# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1530386'
_audit_update_record             
;
2017-01-31 deposited with the CCDC.
2017-03-13 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C52 H50 N14 O32 Ru2 W10'
_chemical_formula_weight         3423.70

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.6893(19)
_cell_length_b                   13.959(2)
_cell_length_c                   14.063(2)
_cell_angle_alpha                70.144(10)
_cell_angle_beta                 70.634(10)
_cell_angle_gamma                89.661(11)
_cell_volume                     1848.5(5)
_cell_formula_units_Z            1
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    4782
_cell_measurement_theta_min      2.42
_cell_measurement_theta_max      27.47

_exptl_crystal_description       block
_exptl_crystal_colour            gray
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.22
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.076
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1544
_exptl_absorpt_coefficient_mu    15.971
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.1086
_exptl_absorpt_correction_T_max  0.1270
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            17626
_diffrn_reflns_av_R_equivalents  0.0373
_diffrn_reflns_av_sigmaI/netI    0.0449
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.64
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6484
_reflns_number_gt                5136
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0457P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6484
_refine_ls_number_parameters     484
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0474
_refine_ls_R_factor_gt           0.0330
_refine_ls_wR_factor_ref         0.0851
_refine_ls_wR_factor_gt          0.0796
_refine_ls_goodness_of_fit_ref   1.001
_refine_ls_restrained_S_all      1.003
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.58299(4) 0.65598(3) 0.68664(3) 0.03373(11) Uani 1 1 d . . .
W2 W 0.65544(4) 0.43804(3) 0.65224(3) 0.03374(11) Uani 1 1 d . . .
W3 W 0.34411(4) 0.48404(3) 0.72579(3) 0.03449(11) Uani 1 1 d . . .
W4 W 0.42360(4) 0.69829(3) 0.51644(3) 0.03346(11) Uani 1 1 d . . .
W5 W 0.73455(4) 0.65151(3) 0.44354(3) 0.02997(11) Uani 1 1 d . . .
Ru1 Ru 0.97648(7) 0.79385(5) 0.82807(6) 0.02783(17) Uani 1 1 d . . .
O1 O 0.6142(7) 0.7211(5) 0.7616(6) 0.0493(19) Uani 1 1 d . . .
O2 O 0.6702(6) 0.5319(5) 0.7221(5) 0.0382(16) Uani 1 1 d . . .
O3 O 0.4206(6) 0.5699(5) 0.7823(5) 0.0401(16) Uani 1 1 d . . .
O4 O 0.4844(6) 0.7443(5) 0.6127(5) 0.0402(16) Uani 1 1 d . . .
O5 O 0.7335(6) 0.7048(4) 0.5545(5) 0.0336(15) Uani 1 1 d . . .
O6 O 0.5394(5) 0.5700(4) 0.5862(4) 0.0260(13) Uani 1 1 d . . .
O7 O 0.7434(7) 0.3486(5) 0.7097(6) 0.053(2) Uani 1 1 d . . .
O8 O 0.4745(6) 0.3937(5) 0.7504(5) 0.0373(15) Uani 1 1 d . . .
O9 O 0.7879(5) 0.5284(5) 0.5232(5) 0.0317(14) Uani 1 1 d . . .
O10 O 0.2092(7) 0.4322(6) 0.8393(6) 0.053(2) Uani 1 1 d . . .
O11 O 0.2908(6) 0.6072(5) 0.6449(5) 0.0354(15) Uani 1 1 d . . .
O12 O 0.3100(6) 0.4186(5) 0.6372(5) 0.0349(15) Uani 1 1 d . . .
O13 O 0.3444(7) 0.8035(5) 0.4780(7) 0.055(2) Uani 1 1 d . . .
O14 O 0.3879(6) 0.6257(4) 0.4367(5) 0.0352(15) Uani 1 1 d . . .
O15 O 0.8823(7) 0.7204(6) 0.3527(5) 0.0511(19) Uani 1 1 d . . .
O16 O 0.6043(6) 0.7408(4) 0.4160(5) 0.0345(15) Uani 1 1 d . . .
C1 C 0.8167(9) 0.9227(7) 0.6966(8) 0.038(2) Uani 1 1 d . . .
H1A H 0.7484 0.8685 0.7356 0.045 Uiso 1 1 calc R . .
C2 C 0.7930(10) 1.0098(8) 0.6257(9) 0.051(3) Uani 1 1 d . . .
H2A H 0.7102 1.0147 0.6173 0.062 Uiso 1 1 calc R . .
C3 C 0.8948(11) 1.0907(8) 0.5666(10) 0.058(3) Uani 1 1 d . . .
H3A H 0.8808 1.1513 0.5191 0.069 Uiso 1 1 calc R . .
C4 C 1.0153(10) 1.0798(7) 0.5793(9) 0.045(3) Uani 1 1 d . . .
H4A H 1.0850 1.1328 0.5399 0.054 Uiso 1 1 calc R . .
C5 C 1.0337(9) 0.9905(7) 0.6504(8) 0.035(2) Uani 1 1 d . . .
C6 C 1.1632(9) 0.9706(6) 0.6663(7) 0.030(2) Uani 1 1 d . . .
C7 C 1.2792(9) 1.0361(7) 0.6053(8) 0.040(2) Uani 1 1 d . . .
H7B H 1.2790 1.0983 0.5526 0.048 Uiso 1 1 calc R . .
C8 C 1.3982(10) 1.0082(8) 0.6233(9) 0.045(3) Uani 1 1 d . . .
H8A H 1.4779 1.0515 0.5828 0.053 Uiso 1 1 calc R . .
C9 C 1.3948(9) 0.9168(8) 0.7010(9) 0.045(3) Uani 1 1 d . . .
H9A H 1.4716 0.8971 0.7159 0.055 Uiso 1 1 calc R . .
C10 C 1.2754(9) 0.8538(7) 0.7574(8) 0.040(2) Uani 1 1 d . . .
H10B H 1.2749 0.7900 0.8079 0.048 Uiso 1 1 calc R . .
C11 C 1.1051(10) 0.6150(8) 0.9387(9) 0.047(3) Uani 1 1 d . . .
H11A H 1.1111 0.5925 0.8824 0.057 Uiso 1 1 calc R . .
C12 C 1.1626(12) 0.5617(9) 1.0144(10) 0.059(3) Uani 1 1 d . . .
H12B H 1.2059 0.5048 1.0087 0.071 Uiso 1 1 calc R . .
C13 C 1.1535(12) 0.5951(10) 1.0975(11) 0.067(4) Uani 1 1 d . . .
H13B H 1.1934 0.5624 1.1476 0.080 Uiso 1 1 calc R . .
C14 C 1.0851(11) 0.6771(9) 1.1059(9) 0.056(3) Uani 1 1 d . . .
H14B H 1.0766 0.6993 1.1628 0.067 Uiso 1 1 calc R . .
C15 C 1.0286(10) 0.7269(7) 1.0296(8) 0.041(2) Uani 1 1 d . . .
C16 C 0.9564(10) 0.8153(8) 1.0293(8) 0.044(3) Uani 1 1 d . . .
C17 C 0.9088(13) 0.8474(11) 1.1161(9) 0.067(4) Uani 1 1 d . . .
H17A H 0.9263 0.8133 1.1790 0.081 Uiso 1 1 calc R . .
C18 C 0.8358(15) 0.9294(13) 1.1106(13) 0.085(5) Uani 1 1 d . . .
H18A H 0.8016 0.9502 1.1695 0.102 Uiso 1 1 calc R . .
C19 C 0.8155(12) 0.9781(10) 1.0188(11) 0.064(4) Uani 1 1 d . . .
H19A H 0.7696 1.0354 1.0124 0.077 Uiso 1 1 calc R . .
C20 C 0.8608(11) 0.9453(8) 0.9344(10) 0.051(3) Uani 1 1 d . . .
H20A H 0.8443 0.9803 0.8713 0.061 Uiso 1 1 calc R . .
C21 C 0.6775(11) 0.6875(8) 0.9519(9) 0.049(3) Uani 1 1 d . . .
C22 C 0.5376(11) 0.6454(12) 1.0066(10) 0.079(4) Uani 1 1 d . . .
H22A H 0.4941 0.6802 1.0547 0.118 Uiso 1 1 calc R . .
H22B H 0.5310 0.5735 1.0470 0.118 Uiso 1 1 calc R . .
H22C H 0.4952 0.6547 0.9541 0.118 Uiso 1 1 calc R . .
C24 C 1.0179(10) 0.6029(10) 0.6096(10) 0.057(3) Uani 1 1 d . . .
H24A H 0.9355 0.6038 0.5962 0.086 Uiso 1 1 calc R . .
H24B H 1.0306 0.5332 0.6444 0.086 Uiso 1 1 calc R . .
H24C H 1.0906 0.6333 0.5425 0.086 Uiso 1 1 calc R . .
C23 C 1.0133(10) 0.6611(8) 0.6796(9) 0.042(2) Uani 1 1 d . . .
C25 C 0.538(3) 0.0140(18) 0.862(2) 0.171(10) Uiso 1 1 d D . .
C26 C 0.546(2) 0.1313(15) 0.8159(17) 0.132(7) Uiso 1 1 d D . .
H26A H 0.6295 0.1589 0.7571 0.198 Uiso 1 1 calc R . .
H26B H 0.5410 0.1581 0.8714 0.198 Uiso 1 1 calc R . .
H26C H 0.4736 0.1503 0.7904 0.198 Uiso 1 1 calc R . .
N1 N 0.9348(7) 0.9120(5) 0.7123(6) 0.0300(17) Uani 1 1 d . . .
N2 N 1.1605(7) 0.8791(5) 0.7435(6) 0.0296(17) Uani 1 1 d . . .
N3 N 1.0427(7) 0.6962(5) 0.9438(6) 0.0359(19) Uani 1 1 d . . .
N4 N 0.9293(7) 0.8631(6) 0.9396(6) 0.0343(18) Uani 1 1 d . . .
N5 N 0.7861(8) 0.7215(6) 0.9075(6) 0.0353(18) Uani 1 1 d . . .
N6 N 1.0074(7) 0.7095(6) 0.7305(6) 0.0354(18) Uani 1 1 d . . .
N7 N 0.515(3) -0.0756(19) 0.915(2) 0.217(10) Uiso 1 1 d D . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O1 1.714(6) . ?
W1 O4 1.885(7) . ?
W1 O3 1.909(6) . ?
W1 O5 1.918(6) . ?
W1 O2 1.955(7) . ?
W1 O6 2.291(5) . ?
W2 O7 1.703(7) . ?
W2 O9 1.911(6) . ?
W2 O2 1.920(6) . ?
W2 O8 1.921(6) . ?
W2 O14 1.928(6) 2_666 ?
W2 O6 2.317(6) . ?
W3 O10 1.689(6) . ?
W3 O12 1.897(6) . ?
W3 O8 1.912(7) . ?
W3 O11 1.914(7) . ?
W3 O3 1.955(6) . ?
W3 O6 2.316(5) . ?
W4 O13 1.707(7) . ?
W4 O14 1.868(6) . ?
W4 O11 1.912(6) . ?
W4 O16 1.927(6) . ?
W4 O4 1.962(6) . ?
W4 O6 2.299(6) . ?
W5 O15 1.702(6) . ?
W5 O12 1.896(6) 2_666 ?
W5 O9 1.908(6) . ?
W5 O16 1.911(6) . ?
W5 O5 1.940(6) . ?
W5 O6 2.318(5) . ?
Ru1 N4 2.037(7) . ?
Ru1 N5 2.040(8) . ?
Ru1 N6 2.042(8) . ?
Ru1 N1 2.053(7) . ?
Ru1 N2 2.054(7) . ?
Ru1 N3 2.062(8) . ?
O12 W5 1.896(6) 2_666 ?
O14 W2 1.928(6) 2_666 ?
C1 N1 1.352(12) . ?
C1 C2 1.370(14) . ?
C1 H1A 0.9300 . ?
C2 C3 1.388(14) . ?
C2 H2A 0.9300 . ?
C3 C4 1.359(14) . ?
C3 H3A 0.9300 . ?
C4 C5 1.368(13) . ?
C4 H4A 0.9300 . ?
C5 N1 1.353(11) . ?
C5 C6 1.484(13) . ?
C6 N2 1.360(11) . ?
C6 C7 1.373(12) . ?
C7 C8 1.405(14) . ?
C7 H7B 0.9300 . ?
C8 C9 1.361(15) . ?
C8 H8A 0.9300 . ?
C9 C10 1.378(13) . ?
C9 H9A 0.9300 . ?
C10 N2 1.333(12) . ?
C10 H10B 0.9300 . ?
C11 N3 1.322(12) . ?
C11 C12 1.399(16) . ?
C11 H11A 0.9300 . ?
C12 C13 1.373(17) . ?
C12 H12B 0.9300 . ?
C13 C14 1.374(17) . ?
C13 H13B 0.9300 . ?
C14 C15 1.384(15) . ?
C14 H14B 0.9300 . ?
C15 N3 1.376(12) . ?
C15 C16 1.452(15) . ?
C16 N4 1.338(13) . ?
C16 C17 1.381(14) . ?
C17 C18 1.38(2) . ?
C17 H17A 0.9300 . ?
C18 C19 1.33(2) . ?
C18 H18A 0.9300 . ?
C19 C20 1.356(15) . ?
C19 H19A 0.9300 . ?
C20 N4 1.352(13) . ?
C20 H20A 0.9300 . ?
C21 N5 1.134(12) . ?
C21 C22 1.455(15) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C24 C23 1.464(14) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C23 N6 1.127(11) . ?
C25 N7 1.196(17) . ?
C25 C26 1.533(17) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 W1 O4 102.4(3) . . ?
O1 W1 O3 103.1(3) . . ?
O4 W1 O3 89.0(3) . . ?
O1 W1 O5 103.5(3) . . ?
O4 W1 O5 87.5(3) . . ?
O3 W1 O5 153.4(2) . . ?
O1 W1 O2 104.2(3) . . ?
O4 W1 O2 153.4(3) . . ?
O3 W1 O2 85.7(3) . . ?
O5 W1 O2 85.7(3) . . ?
O1 W1 O6 179.4(3) . . ?
O4 W1 O6 77.0(2) . . ?
O3 W1 O6 76.8(2) . . ?
O5 W1 O6 76.7(2) . . ?
O2 W1 O6 76.4(2) . . ?
O7 W2 O9 103.9(3) . . ?
O7 W2 O2 96.9(3) . . ?
O9 W2 O2 88.7(3) . . ?
O7 W2 O8 103.4(3) . . ?
O9 W2 O8 152.6(3) . . ?
O2 W2 O8 88.8(3) . . ?
O7 W2 O14 99.9(3) . 2_666 ?
O9 W2 O14 87.1(3) . 2_666 ?
O2 W2 O14 163.2(3) . 2_666 ?
O8 W2 O14 87.4(3) . 2_666 ?
O7 W2 O6 173.4(3) . . ?
O9 W2 O6 76.5(2) . . ?
O2 W2 O6 76.4(2) . . ?
O8 W2 O6 76.4(2) . . ?
O14 W2 O6 86.7(2) 2_666 . ?
O10 W3 O12 100.4(3) . . ?
O10 W3 O8 103.2(3) . . ?
O12 W3 O8 89.8(3) . . ?
O10 W3 O11 104.3(3) . . ?
O12 W3 O11 89.2(3) . . ?
O8 W3 O11 152.3(3) . . ?
O10 W3 O3 94.9(3) . . ?
O12 W3 O3 164.6(3) . . ?
O8 W3 O3 87.4(3) . . ?
O11 W3 O3 86.3(3) . . ?
O10 W3 O6 170.3(3) . . ?
O12 W3 O6 89.3(2) . . ?
O8 W3 O6 76.6(2) . . ?
O11 W3 O6 75.7(2) . . ?
O3 W3 O6 75.3(2) . . ?
O13 W4 O14 99.9(3) . . ?
O13 W4 O11 103.6(3) . . ?
O14 W4 O11 90.4(3) . . ?
O13 W4 O16 103.2(3) . . ?
O14 W4 O16 90.7(3) . . ?
O11 W4 O16 152.6(3) . . ?
O13 W4 O4 94.7(3) . . ?
O14 W4 O4 165.4(3) . . ?
O11 W4 O4 86.1(3) . . ?
O16 W4 O4 86.0(3) . . ?
O13 W4 O6 170.1(3) . . ?
O14 W4 O6 90.0(2) . . ?
O11 W4 O6 76.1(2) . . ?
O16 W4 O6 76.5(2) . . ?
O4 W4 O6 75.4(2) . . ?
O15 W5 O12 100.6(3) . 2_666 ?
O15 W5 O9 103.2(3) . . ?
O12 W5 O9 89.4(3) 2_666 . ?
O15 W5 O16 103.9(3) . . ?
O12 W5 O16 88.1(3) 2_666 . ?
O9 W5 O16 152.8(2) . . ?
O15 W5 O5 94.8(3) . . ?
O12 W5 O5 164.5(2) 2_666 . ?
O9 W5 O5 88.0(3) . . ?
O16 W5 O5 87.3(3) . . ?
O15 W5 O6 170.5(3) . . ?
O12 W5 O6 88.9(2) 2_666 . ?
O9 W5 O6 76.5(2) . . ?
O16 W5 O6 76.4(2) . . ?
O5 W5 O6 75.7(2) . . ?
N4 Ru1 N5 84.8(3) . . ?
N4 Ru1 N6 172.9(3) . . ?
N5 Ru1 N6 89.0(3) . . ?
N4 Ru1 N1 94.9(3) . . ?
N5 Ru1 N1 96.5(3) . . ?
N6 Ru1 N1 89.2(3) . . ?
N4 Ru1 N2 93.2(3) . . ?
N5 Ru1 N2 174.6(3) . . ?
N6 Ru1 N2 93.2(3) . . ?
N1 Ru1 N2 78.7(3) . . ?
N4 Ru1 N3 79.2(3) . . ?
N5 Ru1 N3 92.0(3) . . ?
N6 Ru1 N3 97.6(3) . . ?
N1 Ru1 N3 169.1(3) . . ?
N2 Ru1 N3 92.5(3) . . ?
W2 O2 W1 116.1(3) . . ?
W1 O3 W3 116.7(3) . . ?
W1 O4 W4 116.6(3) . . ?
W1 O5 W5 116.7(3) . . ?
W1 O6 W4 90.96(18) . . ?
W1 O6 W3 91.15(18) . . ?
W4 O6 W3 90.39(19) . . ?
W1 O6 W2 91.1(2) . . ?
W4 O6 W2 178.0(3) . . ?
W3 O6 W2 89.82(18) . . ?
W1 O6 W5 90.90(18) . . ?
W4 O6 W5 90.20(18) . . ?
W3 O6 W5 177.9(3) . . ?
W2 O6 W5 89.52(19) . . ?
W3 O8 W2 117.1(3) . . ?
W5 O9 W2 117.4(3) . . ?
W4 O11 W3 117.7(3) . . ?
W5 O12 W3 176.2(3) 2_666 . ?
W4 O14 W2 174.6(4) . 2_666 ?
W5 O16 W4 116.9(3) . . ?
N1 C1 C2 122.9(9) . . ?
N1 C1 H1A 118.5 . . ?
C2 C1 H1A 118.5 . . ?
C1 C2 C3 118.8(10) . . ?
C1 C2 H2A 120.6 . . ?
C3 C2 H2A 120.6 . . ?
C4 C3 C2 118.9(10) . . ?
C4 C3 H3A 120.6 . . ?
C2 C3 H3A 120.6 . . ?
C3 C4 C5 119.8(9) . . ?
C3 C4 H4A 120.1 . . ?
C5 C4 H4A 120.1 . . ?
N1 C5 C4 122.7(9) . . ?
N1 C5 C6 113.9(8) . . ?
C4 C5 C6 123.4(8) . . ?
N2 C6 C7 121.7(9) . . ?
N2 C6 C5 114.8(8) . . ?
C7 C6 C5 123.5(9) . . ?
C6 C7 C8 119.2(9) . . ?
C6 C7 H7B 120.4 . . ?
C8 C7 H7B 120.4 . . ?
C9 C8 C7 118.8(9) . . ?
C9 C8 H8A 120.6 . . ?
C7 C8 H8A 120.6 . . ?
C8 C9 C10 118.8(10) . . ?
C8 C9 H9A 120.6 . . ?
C10 C9 H9A 120.6 . . ?
N2 C10 C9 123.6(10) . . ?
N2 C10 H10B 118.2 . . ?
C9 C10 H10B 118.2 . . ?
N3 C11 C12 122.7(11) . . ?
N3 C11 H11A 118.6 . . ?
C12 C11 H11A 118.6 . . ?
C13 C12 C11 118.5(12) . . ?
C13 C12 H12B 120.7 . . ?
C11 C12 H12B 120.7 . . ?
C12 C13 C14 119.4(11) . . ?
C12 C13 H13B 120.3 . . ?
C14 C13 H13B 120.3 . . ?
C13 C14 C15 120.0(11) . . ?
C13 C14 H14B 120.0 . . ?
C15 C14 H14B 120.0 . . ?
N3 C15 C14 120.5(10) . . ?
N3 C15 C16 114.7(9) . . ?
C14 C15 C16 124.7(10) . . ?
N4 C16 C17 119.8(11) . . ?
N4 C16 C15 115.6(9) . . ?
C17 C16 C15 124.5(11) . . ?
C18 C17 C16 120.6(13) . . ?
C18 C17 H17A 119.7 . . ?
C16 C17 H17A 119.7 . . ?
C19 C18 C17 118.2(12) . . ?
C19 C18 H18A 120.9 . . ?
C17 C18 H18A 120.9 . . ?
C18 C19 C20 120.9(13) . . ?
C18 C19 H19A 119.6 . . ?
C20 C19 H19A 119.6 . . ?
N4 C20 C19 121.7(12) . . ?
N4 C20 H20A 119.2 . . ?
C19 C20 H20A 119.2 . . ?
N5 C21 C22 178.6(13) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N6 C23 C24 176.7(12) . . ?
N7 C25 C26 167(3) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C1 N1 C5 116.8(8) . . ?
C1 N1 Ru1 126.8(6) . . ?
C5 N1 Ru1 116.2(6) . . ?
C10 N2 C6 117.8(8) . . ?
C10 N2 Ru1 126.6(6) . . ?
C6 N2 Ru1 115.6(6) . . ?
C11 N3 C15 118.7(9) . . ?
C11 N3 Ru1 127.0(7) . . ?
C15 N3 Ru1 114.0(6) . . ?
C16 N4 C20 118.8(9) . . ?
C16 N4 Ru1 115.9(7) . . ?
C20 N4 Ru1 124.9(7) . . ?
C21 N5 Ru1 175.3(8) . . ?
C23 N6 Ru1 174.3(8) . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.790
_refine_diff_density_min         -1.323
_refine_diff_density_rms         0.204
