# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_af1b
_database_code_depnum_ccdc_archive 'CCDC 1566146'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ag3.31 Cu1.69 Eu In'
_chemical_formula_weight         731.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Pnma

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   8.9113(7)
_cell_length_b                   5.3870(5)
_cell_length_c                   11.2599(8)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     540.53(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6985
_cell_measurement_theta_min      2.92
_cell_measurement_theta_max      31.87

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    8.984
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1266
_exptl_absorpt_coefficient_mu    33.701
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.002
_exptl_absorpt_correction_T_max  0.003
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            6985
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_sigmaI/netI    0.0206
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.92
_diffrn_reflns_theta_max         31.87
_reflns_number_total             975
_reflns_number_gt                841
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0157P)²+0.5904P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         975
_refine_ls_number_parameters     43
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0290
_refine_ls_R_factor_gt           0.0212
_refine_ls_wR_factor_ref         0.0391
_refine_ls_wR_factor_gt          0.0372
_refine_ls_goodness_of_fit_ref   1.080
_refine_ls_restrained_S_all      1.080
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.24249(3) 0.2500 0.56167(3) 0.01609(9) Uani 1 2 d S . .
In2 In 0.35377(4) 0.2500 0.85431(4) 0.01610(11) Uani 1 2 d S . .
Ag3 Ag 0.43432(5) 0.50473(8) 0.30621(3) 0.01710(16) Uani 0.386(5) 1 d P . .
Cu3 Cu 0.43432(5) 0.50473(8) 0.30621(3) 0.01710(16) Uani 0.614(5) 1 d P . .
Ag4 Ag 0.08734(5) 0.2500 0.01519(4) 0.01838(17) Uani 0.890(6) 2 d SP . .
Cu4 Cu 0.08734(5) 0.2500 0.01519(4) 0.01838(17) Uani 0.110(6) 2 d SP . .
Ag5 Ag 0.18552(5) 0.2500 0.25012(5) 0.01694(18) Uani 0.646(6) 2 d SP . .
Cu5 Cu 0.18552(5) 0.2500 0.25012(5) 0.01694(18) Uani 0.354(6) 2 d SP . .
Ag6 Ag 0.44279(5) 0.2500 0.09111(4) 0.02133(12) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Cu4 3.1351(4) 2_565 ?
Eu1 Ag4 3.1351(4) 2_565 ?
Eu1 Cu4 3.1351(4) 2 ?
Eu1 Ag4 3.1351(4) 2 ?
Eu1 Ag6 3.1766(4) 2 ?
Eu1 Ag6 3.1766(4) 2_565 ?
Eu1 Ag6 3.1768(6) 6_556 ?
Eu1 Cu4 3.1925(6) 6_656 ?
Eu1 Ag4 3.1925(6) 6_656 ?
Eu1 Cu3 3.4365(5) 2_565 ?
Eu1 Ag3 3.4365(5) 2_565 ?
Eu1 Cu3 3.4365(5) 8_656 ?
In2 Ag6 2.7818(6) 1_556 ?
In2 Cu3 2.9290(6) 3_646 ?
In2 Cu3 2.9290(6) 5_666 ?
In2 Ag3 2.9290(6) 3_646 ?
In2 Ag3 2.9290(6) 5_666 ?
In2 Cu3 2.9377(6) 8_656 ?
In2 Ag3 2.9377(6) 8_656 ?
In2 Ag3 2.9377(6) 2_565 ?
In2 Cu3 2.9377(6) 2_565 ?
In2 Cu5 2.9587(4) 2 ?
In2 Ag5 2.9587(4) 2 ?
In2 Cu5 2.9587(4) 2_565 ?
Ag3 Cu3 2.6425(9) 7_575 ?
Ag3 Ag3 2.6425(9) 7_575 ?
Ag3 Ag5 2.6828(6) . ?
Ag3 Cu5 2.7012(6) 6_656 ?
Ag3 Ag5 2.7012(6) 6_656 ?
Ag3 Cu4 2.7055(6) 2_565 ?
Ag3 Ag4 2.7055(6) 2_565 ?
Ag3 Cu3 2.7445(9) 7_565 ?
Ag3 Ag3 2.7445(9) 7_565 ?
Ag3 Ag6 2.7848(6) . ?
Ag3 Cu4 2.7905(6) 6_656 ?
Ag4 Cu3 2.7055(6) 8_655 ?
Ag4 Ag3 2.7055(6) 8_655 ?
Ag4 Cu3 2.7055(6) 2_564 ?
Ag4 Ag3 2.7055(6) 2_564 ?
Ag4 Ag5 2.7863(7) . ?
Ag4 Cu3 2.7905(6) 6_556 ?
Ag4 Ag3 2.7905(6) 6_556 ?
Ag4 Cu3 2.7905(6) 4_455 ?
Ag4 Ag3 2.7905(6) 4_455 ?
Ag4 In2 2.9864(6) 1_554 ?
Ag4 Cu4 3.1297(5) 5 ?
Ag5 Cu3 2.6828(6) 7_565 ?
Ag5 Ag3 2.6828(6) 7_565 ?
Ag5 Cu3 2.7012(6) 4_455 ?
Ag5 Ag3 2.7012(6) 4_455 ?
Ag5 Cu3 2.7012(6) 6_556 ?
Ag5 Ag3 2.7012(6) 6_556 ?
Ag5 Ag6 2.8062(7) 6_556 ?
Ag5 Ag6 2.9090(7) . ?
Ag6 In2 2.7818(6) 1_554 ?
Ag6 Cu3 2.7848(6) 7_565 ?
Ag6 Ag3 2.7848(6) 7_565 ?
Ag6 Cu5 2.8062(7) 6_656 ?
Ag6 Ag5 2.8062(7) 6_656 ?
Ag6 Eu1 3.1766(4) 2_554 ?
Ag6 Eu1 3.1766(4) 2_564 ?
Ag6 Eu1 3.1768(6) 6_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu4 Eu1 Ag4 0.000(16) 2_565 2_565 ?
Cu4 Eu1 Cu4 118.444(18) 2_565 2 ?
Ag4 Eu1 Cu4 118.444(18) 2_565 2 ?
Cu4 Eu1 Ag4 118.444(18) 2_565 2 ?
Ag4 Eu1 Ag4 118.444(18) 2_565 2 ?
Cu4 Eu1 Ag4 0.000(16) 2 2 ?
Cu4 Eu1 Ag6 175.809(15) 2_565 2 ?
Ag4 Eu1 Ag6 175.809(15) 2_565 2 ?
Cu4 Eu1 Ag6 62.636(12) 2 2 ?
Ag4 Eu1 Ag6 62.636(12) 2 2 ?
Cu4 Eu1 Ag6 62.636(12) 2_565 2_565 ?
Ag4 Eu1 Ag6 62.636(12) 2_565 2_565 ?
Cu4 Eu1 Ag6 175.809(15) 2 2_565 ?
Ag4 Eu1 Ag6 175.809(15) 2 2_565 ?
Ag6 Eu1 Ag6 115.970(17) 2 2_565 ?
Cu4 Eu1 Ag6 108.436(11) 2_565 6_556 ?
Ag4 Eu1 Ag6 108.436(11) 2_565 6_556 ?
Cu4 Eu1 Ag6 108.436(11) 2 6_556 ?
Ag4 Eu1 Ag6 108.436(11) 2 6_556 ?
Ag6 Eu1 Ag6 67.637(10) 2 6_556 ?
Ag6 Eu1 Ag6 67.637(10) 2_565 6_556 ?
Cu4 Eu1 Cu4 59.279(9) 2_565 6_656 ?
Ag4 Eu1 Cu4 59.279(9) 2_565 6_656 ?
Cu4 Eu1 Cu4 59.279(9) 2 6_656 ?
Ag4 Eu1 Cu4 59.279(9) 2 6_656 ?
Ag6 Eu1 Cu4 121.910(9) 2 6_656 ?
Ag6 Eu1 Cu4 121.910(9) 2_565 6_656 ?
Ag6 Eu1 Cu4 131.485(15) 6_556 6_656 ?
Cu4 Eu1 Ag4 59.279(9) 2_565 6_656 ?
Ag4 Eu1 Ag4 59.279(9) 2_565 6_656 ?
Cu4 Eu1 Ag4 59.279(9) 2 6_656 ?
Ag4 Eu1 Ag4 59.279(9) 2 6_656 ?
Ag6 Eu1 Ag4 121.910(9) 2 6_656 ?
Ag6 Eu1 Ag4 121.910(9) 2_565 6_656 ?
Ag6 Eu1 Ag4 131.485(15) 6_556 6_656 ?
Cu4 Eu1 Ag4 0.000(16) 6_656 6_656 ?
Cu4 Eu1 Cu3 91.445(12) 2_565 2_565 ?
Ag4 Eu1 Cu3 91.445(12) 2_565 2_565 ?
Cu4 Eu1 Cu3 133.304(13) 2 2_565 ?
Ag4 Eu1 Cu3 133.304(13) 2 2_565 ?
Ag6 Eu1 Cu3 90.235(13) 2 2_565 ?
Ag6 Eu1 Cu3 49.617(11) 2_565 2_565 ?
Ag6 Eu1 Cu3 92.776(13) 6_556 2_565 ?
Cu4 Eu1 Cu3 131.186(13) 6_656 2_565 ?
Ag4 Eu1 Cu3 131.186(13) 6_656 2_565 ?
Cu4 Eu1 Ag3 91.445(12) 2_565 2_565 ?
Ag4 Eu1 Ag3 91.445(12) 2_565 2_565 ?
Cu4 Eu1 Ag3 133.304(13) 2 2_565 ?
Ag4 Eu1 Ag3 133.304(13) 2 2_565 ?
Ag6 Eu1 Ag3 90.235(13) 2 2_565 ?
Ag6 Eu1 Ag3 49.617(11) 2_565 2_565 ?
Ag6 Eu1 Ag3 92.776(13) 6_556 2_565 ?
Cu4 Eu1 Ag3 131.186(13) 6_656 2_565 ?
Ag4 Eu1 Ag3 131.186(13) 6_656 2_565 ?
Cu3 Eu1 Ag3 0.000(12) 2_565 2_565 ?
Cu4 Eu1 Cu3 133.304(13) 2_565 8_656 ?
Ag4 Eu1 Cu3 133.304(13) 2_565 8_656 ?
Cu4 Eu1 Cu3 91.445(12) 2 8_656 ?
Ag4 Eu1 Cu3 91.445(12) 2 8_656 ?
Ag6 Eu1 Cu3 49.617(11) 2 8_656 ?
Ag6 Eu1 Cu3 90.235(13) 2_565 8_656 ?
Ag6 Eu1 Cu3 92.776(13) 6_556 8_656 ?
Cu4 Eu1 Cu3 131.186(13) 6_656 8_656 ?
Ag4 Eu1 Cu3 131.186(13) 6_656 8_656 ?
Cu3 Eu1 Cu3 45.223(16) 2_565 8_656 ?
Ag3 Eu1 Cu3 45.223(16) 2_565 8_656 ?
Ag6 In2 Cu3 114.056(17) 1_556 3_646 ?
Ag6 In2 Cu3 114.055(17) 1_556 5_666 ?
Cu3 In2 Cu3 53.629(19) 3_646 5_666 ?
Ag6 In2 Ag3 114.056(17) 1_556 3_646 ?
Cu3 In2 Ag3 0.00(2) 3_646 3_646 ?
Cu3 In2 Ag3 53.629(19) 5_666 3_646 ?
Ag6 In2 Ag3 114.055(17) 1_556 5_666 ?
Cu3 In2 Ag3 53.629(19) 3_646 5_666 ?
Cu3 In2 Ag3 0.000(12) 5_666 5_666 ?
Ag3 In2 Ag3 53.629(19) 3_646 5_666 ?
Ag6 In2 Cu3 115.210(17) 1_556 8_656 ?
Cu3 In2 Cu3 104.286(14) 3_646 8_656 ?
Cu3 In2 Cu3 130.734(16) 5_666 8_656 ?
Ag3 In2 Cu3 104.286(14) 3_646 8_656 ?
Ag3 In2 Cu3 130.734(16) 5_666 8_656 ?
Ag6 In2 Ag3 115.210(17) 1_556 8_656 ?
Cu3 In2 Ag3 104.286(14) 3_646 8_656 ?
Cu3 In2 Ag3 130.734(16) 5_666 8_656 ?
Ag3 In2 Ag3 104.286(14) 3_646 8_656 ?
Ag3 In2 Ag3 130.734(16) 5_666 8_656 ?
Cu3 In2 Ag3 0.00(2) 8_656 8_656 ?
Ag6 In2 Ag3 115.210(17) 1_556 2_565 ?
Cu3 In2 Ag3 130.734(16) 3_646 2_565 ?
Cu3 In2 Ag3 104.286(14) 5_666 2_565 ?
Ag3 In2 Ag3 130.734(16) 3_646 2_565 ?
Ag3 In2 Ag3 104.286(14) 5_666 2_565 ?
Cu3 In2 Ag3 53.458(19) 8_656 2_565 ?
Ag3 In2 Ag3 53.458(19) 8_656 2_565 ?
Ag6 In2 Cu3 115.210(17) 1_556 2_565 ?
Cu3 In2 Cu3 130.734(16) 3_646 2_565 ?
Cu3 In2 Cu3 104.286(14) 5_666 2_565 ?
Ag3 In2 Cu3 130.734(16) 3_646 2_565 ?
Ag3 In2 Cu3 104.286(14) 5_666 2_565 ?
Cu3 In2 Cu3 53.458(19) 8_656 2_565 ?
Ag3 In2 Cu3 53.458(19) 8_656 2_565 ?
Ag3 In2 Cu3 0.000(16) 2_565 2_565 ?
Ag6 In2 Cu5 114.444(12) 1_556 2 ?
Cu3 In2 Cu5 54.615(14) 3_646 2 ?
Cu3 In2 Cu5 104.021(18) 5_666 2 ?
Ag3 In2 Cu5 54.615(14) 3_646 2 ?
Ag3 In2 Cu5 104.021(18) 5_666 2 ?
Cu3 In2 Cu5 54.128(13) 8_656 2 ?
Ag3 In2 Cu5 54.128(13) 8_656 2 ?
Ag3 In2 Cu5 103.470(17) 2_565 2 ?
Cu3 In2 Cu5 103.470(17) 2_565 2 ?
Ag6 In2 Ag5 114.444(12) 1_556 2 ?
Cu3 In2 Ag5 54.615(14) 3_646 2 ?
Cu3 In2 Ag5 104.021(18) 5_666 2 ?
Ag3 In2 Ag5 54.615(14) 3_646 2 ?
Ag3 In2 Ag5 104.021(18) 5_666 2 ?
Cu3 In2 Ag5 54.128(13) 8_656 2 ?
Ag3 In2 Ag5 54.128(13) 8_656 2 ?
Ag3 In2 Ag5 103.470(17) 2_565 2 ?
Cu3 In2 Ag5 103.470(17) 2_565 2 ?
Cu5 In2 Ag5 0.000(19) 2 2 ?
Ag6 In2 Cu5 114.444(12) 1_556 2_565 ?
Cu3 In2 Cu5 104.021(18) 3_646 2_565 ?
Cu3 In2 Cu5 54.615(14) 5_666 2_565 ?
Ag3 In2 Cu5 104.021(18) 3_646 2_565 ?
Ag3 In2 Cu5 54.615(14) 5_666 2_565 ?
Cu3 In2 Cu5 103.470(17) 8_656 2_565 ?
Ag3 In2 Cu5 103.470(17) 8_656 2_565 ?
Ag3 In2 Cu5 54.128(13) 2_565 2_565 ?
Cu3 In2 Cu5 54.128(13) 2_565 2_565 ?
Cu5 In2 Cu5 131.11(2) 2 2_565 ?
Ag5 In2 Cu5 131.11(2) 2 2_565 ?
Cu3 Ag3 Ag3 0.00(2) 7_575 7_575 ?
Cu3 Ag3 Ag5 120.763(11) 7_575 . ?
Ag3 Ag3 Ag5 120.763(11) 7_575 . ?
Cu3 Ag3 Cu5 120.531(11) 7_575 6_656 ?
Ag3 Ag3 Cu5 120.531(11) 7_575 6_656 ?
Ag5 Ag3 Cu5 111.700(16) . 6_656 ?
Cu3 Ag3 Ag5 120.531(11) 7_575 6_656 ?
Ag3 Ag3 Ag5 120.531(11) 7_575 6_656 ?
Ag5 Ag3 Ag5 111.700(16) . 6_656 ?
Cu5 Ag3 Ag5 0.00(2) 6_656 6_656 ?
Cu3 Ag3 Cu4 60.767(11) 7_575 2_565 ?
Ag3 Ag3 Cu4 60.767(11) 7_575 2_565 ?
Ag5 Ag3 Cu4 113.30(2) . 2_565 ?
Cu5 Ag3 Cu4 120.76(2) 6_656 2_565 ?
Ag5 Ag3 Cu4 120.76(2) 6_656 2_565 ?
Cu3 Ag3 Ag4 60.767(11) 7_575 2_565 ?
Ag3 Ag3 Ag4 60.767(11) 7_575 2_565 ?
Ag5 Ag3 Ag4 113.30(2) . 2_565 ?
Cu5 Ag3 Ag4 120.76(2) 6_656 2_565 ?
Ag5 Ag3 Ag4 120.76(2) 6_656 2_565 ?
Cu4 Ag3 Ag4 0.00(2) 2_565 2_565 ?
Cu3 Ag3 Cu3 180.0 7_575 7_565 ?
Ag3 Ag3 Cu3 180.0 7_575 7_565 ?
Ag5 Ag3 Cu3 59.237(11) . 7_565 ?
Cu5 Ag3 Cu3 59.469(11) 6_656 7_565 ?
Ag5 Ag3 Cu3 59.469(11) 6_656 7_565 ?
Cu4 Ag3 Cu3 119.233(11) 2_565 7_565 ?
Ag4 Ag3 Cu3 119.233(11) 2_565 7_565 ?
Cu3 Ag3 Ag3 180.0 7_575 7_565 ?
Ag3 Ag3 Ag3 180.0 7_575 7_565 ?
Ag5 Ag3 Ag3 59.237(11) . 7_565 ?
Cu5 Ag3 Ag3 59.469(11) 6_656 7_565 ?
Ag5 Ag3 Ag3 59.469(11) 6_656 7_565 ?
Cu4 Ag3 Ag3 119.233(11) 2_565 7_565 ?
Ag4 Ag3 Ag3 119.233(11) 2_565 7_565 ?
Cu3 Ag3 Ag3 0.00(2) 7_565 7_565 ?
Cu3 Ag3 Ag6 119.522(10) 7_575 . ?
Ag3 Ag3 Ag6 119.522(10) 7_575 . ?
Ag5 Ag3 Ag6 64.256(16) . . ?
Cu5 Ag3 Ag6 61.507(16) 6_656 . ?
Ag5 Ag3 Ag6 61.507(16) 6_656 . ?
Cu4 Ag3 Ag6 177.46(2) 2_565 . ?
Ag4 Ag3 Ag6 177.46(2) 2_565 . ?
Cu3 Ag3 Ag6 60.478(10) 7_565 . ?
Ag3 Ag3 Ag6 60.478(10) 7_565 . ?
Cu3 Ag3 Cu4 119.456(10) 7_575 6_656 ?
Ag3 Ag3 Cu4 119.456(10) 7_575 6_656 ?
Ag5 Ag3 Cu4 108.781(19) . 6_656 ?
Cu5 Ag3 Cu4 60.952(17) 6_656 6_656 ?
Ag5 Ag3 Cu4 60.952(17) 6_656 6_656 ?
Cu4 Ag3 Cu4 69.403(13) 2_565 6_656 ?
Ag4 Ag3 Cu4 69.403(13) 2_565 6_656 ?
Cu3 Ag3 Cu4 60.544(10) 7_565 6_656 ?
Ag3 Ag3 Cu4 60.544(10) 7_565 6_656 ?
Ag6 Ag3 Cu4 111.792(18) . 6_656 ?
Cu3 Ag4 Ag3 0.000(8) 8_655 8_655 ?
Cu3 Ag4 Cu3 58.47(2) 8_655 2_564 ?
Ag3 Ag4 Cu3 58.47(2) 8_655 2_564 ?
Cu3 Ag4 Ag3 58.47(2) 8_655 2_564 ?
Ag3 Ag4 Ag3 58.47(2) 8_655 2_564 ?
Cu3 Ag4 Ag3 0.00(2) 2_564 2_564 ?
Cu3 Ag4 Ag5 148.008(14) 8_655 . ?
Ag3 Ag4 Ag5 148.008(14) 8_655 . ?
Cu3 Ag4 Ag5 148.008(14) 2_564 . ?
Ag3 Ag4 Ag5 148.008(14) 2_564 . ?
Cu3 Ag4 Cu3 146.315(19) 8_655 6_556 ?
Ag3 Ag4 Cu3 146.315(19) 8_655 6_556 ?
Cu3 Ag4 Cu3 110.597(13) 2_564 6_556 ?
Ag3 Ag4 Cu3 110.597(13) 2_564 6_556 ?
Ag5 Ag4 Cu3 57.941(15) . 6_556 ?
Cu3 Ag4 Ag3 146.315(19) 8_655 6_556 ?
Ag3 Ag4 Ag3 146.315(19) 8_655 6_556 ?
Cu3 Ag4 Ag3 110.597(13) 2_564 6_556 ?
Ag3 Ag4 Ag3 110.597(13) 2_564 6_556 ?
Ag5 Ag4 Ag3 57.941(15) . 6_556 ?
Cu3 Ag4 Ag3 0.000(18) 6_556 6_556 ?
Cu3 Ag4 Cu3 110.597(13) 8_655 4_455 ?
Ag3 Ag4 Cu3 110.597(13) 8_655 4_455 ?
Cu3 Ag4 Cu3 146.315(19) 2_564 4_455 ?
Ag3 Ag4 Cu3 146.315(19) 2_564 4_455 ?
Ag5 Ag4 Cu3 57.941(15) . 4_455 ?
Cu3 Ag4 Cu3 58.91(2) 6_556 4_455 ?
Ag3 Ag4 Cu3 58.91(2) 6_556 4_455 ?
Cu3 Ag4 Ag3 110.597(13) 8_655 4_455 ?
Ag3 Ag4 Ag3 110.597(13) 8_655 4_455 ?
Cu3 Ag4 Ag3 146.315(19) 2_564 4_455 ?
Ag3 Ag4 Ag3 146.315(19) 2_564 4_455 ?
Ag5 Ag4 Ag3 57.941(15) . 4_455 ?
Cu3 Ag4 Ag3 58.91(2) 6_556 4_455 ?
Ag3 Ag4 Ag3 58.91(2) 6_556 4_455 ?
Cu3 Ag4 Ag3 0.00(2) 4_455 4_455 ?
Cu3 Ag4 In2 61.911(14) 8_655 1_554 ?
Ag3 Ag4 In2 61.911(14) 8_655 1_554 ?
Cu3 Ag4 In2 61.911(14) 2_564 1_554 ?
Ag3 Ag4 In2 61.911(14) 2_564 1_554 ?
Ag5 Ag4 In2 109.04(2) . 1_554 ?
Cu3 Ag4 In2 145.654(14) 6_556 1_554 ?
Ag3 Ag4 In2 145.654(14) 6_556 1_554 ?
Cu3 Ag4 In2 145.654(14) 4_455 1_554 ?
Ag3 Ag4 In2 145.654(14) 4_455 1_554 ?
Cu3 Ag4 Cu4 56.578(15) 8_655 5 ?
Ag3 Ag4 Cu4 56.578(15) 8_655 5 ?
Cu3 Ag4 Cu4 106.85(2) 2_564 5 ?
Ag3 Ag4 Cu4 106.85(2) 2_564 5 ?
Ag5 Ag4 Cu4 105.065(18) . 5 ?
Cu3 Ag4 Cu4 105.01(2) 6_556 5 ?
Ag3 Ag4 Cu4 105.01(2) 6_556 5 ?
Cu3 Ag4 Cu4 54.020(15) 4_455 5 ?
Ag3 Ag4 Cu4 54.020(15) 4_455 5 ?
In2 Ag4 Cu4 109.216(17) 1_554 5 ?
Ag3 Ag5 Cu3 61.53(2) . 7_565 ?
Ag3 Ag5 Ag3 61.53(2) . 7_565 ?
Cu3 Ag5 Ag3 0.00(2) 7_565 7_565 ?
Ag3 Ag5 Cu3 179.759(16) . 4_455 ?
Cu3 Ag5 Cu3 118.705(18) 7_565 4_455 ?
Ag3 Ag5 Cu3 118.705(18) 7_565 4_455 ?
Ag3 Ag5 Ag3 179.759(16) . 4_455 ?
Cu3 Ag5 Ag3 118.705(18) 7_565 4_455 ?
Ag3 Ag5 Ag3 118.705(18) 7_565 4_455 ?
Cu3 Ag5 Ag3 0.00(2) 4_455 4_455 ?
Ag3 Ag5 Cu3 118.705(18) . 6_556 ?
Cu3 Ag5 Cu3 179.759(16) 7_565 6_556 ?
Ag3 Ag5 Cu3 179.759(16) 7_565 6_556 ?
Cu3 Ag5 Cu3 61.06(2) 4_455 6_556 ?
Ag3 Ag5 Cu3 61.06(2) 4_455 6_556 ?
Ag3 Ag5 Ag3 118.705(18) . 6_556 ?
Cu3 Ag5 Ag3 179.759(16) 7_565 6_556 ?
Ag3 Ag5 Ag3 179.759(16) 7_565 6_556 ?
Cu3 Ag5 Ag3 61.06(2) 4_455 6_556 ?
Ag3 Ag5 Ag3 61.06(2) 4_455 6_556 ?
Cu3 Ag5 Ag3 0.000(18) 6_556 6_556 ?
Ag3 Ag5 Ag4 118.881(19) . . ?
Cu3 Ag5 Ag4 118.881(19) 7_565 . ?
Ag3 Ag5 Ag4 118.881(19) 7_565 . ?
Cu3 Ag5 Ag4 61.107(15) 4_455 . ?
Ag3 Ag5 Ag4 61.107(15) 4_455 . ?
Cu3 Ag5 Ag4 61.107(15) 6_556 . ?
Ag3 Ag5 Ag4 61.107(15) 6_556 . ?
Ag3 Ag5 Ag6 119.15(2) . 6_556 ?
Cu3 Ag5 Ag6 119.15(2) 7_565 6_556 ?
Ag3 Ag5 Ag6 119.15(2) 7_565 6_556 ?
Cu3 Ag5 Ag6 60.714(15) 4_455 6_556 ?
Ag3 Ag5 Ag6 60.714(15) 4_455 6_556 ?
Cu3 Ag5 Ag6 60.714(15) 6_556 6_556 ?
Ag3 Ag5 Ag6 60.714(15) 6_556 6_556 ?
Ag4 Ag5 Ag6 111.27(2) . 6_556 ?
Ag3 Ag5 Ag6 59.573(15) . . ?
Cu3 Ag5 Ag6 59.573(15) 7_565 . ?
Ag3 Ag5 Ag6 59.573(15) 7_565 . ?
Cu3 Ag5 Ag6 120.570(19) 4_455 . ?
Ag3 Ag5 Ag6 120.570(19) 4_455 . ?
Cu3 Ag5 Ag6 120.570(19) 6_556 . ?
Ag3 Ag5 Ag6 120.570(19) 6_556 . ?
Ag4 Ag5 Ag6 70.312(18) . . ?
Ag6 Ag5 Ag6 178.42(2) 6_556 . ?
In2 Ag6 Ag3 145.679(14) 1_554 . ?
In2 Ag6 Cu3 145.679(14) 1_554 7_565 ?
Ag3 Ag6 Cu3 59.04(2) . 7_565 ?
In2 Ag6 Ag3 145.679(14) 1_554 7_565 ?
Ag3 Ag6 Ag3 59.04(2) . 7_565 ?
Cu3 Ag6 Ag3 0.00(2) 7_565 7_565 ?
In2 Ag6 Cu5 146.14(2) 1_554 6_656 ?
Ag3 Ag6 Cu5 57.779(15) . 6_656 ?
Cu3 Ag6 Cu5 57.779(15) 7_565 6_656 ?
Ag3 Ag6 Cu5 57.779(15) 7_565 6_656 ?
In2 Ag6 Ag5 146.14(2) 1_554 6_656 ?
Ag3 Ag6 Ag5 57.779(15) . 6_656 ?
Cu3 Ag6 Ag5 57.779(15) 7_565 6_656 ?
Ag3 Ag6 Ag5 57.779(15) 7_565 6_656 ?
Cu5 Ag6 Ag5 0.000(16) 6_656 6_656 ?
In2 Ag6 Ag5 111.42(2) 1_554 . ?
Ag3 Ag6 Ag5 56.171(14) . . ?
Cu3 Ag6 Ag5 56.171(14) 7_565 . ?
Ag3 Ag6 Ag5 56.171(14) 7_565 . ?
Cu5 Ag6 Ag5 102.437(15) 6_656 . ?
Ag5 Ag6 Ag5 102.437(15) 6_656 . ?
In2 Ag6 Eu1 75.628(11) 1_554 2_554 ?
Ag3 Ag6 Eu1 119.634(17) . 2_554 ?
Cu3 Ag6 Eu1 70.052(12) 7_565 2_554 ?
Ag3 Ag6 Eu1 70.052(12) 7_565 2_554 ?
Cu5 Ag6 Eu1 117.847(10) 6_656 2_554 ?
Ag5 Ag6 Eu1 117.847(10) 6_656 2_554 ?
Ag5 Ag6 Eu1 69.792(11) . 2_554 ?
In2 Ag6 Eu1 75.628(11) 1_554 2_564 ?
Ag3 Ag6 Eu1 70.051(12) . 2_564 ?
Cu3 Ag6 Eu1 119.634(17) 7_565 2_564 ?
Ag3 Ag6 Eu1 119.634(17) 7_565 2_564 ?
Cu5 Ag6 Eu1 117.847(10) 6_656 2_564 ?
Ag5 Ag6 Eu1 117.847(10) 6_656 2_564 ?
Ag5 Ag6 Eu1 69.792(11) . 2_564 ?
Eu1 Ag6 Eu1 115.970(17) 2_554 2_564 ?
In2 Ag6 Eu1 73.783(15) 1_554 6_656 ?
Ag3 Ag6 Eu1 119.589(17) . 6_656 ?
Cu3 Ag6 Eu1 119.589(17) 7_565 6_656 ?
Ag3 Ag6 Eu1 119.589(17) 7_565 6_656 ?
Cu5 Ag6 Eu1 72.361(17) 6_656 6_656 ?
Ag5 Ag6 Eu1 72.361(17) 6_656 6_656 ?
Ag5 Ag6 Eu1 174.80(2) . 6_656 ?
Eu1 Ag6 Eu1 112.363(10) 2_554 6_656 ?
Eu1 Ag6 Eu1 112.363(10) 2_564 6_656 ?

_diffrn_measured_fraction_theta_max 0.973
_diffrn_reflns_theta_full        31.87
_diffrn_measured_fraction_theta_full 0.973
_refine_diff_density_max         1.110
_refine_diff_density_min         -1.358
_refine_diff_density_rms         0.282
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_eucu4
_database_code_depnum_ccdc_archive 'CCDC 1566151'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Au3.94 Cu1.06 Eu In'
_chemical_formula_weight         1110.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Pnma

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   8.9764(3)
_cell_length_b                   5.4247(2)
_cell_length_c                   11.1792(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     544.36(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    6267
_cell_measurement_theta_min      2.91
_cell_measurement_theta_max      32.00

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    13.550
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1817
_exptl_absorpt_coefficient_mu    125.217
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.11
_exptl_absorpt_correction_T_max  0.13
_exptl_absorpt_process_details   'Blessing 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker CCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            6267
_diffrn_reflns_av_R_equivalents  0.0652
_diffrn_reflns_av_sigmaI/netI    0.0484
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.91
_diffrn_reflns_theta_max         32.00
_reflns_number_total             984
_reflns_number_gt                811
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0218P)²+1.5012P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00111(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         984
_refine_ls_number_parameters     43
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0455
_refine_ls_R_factor_gt           0.0329
_refine_ls_wR_factor_ref         0.0656
_refine_ls_wR_factor_gt          0.0621
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.24407(8) 0.2500 0.55974(7) 0.01009(19) Uani 1 2 d S . .
In2 In 0.35167(11) 0.2500 0.85438(9) 0.0079(2) Uani 1 2 d S . .
Au3 Au 0.43381(7) 0.51389(12) 0.30160(5) 0.0112(2) Uani 0.530(4) 1 d P . .
Cu3 Cu 0.43381(7) 0.51389(12) 0.30160(5) 0.0112(2) Uani 0.470(4) 1 d P . .
Au4 Au 0.08614(7) 0.2500 0.01616(5) 0.01206(17) Uani 1 2 d S . .
Au5 Au 0.18456(7) 0.2500 0.25637(6) 0.0123(2) Uani 0.883(5) 2 d SP . .
Cu5 Cu 0.18456(7) 0.2500 0.25637(6) 0.0123(2) Uani 0.117(5) 2 d SP . .
Au6 Au 0.43803(7) 0.2500 0.08543(5) 0.01413(18) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Au4 3.1491(5) 2_565 ?
Eu1 Au4 3.1491(5) 2 ?
Eu1 Au6 3.1798(5) 2 ?
Eu1 Au6 3.1798(5) 2_565 ?
Eu1 Au4 3.1856(9) 6_656 ?
Eu1 Au6 3.1907(10) 6_556 ?
Eu1 Cu3 3.3913(9) 2_565 ?
Eu1 Au3 3.3913(9) 2_565 ?
Eu1 Cu3 3.3913(9) 8_656 ?
Eu1 Au3 3.3913(9) 8_656 ?
Eu1 In2 3.4325(13) . ?
Eu1 Au5 3.4332(10) . ?
In2 Au6 2.6968(11) 1_556 ?
In2 Cu3 2.8964(11) 3_646 ?
In2 Cu3 2.8964(11) 5_666 ?
In2 Au3 2.8964(11) 3_646 ?
In2 Au3 2.8964(11) 5_666 ?
In2 Cu3 2.9250(11) 8_656 ?
In2 Au3 2.9250(11) 8_656 ?
In2 Au3 2.9250(11) 2_565 ?
In2 Cu3 2.9250(11) 2_565 ?
In2 Cu5 2.9433(5) 2 ?
In2 Au5 2.9433(5) 2 ?
In2 Cu5 2.9433(5) 2_565 ?
Au3 Cu3 2.5617(14) 7_575 ?
Au3 Au3 2.5617(14) 7_575 ?
Au3 Au5 2.7039(8) . ?
Au3 Au4 2.7250(8) 2_565 ?
Au3 Cu5 2.7451(8) 6_656 ?
Au3 Au5 2.7451(8) 6_656 ?
Au3 Au6 2.8091(8) . ?
Au3 Au4 2.8407(8) 6_656 ?
Au3 Au3 2.8630(14) 7_565 ?
Au3 Cu3 2.8630(14) 7_565 ?
Au3 In2 2.8964(11) 5_666 ?
Au4 Cu3 2.7250(8) 8_655 ?
Au4 Au3 2.7250(8) 8_655 ?
Au4 Cu3 2.7250(8) 2_564 ?
Au4 Au3 2.7250(8) 2_564 ?
Au4 Au5 2.8270(9) . ?
Au4 Cu3 2.8407(8) 6_556 ?
Au4 Au3 2.8407(8) 6_556 ?
Au4 Cu3 2.8407(8) 4_455 ?
Au4 Au3 2.8407(8) 4_455 ?
Au4 In2 2.9920(12) 1_554 ?
Au4 Au4 3.1431(6) 5 ?
Au5 Cu3 2.7039(8) 7_565 ?
Au5 Au3 2.7039(8) 7_565 ?
Au5 Cu3 2.7451(8) 4_455 ?
Au5 Au3 2.7451(8) 4_455 ?
Au5 Cu3 2.7451(8) 6_556 ?
Au5 Au3 2.7451(8) 6_556 ?
Au5 Au6 2.8328(9) 6_556 ?
Au5 In2 2.9433(5) 2_564 ?
Au5 In2 2.9433(5) 2_554 ?
Au6 In2 2.6968(11) 1_554 ?
Au6 Cu3 2.8091(8) 7_565 ?
Au6 Au3 2.8091(8) 7_565 ?
Au6 Cu5 2.8328(9) 6_656 ?
Au6 Au5 2.8328(9) 6_656 ?
Au6 Eu1 3.1798(5) 2_554 ?
Au6 Eu1 3.1798(5) 2_564 ?
Au6 Eu1 3.1907(10) 6_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au4 Eu1 Au4 118.93(3) 2_565 2 ?
Au4 Eu1 Au6 175.90(3) 2_565 2 ?
Au4 Eu1 Au6 61.841(14) 2 2 ?
Au4 Eu1 Au6 61.841(14) 2_565 2_565 ?
Au4 Eu1 Au6 175.90(3) 2 2_565 ?
Au6 Eu1 Au6 117.08(3) 2 2_565 ?
Au4 Eu1 Au4 59.489(15) 2_565 6_656 ?
Au4 Eu1 Au4 59.490(15) 2 6_656 ?
Au6 Eu1 Au4 121.301(15) 2 6_656 ?
Au6 Eu1 Au4 121.301(15) 2_565 6_656 ?
Au4 Eu1 Au6 109.755(18) 2_565 6_556 ?
Au4 Eu1 Au6 109.755(18) 2 6_556 ?
Au6 Eu1 Au6 66.630(17) 2 6_556 ?
Au6 Eu1 Au6 66.630(17) 2_565 6_556 ?
Au4 Eu1 Au6 133.98(3) 6_656 6_556 ?
Au4 Eu1 Cu3 91.486(17) 2_565 2_565 ?
Au4 Eu1 Cu3 132.57(2) 2 2_565 ?
Au6 Eu1 Cu3 90.47(2) 2 2_565 ?
Au6 Eu1 Cu3 50.491(17) 2_565 2_565 ?
Au4 Eu1 Cu3 131.77(3) 6_656 2_565 ?
Au6 Eu1 Cu3 90.01(2) 6_556 2_565 ?
Au4 Eu1 Au3 91.486(17) 2_565 2_565 ?
Au4 Eu1 Au3 132.57(2) 2 2_565 ?
Au6 Eu1 Au3 90.47(2) 2 2_565 ?
Au6 Eu1 Au3 50.491(17) 2_565 2_565 ?
Au4 Eu1 Au3 131.77(3) 6_656 2_565 ?
Au6 Eu1 Au3 90.01(2) 6_556 2_565 ?
Cu3 Eu1 Au3 0.000(18) 2_565 2_565 ?
Au4 Eu1 Cu3 132.57(2) 2_565 8_656 ?
Au4 Eu1 Cu3 91.486(17) 2 8_656 ?
Au6 Eu1 Cu3 50.491(17) 2 8_656 ?
Au6 Eu1 Cu3 90.47(2) 2_565 8_656 ?
Au4 Eu1 Cu3 131.77(3) 6_656 8_656 ?
Au6 Eu1 Cu3 90.01(2) 6_556 8_656 ?
Cu3 Eu1 Cu3 44.38(2) 2_565 8_656 ?
Au3 Eu1 Cu3 44.38(2) 2_565 8_656 ?
Au4 Eu1 Au3 132.57(2) 2_565 8_656 ?
Au4 Eu1 Au3 91.486(17) 2 8_656 ?
Au6 Eu1 Au3 50.491(17) 2 8_656 ?
Au6 Eu1 Au3 90.47(2) 2_565 8_656 ?
Au4 Eu1 Au3 131.77(3) 6_656 8_656 ?
Au6 Eu1 Au3 90.01(2) 6_556 8_656 ?
Cu3 Eu1 Au3 44.38(2) 2_565 8_656 ?
Au3 Eu1 Au3 44.38(2) 2_565 8_656 ?
Cu3 Eu1 Au3 0.00(3) 8_656 8_656 ?
Au4 Eu1 In2 90.70(2) 2_565 . ?
Au4 Eu1 In2 90.70(2) 2 . ?
Au6 Eu1 In2 93.32(2) 2 . ?
Au6 Eu1 In2 93.32(2) 2_565 . ?
Au4 Eu1 In2 89.10(3) 6_656 . ?
Au6 Eu1 In2 136.92(3) 6_556 . ?
Cu3 Eu1 In2 50.76(2) 2_565 . ?
Au3 Eu1 In2 50.76(2) 2_565 . ?
Cu3 Eu1 In2 50.76(2) 8_656 . ?
Au3 Eu1 In2 50.76(2) 8_656 . ?
Au4 Eu1 Au5 85.554(19) 2_565 . ?
Au4 Eu1 Au5 85.554(19) 2 . ?
Au6 Eu1 Au5 90.528(19) 2 . ?
Au6 Eu1 Au5 90.528(19) 2_565 . ?
Au4 Eu1 Au5 83.51(2) 6_656 . ?
Au6 Eu1 Au5 50.476(19) 6_556 . ?
Cu3 Eu1 Au5 135.59(2) 2_565 . ?
Au3 Eu1 Au5 135.59(2) 2_565 . ?
Cu3 Eu1 Au5 135.59(2) 8_656 . ?
Au3 Eu1 Au5 135.59(2) 8_656 . ?
In2 Eu1 Au5 172.61(3) . . ?
Au6 In2 Cu3 112.68(4) 1_556 3_646 ?
Au6 In2 Cu3 112.68(4) 1_556 5_666 ?
Cu3 In2 Cu3 52.49(3) 3_646 5_666 ?
Au6 In2 Au3 112.68(4) 1_556 3_646 ?
Cu3 In2 Au3 0.00(3) 3_646 3_646 ?
Cu3 In2 Au3 52.49(3) 5_666 3_646 ?
Au6 In2 Au3 112.68(4) 1_556 5_666 ?
Cu3 In2 Au3 52.49(3) 3_646 5_666 ?
Cu3 In2 Au3 0.000(18) 5_666 5_666 ?
Au3 In2 Au3 52.49(3) 3_646 5_666 ?
Au6 In2 Cu3 116.42(4) 1_556 8_656 ?
Cu3 In2 Cu3 105.51(3) 3_646 8_656 ?
Cu3 In2 Cu3 130.89(4) 5_666 8_656 ?
Au3 In2 Cu3 105.51(3) 3_646 8_656 ?
Au3 In2 Cu3 130.89(4) 5_666 8_656 ?
Au6 In2 Au3 116.42(4) 1_556 8_656 ?
Cu3 In2 Au3 105.51(3) 3_646 8_656 ?
Cu3 In2 Au3 130.89(4) 5_666 8_656 ?
Au3 In2 Au3 105.51(3) 3_646 8_656 ?
Au3 In2 Au3 130.89(4) 5_666 8_656 ?
Cu3 In2 Au3 0.00(2) 8_656 8_656 ?
Au6 In2 Au3 116.42(4) 1_556 2_565 ?
Cu3 In2 Au3 130.89(4) 3_646 2_565 ?
Cu3 In2 Au3 105.51(3) 5_666 2_565 ?
Au3 In2 Au3 130.89(4) 3_646 2_565 ?
Au3 In2 Au3 105.51(3) 5_666 2_565 ?
Cu3 In2 Au3 51.94(3) 8_656 2_565 ?
Au3 In2 Au3 51.94(3) 8_656 2_565 ?
Au6 In2 Cu3 116.42(4) 1_556 2_565 ?
Cu3 In2 Cu3 130.89(4) 3_646 2_565 ?
Cu3 In2 Cu3 105.51(3) 5_666 2_565 ?
Au3 In2 Cu3 130.89(4) 3_646 2_565 ?
Au3 In2 Cu3 105.51(3) 5_666 2_565 ?
Cu3 In2 Cu3 51.94(3) 8_656 2_565 ?
Au3 In2 Cu3 51.94(3) 8_656 2_565 ?
Au3 In2 Cu3 0.000(12) 2_565 2_565 ?
Au6 In2 Cu5 112.85(2) 1_556 2 ?
Cu3 In2 Cu5 56.07(2) 3_646 2 ?
Cu3 In2 Cu5 104.88(3) 5_666 2 ?
Au3 In2 Cu5 56.07(2) 3_646 2 ?
Au3 In2 Cu5 104.88(3) 5_666 2 ?
Cu3 In2 Cu5 54.87(2) 8_656 2 ?
Au3 In2 Cu5 54.87(2) 8_656 2 ?
Au3 In2 Cu5 103.39(3) 2_565 2 ?
Cu3 In2 Cu5 103.39(3) 2_565 2 ?
Au6 In2 Au5 112.85(2) 1_556 2 ?
Cu3 In2 Au5 56.07(2) 3_646 2 ?
Cu3 In2 Au5 104.88(3) 5_666 2 ?
Au3 In2 Au5 56.07(2) 3_646 2 ?
Au3 In2 Au5 104.88(3) 5_666 2 ?
Cu3 In2 Au5 54.87(2) 8_656 2 ?
Au3 In2 Au5 54.87(2) 8_656 2 ?
Au3 In2 Au5 103.39(3) 2_565 2 ?
Cu3 In2 Au5 103.39(3) 2_565 2 ?
Cu5 In2 Au5 0.00(2) 2 2 ?
Au6 In2 Cu5 112.85(2) 1_556 2_565 ?
Cu3 In2 Cu5 104.88(3) 3_646 2_565 ?
Cu3 In2 Cu5 56.07(2) 5_666 2_565 ?
Au3 In2 Cu5 104.88(3) 3_646 2_565 ?
Au3 In2 Cu5 56.07(2) 5_666 2_565 ?
Cu3 In2 Cu5 103.39(3) 8_656 2_565 ?
Au3 In2 Cu5 103.39(3) 8_656 2_565 ?
Au3 In2 Cu5 54.87(2) 2_565 2_565 ?
Cu3 In2 Cu5 54.87(2) 2_565 2_565 ?
Cu5 In2 Cu5 134.30(4) 2 2_565 ?
Au5 In2 Cu5 134.30(4) 2 2_565 ?
Cu3 Au3 Au3 0.00(4) 7_575 7_575 ?
Cu3 Au3 Au5 121.967(16) 7_575 . ?
Au3 Au3 Au5 121.967(16) 7_575 . ?
Cu3 Au3 Au4 61.964(15) 7_575 2_565 ?
Au3 Au3 Au4 61.964(15) 7_575 2_565 ?
Au5 Au3 Au4 111.04(3) . 2_565 ?
Cu3 Au3 Cu5 121.432(16) 7_575 6_656 ?
Au3 Au3 Cu5 121.432(16) 7_575 6_656 ?
Au5 Au3 Cu5 110.99(2) . 6_656 ?
Au4 Au3 Cu5 120.45(3) 2_565 6_656 ?
Cu3 Au3 Au5 121.432(16) 7_575 6_656 ?
Au3 Au3 Au5 121.432(16) 7_575 6_656 ?
Au5 Au3 Au5 110.99(2) . 6_656 ?
Au4 Au3 Au5 120.45(3) 2_565 6_656 ?
Cu5 Au3 Au5 0.00(3) 6_656 6_656 ?
Cu3 Au3 Au6 120.637(15) 7_575 . ?
Au3 Au3 Au6 120.637(15) 7_575 . ?
Au5 Au3 Au6 65.20(2) . . ?
Au4 Au3 Au6 176.08(3) 2_565 . ?
Cu5 Au3 Au6 61.32(2) 6_656 . ?
Au5 Au3 Au6 61.32(2) 6_656 . ?
Cu3 Au3 Au4 120.260(14) 7_575 6_656 ?
Au3 Au3 Au4 120.260(14) 7_575 6_656 ?
Au5 Au3 Au4 105.40(3) . 6_656 ?
Au4 Au3 Au4 68.730(17) 2_565 6_656 ?
Cu5 Au3 Au4 60.78(2) 6_656 6_656 ?
Au5 Au3 Au4 60.78(2) 6_656 6_656 ?
Au6 Au3 Au4 110.71(2) . 6_656 ?
Cu3 Au3 Au3 180.0 7_575 7_565 ?
Au3 Au3 Au3 180.0 7_575 7_565 ?
Au5 Au3 Au3 58.033(16) . 7_565 ?
Au4 Au3 Au3 118.036(15) 2_565 7_565 ?
Cu5 Au3 Au3 58.568(16) 6_656 7_565 ?
Au5 Au3 Au3 58.568(16) 6_656 7_565 ?
Au6 Au3 Au3 59.363(15) . 7_565 ?
Au4 Au3 Au3 59.740(14) 6_656 7_565 ?
Cu3 Au3 Cu3 180.0 7_575 7_565 ?
Au3 Au3 Cu3 180.0 7_575 7_565 ?
Au5 Au3 Cu3 58.033(16) . 7_565 ?
Au4 Au3 Cu3 118.036(15) 2_565 7_565 ?
Cu5 Au3 Cu3 58.568(16) 6_656 7_565 ?
Au5 Au3 Cu3 58.568(16) 6_656 7_565 ?
Au6 Au3 Cu3 59.363(15) . 7_565 ?
Au4 Au3 Cu3 59.740(14) 6_656 7_565 ?
Au3 Au3 Cu3 0.00(3) 7_565 7_565 ?
Cu3 Au3 In2 63.755(16) 7_575 5_666 ?
Au3 Au3 In2 63.755(16) 7_575 5_666 ?
Au5 Au3 In2 132.20(3) . 5_666 ?
Au4 Au3 In2 111.45(3) 2_565 5_666 ?
Cu5 Au3 In2 62.829(19) 6_656 5_666 ?
Au5 Au3 In2 62.829(19) 6_656 5_666 ?
Au6 Au3 In2 72.45(2) . 5_666 ?
Au4 Au3 In2 109.55(3) 6_656 5_666 ?
Au3 Au3 In2 116.245(15) 7_565 5_666 ?
Cu3 Au3 In2 116.245(15) 7_565 5_666 ?
Cu3 Au4 Au3 0.000(11) 8_655 8_655 ?
Cu3 Au4 Cu3 56.07(3) 8_655 2_564 ?
Au3 Au4 Cu3 56.07(3) 8_655 2_564 ?
Cu3 Au4 Au3 56.07(3) 8_655 2_564 ?
Au3 Au4 Au3 56.07(3) 8_655 2_564 ?
Cu3 Au4 Au3 0.00(4) 2_564 2_564 ?
Cu3 Au4 Au5 148.943(19) 8_655 . ?
Au3 Au4 Au5 148.943(19) 8_655 . ?
Cu3 Au4 Au5 148.943(19) 2_564 . ?
Au3 Au4 Au5 148.943(19) 2_564 . ?
Cu3 Au4 Cu3 146.77(2) 8_655 6_556 ?
Au3 Au4 Cu3 146.77(2) 8_655 6_556 ?
Cu3 Au4 Cu3 111.270(17) 2_564 6_556 ?
Au3 Au4 Cu3 111.270(17) 2_564 6_556 ?
Au5 Au4 Cu3 57.937(19) . 6_556 ?
Cu3 Au4 Au3 146.77(2) 8_655 6_556 ?
Au3 Au4 Au3 146.77(2) 8_655 6_556 ?
Cu3 Au4 Au3 111.270(17) 2_564 6_556 ?
Au3 Au4 Au3 111.270(17) 2_564 6_556 ?
Au5 Au4 Au3 57.937(19) . 6_556 ?
Cu3 Au4 Au3 0.00(3) 6_556 6_556 ?
Cu3 Au4 Cu3 111.270(17) 8_655 4_455 ?
Au3 Au4 Cu3 111.270(17) 8_655 4_455 ?
Cu3 Au4 Cu3 146.77(2) 2_564 4_455 ?
Au3 Au4 Cu3 146.77(2) 2_564 4_455 ?
Au5 Au4 Cu3 57.937(19) . 4_455 ?
Cu3 Au4 Cu3 60.52(3) 6_556 4_455 ?
Au3 Au4 Cu3 60.52(3) 6_556 4_455 ?
Cu3 Au4 Au3 111.270(17) 8_655 4_455 ?
Au3 Au4 Au3 111.270(17) 8_655 4_455 ?
Cu3 Au4 Au3 146.77(2) 2_564 4_455 ?
Au3 Au4 Au3 146.77(2) 2_564 4_455 ?
Au5 Au4 Au3 57.937(19) . 4_455 ?
Cu3 Au4 Au3 60.52(3) 6_556 4_455 ?
Au3 Au4 Au3 60.52(3) 6_556 4_455 ?
Cu3 Au4 Au3 0.00(3) 4_455 4_455 ?
Cu3 Au4 In2 61.33(2) 8_655 1_554 ?
Au3 Au4 In2 61.33(2) 8_655 1_554 ?
Cu3 Au4 In2 61.33(2) 2_564 1_554 ?
Au3 Au4 In2 61.33(2) 2_564 1_554 ?
Au5 Au4 In2 108.98(3) . 1_554 ?
Cu3 Au4 In2 144.78(2) 6_556 1_554 ?
Au3 Au4 In2 144.78(2) 6_556 1_554 ?
Cu3 Au4 In2 144.78(2) 4_455 1_554 ?
Au3 Au4 In2 144.78(2) 4_455 1_554 ?
Cu3 Au4 Au4 57.38(2) 8_655 5 ?
Au3 Au4 Au4 57.38(2) 8_655 5 ?
Cu3 Au4 Au4 105.79(3) 2_564 5 ?
Au3 Au4 Au4 105.79(3) 2_564 5 ?
Au5 Au4 Au4 105.24(2) . 5 ?
Cu3 Au4 Au4 106.29(3) 6_556 5 ?
Au3 Au4 Au4 106.29(3) 6_556 5 ?
Cu3 Au4 Au4 53.893(19) 4_455 5 ?
Au3 Au4 Au4 53.893(19) 4_455 5 ?
In2 Au4 Au4 108.81(2) 1_554 5 ?
Au3 Au5 Cu3 63.93(3) . 7_565 ?
Au3 Au5 Au3 63.93(3) . 7_565 ?
Cu3 Au5 Au3 0.00(3) 7_565 7_565 ?
Au3 Au5 Cu3 177.12(3) . 4_455 ?
Cu3 Au5 Cu3 116.52(2) 7_565 4_455 ?
Au3 Au5 Cu3 116.52(2) 7_565 4_455 ?
Au3 Au5 Au3 177.12(3) . 4_455 ?
Cu3 Au5 Au3 116.52(2) 7_565 4_455 ?
Au3 Au5 Au3 116.52(2) 7_565 4_455 ?
Cu3 Au5 Au3 0.00(3) 4_455 4_455 ?
Au3 Au5 Cu3 116.52(2) . 6_556 ?
Cu3 Au5 Cu3 177.12(3) 7_565 6_556 ?
Au3 Au5 Cu3 177.12(3) 7_565 6_556 ?
Cu3 Au5 Cu3 62.86(3) 4_455 6_556 ?
Au3 Au5 Cu3 62.86(3) 4_455 6_556 ?
Au3 Au5 Au3 116.52(2) . 6_556 ?
Cu3 Au5 Au3 177.12(3) 7_565 6_556 ?
Au3 Au5 Au3 177.12(3) 7_565 6_556 ?
Cu3 Au5 Au3 62.86(3) 4_455 6_556 ?
Au3 Au5 Au3 62.86(3) 4_455 6_556 ?
Cu3 Au5 Au3 0.000(14) 6_556 6_556 ?
Au3 Au5 Au4 115.86(3) . . ?
Cu3 Au5 Au4 115.86(3) 7_565 . ?
Au3 Au5 Au4 115.86(3) 7_565 . ?
Cu3 Au5 Au4 61.28(2) 4_455 . ?
Au3 Au5 Au4 61.28(2) 4_455 . ?
Cu3 Au5 Au4 61.28(2) 6_556 . ?
Au3 Au5 Au4 61.28(2) 6_556 . ?
Au3 Au5 Au6 121.98(2) . 6_556 ?
Cu3 Au5 Au6 121.98(2) 7_565 6_556 ?
Au3 Au5 Au6 121.98(2) 7_565 6_556 ?
Cu3 Au5 Au6 60.45(2) 4_455 6_556 ?
Au3 Au5 Au6 60.45(2) 4_455 6_556 ?
Cu3 Au5 Au6 60.45(2) 6_556 6_556 ?
Au3 Au5 Au6 60.45(2) 6_556 6_556 ?
Au4 Au5 Au6 110.42(3) . 6_556 ?
Au3 Au5 In2 62.22(2) . 2_564 ?
Cu3 Au5 In2 120.64(3) 7_565 2_564 ?
Au3 Au5 In2 120.64(3) 7_565 2_564 ?
Cu3 Au5 In2 118.55(3) 4_455 2_564 ?
Au3 Au5 In2 118.55(3) 4_455 2_564 ?
Cu3 Au5 In2 61.10(2) 6_556 2_564 ?
Au3 Au5 In2 61.10(2) 6_556 2_564 ?
Au4 Au5 In2 108.61(2) . 2_564 ?
Au6 Au5 In2 71.42(2) 6_556 2_564 ?
Au3 Au5 In2 120.64(3) . 2_554 ?
Cu3 Au5 In2 62.22(2) 7_565 2_554 ?
Au3 Au5 In2 62.22(2) 7_565 2_554 ?
Cu3 Au5 In2 61.10(2) 4_455 2_554 ?
Au3 Au5 In2 61.10(2) 4_455 2_554 ?
Cu3 Au5 In2 118.55(3) 6_556 2_554 ?
Au3 Au5 In2 118.55(3) 6_556 2_554 ?
Au4 Au5 In2 108.61(2) . 2_554 ?
Au6 Au5 In2 71.42(2) 6_556 2_554 ?
In2 Au5 In2 134.30(4) 2_564 2_554 ?
In2 Au6 Au3 145.10(2) 1_554 . ?
In2 Au6 Cu3 145.10(2) 1_554 7_565 ?
Au3 Au6 Cu3 61.27(3) . 7_565 ?
In2 Au6 Au3 145.10(2) 1_554 7_565 ?
Au3 Au6 Au3 61.27(3) . 7_565 ?
Cu3 Au6 Au3 0.00(3) 7_565 7_565 ?
In2 Au6 Cu5 145.34(4) 1_554 6_656 ?
Au3 Au6 Cu5 58.23(2) . 6_656 ?
Cu3 Au6 Cu5 58.23(2) 7_565 6_656 ?
Au3 Au6 Cu5 58.23(2) 7_565 6_656 ?
In2 Au6 Au5 145.34(4) 1_554 6_656 ?
Au3 Au6 Au5 58.23(2) . 6_656 ?
Cu3 Au6 Au5 58.23(2) 7_565 6_656 ?
Au3 Au6 Au5 58.23(2) 7_565 6_656 ?
Cu5 Au6 Au5 0.00(2) 6_656 6_656 ?
In2 Au6 Au5 113.32(3) 1_554 . ?
Au3 Au6 Au5 55.693(19) . . ?
Cu3 Au6 Au5 55.693(19) 7_565 . ?
Au3 Au6 Au5 55.693(19) 7_565 . ?
Cu5 Au6 Au5 101.341(18) 6_656 . ?
Au5 Au6 Au5 101.341(18) 6_656 . ?
In2 Au6 Eu1 76.45(2) 1_554 2_554 ?
Au3 Au6 Eu1 120.36(3) . 2_554 ?
Cu3 Au6 Eu1 68.66(2) 7_565 2_554 ?
Au3 Au6 Eu1 68.66(2) 7_565 2_554 ?
Cu5 Au6 Eu1 117.255(16) 6_656 2_554 ?
Au5 Au6 Eu1 117.255(16) 6_656 2_554 ?
Au5 Au6 Eu1 70.394(18) . 2_554 ?
In2 Au6 Eu1 76.45(2) 1_554 2_564 ?
Au3 Au6 Eu1 68.66(2) . 2_564 ?
Cu3 Au6 Eu1 120.36(3) 7_565 2_564 ?
Au3 Au6 Eu1 120.36(3) 7_565 2_564 ?
Cu5 Au6 Eu1 117.255(16) 6_656 2_564 ?
Au5 Au6 Eu1 117.255(16) 6_656 2_564 ?
Au5 Au6 Eu1 70.394(18) . 2_564 ?
Eu1 Au6 Eu1 117.08(3) 2_554 2_564 ?
In2 Au6 Eu1 76.13(3) 1_554 6_656 ?
Au3 Au6 Eu1 116.69(2) . 6_656 ?
Cu3 Au6 Eu1 116.69(2) 7_565 6_656 ?
Au3 Au6 Eu1 116.69(2) 7_565 6_656 ?
Cu5 Au6 Eu1 69.20(2) 6_656 6_656 ?
Au5 Au6 Eu1 69.20(2) 6_656 6_656 ?
Au5 Au6 Eu1 170.54(3) . 6_656 ?
Eu1 Au6 Eu1 113.370(17) 2_554 6_656 ?
Eu1 Au6 Eu1 113.370(17) 2_564 6_656 ?

_diffrn_measured_fraction_theta_max 0.981
_diffrn_reflns_theta_full        32.00
_diffrn_measured_fraction_theta_full 0.981
_refine_diff_density_max         3.253
_refine_diff_density_min         -4.201
_refine_diff_density_rms         0.767
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_af3
_database_code_depnum_ccdc_archive 'CCDC 1566152'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Au3.03 Cu1.97 Eu In'
_chemical_formula_weight         989.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Pnma

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   8.8585(13)
_cell_length_b                   5.3061(6)
_cell_length_c                   11.0668(11)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     520.18(11)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    3784
_cell_measurement_theta_min      2.95
_cell_measurement_theta_max      31.92

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    12.630
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1635
_exptl_absorpt_coefficient_mu    109.121
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.01
_exptl_absorpt_correction_T_max  0.013
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            3784
_diffrn_reflns_av_R_equivalents  0.0512
_diffrn_reflns_av_sigmaI/netI    0.0532
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.95
_diffrn_reflns_theta_max         31.92
_reflns_number_total             935
_reflns_number_gt                731
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0175P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00164(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         935
_refine_ls_number_parameters     44
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0483
_refine_ls_R_factor_gt           0.0313
_refine_ls_wR_factor_ref         0.0594
_refine_ls_wR_factor_gt          0.0547
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_restrained_S_all      1.000
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.24352(9) 0.2500 0.56158(6) 0.01033(19) Uani 1 2 d S . .
In2 In 0.35307(12) 0.2500 0.85435(8) 0.0076(2) Uani 1 2 d S . .
Au3 Au 0.43199(11) 0.50730(14) 0.30424(7) 0.0117(3) Uani 0.239(3) 1 d P . .
Cu3 Cu 0.43199(11) 0.50730(14) 0.30424(7) 0.0117(3) Uani 0.761(3) 1 d P . .
Au4 Au 0.08346(7) 0.2500 0.01423(5) 0.0112(2) Uani 0.950(4) 2 d SP . .
Cu4 Cu 0.08346(7) 0.2500 0.01423(5) 0.0112(2) Uani 0.050(4) 2 d SP . .
Au5 Au 0.18653(9) 0.2500 0.25218(7) 0.0106(3) Uani 0.604(4) 2 d SP . .
Cu5 Cu 0.18653(9) 0.2500 0.25218(7) 0.0106(3) Uani 0.396(4) 2 d SP . .
Au6 Au 0.44266(8) 0.2500 0.09043(5) 0.01532(18) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Cu4 3.1084(6) 2_565 ?
Eu1 Au4 3.1084(6) 2_565 ?
Eu1 Cu4 3.1084(6) 2 ?
Eu1 Au4 3.1084(6) 2 ?
Eu1 Cu4 3.1261(11) 6_656 ?
Eu1 Au4 3.1261(11) 6_656 ?
Eu1 Au6 3.1402(6) 2 ?
Eu1 Au6 3.1402(6) 2_565 ?
Eu1 Au6 3.1517(10) 6_556 ?
Eu1 Cu3 3.3596(11) 2_565 ?
Eu1 Au3 3.3596(11) 2_565 ?
Eu1 Cu3 3.3596(11) 8_656 ?
In2 Au6 2.7305(11) 1_556 ?
In2 Cu3 2.8884(14) 8_656 ?
In2 Au3 2.8884(14) 8_656 ?
In2 Cu3 2.8884(13) 2_565 ?
In2 Au3 2.8884(13) 2_565 ?
In2 Cu3 2.8920(13) 3_646 ?
In2 Au3 2.8920(13) 5_666 ?
In2 Au3 2.8920(13) 3_646 ?
In2 Cu3 2.8920(13) 5_666 ?
In2 Cu5 2.9052(6) 2 ?
In2 Au5 2.9052(6) 2 ?
In2 Cu5 2.9052(6) 2_565 ?
Au3 Cu3 2.5755(15) 7_575 ?
Au3 Au3 2.5755(15) 7_575 ?
Au3 Au5 2.6313(12) . ?
Au3 Cu4 2.6604(9) 2_565 ?
Au3 Au4 2.6604(9) 2_565 ?
Au3 Cu5 2.7089(12) 6_656 ?
Au3 Au5 2.7089(12) 6_656 ?
Au3 Cu3 2.7306(16) 7_565 ?
Au3 Au3 2.7306(16) 7_565 ?
Au3 Au6 2.7334(9) . ?
Au3 Cu4 2.7750(10) 6_656 ?
Au4 Cu3 2.6604(9) 8_655 ?
Au4 Au3 2.6604(9) 8_655 ?
Au4 Cu3 2.6604(9) 2_564 ?
Au4 Au3 2.6604(9) 2_564 ?
Au4 Cu3 2.7750(10) 6_556 ?
Au4 Au3 2.7750(10) 6_556 ?
Au4 Cu3 2.7750(10) 4_455 ?
Au4 Au3 2.7750(10) 4_455 ?
Au4 Au5 2.7871(10) . ?
Au4 In2 2.9723(12) 1_554 ?
Au4 Cu4 3.0536(7) 5 ?
Au5 Cu3 2.6313(12) 7_565 ?
Au5 Au3 2.6313(12) 7_565 ?
Au5 Cu3 2.7089(12) 4_455 ?
Au5 Au3 2.7089(12) 4_455 ?
Au5 Cu3 2.7089(12) 6_556 ?
Au5 Au3 2.7089(12) 6_556 ?
Au5 Au6 2.7751(10) 6_556 ?
Au5 Au6 2.8900(10) . ?
Au6 In2 2.7305(11) 1_554 ?
Au6 Cu3 2.7334(9) 7_565 ?
Au6 Au3 2.7334(9) 7_565 ?
Au6 Cu5 2.7751(10) 6_656 ?
Au6 Au5 2.7751(10) 6_656 ?
Au6 Eu1 3.1402(6) 2_554 ?
Au6 Eu1 3.1402(6) 2_564 ?
Au6 Eu1 3.1517(10) 6_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu4 Eu1 Au4 0.00(2) 2_565 2_565 ?
Cu4 Eu1 Cu4 117.19(3) 2_565 2 ?
Au4 Eu1 Cu4 117.19(3) 2_565 2 ?
Cu4 Eu1 Au4 117.19(3) 2_565 2 ?
Au4 Eu1 Au4 117.19(3) 2_565 2 ?
Cu4 Eu1 Au4 0.00(2) 2 2 ?
Cu4 Eu1 Cu4 58.652(17) 2_565 6_656 ?
Au4 Eu1 Cu4 58.652(17) 2_565 6_656 ?
Cu4 Eu1 Cu4 58.652(17) 2 6_656 ?
Au4 Eu1 Cu4 58.652(17) 2 6_656 ?
Cu4 Eu1 Au4 58.652(17) 2_565 6_656 ?
Au4 Eu1 Au4 58.652(17) 2_565 6_656 ?
Cu4 Eu1 Au4 58.652(17) 2 6_656 ?
Au4 Eu1 Au4 58.652(17) 2 6_656 ?
Cu4 Eu1 Au4 0.000(19) 6_656 6_656 ?
Cu4 Eu1 Au6 175.72(3) 2_565 2 ?
Au4 Eu1 Au6 175.72(3) 2_565 2 ?
Cu4 Eu1 Au6 63.577(17) 2 2 ?
Au4 Eu1 Au6 63.577(17) 2 2 ?
Cu4 Eu1 Au6 122.224(17) 6_656 2 ?
Au4 Eu1 Au6 122.224(17) 6_656 2 ?
Cu4 Eu1 Au6 63.577(17) 2_565 2_565 ?
Au4 Eu1 Au6 63.577(17) 2_565 2_565 ?
Cu4 Eu1 Au6 175.72(3) 2 2_565 ?
Au4 Eu1 Au6 175.72(3) 2 2_565 ?
Cu4 Eu1 Au6 122.224(17) 6_656 2_565 ?
Au4 Eu1 Au6 122.224(17) 6_656 2_565 ?
Au6 Eu1 Au6 115.32(3) 2 2_565 ?
Cu4 Eu1 Au6 109.085(19) 2_565 6_556 ?
Au4 Eu1 Au6 109.085(19) 2_565 6_556 ?
Cu4 Eu1 Au6 109.085(19) 2 6_556 ?
Au4 Eu1 Au6 109.085(19) 2 6_556 ?
Cu4 Eu1 Au6 132.17(3) 6_656 6_556 ?
Au4 Eu1 Au6 132.17(3) 6_656 6_556 ?
Au6 Eu1 Au6 67.054(19) 2 6_556 ?
Au6 Eu1 Au6 67.054(19) 2_565 6_556 ?
Cu4 Eu1 Cu3 92.051(19) 2_565 2_565 ?
Au4 Eu1 Cu3 92.051(19) 2_565 2_565 ?
Cu4 Eu1 Cu3 133.64(2) 2 2_565 ?
Au4 Eu1 Cu3 133.64(2) 2 2_565 ?
Cu4 Eu1 Cu3 131.32(3) 6_656 2_565 ?
Au4 Eu1 Cu3 131.32(3) 6_656 2_565 ?
Au6 Eu1 Cu3 89.97(3) 2 2_565 ?
Au6 Eu1 Cu3 49.596(18) 2_565 2_565 ?
Au6 Eu1 Cu3 92.02(3) 6_556 2_565 ?
Cu4 Eu1 Au3 92.051(19) 2_565 2_565 ?
Au4 Eu1 Au3 92.051(19) 2_565 2_565 ?
Cu4 Eu1 Au3 133.64(2) 2 2_565 ?
Au4 Eu1 Au3 133.64(2) 2 2_565 ?
Cu4 Eu1 Au3 131.32(3) 6_656 2_565 ?
Au4 Eu1 Au3 131.32(3) 6_656 2_565 ?
Au6 Eu1 Au3 89.97(3) 2 2_565 ?
Au6 Eu1 Au3 49.596(18) 2_565 2_565 ?
Au6 Eu1 Au3 92.02(3) 6_556 2_565 ?
Cu3 Eu1 Au3 0.00(3) 2_565 2_565 ?
Cu4 Eu1 Cu3 133.64(2) 2_565 8_656 ?
Au4 Eu1 Cu3 133.64(2) 2_565 8_656 ?
Cu4 Eu1 Cu3 92.051(19) 2 8_656 ?
Au4 Eu1 Cu3 92.051(19) 2 8_656 ?
Cu4 Eu1 Cu3 131.32(3) 6_656 8_656 ?
Au4 Eu1 Cu3 131.32(3) 6_656 8_656 ?
Au6 Eu1 Cu3 49.597(19) 2 8_656 ?
Au6 Eu1 Cu3 89.97(3) 2_565 8_656 ?
Au6 Eu1 Cu3 92.02(3) 6_556 8_656 ?
Cu3 Eu1 Cu3 45.08(3) 2_565 8_656 ?
Au3 Eu1 Cu3 45.08(3) 2_565 8_656 ?
Au6 In2 Cu3 115.96(4) 1_556 8_656 ?
Au6 In2 Au3 115.96(4) 1_556 8_656 ?
Cu3 In2 Au3 0.00(3) 8_656 8_656 ?
Au6 In2 Cu3 115.96(4) 1_556 2_565 ?
Cu3 In2 Cu3 52.96(4) 8_656 2_565 ?
Au3 In2 Cu3 52.96(4) 8_656 2_565 ?
Au6 In2 Au3 115.96(4) 1_556 2_565 ?
Cu3 In2 Au3 52.96(4) 8_656 2_565 ?
Au3 In2 Au3 52.96(4) 8_656 2_565 ?
Cu3 In2 Au3 0.000(19) 2_565 2_565 ?
Au6 In2 Cu3 112.91(4) 1_556 3_646 ?
Cu3 In2 Cu3 105.10(3) 8_656 3_646 ?
Au3 In2 Cu3 105.10(3) 8_656 3_646 ?
Cu3 In2 Cu3 131.12(4) 2_565 3_646 ?
Au3 In2 Cu3 131.12(4) 2_565 3_646 ?
Au6 In2 Au3 112.91(4) 1_556 5_666 ?
Cu3 In2 Au3 131.12(4) 8_656 5_666 ?
Au3 In2 Au3 131.12(4) 8_656 5_666 ?
Cu3 In2 Au3 105.10(3) 2_565 5_666 ?
Au3 In2 Au3 105.10(3) 2_565 5_666 ?
Cu3 In2 Au3 52.88(4) 3_646 5_666 ?
Au6 In2 Au3 112.91(4) 1_556 3_646 ?
Cu3 In2 Au3 105.10(3) 8_656 3_646 ?
Au3 In2 Au3 105.10(3) 8_656 3_646 ?
Cu3 In2 Au3 131.12(4) 2_565 3_646 ?
Au3 In2 Au3 131.12(4) 2_565 3_646 ?
Cu3 In2 Au3 0.00(4) 3_646 3_646 ?
Au3 In2 Au3 52.88(4) 5_666 3_646 ?
Au6 In2 Cu3 112.91(4) 1_556 5_666 ?
Cu3 In2 Cu3 131.12(4) 8_656 5_666 ?
Au3 In2 Cu3 131.12(4) 8_656 5_666 ?
Cu3 In2 Cu3 105.10(3) 2_565 5_666 ?
Au3 In2 Cu3 105.10(3) 2_565 5_666 ?
Cu3 In2 Cu3 52.88(4) 3_646 5_666 ?
Au3 In2 Cu3 0.00(2) 5_666 5_666 ?
Au3 In2 Cu3 52.88(4) 3_646 5_666 ?
Au6 In2 Cu5 114.05(2) 1_556 2 ?
Cu3 In2 Cu5 54.02(3) 8_656 2 ?
Au3 In2 Cu5 54.02(3) 8_656 2 ?
Cu3 In2 Cu5 103.11(4) 2_565 2 ?
Au3 In2 Cu5 103.11(4) 2_565 2 ?
Cu3 In2 Cu5 55.71(3) 3_646 2 ?
Au3 In2 Cu5 104.47(4) 5_666 2 ?
Au3 In2 Cu5 55.71(3) 3_646 2 ?
Cu3 In2 Cu5 104.47(4) 5_666 2 ?
Au6 In2 Au5 114.05(2) 1_556 2 ?
Cu3 In2 Au5 54.02(3) 8_656 2 ?
Au3 In2 Au5 54.02(3) 8_656 2 ?
Cu3 In2 Au5 103.11(4) 2_565 2 ?
Au3 In2 Au5 103.11(4) 2_565 2 ?
Cu3 In2 Au5 55.71(3) 3_646 2 ?
Au3 In2 Au5 104.47(4) 5_666 2 ?
Au3 In2 Au5 55.71(3) 3_646 2 ?
Cu3 In2 Au5 104.47(4) 5_666 2 ?
Cu5 In2 Au5 0.00(3) 2 2 ?
Au6 In2 Cu5 114.05(2) 1_556 2_565 ?
Cu3 In2 Cu5 103.11(4) 8_656 2_565 ?
Au3 In2 Cu5 103.11(4) 8_656 2_565 ?
Cu3 In2 Cu5 54.02(3) 2_565 2_565 ?
Au3 In2 Cu5 54.02(3) 2_565 2_565 ?
Cu3 In2 Cu5 104.47(4) 3_646 2_565 ?
Au3 In2 Cu5 55.71(3) 5_666 2_565 ?
Au3 In2 Cu5 104.47(4) 3_646 2_565 ?
Cu3 In2 Cu5 55.71(3) 5_666 2_565 ?
Cu5 In2 Cu5 131.90(4) 2 2_565 ?
Au5 In2 Cu5 131.90(4) 2 2_565 ?
Cu3 Au3 Au3 0.00(6) 7_575 7_575 ?
Cu3 Au3 Au5 121.26(2) 7_575 . ?
Au3 Au3 Au5 121.26(2) 7_575 . ?
Cu3 Au3 Cu4 61.050(18) 7_575 2_565 ?
Au3 Au3 Cu4 61.050(18) 7_575 2_565 ?
Au5 Au3 Cu4 113.57(4) . 2_565 ?
Cu3 Au3 Au4 61.050(18) 7_575 2_565 ?
Au3 Au3 Au4 61.050(18) 7_575 2_565 ?
Au5 Au3 Au4 113.57(4) . 2_565 ?
Cu4 Au3 Au4 0.00(3) 2_565 2_565 ?
Cu3 Au3 Cu5 120.26(2) 7_575 6_656 ?
Au3 Au3 Cu5 120.26(2) 7_575 6_656 ?
Au5 Au3 Cu5 112.08(3) . 6_656 ?
Cu4 Au3 Cu5 119.22(4) 2_565 6_656 ?
Au4 Au3 Cu5 119.22(4) 2_565 6_656 ?
Cu3 Au3 Au5 120.26(2) 7_575 6_656 ?
Au3 Au3 Au5 120.26(2) 7_575 6_656 ?
Au5 Au3 Au5 112.08(3) . 6_656 ?
Cu4 Au3 Au5 119.22(4) 2_565 6_656 ?
Au4 Au3 Au5 119.22(4) 2_565 6_656 ?
Cu5 Au3 Au5 0.00(3) 6_656 6_656 ?
Cu3 Au3 Cu3 180.00(11) 7_575 7_565 ?
Au3 Au3 Cu3 180.00(11) 7_575 7_565 ?
Au5 Au3 Cu3 58.74(2) . 7_565 ?
Cu4 Au3 Cu3 118.950(18) 2_565 7_565 ?
Au4 Au3 Cu3 118.950(18) 2_565 7_565 ?
Cu5 Au3 Cu3 59.74(2) 6_656 7_565 ?
Au5 Au3 Cu3 59.74(2) 6_656 7_565 ?
Cu3 Au3 Au3 180.00(11) 7_575 7_565 ?
Au3 Au3 Au3 180.00(11) 7_575 7_565 ?
Au5 Au3 Au3 58.74(2) . 7_565 ?
Cu4 Au3 Au3 118.950(18) 2_565 7_565 ?
Au4 Au3 Au3 118.950(18) 2_565 7_565 ?
Cu5 Au3 Au3 59.74(2) 6_656 7_565 ?
Au5 Au3 Au3 59.74(2) 6_656 7_565 ?
Cu3 Au3 Au3 0.00(5) 7_565 7_565 ?
Cu3 Au3 Au6 119.965(18) 7_575 . ?
Au3 Au3 Au6 119.965(18) 7_575 . ?
Au5 Au3 Au6 65.16(3) . . ?
Cu4 Au3 Au6 178.61(4) 2_565 . ?
Au4 Au3 Au6 178.61(4) 2_565 . ?
Cu5 Au3 Au6 61.31(3) 6_656 . ?
Au5 Au3 Au6 61.31(3) 6_656 . ?
Cu3 Au3 Au6 60.035(18) 7_565 . ?
Au3 Au3 Au6 60.035(18) 7_565 . ?
Cu3 Au3 Cu4 119.471(17) 7_575 6_656 ?
Au3 Au3 Cu4 119.471(17) 7_575 6_656 ?
Au5 Au3 Cu4 107.63(3) . 6_656 ?
Cu4 Au3 Cu4 68.32(2) 2_565 6_656 ?
Au4 Au3 Cu4 68.32(2) 2_565 6_656 ?
Cu5 Au3 Cu4 61.08(3) 6_656 6_656 ?
Au5 Au3 Cu4 61.08(3) 6_656 6_656 ?
Cu3 Au3 Cu4 60.529(17) 7_565 6_656 ?
Au3 Au3 Cu4 60.529(17) 7_565 6_656 ?
Au6 Au3 Cu4 111.36(3) . 6_656 ?
Cu3 Au4 Au3 0.000(16) 8_655 8_655 ?
Cu3 Au4 Cu3 57.90(4) 8_655 2_564 ?
Au3 Au4 Cu3 57.90(4) 8_655 2_564 ?
Cu3 Au4 Au3 57.90(4) 8_655 2_564 ?
Au3 Au4 Au3 57.90(4) 8_655 2_564 ?
Cu3 Au4 Au3 0.00(5) 2_564 2_564 ?
Cu3 Au4 Cu3 147.74(3) 8_655 6_556 ?
Au3 Au4 Cu3 147.74(3) 8_655 6_556 ?
Cu3 Au4 Cu3 111.68(2) 2_564 6_556 ?
Au3 Au4 Cu3 111.68(2) 2_564 6_556 ?
Cu3 Au4 Au3 147.74(3) 8_655 6_556 ?
Au3 Au4 Au3 147.74(3) 8_655 6_556 ?
Cu3 Au4 Au3 111.68(2) 2_564 6_556 ?
Au3 Au4 Au3 111.68(2) 2_564 6_556 ?
Cu3 Au4 Au3 0.00(4) 6_556 6_556 ?
Cu3 Au4 Cu3 111.68(2) 8_655 4_455 ?
Au3 Au4 Cu3 111.68(2) 8_655 4_455 ?
Cu3 Au4 Cu3 147.74(3) 2_564 4_455 ?
Au3 Au4 Cu3 147.74(3) 2_564 4_455 ?
Cu3 Au4 Cu3 58.94(3) 6_556 4_455 ?
Au3 Au4 Cu3 58.94(3) 6_556 4_455 ?
Cu3 Au4 Au3 111.68(2) 8_655 4_455 ?
Au3 Au4 Au3 111.68(2) 8_655 4_455 ?
Cu3 Au4 Au3 147.74(3) 2_564 4_455 ?
Au3 Au4 Au3 147.74(3) 2_564 4_455 ?
Cu3 Au4 Au3 58.94(3) 6_556 4_455 ?
Au3 Au4 Au3 58.94(3) 6_556 4_455 ?
Cu3 Au4 Au3 0.00(4) 4_455 4_455 ?
Cu3 Au4 Au5 147.37(2) 8_655 . ?
Au3 Au4 Au5 147.37(2) 8_655 . ?
Cu3 Au4 Au5 147.37(2) 2_564 . ?
Au3 Au4 Au5 147.37(2) 2_564 . ?
Cu3 Au4 Au5 58.29(3) 6_556 . ?
Au3 Au4 Au5 58.29(3) 6_556 . ?
Cu3 Au4 Au5 58.29(3) 4_455 . ?
Au3 Au4 Au5 58.29(3) 4_455 . ?
Cu3 Au4 In2 61.40(3) 8_655 1_554 ?
Au3 Au4 In2 61.40(3) 8_655 1_554 ?
Cu3 Au4 In2 61.40(3) 2_564 1_554 ?
Au3 Au4 In2 61.40(3) 2_564 1_554 ?
Cu3 Au4 In2 145.03(2) 6_556 1_554 ?
Au3 Au4 In2 145.03(2) 6_556 1_554 ?
Cu3 Au4 In2 145.03(2) 4_455 1_554 ?
Au3 Au4 In2 145.03(2) 4_455 1_554 ?
Au5 Au4 In2 107.41(3) . 1_554 ?
Cu3 Au4 Cu4 57.62(2) 8_655 5 ?
Au3 Au4 Cu4 57.62(2) 8_655 5 ?
Cu3 Au4 Cu4 107.79(3) 2_564 5 ?
Au3 Au4 Cu4 107.79(3) 2_564 5 ?
Cu3 Au4 Cu4 105.54(3) 6_556 5 ?
Au3 Au4 Cu4 105.54(3) 6_556 5 ?
Cu3 Au4 Cu4 54.06(2) 4_455 5 ?
Au3 Au4 Cu4 54.06(2) 4_455 5 ?
Au5 Au4 Cu4 104.84(2) . 5 ?
In2 Au4 Cu4 109.13(2) 1_554 5 ?
Au3 Au5 Cu3 62.51(4) . 7_565 ?
Au3 Au5 Au3 62.51(4) . 7_565 ?
Cu3 Au5 Au3 0.00(4) 7_565 7_565 ?
Au3 Au5 Cu3 178.87(3) . 4_455 ?
Cu3 Au5 Cu3 118.48(3) 7_565 4_455 ?
Au3 Au5 Cu3 118.48(3) 7_565 4_455 ?
Au3 Au5 Au3 178.87(3) . 4_455 ?
Cu3 Au5 Au3 118.48(3) 7_565 4_455 ?
Au3 Au5 Au3 118.48(3) 7_565 4_455 ?
Cu3 Au5 Au3 0.00(5) 4_455 4_455 ?
Au3 Au5 Cu3 118.48(3) . 6_556 ?
Cu3 Au5 Cu3 178.87(3) 7_565 6_556 ?
Au3 Au5 Cu3 178.87(3) 7_565 6_556 ?
Cu3 Au5 Cu3 60.53(4) 4_455 6_556 ?
Au3 Au5 Cu3 60.53(4) 4_455 6_556 ?
Au3 Au5 Au3 118.48(3) . 6_556 ?
Cu3 Au5 Au3 178.87(3) 7_565 6_556 ?
Au3 Au5 Au3 178.87(3) 7_565 6_556 ?
Cu3 Au5 Au3 60.53(4) 4_455 6_556 ?
Au3 Au5 Au3 60.53(4) 4_455 6_556 ?
Cu3 Au5 Au3 0.00(4) 6_556 6_556 ?
Au3 Au5 Au6 120.39(3) . 6_556 ?
Cu3 Au5 Au6 120.39(3) 7_565 6_556 ?
Au3 Au5 Au6 120.39(3) 7_565 6_556 ?
Cu3 Au5 Au6 59.78(3) 4_455 6_556 ?
Au3 Au5 Au6 59.78(3) 4_455 6_556 ?
Cu3 Au5 Au6 59.78(3) 6_556 6_556 ?
Au3 Au5 Au6 59.78(3) 6_556 6_556 ?
Au3 Au5 Au4 118.53(3) . . ?
Cu3 Au5 Au4 118.53(3) 7_565 . ?
Au3 Au5 Au4 118.53(3) 7_565 . ?
Cu3 Au5 Au4 60.63(3) 4_455 . ?
Au3 Au5 Au4 60.63(3) 4_455 . ?
Cu3 Au5 Au4 60.63(3) 6_556 . ?
Au3 Au5 Au4 60.63(3) 6_556 . ?
Au6 Au5 Au4 109.76(3) 6_556 . ?
Au3 Au5 Au6 59.13(3) . . ?
Cu3 Au5 Au6 59.13(3) 7_565 . ?
Au3 Au5 Au6 59.13(3) 7_565 . ?
Cu3 Au5 Au6 120.71(3) 4_455 . ?
Au3 Au5 Au6 120.71(3) 4_455 . ?
Cu3 Au5 Au6 120.71(3) 6_556 . ?
Au3 Au5 Au6 120.71(3) 6_556 . ?
Au6 Au5 Au6 179.39(4) 6_556 . ?
Au4 Au5 Au6 70.85(3) . . ?
In2 Au6 Au3 144.91(3) 1_554 . ?
In2 Au6 Cu3 144.91(3) 1_554 7_565 ?
Au3 Au6 Cu3 59.93(4) . 7_565 ?
In2 Au6 Au3 144.91(3) 1_554 7_565 ?
Au3 Au6 Au3 59.93(4) . 7_565 ?
Cu3 Au6 Au3 0.00(5) 7_565 7_565 ?
In2 Au6 Cu5 145.77(4) 1_554 6_656 ?
Au3 Au6 Cu5 58.91(3) . 6_656 ?
Cu3 Au6 Cu5 58.91(3) 7_565 6_656 ?
Au3 Au6 Cu5 58.91(3) 7_565 6_656 ?
In2 Au6 Au5 145.77(4) 1_554 6_656 ?
Au3 Au6 Au5 58.91(3) . 6_656 ?
Cu3 Au6 Au5 58.91(3) 7_565 6_656 ?
Au3 Au6 Au5 58.91(3) 7_565 6_656 ?
Cu5 Au6 Au5 0.00(2) 6_656 6_656 ?
In2 Au6 Au5 111.38(4) 1_554 . ?
Au3 Au6 Au5 55.71(3) . . ?
Cu3 Au6 Au5 55.71(3) 7_565 . ?
Au3 Au6 Au5 55.71(3) 7_565 . ?
Cu5 Au6 Au5 102.85(2) 6_656 . ?
Au5 Au6 Au5 102.85(2) 6_656 . ?
In2 Au6 Eu1 75.53(2) 1_554 2_554 ?
Au3 Au6 Eu1 119.46(3) . 2_554 ?
Cu3 Au6 Eu1 69.38(2) 7_565 2_554 ?
Au3 Au6 Eu1 69.38(2) 7_565 2_554 ?
Cu5 Au6 Eu1 118.209(17) 6_656 2_554 ?
Au5 Au6 Eu1 118.209(17) 6_656 2_554 ?
Au5 Au6 Eu1 69.55(2) . 2_554 ?
In2 Au6 Eu1 75.53(2) 1_554 2_564 ?
Au3 Au6 Eu1 69.38(2) . 2_564 ?
Cu3 Au6 Eu1 119.46(3) 7_565 2_564 ?
Au3 Au6 Eu1 119.46(3) 7_565 2_564 ?
Cu5 Au6 Eu1 118.208(17) 6_656 2_564 ?
Au5 Au6 Eu1 118.208(17) 6_656 2_564 ?
Au5 Au6 Eu1 69.55(2) . 2_564 ?
Eu1 Au6 Eu1 115.32(3) 2_554 2_564 ?
In2 Au6 Eu1 74.64(3) 1_554 6_656 ?
Au3 Au6 Eu1 119.43(3) . 6_656 ?
Cu3 Au6 Eu1 119.43(3) 7_565 6_656 ?
Au3 Au6 Eu1 119.43(3) 7_565 6_656 ?
Cu5 Au6 Eu1 71.14(3) 6_656 6_656 ?
Au5 Au6 Eu1 71.14(3) 6_656 6_656 ?
Au5 Au6 Eu1 173.99(3) . 6_656 ?
Eu1 Au6 Eu1 112.946(19) 2_554 6_656 ?
Eu1 Au6 Eu1 112.946(19) 2_564 6_656 ?

_diffrn_measured_fraction_theta_max 0.989
_diffrn_reflns_theta_full        31.92
_diffrn_measured_fraction_theta_full 0.989
_refine_diff_density_max         2.869
_refine_diff_density_min         -2.824
_refine_diff_density_rms         0.689
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_vsAuAg_0m
_database_code_depnum_ccdc_archive 'CCDC 1566154'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_shelx_SHELXL_version_number     97
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ag3.23 Au1.77 Eu In'
_chemical_formula_weight         963.65

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      tetragonal
_space_group_IT_number           139
_space_group_name_H-M_alt        'I 4/m m m'
_space_group_name_Hall           '-I 4 2'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'-x, y, -z'
'x, -y, -z'
'y, x, -z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'x, -y, z'
'-x, y, z'
'-y, -x, z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'y+1/2, x+1/2, z+1/2'

_cell_length_a                   7.199(2)
_cell_length_b                   7.199
_cell_length_c                   5.5082(16)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     285.43(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    2390
_cell_measurement_theta_min      4.003
_cell_measurement_theta_max      37.611

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    11.213
_exptl_crystal_F_000             807.2
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.07
_exptl_absorpt_coefficient_mu    70.734
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.03
_exptl_absorpt_correction_T_max  0.07
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       'w amd f scan'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            2390
_diffrn_reflns_av_unetI/netI     0.0430
_diffrn_reflns_av_R_equivalents  0.0714
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_theta_min         4.003
_diffrn_reflns_theta_max         37.611
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             249
_reflns_number_gt                208
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0270P)²+1.2509P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-97 (Sheldrick 2008)'
_refine_ls_extinction_coef       0.0043(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         249
_refine_ls_number_parameters     11
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0505
_refine_ls_R_factor_gt           0.0348
_refine_ls_wR_factor_ref         0.0617
_refine_ls_wR_factor_gt          0.0581
_refine_ls_goodness_of_fit_ref   1.137
_refine_ls_restrained_S_all      1.137
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 0.0000 0.0000 0.0107(3) Uani 1 16 d S T P . .
Au1 Au 0.30677(6) 0.30677(6) 0.0000 0.0109(2) Uani 0.442(7) 4 d S T P . .
Ag1 Ag 0.30677(6) 0.30677(6) 0.0000 0.0109(2) Uani 0.558(7) 4 d S T P . .
In2 In 0.5000 0.0000 0.2500 0.0104(3) Uani 0.5 8 d S T P . .
Ag2 Ag 0.5000 0.0000 0.2500 0.0104(3) Uani 0.5 8 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Au1 3.1230(8) . ?
Eu1 Ag1 3.1230(8) 17 ?
Eu1 Au1 3.1230(8) 17 ?
Eu1 Ag1 3.1230(8) 19 ?
Eu1 Ag1 3.1230(8) 3 ?
Eu1 Au1 3.1230(8) 19 ?
Eu1 Au1 3.1230(8) 3 ?
Eu1 Au1 3.3845(8) 9_444 ?
Eu1 Au1 3.3845(8) 25 ?
Eu1 Ag1 3.3845(8) 25 ?
Eu1 Ag1 3.3845(8) 9_444 ?
Au1 Ag1 2.7819(9) 19_565 ?
Au1 Ag1 2.7819(12) 3_655 ?
Au1 Au1 2.7819(9) 19_565 ?
Au1 Au1 2.7819(12) 3_655 ?
Au1 Ag2 2.9509(3) 17_655 ?
Au1 Ag2 2.9509(5) 9_454 ?
Au1 In2 2.9509(3) 17_655 ?
Au1 In2 2.9509(5) 9_454 ?
Au1 Ag2 2.9509(5) 25 ?
Au1 In2 2.9509(5) 25 ?
Au1 In2 2.9509(3) . ?
In2 Ag2 2.7541(8) 17_656 ?
In2 Ag2 2.7541(8) 17_655 ?
In2 In2 2.7541(8) 17_656 ?
In2 In2 2.7541(8) 17_655 ?
In2 Ag1 2.9509(5) 27 ?
In2 Ag1 2.9509(3) 19 ?
In2 Au1 2.9509(5) 27 ?
In2 Au1 2.9509(3) 19 ?
In2 Au1 2.9509(3) 3_655 ?
In2 Au1 2.9509(5) 11_545 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au1 Eu1 Ag1 180.0 . 17 ?
Au1 Eu1 Au1 180.000(11) . 17 ?
Ag1 Eu1 Au1 0.0 17 17 ?
Au1 Eu1 Ag1 90.0 . 19 ?
Ag1 Eu1 Ag1 90.000(17) 17 19 ?
Au1 Eu1 Ag1 90.000(17) 17 19 ?
Au1 Eu1 Ag1 90.0 . 3 ?
Ag1 Eu1 Ag1 90.000(17) 17 3 ?
Au1 Eu1 Ag1 90.000(17) 17 3 ?
Ag1 Eu1 Ag1 180.0 19 3 ?
Au1 Eu1 Au1 90.000(17) . 19 ?
Ag1 Eu1 Au1 90.0 17 19 ?
Au1 Eu1 Au1 90.000(17) 17 19 ?
Ag1 Eu1 Au1 0.0 19 19 ?
Ag1 Eu1 Au1 180.0 3 19 ?
Au1 Eu1 Au1 90.000(17) . 3 ?
Ag1 Eu1 Au1 90.0 17 3 ?
Au1 Eu1 Au1 90.000(17) 17 3 ?
Ag1 Eu1 Au1 180.0 19 3 ?
Ag1 Eu1 Au1 0.0 3 3 ?
Au1 Eu1 Au1 180.0 19 3 ?
Au1 Eu1 Au1 125.536(12) . 9_444 ?
Ag1 Eu1 Au1 54.5 17 9_444 ?
Au1 Eu1 Au1 54.464(12) 17 9_444 ?
Ag1 Eu1 Au1 90.0 19 9_444 ?
Ag1 Eu1 Au1 90.0 3 9_444 ?
Au1 Eu1 Au1 90.000(10) 19 9_444 ?
Au1 Eu1 Au1 90.000(10) 3 9_444 ?
Au1 Eu1 Au1 54.464(12) . 25 ?
Ag1 Eu1 Au1 125.5 17 25 ?
Au1 Eu1 Au1 125.536(12) 17 25 ?
Ag1 Eu1 Au1 90.0 19 25 ?
Ag1 Eu1 Au1 90.0 3 25 ?
Au1 Eu1 Au1 90.000(10) 19 25 ?
Au1 Eu1 Au1 90.000(10) 3 25 ?
Au1 Eu1 Au1 180.000(14) 9_444 25 ?
Au1 Eu1 Ag1 54.5 . 25 ?
Ag1 Eu1 Ag1 125.536(12) 17 25 ?
Au1 Eu1 Ag1 125.536(12) 17 25 ?
Ag1 Eu1 Ag1 90.000(10) 19 25 ?
Ag1 Eu1 Ag1 90.000(10) 3 25 ?
Au1 Eu1 Ag1 90.000(10) 19 25 ?
Au1 Eu1 Ag1 90.000(10) 3 25 ?
Au1 Eu1 Ag1 180.000(14) 9_444 25 ?
Au1 Eu1 Ag1 0.00(3) 25 25 ?
Au1 Eu1 Ag1 125.5 . 9_444 ?
Ag1 Eu1 Ag1 54.464(12) 17 9_444 ?
Au1 Eu1 Ag1 54.464(12) 17 9_444 ?
Ag1 Eu1 Ag1 90.000(10) 19 9_444 ?
Ag1 Eu1 Ag1 90.000(10) 3 9_444 ?
Au1 Eu1 Ag1 90.000(10) 19 9_444 ?
Au1 Eu1 Ag1 90.000(10) 3 9_444 ?
Au1 Eu1 Ag1 0.0 9_444 9_444 ?
Au1 Eu1 Ag1 180.0 25 9_444 ?
Ag1 Eu1 Ag1 180.0 25 9_444 ?
Ag1 Au1 Ag1 90.0 19_565 3_655 ?
Ag1 Au1 Au1 0.0 19_565 19_565 ?
Ag1 Au1 Au1 90.0 3_655 19_565 ?
Ag1 Au1 Au1 90.0 19_565 3_655 ?
Ag1 Au1 Au1 0.0 3_655 3_655 ?
Au1 Au1 Au1 90.0 19_565 3_655 ?
Ag1 Au1 Ag2 138.448(12) 19_565 17_655 ?
Ag1 Au1 Ag2 61.876(13) 3_655 17_655 ?
Au1 Au1 Ag2 138.448(12) 19_565 17_655 ?
Au1 Au1 Ag2 61.876(13) 3_655 17_655 ?
Ag1 Au1 Ag2 61.876(12) 19_565 9_454 ?
Ag1 Au1 Ag2 138.448(13) 3_655 9_454 ?
Au1 Au1 Ag2 61.876(12) 19_565 9_454 ?
Au1 Au1 Ag2 138.448(13) 3_655 9_454 ?
Ag2 Au1 Ag2 119.192(16) 17_655 9_454 ?
Ag1 Au1 In2 138.448(12) 19_565 17_655 ?
Ag1 Au1 In2 61.876(13) 3_655 17_655 ?
Au1 Au1 In2 138.448(12) 19_565 17_655 ?
Au1 Au1 In2 61.876(13) 3_655 17_655 ?
Ag2 Au1 In2 0.0 17_655 17_655 ?
Ag2 Au1 In2 119.2 9_454 17_655 ?
Ag1 Au1 In2 61.876(12) 19_565 9_454 ?
Ag1 Au1 In2 138.448(13) 3_655 9_454 ?
Au1 Au1 In2 61.876(12) 19_565 9_454 ?
Au1 Au1 In2 138.448(13) 3_655 9_454 ?
Ag2 Au1 In2 119.2 17_655 9_454 ?
Ag2 Au1 In2 0.0 9_454 9_454 ?
In2 Au1 In2 119.192(16) 17_655 9_454 ?
Ag1 Au1 Ag2 61.876(13) 19_565 25 ?
Ag1 Au1 Ag2 138.448(14) 3_655 25 ?
Au1 Au1 Ag2 61.876(13) 19_565 25 ?
Au1 Au1 Ag2 138.448(14) 3_655 25 ?
Ag2 Au1 Ag2 157.41(2) 17_655 25 ?
Ag2 Au1 Ag2 55.635(17) 9_454 25 ?
In2 Au1 Ag2 157.41(2) 17_655 25 ?
In2 Au1 Ag2 55.635(17) 9_454 25 ?
Ag1 Au1 In2 61.876(13) 19_565 25 ?
Ag1 Au1 In2 138.448(14) 3_655 25 ?
Au1 Au1 In2 61.876(13) 19_565 25 ?
Au1 Au1 In2 138.448(14) 3_655 25 ?
Ag2 Au1 In2 157.4 17_655 25 ?
Ag2 Au1 In2 55.6 9_454 25 ?
In2 Au1 In2 157.41(2) 17_655 25 ?
In2 Au1 In2 55.635(17) 9_454 25 ?
Ag2 Au1 In2 0.0 25 25 ?
Ag1 Au1 In2 138.448(12) 19_565 . ?
Ag1 Au1 In2 61.876(13) 3_655 . ?
Au1 Au1 In2 138.448(12) 19_565 . ?
Au1 Au1 In2 61.876(13) 3_655 . ?
Ag2 Au1 In2 55.6 17_655 . ?
Ag2 Au1 In2 157.4 9_454 . ?
In2 Au1 In2 55.635(14) 17_655 . ?
In2 Au1 In2 157.41(2) 9_454 . ?
Ag2 Au1 In2 119.2 25 . ?
In2 Au1 In2 119.192(16) 25 . ?
Ag2 In2 Ag2 180.0 17_656 17_655 ?
Ag2 In2 In2 0.0 17_656 17_656 ?
Ag2 In2 In2 180.0 17_655 17_656 ?
Ag2 In2 In2 180.0 17_656 17_655 ?
Ag2 In2 In2 0.0 17_655 17_655 ?
In2 In2 In2 180.0 17_656 17_655 ?
Ag2 In2 Ag1 62.182(8) 17_656 27 ?
Ag2 In2 Ag1 117.818(8) 17_655 27 ?
In2 In2 Ag1 62.182(8) 17_656 27 ?
In2 In2 Ag1 117.818(8) 17_655 27 ?
Ag2 In2 Ag1 117.818(7) 17_656 19 ?
Ag2 In2 Ag1 62.182(7) 17_655 19 ?
In2 In2 Ag1 117.818(7) 17_656 19 ?
In2 In2 Ag1 62.182(7) 17_655 19 ?
Ag1 In2 Ag1 157.41(2) 27 19 ?
Ag2 In2 Au1 62.182(8) 17_656 27 ?
Ag2 In2 Au1 117.818(8) 17_655 27 ?
In2 In2 Au1 62.182(8) 17_656 27 ?
In2 In2 Au1 117.818(8) 17_655 27 ?
Ag1 In2 Au1 0.0 27 27 ?
Ag1 In2 Au1 157.4 19 27 ?
Ag2 In2 Au1 117.818(7) 17_656 19 ?
Ag2 In2 Au1 62.182(7) 17_655 19 ?
In2 In2 Au1 117.818(7) 17_656 19 ?
In2 In2 Au1 62.182(7) 17_655 19 ?
Ag1 In2 Au1 157.4 27 19 ?
Ag1 In2 Au1 0.0 19 19 ?
Au1 In2 Au1 157.41(2) 27 19 ?
Ag2 In2 Au1 117.818(7) 17_656 . ?
Ag2 In2 Au1 62.182(7) 17_655 . ?
In2 In2 Au1 117.818(7) 17_656 . ?
In2 In2 Au1 62.182(7) 17_655 . ?
Ag1 In2 Au1 102.6 27 . ?
Ag1 In2 Au1 96.9 19 . ?
Au1 In2 Au1 102.578(11) 27 . ?
Au1 In2 Au1 96.90(2) 19 . ?
Ag2 In2 Au1 117.818(7) 17_656 3_655 ?
Ag2 In2 Au1 62.182(7) 17_655 3_655 ?
In2 In2 Au1 117.818(7) 17_656 3_655 ?
In2 In2 Au1 62.182(7) 17_655 3_655 ?
Ag1 In2 Au1 60.8 27 3_655 ?
Ag1 In2 Au1 124.4 19 3_655 ?
Au1 In2 Au1 60.808(16) 27 3_655 ?
Au1 In2 Au1 124.365(15) 19 3_655 ?
Au1 In2 Au1 56.25(3) . 3_655 ?
Ag2 In2 Au1 62.182(8) 17_656 11_545 ?
Ag2 In2 Au1 117.818(8) 17_655 11_545 ?
In2 In2 Au1 62.182(8) 17_656 11_545 ?
In2 In2 Au1 117.818(8) 17_655 11_545 ?
Ag1 In2 Au1 124.4 27 11_545 ?
Ag1 In2 Au1 60.8 19 11_545 ?
Au1 In2 Au1 124.365(17) 27 11_545 ?
Au1 In2 Au1 60.808(16) 19 11_545 ?
Au1 In2 Au1 102.578(16) . 11_545 ?
Au1 In2 Au1 157.41(2) 3_655 11_545 ?

_refine_diff_density_max         3.832
_refine_diff_density_min         -2.425
_refine_diff_density_rms         0.671

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_afid
_database_code_depnum_ccdc_archive 'CCDC 1566147'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ag3.21 Cu1.79 Eu In'
_chemical_formula_weight         726.89

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Pnma

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   8.8995(12)
_cell_length_b                   5.3795(8)
_cell_length_c                   11.2661(13)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     539.36(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    7443
_cell_measurement_theta_min      2.92
_cell_measurement_theta_max      27.89

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    8.952
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1259
_exptl_absorpt_coefficient_mu    33.803
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.05
_exptl_absorpt_correction_T_max  0.08
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            7443
_diffrn_reflns_av_R_equivalents  0.0843
_diffrn_reflns_av_sigmaI/netI    0.0536
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_theta_min         2.92
_diffrn_reflns_theta_max         27.89
_reflns_number_total             709
_reflns_number_gt                565
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0442P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         709
_refine_ls_number_parameters     43
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0480
_refine_ls_R_factor_gt           0.0355
_refine_ls_wR_factor_ref         0.0907
_refine_ls_wR_factor_gt          0.0861
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.24234(8) 0.2500 0.56169(6) 0.0216(3) Uani 1 2 d S . .
In2 In 0.35371(11) 0.2500 0.85434(8) 0.0217(3) Uani 1 2 d S . .
Ag3 Ag 0.43446(11) 0.50480(19) 0.30617(8) 0.0224(4) Uani 0.351(12) 1 d P . .
Cu3 Cu 0.43446(11) 0.50480(19) 0.30617(8) 0.0224(4) Uani 0.649(12) 1 d P . .
Ag4 Ag 0.08688(12) 0.2500 0.01498(10) 0.0233(5) Uani 0.877(15) 2 d SP . .
Cu4 Cu 0.08688(12) 0.2500 0.01498(10) 0.0233(5) Uani 0.123(15) 2 d SP . .
Ag5 Ag 0.18581(13) 0.2500 0.24954(10) 0.0216(5) Uani 0.632(16) 2 d SP . .
Cu5 Cu 0.18581(13) 0.2500 0.24954(10) 0.0216(5) Uani 0.368(16) 2 d SP . .
Ag6 Ag 0.44317(12) 0.2500 0.09110(9) 0.0266(3) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Cu4 3.1339(8) 2_565 ?
Eu1 Ag4 3.1339(8) 2_565 ?
Eu1 Cu4 3.1339(8) 2 ?
Eu1 Ag4 3.1339(8) 2 ?
Eu1 Ag6 3.1705(14) 6_556 ?
Eu1 Ag6 3.1733(7) 2 ?
Eu1 Ag6 3.1733(7) 2_565 ?
Eu1 Cu4 3.1856(14) 6_656 ?
Eu1 Ag4 3.1856(14) 6_656 ?
Eu1 Cu3 3.4354(12) 2_565 ?
Eu1 Ag3 3.4354(12) 2_565 ?
Eu1 Cu3 3.4354(12) 8_656 ?
In2 Ag6 2.7837(14) 1_556 ?
In2 Cu3 2.9263(13) 3_646 ?
In2 Cu3 2.9263(13) 5_666 ?
In2 Ag3 2.9263(13) 3_646 ?
In2 Ag3 2.9263(13) 5_666 ?
In2 Cu3 2.9346(13) 8_656 ?
In2 Ag3 2.9346(13) 8_656 ?
In2 Ag3 2.9346(13) 2_565 ?
In2 Cu3 2.9346(13) 2_565 ?
In2 Cu5 2.9584(7) 2 ?
In2 Ag5 2.9584(7) 2 ?
In2 Cu5 2.9584(7) 2_565 ?
Ag3 Cu3 2.638(2) 7_575 ?
Ag3 Ag3 2.638(2) 7_575 ?
Ag3 Ag5 2.6800(14) . ?
Ag3 Cu5 2.6974(14) 6_656 ?
Ag3 Ag5 2.6974(14) 6_656 ?
Ag3 Cu4 2.7037(13) 2_565 ?
Ag3 Ag4 2.7037(13) 2_565 ?
Ag3 Cu3 2.741(2) 7_565 ?
Ag3 Ag3 2.741(2) 7_565 ?
Ag3 Ag6 2.7849(13) . ?
Ag3 Cu4 2.7891(14) 6_656 ?
Ag4 Cu3 2.7037(13) 8_655 ?
Ag4 Ag3 2.7037(13) 8_655 ?
Ag4 Cu3 2.7037(13) 2_564 ?
Ag4 Ag3 2.7037(13) 2_564 ?
Ag4 Ag5 2.7854(16) . ?
Ag4 Cu3 2.7891(14) 6_556 ?
Ag4 Ag3 2.7891(14) 6_556 ?
Ag4 Cu3 2.7891(14) 4_455 ?
Ag4 Ag3 2.7891(14) 4_455 ?
Ag4 In2 2.9857(15) 1_554 ?
Ag4 Cu4 3.1209(12) 5 ?
Ag5 Cu3 2.6800(14) 7_565 ?
Ag5 Ag3 2.6800(14) 7_565 ?
Ag5 Cu3 2.6974(14) 4_455 ?
Ag5 Ag3 2.6974(14) 4_455 ?
Ag5 Cu3 2.6974(14) 6_556 ?
Ag5 Ag3 2.6974(14) 6_556 ?
Ag5 Ag6 2.8082(16) 6_556 ?
Ag5 Ag6 2.9038(16) . ?
Ag6 In2 2.7837(14) 1_554 ?
Ag6 Cu3 2.7849(13) 7_565 ?
Ag6 Ag3 2.7849(13) 7_565 ?
Ag6 Cu5 2.8082(16) 6_656 ?
Ag6 Ag5 2.8082(16) 6_656 ?
Ag6 Eu1 3.1705(13) 6_656 ?
Ag6 Eu1 3.1733(7) 2_554 ?
Ag6 Eu1 3.1733(7) 2_564 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu4 Eu1 Ag4 0.00(4) 2_565 2_565 ?
Cu4 Eu1 Cu4 118.24(4) 2_565 2 ?
Ag4 Eu1 Cu4 118.24(4) 2_565 2 ?
Cu4 Eu1 Ag4 118.24(4) 2_565 2 ?
Ag4 Eu1 Ag4 118.24(4) 2_565 2 ?
Cu4 Eu1 Ag4 0.00(4) 2 2 ?
Cu4 Eu1 Ag6 108.43(3) 2_565 6_556 ?
Ag4 Eu1 Ag6 108.43(3) 2_565 6_556 ?
Cu4 Eu1 Ag6 108.43(3) 2 6_556 ?
Ag4 Eu1 Ag6 108.43(3) 2 6_556 ?
Cu4 Eu1 Ag6 175.79(4) 2_565 2 ?
Ag4 Eu1 Ag6 175.79(4) 2_565 2 ?
Cu4 Eu1 Ag6 62.76(3) 2 2 ?
Ag4 Eu1 Ag6 62.76(3) 2 2 ?
Ag6 Eu1 Ag6 67.65(2) 6_556 2 ?
Cu4 Eu1 Ag6 62.76(3) 2_565 2_565 ?
Ag4 Eu1 Ag6 62.76(3) 2_565 2_565 ?
Cu4 Eu1 Ag6 175.79(4) 2 2_565 ?
Ag4 Eu1 Ag6 175.79(4) 2 2_565 ?
Ag6 Eu1 Ag6 67.65(2) 6_556 2_565 ?
Ag6 Eu1 Ag6 115.90(4) 2 2_565 ?
Cu4 Eu1 Cu4 59.18(2) 2_565 6_656 ?
Ag4 Eu1 Cu4 59.18(2) 2_565 6_656 ?
Cu4 Eu1 Cu4 59.18(2) 2 6_656 ?
Ag4 Eu1 Cu4 59.18(2) 2 6_656 ?
Ag6 Eu1 Cu4 131.38(4) 6_556 6_656 ?
Ag6 Eu1 Cu4 121.943(19) 2 6_656 ?
Ag6 Eu1 Cu4 121.942(19) 2_565 6_656 ?
Cu4 Eu1 Ag4 59.18(2) 2_565 6_656 ?
Ag4 Eu1 Ag4 59.18(2) 2_565 6_656 ?
Cu4 Eu1 Ag4 59.18(2) 2 6_656 ?
Ag4 Eu1 Ag4 59.18(2) 2 6_656 ?
Ag6 Eu1 Ag4 131.38(4) 6_556 6_656 ?
Ag6 Eu1 Ag4 121.943(19) 2 6_656 ?
Ag6 Eu1 Ag4 121.942(19) 2_565 6_656 ?
Cu4 Eu1 Ag4 0.00(4) 6_656 6_656 ?
Cu4 Eu1 Cu3 91.56(3) 2_565 2_565 ?
Ag4 Eu1 Cu3 91.56(3) 2_565 2_565 ?
Cu4 Eu1 Cu3 133.34(3) 2 2_565 ?
Ag4 Eu1 Cu3 133.34(3) 2 2_565 ?
Ag6 Eu1 Cu3 92.90(3) 6_556 2_565 ?
Ag6 Eu1 Cu3 90.20(3) 2 2_565 ?
Ag6 Eu1 Cu3 49.65(3) 2_565 2_565 ?
Cu4 Eu1 Cu3 131.17(3) 6_656 2_565 ?
Ag4 Eu1 Cu3 131.17(3) 6_656 2_565 ?
Cu4 Eu1 Ag3 91.56(3) 2_565 2_565 ?
Ag4 Eu1 Ag3 91.56(3) 2_565 2_565 ?
Cu4 Eu1 Ag3 133.34(3) 2 2_565 ?
Ag4 Eu1 Ag3 133.34(3) 2 2_565 ?
Ag6 Eu1 Ag3 92.90(3) 6_556 2_565 ?
Ag6 Eu1 Ag3 90.20(3) 2 2_565 ?
Ag6 Eu1 Ag3 49.65(3) 2_565 2_565 ?
Cu4 Eu1 Ag3 131.17(3) 6_656 2_565 ?
Ag4 Eu1 Ag3 131.17(3) 6_656 2_565 ?
Cu3 Eu1 Ag3 0.00(3) 2_565 2_565 ?
Cu4 Eu1 Cu3 133.34(3) 2_565 8_656 ?
Ag4 Eu1 Cu3 133.34(3) 2_565 8_656 ?
Cu4 Eu1 Cu3 91.56(3) 2 8_656 ?
Ag4 Eu1 Cu3 91.56(3) 2 8_656 ?
Ag6 Eu1 Cu3 92.90(3) 6_556 8_656 ?
Ag6 Eu1 Cu3 49.65(3) 2 8_656 ?
Ag6 Eu1 Cu3 90.20(3) 2_565 8_656 ?
Cu4 Eu1 Cu3 131.17(3) 6_656 8_656 ?
Ag4 Eu1 Cu3 131.17(3) 6_656 8_656 ?
Cu3 Eu1 Cu3 45.16(4) 2_565 8_656 ?
Ag3 Eu1 Cu3 45.16(4) 2_565 8_656 ?
Ag6 In2 Cu3 114.07(4) 1_556 3_646 ?
Ag6 In2 Cu3 114.07(4) 1_556 5_666 ?
Cu3 In2 Cu3 53.58(4) 3_646 5_666 ?
Ag6 In2 Ag3 114.07(4) 1_556 3_646 ?
Cu3 In2 Ag3 0.00(5) 3_646 3_646 ?
Cu3 In2 Ag3 53.58(4) 5_666 3_646 ?
Ag6 In2 Ag3 114.07(4) 1_556 5_666 ?
Cu3 In2 Ag3 53.58(4) 3_646 5_666 ?
Cu3 In2 Ag3 0.00(3) 5_666 5_666 ?
Ag3 In2 Ag3 53.58(4) 3_646 5_666 ?
Ag6 In2 Cu3 115.29(4) 1_556 8_656 ?
Cu3 In2 Cu3 104.25(3) 3_646 8_656 ?
Cu3 In2 Cu3 130.64(4) 5_666 8_656 ?
Ag3 In2 Cu3 104.25(3) 3_646 8_656 ?
Ag3 In2 Cu3 130.64(4) 5_666 8_656 ?
Ag6 In2 Ag3 115.29(4) 1_556 8_656 ?
Cu3 In2 Ag3 104.25(3) 3_646 8_656 ?
Cu3 In2 Ag3 130.64(4) 5_666 8_656 ?
Ag3 In2 Ag3 104.25(3) 3_646 8_656 ?
Ag3 In2 Ag3 130.64(4) 5_666 8_656 ?
Cu3 In2 Ag3 0.00(4) 8_656 8_656 ?
Ag6 In2 Ag3 115.29(4) 1_556 2_565 ?
Cu3 In2 Ag3 130.64(4) 3_646 2_565 ?
Cu3 In2 Ag3 104.25(3) 5_666 2_565 ?
Ag3 In2 Ag3 130.64(4) 3_646 2_565 ?
Ag3 In2 Ag3 104.25(3) 5_666 2_565 ?
Cu3 In2 Ag3 53.42(4) 8_656 2_565 ?
Ag3 In2 Ag3 53.42(4) 8_656 2_565 ?
Ag6 In2 Cu3 115.29(4) 1_556 2_565 ?
Cu3 In2 Cu3 130.64(4) 3_646 2_565 ?
Cu3 In2 Cu3 104.25(3) 5_666 2_565 ?
Ag3 In2 Cu3 130.64(4) 3_646 2_565 ?
Ag3 In2 Cu3 104.25(3) 5_666 2_565 ?
Cu3 In2 Cu3 53.42(4) 8_656 2_565 ?
Ag3 In2 Cu3 53.42(4) 8_656 2_565 ?
Ag3 In2 Cu3 0.000(19) 2_565 2_565 ?
Ag6 In2 Cu5 114.61(3) 1_556 2 ?
Cu3 In2 Cu5 54.56(3) 3_646 2 ?
Cu3 In2 Cu5 103.88(4) 5_666 2 ?
Ag3 In2 Cu5 54.56(3) 3_646 2 ?
Ag3 In2 Cu5 103.88(4) 5_666 2 ?
Cu3 In2 Cu5 54.10(3) 8_656 2 ?
Ag3 In2 Cu5 54.10(3) 8_656 2 ?
Ag3 In2 Cu5 103.35(4) 2_565 2 ?
Cu3 In2 Cu5 103.35(4) 2_565 2 ?
Ag6 In2 Ag5 114.61(3) 1_556 2 ?
Cu3 In2 Ag5 54.56(3) 3_646 2 ?
Cu3 In2 Ag5 103.88(4) 5_666 2 ?
Ag3 In2 Ag5 54.56(3) 3_646 2 ?
Ag3 In2 Ag5 103.88(4) 5_666 2 ?
Cu3 In2 Ag5 54.10(3) 8_656 2 ?
Ag3 In2 Ag5 54.10(3) 8_656 2 ?
Ag3 In2 Ag5 103.35(4) 2_565 2 ?
Cu3 In2 Ag5 103.35(4) 2_565 2 ?
Cu5 In2 Ag5 0.00(4) 2 2 ?
Ag6 In2 Cu5 114.61(3) 1_556 2_565 ?
Cu3 In2 Cu5 103.88(4) 3_646 2_565 ?
Cu3 In2 Cu5 54.56(3) 5_666 2_565 ?
Ag3 In2 Cu5 103.88(4) 3_646 2_565 ?
Ag3 In2 Cu5 54.56(3) 5_666 2_565 ?
Cu3 In2 Cu5 103.35(4) 8_656 2_565 ?
Ag3 In2 Cu5 103.35(4) 8_656 2_565 ?
Ag3 In2 Cu5 54.10(3) 2_565 2_565 ?
Cu3 In2 Cu5 54.10(3) 2_565 2_565 ?
Cu5 In2 Cu5 130.79(5) 2 2_565 ?
Ag5 In2 Cu5 130.79(5) 2 2_565 ?
Cu3 Ag3 Ag3 0.00(6) 7_575 7_575 ?
Cu3 Ag3 Ag5 120.76(3) 7_575 . ?
Ag3 Ag3 Ag5 120.76(3) 7_575 . ?
Cu3 Ag3 Cu5 120.54(3) 7_575 6_656 ?
Ag3 Ag3 Cu5 120.54(3) 7_575 6_656 ?
Ag5 Ag3 Cu5 111.68(4) . 6_656 ?
Cu3 Ag3 Ag5 120.54(3) 7_575 6_656 ?
Ag3 Ag3 Ag5 120.54(3) 7_575 6_656 ?
Ag5 Ag3 Ag5 111.68(4) . 6_656 ?
Cu5 Ag3 Ag5 0.00(5) 6_656 6_656 ?
Cu3 Ag3 Cu4 60.80(2) 7_575 2_565 ?
Ag3 Ag3 Cu4 60.80(2) 7_575 2_565 ?
Ag5 Ag3 Cu4 113.49(5) . 2_565 ?
Cu5 Ag3 Cu4 120.57(5) 6_656 2_565 ?
Ag5 Ag3 Cu4 120.57(5) 6_656 2_565 ?
Cu3 Ag3 Ag4 60.80(2) 7_575 2_565 ?
Ag3 Ag3 Ag4 60.80(2) 7_575 2_565 ?
Ag5 Ag3 Ag4 113.49(5) . 2_565 ?
Cu5 Ag3 Ag4 120.57(5) 6_656 2_565 ?
Ag5 Ag3 Ag4 120.57(5) 6_656 2_565 ?
Cu4 Ag3 Ag4 0.00(5) 2_565 2_565 ?
Cu3 Ag3 Cu3 180.0 7_575 7_565 ?
Ag3 Ag3 Cu3 180.0 7_575 7_565 ?
Ag5 Ag3 Cu3 59.24(3) . 7_565 ?
Cu5 Ag3 Cu3 59.46(3) 6_656 7_565 ?
Ag5 Ag3 Cu3 59.46(3) 6_656 7_565 ?
Cu4 Ag3 Cu3 119.20(2) 2_565 7_565 ?
Ag4 Ag3 Cu3 119.20(2) 2_565 7_565 ?
Cu3 Ag3 Ag3 180.0 7_575 7_565 ?
Ag3 Ag3 Ag3 180.0 7_575 7_565 ?
Ag5 Ag3 Ag3 59.24(3) . 7_565 ?
Cu5 Ag3 Ag3 59.46(3) 6_656 7_565 ?
Ag5 Ag3 Ag3 59.46(3) 6_656 7_565 ?
Cu4 Ag3 Ag3 119.20(2) 2_565 7_565 ?
Ag4 Ag3 Ag3 119.20(2) 2_565 7_565 ?
Cu3 Ag3 Ag3 0.00(6) 7_565 7_565 ?
Cu3 Ag3 Ag6 119.48(2) 7_575 . ?
Ag3 Ag3 Ag6 119.48(2) 7_575 . ?
Ag5 Ag3 Ag6 64.16(4) . . ?
Cu5 Ag3 Ag6 61.60(4) 6_656 . ?
Ag5 Ag3 Ag6 61.60(4) 6_656 . ?
Cu4 Ag3 Ag6 177.55(5) 2_565 . ?
Ag4 Ag3 Ag6 177.55(5) 2_565 . ?
Cu3 Ag3 Ag6 60.52(2) 7_565 . ?
Ag3 Ag3 Ag6 60.52(2) 7_565 . ?
Cu3 Ag3 Cu4 119.44(2) 7_575 6_656 ?
Ag3 Ag3 Cu4 119.44(2) 7_575 6_656 ?
Ag5 Ag3 Cu4 108.80(4) . 6_656 ?
Cu5 Ag3 Cu4 60.99(4) 6_656 6_656 ?
Ag5 Ag3 Cu4 60.99(4) 6_656 6_656 ?
Cu4 Ag3 Cu4 69.23(3) 2_565 6_656 ?
Ag4 Ag3 Cu4 69.23(3) 2_565 6_656 ?
Cu3 Ag3 Cu4 60.56(2) 7_565 6_656 ?
Ag3 Ag3 Cu4 60.56(2) 7_565 6_656 ?
Ag6 Ag3 Cu4 111.91(4) . 6_656 ?
Cu3 Ag4 Ag3 0.000(19) 8_655 8_655 ?
Cu3 Ag4 Cu3 58.40(5) 8_655 2_564 ?
Ag3 Ag4 Cu3 58.40(5) 8_655 2_564 ?
Cu3 Ag4 Ag3 58.40(5) 8_655 2_564 ?
Ag3 Ag4 Ag3 58.40(5) 8_655 2_564 ?
Cu3 Ag4 Ag3 0.00(6) 2_564 2_564 ?
Cu3 Ag4 Ag5 147.96(3) 8_655 . ?
Ag3 Ag4 Ag5 147.96(3) 8_655 . ?
Cu3 Ag4 Ag5 147.96(3) 2_564 . ?
Ag3 Ag4 Ag5 147.96(3) 2_564 . ?
Cu3 Ag4 Cu3 146.53(5) 8_655 6_556 ?
Ag3 Ag4 Cu3 146.53(5) 8_655 6_556 ?
Cu3 Ag4 Cu3 110.77(3) 2_564 6_556 ?
Ag3 Ag4 Cu3 110.77(3) 2_564 6_556 ?
Ag5 Ag4 Cu3 57.88(3) . 6_556 ?
Cu3 Ag4 Ag3 146.53(5) 8_655 6_556 ?
Ag3 Ag4 Ag3 146.53(5) 8_655 6_556 ?
Cu3 Ag4 Ag3 110.77(3) 2_564 6_556 ?
Ag3 Ag4 Ag3 110.77(3) 2_564 6_556 ?
Ag5 Ag4 Ag3 57.88(3) . 6_556 ?
Cu3 Ag4 Ag3 0.00(4) 6_556 6_556 ?
Cu3 Ag4 Cu3 110.77(3) 8_655 4_455 ?
Ag3 Ag4 Cu3 110.77(3) 8_655 4_455 ?
Cu3 Ag4 Cu3 146.53(5) 2_564 4_455 ?
Ag3 Ag4 Cu3 146.53(5) 2_564 4_455 ?
Ag5 Ag4 Cu3 57.88(3) . 4_455 ?
Cu3 Ag4 Cu3 58.87(5) 6_556 4_455 ?
Ag3 Ag4 Cu3 58.87(5) 6_556 4_455 ?
Cu3 Ag4 Ag3 110.77(3) 8_655 4_455 ?
Ag3 Ag4 Ag3 110.77(3) 8_655 4_455 ?
Cu3 Ag4 Ag3 146.53(5) 2_564 4_455 ?
Ag3 Ag4 Ag3 146.53(5) 2_564 4_455 ?
Ag5 Ag4 Ag3 57.88(3) . 4_455 ?
Cu3 Ag4 Ag3 58.87(5) 6_556 4_455 ?
Ag3 Ag4 Ag3 58.87(5) 6_556 4_455 ?
Cu3 Ag4 Ag3 0.00(5) 4_455 4_455 ?
Cu3 Ag4 In2 61.87(3) 8_655 1_554 ?
Ag3 Ag4 In2 61.87(3) 8_655 1_554 ?
Cu3 Ag4 In2 61.87(3) 2_564 1_554 ?
Ag3 Ag4 In2 61.87(3) 2_564 1_554 ?
Ag5 Ag4 In2 108.89(5) . 1_554 ?
Cu3 Ag4 In2 145.56(3) 6_556 1_554 ?
Ag3 Ag4 In2 145.56(3) 6_556 1_554 ?
Cu3 Ag4 In2 145.56(3) 4_455 1_554 ?
Ag3 Ag4 In2 145.56(3) 4_455 1_554 ?
Cu3 Ag4 Cu4 56.68(4) 8_655 5 ?
Ag3 Ag4 Cu4 56.68(4) 8_655 5 ?
Cu3 Ag4 Cu4 106.95(6) 2_564 5 ?
Ag3 Ag4 Cu4 106.95(6) 2_564 5 ?
Ag5 Ag4 Cu4 105.02(4) . 5 ?
Cu3 Ag4 Cu4 105.11(5) 6_556 5 ?
Ag3 Ag4 Cu4 105.11(5) 6_556 5 ?
Cu3 Ag4 Cu4 54.10(3) 4_455 5 ?
Ag3 Ag4 Cu4 54.10(3) 4_455 5 ?
In2 Ag4 Cu4 109.18(4) 1_554 5 ?
Ag3 Ag5 Cu3 61.52(5) . 7_565 ?
Ag3 Ag5 Ag3 61.52(5) . 7_565 ?
Cu3 Ag5 Ag3 0.00(5) 7_565 7_565 ?
Ag3 Ag5 Cu3 179.59(5) . 4_455 ?
Cu3 Ag5 Cu3 118.70(4) 7_565 4_455 ?
Ag3 Ag5 Cu3 118.70(4) 7_565 4_455 ?
Ag3 Ag5 Ag3 179.59(5) . 4_455 ?
Cu3 Ag5 Ag3 118.70(4) 7_565 4_455 ?
Ag3 Ag5 Ag3 118.70(4) 7_565 4_455 ?
Cu3 Ag5 Ag3 0.00(6) 4_455 4_455 ?
Ag3 Ag5 Cu3 118.70(4) . 6_556 ?
Cu3 Ag5 Cu3 179.59(5) 7_565 6_556 ?
Ag3 Ag5 Cu3 179.59(5) 7_565 6_556 ?
Cu3 Ag5 Cu3 61.08(5) 4_455 6_556 ?
Ag3 Ag5 Cu3 61.08(5) 4_455 6_556 ?
Ag3 Ag5 Ag3 118.70(4) . 6_556 ?
Cu3 Ag5 Ag3 179.59(5) 7_565 6_556 ?
Ag3 Ag5 Ag3 179.59(5) 7_565 6_556 ?
Cu3 Ag5 Ag3 61.08(5) 4_455 6_556 ?
Ag3 Ag5 Ag3 61.08(5) 4_455 6_556 ?
Cu3 Ag5 Ag3 0.00(4) 6_556 6_556 ?
Ag3 Ag5 Ag4 119.13(4) . . ?
Cu3 Ag5 Ag4 119.13(4) 7_565 . ?
Ag3 Ag5 Ag4 119.13(4) 7_565 . ?
Cu3 Ag5 Ag4 61.13(4) 4_455 . ?
Ag3 Ag5 Ag4 61.13(4) 4_455 . ?
Cu3 Ag5 Ag4 61.13(4) 6_556 . ?
Ag3 Ag5 Ag4 61.13(4) 6_556 . ?
Ag3 Ag5 Ag6 118.87(5) . 6_556 ?
Cu3 Ag5 Ag6 118.87(5) 7_565 6_556 ?
Ag3 Ag5 Ag6 118.87(5) 7_565 6_556 ?
Cu3 Ag5 Ag6 60.73(4) 4_455 6_556 ?
Ag3 Ag5 Ag6 60.73(4) 4_455 6_556 ?
Cu3 Ag5 Ag6 60.73(4) 6_556 6_556 ?
Ag3 Ag5 Ag6 60.73(4) 6_556 6_556 ?
Ag4 Ag5 Ag6 111.31(5) . 6_556 ?
Ag3 Ag5 Ag6 59.67(3) . . ?
Cu3 Ag5 Ag6 59.67(3) 7_565 . ?
Ag3 Ag5 Ag6 59.67(3) 7_565 . ?
Cu3 Ag5 Ag6 120.73(4) 4_455 . ?
Ag3 Ag5 Ag6 120.73(4) 4_455 . ?
Cu3 Ag5 Ag6 120.73(4) 6_556 . ?
Ag3 Ag5 Ag6 120.73(4) 6_556 . ?
Ag4 Ag5 Ag6 70.49(4) . . ?
Ag6 Ag5 Ag6 178.19(5) 6_556 . ?
In2 Ag6 Ag3 145.67(3) 1_554 . ?
In2 Ag6 Cu3 145.67(3) 1_554 7_565 ?
Ag3 Ag6 Cu3 58.97(5) . 7_565 ?
In2 Ag6 Ag3 145.67(3) 1_554 7_565 ?
Ag3 Ag6 Ag3 58.97(5) . 7_565 ?
Cu3 Ag6 Ag3 0.00(5) 7_565 7_565 ?
In2 Ag6 Cu5 146.36(5) 1_554 6_656 ?
Ag3 Ag6 Cu5 57.67(3) . 6_656 ?
Cu3 Ag6 Cu5 57.67(3) 7_565 6_656 ?
Ag3 Ag6 Cu5 57.67(3) 7_565 6_656 ?
In2 Ag6 Ag5 146.36(5) 1_554 6_656 ?
Ag3 Ag6 Ag5 57.67(3) . 6_656 ?
Cu3 Ag6 Ag5 57.67(3) 7_565 6_656 ?
Ag3 Ag6 Ag5 57.67(3) 7_565 6_656 ?
Cu5 Ag6 Ag5 0.00(4) 6_656 6_656 ?
In2 Ag6 Ag5 111.31(5) 1_554 . ?
Ag3 Ag6 Ag5 56.17(3) . . ?
Cu3 Ag6 Ag5 56.17(3) 7_565 . ?
Ag3 Ag6 Ag5 56.17(3) 7_565 . ?
Cu5 Ag6 Ag5 102.33(3) 6_656 . ?
Ag5 Ag6 Ag5 102.33(3) 6_656 . ?
In2 Ag6 Eu1 73.73(4) 1_554 6_656 ?
Ag3 Ag6 Eu1 119.72(4) . 6_656 ?
Cu3 Ag6 Eu1 119.72(4) 7_565 6_656 ?
Ag3 Ag6 Eu1 119.72(4) 7_565 6_656 ?
Cu5 Ag6 Eu1 72.62(4) 6_656 6_656 ?
Ag5 Ag6 Eu1 72.62(4) 6_656 6_656 ?
Ag5 Ag6 Eu1 174.95(5) . 6_656 ?
In2 Ag6 Eu1 75.59(3) 1_554 2_554 ?
Ag3 Ag6 Eu1 119.57(4) . 2_554 ?
Cu3 Ag6 Eu1 70.07(3) 7_565 2_554 ?
Ag3 Ag6 Eu1 70.07(3) 7_565 2_554 ?
Cu5 Ag6 Eu1 117.83(2) 6_656 2_554 ?
Ag5 Ag6 Eu1 117.83(2) 6_656 2_554 ?
Ag5 Ag6 Eu1 69.75(2) . 2_554 ?
Eu1 Ag6 Eu1 112.35(2) 6_656 2_554 ?
In2 Ag6 Eu1 75.59(3) 1_554 2_564 ?
Ag3 Ag6 Eu1 70.07(3) . 2_564 ?
Cu3 Ag6 Eu1 119.57(4) 7_565 2_564 ?
Ag3 Ag6 Eu1 119.57(4) 7_565 2_564 ?
Cu5 Ag6 Eu1 117.83(2) 6_656 2_564 ?
Ag5 Ag6 Eu1 117.83(2) 6_656 2_564 ?
Ag5 Ag6 Eu1 69.75(2) . 2_564 ?
Eu1 Ag6 Eu1 112.35(2) 6_656 2_564 ?
Eu1 Ag6 Eu1 115.90(4) 2_554 2_564 ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        27.89
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.993
_refine_diff_density_min         -2.201
_refine_diff_density_rms         0.516
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_23
_database_code_depnum_ccdc_archive 'CCDC 1566148'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ag3.09 Cu1.91 Eu In'
_chemical_formula_weight         721.40

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   8.8834(18)
_cell_length_b                   5.3927(11)
_cell_length_c                   11.243(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     538.60(19)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    1373
_cell_measurement_theta_min      2.922
_cell_measurement_theta_max      29.252

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    8.903
_exptl_crystal_F_000             1250
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_absorpt_coefficient_mu    33.886
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.008
_exptl_absorpt_correction_T_max  0.01
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            1373
_diffrn_reflns_av_unetI/netI     0.1001
_diffrn_reflns_av_R_equivalents  0.0712
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_theta_min         2.922
_diffrn_reflns_theta_max         29.252
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             800
_reflns_number_gt                516
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0451P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         800
_refine_ls_number_parameters     43
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1047
_refine_ls_R_factor_gt           0.0551
_refine_ls_wR_factor_ref         0.1137
_refine_ls_wR_factor_gt          0.1026
_refine_ls_goodness_of_fit_ref   0.983
_refine_ls_restrained_S_all      0.983
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.24251(19) 0.2500 0.56180(12) 0.0173(4) Uani 1 2 d S T P . .
In2 In -0.1464(2) 0.2500 0.64597(16) 0.0173(5) Uani 1 2 d S T P . .
Ag3 Ag 0.5868(3) 0.2500 0.48531(19) 0.0202(10) Uani 0.93(4) 2 d S T P . .
Cu3 Cu 0.5868(3) 0.2500 0.48531(19) 0.0202(10) Uani 0.07(4) 2 d S T P . .
Ag4 Ag 0.1859(3) 0.2500 0.2493(2) 0.0176(10) Uani 0.59(4) 2 d S T P . .
Cu4 Cu 0.1859(3) 0.2500 0.2493(2) 0.0176(10) Uani 0.41(4) 2 d S T P . .
Ag5 Ag 0.5656(2) 0.0048(5) 0.69389(17) 0.0172(8) Uani 0.29(3) 1 d . . P . .
Cu5 Cu 0.5656(2) 0.0048(5) 0.69389(17) 0.0172(8) Uani 0.71(3) 1 d . . P . .
Ag6 Ag -0.0569(3) 0.2500 0.40910(18) 0.0231(6) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Cu3 3.1385(17) 5_666 ?
Eu1 Ag3 3.1385(17) 5_666 ?
Eu1 Cu3 3.1385(16) 5_656 ?
Eu1 Ag3 3.1385(16) 5_656 ?
Eu1 Ag6 3.165(3) . ?
Eu1 Ag3 3.177(3) . ?
Eu1 Ag6 3.1776(19) 5_556 ?
Eu1 Ag6 3.1776(19) 5_566 ?
Eu1 Cu5 3.430(3) 4_456 ?
Eu1 Ag5 3.430(3) 4_456 ?
Eu1 Cu5 3.430(3) 6_557 ?
In2 Ag6 2.779(3) . ?
In2 Cu5 2.922(3) 4_456 ?
In2 Ag5 2.922(3) 4_456 ?
In2 Cu5 2.922(3) 6_557 ?
In2 Ag5 2.922(3) 6_557 ?
In2 Cu5 2.930(3) 1_455 ?
In2 Ag5 2.930(3) 1_455 ?
In2 Cu5 2.930(3) 7_465 ?
In2 Ag5 2.930(3) 7_465 ?
In2 Ag4 2.9631(14) 5_566 ?
In2 Cu4 2.9631(14) 5_566 ?
In2 Ag4 2.9631(14) 5_556 ?
Ag3 Ag5 2.699(3) . ?
Ag3 Cu5 2.699(3) 7_565 ?
Ag3 Ag5 2.699(3) 7_565 ?
Ag3 Cu4 2.780(3) 6_656 ?
Ag3 Ag4 2.780(3) 6_656 ?
Ag3 Cu5 2.789(3) 5_656 ?
Ag3 Ag5 2.789(3) 5_656 ?
Ag3 Cu5 2.789(3) 3_656 ?
Ag3 Ag5 2.789(3) 3_656 ?
Ag3 In2 2.980(3) 1_655 ?
Ag3 Cu3 3.124(3) 5_656 ?
Ag4 Cu5 2.678(3) 3_656 ?
Ag4 Ag5 2.678(3) 3_656 ?
Ag4 Cu5 2.678(3) 5_656 ?
Ag4 Ag5 2.678(3) 5_656 ?
Ag4 Cu5 2.696(3) 2_554 ?
Ag4 Ag5 2.696(3) 2_554 ?
Ag4 Cu5 2.696(3) 8_665 ?
Ag4 Ag5 2.696(3) 8_665 ?
Ag4 Ag3 2.780(3) 6_556 ?
Ag4 Cu3 2.780(3) 6_556 ?
Ag4 Ag6 2.807(4) . ?
Ag4 Ag6 2.897(4) 6_656 ?
Ag5 Cu5 2.644(5) 7_565 ?
Ag5 Ag5 2.644(5) 7_565 ?
Ag5 Cu4 2.678(3) 5_656 ?
Ag5 Ag4 2.678(3) 5_656 ?
Ag5 Cu4 2.696(3) 2 ?
Ag5 Ag4 2.696(3) 2 ?
Ag5 Cu5 2.749(5) 7 ?
Ag5 Ag5 2.749(5) 7 ?
Ag5 Ag6 2.784(3) 2 ?
Ag5 Cu3 2.789(3) 5_656 ?
Ag6 Cu5 2.784(3) 2_554 ?
Ag6 Ag5 2.784(3) 2_554 ?
Ag6 Cu5 2.784(3) 8_665 ?
Ag6 Ag5 2.784(3) 8_665 ?
Ag6 Cu4 2.897(4) 6_556 ?
Ag6 Ag4 2.897(4) 6_556 ?
Ag6 Eu1 3.1776(19) 5_556 ?
Ag6 Eu1 3.1776(19) 5_566 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu3 Eu1 Ag3 0.0 5_666 5_666 ?
Cu3 Eu1 Cu3 118.43(10) 5_666 5_656 ?
Ag3 Eu1 Cu3 118.43(10) 5_666 5_656 ?
Cu3 Eu1 Ag3 118.4 5_666 5_656 ?
Ag3 Eu1 Ag3 118.43(10) 5_666 5_656 ?
Cu3 Eu1 Ag3 0.0 5_656 5_656 ?
Cu3 Eu1 Ag6 108.33(5) 5_666 . ?
Ag3 Eu1 Ag6 108.33(5) 5_666 . ?
Cu3 Eu1 Ag6 108.33(5) 5_656 . ?
Ag3 Eu1 Ag6 108.33(5) 5_656 . ?
Cu3 Eu1 Ag3 59.3 5_666 . ?
Ag3 Eu1 Ag3 59.28(5) 5_666 . ?
Cu3 Eu1 Ag3 59.3 5_656 . ?
Ag3 Eu1 Ag3 59.28(5) 5_656 . ?
Ag6 Eu1 Ag3 131.45(8) . . ?
Cu3 Eu1 Ag6 175.67(7) 5_666 5_556 ?
Ag3 Eu1 Ag6 175.67(7) 5_666 5_556 ?
Cu3 Eu1 Ag6 62.56(6) 5_656 5_556 ?
Ag3 Eu1 Ag6 62.56(6) 5_656 5_556 ?
Ag6 Eu1 Ag6 67.65(5) . 5_556 ?
Ag3 Eu1 Ag6 121.84(5) . 5_556 ?
Cu3 Eu1 Ag6 62.56(6) 5_666 5_566 ?
Ag3 Eu1 Ag6 62.56(6) 5_666 5_566 ?
Cu3 Eu1 Ag6 175.67(7) 5_656 5_566 ?
Ag3 Eu1 Ag6 175.67(7) 5_656 5_566 ?
Ag6 Eu1 Ag6 67.65(5) . 5_566 ?
Ag3 Eu1 Ag6 121.84(5) . 5_566 ?
Ag6 Eu1 Ag6 116.11(11) 5_556 5_566 ?
Cu3 Eu1 Cu5 91.45(6) 5_666 4_456 ?
Ag3 Eu1 Cu5 91.45(6) 5_666 4_456 ?
Cu3 Eu1 Cu5 133.45(7) 5_656 4_456 ?
Ag3 Eu1 Cu5 133.45(7) 5_656 4_456 ?
Ag6 Eu1 Cu5 92.83(7) . 4_456 ?
Ag3 Eu1 Cu5 131.14(7) . 4_456 ?
Ag6 Eu1 Cu5 90.39(7) 5_556 4_456 ?
Ag6 Eu1 Cu5 49.66(6) 5_566 4_456 ?
Cu3 Eu1 Ag5 91.45(6) 5_666 4_456 ?
Ag3 Eu1 Ag5 91.45(6) 5_666 4_456 ?
Cu3 Eu1 Ag5 133.45(7) 5_656 4_456 ?
Ag3 Eu1 Ag5 133.45(7) 5_656 4_456 ?
Ag6 Eu1 Ag5 92.83(7) . 4_456 ?
Ag3 Eu1 Ag5 131.14(7) . 4_456 ?
Ag6 Eu1 Ag5 90.39(7) 5_556 4_456 ?
Ag6 Eu1 Ag5 49.66(6) 5_566 4_456 ?
Cu5 Eu1 Ag5 0.0 4_456 4_456 ?
Cu3 Eu1 Cu5 133.45(7) 5_666 6_557 ?
Ag3 Eu1 Cu5 133.45(7) 5_666 6_557 ?
Cu3 Eu1 Cu5 91.45(6) 5_656 6_557 ?
Ag3 Eu1 Cu5 91.45(6) 5_656 6_557 ?
Ag6 Eu1 Cu5 92.83(7) . 6_557 ?
Ag3 Eu1 Cu5 131.14(7) . 6_557 ?
Ag6 Eu1 Cu5 49.66(6) 5_556 6_557 ?
Ag6 Eu1 Cu5 90.39(7) 5_566 6_557 ?
Cu5 Eu1 Cu5 45.35(9) 4_456 6_557 ?
Ag5 Eu1 Cu5 45.35(9) 4_456 6_557 ?
Ag6 In2 Cu5 113.95(9) . 4_456 ?
Ag6 In2 Ag5 113.95(9) . 4_456 ?
Cu5 In2 Ag5 0.0 4_456 4_456 ?
Ag6 In2 Cu5 113.95(9) . 6_557 ?
Cu5 In2 Cu5 53.81(11) 4_456 6_557 ?
Ag5 In2 Cu5 53.81(11) 4_456 6_557 ?
Ag6 In2 Ag5 113.95(9) . 6_557 ?
Cu5 In2 Ag5 53.8 4_456 6_557 ?
Ag5 In2 Ag5 53.81(11) 4_456 6_557 ?
Cu5 In2 Ag5 0.0 6_557 6_557 ?
Ag6 In2 Cu5 115.22(9) . 1_455 ?
Cu5 In2 Cu5 130.83(7) 4_456 1_455 ?
Ag5 In2 Cu5 130.83(7) 4_456 1_455 ?
Cu5 In2 Cu5 104.20(8) 6_557 1_455 ?
Ag5 In2 Cu5 104.20(8) 6_557 1_455 ?
Ag6 In2 Ag5 115.22(9) . 1_455 ?
Cu5 In2 Ag5 130.8 4_456 1_455 ?
Ag5 In2 Ag5 130.83(7) 4_456 1_455 ?
Cu5 In2 Ag5 104.2 6_557 1_455 ?
Ag5 In2 Ag5 104.20(8) 6_557 1_455 ?
Cu5 In2 Ag5 0.0 1_455 1_455 ?
Ag6 In2 Cu5 115.22(9) . 7_465 ?
Cu5 In2 Cu5 104.20(8) 4_456 7_465 ?
Ag5 In2 Cu5 104.20(8) 4_456 7_465 ?
Cu5 In2 Cu5 130.83(7) 6_557 7_465 ?
Ag5 In2 Cu5 130.83(7) 6_557 7_465 ?
Cu5 In2 Cu5 53.65(11) 1_455 7_465 ?
Ag5 In2 Cu5 53.65(11) 1_455 7_465 ?
Ag6 In2 Ag5 115.22(9) . 7_465 ?
Cu5 In2 Ag5 104.2 4_456 7_465 ?
Ag5 In2 Ag5 104.20(8) 4_456 7_465 ?
Cu5 In2 Ag5 130.8 6_557 7_465 ?
Ag5 In2 Ag5 130.83(7) 6_557 7_465 ?
Cu5 In2 Ag5 53.7 1_455 7_465 ?
Ag5 In2 Ag5 53.65(11) 1_455 7_465 ?
Cu5 In2 Ag5 0.0 7_465 7_465 ?
Ag6 In2 Ag4 114.50(6) . 5_566 ?
Cu5 In2 Ag4 54.52(7) 4_456 5_566 ?
Ag5 In2 Ag4 54.52(7) 4_456 5_566 ?
Cu5 In2 Ag4 104.07(9) 6_557 5_566 ?
Ag5 In2 Ag4 104.07(9) 6_557 5_566 ?
Cu5 In2 Ag4 103.55(10) 1_455 5_566 ?
Ag5 In2 Ag4 103.55(10) 1_455 5_566 ?
Cu5 In2 Ag4 54.05(8) 7_465 5_566 ?
Ag5 In2 Ag4 54.05(8) 7_465 5_566 ?
Ag6 In2 Cu4 114.50(6) . 5_566 ?
Cu5 In2 Cu4 54.52(7) 4_456 5_566 ?
Ag5 In2 Cu4 54.52(7) 4_456 5_566 ?
Cu5 In2 Cu4 104.07(9) 6_557 5_566 ?
Ag5 In2 Cu4 104.07(9) 6_557 5_566 ?
Cu5 In2 Cu4 103.55(10) 1_455 5_566 ?
Ag5 In2 Cu4 103.55(10) 1_455 5_566 ?
Cu5 In2 Cu4 54.05(8) 7_465 5_566 ?
Ag5 In2 Cu4 54.05(8) 7_465 5_566 ?
Ag4 In2 Cu4 0.00(11) 5_566 5_566 ?
Ag6 In2 Ag4 114.50(6) . 5_556 ?
Cu5 In2 Ag4 104.07(9) 4_456 5_556 ?
Ag5 In2 Ag4 104.07(9) 4_456 5_556 ?
Cu5 In2 Ag4 54.52(7) 6_557 5_556 ?
Ag5 In2 Ag4 54.52(7) 6_557 5_556 ?
Cu5 In2 Ag4 54.05(8) 1_455 5_556 ?
Ag5 In2 Ag4 54.05(8) 1_455 5_556 ?
Cu5 In2 Ag4 103.55(10) 7_465 5_556 ?
Ag5 In2 Ag4 103.55(10) 7_465 5_556 ?
Ag4 In2 Ag4 131.00(11) 5_566 5_556 ?
Cu4 In2 Ag4 131.0 5_566 5_556 ?
Ag5 Ag3 Cu5 58.7 . 7_565 ?
Ag5 Ag3 Ag5 58.67(12) . 7_565 ?
Cu5 Ag3 Ag5 0.0 7_565 7_565 ?
Ag5 Ag3 Cu4 147.81(8) . 6_656 ?
Cu5 Ag3 Cu4 147.81(8) 7_565 6_656 ?
Ag5 Ag3 Cu4 147.81(8) 7_565 6_656 ?
Ag5 Ag3 Ag4 147.81(8) . 6_656 ?
Cu5 Ag3 Ag4 147.81(8) 7_565 6_656 ?
Ag5 Ag3 Ag4 147.81(8) 7_565 6_656 ?
Cu4 Ag3 Ag4 0.0 6_656 6_656 ?
Ag5 Ag3 Cu5 110.6 . 5_656 ?
Cu5 Ag3 Cu5 146.64(11) 7_565 5_656 ?
Ag5 Ag3 Cu5 146.64(11) 7_565 5_656 ?
Cu4 Ag3 Cu5 57.89(7) 6_656 5_656 ?
Ag4 Ag3 Cu5 57.89(7) 6_656 5_656 ?
Ag5 Ag3 Ag5 110.64(7) . 5_656 ?
Cu5 Ag3 Ag5 146.6 7_565 5_656 ?
Ag5 Ag3 Ag5 146.64(11) 7_565 5_656 ?
Cu4 Ag3 Ag5 57.89(7) 6_656 5_656 ?
Ag4 Ag3 Ag5 57.89(7) 6_656 5_656 ?
Cu5 Ag3 Ag5 0.0 5_656 5_656 ?
Ag5 Ag3 Cu5 146.6 . 3_656 ?
Cu5 Ag3 Cu5 110.64(7) 7_565 3_656 ?
Ag5 Ag3 Cu5 110.64(7) 7_565 3_656 ?
Cu4 Ag3 Cu5 57.89(7) 6_656 3_656 ?
Ag4 Ag3 Cu5 57.89(7) 6_656 3_656 ?
Cu5 Ag3 Cu5 59.03(11) 5_656 3_656 ?
Ag5 Ag3 Cu5 59.03(11) 5_656 3_656 ?
Ag5 Ag3 Ag5 146.64(11) . 3_656 ?
Cu5 Ag3 Ag5 110.6 7_565 3_656 ?
Ag5 Ag3 Ag5 110.64(7) 7_565 3_656 ?
Cu4 Ag3 Ag5 57.89(7) 6_656 3_656 ?
Ag4 Ag3 Ag5 57.89(7) 6_656 3_656 ?
Cu5 Ag3 Ag5 59.0 5_656 3_656 ?
Ag5 Ag3 Ag5 59.03(11) 5_656 3_656 ?
Cu5 Ag3 Ag5 0.0 3_656 3_656 ?
Ag5 Ag3 In2 61.88(8) . 1_655 ?
Cu5 Ag3 In2 61.88(8) 7_565 1_655 ?
Ag5 Ag3 In2 61.88(8) 7_565 1_655 ?
Cu4 Ag3 In2 108.85(12) 6_656 1_655 ?
Ag4 Ag3 In2 108.85(12) 6_656 1_655 ?
Cu5 Ag3 In2 145.47(8) 5_656 1_655 ?
Ag5 Ag3 In2 145.47(8) 5_656 1_655 ?
Cu5 Ag3 In2 145.47(8) 3_656 1_655 ?
Ag5 Ag3 In2 145.47(8) 3_656 1_655 ?
Ag5 Ag3 Cu3 56.69(8) . 5_656 ?
Cu5 Ag3 Cu3 107.26(12) 7_565 5_656 ?
Ag5 Ag3 Cu3 107.26(12) 7_565 5_656 ?
Cu4 Ag3 Cu3 104.87(8) 6_656 5_656 ?
Ag4 Ag3 Cu3 104.87(8) 6_656 5_656 ?
Cu5 Ag3 Cu3 53.95(8) 5_656 5_656 ?
Ag5 Ag3 Cu3 53.95(8) 5_656 5_656 ?
Cu5 Ag3 Cu3 105.20(12) 3_656 5_656 ?
Ag5 Ag3 Cu3 105.20(12) 3_656 5_656 ?
In2 Ag3 Cu3 109.18(9) 1_655 5_656 ?
Cu5 Ag4 Ag5 0.0 3_656 3_656 ?
Cu5 Ag4 Cu5 61.76(13) 3_656 5_656 ?
Ag5 Ag4 Cu5 61.76(13) 3_656 5_656 ?
Cu5 Ag4 Ag5 61.8 3_656 5_656 ?
Ag5 Ag4 Ag5 61.76(13) 3_656 5_656 ?
Cu5 Ag4 Ag5 0.0 5_656 5_656 ?
Cu5 Ag4 Cu5 179.46(11) 3_656 2_554 ?
Ag5 Ag4 Cu5 179.46(11) 3_656 2_554 ?
Cu5 Ag4 Cu5 118.47(10) 5_656 2_554 ?
Ag5 Ag4 Cu5 118.47(10) 5_656 2_554 ?
Cu5 Ag4 Ag5 179.5 3_656 2_554 ?
Ag5 Ag4 Ag5 179.46(11) 3_656 2_554 ?
Cu5 Ag4 Ag5 118.5 5_656 2_554 ?
Ag5 Ag4 Ag5 118.47(10) 5_656 2_554 ?
Cu5 Ag4 Ag5 0.0 2_554 2_554 ?
Cu5 Ag4 Cu5 118.47(10) 3_656 8_665 ?
Ag5 Ag4 Cu5 118.47(10) 3_656 8_665 ?
Cu5 Ag4 Cu5 179.46(11) 5_656 8_665 ?
Ag5 Ag4 Cu5 179.46(11) 5_656 8_665 ?
Cu5 Ag4 Cu5 61.30(13) 2_554 8_665 ?
Ag5 Ag4 Cu5 61.30(13) 2_554 8_665 ?
Cu5 Ag4 Ag5 118.5 3_656 8_665 ?
Ag5 Ag4 Ag5 118.47(10) 3_656 8_665 ?
Cu5 Ag4 Ag5 179.5 5_656 8_665 ?
Ag5 Ag4 Ag5 179.46(11) 5_656 8_665 ?
Cu5 Ag4 Ag5 61.3 2_554 8_665 ?
Ag5 Ag4 Ag5 61.30(13) 2_554 8_665 ?
Cu5 Ag4 Ag5 0.0 8_665 8_665 ?
Cu5 Ag4 Ag3 119.16(10) 3_656 6_556 ?
Ag5 Ag4 Ag3 119.16(10) 3_656 6_556 ?
Cu5 Ag4 Ag3 119.16(10) 5_656 6_556 ?
Ag5 Ag4 Ag3 119.16(10) 5_656 6_556 ?
Cu5 Ag4 Ag3 61.22(8) 2_554 6_556 ?
Ag5 Ag4 Ag3 61.22(8) 2_554 6_556 ?
Cu5 Ag4 Ag3 61.22(8) 8_665 6_556 ?
Ag5 Ag4 Ag3 61.22(8) 8_665 6_556 ?
Cu5 Ag4 Cu3 119.16(10) 3_656 6_556 ?
Ag5 Ag4 Cu3 119.16(10) 3_656 6_556 ?
Cu5 Ag4 Cu3 119.16(10) 5_656 6_556 ?
Ag5 Ag4 Cu3 119.16(10) 5_656 6_556 ?
Cu5 Ag4 Cu3 61.22(8) 2_554 6_556 ?
Ag5 Ag4 Cu3 61.22(8) 2_554 6_556 ?
Cu5 Ag4 Cu3 61.22(8) 8_665 6_556 ?
Ag5 Ag4 Cu3 61.22(8) 8_665 6_556 ?
Ag3 Ag4 Cu3 0.00(10) 6_556 6_556 ?
Cu5 Ag4 Ag6 118.72(10) 3_656 . ?
Ag5 Ag4 Ag6 118.72(10) 3_656 . ?
Cu5 Ag4 Ag6 118.72(10) 5_656 . ?
Ag5 Ag4 Ag6 118.72(10) 5_656 . ?
Cu5 Ag4 Ag6 60.74(8) 2_554 . ?
Ag5 Ag4 Ag6 60.74(8) 2_554 . ?
Cu5 Ag4 Ag6 60.74(8) 8_665 . ?
Ag5 Ag4 Ag6 60.74(8) 8_665 . ?
Ag3 Ag4 Ag6 111.35(12) 6_556 . ?
Cu3 Ag4 Ag6 111.35(12) 6_556 . ?
Cu5 Ag4 Ag6 59.76(8) 3_656 6_656 ?
Ag5 Ag4 Ag6 59.76(8) 3_656 6_656 ?
Cu5 Ag4 Ag6 59.76(8) 5_656 6_656 ?
Ag5 Ag4 Ag6 59.76(8) 5_656 6_656 ?
Cu5 Ag4 Ag6 120.78(10) 2_554 6_656 ?
Ag5 Ag4 Ag6 120.78(10) 2_554 6_656 ?
Cu5 Ag4 Ag6 120.78(10) 8_665 6_656 ?
Ag5 Ag4 Ag6 120.78(10) 8_665 6_656 ?
Ag3 Ag4 Ag6 70.53(10) 6_556 6_656 ?
Cu3 Ag4 Ag6 70.53(10) 6_556 6_656 ?
Ag6 Ag4 Ag6 178.12(13) . 6_656 ?
Cu5 Ag5 Ag5 0.0 7_565 7_565 ?
Cu5 Ag5 Cu4 120.88(6) 7_565 5_656 ?
Ag5 Ag5 Cu4 120.88(6) 7_565 5_656 ?
Cu5 Ag5 Ag4 120.88(6) 7_565 5_656 ?
Ag5 Ag5 Ag4 120.88(6) 7_565 5_656 ?
Cu4 Ag5 Ag4 0.0 5_656 5_656 ?
Cu5 Ag5 Cu4 120.65(6) 7_565 2 ?
Ag5 Ag5 Cu4 120.65(6) 7_565 2 ?
Cu4 Ag5 Cu4 111.50(9) 5_656 2 ?
Ag4 Ag5 Cu4 111.50(9) 5_656 2 ?
Cu5 Ag5 Ag4 120.65(6) 7_565 2 ?
Ag5 Ag5 Ag4 120.65(6) 7_565 2 ?
Cu4 Ag5 Ag4 111.5 5_656 2 ?
Ag4 Ag5 Ag4 111.50(9) 5_656 2 ?
Cu4 Ag5 Ag4 0.0 2 2 ?
Cu5 Ag5 Ag3 60.67(6) 7_565 . ?
Ag5 Ag5 Ag3 60.67(6) 7_565 . ?
Cu4 Ag5 Ag3 113.67(11) 5_656 . ?
Ag4 Ag5 Ag3 113.67(11) 5_656 . ?
Cu4 Ag5 Ag3 120.54(11) 2 . ?
Ag4 Ag5 Ag3 120.54(11) 2 . ?
Cu5 Ag5 Cu5 180.0 7_565 7 ?
Ag5 Ag5 Cu5 180.0 7_565 7 ?
Cu4 Ag5 Cu5 59.12(6) 5_656 7 ?
Ag4 Ag5 Cu5 59.12(6) 5_656 7 ?
Cu4 Ag5 Cu5 59.35(6) 2 7 ?
Ag4 Ag5 Cu5 59.35(6) 2 7 ?
Ag3 Ag5 Cu5 119.34(6) . 7 ?
Cu5 Ag5 Ag5 180.0 7_565 7 ?
Ag5 Ag5 Ag5 180.0 7_565 7 ?
Cu4 Ag5 Ag5 59.12(6) 5_656 7 ?
Ag4 Ag5 Ag5 59.12(6) 5_656 7 ?
Cu4 Ag5 Ag5 59.35(6) 2 7 ?
Ag4 Ag5 Ag5 59.35(6) 2 7 ?
Ag3 Ag5 Ag5 119.34(6) . 7 ?
Cu5 Ag5 Ag5 0.0 7 7 ?
Cu5 Ag5 Ag6 119.58(6) 7_565 2 ?
Ag5 Ag5 Ag6 119.58(6) 7_565 2 ?
Cu4 Ag5 Ag6 64.04(9) 5_656 2 ?
Ag4 Ag5 Ag6 64.04(9) 5_656 2 ?
Cu4 Ag5 Ag6 61.60(9) 2 2 ?
Ag4 Ag5 Ag6 61.60(9) 2 2 ?
Ag3 Ag5 Ag6 177.61(13) . 2 ?
Cu5 Ag5 Ag6 60.42(6) 7 2 ?
Ag5 Ag5 Ag6 60.42(6) 7 2 ?
Cu5 Ag5 Cu3 119.52(6) 7_565 5_656 ?
Ag5 Ag5 Cu3 119.52(6) 7_565 5_656 ?
Cu4 Ag5 Cu3 108.64(10) 5_656 5_656 ?
Ag4 Ag5 Cu3 108.64(10) 5_656 5_656 ?
Cu4 Ag5 Cu3 60.89(9) 2 5_656 ?
Ag4 Ag5 Cu3 60.89(9) 2 5_656 ?
Ag3 Ag5 Cu3 69.4 . 5_656 ?
Cu5 Ag5 Cu3 60.48(6) 7 5_656 ?
Ag5 Ag5 Cu3 60.48(6) 7 5_656 ?
Ag6 Ag5 Cu3 111.78(10) 2 5_656 ?
In2 Ag6 Cu5 145.57(8) . 2_554 ?
In2 Ag6 Ag5 145.57(8) . 2_554 ?
Cu5 Ag6 Ag5 0.0 2_554 2_554 ?
In2 Ag6 Cu5 145.57(8) . 8_665 ?
Cu5 Ag6 Cu5 59.16(12) 2_554 8_665 ?
Ag5 Ag6 Cu5 59.16(12) 2_554 8_665 ?
In2 Ag6 Ag5 145.57(8) . 8_665 ?
Cu5 Ag6 Ag5 59.2 2_554 8_665 ?
Ag5 Ag6 Ag5 59.16(12) 2_554 8_665 ?
Cu5 Ag6 Ag5 0.0 8_665 8_665 ?
In2 Ag6 Ag4 146.44(12) . . ?
Cu5 Ag6 Ag4 57.66(8) 2_554 . ?
Ag5 Ag6 Ag4 57.66(8) 2_554 . ?
Cu5 Ag6 Ag4 57.66(8) 8_665 . ?
Ag5 Ag6 Ag4 57.66(8) 8_665 . ?
In2 Ag6 Cu4 111.29(11) . 6_556 ?
Cu5 Ag6 Cu4 56.20(8) 2_554 6_556 ?
Ag5 Ag6 Cu4 56.20(8) 2_554 6_556 ?
Cu5 Ag6 Cu4 56.20(8) 8_665 6_556 ?
Ag5 Ag6 Cu4 56.20(8) 8_665 6_556 ?
Ag4 Ag6 Cu4 102.3 . 6_556 ?
In2 Ag6 Ag4 111.29(11) . 6_556 ?
Cu5 Ag6 Ag4 56.20(8) 2_554 6_556 ?
Ag5 Ag6 Ag4 56.20(8) 2_554 6_556 ?
Cu5 Ag6 Ag4 56.20(8) 8_665 6_556 ?
Ag5 Ag6 Ag4 56.20(8) 8_665 6_556 ?
Ag4 Ag6 Ag4 102.27(7) . 6_556 ?
Cu4 Ag6 Ag4 0.0 6_556 6_556 ?
In2 Ag6 Eu1 73.79(7) . . ?
Cu5 Ag6 Eu1 119.67(10) 2_554 . ?
Ag5 Ag6 Eu1 119.67(10) 2_554 . ?
Cu5 Ag6 Eu1 119.67(10) 8_665 . ?
Ag5 Ag6 Eu1 119.67(10) 8_665 . ?
Ag4 Ag6 Eu1 72.65(9) . . ?
Cu4 Ag6 Eu1 174.92(11) 6_556 . ?
Ag4 Ag6 Eu1 174.92(11) 6_556 . ?
In2 Ag6 Eu1 75.69(5) . 5_556 ?
Cu5 Ag6 Eu1 69.88(6) 2_554 5_556 ?
Ag5 Ag6 Eu1 69.88(6) 2_554 5_556 ?
Cu5 Ag6 Eu1 119.59(9) 8_665 5_556 ?
Ag5 Ag6 Eu1 119.59(9) 8_665 5_556 ?
Ag4 Ag6 Eu1 117.69(5) . 5_556 ?
Cu4 Ag6 Eu1 69.75(6) 6_556 5_556 ?
Ag4 Ag6 Eu1 69.75(6) 6_556 5_556 ?
Eu1 Ag6 Eu1 112.35(5) . 5_556 ?
In2 Ag6 Eu1 75.69(5) . 5_566 ?
Cu5 Ag6 Eu1 119.59(9) 2_554 5_566 ?
Ag5 Ag6 Eu1 119.59(9) 2_554 5_566 ?
Cu5 Ag6 Eu1 69.88(6) 8_665 5_566 ?
Ag5 Ag6 Eu1 69.88(6) 8_665 5_566 ?
Ag4 Ag6 Eu1 117.69(5) . 5_566 ?
Cu4 Ag6 Eu1 69.75(6) 6_556 5_566 ?
Ag4 Ag6 Eu1 69.75(6) 6_556 5_566 ?
Eu1 Ag6 Eu1 112.35(5) . 5_566 ?
Eu1 Ag6 Eu1 116.11(11) 5_556 5_566 ?

_refine_diff_density_max         2.548
_refine_diff_density_min         -3.901
_refine_diff_density_rms         0.736

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_vsaf2b_0m
_database_code_depnum_ccdc_archive 'CCDC 1566149'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ag2.39 Au2.61 Eu In'
_chemical_formula_weight         1039.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_H-M   I4/mmm

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'-x, y, -z'
'x, -y, -z'
'y, x, -z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'x, -y, z'
'-x, y, z'
'-y, -x, z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'y+1/2, x+1/2, z+1/2'

_cell_length_a                   7.1887(3)
_cell_length_b                   7.1887(3)
_cell_length_c                   5.4762(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     283.00(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    1359
_cell_measurement_theta_min      4.01
_cell_measurement_theta_max      31.68

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    12.200
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             862
_exptl_absorpt_coefficient_mu    90.453
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.1
_exptl_absorpt_correction_T_max  0.17
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            1359
_diffrn_reflns_av_R_equivalents  0.0311
_diffrn_reflns_av_sigmaI/netI    0.0196
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_theta_min         4.01
_diffrn_reflns_theta_max         31.68
_reflns_number_total             164
_reflns_number_gt                159
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0073P)²+4.2921P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0036(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         164
_refine_ls_number_parameters     12
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0169
_refine_ls_R_factor_gt           0.0162
_refine_ls_wR_factor_ref         0.0319
_refine_ls_wR_factor_gt          0.0317
_refine_ls_goodness_of_fit_ref   1.243
_refine_ls_restrained_S_all      1.243
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 0.0000 0.0000 0.0097(3) Uani 1 16 d S . .
Au1 Au 0.30646(4) 0.30646(4) 0.0000 0.01014(17) Uani 0.653(7) 4 d SP . .
Ag1 Ag 0.30646(4) 0.30646(4) 0.0000 0.01014(17) Uani 0.347(7) 4 d SP . .
In2 In 0.0000 0.5000 0.2500 0.0097(3) Uani 0.50 8 d SP . .
Ag2 Ag 0.0000 0.5000 0.2500 0.0097(3) Uani 0.50 8 d SP . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Au1 3.1156(5) . ?
Eu1 Ag1 3.1156(5) 17 ?
Eu1 Au1 3.1156(5) 17 ?
Eu1 Ag1 3.1156(5) 19 ?
Eu1 Au1 3.1156(5) 19 ?
Eu1 Ag1 3.1156(5) 3 ?
Eu1 Au1 3.1156(5) 3 ?
Eu1 Au1 3.3717(3) 9_444 ?
Eu1 Ag1 3.3717(3) 9_444 ?
Eu1 Au1 3.3717(3) 25 ?
Eu1 Ag1 3.3717(3) 25 ?
Au1 Ag1 2.7826(6) 3_655 ?
Au1 Au1 2.7826(6) 3_655 ?
Au1 Ag1 2.7826(6) 19_565 ?
Au1 Au1 2.7826(6) 19_565 ?
Au1 Ag2 2.94337(14) 17_565 ?
Au1 Ag2 2.94337(14) 9_544 ?
Au1 In2 2.94337(14) 17_565 ?
Au1 In2 2.94337(14) 9_544 ?
Au1 Ag2 2.94337(14) 25 ?
Au1 In2 2.94337(14) 25 ?
Au1 In2 2.94337(14) . ?
In2 Ag2 2.7381(3) 17_566 ?
In2 Ag2 2.7381(3) 17_565 ?
In2 In2 2.7381(3) 17_566 ?
In2 In2 2.7381(3) 17_565 ?
In2 Ag1 2.94338(14) 11 ?
In2 Au1 2.94338(14) 11 ?
In2 Ag1 2.94338(14) 3 ?
In2 Au1 2.94338(14) 3 ?
In2 Ag1 2.94337(14) 27_455 ?
In2 Au1 2.94337(14) 9_455 ?
In2 Ag1 2.94337(14) 9_455 ?
In2 Au1 2.94337(14) 27_455 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au1 Eu1 Ag1 180.000(8) . 17 ?
Au1 Eu1 Au1 180.000(8) . 17 ?
Ag1 Eu1 Au1 0.000(8) 17 17 ?
Au1 Eu1 Ag1 90.0 . 19 ?
Ag1 Eu1 Ag1 90.0 17 19 ?
Au1 Eu1 Ag1 90.0 17 19 ?
Au1 Eu1 Au1 90.0 . 19 ?
Ag1 Eu1 Au1 90.0 17 19 ?
Au1 Eu1 Au1 90.0 17 19 ?
Ag1 Eu1 Au1 0.000(8) 19 19 ?
Au1 Eu1 Ag1 90.0 . 3 ?
Ag1 Eu1 Ag1 90.0 17 3 ?
Au1 Eu1 Ag1 90.0 17 3 ?
Ag1 Eu1 Ag1 180.000(8) 19 3 ?
Au1 Eu1 Ag1 180.000(8) 19 3 ?
Au1 Eu1 Au1 90.0 . 3 ?
Ag1 Eu1 Au1 90.0 17 3 ?
Au1 Eu1 Au1 90.0 17 3 ?
Ag1 Eu1 Au1 180.000(8) 19 3 ?
Au1 Eu1 Au1 180.000(8) 19 3 ?
Ag1 Eu1 Au1 0.000(8) 3 3 ?
Au1 Eu1 Au1 125.701(7) . 9_444 ?
Ag1 Eu1 Au1 54.299(7) 17 9_444 ?
Au1 Eu1 Au1 54.299(7) 17 9_444 ?
Ag1 Eu1 Au1 90.0 19 9_444 ?
Au1 Eu1 Au1 90.0 19 9_444 ?
Ag1 Eu1 Au1 90.0 3 9_444 ?
Au1 Eu1 Au1 90.0 3 9_444 ?
Au1 Eu1 Ag1 125.701(7) . 9_444 ?
Ag1 Eu1 Ag1 54.299(7) 17 9_444 ?
Au1 Eu1 Ag1 54.299(7) 17 9_444 ?
Ag1 Eu1 Ag1 90.0 19 9_444 ?
Au1 Eu1 Ag1 90.0 19 9_444 ?
Ag1 Eu1 Ag1 90.0 3 9_444 ?
Au1 Eu1 Ag1 90.0 3 9_444 ?
Au1 Eu1 Ag1 0.0 9_444 9_444 ?
Au1 Eu1 Au1 54.299(7) . 25 ?
Ag1 Eu1 Au1 125.701(7) 17 25 ?
Au1 Eu1 Au1 125.701(7) 17 25 ?
Ag1 Eu1 Au1 90.0 19 25 ?
Au1 Eu1 Au1 90.0 19 25 ?
Ag1 Eu1 Au1 90.0 3 25 ?
Au1 Eu1 Au1 90.0 3 25 ?
Au1 Eu1 Au1 180.000(10) 9_444 25 ?
Ag1 Eu1 Au1 180.000(10) 9_444 25 ?
Au1 Eu1 Ag1 54.299(7) . 25 ?
Ag1 Eu1 Ag1 125.701(7) 17 25 ?
Au1 Eu1 Ag1 125.701(7) 17 25 ?
Ag1 Eu1 Ag1 90.0 19 25 ?
Au1 Eu1 Ag1 90.0 19 25 ?
Ag1 Eu1 Ag1 90.0 3 25 ?
Au1 Eu1 Ag1 90.0 3 25 ?
Au1 Eu1 Ag1 180.000(10) 9_444 25 ?
Ag1 Eu1 Ag1 180.000(10) 9_444 25 ?
Au1 Eu1 Ag1 0.0 25 25 ?
Ag1 Au1 Au1 0.000(13) 3_655 3_655 ?
Ag1 Au1 Ag1 90.0 3_655 19_565 ?
Au1 Au1 Ag1 90.0 3_655 19_565 ?
Ag1 Au1 Au1 90.0 3_655 19_565 ?
Au1 Au1 Au1 90.0 3_655 19_565 ?
Ag1 Au1 Au1 0.000(13) 19_565 19_565 ?
Ag1 Au1 Ag2 138.459(7) 3_655 17_565 ?
Au1 Au1 Ag2 138.459(7) 3_655 17_565 ?
Ag1 Au1 Ag2 61.791(8) 19_565 17_565 ?
Au1 Au1 Ag2 61.791(8) 19_565 17_565 ?
Ag1 Au1 Ag2 61.791(8) 3_655 9_544 ?
Au1 Au1 Ag2 61.791(8) 3_655 9_544 ?
Ag1 Au1 Ag2 138.459(7) 19_565 9_544 ?
Au1 Au1 Ag2 138.459(7) 19_565 9_544 ?
Ag2 Au1 Ag2 119.423(7) 17_565 9_544 ?
Ag1 Au1 In2 138.459(7) 3_655 17_565 ?
Au1 Au1 In2 138.459(7) 3_655 17_565 ?
Ag1 Au1 In2 61.791(8) 19_565 17_565 ?
Au1 Au1 In2 61.791(8) 19_565 17_565 ?
Ag2 Au1 In2 0.0 17_565 17_565 ?
Ag2 Au1 In2 119.423(7) 9_544 17_565 ?
Ag1 Au1 In2 61.791(8) 3_655 9_544 ?
Au1 Au1 In2 61.791(8) 3_655 9_544 ?
Ag1 Au1 In2 138.459(7) 19_565 9_544 ?
Au1 Au1 In2 138.459(7) 19_565 9_544 ?
Ag2 Au1 In2 119.423(7) 17_565 9_544 ?
Ag2 Au1 In2 0.0 9_544 9_544 ?
In2 Au1 In2 119.423(7) 17_565 9_544 ?
Ag1 Au1 Ag2 61.791(8) 3_655 25 ?
Au1 Au1 Ag2 61.791(8) 3_655 25 ?
Ag1 Au1 Ag2 138.459(7) 19_565 25 ?
Au1 Au1 Ag2 138.459(7) 19_565 25 ?
Ag2 Au1 Ag2 157.509(17) 17_565 25 ?
Ag2 Au1 Ag2 55.437(5) 9_544 25 ?
In2 Au1 Ag2 157.509(17) 17_565 25 ?
In2 Au1 Ag2 55.437(5) 9_544 25 ?
Ag1 Au1 In2 61.791(8) 3_655 25 ?
Au1 Au1 In2 61.791(8) 3_655 25 ?
Ag1 Au1 In2 138.459(7) 19_565 25 ?
Au1 Au1 In2 138.459(7) 19_565 25 ?
Ag2 Au1 In2 157.509(17) 17_565 25 ?
Ag2 Au1 In2 55.437(5) 9_544 25 ?
In2 Au1 In2 157.509(17) 17_565 25 ?
In2 Au1 In2 55.437(5) 9_544 25 ?
Ag2 Au1 In2 0.0 25 25 ?
Ag1 Au1 In2 138.459(7) 3_655 . ?
Au1 Au1 In2 138.459(7) 3_655 . ?
Ag1 Au1 In2 61.791(8) 19_565 . ?
Au1 Au1 In2 61.791(8) 19_565 . ?
Ag2 Au1 In2 55.437(5) 17_565 . ?
Ag2 Au1 In2 157.509(17) 9_544 . ?
In2 Au1 In2 55.437(5) 17_565 . ?
In2 Au1 In2 157.509(17) 9_544 . ?
Ag2 Au1 In2 119.423(7) 25 . ?
In2 Au1 In2 119.423(7) 25 . ?
Ag2 In2 Ag2 180.0 17_566 17_565 ?
Ag2 In2 In2 0.0 17_566 17_566 ?
Ag2 In2 In2 180.0 17_565 17_566 ?
Ag2 In2 In2 180.0 17_566 17_565 ?
Ag2 In2 In2 0.0 17_565 17_565 ?
In2 In2 In2 180.0 17_566 17_565 ?
Ag2 In2 Ag1 62.281(3) 17_566 11 ?
Ag2 In2 Ag1 117.719(3) 17_565 11 ?
In2 In2 Ag1 62.281(3) 17_566 11 ?
In2 In2 Ag1 117.719(3) 17_565 11 ?
Ag2 In2 Au1 62.281(3) 17_566 11 ?
Ag2 In2 Au1 117.719(3) 17_565 11 ?
In2 In2 Au1 62.281(3) 17_566 11 ?
In2 In2 Au1 117.719(3) 17_565 11 ?
Ag1 In2 Au1 0.000(8) 11 11 ?
Ag2 In2 Ag1 117.719(3) 17_566 3 ?
Ag2 In2 Ag1 62.281(2) 17_565 3 ?
In2 In2 Ag1 117.719(3) 17_566 3 ?
In2 In2 Ag1 62.281(2) 17_565 3 ?
Ag1 In2 Ag1 157.509(17) 11 3 ?
Au1 In2 Ag1 157.509(17) 11 3 ?
Ag2 In2 Au1 117.719(3) 17_566 3 ?
Ag2 In2 Au1 62.281(2) 17_565 3 ?
In2 In2 Au1 117.719(3) 17_566 3 ?
In2 In2 Au1 62.281(2) 17_565 3 ?
Ag1 In2 Au1 157.509(17) 11 3 ?
Au1 In2 Au1 157.509(17) 11 3 ?
Ag1 In2 Au1 0.000(8) 3 3 ?
Ag2 In2 Ag1 62.281(2) 17_566 27_455 ?
Ag2 In2 Ag1 117.719(3) 17_565 27_455 ?
In2 In2 Ag1 62.281(2) 17_566 27_455 ?
In2 In2 Ag1 117.719(3) 17_565 27_455 ?
Ag1 In2 Ag1 124.563(5) 11 27_455 ?
Au1 In2 Ag1 124.563(5) 11 27_455 ?
Ag1 In2 Ag1 60.577(7) 3 27_455 ?
Au1 In2 Ag1 60.577(7) 3 27_455 ?
Ag2 In2 Au1 62.281(3) 17_566 9_455 ?
Ag2 In2 Au1 117.719(3) 17_565 9_455 ?
In2 In2 Au1 62.281(3) 17_566 9_455 ?
In2 In2 Au1 117.719(3) 17_565 9_455 ?
Ag1 In2 Au1 56.418(16) 11 9_455 ?
Au1 In2 Au1 56.418(16) 11 9_455 ?
Ag1 In2 Au1 102.494(2) 3 9_455 ?
Au1 In2 Au1 102.494(2) 3 9_455 ?
Ag1 In2 Au1 96.918(15) 27_455 9_455 ?
Ag2 In2 Ag1 62.281(3) 17_566 9_455 ?
Ag2 In2 Ag1 117.719(3) 17_565 9_455 ?
In2 In2 Ag1 62.281(3) 17_566 9_455 ?
In2 In2 Ag1 117.719(3) 17_565 9_455 ?
Ag1 In2 Ag1 56.418(16) 11 9_455 ?
Au1 In2 Ag1 56.418(16) 11 9_455 ?
Ag1 In2 Ag1 102.494(2) 3 9_455 ?
Au1 In2 Ag1 102.494(2) 3 9_455 ?
Ag1 In2 Ag1 96.918(15) 27_455 9_455 ?
Au1 In2 Ag1 0.000(11) 9_455 9_455 ?
Ag2 In2 Au1 62.281(2) 17_566 27_455 ?
Ag2 In2 Au1 117.719(3) 17_565 27_455 ?
In2 In2 Au1 62.281(2) 17_566 27_455 ?
In2 In2 Au1 117.719(3) 17_565 27_455 ?
Ag1 In2 Au1 124.563(5) 11 27_455 ?
Au1 In2 Au1 124.563(5) 11 27_455 ?
Ag1 In2 Au1 60.577(7) 3 27_455 ?
Au1 In2 Au1 60.577(7) 3 27_455 ?
Ag1 In2 Au1 0.000(3) 27_455 27_455 ?
Au1 In2 Au1 96.918(15) 9_455 27_455 ?
Ag1 In2 Au1 96.918(15) 9_455 27_455 ?

_diffrn_measured_fraction_theta_max 0.988
_diffrn_reflns_theta_full        31.68
_diffrn_measured_fraction_theta_full 0.988
_refine_diff_density_max         1.503
_refine_diff_density_min         -2.075
_refine_diff_density_rms         0.362
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_af7_0m
_database_code_depnum_ccdc_archive 'CCDC 1566155'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_shelx_SHELXL_version_number     97
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Au4.61 Cu0.39 Eu In'
_chemical_formula_weight         1199.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      tetragonal
_space_group_IT_number           139
_space_group_name_H-M_alt        'I 4/m m m'
_space_group_name_Hall           '-I 4 2'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'-x, y, -z'
'x, -y, -z'
'y, x, -z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'x, -y, z'
'-x, y, z'
'-y, -x, z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'y+1/2, x+1/2, z+1/2'

_cell_length_a                   7.139(2)
_cell_length_b                   7.139(2)
_cell_length_c                   5.417(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     276.1(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    909
_cell_measurement_theta_min      4.724
_cell_measurement_theta_max      31.889

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    14.433
_exptl_crystal_F_000             975
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_absorpt_coefficient_mu    138.636
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.02
_exptl_absorpt_correction_T_max  0.03
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            990
_diffrn_reflns_av_unetI/netI     0.0261
_diffrn_reflns_av_R_equivalents  0.0401
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_theta_min         4.724
_diffrn_reflns_theta_max         31.889
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.963
_diffrn_measured_fraction_theta_full 0.978
_diffrn_reflns_Laue_measured_fraction_max 0.963
_diffrn_reflns_Laue_measured_fraction_full 0.978
_diffrn_reflns_point_group_measured_fraction_max 0.963
_diffrn_reflns_point_group_measured_fraction_full 0.978
_reflns_number_total             158
_reflns_number_gt                145
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0407P)²+11.0268P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         158
_refine_ls_number_parameters     10
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0366
_refine_ls_R_factor_gt           0.0338
_refine_ls_wR_factor_ref         0.0760
_refine_ls_wR_factor_gt          0.0751
_refine_ls_goodness_of_fit_ref   1.189
_refine_ls_restrained_S_all      1.189
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 0.0000 0.5000 0.0083(5) Uani 1 16 d S T P . .
Au1 Au 0.19440(9) 0.19440(9) 0.0000 0.0104(3) Uani 1 4 d S T P . .
Au2 Au 0.0000 0.5000 0.2500 0.0113(7) Uani 0.306(14) 8 d S T P . .
Cu2 Cu 0.0000 0.5000 0.2500 0.0113(7) Uani 0.194(14) 8 d S T P . .
In2 In 0.0000 0.5000 0.2500 0.0113(7) Uani 0.5 8 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Au1 3.0855(13) 25 ?
Eu1 Au1 3.0855(13) 9_445 ?
Eu1 Au1 3.0855(13) 27_455 ?
Eu1 Au1 3.0855(13) 11_545 ?
Eu1 Au1 3.3448(15) 1_556 ?
Eu1 Au1 3.3448(15) 17 ?
Eu1 Au1 3.3448(15) 19_556 ?
Eu1 Au1 3.3448(15) 19 ?
Eu1 Au1 3.3448(15) 3_556 ?
Eu1 Au1 3.3448(15) 3 ?
Eu1 Au1 3.3448(15) 17_556 ?
Eu1 Au1 3.3448(15) . ?
Au1 Au1 2.7757(15) 19 ?
Au1 Au1 2.7757(15) 3 ?
Au1 In2 2.9189(8) 25 ?
Au1 Cu2 2.9189(8) 25 ?
Au1 Au2 2.9189(8) 25 ?
Au1 Au2 2.9189(8) . ?
Au1 In2 2.9189(8) 9_544 ?
Au1 Cu2 2.9189(8) 9_544 ?
Au1 Au2 2.9189(8) 9_544 ?
Au1 In2 2.9189(8) 17_565 ?
Au2 In2 2.7084(17) 17_566 ?
Au2 In2 2.7084(17) 17_565 ?
Au2 Cu2 2.7084(17) 17_566 ?
Au2 Cu2 2.7084(17) 17_565 ?
Au2 Au2 2.7084(17) 17_566 ?
Au2 Au2 2.7084(17) 17_565 ?
Au2 Au1 2.9189(8) 11 ?
Au2 Au1 2.9189(8) 3 ?
Au2 Au1 2.9189(8) 25 ?
Au2 Au1 2.9189(8) 27_455 ?
Au2 Au1 2.9189(8) 19_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au1 Eu1 Au1 180.000(17) 25 9_445 ?
Au1 Eu1 Au1 90.0 25 27_455 ?
Au1 Eu1 Au1 90.0 9_445 27_455 ?
Au1 Eu1 Au1 90.0 25 11_545 ?
Au1 Eu1 Au1 90.0 9_445 11_545 ?
Au1 Eu1 Au1 180.0 27_455 11_545 ?
Au1 Eu1 Au1 54.07(2) 25 1_556 ?
Au1 Eu1 Au1 125.93(2) 9_445 1_556 ?
Au1 Eu1 Au1 90.0 27_455 1_556 ?
Au1 Eu1 Au1 90.0 11_545 1_556 ?
Au1 Eu1 Au1 125.93(2) 25 17 ?
Au1 Eu1 Au1 54.07(2) 9_445 17 ?
Au1 Eu1 Au1 90.0 27_455 17 ?
Au1 Eu1 Au1 90.0 11_545 17 ?
Au1 Eu1 Au1 180.0 1_556 17 ?
Au1 Eu1 Au1 90.0 25 19_556 ?
Au1 Eu1 Au1 90.0 9_445 19_556 ?
Au1 Eu1 Au1 125.93(2) 27_455 19_556 ?
Au1 Eu1 Au1 54.07(2) 11_545 19_556 ?
Au1 Eu1 Au1 49.03(3) 1_556 19_556 ?
Au1 Eu1 Au1 130.97(3) 17 19_556 ?
Au1 Eu1 Au1 90.0 25 19 ?
Au1 Eu1 Au1 90.0 9_445 19 ?
Au1 Eu1 Au1 125.93(2) 27_455 19 ?
Au1 Eu1 Au1 54.07(2) 11_545 19 ?
Au1 Eu1 Au1 130.97(3) 1_556 19 ?
Au1 Eu1 Au1 49.03(3) 17 19 ?
Au1 Eu1 Au1 108.14(5) 19_556 19 ?
Au1 Eu1 Au1 90.0 25 3_556 ?
Au1 Eu1 Au1 90.0 9_445 3_556 ?
Au1 Eu1 Au1 54.07(2) 27_455 3_556 ?
Au1 Eu1 Au1 125.93(2) 11_545 3_556 ?
Au1 Eu1 Au1 49.03(3) 1_556 3_556 ?
Au1 Eu1 Au1 130.97(3) 17 3_556 ?
Au1 Eu1 Au1 71.86(5) 19_556 3_556 ?
Au1 Eu1 Au1 180.00(2) 19 3_556 ?
Au1 Eu1 Au1 90.0 25 3 ?
Au1 Eu1 Au1 90.0 9_445 3 ?
Au1 Eu1 Au1 54.07(2) 27_455 3 ?
Au1 Eu1 Au1 125.93(2) 11_545 3 ?
Au1 Eu1 Au1 130.97(3) 1_556 3 ?
Au1 Eu1 Au1 49.03(3) 17 3 ?
Au1 Eu1 Au1 180.0 19_556 3 ?
Au1 Eu1 Au1 71.86(5) 19 3 ?
Au1 Eu1 Au1 108.14(5) 3_556 3 ?
Au1 Eu1 Au1 125.93(2) 25 17_556 ?
Au1 Eu1 Au1 54.07(2) 9_445 17_556 ?
Au1 Eu1 Au1 90.0 27_455 17_556 ?
Au1 Eu1 Au1 90.0 11_545 17_556 ?
Au1 Eu1 Au1 71.86(5) 1_556 17_556 ?
Au1 Eu1 Au1 108.14(5) 17 17_556 ?
Au1 Eu1 Au1 49.03(3) 19_556 17_556 ?
Au1 Eu1 Au1 130.97(3) 19 17_556 ?
Au1 Eu1 Au1 49.03(3) 3_556 17_556 ?
Au1 Eu1 Au1 130.97(3) 3 17_556 ?
Au1 Eu1 Au1 54.07(2) 25 . ?
Au1 Eu1 Au1 125.93(2) 9_445 . ?
Au1 Eu1 Au1 90.0 27_455 . ?
Au1 Eu1 Au1 90.0 11_545 . ?
Au1 Eu1 Au1 108.14(5) 1_556 . ?
Au1 Eu1 Au1 71.86(5) 17 . ?
Au1 Eu1 Au1 130.97(3) 19_556 . ?
Au1 Eu1 Au1 49.03(3) 19 . ?
Au1 Eu1 Au1 130.97(3) 3_556 . ?
Au1 Eu1 Au1 49.03(3) 3 . ?
Au1 Eu1 Au1 180.0 17_556 . ?
Au1 Au1 Au1 90.0 19 3 ?
Au1 Au1 In2 61.610(17) 19 25 ?
Au1 Au1 In2 138.370(18) 3 25 ?
Au1 Au1 Cu2 61.610(17) 19 25 ?
Au1 Au1 Cu2 138.370(18) 3 25 ?
In2 Au1 Cu2 0.0 25 25 ?
Au1 Au1 Au2 61.610(17) 19 25 ?
Au1 Au1 Au2 138.370(18) 3 25 ?
In2 Au1 Au2 0.0 25 25 ?
Cu2 Au1 Au2 0.0 25 25 ?
Au1 Au1 Au2 138.370(18) 19 . ?
Au1 Au1 Au2 61.610(17) 3 . ?
In2 Au1 Au2 119.7 25 . ?
Cu2 Au1 Au2 119.7 25 . ?
Au2 Au1 Au2 119.71(3) 25 . ?
Au1 Au1 In2 61.610(17) 19 9_544 ?
Au1 Au1 In2 138.370(18) 3 9_544 ?
In2 Au1 In2 55.28(3) 25 9_544 ?
Cu2 Au1 In2 55.28(3) 25 9_544 ?
Au2 Au1 In2 55.28(3) 25 9_544 ?
Au2 Au1 In2 157.8 . 9_544 ?
Au1 Au1 Cu2 61.610(17) 19 9_544 ?
Au1 Au1 Cu2 138.370(18) 3 9_544 ?
In2 Au1 Cu2 55.28(3) 25 9_544 ?
Cu2 Au1 Cu2 55.28(3) 25 9_544 ?
Au2 Au1 Cu2 55.28(3) 25 9_544 ?
Au2 Au1 Cu2 157.8 . 9_544 ?
In2 Au1 Cu2 0.0 9_544 9_544 ?
Au1 Au1 Au2 61.610(17) 19 9_544 ?
Au1 Au1 Au2 138.370(18) 3 9_544 ?
In2 Au1 Au2 55.3 25 9_544 ?
Cu2 Au1 Au2 55.3 25 9_544 ?
Au2 Au1 Au2 55.28(3) 25 9_544 ?
Au2 Au1 Au2 157.82(3) . 9_544 ?
In2 Au1 Au2 0.0 9_544 9_544 ?
Cu2 Au1 Au2 0.0 9_544 9_544 ?
Au1 Au1 In2 138.370(18) 19 17_565 ?
Au1 Au1 In2 61.610(17) 3 17_565 ?
In2 Au1 In2 157.82(3) 25 17_565 ?
Cu2 Au1 In2 157.82(3) 25 17_565 ?
Au2 Au1 In2 157.82(3) 25 17_565 ?
Au2 Au1 In2 55.3 . 17_565 ?
In2 Au1 In2 119.71(3) 9_544 17_565 ?
Cu2 Au1 In2 119.71(3) 9_544 17_565 ?
Au2 Au1 In2 119.71(3) 9_544 17_565 ?
In2 Au2 In2 180.0 17_566 17_565 ?
In2 Au2 Cu2 0.0 17_566 17_566 ?
In2 Au2 Cu2 180.0 17_565 17_566 ?
In2 Au2 Cu2 180.0 17_566 17_565 ?
In2 Au2 Cu2 0.0 17_565 17_565 ?
Cu2 Au2 Cu2 180.0 17_566 17_565 ?
In2 Au2 Au2 0.0 17_566 17_566 ?
In2 Au2 Au2 180.0 17_565 17_566 ?
Cu2 Au2 Au2 0.0 17_566 17_566 ?
Cu2 Au2 Au2 180.0 17_565 17_566 ?
In2 Au2 Au2 180.0 17_566 17_565 ?
In2 Au2 Au2 0.0 17_565 17_565 ?
Cu2 Au2 Au2 180.0 17_566 17_565 ?
Cu2 Au2 Au2 0.0 17_565 17_565 ?
Au2 Au2 Au2 180.0 17_566 17_565 ?
In2 Au2 Au1 117.641(17) 17_566 . ?
In2 Au2 Au1 62.359(17) 17_565 . ?
Cu2 Au2 Au1 117.641(17) 17_566 . ?
Cu2 Au2 Au1 62.359(17) 17_565 . ?
Au2 Au2 Au1 117.641(17) 17_566 . ?
Au2 Au2 Au1 62.359(17) 17_565 . ?
In2 Au2 Au1 62.359(17) 17_566 11 ?
In2 Au2 Au1 117.641(17) 17_565 11 ?
Cu2 Au2 Au1 62.359(17) 17_566 11 ?
Cu2 Au2 Au1 117.641(17) 17_565 11 ?
Au2 Au2 Au1 62.359(17) 17_566 11 ?
Au2 Au2 Au1 117.641(17) 17_565 11 ?
Au1 Au2 Au1 102.429(14) . 11 ?
In2 Au2 Au1 117.641(17) 17_566 3 ?
In2 Au2 Au1 62.359(17) 17_565 3 ?
Cu2 Au2 Au1 117.641(17) 17_566 3 ?
Cu2 Au2 Au1 62.359(17) 17_565 3 ?
Au2 Au2 Au1 117.641(17) 17_566 3 ?
Au2 Au2 Au1 62.359(17) 17_565 3 ?
Au1 Au2 Au1 56.78(3) . 3 ?
Au1 Au2 Au1 157.82(3) 11 3 ?
In2 Au2 Au1 62.359(17) 17_566 25 ?
In2 Au2 Au1 117.641(17) 17_565 25 ?
Cu2 Au2 Au1 62.359(17) 17_566 25 ?
Cu2 Au2 Au1 117.641(17) 17_565 25 ?
Au2 Au2 Au1 62.359(17) 17_566 25 ?
Au2 Au2 Au1 117.641(17) 17_565 25 ?
Au1 Au2 Au1 60.29(3) . 25 ?
Au1 Au2 Au1 56.78(3) 11 25 ?
Au1 Au2 Au1 102.429(14) 3 25 ?
In2 Au2 Au1 62.359(16) 17_566 27_455 ?
In2 Au2 Au1 117.641(17) 17_565 27_455 ?
Cu2 Au2 Au1 62.359(16) 17_566 27_455 ?
Cu2 Au2 Au1 117.641(17) 17_565 27_455 ?
Au2 Au2 Au1 62.359(16) 17_566 27_455 ?
Au2 Au2 Au1 117.641(17) 17_565 27_455 ?
Au1 Au2 Au1 102.430(14) . 27_455 ?
Au1 Au2 Au1 124.72(3) 11 27_455 ?
Au1 Au2 Au1 60.29(3) 3 27_455 ?
Au1 Au2 Au1 96.74(4) 25 27_455 ?
In2 Au2 Au1 117.641(17) 17_566 19_565 ?
In2 Au2 Au1 62.359(16) 17_565 19_565 ?
Cu2 Au2 Au1 117.641(17) 17_566 19_565 ?
Cu2 Au2 Au1 62.359(16) 17_565 19_565 ?
Au2 Au2 Au1 117.641(17) 17_566 19_565 ?
Au2 Au2 Au1 62.359(16) 17_565 19_565 ?
Au1 Au2 Au1 96.74(4) . 19_565 ?
Au1 Au2 Au1 60.29(3) 11 19_565 ?
Au1 Au2 Au1 124.72(3) 3 19_565 ?
Au1 Au2 Au1 102.429(14) 25 19_565 ?
Au1 Au2 Au1 157.82(3) 27_455 19_565 ?

_refine_diff_density_max         2.412
_refine_diff_density_min         -4.532
_refine_diff_density_rms         0.935

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_vsAg4Au_0m
_database_code_depnum_ccdc_archive 'CCDC 1566153'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ag4.15 Au0.85 Eu In'
_chemical_formula_weight         882.08

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'x+1/2, -y+1/2, -z+1/2'
'-x, y+1/2, -z'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, z-1/2'
'x, -y-1/2, z'
'x-1/2, y, -z-1/2'

_cell_length_a                   9.0774(17)
_cell_length_b                   5.6371(10)
_cell_length_c                   11.382(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     582.41(19)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5098
_cell_measurement_theta_min      2.870
_cell_measurement_theta_max      29.995

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    10.060
_exptl_crystal_F_000             1497
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_absorpt_coefficient_mu    49.373
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.1
_exptl_absorpt_correction_T_max  0.2
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       'w and f scan'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            5098
_diffrn_reflns_av_unetI/netI     0.0299
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.870
_diffrn_reflns_theta_max         29.995
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             923
_reflns_number_gt                797
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0244P)²+2.7793P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         923
_refine_ls_number_parameters     44
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0437
_refine_ls_R_factor_gt           0.0345
_refine_ls_wR_factor_ref         0.0654
_refine_ls_wR_factor_gt          0.0630
_refine_ls_goodness_of_fit_ref   1.262
_refine_ls_restrained_S_all      1.262
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.24104(7) 0.2500 0.55926(6) 0.01306(19) Uani 1 2 d S T P . .
In2 In 0.35337(9) 0.2500 0.85467(7) 0.0098(2) Uani 1 2 d S T P . .
Au3 Au 0.43474(6) 0.50656(11) 0.30606(5) 0.0101(2) Uani 0.037(5) 1 d . . P . .
Ag3 Ag 0.43474(6) 0.50656(11) 0.30606(5) 0.0101(2) Uani 0.963(5) 1 d . . P . .
Au4 Au 0.09627(9) 0.2500 0.01815(7) 0.0146(3) Uani 0.286(6) 2 d S T P . .
Ag4 Ag 0.09627(9) 0.2500 0.01815(7) 0.0146(3) Uani 0.714(6) 2 d S T P . .
Au5 Au 0.18249(10) 0.2500 0.25817(8) 0.0120(3) Uani 0.024(6) 2 d S T P . .
Ag5 Ag 0.18249(10) 0.2500 0.25817(8) 0.0120(3) Uani 0.976(6) 2 d S T P . .
Au6 Au 0.43257(8) 0.2500 0.08630(6) 0.0175(3) Uani 0.469(6) 2 d S T P . .
Ag6 Ag 0.43257(8) 0.2500 0.08630(6) 0.0175(3) Uani 0.531(6) 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Ag4 3.2162(7) 6_666 ?
Eu1 Au4 3.2162(7) 6_666 ?
Eu1 Ag4 3.2162(7) 6_656 ?
Eu1 Au4 3.2162(7) 6_656 ?
Eu1 Ag6 3.2439(6) 6_656 ?
Eu1 Au6 3.2439(6) 6_656 ?
Eu1 Ag6 3.2439(7) 6_666 ?
Eu1 Au6 3.2439(7) 6_666 ?
Eu1 Ag6 3.2535(10) 2_455 ?
Eu1 Au6 3.2535(10) 2_455 ?
Eu1 Ag4 3.3428(12) 2 ?
Eu1 Au4 3.3428(12) 2 ?
In2 Ag6 2.7326(12) 1_556 ?
In2 Au6 2.7326(12) 1_556 ?
In2 Ag4 2.9848(12) 1_556 ?
In2 Au4 2.9848(12) 1_556 ?
In2 Ag3 2.9882(10) 3_646 ?
In2 Au3 2.9882(10) 5_666 ?
In2 Ag3 2.9882(10) 5_666 ?
In2 Au3 2.9882(10) 3_646 ?
In2 Au3 3.0048(10) 6_656 ?
In2 Ag3 3.0048(10) 6_656 ?
In2 Ag3 3.0048(10) 4_565 ?
In2 Au3 3.0048(10) 4_565 ?
Au3 Ag3 2.7447(13) 7_575 ?
Au3 Au3 2.7447(13) 7_575 ?
Au3 Au5 2.7626(10) . ?
Au3 Ag5 2.7719(10) 2 ?
Au3 Au5 2.7719(10) 2 ?
Au3 Ag4 2.7910(10) 6_666 ?
Au3 Au4 2.7910(10) 6_666 ?
Au3 Ag4 2.8714(10) 2 ?
Au3 Au4 2.8714(10) 2 ?
Au3 Au6 2.8894(9) . ?
Au4 Ag3 2.7910(10) 6_655 ?
Au4 Au3 2.7910(10) 6_655 ?
Au4 Ag3 2.7910(10) 4_564 ?
Au4 Au3 2.7910(10) 4_564 ?
Au4 Au5 2.8418(13) . ?
Au4 Ag3 2.8714(10) 8_556 ?
Au4 Au3 2.8714(10) 8_556 ?
Au4 Ag3 2.8714(10) 2_455 ?
Au4 Au3 2.8714(10) 2_455 ?
Au4 In2 2.9848(12) 1_554 ?
Au4 Au6 3.1497(12) . ?
Au5 Ag3 2.7625(10) 7_565 ?
Au5 Au3 2.7625(10) 7_565 ?
Au5 Ag3 2.7720(10) 2_455 ?
Au5 Au3 2.7720(10) 2_455 ?
Au5 Ag3 2.7720(10) 8_556 ?
Au5 Au3 2.7720(10) 8_556 ?
Au5 Ag6 2.8776(12) 2_455 ?
Au5 Au6 2.8776(12) 2_455 ?
Au6 In2 2.7326(12) 1_554 ?
Au6 Ag5 2.8777(12) 2 ?
Au6 Au5 2.8777(12) 2 ?
Au6 Ag3 2.8894(9) 7_565 ?
Au6 Au3 2.8894(9) 7_565 ?
Au6 Eu1 3.2439(7) 6_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag4 Eu1 Au4 0.0 6_666 6_666 ?
Ag4 Eu1 Ag4 122.41(3) 6_666 6_656 ?
Au4 Eu1 Ag4 122.41(3) 6_666 6_656 ?
Ag4 Eu1 Au4 122.4 6_666 6_656 ?
Au4 Eu1 Au4 122.41(3) 6_666 6_656 ?
Ag4 Eu1 Au4 0.0 6_656 6_656 ?
Ag4 Eu1 Ag6 176.69(3) 6_666 6_656 ?
Au4 Eu1 Ag6 176.69(3) 6_666 6_656 ?
Ag4 Eu1 Ag6 58.36(2) 6_656 6_656 ?
Au4 Eu1 Ag6 58.36(2) 6_656 6_656 ?
Ag4 Eu1 Au6 176.69(3) 6_666 6_656 ?
Au4 Eu1 Au6 176.69(3) 6_666 6_656 ?
Ag4 Eu1 Au6 58.36(2) 6_656 6_656 ?
Au4 Eu1 Au6 58.36(2) 6_656 6_656 ?
Ag6 Eu1 Au6 0.0 6_656 6_656 ?
Ag4 Eu1 Ag6 58.36(2) 6_666 6_666 ?
Au4 Eu1 Ag6 58.36(2) 6_666 6_666 ?
Ag4 Eu1 Ag6 176.69(3) 6_656 6_666 ?
Au4 Eu1 Ag6 176.69(3) 6_656 6_666 ?
Ag6 Eu1 Ag6 120.66(3) 6_656 6_666 ?
Au6 Eu1 Ag6 120.66(3) 6_656 6_666 ?
Ag4 Eu1 Au6 58.36(2) 6_666 6_666 ?
Au4 Eu1 Au6 58.36(2) 6_666 6_666 ?
Ag4 Eu1 Au6 176.69(3) 6_656 6_666 ?
Au4 Eu1 Au6 176.69(3) 6_656 6_666 ?
Ag6 Eu1 Au6 120.7 6_656 6_666 ?
Au6 Eu1 Au6 120.66(3) 6_656 6_666 ?
Ag6 Eu1 Au6 0.0 6_666 6_666 ?
Ag4 Eu1 Ag6 108.73(2) 6_666 2_455 ?
Au4 Eu1 Ag6 108.73(2) 6_666 2_455 ?
Ag4 Eu1 Ag6 108.73(2) 6_656 2_455 ?
Au4 Eu1 Ag6 108.73(2) 6_656 2_455 ?
Ag6 Eu1 Ag6 68.295(18) 6_656 2_455 ?
Au6 Eu1 Ag6 68.295(18) 6_656 2_455 ?
Ag6 Eu1 Ag6 68.295(18) 6_666 2_455 ?
Au6 Eu1 Ag6 68.295(18) 6_666 2_455 ?
Ag4 Eu1 Au6 108.73(2) 6_666 2_455 ?
Au4 Eu1 Au6 108.73(2) 6_666 2_455 ?
Ag4 Eu1 Au6 108.73(2) 6_656 2_455 ?
Au4 Eu1 Au6 108.73(2) 6_656 2_455 ?
Ag6 Eu1 Au6 68.3 6_656 2_455 ?
Au6 Eu1 Au6 68.295(18) 6_656 2_455 ?
Ag6 Eu1 Au6 68.3 6_666 2_455 ?
Au6 Eu1 Au6 68.295(18) 6_666 2_455 ?
Ag6 Eu1 Au6 0.0 2_455 2_455 ?
Ag4 Eu1 Ag4 61.232(17) 6_666 2 ?
Au4 Eu1 Ag4 61.232(17) 6_666 2 ?
Ag4 Eu1 Ag4 61.232(17) 6_656 2 ?
Au4 Eu1 Ag4 61.232(17) 6_656 2 ?
Ag6 Eu1 Ag4 119.581(16) 6_656 2 ?
Au6 Eu1 Ag4 119.581(16) 6_656 2 ?
Ag6 Eu1 Ag4 119.581(16) 6_666 2 ?
Au6 Eu1 Ag4 119.581(16) 6_666 2 ?
Ag6 Eu1 Ag4 134.11(3) 2_455 2 ?
Au6 Eu1 Ag4 134.11(3) 2_455 2 ?
Ag4 Eu1 Au4 61.2 6_666 2 ?
Au4 Eu1 Au4 61.232(17) 6_666 2 ?
Ag4 Eu1 Au4 61.2 6_656 2 ?
Au4 Eu1 Au4 61.232(17) 6_656 2 ?
Ag6 Eu1 Au4 119.581(16) 6_656 2 ?
Au6 Eu1 Au4 119.581(16) 6_656 2 ?
Ag6 Eu1 Au4 119.581(16) 6_666 2 ?
Au6 Eu1 Au4 119.581(16) 6_666 2 ?
Ag6 Eu1 Au4 134.11(3) 2_455 2 ?
Au6 Eu1 Au4 134.11(3) 2_455 2 ?
Ag4 Eu1 Au4 0.0 2 2 ?
Ag6 In2 Au6 0.0 1_556 1_556 ?
Ag6 In2 Ag4 66.69(3) 1_556 1_556 ?
Au6 In2 Ag4 66.69(3) 1_556 1_556 ?
Ag6 In2 Au4 66.69(3) 1_556 1_556 ?
Au6 In2 Au4 66.69(3) 1_556 1_556 ?
Ag4 In2 Au4 0.0 1_556 1_556 ?
Ag6 In2 Ag3 114.92(3) 1_556 3_646 ?
Au6 In2 Ag3 114.92(3) 1_556 3_646 ?
Ag4 In2 Ag3 152.243(16) 1_556 3_646 ?
Au4 In2 Ag3 152.243(16) 1_556 3_646 ?
Ag6 In2 Au3 114.92(3) 1_556 5_666 ?
Au6 In2 Au3 114.92(3) 1_556 5_666 ?
Ag4 In2 Au3 152.243(16) 1_556 5_666 ?
Au4 In2 Au3 152.243(16) 1_556 5_666 ?
Ag3 In2 Au3 54.7 3_646 5_666 ?
Ag6 In2 Ag3 114.92(3) 1_556 5_666 ?
Au6 In2 Ag3 114.92(3) 1_556 5_666 ?
Ag4 In2 Ag3 152.243(16) 1_556 5_666 ?
Au4 In2 Ag3 152.243(16) 1_556 5_666 ?
Ag3 In2 Ag3 54.68(3) 3_646 5_666 ?
Au3 In2 Ag3 0.00(3) 5_666 5_666 ?
Ag6 In2 Au3 114.92(3) 1_556 3_646 ?
Au6 In2 Au3 114.92(3) 1_556 3_646 ?
Ag4 In2 Au3 152.243(16) 1_556 3_646 ?
Au4 In2 Au3 152.243(16) 1_556 3_646 ?
Ag3 In2 Au3 0.0 3_646 3_646 ?
Au3 In2 Au3 54.68(3) 5_666 3_646 ?
Ag3 In2 Au3 54.7 5_666 3_646 ?
Ag6 In2 Au3 113.99(3) 1_556 6_656 ?
Au6 In2 Au3 113.99(3) 1_556 6_656 ?
Ag4 In2 Au3 55.55(2) 1_556 6_656 ?
Au4 In2 Au3 55.55(2) 1_556 6_656 ?
Ag3 In2 Au3 103.8 3_646 6_656 ?
Au3 In2 Au3 131.09(3) 5_666 6_656 ?
Ag3 In2 Au3 131.1 5_666 6_656 ?
Au3 In2 Au3 103.75(2) 3_646 6_656 ?
Ag6 In2 Ag3 113.99(3) 1_556 6_656 ?
Au6 In2 Ag3 113.99(3) 1_556 6_656 ?
Ag4 In2 Ag3 55.55(2) 1_556 6_656 ?
Au4 In2 Ag3 55.55(2) 1_556 6_656 ?
Ag3 In2 Ag3 103.75(2) 3_646 6_656 ?
Au3 In2 Ag3 131.09(3) 5_666 6_656 ?
Ag3 In2 Ag3 131.09(3) 5_666 6_656 ?
Au3 In2 Ag3 103.75(2) 3_646 6_656 ?
Au3 In2 Ag3 0.00(2) 6_656 6_656 ?
Ag6 In2 Ag3 113.99(3) 1_556 4_565 ?
Au6 In2 Ag3 113.99(3) 1_556 4_565 ?
Ag4 In2 Ag3 55.55(2) 1_556 4_565 ?
Au4 In2 Ag3 55.55(2) 1_556 4_565 ?
Ag3 In2 Ag3 131.09(3) 3_646 4_565 ?
Au3 In2 Ag3 103.75(2) 5_666 4_565 ?
Ag3 In2 Ag3 103.75(2) 5_666 4_565 ?
Au3 In2 Ag3 131.09(3) 3_646 4_565 ?
Au3 In2 Ag3 54.35(3) 6_656 4_565 ?
Ag3 In2 Ag3 54.35(3) 6_656 4_565 ?
Ag6 In2 Au3 113.99(3) 1_556 4_565 ?
Au6 In2 Au3 113.99(3) 1_556 4_565 ?
Ag4 In2 Au3 55.55(2) 1_556 4_565 ?
Au4 In2 Au3 55.55(2) 1_556 4_565 ?
Ag3 In2 Au3 131.1 3_646 4_565 ?
Au3 In2 Au3 103.75(2) 5_666 4_565 ?
Ag3 In2 Au3 103.8 5_666 4_565 ?
Au3 In2 Au3 131.09(3) 3_646 4_565 ?
Au3 In2 Au3 54.35(3) 6_656 4_565 ?
Ag3 In2 Au3 54.3 6_656 4_565 ?
Ag3 In2 Au3 0.0 4_565 4_565 ?
Ag3 Au3 Au3 0.0 7_575 7_575 ?
Ag3 Au3 Au5 121.567(17) 7_575 . ?
Au3 Au3 Au5 121.567(17) 7_575 . ?
Ag3 Au3 Ag5 121.450(17) 7_575 2 ?
Au3 Au3 Ag5 121.450(17) 7_575 2 ?
Au5 Au3 Ag5 110.3 . 2 ?
Ag3 Au3 Au5 121.450(17) 7_575 2 ?
Au3 Au3 Au5 121.450(17) 7_575 2 ?
Au5 Au3 Au5 110.32(2) . 2 ?
Ag5 Au3 Au5 0.0 2 2 ?
Ag3 Au3 Ag4 60.548(16) 7_575 6_666 ?
Au3 Au3 Ag4 60.548(16) 7_575 6_666 ?
Au5 Au3 Ag4 110.15(3) . 6_666 ?
Ag5 Au3 Ag4 124.50(3) 2 6_666 ?
Au5 Au3 Ag4 124.50(3) 2 6_666 ?
Ag3 Au3 Au4 60.548(16) 7_575 6_666 ?
Au3 Au3 Au4 60.548(16) 7_575 6_666 ?
Au5 Au3 Au4 110.15(3) . 6_666 ?
Ag5 Au3 Au4 124.50(3) 2 6_666 ?
Au5 Au3 Au4 124.50(3) 2 6_666 ?
Ag4 Au3 Au4 0.0 6_666 6_666 ?
Ag3 Au3 Ag4 120.243(16) 7_575 2 ?
Au3 Au3 Ag4 120.243(16) 7_575 2 ?
Au5 Au3 Ag4 107.28(3) . 2 ?
Ag5 Au3 Ag4 60.44(3) 2 2 ?
Au5 Au3 Ag4 60.44(3) 2 2 ?
Ag4 Au3 Ag4 72.33(2) 6_666 2 ?
Au4 Au3 Ag4 72.33(2) 6_666 2 ?
Ag3 Au3 Au4 120.243(16) 7_575 2 ?
Au3 Au3 Au4 120.243(16) 7_575 2 ?
Au5 Au3 Au4 107.28(3) . 2 ?
Ag5 Au3 Au4 60.44(3) 2 2 ?
Au5 Au3 Au4 60.44(3) 2 2 ?
Ag4 Au3 Au4 72.3 6_666 2 ?
Au4 Au3 Au4 72.33(2) 6_666 2 ?
Ag4 Au3 Au4 0.0 2 2 ?
Ag3 Au3 Au6 120.036(15) 7_575 . ?
Au3 Au3 Au6 120.036(15) 7_575 . ?
Au5 Au3 Au6 63.99(3) . . ?
Ag5 Au3 Au6 61.06(3) 2 . ?
Au5 Au3 Au6 61.06(3) 2 . ?
Ag4 Au3 Au6 173.81(3) 6_666 . ?
Au4 Au3 Au6 173.81(3) 6_666 . ?
Ag4 Au3 Au6 110.77(3) 2 . ?
Au4 Au3 Au6 110.77(3) 2 . ?
Ag3 Au4 Au3 0.0 6_655 6_655 ?
Ag3 Au4 Ag3 58.90(3) 6_655 4_564 ?
Au3 Au4 Ag3 58.90(3) 6_655 4_564 ?
Ag3 Au4 Au3 58.9 6_655 4_564 ?
Au3 Au4 Au3 58.90(3) 6_655 4_564 ?
Ag3 Au4 Au3 0.0 4_564 4_564 ?
Ag3 Au4 Au5 149.231(19) 6_655 . ?
Au3 Au4 Au5 149.231(19) 6_655 . ?
Ag3 Au4 Au5 149.231(19) 4_564 . ?
Au3 Au4 Au5 149.231(19) 4_564 . ?
Ag3 Au4 Ag3 143.02(3) 6_655 8_556 ?
Au3 Au4 Ag3 143.02(3) 6_655 8_556 ?
Ag3 Au4 Ag3 107.67(2) 4_564 8_556 ?
Au3 Au4 Ag3 107.67(2) 4_564 8_556 ?
Au5 Au4 Ag3 58.05(3) . 8_556 ?
Ag3 Au4 Au3 143.0 6_655 8_556 ?
Au3 Au4 Au3 143.02(3) 6_655 8_556 ?
Ag3 Au4 Au3 107.7 4_564 8_556 ?
Au3 Au4 Au3 107.67(2) 4_564 8_556 ?
Au5 Au4 Au3 58.05(3) . 8_556 ?
Ag3 Au4 Au3 0.0 8_556 8_556 ?
Ag3 Au4 Ag3 107.67(2) 6_655 2_455 ?
Au3 Au4 Ag3 107.67(2) 6_655 2_455 ?
Ag3 Au4 Ag3 143.02(3) 4_564 2_455 ?
Au3 Au4 Ag3 143.02(3) 4_564 2_455 ?
Au5 Au4 Ag3 58.05(3) . 2_455 ?
Ag3 Au4 Ag3 60.49(3) 8_556 2_455 ?
Au3 Au4 Ag3 60.49(3) 8_556 2_455 ?
Ag3 Au4 Au3 107.7 6_655 2_455 ?
Au3 Au4 Au3 107.67(2) 6_655 2_455 ?
Ag3 Au4 Au3 143.0 4_564 2_455 ?
Au3 Au4 Au3 143.02(3) 4_564 2_455 ?
Au5 Au4 Au3 58.05(3) . 2_455 ?
Ag3 Au4 Au3 60.5 8_556 2_455 ?
Au3 Au4 Au3 60.49(3) 8_556 2_455 ?
Ag3 Au4 Au3 0.0 2_455 2_455 ?
Ag3 Au4 In2 62.59(3) 6_655 1_554 ?
Au3 Au4 In2 62.59(3) 6_655 1_554 ?
Ag3 Au4 In2 62.59(3) 4_564 1_554 ?
Au3 Au4 In2 62.59(3) 4_564 1_554 ?
Au5 Au4 In2 112.58(4) . 1_554 ?
Ag3 Au4 In2 146.48(2) 8_556 1_554 ?
Au3 Au4 In2 146.48(2) 8_556 1_554 ?
Ag3 Au4 In2 146.48(2) 2_455 1_554 ?
Au3 Au4 In2 146.48(2) 2_455 1_554 ?
Ag3 Au4 Au6 108.10(3) 6_655 . ?
Au3 Au4 Au6 108.10(3) 6_655 . ?
Ag3 Au4 Au6 108.10(3) 4_564 . ?
Au3 Au4 Au6 108.10(3) 4_564 . ?
Au5 Au4 Au6 59.76(3) . . ?
Ag3 Au4 Au6 108.86(3) 8_556 . ?
Au3 Au4 Au6 108.86(3) 8_556 . ?
Ag3 Au4 Au6 108.86(3) 2_455 . ?
Au3 Au4 Au6 108.86(3) 2_455 . ?
In2 Au4 Au6 52.82(3) 1_554 . ?
Ag3 Au5 Au3 0.0 7_565 7_565 ?
Ag3 Au5 Au3 63.1 7_565 . ?
Au3 Au5 Au3 63.14(3) 7_565 . ?
Ag3 Au5 Ag3 116.83(3) 7_565 2_455 ?
Au3 Au5 Ag3 116.83(3) 7_565 2_455 ?
Au3 Au5 Ag3 176.1 . 2_455 ?
Ag3 Au5 Au3 116.8 7_565 2_455 ?
Au3 Au5 Au3 116.83(3) 7_565 2_455 ?
Au3 Au5 Au3 176.06(4) . 2_455 ?
Ag3 Au5 Au3 0.0 2_455 2_455 ?
Ag3 Au5 Ag3 176.06(4) 7_565 8_556 ?
Au3 Au5 Ag3 176.06(4) 7_565 8_556 ?
Au3 Au5 Ag3 116.8 . 8_556 ?
Ag3 Au5 Ag3 62.90(3) 2_455 8_556 ?
Au3 Au5 Ag3 62.90(3) 2_455 8_556 ?
Ag3 Au5 Au3 176.1 7_565 8_556 ?
Au3 Au5 Au3 176.06(4) 7_565 8_556 ?
Au3 Au5 Au3 116.83(3) . 8_556 ?
Ag3 Au5 Au3 62.9 2_455 8_556 ?
Au3 Au5 Au3 62.90(3) 2_455 8_556 ?
Ag3 Au5 Au3 0.0 8_556 8_556 ?
Ag3 Au5 Au4 114.71(3) 7_565 . ?
Au3 Au5 Au4 114.71(3) 7_565 . ?
Au3 Au5 Au4 114.71(3) . . ?
Ag3 Au5 Au4 61.51(3) 2_455 . ?
Au3 Au5 Au4 61.51(3) 2_455 . ?
Ag3 Au5 Au4 61.51(3) 8_556 . ?
Au3 Au5 Au4 61.51(3) 8_556 . ?
Ag3 Au5 Ag6 122.14(3) 7_565 2_455 ?
Au3 Au5 Ag6 122.14(3) 7_565 2_455 ?
Au3 Au5 Ag6 122.14(3) . 2_455 ?
Ag3 Au5 Ag6 61.49(3) 2_455 2_455 ?
Au3 Au5 Ag6 61.49(3) 2_455 2_455 ?
Ag3 Au5 Ag6 61.49(3) 8_556 2_455 ?
Au3 Au5 Ag6 61.49(3) 8_556 2_455 ?
Au4 Au5 Ag6 111.98(4) . 2_455 ?
Ag3 Au5 Au6 122.14(3) 7_565 2_455 ?
Au3 Au5 Au6 122.14(3) 7_565 2_455 ?
Au3 Au5 Au6 122.14(3) . 2_455 ?
Ag3 Au5 Au6 61.49(3) 2_455 2_455 ?
Au3 Au5 Au6 61.49(3) 2_455 2_455 ?
Ag3 Au5 Au6 61.49(3) 8_556 2_455 ?
Au3 Au5 Au6 61.49(3) 8_556 2_455 ?
Au4 Au5 Au6 111.98(4) . 2_455 ?
Ag6 Au5 Au6 0.0 2_455 2_455 ?
In2 Au6 Ag5 143.22(4) 1_554 2 ?
In2 Au6 Au5 143.22(4) 1_554 2 ?
Ag5 Au6 Au5 0.0 2 2 ?
In2 Au6 Au3 146.82(2) 1_554 . ?
Ag5 Au6 Au3 57.46(2) 2 . ?
Au5 Au6 Au3 57.46(2) 2 . ?
In2 Au6 Ag3 146.82(2) 1_554 7_565 ?
Ag5 Au6 Ag3 57.46(2) 2 7_565 ?
Au5 Au6 Ag3 57.46(2) 2 7_565 ?
Au3 Au6 Ag3 60.1 . 7_565 ?
In2 Au6 Au3 146.82(2) 1_554 7_565 ?
Ag5 Au6 Au3 57.46(2) 2 7_565 ?
Au5 Au6 Au3 57.46(2) 2 7_565 ?
Au3 Au6 Au3 60.07(3) . 7_565 ?
Ag3 Au6 Au3 0.0 7_565 7_565 ?
In2 Au6 Au5 115.50(4) 1_554 . ?
Ag5 Au6 Au5 101.3 2 . ?
Au5 Au6 Au5 101.28(3) 2 . ?
Au3 Au6 Au5 55.95(2) . . ?
Ag3 Au6 Au5 55.95(2) 7_565 . ?
Au3 Au6 Au5 55.95(2) 7_565 . ?
In2 Au6 Au4 60.49(3) 1_554 . ?
Ag5 Au6 Au4 156.29(3) 2 . ?
Au5 Au6 Au4 156.29(3) 2 . ?
Au3 Au6 Au4 102.70(3) . . ?
Ag3 Au6 Au4 102.70(3) 7_565 . ?
Au3 Au6 Au4 102.70(3) 7_565 . ?
Au5 Au6 Au4 55.01(3) . . ?
In2 Au6 Eu1 77.331(19) 1_554 6_655 ?
Ag5 Au6 Eu1 116.191(17) 2 6_655 ?
Au5 Au6 Eu1 116.191(17) 2 6_655 ?
Au3 Au6 Eu1 121.35(3) . 6_655 ?
Ag3 Au6 Eu1 69.544(19) 7_565 6_655 ?
Au3 Au6 Eu1 69.544(19) 7_565 6_655 ?
Au5 Au6 Eu1 72.174(19) . 6_655 ?
Au4 Au6 Eu1 60.381(16) . 6_655 ?


_refine_diff_density_max         1.652
_refine_diff_density_min         -3.420
_refine_diff_density_rms         0.649

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mix5
_database_code_depnum_ccdc_archive 'CCDC 1566150'
_audit_update_record             
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Au2.66 Cu2.34 Eu In'
_chemical_formula_weight         939.73

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Pnma

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   8.832(3)
_cell_length_b                   5.3062(19)
_cell_length_c                   11.059(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     518.3(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    4149
_cell_measurement_theta_min      2.95
_cell_measurement_theta_max      32.42

_exptl_crystal_description       'irregular fragment'
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    12.044
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1560
_exptl_absorpt_coefficient_mu    100.580
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.002
_exptl_absorpt_correction_T_max  0.004
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            4149
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_av_sigmaI/netI    0.0832
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_theta_min         2.95
_diffrn_reflns_theta_max         32.42
_reflns_number_total             968
_reflns_number_gt                781
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0298P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00185(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         968
_refine_ls_number_parameters     44
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0583
_refine_ls_R_factor_gt           0.0423
_refine_ls_wR_factor_ref         0.0965
_refine_ls_wR_factor_gt          0.0897
_refine_ls_goodness_of_fit_ref   0.954
_refine_ls_restrained_S_all      0.954
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.75704(10) 0.2500 0.43794(8) 0.0117(2) Uani 1 2 d S . .
Au1 Au 0.41793(8) 0.2500 0.51337(7) 0.0114(3) Uani 0.937(6) 2 d SP . .
Cu1 Cu 0.41793(8) 0.2500 0.51337(7) 0.0114(3) Uani 0.063(6) 2 d SP . .
Au2 Au 0.05609(9) 0.2500 0.59238(7) 0.0162(2) Uani 1 2 d S . .
Au3 Au 0.31280(12) 0.2500 0.75136(9) 0.0114(3) Uani 0.561(6) 2 d SP . .
Cu3 Cu 0.31280(12) 0.2500 0.75136(9) 0.0114(3) Uani 0.439(6) 2 d SP . .
Au4 Au 0.43303(16) 0.0042(2) 0.30534(12) 0.0116(5) Uani 0.096(6) 1 d P . .
Cu4 Cu 0.43303(16) 0.0042(2) 0.30534(12) 0.0116(5) Uani 0.904(6) 1 d P . .
In5 In 0.14712(14) 0.2500 0.35448(12) 0.0098(3) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Au1 3.1089(16) . ?
Eu1 Cu1 3.1172(11) 5_656 ?
Eu1 Au1 3.1172(11) 5_656 ?
Eu1 Cu1 3.1172(11) 5_666 ?
Eu1 Au1 3.1172(11) 5_666 ?
Eu1 Au2 3.1425(11) 5_666 ?
Eu1 Au2 3.1425(11) 5_656 ?
Eu1 Au2 3.1453(15) 1_655 ?
Eu1 Cu4 3.3699(17) 6_656 ?
Eu1 Au4 3.3699(17) 6_656 ?
Eu1 Cu4 3.3699(17) 4 ?
Au1 Cu4 2.6481(16) 7_565 ?
Au1 Au4 2.6481(16) 7_565 ?
Au1 Au4 2.6481(16) . ?
Au1 Cu4 2.7516(16) 3_656 ?
Au1 Au4 2.7516(16) 3_656 ?
Au1 Cu4 2.7516(16) 5_656 ?
Au1 Au4 2.7516(16) 5_656 ?
Au1 Au3 2.7910(16) . ?
Au1 In5 2.9679(16) . ?
Au1 Au1 3.0377(11) 5_666 ?
Au2 Cu4 2.7158(16) 8_666 ?
Au2 Au4 2.7158(16) 8_666 ?
Au2 Cu4 2.7158(16) 2 ?
Au2 Au4 2.7158(16) 2 ?
Au2 In5 2.7513(18) . ?
Au2 Cu3 2.7573(15) 6_557 ?
Au2 Au3 2.7573(15) 6_557 ?
Au2 Au3 2.8691(15) . ?
Au2 Eu1 3.1425(11) 5_666 ?
Au2 Eu1 3.1425(11) 5_656 ?
Au2 Eu1 3.1453(15) 1_455 ?
Au3 Cu4 2.6247(18) 2 ?
Au3 Au4 2.6247(18) 2 ?
Au3 Cu4 2.6247(17) 8_666 ?
Au3 Au4 2.6247(17) 8_666 ?
Au3 Cu4 2.6928(18) 3_656 ?
Au3 Au4 2.6928(18) 3_656 ?
Au3 Cu4 2.6928(18) 5_656 ?
Au3 Au4 2.6928(18) 5_656 ?
Au3 Au2 2.7573(15) 6_657 ?
Au4 Cu4 2.609(2) 7_565 ?
Au4 Au4 2.609(2) 7_565 ?
Au4 Cu3 2.6247(17) 2_554 ?
Au4 Au3 2.6247(17) 2_554 ?
Au4 Cu3 2.6928(18) 5_656 ?
Au4 Au3 2.6928(18) 5_656 ?
Au4 Cu4 2.697(2) 7 ?
Au4 Au4 2.697(2) 7 ?
Au4 Au2 2.7157(16) 2_554 ?
Au4 Cu1 2.7516(16) 5_656 ?
In5 Cu4 2.8935(19) 7_565 ?
In5 Au4 2.8935(19) 7_565 ?
In5 Cu4 2.8984(19) 6_556 ?
In5 Au4 2.8984(19) 6_556 ?
In5 Cu4 2.8984(19) 4_455 ?
In5 Au4 2.8984(19) 4_455 ?
In5 Cu3 2.9094(11) 2_554 ?
In5 Au3 2.9094(11) 2_554 ?
In5 Cu3 2.9094(11) 2_564 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au1 Eu1 Cu1 58.41(2) . 5_656 ?
Au1 Eu1 Au1 58.41(2) . 5_656 ?
Cu1 Eu1 Au1 0.00(2) 5_656 5_656 ?
Au1 Eu1 Cu1 58.41(2) . 5_666 ?
Cu1 Eu1 Cu1 116.67(4) 5_656 5_666 ?
Au1 Eu1 Cu1 116.67(4) 5_656 5_666 ?
Au1 Eu1 Au1 58.41(2) . 5_666 ?
Cu1 Eu1 Au1 116.67(4) 5_656 5_666 ?
Au1 Eu1 Au1 116.67(4) 5_656 5_666 ?
Cu1 Eu1 Au1 0.00(4) 5_666 5_666 ?
Au1 Eu1 Au2 122.31(2) . 5_666 ?
Cu1 Eu1 Au2 175.84(4) 5_656 5_666 ?
Au1 Eu1 Au2 175.84(4) 5_656 5_666 ?
Cu1 Eu1 Au2 63.91(3) 5_666 5_666 ?
Au1 Eu1 Au2 63.91(3) 5_666 5_666 ?
Au1 Eu1 Au2 122.31(2) . 5_656 ?
Cu1 Eu1 Au2 63.91(3) 5_656 5_656 ?
Au1 Eu1 Au2 63.91(3) 5_656 5_656 ?
Cu1 Eu1 Au2 175.84(4) 5_666 5_656 ?
Au1 Eu1 Au2 175.84(4) 5_666 5_656 ?
Au2 Eu1 Au2 115.19(5) 5_666 5_656 ?
Au1 Eu1 Au2 131.54(4) . 1_655 ?
Cu1 Eu1 Au2 108.81(3) 5_656 1_655 ?
Au1 Eu1 Au2 108.81(3) 5_656 1_655 ?
Cu1 Eu1 Au2 108.81(3) 5_666 1_655 ?
Au1 Eu1 Au2 108.81(3) 5_666 1_655 ?
Au2 Eu1 Au2 67.48(3) 5_666 1_655 ?
Au2 Eu1 Au2 67.48(3) 5_656 1_655 ?
Au1 Eu1 Cu4 131.19(4) . 6_656 ?
Cu1 Eu1 Cu4 92.13(3) 5_656 6_656 ?
Au1 Eu1 Cu4 92.13(3) 5_656 6_656 ?
Cu1 Eu1 Cu4 134.11(4) 5_666 6_656 ?
Au1 Eu1 Cu4 134.11(4) 5_666 6_656 ?
Au2 Eu1 Cu4 89.96(4) 5_666 6_656 ?
Au2 Eu1 Cu4 49.14(3) 5_656 6_656 ?
Au2 Eu1 Cu4 92.66(4) 1_655 6_656 ?
Au1 Eu1 Au4 131.19(4) . 6_656 ?
Cu1 Eu1 Au4 92.13(3) 5_656 6_656 ?
Au1 Eu1 Au4 92.13(3) 5_656 6_656 ?
Cu1 Eu1 Au4 134.11(4) 5_666 6_656 ?
Au1 Eu1 Au4 134.11(4) 5_666 6_656 ?
Au2 Eu1 Au4 89.96(4) 5_666 6_656 ?
Au2 Eu1 Au4 49.14(3) 5_656 6_656 ?
Au2 Eu1 Au4 92.66(4) 1_655 6_656 ?
Cu4 Eu1 Au4 0.00(4) 6_656 6_656 ?
Au1 Eu1 Cu4 131.19(4) . 4 ?
Cu1 Eu1 Cu4 134.11(4) 5_656 4 ?
Au1 Eu1 Cu4 134.11(4) 5_656 4 ?
Cu1 Eu1 Cu4 92.13(3) 5_666 4 ?
Au1 Eu1 Cu4 92.13(3) 5_666 4 ?
Au2 Eu1 Cu4 49.14(3) 5_666 4 ?
Au2 Eu1 Cu4 89.96(4) 5_656 4 ?
Au2 Eu1 Cu4 92.66(4) 1_655 4 ?
Cu4 Eu1 Cu4 45.54(4) 6_656 4 ?
Au4 Eu1 Cu4 45.54(4) 6_656 4 ?
Cu4 Au1 Au4 0.00(7) 7_565 7_565 ?
Cu4 Au1 Au4 59.02(6) 7_565 . ?
Au4 Au1 Au4 59.02(6) 7_565 . ?
Cu4 Au1 Cu4 111.56(4) 7_565 3_656 ?
Au4 Au1 Cu4 111.56(4) 7_565 3_656 ?
Au4 Au1 Cu4 148.25(3) . 3_656 ?
Cu4 Au1 Au4 111.56(4) 7_565 3_656 ?
Au4 Au1 Au4 111.56(4) 7_565 3_656 ?
Au4 Au1 Au4 148.25(3) . 3_656 ?
Cu4 Au1 Au4 0.00(4) 3_656 3_656 ?
Cu4 Au1 Cu4 148.26(3) 7_565 5_656 ?
Au4 Au1 Cu4 148.26(3) 7_565 5_656 ?
Au4 Au1 Cu4 111.56(4) . 5_656 ?
Cu4 Au1 Cu4 58.70(5) 3_656 5_656 ?
Au4 Au1 Cu4 58.70(5) 3_656 5_656 ?
Cu4 Au1 Au4 148.26(3) 7_565 5_656 ?
Au4 Au1 Au4 148.26(3) 7_565 5_656 ?
Au4 Au1 Au4 111.56(4) . 5_656 ?
Cu4 Au1 Au4 58.70(5) 3_656 5_656 ?
Au4 Au1 Au4 58.70(5) 3_656 5_656 ?
Cu4 Au1 Au4 0.00(6) 5_656 5_656 ?
Cu4 Au1 Au3 146.73(3) 7_565 . ?
Au4 Au1 Au3 146.73(3) 7_565 . ?
Au4 Au1 Au3 146.73(3) . . ?
Cu4 Au1 Au3 58.13(4) 3_656 . ?
Au4 Au1 Au3 58.13(4) 3_656 . ?
Cu4 Au1 Au3 58.13(4) 5_656 . ?
Au4 Au1 Au3 58.13(4) 5_656 . ?
Cu4 Au1 In5 61.71(4) 7_565 . ?
Au4 Au1 In5 61.71(4) 7_565 . ?
Au4 Au1 In5 61.72(4) . . ?
Cu4 Au1 In5 144.78(3) 3_656 . ?
Au4 Au1 In5 144.78(3) 3_656 . ?
Cu4 Au1 In5 144.78(3) 5_656 . ?
Au4 Au1 In5 144.78(3) 5_656 . ?
Au3 Au1 In5 106.88(5) . . ?
Cu4 Au1 Au1 57.40(4) 7_565 5_666 ?
Au4 Au1 Au1 57.40(4) 7_565 5_666 ?
Au4 Au1 Au1 108.76(5) . 5_666 ?
Cu4 Au1 Au1 54.17(3) 3_656 5_666 ?
Au4 Au1 Au1 54.17(3) 3_656 5_666 ?
Cu4 Au1 Au1 105.71(5) 5_656 5_666 ?
Au4 Au1 Au1 105.71(5) 5_656 5_666 ?
Au3 Au1 Au1 104.51(3) . 5_666 ?
In5 Au1 Au1 109.08(3) . 5_666 ?
Cu4 Au2 Au4 0.00(6) 8_666 8_666 ?
Cu4 Au2 Cu4 59.55(6) 8_666 2 ?
Au4 Au2 Cu4 59.55(6) 8_666 2 ?
Cu4 Au2 Au4 59.55(6) 8_666 2 ?
Au4 Au2 Au4 59.55(6) 8_666 2 ?
Cu4 Au2 Au4 0.00(7) 2 2 ?
Cu4 Au2 In5 144.99(4) 8_666 . ?
Au4 Au2 In5 144.99(4) 8_666 . ?
Cu4 Au2 In5 144.99(4) 2 . ?
Au4 Au2 In5 144.99(4) 2 . ?
Cu4 Au2 Cu3 58.94(4) 8_666 6_557 ?
Au4 Au2 Cu3 58.94(4) 8_666 6_557 ?
Cu4 Au2 Cu3 58.94(4) 2 6_557 ?
Au4 Au2 Cu3 58.94(4) 2 6_557 ?
In5 Au2 Cu3 145.80(5) . 6_557 ?
Cu4 Au2 Au3 58.94(4) 8_666 6_557 ?
Au4 Au2 Au3 58.94(4) 8_666 6_557 ?
Cu4 Au2 Au3 58.94(4) 2 6_557 ?
Au4 Au2 Au3 58.94(4) 2 6_557 ?
In5 Au2 Au3 145.80(5) . 6_557 ?
Cu3 Au2 Au3 0.00(3) 6_557 6_557 ?
Cu4 Au2 Au3 55.98(4) 8_666 . ?
Au4 Au2 Au3 55.98(4) 8_666 . ?
Cu4 Au2 Au3 55.98(4) 2 . ?
Au4 Au2 Au3 55.98(4) 2 . ?
In5 Au2 Au3 110.80(5) . . ?
Cu3 Au2 Au3 103.40(4) 6_557 . ?
Au3 Au2 Au3 103.40(4) 6_557 . ?
Cu4 Au2 Eu1 69.80(4) 8_666 5_666 ?
Au4 Au2 Eu1 69.80(4) 8_666 5_666 ?
Cu4 Au2 Eu1 119.55(4) 2 5_666 ?
Au4 Au2 Eu1 119.55(4) 2 5_666 ?
In5 Au2 Eu1 75.19(3) . 5_666 ?
Cu3 Au2 Eu1 118.43(2) 6_557 5_666 ?
Au3 Au2 Eu1 118.43(2) 6_557 5_666 ?
Au3 Au2 Eu1 69.54(3) . 5_666 ?
Cu4 Au2 Eu1 119.55(4) 8_666 5_656 ?
Au4 Au2 Eu1 119.55(4) 8_666 5_656 ?
Cu4 Au2 Eu1 69.80(3) 2 5_656 ?
Au4 Au2 Eu1 69.80(3) 2 5_656 ?
In5 Au2 Eu1 75.19(3) . 5_656 ?
Cu3 Au2 Eu1 118.43(2) 6_557 5_656 ?
Au3 Au2 Eu1 118.43(2) 6_557 5_656 ?
Au3 Au2 Eu1 69.54(3) . 5_656 ?
Eu1 Au2 Eu1 115.19(5) 5_666 5_656 ?
Cu4 Au2 Eu1 120.05(4) 8_666 1_455 ?
Au4 Au2 Eu1 120.05(4) 8_666 1_455 ?
Cu4 Au2 Eu1 120.05(4) 2 1_455 ?
Au4 Au2 Eu1 120.05(4) 2 1_455 ?
In5 Au2 Eu1 74.10(4) . 1_455 ?
Cu3 Au2 Eu1 71.70(4) 6_557 1_455 ?
Au3 Au2 Eu1 71.70(4) 6_557 1_455 ?
Au3 Au2 Eu1 175.10(4) . 1_455 ?
Eu1 Au2 Eu1 112.52(3) 5_666 1_455 ?
Eu1 Au2 Eu1 112.52(3) 5_656 1_455 ?
Cu4 Au3 Au4 0.00(4) 2 2 ?
Cu4 Au3 Cu4 61.84(6) 2 8_666 ?
Au4 Au3 Cu4 61.84(6) 2 8_666 ?
Cu4 Au3 Au4 61.84(6) 2 8_666 ?
Au4 Au3 Au4 61.84(6) 2 8_666 ?
Cu4 Au3 Au4 0.00(3) 8_666 8_666 ?
Cu4 Au3 Cu4 179.11(4) 2 3_656 ?
Au4 Au3 Cu4 179.11(4) 2 3_656 ?
Cu4 Au3 Cu4 119.02(5) 8_666 3_656 ?
Au4 Au3 Cu4 119.02(5) 8_666 3_656 ?
Cu4 Au3 Au4 179.11(4) 2 3_656 ?
Au4 Au3 Au4 179.11(4) 2 3_656 ?
Cu4 Au3 Au4 119.02(5) 8_666 3_656 ?
Au4 Au3 Au4 119.02(5) 8_666 3_656 ?
Cu4 Au3 Au4 0.00(6) 3_656 3_656 ?
Cu4 Au3 Cu4 119.02(5) 2 5_656 ?
Au4 Au3 Cu4 119.02(5) 2 5_656 ?
Cu4 Au3 Cu4 179.11(4) 8_666 5_656 ?
Au4 Au3 Cu4 179.11(4) 8_666 5_656 ?
Cu4 Au3 Cu4 60.11(6) 3_656 5_656 ?
Au4 Au3 Cu4 60.11(6) 3_656 5_656 ?
Cu4 Au3 Au4 119.02(5) 2 5_656 ?
Au4 Au3 Au4 119.02(5) 2 5_656 ?
Cu4 Au3 Au4 179.11(4) 8_666 5_656 ?
Au4 Au3 Au4 179.11(4) 8_666 5_656 ?
Cu4 Au3 Au4 60.11(6) 3_656 5_656 ?
Au4 Au3 Au4 60.11(6) 3_656 5_656 ?
Cu4 Au3 Au4 0.00(7) 5_656 5_656 ?
Cu4 Au3 Au2 120.13(5) 2 6_657 ?
Au4 Au3 Au2 120.13(5) 2 6_657 ?
Cu4 Au3 Au2 120.13(5) 8_666 6_657 ?
Au4 Au3 Au2 120.13(5) 8_666 6_657 ?
Cu4 Au3 Au2 59.76(4) 3_656 6_657 ?
Au4 Au3 Au2 59.76(4) 3_656 6_657 ?
Cu4 Au3 Au2 59.76(4) 5_656 6_657 ?
Au4 Au3 Au2 59.76(4) 5_656 6_657 ?
Cu4 Au3 Au1 119.32(5) 2 . ?
Au4 Au3 Au1 119.32(5) 2 . ?
Cu4 Au3 Au1 119.32(4) 8_666 . ?
Au4 Au3 Au1 119.32(4) 8_666 . ?
Cu4 Au3 Au1 60.20(4) 3_656 . ?
Au4 Au3 Au1 60.20(4) 3_656 . ?
Cu4 Au3 Au1 60.20(4) 5_656 . ?
Au4 Au3 Au1 60.20(4) 5_656 . ?
Au2 Au3 Au1 109.38(5) 6_657 . ?
Cu4 Au3 Au2 59.05(4) 2 . ?
Au4 Au3 Au2 59.05(4) 2 . ?
Cu4 Au3 Au2 59.05(4) 8_666 . ?
Au4 Au3 Au2 59.05(4) 8_666 . ?
Cu4 Au3 Au2 121.07(5) 3_656 . ?
Au4 Au3 Au2 121.07(5) 3_656 . ?
Cu4 Au3 Au2 121.07(5) 5_656 . ?
Au4 Au3 Au2 121.07(5) 5_656 . ?
Au2 Au3 Au2 178.98(5) 6_657 . ?
Au1 Au3 Au2 71.64(4) . . ?
Cu4 Au4 Au4 0.00(8) 7_565 7_565 ?
Cu4 Au4 Cu3 120.92(3) 7_565 2_554 ?
Au4 Au4 Cu3 120.92(3) 7_565 2_554 ?
Cu4 Au4 Au3 120.92(3) 7_565 2_554 ?
Au4 Au4 Au3 120.92(3) 7_565 2_554 ?
Cu3 Au4 Au3 0.00(4) 2_554 2_554 ?
Cu4 Au4 Au1 60.49(3) 7_565 . ?
Au4 Au4 Au1 60.49(3) 7_565 . ?
Cu3 Au4 Au1 114.15(6) 2_554 . ?
Au3 Au4 Au1 114.15(6) 2_554 . ?
Cu4 Au4 Cu3 120.06(3) 7_565 5_656 ?
Au4 Au4 Cu3 120.06(3) 7_565 5_656 ?
Cu3 Au4 Cu3 112.28(5) 2_554 5_656 ?
Au3 Au4 Cu3 112.28(5) 2_554 5_656 ?
Au1 Au4 Cu3 119.41(6) . 5_656 ?
Cu4 Au4 Au3 120.06(3) 7_565 5_656 ?
Au4 Au4 Au3 120.06(3) 7_565 5_656 ?
Cu3 Au4 Au3 112.28(5) 2_554 5_656 ?
Au3 Au4 Au3 112.28(5) 2_554 5_656 ?
Au1 Au4 Au3 119.41(6) . 5_656 ?
Cu3 Au4 Au3 0.00(4) 5_656 5_656 ?
Cu4 Au4 Cu4 179.999(1) 7_565 7 ?
Au4 Au4 Cu4 179.999(1) 7_565 7 ?
Cu3 Au4 Cu4 59.08(3) 2_554 7 ?
Au3 Au4 Cu4 59.08(3) 2_554 7 ?
Au1 Au4 Cu4 119.51(3) . 7 ?
Cu3 Au4 Cu4 59.94(3) 5_656 7 ?
Au3 Au4 Cu4 59.94(3) 5_656 7 ?
Cu4 Au4 Au4 179.999(1) 7_565 7 ?
Au4 Au4 Au4 179.999(1) 7_565 7 ?
Cu3 Au4 Au4 59.08(3) 2_554 7 ?
Au3 Au4 Au4 59.08(3) 2_554 7 ?
Au1 Au4 Au4 119.51(3) . 7 ?
Cu3 Au4 Au4 59.94(3) 5_656 7 ?
Au3 Au4 Au4 59.94(3) 5_656 7 ?
Cu4 Au4 Au4 0.00(8) 7 7 ?
Cu4 Au4 Au2 119.78(3) 7_565 2_554 ?
Au4 Au4 Au2 119.78(3) 7_565 2_554 ?
Cu3 Au4 Au2 64.96(4) 2_554 2_554 ?
Au3 Au4 Au2 64.96(4) 2_554 2_554 ?
Au1 Au4 Au2 179.11(6) . 2_554 ?
Cu3 Au4 Au2 61.30(4) 5_656 2_554 ?
Au3 Au4 Au2 61.30(4) 5_656 2_554 ?
Cu4 Au4 Au2 60.22(3) 7 2_554 ?
Au4 Au4 Au2 60.22(3) 7 2_554 ?
Cu4 Au4 Cu1 119.35(3) 7_565 5_656 ?
Au4 Au4 Cu1 119.35(3) 7_565 5_656 ?
Cu3 Au4 Cu1 108.03(5) 2_554 5_656 ?
Au3 Au4 Cu1 108.03(5) 2_554 5_656 ?
Au1 Au4 Cu1 68.44(4) . 5_656 ?
Cu3 Au4 Cu1 61.67(4) 5_656 5_656 ?
Au3 Au4 Cu1 61.67(4) 5_656 5_656 ?
Cu4 Au4 Cu1 60.65(3) 7 5_656 ?
Au4 Au4 Cu1 60.65(3) 7 5_656 ?
Au2 Au4 Cu1 111.81(5) 2_554 5_656 ?
Au2 In5 Cu4 115.76(5) . 7_565 ?
Au2 In5 Au4 115.76(5) . 7_565 ?
Cu4 In5 Au4 0.00(6) 7_565 7_565 ?
Au2 In5 Au4 115.76(5) . . ?
Cu4 In5 Au4 53.59(6) 7_565 . ?
Au4 In5 Au4 53.59(6) 7_565 . ?
Au2 In5 Cu4 113.11(5) . 6_556 ?
Cu4 In5 Cu4 131.12(5) 7_565 6_556 ?
Au4 In5 Cu4 131.12(5) 7_565 6_556 ?
Au4 In5 Cu4 104.59(4) . 6_556 ?
Au2 In5 Au4 113.11(5) . 6_556 ?
Cu4 In5 Au4 131.12(5) 7_565 6_556 ?
Au4 In5 Au4 131.12(5) 7_565 6_556 ?
Au4 In5 Au4 104.59(4) . 6_556 ?
Cu4 In5 Au4 0.00(7) 6_556 6_556 ?
Au2 In5 Cu4 113.11(5) . 4_455 ?
Cu4 In5 Cu4 104.59(4) 7_565 4_455 ?
Au4 In5 Cu4 104.59(4) 7_565 4_455 ?
Au4 In5 Cu4 131.12(5) . 4_455 ?
Cu4 In5 Cu4 53.49(5) 6_556 4_455 ?
Au4 In5 Cu4 53.49(5) 6_556 4_455 ?
Au2 In5 Au4 113.11(5) . 4_455 ?
Cu4 In5 Au4 104.59(4) 7_565 4_455 ?
Au4 In5 Au4 104.59(4) 7_565 4_455 ?
Au4 In5 Au4 131.12(5) . 4_455 ?
Cu4 In5 Au4 53.49(5) 6_556 4_455 ?
Au4 In5 Au4 53.49(5) 6_556 4_455 ?
Cu4 In5 Au4 0.00(7) 4_455 4_455 ?
Au2 In5 Cu3 114.23(3) . 2_554 ?
Cu4 In5 Cu3 103.38(5) 7_565 2_554 ?
Au4 In5 Cu3 103.38(5) 7_565 2_554 ?
Au4 In5 Cu3 53.78(3) . 2_554 ?
Cu4 In5 Cu3 55.24(4) 6_556 2_554 ?
Au4 In5 Cu3 55.24(4) 6_556 2_554 ?
Cu4 In5 Cu3 104.52(5) 4_455 2_554 ?
Au4 In5 Cu3 104.52(5) 4_455 2_554 ?
Au2 In5 Au3 114.23(3) . 2_554 ?
Cu4 In5 Au3 103.38(5) 7_565 2_554 ?
Au4 In5 Au3 103.38(5) 7_565 2_554 ?
Au4 In5 Au3 53.78(3) . 2_554 ?
Cu4 In5 Au3 55.24(4) 6_556 2_554 ?
Au4 In5 Au3 55.24(4) 6_556 2_554 ?
Cu4 In5 Au3 104.52(5) 4_455 2_554 ?
Au4 In5 Au3 104.52(5) 4_455 2_554 ?
Cu3 In5 Au3 0.00(6) 2_554 2_554 ?
Au2 In5 Cu3 114.23(3) . 2_564 ?
Cu4 In5 Cu3 53.78(3) 7_565 2_564 ?
Au4 In5 Cu3 53.78(3) 7_565 2_564 ?
Au4 In5 Cu3 103.38(5) . 2_564 ?
Cu4 In5 Cu3 104.52(5) 6_556 2_564 ?
Au4 In5 Cu3 104.52(5) 6_556 2_564 ?
Cu4 In5 Cu3 55.24(4) 4_455 2_564 ?
Au4 In5 Cu3 55.24(4) 4_455 2_564 ?
Cu3 In5 Cu3 131.54(7) 2_554 2_564 ?
Au3 In5 Cu3 131.54(7) 2_554 2_564 ?

_diffrn_measured_fraction_theta_max 0.973
_diffrn_reflns_theta_full        32.42
_diffrn_measured_fraction_theta_full 0.973
_refine_diff_density_max         4.178
_refine_diff_density_min         -3.029
_refine_diff_density_rms         0.795
