# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_d_RZSO_CIF_ZBQ
_database_code_depnum_ccdc_archive 'CCDC 1516213'
_audit_update_record             
;
2017-05-16 deposited with the CCDC.
2017-09-23 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        Rb2ZnSi3O8
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'O8 Rb2 Si3 Zn'
_chemical_formula_weight         448.58

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'

_cell_length_a                   12.778(2)
_cell_length_b                   5.3414(3)
_cell_length_c                   8.7036(15)
_cell_angle_alpha                90.00
_cell_angle_beta                 134.15(3)
_cell_angle_gamma                90.00
_cell_volume                     426.26(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    3042
_cell_measurement_theta_min      4.3880
_cell_measurement_theta_max      29.4570

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.495
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             420
_exptl_absorpt_coefficient_mu    14.663
_exptl_absorpt_correction_type   Empirical
_exptl_absorpt_correction_T_min  0.2954
_exptl_absorpt_correction_T_max  0.3867
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'SuperNova (Mo) X-ray Source'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            5125
_diffrn_reflns_av_R_equivalents  0.0317
_diffrn_reflns_av_sigmaI/netI    0.0197
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         4.42
_diffrn_reflns_theta_max         27.86
_reflns_number_total             999
_reflns_number_gt                963
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0653P)²+2.8719P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   none
_refine_ls_hydrogen_treatment    none
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.48(2)
_refine_ls_number_reflns         999
_refine_ls_number_parameters     83
_refine_ls_number_restraints     8
_refine_ls_R_factor_all          0.0430
_refine_ls_R_factor_gt           0.0415
_refine_ls_wR_factor_ref         0.1102
_refine_ls_wR_factor_gt          0.1082
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_restrained_S_all      1.122
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rb1 Rb 0.94866(7) 0.5327 0.70962(11) 0.0387(2) Uani 1 1 d . . .
Zn2 Zn 0.83652(13) 1.0456(4) 0.89779(17) 0.0351(3) Uani 0.50 1 d P . .
Si2 Si 0.83652(13) 1.0456(4) 0.89779(17) 0.0351(3) Uani 0.50 1 d PD . .
Si1 Si 0.6597(2) 0.5448(6) 0.7168(3) 0.0311(4) Uani 1 1 d . . .
O4 O 0.5009(12) 0.624(2) 0.4490(17) 0.031(2) Uani 0.50 1 d P . .
O2 O 0.7687(7) 0.7544(14) 0.7590(10) 0.0440(15) Uani 1 1 d . . .
O3 O 0.6986(9) 0.2729(15) 0.6902(11) 0.0507(19) Uani 1 1 d . . .
O1 O 0.7143(9) 0.536(3) 0.9613(14) 0.0315(19) Uani 0.50 1 d P . .
O5 O 0.6090(11) 0.548(3) 0.8350(16) 0.034(2) Uani 0.50 1 d P . .
O6 O 0.9929(8) 1.135(2) 1.023(2) 0.060(5) Uani 0.50 1 d PDU . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rb1 O6 2.841(13) 2_747 ?
Rb1 O3 2.859(7) 4_656 ?
Rb1 O4 2.884(10) 4_646 ?
Rb1 O5 2.995(15) 3_545 ?
Rb1 O1 3.093(9) 2_757 ?
Rb1 O5 3.140(17) 3 ?
Rb1 O6 3.178(13) 1_545 ?
Rb1 O2 3.283(7) 4_646 ?
Rb1 O4 3.529(11) 3_545 ?
Rb1 O2 3.545(7) 2_757 ?
Rb1 O3 3.554(10) 3 ?
Rb1 Si2 3.594(2) 2_747 ?
Zn2 O6 1.542(5) . ?
Zn2 O1 1.743(8) 4_657 ?
Zn2 O2 1.781(8) . ?
Zn2 O6 1.832(10) 2_757 ?
Zn2 O3 1.846(7) 1_565 ?
Zn2 O5 1.908(10) 4_657 ?
Zn2 Rb1 3.593(2) 2_767 ?
Zn2 Rb1 3.695(2) 2_757 ?
Zn2 Rb1 3.794(2) 4_656 ?
Zn2 Rb1 3.8435(17) 1_565 ?
Zn2 Rb1 3.9929(19) 3_455 ?
Si1 O4 1.533(11) 2_656 ?
Si1 O5 1.551(10) . ?
Si1 O3 1.603(8) . ?
Si1 O2 1.617(7) . ?
Si1 O1 1.717(8) . ?
Si1 O4 1.773(11) . ?
Si1 Rb1 3.719(3) 3_455 ?
Si1 Rb1 3.811(3) 3_445 ?
Si1 Rb1 3.895(3) 2_757 ?
Si1 Rb1 3.915(3) 4_656 ?
Si1 Rb1 4.002(3) 4_646 ?
O4 O4 0.90(2) 2_656 ?
O4 Si1 1.532(11) 2_656 ?
O4 Rb1 2.884(10) 4_656 ?
O4 Rb1 3.529(11) 3_455 ?
O2 Rb1 3.283(7) 4_656 ?
O2 Rb1 3.545(7) 2_757 ?
O3 Zn2 1.846(7) 1_545 ?
O3 Si2 1.846(7) 1_545 ?
O3 Rb1 2.859(7) 4_646 ?
O3 Rb1 3.554(10) 3_445 ?
O1 Zn2 1.743(8) 4_647 ?
O1 Si2 1.743(8) 4_647 ?
O1 Rb1 3.093(9) 2_757 ?
O1 Rb1 3.604(13) 3_455 ?
O1 Rb1 3.633(13) 3_445 ?
O5 Zn2 1.908(10) 4_647 ?
O5 Si2 1.908(10) 4_647 ?
O5 Rb1 2.995(15) 3_455 ?
O5 Rb1 3.140(17) 3_445 ?
O6 O6 0.54(3) 2_757 ?
O6 Si2 1.832(10) 2_757 ?
O6 Zn2 1.832(10) 2_757 ?
O6 Rb1 2.841(13) 2_767 ?
O6 Rb1 3.178(13) 1_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Rb1 O3 155.2(3) 2_747 4_656 ?
O6 Rb1 O4 79.0(3) 2_747 4_646 ?
O3 Rb1 O4 86.2(3) 4_656 4_646 ?
O6 Rb1 O5 48.2(3) 2_747 3_545 ?
O3 Rb1 O5 122.3(3) 4_656 3_545 ?
O4 Rb1 O5 36.6(3) 4_646 3_545 ?
O6 Rb1 O1 81.0(3) 2_747 2_757 ?
O3 Rb1 O1 115.8(3) 4_656 2_757 ?
O4 Rb1 O1 79.4(3) 4_646 2_757 ?
O5 Rb1 O1 60.7(4) 3_545 2_757 ?
O6 Rb1 O5 129.4(3) 2_747 3 ?
O3 Rb1 O5 75.3(2) 4_656 3 ?
O4 Rb1 O5 121.3(3) 4_646 3 ?
O5 Rb1 O5 121.0(3) 3_545 3 ?
O1 Rb1 O5 61.4(4) 2_757 3 ?
O6 Rb1 O6 7.9(3) 2_747 1_545 ?
O3 Rb1 O6 156.4(2) 4_656 1_545 ?
O4 Rb1 O6 86.5(3) 4_646 1_545 ?
O5 Rb1 O6 56.1(3) 3_545 1_545 ?
O1 Rb1 O6 84.8(3) 2_757 1_545 ?
O5 Rb1 O6 127.2(3) 3 1_545 ?
O6 Rb1 O2 101.1(3) 2_747 4_646 ?
O3 Rb1 O2 54.61(17) 4_656 4_646 ?
O4 Rb1 O2 48.7(2) 4_646 4_646 ?
O5 Rb1 O2 80.4(2) 3_545 4_646 ?
O1 Rb1 O2 125.5(2) 2_757 4_646 ?
O5 Rb1 O2 127.7(2) 3 4_646 ?
O6 Rb1 O2 104.7(2) 1_545 4_646 ?
O6 Rb1 O4 90.4(3) 2_747 3_545 ?
O3 Rb1 O4 75.7(3) 4_656 3_545 ?
O4 Rb1 O4 11.4(3) 4_646 3_545 ?
O5 Rb1 O4 46.6(2) 3_545 3_545 ?
O1 Rb1 O4 80.5(3) 2_757 3_545 ?
O5 Rb1 O4 113.3(3) 3 3_545 ?
O6 Rb1 O4 97.9(3) 1_545 3_545 ?
O2 Rb1 O4 45.3(2) 4_646 3_545 ?
O6 Rb1 O2 74.5(3) 2_747 2_757 ?
O3 Rb1 O2 130.3(2) 4_656 2_757 ?
O4 Rb1 O2 120.8(2) 4_646 2_757 ?
O5 Rb1 O2 89.8(3) 3_545 2_757 ?
O1 Rb1 O2 45.0(2) 2_757 2_757 ?
O5 Rb1 O2 55.1(2) 3 2_757 ?
O6 Rb1 O2 72.2(2) 1_545 2_757 ?
O2 Rb1 O2 169.6(2) 4_646 2_757 ?
O4 Rb1 O2 124.6(2) 3_545 2_757 ?
O6 Rb1 O3 125.26(18) 2_747 3 ?
O3 Rb1 O3 68.4(2) 4_656 3 ?
O4 Rb1 O3 75.1(3) 4_646 3 ?
O5 Rb1 O3 85.4(3) 3_545 3 ?
O1 Rb1 O3 47.5(2) 2_757 3 ?
O5 Rb1 O3 46.3(2) 3 3 ?
O6 Rb1 O3 130.75(18) 1_545 3 ?
O2 Rb1 O3 96.59(19) 4_646 3 ?
O4 Rb1 O3 67.3(2) 3_545 3 ?
O2 Rb1 O3 78.96(15) 2_757 3 ?
O6 Rb1 Si2 24.32(13) 2_747 2_747 ?
O3 Rb1 Si2 154.36(19) 4_656 2_747 ?
O4 Rb1 Si2 68.3(2) 4_646 2_747 ?
O5 Rb1 Si2 32.05(19) 3_545 2_747 ?
O1 Rb1 Si2 58.4(3) 2_757 2_747 ?
O5 Rb1 Si2 115.0(2) 3 2_747 ?
O6 Rb1 Si2 30.62(17) 1_545 2_747 ?
O2 Rb1 Si2 106.17(13) 4_646 2_747 ?
O4 Rb1 Si2 78.62(17) 3_545 2_747 ?
O2 Rb1 Si2 65.92(13) 2_757 2_747 ?
O3 Rb1 Si2 100.95(12) 3 2_747 ?
O6 Zn2 O1 116.6(6) . 4_657 ?
O6 Zn2 O2 122.0(5) . . ?
O1 Zn2 O2 102.0(5) 4_657 . ?
O6 Zn2 O6 15.4(9) . 2_757 ?
O1 Zn2 O6 132.0(5) 4_657 2_757 ?
O2 Zn2 O6 112.0(5) . 2_757 ?
O6 Zn2 O3 111.7(6) . 1_565 ?
O1 Zn2 O3 97.9(5) 4_657 1_565 ?
O2 Zn2 O3 103.2(4) . 1_565 ?
O6 Zn2 O3 105.7(5) 2_757 1_565 ?
O6 Zn2 O5 86.9(6) . 4_657 ?
O1 Zn2 O5 30.7(4) 4_657 4_657 ?
O2 Zn2 O5 115.2(5) . 4_657 ?
O6 Zn2 O5 102.1(5) 2_757 4_657 ?
O3 Zn2 O5 118.5(5) 1_565 4_657 ?
O6 Zn2 Rb1 49.3(5) . 2_767 ?
O1 Zn2 Rb1 76.3(4) 4_657 2_767 ?
O2 Zn2 Rb1 165.0(2) . 2_767 ?
O6 Zn2 Rb1 62.1(4) 2_757 2_767 ?
O3 Zn2 Rb1 91.8(3) 1_565 2_767 ?
O5 Zn2 Rb1 56.4(5) 4_657 2_767 ?
O6 Zn2 Rb1 79.4(5) . 2_757 ?
O1 Zn2 Rb1 74.3(4) 4_657 2_757 ?
O2 Zn2 Rb1 71.1(2) . 2_757 ?
O6 Zn2 Rb1 85.5(3) 2_757 2_757 ?
O3 Zn2 Rb1 168.7(3) 1_565 2_757 ?
O5 Zn2 Rb1 58.2(5) 4_657 2_757 ?
Rb1 Zn2 Rb1 94.25(5) 2_767 2_757 ?
O6 Zn2 Rb1 120.2(5) . 4_656 ?
O1 Zn2 Rb1 120.9(3) 4_657 4_656 ?
O2 Zn2 Rb1 59.9(2) . 4_656 ?
O6 Zn2 Rb1 105.5(4) 2_757 4_656 ?
O3 Zn2 Rb1 46.6(2) 1_565 4_656 ?
O5 Zn2 Rb1 151.6(3) 4_657 4_656 ?
Rb1 Zn2 Rb1 133.97(6) 2_767 4_656 ?
Rb1 Zn2 Rb1 130.46(6) 2_757 4_656 ?
O6 Zn2 Rb1 53.5(5) . 1_565 ?
O1 Zn2 Rb1 138.7(5) 4_657 1_565 ?
O2 Zn2 Rb1 116.9(2) . 1_565 ?
O6 Zn2 Rb1 44.4(4) 2_757 1_565 ?
O3 Zn2 Rb1 61.5(3) 1_565 1_565 ?
O5 Zn2 Rb1 125.9(4) 4_657 1_565 ?
Rb1 Zn2 Rb1 69.55(4) 2_767 1_565 ?
Rb1 Zn2 Rb1 129.69(4) 2_757 1_565 ?
Rb1 Zn2 Rb1 72.54(3) 4_656 1_565 ?
O6 Zn2 Rb1 157.4(5) . 3_455 ?
O1 Zn2 Rb1 47.5(3) 4_657 3_455 ?
O2 Zn2 Rb1 80.1(2) . 3_455 ?
O6 Zn2 Rb1 165.8(3) 2_757 3_455 ?
O3 Zn2 Rb1 62.9(3) 1_565 3_455 ?
O5 Zn2 Rb1 78.1(3) 4_657 3_455 ?
Rb1 Zn2 Rb1 108.08(5) 2_767 3_455 ?
Rb1 Zn2 Rb1 106.07(5) 2_757 3_455 ?
Rb1 Zn2 Rb1 73.44(5) 4_656 3_455 ?
Rb1 Zn2 Rb1 124.16(5) 1_565 3_455 ?
O4 Si1 O5 73.6(5) 2_656 . ?
O4 Si1 O3 117.5(5) 2_656 . ?
O5 Si1 O3 114.9(8) . . ?
O4 Si1 O2 113.5(5) 2_656 . ?
O5 Si1 O2 122.1(7) . . ?
O3 Si1 O2 110.8(5) . . ?
O4 Si1 O1 107.2(5) 2_656 . ?
O5 Si1 O1 34.4(5) . . ?
O3 Si1 O1 104.8(6) . . ?
O2 Si1 O1 101.2(5) . . ?
O4 Si1 O4 30.6(7) 2_656 . ?
O5 Si1 O4 104.2(5) . . ?
O3 Si1 O4 102.3(4) . . ?
O2 Si1 O4 98.6(4) . . ?
O1 Si1 O4 137.8(5) . . ?
O4 Si1 Rb1 46.4(4) 2_656 3_455 ?
O5 Si1 Rb1 50.9(6) . 3_455 ?
O3 Si1 Rb1 157.9(4) . 3_455 ?
O2 Si1 Rb1 91.0(3) . 3_455 ?
O1 Si1 Rb1 72.7(5) . 3_455 ?
O4 Si1 Rb1 69.9(4) . 3_455 ?
O4 Si1 Rb1 73.5(4) 2_656 3_445 ?
O5 Si1 Rb1 53.3(6) . 3_445 ?
O3 Si1 Rb1 68.6(4) . 3_445 ?
O2 Si1 Rb1 171.2(3) . 3_445 ?
O1 Si1 Rb1 70.9(4) . 3_445 ?
O4 Si1 Rb1 90.1(4) . 3_445 ?
Rb1 Si1 Rb1 90.35(4) 3_455 3_445 ?
O4 Si1 Rb1 153.3(4) 2_656 2_757 ?
O5 Si1 Rb1 84.7(4) . 2_757 ?
O3 Si1 Rb1 85.4(3) . 2_757 ?
O2 Si1 Rb1 65.5(2) . 2_757 ?
O1 Si1 Rb1 50.3(3) . 2_757 ?
O4 Si1 Rb1 164.1(4) . 2_757 ?
Rb1 Si1 Rb1 107.60(6) 3_455 2_757 ?
Rb1 Si1 Rb1 105.77(6) 3_445 2_757 ?
O4 Si1 Rb1 64.2(4) 2_656 4_656 ?
O5 Si1 Rb1 125.8(6) . 4_656 ?
O3 Si1 Rb1 114.0(3) . 4_656 ?
O2 Si1 Rb1 55.6(3) . 4_656 ?
O1 Si1 Rb1 139.7(6) . 4_656 ?
O4 Si1 Rb1 43.0(3) . 4_656 ?
Rb1 Si1 Rb1 75.17(6) 3_455 4_656 ?
Rb1 Si1 Rb1 133.10(6) 3_445 4_656 ?
Rb1 Si1 Rb1 121.10(7) 2_757 4_656 ?
O4 Si1 Rb1 86.8(4) 2_656 4_646 ?
O5 Si1 Rb1 126.1(6) . 4_646 ?
O3 Si1 Rb1 35.8(2) . 4_646 ?
O2 Si1 Rb1 111.8(3) . 4_646 ?
O1 Si1 Rb1 135.3(6) . 4_646 ?
O4 Si1 Rb1 66.7(4) . 4_646 ?
Rb1 Si1 Rb1 133.22(6) 3_455 4_646 ?
Rb1 Si1 Rb1 73.16(5) 3_445 4_646 ?
Rb1 Si1 Rb1 118.89(7) 2_757 4_646 ?
Rb1 Si1 Rb1 84.86(4) 4_656 4_646 ?
O4 O4 Si1 89.5(14) 2_656 2_656 ?
O4 O4 Si1 59.8(12) 2_656 . ?
Si1 O4 Si1 136.7(7) 2_656 . ?
O4 O4 Rb1 129.6(4) 2_656 4_656 ?
Si1 O4 Rb1 111.0(5) 2_656 4_656 ?
Si1 O4 Rb1 112.2(5) . 4_656 ?
O4 O4 Rb1 39.0(3) 2_656 3_455 ?
Si1 O4 Rb1 92.8(5) 2_656 3_455 ?
Si1 O4 Rb1 81.9(4) . 3_455 ?
Rb1 O4 Rb1 92.6(3) 4_656 3_455 ?
Si1 O2 Zn2 134.0(5) . . ?
Si1 O2 Rb1 100.5(3) . 4_656 ?
Zn2 O2 Rb1 92.2(3) . 4_656 ?
Si1 O2 Rb1 89.9(3) . 2_757 ?
Zn2 O2 Rb1 80.5(2) . 2_757 ?
Rb1 O2 Rb1 169.6(2) 4_656 2_757 ?
Si1 O3 Zn2 129.4(4) . 1_545 ?
Si1 O3 Si2 129.4(4) . 1_545 ?
Zn2 O3 Si2 0.00(13) 1_545 1_545 ?
Si1 O3 Rb1 125.1(3) . 4_646 ?
Zn2 O3 Rb1 105.5(3) 1_545 4_646 ?
Si2 O3 Rb1 105.5(3) 1_545 4_646 ?
Si1 O3 Rb1 86.6(3) . 3_445 ?
Zn2 O3 Rb1 89.6(3) 1_545 3_445 ?
Si2 O3 Rb1 89.6(3) 1_545 3_445 ?
Rb1 O3 Rb1 92.5(2) 4_646 3_445 ?
Si1 O1 Zn2 147.4(6) . 4_647 ?
Si1 O1 Si2 147.4(6) . 4_647 ?
Zn2 O1 Si2 0.00(15) 4_647 4_647 ?
Si1 O1 Rb1 104.4(3) . 2_757 ?
Zn2 O1 Rb1 108.0(4) 4_647 2_757 ?
Si2 O1 Rb1 108.0(4) 4_647 2_757 ?
Si1 O1 Rb1 80.2(4) . 3_455 ?
Zn2 O1 Rb1 75.6(4) 4_647 3_455 ?
Si2 O1 Rb1 75.6(4) 4_647 3_455 ?
Rb1 O1 Rb1 133.0(5) 2_757 3_455 ?
Si1 O1 Rb1 82.5(5) . 3_445 ?
Zn2 O1 Rb1 78.2(4) 4_647 3_445 ?
Si2 O1 Rb1 78.2(4) 4_647 3_445 ?
Rb1 O1 Rb1 131.8(5) 2_757 3_445 ?
Rb1 O1 Rb1 95.1(2) 3_455 3_445 ?
Si1 O5 Zn2 147.4(7) . 4_647 ?
Si1 O5 Si2 147.4(7) . 4_647 ?
Zn2 O5 Si2 0.00(15) 4_647 4_647 ?
Si1 O5 Rb1 105.3(7) . 3_455 ?
Zn2 O5 Rb1 91.5(5) 4_647 3_455 ?
Si2 O5 Rb1 91.5(5) 4_647 3_455 ?
Si1 O5 Rb1 103.4(7) . 3_445 ?
Zn2 O5 Rb1 90.7(5) 4_647 3_445 ?
Si2 O5 Rb1 90.7(5) 4_647 3_445 ?
Rb1 O5 Rb1 121.0(3) 3_455 3_445 ?
O6 O6 Zn2 115(2) 2_757 . ?
O6 O6 Si2 49.9(14) 2_757 2_757 ?
Zn2 O6 Si2 143.3(8) . 2_757 ?
O6 O6 Zn2 49.9(14) 2_757 2_757 ?
Zn2 O6 Zn2 143.3(8) . 2_757 ?
Si2 O6 Zn2 0.00(15) 2_757 2_757 ?
O6 O6 Rb1 124.9(7) 2_757 2_767 ?
Zn2 O6 Rb1 106.3(6) . 2_767 ?
Si2 O6 Rb1 108.7(3) 2_757 2_767 ?
Zn2 O6 Rb1 108.7(3) 2_757 2_767 ?
O6 O6 Rb1 47.1(8) 2_757 1_565 ?
Zn2 O6 Rb1 103.5(6) . 1_565 ?
Si2 O6 Rb1 87.3(4) 2_757 1_565 ?
Zn2 O6 Rb1 87.3(4) 2_757 1_565 ?
Rb1 O6 Rb1 89.6(3) 2_767 1_565 ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        27.86
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         1.181
_refine_diff_density_min         -0.908
_refine_diff_density_rms         0.233
