# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_y
_database_code_depnum_ccdc_archive 'CCDC 1563389'
_audit_update_record             
;
2017-07-20 deposited with the CCDC.
2017-11-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        JLG-16
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H0 F10 Ge28 N18 O62'
_chemical_formula_weight         3755.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   38.2008(15)
_cell_length_b                   8.8262(4)
_cell_length_c                   31.1789(13)
_cell_angle_alpha                90.00
_cell_angle_beta                 108.5470(10)
_cell_angle_gamma                90.00
_cell_volume                     9966.5(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    7632
_cell_measurement_theta_min      2.23
_cell_measurement_theta_max      25.03

_exptl_crystal_description       block
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.503
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             7005
_exptl_absorpt_coefficient_mu    8.420
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2708
_exptl_absorpt_correction_T_max  0.3125
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            31117
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_av_sigmaI/netI    0.0444
_diffrn_reflns_limit_h_min       -45
_diffrn_reflns_limit_h_max       45
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         1.12
_diffrn_reflns_theta_max         25.09
_reflns_number_total             8845
_reflns_number_gt                7545
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0193P)²+873.8065P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   ?
_refine_ls_hydrogen_treatment    ?
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8845
_refine_ls_number_parameters     654
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0740
_refine_ls_R_factor_gt           0.0635
_refine_ls_wR_factor_ref         0.1567
_refine_ls_wR_factor_gt          0.1527
_refine_ls_goodness_of_fit_ref   1.203
_refine_ls_restrained_S_all      1.203
_refine_ls_shift/su_max          0.178
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.912351(16) 0.79207(7) 1.12025(2) 0.01154(15) Uani 1 1 d . . .
Ge2 Ge 0.895314(16) 0.41364(7) 0.69184(2) 0.01202(15) Uani 1 1 d . . .
Ge3 Ge 0.854683(16) 0.61387(7) 0.61761(2) 0.01260(16) Uani 1 1 d . . .
Ge4 Ge 0.793720(17) 0.38648(8) 0.86130(2) 0.01594(16) Uani 1 1 d . . .
Ge5 Ge 0.840885(17) 0.59557(7) 0.93607(2) 0.01274(15) Uani 1 1 d . . .
Ge6 Ge 0.865566(17) 0.37769(7) 0.77979(2) 0.01233(15) Uani 1 1 d . . .
Ge7 Ge 0.917889(17) 0.16406(7) 1.12989(2) 0.01225(16) Uani 1 1 d . . .
Ge8 Ge 0.853332(17) 0.79989(7) 0.86439(2) 0.01321(16) Uani 1 1 d . . .
Ge9 Ge 0.890065(16) 0.48363(7) 0.88036(2) 0.01073(15) Uani 1 1 d . . .
Ge10 Ge 0.804328(17) 0.58431(8) 0.79295(2) 0.01600(16) Uani 1 1 d . . .
Ge11 Ge 0.866159(17) 0.59255(7) 1.04455(2) 0.01282(16) Uani 1 1 d . . .
Ge12 Ge 0.941623(16) 0.47655(7) 1.10544(2) 0.01093(15) Uani 1 1 d . . .
Ge13 Ge 0.962310(17) 0.62775(7) 0.70459(2) 0.01263(16) Uani 1 1 d . . .
Ge14 Ge 0.854320(17) 0.17196(7) 0.85325(2) 0.01348(16) Uani 1 1 d . . .
F1 F 0.76977(11) 0.6613(5) 0.74455(13) 0.0334(12) Uani 1 1 d . . .
F2 F 0.93987(9) 0.4853(4) 0.90896(13) 0.0219(10) Uani 1 1 d . . .
F3 F 0.97899(9) 0.4753(4) 1.08091(12) 0.0201(9) Uani 1 1 d . . .
F4 F 0.80839(9) 0.6824(5) 0.61078(12) 0.0248(10) Uani 1 1 d . . .
F5 F 0.75092(10) 0.3121(5) 0.86329(15) 0.0366(12) Uani 1 1 d . . .
O1 O 0.88219(12) 0.3262(5) 0.73662(13) 0.0178(11) Uani 1 1 d . . .
O2 O 0.80288(11) 0.4769(5) 0.91435(15) 0.0206(12) Uani 1 1 d . . .
O3 O 0.83300(12) 0.7690(5) 0.90707(14) 0.0183(12) Uani 1 1 d . . .
O4 O 0.88232(11) 0.5134(5) 0.93681(13) 0.0169(11) Uani 1 1 d . . .
O5 O 0.88921(12) 0.2763(5) 0.89055(14) 0.0174(11) Uani 1 1 d . . .
O6 O 0.89273(11) 0.6929(5) 0.87402(14) 0.0178(11) Uani 1 1 d . . .
O7 O 0.81129(12) 0.2016(5) 0.86058(16) 0.0208(12) Uani 1 1 d . . .
O8 O 0.82641(12) 0.4934(5) 0.75790(14) 0.0211(12) Uani 1 1 d . . .
O9 O 0.82088(12) 0.7699(5) 0.81111(14) 0.0202(12) Uani 1 1 d . . .
O10 O 0.89916(11) 0.4534(5) 0.82516(13) 0.0149(11) Uani 1 1 d . . .
O11 O 0.93598(11) 0.2682(5) 1.09518(14) 0.0163(11) Uani 1 1 d . . .
O12 O 0.90768(11) 0.5101(5) 1.04650(14) 0.0186(12) Uani 1 1 d . . .
O13 O 0.83972(12) 0.6426(6) 0.98965(14) 0.0223(12) Uani 1 1 d . . .
O14 O 0.83790(11) 0.4718(5) 1.06337(14) 0.0187(12) Uani 1 1 d . . .
O15 O 0.87203(11) 0.7635(5) 1.07446(14) 0.0182(12) Uani 1 1 d . . .
O16 O 0.85395(11) 0.5157(5) 0.66746(14) 0.0190(12) Uani 1 1 d . . .
O17 O 0.90336(12) 0.7646(5) 1.17103(14) 0.0173(11) Uani 1 1 d . . .
O18 O 0.93516(12) 0.5085(5) 0.72590(14) 0.0210(12) Uani 1 1 d . . .
O19 O 1.0000 0.6812(7) 0.7500 0.0230(18) Uani 1 2 d S . .
O20 O 0.97727(11) 0.4496(5) 1.16275(14) 0.0164(11) Uani 1 1 d . . .
O21 O 0.94045(12) 0.1960(5) 1.18734(13) 0.0186(12) Uani 1 1 d . . .
O22 O 0.87063(11) 0.1979(5) 1.11857(14) 0.0167(11) Uani 1 1 d . . .
O23 O 0.94803(11) 0.6842(5) 1.11430(14) 0.0157(11) Uani 1 1 d . . .
O24 O 0.85062(12) 0.2023(5) 0.79624(14) 0.0203(12) Uani 1 1 d . . .
O25 O 0.77066(11) 0.4896(6) 0.81097(16) 0.0239(13) Uani 1 1 d . . .
O26 O 0.92583(11) 0.9779(5) 1.11746(15) 0.0178(11) Uani 1 1 d . . .
O27 O 0.83628(10) 0.4860(5) 0.84905(13) 0.0108(10) Uani 1 1 d . . .
O28 O 0.90309(10) 0.4785(5) 1.13273(13) 0.0114(10) Uani 1 1 d . . .
O29 O 0.86804(13) 0.9860(5) 0.86728(17) 0.0277(13) Uani 1 1 d . . .
N1 N 0.80571(17) -0.0232(8) 0.7321(2) 0.0355(19) Uani 1 1 d . . .
N2 N 0.80260(18) 0.2076(8) 0.6696(2) 0.038(2) Uani 1 1 d . . .
N3 N 0.77639(15) 0.5270(7) 0.66626(18) 0.0234(15) Uani 1 1 d . . .
C1 C 0.8309(2) -0.0322(10) 0.7029(3) 0.044(3) Uani 1 1 d . . .
C2 C 0.8149(2) 0.0589(10) 0.6601(3) 0.041(2) Uani 1 1 d . . .
C3 C 0.7743(3) 0.2779(10) 0.6297(3) 0.046(3) Uani 1 1 d . . .
C4 C 0.7528(2) 0.3959(10) 0.6457(3) 0.041(3) Uani 1 1 d . . .
N4 N 0.96224(19) -0.2496(11) 0.8637(3) 0.060(3) Uani 1 1 d . . .
N5 N 0.9422(6) 0.0189(15) 0.8081(5) 0.217(9) Uani 1 1 d . . .
N6 N 0.9752(2) 0.2734(11) 0.8566(4) 0.087(4) Uani 1 1 d . . .
C5 C 0.9492(3) -0.2503(16) 0.8155(4) 0.076(4) Uani 1 1 d . . .
C6 C 0.9279(4) -0.1192(14) 0.7940(4) 0.089(5) Uani 1 1 d . . .
C7 C 0.9709(5) 0.1113(18) 0.7908(5) 0.146(6) Uani 1 1 d . . .
C8 C 0.9710(3) 0.2708(18) 0.8090(4) 0.089(5) Uani 1 1 d . . .
N7 N 0.8984(3) 0.2283(10) -0.0079(3) 0.079(3) Uani 1 1 d . . .
N8 N 0.8116(4) 0.014(2) -0.0116(6) 0.159(8) Uani 1 1 d . . .
N9 N 0.7436(4) 0.1155(19) -0.0083(10) 0.257(14) Uani 1 1 d . . .
C9 C 0.8561(5) 0.174(2) -0.0149(5) 0.180(7) Uani 1 1 d . . .
C10 C 0.8511(5) 0.054(2) -0.0010(8) 0.162(9) Uani 1 1 d . . .
C11 C 0.7998(5) 0.001(2) 0.0248(7) 0.154(8) Uani 1 1 d . . .
C12 C 0.7588(4) -0.0061(18) 0.0132(7) 0.123(7) Uani 1 1 d . . .
O1W O 0.9544(3) 0.6489(17) 0.9953(3) 0.163(5) Uani 1 1 d . A 1
O2W O 0.9991(4) 0.5898(18) 1.0014(4) 0.068(5) Uani 0.50 1 d P . 2
O3W O 0.9893(4) 0.975(3) 0.5756(7) 0.170(10) Uani 0.50 1 d P B 3
O4W O 0.9548(5) 0.959(3) 0.9956(6) 0.106(7) Uani 0.50 1 d P C 4


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 O23 1.720(4) . ?
Ge1 O26 1.729(4) . ?
Ge1 O17 1.740(5) . ?
Ge1 O15 1.754(4) . ?
Ge1 Ge11 3.0226(8) . ?
Ge2 O18 1.766(4) . ?
Ge2 O17 1.766(4) 6_565 ?
Ge2 O16 1.767(4) . ?
Ge2 O1 1.800(5) . ?
Ge2 O28 2.177(4) 6_565 ?
Ge2 Ge3 2.9331(8) . ?
Ge3 O22 1.767(4) 6_565 ?
Ge3 O14 1.776(4) 6_565 ?
Ge3 O16 1.787(5) . ?
Ge3 F4 1.816(4) . ?
Ge3 O28 1.937(4) 6_565 ?
Ge3 Ge7 3.0381(9) 6_565 ?
Ge4 O7 1.768(4) . ?
Ge4 O2 1.768(5) . ?
Ge4 F5 1.781(4) . ?
Ge4 O25 1.786(5) . ?
Ge4 O27 1.989(4) . ?
Ge4 Ge10 2.8817(10) . ?
Ge5 O4 1.735(4) . ?
Ge5 O13 1.736(4) . ?
Ge5 O2 1.743(4) . ?
Ge5 O3 1.755(4) . ?
Ge5 Ge8 3.0248(9) . ?
Ge6 O10 1.715(4) . ?
Ge6 O1 1.722(5) . ?
Ge6 O8 1.760(4) . ?
Ge6 O24 1.781(5) . ?
Ge7 O11 1.723(5) . ?
Ge7 O26 1.737(4) 1_545 ?
Ge7 O21 1.746(4) . ?
Ge7 O22 1.751(4) . ?
Ge7 Ge13 3.0276(8) 6_566 ?
Ge7 Ge3 3.0382(9) 6_566 ?
Ge8 O6 1.720(4) . ?
Ge8 O29 1.729(4) . ?
Ge8 O9 1.748(4) . ?
Ge8 O3 1.762(5) . ?
Ge9 F2 1.827(3) . ?
Ge9 O5 1.859(4) . ?
Ge9 O6 1.864(4) . ?
Ge9 O10 1.880(4) . ?
Ge9 O4 1.893(4) . ?
Ge9 O27 1.974(4) . ?
Ge10 O25 1.768(5) . ?
Ge10 O8 1.771(5) . ?
Ge10 O9 1.782(5) . ?
Ge10 F1 1.793(4) . ?
Ge10 O27 1.986(4) . ?
Ge11 O12 1.729(5) . ?
Ge11 O13 1.745(4) . ?
Ge11 O14 1.746(5) . ?
Ge11 O15 1.750(4) . ?
Ge12 F3 1.821(4) . ?
Ge12 O23 1.858(4) . ?
Ge12 O11 1.867(4) . ?
Ge12 O20 1.886(4) . ?
Ge12 O12 1.905(4) . ?
Ge12 O28 1.921(4) . ?
Ge13 O20 1.723(5) 6_565 ?
Ge13 O19 1.733(2) . ?
Ge13 O18 1.750(5) . ?
Ge13 O21 1.766(4) 6_565 ?
Ge13 Ge7 3.0275(8) 6_565 ?
Ge14 O5 1.730(4) . ?
Ge14 O29 1.736(4) 1_545 ?
Ge14 O7 1.750(5) . ?
Ge14 O24 1.758(4) . ?
O14 Ge3 1.776(4) 6_566 ?
O17 Ge2 1.765(4) 6_566 ?
O19 Ge13 1.7328(19) 2_756 ?
O20 Ge13 1.723(5) 6_566 ?
O21 Ge13 1.766(4) 6_566 ?
O22 Ge3 1.767(4) 6_566 ?
O26 Ge7 1.737(4) 1_565 ?
O28 Ge3 1.937(4) 6_566 ?
O28 Ge2 2.177(4) 6_566 ?
O29 Ge14 1.736(4) 1_565 ?
N1 C1 1.523(13) . ?
N2 C2 1.455(11) . ?
N2 C3 1.497(10) . ?
N3 C4 1.482(10) . ?
C1 C2 1.510(12) . ?
C3 C4 1.508(13) . ?
N4 C5 1.422(14) . ?
N5 C6 1.351(18) . ?
N5 C7 1.59(3) . ?
N6 C8 1.442(17) . ?
C5 C6 1.450(17) . ?
C7 C8 1.52(2) . ?
N7 C9 1.63(2) . ?
N8 C11 1.36(3) . ?
N8 C10 1.48(2) . ?
N9 C12 1.30(2) . ?
C9 C10 1.19(3) . ?
C11 C12 1.49(2) . ?
O2W O2W 1.59(3) 5_767 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O23 Ge1 O26 105.1(2) . . ?
O23 Ge1 O17 114.4(2) . . ?
O26 Ge1 O17 109.0(2) . . ?
O23 Ge1 O15 110.7(2) . . ?
O26 Ge1 O15 107.1(2) . . ?
O17 Ge1 O15 110.1(2) . . ?
O23 Ge1 Ge11 83.05(13) . . ?
O26 Ge1 Ge11 128.49(14) . . ?
O17 Ge1 Ge11 113.20(14) . . ?
O15 Ge1 Ge11 30.34(15) . . ?
O18 Ge2 O17 115.2(2) . 6_565 ?
O18 Ge2 O16 119.9(2) . . ?
O17 Ge2 O16 122.19(19) 6_565 . ?
O18 Ge2 O1 97.8(2) . . ?
O17 Ge2 O1 91.6(2) 6_565 . ?
O16 Ge2 O1 96.9(2) . . ?
O18 Ge2 O28 88.75(18) . 6_565 ?
O17 Ge2 O28 89.54(18) 6_565 6_565 ?
O16 Ge2 O28 75.94(18) . 6_565 ?
O1 Ge2 O28 172.12(16) . 6_565 ?
O18 Ge2 Ge3 109.12(15) . . ?
O17 Ge2 Ge3 110.93(13) 6_565 . ?
O16 Ge2 Ge3 34.61(15) . . ?
O1 Ge2 Ge3 131.45(14) . . ?
O28 Ge2 Ge3 41.32(10) 6_565 . ?
O22 Ge3 O14 115.8(2) 6_565 6_565 ?
O22 Ge3 O16 122.8(2) 6_565 . ?
O14 Ge3 O16 121.4(2) 6_565 . ?
O22 Ge3 F4 90.36(19) 6_565 . ?
O14 Ge3 F4 89.26(19) 6_565 . ?
O16 Ge3 F4 88.83(19) . . ?
O22 Ge3 O28 95.43(18) 6_565 6_565 ?
O14 Ge3 O28 94.59(18) 6_565 6_565 ?
O16 Ge3 O28 82.07(18) . 6_565 ?
F4 Ge3 O28 170.84(18) . 6_565 ?
O22 Ge3 Ge2 117.41(12) 6_565 . ?
O14 Ge3 Ge2 115.77(14) 6_565 . ?
O16 Ge3 Ge2 34.16(13) . . ?
F4 Ge3 Ge2 122.98(13) . . ?
O28 Ge3 Ge2 47.91(13) 6_565 . ?
O22 Ge3 Ge7 30.14(14) 6_565 6_565 ?
O14 Ge3 Ge7 115.26(16) 6_565 6_565 ?
O16 Ge3 Ge7 115.77(13) . 6_565 ?
F4 Ge3 Ge7 120.33(13) . 6_565 ?
O28 Ge3 Ge7 65.29(12) 6_565 6_565 ?
Ge2 Ge3 Ge7 95.13(2) . 6_565 ?
O7 Ge4 O2 117.8(2) . . ?
O7 Ge4 F5 90.9(2) . . ?
O2 Ge4 F5 92.6(2) . . ?
O7 Ge4 O25 122.9(2) . . ?
O2 Ge4 O25 119.2(2) . . ?
F5 Ge4 O25 91.0(2) . . ?
O7 Ge4 O27 93.9(2) . . ?
O2 Ge4 O27 92.84(19) . . ?
F5 Ge4 O27 170.05(17) . . ?
O25 Ge4 O27 79.09(18) . . ?
O7 Ge4 Ge10 114.00(17) . . ?
O2 Ge4 Ge10 112.69(16) . . ?
F5 Ge4 Ge10 126.57(14) . . ?
O25 Ge4 Ge10 35.62(15) . . ?
O27 Ge4 Ge10 43.49(10) . . ?
O4 Ge5 O13 113.0(2) . . ?
O4 Ge5 O2 113.4(2) . . ?
O13 Ge5 O2 104.2(2) . . ?
O4 Ge5 O3 112.2(2) . . ?
O13 Ge5 O3 103.6(2) . . ?
O2 Ge5 O3 109.8(2) . . ?
O4 Ge5 Ge8 84.37(15) . . ?
O13 Ge5 Ge8 128.80(17) . . ?
O2 Ge5 Ge8 112.23(15) . . ?
O3 Ge5 Ge8 30.76(16) . . ?
O10 Ge6 O1 112.5(2) . . ?
O10 Ge6 O8 114.5(2) . . ?
O1 Ge6 O8 109.2(2) . . ?
O10 Ge6 O24 108.99(19) . . ?
O1 Ge6 O24 103.2(2) . . ?
O8 Ge6 O24 107.8(2) . . ?
O11 Ge7 O26 103.4(2) . 1_545 ?
O11 Ge7 O21 113.1(2) . . ?
O26 Ge7 O21 108.5(2) 1_545 . ?
O11 Ge7 O22 112.1(2) . . ?
O26 Ge7 O22 111.0(2) 1_545 . ?
O21 Ge7 O22 108.7(2) . . ?
O11 Ge7 Ge13 85.46(14) . 6_566 ?
O26 Ge7 Ge13 130.61(13) 1_545 6_566 ?
O21 Ge7 Ge13 30.65(15) . 6_566 ?
O22 Ge7 Ge13 109.95(14) . 6_566 ?
O11 Ge7 Ge3 92.19(14) . 6_566 ?
O26 Ge7 Ge3 140.39(14) 1_545 6_566 ?
O21 Ge7 Ge3 97.95(15) . 6_566 ?
O22 Ge7 Ge3 30.43(14) . 6_566 ?
Ge13 Ge7 Ge3 86.21(2) 6_566 6_566 ?
O6 Ge8 O29 105.1(2) . . ?
O6 Ge8 O9 113.5(2) . . ?
O29 Ge8 O9 108.3(2) . . ?
O6 Ge8 O3 110.8(2) . . ?
O29 Ge8 O3 108.7(2) . . ?
O9 Ge8 O3 110.1(2) . . ?
O6 Ge8 Ge5 83.01(16) . . ?
O29 Ge8 Ge5 130.75(18) . . ?
O9 Ge8 Ge5 112.41(16) . . ?
O3 Ge8 Ge5 30.61(14) . . ?
F2 Ge9 O5 89.81(17) . . ?
F2 Ge9 O6 87.72(17) . . ?
O5 Ge9 O6 176.33(18) . . ?
F2 Ge9 O10 88.90(17) . . ?
O5 Ge9 O10 92.0(2) . . ?
O6 Ge9 O10 90.6(2) . . ?
F2 Ge9 O4 89.52(18) . . ?
O5 Ge9 O4 87.77(19) . . ?
O6 Ge9 O4 89.5(2) . . ?
O10 Ge9 O4 178.41(17) . . ?
F2 Ge9 O27 178.85(18) . . ?
O5 Ge9 O27 91.32(17) . . ?
O6 Ge9 O27 91.16(17) . . ?
O10 Ge9 O27 90.87(17) . . ?
O4 Ge9 O27 90.72(17) . . ?
O25 Ge10 O8 121.3(2) . . ?
O25 Ge10 O9 123.6(2) . . ?
O8 Ge10 O9 115.0(2) . . ?
O25 Ge10 F1 91.8(2) . . ?
O8 Ge10 F1 91.14(19) . . ?
O9 Ge10 F1 90.63(19) . . ?
O25 Ge10 O27 79.59(18) . . ?
O8 Ge10 O27 93.77(18) . . ?
O9 Ge10 O27 93.72(17) . . ?
F1 Ge10 O27 171.4(2) . . ?
O25 Ge10 Ge4 36.02(13) . . ?
O8 Ge10 Ge4 112.87(16) . . ?
O9 Ge10 Ge4 116.17(15) . . ?
F1 Ge10 Ge4 127.81(15) . . ?
O27 Ge10 Ge4 43.58(12) . . ?
O12 Ge11 O13 112.3(2) . . ?
O12 Ge11 O14 113.0(2) . . ?
O13 Ge11 O14 104.9(2) . . ?
O12 Ge11 O15 112.6(2) . . ?
O13 Ge11 O15 103.9(2) . . ?
O14 Ge11 O15 109.6(2) . . ?
O12 Ge11 Ge1 85.21(14) . . ?
O13 Ge11 Ge1 129.08(17) . . ?
O14 Ge11 Ge1 111.28(14) . . ?
O15 Ge11 Ge1 30.42(13) . . ?
F3 Ge12 O23 89.12(19) . . ?
F3 Ge12 O11 89.17(19) . . ?
O23 Ge12 O11 178.2(2) . . ?
F3 Ge12 O20 88.34(17) . . ?
O23 Ge12 O20 87.84(18) . . ?
O11 Ge12 O20 92.71(18) . . ?
F3 Ge12 O12 88.85(18) . . ?
O23 Ge12 O12 90.41(18) . . ?
O11 Ge12 O12 88.96(18) . . ?
O20 Ge12 O12 176.7(2) . . ?
F3 Ge12 O28 178.60(15) . . ?
O23 Ge12 O28 90.49(19) . . ?
O11 Ge12 O28 91.24(19) . . ?
O20 Ge12 O28 90.31(18) . . ?
O12 Ge12 O28 92.50(18) . . ?
O20 Ge13 O19 109.68(15) 6_565 . ?
O20 Ge13 O18 115.4(2) 6_565 . ?
O19 Ge13 O18 106.99(18) . . ?
O20 Ge13 O21 110.9(2) 6_565 6_565 ?
O19 Ge13 O21 101.5(2) . 6_565 ?
O18 Ge13 O21 111.4(2) . 6_565 ?
O20 Ge13 Ge7 84.13(13) 6_565 6_565 ?
O19 Ge13 Ge7 125.5(2) . 6_565 ?
O18 Ge13 Ge7 113.71(14) . 6_565 ?
O21 Ge13 Ge7 30.26(13) 6_565 6_565 ?
O5 Ge14 O29 103.2(2) . 1_545 ?
O5 Ge14 O7 112.8(2) . . ?
O29 Ge14 O7 109.2(2) 1_545 . ?
O5 Ge14 O24 113.3(2) . . ?
O29 Ge14 O24 108.6(2) 1_545 . ?
O7 Ge14 O24 109.4(2) . . ?
Ge6 O1 Ge2 139.1(3) . . ?
Ge5 O2 Ge4 121.8(3) . . ?
Ge5 O3 Ge8 118.6(3) . . ?
Ge5 O4 Ge9 117.2(2) . . ?
Ge14 O5 Ge9 117.4(2) . . ?
Ge8 O6 Ge9 119.2(2) . . ?
Ge14 O7 Ge4 121.1(3) . . ?
Ge6 O8 Ge10 122.4(2) . . ?
Ge8 O9 Ge10 120.9(2) . . ?
Ge6 O10 Ge9 120.2(2) . . ?
Ge7 O11 Ge12 117.7(3) . . ?
Ge11 O12 Ge12 115.8(2) . . ?
Ge5 O13 Ge11 134.4(3) . . ?
Ge11 O14 Ge3 120.4(2) . 6_566 ?
Ge11 O15 Ge1 119.2(2) . . ?
Ge2 O16 Ge3 111.2(2) . . ?
Ge1 O17 Ge2 124.5(2) . 6_566 ?
Ge13 O18 Ge2 124.0(2) . . ?
Ge13 O19 Ge13 148.4(4) 2_756 . ?
Ge13 O20 Ge12 117.0(2) 6_566 . ?
Ge7 O21 Ge13 119.1(2) . 6_566 ?
Ge7 O22 Ge3 119.4(2) . 6_566 ?
Ge1 O23 Ge12 119.4(2) . . ?
Ge14 O24 Ge6 119.6(2) . . ?
Ge10 O25 Ge4 108.4(2) . . ?
Ge1 O26 Ge7 144.1(3) . 1_565 ?
Ge9 O27 Ge10 133.8(2) . . ?
Ge9 O27 Ge4 133.3(2) . . ?
Ge10 O27 Ge4 92.93(15) . . ?
Ge12 O28 Ge3 134.1(2) . 6_566 ?
Ge12 O28 Ge2 135.17(19) . 6_566 ?
Ge3 O28 Ge2 90.77(17) 6_566 6_566 ?
Ge8 O29 Ge14 144.9(3) . 1_565 ?
C2 N2 C3 113.5(6) . . ?
C2 C1 N1 110.2(7) . . ?
N2 C2 C1 111.5(7) . . ?
N2 C3 C4 109.7(7) . . ?
N3 C4 C3 111.2(7) . . ?
C6 N5 C7 127.3(16) . . ?
N4 C5 C6 116.2(11) . . ?
N5 C6 C5 117.4(13) . . ?
C8 C7 N5 105.7(13) . . ?
N6 C8 C7 112.7(12) . . ?
C11 N8 C10 115.0(17) . . ?
C10 C9 N7 118.7(17) . . ?
C9 C10 N8 113.6(19) . . ?
N8 C11 C12 113.9(16) . . ?
N9 C12 C11 110.8(16) . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        25.09
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         1.783
_refine_diff_density_min         -1.243
_refine_diff_density_rms         0.265
