# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_dym
_database_code_depnum_ccdc_archive 'CCDC 1543939'
_audit_update_record             
;
2017-04-13 deposited with the CCDC.
2017-09-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        Dy2L4
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C48 H56 Dy2 N8 O15'
_chemical_formula_weight         1310.01

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.2768(4)
_cell_length_b                   11.5328(3)
_cell_length_c                   35.2040(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 98.806(1)
_cell_angle_gamma                90.00
_cell_volume                     5326.8(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    31232
_cell_measurement_theta_min      3.00
_cell_measurement_theta_max      27.49

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.11
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.633
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2608
_exptl_absorpt_coefficient_mu    2.856
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6424
_exptl_absorpt_correction_T_max  0.7441
_exptl_absorpt_process_details   'Sadabs (Sheldrick,1996)'

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  RAXIS-RAPID
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            36842
_diffrn_reflns_av_R_equivalents  0.0677
_diffrn_reflns_av_sigmaI/netI    0.0719
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -45
_diffrn_reflns_limit_l_max       45
_diffrn_reflns_theta_min         3.00
_diffrn_reflns_theta_max         27.48
_reflns_number_total             12073
_reflns_number_gt                9965
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0585P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         12073
_refine_ls_number_parameters     666
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0537
_refine_ls_R_factor_gt           0.0439
_refine_ls_wR_factor_ref         0.1141
_refine_ls_wR_factor_gt          0.1088
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.296453(13) 0.658911(17) 0.094343(5) 0.02783(7) Uani 1 1 d . . .
Dy2 Dy 0.209363(14) 0.447460(17) 0.151612(5) 0.02987(7) Uani 1 1 d . . .
O1 O 0.2662(2) 0.4575(2) 0.09230(8) 0.0297(6) Uani 1 1 d . . .
O2 O 0.15567(19) 0.6232(3) 0.12502(7) 0.0312(6) Uani 1 1 d . . .
O3 O 0.3442(2) 0.5756(3) 0.15530(8) 0.0337(6) Uani 1 1 d . . .
O4 O 0.3229(2) 0.7584(3) 0.04241(7) 0.0339(6) Uani 1 1 d . . .
O5 O 0.2138(2) 0.2367(3) 0.15331(8) 0.0400(7) Uani 1 1 d . . .
O6 O 0.3611(2) 0.3222(3) 0.16390(9) 0.0408(7) Uani 1 1 d . . .
O7 O 0.3545(3) 0.1327(3) 0.16418(10) 0.0638(11) Uani 1 1 d . . .
O8 O 0.0650(2) 0.3807(3) 0.10462(9) 0.0456(8) Uani 1 1 d . . .
O9 O 0.0332(2) 0.4097(3) 0.16187(9) 0.0456(8) Uani 1 1 d . . .
O10 O -0.0896(3) 0.3553(4) 0.11682(11) 0.0721(13) Uani 1 1 d . . .
O11 O 0.2283(2) 0.3981(3) 0.22077(8) 0.0411(7) Uani 1 1 d . . .
O12 O 0.1732(3) 0.5711(3) 0.20651(9) 0.0448(8) Uani 1 1 d . . .
O13 O 0.1920(3) 0.5131(4) 0.26622(9) 0.0648(11) Uani 1 1 d . . .
N1 N 0.4401(2) 0.5383(3) 0.07014(10) 0.0323(8) Uani 1 1 d . . .
N2 N 0.1227(2) 0.6342(3) 0.04790(9) 0.0285(7) Uani 1 1 d . . .
N3 N 0.4384(2) 0.7753(3) 0.14213(9) 0.0338(8) Uani 1 1 d . . .
N4 N 0.2149(3) 0.8588(3) 0.09179(10) 0.0326(8) Uani 1 1 d . . .
N5 N 0.3113(3) 0.2272(4) 0.16106(10) 0.0461(10) Uani 1 1 d . . .
N6 N 0.0002(3) 0.3804(4) 0.12723(11) 0.0467(10) Uani 1 1 d . . .
N7 N 0.1976(3) 0.4940(4) 0.23219(10) 0.0435(9) Uani 1 1 d . . .
C1 C 0.5263(3) 0.5748(4) 0.05987(13) 0.0394(10) Uani 1 1 d . . .
C2 C 0.5910(3) 0.4997(4) 0.04222(15) 0.0492(12) Uani 1 1 d . . .
H2 H 0.6533 0.5283 0.0358 0.059 Uiso 1 1 calc R . .
C3 C 0.5642(4) 0.3880(4) 0.03466(16) 0.0515(13) Uani 1 1 d . . .
H3 H 0.6075 0.3390 0.0227 0.062 Uiso 1 1 calc R . .
C4 C 0.4720(3) 0.3435(4) 0.04448(13) 0.0386(10) Uani 1 1 d . . .
C5 C 0.4391(3) 0.2290(4) 0.03781(13) 0.0407(10) Uani 1 1 d . . .
H5 H 0.4789 0.1760 0.0257 0.049 Uiso 1 1 calc R . .
C6 C 0.3502(4) 0.1939(4) 0.04861(13) 0.0422(11) Uani 1 1 d . . .
H6 H 0.3271 0.1167 0.0435 0.051 Uiso 1 1 calc R . .
C7 C 0.2921(3) 0.2709(4) 0.06724(11) 0.0331(9) Uani 1 1 d . . .
H7 H 0.2306 0.2437 0.0747 0.040 Uiso 1 1 calc R . .
C8 C 0.3205(3) 0.3836(4) 0.07505(11) 0.0303(9) Uani 1 1 d . . .
C9 C 0.4137(3) 0.4230(4) 0.06303(12) 0.0319(9) Uani 1 1 d . . .
C10 C 0.5573(3) 0.6990(4) 0.06654(14) 0.0440(11) Uani 1 1 d . . .
H10A H 0.5007 0.7496 0.0559 0.066 Uiso 1 1 calc R . .
H10B H 0.6166 0.7154 0.0539 0.066 Uiso 1 1 calc R . .
H10C H 0.5749 0.7132 0.0942 0.066 Uiso 1 1 calc R . .
C11 C 0.1041(3) 0.6236(4) 0.00975(12) 0.0343(9) Uani 1 1 d . . .
C12 C 0.0054(4) 0.6469(4) -0.01115(13) 0.0419(11) Uani 1 1 d . . .
H12 H -0.0062 0.6396 -0.0383 0.050 Uiso 1 1 calc R . .
C13 C -0.0722(3) 0.6797(4) 0.00768(13) 0.0420(11) Uani 1 1 d . . .
H13 H -0.1372 0.6976 -0.0064 0.050 Uiso 1 1 calc R . .
C14 C -0.0562(3) 0.6868(4) 0.04805(13) 0.0359(10) Uani 1 1 d . . .
C15 C -0.1327(3) 0.7167(4) 0.07010(14) 0.0447(11) Uani 1 1 d . . .
H15 H -0.1986 0.7379 0.0576 0.054 Uiso 1 1 calc R . .
C16 C -0.1123(3) 0.7152(5) 0.10952(14) 0.0484(12) Uani 1 1 d . . .
H16 H -0.1641 0.7359 0.1241 0.058 Uiso 1 1 calc R . .
C17 C -0.0157(3) 0.6833(4) 0.12842(13) 0.0410(10) Uani 1 1 d . . .
H17 H -0.0034 0.6810 0.1557 0.049 Uiso 1 1 calc R . .
C18 C 0.0618(3) 0.6552(3) 0.10827(12) 0.0328(9) Uani 1 1 d . . .
C19 C 0.0429(3) 0.6595(3) 0.06688(12) 0.0310(9) Uani 1 1 d . . .
C20 C 0.1879(4) 0.5869(4) -0.01117(12) 0.0424(11) Uani 1 1 d . . .
H20A H 0.2420 0.5500 0.0068 0.064 Uiso 1 1 calc R . .
H20B H 0.2154 0.6549 -0.0228 0.064 Uiso 1 1 calc R . .
H20C H 0.1615 0.5315 -0.0314 0.064 Uiso 1 1 calc R . .
C21 C 0.4827(3) 0.8765(4) 0.13682(12) 0.0378(10) Uani 1 1 d . . .
C22 C 0.5651(4) 0.9190(4) 0.16367(14) 0.0501(12) Uani 1 1 d . . .
H22 H 0.5961 0.9907 0.1589 0.060 Uiso 1 1 calc R . .
C23 C 0.6000(4) 0.8587(5) 0.19584(15) 0.0548(14) Uani 1 1 d . . .
H23 H 0.6563 0.8872 0.2132 0.066 Uiso 1 1 calc R . .
C24 C 0.5528(3) 0.7528(4) 0.20381(12) 0.0405(10) Uani 1 1 d . . .
C25 C 0.5806(4) 0.6890(5) 0.23811(13) 0.0482(12) Uani 1 1 d . . .
H25 H 0.6355 0.7144 0.2568 0.058 Uiso 1 1 calc R . .
C26 C 0.5285(3) 0.5917(4) 0.24419(13) 0.0427(11) Uani 1 1 d . . .
H26 H 0.5458 0.5505 0.2676 0.051 Uiso 1 1 calc R . .
C27 C 0.4488(3) 0.5501(4) 0.21621(12) 0.0368(10) Uani 1 1 d . . .
H27 H 0.4151 0.4799 0.2207 0.044 Uiso 1 1 calc R . .
C28 C 0.4194(3) 0.6104(4) 0.18249(11) 0.0320(9) Uani 1 1 d . . .
C29 C 0.4716(3) 0.7147(4) 0.17584(11) 0.0338(9) Uani 1 1 d . . .
C30 C 0.4479(4) 0.9489(4) 0.10243(13) 0.0415(11) Uani 1 1 d . . .
H30A H 0.4132 0.8999 0.0817 0.062 Uiso 1 1 calc R . .
H30B H 0.5069 0.9863 0.0939 0.062 Uiso 1 1 calc R . .
H30C H 0.4007 1.0084 0.1089 0.062 Uiso 1 1 calc R . .
C31 C 0.1676(3) 0.9138(4) 0.11762(14) 0.0410(10) Uani 1 1 d . . .
C32 C 0.1003(3) 1.0077(4) 0.10688(16) 0.0483(12) Uani 1 1 d . . .
H32 H 0.0676 1.0453 0.1257 0.058 Uiso 1 1 calc R . .
C33 C 0.0823(4) 1.0444(4) 0.06952(17) 0.0516(14) Uani 1 1 d . . .
H33 H 0.0345 1.1046 0.0621 0.062 Uiso 1 1 calc R . .
C34 C 0.1355(3) 0.9919(4) 0.04173(14) 0.0413(11) Uani 1 1 d . . .
C35 C 0.1270(4) 1.0282(4) 0.00288(15) 0.0510(13) Uani 1 1 d . . .
H35 H 0.0805 1.0879 -0.0066 0.061 Uiso 1 1 calc R . .
C36 C 0.1856(4) 0.9774(4) -0.02073(15) 0.0507(13) Uani 1 1 d . . .
H36 H 0.1807 1.0032 -0.0466 0.061 Uiso 1 1 calc R . .
C37 C 0.2531(4) 0.8879(4) -0.00779(13) 0.0424(11) Uani 1 1 d . . .
H37 H 0.2942 0.8557 -0.0250 0.051 Uiso 1 1 calc R . .
C38 C 0.2622(3) 0.8443(4) 0.02934(13) 0.0349(10) Uani 1 1 d . . .
C39 C 0.2012(3) 0.8993(4) 0.05458(13) 0.0358(10) Uani 1 1 d . . .
C40 C 0.1901(4) 0.8789(5) 0.15925(14) 0.0500(12) Uani 1 1 d . . .
H40A H 0.2287 0.8062 0.1616 0.075 Uiso 1 1 calc R . .
H40B H 0.1260 0.8682 0.1694 0.075 Uiso 1 1 calc R . .
H40C H 0.2304 0.9398 0.1739 0.075 Uiso 1 1 calc R . .
N8 N 0.6888(3) 0.3207(4) 0.17279(13) 0.0550(11) Uani 1 1 d . . .
H8N H 0.7563 0.3342 0.1835 0.066 Uiso 1 1 calc R . .
C41 C 0.6382(4) 0.2567(6) 0.20242(15) 0.0672(16) Uani 1 1 d . . .
H41A H 0.5633 0.2637 0.1957 0.081 Uiso 1 1 calc R . .
H41B H 0.6560 0.1734 0.2020 0.081 Uiso 1 1 calc R . .
C42 C 0.6710(4) 0.3038(5) 0.24241(17) 0.0636(15) Uani 1 1 d . . .
H42A H 0.6337 0.2636 0.2605 0.095 Uiso 1 1 calc R . .
H42B H 0.6561 0.3870 0.2427 0.095 Uiso 1 1 calc R . .
H42C H 0.7443 0.2914 0.2500 0.095 Uiso 1 1 calc R . .
C43 C 0.6386(5) 0.4375(6) 0.1635(2) 0.0745(19) Uani 1 1 d . . .
H43A H 0.6171 0.4696 0.1871 0.089 Uiso 1 1 calc R . .
H43B H 0.5767 0.4265 0.1442 0.089 Uiso 1 1 calc R . .
C44 C 0.7087(5) 0.5241(6) 0.14797(18) 0.0788(19) Uani 1 1 d . . .
H44A H 0.6748 0.5997 0.1446 0.118 Uiso 1 1 calc R . .
H44B H 0.7243 0.4968 0.1232 0.118 Uiso 1 1 calc R . .
H44C H 0.7721 0.5316 0.1662 0.118 Uiso 1 1 calc R . .
C45 C 0.6893(5) 0.2499(6) 0.13727(17) 0.0765(18) Uani 1 1 d . . .
H45A H 0.7047 0.3014 0.1164 0.092 Uiso 1 1 calc R . .
H45B H 0.6202 0.2176 0.1293 0.092 Uiso 1 1 calc R . .
C46 C 0.7665(6) 0.1495(6) 0.1420(2) 0.092(2) Uani 1 1 d . . .
H46A H 0.7614 0.1061 0.1179 0.137 Uiso 1 1 calc R . .
H46B H 0.7518 0.0977 0.1625 0.137 Uiso 1 1 calc R . .
H46C H 0.8356 0.1807 0.1487 0.137 Uiso 1 1 calc R . .
O14 O 0.9685(3) 0.2379(4) 0.26630(13) 0.0823(13) Uani 1 1 d . . .
H14O H 0.9300 0.1838 0.2720 0.099 Uiso 1 1 d R . .
C47 C 1.0660(6) 0.1881(8) 0.2627(3) 0.112(3) Uani 1 1 d . . .
H47A H 1.1179 0.2504 0.2656 0.134 Uiso 1 1 calc R . .
H47B H 1.0849 0.1319 0.2838 0.134 Uiso 1 1 calc R . .
C48 C 1.0681(9) 0.1305(10) 0.2267(3) 0.141(4) Uani 1 1 d . . .
H48A H 1.1379 0.1306 0.2208 0.212 Uiso 1 1 calc R . .
H48B H 1.0232 0.1711 0.2063 0.212 Uiso 1 1 calc R . .
H48C H 1.0447 0.0504 0.2285 0.212 Uiso 1 1 calc R . .
O1W O 0.8810(3) 0.3711(4) 0.20840(11) 0.0733(12) Uani 1 1 d . . .
H1WA H 0.9013 0.3204 0.2254 0.088 Uiso 1 1 d R . .
H1WB H 0.9239 0.3757 0.1929 0.088 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O4 2.231(3) . ?
Dy1 O2 2.334(3) . ?
Dy1 O3 2.348(3) . ?
Dy1 O1 2.356(3) . ?
Dy1 N4 2.543(3) . ?
Dy1 N1 2.607(3) . ?
Dy1 N2 2.631(3) . ?
Dy1 N3 2.686(3) . ?
Dy1 Dy2 3.4731(3) . ?
Dy2 O2 2.300(3) . ?
Dy2 O3 2.309(3) . ?
Dy2 O1 2.329(3) . ?
Dy2 O5 2.431(3) . ?
Dy2 O8 2.456(3) . ?
Dy2 O9 2.460(3) . ?
Dy2 O6 2.462(3) . ?
Dy2 O11 2.475(3) . ?
Dy2 O12 2.506(3) . ?
Dy2 N5 2.873(4) . ?
Dy2 N6 2.884(4) . ?
Dy2 N7 2.914(4) . ?
O1 C8 1.322(5) . ?
O2 C18 1.346(4) . ?
O3 C28 1.334(4) . ?
O4 C38 1.315(5) . ?
O5 N5 1.286(5) . ?
O6 N5 1.276(5) . ?
O7 N5 1.229(5) . ?
O8 N6 1.259(5) . ?
O9 N6 1.276(5) . ?
O10 N6 1.227(5) . ?
O11 N7 1.265(5) . ?
O12 N7 1.274(5) . ?
O13 N7 1.232(5) . ?
N1 C1 1.320(6) . ?
N1 C9 1.389(5) . ?
N2 C11 1.333(5) . ?
N2 C19 1.369(5) . ?
N3 C21 1.333(6) . ?
N3 C29 1.389(5) . ?
N4 C31 1.341(6) . ?
N4 C39 1.376(5) . ?
C1 C2 1.427(6) . ?
C1 C10 1.499(6) . ?
C2 C3 1.351(7) . ?
C2 H2 0.9500 . ?
C3 C4 1.419(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.399(6) . ?
C4 C9 1.422(6) . ?
C5 C6 1.355(7) . ?
C5 H5 0.9500 . ?
C6 C7 1.403(6) . ?
C6 H6 0.9500 . ?
C7 C8 1.370(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.441(6) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.427(6) . ?
C11 C20 1.487(6) . ?
C12 C13 1.361(7) . ?
C12 H12 0.9500 . ?
C13 C14 1.407(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.412(6) . ?
C14 C19 1.415(5) . ?
C15 C16 1.373(7) . ?
C15 H15 0.9500 . ?
C16 C17 1.401(6) . ?
C16 H16 0.9500 . ?
C17 C18 1.374(6) . ?
C17 H17 0.9500 . ?
C18 C19 1.441(6) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.419(6) . ?
C21 C30 1.485(6) . ?
C22 C23 1.349(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.420(7) . ?
C23 H23 0.9500 . ?
C24 C29 1.414(5) . ?
C24 C25 1.414(6) . ?
C25 C26 1.352(7) . ?
C25 H25 0.9500 . ?
C26 C27 1.415(6) . ?
C26 H26 0.9500 . ?
C27 C28 1.380(6) . ?
C27 H27 0.9500 . ?
C28 C29 1.427(6) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.418(7) . ?
C31 C40 1.505(7) . ?
C32 C33 1.367(7) . ?
C32 H32 0.9500 . ?
C33 C34 1.426(7) . ?
C33 H33 0.9500 . ?
C34 C39 1.409(6) . ?
C34 C35 1.418(7) . ?
C35 C36 1.356(8) . ?
C35 H35 0.9500 . ?
C36 C37 1.397(7) . ?
C36 H36 0.9500 . ?
C37 C38 1.388(6) . ?
C37 H37 0.9500 . ?
C38 C39 1.437(6) . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
N8 C45 1.494(8) . ?
N8 C43 1.515(7) . ?
N8 C41 1.516(7) . ?
N8 H8N 0.9300 . ?
C41 C42 1.510(8) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 C44 1.523(9) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C46 1.539(10) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
O14 C47 1.440(8) . ?
O14 H14O 0.8500 . ?
C47 C48 1.433(11) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
O1W H1WA 0.8500 . ?
O1W H1WB 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Dy1 O2 135.01(9) . . ?
O4 Dy1 O3 154.82(9) . . ?
O2 Dy1 O3 68.18(9) . . ?
O4 Dy1 O1 121.97(10) . . ?
O2 Dy1 O1 72.27(10) . . ?
O3 Dy1 O1 69.23(10) . . ?
O4 Dy1 N4 67.92(11) . . ?
O2 Dy1 N4 79.01(11) . . ?
O3 Dy1 N4 117.22(11) . . ?
O1 Dy1 N4 145.37(10) . . ?
O4 Dy1 N1 77.99(10) . . ?
O2 Dy1 N1 137.32(10) . . ?
O3 Dy1 N1 88.38(10) . . ?
O1 Dy1 N1 66.06(10) . . ?
N4 Dy1 N1 143.22(11) . . ?
O4 Dy1 N2 77.26(10) . . ?
O2 Dy1 N2 65.19(9) . . ?
O3 Dy1 N2 127.73(10) . . ?
O1 Dy1 N2 75.22(10) . . ?
N4 Dy1 N2 75.42(10) . . ?
N1 Dy1 N2 110.78(10) . . ?
O4 Dy1 N3 94.18(10) . . ?
O2 Dy1 N3 109.47(10) . . ?
O3 Dy1 N3 64.33(10) . . ?
O1 Dy1 N3 127.71(10) . . ?
N4 Dy1 N3 79.83(10) . . ?
N1 Dy1 N3 89.58(10) . . ?
N2 Dy1 N3 155.24(10) . . ?
O4 Dy1 Dy2 160.88(7) . . ?
O2 Dy1 Dy2 41.08(7) . . ?
O3 Dy1 Dy2 41.36(7) . . ?
O1 Dy1 Dy2 41.86(7) . . ?
N4 Dy1 Dy2 118.64(8) . . ?
N1 Dy1 Dy2 98.08(8) . . ?
N2 Dy1 Dy2 86.93(7) . . ?
N3 Dy1 Dy2 104.56(8) . . ?
O2 Dy2 O3 69.41(9) . . ?
O2 Dy2 O1 73.37(10) . . ?
O3 Dy2 O1 70.36(10) . . ?
O2 Dy2 O5 153.62(9) . . ?
O3 Dy2 O5 128.48(10) . . ?
O1 Dy2 O5 93.55(10) . . ?
O2 Dy2 O8 80.85(11) . . ?
O3 Dy2 O8 139.18(10) . . ?
O1 Dy2 O8 74.82(10) . . ?
O5 Dy2 O8 73.55(11) . . ?
O2 Dy2 O9 88.48(11) . . ?
O3 Dy2 O9 148.38(11) . . ?
O1 Dy2 O9 125.89(10) . . ?
O5 Dy2 O9 80.76(11) . . ?
O8 Dy2 O9 51.81(10) . . ?
O2 Dy2 O6 141.51(10) . . ?
O3 Dy2 O6 76.07(10) . . ?
O1 Dy2 O6 79.53(10) . . ?
O5 Dy2 O6 52.64(10) . . ?
O8 Dy2 O6 117.86(11) . . ?
O9 Dy2 O6 129.86(11) . . ?
O2 Dy2 O11 125.55(10) . . ?
O3 Dy2 O11 97.51(10) . . ?
O1 Dy2 O11 153.54(10) . . ?
O5 Dy2 O11 75.39(10) . . ?
O8 Dy2 O11 122.79(11) . . ?
O9 Dy2 O11 76.73(10) . . ?
O6 Dy2 O11 74.65(10) . . ?
O2 Dy2 O12 74.25(10) . . ?
O3 Dy2 O12 80.28(11) . . ?
O1 Dy2 O12 142.14(10) . . ?
O5 Dy2 O12 123.81(10) . . ?
O8 Dy2 O12 118.41(11) . . ?
O9 Dy2 O12 71.87(11) . . ?
O6 Dy2 O12 116.51(10) . . ?
O11 Dy2 O12 51.31(10) . . ?
O2 Dy2 N5 159.62(11) . . ?
O3 Dy2 N5 102.22(11) . . ?
O1 Dy2 N5 86.36(10) . . ?
O5 Dy2 N5 26.40(10) . . ?
O8 Dy2 N5 96.08(11) . . ?
O9 Dy2 N5 105.54(12) . . ?
O6 Dy2 N5 26.24(11) . . ?
O11 Dy2 N5 73.02(10) . . ?
O12 Dy2 N5 123.78(10) . . ?
O2 Dy2 N6 83.74(11) . . ?
O3 Dy2 N6 153.02(11) . . ?
O1 Dy2 N6 100.13(10) . . ?
O5 Dy2 N6 76.00(11) . . ?
O8 Dy2 N6 25.70(10) . . ?
O9 Dy2 N6 26.12(10) . . ?
O6 Dy2 N6 128.28(12) . . ?
O11 Dy2 N6 100.32(11) . . ?
O12 Dy2 N6 95.30(12) . . ?
N5 Dy2 N6 102.26(12) . . ?
O2 Dy2 N7 100.04(11) . . ?
O3 Dy2 N7 89.07(11) . . ?
O1 Dy2 N7 159.43(11) . . ?
O5 Dy2 N7 99.50(11) . . ?
O8 Dy2 N7 124.12(11) . . ?
O9 Dy2 N7 72.31(10) . . ?
O6 Dy2 N7 95.81(10) . . ?
O11 Dy2 N7 25.51(11) . . ?
O12 Dy2 N7 25.80(11) . . ?
N5 Dy2 N7 98.31(11) . . ?
N6 Dy2 N7 98.43(11) . . ?
C8 O1 Dy2 130.8(2) . . ?
C8 O1 Dy1 123.2(3) . . ?
Dy2 O1 Dy1 95.68(10) . . ?
C18 O2 Dy2 128.9(2) . . ?
C18 O2 Dy1 120.2(2) . . ?
Dy2 O2 Dy1 97.09(10) . . ?
C28 O3 Dy2 136.1(3) . . ?
C28 O3 Dy1 126.9(3) . . ?
Dy2 O3 Dy1 96.43(9) . . ?
C38 O4 Dy1 120.6(3) . . ?
N5 O5 Dy2 96.4(2) . . ?
N5 O6 Dy2 95.2(2) . . ?
N6 O8 Dy2 96.5(2) . . ?
N6 O9 Dy2 95.8(2) . . ?
N7 O11 Dy2 97.0(2) . . ?
N7 O12 Dy2 95.3(3) . . ?
C1 N1 C9 117.5(4) . . ?
C1 N1 Dy1 128.9(3) . . ?
C9 N1 Dy1 113.1(3) . . ?
C11 N2 C19 118.2(3) . . ?
C11 N2 Dy1 130.2(3) . . ?
C19 N2 Dy1 110.1(2) . . ?
C21 N3 C29 118.1(3) . . ?
C21 N3 Dy1 129.2(3) . . ?
C29 N3 Dy1 112.6(3) . . ?
C31 N4 C39 118.6(4) . . ?
C31 N4 Dy1 130.2(3) . . ?
C39 N4 Dy1 109.5(3) . . ?
O7 N5 O6 121.7(4) . . ?
O7 N5 O5 122.4(4) . . ?
O6 N5 O5 115.8(4) . . ?
O7 N5 Dy2 178.5(3) . . ?
O6 N5 Dy2 58.6(2) . . ?
O5 N5 Dy2 57.2(2) . . ?
O10 N6 O8 122.6(4) . . ?
O10 N6 O9 121.6(4) . . ?
O8 N6 O9 115.8(3) . . ?
O10 N6 Dy2 178.1(4) . . ?
O8 N6 Dy2 57.80(19) . . ?
O9 N6 Dy2 58.0(2) . . ?
O13 N7 O11 122.4(4) . . ?
O13 N7 O12 121.3(4) . . ?
O11 N7 O12 116.3(4) . . ?
O13 N7 Dy2 179.5(4) . . ?
O11 N7 Dy2 57.44(19) . . ?
O12 N7 Dy2 58.9(2) . . ?
N1 C1 C2 122.0(4) . . ?
N1 C1 C10 119.3(4) . . ?
C2 C1 C10 118.6(4) . . ?
C3 C2 C1 120.4(4) . . ?
C3 C2 H2 119.8 . . ?
C1 C2 H2 119.8 . . ?
C2 C3 C4 120.6(4) . . ?
C2 C3 H3 119.7 . . ?
C4 C3 H3 119.7 . . ?
C5 C4 C3 124.1(4) . . ?
C5 C4 C9 120.5(4) . . ?
C3 C4 C9 115.4(4) . . ?
C6 C5 C4 119.8(4) . . ?
C6 C5 H5 120.1 . . ?
C4 C5 H5 120.1 . . ?
C5 C6 C7 120.4(4) . . ?
C5 C6 H6 119.8 . . ?
C7 C6 H6 119.8 . . ?
C8 C7 C6 122.7(4) . . ?
C8 C7 H7 118.6 . . ?
C6 C7 H7 118.6 . . ?
O1 C8 C7 123.5(4) . . ?
O1 C8 C9 119.0(4) . . ?
C7 C8 C9 117.5(4) . . ?
N1 C9 C4 124.1(4) . . ?
N1 C9 C8 117.0(4) . . ?
C4 C9 C8 118.9(4) . . ?
C1 C10 H10A 109.5 . . ?
C1 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C1 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N2 C11 C12 121.1(4) . . ?
N2 C11 C20 119.2(4) . . ?
C12 C11 C20 119.8(4) . . ?
C13 C12 C11 120.4(4) . . ?
C13 C12 H12 119.8 . . ?
C11 C12 H12 119.8 . . ?
C12 C13 C14 119.9(4) . . ?
C12 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C13 C14 C15 124.0(4) . . ?
C13 C14 C19 116.5(4) . . ?
C15 C14 C19 119.5(4) . . ?
C16 C15 C14 120.4(4) . . ?
C16 C15 H15 119.8 . . ?
C14 C15 H15 119.8 . . ?
C15 C16 C17 120.5(4) . . ?
C15 C16 H16 119.7 . . ?
C17 C16 H16 119.7 . . ?
C18 C17 C16 121.3(4) . . ?
C18 C17 H17 119.3 . . ?
C16 C17 H17 119.3 . . ?
O2 C18 C17 123.6(4) . . ?
O2 C18 C19 117.3(4) . . ?
C17 C18 C19 119.1(4) . . ?
N2 C19 C14 123.6(4) . . ?
N2 C19 C18 117.3(3) . . ?
C14 C19 C18 119.1(4) . . ?
C11 C20 H20A 109.5 . . ?
C11 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C11 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N3 C21 C22 121.4(4) . . ?
N3 C21 C30 121.2(4) . . ?
C22 C21 C30 117.4(4) . . ?
C23 C22 C21 120.8(5) . . ?
C23 C22 H22 119.6 . . ?
C21 C22 H22 119.6 . . ?
C22 C23 C24 120.3(4) . . ?
C22 C23 H23 119.9 . . ?
C24 C23 H23 119.9 . . ?
C29 C24 C25 120.3(4) . . ?
C29 C24 C23 116.2(4) . . ?
C25 C24 C23 123.4(4) . . ?
C26 C25 C24 119.6(4) . . ?
C26 C25 H25 120.2 . . ?
C24 C25 H25 120.2 . . ?
C25 C26 C27 121.1(4) . . ?
C25 C26 H26 119.4 . . ?
C27 C26 H26 119.4 . . ?
C28 C27 C26 120.8(4) . . ?
C28 C27 H27 119.6 . . ?
C26 C27 H27 119.6 . . ?
O3 C28 C27 123.2(4) . . ?
O3 C28 C29 117.7(4) . . ?
C27 C28 C29 119.0(4) . . ?
N3 C29 C24 123.2(4) . . ?
N3 C29 C28 117.7(3) . . ?
C24 C29 C28 119.1(4) . . ?
C21 C30 H30A 109.5 . . ?
C21 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C21 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N4 C31 C32 121.5(5) . . ?
N4 C31 C40 119.3(4) . . ?
C32 C31 C40 119.1(4) . . ?
C33 C32 C31 120.2(5) . . ?
C33 C32 H32 119.9 . . ?
C31 C32 H32 119.9 . . ?
C32 C33 C34 119.8(5) . . ?
C32 C33 H33 120.1 . . ?
C34 C33 H33 120.1 . . ?
C39 C34 C35 119.2(5) . . ?
C39 C34 C33 116.7(4) . . ?
C35 C34 C33 124.2(5) . . ?
C36 C35 C34 119.7(5) . . ?
C36 C35 H35 120.2 . . ?
C34 C35 H35 120.2 . . ?
C35 C36 C37 121.3(5) . . ?
C35 C36 H36 119.4 . . ?
C37 C36 H36 119.4 . . ?
C38 C37 C36 122.2(5) . . ?
C38 C37 H37 118.9 . . ?
C36 C37 H37 118.9 . . ?
O4 C38 C37 124.2(4) . . ?
O4 C38 C39 119.3(4) . . ?
C37 C38 C39 116.5(4) . . ?
N4 C39 C34 123.2(4) . . ?
N4 C39 C38 115.7(4) . . ?
C34 C39 C38 121.0(4) . . ?
C31 C40 H40A 109.5 . . ?
C31 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C31 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C45 N8 C43 111.3(5) . . ?
C45 N8 C41 111.6(5) . . ?
C43 N8 C41 110.8(5) . . ?
C45 N8 H8N 107.6 . . ?
C43 N8 H8N 107.6 . . ?
C41 N8 H8N 107.6 . . ?
C42 C41 N8 111.8(5) . . ?
C42 C41 H41A 109.3 . . ?
N8 C41 H41A 109.3 . . ?
C42 C41 H41B 109.3 . . ?
N8 C41 H41B 109.3 . . ?
H41A C41 H41B 107.9 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
N8 C43 C44 112.8(5) . . ?
N8 C43 H43A 109.0 . . ?
C44 C43 H43A 109.0 . . ?
N8 C43 H43B 109.0 . . ?
C44 C43 H43B 109.0 . . ?
H43A C43 H43B 107.8 . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N8 C45 C46 114.1(5) . . ?
N8 C45 H45A 108.7 . . ?
C46 C45 H45A 108.7 . . ?
N8 C45 H45B 108.7 . . ?
C46 C45 H45B 108.7 . . ?
H45A C45 H45B 107.6 . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C47 O14 H14O 108.0 . . ?
C48 C47 O14 113.8(8) . . ?
C48 C47 H47A 108.8 . . ?
O14 C47 H47A 108.8 . . ?
C48 C47 H47B 108.8 . . ?
O14 C47 H47B 108.8 . . ?
H47A C47 H47B 107.7 . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
H1WA O1W H1WB 108.9 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N8 H8N O1W 0.93 1.80 2.728(6) 173.1 .
O14 H14O O12 0.85 2.11 2.951(6) 169.5 2_645
O1W H1WA O14 0.85 1.84 2.672(6) 165.9 .
O1W H1WB O9 0.85 1.98 2.825(5) 170.2 1_655

_diffrn_measured_fraction_theta_max 0.988
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.988
_refine_diff_density_max         2.392
_refine_diff_density_min         -1.815
_refine_diff_density_rms         0.143
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_A
_database_code_depnum_ccdc_archive 'CCDC 1543942'
_audit_update_record             
;
2017-04-13 deposited with the CCDC.
2017-09-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        Dy3L8
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C80 H64 Dy3 N9 O11'
_chemical_formula_sum            'C80 H64 Dy3 N9 O11'
_chemical_formula_weight         1814.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.7278(5)
_cell_length_b                   27.8929(10)
_cell_length_c                   15.8319(6)
_cell_angle_alpha                90
_cell_angle_beta                 94.0610(10)
_cell_angle_gamma                90
_cell_volume                     6927.9(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    9849
_cell_measurement_theta_min      2.29
_cell_measurement_theta_max      27.52

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.740
_exptl_crystal_F_000             3572
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.198
_exptl_crystal_size_mid          0.194
_exptl_crystal_size_min          0.092
_exptl_absorpt_coefficient_mu    3.273
_shelx_estimated_absorpt_T_min   0.563
_shelx_estimated_absorpt_T_max   0.753
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.649
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_process_details   SADABS-2014/5'(Bruker,2014/5)
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            77549
_diffrn_reflns_av_unetI/netI     0.0308
_diffrn_reflns_av_R_equivalents  0.0381
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.290
_diffrn_reflns_theta_max         27.541
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             15930
_reflns_number_gt                13517
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0195P)²+5.0507P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15930
_refine_ls_number_parameters     936
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0330
_refine_ls_R_factor_gt           0.0223
_refine_ls_wR_factor_ref         0.0468
_refine_ls_wR_factor_gt          0.0440
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_restrained_S_all      1.021
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.81872(2) 0.41767(2) 0.26235(2) 0.01012(3) Uani 1 1 d . . . . .
Dy2 Dy 0.73114(2) 0.53281(2) 0.23699(2) 0.00883(3) Uani 1 1 d . . . . .
Dy3 Dy 0.66029(2) 0.63364(2) 0.34387(2) 0.00907(3) Uani 1 1 d . . . . .
O8 O 0.86258(10) 0.49699(6) 0.26585(11) 0.0118(4) Uani 1 1 d . . . . .
O4 O 0.60485(10) 0.56235(6) 0.28396(11) 0.0108(3) Uani 1 1 d . . . . .
O7 O 0.71511(10) 0.46750(6) 0.32336(10) 0.0115(3) Uani 1 1 d . . . . .
O3 O 0.76006(10) 0.57099(6) 0.36538(11) 0.0112(3) Uani 1 1 d . . . . .
O1 O 0.65243(10) 0.70112(6) 0.42053(10) 0.0116(3) Uani 1 1 d . . . . .
O2 O 0.73251(10) 0.61959(6) 0.22443(11) 0.0113(3) Uani 1 1 d . . . . .
O6 O 0.73097(10) 0.45571(6) 0.16206(11) 0.0113(3) Uani 1 1 d . . . . .
O10 O 0.79492(10) 0.54696(6) 0.10272(11) 0.0150(4) Uani 1 1 d . . . . .
O9 O 0.65723(10) 0.55163(6) 0.10071(11) 0.0153(4) Uani 1 1 d . . . . .
O5 O 0.85001(11) 0.34047(6) 0.28818(11) 0.0155(4) Uani 1 1 d . . . . .
N1 N 0.63212(12) 0.70834(7) 0.25034(13) 0.0110(4) Uani 1 1 d . . . . .
N8 N 0.98438(12) 0.43598(7) 0.22136(13) 0.0135(4) Uani 1 1 d . . . . .
N2 N 0.81314(12) 0.67019(7) 0.35322(13) 0.0123(4) Uani 1 1 d . . . . .
N4 N 0.49185(12) 0.63435(7) 0.29965(14) 0.0142(4) Uani 1 1 d . . . . .
N3 N 0.65821(12) 0.59356(7) 0.48926(13) 0.0113(4) Uani 1 1 d . . . . .
N6 N 0.67072(12) 0.37749(7) 0.24688(14) 0.0134(4) Uani 1 1 d . . . . .
N9 N 0.72443(14) 0.55308(8) 0.05982(14) 0.0162(5) Uani 1 1 d . . . . .
N7 N 0.82919(12) 0.41762(7) 0.42343(13) 0.0122(4) Uani 1 1 d . . . . .
O11 O 0.72032(13) 0.56015(7) -0.01687(12) 0.0275(5) Uani 1 1 d . . . . .
C79 C 0.93623(14) 0.51598(9) 0.24474(15) 0.0115(5) Uani 1 1 d . . . . .
C78 C 0.95243(15) 0.56462(9) 0.25057(16) 0.0144(5) Uani 1 1 d . . . . .
H78 H 0.9120 0.5852 0.2737 0.017 Uiso 1 1 calc R U . . .
N5 N 0.84266(13) 0.36958(8) 0.12658(14) 0.0161(5) Uani 1 1 d . . . . .
C40 C 0.46648(15) 0.59431(9) 0.25270(16) 0.0131(5) Uani 1 1 d . . . . .
C39 C 0.52551(14) 0.55563(9) 0.24946(16) 0.0123(5) Uani 1 1 d . . . . .
C2 C 0.61402(15) 0.71279(9) 0.16749(16) 0.0138(5) Uani 1 1 d . . . . .
C80 C 0.99937(14) 0.48466(9) 0.21619(15) 0.0106(5) Uani 1 1 d . . . . .
C20 C 0.83892(14) 0.67630(8) 0.27279(16) 0.0128(5) Uani 1 1 d . . . . .
C10 C 0.66399(14) 0.74752(8) 0.29529(15) 0.0102(5) Uani 1 1 d . . . . .
C69 C 0.69566(15) 0.45909(8) 0.40231(16) 0.0113(5) Uani 1 1 d . . . . .
C9 C 0.67476(14) 0.74228(8) 0.38601(16) 0.0112(5) Uani 1 1 d . . . . .
C68 C 0.61991(15) 0.47386(9) 0.43381(16) 0.0141(5) Uani 1 1 d . . . . .
H68 H 0.5784 0.4900 0.3978 0.017 Uiso 1 1 calc R U . . .
C70 C 0.75561(15) 0.43373(8) 0.45749(16) 0.0122(5) Uani 1 1 d . . . . .
C59 C 0.65978(15) 0.43364(9) 0.13002(16) 0.0130(5) Uani 1 1 d . . . . .
C29 C 0.78680(15) 0.55855(8) 0.44423(16) 0.0118(5) Uani 1 1 d . . . . .
C38 C 0.49922(15) 0.51303(9) 0.21169(17) 0.0167(5) Uani 1 1 d . . . . .
H38 H 0.5370 0.4864 0.2133 0.020 Uiso 1 1 calc R U . . .
C77 C 1.02830(16) 0.58398(9) 0.22256(17) 0.0173(5) Uani 1 1 d . . . . .
H77 H 1.0384 0.6175 0.2268 0.021 Uiso 1 1 calc R U . . .
C72 C 1.04370(15) 0.40684(9) 0.19372(18) 0.0174(6) Uani 1 1 d . . . . .
C52 C 0.63561(16) 0.34371(9) 0.29264(17) 0.0169(5) Uani 1 1 d . . . . .
C30 C 0.73239(15) 0.56843(8) 0.51056(16) 0.0124(5) Uani 1 1 d . . . . .
C19 C 0.79406(15) 0.65042(9) 0.20553(16) 0.0127(5) Uani 1 1 d . . . . .
C60 C 0.62462(15) 0.39479(9) 0.17572(17) 0.0142(5) Uani 1 1 d . . . . .
C22 C 0.60375(15) 0.60008(9) 0.54861(16) 0.0141(5) Uani 1 1 d . . . . .
C14 C 0.95374(16) 0.72819(9) 0.32577(19) 0.0206(6) Uani 1 1 d . . . . .
H14 H 1.0006 0.7487 0.3175 0.025 Uiso 1 1 calc R U . . .
C3 C 0.62971(16) 0.75621(9) 0.12425(16) 0.0160(5) Uani 1 1 d . . . . .
H3 H 0.6137 0.7590 0.0655 0.019 Uiso 1 1 calc R U . . .
C12 C 0.85834(15) 0.69069(9) 0.41802(17) 0.0150(5) Uani 1 1 d . . . . .
C76 C 1.08764(16) 0.55480(9) 0.18927(16) 0.0165(5) Uani 1 1 d . . . . .
H76 H 1.1381 0.5682 0.1694 0.020 Uiso 1 1 calc R U . . .
C15 C 0.90848(15) 0.70647(9) 0.25512(18) 0.0167(5) Uani 1 1 d . . . . .
C49 C 0.83875(15) 0.30721(9) 0.22966(18) 0.0160(5) Uani 1 1 d . . . . .
C5 C 0.68561(15) 0.79088(9) 0.25578(16) 0.0130(5) Uani 1 1 d . . . . .
C28 C 0.86448(15) 0.53675(9) 0.46465(17) 0.0158(5) Uani 1 1 d . . . . .
H28 H 0.9024 0.5312 0.4216 0.019 Uiso 1 1 calc R U . . .
C4 C 0.66764(16) 0.79377(9) 0.16707(17) 0.0169(5) Uani 1 1 d . . . . .
H4 H 0.6820 0.8219 0.1374 0.020 Uiso 1 1 calc R U . . .
C75 C 1.07361(15) 0.50459(9) 0.18449(16) 0.0135(5) Uani 1 1 d . . . . .
C18 C 0.81659(16) 0.65788(9) 0.12378(17) 0.0174(5) Uani 1 1 d . . . . .
H18 H 0.7861 0.6418 0.0782 0.021 Uiso 1 1 calc R U . . .
C1 C 0.57601(17) 0.67090(9) 0.11871(17) 0.0196(6) Uani 1 1 d . . . . .
H1A H 0.6049 0.6414 0.1382 0.029 Uiso 1 1 calc R U . . .
H1B H 0.5832 0.6754 0.0582 0.029 Uiso 1 1 calc R U . . .
H1C H 0.5152 0.6686 0.1278 0.029 Uiso 1 1 calc R U . . .
C48 C 0.83282(17) 0.25830(9) 0.2471(2) 0.0233(6) Uani 1 1 d . . . . .
H48 H 0.8337 0.2478 0.3042 0.028 Uiso 1 1 calc R U . . .
C32 C 0.43689(16) 0.67054(9) 0.30229(19) 0.0200(6) Uani 1 1 d . . . . .
C73 C 1.11564(16) 0.42441(9) 0.15429(18) 0.0195(6) Uani 1 1 d . . . . .
H73 H 1.1537 0.4025 0.1308 0.023 Uiso 1 1 calc R U . . .
C67 C 0.60404(16) 0.46507(9) 0.51903(17) 0.0179(6) Uani 1 1 d . . . . .
H67 H 0.5515 0.4753 0.5391 0.022 Uiso 1 1 calc R U . . .
C13 C 0.93000(16) 0.71963(9) 0.40551(18) 0.0191(6) Uani 1 1 d . . . . .
H13 H 0.9618 0.7332 0.4529 0.023 Uiso 1 1 calc R U . . .
C23 C 0.61900(18) 0.58173(9) 0.63191(17) 0.0202(6) Uani 1 1 d . . . . .
H23 H 0.5770 0.5851 0.6718 0.024 Uiso 1 1 calc R U . . .
C61 C 0.96841(16) 0.37920(10) 0.43750(18) 0.0210(6) Uani 1 1 d . . . . .
H61A H 0.9612 0.3456 0.4201 0.031 Uiso 1 1 calc R U . . .
H61B H 1.0164 0.3818 0.4803 0.031 Uiso 1 1 calc R U . . .
H61C H 0.9798 0.3988 0.3882 0.031 Uiso 1 1 calc R U . . .
C62 C 0.88861(16) 0.39652(9) 0.47416(17) 0.0155(5) Uani 1 1 d . . . . .
C11 C 0.83174(16) 0.68223(9) 0.50611(17) 0.0179(6) Uani 1 1 d . . . . .
H11A H 0.7706 0.6887 0.5077 0.027 Uiso 1 1 calc R U . . .
H11B H 0.8639 0.7036 0.5457 0.027 Uiso 1 1 calc R U . . .
H11C H 0.8434 0.6488 0.5223 0.027 Uiso 1 1 calc R U . . .
C16 C 0.92968(17) 0.71263(10) 0.17056(19) 0.0233(6) Uani 1 1 d . . . . .
H16 H 0.9753 0.7332 0.1582 0.028 Uiso 1 1 calc R U . . .
C24 C 0.69440(18) 0.55926(9) 0.65444(17) 0.0208(6) Uani 1 1 d . . . . .
H24 H 0.7060 0.5482 0.7108 0.025 Uiso 1 1 calc R U . . .
C58 C 0.61695(16) 0.44823(9) 0.05495(17) 0.0176(6) Uani 1 1 d . . . . .
H58 H 0.6417 0.4722 0.0218 0.021 Uiso 1 1 calc R U . . .
C53 C 0.55356(17) 0.32471(10) 0.26879(19) 0.0240(6) Uani 1 1 d . . . . .
H53 H 0.5296 0.3012 0.3034 0.029 Uiso 1 1 calc R U . . .
C74 C 1.13083(16) 0.47228(10) 0.14973(17) 0.0182(6) Uani 1 1 d . . . . .
H74 H 1.1793 0.4839 0.1235 0.022 Uiso 1 1 calc R U . . .
C37 C 0.41706(16) 0.50847(10) 0.17075(17) 0.0207(6) Uani 1 1 d . . . . .
H37 H 0.4000 0.4789 0.1452 0.025 Uiso 1 1 calc R U . . .
C50 C 0.83625(16) 0.32106(9) 0.14207(17) 0.0175(6) Uani 1 1 d . . . . .
C55 C 0.54348(16) 0.37600(9) 0.14697(18) 0.0185(6) Uani 1 1 d . . . . .
C42 C 0.85181(18) 0.38424(10) 0.04814(18) 0.0244(6) Uani 1 1 d . . . . .
C21 C 0.52507(16) 0.62931(9) 0.52612(17) 0.0176(6) Uani 1 1 d . . . . .
H21A H 0.5390 0.6635 0.5310 0.026 Uiso 1 1 calc R U . . .
H21B H 0.4812 0.6214 0.5649 0.026 Uiso 1 1 calc R U . . .
H21C H 0.5037 0.6221 0.4678 0.026 Uiso 1 1 calc R U . . .
C27 C 0.88787(16) 0.52277(9) 0.54809(18) 0.0197(6) Uani 1 1 d . . . . .
H27 H 0.9417 0.5080 0.5606 0.024 Uiso 1 1 calc R U . . .
C25 C 0.75503(16) 0.55257(9) 0.59395(17) 0.0167(5) Uani 1 1 d . . . . .
C56 C 0.50021(17) 0.39401(10) 0.07265(18) 0.0228(6) Uani 1 1 d . . . . .
H56 H 0.4452 0.3822 0.0548 0.027 Uiso 1 1 calc R U . . .
C41 C 0.86304(19) 0.43641(10) 0.03116(19) 0.0266(7) Uani 1 1 d . . . . .
H41A H 0.8125 0.4486 -0.0018 0.040 Uiso 1 1 calc R U . . .
H41B H 0.9135 0.4411 -0.0009 0.040 Uiso 1 1 calc R U . . .
H41C H 0.8705 0.4538 0.0850 0.040 Uiso 1 1 calc R U . . .
C54 C 0.50928(17) 0.33979(10) 0.19744(19) 0.0236(6) Uani 1 1 d . . . . .
H54 H 0.4553 0.3261 0.1811 0.028 Uiso 1 1 calc R U . . .
C51 C 0.68179(17) 0.32578(9) 0.37274(18) 0.0209(6) Uani 1 1 d . . . . .
H51A H 0.7433 0.3296 0.3690 0.031 Uiso 1 1 calc R U . . .
H51B H 0.6685 0.2918 0.3805 0.031 Uiso 1 1 calc R U . . .
H51C H 0.6637 0.3442 0.4210 0.031 Uiso 1 1 calc R U . . .
C57 C 0.53747(17) 0.42839(10) 0.02636(18) 0.0220(6) Uani 1 1 d . . . . .
H57 H 0.5097 0.4391 -0.0255 0.026 Uiso 1 1 calc R U . . .
C7 C 0.72972(15) 0.82400(9) 0.39188(17) 0.0172(5) Uani 1 1 d . . . . .
H7 H 0.7520 0.8500 0.4254 0.021 Uiso 1 1 calc R U . . .
C36 C 0.36172(16) 0.54642(11) 0.16759(18) 0.0227(6) Uani 1 1 d . . . . .
H36 H 0.3072 0.5434 0.1382 0.027 Uiso 1 1 calc R U . . .
C17 C 0.88440(17) 0.68902(10) 0.10685(18) 0.0222(6) Uani 1 1 d . . . . .
H17 H 0.8986 0.6935 0.0501 0.027 Uiso 1 1 calc R U . . .
C35 C 0.38540(15) 0.58999(10) 0.20785(17) 0.0184(6) Uani 1 1 d . . . . .
C45 C 0.83275(18) 0.28623(10) 0.0771(2) 0.0264(7) Uani 1 1 d . . . . .
C8 C 0.70782(15) 0.78107(9) 0.43215(16) 0.0140(5) Uani 1 1 d . . . . .
H8 H 0.7159 0.7787 0.4920 0.017 Uiso 1 1 calc R U . . .
C26 C 0.83502(17) 0.52984(10) 0.61199(17) 0.0211(6) Uani 1 1 d . . . . .
H26 H 0.8517 0.5196 0.6680 0.025 Uiso 1 1 calc R U . . .
C6 C 0.71973(15) 0.82923(9) 0.30600(17) 0.0165(5) Uani 1 1 d . . . . .
H6 H 0.7355 0.8583 0.2802 0.020 Uiso 1 1 calc R U . . .
C63 C 0.87821(17) 0.38954(9) 0.56155(18) 0.0207(6) Uani 1 1 d . . . . .
H63 H 0.9225 0.3751 0.5967 0.025 Uiso 1 1 calc R U . . .
C47 C 0.82558(17) 0.22427(10) 0.1811(2) 0.0279(7) Uani 1 1 d . . . . .
H47 H 0.8204 0.1913 0.1951 0.033 Uiso 1 1 calc R U . . .
C66 C 0.66203(17) 0.44234(9) 0.57364(17) 0.0192(6) Uani 1 1 d . . . . .
H66 H 0.6505 0.4375 0.6311 0.023 Uiso 1 1 calc R U . . .
C31 C 0.45662(18) 0.71254(10) 0.3592(2) 0.0288(7) Uani 1 1 d . . . . .
H31A H 0.4119 0.7159 0.3989 0.043 Uiso 1 1 calc R U . . .
H31B H 0.4592 0.7417 0.3251 0.043 Uiso 1 1 calc R U . . .
H31C H 0.5117 0.7075 0.3910 0.043 Uiso 1 1 calc R U . . .
C71 C 1.03512(17) 0.35351(9) 0.2045(2) 0.0268(7) Uani 1 1 d . . . . .
H71A H 0.9929 0.3468 0.2456 0.040 Uiso 1 1 calc R U . . .
H71B H 1.0903 0.3400 0.2250 0.040 Uiso 1 1 calc R U . . .
H71C H 1.0166 0.3390 0.1499 0.040 Uiso 1 1 calc R U . . .
C46 C 0.82570(19) 0.23691(10) 0.0983(2) 0.0310(7) Uani 1 1 d . . . . .
H46 H 0.8211 0.2132 0.0552 0.037 Uiso 1 1 calc R U . . .
C64 C 0.80465(17) 0.40362(9) 0.59513(17) 0.0206(6) Uani 1 1 d . . . . .
H64 H 0.7972 0.3983 0.6534 0.025 Uiso 1 1 calc R U . . .
C65 C 0.73955(16) 0.42608(9) 0.54334(17) 0.0167(5) Uani 1 1 d . . . . .
C33 C 0.35774(17) 0.67013(11) 0.2532(2) 0.0288(7) Uani 1 1 d . . . . .
H33 H 0.3221 0.6976 0.2524 0.035 Uiso 1 1 calc R U . . .
C34 C 0.33267(17) 0.63106(11) 0.2077(2) 0.0277(7) Uani 1 1 d . . . . .
H34 H 0.2794 0.6312 0.1755 0.033 Uiso 1 1 calc R U . . .
C44 C 0.8419(2) 0.30325(12) -0.0057(2) 0.0406(9) Uani 1 1 d . . . . .
H44 H 0.8403 0.2814 -0.0518 0.049 Uiso 1 1 calc R U . . .
C43 C 0.8530(2) 0.35086(12) -0.0198(2) 0.0391(8) Uani 1 1 d . . . . .
H43 H 0.8616 0.3619 -0.0753 0.047 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O5 2.2400(17) . ?
Dy1 O6 2.2895(16) . ?
Dy1 O8 2.3171(16) . ?
Dy1 O7 2.3965(16) . ?
Dy1 N7 2.544(2) . ?
Dy1 N6 2.579(2) . ?
Dy1 N5 2.584(2) . ?
Dy1 N8 2.777(2) . ?
Dy1 Dy2 3.50647(19) . ?
Dy2 O7 2.3025(16) . ?
Dy2 O3 2.3113(17) . ?
Dy2 O8 2.3123(15) . ?
Dy2 O4 2.3209(15) . ?
Dy2 O2 2.4289(16) . ?
Dy2 O9 2.4344(17) . ?
Dy2 O10 2.4460(18) . ?
Dy2 O6 2.4559(16) . ?
Dy2 N9 2.856(2) . ?
Dy2 Dy3 3.50461(18) . ?
Dy3 O1 2.2477(16) . ?
Dy3 O2 2.3073(16) . ?
Dy3 O4 2.3447(16) . ?
Dy3 O3 2.3572(16) . ?
Dy3 N3 2.561(2) . ?
Dy3 N1 2.576(2) . ?
Dy3 N2 2.6057(19) . ?
Dy3 N4 2.692(2) . ?
O8 C79 1.338(3) . ?
O4 C39 1.339(3) . ?
O7 C69 1.329(3) . ?
O3 C29 1.335(3) . ?
O1 C9 1.329(3) . ?
O2 C19 1.344(3) . ?
O6 C59 1.345(3) . ?
O10 N9 1.270(3) . ?
O9 N9 1.279(3) . ?
O5 C49 1.314(3) . ?
N1 C2 1.328(3) . ?
N1 C10 1.379(3) . ?
N8 C72 1.334(3) . ?
N8 C80 1.382(3) . ?
N2 C12 1.335(3) . ?
N2 C20 1.374(3) . ?
N4 C32 1.331(3) . ?
N4 C40 1.385(3) . ?
N3 C22 1.328(3) . ?
N3 C30 1.382(3) . ?
N6 C52 1.332(3) . ?
N6 C60 1.383(3) . ?
N9 O11 1.227(3) . ?
N7 C62 1.326(3) . ?
N7 C70 1.386(3) . ?
C79 C78 1.382(3) . ?
C79 C80 1.420(3) . ?
C78 C77 1.410(3) . ?
C78 H78 0.9500 . ?
N5 C42 1.325(4) . ?
N5 C50 1.380(3) . ?
C40 C35 1.420(3) . ?
C40 C39 1.427(3) . ?
C39 C38 1.380(4) . ?
C2 C3 1.422(3) . ?
C2 C1 1.501(4) . ?
C80 C75 1.417(3) . ?
C20 C15 1.424(3) . ?
C20 C19 1.431(4) . ?
C10 C5 1.414(3) . ?
C10 C9 1.442(3) . ?
C69 C68 1.386(3) . ?
C69 C70 1.427(3) . ?
C9 C8 1.386(3) . ?
C68 C67 1.411(4) . ?
C68 H68 0.9500 . ?
C70 C65 1.416(4) . ?
C59 C58 1.385(4) . ?
C59 C60 1.435(4) . ?
C29 C28 1.382(3) . ?
C29 C30 1.428(3) . ?
C38 C37 1.410(4) . ?
C38 H38 0.9500 . ?
C77 C76 1.371(4) . ?
C77 H77 0.9500 . ?
C72 C73 1.418(4) . ?
C72 C71 1.504(4) . ?
C52 C53 1.421(4) . ?
C52 C51 1.502(4) . ?
C30 C25 1.414(4) . ?
C19 C18 1.382(4) . ?
C60 C55 1.424(3) . ?
C22 C23 1.419(4) . ?
C22 C21 1.503(3) . ?
C14 C13 1.363(4) . ?
C14 C15 1.418(4) . ?
C14 H14 0.9500 . ?
C3 C4 1.362(4) . ?
C3 H3 0.9500 . ?
C12 C13 1.412(3) . ?
C12 C11 1.503(4) . ?
C76 C75 1.419(4) . ?
C76 H76 0.9500 . ?
C15 C16 1.413(4) . ?
C49 C48 1.396(4) . ?
C49 C50 1.437(4) . ?
C5 C4 1.415(4) . ?
C5 C6 1.416(3) . ?
C28 C27 1.401(4) . ?
C28 H28 0.9500 . ?
C4 H4 0.9500 . ?
C75 C74 1.412(3) . ?
C18 C17 1.416(4) . ?
C18 H18 0.9500 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C48 C47 1.410(4) . ?
C48 H48 0.9500 . ?
C32 C33 1.420(4) . ?
C32 C31 1.497(4) . ?
C73 C74 1.359(4) . ?
C73 H73 0.9500 . ?
C67 C66 1.367(4) . ?
C67 H67 0.9500 . ?
C13 H13 0.9500 . ?
C23 C24 1.366(4) . ?
C23 H23 0.9500 . ?
C61 C62 1.500(4) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 C63 1.418(4) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C16 C17 1.363(4) . ?
C16 H16 0.9500 . ?
C24 C25 1.411(4) . ?
C24 H24 0.9500 . ?
C58 C57 1.412(4) . ?
C58 H58 0.9500 . ?
C53 C54 1.351(4) . ?
C53 H53 0.9500 . ?
C74 H74 0.9500 . ?
C37 C36 1.369(4) . ?
C37 H37 0.9500 . ?
C50 C45 1.413(4) . ?
C55 C56 1.409(4) . ?
C55 C54 1.417(4) . ?
C42 C43 1.424(4) . ?
C42 C41 1.493(4) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C27 C26 1.368(4) . ?
C27 H27 0.9500 . ?
C25 C26 1.420(4) . ?
C56 C57 1.364(4) . ?
C56 H56 0.9500 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C54 H54 0.9500 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C57 H57 0.9500 . ?
C7 C6 1.365(4) . ?
C7 C8 1.411(4) . ?
C7 H7 0.9500 . ?
C36 C35 1.410(4) . ?
C36 H36 0.9500 . ?
C17 H17 0.9500 . ?
C35 C34 1.414(4) . ?
C45 C44 1.412(5) . ?
C45 C46 1.422(4) . ?
C8 H8 0.9500 . ?
C26 H26 0.9500 . ?
C6 H6 0.9500 . ?
C63 C64 1.365(4) . ?
C63 H63 0.9500 . ?
C47 C46 1.358(5) . ?
C47 H47 0.9500 . ?
C66 C65 1.416(4) . ?
C66 H66 0.9500 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C46 H46 0.9500 . ?
C64 C65 1.412(4) . ?
C64 H64 0.9500 . ?
C33 C34 1.350(4) . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?
C44 C43 1.360(5) . ?
C44 H44 0.9500 . ?
C43 H43 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 O6 133.32(6) . . ?
O5 Dy1 O8 148.47(6) . . ?
O6 Dy1 O8 74.80(6) . . ?
O5 Dy1 O7 129.11(6) . . ?
O6 Dy1 O7 67.48(6) . . ?
O8 Dy1 O7 69.29(5) . . ?
O5 Dy1 N7 79.55(6) . . ?
O6 Dy1 N7 133.51(6) . . ?
O8 Dy1 N7 88.77(6) . . ?
O7 Dy1 N7 66.03(6) . . ?
O5 Dy1 N6 77.57(6) . . ?
O6 Dy1 N6 68.90(6) . . ?
O8 Dy1 N6 133.02(6) . . ?
O7 Dy1 N6 69.85(6) . . ?
N7 Dy1 N6 95.10(6) . . ?
O5 Dy1 N5 67.03(7) . . ?
O6 Dy1 N5 77.29(6) . . ?
O8 Dy1 N5 117.06(6) . . ?
O7 Dy1 N5 141.24(6) . . ?
N7 Dy1 N5 146.18(6) . . ?
N6 Dy1 N5 83.06(6) . . ?
O5 Dy1 N8 91.25(6) . . ?
O6 Dy1 N8 106.39(6) . . ?
O8 Dy1 N8 63.08(6) . . ?
O7 Dy1 N8 131.57(6) . . ?
N7 Dy1 N8 103.84(6) . . ?
N6 Dy1 N8 155.94(6) . . ?
N5 Dy1 N8 72.94(6) . . ?
O5 Dy1 Dy2 168.76(4) . . ?
O6 Dy1 Dy2 44.23(4) . . ?
O8 Dy1 Dy2 40.71(4) . . ?
O7 Dy1 Dy2 40.72(4) . . ?
N7 Dy1 Dy2 96.45(4) . . ?
N6 Dy1 Dy2 92.44(4) . . ?
N5 Dy1 Dy2 117.35(5) . . ?
N8 Dy1 Dy2 99.92(4) . . ?
O7 Dy2 O3 82.25(6) . . ?
O7 Dy2 O8 71.02(6) . . ?
O3 Dy2 O8 84.71(6) . . ?
O7 Dy2 O4 87.61(6) . . ?
O3 Dy2 O4 70.99(6) . . ?
O8 Dy2 O4 149.71(6) . . ?
O7 Dy2 O2 147.04(6) . . ?
O3 Dy2 O2 67.07(6) . . ?
O8 Dy2 O2 115.71(5) . . ?
O4 Dy2 O2 71.65(5) . . ?
O7 Dy2 O9 129.16(6) . . ?
O3 Dy2 O9 137.05(6) . . ?
O8 Dy2 O9 129.23(6) . . ?
O4 Dy2 O9 80.89(6) . . ?
O2 Dy2 O9 73.68(6) . . ?
O7 Dy2 O10 135.46(6) . . ?
O3 Dy2 O10 128.52(6) . . ?
O8 Dy2 O10 79.95(6) . . ?
O4 Dy2 O10 129.36(6) . . ?
O2 Dy2 O10 76.20(6) . . ?
O9 Dy2 O10 52.73(6) . . ?
O7 Dy2 O6 66.27(6) . . ?
O3 Dy2 O6 145.25(6) . . ?
O8 Dy2 O6 71.79(5) . . ?
O4 Dy2 O6 119.60(5) . . ?
O2 Dy2 O6 146.39(5) . . ?
O9 Dy2 O6 77.09(6) . . ?
O10 Dy2 O6 73.02(6) . . ?
O7 Dy2 N9 137.90(6) . . ?
O3 Dy2 N9 139.81(6) . . ?
O8 Dy2 N9 104.47(6) . . ?
O4 Dy2 N9 105.75(6) . . ?
O2 Dy2 N9 73.88(6) . . ?
O9 Dy2 N9 26.46(6) . . ?
O10 Dy2 N9 26.29(6) . . ?
O6 Dy2 N9 72.55(6) . . ?
O7 Dy2 Dy3 107.23(4) . . ?
O3 Dy2 Dy3 41.85(4) . . ?
O8 Dy2 Dy3 124.18(4) . . ?
O4 Dy2 Dy3 41.57(4) . . ?
O2 Dy2 Dy3 40.95(4) . . ?
O9 Dy2 Dy3 96.12(4) . . ?
O10 Dy2 Dy3 117.01(4) . . ?
O6 Dy2 Dy3 161.16(4) . . ?
N9 Dy2 Dy3 108.93(4) . . ?
O7 Dy2 Dy1 42.77(4) . . ?
O3 Dy2 Dy1 105.67(4) . . ?
O8 Dy2 Dy1 40.81(4) . . ?
O4 Dy2 Dy1 128.80(4) . . ?
O2 Dy2 Dy1 156.42(4) . . ?
O9 Dy2 Dy1 117.26(4) . . ?
O10 Dy2 Dy1 93.75(4) . . ?
O6 Dy2 Dy1 40.56(4) . . ?
N9 Dy2 Dy1 106.30(4) . . ?
Dy3 Dy2 Dy1 144.639(5) . . ?
O1 Dy3 O2 129.33(6) . . ?
O1 Dy3 O4 153.58(6) . . ?
O2 Dy3 O4 73.44(6) . . ?
O1 Dy3 O3 127.18(6) . . ?
O2 Dy3 O3 68.36(6) . . ?
O4 Dy3 O3 69.78(5) . . ?
O1 Dy3 N3 82.86(6) . . ?
O2 Dy3 N3 134.49(6) . . ?
O4 Dy3 N3 88.01(6) . . ?
O3 Dy3 N3 66.25(6) . . ?
O1 Dy3 N1 67.62(6) . . ?
O2 Dy3 N1 74.98(6) . . ?
O4 Dy3 N1 114.18(6) . . ?
O3 Dy3 N1 140.20(6) . . ?
N3 Dy3 N1 148.98(6) . . ?
O1 Dy3 N2 74.19(6) . . ?
O2 Dy3 N2 66.88(6) . . ?
O4 Dy3 N2 132.07(6) . . ?
O3 Dy3 N2 71.33(6) . . ?
N3 Dy3 N2 100.97(6) . . ?
N1 Dy3 N2 80.60(6) . . ?
O1 Dy3 N4 92.49(6) . . ?
O2 Dy3 N4 108.70(6) . . ?
O4 Dy3 N4 64.54(6) . . ?
O3 Dy3 N4 132.52(6) . . ?
N3 Dy3 N4 99.32(6) . . ?
N1 Dy3 N4 73.65(6) . . ?
N2 Dy3 N4 154.01(6) . . ?
O1 Dy3 Dy2 164.63(4) . . ?
O2 Dy3 Dy2 43.63(4) . . ?
O4 Dy3 Dy2 41.05(4) . . ?
O3 Dy3 Dy2 40.86(4) . . ?
N3 Dy3 Dy2 96.22(4) . . ?
N1 Dy3 Dy2 114.78(4) . . ?
N2 Dy3 Dy2 91.02(4) . . ?
N4 Dy3 Dy2 102.77(4) . . ?
C79 O8 Dy2 123.88(14) . . ?
C79 O8 Dy1 129.33(14) . . ?
Dy2 O8 Dy1 98.48(6) . . ?
C39 O4 Dy2 127.84(15) . . ?
C39 O4 Dy3 126.35(15) . . ?
Dy2 O4 Dy3 97.38(6) . . ?
C69 O7 Dy2 137.78(14) . . ?
C69 O7 Dy1 119.03(14) . . ?
Dy2 O7 Dy1 96.51(6) . . ?
C29 O3 Dy2 137.07(14) . . ?
C29 O3 Dy3 119.36(14) . . ?
Dy2 O3 Dy3 97.29(6) . . ?
C9 O1 Dy3 118.36(14) . . ?
C19 O2 Dy3 118.55(15) . . ?
C19 O2 Dy2 131.79(14) . . ?
Dy3 O2 Dy2 95.42(6) . . ?
C59 O6 Dy1 119.61(14) . . ?
C59 O6 Dy2 123.74(14) . . ?
Dy1 O6 Dy2 95.21(6) . . ?
N9 O10 Dy2 95.17(13) . . ?
N9 O9 Dy2 95.48(13) . . ?
C49 O5 Dy1 122.21(16) . . ?
C2 N1 C10 118.7(2) . . ?
C2 N1 Dy3 131.24(16) . . ?
C10 N1 Dy3 107.63(15) . . ?
C72 N8 C80 116.9(2) . . ?
C72 N8 Dy1 130.85(16) . . ?
C80 N8 Dy1 111.19(14) . . ?
C12 N2 C20 118.9(2) . . ?
C12 N2 Dy3 130.56(17) . . ?
C20 N2 Dy3 109.12(15) . . ?
C32 N4 C40 117.7(2) . . ?
C32 N4 Dy3 128.79(17) . . ?
C40 N4 Dy3 112.00(14) . . ?
C22 N3 C30 118.2(2) . . ?
C22 N3 Dy3 128.75(16) . . ?
C30 N3 Dy3 112.11(15) . . ?
C52 N6 C60 118.5(2) . . ?
C52 N6 Dy1 131.44(17) . . ?
C60 N6 Dy1 110.07(15) . . ?
O11 N9 O10 122.2(2) . . ?
O11 N9 O9 121.2(2) . . ?
O10 N9 O9 116.5(2) . . ?
O11 N9 Dy2 177.66(18) . . ?
O10 N9 Dy2 58.54(12) . . ?
O9 N9 Dy2 58.05(12) . . ?
C62 N7 C70 118.7(2) . . ?
C62 N7 Dy1 126.89(17) . . ?
C70 N7 Dy1 113.17(15) . . ?
O8 C79 C78 122.1(2) . . ?
O8 C79 C80 118.3(2) . . ?
C78 C79 C80 119.7(2) . . ?
C79 C78 C77 120.7(2) . . ?
C79 C78 H78 119.6 . . ?
C77 C78 H78 119.6 . . ?
C42 N5 C50 118.9(2) . . ?
C42 N5 Dy1 130.65(18) . . ?
C50 N5 Dy1 110.15(16) . . ?
N4 C40 C35 123.5(2) . . ?
N4 C40 C39 117.8(2) . . ?
C35 C40 C39 118.8(2) . . ?
O4 C39 C38 122.6(2) . . ?
O4 C39 C40 118.0(2) . . ?
C38 C39 C40 119.4(2) . . ?
N1 C2 C3 121.5(2) . . ?
N1 C2 C1 119.0(2) . . ?
C3 C2 C1 119.5(2) . . ?
N8 C80 C75 123.7(2) . . ?
N8 C80 C79 117.4(2) . . ?
C75 C80 C79 118.9(2) . . ?
N2 C20 C15 122.5(2) . . ?
N2 C20 C19 117.7(2) . . ?
C15 C20 C19 119.8(2) . . ?
N1 C10 C5 122.6(2) . . ?
N1 C10 C9 116.5(2) . . ?
C5 C10 C9 120.8(2) . . ?
O7 C69 C68 123.2(2) . . ?
O7 C69 C70 118.5(2) . . ?
C68 C69 C70 118.3(2) . . ?
O1 C9 C8 123.9(2) . . ?
O1 C9 C10 118.8(2) . . ?
C8 C9 C10 117.3(2) . . ?
C69 C68 C67 120.5(2) . . ?
C69 C68 H68 119.8 . . ?
C67 C68 H68 119.8 . . ?
N7 C70 C65 122.4(2) . . ?
N7 C70 C69 117.1(2) . . ?
C65 C70 C69 120.5(2) . . ?
O6 C59 C58 122.0(2) . . ?
O6 C59 C60 119.7(2) . . ?
C58 C59 C60 118.2(2) . . ?
O3 C29 C28 123.2(2) . . ?
O3 C29 C30 118.2(2) . . ?
C28 C29 C30 118.6(2) . . ?
C39 C38 C37 120.9(2) . . ?
C39 C38 H38 119.6 . . ?
C37 C38 H38 119.6 . . ?
C76 C77 C78 120.5(2) . . ?
C76 C77 H77 119.7 . . ?
C78 C77 H77 119.7 . . ?
N8 C72 C73 122.1(2) . . ?
N8 C72 C71 119.7(2) . . ?
C73 C72 C71 118.2(2) . . ?
N6 C52 C53 121.5(3) . . ?
N6 C52 C51 120.0(2) . . ?
C53 C52 C51 118.4(2) . . ?
N3 C30 C25 122.6(2) . . ?
N3 C30 C29 117.3(2) . . ?
C25 C30 C29 120.1(2) . . ?
O2 C19 C18 122.8(2) . . ?
O2 C19 C20 118.8(2) . . ?
C18 C19 C20 118.4(2) . . ?
N6 C60 C55 122.6(2) . . ?
N6 C60 C59 118.4(2) . . ?
C55 C60 C59 119.0(2) . . ?
N3 C22 C23 122.2(2) . . ?
N3 C22 C21 117.9(2) . . ?
C23 C22 C21 119.8(2) . . ?
C13 C14 C15 120.0(2) . . ?
C13 C14 H14 120.0 . . ?
C15 C14 H14 120.0 . . ?
C4 C3 C2 120.0(2) . . ?
C4 C3 H3 120.0 . . ?
C2 C3 H3 120.0 . . ?
N2 C12 C13 121.6(2) . . ?
N2 C12 C11 118.5(2) . . ?
C13 C12 C11 119.8(2) . . ?
C77 C76 C75 119.9(2) . . ?
C77 C76 H76 120.0 . . ?
C75 C76 H76 120.0 . . ?
C16 C15 C14 123.8(2) . . ?
C16 C15 C20 119.6(2) . . ?
C14 C15 C20 116.6(2) . . ?
O5 C49 C48 123.9(3) . . ?
O5 C49 C50 118.9(2) . . ?
C48 C49 C50 117.1(2) . . ?
C10 C5 C4 116.8(2) . . ?
C10 C5 C6 119.4(2) . . ?
C4 C5 C6 123.7(2) . . ?
C29 C28 C27 120.8(2) . . ?
C29 C28 H28 119.6 . . ?
C27 C28 H28 119.6 . . ?
C3 C4 C5 120.0(2) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C74 C75 C80 116.8(2) . . ?
C74 C75 C76 123.3(2) . . ?
C80 C75 C76 119.8(2) . . ?
C19 C18 C17 121.1(3) . . ?
C19 C18 H18 119.5 . . ?
C17 C18 H18 119.5 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C49 C48 C47 121.0(3) . . ?
C49 C48 H48 119.5 . . ?
C47 C48 H48 119.5 . . ?
N4 C32 C33 121.5(3) . . ?
N4 C32 C31 120.3(2) . . ?
C33 C32 C31 118.2(2) . . ?
C74 C73 C72 120.8(2) . . ?
C74 C73 H73 119.6 . . ?
C72 C73 H73 119.6 . . ?
C66 C67 C68 122.0(2) . . ?
C66 C67 H67 119.0 . . ?
C68 C67 H67 119.0 . . ?
C14 C13 C12 120.3(2) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C24 C23 C22 119.6(2) . . ?
C24 C23 H23 120.2 . . ?
C22 C23 H23 120.2 . . ?
C62 C61 H61A 109.5 . . ?
C62 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C62 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
N7 C62 C63 121.8(2) . . ?
N7 C62 C61 118.8(2) . . ?
C63 C62 C61 119.4(2) . . ?
C12 C11 H11A 109.5 . . ?
C12 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C12 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C17 C16 C15 119.8(2) . . ?
C17 C16 H16 120.1 . . ?
C15 C16 H16 120.1 . . ?
C23 C24 C25 120.0(2) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 H24 120.0 . . ?
C59 C58 C57 121.7(3) . . ?
C59 C58 H58 119.1 . . ?
C57 C58 H58 119.1 . . ?
C54 C53 C52 120.7(3) . . ?
C54 C53 H53 119.7 . . ?
C52 C53 H53 119.7 . . ?
C73 C74 C75 119.1(2) . . ?
C73 C74 H74 120.4 . . ?
C75 C74 H74 120.4 . . ?
C36 C37 C38 120.4(2) . . ?
C36 C37 H37 119.8 . . ?
C38 C37 H37 119.8 . . ?
N5 C50 C45 123.0(3) . . ?
N5 C50 C49 115.9(2) . . ?
C45 C50 C49 121.0(2) . . ?
C56 C55 C54 123.0(2) . . ?
C56 C55 C60 120.3(2) . . ?
C54 C55 C60 116.7(3) . . ?
N5 C42 C43 121.0(3) . . ?
N5 C42 C41 119.5(3) . . ?
C43 C42 C41 119.6(3) . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C22 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C26 C27 C28 121.6(2) . . ?
C26 C27 H27 119.2 . . ?
C28 C27 H27 119.2 . . ?
C24 C25 C30 117.1(2) . . ?
C24 C25 C26 123.7(2) . . ?
C30 C25 C26 119.2(2) . . ?
C57 C56 C55 119.9(2) . . ?
C57 C56 H56 120.0 . . ?
C55 C56 H56 120.0 . . ?
C42 C41 H41A 109.5 . . ?
C42 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C42 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C53 C54 C55 120.0(2) . . ?
C53 C54 H54 120.0 . . ?
C55 C54 H54 120.0 . . ?
C52 C51 H51A 109.5 . . ?
C52 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C52 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C56 C57 C58 120.5(3) . . ?
C56 C57 H57 119.8 . . ?
C58 C57 H57 119.8 . . ?
C6 C7 C8 121.7(2) . . ?
C6 C7 H7 119.1 . . ?
C8 C7 H7 119.1 . . ?
C37 C36 C35 120.2(2) . . ?
C37 C36 H36 119.9 . . ?
C35 C36 H36 119.9 . . ?
C16 C17 C18 121.2(3) . . ?
C16 C17 H17 119.4 . . ?
C18 C17 H17 119.4 . . ?
C36 C35 C34 124.2(2) . . ?
C36 C35 C40 119.9(2) . . ?
C34 C35 C40 116.0(3) . . ?
C44 C45 C50 116.4(3) . . ?
C44 C45 C46 124.0(3) . . ?
C50 C45 C46 119.5(3) . . ?
C9 C8 C7 121.3(2) . . ?
C9 C8 H8 119.4 . . ?
C7 C8 H8 119.4 . . ?
C27 C26 C25 119.5(2) . . ?
C27 C26 H26 120.3 . . ?
C25 C26 H26 120.3 . . ?
C7 C6 C5 119.4(2) . . ?
C7 C6 H6 120.3 . . ?
C5 C6 H6 120.3 . . ?
C64 C63 C62 120.0(2) . . ?
C64 C63 H63 120.0 . . ?
C62 C63 H63 120.0 . . ?
C46 C47 C48 122.3(3) . . ?
C46 C47 H47 118.8 . . ?
C48 C47 H47 118.8 . . ?
C67 C66 C65 119.1(2) . . ?
C67 C66 H66 120.5 . . ?
C65 C66 H66 120.5 . . ?
C32 C31 H31A 109.5 . . ?
C32 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C32 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C72 C71 H71A 109.5 . . ?
C72 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C72 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C47 C46 C45 119.0(3) . . ?
C47 C46 H46 120.5 . . ?
C45 C46 H46 120.5 . . ?
C63 C64 C65 120.1(3) . . ?
C63 C64 H64 120.0 . . ?
C65 C64 H64 120.0 . . ?
C64 C65 C70 116.9(2) . . ?
C64 C65 C66 123.5(2) . . ?
C70 C65 C66 119.6(2) . . ?
C34 C33 C32 120.7(3) . . ?
C34 C33 H33 119.7 . . ?
C32 C33 H33 119.7 . . ?
C33 C34 C35 120.3(3) . . ?
C33 C34 H34 119.9 . . ?
C35 C34 H34 119.9 . . ?
C43 C44 C45 120.2(3) . . ?
C43 C44 H44 119.9 . . ?
C45 C44 H44 119.9 . . ?
C44 C43 C42 120.4(3) . . ?
C44 C43 H43 119.8 . . ?
C42 C43 H43 119.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy2 O10 N9 O11 -177.4(2) . . . . ?
Dy2 O10 N9 O9 2.8(2) . . . . ?
Dy2 O9 N9 O11 177.4(2) . . . . ?
Dy2 O9 N9 O10 -2.8(2) . . . . ?
Dy2 O8 C79 C78 38.7(3) . . . . ?
Dy1 O8 C79 C78 179.98(17) . . . . ?
Dy2 O8 C79 C80 -141.77(18) . . . . ?
Dy1 O8 C79 C80 -0.5(3) . . . . ?
O8 C79 C78 C77 -175.7(2) . . . . ?
C80 C79 C78 C77 4.8(4) . . . . ?
C32 N4 C40 C35 -0.1(4) . . . . ?
Dy3 N4 C40 C35 -167.52(19) . . . . ?
C32 N4 C40 C39 179.7(2) . . . . ?
Dy3 N4 C40 C39 12.3(3) . . . . ?
Dy2 O4 C39 C38 36.0(3) . . . . ?
Dy3 O4 C39 C38 176.69(18) . . . . ?
Dy2 O4 C39 C40 -144.25(17) . . . . ?
Dy3 O4 C39 C40 -3.6(3) . . . . ?
N4 C40 C39 O4 -7.2(3) . . . . ?
C35 C40 C39 O4 172.6(2) . . . . ?
N4 C40 C39 C38 172.5(2) . . . . ?
C35 C40 C39 C38 -7.7(4) . . . . ?
C10 N1 C2 C3 2.4(3) . . . . ?
Dy3 N1 C2 C3 -157.60(17) . . . . ?
C10 N1 C2 C1 -177.6(2) . . . . ?
Dy3 N1 C2 C1 22.5(3) . . . . ?
C72 N8 C80 C75 -0.7(4) . . . . ?
Dy1 N8 C80 C75 -170.45(19) . . . . ?
C72 N8 C80 C79 179.4(2) . . . . ?
Dy1 N8 C80 C79 9.7(3) . . . . ?
O8 C79 C80 N8 -7.3(3) . . . . ?
C78 C79 C80 N8 172.2(2) . . . . ?
O8 C79 C80 C75 172.9(2) . . . . ?
C78 C79 C80 C75 -7.6(4) . . . . ?
C12 N2 C20 C15 -4.6(3) . . . . ?
Dy3 N2 C20 C15 163.17(18) . . . . ?
C12 N2 C20 C19 174.4(2) . . . . ?
Dy3 N2 C20 C19 -17.8(2) . . . . ?
C2 N1 C10 C5 -6.0(3) . . . . ?
Dy3 N1 C10 C5 158.30(18) . . . . ?
C2 N1 C10 C9 174.1(2) . . . . ?
Dy3 N1 C10 C9 -21.5(2) . . . . ?
Dy2 O7 C69 C68 58.5(3) . . . . ?
Dy1 O7 C69 C68 -157.88(18) . . . . ?
Dy2 O7 C69 C70 -121.3(2) . . . . ?
Dy1 O7 C69 C70 22.3(3) . . . . ?
Dy3 O1 C9 C8 -151.27(19) . . . . ?
Dy3 O1 C9 C10 29.0(3) . . . . ?
N1 C10 C9 O1 -1.1(3) . . . . ?
C5 C10 C9 O1 179.0(2) . . . . ?
N1 C10 C9 C8 179.1(2) . . . . ?
C5 C10 C9 C8 -0.7(3) . . . . ?
O7 C69 C68 C67 -178.1(2) . . . . ?
C70 C69 C68 C67 1.7(4) . . . . ?
C62 N7 C70 C65 -3.6(3) . . . . ?
Dy1 N7 C70 C65 164.52(19) . . . . ?
C62 N7 C70 C69 175.9(2) . . . . ?
Dy1 N7 C70 C69 -15.9(3) . . . . ?
O7 C69 C70 N7 -2.8(3) . . . . ?
C68 C69 C70 N7 177.4(2) . . . . ?
O7 C69 C70 C65 176.8(2) . . . . ?
C68 C69 C70 C65 -3.1(3) . . . . ?
Dy1 O6 C59 C58 -162.23(19) . . . . ?
Dy2 O6 C59 C58 77.4(3) . . . . ?
Dy1 O6 C59 C60 20.0(3) . . . . ?
Dy2 O6 C59 C60 -100.3(2) . . . . ?
Dy2 O3 C29 C28 60.3(3) . . . . ?
Dy3 O3 C29 C28 -154.76(19) . . . . ?
Dy2 O3 C29 C30 -119.9(2) . . . . ?
Dy3 O3 C29 C30 25.1(3) . . . . ?
O4 C39 C38 C37 -175.4(2) . . . . ?
C40 C39 C38 C37 4.9(4) . . . . ?
C79 C78 C77 C76 -0.3(4) . . . . ?
C80 N8 C72 C73 -5.1(4) . . . . ?
Dy1 N8 C72 C73 162.18(19) . . . . ?
C80 N8 C72 C71 174.7(2) . . . . ?
Dy1 N8 C72 C71 -18.0(4) . . . . ?
C60 N6 C52 C53 1.4(4) . . . . ?
Dy1 N6 C52 C53 -176.07(18) . . . . ?
C60 N6 C52 C51 -176.9(2) . . . . ?
Dy1 N6 C52 C51 5.6(3) . . . . ?
C22 N3 C30 C25 -4.6(3) . . . . ?
Dy3 N3 C30 C25 165.20(19) . . . . ?
C22 N3 C30 C29 175.2(2) . . . . ?
Dy3 N3 C30 C29 -15.0(2) . . . . ?
O3 C29 C30 N3 -4.7(3) . . . . ?
C28 C29 C30 N3 175.1(2) . . . . ?
O3 C29 C30 C25 175.1(2) . . . . ?
C28 C29 C30 C25 -5.1(3) . . . . ?
Dy3 O2 C19 C18 -152.86(19) . . . . ?
Dy2 O2 C19 C18 78.1(3) . . . . ?
Dy3 O2 C19 C20 27.8(3) . . . . ?
Dy2 O2 C19 C20 -101.3(2) . . . . ?
N2 C20 C19 O2 -3.6(3) . . . . ?
C15 C20 C19 O2 175.4(2) . . . . ?
N2 C20 C19 C18 177.0(2) . . . . ?
C15 C20 C19 C18 -3.9(3) . . . . ?
C52 N6 C60 C55 -3.7(4) . . . . ?
Dy1 N6 C60 C55 174.30(19) . . . . ?
C52 N6 C60 C59 175.4(2) . . . . ?
Dy1 N6 C60 C59 -6.6(3) . . . . ?
O6 C59 C60 N6 -7.4(3) . . . . ?
C58 C59 C60 N6 174.7(2) . . . . ?
O6 C59 C60 C55 171.7(2) . . . . ?
C58 C59 C60 C55 -6.1(3) . . . . ?
C30 N3 C22 C23 -0.7(3) . . . . ?
Dy3 N3 C22 C23 -168.62(18) . . . . ?
C30 N3 C22 C21 177.3(2) . . . . ?
Dy3 N3 C22 C21 9.5(3) . . . . ?
N1 C2 C3 C4 3.0(4) . . . . ?
C1 C2 C3 C4 -177.1(2) . . . . ?
C20 N2 C12 C13 2.1(3) . . . . ?
Dy3 N2 C12 C13 -162.61(17) . . . . ?
C20 N2 C12 C11 -177.6(2) . . . . ?
Dy3 N2 C12 C11 17.7(3) . . . . ?
C78 C77 C76 C75 -1.3(4) . . . . ?
C13 C14 C15 C16 -178.8(3) . . . . ?
C13 C14 C15 C20 0.2(4) . . . . ?
N2 C20 C15 C16 -177.6(2) . . . . ?
C19 C20 C15 C16 3.5(4) . . . . ?
N2 C20 C15 C14 3.4(3) . . . . ?
C19 C20 C15 C14 -175.5(2) . . . . ?
Dy1 O5 C49 C48 -160.29(19) . . . . ?
Dy1 O5 C49 C50 22.8(3) . . . . ?
N1 C10 C5 C4 4.2(3) . . . . ?
C9 C10 C5 C4 -176.0(2) . . . . ?
N1 C10 C5 C6 -178.6(2) . . . . ?
C9 C10 C5 C6 1.2(3) . . . . ?
O3 C29 C28 C27 -177.5(2) . . . . ?
C30 C29 C28 C27 2.7(4) . . . . ?
C2 C3 C4 C5 -4.8(4) . . . . ?
C10 C5 C4 C3 1.3(3) . . . . ?
C6 C5 C4 C3 -175.7(2) . . . . ?
N8 C80 C75 C74 5.8(4) . . . . ?
C79 C80 C75 C74 -174.4(2) . . . . ?
N8 C80 C75 C76 -173.8(2) . . . . ?
C79 C80 C75 C76 6.1(4) . . . . ?
C77 C76 C75 C74 178.8(3) . . . . ?
C77 C76 C75 C80 -1.7(4) . . . . ?
O2 C19 C18 C17 -177.1(2) . . . . ?
C20 C19 C18 C17 2.2(4) . . . . ?
O5 C49 C48 C47 -176.4(2) . . . . ?
C50 C49 C48 C47 0.6(4) . . . . ?
C40 N4 C32 C33 -5.2(4) . . . . ?
Dy3 N4 C32 C33 159.7(2) . . . . ?
C40 N4 C32 C31 173.4(2) . . . . ?
Dy3 N4 C32 C31 -21.7(4) . . . . ?
N8 C72 C73 C74 5.8(4) . . . . ?
C71 C72 C73 C74 -174.0(3) . . . . ?
C69 C68 C67 C66 0.6(4) . . . . ?
C15 C14 C13 C12 -2.5(4) . . . . ?
N2 C12 C13 C14 1.4(4) . . . . ?
C11 C12 C13 C14 -178.9(2) . . . . ?
N3 C22 C23 C24 4.4(4) . . . . ?
C21 C22 C23 C24 -173.6(2) . . . . ?
C70 N7 C62 C63 0.8(4) . . . . ?
Dy1 N7 C62 C63 -165.51(18) . . . . ?
C70 N7 C62 C61 -179.8(2) . . . . ?
Dy1 N7 C62 C61 13.8(3) . . . . ?
C14 C15 C16 C17 177.7(3) . . . . ?
C20 C15 C16 C17 -1.2(4) . . . . ?
C22 C23 C24 C25 -2.8(4) . . . . ?
O6 C59 C58 C57 -173.0(2) . . . . ?
C60 C59 C58 C57 4.8(4) . . . . ?
N6 C52 C53 C54 1.4(4) . . . . ?
C51 C52 C53 C54 179.8(3) . . . . ?
C72 C73 C74 C75 -0.3(4) . . . . ?
C80 C75 C74 C73 -5.0(4) . . . . ?
C76 C75 C74 C73 174.5(3) . . . . ?
C39 C38 C37 C36 0.1(4) . . . . ?
C42 N5 C50 C45 -4.7(4) . . . . ?
Dy1 N5 C50 C45 169.6(2) . . . . ?
C42 N5 C50 C49 171.4(2) . . . . ?
Dy1 N5 C50 C49 -14.3(3) . . . . ?
O5 C49 C50 N5 -2.5(3) . . . . ?
C48 C49 C50 N5 -179.7(2) . . . . ?
O5 C49 C50 C45 173.7(2) . . . . ?
C48 C49 C50 C45 -3.4(4) . . . . ?
N6 C60 C55 C56 -178.2(2) . . . . ?
C59 C60 C55 C56 2.7(4) . . . . ?
N6 C60 C55 C54 3.1(4) . . . . ?
C59 C60 C55 C54 -176.1(2) . . . . ?
C50 N5 C42 C43 1.5(4) . . . . ?
Dy1 N5 C42 C43 -171.4(2) . . . . ?
C50 N5 C42 C41 -177.1(2) . . . . ?
Dy1 N5 C42 C41 10.0(4) . . . . ?
C29 C28 C27 C26 0.3(4) . . . . ?
C23 C24 C25 C30 -2.2(4) . . . . ?
C23 C24 C25 C26 179.7(3) . . . . ?
N3 C30 C25 C24 6.1(4) . . . . ?
C29 C30 C25 C24 -173.7(2) . . . . ?
N3 C30 C25 C26 -175.7(2) . . . . ?
C29 C30 C25 C26 4.5(4) . . . . ?
C54 C55 C56 C57 -179.0(3) . . . . ?
C60 C55 C56 C57 2.3(4) . . . . ?
C52 C53 C54 C55 -2.0(4) . . . . ?
C56 C55 C54 C53 -178.9(3) . . . . ?
C60 C55 C54 C53 -0.2(4) . . . . ?
C55 C56 C57 C58 -3.8(4) . . . . ?
C59 C58 C57 C56 0.2(4) . . . . ?
C38 C37 C36 C35 -2.2(4) . . . . ?
C15 C16 C17 C18 -0.6(4) . . . . ?
C19 C18 C17 C16 0.0(4) . . . . ?
C37 C36 C35 C34 179.8(3) . . . . ?
C37 C36 C35 C40 -0.8(4) . . . . ?
N4 C40 C35 C36 -174.5(2) . . . . ?
C39 C40 C35 C36 5.7(4) . . . . ?
N4 C40 C35 C34 5.0(4) . . . . ?
C39 C40 C35 C34 -174.8(2) . . . . ?
N5 C50 C45 C44 4.1(4) . . . . ?
C49 C50 C45 C44 -171.9(3) . . . . ?
N5 C50 C45 C46 -179.7(2) . . . . ?
C49 C50 C45 C46 4.4(4) . . . . ?
O1 C9 C8 C7 -179.5(2) . . . . ?
C10 C9 C8 C7 0.2(3) . . . . ?
C6 C7 C8 C9 -0.3(4) . . . . ?
C28 C27 C26 C25 -1.0(4) . . . . ?
C24 C25 C26 C27 176.6(3) . . . . ?
C30 C25 C26 C27 -1.4(4) . . . . ?
C8 C7 C6 C5 0.7(4) . . . . ?
C10 C5 C6 C7 -1.2(4) . . . . ?
C4 C5 C6 C7 175.8(2) . . . . ?
N7 C62 C63 C64 1.6(4) . . . . ?
C61 C62 C63 C64 -177.7(2) . . . . ?
C49 C48 C47 C46 1.3(4) . . . . ?
C68 C67 C66 C65 -1.5(4) . . . . ?
C48 C47 C46 C45 -0.5(4) . . . . ?
C44 C45 C46 C47 173.6(3) . . . . ?
C50 C45 C46 C47 -2.4(4) . . . . ?
C62 C63 C64 C65 -1.4(4) . . . . ?
C63 C64 C65 C70 -1.2(4) . . . . ?
C63 C64 C65 C66 -179.0(3) . . . . ?
N7 C70 C65 C64 3.8(4) . . . . ?
C69 C70 C65 C64 -175.7(2) . . . . ?
N7 C70 C65 C66 -178.3(2) . . . . ?
C69 C70 C65 C66 2.2(4) . . . . ?
C67 C66 C65 C64 177.9(2) . . . . ?
C67 C66 C65 C70 0.2(4) . . . . ?
N4 C32 C33 C34 5.7(4) . . . . ?
C31 C32 C33 C34 -173.0(3) . . . . ?
C32 C33 C34 C35 -0.5(5) . . . . ?
C36 C35 C34 C33 175.0(3) . . . . ?
C40 C35 C34 C33 -4.5(4) . . . . ?
C50 C45 C44 C43 -0.3(5) . . . . ?
C46 C45 C44 C43 -176.3(3) . . . . ?
C45 C44 C43 C42 -2.8(5) . . . . ?
N5 C42 C43 C44 2.2(5) . . . . ?
C41 C42 C43 C44 -179.2(3) . . . . ?

_refine_diff_density_max         0.480
_refine_diff_density_min         -0.730
_refine_diff_density_rms         0.102



