# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_njy1
_database_code_depnum_ccdc_archive 'CCDC 1526285'
_audit_update_record             
;
2017-01-09 deposited with the CCDC.
2017-05-17 downloaded from the CCDC.
;
_audit_creation_date             2016-07-09
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C4 H16 N4 Na8 Nb10 Ni3 O58, 2(O)'
_chemical_formula_sum            'C4 H72 N4 Na8 Nb10 Ni3 O60'
_chemical_formula_weight         2425.80
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nb Nb -2.0727 0.6215 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.5635(8)
_cell_length_b                   12.9279(9)
_cell_length_c                   13.1370(9)
_cell_angle_alpha                61.8590(10)
_cell_angle_beta                 63.6420(10)
_cell_angle_gamma                61.2230(10)
_cell_volume                     1582.83(19)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    3147
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.25
_cell_measurement_theta_min      2.19
_shelx_estimated_absorpt_T_max   0.768
_shelx_estimated_absorpt_T_min   0.426
_exptl_absorpt_coefficient_mu    2.783
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.5961
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0592 before and 0.0311 after correction.
The Ratio of minimum to maximum transmission is 0.7994.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.545
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1186
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.1
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0193
_diffrn_reflns_av_unetI/netI     0.0405
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            8189
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.098
_diffrn_reflns_theta_max         25.098
_diffrn_reflns_theta_min         1.832
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4475
_reflns_number_total             5578
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS-1997 (Sheldrick, 2008)'
_refine_diff_density_max         1.718
_refine_diff_density_min         -1.041
_refine_diff_density_rms         0.163
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     238
_refine_ls_number_reflns         5578
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0545
_refine_ls_R_factor_gt           0.0411
_refine_ls_restrained_S_all      1.021
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0461P)²+9.6880P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0992
_refine_ls_wR_factor_ref         0.1077
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups, All N(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 N1(H1A,H1B), N2(H2A,H2B), C1(H1C,H1D), C2(H2C,H2D)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Nb1 Nb 0.59637(5) -0.12392(5) 0.30544(5) 0.01312(14) Uani 1 1 d . . . . .
Nb2 Nb 0.60720(5) -0.29665(5) 0.58911(5) 0.01386(14) Uani 1 1 d . . . . .
Nb3 Nb 0.74987(5) -0.12071(5) 0.57941(5) 0.01361(14) Uani 1 1 d . . . . .
Nb4 Nb 0.73965(5) 0.05176(5) 0.29457(5) 0.01304(14) Uani 1 1 d . . . . .
Nb5 Nb 0.87037(5) -0.26020(5) 0.37479(5) 0.01473(15) Uani 1 1 d . . . . .
Ni1 Ni 0.5000 0.0000 0.5000 0.0117(2) Uani 1 2 d S T P . .
Ni2 Ni 0.50651(8) -0.16180(8) 0.77204(8) 0.0174(2) Uani 1 1 d . . . . .
Na1 Na 0.8574(3) -0.0843(3) 0.0770(3) 0.0310(7) Uani 1 1 d . . . . .
Na2 Na 0.9393(3) -0.3417(3) -0.0102(3) 0.0306(7) Uani 1 1 d . . . . .
Na3 Na 1.2138(3) -0.3998(3) -0.3303(3) 0.0324(7) Uani 1 1 d . . . . .
Na4 Na 1.2229(4) -0.2273(3) -0.6321(3) 0.0515(9) Uani 1 1 d . . . . .
O1 O 1.0215(5) -0.3581(4) 0.3154(4) 0.0277(11) Uiso 1 1 d . . . . .
O2 O 0.5604(4) -0.4256(4) 0.7005(4) 0.0235(11) Uiso 1 1 d . . . . .
O3 O 0.5495(4) -0.1275(4) 0.1986(4) 0.0229(10) Uiso 1 1 d . . . . .
O4 O 0.7942(4) 0.1762(4) 0.1840(4) 0.0259(11) Uiso 1 1 d . . . . .
O5 O 0.8944(4) -0.2335(4) 0.4982(4) 0.0182(10) Uiso 1 1 d . . . . .
O6 O 0.8097(4) -0.1232(4) 0.6800(4) 0.0255(11) Uiso 1 1 d . . . . .
O7 O 0.7720(4) -0.2326(4) 0.2728(4) 0.0157(9) Uiso 1 1 d . . . . .
O8 O 0.8861(4) -0.0925(4) 0.2629(4) 0.0174(9) Uiso 1 1 d . . . . .
O9 O 0.7786(4) -0.3759(4) 0.5060(4) 0.0178(10) Uiso 1 1 d . . . . .
O10 O 0.7783(4) 0.0235(4) 0.4372(4) 0.0163(9) Uiso 1 1 d . . . . .
O11 O 0.6624(4) 0.0210(4) 0.2077(4) 0.0149(9) Uiso 1 1 d . . . . .
O12 O 0.5463(4) -0.2543(4) 0.4546(4) 0.0155(9) Uiso 1 1 d . . . . .
O13 O 0.6707(4) -0.1200(4) 0.4420(4) 0.0131(9) Uiso 1 1 d . . . . .
O14 O 0.6745(4) -0.2588(4) 0.6778(4) 0.0165(9) Uiso 1 1 d . . . . .
O15 O 0.4458(4) -0.1502(4) 0.6379(4) 0.0130(9) Uiso 1 1 d . . . . .
O16 O 0.5629(4) -0.0097(4) 0.6296(4) 0.0140(9) Uani 1 1 d . . . . .
N1 N 0.4504(6) -0.3090(5) 0.9060(5) 0.0271(14) Uiso 1 1 d . . . . .
H1A H 0.3671 -0.2826 0.9387 0.033 Uiso 1 1 calc R . . . .
H1B H 0.4702 -0.3670 0.8760 0.033 Uiso 1 1 calc R . . . .
N2 N 0.5677(6) -0.1722(6) 0.9009(5) 0.0289(14) Uiso 1 1 d . . . . .
H2A H 0.6519 -0.2013 0.8810 0.035 Uiso 1 1 calc R . . . .
H2B H 0.5405 -0.0965 0.9056 0.035 Uiso 1 1 calc R . . . .
C1 C 0.5167(7) -0.3613(7) 0.9974(7) 0.0313(17) Uiso 1 1 d . . . . .
H1C H 0.6030 -0.4142 0.9705 0.038 Uiso 1 1 calc R . . . .
H1D H 0.4743 -0.4117 1.0723 0.038 Uiso 1 1 calc R . . . .
C2 C 0.5171(8) -0.2560(7) 1.0169(7) 0.0352(18) Uiso 1 1 d . . . . .
H2C H 0.4317 -0.2102 1.0546 0.042 Uiso 1 1 calc R . . . .
H2D H 0.5688 -0.2891 1.0697 0.042 Uiso 1 1 calc R . . . .
O1W O 1.2948(5) -0.2354(5) -0.4875(4) 0.0289(11) Uiso 1 1 d . . . . .
O2W O 1.1336(5) -0.3849(5) -0.4739(5) 0.0328(12) Uiso 1 1 d . . . . .
O3W O 1.3044(5) -0.0600(5) -0.7910(5) 0.0306(12) Uiso 1 1 d . . . . .
O4W O 1.3071(5) -0.4135(5) -0.1967(5) 0.0305(12) Uiso 1 1 d . . . . .
O5W O 1.1213(5) -0.5606(5) -0.2035(5) 0.0307(12) Uiso 1 1 d . . . . .
O6W O 1.0209(5) -0.2511(5) -0.2280(5) 0.0388(13) Uiso 1 1 d . . . . .
O7W O 1.0424(5) -0.2512(5) 0.0304(5) 0.0338(12) Uiso 1 1 d . . . . .
O8W O 0.8550(5) -0.4679(5) -0.0095(5) 0.0356(13) Uiso 1 1 d . . . . .
O9W O 0.7614(5) -0.1454(5) -0.0029(5) 0.0330(12) Uiso 1 1 d . . . . .
O10W O 1.2546(6) -0.3322(6) -0.7592(6) 0.0480(15) Uiso 1 1 d . . . . .
O11W O 0.1468(6) 0.4616(6) 0.2176(6) 0.0477(15) Uiso 1 1 d . . . . .
O12W O 0.8864(6) 0.0770(6) -0.0989(6) 0.0562(17) Uiso 1 1 d . . . . .
O13W O 1.0472(8) -0.0486(8) -0.6074(7) 0.082(2) Uiso 1 1 d . . . . .
O14W O 1.4147(10) -0.5541(9) -0.3895(9) 0.107(3) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Nb1 Nb2 3.3467(8) . ?
Nb1 Nb5 3.3489(8) . ?
Nb1 Ni1 3.1324(6) . ?
Nb1 Ni2 3.0619(10) 2_656 ?
Nb1 Na1 3.384(3) . ?
Nb1 O3 1.773(5) . ?
Nb1 O7 1.941(4) . ?
Nb1 O11 2.032(4) . ?
Nb1 O12 1.972(4) . ?
Nb1 O13 2.390(4) . ?
Nb1 O16 2.064(4) 2_656 ?
Nb2 Nb5 3.3261(8) . ?
Nb2 Ni1 3.1755(6) . ?
Nb2 Ni2 3.0892(10) . ?
Nb2 O2 1.773(5) . ?
Nb2 O9 1.929(4) . ?
Nb2 O12 1.973(4) . ?
Nb2 O13 2.410(4) . ?
Nb2 O14 2.030(4) . ?
Nb2 O15 2.098(4) . ?
Nb3 Nb4 3.3573(8) . ?
Nb3 Nb5 3.3317(8) . ?
Nb3 Ni1 3.1677(6) . ?
Nb3 Ni2 3.0757(10) . ?
Nb3 O5 1.939(4) . ?
Nb3 O6 1.770(5) . ?
Nb3 O10 1.964(4) . ?
Nb3 O13 2.412(4) . ?
Nb3 O14 2.029(4) . ?
Nb3 O16 2.070(4) . ?
Nb4 Nb5 3.3501(8) . ?
Nb4 Ni1 3.1332(6) . ?
Nb4 Ni2 3.0571(10) 2_656 ?
Nb4 Na1 3.455(3) . ?
Nb4 O4 1.773(5) . ?
Nb4 O8 1.945(4) . ?
Nb4 O10 1.968(4) . ?
Nb4 O11 2.046(4) . ?
Nb4 O13 2.395(4) . ?
Nb4 O15 2.052(4) 2_656 ?
Nb5 Na1 3.510(3) . ?
Nb5 O1 1.766(5) . ?
Nb5 O5 1.976(4) . ?
Nb5 O7 2.012(4) . ?
Nb5 O8 2.012(4) . ?
Nb5 O9 2.000(4) . ?
Nb5 O13 2.350(4) . ?
Ni1 Nb1 3.1324(6) 2_656 ?
Ni1 Nb3 3.1677(6) 2_656 ?
Ni1 Nb4 3.1332(6) 2_656 ?
Ni1 O13 2.012(4) . ?
Ni1 O13 2.012(4) 2_656 ?
Ni1 O15 2.092(4) . ?
Ni1 O15 2.091(4) 2_656 ?
Ni1 O16 2.107(4) . ?
Ni1 O16 2.107(4) 2_656 ?
Ni2 Nb1 3.0619(10) 2_656 ?
Ni2 Nb4 3.0571(10) 2_656 ?
Ni2 O11 2.031(4) 2_656 ?
Ni2 O14 2.039(4) . ?
Ni2 O15 2.132(4) . ?
Ni2 O16 2.136(4) . ?
Ni2 N1 2.061(6) . ?
Ni2 N2 2.078(6) . ?
Na1 Na2 3.563(4) . ?
Na1 O7 2.514(5) . ?
Na1 O8 2.570(5) . ?
Na1 O11 2.462(5) . ?
Na1 O7W 2.363(6) . ?
Na1 O9W 2.450(6) . ?
Na1 O12W 2.294(7) . ?
Na2 Na2 3.530(6) 2_745 ?
Na2 Na3 4.214(4) . ?
Na2 O5W 2.395(6) 2_745 ?
Na2 O6W 2.450(6) . ?
Na2 O7W 2.448(6) . ?
Na2 O8W 2.330(6) . ?
Na2 O8W 2.583(6) 2_745 ?
Na2 O9W 2.454(6) . ?
Na3 Na4 3.494(5) . ?
Na3 O1W 2.428(6) . ?
Na3 O2W 2.402(6) . ?
Na3 O4W 2.413(6) . ?
Na3 O5W 2.406(6) . ?
Na3 O6W 2.537(6) . ?
Na3 O14W 2.414(11) . ?
Na4 O1W 2.384(6) . ?
Na4 O2W 2.422(6) . ?
Na4 O3W 2.461(6) . ?
Na4 O10W 2.410(7) . ?
Na4 O13W 2.341(9) . ?
O11 Ni2 2.030(4) 2_656 ?
O15 Nb4 2.052(4) 2_656 ?
O16 Nb1 2.064(4) 2_656 ?
N1 H1A 0.8900 . ?
N1 H1B 0.8900 . ?
N1 C1 1.474(9) . ?
N2 H2A 0.8900 . ?
N2 H2B 0.8900 . ?
N2 C2 1.465(9) . ?
C1 H1C 0.9700 . ?
C1 H1D 0.9700 . ?
C1 C2 1.501(10) . ?
C2 H2C 0.9700 . ?
C2 H2D 0.9700 . ?
O5W Na2 2.395(6) 2_745 ?
O8W Na2 2.583(6) 2_745 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Nb2 Nb1 Nb5 59.572(17) . . ?
Nb2 Nb1 Na1 122.39(5) . . ?
Nb5 Nb1 Na1 62.83(5) . . ?
Ni1 Nb1 Nb2 58.585(14) . . ?
Ni1 Nb1 Nb5 84.524(17) . . ?
Ni1 Nb1 Na1 117.57(5) . . ?
Ni2 Nb1 Nb2 120.64(2) 2_656 . ?
Ni2 Nb1 Nb5 114.87(2) 2_656 . ?
Ni2 Nb1 Ni1 62.053(19) 2_656 . ?
Ni2 Nb1 Na1 84.54(5) 2_656 . ?
O3 Nb1 Nb2 135.64(15) . . ?
O3 Nb1 Nb5 132.89(15) . . ?
O3 Nb1 Ni1 142.52(15) . . ?
O3 Nb1 Ni2 93.70(15) . 2_656 ?
O3 Nb1 Na1 85.16(16) . . ?
O3 Nb1 O7 100.1(2) . . ?
O3 Nb1 O11 101.47(19) . . ?
O3 Nb1 O12 104.22(19) . . ?
O3 Nb1 O13 176.90(18) . . ?
O3 Nb1 O16 100.73(19) . 2_656 ?
O7 Nb1 Nb2 81.31(13) . . ?
O7 Nb1 Nb5 32.75(13) . . ?
O7 Nb1 Ni1 117.24(13) . . ?
O7 Nb1 Ni2 127.66(12) . 2_656 ?
O7 Nb1 Na1 47.37(13) . . ?
O7 Nb1 O11 86.63(17) . . ?
O7 Nb1 O12 92.13(17) . . ?
O7 Nb1 O13 77.29(16) . . ?
O7 Nb1 O16 158.08(17) . 2_656 ?
O11 Nb1 Nb2 122.81(12) . . ?
O11 Nb1 Nb5 81.29(12) . . ?
O11 Nb1 Ni1 79.28(12) . . ?
O11 Nb1 Ni2 41.07(12) . 2_656 ?
O11 Nb1 Na1 46.21(13) . . ?
O11 Nb1 O13 76.76(15) . . ?
O11 Nb1 O16 82.76(16) . 2_656 ?
O12 Nb1 Nb2 31.96(12) . . ?
O12 Nb1 Nb5 83.75(12) . . ?
O12 Nb1 Ni1 78.33(12) . . ?
O12 Nb1 Ni2 132.71(12) . 2_656 ?
O12 Nb1 Na1 139.47(13) . . ?
O12 Nb1 O11 154.09(17) . . ?
O12 Nb1 O13 77.72(15) . . ?
O12 Nb1 O16 89.18(17) . 2_656 ?
O13 Nb1 Nb2 46.05(9) . . ?
O13 Nb1 Nb5 44.56(10) . . ?
O13 Nb1 Ni1 39.97(10) . . ?
O13 Nb1 Ni2 86.61(10) . 2_656 ?
O13 Nb1 Na1 91.80(11) . . ?
O16 Nb1 Nb2 88.41(11) 2_656 . ?
O16 Nb1 Nb5 126.04(12) 2_656 . ?
O16 Nb1 Ni1 41.84(11) 2_656 . ?
O16 Nb1 Ni2 44.13(11) 2_656 2_656 ?
O16 Nb1 Na1 128.36(13) 2_656 . ?
O16 Nb1 O13 81.63(15) 2_656 . ?
Nb5 Nb2 Nb1 60.247(17) . . ?
Ni1 Nb2 Nb1 57.334(13) . . ?
Ni1 Nb2 Nb5 84.236(16) . . ?
Ni2 Nb2 Nb1 118.61(2) . . ?
Ni2 Nb2 Nb5 114.81(2) . . ?
Ni2 Nb2 Ni1 61.274(18) . . ?
O2 Nb2 Nb1 135.93(15) . . ?
O2 Nb2 Nb5 135.60(15) . . ?
O2 Nb2 Ni1 140.12(15) . . ?
O2 Nb2 Ni2 92.70(15) . . ?
O2 Nb2 O9 102.8(2) . . ?
O2 Nb2 O12 104.22(19) . . ?
O2 Nb2 O13 178.43(18) . . ?
O2 Nb2 O14 102.15(19) . . ?
O2 Nb2 O15 99.55(19) . . ?
O9 Nb2 Nb1 80.86(13) . . ?
O9 Nb2 Nb5 32.82(13) . . ?
O9 Nb2 Ni1 117.05(13) . . ?
O9 Nb2 Ni2 130.25(13) . . ?
O9 Nb2 O12 91.20(18) . . ?
O9 Nb2 O13 77.74(16) . . ?
O9 Nb2 O14 89.61(18) . . ?
O9 Nb2 O15 157.22(17) . . ?
O12 Nb2 Nb1 31.94(12) . . ?
O12 Nb2 Nb5 84.36(12) . . ?
O12 Nb2 Ni1 77.21(12) . . ?
O12 Nb2 Ni2 130.48(12) . . ?
O12 Nb2 O13 77.20(15) . . ?
O12 Nb2 O14 152.75(17) . . ?
O12 Nb2 O15 87.45(17) . . ?
O13 Nb2 Nb1 45.54(10) . . ?
O13 Nb2 Nb5 44.93(10) . . ?
O13 Nb2 Ni1 39.31(9) . . ?
O13 Nb2 Ni2 85.83(10) . . ?
O14 Nb2 Nb1 121.88(12) . . ?
O14 Nb2 Nb5 81.66(12) . . ?
O14 Nb2 Ni1 78.20(12) . . ?
O14 Nb2 Ni2 40.71(12) . . ?
O14 Nb2 O13 76.36(15) . . ?
O14 Nb2 O15 81.48(16) . . ?
O15 Nb2 Nb1 86.11(11) . . ?
O15 Nb2 Nb5 124.56(11) . . ?
O15 Nb2 Ni1 40.64(11) . . ?
O15 Nb2 Ni2 43.51(11) . . ?
O15 Nb2 O13 79.79(15) . . ?
Nb5 Nb3 Nb4 60.109(17) . . ?
Ni1 Nb3 Nb4 57.307(13) . . ?
Ni1 Nb3 Nb5 84.265(16) . . ?
Ni2 Nb3 Nb4 118.81(2) . . ?
Ni2 Nb3 Nb5 115.03(2) . . ?
Ni2 Nb3 Ni1 61.504(19) . . ?
O5 Nb3 Nb4 80.78(13) . . ?
O5 Nb3 Nb5 32.00(13) . . ?
O5 Nb3 Ni1 116.27(13) . . ?
O5 Nb3 Ni2 129.35(13) . . ?
O5 Nb3 O10 90.38(18) . . ?
O5 Nb3 O13 76.84(16) . . ?
O5 Nb3 O14 88.43(17) . . ?
O5 Nb3 O16 156.86(18) . . ?
O6 Nb3 Nb4 134.75(15) . . ?
O6 Nb3 Nb5 134.42(16) . . ?
O6 Nb3 Ni1 141.32(16) . . ?
O6 Nb3 Ni2 94.21(16) . . ?
O6 Nb3 O5 102.4(2) . . ?
O6 Nb3 O10 103.6(2) . . ?
O6 Nb3 O13 179.21(19) . . ?
O6 Nb3 O14 103.4(2) . . ?
O6 Nb3 O16 100.33(19) . . ?
O10 Nb3 Nb4 31.39(12) . . ?
O10 Nb3 Nb5 83.04(13) . . ?
O10 Nb3 Ni1 77.62(12) . . ?
O10 Nb3 Ni2 131.66(13) . . ?
O10 Nb3 O13 76.73(16) . . ?
O10 Nb3 O14 152.58(17) . . ?
O10 Nb3 O16 88.43(17) . . ?
O13 Nb3 Nb4 45.49(9) . . ?
O13 Nb3 Nb5 44.84(10) . . ?
O13 Nb3 Ni1 39.43(9) . . ?
O13 Nb3 Ni2 86.10(10) . . ?
O14 Nb3 Nb4 121.80(12) . . ?
O14 Nb3 Nb5 81.53(12) . . ?
O14 Nb3 Ni1 78.40(12) . . ?
O14 Nb3 Ni2 41.00(12) . . ?
O14 Nb3 O13 76.33(15) . . ?
O14 Nb3 O16 82.16(17) . . ?
O16 Nb3 Nb4 86.30(11) . . ?
O16 Nb3 Nb5 125.11(12) . . ?
O16 Nb3 Ni1 41.11(11) . . ?
O16 Nb3 Ni2 43.86(11) . . ?
O16 Nb3 O13 80.40(15) . . ?
Nb3 Nb4 Na1 121.63(5) . . ?
Nb5 Nb4 Nb3 59.566(16) . . ?
Nb5 Nb4 Na1 62.08(5) . . ?
Ni1 Nb4 Nb3 58.302(14) . . ?
Ni1 Nb4 Nb5 84.493(16) . . ?
Ni1 Nb4 Na1 115.51(5) . . ?
Ni2 Nb4 Nb3 120.40(2) 2_656 . ?
Ni2 Nb4 Nb5 114.97(2) 2_656 . ?
Ni2 Nb4 Ni1 62.096(19) 2_656 . ?
Ni2 Nb4 Na1 83.41(5) 2_656 . ?
O4 Nb4 Nb3 134.18(16) . . ?
O4 Nb4 Nb5 134.04(16) . . ?
O4 Nb4 Ni1 141.47(16) . . ?
O4 Nb4 Ni2 94.20(15) . 2_656 ?
O4 Nb4 Na1 88.95(16) . . ?
O4 Nb4 O8 101.3(2) . . ?
O4 Nb4 O10 103.1(2) . . ?
O4 Nb4 O11 103.49(19) . . ?
O4 Nb4 O13 178.57(19) . . ?
O4 Nb4 O15 100.29(19) . 2_656 ?
O8 Nb4 Nb3 81.85(13) . . ?
O8 Nb4 Nb5 32.77(13) . . ?
O8 Nb4 Ni1 117.19(13) . . ?
O8 Nb4 Ni2 127.19(13) . 2_656 ?
O8 Nb4 Na1 47.30(14) . . ?
O8 Nb4 O10 91.50(18) . . ?
O8 Nb4 O11 85.98(17) . . ?
O8 Nb4 O13 77.26(16) . . ?
O8 Nb4 O15 157.39(17) . 2_656 ?
O10 Nb4 Nb3 31.32(12) . . ?
O10 Nb4 Nb5 82.49(12) . . ?
O10 Nb4 Ni1 78.47(12) . . ?
O10 Nb4 Ni2 133.47(13) . 2_656 ?
O10 Nb4 Na1 138.78(13) . . ?
O10 Nb4 O11 153.25(17) . . ?
O10 Nb4 O13 77.09(16) . . ?
O10 Nb4 O15 90.02(17) . 2_656 ?
O11 Nb4 Nb3 122.30(12) . . ?
O11 Nb4 Nb5 81.07(12) . . ?
O11 Nb4 Ni1 79.08(12) . . ?
O11 Nb4 Ni2 41.22(12) . 2_656 ?
O11 Nb4 Na1 44.65(13) . . ?
O11 Nb4 O13 76.39(15) . . ?
O11 Nb4 O15 82.59(16) . 2_656 ?
O13 Nb4 Nb3 45.91(10) . . ?
O13 Nb4 Nb5 44.54(10) . . ?
O13 Nb4 Ni1 39.95(10) . . ?
O13 Nb4 Ni2 86.63(10) . 2_656 ?
O13 Nb4 Na1 90.00(11) . . ?
O15 Nb4 Nb3 87.87(11) 2_656 . ?
O15 Nb4 Nb5 125.51(11) 2_656 . ?
O15 Nb4 Ni1 41.35(11) 2_656 . ?
O15 Nb4 Ni2 44.08(11) 2_656 2_656 ?
O15 Nb4 Na1 126.89(13) 2_656 . ?
O15 Nb4 O13 81.12(15) 2_656 . ?
Nb1 Nb5 Nb4 61.756(16) . . ?
Nb1 Nb5 Na1 59.07(5) . . ?
Nb2 Nb5 Nb1 60.180(17) . . ?
Nb2 Nb5 Nb3 62.272(17) . . ?
Nb2 Nb5 Nb4 92.059(19) . . ?
Nb2 Nb5 Na1 119.24(5) . . ?
Nb3 Nb5 Nb1 91.902(19) . . ?
Nb3 Nb5 Nb4 60.325(17) . . ?
Nb3 Nb5 Na1 120.74(5) . . ?
Nb4 Nb5 Na1 60.42(5) . . ?
O1 Nb5 Nb1 132.92(16) . . ?
O1 Nb5 Nb2 136.83(16) . . ?
O1 Nb5 Nb3 135.02(16) . . ?
O1 Nb5 Nb4 131.08(16) . . ?
O1 Nb5 Na1 87.22(17) . . ?
O1 Nb5 O5 103.8(2) . . ?
O1 Nb5 O7 101.5(2) . . ?
O1 Nb5 O8 99.5(2) . . ?
O1 Nb5 O9 105.3(2) . . ?
O1 Nb5 O13 176.38(19) . . ?
O5 Nb5 Nb1 123.23(13) . . ?
O5 Nb5 Nb2 82.30(13) . . ?
O5 Nb5 Nb3 31.33(12) . . ?
O5 Nb5 Nb4 80.51(12) . . ?
O5 Nb5 Na1 134.30(13) . . ?
O5 Nb5 O7 154.66(18) . . ?
O5 Nb5 O8 88.03(18) . . ?
O5 Nb5 O9 89.15(18) . . ?
O5 Nb5 O13 77.70(16) . . ?
O7 Nb5 Nb1 31.47(12) . . ?
O7 Nb5 Nb2 80.95(12) . . ?
O7 Nb5 Nb3 123.34(12) . . ?
O7 Nb5 Nb4 81.23(12) . . ?
O7 Nb5 Na1 44.66(13) . . ?
O7 Nb5 O13 76.97(16) . . ?
O8 Nb5 Nb1 80.88(12) . . ?
O8 Nb5 Nb2 123.54(12) . . ?
O8 Nb5 Nb3 81.66(13) . . ?
O8 Nb5 Nb4 31.56(12) . . ?
O8 Nb5 Na1 46.27(13) . . ?
O8 Nb5 O7 85.54(17) . . ?
O8 Nb5 O13 77.15(16) . . ?
O9 Nb5 Nb1 79.92(12) . . ?
O9 Nb5 Nb2 31.52(12) . . ?
O9 Nb5 Nb3 83.05(13) . . ?
O9 Nb5 Nb4 123.57(12) . . ?
O9 Nb5 Na1 131.09(13) . . ?
O9 Nb5 O7 86.44(17) . . ?
O9 Nb5 O8 154.95(18) . . ?
O9 Nb5 O13 77.93(16) . . ?
O13 Nb5 Nb1 45.53(10) . . ?
O13 Nb5 Nb2 46.42(10) . . ?
O13 Nb5 Nb3 46.38(10) . . ?
O13 Nb5 Nb4 45.64(10) . . ?
O13 Nb5 Na1 89.41(11) . . ?
Nb1 Ni1 Nb1 180.000(17) 2_656 . ?
Nb1 Ni1 Nb3 80.693(14) . 2_656 ?
Nb1 Ni1 Nb3 99.307(14) . . ?
Nb1 Ni1 Nb3 99.308(14) 2_656 2_656 ?
Nb1 Ni1 Nb3 80.692(14) 2_656 . ?
Nb1 Ni1 Nb4 66.556(14) 2_656 2_656 ?
Nb1 Ni1 Nb4 113.444(15) . 2_656 ?
Nb1 Ni1 Nb4 113.443(14) 2_656 . ?
Nb1 Ni1 Nb4 66.557(14) . . ?
Nb3 Ni1 Nb3 180.0 . 2_656 ?
Nb4 Ni1 Nb3 115.609(15) 2_656 . ?
Nb4 Ni1 Nb3 115.609(15) . 2_656 ?
Nb4 Ni1 Nb3 64.392(15) 2_656 2_656 ?
Nb4 Ni1 Nb3 64.391(15) . . ?
Nb4 Ni1 Nb4 180.0 2_656 . ?
O13 Ni1 Nb1 130.28(11) 2_656 . ?
O13 Ni1 Nb1 130.28(11) . 2_656 ?
O13 Ni1 Nb1 49.72(11) 2_656 2_656 ?
O13 Ni1 Nb1 49.72(11) . . ?
O13 Ni1 Nb3 49.59(11) . . ?
O13 Ni1 Nb3 130.41(11) 2_656 . ?
O13 Ni1 Nb3 130.41(11) . 2_656 ?
O13 Ni1 Nb3 49.59(11) 2_656 2_656 ?
O13 Ni1 Nb4 49.85(11) 2_656 2_656 ?
O13 Ni1 Nb4 49.85(11) . . ?
O13 Ni1 Nb4 130.15(11) 2_656 . ?
O13 Ni1 Nb4 130.15(11) . 2_656 ?
O13 Ni1 O13 180.0 . 2_656 ?
O13 Ni1 O15 89.95(16) 2_656 2_656 ?
O13 Ni1 O15 89.95(16) . . ?
O13 Ni1 O15 90.05(16) . 2_656 ?
O13 Ni1 O15 90.05(16) 2_656 . ?
O13 Ni1 O16 90.33(16) . 2_656 ?
O13 Ni1 O16 89.67(16) 2_656 2_656 ?
O13 Ni1 O16 90.33(16) 2_656 . ?
O13 Ni1 O16 89.67(16) . . ?
O15 Ni1 Nb1 87.98(11) . 2_656 ?
O15 Ni1 Nb1 92.02(11) 2_656 2_656 ?
O15 Ni1 Nb1 92.02(11) . . ?
O15 Ni1 Nb1 87.98(11) 2_656 . ?
O15 Ni1 Nb3 92.43(11) . 2_656 ?
O15 Ni1 Nb3 87.57(11) . . ?
O15 Ni1 Nb3 87.57(11) 2_656 2_656 ?
O15 Ni1 Nb3 92.43(11) 2_656 . ?
O15 Ni1 Nb4 40.41(11) 2_656 . ?
O15 Ni1 Nb4 139.59(11) . . ?
O15 Ni1 Nb4 40.41(11) . 2_656 ?
O15 Ni1 Nb4 139.59(11) 2_656 2_656 ?
O15 Ni1 O15 180.0(2) 2_656 . ?
O15 Ni1 O16 82.88(16) 2_656 2_656 ?
O15 Ni1 O16 97.12(16) 2_656 . ?
O15 Ni1 O16 97.12(16) . 2_656 ?
O15 Ni1 O16 82.88(16) . . ?
O16 Ni1 Nb1 40.82(11) 2_656 . ?
O16 Ni1 Nb1 139.19(11) 2_656 2_656 ?
O16 Ni1 Nb1 40.82(11) . 2_656 ?
O16 Ni1 Nb1 139.18(11) . . ?
O16 Ni1 Nb3 139.76(11) . 2_656 ?
O16 Ni1 Nb3 40.24(11) 2_656 2_656 ?
O16 Ni1 Nb3 139.76(11) 2_656 . ?
O16 Ni1 Nb3 40.24(11) . . ?
O16 Ni1 Nb4 91.75(11) 2_656 2_656 ?
O16 Ni1 Nb4 91.74(11) . . ?
O16 Ni1 Nb4 88.25(11) 2_656 . ?
O16 Ni1 Nb4 88.25(11) . 2_656 ?
O16 Ni1 O16 180.0 2_656 . ?
Nb1 Ni2 Nb2 120.75(3) 2_656 . ?
Nb1 Ni2 Nb3 83.30(2) 2_656 . ?
Nb3 Ni2 Nb2 67.89(2) . . ?
Nb4 Ni2 Nb1 68.37(2) 2_656 2_656 ?
Nb4 Ni2 Nb2 83.39(3) 2_656 . ?
Nb4 Ni2 Nb3 120.79(3) 2_656 . ?
O11 Ni2 Nb1 41.10(12) 2_656 2_656 ?
O11 Ni2 Nb2 123.65(12) 2_656 . ?
O11 Ni2 Nb3 123.18(12) 2_656 . ?
O11 Ni2 Nb4 41.60(12) 2_656 2_656 ?
O11 Ni2 O14 155.41(18) 2_656 . ?
O11 Ni2 O15 81.01(16) 2_656 . ?
O11 Ni2 O16 81.02(16) 2_656 . ?
O11 Ni2 N1 98.8(2) 2_656 . ?
O11 Ni2 N2 99.3(2) 2_656 . ?
O14 Ni2 Nb1 122.61(12) . 2_656 ?
O14 Ni2 Nb2 40.50(12) . . ?
O14 Ni2 Nb3 40.77(12) . . ?
O14 Ni2 Nb4 122.49(12) . 2_656 ?
O14 Ni2 O15 80.45(16) . . ?
O14 Ni2 O16 80.32(16) . . ?
O14 Ni2 N1 99.3(2) . . ?
O14 Ni2 N2 99.0(2) . . ?
O15 Ni2 Nb1 89.14(11) . 2_656 ?
O15 Ni2 Nb2 42.65(11) . . ?
O15 Ni2 Nb3 89.31(11) . . ?
O15 Ni2 Nb4 42.05(11) . 2_656 ?
O15 Ni2 O16 81.24(16) . . ?
O16 Ni2 Nb1 42.29(11) . 2_656 ?
O16 Ni2 Nb2 89.39(12) . . ?
O16 Ni2 Nb3 42.17(11) . . ?
O16 Ni2 Nb4 89.76(11) . 2_656 ?
N1 Ni2 Nb1 138.02(17) . 2_656 ?
N1 Ni2 Nb2 89.28(17) . . ?
N1 Ni2 Nb3 137.97(17) . . ?
N1 Ni2 Nb4 89.03(17) . 2_656 ?
N1 Ni2 O15 97.1(2) . . ?
N1 Ni2 O16 178.3(2) . . ?
N1 Ni2 N2 83.7(2) . . ?
N2 Ni2 Nb1 90.60(17) . 2_656 ?
N2 Ni2 Nb2 137.05(18) . . ?
N2 Ni2 Nb3 89.87(17) . . ?
N2 Ni2 Nb4 138.47(18) . 2_656 ?
N2 Ni2 O15 179.2(2) . . ?
N2 Ni2 O16 98.0(2) . . ?
Nb1 Na1 Nb4 60.35(5) . . ?
Nb1 Na1 Nb5 58.10(5) . . ?
Nb1 Na1 Na2 97.16(8) . . ?
Nb4 Na1 Nb5 57.50(5) . . ?
Nb4 Na1 Na2 151.20(10) . . ?
Nb5 Na1 Na2 96.16(8) . . ?
O7 Na1 Nb1 34.62(10) . . ?
O7 Na1 Nb4 73.14(12) . . ?
O7 Na1 Nb5 34.23(10) . . ?
O7 Na1 Na2 78.28(13) . . ?
O7 Na1 O8 65.02(15) . . ?
O8 Na1 Nb1 73.54(12) . . ?
O8 Na1 Nb4 33.81(10) . . ?
O8 Na1 Nb5 34.46(10) . . ?
O8 Na1 Na2 127.28(15) . . ?
O11 Na1 Nb1 36.56(10) . . ?
O11 Na1 Nb4 35.72(10) . . ?
O11 Na1 Nb5 72.84(12) . . ?
O11 Na1 Na2 131.55(15) . . ?
O11 Na1 O7 66.43(15) . . ?
O11 Na1 O8 65.46(15) . . ?
O7W Na1 Nb1 123.72(16) . . ?
O7W Na1 Nb4 132.78(17) . . ?
O7W Na1 Nb5 84.18(15) . . ?
O7W Na1 Na2 43.13(14) . . ?
O7W Na1 O7 90.79(19) . . ?
O7W Na1 O8 99.06(19) . . ?
O7W Na1 O11 156.0(2) . . ?
O7W Na1 O9W 85.5(2) . . ?
O9W Na1 Nb1 77.39(14) . . ?
O9W Na1 Nb4 133.63(16) . . ?
O9W Na1 Nb5 115.86(15) . . ?
O9W Na1 Na2 43.45(14) . . ?
O9W Na1 O7 83.05(18) . . ?
O9W Na1 O8 147.7(2) . . ?
O9W Na1 O11 98.32(19) . . ?
O12W Na1 Nb1 132.3(2) . . ?
O12W Na1 Nb4 102.96(19) . . ?
O12W Na1 Nb5 152.9(2) . . ?
O12W Na1 Na2 105.7(2) . . ?
O12W Na1 O7 166.6(2) . . ?
O12W Na1 O8 118.9(2) . . ?
O12W Na1 O11 102.7(2) . . ?
O12W Na1 O7W 100.8(2) . . ?
O12W Na1 O9W 91.2(2) . . ?
Na1 Na2 Na3 123.56(9) . . ?
Na2 Na2 Na1 156.64(15) 2_745 . ?
Na2 Na2 Na3 68.51(10) 2_745 . ?
O5W Na2 Na1 81.54(15) 2_745 . ?
O5W Na2 Na2 79.36(16) 2_745 2_745 ?
O5W Na2 Na3 143.13(16) 2_745 . ?
O5W Na2 O6W 174.9(2) 2_745 . ?
O5W Na2 O7W 85.3(2) 2_745 . ?
O5W Na2 O8W 81.47(19) 2_745 2_745 ?
O5W Na2 O9W 93.1(2) 2_745 . ?
O6W Na2 Na1 99.25(16) . . ?
O6W Na2 Na2 98.63(18) . 2_745 ?
O6W Na2 Na3 32.96(14) . . ?
O6W Na2 O8W 93.9(2) . 2_745 ?
O6W Na2 O9W 90.9(2) . . ?
O7W Na2 Na1 41.30(14) . . ?
O7W Na2 Na2 123.20(19) . 2_745 ?
O7W Na2 Na3 97.20(15) . . ?
O7W Na2 O6W 92.0(2) . . ?
O7W Na2 O8W 82.63(19) . 2_745 ?
O7W Na2 O9W 83.62(19) . . ?
O8W Na2 Na1 122.30(16) 2_745 . ?
O8W Na2 Na1 142.99(18) . . ?
O8W Na2 Na2 41.28(13) 2_745 2_745 ?
O8W Na2 Na2 47.00(15) . 2_745 ?
O8W Na2 Na3 87.46(16) . . ?
O8W Na2 Na3 62.57(14) 2_745 . ?
O8W Na2 O5W 83.4(2) . 2_745 ?
O8W Na2 O6W 98.7(2) . . ?
O8W Na2 O7W 166.4(2) . . ?
O8W Na2 O8W 88.3(2) . 2_745 ?
O8W Na2 O9W 104.5(2) . . ?
O9W Na2 Na1 43.36(14) . . ?
O9W Na2 Na2 150.85(19) . 2_745 ?
O9W Na2 Na3 123.73(16) . . ?
O9W Na2 O8W 165.6(2) . 2_745 ?
Na4 Na3 Na2 131.47(11) . . ?
O1W Na3 Na2 120.62(16) . . ?
O1W Na3 Na4 42.94(14) . . ?
O1W Na3 O6W 93.6(2) . . ?
O2W Na3 Na2 114.99(16) . . ?
O2W Na3 Na4 43.82(14) . . ?
O2W Na3 O1W 86.71(19) . . ?
O2W Na3 O4W 176.2(2) . . ?
O2W Na3 O5W 82.48(19) . . ?
O2W Na3 O6W 99.8(2) . . ?
O2W Na3 O14W 93.2(3) . . ?
O4W Na3 Na2 68.66(14) . . ?
O4W Na3 Na4 133.17(17) . . ?
O4W Na3 O1W 90.43(19) . . ?
O4W Na3 O6W 82.9(2) . . ?
O4W Na3 O14W 84.3(3) . . ?
O5W Na3 Na2 65.31(15) . . ?
O5W Na3 Na4 126.23(17) . . ?
O5W Na3 O1W 169.2(2) . . ?
O5W Na3 O4W 100.3(2) . . ?
O5W Na3 O6W 88.9(2) . . ?
O5W Na3 O14W 90.3(3) . . ?
O6W Na3 Na2 31.71(14) . . ?
O6W Na3 Na4 100.79(17) . . ?
O14W Na3 Na2 138.2(3) . . ?
O14W Na3 Na4 90.3(3) . . ?
O14W Na3 O1W 89.6(3) . . ?
O14W Na3 O6W 166.8(3) . . ?
O1W Na4 Na3 43.92(14) . . ?
O1W Na4 O2W 87.2(2) . . ?
O1W Na4 O3W 93.0(2) . . ?
O1W Na4 O10W 145.7(3) . . ?
O2W Na4 Na3 43.36(14) . . ?
O2W Na4 O3W 177.5(3) . . ?
O3W Na4 Na3 136.97(18) . . ?
O10W Na4 Na3 118.25(19) . . ?
O10W Na4 O2W 83.5(2) . . ?
O10W Na4 O3W 97.7(2) . . ?
O13W Na4 Na3 99.1(2) . . ?
O13W Na4 O1W 91.9(3) . . ?
O13W Na4 O2W 99.0(3) . . ?
O13W Na4 O3W 78.5(3) . . ?
O13W Na4 O10W 122.2(3) . . ?
Nb3 O5 Nb5 116.7(2) . . ?
Nb1 O7 Nb5 115.8(2) . . ?
Nb1 O7 Na1 98.01(18) . . ?
Nb5 O7 Na1 101.10(18) . . ?
Nb4 O8 Nb5 115.7(2) . . ?
Nb4 O8 Na1 98.89(18) . . ?
Nb5 O8 Na1 99.27(18) . . ?
Nb2 O9 Nb5 115.7(2) . . ?
Nb3 O10 Nb4 117.3(2) . . ?
Nb1 O11 Nb4 115.0(2) . . ?
Nb1 O11 Na1 97.23(17) . . ?
Nb4 O11 Na1 99.63(17) . . ?
Ni2 O11 Nb1 97.84(18) 2_656 . ?
Ni2 O11 Nb4 97.18(18) 2_656 . ?
Ni2 O11 Na1 150.1(2) 2_656 . ?
Nb1 O12 Nb2 116.1(2) . . ?
Nb1 O13 Nb2 88.41(13) . . ?
Nb1 O13 Nb3 178.62(19) . . ?
Nb1 O13 Nb4 91.87(14) . . ?
Nb2 O13 Nb3 91.10(14) . . ?
Nb4 O13 Nb2 178.4(2) . . ?
Nb4 O13 Nb3 88.59(13) . . ?
Nb5 O13 Nb1 89.92(14) . . ?
Nb5 O13 Nb2 88.65(13) . . ?
Nb5 O13 Nb3 88.79(13) . . ?
Nb5 O13 Nb4 89.82(14) . . ?
Ni1 O13 Nb1 90.32(15) . . ?
Ni1 O13 Nb2 91.34(15) . . ?
Ni1 O13 Nb3 90.98(15) . . ?
Ni1 O13 Nb4 90.19(15) . . ?
Ni1 O13 Nb5 179.8(2) . . ?
Nb2 O14 Ni2 98.80(18) . . ?
Nb3 O14 Nb2 116.0(2) . . ?
Nb3 O14 Ni2 98.24(18) . . ?
Nb2 O15 Ni2 93.84(16) . . ?
Nb4 O15 Nb2 160.3(2) 2_656 . ?
Nb4 O15 Ni1 98.25(17) 2_656 . ?
Nb4 O15 Ni2 93.87(17) 2_656 . ?
Ni1 O15 Nb2 98.58(17) . . ?
Ni1 O15 Ni2 98.25(16) . . ?
Nb1 O16 Nb3 161.2(2) 2_656 . ?
Nb1 O16 Ni1 97.34(16) 2_656 . ?
Nb1 O16 Ni2 93.58(17) 2_656 . ?
Nb3 O16 Ni1 98.65(17) . . ?
Nb3 O16 Ni2 93.97(16) . . ?
Ni1 O16 Ni2 97.63(17) . . ?
Ni2 N1 H1A 110.2 . . ?
Ni2 N1 H1B 110.2 . . ?
H1A N1 H1B 108.5 . . ?
C1 N1 Ni2 107.5(4) . . ?
C1 N1 H1A 110.2 . . ?
C1 N1 H1B 110.2 . . ?
Ni2 N2 H2A 110.0 . . ?
Ni2 N2 H2B 110.0 . . ?
H2A N2 H2B 108.4 . . ?
C2 N2 Ni2 108.3(5) . . ?
C2 N2 H2A 110.0 . . ?
C2 N2 H2B 110.0 . . ?
N1 C1 H1C 109.9 . . ?
N1 C1 H1D 109.9 . . ?
N1 C1 C2 109.0(6) . . ?
H1C C1 H1D 108.3 . . ?
C2 C1 H1C 109.9 . . ?
C2 C1 H1D 109.9 . . ?
N2 C2 C1 109.4(7) . . ?
N2 C2 H2C 109.8 . . ?
N2 C2 H2D 109.8 . . ?
C1 C2 H2C 109.8 . . ?
C1 C2 H2D 109.8 . . ?
H2C C2 H2D 108.2 . . ?
Na4 O1W Na3 93.1(2) . . ?
Na3 O2W Na4 92.8(2) . . ?
Na2 O5W Na3 132.6(2) 2_745 . ?
Na2 O6W Na3 115.3(2) . . ?
Na1 O7W Na2 95.6(2) . . ?
Na2 O8W Na2 91.7(2) . 2_745 ?
Na1 O9W Na2 93.2(2) . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
