# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1536335'
_audit_update_record             
;
2017-03-07 deposited with the CCDC.
2017-11-29 downloaded from the CCDC.
;
_audit_creation_date             2016-11-22
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.11.07 svn.r3352 for OlexSys, GUI svn.r5261)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C24 H22 Cl N3 O2'
_chemical_formula_sum            'C24 H22 Cl N3 O2'
_chemical_formula_weight         419.89
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.9332(14)
_cell_length_b                   10.9116(18)
_cell_length_c                   12.9665(19)
_cell_angle_alpha                96.881(4)
_cell_angle_beta                 92.036(2)
_cell_angle_gamma                109.013(5)
_cell_volume                     1050.2(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    3098
_cell_measurement_temperature    113
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_shelx_estimated_absorpt_T_max   0.971
_shelx_estimated_absorpt_T_min   0.960
_exptl_absorpt_coefficient_mu    0.208
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.673
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.328
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    "'not measured'"
_exptl_crystal_description       Prism
_exptl_crystal_F_000             440
_exptl_crystal_preparation       Fiber
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_av_unetI/netI     0.0237
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            13555
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         27.517
_diffrn_reflns_theta_min         3.042
_diffrn_ambient_temperature      113
_diffrn_detector                 PILT
_diffrn_detector_area_resol_mean 5.8140
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_details      
;
scan:
	Number of images: 360
	           Slice: -105.0000 - 75.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 0.0000
	             XTD: 44.9819
	          2theta: -15.0868
scan:
	Number of images: 360
	           Slice: -105.0000 - 75.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 90.0000
	             XTD: 44.9819
	          2theta: -15.0868
scan:
	Number of images: 360
	           Slice: -105.0000 - 75.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 180.0000
	             XTD: 44.9819
	          2theta: -15.0868
;
_diffrn_measurement_device       
;
AFC10: Fixed Chi 2 circle
;
_diffrn_measurement_device_type  'Rigaku Pilatus 200K'
_diffrn_measurement_method       'ω scans'
_diffrn_measurement_specimen_support Fiber
_diffrn_orient_matrix_type       d*Trek
_diffrn_orient_matrix_UB_11      0.098887
_diffrn_orient_matrix_UB_12      0.023691
_diffrn_orient_matrix_UB_13      -0.086883
_diffrn_orient_matrix_UB_21      0.086068
_diffrn_orient_matrix_UB_22      -0.005770
_diffrn_orient_matrix_UB_23      0.046263
_diffrn_orient_matrix_UB_31      0.014541
_diffrn_orient_matrix_UB_32      -0.075355
_diffrn_orient_matrix_UB_33      -0.013525
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating Anode'
_diffrn_source_current           24.0
_diffrn_source_power             1.2
_diffrn_source_voltage           50.0
_diffrn_special_details          
;
 ?
;
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4106
_reflns_number_total             4737
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_collection       
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_reduction        
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.296
_refine_diff_density_min         -0.291
_refine_diff_density_rms         0.041
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     313
_refine_ls_number_reflns         4737
_refine_ls_number_restraints     84
_refine_ls_R_factor_all          0.0399
_refine_ls_R_factor_gt           0.0334
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0444P)²+0.3363P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0867
_refine_ls_wR_factor_ref         0.0905
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C18) \\sim Ueq, Uanis(C18') \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.02
Uanis(C19) \\sim Ueq, Uanis(C20) \\sim Ueq, Uanis(C21) \\sim Ueq, Uanis(C22)
\\sim Ueq, Uanis(C23) \\sim Ueq, Uanis(C24) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
Uanis(C19') \\sim Ueq, Uanis(C20') \\sim Ueq, Uanis(C21') \\sim Ueq,
Uanis(C22') \\sim Ueq, Uanis(C23') \\sim Ueq, Uanis(C24') \\sim Ueq: with sigma
of 0.01 and sigma for terminal atoms of 0.02
3. Others
 Sof(C19')=Sof(C20')=Sof(H20')=Sof(C21')=Sof(H21')=Sof(C22')=Sof(H22')=
 Sof(C23')=Sof(H23')=Sof(C24')=Sof(H24')=1-FVAR(1)
 Sof(C18')=Sof(H18A)=Sof(H18B)=Sof(C18)=Sof(H18C)=Sof(H18D)=Sof(C19)=Sof(C20)=
 Sof(H20)=Sof(C21)=Sof(H21)=Sof(C22)=Sof(H22)=Sof(C23)=Sof(H23)=Sof(C24)=
 Sof(H24)=FVAR(1)
4.a Secondary CH2 refined with riding coordinates:
 C18'(H18A,H18B), C18(H18C,H18D)
4.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C7(H7), C9(H9), C10(H10), C11(H11), C12(H12),
 C13(H13), C20'(H20'), C21'(H21'), C22'(H22'), C23'(H23'), C24'(H24'), C20(H20),
  C21(H21), C22(H22), C23(H23), C24(H24)
4.c Fitted hexagon refined as free rotating group:
 C19'(C20',C21',C22',C23',C24'), C19(C20,C21,C22,C23,C24)
4.d Idealised Me refined as rotating group:
 C15(H15A,H15B,H15C), C16(H16A,H16B,H16C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl -0.00921(5) 0.44262(3) 0.13363(3) 0.03414(11) Uani 1 1 d . . . . .
O1 O 0.32384(11) 0.13804(7) 0.25166(6) 0.01992(18) Uani 1 1 d . . . . .
O2 O 0.12247(11) -0.07965(8) 0.16245(7) 0.02091(18) Uani 1 1 d . . . . .
N1 N 0.55284(13) 0.26201(9) 0.38025(7) 0.0176(2) Uani 1 1 d . . . . .
N2 N 0.59611(13) 0.14927(9) 0.38957(7) 0.0169(2) Uani 1 1 d . . . . .
N3 N 0.29494(13) -0.07673(10) 0.19812(8) 0.0210(2) Uani 1 1 d . . . . .
C1 C 0.42465(15) 0.25199(10) 0.31428(8) 0.0166(2) Uani 1 1 d . . . . .
C2 C 0.36342(15) 0.36356(11) 0.30256(8) 0.0168(2) Uani 1 1 d . . . . .
C3 C 0.44797(16) 0.48365(11) 0.36484(9) 0.0211(2) Uani 1 1 d . . . . .
H3 H 0.5484 0.4938 0.4113 0.025 Uiso 1 1 calc R . . . .
C4 C 0.38647(17) 0.58789(12) 0.35935(9) 0.0237(3) Uani 1 1 d . . . . .
H4 H 0.4427 0.6682 0.4036 0.028 Uiso 1 1 calc R . . . .
C5 C 0.24270(17) 0.57597(12) 0.28948(10) 0.0232(2) Uani 1 1 d . . . . .
H5 H 0.1996 0.6471 0.2855 0.028 Uiso 1 1 calc R . . . .
C6 C 0.16438(16) 0.45772(11) 0.22597(9) 0.0205(2) Uani 1 1 d . . . . .
C7 C 0.22052(15) 0.35042(11) 0.23135(9) 0.0179(2) Uani 1 1 d . . . . .
H7 H 0.1629 0.2700 0.1875 0.022 Uiso 1 1 calc R . . . .
C8 C 0.76336(15) 0.18354(11) 0.45257(8) 0.0178(2) Uani 1 1 d . . . . .
C9 C 0.78301(16) 0.09948(12) 0.52126(9) 0.0218(2) Uani 1 1 d . . . . .
H9 H 0.6884 0.0204 0.5253 0.026 Uiso 1 1 calc R . . . .
C10 C 0.94131(17) 0.13138(13) 0.58389(10) 0.0265(3) Uani 1 1 d . . . . .
H10 H 0.9553 0.0732 0.6298 0.032 Uiso 1 1 calc R . . . .
C11 C 1.07907(17) 0.24777(14) 0.57967(10) 0.0276(3) Uani 1 1 d . . . . .
H11 H 1.1869 0.2695 0.6228 0.033 Uiso 1 1 calc R . . . .
C12 C 1.05845(17) 0.33235(13) 0.51204(10) 0.0266(3) Uani 1 1 d . . . . .
H12 H 1.1521 0.4124 0.5094 0.032 Uiso 1 1 calc R . . . .
C13 C 0.90160(16) 0.30055(12) 0.44822(9) 0.0213(2) Uani 1 1 d . . . . .
H13 H 0.8885 0.3584 0.4017 0.026 Uiso 1 1 calc R . . . .
C14 C 0.57921(15) 0.06273(11) 0.28775(9) 0.0183(2) Uani 1 1 d . . . . .
C15 C 0.60927(17) -0.06451(12) 0.30499(10) 0.0252(3) Uani 1 1 d . . . . .
H15A H 0.7342 -0.0458 0.3302 0.038 Uiso 1 1 calc GR . . . .
H15B H 0.5825 -0.1240 0.2391 0.038 Uiso 1 1 calc GR . . . .
H15C H 0.5305 -0.1056 0.3567 0.038 Uiso 1 1 calc GR . . . .
C16 C 0.70993(16) 0.13363(13) 0.21202(9) 0.0239(3) Uani 1 1 d . . . . .
H16A H 0.6885 0.2149 0.2015 0.036 Uiso 1 1 calc GR . . . .
H16B H 0.6914 0.0770 0.1450 0.036 Uiso 1 1 calc GR . . . .
H16C H 0.8331 0.1540 0.2413 0.036 Uiso 1 1 calc GR . . . .
C17 C 0.38834(15) 0.03532(11) 0.24451(9) 0.0175(2) Uani 1 1 d . . . . .
C18' C 0.0299(8) -0.2099(6) 0.1151(5) 0.0561(17) Uani 0.499(3) 1 d . U P A 2
H18A H 0.0357 -0.2712 0.1646 0.067 Uiso 0.499(3) 1 calc R . P A 2
H18B H 0.0897 -0.2300 0.0528 0.067 Uiso 0.499(3) 1 calc R . P A 2
C19' C -0.1601(5) -0.2302(7) 0.0842(6) 0.0291(17) Uani 0.501(3) 1 d . U P A 2
C20' C -0.2954(7) -0.3385(5) 0.1082(5) 0.0281(11) Uani 0.501(3) 1 d G U P A 2
H20' H -0.2667 -0.3996 0.1459 0.034 Uiso 0.501(3) 1 calc R . P A 2
C21' C -0.4726(6) -0.3574(4) 0.0773(4) 0.0338(13) Uani 0.501(3) 1 d G U P A 2
H21' H -0.5651 -0.4315 0.0937 0.041 Uiso 0.501(3) 1 calc R . P A 2
C22' C -0.5146(5) -0.2681(5) 0.0223(4) 0.0337(12) Uani 0.501(3) 1 d G U P A 2
H22' H -0.6357 -0.2810 0.0011 0.040 Uiso 0.501(3) 1 calc R . P A 2
C23' C -0.3793(7) -0.1598(4) -0.0018(4) 0.0311(11) Uani 0.501(3) 1 d G U P A 2
H23' H -0.4079 -0.0987 -0.0394 0.037 Uiso 0.501(3) 1 calc R . P A 2
C24' C -0.2020(6) -0.1408(5) 0.0291(5) 0.0348(16) Uani 0.501(3) 1 d G U P A 2
H24' H -0.1095 -0.0668 0.0127 0.042 Uiso 0.501(3) 1 calc R . P A 2
C18 C 0.0504(6) -0.1939(4) 0.0830(2) 0.0132(7) Uani 0.499(3) 1 d . U P A 1
H18C H 0.0800 -0.2691 0.1044 0.016 Uiso 0.499(3) 1 calc R . P A 1
H18D H 0.1020 -0.1748 0.0160 0.016 Uiso 0.499(3) 1 calc R . P A 1
C19 C -0.1514(4) -0.2257(6) 0.0713(5) 0.0167(12) Uani 0.499(3) 1 d . U P A 1
C20 C -0.2533(6) -0.3310(5) 0.1179(5) 0.0237(10) Uani 0.499(3) 1 d G U P A 1
H20 H -0.1960 -0.3759 0.1577 0.028 Uiso 0.499(3) 1 calc R . P A 1
C21 C -0.4389(6) -0.3704(4) 0.1062(3) 0.0287(10) Uani 0.499(3) 1 d G U P A 1
H21 H -0.5085 -0.4423 0.1380 0.034 Uiso 0.499(3) 1 calc R . P A 1
C22 C -0.5226(4) -0.3045(4) 0.0479(3) 0.0286(11) Uani 0.499(3) 1 d G U P A 1
H22 H -0.6494 -0.3315 0.0399 0.034 Uiso 0.499(3) 1 calc R . P A 1
C23 C -0.4207(6) -0.1993(4) 0.0014(4) 0.0269(11) Uani 0.499(3) 1 d G U P A 1
H23 H -0.4779 -0.1544 -0.0384 0.032 Uiso 0.499(3) 1 calc R . P A 1
C24 C -0.2351(6) -0.1599(5) 0.0131(4) 0.0192(8) Uani 0.499(3) 1 d G U P A 1
H24 H -0.1654 -0.0880 -0.0188 0.023 Uiso 0.499(3) 1 calc R . P A 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 C6 1.7449(12) . ?
O1 C1 1.3816(13) . ?
O1 C17 1.3708(13) . ?
O2 N3 1.4178(12) . ?
O2 C18' 1.419(6) . ?
O2 C18 1.459(4) . ?
N1 N2 1.3977(13) . ?
N1 C1 1.2733(15) . ?
N2 C8 1.4471(14) . ?
N2 C14 1.5030(15) . ?
N3 C17 1.2678(15) . ?
C1 C2 1.4715(15) . ?
C2 C3 1.3980(16) . ?
C2 C7 1.3951(16) . ?
C3 H3 0.9500 . ?
C3 C4 1.3840(17) . ?
C4 H4 0.9500 . ?
C4 C5 1.3929(17) . ?
C5 H5 0.9500 . ?
C5 C6 1.3842(17) . ?
C6 C7 1.3896(16) . ?
C7 H7 0.9500 . ?
C8 C9 1.3921(16) . ?
C8 C13 1.3948(16) . ?
C9 H9 0.9500 . ?
C9 C10 1.3902(17) . ?
C10 H10 0.9500 . ?
C10 C11 1.3881(19) . ?
C11 H11 0.9500 . ?
C11 C12 1.3891(18) . ?
C12 H12 0.9500 . ?
C12 C13 1.3893(17) . ?
C13 H13 0.9500 . ?
C14 C15 1.5235(16) . ?
C14 C16 1.5394(16) . ?
C14 C17 1.5168(16) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C18' H18A 0.9900 . ?
C18' H18B 0.9900 . ?
C18' C19' 1.484(7) . ?
C19' C20' 1.3900 . ?
C19' C24' 1.3900 . ?
C20' H20' 0.9500 . ?
C20' C21' 1.3900 . ?
C21' H21' 0.9500 . ?
C21' C22' 1.3900 . ?
C22' H22' 0.9500 . ?
C22' C23' 1.3900 . ?
C23' H23' 0.9500 . ?
C23' C24' 1.3900 . ?
C24' H24' 0.9500 . ?
C18 H18C 0.9900 . ?
C18 H18D 0.9900 . ?
C18 C19 1.521(6) . ?
C19 C20 1.3900 . ?
C19 C24 1.3900 . ?
C20 H20 0.9500 . ?
C20 C21 1.3900 . ?
C21 H21 0.9500 . ?
C21 C22 1.3900 . ?
C22 H22 0.9500 . ?
C22 C23 1.3900 . ?
C23 H23 0.9500 . ?
C23 C24 1.3900 . ?
C24 H24 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C17 O1 C1 117.15(9) . . ?
N3 O2 C18' 106.4(3) . . ?
N3 O2 C18 107.0(2) . . ?
C1 N1 N2 117.55(9) . . ?
N1 N2 C8 109.75(8) . . ?
N1 N2 C14 113.68(8) . . ?
C8 N2 C14 116.41(9) . . ?
C17 N3 O2 111.78(9) . . ?
O1 C1 C2 113.29(9) . . ?
N1 C1 O1 125.10(10) . . ?
N1 C1 C2 121.52(10) . . ?
C3 C2 C1 119.46(10) . . ?
C7 C2 C1 120.87(10) . . ?
C7 C2 C3 119.67(10) . . ?
C2 C3 H3 119.7 . . ?
C4 C3 C2 120.51(11) . . ?
C4 C3 H3 119.7 . . ?
C3 C4 H4 119.7 . . ?
C3 C4 C5 120.52(11) . . ?
C5 C4 H4 119.7 . . ?
C4 C5 H5 120.9 . . ?
C6 C5 C4 118.18(11) . . ?
C6 C5 H5 120.9 . . ?
C5 C6 Cl1 119.08(9) . . ?
C5 C6 C7 122.61(11) . . ?
C7 C6 Cl1 118.30(9) . . ?
C2 C7 H7 120.8 . . ?
C6 C7 C2 118.47(11) . . ?
C6 C7 H7 120.8 . . ?
C9 C8 N2 118.86(10) . . ?
C9 C8 C13 119.78(11) . . ?
C13 C8 N2 121.33(10) . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 119.92(11) . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 119.8 . . ?
C11 C10 C9 120.39(11) . . ?
C11 C10 H10 119.8 . . ?
C10 C11 H11 120.2 . . ?
C10 C11 C12 119.64(11) . . ?
C12 C11 H11 120.2 . . ?
C11 C12 H12 119.8 . . ?
C11 C12 C13 120.38(12) . . ?
C13 C12 H12 119.8 . . ?
C8 C13 H13 120.1 . . ?
C12 C13 C8 119.88(11) . . ?
C12 C13 H13 120.1 . . ?
N2 C14 C15 110.84(9) . . ?
N2 C14 C16 111.15(9) . . ?
N2 C14 C17 104.28(9) . . ?
C15 C14 C16 110.50(10) . . ?
C17 C14 C15 110.29(9) . . ?
C17 C14 C16 109.62(9) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O1 C17 C14 117.62(9) . . ?
N3 C17 O1 120.97(10) . . ?
N3 C17 C14 121.29(10) . . ?
O2 C18' H18A 109.2 . . ?
O2 C18' H18B 109.2 . . ?
O2 C18' C19' 112.0(5) . . ?
H18A C18' H18B 107.9 . . ?
C19' C18' H18A 109.2 . . ?
C19' C18' H18B 109.2 . . ?
C20' C19' C18' 120.6(4) . . ?
C20' C19' C24' 120.0 . . ?
C24' C19' C18' 119.4(4) . . ?
C19' C20' H20' 120.0 . . ?
C19' C20' C21' 120.0 . . ?
C21' C20' H20' 120.0 . . ?
C20' C21' H21' 120.0 . . ?
C20' C21' C22' 120.0 . . ?
C22' C21' H21' 120.0 . . ?
C21' C22' H22' 120.0 . . ?
C23' C22' C21' 120.0 . . ?
C23' C22' H22' 120.0 . . ?
C22' C23' H23' 120.0 . . ?
C22' C23' C24' 120.0 . . ?
C24' C23' H23' 120.0 . . ?
C19' C24' H24' 120.0 . . ?
C23' C24' C19' 120.0 . . ?
C23' C24' H24' 120.0 . . ?
O2 C18 H18C 110.2 . . ?
O2 C18 H18D 110.2 . . ?
O2 C18 C19 107.4(4) . . ?
H18C C18 H18D 108.5 . . ?
C19 C18 H18C 110.2 . . ?
C19 C18 H18D 110.2 . . ?
C20 C19 C18 116.6(4) . . ?
C20 C19 C24 120.0 . . ?
C24 C19 C18 123.4(4) . . ?
C19 C20 H20 120.0 . . ?
C19 C20 C21 120.0 . . ?
C21 C20 H20 120.0 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 C20 120.0 . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 C21 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 120.0 . . ?
C22 C23 C24 120.0 . . ?
C24 C23 H23 120.0 . . ?
C19 C24 H24 120.0 . . ?
C23 C24 C19 120.0 . . ?
C23 C24 H24 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl1 C6 C7 C2 177.79(8) . . . . ?
O1 C1 C2 C3 177.01(10) . . . . ?
O1 C1 C2 C7 -1.99(15) . . . . ?
O2 N3 C17 O1 -2.89(15) . . . . ?
O2 N3 C17 C14 -178.85(9) . . . . ?
O2 C18' C19' C20' -132.9(5) . . . . ?
O2 C18' C19' C24' 48.1(7) . . . . ?
O2 C18 C19 C20 -103.0(4) . . . . ?
O2 C18 C19 C24 80.4(4) . . . . ?
N1 N2 C8 C9 142.36(11) . . . . ?
N1 N2 C8 C13 -35.40(14) . . . . ?
N1 N2 C14 C15 -174.09(9) . . . . ?
N1 N2 C14 C16 62.61(12) . . . . ?
N1 N2 C14 C17 -55.42(11) . . . . ?
N1 C1 C2 C3 0.25(17) . . . . ?
N1 C1 C2 C7 -178.76(10) . . . . ?
N2 N1 C1 O1 0.55(16) . . . . ?
N2 N1 C1 C2 176.91(9) . . . . ?
N2 C8 C9 C10 -178.91(11) . . . . ?
N2 C8 C13 C12 178.06(11) . . . . ?
N2 C14 C17 O1 43.08(12) . . . . ?
N2 C14 C17 N3 -140.83(11) . . . . ?
N3 O2 C18' C19' 173.9(4) . . . . ?
N3 O2 C18 C19 160.7(3) . . . . ?
C1 O1 C17 N3 172.20(10) . . . . ?
C1 O1 C17 C14 -11.69(14) . . . . ?
C1 N1 N2 C8 169.34(10) . . . . ?
C1 N1 N2 C14 37.00(13) . . . . ?
C1 C2 C3 C4 -176.41(11) . . . . ?
C1 C2 C7 C6 177.86(10) . . . . ?
C2 C3 C4 C5 -1.91(19) . . . . ?
C3 C2 C7 C6 -1.14(17) . . . . ?
C3 C4 C5 C6 -0.24(18) . . . . ?
C4 C5 C6 Cl1 -177.09(9) . . . . ?
C4 C5 C6 C7 1.74(18) . . . . ?
C5 C6 C7 C2 -1.05(18) . . . . ?
C7 C2 C3 C4 2.61(18) . . . . ?
C8 N2 C14 C15 56.88(12) . . . . ?
C8 N2 C14 C16 -66.42(12) . . . . ?
C8 N2 C14 C17 175.55(9) . . . . ?
C8 C9 C10 C11 1.10(19) . . . . ?
C9 C8 C13 C12 0.31(18) . . . . ?
C9 C10 C11 C12 -0.3(2) . . . . ?
C10 C11 C12 C13 -0.5(2) . . . . ?
C11 C12 C13 C8 0.50(19) . . . . ?
C13 C8 C9 C10 -1.10(18) . . . . ?
C14 N2 C8 C9 -86.73(13) . . . . ?
C14 N2 C8 C13 95.50(13) . . . . ?
C15 C14 C17 O1 162.12(10) . . . . ?
C15 C14 C17 N3 -21.79(15) . . . . ?
C16 C14 C17 O1 -76.00(12) . . . . ?
C16 C14 C17 N3 100.10(13) . . . . ?
C17 O1 C1 N1 -13.86(16) . . . . ?
C17 O1 C1 C2 169.52(9) . . . . ?
C18' O2 N3 C17 -178.3(3) . . . . ?
C18' C19' C20' C21' -179.0(7) . . . . ?
C18' C19' C24' C23' 179.0(6) . . . . ?
C19' C20' C21' C22' 0.0 . . . . ?
C20' C19' C24' C23' 0.0 . . . . ?
C20' C21' C22' C23' 0.0 . . . . ?
C21' C22' C23' C24' 0.0 . . . . ?
C22' C23' C24' C19' 0.0 . . . . ?
C24' C19' C20' C21' 0.0 . . . . ?
C18 O2 N3 C17 161.55(15) . . . . ?
C18 C19 C20 C21 -176.7(5) . . . . ?
C18 C19 C24 C23 176.5(6) . . . . ?
C19 C20 C21 C22 0.0 . . . . ?
C20 C19 C24 C23 0.0 . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C21 C22 C23 C24 0.0 . . . . ?
C22 C23 C24 C19 0.0 . . . . ?
C24 C19 C20 C21 0.0 . . . . ?

_shelx_SHELXL_version_number     2014/8
_olex2_submission_special_instructions 'No special instructions were received'
