# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2017

 
data_wei083_0m 
  
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'Cr22 Sn24 Zn72' 
_chemical_formula_weight          8699.20 
  
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'Cr'  'Cr'   0.3209   0.6236 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Zn'  'Zn'   0.2839   1.4301 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Sn'  'Sn'  -0.6537   1.4246 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
  
_symmetry_cell_setting            Cubic 
_symmetry_space_group_name_H-M    Fm-3c 
  
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, -y, z' 
 '-x, y, -z' 
 'x, -y, -z' 
 'z, x, y' 
 'z, -x, -y' 
 '-z, -x, y' 
 '-z, x, -y' 
 'y, z, x' 
 '-y, z, -x' 
 'y, -z, -x' 
 '-y, -z, x' 
 'y+1/2, x+1/2, -z+1/2' 
 '-y+1/2, -x+1/2, -z+1/2' 
 'y+1/2, -x+1/2, z+1/2' 
 '-y+1/2, x+1/2, z+1/2' 
 'x+1/2, z+1/2, -y+1/2' 
 '-x+1/2, z+1/2, y+1/2' 
 '-x+1/2, -z+1/2, -y+1/2' 
 'x+1/2, -z+1/2, y+1/2' 
 'z+1/2, y+1/2, -x+1/2' 
 'z+1/2, -y+1/2, x+1/2' 
 '-z+1/2, y+1/2, x+1/2' 
 '-z+1/2, -y+1/2, -x+1/2' 
 'x, y+1/2, z+1/2' 
 '-x, -y+1/2, z+1/2' 
 '-x, y+1/2, -z+1/2' 
 'x, -y+1/2, -z+1/2' 
 'z, x+1/2, y+1/2' 
 'z, -x+1/2, -y+1/2' 
 '-z, -x+1/2, y+1/2' 
 '-z, x+1/2, -y+1/2' 
 'y, z+1/2, x+1/2' 
 '-y, z+1/2, -x+1/2' 
 'y, -z+1/2, -x+1/2' 
 '-y, -z+1/2, x+1/2' 
 'y+1/2, x+1, -z+1' 
 '-y+1/2, -x+1, -z+1' 
 'y+1/2, -x+1, z+1' 
 '-y+1/2, x+1, z+1' 
 'x+1/2, z+1, -y+1' 
 '-x+1/2, z+1, y+1' 
 '-x+1/2, -z+1, -y+1' 
 'x+1/2, -z+1, y+1' 
 'z+1/2, y+1, -x+1' 
 'z+1/2, -y+1, x+1' 
 '-z+1/2, y+1, x+1' 
 '-z+1/2, -y+1, -x+1' 
 'x+1/2, y, z+1/2' 
 '-x+1/2, -y, z+1/2' 
 '-x+1/2, y, -z+1/2' 
 'x+1/2, -y, -z+1/2' 
 'z+1/2, x, y+1/2' 
 'z+1/2, -x, -y+1/2' 
 '-z+1/2, -x, y+1/2' 
 '-z+1/2, x, -y+1/2' 
 'y+1/2, z, x+1/2' 
 '-y+1/2, z, -x+1/2' 
 'y+1/2, -z, -x+1/2' 
 '-y+1/2, -z, x+1/2' 
 'y+1, x+1/2, -z+1' 
 '-y+1, -x+1/2, -z+1' 
 'y+1, -x+1/2, z+1' 
 '-y+1, x+1/2, z+1' 
 'x+1, z+1/2, -y+1' 
 '-x+1, z+1/2, y+1' 
 '-x+1, -z+1/2, -y+1' 
 'x+1, -z+1/2, y+1' 
 'z+1, y+1/2, -x+1' 
 'z+1, -y+1/2, x+1' 
 '-z+1, y+1/2, x+1' 
 '-z+1, -y+1/2, -x+1' 
 'x+1/2, y+1/2, z' 
 '-x+1/2, -y+1/2, z' 
 '-x+1/2, y+1/2, -z' 
 'x+1/2, -y+1/2, -z' 
 'z+1/2, x+1/2, y' 
 'z+1/2, -x+1/2, -y' 
 '-z+1/2, -x+1/2, y' 
 '-z+1/2, x+1/2, -y' 
 'y+1/2, z+1/2, x' 
 '-y+1/2, z+1/2, -x' 
 'y+1/2, -z+1/2, -x' 
 '-y+1/2, -z+1/2, x' 
 'y+1, x+1, -z+1/2' 
 '-y+1, -x+1, -z+1/2' 
 'y+1, -x+1, z+1/2' 
 '-y+1, x+1, z+1/2' 
 'x+1, z+1, -y+1/2' 
 '-x+1, z+1, y+1/2' 
 '-x+1, -z+1, -y+1/2' 
 'x+1, -z+1, y+1/2' 
 'z+1, y+1, -x+1/2' 
 'z+1, -y+1, x+1/2' 
 '-z+1, y+1, x+1/2' 
 '-z+1, -y+1, -x+1/2' 
 '-x, -y, -z' 
 'x, y, -z' 
 'x, -y, z' 
 '-x, y, z' 
 '-z, -x, -y' 
 '-z, x, y' 
 'z, x, -y' 
 'z, -x, y' 
 '-y, -z, -x' 
 'y, -z, x' 
 '-y, z, x' 
 'y, z, -x' 
 '-y-1/2, -x-1/2, z-1/2' 
 'y-1/2, x-1/2, z-1/2' 
 '-y-1/2, x-1/2, -z-1/2' 
 'y-1/2, -x-1/2, -z-1/2' 
 '-x-1/2, -z-1/2, y-1/2' 
 'x-1/2, -z-1/2, -y-1/2' 
 'x-1/2, z-1/2, y-1/2' 
 '-x-1/2, z-1/2, -y-1/2' 
 '-z-1/2, -y-1/2, x-1/2' 
 '-z-1/2, y-1/2, -x-1/2' 
 'z-1/2, -y-1/2, -x-1/2' 
 'z-1/2, y-1/2, x-1/2' 
 '-x, -y+1/2, -z+1/2' 
 'x, y+1/2, -z+1/2' 
 'x, -y+1/2, z+1/2' 
 '-x, y+1/2, z+1/2' 
 '-z, -x+1/2, -y+1/2' 
 '-z, x+1/2, y+1/2' 
 'z, x+1/2, -y+1/2' 
 'z, -x+1/2, y+1/2' 
 '-y, -z+1/2, -x+1/2' 
 'y, -z+1/2, x+1/2' 
 '-y, z+1/2, x+1/2' 
 'y, z+1/2, -x+1/2' 
 '-y-1/2, -x, z' 
 'y-1/2, x, z' 
 '-y-1/2, x, -z' 
 'y-1/2, -x, -z' 
 '-x-1/2, -z, y' 
 'x-1/2, -z, -y' 
 'x-1/2, z, y' 
 '-x-1/2, z, -y' 
 '-z-1/2, -y, x' 
 '-z-1/2, y, -x' 
 'z-1/2, -y, -x' 
 'z-1/2, y, x' 
 '-x+1/2, -y, -z+1/2' 
 'x+1/2, y, -z+1/2' 
 'x+1/2, -y, z+1/2' 
 '-x+1/2, y, z+1/2' 
 '-z+1/2, -x, -y+1/2' 
 '-z+1/2, x, y+1/2' 
 'z+1/2, x, -y+1/2' 
 'z+1/2, -x, y+1/2' 
 '-y+1/2, -z, -x+1/2' 
 'y+1/2, -z, x+1/2' 
 '-y+1/2, z, x+1/2' 
 'y+1/2, z, -x+1/2' 
 '-y, -x-1/2, z' 
 'y, x-1/2, z' 
 '-y, x-1/2, -z' 
 'y, -x-1/2, -z' 
 '-x, -z-1/2, y' 
 'x, -z-1/2, -y' 
 'x, z-1/2, y' 
 '-x, z-1/2, -y' 
 '-z, -y-1/2, x' 
 '-z, y-1/2, -x' 
 'z, -y-1/2, -x' 
 'z, y-1/2, x' 
 '-x+1/2, -y+1/2, -z' 
 'x+1/2, y+1/2, -z' 
 'x+1/2, -y+1/2, z' 
 '-x+1/2, y+1/2, z' 
 '-z+1/2, -x+1/2, -y' 
 '-z+1/2, x+1/2, y' 
 'z+1/2, x+1/2, -y' 
 'z+1/2, -x+1/2, y' 
 '-y+1/2, -z+1/2, -x' 
 'y+1/2, -z+1/2, x' 
 '-y+1/2, z+1/2, x' 
 'y+1/2, z+1/2, -x' 
 '-y, -x, z-1/2' 
 'y, x, z-1/2' 
 '-y, x, -z-1/2' 
 'y, -x, -z-1/2' 
 '-x, -z, y-1/2' 
 'x, -z, -y-1/2' 
 'x, z, y-1/2' 
 '-x, z, -y-1/2' 
 '-z, -y, x-1/2' 
 '-z, y, -x-1/2' 
 'z, -y, -x-1/2' 
 'z, y, x-1/2' 
  
_cell_length_a                    25.184(3) 
_cell_length_b                    25.184(3) 
_cell_length_c                    25.184(3) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  90.00 
_cell_angle_gamma                 90.00 
_cell_volume                      15972(4) 
_cell_formula_units_Z             8 
_cell_measurement_temperature     273(2) 
_cell_measurement_reflns_used     4254 
_cell_measurement_theta_min       2.80 
_cell_measurement_theta_max       26.10 
  
_exptl_crystal_description        Cubic 
_exptl_crystal_colour             Metallic 
_exptl_crystal_size_max           60 
_exptl_crystal_size_mid           50 
_exptl_crystal_size_min           30 
_exptl_crystal_density_meas       none 
_exptl_crystal_density_diffrn     7.235 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              31104 
_exptl_absorpt_coefficient_mu     31.320 
_exptl_absorpt_correction_type    multi-scan 
_exptl_absorpt_correction_T_min   0.3667 
_exptl_absorpt_correction_T_max   0.7457 
_exptl_absorpt_process_details    ? 
  
_exptl_special_details 
; 
 ? 
; 
  
_diffrn_ambient_temperature       273(2) 
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'Bruker APEX-II CCD' 
_diffrn_measurement_method        'φ and ω scans' 
_diffrn_detector_area_resol_mean  ? 
_diffrn_reflns_number             32313 
_diffrn_reflns_av_R_equivalents   0.0817 
_diffrn_reflns_av_sigmaI/netI     0.0271 
_diffrn_reflns_limit_h_min        -33 
_diffrn_reflns_limit_h_max        33 
_diffrn_reflns_limit_k_min        -32 
_diffrn_reflns_limit_k_max        33 
_diffrn_reflns_limit_l_min        -33 
_diffrn_reflns_limit_l_max        32 
_diffrn_reflns_theta_min          1.62 
_diffrn_reflns_theta_max          28.33 
_reflns_number_total              896 
_reflns_number_gt                 757 
_reflns_threshold_expression      >2sigma(I) 
  
_computing_data_collection        'Bruker APEX2' 
_computing_cell_refinement        'Bruker SAINT' 
_computing_data_reduction         'Bruker SAINT' 
_computing_structure_solution     'SHELXS-97 (Sheldrick, 2008)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 2008)' 
_computing_molecular_graphics     'Bruker SHELXTL' 
_computing_publication_material   'Bruker SHELXTL' 
  
_refine_special_details 
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
  
_refine_ls_structure_factor_coef  Fsqd 
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc 
_refine_ls_weighting_details 
 'calc w=1/[σ²(Fo²)+(0.0191P)²+1774.8928P] where P=(Fo²+2Fc²)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    none 
_refine_ls_hydrogen_treatment     none 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          896 
_refine_ls_number_parameters      60 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0406 
_refine_ls_R_factor_gt            0.0308 
_refine_ls_wR_factor_ref          0.0699 
_refine_ls_wR_factor_gt           0.0661 
_refine_ls_goodness_of_fit_ref    1.094 
_refine_ls_restrained_S_all       1.094 
_refine_ls_shift/su_max           0.010 
_refine_ls_shift/su_mean          0.001 
  
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Cr1 Cr 0.2500 0.2500 0.2500 0.0046(10) Uani 1 24 d S . . 
Cr2 Cr 0.0000 0.0000 0.0000 0.0047(10) Uani 1 24 d S . . 
Cr3 Cr 0.19032(6) 0.19032(6) 0.19032(6) 0.0471(8) Uani 1 3 d S . . 
Cr4 Cr 0.0000 0.11027(6) 0.17559(6) 0.0071(3) Uani 1 2 d S . . 
Zn5 Zn 0.17801(7) 0.0000 0.0000 0.0119(3) Uani 1 4 d S . . 
Zn6 Zn 0.0000 0.05479(5) 0.08698(5) 0.0094(2) Uani 1 2 d S . . 
Zn7 Zn 0.05716(3) 0.14636(3) 0.09011(3) 0.0123(2) Uani 1 1 d . . . 
Zn8 Zn 0.2500 0.05637(3) 0.05637(3) 0.0125(3) Uani 1 2 d S . . 
Zn9 Zn 0.0000 0.21888(5) 0.14842(5) 0.0162(3) Uani 1 2 d S . . 
Zn10 Zn 0.1536(2) 0.2671(3) 0.2689(7) 0.120(7) Uani 0.25 1 d P . . 
Sn11 Sn 0.08595(2) 0.16302(2) 0.20538(2) 0.01759(17) Uani 1 1 d . . . 
  
  
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
  
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Cr1 Zn10 2.512(5) 93_445 ? 
Cr1 Zn10 2.512(5) 42_544 ? 
Cr1 Zn10 2.512(5) 84 ? 
Cr1 Zn10 2.512(5) 56 ? 
Cr1 Zn10 2.512(5) 63_454 ? 
Cr1 Zn10 2.512(5) 28 ? 
Cr1 Zn10 2.512(5) 89_445 ? 
Cr1 Zn10 2.512(5) 40_544 ? 
Cr1 Zn10 2.512(5) 79 ? 
Cr1 Zn10 2.512(5) 51 ? 
Cr1 Zn10 2.512(5) 47_544 ? 
Cr1 Zn10 2.512(5) 74 ? 
Cr2 Sn5 2.5889(12) 97 ? 
Cr2 Sn5 2.5889(12) 105 ? 
Cr2 Sn5 2.5889(12) 9 ? 
Cr2 Sn5 2.5889(12) 101 ? 
Cr2 Sn5 2.5889(12) 5 ? 
Cr2 Sn5 2.5889(12) 2 ? 
Cr2 Sn5 2.5889(12) 98 ? 
Cr2 Sn5 2.5889(12) 106 ? 
Cr2 Sn5 2.5889(12) 102 ? 
Cr2 Sn5 2.5889(12) 6 ? 
Cr2 Sn5 2.5889(12) 10 ? 
Cr2 Sn5 2.5889(12) . ? 
Cr3 Zn10 1.749(10) 84 ? 
Cr3 Zn10 1.749(10) 56 ? 
Cr3 Zn10 1.749(10) 28 ? 
Cr3 Zn10 2.434(15) 89_445 ? 
Cr3 Zn10 2.434(15) 40_544 ? 
Cr3 Zn10 2.434(15) 70_454 ? 
Cr3 Zn10 2.377(12) 85_445 ? 
Cr3 Zn10 2.377(12) 47_544 ? 
Cr3 Zn10 2.377(12) 68_454 ? 
Cr3 Sn11 2.7432(18) . ? 
Cr3 Sn11 2.7432(18) 9 ? 
Cr4 Sn5 2.633(2) . ? 
Cr4 Sn11 2.6482(11) . ? 
Cr4 Sn11 2.6482(11) 100 ? 
Cr4 Sn7 2.7147(14) 9 ? 
Cr4 Sn7 2.7147(14) 107 ? 
Cr4 Sn6 2.7350(13) 102 ? 
Cr4 Sn6 2.7350(13) 5 ? 
Cr4 Sn6 2.7445(16) 100 ? 
Cr4 Sn6 2.7446(16) . ? 
Cr4 Sn4 2.7776(16) 9 ? 
Cr4 Zn9 2.819(2) . ? 
Cr4 Zn9 2.826(2) 89_445 ? 
Sn4 Sn5 2.6756(19) 6 ? 
Sn4 Sn5 2.6756(19) 5 ? 
Sn4 Sn7 2.7050(15) . ? 
Sn4 Sn7 2.7050(15) 98 ? 
Sn4 Sn7 2.7050(15) 99 ? 
Sn4 Sn7 2.7050(15) 4 ? 
Sn4 Cr4 2.7776(16) 6 ? 
Sn4 Cr4 2.7776(16) 5 ? 
Sn4 Sn6 2.8031(11) 11 ? 
Sn4 Sn6 2.8031(11) 9 ? 
Sn4 Sn6 2.8031(11) 106 ? 
Sn4 Sn6 2.8031(11) 108 ? 
Sn5 Sn4 2.6756(19) 9 ? 
Sn5 Sn5 2.7129(14) 10 ? 
Sn5 Sn5 2.7129(14) 9 ? 
Sn5 Sn5 2.7129(14) 102 ? 
Sn5 Sn5 2.7129(14) 5 ? 
Sn5 Sn6 2.7184(11) 5 ? 
Sn5 Sn6 2.7184(11) 102 ? 
Sn5 Sn6 2.7198(14) . ? 
Sn5 Sn6 2.7198(14) 100 ? 
Sn5 Sn5 2.759(2) 2 ? 
Sn6 Sn5 2.7183(11) 9 ? 
Sn6 Cr4 2.7349(13) 9 ? 
Sn6 Sn7 2.7450(10) 5 ? 
Sn6 Zn9 2.7503(15) . ? 
Sn6 Sn6 2.7823(15) 9 ? 
Sn6 Sn6 2.7824(15) 5 ? 
Sn6 Sn4 2.8031(11) 5 ? 
Sn6 Sn6 2.8792(18) 100 ? 
Sn6 Sn11 3.0214(11) . ? 
Sn6 Sn11 3.0541(11) 9 ? 
Sn7 Sn4 2.7050(14) 137_655 ? 
Sn7 Cr4 2.7146(14) 5 ? 
Sn7 Cr4 2.7146(14) 142_655 ? 
Sn7 Sn6 2.7449(10) 40_544 ? 
Sn7 Sn6 2.7449(10) 9 ? 
Sn7 Zn9 2.8291(12) 133_655 ? 
Sn7 Zn9 2.8291(12) 9 ? 
Sn7 Sn7 2.8390(17) 98 ? 
Sn7 Sn7 2.8390(17) 99 ? 
Sn7 Sn11 3.0053(12) 47_544 ? 
Sn7 Sn11 3.0053(12) 5 ? 
Zn9 Sn6 2.7502(15) 100 ? 
Zn9 Cr4 2.826(2) 161_565 ? 
Zn9 Sn7 2.8291(12) 102 ? 
Zn9 Sn7 2.8291(12) 5 ? 
Zn9 Sn11 2.9083(11) 68_454 ? 
Zn9 Sn11 2.9083(11) 161_565 ? 
Zn9 Sn11 2.9532(11) . ? 
Zn9 Sn11 2.9532(11) 100 ? 
Zn10 Zn10 0.910(15) 89_445 ? 
Zn10 Zn10 0.910(15) 68_454 ? 
Zn10 Zn10 1.29(2) 28 ? 
Zn10 Cr3 1.748(10) 28 ? 
Zn10 Cr3 2.434(15) 63_454 ? 
Zn10 Cr3 2.377(12) 85_445 ? 
Zn10 Sn11 2.532(5) 28 ? 
Zn10 Zn10 2.793(15) 79 ? 
Zn10 Zn10 2.793(15) 58 ? 
Zn10 Zn10 2.98(2) 14 ? 
Sn11 Zn10 2.532(5) 28 ? 
Sn11 Zn9 2.9083(11) 89_445 ? 
Sn11 Zn10 2.873(13) 68_454 ? 
Sn11 Sn7 3.0053(12) 9 ? 
Sn11 Sn6 3.0540(11) 5 ? 
Sn11 Zn10 3.240(16) 89_445 ? 
  
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
Zn10 Cr1 Zn10 67.5(4) 93_445 42_544 ? 
Zn10 Cr1 Zn10 178.5(7) 93_445 84 ? 
Zn10 Cr1 Zn10 111.6(3) 42_544 84 ? 
Zn10 Cr1 Zn10 111.6(3) 93_445 56 ? 
Zn10 Cr1 Zn10 113.4(7) 42_544 56 ? 
Zn10 Cr1 Zn10 67.5(4) 84 56 ? 
Zn10 Cr1 Zn10 67.5(4) 93_445 63_454 ? 
Zn10 Cr1 Zn10 67.5(4) 42_544 63_454 ? 
Zn10 Cr1 Zn10 113.4(7) 84 63_454 ? 
Zn10 Cr1 Zn10 178.5(7) 56 63_454 ? 
Zn10 Cr1 Zn10 113.4(7) 93_445 28 ? 
Zn10 Cr1 Zn10 178.5(7) 42_544 28 ? 
Zn10 Cr1 Zn10 67.5(4) 84 28 ? 
Zn10 Cr1 Zn10 67.5(4) 56 28 ? 
Zn10 Cr1 Zn10 111.6(3) 63_454 28 ? 
Zn10 Cr1 Zn10 108.5(2) 93_445 89_445 ? 
Zn10 Cr1 Zn10 158.1(8) 42_544 89_445 ? 
Zn10 Cr1 Zn10 72.8(5) 84 89_445 ? 
Zn10 Cr1 Zn10 88.31(7) 56 89_445 ? 
Zn10 Cr1 Zn10 90.9(4) 63_454 89_445 ? 
Zn10 Cr1 Zn10 20.9(3) 28 89_445 ? 
Zn10 Cr1 Zn10 90.9(4) 93_445 40_544 ? 
Zn10 Cr1 Zn10 108.5(2) 42_544 40_544 ? 
Zn10 Cr1 Zn10 88.31(7) 84 40_544 ? 
Zn10 Cr1 Zn10 20.9(3) 56 40_544 ? 
Zn10 Cr1 Zn10 158.1(8) 63_454 40_544 ? 
Zn10 Cr1 Zn10 72.8(5) 28 40_544 ? 
Zn10 Cr1 Zn10 92.9(5) 89_445 40_544 ? 
Zn10 Cr1 Zn10 72.8(5) 93_445 79 ? 
Zn10 Cr1 Zn10 88.31(7) 42_544 79 ? 
Zn10 Cr1 Zn10 108.5(2) 84 79 ? 
Zn10 Cr1 Zn10 158.1(8) 56 79 ? 
Zn10 Cr1 Zn10 20.9(4) 63_454 79 ? 
Zn10 Cr1 Zn10 90.9(5) 28 79 ? 
Zn10 Cr1 Zn10 70.3(8) 89_445 79 ? 
Zn10 Cr1 Zn10 150.4(5) 40_544 79 ? 
Zn10 Cr1 Zn10 88.31(7) 93_445 51 ? 
Zn10 Cr1 Zn10 20.9(3) 42_544 51 ? 
Zn10 Cr1 Zn10 90.9(4) 84 51 ? 
Zn10 Cr1 Zn10 108.5(2) 56 51 ? 
Zn10 Cr1 Zn10 72.8(5) 63_454 51 ? 
Zn10 Cr1 Zn10 158.1(8) 28 51 ? 
Zn10 Cr1 Zn10 150.4(5) 89_445 51 ? 
Zn10 Cr1 Zn10 111.6(3) 40_544 51 ? 
Zn10 Cr1 Zn10 92.9(5) 79 51 ? 
Zn10 Cr1 Zn10 160.2(4) 93_445 47_544 ? 
Zn10 Cr1 Zn10 108.5(2) 42_544 47_544 ? 
Zn10 Cr1 Zn10 20.9(3) 84 47_544 ? 
Zn10 Cr1 Zn10 87.93(14) 56 47_544 ? 
Zn10 Cr1 Zn10 92.9(5) 63_454 47_544 ? 
Zn10 Cr1 Zn10 70.3(8) 28 47_544 ? 
Zn10 Cr1 Zn10 67.5(4) 89_445 47_544 ? 
Zn10 Cr1 Zn10 108.5(2) 40_544 47_544 ? 
Zn10 Cr1 Zn10 87.93(14) 79 47_544 ? 
Zn10 Cr1 Zn10 88.31(7) 51 47_544 ? 
Zn10 Cr1 Zn10 70.3(8) 93_445 74 ? 
Zn10 Cr1 Zn10 20.9(3) 42_544 74 ? 
Zn10 Cr1 Zn10 108.5(2) 84 74 ? 
Zn10 Cr1 Zn10 92.9(5) 56 74 ? 
Zn10 Cr1 Zn10 87.93(14) 63_454 74 ? 
Zn10 Cr1 Zn10 160.2(4) 28 74 ? 
Zn10 Cr1 Zn10 178.5(7) 89_445 74 ? 
Zn10 Cr1 Zn10 87.93(14) 40_544 74 ? 
Zn10 Cr1 Zn10 108.5(2) 79 74 ? 
Zn10 Cr1 Zn10 29.7(5) 51 74 ? 
Zn10 Cr1 Zn10 113.4(7) 47_544 74 ? 
Sn5 Cr2 Sn5 63.195(13) 97 105 ? 
Sn5 Cr2 Sn5 116.805(13) 97 9 ? 
Sn5 Cr2 Sn5 180.00(5) 105 9 ? 
Sn5 Cr2 Sn5 63.195(13) 97 101 ? 
Sn5 Cr2 Sn5 63.195(13) 105 101 ? 
Sn5 Cr2 Sn5 116.805(13) 9 101 ? 
Sn5 Cr2 Sn5 116.805(13) 97 5 ? 
Sn5 Cr2 Sn5 116.805(13) 105 5 ? 
Sn5 Cr2 Sn5 63.195(13) 9 5 ? 
Sn5 Cr2 Sn5 180.00(5) 101 5 ? 
Sn5 Cr2 Sn5 115.59(5) 97 2 ? 
Sn5 Cr2 Sn5 63.195(13) 105 2 ? 
Sn5 Cr2 Sn5 116.805(13) 9 2 ? 
Sn5 Cr2 Sn5 116.805(13) 101 2 ? 
Sn5 Cr2 Sn5 63.195(13) 5 2 ? 
Sn5 Cr2 Sn5 64.41(5) 97 98 ? 
Sn5 Cr2 Sn5 116.805(13) 105 98 ? 
Sn5 Cr2 Sn5 63.195(13) 9 98 ? 
Sn5 Cr2 Sn5 63.195(13) 101 98 ? 
Sn5 Cr2 Sn5 116.805(13) 5 98 ? 
Sn5 Cr2 Sn5 180.00(5) 2 98 ? 
Sn5 Cr2 Sn5 63.195(13) 97 106 ? 
Sn5 Cr2 Sn5 64.41(5) 105 106 ? 
Sn5 Cr2 Sn5 115.59(5) 9 106 ? 
Sn5 Cr2 Sn5 116.805(13) 101 106 ? 
Sn5 Cr2 Sn5 63.195(13) 5 106 ? 
Sn5 Cr2 Sn5 63.195(13) 2 106 ? 
Sn5 Cr2 Sn5 116.805(13) 98 106 ? 
Sn5 Cr2 Sn5 116.805(13) 97 102 ? 
Sn5 Cr2 Sn5 63.195(13) 105 102 ? 
Sn5 Cr2 Sn5 116.805(13) 9 102 ? 
Sn5 Cr2 Sn5 64.41(5) 101 102 ? 
Sn5 Cr2 Sn5 115.59(5) 5 102 ? 
Sn5 Cr2 Sn5 63.195(13) 2 102 ? 
Sn5 Cr2 Sn5 116.805(13) 98 102 ? 
Sn5 Cr2 Sn5 116.805(13) 106 102 ? 
Sn5 Cr2 Sn5 63.195(13) 97 6 ? 
Sn5 Cr2 Sn5 116.805(13) 105 6 ? 
Sn5 Cr2 Sn5 63.195(13) 9 6 ? 
Sn5 Cr2 Sn5 115.59(5) 101 6 ? 
Sn5 Cr2 Sn5 64.41(5) 5 6 ? 
Sn5 Cr2 Sn5 116.805(13) 2 6 ? 
Sn5 Cr2 Sn5 63.195(13) 98 6 ? 
Sn5 Cr2 Sn5 63.195(13) 106 6 ? 
Sn5 Cr2 Sn5 180.00(5) 102 6 ? 
Sn5 Cr2 Sn5 116.805(13) 97 10 ? 
Sn5 Cr2 Sn5 115.59(5) 105 10 ? 
Sn5 Cr2 Sn5 64.41(5) 9 10 ? 
Sn5 Cr2 Sn5 63.195(13) 101 10 ? 
Sn5 Cr2 Sn5 116.805(13) 5 10 ? 
Sn5 Cr2 Sn5 116.805(13) 2 10 ? 
Sn5 Cr2 Sn5 63.195(13) 98 10 ? 
Sn5 Cr2 Sn5 180.00(5) 106 10 ? 
Sn5 Cr2 Sn5 63.195(13) 102 10 ? 
Sn5 Cr2 Sn5 116.805(13) 6 10 ? 
Sn5 Cr2 Sn5 180.00(5) 97 . ? 
Sn5 Cr2 Sn5 116.805(13) 105 . ? 
Sn5 Cr2 Sn5 63.195(13) 9 . ? 
Sn5 Cr2 Sn5 116.805(13) 101 . ? 
Sn5 Cr2 Sn5 63.195(13) 5 . ? 
Sn5 Cr2 Sn5 64.41(5) 2 . ? 
Sn5 Cr2 Sn5 115.59(5) 98 . ? 
Sn5 Cr2 Sn5 116.805(13) 106 . ? 
Sn5 Cr2 Sn5 63.195(13) 102 . ? 
Sn5 Cr2 Sn5 116.805(13) 6 . ? 
Sn5 Cr2 Sn5 63.195(13) 10 . ? 
Zn10 Cr3 Zn10 106.0(2) 84 56 ? 
Zn10 Cr3 Zn10 106.0(2) 84 28 ? 
Zn10 Cr3 Zn10 106.0(2) 56 28 ? 
Zn10 Cr3 Zn10 89.4(4) 84 89_445 ? 
Zn10 Cr3 Zn10 112.6(4) 56 89_445 ? 
Zn10 Cr3 Zn10 16.7(3) 28 89_445 ? 
Zn10 Cr3 Zn10 112.6(4) 84 40_544 ? 
Zn10 Cr3 Zn10 16.7(3) 56 40_544 ? 
Zn10 Cr3 Zn10 89.4(4) 28 40_544 ? 
Zn10 Cr3 Zn10 96.8(2) 89_445 40_544 ? 
Zn10 Cr3 Zn10 16.7(3) 84 70_454 ? 
Zn10 Cr3 Zn10 89.4(4) 56 70_454 ? 
Zn10 Cr3 Zn10 112.6(4) 28 70_454 ? 
Zn10 Cr3 Zn10 96.8(2) 89_445 70_454 ? 
Zn10 Cr3 Zn10 96.8(2) 40_544 70_454 ? 
Zn10 Cr3 Zn10 87.6(6) 84 85_445 ? 
Zn10 Cr3 Zn10 18.6(7) 56 85_445 ? 
Zn10 Cr3 Zn10 114.6(7) 28 85_445 ? 
Zn10 Cr3 Zn10 115.9(3) 89_445 85_445 ? 
Zn10 Cr3 Zn10 31.0(5) 40_544 85_445 ? 
Zn10 Cr3 Zn10 70.9(5) 70_454 85_445 ? 
Zn10 Cr3 Zn10 18.6(7) 84 47_544 ? 
Zn10 Cr3 Zn10 114.6(7) 56 47_544 ? 
Zn10 Cr3 Zn10 87.6(6) 28 47_544 ? 
Zn10 Cr3 Zn10 70.9(5) 89_445 47_544 ? 
Zn10 Cr3 Zn10 115.9(3) 40_544 47_544 ? 
Zn10 Cr3 Zn10 31.0(5) 70_454 47_544 ? 
Zn10 Cr3 Zn10 97.7(3) 85_445 47_544 ? 
Zn10 Cr3 Zn10 114.6(7) 84 68_454 ? 
Zn10 Cr3 Zn10 87.6(6) 56 68_454 ? 
Zn10 Cr3 Zn10 18.6(7) 28 68_454 ? 
Zn10 Cr3 Zn10 31.0(5) 89_445 68_454 ? 
Zn10 Cr3 Zn10 70.9(5) 40_544 68_454 ? 
Zn10 Cr3 Zn10 115.9(3) 70_454 68_454 ? 
Zn10 Cr3 Zn10 97.7(3) 85_445 68_454 ? 
Zn10 Cr3 Zn10 97.7(3) 47_544 68_454 ? 
Zn10 Cr3 Cr1 67.2(2) 84 . ? 
Zn10 Cr3 Cr1 67.2(2) 56 . ? 
Zn10 Cr3 Cr1 67.2(2) 28 . ? 
Zn10 Cr3 Cr1 59.72(19) 89_445 . ? 
Zn10 Cr3 Cr1 59.72(19) 40_544 . ? 
Zn10 Cr3 Cr1 59.72(19) 70_454 . ? 
Zn10 Cr3 Cr1 60.4(2) 85_445 . ? 
Zn10 Cr3 Cr1 60.4(2) 47_544 . ? 
Zn10 Cr3 Cr1 60.4(2) 68_454 . ? 
Zn10 Cr3 Sn11 143.8(4) 84 . ? 
Zn10 Cr3 Sn11 110.2(5) 56 . ? 
Zn10 Cr3 Sn11 64.23(17) 28 . ? 
Zn10 Cr3 Sn11 77.2(2) 89_445 . ? 
Zn10 Cr3 Sn11 102.36(15) 40_544 . ? 
Zn10 Cr3 Sn11 160.4(2) 70_454 . ? 
Zn10 Cr3 Sn11 128.5(2) 85_445 . ? 
Zn10 Cr3 Sn11 132.2(3) 47_544 . ? 
Zn10 Cr3 Sn11 67.8(2) 68_454 . ? 
Cr1 Cr3 Sn11 128.17(4) . . ? 
Zn10 Cr3 Sn11 64.23(17) 84 9 ? 
Zn10 Cr3 Sn11 143.8(4) 56 9 ? 
Zn10 Cr3 Sn11 110.2(5) 28 9 ? 
Zn10 Cr3 Sn11 102.35(15) 89_445 9 ? 
Zn10 Cr3 Sn11 160.4(2) 40_544 9 ? 
Zn10 Cr3 Sn11 77.2(2) 70_454 9 ? 
Zn10 Cr3 Sn11 132.2(3) 85_445 9 ? 
Zn10 Cr3 Sn11 67.8(2) 47_544 9 ? 
Zn10 Cr3 Sn11 128.5(2) 68_454 9 ? 
Cr1 Cr3 Sn11 128.17(4) . 9 ? 
Sn11 Cr3 Sn11 85.82(7) . 9 ? 
Sn5 Cr4 Sn11 120.42(4) . . ? 
Sn5 Cr4 Sn11 120.43(4) . 100 ? 
Sn11 Cr4 Sn11 109.64(6) . 100 ? 
Sn5 Cr4 Sn7 108.65(6) . 9 ? 
Sn11 Cr4 Sn7 68.15(4) . 9 ? 
Sn11 Cr4 Sn7 118.86(6) 100 9 ? 
Sn5 Cr4 Sn7 108.65(6) . 107 ? 
Sn11 Cr4 Sn7 118.86(6) . 107 ? 
Sn11 Cr4 Sn7 68.15(4) 100 107 ? 
Sn7 Cr4 Sn7 63.05(5) 9 107 ? 
Sn5 Cr4 Sn6 60.82(4) . 102 ? 
Sn11 Cr4 Sn6 178.70(6) . 102 ? 
Sn11 Cr4 Sn6 69.11(2) 100 102 ? 
Sn7 Cr4 Sn6 112.03(6) 9 102 ? 
Sn7 Cr4 Sn6 60.49(3) 107 102 ? 
Sn5 Cr4 Sn6 60.82(4) . 5 ? 
Sn11 Cr4 Sn6 69.11(2) . 5 ? 
Sn11 Cr4 Sn6 178.69(6) 100 5 ? 
Sn7 Cr4 Sn6 60.49(3) 9 5 ? 
Sn7 Cr4 Sn6 112.03(6) 107 5 ? 
Sn6 Cr4 Sn6 112.15(7) 102 5 ? 
Sn5 Cr4 Sn6 60.73(4) . 100 ? 
Sn11 Cr4 Sn6 119.00(6) . 100 ? 
Sn11 Cr4 Sn6 68.12(3) 100 100 ? 
Sn7 Cr4 Sn6 168.91(7) 9 100 ? 
Sn7 Cr4 Sn6 115.64(3) 107 100 ? 
Sn6 Cr4 Sn6 61.03(4) 102 100 ? 
Sn6 Cr4 Sn6 112.71(6) 5 100 ? 
Sn5 Cr4 Sn6 60.73(4) . . ? 
Sn11 Cr4 Sn6 68.12(3) . . ? 
Sn11 Cr4 Sn6 119.00(6) 100 . ? 
Sn7 Cr4 Sn6 115.64(3) 9 . ? 
Sn7 Cr4 Sn6 168.91(7) 107 . ? 
Sn6 Cr4 Sn6 112.71(6) 102 . ? 
Sn6 Cr4 Sn6 61.03(4) 5 . ? 
Sn6 Cr4 Sn6 63.27(5) 100 . ? 
Sn5 Cr4 Sn4 59.21(6) . 9 ? 
Sn11 Cr4 Sn4 119.69(4) . 9 ? 
Sn11 Cr4 Sn4 119.69(4) 100 9 ? 
Sn7 Cr4 Sn4 59.00(5) 9 9 ? 
Sn7 Cr4 Sn4 59.00(5) 107 9 ? 
Sn6 Cr4 Sn4 61.12(4) 102 9 ? 
Sn6 Cr4 Sn4 61.12(4) 5 9 ? 
Sn6 Cr4 Sn4 110.39(6) 100 9 ? 
Sn6 Cr4 Sn4 110.39(6) . 9 ? 
Sn5 Cr4 Zn9 108.01(6) . . ? 
Sn11 Cr4 Zn9 65.30(4) . . ? 
Sn11 Cr4 Zn9 65.30(4) 100 . ? 
Sn7 Cr4 Zn9 130.74(6) 9 . ? 
Sn7 Cr4 Zn9 130.74(6) 107 . ? 
Sn6 Cr4 Zn9 114.15(4) 102 . ? 
Sn6 Cr4 Zn9 114.15(4) 5 . ? 
Sn6 Cr4 Zn9 59.23(4) 100 . ? 
Sn6 Cr4 Zn9 59.23(4) . . ? 
Sn4 Cr4 Zn9 167.22(8) 9 . ? 
Sn5 Cr4 Zn9 167.82(8) . 89_445 ? 
Sn11 Cr4 Zn9 64.09(4) . 89_445 ? 
Sn11 Cr4 Zn9 64.08(4) 100 89_445 ? 
Sn7 Cr4 Zn9 61.37(4) 9 89_445 ? 
Sn7 Cr4 Zn9 61.37(4) 107 89_445 ? 
Sn6 Cr4 Zn9 114.79(4) 102 89_445 ? 
Sn6 Cr4 Zn9 114.79(4) 5 89_445 ? 
Sn6 Cr4 Zn9 128.68(5) 100 89_445 ? 
Sn6 Cr4 Zn9 128.68(5) . 89_445 ? 
Sn4 Cr4 Zn9 108.62(7) 9 89_445 ? 
Zn9 Cr4 Zn9 84.17(7) . 89_445 ? 
Sn5 Sn4 Sn5 62.08(6) 6 5 ? 
Sn5 Sn4 Sn7 147.66(3) 6 . ? 
Sn5 Sn4 Sn7 107.68(3) 5 . ? 
Sn5 Sn4 Sn7 107.68(3) 6 98 ? 
Sn5 Sn4 Sn7 147.66(3) 5 98 ? 
Sn7 Sn4 Sn7 63.31(4) . 98 ? 
Sn5 Sn4 Sn7 147.66(3) 6 99 ? 
Sn5 Sn4 Sn7 107.68(3) 5 99 ? 
Sn7 Sn4 Sn7 63.31(4) . 99 ? 
Sn7 Sn4 Sn7 95.83(6) 98 99 ? 
Sn5 Sn4 Sn7 107.68(3) 6 4 ? 
Sn5 Sn4 Sn7 147.66(3) 5 4 ? 
Sn7 Sn4 Sn7 95.83(6) . 4 ? 
Sn7 Sn4 Sn7 63.31(4) 98 4 ? 
Sn7 Sn4 Sn7 63.31(4) 99 4 ? 
Sn5 Sn4 Cr4 57.70(5) 6 6 ? 
Sn5 Sn4 Cr4 119.78(7) 5 6 ? 
Sn7 Sn4 Cr4 122.64(5) . 6 ? 
Sn7 Sn4 Cr4 59.34(3) 98 6 ? 
Sn7 Sn4 Cr4 122.64(5) 99 6 ? 
Sn7 Sn4 Cr4 59.34(3) 4 6 ? 
Sn5 Sn4 Cr4 119.78(7) 6 5 ? 
Sn5 Sn4 Cr4 57.70(5) 5 5 ? 
Sn7 Sn4 Cr4 59.34(3) . 5 ? 
Sn7 Sn4 Cr4 122.64(5) 98 5 ? 
Sn7 Sn4 Cr4 59.34(3) 99 5 ? 
Sn7 Sn4 Cr4 122.64(5) 4 5 ? 
Cr4 Sn4 Cr4 177.48(10) 6 5 ? 
Sn5 Sn4 Sn6 59.44(3) 6 11 ? 
Sn5 Sn4 Sn6 91.21(5) 5 11 ? 
Sn7 Sn4 Sn6 152.24(6) . 11 ? 
Sn7 Sn4 Sn6 110.24(3) 98 11 ? 
Sn7 Sn4 Sn6 92.02(2) 99 11 ? 
Sn7 Sn4 Sn6 59.75(2) 4 11 ? 
Cr4 Sn4 Sn6 58.69(2) 6 11 ? 
Cr4 Sn4 Sn6 120.48(3) 5 11 ? 
Sn5 Sn4 Sn6 91.21(5) 6 9 ? 
Sn5 Sn4 Sn6 59.44(3) 5 9 ? 
Sn7 Sn4 Sn6 59.75(2) . 9 ? 
Sn7 Sn4 Sn6 92.02(2) 98 9 ? 
Sn7 Sn4 Sn6 110.24(3) 99 9 ? 
Sn7 Sn4 Sn6 152.24(6) 4 9 ? 
Cr4 Sn4 Sn6 120.48(3) 6 9 ? 
Cr4 Sn4 Sn6 58.69(2) 5 9 ? 
Sn6 Sn4 Sn6 146.96(7) 11 9 ? 
Sn5 Sn4 Sn6 91.21(5) 6 106 ? 
Sn5 Sn4 Sn6 59.44(3) 5 106 ? 
Sn7 Sn4 Sn6 110.24(3) . 106 ? 
Sn7 Sn4 Sn6 152.24(6) 98 106 ? 
Sn7 Sn4 Sn6 59.75(2) 99 106 ? 
Sn7 Sn4 Sn6 92.02(2) 4 106 ? 
Cr4 Sn4 Sn6 120.48(3) 6 106 ? 
Cr4 Sn4 Sn6 58.69(2) 5 106 ? 
Sn6 Sn4 Sn6 61.80(4) 11 106 ? 
Sn6 Sn4 Sn6 108.11(4) 9 106 ? 
Sn5 Sn4 Sn6 59.44(3) 6 108 ? 
Sn5 Sn4 Sn6 91.21(5) 5 108 ? 
Sn7 Sn4 Sn6 92.02(2) . 108 ? 
Sn7 Sn4 Sn6 59.75(2) 98 108 ? 
Sn7 Sn4 Sn6 152.24(6) 99 108 ? 
Sn7 Sn4 Sn6 110.24(3) 4 108 ? 
Cr4 Sn4 Sn6 58.69(2) 6 108 ? 
Cr4 Sn4 Sn6 120.48(3) 5 108 ? 
Sn6 Sn4 Sn6 108.11(4) 11 108 ? 
Sn6 Sn4 Sn6 61.80(4) 9 108 ? 
Sn6 Sn4 Sn6 146.96(7) 106 108 ? 
Cr2 Sn5 Cr4 179.85(6) . . ? 
Cr2 Sn5 Sn4 116.75(5) . 9 ? 
Cr4 Sn5 Sn4 63.10(5) . 9 ? 
Cr2 Sn5 Sn5 58.402(6) . 10 ? 
Cr4 Sn5 Sn5 121.72(5) . 10 ? 
Sn4 Sn5 Sn5 147.77(4) 9 10 ? 
Cr2 Sn5 Sn5 58.402(6) . 9 ? 
Cr4 Sn5 Sn5 121.72(5) . 9 ? 
Sn4 Sn5 Sn5 147.77(4) 9 9 ? 
Sn5 Sn5 Sn5 61.14(6) 10 9 ? 
Cr2 Sn5 Sn5 58.402(6) . 102 ? 
Cr4 Sn5 Sn5 121.55(3) . 102 ? 
Sn4 Sn5 Sn5 89.65(5) 9 102 ? 
Sn5 Sn5 Sn5 60.0 10 102 ? 
Sn5 Sn5 Sn5 108.74(4) 9 102 ? 
Cr2 Sn5 Sn5 58.402(6) . 5 ? 
Cr4 Sn5 Sn5 121.55(3) . 5 ? 
Sn4 Sn5 Sn5 89.65(5) 9 5 ? 
Sn5 Sn5 Sn5 108.74(4) 10 5 ? 
Sn5 Sn5 Sn5 60.0 9 5 ? 
Sn5 Sn5 Sn5 107.699(17) 102 5 ? 
Cr2 Sn5 Sn6 118.50(3) . 5 ? 
Cr4 Sn5 Sn6 61.45(3) . 5 ? 
Sn4 Sn5 Sn6 62.62(3) 9 5 ? 
Sn5 Sn5 Sn6 149.56(6) 10 5 ? 
Sn5 Sn5 Sn6 90.75(2) 9 5 ? 
Sn5 Sn5 Sn6 148.18(7) 102 5 ? 
Sn5 Sn5 Sn6 60.10(3) 5 5 ? 
Cr2 Sn5 Sn6 118.50(3) . 102 ? 
Cr4 Sn5 Sn6 61.45(3) . 102 ? 
Sn4 Sn5 Sn6 62.62(3) 9 102 ? 
Sn5 Sn5 Sn6 90.75(2) 10 102 ? 
Sn5 Sn5 Sn6 149.56(6) 9 102 ? 
Sn5 Sn5 Sn6 60.10(3) 102 102 ? 
Sn5 Sn5 Sn6 148.18(7) 5 102 ? 
Sn6 Sn5 Sn6 113.19(5) 5 102 ? 
Cr2 Sn5 Sn6 118.45(4) . . ? 
Cr4 Sn5 Sn6 61.67(4) . . ? 
Sn4 Sn5 Sn6 114.36(4) 9 . ? 
Sn5 Sn5 Sn6 92.24(6) 10 . ? 
Sn5 Sn5 Sn6 60.05(4) 9 . ? 
Sn5 Sn5 Sn6 150.15(6) 102 . ? 
Sn5 Sn5 Sn6 90.72(3) 5 . ? 
Sn6 Sn5 Sn6 61.55(4) 5 . ? 
Sn6 Sn5 Sn6 114.03(4) 102 . ? 
Cr2 Sn5 Sn6 118.45(4) . 100 ? 
Cr4 Sn5 Sn6 61.67(4) . 100 ? 
Sn4 Sn5 Sn6 114.36(4) 9 100 ? 
Sn5 Sn5 Sn6 60.05(4) 10 100 ? 
Sn5 Sn5 Sn6 92.24(6) 9 100 ? 
Sn5 Sn5 Sn6 90.72(3) 102 100 ? 
Sn5 Sn5 Sn6 150.15(6) 5 100 ? 
Sn6 Sn5 Sn6 114.03(4) 5 100 ? 
Sn6 Sn5 Sn6 61.55(4) 102 100 ? 
Sn6 Sn5 Sn6 63.92(4) . 100 ? 
Cr2 Sn5 Sn5 57.79(3) . 2 ? 
Cr4 Sn5 Sn5 122.05(4) . 2 ? 
Sn4 Sn5 Sn5 58.96(3) 9 2 ? 
Sn5 Sn5 Sn5 107.39(3) 10 2 ? 
Sn5 Sn5 Sn5 107.39(3) 9 2 ? 
Sn5 Sn5 Sn5 59.43(3) 102 2 ? 
Sn5 Sn5 Sn5 59.43(3) 5 2 ? 
Sn6 Sn5 Sn5 91.26(3) 5 2 ? 
Sn6 Sn5 Sn5 91.26(3) 102 2 ? 
Sn6 Sn5 Sn5 147.99(2) . 2 ? 
Sn6 Sn5 Sn5 147.99(2) 100 2 ? 
Sn5 Sn6 Sn5 59.85(5) 9 . ? 
Sn5 Sn6 Cr4 57.73(4) 9 9 ? 
Sn5 Sn6 Cr4 117.58(5) . 9 ? 
Sn5 Sn6 Cr4 117.45(5) 9 . ? 
Sn5 Sn6 Cr4 57.60(4) . . ? 
Cr4 Sn6 Cr4 175.15(7) 9 . ? 
Sn5 Sn6 Sn7 105.34(4) 9 5 ? 
Sn5 Sn6 Sn7 142.51(5) . 5 ? 
Cr4 Sn6 Sn7 59.39(4) 9 5 ? 
Cr4 Sn6 Sn7 123.63(4) . 5 ? 
Sn5 Sn6 Zn9 143.08(5) 9 . ? 
Sn5 Sn6 Zn9 107.54(4) . . ? 
Cr4 Sn6 Zn9 121.35(5) 9 . ? 
Cr4 Sn6 Zn9 61.74(4) . . ? 
Sn7 Sn6 Zn9 61.97(3) 5 . ? 
Sn5 Sn6 Sn6 59.25(3) 9 9 ? 
Sn5 Sn6 Sn6 89.26(2) . 9 ? 
Cr4 Sn6 Sn6 59.66(5) 9 9 ? 
Cr4 Sn6 Sn6 119.26(4) . 9 ? 
Sn7 Sn6 Sn6 113.43(4) 5 9 ? 
Zn9 Sn6 Sn6 156.91(2) . 9 ? 
Sn5 Sn6 Sn6 89.28(3) 9 5 ? 
Sn5 Sn6 Sn6 59.20(3) . 5 ? 
Cr4 Sn6 Sn6 119.60(5) 9 5 ? 
Cr4 Sn6 Sn6 59.31(4) . 5 ? 
Sn7 Sn6 Sn6 158.05(3) 5 5 ? 
Zn9 Sn6 Sn6 114.85(5) . 5 ? 
Sn6 Sn6 Sn6 60.0 9 5 ? 
Sn5 Sn6 Sn4 57.95(4) 9 5 ? 
Sn5 Sn6 Sn4 86.89(4) . 5 ? 
Cr4 Sn6 Sn4 60.19(3) 9 5 ? 
Cr4 Sn6 Sn4 117.37(4) . 5 ? 
Sn7 Sn6 Sn4 58.35(4) 5 5 ? 
Zn9 Sn6 Sn4 88.55(4) . 5 ? 
Sn6 Sn6 Sn4 108.54(4) 9 5 ? 
Sn6 Sn6 Sn4 142.65(4) 5 5 ? 
Sn5 Sn6 Sn6 88.74(3) 9 100 ? 
Sn5 Sn6 Sn6 58.04(2) . 100 ? 
Cr4 Sn6 Sn6 119.27(3) 9 100 ? 
Cr4 Sn6 Sn6 58.36(3) . 100 ? 
Sn7 Sn6 Sn6 89.58(3) 5 100 ? 
Zn9 Sn6 Sn6 58.44(2) . 100 ? 
Sn6 Sn6 Sn6 143.841(6) 9 100 ? 
Sn6 Sn6 Sn6 107.35(2) 5 100 ? 
Sn4 Sn6 Sn6 59.098(19) 5 100 ? 
Sn5 Sn6 Sn11 152.10(4) 9 . ? 
Sn5 Sn6 Sn11 105.82(4) . . ? 
Cr4 Sn6 Sn11 129.98(4) 9 . ? 
Cr4 Sn6 Sn11 54.42(3) . . ? 
Sn7 Sn6 Sn11 99.62(4) 5 . ? 
Zn9 Sn6 Sn11 61.34(3) . . ? 
Sn6 Sn6 Sn11 99.41(2) 9 . ? 
Sn6 Sn6 Sn11 63.34(3) 5 . ? 
Sn4 Sn6 Sn11 149.49(4) 5 . ? 
Sn6 Sn6 Sn11 103.88(2) 100 . ? 
Sn5 Sn6 Sn11 104.97(4) 9 9 ? 
Sn5 Sn6 Sn11 150.89(4) . 9 ? 
Cr4 Sn6 Sn11 54.11(3) 9 9 ? 
Cr4 Sn6 Sn11 130.24(4) . 9 ? 
Sn7 Sn6 Sn11 62.16(3) 5 9 ? 
Zn9 Sn6 Sn11 98.75(3) . 9 ? 
Sn6 Sn6 Sn11 62.15(3) 9 9 ? 
Sn6 Sn6 Sn11 98.63(2) 5 9 ? 
Sn4 Sn6 Sn11 106.39(4) 5 9 ? 
Sn6 Sn6 Sn11 150.796(19) 100 9 ? 
Sn11 Sn6 Sn11 75.88(3) . 9 ? 
Sn4 Sn7 Sn4 84.17(6) . 137_655 ? 
Sn4 Sn7 Cr4 61.66(4) . 5 ? 
Sn4 Sn7 Cr4 116.79(4) 137_655 5 ? 
Sn4 Sn7 Cr4 116.79(4) . 142_655 ? 
Sn4 Sn7 Cr4 61.66(4) 137_655 142_655 ? 
Cr4 Sn7 Cr4 178.14(7) 5 142_655 ? 
Sn4 Sn7 Sn6 143.47(5) . 40_544 ? 
Sn4 Sn7 Sn6 61.90(3) 137_655 40_544 ? 
Cr4 Sn7 Sn6 120.36(4) 5 40_544 ? 
Cr4 Sn7 Sn6 60.12(3) 142_655 40_544 ? 
Sn4 Sn7 Sn6 61.90(3) . 9 ? 
Sn4 Sn7 Sn6 143.47(5) 137_655 9 ? 
Cr4 Sn7 Sn6 60.12(3) 5 9 ? 
Cr4 Sn7 Sn6 120.36(4) 142_655 9 ? 
Sn6 Sn7 Sn6 154.10(6) 40_544 9 ? 
Sn4 Sn7 Zn9 110.63(2) . 133_655 ? 
Sn4 Sn7 Zn9 88.91(3) 137_655 133_655 ? 
Cr4 Sn7 Zn9 61.26(4) 5 133_655 ? 
Cr4 Sn7 Zn9 119.22(4) 142_655 133_655 ? 
Sn6 Sn7 Zn9 59.11(3) 40_544 133_655 ? 
Sn6 Sn7 Zn9 114.38(4) 9 133_655 ? 
Sn4 Sn7 Zn9 88.91(3) . 9 ? 
Sn4 Sn7 Zn9 110.63(2) 137_655 9 ? 
Cr4 Sn7 Zn9 119.22(4) 5 9 ? 
Cr4 Sn7 Zn9 61.26(4) 142_655 9 ? 
Sn6 Sn7 Zn9 114.38(4) 40_544 9 ? 
Sn6 Sn7 Zn9 59.11(3) 9 9 ? 
Zn9 Sn7 Zn9 154.04(5) 133_655 9 ? 
Sn4 Sn7 Sn7 58.346(18) . 98 ? 
Sn4 Sn7 Sn7 58.347(18) 137_655 98 ? 
Cr4 Sn7 Sn7 120.00(4) 5 98 ? 
Cr4 Sn7 Sn7 58.47(3) 142_655 98 ? 
Sn6 Sn7 Sn7 108.03(2) 40_544 98 ? 
Sn6 Sn7 Sn7 90.42(3) 9 98 ? 
Zn9 Sn7 Sn7 145.03(3) 133_655 98 ? 
Zn9 Sn7 Sn7 59.88(3) 9 98 ? 
Sn4 Sn7 Sn7 58.346(18) . 99 ? 
Sn4 Sn7 Sn7 58.347(18) 137_655 99 ? 
Cr4 Sn7 Sn7 58.47(3) 5 99 ? 
Cr4 Sn7 Sn7 120.00(4) 142_655 99 ? 
Sn6 Sn7 Sn7 90.42(3) 40_544 99 ? 
Sn6 Sn7 Sn7 108.03(2) 9 99 ? 
Zn9 Sn7 Sn7 59.88(3) 133_655 99 ? 
Zn9 Sn7 Sn7 145.03(3) 9 99 ? 
Sn7 Sn7 Sn7 90.0 98 99 ? 
Sn4 Sn7 Sn11 148.177(18) . 47_544 ? 
Sn4 Sn7 Sn11 110.40(3) 137_655 47_544 ? 
Cr4 Sn7 Sn11 126.98(5) 5 47_544 ? 
Cr4 Sn7 Sn11 54.87(3) 142_655 47_544 ? 
Sn6 Sn7 Sn11 63.98(3) 40_544 47_544 ? 
Sn6 Sn7 Sn11 94.42(3) 9 47_544 ? 
Zn9 Sn7 Sn11 98.15(3) 133_655 47_544 ? 
Zn9 Sn7 Sn11 59.71(3) 9 47_544 ? 
Sn7 Sn7 Sn11 104.351(16) 98 47_544 ? 
Sn7 Sn7 Sn11 153.348(11) 99 47_544 ? 
Sn4 Sn7 Sn11 110.40(3) . 5 ? 
Sn4 Sn7 Sn11 148.176(18) 137_655 5 ? 
Cr4 Sn7 Sn11 54.87(3) 5 5 ? 
Cr4 Sn7 Sn11 126.98(5) 142_655 5 ? 
Sn6 Sn7 Sn11 94.42(3) 40_544 5 ? 
Sn6 Sn7 Sn11 63.98(3) 9 5 ? 
Zn9 Sn7 Sn11 59.71(3) 133_655 5 ? 
Zn9 Sn7 Sn11 98.15(3) 9 5 ? 
Sn7 Sn7 Sn11 153.348(11) 98 5 ? 
Sn7 Sn7 Sn11 104.351(16) 99 5 ? 
Sn11 Sn7 Sn11 72.35(3) 47_544 5 ? 
Sn6 Zn9 Sn6 63.13(5) 100 . ? 
Sn6 Zn9 Cr4 59.03(4) 100 . ? 
Sn6 Zn9 Cr4 59.03(4) . . ? 
Sn6 Zn9 Cr4 116.29(5) 100 161_565 ? 
Sn6 Zn9 Cr4 116.29(5) . 161_565 ? 
Cr4 Zn9 Cr4 174.16(7) . 161_565 ? 
Sn6 Zn9 Sn7 58.92(3) 100 102 ? 
Sn6 Zn9 Sn7 90.52(5) . 102 ? 
Cr4 Zn9 Sn7 117.88(5) . 102 ? 
Cr4 Zn9 Sn7 57.37(4) 161_565 102 ? 
Sn6 Zn9 Sn7 90.52(5) 100 5 ? 
Sn6 Zn9 Sn7 58.92(3) . 5 ? 
Cr4 Zn9 Sn7 117.88(5) . 5 ? 
Cr4 Zn9 Sn7 57.37(4) 161_565 5 ? 
Sn7 Zn9 Sn7 60.23(5) 102 5 ? 
Sn6 Zn9 Sn11 153.20(5) 100 68_454 ? 
Sn6 Zn9 Sn11 96.51(2) . 68_454 ? 
Cr4 Zn9 Sn11 127.27(3) . 68_454 ? 
Cr4 Zn9 Sn11 54.98(3) 161_565 68_454 ? 
Sn7 Zn9 Sn11 107.18(4) 102 68_454 ? 
Sn7 Zn9 Sn11 63.16(3) 5 68_454 ? 
Sn6 Zn9 Sn11 96.51(2) 100 161_565 ? 
Sn6 Zn9 Sn11 153.20(5) . 161_565 ? 
Cr4 Zn9 Sn11 127.27(3) . 161_565 ? 
Cr4 Zn9 Sn11 54.98(3) 161_565 161_565 ? 
Sn7 Zn9 Sn11 63.16(3) 102 161_565 ? 
Sn7 Zn9 Sn11 107.18(4) 5 161_565 ? 
Sn11 Zn9 Sn11 96.18(4) 68_454 161_565 ? 
Sn6 Zn9 Sn11 109.07(5) 100 . ? 
Sn6 Zn9 Sn11 63.86(3) . . ? 
Cr4 Zn9 Sn11 54.55(3) . . ? 
Cr4 Zn9 Sn11 127.81(3) 161_565 . ? 
Sn7 Zn9 Sn11 153.86(5) 102 . ? 
Sn7 Zn9 Sn11 99.34(3) 5 . ? 
Sn11 Zn9 Sn11 72.87(2) 68_454 . ? 
Sn11 Zn9 Sn11 142.79(5) 161_565 . ? 
Sn6 Zn9 Sn11 63.86(3) 100 100 ? 
Sn6 Zn9 Sn11 109.07(5) . 100 ? 
Cr4 Zn9 Sn11 54.55(3) . 100 ? 
Cr4 Zn9 Sn11 127.81(3) 161_565 100 ? 
Sn7 Zn9 Sn11 99.34(3) 102 100 ? 
Sn7 Zn9 Sn11 153.86(5) 5 100 ? 
Sn11 Zn9 Sn11 142.79(5) 68_454 100 ? 
Sn11 Zn9 Sn11 72.87(2) 161_565 100 ? 
Sn11 Zn9 Sn11 94.26(4) . 100 ? 
Zn10 Zn10 Zn10 89.992(2) 89_445 68_454 ? 
Zn10 Zn10 Zn10 44.996(3) 89_445 28 ? 
Zn10 Zn10 Zn10 44.996(2) 68_454 28 ? 
Zn10 Zn10 Cr3 123.7(15) 89_445 28 ? 
Zn10 Zn10 Cr3 129.9(14) 68_454 28 ? 
Zn10 Zn10 Cr3 147.8(4) 28 28 ? 
Zn10 Zn10 Cr3 33.4(11) 89_445 63_454 ? 
Zn10 Zn10 Cr3 113.5(12) 68_454 63_454 ? 
Zn10 Zn10 Cr3 72.1(13) 28 63_454 ? 
Cr3 Zn10 Cr3 90.4(4) 28 63_454 ? 
Zn10 Zn10 Cr3 118.1(9) 89_445 85_445 ? 
Zn10 Zn10 Cr3 37.7(9) 68_454 85_445 ? 
Zn10 Zn10 Cr3 76.9(10) 28 85_445 ? 
Cr3 Zn10 Cr3 92.3(6) 28 85_445 ? 
Cr3 Zn10 Cr3 124.1(3) 63_454 85_445 ? 
Zn10 Zn10 Sn11 102.7(13) 89_445 28 ? 
Zn10 Zn10 Sn11 135.0(6) 68_454 28 ? 
Zn10 Zn10 Sn11 130.9(9) 28 28 ? 
Cr3 Zn10 Sn11 77.3(3) 28 28 ? 
Cr3 Zn10 Sn11 99.1(4) 63_454 28 ? 
Cr3 Zn10 Sn11 135.8(7) 85_445 28 ? 
Zn10 Zn10 Cr1 79.56(17) 89_445 . ? 
Zn10 Zn10 Cr1 79.56(17) 68_454 . ? 
Zn10 Zn10 Cr1 75.2(3) 28 . ? 
Cr3 Zn10 Cr1 72.8(2) 28 . ? 
Cr3 Zn10 Cr1 63.5(3) 63_454 . ? 
Cr3 Zn10 Cr1 64.27(19) 85_445 . ? 
Sn11 Zn10 Cr1 144.9(3) 28 . ? 
Zn10 Zn10 Zn10 87.0(14) 89_445 79 ? 
Zn10 Zn10 Zn10 135.51(17) 68_454 79 ? 
Zn10 Zn10 Zn10 117.9(10) 28 79 ? 
Cr3 Zn10 Zn10 37.01(12) 28 79 ? 
Cr3 Zn10 Zn10 53.6(4) 63_454 79 ? 
Cr3 Zn10 Zn10 108.5(5) 85_445 79 ? 
Sn11 Zn10 Zn10 88.7(3) 28 79 ? 
Cr1 Zn10 Zn10 56.24(19) . 79 ? 
Zn10 Zn10 Zn10 134.2(5) 89_445 58 ? 
Zn10 Zn10 Zn10 92.9(14) 68_454 58 ? 
Zn10 Zn10 Zn10 121.9(9) 28 58 ? 
Cr3 Zn10 Zn10 37.01(11) 28 58 ? 
Cr3 Zn10 Zn10 106.8(4) 63_454 58 ? 
Cr3 Zn10 Zn10 55.5(6) 85_445 58 ? 
Sn11 Zn10 Zn10 106.9(2) 28 58 ? 
Cr1 Zn10 Zn10 56.24(19) . 58 ? 
Zn10 Zn10 Zn10 60.0 79 58 ? 
Zn10 Zn10 Zn10 69.3(15) 89_445 14 ? 
Zn10 Zn10 Zn10 130.8(8) 68_454 14 ? 
Zn10 Zn10 Zn10 102.2(15) 28 14 ? 
Cr3 Zn10 Zn10 54.7(3) 28 14 ? 
Cr3 Zn10 Zn10 35.9(4) 63_454 14 ? 
Cr3 Zn10 Zn10 115.0(2) 85_445 14 ? 
Sn11 Zn10 Zn10 93.84(18) 28 14 ? 
Cr1 Zn10 Zn10 53.6(2) . 14 ? 
Zn10 Zn10 Zn10 17.7(3) 79 14 ? 
Zn10 Zn10 Zn10 74.6(2) 58 14 ? 
Zn10 Zn10 Cr3 49.9(9) 89_445 . ? 
Zn10 Zn10 Cr3 45.9(9) 68_454 . ? 
Zn10 Zn10 Cr3 18.61(15) 28 . ? 
Cr3 Zn10 Cr3 129.5(3) 28 . ? 
Cr3 Zn10 Cr3 67.6(3) 63_454 . ? 
Cr3 Zn10 Cr3 68.28(16) 85_445 . ? 
Sn11 Zn10 Cr3 147.9(6) 28 . ? 
Cr1 Zn10 Cr3 56.69(16) . . ? 
Zn10 Zn10 Cr3 104.0(2) 79 . ? 
Zn10 Zn10 Cr3 105.0(3) 58 . ? 
Zn10 Zn10 Cr3 90.8(6) 14 . ? 
Zn10 Sn11 Cr4 166.05(19) 28 . ? 
Zn10 Sn11 Cr3 38.5(2) 28 . ? 
Cr4 Sn11 Cr3 150.42(6) . . ? 
Zn10 Sn11 Zn9 114.9(3) 28 89_445 ? 
Cr4 Sn11 Zn9 60.93(4) . 89_445 ? 
Cr3 Sn11 Zn9 146.67(5) . 89_445 ? 
Zn10 Sn11 Zn10 18.0(5) 28 68_454 ? 
Cr4 Sn11 Zn10 159.55(17) . 68_454 ? 
Cr3 Sn11 Zn10 50.02(17) . 68_454 ? 
Zn9 Sn11 Zn10 99.29(13) 89_445 68_454 ? 
Zn10 Sn11 Zn9 106.6(3) 28 . ? 
Cr4 Sn11 Zn9 60.15(4) . . ? 
Cr3 Sn11 Zn9 121.05(3) . . ? 
Zn9 Sn11 Zn9 80.40(4) 89_445 . ? 
Zn10 Sn11 Zn9 114.4(3) 68_454 . ? 
Zn10 Sn11 Sn7 133.8(3) 28 9 ? 
Cr4 Sn11 Sn7 56.97(4) . 9 ? 
Cr3 Sn11 Sn7 120.88(2) . 9 ? 
Zn9 Sn11 Sn7 57.13(3) 89_445 9 ? 
Zn10 Sn11 Sn7 118.5(2) 68_454 9 ? 
Zn9 Sn11 Sn7 115.19(3) . 9 ? 
Zn10 Sn11 Sn6 120.2(4) 28 . ? 
Cr4 Sn11 Sn6 57.45(4) . . ? 
Cr3 Sn11 Sn6 97.57(5) . . ? 
Zn9 Sn11 Sn6 115.73(3) 89_445 . ? 
Zn10 Sn11 Sn6 138.17(14) 68_454 . ? 
Zn9 Sn11 Sn6 54.80(3) . . ? 
Sn7 Sn11 Sn6 100.12(3) 9 . ? 
Zn10 Sn11 Sn6 135.0(2) 28 5 ? 
Cr4 Sn11 Sn6 56.79(3) . 5 ? 
Cr3 Sn11 Sn6 96.81(4) . 5 ? 
Zn9 Sn11 Sn6 103.56(3) 89_445 5 ? 
Zn10 Sn11 Sn6 139.8(3) 68_454 5 ? 
Zn9 Sn11 Sn6 101.80(3) . 5 ? 
Sn7 Sn11 Sn6 53.867(19) 9 5 ? 
Sn6 Sn11 Sn6 54.51(3) . 5 ? 
Zn10 Sn11 Zn10 11.46(15) 28 89_445 ? 
Cr4 Sn11 Zn10 154.59(15) . 89_445 ? 
Cr3 Sn11 Zn10 47.12(17) . 89_445 ? 
Zn9 Sn11 Zn10 110.80(16) 89_445 89_445 ? 
Zn10 Sn11 Zn10 23.3(3) 68_454 89_445 ? 
Zn9 Sn11 Zn10 95.56(14) . 89_445 ? 
Sn7 Sn11 Zn10 141.85(12) 9 89_445 ? 
Sn6 Sn11 Zn10 116.47(13) . 89_445 ? 
Sn6 Sn11 Zn10 143.58(17) 5 89_445 ? 
  
_diffrn_measured_fraction_theta_max    0.996 
_diffrn_reflns_theta_full              28.33 
_diffrn_measured_fraction_theta_full   0.996 
_refine_diff_density_max    2.939 
_refine_diff_density_min   -2.465 
_refine_diff_density_rms    0.274 
