# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Eupypptta
_database_code_depnum_ccdc_archive 'CCDC 1566126'
_audit_update_record             
;
2017-08-02 deposited with the CCDC.
2017-09-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_absolute_configuration rm
_chemical_formula_moiety         'C47.50 H26.50 Eu F9 N O7 S3'
_chemical_formula_sum            'C47.50 H26.50 Eu F9 N O7 S3'
_chemical_formula_weight         1142.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1
_symmetry_space_group_name_HALL  '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.5489(9)
_cell_length_b                   10.8247(9)
_cell_length_c                   21.7672(19)
_cell_angle_alpha                99.053(2)
_cell_angle_beta                 101.429(2)
_cell_angle_gamma                105.634(2)
_cell_volume                     2286.9(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9958
_cell_measurement_theta_min      2.42
_cell_measurement_theta_max      25.04

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.659
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1133
_exptl_absorpt_coefficient_mu    1.598
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7406
_exptl_absorpt_correction_T_max  0.7619
_exptl_absorpt_process_details   SADABS(Sheldrick,1997)

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            45431
_diffrn_reflns_av_R_equivalents  0.0588
_diffrn_reflns_av_sigmaI/netI    0.0462
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         2.00
_diffrn_reflns_theta_max         25.07
_reflns_number_total             8100
_reflns_number_gt                6954
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX II V2012.4-3'
_computing_cell_refinement       'Bruker APEX II V2012.4-3'
_computing_data_reduction        'Bruker APEX II V2012.4-3'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1000P)²+20.2067P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8100
_refine_ls_number_parameters     604
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0806
_refine_ls_R_factor_gt           0.0663
_refine_ls_wR_factor_ref         0.1867
_refine_ls_wR_factor_gt          0.1726
_refine_ls_goodness_of_fit_ref   1.109
_refine_ls_restrained_S_all      1.112
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6610(8) 1.0106(8) 0.7756(4) 0.0235(17) Uani 1 1 d . . .
H1 H 0.6261 1.0658 0.8014 0.028 Uiso 1 1 calc R . .
C2 C 0.7880(8) 1.0633(8) 0.7653(4) 0.0270(18) Uani 1 1 d . . .
H2 H 0.8386 1.1532 0.7832 0.032 Uiso 1 1 calc R . .
C3 C 0.8393(8) 0.9838(8) 0.7289(4) 0.0282(19) Uani 1 1 d . . .
H3 H 0.9270 1.0172 0.7219 0.034 Uiso 1 1 calc R . .
C4 C 0.7628(8) 0.8557(8) 0.7028(4) 0.0281(18) Uani 1 1 d . . .
H4 H 0.7964 0.7989 0.6772 0.034 Uiso 1 1 calc R . .
C5 C 0.6354(8) 0.8096(8) 0.7141(4) 0.0196(16) Uani 1 1 d . . .
C6 C 0.5368(8) 0.6722(8) 0.6840(4) 0.0212(16) Uani 1 1 d . . .
C7 C 0.5725(8) 0.5832(8) 0.6384(4) 0.0241(17) Uani 1 1 d . . .
H7 H 0.6609 0.6077 0.6311 0.029 Uiso 1 1 calc R . .
C8 C 0.4816(8) 0.4657(8) 0.6061(4) 0.0218(17) Uani 1 1 d . . .
H8 H 0.3972 0.4419 0.6175 0.026 Uiso 1 1 calc R . .
C9 C 0.5006(8) 0.3727(7) 0.5560(4) 0.0185(16) Uani 1 1 d . . .
C10 C 0.6118(8) 0.4097(8) 0.5287(4) 0.0221(17) Uani 1 1 d . . .
H10 H 0.6745 0.4959 0.5443 0.027 Uiso 1 1 calc R . .
C11 C 0.6324(8) 0.3259(8) 0.4806(4) 0.0223(17) Uani 1 1 d . . .
H11 H 0.7085 0.3544 0.4634 0.027 Uiso 1 1 calc R . .
C12 C 0.5423(8) 0.1987(8) 0.4567(4) 0.0195(16) Uani 1 1 d . . .
C13 C 0.5633(8) 0.1068(8) 0.4070(4) 0.0198(16) Uani 1 1 d . . .
H13 H 0.6400 0.1340 0.3900 0.024 Uiso 1 1 calc R . .
C14 C 0.4773(8) -0.0164(8) 0.3842(4) 0.0247(18) Uani 1 1 d . . .
H14 H 0.4949 -0.0745 0.3518 0.030 Uiso 1 1 calc R . .
C15 C 0.3595(8) -0.0616(8) 0.4079(4) 0.0220(17) Uani 1 1 d . . .
C16 C 0.2685(8) -0.1877(8) 0.3856(4) 0.0257(18) Uani 1 1 d . . .
H16 H 0.2833 -0.2474 0.3529 0.031 Uiso 1 1 calc R . .
C17 C 0.1573(9) -0.2280(8) 0.4098(4) 0.0284(19) Uani 1 1 d . . .
H17 H 0.0964 -0.3148 0.3935 0.034 Uiso 1 1 calc R . .
C18 C 0.1331(9) -0.1442(8) 0.4573(4) 0.0274(18) Uani 1 1 d . . .
H18 H 0.0564 -0.1740 0.4739 0.033 Uiso 1 1 calc R . .
C19 C 0.2200(8) -0.0164(8) 0.4811(4) 0.0226(17) Uani 1 1 d . . .
C20 C 0.2008(8) 0.0747(8) 0.5310(4) 0.0233(17) Uani 1 1 d . . .
H20 H 0.1242 0.0477 0.5480 0.028 Uiso 1 1 calc R . .
C21 C 0.2877(8) 0.1972(8) 0.5544(4) 0.0217(16) Uani 1 1 d . . .
H21 H 0.2701 0.2539 0.5874 0.026 Uiso 1 1 calc R . .
C22 C 0.4056(8) 0.2452(8) 0.5316(4) 0.0196(16) Uani 1 1 d . . .
C23 C 0.4279(8) 0.1575(7) 0.4819(3) 0.0179(15) Uani 1 1 d . . .
C24 C 0.3355(8) 0.0278(7) 0.4571(4) 0.0188(16) Uani 1 1 d . . .
C25 C 0.5544(8) 0.7316(8) 0.8951(4) 0.0242(17) Uani 1 1 d . . .
C26 C 0.6100(10) 0.6248(9) 0.9167(5) 0.038(2) Uani 1 1 d . . .
C27 C 0.5988(9) 0.8555(8) 0.9336(4) 0.0267(18) Uani 1 1 d . . .
H27 H 0.6618 0.8715 0.9740 0.032 Uiso 1 1 calc R . .
C28 C 0.5562(8) 0.9594(8) 0.9163(4) 0.0200(16) Uani 1 1 d . . .
C29 C 0.6134(8) 1.0922(8) 0.9586(4) 0.0206(16) Uani 1 1 d . . .
C30 C 0.7047(7) 1.1366(7) 1.0219(3) 0.0164(15) Uani 1 1 d . . .
H30 H 0.7427 1.0835 1.0460 0.020 Uiso 1 1 calc R . .
C31 C 0.7277(10) 1.2735(9) 1.0418(4) 0.037(2) Uani 1 1 d . . .
H31 H 0.7843 1.3235 1.0826 0.044 Uiso 1 1 calc R . .
C32 C 0.6650(11) 1.3271(9) 0.9995(5) 0.042(2) Uani 1 1 d . . .
H32 H 0.6735 1.4182 1.0070 0.051 Uiso 1 1 calc R . .
C33 C 0.0529(9) 0.6069(9) 0.7972(4) 0.032(2) Uani 1 1 d . . .
C34 C -0.0373(11) 0.4684(10) 0.7903(5) 0.045(3) Uani 1 1 d . . .
C35 C 0.0044(9) 0.7078(9) 0.8180(5) 0.035(2) Uani 1 1 d . . .
H35 H -0.0840 0.6878 0.8253 0.042 Uiso 1 1 calc R . .
C36 C 0.0851(8) 0.8422(8) 0.8286(4) 0.0249(18) Uani 1 1 d . . .
C37 C 0.0401(9) 0.9452(9) 0.8630(4) 0.0285(10) Uani 1 1 d D . .
C38 C -0.0809(15) 0.9275(14) 0.8942(7) 0.0285(10) Uani 0.50 1 d PD . .
H38 H -0.1492 0.8502 0.8949 0.034 Uiso 0.50 1 calc PR . .
C39 C -0.0580(9) 1.0701(8) 0.9231(4) 0.0285(10) Uani 1 1 d D . .
H39 H -0.1153 1.0954 0.9479 0.034 Uiso 1 1 calc R . .
C40 C 0.0477(9) 1.1616(9) 0.9125(4) 0.0285(10) Uani 1 1 d . . .
H40 H 0.0674 1.2532 0.9288 0.034 Uiso 1 1 calc R . .
C41 C 0.1051(8) 0.7727(8) 0.6471(4) 0.0244(17) Uani 1 1 d . . .
C42 C -0.0219(9) 0.6812(9) 0.5985(4) 0.031(2) Uani 1 1 d . . .
C43 C 0.1217(8) 0.9069(8) 0.6602(4) 0.0263(18) Uani 1 1 d . . .
H43 H 0.0495 0.9367 0.6414 0.032 Uiso 1 1 calc R . .
C44 C 0.2422(8) 1.0005(8) 0.7006(4) 0.0239(17) Uani 1 1 d . . .
C45 C 0.2549(9) 1.1412(8) 0.7119(4) 0.0255(18) Uani 1 1 d . . .
C46 C 0.1586(8) 1.2042(7) 0.6906(4) 0.0208(16) Uani 1 1 d . . .
H46 H 0.0686 1.1601 0.6651 0.025 Uiso 1 1 calc R . .
C47 C 0.2156(11) 1.3426(9) 0.7129(5) 0.039(2) Uani 1 1 d . . .
H47 H 0.1699 1.4041 0.7026 0.047 Uiso 1 1 calc R . .
C48 C 0.3476(12) 1.3768(9) 0.7517(5) 0.047(3) Uani 1 1 d . . .
H48 H 0.4010 1.4652 0.7716 0.057 Uiso 1 1 calc R . .
Eu1 Eu 0.34681(4) 0.78526(4) 0.770671(18) 0.01896(16) Uani 1 1 d . . .
F1 F 0.6829(8) 0.5878(7) 0.8792(4) 0.073(2) Uani 1 1 d . . .
F2 F 0.5098(7) 0.5168(5) 0.9137(3) 0.0525(16) Uani 1 1 d . . .
F3 F 0.6857(8) 0.6601(6) 0.9769(3) 0.077(3) Uani 1 1 d . . .
F4 F -0.0573(8) 0.3936(7) 0.7343(4) 0.075(2) Uani 1 1 d . . .
F5 F 0.0247(8) 0.4121(7) 0.8329(4) 0.075(2) Uani 1 1 d . . .
F6 F -0.1591(8) 0.4593(7) 0.7997(6) 0.108(4) Uani 1 1 d . . .
F7 F -0.0904(5) 0.5923(5) 0.6271(3) 0.0449(14) Uani 1 1 d . . .
F8 F 0.0076(6) 0.6139(6) 0.5497(3) 0.0486(16) Uani 1 1 d . . .
F9 F -0.1112(5) 0.7360(5) 0.5736(3) 0.0399(13) Uani 1 1 d . . .
N1 N 0.5853(6) 0.8845(6) 0.7506(3) 0.0185(13) Uani 1 1 d . . .
O1 O 0.4262(5) 0.6427(5) 0.6984(3) 0.0214(12) Uani 1 1 d . . .
O2 O 0.4728(6) 0.6906(5) 0.8405(3) 0.0256(12) Uani 1 1 d . . .
O3 O 0.4732(5) 0.9478(5) 0.8643(2) 0.0210(11) Uani 1 1 d . . .
O4 O 0.1679(6) 0.6138(5) 0.7851(3) 0.0288(13) Uani 1 1 d . . .
O5 O 0.1928(5) 0.8775(5) 0.8110(3) 0.0245(12) Uani 1 1 d . . .
O6 O 0.1849(5) 0.7152(5) 0.6705(3) 0.0239(12) Uani 1 1 d . . .
O7 O 0.3442(5) 0.9718(5) 0.7286(3) 0.0227(12) Uani 1 1 d . . .
S1 S 0.5684(3) 1.2175(2) 0.93118(11) 0.0380(6) Uani 1 1 d . . .
S2 S 0.1377(4) 1.1041(4) 0.87025(18) 0.0689(9) Uani 1 1 d . . .
S3 S 0.4026(3) 1.2494(2) 0.75987(13) 0.0422(6) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.344(10) . ?
C1 C2 1.384(12) . ?
C1 H1 0.9500 . ?
C2 C3 1.367(12) . ?
C2 H2 0.9500 . ?
C3 C4 1.365(12) . ?
C3 H3 0.9500 . ?
C4 C5 1.387(11) . ?
C4 H4 0.9500 . ?
C5 N1 1.327(10) . ?
C5 C6 1.521(11) . ?
C6 O1 1.239(9) . ?
C6 C7 1.450(11) . ?
C7 C8 1.351(11) . ?
C7 H7 0.9500 . ?
C8 C9 1.448(10) . ?
C8 H8 0.9500 . ?
C9 C10 1.409(11) . ?
C9 C22 1.416(11) . ?
C10 C11 1.365(11) . ?
C10 H10 0.9500 . ?
C11 C12 1.394(11) . ?
C11 H11 0.9500 . ?
C12 C23 1.416(11) . ?
C12 C13 1.443(11) . ?
C13 C14 1.345(12) . ?
C13 H13 0.9500 . ?
C14 C15 1.434(12) . ?
C14 H14 0.9500 . ?
C15 C16 1.386(12) . ?
C15 C24 1.434(11) . ?
C16 C17 1.372(12) . ?
C16 H16 0.9500 . ?
C17 C18 1.375(12) . ?
C17 H17 0.9500 . ?
C18 C19 1.387(12) . ?
C18 H18 0.9500 . ?
C19 C24 1.416(11) . ?
C19 C20 1.432(11) . ?
C20 C21 1.343(12) . ?
C20 H20 0.9500 . ?
C21 C22 1.430(11) . ?
C21 H21 0.9500 . ?
C22 C23 1.423(11) . ?
C23 C24 1.424(11) . ?
C25 O2 1.254(10) . ?
C25 C27 1.368(12) . ?
C25 C26 1.526(12) . ?
C26 F1 1.315(12) . ?
C26 F3 1.328(11) . ?
C26 F2 1.331(11) . ?
C27 C28 1.396(12) . ?
C27 H27 0.9500 . ?
C28 O3 1.252(9) . ?
C28 C29 1.473(11) . ?
C29 C30 1.441(11) . ?
C29 S1 1.706(8) . ?
C30 C31 1.416(12) . ?
C30 H30 0.9500 . ?
C31 C32 1.324(14) . ?
C31 H31 0.9500 . ?
C32 S1 1.689(10) . ?
C32 H32 0.9500 . ?
C33 O4 1.276(11) . ?
C33 C35 1.378(13) . ?
C33 C34 1.510(13) . ?
C34 F4 1.296(12) . ?
C34 F6 1.320(12) . ?
C34 F5 1.345(14) . ?
C35 C36 1.429(12) . ?
C35 H35 0.9500 . ?
C36 O5 1.252(10) . ?
C36 C37 1.481(11) . ?
C37 C38 1.541(14) . ?
C37 S2 1.714(10) . ?
C38 C39 1.507(14) . ?
C38 H38 0.9500 . ?
C39 C40 1.363(13) . ?
C39 H39 0.9500 . ?
C40 S2 1.617(9) . ?
C40 H40 0.9500 . ?
C41 O6 1.251(10) . ?
C41 C43 1.392(12) . ?
C41 C42 1.513(12) . ?
C42 F9 1.315(10) . ?
C42 F8 1.330(10) . ?
C42 F7 1.352(11) . ?
C43 C44 1.414(12) . ?
C43 H43 0.9500 . ?
C44 O7 1.268(10) . ?
C44 C45 1.469(11) . ?
C45 C46 1.413(12) . ?
C45 S3 1.696(9) . ?
C46 C47 1.418(12) . ?
C46 H46 0.9500 . ?
C47 C48 1.395(16) . ?
C47 H47 0.9500 . ?
C48 S3 1.655(11) . ?
C48 H48 0.9500 . ?
Eu1 O7 2.349(5) . ?
Eu1 O2 2.356(6) . ?
Eu1 O3 2.357(5) . ?
Eu1 O6 2.357(5) . ?
Eu1 O5 2.360(5) . ?
Eu1 O4 2.375(6) . ?
Eu1 O1 2.453(5) . ?
Eu1 N1 2.608(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 122.5(8) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C3 C2 C1 118.9(8) . . ?
C3 C2 H2 120.5 . . ?
C1 C2 H2 120.5 . . ?
C4 C3 C2 119.1(8) . . ?
C4 C3 H3 120.5 . . ?
C2 C3 H3 120.5 . . ?
C3 C4 C5 119.2(8) . . ?
C3 C4 H4 120.4 . . ?
C5 C4 H4 120.4 . . ?
N1 C5 C4 122.6(7) . . ?
N1 C5 C6 113.2(7) . . ?
C4 C5 C6 124.1(7) . . ?
O1 C6 C7 122.6(7) . . ?
O1 C6 C5 117.9(7) . . ?
C7 C6 C5 119.5(7) . . ?
C8 C7 C6 120.7(7) . . ?
C8 C7 H7 119.7 . . ?
C6 C7 H7 119.7 . . ?
C7 C8 C9 126.1(7) . . ?
C7 C8 H8 117.0 . . ?
C9 C8 H8 117.0 . . ?
C10 C9 C22 118.7(7) . . ?
C10 C9 C8 120.3(7) . . ?
C22 C9 C8 120.9(7) . . ?
C11 C10 C9 122.2(7) . . ?
C11 C10 H10 118.9 . . ?
C9 C10 H10 118.9 . . ?
C10 C11 C12 120.4(7) . . ?
C10 C11 H11 119.8 . . ?
C12 C11 H11 119.8 . . ?
C11 C12 C23 119.6(7) . . ?
C11 C12 C13 121.6(7) . . ?
C23 C12 C13 118.8(7) . . ?
C14 C13 C12 121.7(7) . . ?
C14 C13 H13 119.1 . . ?
C12 C13 H13 119.1 . . ?
C13 C14 C15 121.2(7) . . ?
C13 C14 H14 119.4 . . ?
C15 C14 H14 119.4 . . ?
C16 C15 C14 122.9(7) . . ?
C16 C15 C24 118.8(7) . . ?
C14 C15 C24 118.3(7) . . ?
C17 C16 C15 121.3(8) . . ?
C17 C16 H16 119.4 . . ?
C15 C16 H16 119.4 . . ?
C16 C17 C18 120.9(8) . . ?
C16 C17 H17 119.6 . . ?
C18 C17 H17 119.6 . . ?
C17 C18 C19 120.4(8) . . ?
C17 C18 H18 119.8 . . ?
C19 C18 H18 119.8 . . ?
C18 C19 C24 119.9(7) . . ?
C18 C19 C20 122.9(7) . . ?
C24 C19 C20 117.1(7) . . ?
C21 C20 C19 122.1(7) . . ?
C21 C20 H20 118.9 . . ?
C19 C20 H20 118.9 . . ?
C20 C21 C22 122.4(7) . . ?
C20 C21 H21 118.8 . . ?
C22 C21 H21 118.8 . . ?
C9 C22 C23 119.0(7) . . ?
C9 C22 C21 123.9(7) . . ?
C23 C22 C21 117.1(7) . . ?
C12 C23 C22 120.1(7) . . ?
C12 C23 C24 119.5(7) . . ?
C22 C23 C24 120.3(7) . . ?
C19 C24 C23 120.9(7) . . ?
C19 C24 C15 118.7(7) . . ?
C23 C24 C15 120.4(7) . . ?
O2 C25 C27 128.3(8) . . ?
O2 C25 C26 111.9(7) . . ?
C27 C25 C26 119.7(7) . . ?
F1 C26 F3 108.0(9) . . ?
F1 C26 F2 105.8(8) . . ?
F3 C26 F2 106.0(8) . . ?
F1 C26 C25 111.6(8) . . ?
F3 C26 C25 113.7(7) . . ?
F2 C26 C25 111.3(8) . . ?
C25 C27 C28 123.2(8) . . ?
C25 C27 H27 118.4 . . ?
C28 C27 H27 118.4 . . ?
O3 C28 C27 123.1(7) . . ?
O3 C28 C29 116.5(7) . . ?
C27 C28 C29 120.4(7) . . ?
C30 C29 C28 130.1(7) . . ?
C30 C29 S1 112.1(6) . . ?
C28 C29 S1 117.8(6) . . ?
C31 C30 C29 107.8(7) . . ?
C31 C30 H30 126.1 . . ?
C29 C30 H30 126.1 . . ?
C32 C31 C30 115.4(8) . . ?
C32 C31 H31 122.3 . . ?
C30 C31 H31 122.3 . . ?
C31 C32 S1 113.3(7) . . ?
C31 C32 H32 123.3 . . ?
S1 C32 H32 123.3 . . ?
O4 C33 C35 128.7(8) . . ?
O4 C33 C34 114.3(8) . . ?
C35 C33 C34 116.9(8) . . ?
F4 C34 F6 106.2(10) . . ?
F4 C34 F5 105.6(9) . . ?
F6 C34 F5 107.8(10) . . ?
F4 C34 C33 112.8(9) . . ?
F6 C34 C33 115.0(9) . . ?
F5 C34 C33 108.9(9) . . ?
C33 C35 C36 120.9(8) . . ?
C33 C35 H35 119.5 . . ?
C36 C35 H35 119.5 . . ?
O5 C36 C35 123.5(8) . . ?
O5 C36 C37 118.2(8) . . ?
C35 C36 C37 118.3(8) . . ?
C36 C37 C38 128.3(9) . . ?
C36 C37 S2 115.4(6) . . ?
C38 C37 S2 116.2(8) . . ?
C39 C38 C37 98.6(10) . . ?
C39 C38 H38 130.7 . . ?
C37 C38 H38 130.7 . . ?
C40 C39 C38 117.6(9) . . ?
C40 C39 H39 121.2 . . ?
C38 C39 H39 121.2 . . ?
C39 C40 S2 115.7(7) . . ?
C39 C40 H40 122.1 . . ?
S2 C40 H40 122.1 . . ?
O6 C41 C43 127.7(8) . . ?
O6 C41 C42 113.8(7) . . ?
C43 C41 C42 118.5(8) . . ?
F9 C42 F8 107.0(7) . . ?
F9 C42 F7 105.0(7) . . ?
F8 C42 F7 107.1(7) . . ?
F9 C42 C41 116.4(7) . . ?
F8 C42 C41 111.7(7) . . ?
F7 C42 C41 109.2(7) . . ?
C41 C43 C44 122.3(8) . . ?
C41 C43 H43 118.9 . . ?
C44 C43 H43 118.9 . . ?
O7 C44 C43 124.2(7) . . ?
O7 C44 C45 115.9(7) . . ?
C43 C44 C45 119.9(8) . . ?
C46 C45 C44 129.8(8) . . ?
C46 C45 S3 112.2(6) . . ?
C44 C45 S3 117.9(6) . . ?
C45 C46 C47 110.3(8) . . ?
C45 C46 H46 124.8 . . ?
C47 C46 H46 124.8 . . ?
C48 C47 C46 111.2(8) . . ?
C48 C47 H47 124.4 . . ?
C46 C47 H47 124.4 . . ?
C47 C48 S3 113.9(7) . . ?
C47 C48 H48 123.1 . . ?
S3 C48 H48 123.1 . . ?
O7 Eu1 O2 146.39(19) . . ?
O7 Eu1 O3 81.72(19) . . ?
O2 Eu1 O3 71.36(18) . . ?
O7 Eu1 O6 72.15(19) . . ?
O2 Eu1 O6 137.44(19) . . ?
O3 Eu1 O6 151.04(19) . . ?
O7 Eu1 O5 71.90(19) . . ?
O2 Eu1 O5 116.6(2) . . ?
O3 Eu1 O5 72.73(19) . . ?
O6 Eu1 O5 87.18(19) . . ?
O7 Eu1 O4 131.3(2) . . ?
O2 Eu1 O4 79.7(2) . . ?
O3 Eu1 O4 115.29(19) . . ?
O6 Eu1 O4 75.6(2) . . ?
O5 Eu1 O4 71.02(19) . . ?
O7 Eu1 O1 107.64(18) . . ?
O2 Eu1 O1 76.34(18) . . ?
O3 Eu1 O1 129.02(18) . . ?
O6 Eu1 O1 72.44(18) . . ?
O5 Eu1 O1 158.25(19) . . ?
O4 Eu1 O1 95.94(19) . . ?
O7 Eu1 N1 72.06(19) . . ?
O2 Eu1 N1 81.4(2) . . ?
O3 Eu1 N1 74.44(19) . . ?
O6 Eu1 N1 107.94(19) . . ?
O5 Eu1 N1 133.86(19) . . ?
O4 Eu1 N1 154.2(2) . . ?
O1 Eu1 N1 62.43(18) . . ?
C5 N1 C1 117.7(7) . . ?
C5 N1 Eu1 119.9(5) . . ?
C1 N1 Eu1 122.4(5) . . ?
C6 O1 Eu1 126.5(5) . . ?
C25 O2 Eu1 135.0(5) . . ?
C28 O3 Eu1 139.1(5) . . ?
C33 O4 Eu1 134.4(5) . . ?
C36 O5 Eu1 139.7(5) . . ?
C41 O6 Eu1 127.8(5) . . ?
C44 O7 Eu1 128.3(5) . . ?
C32 S1 C29 91.4(4) . . ?
C40 S2 C37 91.7(5) . . ?
C48 S3 C45 92.2(5) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.07
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         8.626
_refine_diff_density_min         -1.731
_refine_diff_density_rms         0.218
