# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1571678'
_audit_update_record             
;
2017-08-30 deposited with the CCDC.
2017-11-18 downloaded from the CCDC.
;

_audit_creation_date             2017-04-13T18:28:59-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic

#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#

_chemical_formula_moiety         'C26 H26 Co Dy N10 O7, H2 O'
_chemical_formula_sum            'C26 H28 Co Dy N10 O8'
_chemical_formula_weight         830.01
_chemical_absolute_configuration unk

#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'C m c 21'
_symmetry_space_group_name_Hall  'C 2c -2'
_symmetry_Int_Tables_number      36
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, z'
'x, -y, z+1/2'
'-x, -y, z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'

_cell_length_a                   14.8064(6)
_cell_length_b                   14.9660(4)
_cell_length_c                   14.0417(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3111.54(18)
_cell_formula_units_Z            4
_cell_measurement_temperature    90(2)
_cell_measurement_reflns_used    14956
_cell_measurement_theta_min      3.085
_cell_measurement_theta_max      27.471
_cell_measurement_wavelength     0.71075

#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_exptl_crystal_density_diffrn    1.772
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1644

#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#

_exptl_absorpt_coefficient_mu    2.98
_exptl_absorpt_correction_type   multi-scan
_shelx_estimated_absorpt_T_min   0.735
_shelx_estimated_absorpt_T_max   0.755
_exptl_absorpt_correction_T_min  0.923
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'

#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#

_diffrn_ambient_temperature      90(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_probe          x-ray
_diffrn_standards_number         0
_diffrn_standards_interval_time  .
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_reflns_av_R_equivalents  0.0126
_diffrn_reflns_av_unetI/netI     0.0387
_diffrn_reflns_number            14956
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         3.085
_diffrn_reflns_theta_max         27.471
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_reflns_Friedel_fraction_full    0.996
_reflns_Friedel_fraction_max     0.996
_reflns_Friedel_coverage         0.918
_reflns_number_total             3699
_reflns_number_gt                3406
_reflns_threshold_expression     'I > 2σ(I)'

#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#

_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'

#----------------------------------------------------------------------------#
#                   STRUCTURE SOLUTION                                       #
#----------------------------------------------------------------------------#

_atom_sites_solution_hydrogens   difmap

#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     'w=1/[σ²(Fo²)] where P=(Fo²+2Fc²)/3'
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_extinction_method     none
_refine_ls_number_reflns         3699
_refine_ls_number_parameters     324
_refine_ls_number_restraints     98
_refine_ls_number_constraints    0
_refine_ls_R_factor_all          0.0178
_refine_ls_R_factor_gt           0.0145
_refine_ls_wR_factor_ref         0.0288
_refine_ls_wR_factor_gt          0.0285
_refine_ls_goodness_of_fit_ref   0.894
_refine_ls_restrained_S_all      0.895
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0
_refine_ls_abs_structure_details 
;
 Flack x determined using 1536 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.493(8)
_refine_diff_density_max         0.479
_refine_diff_density_min         -0.758
_refine_diff_density_rms         0.068

#----------------------------------------------------------------------------#
#                   CONSTRAINTS AND RESTRAINTS                               #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.5 0.55205(2) 0.44277(18) 0.00613(5) Uani 1 2 d S T P . .
Co1 Co 0.5 0.18288(3) 0.4427(3) 0.00713(10) Uani 1 2 d S T P A .
O4 O 0.4513(12) 0.5684(11) 0.2926(10) 0.012(3) Uani 0.5 1 d . . P A 1
C16 C 0.3808(13) 0.5911(13) 0.2504(12) 0.013(4) Uiso 0.5 1 d . . P A 1
C17 C 0.2953(13) 0.5845(12) 0.2875(13) 0.012(4) Uiso 0.5 1 d D . P A 1
C18 C 0.2172(10) 0.6017(9) 0.2373(10) 0.013(4) Uiso 0.5 1 d D . P A 1
C19 C 0.3055(11) 0.6520(11) 0.1088(12) 0.016(4) Uiso 0.5 1 d D . P A 1
C20 C 0.3833(12) 0.6315(11) 0.1569(12) 0.014(4) Uiso 0.5 1 d D . P A 1
N8 N 0.2188(11) 0.6376(9) 0.1482(10) 0.017(3) Uiso 0.5 1 d D . P A 1
O3 O 0.3643(12) 0.5055(11) 0.3870(12) 0.014(3) Uani 0.5 1 d . U P A 2
C11 C 0.3184(11) 0.4568(12) 0.3279(10) 0.011(4) Uiso 0.5 1 d . . P A 2
C12 C 0.2216(9) 0.4542(9) 0.3339(8) 0.017(3) Uiso 0.5 1 d D . P A 2
C13 C 0.1673(9) 0.4045(8) 0.2873(8) 0.023(3) Uiso 0.5 1 d D . P A 2
C14 C 0.2908(7) 0.3633(6) 0.1930(6) 0.010(2) Uiso 0.5 1 d D . P A 2
C15 C 0.3501(11) 0.4088(11) 0.2517(11) 0.016(4) Uiso 0.5 1 d D . P A 2
N7 N 0.2027(7) 0.3642(6) 0.2111(8) 0.016(2) Uiso 0.5 1 d D . P A 2
O2 O 0.3609(12) 0.5095(10) 0.4995(11) 0.013(3) Uani 0.5 1 d . U P A 1
C6 C 0.3142(11) 0.4594(12) 0.5518(10) 0.010(4) Uiso 0.5 1 d D . P A 1
C7 C 0.2211(9) 0.4469(10) 0.5384(9) 0.020(3) Uiso 0.5 1 d D . P A 1
C8 C 0.1765(9) 0.4044(9) 0.6218(10) 0.031(4) Uiso 0.5 1 d D . P A 1
C9 C 0.3161(8) 0.3648(7) 0.6958(8) 0.024(3) Uiso 0.5 1 d D . P A 1
C10 C 0.3605(12) 0.4114(11) 0.6304(11) 0.017(4) Uiso 0.5 1 d D . P A 1
N6 N 0.2232(8) 0.3599(6) 0.6904(8) 0.020(2) Uiso 0.5 1 d D . P A 1
O5 O 0.4537(12) 0.5696(11) 0.5929(10) 0.013(3) Uani 0.5 1 d . U P A 2
C21 C 0.3803(12) 0.5937(12) 0.6416(12) 0.009(4) Uiso 0.5 1 d D . P A 2
C22 C 0.3869(13) 0.6249(12) 0.7350(13) 0.015(4) Uiso 0.5 1 d D . P A 2
C23 C 0.3127(10) 0.6469(11) 0.7836(12) 0.017(4) Uiso 0.5 1 d D . P A 2
C24 C 0.2213(11) 0.6107(10) 0.6555(12) 0.016(4) Uiso 0.5 1 d D . P A 2
C25 C 0.2900(13) 0.5804(12) 0.5999(13) 0.014(5) Uiso 0.5 1 d D . P A 2
N9 N 0.2327(7) 0.6408(7) 0.7447(8) 0.013(3) Uiso 0.5 1 d D . P A 2
O6 O 0.0676(9) 0.3261(9) 0.3414(8) 0.011(3) Uiso 0.5 1 d D . P . .
N4 N 0.5 0.1817(11) 0.6633(9) 0.017(3) Uani 1 2 d S TU P A .
N2 N 0.5 -0.0207(2) 0.4425(15) 0.0169(7) Uani 1 2 d S T P . .
N3 N 0.5 0.1810(11) 0.2288(9) 0.015(3) Uani 1 2 d S T P A .
N1 N 0.5 0.38614(19) 0.4397(13) 0.0102(9) Uani 1 2 d S T P A .
N5A N 0.2913(13) 0.1864(16) 0.4759(17) 0.010(3) Uani 0.4 1 d . U P A .
C2 C 0.5 0.0558(3) 0.4426(16) 0.0127(8) Uani 1 2 d S T P . .
C1 C 0.5 0.3092(2) 0.4442(16) 0.0090(7) Uani 1 2 d S TU P . .
C4 C 0.5 0.1829(11) 0.5780(10) 0.008(3) Uani 1 2 d S TU P . .
C3 C 0.5 0.1815(11) 0.3072(11) 0.013(3) Uani 1 2 d S T P . .
C5A C 0.3781(12) 0.1833(13) 0.4567(14) 0.0059(19) Uani 0.4 1 d . U P . .
C5B C 0.3669(8) 0.1845(9) 0.4292(9) 0.0074(15) Uani 0.6 1 d . U P . .
N5B N 0.2977(9) 0.1858(12) 0.4177(11) 0.015(2) Uani 0.6 1 d . U P A .
O1 O 0.40543(16) 0.68239(14) 0.4472(12) 0.0408(10) Uani 1 1 d D . . . .
O7 O 0.0709(9) 0.3262(9) 0.5390(8) 0.014(3) Uiso 0.5 1 d D . P . .
H17 H 0.294(6) 0.554(11) 0.352(6) 0.016 Uiso 0.5 1 d D U P B 1
H18 H 0.158(3) 0.597(7) 0.265(4) 0.016 Uiso 0.5 1 d D U P C 1
H19 H 0.306(9) 0.679(6) 0.047(4) 0.016 Uiso 0.5 1 d D U P D 1
H20 H 0.436(2) 0.627(7) 0.121(5) 0.016 Uiso 0.5 1 d D U P E 1
H8N H 0.178(3) 0.627(6) 0.097(3) 0.016 Uiso 0.5 1 d D U P F 1
H12 H 0.197(6) 0.471(5) 0.393(4) 0.016 Uiso 0.5 1 d D U P G 2
H13 H 0.109(3) 0.381(4) 0.308(4) 0.016 Uiso 0.5 1 d D U P H 2
H14 H 0.309(3) 0.361(5) 0.128(3) 0.016 Uiso 0.5 1 d D U P I 2
H15 H 0.4107(17) 0.401(6) 0.238(6) 0.016 Uiso 0.5 1 d D U P J 2
H7 H 0.193(3) 0.489(4) 0.497(5) 0.016 Uiso 0.5 1 d D U P K 1
H8 H 0.111(2) 0.414(5) 0.619(6) 0.016 Uiso 0.5 1 d D U P L 1
H9 H 0.331(5) 0.326(4) 0.748(4) 0.016 Uiso 0.5 1 d D U P M 1
H10 H 0.420(3) 0.425(6) 0.645(7) 0.016 Uiso 0.5 1 d D U P N 1
H22 H 0.443(3) 0.641(6) 0.762(6) 0.016 Uiso 0.5 1 d D U P O 2
H23 H 0.312(9) 0.666(6) 0.849(3) 0.016 Uiso 0.5 1 d D U P P 2
H24 H 0.161(3) 0.593(7) 0.641(6) 0.016 Uiso 0.5 1 d D U P Q 2
H25 H 0.286(3) 0.560(10) 0.535(4) 0.016 Uiso 0.5 1 d D U P R 2
H9N H 0.180(2) 0.660(5) 0.777(4) 0.016 Uiso 0.5 1 d D U P S 2
H6B H 0.039(4) 0.372(4) 0.369(4) 0.016 Uiso 0.5 1 d D U P . .
H6A H 0.049(5) 0.325(5) 0.281(2) 0.016 Uiso 0.5 1 d D U P . .
H1A H 0.3497(16) 0.6735(19) 0.423(2) 0.016 Uiso 1 1 d D U . . .
H1B H 0.420(2) 0.7288(17) 0.416(2) 0.016 Uiso 1 1 d D U . . .
H7A H 0.065(5) 0.381(3) 0.518(6) 0.016 Uiso 0.5 1 d D U P . .
H7B H 0.026(3) 0.310(4) 0.574(4) 0.016 Uiso 0.5 1 d D U P . .
H6N H 0.191(3) 0.357(4) 0.749(2) 0.016 Uiso 0.5 1 d D U P . .
H7N H 0.159(2) 0.331(4) 0.174(3) 0.016 Uiso 0.5 1 d D U P . .



#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O5 2.232(15) 2_655 ?
Dy1 O5 2.232(15) . ?
Dy1 O4 2.242(14) . ?
Dy1 O4 2.242(14) 2_655 ?
Dy1 O3 2.266(18) . ?
Dy1 O3 2.266(18) 2_655 ?
Dy1 O2 2.298(17) 2_655 ?
Dy1 O2 2.298(17) . ?
Dy1 O1 2.402(2) 2_655 ?
Dy1 O1 2.402(2) . ?
Dy1 N1 2.483(3) . ?
Co1 C5A 1.815(17) 2_655 ?
Co1 C5A 1.815(17) . ?
Co1 C1 1.891(3) . ?
Co1 C3 1.903(16) . ?
Co1 C4 1.899(15) . ?
Co1 C2 1.902(4) . ?
Co1 C5B 1.980(12) . ?
Co1 C5B 1.980(12) 2_655 ?
O4 C16 1.25(2) . ?
O1 H1A 0.90(2) . ?
O1 H1B 0.85(2) . ?
O7 H7A 0.88(3) . ?
O7 H7B 0.86(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 O5 35.7(9) 2_655 . ?
O4 Dy1 O4 37.6(9) . 2_655 ?
O5 Dy1 O3 129.4(6) 2_655 . ?
O5 Dy1 O3 95.2(6) . . ?
O5 Dy1 O3 95.2(6) 2_655 2_655 ?
O5 Dy1 O3 129.4(6) . 2_655 ?
O3 Dy1 O3 124.9(9) . 2_655 ?
O4 Dy1 O2 130.1(6) . 2_655 ?
O4 Dy1 O2 93.9(6) 2_655 2_655 ?
O4 Dy1 O2 93.9(6) . . ?
O4 Dy1 O2 130.1(6) 2_655 . ?
O2 Dy1 O2 127.3(8) 2_655 . ?
O5 Dy1 O1 72.6(6) 2_655 2_655 ?
O5 Dy1 O1 93.4(6) . 2_655 ?
O4 Dy1 O1 97.1(6) . 2_655 ?
O4 Dy1 O1 75.4(6) 2_655 2_655 ?
O3 Dy1 O1 140.8(5) . 2_655 ?
O3 Dy1 O1 75.0(4) 2_655 2_655 ?
O2 Dy1 O1 72.2(4) 2_655 2_655 ?
O2 Dy1 O1 137.6(5) . 2_655 ?
O5 Dy1 O1 93.4(6) 2_655 . ?
O5 Dy1 O1 72.6(6) . . ?
O4 Dy1 O1 75.4(6) . . ?
O4 Dy1 O1 97.1(6) 2_655 . ?
O3 Dy1 O1 75.0(4) . . ?
O3 Dy1 O1 140.8(5) 2_655 . ?
O2 Dy1 O1 137.6(5) 2_655 . ?
O2 Dy1 O1 72.2(4) . . ?
O1 Dy1 O1 71.32(11) 2_655 . ?
O5 Dy1 N1 97.7(6) 2_655 . ?
O5 Dy1 N1 97.7(6) . . ?
O4 Dy1 N1 95.3(6) . . ?
O4 Dy1 N1 95.3(6) 2_655 . ?
O3 Dy1 N1 71.7(4) . . ?
O3 Dy1 N1 71.7(4) 2_655 . ?
O2 Dy1 N1 74.3(4) 2_655 . ?
O2 Dy1 N1 74.3(4) . . ?
O1 Dy1 N1 144.33(6) 2_655 . ?
O1 Dy1 N1 144.33(6) . . ?
C5A Co1 C5A 167.6(13) 2_655 . ?
C5A Co1 C1 89.7(6) 2_655 . ?
C5A Co1 C1 89.7(6) . . ?
C5A Co1 C3 96.2(6) 2_655 . ?
C5A Co1 C3 96.2(6) . . ?
C1 Co1 C3 91.3(8) . . ?
C5A Co1 C4 83.8(6) 2_655 . ?
C5A Co1 C4 83.8(6) . . ?
C1 Co1 C4 89.4(8) . . ?
C3 Co1 C4 179.37(15) . . ?
C5A Co1 C2 90.2(6) 2_655 . ?
C5A Co1 C2 90.2(6) . . ?
C1 Co1 C2 179.4(10) . . ?
C3 Co1 C2 89.3(8) . . ?
C4 Co1 C2 90.1(8) . . ?
C5A Co1 C5B 178.9(7) 2_655 . ?
C5A Co1 C5B 11.7(4) . . ?
C1 Co1 C5B 89.4(4) . . ?
C3 Co1 C5B 84.5(4) . . ?
C4 Co1 C5B 95.5(4) . . ?
C2 Co1 C5B 90.7(4) . . ?
C5A Co1 C5B 11.7(4) 2_655 2_655 ?
C5A Co1 C5B 178.9(7) . 2_655 ?
C1 Co1 C5B 89.4(4) . 2_655 ?
C3 Co1 C5B 84.5(4) . 2_655 ?
C4 Co1 C5B 95.5(4) . 2_655 ?
C2 Co1 C5B 90.7(4) . 2_655 ?
C5B Co1 C5B 168.9(8) . 2_655 ?
C16 O4 O4 146.8(12) . 2_655 ?
C16 O4 Dy1 138.2(14) . . ?
O4 O4 Dy1 71.2(4) 2_655 . ?
O4 C16 C17 124.9(18) . . ?
O4 C16 C9 165.0(19) . 3_564 ?
C17 C16 C9 66.9(13) . 3_564 ?
O4 C16 C20 121.6(18) . . ?
C17 C16 C20 113.4(17) . . ?
C9 C16 C20 47.1(10) 3_564 . ?
O4 C16 C10 127.5(17) . 3_564 ?
C17 C16 C10 102.0(14) . 3_564 ?
C9 C16 C10 49.3(9) 3_564 3_564 ?
C16 C17 C18 124.5(17) . . ?
C16 C17 C9 57.2(11) . 3_564 ?
C18 C17 C9 69.2(11) . 3_564 ?
C16 C17 N6 102.3(13) . 3_564 ?
C9 C17 N6 45.4(7) 3_564 3_564 ?
C16 C17 H17 113(5) . . ?
C18 C17 H17 121(5) . . ?
C9 C17 H17 169(6) 3_564 . ?
N6 C17 H17 145(5) 3_564 . ?
N6 C18 C17 114.9(17) 3_564 . ?
N8 C18 C17 121.9(15) . . ?
N6 C18 C9 56.5(11) 3_564 3_564 ?
N8 C18 C9 62.6(10) . 3_564 ?
C17 C18 C9 59.7(10) . 3_564 ?
N6 C18 C8 50.8(10) 3_564 3_564 ?
C17 C18 C8 139.5(14) . 3_564 ?
C9 C18 C8 89.6(9) 3_564 3_564 ?
N6 C18 H18 116(4) 3_564 . ?
N8 C18 H18 114(3) . . ?
C17 C18 H18 123(4) . . ?
C9 C18 H18 167(6) 3_564 . ?
C8 C18 H18 93(4) 3_564 . ?
C9 C19 C10 62.9(12) 3_564 3_564 ?
C9 C19 C20 51.0(11) 3_564 . ?
C9 C19 N8 72.7(12) 3_564 . ?
C10 C19 N8 111.7(14) 3_564 . ?
C20 C19 N8 122.4(15) . . ?
C9 C19 N6 53.6(9) 3_564 3_564 ?
C10 C19 N6 102.7(12) 3_564 3_564 ?
C20 C19 N6 104.4(13) . 3_564 ?
C9 C19 C6 103.4(12) 3_564 3_564 ?
C10 C19 C6 52.8(10) 3_564 3_564 ?
C20 C19 C6 87.3(11) . 3_564 ?
N8 C19 C6 95.4(11) . 3_564 ?
N6 C19 C6 104.5(10) 3_564 3_564 ?
C9 C19 H19 164(7) 3_564 . ?
C10 C19 H19 122(7) 3_564 . ?
C20 C19 H19 122(8) . . ?
N8 C19 H19 115(8) . . ?
N6 C19 H19 132(8) 3_564 . ?
C6 C19 H19 90(6) 3_564 . ?
C10 C20 C9 84(2) 3_564 3_564 ?
C10 C20 C19 66.6(18) 3_564 . ?
C9 C20 C19 59.3(12) 3_564 . ?
C10 C20 C16 94(2) 3_564 . ?
C9 C20 C16 64.1(13) 3_564 . ?
C19 C20 C16 121.4(17) . . ?
C10 C20 H20 92(6) 3_564 . ?
C9 C20 H20 176(5) 3_564 . ?
C19 C20 H20 117(4) . . ?
C16 C20 H20 119(5) . . ?
N6 N8 C8 120(3) 3_564 3_564 ?
C8 N8 C18 94.9(15) 3_564 . ?
N6 N8 C19 106(3) 3_564 . ?
C8 N8 C19 122.7(17) 3_564 . ?
C18 N8 C19 115.8(14) . . ?
N6 N8 C9 59(2) 3_564 3_564 ?
C8 N8 C9 137.6(16) 3_564 3_564 ?
C18 N8 C9 67.7(10) . 3_564 ?
C19 N8 C9 49.1(9) . 3_564 ?
N6 N8 H8N 146(4) 3_564 . ?
C18 N8 H8N 128(4) . . ?
C19 N8 H8N 108(3) . . ?
C9 N8 H8N 153(4) 3_564 . ?
C11 O3 Dy1 149.2(14) . . ?
O3 C11 C15 127.9(16) . . ?
O3 C11 C12 120.0(15) . . ?
C15 C11 C12 112.0(14) . . ?
O3 C11 C23 141.7(16) . 3_564 ?
C12 C11 C23 87.0(12) . 3_564 ?
C13 C12 C11 127.9(13) . . ?
C11 C12 N9 84.0(9) . 3_564 ?
C13 C12 H12 112(5) . . ?
C11 C12 H12 115(6) . . ?
N9 C12 H12 145(5) 3_564 . ?
C12 C13 N9 94.0(11) . 3_564 ?
C12 C13 N7 115.3(12) . . ?
C12 C13 H13 128(4) . . ?
N9 C13 H13 127(4) 3_564 . ?
N7 C13 H13 115(3) . . ?
N9 C14 C24 69.6(12) 3_564 3_564 ?
N9 C14 C23 64.0(10) 3_564 3_564 ?
C24 C14 C23 131.3(14) 3_564 3_564 ?
C23 C14 N7 93.3(10) 3_564 . ?
N9 C14 C15 97.4(10) 3_564 . ?
C24 C14 C15 129.5(12) 3_564 . ?
C23 C14 C15 47.8(9) 3_564 . ?
N7 C14 C15 120.3(10) . . ?
N9 C14 C22 117.5(11) 3_564 3_564 ?
C24 C14 C22 154.5(12) 3_564 3_564 ?
C23 C14 C22 54.7(11) 3_564 3_564 ?
N7 C14 C22 145.8(11) . 3_564 ?
N9 C14 C25 124.4(12) 3_564 3_564 ?
C24 C14 C25 57.2(11) 3_564 3_564 ?
C23 C14 C25 150.9(12) 3_564 3_564 ?
N7 C14 C25 98.5(11) . 3_564 ?
C15 C14 C25 103.8(12) . 3_564 ?
C22 C14 C25 105.3(12) 3_564 3_564 ?
N9 C14 C21 157.1(11) 3_564 3_564 ?
C24 C14 C21 111.5(12) 3_564 3_564 ?
C23 C14 C21 105.7(11) 3_564 3_564 ?
N7 C14 C21 150.9(10) . 3_564 ?
C15 C14 C21 63.6(10) . 3_564 ?
C22 C14 C21 51.7(10) 3_564 3_564 ?
C25 C14 C21 54.8(10) 3_564 3_564 ?
N9 C14 H14 147(3) 3_564 . ?
C24 C14 H14 81(3) 3_564 . ?
C23 C14 H14 148(4) 3_564 . ?
N7 C14 H14 118(3) . . ?
C15 C14 H14 114(4) . . ?
C22 C14 H14 96(3) 3_564 . ?
C21 C14 H14 50(4) 3_564 . ?
C22 C15 C23 89(2) 3_564 3_564 ?
C22 C15 C11 144(2) 3_564 . ?
C23 C15 C11 84.6(15) 3_564 . ?
C22 C15 C14 87(2) 3_564 . ?
C23 C15 C14 63.2(12) 3_564 . ?
C11 C15 C14 120.3(14) . . ?
C22 C15 C21 60.1(19) 3_564 3_564 ?
C23 C15 C21 121.0(16) 3_564 3_564 ?
C11 C15 C21 148.9(16) . 3_564 ?
C14 C15 C21 66.0(10) . 3_564 ?
C22 C15 N9 112(2) 3_564 3_564 ?
C11 C15 N9 86.0(11) . 3_564 ?
C21 C15 N9 101.3(11) 3_564 3_564 ?
C23 C15 H15 119(7) 3_564 . ?
C11 C15 H15 124(4) . . ?
C14 C15 H15 116(4) . . ?
C21 C15 H15 62(5) 3_564 . ?
N9 C15 H15 147(4) 3_564 . ?
N9 N7 C24 117.5(19) 3_564 3_564 ?
N9 N7 C14 57.9(13) 3_564 . ?
C24 N7 C14 62.7(13) 3_564 . ?
N9 N7 C13 74.9(15) 3_564 . ?
C24 N7 C13 128.3(16) 3_564 . ?
C14 N7 C13 122.9(11) . . ?
C24 N7 C23 103.5(14) 3_564 3_564 ?
C13 N7 C23 87.0(9) . 3_564 ?
N9 N7 H7N 142(5) 3_564 . ?
C24 N7 H7N 87(4) 3_564 . ?
C14 N7 H7N 123(2) . . ?
C13 N7 H7N 113.7(19) . . ?
C23 N7 H7N 143(4) 3_564 . ?
C6 O2 Dy1 149.4(14) . . ?
O2 C6 C7 122.8(15) . . ?
O2 C6 C10 118.0(15) . . ?
C7 C6 C10 119.2(14) . . ?
O2 C6 C19 145.8(15) . 3_565 ?
C7 C6 C19 82.5(11) . 3_565 ?
C6 C7 C8 112.8(11) . . ?
C6 C7 H7 115(4) . . ?
C8 C7 H7 124(4) . . ?
N8 C8 C7 107.1(16) 3_565 . ?
N6 C8 C7 122.8(12) . . ?
N8 C8 C18 51.6(12) 3_565 3_565 ?
C7 C8 C18 127.2(11) . 3_565 ?
N8 C8 H8 139(5) 3_565 . ?
N6 C8 H8 127(5) . . ?
C7 C8 H8 110(5) . . ?
C18 C8 H8 113(5) 3_565 . ?
C20 C9 C19 69.6(13) 3_565 3_565 ?
C19 C9 C10 59.6(11) 3_565 . ?
C20 C9 N6 148.2(14) 3_565 . ?
C19 C9 N6 79.2(11) 3_565 . ?
C10 C9 N6 119.0(12) . . ?
C20 C9 C16 68.8(13) 3_565 3_565 ?
C19 C9 C16 135.6(14) 3_565 3_565 ?
C10 C9 C16 77.9(12) . 3_565 ?
N6 C9 C16 137.8(12) . 3_565 ?
C20 C9 C17 123.9(15) 3_565 3_565 ?
C19 C9 C17 153.4(14) 3_565 3_565 ?
C10 C9 C17 115.0(13) . 3_565 ?
N6 C9 C17 82.6(10) . 3_565 ?
C16 C9 C17 55.9(11) 3_565 3_565 ?
C20 C9 N8 126.4(13) 3_565 3_565 ?
C19 C9 N8 58.3(10) 3_565 3_565 ?
C10 C9 N8 99.8(12) . 3_565 ?
C16 C9 N8 150.0(13) 3_565 3_565 ?
C17 C9 N8 100.6(11) 3_565 3_565 ?
C20 C9 C18 158.4(14) 3_565 3_565 ?
C19 C9 C18 107.1(12) 3_565 3_565 ?
C10 C9 C18 121.6(12) . 3_565 ?
C16 C9 C18 105.7(11) 3_565 3_565 ?
C17 C9 C18 51.1(9) 3_565 3_565 ?
N8 C9 C18 49.7(8) 3_565 3_565 ?
C20 C9 H9 101(5) 3_565 . ?
C19 C9 H9 130(5) 3_565 . ?
C10 C9 H9 137(5) . . ?
N6 C9 H9 104(5) . . ?
C16 C9 H9 73(5) 3_565 . ?
C17 C9 H9 73(5) 3_565 . ?
N8 C9 H9 121(5) 3_565 . ?
C18 C9 H9 97(5) 3_565 . ?
C20 C10 C19 77.9(19) 3_565 3_565 ?
C20 C10 C9 58.4(16) 3_565 . ?
C19 C10 C9 57.5(11) 3_565 . ?
C20 C10 C6 156(2) 3_565 . ?
C19 C10 C6 83.6(13) 3_565 . ?
C9 C10 C6 122.7(15) . . ?
C20 C10 C16 57.3(16) 3_565 3_565 ?
C19 C10 C16 109.2(14) 3_565 3_565 ?
C9 C10 C16 52.8(10) . 3_565 ?
C6 C10 C16 145.4(15) . 3_565 ?
C20 C10 H10 71(5) 3_565 . ?
C19 C10 H10 145(6) 3_565 . ?
C9 C10 H10 116(5) . . ?
C6 C10 H10 120(5) . . ?
C16 C10 H10 68(6) 3_565 . ?
N8 N6 C18 134(2) 3_565 3_565 ?
C18 N6 C8 99.2(13) 3_565 . ?
N8 N6 C9 99(2) 3_565 . ?
C18 N6 C9 91.4(13) 3_565 . ?
C8 N6 C9 121.3(11) . . ?
N8 N6 C19 54(2) 3_565 3_565 ?
C18 N6 C19 130.7(14) 3_565 3_565 ?
C8 N6 C19 86.4(10) . 3_565 ?
C9 N6 C19 47.2(8) . 3_565 ?
N8 N6 C17 137(2) 3_565 3_565 ?
C8 N6 C17 124.9(10) . 3_565 ?
C9 N6 C17 52.0(8) . 3_565 ?
C19 N6 C17 97.2(10) 3_565 3_565 ?
N8 N6 H6N 144(4) 3_565 . ?
C18 N6 H6N 48(4) 3_565 . ?
C8 N6 H6N 113(3) . . ?
C9 N6 H6N 117(4) . . ?
C19 N6 H6N 161(3) 3_565 . ?
C17 N6 H6N 71(4) 3_565 . ?
C21 O5 O5 144.6(11) . 2_655 ?
C21 O5 Dy1 140.0(13) . . ?
O5 O5 Dy1 72.1(4) 2_655 . ?
O5 C21 C22 121.0(17) . . ?
O5 C21 C25 120.0(16) . . ?
C22 C21 C25 118.8(16) . . ?
O5 C21 C15 135.4(16) . 3_565 ?
C25 C21 C15 97.3(13) . 3_565 ?
O5 C21 C14 171.8(16) . 3_565 ?
C22 C21 C14 60.8(11) . 3_565 ?
C25 C21 C14 59.6(10) . 3_565 ?
C15 C21 C14 50.4(8) 3_565 3_565 ?
C15 C22 C23 55.3(17) 3_565 . ?
C15 C22 C21 91(2) 3_565 . ?
C23 C22 C21 120.4(18) . . ?
C15 C22 C14 63.0(18) 3_565 3_565 ?
C23 C22 C14 53.9(10) . 3_565 ?
C21 C22 C14 67.4(12) . 3_565 ?
C15 C22 H22 131(6) 3_565 . ?
C23 C22 H22 117(6) . . ?
C21 C22 H22 122(6) . . ?
C14 C22 H22 159(6) 3_565 . ?
C15 C23 N9 103.5(15) 3_565 . ?
C15 C23 C14 69.0(13) 3_565 3_565 ?
N9 C23 C14 50.7(9) . 3_565 ?
N9 C23 C22 120.9(16) . . ?
C14 C23 C22 71.4(13) 3_565 . ?
C15 C23 C11 54.7(12) 3_565 3_565 ?
N9 C23 C11 97.8(12) . 3_565 ?
C14 C23 C11 105.2(12) 3_565 3_565 ?
C22 C23 C11 85.4(13) . 3_565 ?
C15 C23 N7 98.3(13) 3_565 3_565 ?
C22 C23 N7 113.8(14) . 3_565 ?
C11 C23 N7 99.1(10) 3_565 3_565 ?
C15 C23 H23 128(7) 3_565 . ?
N9 C23 H23 114(8) . . ?
C14 C23 H23 162(7) 3_565 . ?
C22 C23 H23 125(8) . . ?
C11 C23 H23 85(6) 3_565 . ?
N7 C23 H23 121(8) 3_565 . ?
N7 C24 C14 75.7(14) 3_565 3_565 ?
N7 C24 C25 149(2) 3_565 . ?
C14 C24 C25 73.9(13) 3_565 . ?
C14 C24 N9 52.0(9) 3_565 . ?
C25 C24 N9 123.6(16) . . ?
N7 C24 H24 91(5) 3_565 . ?
C14 C24 H24 166(5) 3_565 . ?
C25 C24 H24 119(6) . . ?
N9 C24 H24 114(5) . . ?
C24 C25 C21 113.9(16) . . ?
C24 C25 C14 48.9(10) . 3_565 ?
C21 C25 C14 65.6(11) . 3_565 ?
C24 C25 H25 127(4) . . ?
C21 C25 H25 118(3) . . ?
C14 C25 H25 166(10) 3_565 . ?
N7 N9 C14 92.8(16) 3_565 3_565 ?
N7 N9 C23 158.0(19) 3_565 . ?
C14 N9 C23 65.3(11) 3_565 . ?
N7 N9 C13 76.7(14) 3_565 3_565 ?
C14 N9 C13 145.1(12) 3_565 3_565 ?
C23 N9 C13 120.5(12) . 3_565 ?
C14 N9 C24 58.4(10) 3_565 . ?
C23 N9 C24 121.8(13) . . ?
C13 N9 C24 99.1(11) 3_565 . ?
N7 N9 C15 128.2(15) 3_565 3_565 ?
C14 N9 C15 46.5(8) 3_565 3_565 ?
C13 N9 C15 116.5(10) 3_565 3_565 ?
C24 N9 C15 91.8(10) . 3_565 ?
N7 N9 C12 109.4(14) 3_565 3_565 ?
C14 N9 C12 116.7(10) 3_565 3_565 ?
C23 N9 C12 81.7(10) . 3_565 ?
C24 N9 C12 110.7(10) . 3_565 ?
C15 N9 C12 75.6(8) 3_565 3_565 ?
N7 N9 H9N 80(3) 3_565 . ?
C14 N9 H9N 162(5) 3_565 . ?
C23 N9 H9N 121(3) . . ?
C13 N9 H9N 49(4) 3_565 . ?
C24 N9 H9N 117(3) . . ?
C15 N9 H9N 148(4) 3_565 . ?
C12 N9 H9N 81(4) 3_565 . ?
H13 O6 H6B 83(5) . . ?
H13 O6 H6A 77(5) . . ?
H6B O6 H6A 107(4) . . ?
C1 N1 Dy1 175.9(17) . . ?
N5B N5A C5B 53.0(19) . . ?
N5B N5A C5A 72(2) . . ?
N2 C2 Co1 180(2) . . ?
N1 C1 Co1 176(2) . . ?
N4 C4 Co1 179.1(14) . . ?
N3 C3 Co1 179.7(15) . . ?
N5B C5A Co1 149.1(16) . . ?
N5A C5A Co1 174.1(19) . . ?
N5B C5B Co1 176.5(15) . . ?
N5A C5B Co1 144.1(15) . . ?
N5A N5B C5B 88(2) . . ?
N5A N5B C5A 72(2) . . ?
Dy1 O1 H1A 114(2) . . ?
Dy1 O1 H1B 120(2) . . ?
H1A O1 H1B 99(3) . . ?
H7A O7 H7B 112(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O4 O4 C16 C17 -171.2(12) 2_655 . . . ?
Dy1 O4 C16 C17 -25(3) . . . . ?
O4 O4 C16 C9 -32(9) 2_655 . . 3_564 ?
Dy1 O4 C16 C9 114(7) . . . 3_564 ?
O4 O4 C16 C20 6(3) 2_655 . . . ?
Dy1 O4 C16 C20 152.0(15) . . . . ?
O4 O4 C16 C10 40(3) 2_655 . . 3_564 ?
Dy1 O4 C16 C10 -174.2(12) . . . 3_564 ?
O4 C16 C17 C18 -173.5(18) . . . . ?
C9 C16 C17 C18 17.0(18) 3_564 . . . ?
C20 C16 C17 C18 9(3) . . . . ?
C10 C16 C17 C18 -18(2) 3_564 . . . ?
O4 C16 C17 C9 169(2) . . . 3_564 ?
C20 C16 C17 C9 -8.0(13) . . . 3_564 ?
C10 C16 C17 C9 -35.3(10) 3_564 . . 3_564 ?
O4 C16 C17 N6 175.2(18) . . . 3_564 ?
C9 C16 C17 N6 5.7(10) 3_564 . . 3_564 ?
C20 C16 C17 N6 -2.3(19) . . . 3_564 ?
C10 C16 C17 N6 -29.6(15) 3_564 . . 3_564 ?
C16 C17 C18 N6 -28(3) . . . 3_564 ?
C9 C17 C18 N6 -12.3(15) 3_564 . . 3_564 ?
C16 C17 C18 N8 -8(3) . . . . ?
C9 C17 C18 N8 7.2(15) 3_564 . . . ?
N6 C17 C18 N8 19.5(11) 3_564 . . . ?
C16 C17 C18 C9 -15.3(16) . . . 3_564 ?
N6 C17 C18 C9 12.3(15) 3_564 . . 3_564 ?
C16 C17 C18 C8 30(3) . . . 3_564 ?
C9 C17 C18 C8 45.7(19) 3_564 . . 3_564 ?
N6 C17 C18 C8 58.0(18) 3_564 . . 3_564 ?
C9 C19 C20 C10 97.1(19) 3_564 . . 3_564 ?
N8 C19 C20 C10 82(2) . . . 3_564 ?
N6 C19 C20 C10 91.7(18) 3_564 . . 3_564 ?
C6 C19 C20 C10 -12.5(16) 3_564 . . 3_564 ?
C10 C19 C20 C9 -97.1(19) 3_564 . . 3_564 ?
N8 C19 C20 C9 -14.9(16) . . . 3_564 ?
N6 C19 C20 C9 -5.4(11) 3_564 . . 3_564 ?
C6 C19 C20 C9 -109.6(12) 3_564 . . 3_564 ?
C9 C19 C20 C16 16.8(15) 3_564 . . . ?
C10 C19 C20 C16 -80(2) 3_564 . . . ?
N8 C19 C20 C16 2(2) . . . . ?
N6 C19 C20 C16 11(2) 3_564 . . . ?
C6 C19 C20 C16 -92.9(16) 3_564 . . . ?
O4 C16 C20 C10 111(2) . . . 3_564 ?
C17 C16 C20 C10 -71(2) . . . 3_564 ?
C9 C16 C20 C10 -81(2) 3_564 . . 3_564 ?
O4 C16 C20 C9 -167(2) . . . 3_564 ?
C17 C16 C20 C9 10.0(16) . . . 3_564 ?
C10 C16 C20 C9 81(2) 3_564 . . 3_564 ?
O4 C16 C20 C19 176.5(18) . . . . ?
C17 C16 C20 C19 -6(2) . . . . ?
C9 C16 C20 C19 -16.0(14) 3_564 . . . ?
C10 C16 C20 C19 65(2) 3_564 . . . ?
C17 C18 N8 N6 -73(4) . . . 3_564 ?
C9 C18 N8 N6 -66(4) 3_564 . . 3_564 ?
C8 C18 N8 N6 154(4) 3_564 . . 3_564 ?
N6 C18 N8 C8 -154(4) 3_564 . . 3_564 ?
C17 C18 N8 C8 133.0(17) . . . 3_564 ?
C9 C18 N8 C8 140.0(16) 3_564 . . 3_564 ?
N6 C18 N8 C19 76(4) 3_564 . . . ?
C17 C18 N8 C19 3(2) . . . . ?
C9 C18 N8 C19 10.0(12) 3_564 . . . ?
C8 C18 N8 C19 -130(2) 3_564 . . . ?
N6 C18 N8 C9 66(4) 3_564 . . 3_564 ?
C17 C18 N8 C9 -7.0(15) . . . 3_564 ?
C8 C18 N8 C9 -140.0(16) 3_564 . . 3_564 ?
C9 C19 N8 N6 15.9(19) 3_564 . . 3_564 ?
C10 C19 N8 N6 66(2) 3_564 . . 3_564 ?
C20 C19 N8 N6 28(3) . . . 3_564 ?
C6 C19 N8 N6 118(2) 3_564 . . 3_564 ?
C9 C19 N8 C8 -127.2(19) 3_564 . . 3_564 ?
C10 C19 N8 C8 -77(2) 3_564 . . 3_564 ?
C20 C19 N8 C8 -115(2) . . . 3_564 ?
N6 C19 N8 C8 -143(3) 3_564 . . 3_564 ?
C6 C19 N8 C8 -24.8(19) 3_564 . . 3_564 ?
C9 C19 N8 C18 -12.2(14) 3_564 . . . ?
C10 C19 N8 C18 38(2) 3_564 . . . ?
C20 C19 N8 C18 0(2) . . . . ?
N6 C19 N8 C18 -28.1(14) 3_564 . . . ?
C6 C19 N8 C18 90.1(14) 3_564 . . . ?
C10 C19 N8 C9 50.4(13) 3_564 . . 3_564 ?
C20 C19 N8 C9 12.1(13) . . . 3_564 ?
N6 C19 N8 C9 -15.9(19) 3_564 . . 3_564 ?
C6 C19 N8 C9 102.4(11) 3_564 . . 3_564 ?
Dy1 O3 C11 C15 -9(4) . . . . ?
Dy1 O3 C11 C12 176.4(18) . . . . ?
Dy1 O3 C11 C23 47(4) . . . 3_564 ?
O3 C11 C12 C13 -173.4(16) . . . . ?
C15 C11 C12 C13 11(2) . . . . ?
C23 C11 C12 C13 -22.1(18) 3_564 . . . ?
O3 C11 C12 N9 -170.4(16) . . . 3_564 ?
C15 C11 C12 N9 13.9(14) . . . 3_564 ?
C23 C11 C12 N9 -19.0(8) 3_564 . . 3_564 ?
C11 C12 C13 N9 4.4(19) . . . 3_564 ?
C11 C12 C13 N7 -15(2) . . . . ?
N9 C12 C13 N7 -19.5(8) 3_564 . . . ?
O3 C11 C15 C22 48(5) . . . 3_564 ?
C12 C11 C15 C22 -137(4) . . . 3_564 ?
C23 C11 C15 C22 -81(4) 3_564 . . 3_564 ?
O3 C11 C15 C23 128(2) . . . 3_564 ?
C12 C11 C15 C23 -56.3(17) . . . 3_564 ?
O3 C11 C15 C14 -177.1(16) . . . . ?
C12 C11 C15 C14 -2(2) . . . . ?
C23 C11 C15 C14 54.6(14) 3_564 . . . ?
O3 C11 C15 C21 -84(3) . . . 3_564 ?
C12 C11 C15 C21 92(3) . . . 3_564 ?
C23 C11 C15 C21 148(3) 3_564 . . 3_564 ?
O3 C11 C15 N9 170.8(19) . . . 3_564 ?
C12 C11 C15 N9 -13.9(14) . . . 3_564 ?
C23 C11 C15 N9 42.4(10) 3_564 . . 3_564 ?
N9 C14 C15 C22 134.9(19) 3_564 . . 3_564 ?
C24 C14 C15 C22 -155(2) 3_564 . . 3_564 ?
C23 C14 C15 C22 91(2) 3_564 . . 3_564 ?
N7 C14 C15 C22 154.4(18) . . . 3_564 ?
C25 C14 C15 C22 -96.9(19) 3_564 . . 3_564 ?
C21 C14 C15 C22 -58.5(18) 3_564 . . 3_564 ?
N9 C14 C15 C23 44.4(14) 3_564 . . 3_564 ?
C24 C14 C15 C23 114.0(19) 3_564 . . 3_564 ?
N7 C14 C15 C23 63.9(15) . . . 3_564 ?
C22 C14 C15 C23 -91(2) 3_564 . . 3_564 ?
C25 C14 C15 C23 172.6(14) 3_564 . . 3_564 ?
C21 C14 C15 C23 -149.0(16) 3_564 . . 3_564 ?
N9 C14 C15 C11 -20.9(17) 3_564 . . . ?
C24 C14 C15 C11 49(2) 3_564 . . . ?
C23 C14 C15 C11 -65.3(17) 3_564 . . . ?
N7 C14 C15 C11 -1(2) . . . . ?
C22 C14 C15 C11 -156(3) 3_564 . . . ?
C25 C14 C15 C11 107.3(16) 3_564 . . . ?
C21 C14 C15 C11 145.6(18) 3_564 . . . ?
N9 C14 C15 C21 -166.6(12) 3_564 . . 3_564 ?
C24 C14 C15 C21 -97.0(17) 3_564 . . 3_564 ?
C23 C14 C15 C21 149.0(16) 3_564 . . 3_564 ?
N7 C14 C15 C21 -147.1(12) . . . 3_564 ?
C22 C14 C15 C21 58.5(18) 3_564 . . 3_564 ?
C25 C14 C15 C21 -38.4(12) 3_564 . . 3_564 ?
C24 C14 C15 N9 69.6(16) 3_564 . . 3_564 ?
C23 C14 C15 N9 -44.4(14) 3_564 . . 3_564 ?
N7 C14 C15 N9 19.5(8) . . . 3_564 ?
C22 C14 C15 N9 -134.9(19) 3_564 . . 3_564 ?
C25 C14 C15 N9 128.2(13) 3_564 . . 3_564 ?
C21 C14 C15 N9 166.6(12) 3_564 . . 3_564 ?
C24 C14 N7 N9 -159.4(19) 3_564 . . 3_564 ?
C23 C14 N7 N9 -0.8(14) 3_564 . . 3_564 ?
C15 C14 N7 N9 -42.5(15) . . . 3_564 ?
C22 C14 N7 N9 -20(2) 3_564 . . 3_564 ?
C25 C14 N7 N9 -154.1(15) 3_564 . . 3_564 ?
C21 C14 N7 N9 -132(2) 3_564 . . 3_564 ?
N9 C14 N7 C24 159.4(19) 3_564 . . 3_564 ?
C23 C14 N7 C24 158.6(15) 3_564 . . 3_564 ?
C15 C14 N7 C24 116.9(16) . . . 3_564 ?
C22 C14 N7 C24 139(2) 3_564 . . 3_564 ?
C25 C14 N7 C24 5.3(14) 3_564 . . 3_564 ?
C21 C14 N7 C24 27(2) 3_564 . . 3_564 ?
N9 C14 N7 C13 39.5(15) 3_564 . . . ?
C24 C14 N7 C13 -119.9(18) 3_564 . . . ?
C23 C14 N7 C13 38.8(14) 3_564 . . . ?
C15 C14 N7 C13 -3.0(17) . . . . ?
C22 C14 N7 C13 20(2) 3_564 . . . ?
C25 C14 N7 C13 -114.5(13) 3_564 . . . ?
C21 C14 N7 C13 -92(2) 3_564 . . . ?
N9 C14 N7 C23 0.8(14) 3_564 . . 3_564 ?
C24 C14 N7 C23 -158.6(15) 3_564 . . 3_564 ?
C15 C14 N7 C23 -41.8(11) . . . 3_564 ?
C22 C14 N7 C23 -19.2(17) 3_564 . . 3_564 ?
C25 C14 N7 C23 -153.3(13) 3_564 . . 3_564 ?
C21 C14 N7 C23 -131(2) 3_564 . . 3_564 ?
C12 C13 N7 N9 44.6(16) . . . 3_564 ?
C12 C13 N7 C24 -69(2) . . . 3_564 ?
N9 C13 N7 C24 -113(2) 3_564 . . 3_564 ?
C12 C13 N7 C14 10.6(18) . . . . ?
N9 C13 N7 C14 -34.0(12) 3_564 . . . ?
C12 C13 N7 C23 36.0(13) . . . 3_564 ?
N9 C13 N7 C23 -8.5(11) 3_564 . . 3_564 ?
Dy1 O2 C6 C7 -160.9(18) . . . . ?
Dy1 O2 C6 C10 19(4) . . . . ?
Dy1 O2 C6 C19 -29(4) . . . 3_565 ?
O2 C6 C7 C8 -165.3(16) . . . . ?
C10 C6 C7 C8 15(2) . . . . ?
C19 C6 C7 C8 39.5(13) 3_565 . . . ?
C6 C7 C8 N8 -35.4(19) . . . 3_565 ?
C6 C7 C8 N6 -18(2) . . . . ?
C6 C7 C8 C18 19(2) . . . 3_565 ?
C19 C9 C10 C20 -96(2) 3_565 . . 3_565 ?
N6 C9 C10 C20 -150.8(19) . . . 3_565 ?
C16 C9 C10 C20 70.8(19) 3_565 . . 3_565 ?
C17 C9 C10 C20 114(2) 3_565 . . 3_565 ?
N8 C9 C10 C20 -139.7(18) 3_565 . . 3_565 ?
C18 C9 C10 C20 172.0(19) 3_565 . . 3_565 ?
C20 C9 C10 C19 96(2) 3_565 . . 3_565 ?
N6 C9 C10 C19 -55.0(14) . . . 3_565 ?
C16 C9 C10 C19 166.6(15) 3_565 . . 3_565 ?
C17 C9 C10 C19 -150.5(16) 3_565 . . 3_565 ?
N8 C9 C10 C19 -43.9(12) 3_565 . . 3_565 ?
C18 C9 C10 C19 -92.3(15) 3_565 . . 3_565 ?
C20 C9 C10 C6 151(3) 3_565 . . . ?
C19 C9 C10 C6 55.6(16) 3_565 . . . ?
N6 C9 C10 C6 1(2) . . . . ?
C16 C9 C10 C6 -137.8(18) 3_565 . . . ?
C17 C9 C10 C6 -94.9(18) 3_565 . . . ?
N8 C9 C10 C6 11.7(18) 3_565 . . . ?
C18 C9 C10 C6 -37(2) 3_565 . . . ?
C20 C9 C10 C16 -70.8(19) 3_565 . . 3_565 ?
C19 C9 C10 C16 -166.6(15) 3_565 . . 3_565 ?
N6 C9 C10 C16 138.4(15) . . . 3_565 ?
C17 C9 C10 C16 42.9(13) 3_565 . . 3_565 ?
N8 C9 C10 C16 149.5(13) 3_565 . . 3_565 ?
C18 C9 C10 C16 101.2(14) 3_565 . . 3_565 ?
O2 C6 C10 C20 -103(5) . . . 3_565 ?
C7 C6 C10 C20 77(6) . . . 3_565 ?
C19 C6 C10 C20 40(5) 3_565 . . 3_565 ?
O2 C6 C10 C19 -143.1(17) . . . 3_565 ?
C7 C6 C10 C19 36.5(17) . . . 3_565 ?
O2 C6 C10 C9 172.5(15) . . . . ?
C7 C6 C10 C9 -8(2) . . . . ?
C19 C6 C10 C9 -44.4(14) 3_565 . . . ?
O2 C6 C10 C16 102(3) . . . 3_565 ?
C7 C6 C10 C16 -78(3) . . . 3_565 ?
C19 C6 C10 C16 -115(3) 3_565 . . 3_565 ?
C7 C8 N6 N8 -50(3) . . . 3_565 ?
C18 C8 N6 N8 -159(3) 3_565 . . 3_565 ?
N8 C8 N6 C18 159(3) 3_565 . . 3_565 ?
C7 C8 N6 C18 108.8(17) . . . 3_565 ?
N8 C8 N6 C9 61(3) 3_565 . . . ?
C7 C8 N6 C9 11.6(19) . . . . ?
C18 C8 N6 C9 -97.3(15) 3_565 . . . ?
N8 C8 N6 C19 28(3) 3_565 . . 3_565 ?
C7 C8 N6 C19 -21.8(14) . . . 3_565 ?
C18 C8 N6 C19 -130.6(14) 3_565 . . 3_565 ?
N8 C8 N6 C17 124(3) 3_565 . . 3_565 ?
C7 C8 N6 C17 74.5(18) . . . 3_565 ?
C18 C8 N6 C17 -34.3(13) 3_565 . . 3_565 ?
C20 C9 N6 N8 -4(3) 3_565 . . 3_565 ?
C19 C9 N6 N8 -15.3(19) 3_565 . . 3_565 ?
C10 C9 N6 N8 31(2) . . . 3_565 ?
C16 C9 N6 N8 136(2) 3_565 . . 3_565 ?
C17 C9 N6 N8 145.2(19) 3_565 . . 3_565 ?
C18 C9 N6 N8 135(2) 3_565 . . 3_565 ?
C20 C9 N6 C18 -138(3) 3_565 . . 3_565 ?
C19 C9 N6 C18 -150.1(14) 3_565 . . 3_565 ?
C10 C9 N6 C18 -104.0(16) . . . 3_565 ?
C16 C9 N6 C18 1(2) 3_565 . . 3_565 ?
C17 C9 N6 C18 10.5(13) 3_565 . . 3_565 ?
N8 C9 N6 C18 -135(2) 3_565 . . 3_565 ?
C20 C9 N6 C8 -37(3) 3_565 . . . ?
C19 C9 N6 C8 -48.5(14) 3_565 . . . ?
C10 C9 N6 C8 -2.4(18) . . . . ?
C16 C9 N6 C8 102(2) 3_565 . . . ?
C17 C9 N6 C8 112.1(13) 3_565 . . . ?
N8 C9 N6 C8 -33.1(16) 3_565 . . . ?
C18 C9 N6 C8 101.6(15) 3_565 . . . ?
C20 C9 N6 C19 12(2) 3_565 . . 3_565 ?
C10 C9 N6 C19 46.0(13) . . . 3_565 ?
C16 C9 N6 C19 151(2) 3_565 . . 3_565 ?
C17 C9 N6 C19 160.5(13) 3_565 . . 3_565 ?
N8 C9 N6 C19 15.3(19) 3_565 . . 3_565 ?
C18 C9 N6 C19 150.1(14) 3_565 . . 3_565 ?
C20 C9 N6 C17 -149(3) 3_565 . . 3_565 ?
C19 C9 N6 C17 -160.5(13) 3_565 . . 3_565 ?
C10 C9 N6 C17 -114.5(15) . . . 3_565 ?
C16 C9 N6 C17 -9.7(17) 3_565 . . 3_565 ?
N8 C9 N6 C17 -145.2(19) 3_565 . . 3_565 ?
C18 C9 N6 C17 -10.5(13) 3_565 . . 3_565 ?
O5 O5 C21 C22 -10(3) 2_655 . . . ?
Dy1 O5 C21 C22 -158.0(15) . . . . ?
O5 O5 C21 C25 175.6(10) 2_655 . . . ?
Dy1 O5 C21 C25 27(3) . . . . ?
O5 O5 C21 C15 -42(3) 2_655 . . 3_565 ?
Dy1 O5 C21 C15 169.7(14) . . . 3_565 ?
O5 C21 C22 C15 -129(2) . . . 3_565 ?
C25 C21 C22 C15 46(3) . . . 3_565 ?
C14 C21 C22 C15 60.1(18) 3_565 . . 3_565 ?
O5 C21 C22 C23 -178.6(17) . . . . ?
C25 C21 C22 C23 -4(3) . . . . ?
C15 C21 C22 C23 -49.4(19) 3_565 . . . ?
C14 C21 C22 C23 10.7(15) 3_565 . . . ?
O5 C21 C22 C14 170.8(19) . . . 3_565 ?
C25 C21 C22 C14 -14.3(15) . . . 3_565 ?
C15 C21 C22 C14 -60.1(18) 3_565 . . 3_565 ?
C21 C22 C23 C15 67(2) . . . 3_565 ?
C14 C22 C23 C15 80(2) 3_565 . . 3_565 ?
C15 C22 C23 N9 -68(2) 3_565 . . . ?
C21 C22 C23 N9 -1(3) . . . . ?
C14 C22 C23 N9 11.4(13) 3_565 . . . ?
C15 C22 C23 C14 -80(2) 3_565 . . 3_565 ?
C21 C22 C23 C14 -12.2(17) . . . 3_565 ?
C15 C22 C23 C11 28.0(19) 3_565 . . 3_565 ?
C21 C22 C23 C11 95.5(18) . . . 3_565 ?
C14 C22 C23 C11 107.7(11) 3_565 . . 3_565 ?
C15 C22 C23 N7 -70(2) 3_565 . . 3_565 ?
C21 C22 C23 N7 -2(2) . . . 3_565 ?
C14 C22 C23 N7 9.8(9) 3_565 . . 3_565 ?
N7 C24 C25 C21 -3(4) 3_565 . . . ?
C14 C24 C25 C21 8.7(15) 3_565 . . . ?
N9 C24 C25 C21 -7(2) . . . . ?
N7 C24 C25 C14 -12(3) 3_565 . . 3_565 ?
N9 C24 C25 C14 -15.9(12) . . . 3_565 ?
O5 C21 C25 C24 -177.8(16) . . . . ?
C22 C21 C25 C24 7(2) . . . . ?
C15 C21 C25 C24 27.7(19) 3_565 . . . ?
C14 C21 C25 C24 -7.2(13) 3_565 . . . ?
O5 C21 C25 C14 -170.6(18) . . . 3_565 ?
C22 C21 C25 C14 14.5(15) . . . 3_565 ?
C15 C21 C25 C14 34.9(10) 3_565 . . 3_565 ?
C15 C23 N9 N7 -46(5) 3_565 . . 3_565 ?
C14 C23 N9 N7 2(4) 3_565 . . 3_565 ?
C22 C23 N9 N7 -12(5) . . . 3_565 ?
C11 C23 N9 N7 -101(4) 3_565 . . 3_565 ?
C15 C23 N9 C14 -47.9(15) 3_565 . . 3_565 ?
C22 C23 N9 C14 -14.0(16) . . . 3_565 ?
C11 C23 N9 C14 -103.3(12) 3_565 . . 3_565 ?
N7 C23 N9 C14 -2(4) 3_565 . . 3_565 ?
C15 C23 N9 C13 93.2(17) 3_565 . . 3_565 ?
C14 C23 N9 C13 141.0(14) 3_565 . . 3_565 ?
C22 C23 N9 C13 127.0(17) . . . 3_565 ?
C11 C23 N9 C13 37.7(15) 3_565 . . 3_565 ?
N7 C23 N9 C13 139(5) 3_565 . . 3_565 ?
C15 C23 N9 C24 -33(2) 3_565 . . . ?
C14 C23 N9 C24 15.3(13) 3_565 . . . ?
C22 C23 N9 C24 1(2) . . . . ?
C11 C23 N9 C24 -88.0(15) 3_565 . . . ?
N7 C23 N9 C24 13(4) 3_565 . . . ?
C14 C23 N9 C15 47.9(15) 3_565 . . 3_565 ?
C22 C23 N9 C15 33.8(15) . . . 3_565 ?
C11 C23 N9 C15 -55.4(13) 3_565 . . 3_565 ?
N7 C23 N9 C15 46(5) 3_565 . . 3_565 ?
C15 C23 N9 C12 76.7(14) 3_565 . . 3_565 ?
C14 C23 N9 C12 124.5(9) 3_565 . . 3_565 ?
C22 C23 N9 C12 110.5(17) . . . 3_565 ?
C11 C23 N9 C12 21.3(9) 3_565 . . 3_565 ?
N7 C23 N9 C12 122(4) 3_565 . . 3_565 ?
C14 C24 N9 N7 156(2) 3_565 . . 3_565 ?
C25 C24 N9 N7 175(3) . . . 3_565 ?
N7 C24 N9 C14 -156(2) 3_565 . . 3_565 ?
C25 C24 N9 C14 19.6(15) . . . 3_565 ?
N7 C24 N9 C23 -172(2) 3_565 . . . ?
C14 C24 N9 C23 -16.4(14) 3_565 . . . ?
C25 C24 N9 C23 3(2) . . . . ?
N7 C24 N9 C13 53(2) 3_565 . . 3_565 ?
C14 C24 N9 C13 -151.3(12) 3_565 . . 3_565 ?
C25 C24 N9 C13 -131.7(16) . . . 3_565 ?
N7 C24 N9 C15 170(2) 3_565 . . 3_565 ?
C14 C24 N9 C15 -34.0(9) 3_565 . . 3_565 ?
C25 C24 N9 C15 -14.5(17) . . . 3_565 ?
N7 C24 N9 C12 95(2) 3_565 . . 3_565 ?
C14 C24 N9 C12 -109.3(11) 3_565 . . 3_565 ?
C25 C24 N9 C12 -89.8(17) . . . 3_565 ?
C5B N5A C5A N5B -2(5) . . . . ?
C5A Co1 C5A N5B 175(3) 2_655 . . . ?
C1 Co1 C5A N5B 88(3) . . . . ?
C3 Co1 C5A N5B -4(3) . . . . ?
C4 Co1 C5A N5B 177(3) . . . . ?
C2 Co1 C5A N5B -93(3) . . . . ?
C5B Co1 C5A N5B 0(3) . . . . ?
C5A N5A C5B N5B 178(6) . . . . ?
N5B N5A C5B Co1 179(2) . . . . ?
C5A N5A C5B Co1 -3(3) . . . . ?
C5A N5A N5B C5B -0.8(19) . . . . ?
C5B N5A N5B C5A 0.8(19) . . . . ?
N5A C5B N5B C5A -3(7) . . . . ?
Co1 C5A N5B N5A -176(3) . . . . ?
N5A C5A N5B C5B 177(7) . . . . ?
Co1 C5A N5B C5B 1(4) . . . . ?


# END of CIF
_exptl_crystal_preparation       'Magnetic properties,Luminescent'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 1571679'
_audit_update_record             
;
2017-08-30 deposited with the CCDC.
2017-11-18 downloaded from the CCDC.
;

_audit_creation_date             2017-04-23T19:31:02-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic

#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#

_chemical_formula_moiety         'C26 H26 Dy N10 O7 Rh, H2 O'
_chemical_formula_sum            'C26 H28 Dy N10 O8 Rh'
_chemical_formula_weight         873.99
_chemical_absolute_configuration unk

#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'C m c 21'
_symmetry_space_group_name_Hall  'C 2c -2'
_symmetry_Int_Tables_number      36
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, z'
'x, -y, z+1/2'
'-x, -y, z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'

_cell_length_a                   14.8508(9)
_cell_length_b                   15.1527(10)
_cell_length_c                   14.0756(10)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3167.4(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    90(2)
_cell_measurement_reflns_used    24918
_cell_measurement_theta_min      3.054
_cell_measurement_theta_max      27.478
_cell_measurement_wavelength     0.71075

#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.06
_exptl_crystal_density_diffrn    1.833
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1716

#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#

_exptl_absorpt_coefficient_mu    2.925
_exptl_absorpt_correction_type   multi-scan
_shelx_estimated_absorpt_T_min   0.735
_shelx_estimated_absorpt_T_max   0.755
_exptl_absorpt_correction_T_min  0.879
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'

#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#

_diffrn_ambient_temperature      90(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_probe          x-ray
_diffrn_standards_number         0
_diffrn_standards_interval_time  .
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_reflns_av_R_equivalents  0.0831
_diffrn_reflns_av_unetI/netI     0.0485
_diffrn_reflns_number            24918
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         3.054
_diffrn_reflns_theta_max         27.478
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     0.999
_reflns_Friedel_coverage         0.921
_reflns_number_total             3759
_reflns_number_gt                3407
_reflns_threshold_expression     'I > 2σ(I)'

#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#

_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'

#----------------------------------------------------------------------------#
#                   STRUCTURE SOLUTION                                       #
#----------------------------------------------------------------------------#

_atom_sites_solution_hydrogens   difmap

#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0129P)²+25.7197P] where P=(Fo²+2Fc²)/3'
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_extinction_method     none
_refine_ls_number_reflns         3759
_refine_ls_number_parameters     323
_refine_ls_number_restraints     122
_refine_ls_number_constraints    0
_refine_ls_R_factor_all          0.0542
_refine_ls_R_factor_gt           0.0456
_refine_ls_wR_factor_ref         0.0689
_refine_ls_wR_factor_gt          0.067
_refine_ls_goodness_of_fit_ref   1.113
_refine_ls_restrained_S_all      1.101
_refine_ls_shift/su_max          0.02
_refine_ls_shift/su_mean         0.002
_refine_ls_abs_structure_details 
;
 Flack x determined using 1329 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.45(2)
_refine_diff_density_max         1.136
_refine_diff_density_min         -2.379
_refine_diff_density_rms         0.141

#----------------------------------------------------------------------------#
#                   CONSTRAINTS AND RESTRAINTS                               #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.5 0.55689(3) 0.4437(2) 0.01437(14) Uani 1 2 d S T P . .
Rh1 Rh 0.5 0.18575(5) 0.4444(3) 0.0198(2) Uani 1 2 d S T P A .
O4 O 0.4535(18) 0.5758(15) 0.2920(18) 0.018(5) Uani 0.5 1 d . U P A 1
C16 C 0.381(2) 0.590(2) 0.249(2) 0.013(7) Uiso 0.5 1 d . . P A 1
C17 C 0.293(2) 0.589(2) 0.285(2) 0.019(8) Uiso 0.5 1 d D . P A 1
C18 C 0.214(2) 0.600(2) 0.233(2) 0.025(8) Uiso 0.5 1 d D . P A 1
C19 C 0.3076(18) 0.641(2) 0.102(2) 0.023(7) Uiso 0.5 1 d D . P A 1
C20 C 0.3878(19) 0.6276(18) 0.153(2) 0.011(6) Uiso 0.5 1 d D . P A 1
N8 N 0.2355(16) 0.6468(16) 0.1448(18) 0.027(6) Uiso 0.5 1 d D . P A 1
O3 O 0.367(2) 0.510(2) 0.390(2) 0.029(7) Uani 0.5 1 d . U P A 2
C11 C 0.3205(18) 0.4643(19) 0.3269(19) 0.013(6) Uiso 0.5 1 d D . P A 2
C12 C 0.226(2) 0.461(2) 0.331(2) 0.032(8) Uiso 0.5 1 d D . P A 2
C13 C 0.171(2) 0.403(2) 0.295(2) 0.041(8) Uiso 0.5 1 d D . P A 2
C14 C 0.2920(18) 0.3649(18) 0.1967(18) 0.028(6) Uiso 0.5 1 d D . P A 2
C15 C 0.363(2) 0.411(2) 0.253(2) 0.017(7) Uiso 0.5 1 d D . P A 2
N7 N 0.2060(16) 0.3609(18) 0.220(2) 0.027(7) Uiso 0.5 1 d D . P A 2
O2 O 0.3593(19) 0.515(2) 0.5054(19) 0.020(6) Uani 0.5 1 d . . P A 1
C6 C 0.315(2) 0.459(2) 0.547(2) 0.033(9) Uiso 0.5 1 d D . P A 1
C7 C 0.2228(18) 0.4477(19) 0.536(2) 0.026(6) Uiso 0.5 1 d D . P A 1
C8 C 0.177(2) 0.411(2) 0.623(2) 0.049(9) Uiso 0.5 1 d D . P A 1
C9 C 0.320(2) 0.363(2) 0.692(2) 0.044(9) Uiso 0.5 1 d D . P A 1
C10 C 0.350(3) 0.416(3) 0.625(3) 0.046(13) Uiso 0.5 1 d D . P A 1
N6 N 0.2242(17) 0.3646(16) 0.6907(18) 0.027(6) Uiso 0.5 1 d D . P A 1
O5 O 0.448(2) 0.5619(16) 0.591(2) 0.029(7) Uani 0.5 1 d . U P A 2
C21 C 0.375(2) 0.597(3) 0.641(3) 0.033(11) Uiso 0.5 1 d D . P A 2
C22 C 0.376(4) 0.628(4) 0.729(4) 0.064(17) Uiso 0.5 1 d D . P A 2
C23 C 0.306(2) 0.654(2) 0.771(2) 0.035(10) Uiso 0.5 1 d D . P A 2
C24 C 0.224(2) 0.613(2) 0.649(2) 0.037(10) Uiso 0.5 1 d D . P A 2
C25 C 0.290(3) 0.577(2) 0.598(2) 0.026(9) Uiso 0.5 1 d D . P A 2
N9 N 0.2185(18) 0.6279(19) 0.7457(18) 0.026(7) Uiso 0.5 1 d D . P A 2
O6 O 0.0615(16) 0.3299(18) 0.3401(18) 0.044(7) Uiso 0.5 1 d D . P . .
N4 N 0.5 0.183(2) 0.6621(19) 0.029(6) Uani 1 2 d S T P A .
N2 N 0.5 -0.0219(7) 0.453(2) 0.026(4) Uani 1 2 d S TU P . .
N3 N 0.5 0.185(2) 0.213(2) 0.037(7) Uani 1 2 d S TU P A .
N1 N 0.5 0.3945(6) 0.439(2) 0.018(2) Uani 1 2 d S TU P A .
N5A N 0.289(3) 0.191(2) 0.469(3) 0.032(9) Uani 0.5 1 d . U P A .
C2 C 0.5 0.0488(8) 0.450(3) 0.020(3) Uani 1 2 d S TU P . .
C1 C 0.5 0.3151(8) 0.4551(17) 0.020(4) Uani 1 2 d S TU P . .
C4 C 0.5 0.189(2) 0.587(2) 0.018(6) Uani 1 2 d S TU P . .
C3 C 0.5 0.181(2) 0.299(3) 0.026(7) Uani 1 2 d S TU P . .
C5A C 0.360(2) 0.191(2) 0.459(3) 0.013(8) Uani 0.5 1 d . U P . .
C5B C 0.369(3) 0.182(2) 0.428(3) 0.021(9) Uani 0.5 1 d . U P . .
N5B N 0.288(3) 0.188(2) 0.406(2) 0.024(7) Uani 0.5 1 d . U P A .
O1 O 0.4071(4) 0.6847(4) 0.4623(8) 0.026(3) Uani 1 1 d D U . . .
O7 O 0.0753(11) 0.3255(10) 0.5385(11) 0.006(3) Uiso 0.5 1 d D . P . .
H17 H 0.279(12) 0.545(10) 0.333(11) 0.007 Uiso 0.5 1 d D U P B 1
H18 H 0.152(4) 0.607(10) 0.245(7) 0.007 Uiso 0.5 1 d D U P C 1
H20 H 0.439(3) 0.620(13) 0.114(5) 0.007 Uiso 0.5 1 d D U P D 1
H8N H 0.178(2) 0.645(15) 0.116(6) 0.007 Uiso 0.5 1 d D U P E 1
H13 H 0.108(5) 0.390(9) 0.308(9) 0.007 Uiso 0.5 1 d D U P F 2
H14 H 0.309(5) 0.354(12) 0.132(4) 0.007 Uiso 0.5 1 d D U P G 2
H15 H 0.418(3) 0.386(11) 0.234(12) 0.007 Uiso 0.5 1 d D U P H 2
H7 H 0.200(5) 0.460(10) 0.474(5) 0.007 Uiso 0.5 1 d D U P I 1
H10 H 0.412(4) 0.424(12) 0.634(14) 0.007 Uiso 0.5 1 d D U P J 1
H22 H 0.434(6) 0.649(11) 0.751(12) 0.007 Uiso 0.5 1 d D U P K 2
H23 H 0.311(15) 0.652(12) 0.838(3) 0.007 Uiso 0.5 1 d D U P L 2
H25 H 0.284(6) 0.571(11) 0.530(3) 0.007 Uiso 0.5 1 d D U P M 2
H9N H 0.180(4) 0.636(13) 0.799(6) 0.007 Uiso 0.5 1 d D U P N 2
H6B H 0.075(8) 0.377(7) 0.374(11) 0.007 Uiso 0.5 1 d D U P . .
H6A H 0 0.334(7) 0.328(8) 0.007 Uiso 1 2 d DS U P . .
H1A H 0.414(5) 0.720(5) 0.412(4) 0.007 Uiso 1 1 d D U . . .
H7A H 0.051(10) 0.319(10) 0.597(5) 0.007 Uiso 0.5 1 d D U P . .
H7B H 0.042(8) 0.366(8) 0.508(9) 0.007 Uiso 0.5 1 d D U P . .
H6N H 0.191(5) 0.361(8) 0.748(4) 0.007 Uiso 0.5 1 d D U P . .
H24 H 0.180(8) 0.574(9) 0.624(12) 0.007 Uiso 0.5 1 d D U P . .
H7N H 0.167(6) 0.316(7) 0.195(8) 0.007 Uiso 0.5 1 d D U P . .
H8 H 0.113(4) 0.406(11) 0.629(13) 0.007 Uiso 0.5 1 d D U P . .
H1B H 0.349(2) 0.676(5) 0.473(5) 0.007 Uiso 1 1 d D U . . .
H9 H 0.360(6) 0.331(9) 0.733(8) 0.007 Uiso 0.5 1 d D U P . .
H12 H 0.200(4) 0.493(9) 0.382(8) 0.007 Uiso 0.5 1 d D U P . .
H19 H 0.311(14) 0.681(9) 0.051(8) 0.007 Uiso 0.5 1 d D U P . .



#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O5 2.21(3) . ?
Dy1 O3 2.24(3) 2_655 ?
Dy1 O4 2.26(3) 2_655 ?
Dy1 O2 2.35(3) . ?
Dy1 O2 2.35(3) 2_655 ?
Dy1 O1 2.393(6) . ?
Dy1 N1 2.461(10) . ?
Rh1 C5B 1.95(4) 2_655 ?
Rh1 C1 1.966(12) . ?
Rh1 C4 2.00(3) . ?
Rh1 C3 2.05(4) . ?
Rh1 C2 2.076(12) . ?
Rh1 C5A 2.09(4) . ?
C16 C17 1.40(5) . ?
C16 C20 1.46(4) . ?
C17 C18 1.39(5) . ?
C17 C9 1.55(4) 3_564 ?
C18 N8 1.46(4) . ?
C18 C8 1.65(4) 3_564 ?
C18 H18 0.95(3) . ?
C19 C10 1.12(5) 3_564 ?
C19 N8 1.23(4) . ?
C19 C9 1.27(4) 3_564 ?
C19 C20 1.40(4) . ?
C19 C6 1.70(5) 3_564 ?
N8 C8 1.28(4) 3_564 ?
N8 C9 1.43(4) 3_564 ?
O3 C11 1.32(4) . ?
C11 C12 1.41(4) . ?
C11 C15 1.46(4) . ?
C14 C24 1.26(4) 3_564 ?
C14 N9 1.30(4) 3_564 ?
C14 N7 1.32(3) . ?
C14 C22 1.34(6) 3_564 ?
C14 C15 1.50(4) . ?
C14 C21 1.56(4) 3_564 ?
C14 C25 1.65(4) 3_564 ?
C15 C23 1.32(5) 3_564 ?
C15 C21 1.59(5) 3_564 ?
C6 C10 1.37(5) . ?
C6 C7 1.39(4) . ?
C8 N8 1.28(4) 3_565 ?
C8 N6 1.38(3) . ?
C9 C20 1.15(5) 3_565 ?
C9 C19 1.27(4) 3_565 ?
C9 C10 1.32(5) . ?
C9 C16 1.40(4) 3_565 ?
C9 N6 1.42(3) . ?
C9 N8 1.43(4) 3_565 ?
C9 C17 1.55(4) 3_565 ?
O5 C21 1.40(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 O5 41.1(16) . 2_655 ?
O5 Dy1 O3 129.7(11) . 2_655 ?
O5 Dy1 O3 91.0(12) 2_655 2_655 ?
O5 Dy1 O3 91.0(12) . . ?
O5 Dy1 O3 129.7(11) 2_655 . ?
O3 Dy1 O3 124.8(17) 2_655 . ?
O4 Dy1 O4 35.6(14) 2_655 . ?
O4 Dy1 O2 130.9(10) 2_655 . ?
O4 Dy1 O2 96.4(10) . . ?
O4 Dy1 O2 96.4(10) 2_655 2_655 ?
O4 Dy1 O2 130.9(10) . 2_655 ?
O2 Dy1 O2 125.6(14) . 2_655 ?
O5 Dy1 O1 70.6(8) . . ?
O5 Dy1 O1 94.2(7) 2_655 . ?
O3 Dy1 O1 143.5(9) 2_655 . ?
O3 Dy1 O1 77.4(9) . . ?
O4 Dy1 O1 100.2(7) 2_655 . ?
O4 Dy1 O1 79.9(7) . . ?
O2 Dy1 O1 70.3(7) . . ?
O2 Dy1 O1 133.6(8) 2_655 . ?
O5 Dy1 O1 94.2(7) . 2_655 ?
O5 Dy1 O1 70.6(8) 2_655 2_655 ?
O3 Dy1 O1 77.4(9) 2_655 2_655 ?
O3 Dy1 O1 143.5(9) . 2_655 ?
O4 Dy1 O1 79.9(7) 2_655 2_655 ?
O4 Dy1 O1 100.2(7) . 2_655 ?
O2 Dy1 O1 133.6(8) . 2_655 ?
O2 Dy1 O1 70.3(8) 2_655 2_655 ?
O1 Dy1 O1 70.5(3) . 2_655 ?
O5 Dy1 N1 93.4(10) . . ?
O5 Dy1 N1 93.4(10) 2_655 . ?
O3 Dy1 N1 71.1(9) 2_655 . ?
O3 Dy1 N1 71.1(9) . . ?
O4 Dy1 N1 95.8(10) 2_655 . ?
O4 Dy1 N1 95.8(10) . . ?
O2 Dy1 N1 75.0(8) . . ?
O2 Dy1 N1 75.0(8) 2_655 . ?
O1 Dy1 N1 144.3(2) . . ?
O1 Dy1 N1 144.3(2) 2_655 . ?
C5B Rh1 C5B 166(3) 2_655 . ?
C5B Rh1 C1 92.2(11) 2_655 . ?
C5B Rh1 C1 92.2(11) . . ?
C5B Rh1 C4 96.8(13) 2_655 . ?
C5B Rh1 C4 96.8(13) . . ?
C1 Rh1 C4 84.3(12) . . ?
C5B Rh1 C3 83.2(13) 2_655 . ?
C5B Rh1 C3 83.2(13) . . ?
C1 Rh1 C3 96.5(12) . . ?
C4 Rh1 C3 179.2(5) . . ?
C5B Rh1 C2 88.6(11) 2_655 . ?
C5B Rh1 C2 88.6(11) . . ?
C1 Rh1 C2 173.4(13) . . ?
C4 Rh1 C2 89.0(14) . . ?
C3 Rh1 C2 90.2(14) . . ?
C5B Rh1 C5A 178.8(18) 2_655 . ?
C5B Rh1 C5A 13.2(10) . . ?
C1 Rh1 C5A 87.2(10) . . ?
C4 Rh1 C5A 84.2(10) . . ?
C3 Rh1 C5A 95.9(10) . . ?
C2 Rh1 C5A 92.1(9) . . ?
C5B Rh1 C5A 13.2(10) 2_655 2_655 ?
C5B Rh1 C5A 178.8(18) . 2_655 ?
C1 Rh1 C5A 87.2(10) . 2_655 ?
C4 Rh1 C5A 84.2(10) . 2_655 ?
C3 Rh1 C5A 95.9(10) . 2_655 ?
C2 Rh1 C5A 92.1(9) . 2_655 ?
C5A Rh1 C5A 168(2) . 2_655 ?
C16 O4 O4 148.9(18) . 2_655 ?
C16 O4 Dy1 138(2) . . ?
O4 O4 Dy1 72.2(7) 2_655 . ?
O4 C16 C9 157(3) . 3_564 ?
O4 C16 C17 128(3) . . ?
C9 C16 C17 67(2) 3_564 . ?
O4 C16 C20 117(3) . . ?
C9 C16 C20 47(2) 3_564 . ?
C17 C16 C20 114(3) . . ?
O4 C16 C10 133(3) . 3_564 ?
C9 C16 C10 46(2) 3_564 3_564 ?
C17 C16 C10 96(2) . 3_564 ?
C18 C17 C16 126(3) . . ?
C18 C17 C9 73(2) . 3_564 ?
C16 C17 C9 56(2) . 3_564 ?
C16 C17 N6 105(2) . 3_564 ?
C9 C17 N6 49.1(15) 3_564 3_564 ?
C18 C17 H17 105(10) . . ?
C16 C17 H17 118(10) . . ?
C9 C17 H17 165(10) 3_564 . ?
N6 C17 H17 130(10) 3_564 . ?
N6 C18 C17 108(4) 3_564 . ?
C17 C18 N8 109(3) . . ?
N6 C18 C8 56(3) 3_564 3_564 ?
C17 C18 C8 140(3) . 3_564 ?
N8 C18 C8 47.8(18) . 3_564 ?
N6 C18 C9 53(3) 3_564 3_564 ?
C17 C18 C9 58(2) . 3_564 ?
N8 C18 C9 51.5(18) . 3_564 ?
C8 C18 C9 92(2) 3_564 3_564 ?
N6 C18 H18 103(5) 3_564 . ?
C17 C18 H18 137(7) . . ?
N8 C18 H18 108(4) . . ?
C8 C18 H18 81(8) 3_564 . ?
C9 C18 H18 153(8) 3_564 . ?
C10 C19 N8 114(3) 3_564 . ?
C10 C19 C9 66(3) 3_564 3_564 ?
N8 C19 C9 70(2) . 3_564 ?
N8 C19 C20 120(3) . . ?
C9 C19 C20 51(2) 3_564 . ?
C10 C19 C6 53(3) 3_564 3_564 ?
N8 C19 C6 110(3) . 3_564 ?
C9 C19 C6 113(3) 3_564 3_564 ?
C20 C19 C6 93(2) . 3_564 ?
C10 C19 N6 99(3) 3_564 3_564 ?
C9 C19 N6 53.2(17) 3_564 3_564 ?
C20 C19 N6 103(2) . 3_564 ?
C6 C19 N6 109(2) 3_564 3_564 ?
C10 C19 H19 134(10) 3_564 . ?
N8 C19 H19 112(10) . . ?
C9 C19 H19 141(10) 3_564 . ?
C20 C19 H19 116(10) . . ?
C6 C19 H19 103(10) 3_564 . ?
N6 C19 H19 127(10) 3_564 . ?
C10 C20 C9 76(3) 3_564 3_564 ?
C10 C20 C19 52(3) 3_564 . ?
C9 C20 C19 59(2) 3_564 . ?
C10 C20 C16 94(4) 3_564 . ?
C9 C20 C16 64(2) 3_564 . ?
C19 C20 C16 118(3) . . ?
C10 C20 H20 99(10) 3_564 . ?
C9 C20 H20 172(5) 3_564 . ?
C19 C20 H20 113(4) . . ?
C16 C20 H20 123(7) . . ?
N6 N8 C19 131(4) 3_564 . ?
N6 N8 C8 84(3) 3_564 3_564 ?
C19 N8 C8 116(3) . 3_564 ?
N6 N8 C9 76(3) 3_564 3_564 ?
C19 N8 C9 57(2) . 3_564 ?
C8 N8 C9 130(3) 3_564 3_564 ?
C19 N8 C18 124(3) . . ?
C8 N8 C18 74(2) 3_564 . ?
C9 N8 C18 75(2) 3_564 . ?
N6 N8 C10 103(3) 3_564 3_564 ?
C8 N8 C10 103(3) 3_564 3_564 ?
C18 N8 C10 94(2) . 3_564 ?
N6 N8 H8N 100(9) 3_564 . ?
C19 N8 H8N 125(5) . . ?
C9 N8 H8N 172(10) 3_564 . ?
C18 N8 H8N 99(10) . . ?
C10 N8 H8N 135(10) 3_564 . ?
C11 O3 Dy1 149(3) . . ?
O3 C11 C12 121(3) . . ?
O3 C11 C15 123(3) . . ?
C12 C11 C15 116(3) . . ?
O3 C11 C23 144(3) . 3_564 ?
C12 C11 C23 83(2) . 3_564 ?
C13 C12 C11 129(3) . . ?
C11 C12 N9 93(2) . 3_564 ?
C13 C12 H12 112(6) . . ?
C11 C12 H12 115(5) . . ?
N9 C12 H12 149(7) 3_564 . ?
N9 C13 C12 98(3) 3_564 . ?
C12 C13 N7 113(3) . . ?
N9 C13 H13 131(5) 3_564 . ?
C12 C13 H13 132(6) . . ?
N7 C13 H13 115(4) . . ?
C23 C14 C24 136(3) 3_564 3_564 ?
C23 C14 N9 71(2) 3_564 3_564 ?
C24 C14 N9 65(2) 3_564 3_564 ?
C23 C14 N7 86(3) 3_564 . ?
C24 C14 N7 50(2) 3_564 . ?
C23 C14 C22 61(3) 3_564 3_564 ?
C24 C14 C22 156(4) 3_564 3_564 ?
N9 C14 C22 127(3) 3_564 3_564 ?
N7 C14 C22 146(3) . 3_564 ?
C23 C14 C15 59(2) 3_564 . ?
C24 C14 C15 137(3) 3_564 . ?
N9 C14 C15 106(2) 3_564 . ?
N7 C14 C15 125(3) . . ?
C23 C14 C21 115(3) 3_564 3_564 ?
C24 C14 C21 106(3) 3_564 3_564 ?
N9 C14 C21 154(3) 3_564 3_564 ?
N7 C14 C21 154(3) . 3_564 ?
C22 C14 C21 54(3) 3_564 3_564 ?
C15 C14 C21 63(2) . 3_564 ?
C23 C14 C25 161(3) 3_564 3_564 ?
C24 C14 C25 53(2) 3_564 3_564 ?
N9 C14 C25 113(2) 3_564 3_564 ?
N7 C14 C25 102(3) . 3_564 ?
C22 C14 C25 105(3) 3_564 3_564 ?
C15 C14 C25 102(2) . 3_564 ?
C21 C14 C25 53(2) 3_564 3_564 ?
C23 C14 H14 144(10) 3_564 . ?
C24 C14 H14 76(7) 3_564 . ?
N9 C14 H14 138(5) 3_564 . ?
N7 C14 H14 119(5) . . ?
C22 C14 H14 95(6) 3_564 . ?
C15 C14 H14 114(6) . . ?
C21 C14 H14 52(7) 3_564 . ?
C25 C14 H14 45(10) 3_564 . ?
C22 C15 C23 69(6) 3_564 3_564 ?
C22 C15 C11 157(7) 3_564 . ?
C23 C15 C11 90(3) 3_564 . ?
C22 C15 C14 63(6) 3_564 . ?
C23 C15 C14 45.5(19) 3_564 . ?
C11 C15 C14 109(3) . . ?
C22 C15 C21 56(6) 3_564 3_564 ?
C23 C15 C21 101(3) 3_564 3_564 ?
C11 C15 C21 142(3) . 3_564 ?
C14 C15 C21 61(2) . 3_564 ?
C23 C15 H15 108(10) 3_564 . ?
C11 C15 H15 144(6) . . ?
C14 C15 H15 106(4) . . ?
C21 C15 H15 66(10) 3_564 . ?
N9 N7 C24 120(7) 3_564 3_564 ?
N9 N7 C14 77(5) 3_564 . ?
C24 N7 C14 62(2) 3_564 . ?
N9 N7 C13 48(5) 3_564 . ?
C24 N7 C13 129(3) 3_564 . ?
C14 N7 C13 123(3) . . ?
N9 N7 C23 47(5) 3_564 3_564 ?
C24 N7 C23 103(3) 3_564 3_564 ?
C13 N7 C23 94(3) . 3_564 ?
N9 N7 H7N 145(10) 3_564 . ?
C24 N7 H7N 95(8) 3_564 . ?
C14 N7 H7N 122(5) . . ?
C13 N7 H7N 113(3) . . ?
C23 N7 H7N 126(10) 3_564 . ?
C6 O2 Dy1 147(3) . . ?
O2 C6 C10 121(3) . . ?
O2 C6 C7 123(3) . . ?
C10 C6 C7 114(3) . . ?
O2 C6 C19 151(3) . 3_565 ?
C7 C6 C19 83(2) . 3_565 ?
C6 C7 C8 113(3) . . ?
C6 C7 H7 116(5) . . ?
C8 C7 H7 131(6) . . ?
N8 C8 C7 98(3) 3_565 . ?
N6 C8 C7 121(3) . . ?
N8 C8 C18 58(2) 3_565 3_565 ?
C7 C8 C18 130(3) . 3_565 ?
N8 C8 H8 127(10) 3_565 . ?
N6 C8 H8 114(10) . . ?
C7 C8 H8 123(10) . . ?
C18 C8 H8 104(10) 3_565 . ?
C20 C9 C19 71(2) 3_565 3_565 ?
C20 C9 C10 45(3) 3_565 . ?
C19 C9 C10 51(2) 3_565 . ?
C20 C9 C16 69(2) 3_565 3_565 ?
C19 C9 C16 133(3) 3_565 3_565 ?
C10 C9 C16 83(3) . 3_565 ?
C20 C9 N6 150(3) 3_565 . ?
C19 C9 N6 81(2) 3_565 . ?
C10 C9 N6 108(3) . . ?
C16 C9 N6 130(3) 3_565 . ?
C20 C9 N8 124(3) 3_565 3_565 ?
C19 C9 N8 54(2) 3_565 3_565 ?
C10 C9 N8 91(3) . 3_565 ?
C16 C9 N8 152(3) 3_565 3_565 ?
C20 C9 C17 124(3) 3_565 3_565 ?
C19 C9 C17 145(3) 3_565 3_565 ?
C10 C9 C17 113(3) . 3_565 ?
C16 C9 C17 56(2) 3_565 3_565 ?
N6 C9 C17 75(2) . 3_565 ?
N8 C9 C17 102(3) 3_565 3_565 ?
C20 C9 C18 153(3) 3_565 3_565 ?
C19 C9 C18 102(2) 3_565 3_565 ?
C10 C9 C18 109(3) . 3_565 ?
C16 C9 C18 103(2) 3_565 3_565 ?
N8 C9 C18 53.3(18) 3_565 3_565 ?
C17 C9 C18 49.1(18) 3_565 3_565 ?
C20 C9 H9 79(6) 3_565 . ?
C19 C9 H9 131(10) 3_565 . ?
C10 C9 H9 123(6) . . ?
C16 C9 H9 61(10) 3_565 . ?
N6 C9 H9 129(7) . . ?
N8 C9 H9 140(9) 3_565 . ?
C17 C9 H9 84(10) 3_565 . ?
C18 C9 H9 121(8) 3_565 . ?
C20 C10 C19 85(4) 3_565 3_565 ?
C20 C10 C9 58(3) 3_565 . ?
C19 C10 C9 63(3) 3_565 . ?
C20 C10 C6 151(5) 3_565 . ?
C19 C10 C6 86(3) 3_565 . ?
C9 C10 C6 137(4) . . ?
C20 C10 C16 54(3) 3_565 3_565 ?
C19 C10 C16 112(3) 3_565 3_565 ?
C9 C10 C16 50(2) . 3_565 ?
C6 C10 C16 154(4) . 3_565 ?
C20 C10 N8 97(4) 3_565 3_565 ?
C9 C10 N8 47(2) . 3_565 ?
C6 C10 N8 91(3) . 3_565 ?
C16 C10 N8 94(2) 3_565 3_565 ?
C20 C10 H10 57(10) 3_565 . ?
C19 C10 H10 133(10) 3_565 . ?
C9 C10 H10 108(10) . . ?
C6 C10 H10 114(10) . . ?
C16 C10 H10 68(10) 3_565 . ?
N8 C10 H10 153(10) 3_565 . ?
N8 N6 C18 153(5) 3_565 3_565 ?
N8 N6 C8 67(3) 3_565 . ?
C18 N6 C8 94(3) 3_565 . ?
N8 N6 C9 76(3) 3_565 . ?
C18 N6 C9 100(4) 3_565 . ?
C8 N6 C9 122(3) . . ?
C18 N6 C19 132(3) 3_565 3_565 ?
C8 N6 C19 84(2) . 3_565 ?
C9 N6 C19 45.8(18) . 3_565 ?
N8 N6 C17 130(4) 3_565 3_565 ?
C18 N6 C17 47(3) 3_565 3_565 ?
C8 N6 C17 126(2) . 3_565 ?
C9 N6 C17 55.6(19) . 3_565 ?
C19 N6 C17 97.9(19) 3_565 3_565 ?
N8 N6 H6N 156(9) 3_565 . ?
C18 N6 H6N 48(8) 3_565 . ?
C8 N6 H6N 110(4) . . ?
C9 N6 H6N 121(6) . . ?
C19 N6 H6N 165(5) 3_565 . ?
C17 N6 H6N 72(7) 3_565 . ?
C21 O5 O5 141(2) . 2_655 ?
C21 O5 Dy1 139(3) . . ?
O5 O5 Dy1 69.4(8) 2_655 . ?
C22 C21 O5 126(4) . . ?
C22 C21 C25 119(4) . . ?
O5 C21 C25 113(3) . . ?
C22 C21 C14 54(3) . 3_565 ?
O5 C21 C14 179(4) . 3_565 ?
C25 C21 C14 67(2) . 3_565 ?
O5 C21 C15 124(3) . 3_565 ?
C25 C21 C15 108(3) . 3_565 ?
C14 C21 C15 56.6(18) 3_565 3_565 ?
C15 C22 C23 79(6) 3_565 . ?
C15 C22 C21 98(7) 3_565 . ?
C23 C22 C21 122(5) . . ?
C15 C22 C14 88(7) 3_565 3_565 ?
C23 C22 C14 50(3) . 3_565 ?
C21 C22 C14 72(4) . 3_565 ?
C15 C22 H22 111(10) 3_565 . ?
C23 C22 H22 119(10) . . ?
C21 C22 H22 116(10) . . ?
C14 C22 H22 156(10) 3_565 . ?
C14 C23 C22 69(4) 3_565 . ?
C14 C23 C15 76(3) 3_565 3_565 ?
C14 C23 N9 61(2) 3_565 . ?
C22 C23 N9 124(4) . . ?
C15 C23 N9 110(3) 3_565 . ?
C14 C23 N7 52.3(19) 3_565 3_565 ?
C22 C23 N7 120(4) . 3_565 ?
C15 C23 N7 113(3) 3_565 3_565 ?
C14 C23 C11 99(3) 3_565 3_565 ?
C22 C23 C11 79(3) . 3_565 ?
C15 C23 C11 48(2) 3_565 3_565 ?
N9 C23 C11 87(2) . 3_565 ?
N7 C23 C11 99(2) 3_565 3_565 ?
C14 C23 H23 162(10) 3_565 . ?
C22 C23 H23 113(10) . . ?
C15 C23 H23 96(10) 3_565 . ?
N9 C23 H23 108(10) . . ?
N7 C23 H23 120(10) 3_565 . ?
C11 C23 H23 64(10) 3_565 . ?
N7 C24 C14 68(2) 3_565 3_565 ?
N7 C24 C25 144(4) 3_565 . ?
C14 C24 C25 79(3) 3_565 . ?
C14 C24 N9 59(2) 3_565 . ?
C25 C24 N9 130(3) . . ?
N7 C24 H24 114(10) 3_565 . ?
C14 C24 H24 157(10) 3_565 . ?
C25 C24 H24 93(10) . . ?
N9 C24 H24 116(10) . . ?
C24 C25 C21 109(3) . . ?
C24 C25 C14 49(2) . 3_565 ?
C21 C25 C14 61(2) . 3_565 ?
C24 C25 H25 120(9) . . ?
C21 C25 H25 121(5) . . ?
C14 C25 H25 152(10) 3_565 . ?
N7 N9 C13 115(7) 3_565 3_565 ?
N7 N9 C14 83(5) 3_565 3_565 ?
C13 N9 C14 156(3) 3_565 3_565 ?
C13 N9 C24 126(3) 3_565 . ?
C14 N9 C24 56(2) 3_565 . ?
N7 N9 C23 119(6) 3_565 . ?
C13 N9 C23 124(3) 3_565 . ?
C14 N9 C23 48(2) 3_565 . ?
C24 N9 C23 104(3) . . ?
N7 N9 C12 149(7) 3_565 3_565 ?
C13 N9 C12 45(2) 3_565 3_565 ?
C14 N9 C12 111(2) 3_565 3_565 ?
C24 N9 C12 122(2) . 3_565 ?
C23 N9 C12 89(2) . 3_565 ?
N7 N9 H9N 110(10) 3_565 . ?
C14 N9 H9N 156(5) 3_565 . ?
C24 N9 H9N 146(6) . . ?
C23 N9 H9N 109(4) . . ?
C12 N9 H9N 67(10) 3_565 . ?
H13 O6 H6B 58(10) . . ?
H13 O6 H6A 116(10) . . ?
H6B O6 H6A 106(4) . . ?
C1 N1 Dy1 168(2) . . ?
N5B N5A C5A 85(5) . . ?
N5B N5A C5B 66(5) . . ?
N2 C2 Rh1 180(4) . . ?
N1 C1 Rh1 165(2) . . ?
N4 C4 Rh1 174(3) . . ?
N3 C3 Rh1 175(3) . . ?
N5A C5A Rh1 177(3) . . ?
N5B C5A Rh1 139(3) . . ?
N5B C5B Rh1 171(4) . . ?
N5A C5B Rh1 147(4) . . ?
N5A N5B C5B 74(5) . . ?
N5A N5B C5A 53(4) . . ?
Dy1 O1 H1A 110(6) . . ?
Dy1 O1 H1B 118(5) . . ?
H1A O1 H1B 110(4) . . ?
H7A O7 H7B 107(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O4 O4 C16 C9 -46(10) 2_655 . . 3_564 ?
Dy1 O4 C16 C9 117(8) . . . 3_564 ?
O4 O4 C16 C17 -172(2) 2_655 . . . ?
Dy1 O4 C16 C17 -10(6) . . . . ?
O4 O4 C16 C20 -3(5) 2_655 . . . ?
Dy1 O4 C16 C20 159(2) . . . . ?
O4 O4 C16 C10 32(6) 2_655 . . 3_564 ?
Dy1 O4 C16 C10 -166(3) . . . 3_564 ?
O4 C16 C17 C18 -175(3) . . . . ?
C9 C16 C17 C18 25(4) 3_564 . . . ?
C20 C16 C17 C18 15(5) . . . . ?
C10 C16 C17 C18 -12(4) 3_564 . . . ?
O4 C16 C17 C9 160(4) . . . 3_564 ?
C20 C16 C17 C9 -9(2) . . . 3_564 ?
C10 C16 C17 C9 -37(2) 3_564 . . 3_564 ?
O4 C16 C17 N6 170(3) . . . 3_564 ?
C9 C16 C17 N6 10(2) 3_564 . . 3_564 ?
C20 C16 C17 N6 1(3) . . . 3_564 ?
C10 C16 C17 N6 -27(3) 3_564 . . 3_564 ?
C16 C17 C18 N6 -36(5) . . . 3_564 ?
C9 C17 C18 N6 -14(4) 3_564 . . 3_564 ?
C16 C17 C18 N8 -23(5) . . . . ?
C9 C17 C18 N8 -1(3) 3_564 . . . ?
N6 C17 C18 N8 13(2) 3_564 . . . ?
C16 C17 C18 C8 23(7) . . . 3_564 ?
C9 C17 C18 C8 45(5) 3_564 . . 3_564 ?
N6 C17 C18 C8 59(4) 3_564 . . 3_564 ?
C16 C17 C18 C9 -21(3) . . . 3_564 ?
N6 C17 C18 C9 14(4) 3_564 . . 3_564 ?
N8 C19 C20 C10 93(5) . . . 3_564 ?
C9 C19 C20 C10 97(4) 3_564 . . 3_564 ?
C6 C19 C20 C10 -22(4) 3_564 . . 3_564 ?
N6 C19 C20 C10 89(4) 3_564 . . 3_564 ?
C10 C19 C20 C9 -97(4) 3_564 . . 3_564 ?
N8 C19 C20 C9 -4(3) . . . 3_564 ?
C6 C19 C20 C9 -119(3) 3_564 . . 3_564 ?
N6 C19 C20 C9 -8(3) 3_564 . . 3_564 ?
C10 C19 C20 C16 -72(4) 3_564 . . . ?
N8 C19 C20 C16 21(5) . . . . ?
C9 C19 C20 C16 25(3) 3_564 . . . ?
C6 C19 C20 C16 -94(3) 3_564 . . . ?
N6 C19 C20 C16 16(3) 3_564 . . . ?
O4 C16 C20 C10 128(4) . . . 3_564 ?
C9 C16 C20 C10 -73(3) 3_564 . . 3_564 ?
C17 C16 C20 C10 -61(4) . . . 3_564 ?
O4 C16 C20 C9 -159(4) . . . 3_564 ?
C17 C16 C20 C9 12(3) . . . 3_564 ?
C10 C16 C20 C9 73(3) 3_564 . . 3_564 ?
O4 C16 C20 C19 177(3) . . . . ?
C9 C16 C20 C19 -24(3) 3_564 . . . ?
C17 C16 C20 C19 -12(4) . . . . ?
C10 C16 C20 C19 49(3) 3_564 . . . ?
C10 C19 N8 N6 33(7) 3_564 . . 3_564 ?
C9 C19 N8 N6 -18(6) 3_564 . . 3_564 ?
C20 C19 N8 N6 -15(7) . . . 3_564 ?
C6 C19 N8 N6 90(6) 3_564 . . 3_564 ?
C10 C19 N8 C8 -72(4) 3_564 . . 3_564 ?
C9 C19 N8 C8 -123(3) 3_564 . . 3_564 ?
C20 C19 N8 C8 -120(4) . . . 3_564 ?
C6 C19 N8 C8 -14(4) 3_564 . . 3_564 ?
N6 C19 N8 C8 -104(6) 3_564 . . 3_564 ?
C10 C19 N8 C9 51(3) 3_564 . . 3_564 ?
C20 C19 N8 C9 3(3) . . . 3_564 ?
C6 C19 N8 C9 109(3) 3_564 . . 3_564 ?
N6 C19 N8 C9 18(6) 3_564 . . 3_564 ?
C10 C19 N8 C18 16(5) 3_564 . . . ?
C9 C19 N8 C18 -35(4) 3_564 . . . ?
C20 C19 N8 C18 -32(5) . . . . ?
C6 C19 N8 C18 73(4) 3_564 . . . ?
N6 C19 N8 C18 -17(4) 3_564 . . . ?
C9 C19 N8 C10 -51(3) 3_564 . . 3_564 ?
C20 C19 N8 C10 -48(3) . . . 3_564 ?
C6 C19 N8 C10 58(3) 3_564 . . 3_564 ?
N6 C19 N8 C10 -33(7) 3_564 . . 3_564 ?
C17 C18 N8 N6 -89(12) . . . 3_564 ?
C8 C18 N8 N6 129(12) 3_564 . . 3_564 ?
C9 C18 N8 N6 -90(11) 3_564 . . 3_564 ?
N6 C18 N8 C19 120(12) 3_564 . . . ?
C17 C18 N8 C19 31(4) . . . . ?
C8 C18 N8 C19 -110(4) 3_564 . . . ?
C9 C18 N8 C19 30(3) 3_564 . . . ?
N6 C18 N8 C8 -129(12) 3_564 . . 3_564 ?
C17 C18 N8 C8 142(3) . . . 3_564 ?
C9 C18 N8 C8 140(3) 3_564 . . 3_564 ?
N6 C18 N8 C9 90(11) 3_564 . . 3_564 ?
C17 C18 N8 C9 1(3) . . . 3_564 ?
C8 C18 N8 C9 -140(3) 3_564 . . 3_564 ?
N6 C18 N8 C10 128(12) 3_564 . . 3_564 ?
C17 C18 N8 C10 39(3) . . . 3_564 ?
C8 C18 N8 C10 -102(2) 3_564 . . 3_564 ?
C9 C18 N8 C10 38.1(19) 3_564 . . 3_564 ?
Dy1 O3 C11 C12 -180(4) . . . . ?
Dy1 O3 C11 C15 4(7) . . . . ?
Dy1 O3 C11 C23 57(7) . . . 3_564 ?
O3 C11 C12 C13 -159(4) . . . . ?
C15 C11 C12 C13 17(5) . . . . ?
C23 C11 C12 C13 -9(4) 3_564 . . . ?
O3 C11 C12 N9 -168(3) . . . 3_564 ?
C15 C11 C12 N9 8(3) . . . 3_564 ?
C23 C11 C12 N9 -18.0(18) 3_564 . . 3_564 ?
C11 C12 C13 N9 -15(5) . . . 3_564 ?
C11 C12 C13 N7 -24(5) . . . . ?
N9 C12 C13 N7 -9(2) 3_564 . . . ?
O3 C11 C15 C22 111(18) . . . 3_564 ?
C12 C11 C15 C22 -65(18) . . . 3_564 ?
C23 C11 C15 C22 -24(17) 3_564 . . 3_564 ?
O3 C11 C15 C23 136(3) . . . 3_564 ?
C12 C11 C15 C23 -41(3) . . . 3_564 ?
O3 C11 C15 C14 178(3) . . . . ?
C12 C11 C15 C14 2(4) . . . . ?
C23 C11 C15 C14 42(2) 3_564 . . . ?
O3 C11 C15 C21 -115(5) . . . 3_564 ?
C12 C11 C15 C21 68(5) . . . 3_564 ?
C23 C11 C15 C21 109(5) 3_564 . . 3_564 ?
C23 C14 C15 C22 87(6) 3_564 . . 3_564 ?
C24 C14 C15 C22 -147(7) 3_564 . . 3_564 ?
N9 C14 C15 C22 142(6) 3_564 . . 3_564 ?
N7 C14 C15 C22 145(6) . . . 3_564 ?
C21 C14 C15 C22 -64(6) 3_564 . . 3_564 ?
C25 C14 C15 C22 -100(6) 3_564 . . 3_564 ?
C24 C14 C15 C23 126(5) 3_564 . . 3_564 ?
N9 C14 C15 C23 56(3) 3_564 . . 3_564 ?
N7 C14 C15 C23 59(3) . . . 3_564 ?
C22 C14 C15 C23 -87(6) 3_564 . . 3_564 ?
C21 C14 C15 C23 -150(4) 3_564 . . 3_564 ?
C25 C14 C15 C23 174(3) 3_564 . . 3_564 ?
C23 C14 C15 C11 -70(3) 3_564 . . . ?
C24 C14 C15 C11 56(5) 3_564 . . . ?
N9 C14 C15 C11 -15(3) 3_564 . . . ?
N7 C14 C15 C11 -11(4) . . . . ?
C22 C14 C15 C11 -157(7) 3_564 . . . ?
C21 C14 C15 C11 140(3) 3_564 . . . ?
C25 C14 C15 C11 104(3) 3_564 . . . ?
C23 C14 C15 C21 150(4) 3_564 . . 3_564 ?
C24 C14 C15 C21 -84(4) 3_564 . . 3_564 ?
N9 C14 C15 C21 -154(3) 3_564 . . 3_564 ?
N7 C14 C15 C21 -151(4) . . . 3_564 ?
C22 C14 C15 C21 64(6) 3_564 . . 3_564 ?
C25 C14 C15 C21 -36(3) 3_564 . . 3_564 ?
C23 C14 N7 N9 38(6) 3_564 . . 3_564 ?
C24 C14 N7 N9 -135(7) 3_564 . . 3_564 ?
C22 C14 N7 N9 18(9) 3_564 . . 3_564 ?
C15 C14 N7 N9 -10(7) . . . 3_564 ?
C21 C14 N7 N9 -109(8) 3_564 . . 3_564 ?
C25 C14 N7 N9 -125(6) 3_564 . . 3_564 ?
C23 C14 N7 C24 172(4) 3_564 . . 3_564 ?
N9 C14 N7 C24 135(7) 3_564 . . 3_564 ?
C22 C14 N7 C24 153(6) 3_564 . . 3_564 ?
C15 C14 N7 C24 125(4) . . . 3_564 ?
C21 C14 N7 C24 25(7) 3_564 . . 3_564 ?
C25 C14 N7 C24 10(3) 3_564 . . 3_564 ?
C23 C14 N7 C13 52(4) 3_564 . . . ?
C24 C14 N7 C13 -120(4) 3_564 . . . ?
N9 C14 N7 C13 14(5) 3_564 . . . ?
C22 C14 N7 C13 33(7) 3_564 . . . ?
C15 C14 N7 C13 5(5) . . . . ?
C21 C14 N7 C13 -95(7) 3_564 . . . ?
C25 C14 N7 C13 -111(3) 3_564 . . . ?
C24 C14 N7 C23 -172(4) 3_564 . . 3_564 ?
N9 C14 N7 C23 -38(6) 3_564 . . 3_564 ?
C22 C14 N7 C23 -19(5) 3_564 . . 3_564 ?
C15 C14 N7 C23 -47(3) . . . 3_564 ?
C21 C14 N7 C23 -147(7) 3_564 . . 3_564 ?
C25 C14 N7 C23 -162(3) 3_564 . . 3_564 ?
C12 C13 N7 N9 31(8) . . . 3_564 ?
N9 C13 N7 C24 -98(9) 3_564 . . 3_564 ?
C12 C13 N7 C24 -67(5) . . . 3_564 ?
N9 C13 N7 C14 -19(7) 3_564 . . . ?
C12 C13 N7 C14 12(5) . . . . ?
N9 C13 N7 C23 12(7) 3_564 . . 3_564 ?
C12 C13 N7 C23 44(3) . . . 3_564 ?
Dy1 O2 C6 C10 44(7) . . . . ?
Dy1 O2 C6 C7 -152(3) . . . . ?
Dy1 O2 C6 C19 1(10) . . . 3_565 ?
O2 C6 C7 C8 -151(3) . . . . ?
C10 C6 C7 C8 14(4) . . . . ?
C19 C6 C7 C8 42(3) 3_565 . . . ?
C6 C7 C8 N8 -42(4) . . . 3_565 ?
C6 C7 C8 N6 -22(4) . . . . ?
C6 C7 C8 C18 13(5) . . . 3_565 ?
C19 C9 C10 C20 -101(4) 3_565 . . 3_565 ?
C16 C9 C10 C20 67(3) 3_565 . . 3_565 ?
N6 C9 C10 C20 -163(4) . . . 3_565 ?
N8 C9 C10 C20 -140(4) 3_565 . . 3_565 ?
C17 C9 C10 C20 116(4) 3_565 . . 3_565 ?
C18 C9 C10 C20 168(3) 3_565 . . 3_565 ?
C20 C9 C10 C19 101(4) 3_565 . . 3_565 ?
C16 C9 C10 C19 168(3) 3_565 . . 3_565 ?
N6 C9 C10 C19 -61(3) . . . 3_565 ?
N8 C9 C10 C19 -39(3) 3_565 . . 3_565 ?
C17 C9 C10 C19 -143(3) 3_565 . . 3_565 ?
C18 C9 C10 C19 -90(3) 3_565 . . 3_565 ?
C20 C9 C10 C6 148(7) 3_565 . . . ?
C19 C9 C10 C6 47(5) 3_565 . . . ?
C16 C9 C10 C6 -145(6) 3_565 . . . ?
N6 C9 C10 C6 -15(7) . . . . ?
N8 C9 C10 C6 8(6) 3_565 . . . ?
C17 C9 C10 C6 -96(6) 3_565 . . . ?
C18 C9 C10 C6 -43(7) 3_565 . . . ?
C20 C9 C10 C16 -67(3) 3_565 . . 3_565 ?
C19 C9 C10 C16 -168(3) 3_565 . . 3_565 ?
N6 C9 C10 C16 130(3) . . . 3_565 ?
N8 C9 C10 C16 153(3) 3_565 . . 3_565 ?
C17 C9 C10 C16 49(3) 3_565 . . 3_565 ?
C18 C9 C10 C16 101(3) 3_565 . . 3_565 ?
C20 C9 C10 N8 140(4) 3_565 . . 3_565 ?
C19 C9 C10 N8 39(3) 3_565 . . 3_565 ?
C16 C9 C10 N8 -153(3) 3_565 . . 3_565 ?
N6 C9 C10 N8 -22.7(17) . . . 3_565 ?
C17 C9 C10 N8 -104(3) 3_565 . . 3_565 ?
C18 C9 C10 N8 -51(2) 3_565 . . 3_565 ?
O2 C6 C10 C20 -79(11) . . . 3_565 ?
C7 C6 C10 C20 116(10) . . . 3_565 ?
C19 C6 C10 C20 71(10) 3_565 . . 3_565 ?
O2 C6 C10 C19 -150(4) . . . 3_565 ?
C7 C6 C10 C19 45(4) . . . 3_565 ?
O2 C6 C10 C9 170(5) . . . . ?
C7 C6 C10 C9 4(7) . . . . ?
C19 C6 C10 C9 -40(5) 3_565 . . . ?
O2 C6 C10 C16 76(9) . . . 3_565 ?
C7 C6 C10 C16 -90(8) . . . 3_565 ?
C19 C6 C10 C16 -135(9) 3_565 . . 3_565 ?
O2 C6 C10 N8 176(3) . . . 3_565 ?
C7 C6 C10 N8 10(3) . . . 3_565 ?
C19 C6 C10 N8 -35(2) 3_565 . . 3_565 ?
C7 C8 N6 N8 -43(4) . . . 3_565 ?
C18 C8 N6 N8 -160(5) 3_565 . . 3_565 ?
N8 C8 N6 C18 160(5) 3_565 . . 3_565 ?
C7 C8 N6 C18 117(4) . . . 3_565 ?
N8 C8 N6 C9 55(4) 3_565 . . . ?
C7 C8 N6 C9 12(5) . . . . ?
C18 C8 N6 C9 -105(4) 3_565 . . . ?
N8 C8 N6 C19 28(3) 3_565 . . 3_565 ?
C7 C8 N6 C19 -15(3) . . . 3_565 ?
C18 C8 N6 C19 -132(3) 3_565 . . 3_565 ?
N8 C8 N6 C17 124(4) 3_565 . . 3_565 ?
C7 C8 N6 C17 81(4) . . . 3_565 ?
C18 C8 N6 C17 -36(3) 3_565 . . 3_565 ?
C20 C9 N6 N8 31(7) 3_565 . . 3_565 ?
C19 C9 N6 N8 12(3) 3_565 . . 3_565 ?
C10 C9 N6 N8 55(4) . . . 3_565 ?
C16 C9 N6 N8 152(5) 3_565 . . 3_565 ?
C17 C9 N6 N8 166(4) 3_565 . . 3_565 ?
C18 C9 N6 N8 152(5) 3_565 . . 3_565 ?
C20 C9 N6 C18 -121(7) 3_565 . . 3_565 ?
C19 C9 N6 C18 -141(4) 3_565 . . 3_565 ?
C10 C9 N6 C18 -97(4) . . . 3_565 ?
C16 C9 N6 C18 0(5) 3_565 . . 3_565 ?
N8 C9 N6 C18 -152(5) 3_565 . . 3_565 ?
C17 C9 N6 C18 13(3) 3_565 . . 3_565 ?
C20 C9 N6 C8 -20(8) 3_565 . . . ?
C19 C9 N6 C8 -39(4) 3_565 . . . ?
C10 C9 N6 C8 5(5) . . . . ?
C16 C9 N6 C8 101(4) 3_565 . . . ?
N8 C9 N6 C8 -51(3) 3_565 . . . ?
C17 C9 N6 C8 115(3) 3_565 . . . ?
C18 C9 N6 C8 102(4) 3_565 . . . ?
C20 C9 N6 C19 19(6) 3_565 . . 3_565 ?
C10 C9 N6 C19 44(3) . . . 3_565 ?
C16 C9 N6 C19 140(5) 3_565 . . 3_565 ?
N8 C9 N6 C19 -12(3) 3_565 . . 3_565 ?
C17 C9 N6 C19 154(3) 3_565 . . 3_565 ?
C18 C9 N6 C19 141(4) 3_565 . . 3_565 ?
C20 C9 N6 C17 -135(7) 3_565 . . 3_565 ?
C19 C9 N6 C17 -154(3) 3_565 . . 3_565 ?
C10 C9 N6 C17 -110(4) . . . 3_565 ?
C16 C9 N6 C17 -14(3) 3_565 . . 3_565 ?
N8 C9 N6 C17 -166(4) 3_565 . . 3_565 ?
C18 C9 N6 C17 -13(3) 3_565 . . 3_565 ?
O5 O5 C21 C22 -20(7) 2_655 . . . ?
Dy1 O5 C21 C22 -145(4) . . . . ?
O5 O5 C21 C25 174.8(19) 2_655 . . . ?
Dy1 O5 C21 C25 50(5) . . . . ?
O5 O5 C21 C15 -52(5) 2_655 . . 3_565 ?
Dy1 O5 C21 C15 -177(3) . . . 3_565 ?
O5 C21 C22 C15 -94(8) . . . 3_565 ?
C25 C21 C22 C15 70(8) . . . 3_565 ?
C14 C21 C22 C15 86(7) 3_565 . . 3_565 ?
O5 C21 C22 C23 -176(4) . . . . ?
C25 C21 C22 C23 -12(8) . . . . ?
C14 C21 C22 C23 3(4) 3_565 . . . ?
C15 C21 C22 C23 -82(8) 3_565 . . . ?
O5 C21 C22 C14 -179(5) . . . 3_565 ?
C25 C21 C22 C14 -15(5) . . . 3_565 ?
C15 C21 C22 C14 -86(7) 3_565 . . 3_565 ?
C15 C22 C23 C14 -97(6) 3_565 . . 3_565 ?
C21 C22 C23 C14 -4(5) . . . 3_565 ?
C21 C22 C23 C15 93(8) . . . 3_565 ?
C14 C22 C23 C15 97(6) 3_565 . . 3_565 ?
C15 C22 C23 N9 -71(7) 3_565 . . . ?
C21 C22 C23 N9 22(8) . . . . ?
C14 C22 C23 N9 26(4) 3_565 . . . ?
C15 C22 C23 N7 -86(6) 3_565 . . 3_565 ?
C21 C22 C23 N7 7(7) . . . 3_565 ?
C14 C22 C23 N7 11(3) 3_565 . . 3_565 ?
C15 C22 C23 C11 7(5) 3_565 . . 3_565 ?
C21 C22 C23 C11 101(5) . . . 3_565 ?
C14 C22 C23 C11 105(3) 3_565 . . 3_565 ?
N7 C24 C25 C21 -20(8) 3_565 . . . ?
C14 C24 C25 C21 -1(3) 3_565 . . . ?
N9 C24 C25 C21 -32(6) . . . . ?
N7 C24 C25 C14 -19(6) 3_565 . . 3_565 ?
N9 C24 C25 C14 -31(3) . . . 3_565 ?
C22 C21 C25 C24 14(6) . . . . ?
O5 C21 C25 C24 -180(3) . . . . ?
C14 C21 C25 C24 1(3) 3_565 . . . ?
C15 C21 C25 C24 40(4) 3_565 . . . ?
C22 C21 C25 C14 13(4) . . . 3_565 ?
O5 C21 C25 C14 180(4) . . . 3_565 ?
C15 C21 C25 C14 39(2) 3_565 . . 3_565 ?
C14 C24 N9 N7 120(8) 3_565 . . 3_565 ?
C25 C24 N9 N7 156(9) . . . 3_565 ?
N7 C24 N9 C13 89(8) 3_565 . . 3_565 ?
C14 C24 N9 C13 -151(4) 3_565 . . 3_565 ?
C25 C24 N9 C13 -115(5) . . . 3_565 ?
N7 C24 N9 C14 -120(8) 3_565 . . 3_565 ?
C25 C24 N9 C14 36(4) . . . 3_565 ?
N7 C24 N9 C23 -118(8) 3_565 . . . ?
C14 C24 N9 C23 2(3) 3_565 . . . ?
C25 C24 N9 C23 38(5) . . . . ?
N7 C24 N9 C12 144(9) 3_565 . . 3_565 ?
C14 C24 N9 C12 -96(3) 3_565 . . 3_565 ?
C25 C24 N9 C12 -60(5) . . . 3_565 ?
C14 C23 N9 N7 -47(7) 3_565 . . 3_565 ?
C22 C23 N9 N7 -75(9) . . . 3_565 ?
C15 C23 N9 N7 -107(8) 3_565 . . 3_565 ?
C11 C23 N9 N7 -149(7) 3_565 . . 3_565 ?
C14 C23 N9 C13 152(4) 3_565 . . 3_565 ?
C22 C23 N9 C13 124(5) . . . 3_565 ?
C15 C23 N9 C13 92(4) 3_565 . . 3_565 ?
N7 C23 N9 C13 -161(10) 3_565 . . 3_565 ?
C11 C23 N9 C13 49(4) 3_565 . . 3_565 ?
C22 C23 N9 C14 -28(4) . . . 3_565 ?
C15 C23 N9 C14 -60(3) 3_565 . . 3_565 ?
N7 C23 N9 C14 47(7) 3_565 . . 3_565 ?
C11 C23 N9 C14 -102(3) 3_565 . . 3_565 ?
C14 C23 N9 C24 -2(3) 3_565 . . . ?
C22 C23 N9 C24 -30(5) . . . . ?
C15 C23 N9 C24 -62(4) 3_565 . . . ?
N7 C23 N9 C24 45(7) 3_565 . . . ?
C11 C23 N9 C24 -105(3) 3_565 . . . ?
C14 C23 N9 C12 120(3) 3_565 . . 3_565 ?
C22 C23 N9 C12 92(5) . . . 3_565 ?
C15 C23 N9 C12 61(3) 3_565 . . 3_565 ?
N7 C23 N9 C12 167(8) 3_565 . . 3_565 ?
C11 C23 N9 C12 17.9(18) 3_565 . . 3_565 ?
Dy1 N1 C1 Rh1 180.000(14) . . . . ?
C5B N5A C5A N5B 15(10) . . . . ?
C5A N5A C5B N5B -163(11) . . . . ?
N5B N5A C5B Rh1 169(6) . . . . ?
C5A N5A C5B Rh1 5(7) . . . . ?
C5A N5A N5B C5B 5(4) . . . . ?
C5B N5A N5B C5A -5(4) . . . . ?
N5A C5B N5B C5A 12(8) . . . . ?
Rh1 C5A N5B N5A 176(5) . . . . ?
N5A C5A N5B C5B -166(10) . . . . ?
Rh1 C5A N5B C5B 11(5) . . . . ?


# END of CIF
_exptl_crystal_preparation       'Magnetic properties,Luminescent'
