# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_compound_1
_database_code_depnum_ccdc_archive 'CCDC 1528998'
_audit_update_record             
;
2017-01-23 deposited with the CCDC.
2017-02-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C98 H86 Ag2 Cl6 N2 O8 P6 Pt'
_chemical_formula_weight         2229.04

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.743(3)
_cell_length_b                   23.905(6)
_cell_length_c                   15.527(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.345(5)
_cell_angle_gamma                90.00
_cell_volume                     4729(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    13812
_cell_measurement_theta_min      2.0441
_cell_measurement_theta_max      27.4971

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.25
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.566
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2232
_exptl_absorpt_coefficient_mu    2.213
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.3300
_exptl_absorpt_correction_T_max  0.475
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Saturn724+ (2x2 bin mode)'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            32931
_diffrn_reflns_av_R_equivalents  0.0670
_diffrn_reflns_av_sigmaI/netI    0.0661
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.34
_diffrn_reflns_theta_max         25.00
_reflns_number_total             8260
_reflns_number_gt                7527
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0588P)²+14.4714P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8260
_refine_ls_number_parameters     556
_refine_ls_number_restraints     54
_refine_ls_R_factor_all          0.0823
_refine_ls_R_factor_gt           0.0725
_refine_ls_wR_factor_ref         0.1622
_refine_ls_wR_factor_gt          0.1567
_refine_ls_goodness_of_fit_ref   1.168
_refine_ls_restrained_S_all      1.169
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.0000 0.0000 0.0000 0.03259(14) Uani 1 2 d S . .
Ag1 Ag -0.11684(6) 0.05307(3) 0.13924(5) 0.0511(2) Uani 1 1 d . . .
P1 P -0.08642(17) 0.14693(9) 0.08699(14) 0.0382(5) Uani 1 1 d . . .
P2 P 0.03324(16) 0.08744(8) -0.05743(13) 0.0343(5) Uani 1 1 d . . .
P3 P -0.20747(18) -0.03328(9) 0.16624(15) 0.0443(6) Uani 1 1 d . . .
N1 N 0.4026(6) 0.1445(3) 0.3369(5) 0.059(2) Uani 1 1 d . . .
C1 C 0.0307(6) 0.1450(3) 0.0204(5) 0.0365(18) Uani 1 1 d . . .
H1A H 0.0354 0.1801 -0.0107 0.044 Uiso 1 1 calc R . .
H1B H 0.0923 0.1422 0.0580 0.044 Uiso 1 1 calc R . .
C2 C 0.1708(6) 0.0885(4) -0.0892(6) 0.043(2) Uani 1 1 d . . .
H2A H 0.2150 0.0848 -0.0378 0.052 Uiso 1 1 calc R . .
H2B H 0.1856 0.1246 -0.1146 0.052 Uiso 1 1 calc R . .
C3 C -0.1926(7) 0.1801(4) 0.0244(6) 0.047(2) Uani 1 1 d . . .
C4 C -0.1781(7) 0.2295(4) -0.0187(6) 0.055(2) Uani 1 1 d . . .
H4A H -0.1112 0.2445 -0.0235 0.066 Uiso 1 1 calc R . .
C5 C -0.2639(9) 0.2568(5) -0.0548(7) 0.073(3) Uani 1 1 d . . .
H5A H -0.2542 0.2893 -0.0865 0.087 Uiso 1 1 calc R . .
C6 C -0.3620(9) 0.2366(6) -0.0443(8) 0.081(4) Uani 1 1 d . . .
H6A H -0.4194 0.2566 -0.0657 0.097 Uiso 1 1 calc R . .
C7 C -0.3775(9) 0.1872(6) -0.0028(9) 0.082(4) Uani 1 1 d . . .
H7A H -0.4450 0.1730 0.0023 0.098 Uiso 1 1 calc R . .
C8] C -0.2932(7) 0.1585(5) 0.0315(7) 0.063(3) Uani 1 1 d . . .
H8]A H -0.3034 0.1246 0.0596 0.076 Uiso 1 1 calc R . .
C9 C -0.0591(7) 0.2013(4) 0.1655(6) 0.046(2) Uani 1 1 d . . .
C10 C 0.0356(9) 0.2254(5) 0.1813(7) 0.082(4) Uani 1 1 d . . .
H10A H 0.0937 0.2128 0.1518 0.098 Uiso 1 1 calc R . .
C11 C 0.0482(12) 0.2693(6) 0.2414(8) 0.098(5) Uani 1 1 d . . .
H11A H 0.1133 0.2860 0.2510 0.118 Uiso 1 1 calc R . .
C12 C -0.0366(14) 0.2866(5) 0.2846(8) 0.095(5) Uani 1 1 d . . .
H12A H -0.0291 0.3156 0.3240 0.114 Uiso 1 1 calc R . .
C13 C -0.1328(12) 0.2627(6) 0.2722(8) 0.098(5) Uani 1 1 d . . .
H13A H -0.1898 0.2742 0.3041 0.118 Uiso 1 1 calc R . .
C14 C -0.1431(9) 0.2215(5) 0.2118(7) 0.075(3) Uani 1 1 d . . .
H14A H -0.2093 0.2063 0.2011 0.090 Uiso 1 1 calc R . .
C15 C -0.0476(7) 0.1129(3) -0.1463(5) 0.044(2) Uani 1 1 d . . .
C16 C -0.1533(7) 0.0996(4) -0.1504(6) 0.053(2) Uani 1 1 d . . .
H16A H -0.1809 0.0759 -0.1091 0.063 Uiso 1 1 calc R . .
C17 C -0.2183(9) 0.1208(4) -0.2146(8) 0.070(3) Uani 1 1 d . . .
H17A H -0.2896 0.1125 -0.2155 0.084 Uiso 1 1 calc R . .
C18 C -0.1770(11) 0.1544(5) -0.2775(8) 0.080(4) Uani 1 1 d . . .
H18A H -0.2205 0.1683 -0.3214 0.096 Uiso 1 1 calc R . .
C19 C -0.0733(11) 0.1672(5) -0.2758(7) 0.076(3) Uani 1 1 d . . .
H19A H -0.0458 0.1890 -0.3195 0.091 Uiso 1 1 calc R . .
C20 C -0.0079(8) 0.1482(4) -0.2094(6) 0.059(3) Uani 1 1 d . . .
H20A H 0.0622 0.1589 -0.2069 0.071 Uiso 1 1 calc R . .
C21 C -0.3478(7) -0.0295(4) 0.1556(6) 0.061(3) Uani 1 1 d DU . .
C22 C -0.4006(9) 0.0003(6) 0.2174(9) 0.124(5) Uani 1 1 d DU . .
H22A H -0.3625 0.0164 0.2628 0.149 Uiso 1 1 calc R . .
C23 C -0.5084(9) 0.0068(8) 0.2135(11) 0.137(6) Uani 1 1 d DU . .
H23A H -0.5416 0.0270 0.2562 0.165 Uiso 1 1 calc R . .
C24 C -0.5673(10) -0.0163(6) 0.1468(11) 0.124(5) Uani 1 1 d DU . .
H24A H -0.6390 -0.0095 0.1418 0.148 Uiso 1 1 calc R . .
C25 C -0.5178(8) -0.0497(8) 0.0877(13) 0.171(7) Uani 1 1 d DU . .
H25A H -0.5564 -0.0681 0.0448 0.205 Uiso 1 1 calc R . .
C26 C -0.4097(8) -0.0554(7) 0.0933(10) 0.138(6) Uani 1 1 d DU . .
H26A H -0.3771 -0.0778 0.0529 0.165 Uiso 1 1 calc R . .
C27 C -0.1827(8) -0.0635(4) 0.2725(6) 0.049(2) Uani 1 1 d . . .
C28 C -0.1060(10) -0.0412(5) 0.3240(8) 0.074(3) Uani 1 1 d . . .
H28A H -0.0673 -0.0109 0.3049 0.089 Uiso 1 1 calc R . .
C29 C -0.0851(11) -0.0636(6) 0.4050(8) 0.095(4) Uani 1 1 d . . .
H29A H -0.0328 -0.0484 0.4406 0.114 Uiso 1 1 calc R . .
C30 C -0.1427(13) -0.1085(6) 0.4320(8) 0.098(5) Uani 1 1 d . . .
H30A H -0.1297 -0.1236 0.4865 0.117 Uiso 1 1 calc R . .
C31 C -0.2176(11) -0.1309(5) 0.3808(8) 0.085(4) Uani 1 1 d . . .
H31A H -0.2542 -0.1621 0.3995 0.102 Uiso 1 1 calc R . .
C32 C -0.2416(9) -0.1084(4) 0.2999(7) 0.069(3) Uani 1 1 d . . .
H32A H -0.2956 -0.1231 0.2654 0.083 Uiso 1 1 calc R . .
C33 C 0.0796(6) 0.0256(3) 0.1063(6) 0.041(2) Uani 1 1 d . . .
C34 C 0.1301(7) 0.0395(4) 0.1699(6) 0.045(2) Uani 1 1 d . . .
C35 C 0.1948(7) 0.0509(4) 0.2452(5) 0.045(2) Uani 1 1 d . . .
C36 C 0.1919(8) 0.0129(4) 0.3159(6) 0.056(2) Uani 1 1 d . . .
H36A H 0.1462 -0.0174 0.3137 0.068 Uiso 1 1 calc R . .
C37 C 0.2569(8) 0.0208(4) 0.3880(6) 0.058(3) Uani 1 1 d . . .
H37A H 0.2537 -0.0037 0.4343 0.070 Uiso 1 1 calc R . .
C38 C 0.3264(7) 0.0654(4) 0.3906(6) 0.050(2) Uani 1 1 d . . .
C39 C 0.4050(7) 0.0848(4) 0.4512(6) 0.055(2) Uani 1 1 d . . .
C40 C 0.4403(9) 0.0652(6) 0.5317(7) 0.084(4) Uani 1 1 d . . .
H40A H 0.4109 0.0335 0.5560 0.101 Uiso 1 1 calc R . .
C41 C 0.5193(12) 0.0937(7) 0.5737(8) 0.101(5) Uani 1 1 d . . .
H41A H 0.5436 0.0813 0.6273 0.121 Uiso 1 1 calc R . .
C42 C 0.5635(10) 0.1408(7) 0.5374(9) 0.094(4) Uani 1 1 d . . .
H42A H 0.6172 0.1592 0.5676 0.113 Uiso 1 1 calc R . .
C43 C 0.5308(8) 0.1615(5) 0.4580(8) 0.075(3) Uani 1 1 d . . .
H43A H 0.5608 0.1932 0.4340 0.090 Uiso 1 1 calc R . .
C44 C 0.4508(8) 0.1323(5) 0.4166(7) 0.060(3) Uani 1 1 d . . .
C45 C 0.3269(7) 0.1038(4) 0.3215(6) 0.049(2) Uani 1 1 d . . .
C46 C 0.2629(7) 0.0967(4) 0.2484(6) 0.045(2) Uani 1 1 d . . .
H46A H 0.2654 0.1218 0.2027 0.053 Uiso 1 1 calc R . .
C47 C 0.4313(9) 0.1892(5) 0.2793(8) 0.077(3) Uani 1 1 d . . .
H47A H 0.4518 0.2216 0.3132 0.092 Uiso 1 1 calc R . .
H47B H 0.3703 0.1995 0.2442 0.092 Uiso 1 1 calc R . .
C48 C 0.5193(12) 0.1741(7) 0.2211(11) 0.130(6) Uani 1 1 d . . .
H48A H 0.5345 0.2053 0.1845 0.195 Uiso 1 1 calc R . .
H48B H 0.4992 0.1425 0.1863 0.195 Uiso 1 1 calc R . .
H48C H 0.5807 0.1649 0.2552 0.195 Uiso 1 1 calc R . .
Cl1 Cl 0.3021(2) 0.22116(11) 0.01996(18) 0.0617(7) Uani 1 1 d . . .
O1 O 0.2200(7) 0.2309(4) -0.0421(7) 0.108(3) Uani 1 1 d . . .
O2 O 0.3454(12) 0.1724(6) 0.0024(14) 0.254(11) Uani 1 1 d . . .
O3 O 0.3846(8) 0.2589(5) 0.0189(9) 0.150(5) Uani 1 1 d . . .
O4 O 0.2620(9) 0.2161(10) 0.0985(8) 0.239(10) Uani 1 1 d . . .
Cl2 Cl 0.9816(4) 0.1112(2) 0.3571(3) 0.1371(16) Uani 1 1 d . . .
Cl3 Cl 0.7626(6) 0.0929(4) 0.3679(9) 0.319(6) Uani 1 1 d . . .
C49 C 0.8617(19) 0.1274(10) 0.4142(17) 0.232(15) Uani 1 1 d . . .
H49A H 0.8694 0.1164 0.4741 0.278 Uiso 1 1 calc R . .
H49B H 0.8481 0.1673 0.4120 0.278 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C33 2.013(10) 3 ?
Pt1 C33 2.013(10) . ?
Pt1 P2 2.315(2) . ?
Pt1 P2 2.315(2) 3 ?
Pt1 Ag1 2.9413(8) 3 ?
Pt1 Ag1 2.9413(8) . ?
Ag1 P3 2.407(2) . ?
Ag1 P1 2.420(2) . ?
Ag1 C33 2.650(8) . ?
P1 C9 1.810(9) . ?
P1 C3 1.828(9) . ?
P1 C1 1.837(8) . ?
P2 C15 1.809(9) . ?
P2 C1 1.832(7) . ?
P2 C2 1.832(8) . ?
P3 C21 1.795(10) . ?
P3 C27 1.823(9) . ?
P3 C2 1.849(8) 3 ?
N1 C45 1.386(11) . ?
N1 C44 1.399(13) . ?
N1 C47 1.446(13) . ?
C2 P3 1.849(8) 3 ?
C3 C4 1.372(13) . ?
C3 C8] 1.388(12) . ?
C4 C5 1.381(14) . ?
C5 C6 1.354(16) . ?
C6 C7 1.361(17) . ?
C7 C8] 1.372(15) . ?
C9 C10 1.354(13) . ?
C9 C14 1.390(13) . ?
C10 C11 1.412(15) . ?
C11 C12 1.349(18) . ?
C12 C13 1.361(19) . ?
C13 C14 1.365(15) . ?
C15 C16 1.385(12) . ?
C15 C20 1.396(12) . ?
C16 C17 1.377(13) . ?
C17 C18 1.378(16) . ?
C18 C19 1.357(16) . ?
C19 C20 1.387(14) . ?
C21 C26 1.380(5) . ?
C21 C22 1.381(5) . ?
C22 C23 1.383(5) . ?
C23 C24 1.379(5) . ?
C24 C25 1.380(5) . ?
C25 C26 1.385(5) . ?
C27 C28 1.357(14) . ?
C27 C32 1.381(13) . ?
C28 C29 1.388(16) . ?
C29 C30 1.371(18) . ?
C30 C31 1.339(18) . ?
C31 C32 1.394(15) . ?
C33 C34 1.212(12) . ?
C34 C35 1.442(12) . ?
C35 C46 1.396(12) . ?
C35 C36 1.425(13) . ?
C36 C37 1.390(13) . ?
C37 C38 1.386(13) . ?
C38 C45 1.412(13) . ?
C38 C39 1.436(12) . ?
C39 C44 1.391(14) . ?
C39 C40 1.399(14) . ?
C40 C41 1.369(17) . ?
C41 C42 1.385(19) . ?
C42 C43 1.384(17) . ?
C43 C44 1.381(14) . ?
C45 C46 1.393(12) . ?
C47 C48 1.501(17) . ?
Cl1 O2 1.321(12) . ?
Cl1 O4 1.339(11) . ?
Cl1 O3 1.386(10) . ?
Cl1 O1 1.425(9) . ?
Cl2 C49 1.83(2) . ?
Cl3 C49 1.66(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C33 Pt1 C33 180.0(7) 3 . ?
C33 Pt1 P2 93.0(2) 3 . ?
C33 Pt1 P2 87.0(2) . . ?
C33 Pt1 P2 87.0(2) 3 3 ?
C33 Pt1 P2 93.0(2) . 3 ?
P2 Pt1 P2 180.00(10) . 3 ?
C33 Pt1 Ag1 61.3(2) 3 3 ?
C33 Pt1 Ag1 118.7(2) . 3 ?
P2 Pt1 Ag1 90.34(5) . 3 ?
P2 Pt1 Ag1 89.66(5) 3 3 ?
C33 Pt1 Ag1 118.7(2) 3 . ?
C33 Pt1 Ag1 61.3(2) . . ?
P2 Pt1 Ag1 89.66(5) . . ?
P2 Pt1 Ag1 90.34(5) 3 . ?
Ag1 Pt1 Ag1 180.00(3) 3 . ?
P3 Ag1 P1 159.19(9) . . ?
P3 Ag1 C33 106.30(18) . . ?
P1 Ag1 C33 90.31(17) . . ?
P3 Ag1 Pt1 90.65(6) . . ?
P1 Ag1 Pt1 93.77(5) . . ?
C33 Ag1 Pt1 41.8(2) . . ?
C9 P1 C3 100.1(4) . . ?
C9 P1 C1 104.6(4) . . ?
C3 P1 C1 108.2(4) . . ?
C9 P1 Ag1 118.0(3) . . ?
C3 P1 Ag1 117.2(3) . . ?
C1 P1 Ag1 107.7(3) . . ?
C15 P2 C1 103.4(4) . . ?
C15 P2 C2 108.7(4) . . ?
C1 P2 C2 101.5(4) . . ?
C15 P2 Pt1 119.5(3) . . ?
C1 P2 Pt1 114.7(3) . . ?
C2 P2 Pt1 107.5(3) . . ?
C21 P3 C27 104.7(4) . . ?
C21 P3 C2 104.1(4) . 3 ?
C27 P3 C2 105.2(4) . 3 ?
C21 P3 Ag1 114.9(3) . . ?
C27 P3 Ag1 115.1(3) . . ?
C2 P3 Ag1 111.7(3) 3 . ?
C45 N1 C44 107.3(8) . . ?
C45 N1 C47 126.6(9) . . ?
C44 N1 C47 126.0(9) . . ?
P2 C1 P1 114.7(4) . . ?
P2 C2 P3 115.0(4) . 3 ?
C4 C3 C8] 119.6(9) . . ?
C4 C3 P1 121.7(7) . . ?
C8] C3 P1 118.0(8) . . ?
C3 C4 C5 119.4(10) . . ?
C6 C5 C4 120.4(11) . . ?
C5 C6 C7 120.8(11) . . ?
C6 C7 C8] 119.8(11) . . ?
C7 C8] C3 119.9(11) . . ?
C10 C9 C14 116.9(10) . . ?
C10 C9 P1 125.8(8) . . ?
C14 C9 P1 117.3(8) . . ?
C9 C10 C11 121.6(11) . . ?
C12 C11 C10 118.4(12) . . ?
C11 C12 C13 122.1(12) . . ?
C12 C13 C14 118.1(12) . . ?
C13 C14 C9 122.9(12) . . ?
C16 C15 C20 118.3(9) . . ?
C16 C15 P2 119.6(7) . . ?
C20 C15 P2 122.0(8) . . ?
C17 C16 C15 121.1(10) . . ?
C16 C17 C18 119.6(11) . . ?
C19 C18 C17 120.4(11) . . ?
C18 C19 C20 120.5(11) . . ?
C19 C20 C15 119.9(10) . . ?
C26 C21 C22 116.0(10) . . ?
C26 C21 P3 126.4(7) . . ?
C22 C21 P3 117.5(8) . . ?
C21 C22 C23 121.8(12) . . ?
C24 C23 C22 120.7(13) . . ?
C23 C24 C25 118.8(13) . . ?
C24 C25 C26 119.0(13) . . ?
C21 C26 C25 123.4(12) . . ?
C28 C27 C32 120.9(10) . . ?
C28 C27 P3 118.9(8) . . ?
C32 C27 P3 120.2(8) . . ?
C27 C28 C29 120.2(12) . . ?
C30 C29 C28 119.1(13) . . ?
C31 C30 C29 120.6(12) . . ?
C30 C31 C32 121.3(12) . . ?
C27 C32 C31 117.9(11) . . ?
C34 C33 Pt1 177.7(7) . . ?
C34 C33 Ag1 105.1(6) . . ?
Pt1 C33 Ag1 76.9(3) . . ?
C33 C34 C35 174.6(9) . . ?
C46 C35 C36 120.0(8) . . ?
C46 C35 C34 121.3(8) . . ?
C36 C35 C34 118.7(8) . . ?
C37 C36 C35 120.5(9) . . ?
C38 C37 C36 119.7(9) . . ?
C37 C38 C45 119.5(9) . . ?
C37 C38 C39 134.7(10) . . ?
C45 C38 C39 105.8(8) . . ?
C44 C39 C40 119.4(10) . . ?
C44 C39 C38 107.6(9) . . ?
C40 C39 C38 133.0(11) . . ?
C41 C40 C39 118.4(13) . . ?
C40 C41 C42 120.9(13) . . ?
C43 C42 C41 122.4(12) . . ?
C44 C43 C42 116.0(12) . . ?
C43 C44 C39 122.9(11) . . ?
C43 C44 N1 127.7(11) . . ?
C39 C44 N1 109.3(9) . . ?
N1 C45 C46 128.2(9) . . ?
N1 C45 C38 109.9(8) . . ?
C46 C45 C38 121.7(9) . . ?
C45 C46 C35 118.5(8) . . ?
N1 C47 C48 113.5(11) . . ?
O2 Cl1 O4 106.1(13) . . ?
O2 Cl1 O3 104.7(9) . . ?
O4 Cl1 O3 112.1(10) . . ?
O2 Cl1 O1 108.0(8) . . ?
O4 Cl1 O1 109.9(7) . . ?
O3 Cl1 O1 115.5(7) . . ?
Cl3 C49 Cl2 108.8(11) . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         0.905
_refine_diff_density_min         -1.046
_refine_diff_density_rms         0.100
