# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_audit_block_doi                 10.5517/ccdc.csd.cc1nkhk8
_database_code_depnum_ccdc_archive 'CCDC 1536160'
_audit_update_record             
;
2017-03-06 deposited with the CCDC.
2017-03-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C0 H16 Ag4 N4 O0 S16 Sb8'
_chemical_formula_weight         1990.61

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.548(9)
_cell_length_b                   7.395(6)
_cell_length_c                   11.083(8)
_cell_angle_alpha                90
_cell_angle_beta                 116.731(8)
_cell_angle_gamma                90
_cell_volume                     845.3(11)
_cell_formula_units_Z            1
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    3641
_cell_measurement_theta_min      3.389
_cell_measurement_theta_max      27.199

_exptl_crystal_description       plate
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.910
_exptl_crystal_F_000             896
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    9.535
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  0.4586
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            6705
_diffrn_reflns_av_unetI/netI     0.0488
_diffrn_reflns_av_R_equivalents  0.0494
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         1.975
_diffrn_reflns_theta_max         27.231
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measured_fraction_theta_full 0.982
_diffrn_reflns_Laue_measured_fraction_max 0.975
_diffrn_reflns_Laue_measured_fraction_full 0.982
_diffrn_reflns_point_group_measured_fraction_max 0.975
_diffrn_reflns_point_group_measured_fraction_full 0.982
_reflns_number_total             1843
_reflns_number_gt                1699
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component perfect twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.2000P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef       0.010(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         1843
_refine_ls_number_parameters     74
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0837
_refine_ls_R_factor_gt           0.0812
_refine_ls_wR_factor_ref         0.2669
_refine_ls_wR_factor_gt          0.2625
_refine_ls_goodness_of_fit_ref   1.221
_refine_ls_restrained_S_all      1.221
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.33781(9) 0.07570(13) 0.48760(8) 0.0147(4) Uani 1 1 d . . . . .
Sb2 Sb 0.36417(9) 0.53110(12) 0.33187(8) 0.0140(4) Uani 1 1 d . . . . .
Ag1 Ag 0.33920(13) 0.50138(18) 0.66829(12) 0.0283(5) Uani 1 1 d . . . . .
S1 S 0.2239(3) 0.3771(4) 0.4217(3) 0.0154(7) Uani 1 1 d . . . . .
S2 S 0.2055(3) -0.0945(5) 0.2866(3) 0.0168(8) Uani 1 1 d . . . . .
S3 S 0.1982(4) -0.0069(5) 0.5967(3) 0.0174(8) Uani 1 1 d . . . . .
S4 S 0.4877(3) 0.2646(4) 0.3270(3) 0.0167(7) Uani 1 1 d . . . . .
N1 N 0.0041(11) -0.2960(16) 0.3862(12) 0.028(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 S2 2.412(4) . ?
Sb1 S3 2.487(4) . ?
Sb1 S1 2.523(4) . ?
Sb2 S4 2.448(4) . ?
Sb2 S3 2.451(4) 4_565 ?
Sb2 S1 2.523(4) . ?
Ag1 S2 2.530(4) 4_566 ?
Ag1 S1 2.610(4) . ?
Ag1 S4 2.627(4) 3_666 ?
Ag1 S4 2.681(4) 4_566 ?
S2 Ag1 2.530(4) 4_565 ?
S3 Sb2 2.451(4) 4_566 ?
S4 Ag1 2.627(4) 3_666 ?
S4 Ag1 2.681(4) 4_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S2 Sb1 S3 92.35(13) . . ?
S2 Sb1 S1 99.33(12) . . ?
S3 Sb1 S1 89.43(12) . . ?
S4 Sb2 S3 95.87(12) . 4_565 ?
S4 Sb2 S1 97.43(11) . . ?
S3 Sb2 S1 93.04(13) 4_565 . ?
S2 Ag1 S1 119.70(13) 4_566 . ?
S2 Ag1 S4 116.55(12) 4_566 3_666 ?
S1 Ag1 S4 106.14(11) . 3_666 ?
S2 Ag1 S4 102.65(11) 4_566 4_566 ?
S1 Ag1 S4 107.65(11) . 4_566 ?
S4 Ag1 S4 102.35(8) 3_666 4_566 ?
Sb2 S1 Sb1 99.74(12) . . ?
Sb2 S1 Ag1 97.96(13) . . ?
Sb1 S1 Ag1 93.08(11) . . ?
Sb1 S2 Ag1 93.20(14) . 4_565 ?
Sb2 S3 Sb1 99.64(15) 4_566 . ?
Sb2 S4 Ag1 85.11(12) . 3_666 ?
Sb2 S4 Ag1 113.45(13) . 4_565 ?
Ag1 S4 Ag1 138.83(11) 3_666 4_565 ?

_refine_diff_density_max         4.577
_refine_diff_density_min         -5.464
_refine_diff_density_rms         0.813



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5-75C
_audit_block_doi                 10.5517/ccdc.csd.cc1nkhj7
_database_code_depnum_ccdc_archive 'CCDC 1536159'
_audit_update_record             
;
2017-03-06 deposited with the CCDC.
2017-03-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C0 H6 Ag N O S7 Sb4'
_chemical_formula_weight         855.35

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   6.874(2)
_cell_length_b                   9.281(3)
_cell_length_c                   11.747(4)
_cell_angle_alpha                75.989(3)
_cell_angle_beta                 85.686(3)
_cell_angle_gamma                80.955(3)
_cell_volume                     717.5(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    6126
_cell_measurement_theta_min      2.2855
_cell_measurement_theta_max      27.2895

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.959
_exptl_crystal_F_000             768
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    9.762
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            8327
_diffrn_reflns_av_unetI/netI     0.0215
_diffrn_reflns_av_R_equivalents  0.0212
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.788
_diffrn_reflns_theta_max         27.289
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             3189
_reflns_number_gt                3016
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0246P)²+1.0157P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         3189
_refine_ls_number_parameters     136
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0200
_refine_ls_R_factor_gt           0.0185
_refine_ls_wR_factor_ref         0.0528
_refine_ls_wR_factor_gt          0.0521
_refine_ls_goodness_of_fit_ref   1.161
_refine_ls_restrained_S_all      1.161
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.1687(6) 0.6583(3) 0.6272(4) 0.0364(6) Uani 0.5 1 d . . P . .
Ag2 Ag -0.1869(6) 0.6642(4) 0.6135(4) 0.0443(8) Uani 0.5 1 d . . P . .
Sb1 Sb 0.39764(4) 0.44584(3) 0.65841(2) 0.01667(7) Uani 1 1 d . . . . .
Sb2 Sb 0.00780(3) 0.19011(3) 0.73260(2) 0.01602(7) Uani 1 1 d . . . . .
Sb3 Sb 0.25754(4) 0.88667(3) 0.52895(2) 0.01775(7) Uani 1 1 d . . . . .
Sb4 Sb 0.54944(4) 0.04201(3) 0.83936(2) 0.02007(7) Uani 1 1 d . . . . .
S1 S 0.25007(14) 0.01816(12) 0.95769(9) 0.0229(2) Uani 1 1 d . . . . .
S2 S 0.33622(14) 0.14036(11) 0.64183(8) 0.01938(19) Uani 1 1 d . . . . .
S3 S 0.03673(14) 1.09538(11) 0.34448(8) 0.01871(19) Uani 1 1 d . . . . .
S4 S 0.57730(14) 0.30638(11) 0.83682(8) 0.01806(19) Uani 1 1 d . . . . .
S5 S -0.14282(15) 0.32471(11) 0.54117(8) 0.0206(2) Uani 1 1 d . . . . .
S6 S 0.06849(14) 0.44308(11) 0.76147(8) 0.01739(18) Uani 1 1 d . . . . .
S7 S 0.46444(14) 0.68613(11) 0.69888(9) 0.01986(19) Uani 1 1 d . . . . .
N1 N 0.2831(5) 0.3942(4) 1.0491(3) 0.0296(8) Uani 1 1 d . . . . .
O1 O -0.1010(6) 0.3043(4) 1.0674(3) 0.0485(10) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 S7 2.592(4) 1_455 ?
Ag1 S6 2.640(5) . ?
Ag1 S3 2.688(4) 2_576 ?
Ag1 S5 2.800(4) 2_566 ?
Ag2 S7 2.525(4) 1_455 ?
Ag2 S3 2.761(4) 2_576 ?
Ag2 S5 2.795(4) 2_566 ?
Ag2 S6 2.813(5) . ?
Sb1 S4 2.4832(11) . ?
Sb1 S6 2.4852(12) . ?
Sb1 S7 2.5057(12) . ?
Sb2 S2 2.4484(12) . ?
Sb2 S5 2.5046(11) . ?
Sb2 S6 2.5527(12) . ?
Sb3 S3 2.4272(11) 2_576 ?
Sb3 S5 2.5526(11) 2_566 ?
Sb3 S7 2.6958(11) . ?
Sb3 S3 2.8792(12) . ?
Sb4 S1 2.4040(12) . ?
Sb4 S4 2.4837(13) . ?
Sb4 S2 2.7261(12) . ?
Sb4 S1 2.7390(13) 2_657 ?
S1 Sb4 2.7390(13) 2_657 ?
S3 Sb3 2.4271(11) 2_576 ?
S3 Ag1 2.688(4) 2_576 ?
S3 Ag2 2.761(4) 2_576 ?
S5 Sb3 2.5526(11) 2_566 ?
S5 Ag2 2.795(4) 2_566 ?
S5 Ag1 2.800(4) 2_566 ?
S7 Ag2 2.525(4) 1_655 ?
S7 Ag1 2.591(4) 1_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S7 Ag1 S6 115.50(14) 1_455 . ?
S7 Ag1 S3 105.01(11) 1_455 2_576 ?
S6 Ag1 S3 101.38(17) . 2_576 ?
S7 Ag1 S5 155.1(2) 1_455 2_566 ?
S6 Ag1 S5 86.50(12) . 2_566 ?
S3 Ag1 S5 80.26(9) 2_576 2_566 ?
S7 Ag2 S3 104.75(13) 1_455 2_576 ?
S7 Ag2 S5 163.5(2) 1_455 2_566 ?
S3 Ag2 S5 79.11(10) 2_576 2_566 ?
S7 Ag2 S6 111.86(14) 1_455 . ?
S3 Ag2 S6 95.39(17) 2_576 . ?
S5 Ag2 S6 83.36(11) 2_566 . ?
S4 Sb1 S6 93.76(4) . . ?
S4 Sb1 S7 88.93(4) . . ?
S6 Sb1 S7 96.49(3) . . ?
S2 Sb2 S5 93.43(4) . . ?
S2 Sb2 S6 92.94(3) . . ?
S5 Sb2 S6 88.51(3) . . ?
S3 Sb3 S5 90.52(4) 2_576 2_566 ?
S3 Sb3 S7 92.83(4) 2_576 . ?
S5 Sb3 S7 90.88(4) 2_566 . ?
S3 Sb3 S3 87.67(4) 2_576 . ?
S5 Sb3 S3 87.85(4) 2_566 . ?
S7 Sb3 S3 178.64(3) . . ?
S1 Sb4 S4 98.93(4) . . ?
S1 Sb4 S2 90.16(4) . . ?
S4 Sb4 S2 89.37(3) . . ?
S1 Sb4 S1 88.31(4) . 2_657 ?
S4 Sb4 S1 83.34(3) . 2_657 ?
S2 Sb4 S1 172.22(3) . 2_657 ?
Sb4 S1 Sb4 91.69(4) . 2_657 ?
Sb2 S2 Sb4 99.29(4) . . ?
Sb3 S3 Ag1 96.82(8) 2_576 2_576 ?
Sb3 S3 Ag2 96.86(8) 2_576 2_576 ?
Ag1 S3 Ag2 4.0(2) 2_576 2_576 ?
Sb3 S3 Sb3 92.33(4) 2_576 . ?
Ag1 S3 Sb3 96.17(11) 2_576 . ?
Ag2 S3 Sb3 92.18(11) 2_576 . ?
Sb1 S4 Sb4 102.00(4) . . ?
Sb2 S5 Sb3 102.64(4) . 2_566 ?
Sb2 S5 Ag2 101.94(12) . 2_566 ?
Sb3 S5 Ag2 93.18(10) 2_566 2_566 ?
Sb2 S5 Ag1 105.98(11) . 2_566 ?
Sb3 S5 Ag1 91.25(8) 2_566 2_566 ?
Ag2 S5 Ag1 4.2(2) 2_566 2_566 ?
Sb1 S6 Sb2 96.91(3) . . ?
Sb1 S6 Ag1 105.37(8) . . ?
Sb2 S6 Ag1 108.86(9) . . ?
Sb1 S6 Ag2 105.26(8) . . ?
Sb2 S6 Ag2 106.69(10) . . ?
Ag1 S6 Ag2 2.25(18) . . ?
Sb1 S7 Ag2 94.35(9) . 1_655 ?
Sb1 S7 Ag1 95.50(8) . 1_655 ?
Ag2 S7 Ag1 4.3(2) 1_655 1_655 ?
Sb1 S7 Sb3 100.24(4) . . ?
Ag2 S7 Sb3 103.97(11) 1_655 . ?
Ag1 S7 Sb3 107.79(10) 1_655 . ?

_refine_diff_density_max         0.760
_refine_diff_density_min         -1.265
_refine_diff_density_rms         0.204



