso 1 1 calc R U . . .
H21B H 0.3494 0.5527 0.9850 0.061 Uiso 1 1 calc R U . . .
H21C H 0.3410 0.5717 1.0474 0.061 Uiso 1 1 calc R U . . .
C23 C 0.65257(18) 0.74101(12) 0.95263(12) 0.0186(5) Uani 1 1 d . . . . .
C24 C 0.6554(2) 0.79535(12) 0.93333(12) 0.0214(5) Uani 1 1 d . . . . .
H24 H 0.6409 0.8249 0.9574 0.026 Uiso 1 1 calc R U . . .
C25 C 0.6791(2) 0.80722(13) 0.87960(13) 0.0235(6) Uani 1 1 d . . . . .
C26 C 0.7009(2) 0.76373(13) 0.84492(12) 0.0227(6) Uani 1 1 d . . . . .
H26 H 0.7187 0.7717 0.8084 0.027 Uiso 1 1 calc R U . . .
C27 C 0.69753(19) 0.70862(13) 0.86205(11) 0.0196(5) Uani 1 1 d . . . . .
C28 C 0.6348(2) 0.72997(13) 1.01210(12) 0.0228(6) Uani 1 1 d . . . . .
H28A H 0.5865 0.7550 1.0254 0.034 Uiso 1 1 calc R U . . .
H28B H 0.6918 0.7362 1.0329 0.034 Uiso 1 1 calc R U . . .
H28C H 0.6147 0.6915 1.0168 0.034 Uiso 1 1 calc R U . . .
C29 C 0.6807(3) 0.86684(15) 0.85987(16) 0.0359(8) Uani 1 1 d . . . . .
H29A H 0.7121 0.8688 0.8245 0.054 Uiso 1 1 calc R U . . .
H29B H 0.7138 0.8898 0.8864 0.054 Uiso 1 1 calc R U . . .
H29C H 0.6171 0.8804 0.8560 0.054 Uiso 1 1 calc R U . . .
C31 C 0.5257(3) 0.54374(16) 0.88825(19) 0.0415(9) Uani 1 1 d . . . . .
H31A H 0.4756 0.5185 0.9001 0.050 Uiso 1 1 calc R U . . .
H31B H 0.5067 0.5600 0.8529 0.050 Uiso 1 1 calc R U . . .
C30 C 0.7174(2) 0.66226(15) 0.82239(13) 0.0279(7) Uani 1 1 d . . . . .
H30A H 0.7396 0.6778 0.7879 0.042 Uiso 1 1 calc R U . . .
H30B H 0.6606 0.6411 0.8158 0.042 Uiso 1 1 calc R U . . .
H30C H 0.7648 0.6378 0.8377 0.042 Uiso 1 1 calc R U . . .
C32 C 0.6118(3) 0.50980(19) 0.8790(2) 0.0492(11) Uani 1 1 d . . . . .
H32A H 0.6000 0.4822 0.8505 0.074 Uiso 1 1 calc R U . . .
H32B H 0.6289 0.4910 0.9130 0.074 Uiso 1 1 calc R U . . .
H32C H 0.6624 0.5341 0.8675 0.074 Uiso 1 1 calc R U . . .
C33 C 0.5991(2) 0.65913(13) 0.59971(12) 0.0209(5) Uani 1 1 d . . . . .
C34 C 0.3626(2) 0.63177(15) 0.60120(14) 0.0288(7) Uani 1 1 d . . . . .
C35 C 0.5048(2) 0.58958(13) 0.70056(14) 0.0283(7) Uani 1 1 d . . . . .
C36 C 0.58661(18) 0.72065(11) 0.59590(11) 0.0161(5) Uani 1 1 d . . . . .
C37 C 0.55190(18) 0.74380(12) 0.54740(11) 0.0174(5) Uani 1 1 d . . . . .
C38 C 0.53900(19) 0.80097(12) 0.54543(12) 0.0201(5) Uani 1 1 d . . . . .
H38 H 0.5145 0.8171 0.5132 0.024 Uiso 1 1 calc R U . . .
C39 C 0.5609(2) 0.83516(12) 0.58938(12) 0.0207(5) Uani 1 1 d . . . . .
C40 C 0.5968(2) 0.81102(13) 0.63621(12) 0.0209(5) Uani 1 1 d . . . . .
H40 H 0.6134 0.8340 0.6661 0.025 Uiso 1 1 calc R U . . .
C41 C 0.60895(19) 0.75406(13) 0.64058(11) 0.0181(5) Uani 1 1 d . . . . .
C42 C 0.5316(2) 0.70861(13) 0.49798(11) 0.0231(6) Uani 1 1 d . . . . .
H42A H 0.4860 0.7274 0.4749 0.035 Uiso 1 1 calc R U . . .
H42B H 0.5070 0.6727 0.5097 0.035 Uiso 1 1 calc R U . . .
H42C H 0.5888 0.7029 0.4772 0.035 Uiso 1 1 calc R U . . .
C44 C 0.6438(2) 0.72941(15) 0.69366(12) 0.0260(6) Uani 1 1 d . . . . .
H44A H 0.6768 0.7579 0.7145 0.039 Uiso 1 1 calc R U . . .
H44B H 0.6859 0.6986 0.6857 0.039 Uiso 1 1 calc R U . . .
H44C H 0.5913 0.7158 0.7151 0.039 Uiso 1 1 calc R U . . .
C43 C 0.5452(2) 0.89687(14) 0.58604(14) 0.0323(7) Uani 1 1 d . . . . .
H43A H 0.5475 0.9128 0.6228 0.048 Uiso 1 1 calc R U . . .
H43B H 0.4844 0.9041 0.5698 0.048 Uiso 1 1 calc R U . . .
H43C H 0.5934 0.9137 0.5633 0.048 Uiso 1 1 calc R U . . .
C45 C 0.3367(2) 0.68985(14) 0.58614(12) 0.0233(6) Uani 1 1 d . . . . .
C46 C 0.3008(2) 0.70084(14) 0.53343(12) 0.0227(6) Uani 1 1 d . . . . .
C47 C 0.2821(2) 0.75580(14) 0.51950(12) 0.0237(6) Uani 1 1 d . . . . .
H47 H 0.2595 0.7638 0.4840 0.028 Uiso 1 1 calc R U . . .
C48 C 0.2954(2) 0.79908(14) 0.55610(13) 0.0256(6) Uani 1 1 d . . . . .
C49 C 0.3272(2) 0.78636(15) 0.60820(13) 0.0259(6) Uani 1 1 d . . . . .
H49 H 0.3345 0.8154 0.6340 0.031 Uiso 1 1 calc R U . . .
C50 C 0.34857(19) 0.73288(15) 0.62375(12) 0.0239(6) Uani 1 1 d . . . . .
C51 C 0.2852(2) 0.65587(15) 0.49186(13) 0.0269(6) Uani 1 1 d . . . . .
H51A H 0.2641 0.6724 0.4575 0.040 Uiso 1 1 calc R U . . .
H51B H 0.2381 0.6301 0.5054 0.040 Uiso 1 1 calc R U . . .
H51C H 0.3432 0.6358 0.4856 0.040 Uiso 1 1 calc R U . . .
C54 C 0.5198(2) 0.52972(13) 0.71542(13) 0.0235(6) Uani 1 1 d . . . . .
C53 C 0.3825(2) 0.72118(17) 0.68099(12) 0.0302(7) Uani 1 1 d . . . . .
H53A H 0.3683 0.7528 0.7046 0.045 Uiso 1 1 calc R U . . .
H53B H 0.4495 0.7151 0.6803 0.045 Uiso 1 1 calc R U . . .
H53C H 0.3517 0.6880 0.6951 0.045 Uiso 1 1 calc R U . . .
C52 C 0.2761(3) 0.85811(16) 0.53971(17) 0.0370(8) Uani 1 1 d . . . . .
H52A H 0.2467 0.8777 0.5702 0.056 Uiso 1 1 calc R U . . .
H52B H 0.2347 0.8585 0.5080 0.056 Uiso 1 1 calc R U . . .
H52C H 0.3344 0.8765 0.5303 0.056 Uiso 1 1 calc R U . . .
C55 C 0.4431(2) 0.49609(14) 0.72816(15) 0.0281(7) Uani 1 1 d . . . . .
C56 C 0.4593(2) 0.44121(13) 0.74244(13) 0.0270(6) Uani 1 1 d . . . . .
H56 H 0.4084 0.4180 0.7512 0.032 Uiso 1 1 calc R U . . .
C57 C 0.5485(2) 0.41943(13) 0.74422(12) 0.0250(6) Uani 1 1 d . . . . .
C58 C 0.6226(2) 0.45335(14) 0.73090(13) 0.0261(6) Uani 1 1 d . . . . .
H58 H 0.6834 0.4385 0.7316 0.031 Uiso 1 1 calc R U . . .
C59 C 0.6099(2) 0.50868(14) 0.71650(14) 0.0259(6) Uani 1 1 d . . . . .
C60 C 0.3460(3) 0.51825(19) 0.7270(2) 0.0467(11) Uani 1 1 d . . . . .
H60A H 0.3021 0.4876 0.7310 0.070 Uiso 1 1 calc R U . . .
H60B H 0.3350 0.5371 0.6922 0.070 Uiso 1 1 calc R U . . .
H60C H 0.3375 0.5445 0.7570 0.070 Uiso 1 1 calc R U . . .
C61 C 0.5648(3) 0.36020(15) 0.76202(15) 0.0374(9) Uani 1 1 d . . . . .
H61A H 0.6251 0.3477 0.7485 0.056 Uiso 1 1 calc R U . . .
H61B H 0.5160 0.3364 0.7471 0.056 Uiso 1 1 calc R U . . .
H61C H 0.5639 0.3581 0.8020 0.056 Uiso 1 1 calc R U . . .
C63 C 0.5159(3) 0.53716(15) 0.58141(16) 0.0416(9) Uani 1 1 d . . . . .
H63A H 0.5768 0.5225 0.5928 0.050 Uiso 1 1 calc R U . . .
H63B H 0.4682 0.5101 0.5929 0.050 Uiso 1 1 calc R U . . .
C62 C 0.6924(3) 0.54499(18) 0.7035(2) 0.0426(10) Uani 1 1 d . . . . .
H62A H 0.7493 0.5231 0.7064 0.064 Uiso 1 1 calc R U . . .
H62B H 0.6949 0.5759 0.7295 0.064 Uiso 1 1 calc R U . . .
H62C H 0.6865 0.5595 0.6664 0.064 Uiso 1 1 calc R U . . .
C64 C 0.5144(7) 0.5417(2) 0.52149(19) 0.093(3) Uani 1 1 d . . . . .
H64A H 0.5234 0.5050 0.5053 0.139 Uiso 1 1 calc R U . . .
H64B H 0.5641 0.5665 0.5095 0.139 Uiso 1 1 calc R U . . .
H64C H 0.4546 0.5567 0.5097 0.139 Uiso 1 1 calc R U . . .
C65 C 0.37882(19) 0.66523(12) 0.27235(11) 0.0174(5) Uani 1 1 d . . . . .
C66 C 0.4670(2) 0.58816(11) 0.36453(12) 0.0190(5) Uani 1 1 d . . . . .
C67 C 0.6105(2) 0.62405(13) 0.26157(13) 0.0229(6) Uani 1 1 d . . . . .
C68 C 0.39847(18) 0.72594(11) 0.26603(11) 0.0155(5) Uani 1 1 d . . . . .
C69 C 0.38059(19) 0.76204(12) 0.30966(11) 0.0171(5) Uani 1 1 d . . . . .
C70 C 0.3976(2) 0.81843(12) 0.30187(12) 0.0197(5) Uani 1 1 d . . . . .
H70 H 0.3847 0.8435 0.3308 0.024 Uiso 1 1 calc R U . . .
C71 C 0.4329(2) 0.83898(12) 0.25301(13) 0.0226(6) Uani 1 1 d . . . . .
C72 C 0.4505(2) 0.80216(13) 0.21081(12) 0.0225(6) Uani 1 1 d . . . . .
H72 H 0.4744 0.8159 0.1773 0.027 Uiso 1 1 calc R U . . .
C73 C 0.43393(19) 0.74567(12) 0.21619(11) 0.0178(5) Uani 1 1 d . . . . .
C74 C 0.3466(2) 0.74182(13) 0.36422(11) 0.0213(6) Uani 1 1 d . . . . .
H74A H 0.3224 0.7731 0.3853 0.032 Uiso 1 1 calc R U . . .
H74B H 0.3978 0.7246 0.3842 0.032 Uiso 1 1 calc R U . . .
H74C H 0.2973 0.7145 0.3587 0.032 Uiso 1 1 calc R U . . .
C76 C 0.4490(2) 0.70704(13) 0.16876(12) 0.0230(6) Uani 1 1 d . . . . .
H76A H 0.4852 0.7259 0.1405 0.035 Uiso 1 1 calc R U . . .
H76B H 0.3890 0.6959 0.1537 0.035 Uiso 1 1 calc R U . . .
H76C H 0.4825 0.6741 0.1812 0.035 Uiso 1 1 calc R U . . .
C75 C 0.4513(3) 0.90024(14) 0.24664(16) 0.0357(8) Uani 1 1 d . . . . .
H75A H 0.4957 0.9061 0.2170 0.054 Uiso 1 1 calc R U . . .
H75B H 0.4768 0.9150 0.2807 0.054 Uiso 1 1 calc R U . . .
H75C H 0.3933 0.9194 0.2381 0.054 Uiso 1 1 calc R U . . .
C77 C 0.4542(2) 0.52794(12) 0.37882(12) 0.0196(5) Uani 1 1 d . . . . .
C78 C 0.3639(2) 0.50726(13) 0.38389(12) 0.0209(5) Uani 1 1 d . . . . .
C79 C 0.3525(2) 0.45180(13) 0.39844(13) 0.0258(6) Uani 1 1 d . . . . .
H79 H 0.2917 0.4372 0.4021 0.031 Uiso 1 1 calc R U . . .
C82 C 0.5315(2) 0.49398(13) 0.38673(13) 0.0251(6) Uani 1 1 d . . . . .
C81 C 0.5165(3) 0.43872(13) 0.40178(14) 0.0282(6) Uani 1 1 d . . . . .
H81 H 0.5681 0.4152 0.4081 0.034 Uiso 1 1 calc R U . . .
C80 C 0.4275(3) 0.41762(13) 0.40767(13) 0.0272(7) Uani 1 1 d . . . . .
C83 C 0.2805(2) 0.54381(14) 0.37488(16) 0.0303(7) Uani 1 1 d . . . . .
H83A H 0.2246 0.5209 0.3733 0.045 Uiso 1 1 calc R U . . .
H83B H 0.2875 0.5640 0.3405 0.045 Uiso 1 1 calc R U . . .
H83C H 0.2751 0.5702 0.4051 0.045 Uiso 1 1 calc R U . . .
C86 C 0.64513(19) 0.68129(13) 0.25003(12) 0.0200(5) Uani 1 1 d . . . . .
C85 C 0.6286(2) 0.51634(16) 0.3805(2) 0.0395(9) Uani 1 1 d . . . . .
H85A H 0.6731 0.4885 0.3932 0.059 Uiso 1 1 calc R U . . .
H85B H 0.6352 0.5501 0.4024 0.059 Uiso 1 1 calc R U . . .
H85C H 0.6404 0.5249 0.3421 0.059 Uiso 1 1 calc R U . . .
C84 C 0.4123(3) 0.35790(14) 0.42400(16) 0.0366(9) Uani 1 1 d . . . . .
H84A H 0.4598 0.3468 0.4503 0.055 Uiso 1 1 calc R U . . .
H84B H 0.4161 0.3342 0.3916 0.055 Uiso 1 1 calc R U . . .
H84C H 0.3510 0.3540 0.4407 0.055 Uiso 1 1 calc R U . . .
C87 C 0.6825(2) 0.69340(14) 0.19790(12) 0.0231(6) Uani 1 1 d . . . . .
C88 C 0.7051(2) 0.74834(14) 0.18644(13) 0.0252(6) Uani 1 1 d . . . . .
H88 H 0.7284 0.7573 0.1513 0.030 Uiso 1 1 calc R U . . .
C89 C 0.6946(2) 0.79033(14) 0.22457(13) 0.0250(6) Uani 1 1 d . . . . .
C90 C 0.6619(2) 0.77689(13) 0.27621(13) 0.0229(6) Uani 1 1 d . . . . .
H90 H 0.6569 0.8051 0.3031 0.027 Uiso 1 1 calc R U . . .
C91 C 0.63624(19) 0.72273(13) 0.28942(12) 0.0197(5) Uani 1 1 d . . . . .
C92 C 0.6959(2) 0.64974(16) 0.15427(14) 0.0301(7) Uani 1 1 d . . . . .
H92A H 0.7069 0.6678 0.1190 0.045 Uiso 1 1 calc R U . . .
H92B H 0.6404 0.6266 0.1519 0.045 Uiso 1 1 calc R U . . .
H92C H 0.7493 0.6266 0.1636 0.045 Uiso 1 1 calc R U . . .
C93 C 0.7180(3) 0.84971(15) 0.21080(16) 0.0350(8) Uani 1 1 d . . . . .
H93A H 0.7545 0.8659 0.2405 0.053 Uiso 1 1 calc R U . . .
H93B H 0.6608 0.8709 0.2061 0.053 Uiso 1 1 calc R U . . .
H93C H 0.7539 0.8508 0.1769 0.053 Uiso 1 1 calc R U . . .
C94 C 0.6034(2) 0.70999(13) 0.34640(12) 0.0221(6) Uani 1 1 d . . . . .
H94A H 0.6161 0.7417 0.3702 0.033 Uiso 1 1 calc R U . . .
H94B H 0.6360 0.6773 0.3602 0.033 Uiso 1 1 calc R U . . .
H94C H 0.5367 0.7027 0.3458 0.033 Uiso 1 1 calc R U . . .
C95 C 0.4434(3) 0.54063(14) 0.24359(14) 0.0301(7) Uani 1 1 d . . . . .
H95A H 0.4867 0.5105 0.2537 0.036 Uiso 1 1 calc R U . . .
H95B H 0.3808 0.5293 0.2556 0.036 Uiso 1 1 calc R U . . .
C96 C 0.4429(4) 0.54590(18) 0.18164(16) 0.0502(12) Uani 1 1 d . . . . .
H96A H 0.4290 0.5098 0.1653 0.075 Uiso 1 1 calc R U . . .
H96B H 0.5038 0.5585 0.1691 0.075 Uiso 1 1 calc R U . . .
H96C H 0.3957 0.5728 0.1706 0.075 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C31 1.973(4) . ?
Ge1 C2 2.030(3) . ?
Ge1 C3 2.031(3) . ?
Ge1 C1 2.032(3) . ?
C1 O1 1.216(4) . ?
C1 C4 1.495(4) . ?
Ge2 C63 1.958(3) . ?
Ge2 C33 2.030(3) . ?
Ge2 C34 2.033(4) . ?
Ge2 C35 2.044(3) . ?
C2 O2 1.213(4) . ?
C2 C13 1.503(4) . ?
Ge3 C95 1.956(3) . ?
Ge3 C67 2.027(3) . ?
Ge3 C65 2.028(3) . ?
Ge3 C66 2.035(3) . ?
C3 O3 1.214(4) . ?
C3 C22 1.496(4) . ?
O4 C33 1.214(4) . ?
C4 C5 1.400(4) . ?
C4 C9 1.404(4) . ?
O5 C34 1.213(4) . ?
C5 C6 1.401(4) . ?
C5 C10 1.505(4) . ?
O6 C35 1.217(4) . ?
C6 C7 1.388(5) . ?
C6 H6 0.9500 . ?
O7 C65 1.218(4) . ?
C7 C8 1.398(5) . ?
C7 C11 1.513(5) . ?
O8 C66 1.210(3) . ?
C8 C9 1.389(5) . ?
C8 H8 0.9500 . ?
O9 C67 1.220(4) . ?
C9 C12 1.504(4) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C13 C18 1.395(4) . ?
C13 C14 1.406(4) . ?
C14 C15 1.400(4) . ?
C14 C19 1.513(4) . ?
C15 C16 1.386(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.396(5) . ?
C16 C20 1.505(4) . ?
C17 C18 1.394(4) . ?
C17 H17 0.9500 . ?
C18 C21 1.508(5) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C22 C27 1.402(4) . ?
C22 C23 1.403(4) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C23 C24 1.395(4) . ?
C23 C28 1.503(4) . ?
C24 C25 1.390(4) . ?
C24 H24 0.9500 . ?
C25 C26 1.387(5) . ?
C25 C29 1.519(4) . ?
C26 C27 1.396(4) . ?
C26 H26 0.9500 . ?
C27 C30 1.510(4) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C31 C32 1.507(6) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C36 1.500(4) . ?
C34 C45 1.498(5) . ?
C35 C54 1.506(4) . ?
C36 C41 1.398(4) . ?
C36 C37 1.406(4) . ?
C37 C38 1.394(4) . ?
C37 C42 1.508(4) . ?
C38 C39 1.394(4) . ?
C38 H38 0.9500 . ?
C39 C40 1.387(4) . ?
C39 C43 1.510(5) . ?
C40 C41 1.391(4) . ?
C40 H40 0.9500 . ?
C41 C44 1.516(4) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C45 C50 1.400(5) . ?
C45 C46 1.417(4) . ?
C46 C47 1.397(5) . ?
C46 C51 1.506(4) . ?
C47 C48 1.391(5) . ?
C47 H47 0.9500 . ?
C48 C49 1.391(4) . ?
C48 C52 1.507(5) . ?
C49 C50 1.381(5) . ?
C49 H49 0.9500 . ?
C50 C53 1.512(4) . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C54 C59 1.399(4) . ?
C54 C55 1.408(5) . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C55 C56 1.391(5) . ?
C55 C60 1.503(5) . ?
C56 C57 1.392(5) . ?
C56 H56 0.9500 . ?
C57 C58 1.387(5) . ?
C57 C61 1.514(4) . ?
C58 C59 1.394(5) . ?
C58 H58 0.9500 . ?
C59 C62 1.514(5) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C63 C64 1.473(6) . ?
C63 H63A 0.9900 . ?
C63 H63B 0.9900 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C65 C68 1.501(4) . ?
C66 C77 1.507(4) . ?
C67 C86 1.497(4) . ?
C68 C69 1.403(4) . ?
C68 C73 1.408(4) . ?
C69 C70 1.397(4) . ?
C69 C74 1.506(4) . ?
C70 C71 1.393(4) . ?
C70 H70 0.9500 . ?
C71 C72 1.387(4) . ?
C71 C75 1.511(4) . ?
C72 C73 1.391(4) . ?
C72 H72 0.9500 . ?
C73 C76 1.506(4) . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C75 H75A 0.9800 . ?
C75 H75B 0.9800 . ?
C75 H75C 0.9800 . ?
C77 C82 1.400(4) . ?
C77 C78 1.402(4) . ?
C78 C79 1.396(4) . ?
C78 C83 1.511(5) . ?
C79 C80 1.382(5) . ?
C79 H79 0.9500 . ?
C82 C81 1.401(4) . ?
C82 C85 1.512(5) . ?
C81 C80 1.390(5) . ?
C81 H81 0.9500 . ?
C80 C84 1.513(4) . ?
C83 H83A 0.9800 . ?
C83 H83B 0.9800 . ?
C83 H83C 0.9800 . ?
C86 C91 1.396(4) . ?
C86 C87 1.417(4) . ?
C85 H85A 0.9800 . ?
C85 H85B 0.9800 . ?
C85 H85C 0.9800 . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C87 C88 1.395(5) . ?
C87 C92 1.514(5) . ?
C88 C89 1.387(5) . ?
C88 H88 0.9500 . ?
C89 C90 1.389(4) . ?
C89 C93 1.512(5) . ?
C90 C91 1.397(4) . ?
C90 H90 0.9500 . ?
C91 C94 1.506(4) . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C93 H93A 0.9800 . ?
C93 H93B 0.9800 . ?
C93 H93C 0.9800 . ?
C94 H94A 0.9800 . ?
C94 H94B 0.9800 . ?
C94 H94C 0.9800 . ?
C95 C96 1.523(5) . ?
C95 H95A 0.9900 . ?
C95 H95B 0.9900 . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C31 Ge1 C2 113.48(17) . . ?
C31 Ge1 C3 108.48(14) . . ?
C2 Ge1 C3 103.25(12) . . ?
C31 Ge1 C1 102.98(15) . . ?
C2 Ge1 C1 110.96(12) . . ?
C3 Ge1 C1 118.05(12) . . ?
O1 C1 C4 121.0(3) . . ?
O1 C1 Ge1 113.9(2) . . ?
C4 C1 Ge1 125.1(2) . . ?
C63 Ge2 C33 107.37(16) . . ?
C63 Ge2 C34 107.52(18) . . ?
C33 Ge2 C34 117.98(13) . . ?
C63 Ge2 C35 105.52(15) . . ?
C33 Ge2 C35 107.45(13) . . ?
C34 Ge2 C35 110.28(14) . . ?
O2 C2 C13 120.2(3) . . ?
O2 C2 Ge1 118.2(2) . . ?
C13 C2 Ge1 121.6(2) . . ?
C95 Ge3 C67 105.74(15) . . ?
C95 Ge3 C65 108.26(14) . . ?
C67 Ge3 C65 119.53(12) . . ?
C95 Ge3 C66 106.44(13) . . ?
C67 Ge3 C66 112.62(12) . . ?
C65 Ge3 C66 103.58(11) . . ?
O3 C3 C22 123.5(3) . . ?
O3 C3 Ge1 116.0(2) . . ?
C22 C3 Ge1 120.3(2) . . ?
C5 C4 C9 120.9(3) . . ?
C5 C4 C1 119.3(2) . . ?
C9 C4 C1 119.8(3) . . ?
C4 C5 C6 118.4(3) . . ?
C4 C5 C10 121.3(3) . . ?
C6 C5 C10 120.3(3) . . ?
C7 C6 C5 121.9(3) . . ?
C7 C6 H6 119.0 . . ?
C5 C6 H6 119.0 . . ?
C6 C7 C8 118.3(3) . . ?
C6 C7 C11 121.0(3) . . ?
C8 C7 C11 120.7(3) . . ?
C9 C8 C7 121.6(3) . . ?
C9 C8 H8 119.2 . . ?
C7 C8 H8 119.2 . . ?
C8 C9 C4 118.8(3) . . ?
C8 C9 C12 120.7(3) . . ?
C4 C9 C12 120.4(3) . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C7 C11 H11A 109.5 . . ?
C7 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C7 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C18 C13 C14 121.2(3) . . ?
C18 C13 C2 119.5(3) . . ?
C14 C13 C2 119.0(3) . . ?
C15 C14 C13 118.1(3) . . ?
C15 C14 C19 120.3(3) . . ?
C13 C14 C19 121.6(3) . . ?
C16 C15 C14 121.9(3) . . ?
C16 C15 H15 119.1 . . ?
C14 C15 H15 119.1 . . ?
C15 C16 C17 118.5(3) . . ?
C15 C16 C20 121.7(3) . . ?
C17 C16 C20 119.8(3) . . ?
C18 C17 C16 121.7(3) . . ?
C18 C17 H17 119.2 . . ?
C16 C17 H17 119.2 . . ?
C17 C18 C13 118.6(3) . . ?
C17 C18 C21 120.1(3) . . ?
C13 C18 C21 121.3(3) . . ?
C14 C19 H19A 109.5 . . ?
C14 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C14 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C16 C20 H20A 109.5 . . ?
C16 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C16 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C27 C22 C23 121.0(3) . . ?
C27 C22 C3 119.5(3) . . ?
C23 C22 C3 119.4(2) . . ?
C18 C21 H21A 109.5 . . ?
C18 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C18 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C24 C23 C22 118.6(3) . . ?
C24 C23 C28 120.0(3) . . ?
C22 C23 C28 121.2(3) . . ?
C25 C24 C23 121.5(3) . . ?
C25 C24 H24 119.3 . . ?
C23 C24 H24 119.3 . . ?
C26 C25 C24 118.7(3) . . ?
C26 C25 C29 121.3(3) . . ?
C24 C25 C29 120.0(3) . . ?
C25 C26 C27 122.0(3) . . ?
C25 C26 H26 119.0 . . ?
C27 C26 H26 119.0 . . ?
C26 C27 C22 118.2(3) . . ?
C26 C27 C30 120.4(3) . . ?
C22 C27 C30 121.4(3) . . ?
C23 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C23 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C25 C29 H29A 109.5 . . ?
C25 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C25 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C32 C31 Ge1 116.3(3) . . ?
C32 C31 H31A 108.2 . . ?
Ge1 C31 H31A 108.2 . . ?
C32 C31 H31B 108.2 . . ?
Ge1 C31 H31B 108.2 . . ?
H31A C31 H31B 107.4 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
O4 C33 C36 122.2(3) . . ?
O4 C33 Ge2 115.5(2) . . ?
C36 C33 Ge2 122.3(2) . . ?
O5 C34 C45 123.1(3) . . ?
O5 C34 Ge2 112.7(3) . . ?
C45 C34 Ge2 124.0(2) . . ?
O6 C35 C54 121.1(3) . . ?
O6 C35 Ge2 122.2(2) . . ?
C54 C35 Ge2 116.6(2) . . ?
C41 C36 C37 121.0(3) . . ?
C41 C36 C33 119.7(3) . . ?
C37 C36 C33 119.3(3) . . ?
C38 C37 C36 118.1(3) . . ?
C38 C37 C42 120.3(3) . . ?
C36 C37 C42 121.6(3) . . ?
C39 C38 C37 122.0(3) . . ?
C39 C38 H38 119.0 . . ?
C37 C38 H38 119.0 . . ?
C40 C39 C38 118.4(3) . . ?
C40 C39 C43 121.1(3) . . ?
C38 C39 C43 120.6(3) . . ?
C39 C40 C41 121.8(3) . . ?
C39 C40 H40 119.1 . . ?
C41 C40 H40 119.1 . . ?
C40 C41 C36 118.8(3) . . ?
C40 C41 C44 119.8(3) . . ?
C36 C41 C44 121.5(3) . . ?
C37 C42 H42A 109.5 . . ?
C37 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C37 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C44 H44A 109.5 . . ?
C41 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C41 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C39 C43 H43A 109.5 . . ?
C39 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C39 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C50 C45 C46 120.4(3) . . ?
C50 C45 C34 120.2(3) . . ?
C46 C45 C34 119.4(3) . . ?
C47 C46 C45 118.1(3) . . ?
C47 C46 C51 119.4(3) . . ?
C45 C46 C51 122.4(3) . . ?
C48 C47 C46 122.0(3) . . ?
C48 C47 H47 119.0 . . ?
C46 C47 H47 119.0 . . ?
C47 C48 C49 118.1(3) . . ?
C47 C48 C52 120.9(3) . . ?
C49 C48 C52 121.0(3) . . ?
C50 C49 C48 122.2(3) . . ?
C50 C49 H49 118.9 . . ?
C48 C49 H49 118.9 . . ?
C49 C50 C45 119.0(3) . . ?
C49 C50 C53 120.2(3) . . ?
C45 C50 C53 120.8(3) . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C59 C54 C55 121.3(3) . . ?
C59 C54 C35 119.1(3) . . ?
C55 C54 C35 119.6(3) . . ?
C50 C53 H53A 109.5 . . ?
C50 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C50 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C48 C52 H52A 109.5 . . ?
C48 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C48 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C56 C55 C54 118.2(3) . . ?
C56 C55 C60 120.1(3) . . ?
C54 C55 C60 121.7(3) . . ?
C55 C56 C57 121.6(3) . . ?
C55 C56 H56 119.2 . . ?
C57 C56 H56 119.2 . . ?
C58 C57 C56 119.0(3) . . ?
C58 C57 C61 120.3(3) . . ?
C56 C57 C61 120.7(3) . . ?
C57 C58 C59 121.6(3) . . ?
C57 C58 H58 119.2 . . ?
C59 C58 H58 119.2 . . ?
C58 C59 C54 118.4(3) . . ?
C58 C59 C62 120.3(3) . . ?
C54 C59 C62 121.3(3) . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C57 C61 H61A 109.5 . . ?
C57 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C57 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C64 C63 Ge2 113.9(3) . . ?
C64 C63 H63A 108.8 . . ?
Ge2 C63 H63A 108.8 . . ?
C64 C63 H63B 108.8 . . ?
Ge2 C63 H63B 108.8 . . ?
H63A C63 H63B 107.7 . . ?
C59 C62 H62A 109.5 . . ?
C59 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C59 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
O7 C65 C68 121.6(3) . . ?
O7 C65 Ge3 114.7(2) . . ?
C68 C65 Ge3 123.65(19) . . ?
O8 C66 C77 121.2(3) . . ?
O8 C66 Ge3 121.7(2) . . ?
C77 C66 Ge3 117.0(2) . . ?
O9 C67 C86 123.0(3) . . ?
O9 C67 Ge3 113.1(2) . . ?
C86 C67 Ge3 123.4(2) . . ?
C69 C68 C73 121.2(3) . . ?
C69 C68 C65 119.6(2) . . ?
C73 C68 C65 119.3(2) . . ?
C70 C69 C68 118.0(3) . . ?
C70 C69 C74 119.7(3) . . ?
C68 C69 C74 122.3(3) . . ?
C71 C70 C69 121.9(3) . . ?
C71 C70 H70 119.0 . . ?
C69 C70 H70 119.0 . . ?
C72 C71 C70 118.6(3) . . ?
C72 C71 C75 121.2(3) . . ?
C70 C71 C75 120.1(3) . . ?
C71 C72 C73 121.8(3) . . ?
C71 C72 H72 119.1 . . ?
C73 C72 H72 119.1 . . ?
C72 C73 C68 118.5(3) . . ?
C72 C73 C76 120.6(3) . . ?
C68 C73 C76 120.8(3) . . ?
C69 C74 H74A 109.5 . . ?
C69 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C69 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C73 C76 H76A 109.5 . . ?
C73 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C73 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C71 C75 H75A 109.5 . . ?
C71 C75 H75B 109.5 . . ?
H75A C75 H75B 109.5 . . ?
C71 C75 H75C 109.5 . . ?
H75A C75 H75C 109.5 . . ?
H75B C75 H75C 109.5 . . ?
C82 C77 C78 121.4(3) . . ?
C82 C77 C66 120.0(3) . . ?
C78 C77 C66 118.6(3) . . ?
C79 C78 C77 118.4(3) . . ?
C79 C78 C83 120.2(3) . . ?
C77 C78 C83 121.4(3) . . ?
C80 C79 C78 121.4(3) . . ?
C80 C79 H79 119.3 . . ?
C78 C79 H79 119.3 . . ?
C77 C82 C81 118.1(3) . . ?
C77 C82 C85 121.2(3) . . ?
C81 C82 C85 120.7(3) . . ?
C80 C81 C82 121.3(3) . . ?
C80 C81 H81 119.3 . . ?
C82 C81 H81 119.3 . . ?
C79 C80 C81 119.3(3) . . ?
C79 C80 C84 119.9(3) . . ?
C81 C80 C84 120.8(3) . . ?
C78 C83 H83A 109.5 . . ?
C78 C83 H83B 109.5 . . ?
H83A C83 H83B 109.5 . . ?
C78 C83 H83C 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
C91 C86 C87 120.7(3) . . ?
C91 C86 C67 120.0(3) . . ?
C87 C86 C67 119.2(3) . . ?
C82 C85 H85A 109.5 . . ?
C82 C85 H85B 109.5 . . ?
H85A C85 H85B 109.5 . . ?
C82 C85 H85C 109.5 . . ?
H85A C85 H85C 109.5 . . ?
H85B C85 H85C 109.5 . . ?
C80 C84 H84A 109.5 . . ?
C80 C84 H84B 109.5 . . ?
H84A C84 H84B 109.5 . . ?
C80 C84 H84C 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
C88 C87 C86 117.8(3) . . ?
C88 C87 C92 119.3(3) . . ?
C86 C87 C92 122.8(3) . . ?
C89 C88 C87 122.3(3) . . ?
C89 C88 H88 118.9 . . ?
C87 C88 H88 118.9 . . ?
C88 C89 C90 118.7(3) . . ?
C88 C89 C93 121.2(3) . . ?
C90 C89 C93 120.1(3) . . ?
C89 C90 C91 121.3(3) . . ?
C89 C90 H90 119.3 . . ?
C91 C90 H90 119.3 . . ?
C86 C91 C90 119.1(3) . . ?
C86 C91 C94 121.6(3) . . ?
C90 C91 C94 119.3(3) . . ?
C87 C92 H92A 109.5 . . ?
C87 C92 H92B 109.5 . . ?
H92A C92 H92B 109.5 . . ?
C87 C92 H92C 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
C89 C93 H93A 109.5 . . ?
C89 C93 H93B 109.5 . . ?
H93A C93 H93B 109.5 . . ?
C89 C93 H93C 109.5 . . ?
H93A C93 H93C 109.5 . . ?
H93B C93 H93C 109.5 . . ?
C91 C94 H94A 109.5 . . ?
C91 C94 H94B 109.5 . . ?
H94A C94 H94B 109.5 . . ?
C91 C94 H94C 109.5 . . ?
H94A C94 H94C 109.5 . . ?
H94B C94 H94C 109.5 . . ?
C96 C95 Ge3 115.9(3) . . ?
C96 C95 H95A 108.3 . . ?
Ge3 C95 H95A 108.3 . . ?
C96 C95 H95B 108.3 . . ?
Ge3 C95 H95B 108.3 . . ?
H95A C95 H95B 107.4 . . ?
C95 C96 H96A 109.5 . . ?
C95 C96 H96B 109.5 . . ?
H96A C96 H96B 109.5 . . ?
C95 C96 H96C 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?

_refine_diff_density_max         1.946
_refine_diff_density_min         -1.793
_refine_diff_density_rms         0.083

