# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_shy17098
_database_code_depnum_ccdc_archive 'CCDC 1826208'
_audit_update_record             
;
2018-02-28 deposited with the CCDC.
2018-04-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        
'all-cis 1,2,3,4,5,6-hexafluorocyclohexane tetraphenylphosphonium chloride adduct'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C30 H28 Cl F6 O P'
_chemical_formula_weight         584.94

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.1352(3)
_cell_length_b                   13.5280(7)
_cell_length_c                   14.6245(8)
_cell_angle_alpha                70.019(5)
_cell_angle_beta                 86.507(4)
_cell_angle_gamma                89.808(4)
_cell_volume                     1323.96(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    5972
_cell_measurement_theta_min      2.8510
_cell_measurement_theta_max      28.8580

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_F_000             604
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.170
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.271
_shelx_estimated_absorpt_T_min   0.943
_shelx_estimated_absorpt_T_max   0.973
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.66840
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean 10.3385
_diffrn_reflns_number            14548
_diffrn_reflns_av_unetI/netI     0.0495
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.852
_diffrn_reflns_theta_max         29.520
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.859
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.859
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.859
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             6333
_reflns_number_gt                5056
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0638P)²+0.2834P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6333
_refine_ls_number_parameters     355
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0634
_refine_ls_R_factor_gt           0.0493
_refine_ls_wR_factor_ref         0.1341
_refine_ls_wR_factor_gt          0.1211
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P001 P 0.09091(7) 0.82525(3) 0.77916(3) 0.02374(13) Uani 1 1 d . . . . .
Cl02 Cl -0.11621(7) 0.63354(4) 0.53986(4) 0.03462(14) Uani 1 1 d . . . . .
F003 F -0.46707(17) 0.69436(10) 1.23292(9) 0.0417(3) Uani 1 1 d . . . . .
F004 F -0.15899(18) 0.79587(10) 1.11174(9) 0.0441(3) Uani 1 1 d . . . . .
F005 F -0.38981(19) 0.48949(9) 1.33757(10) 0.0464(3) Uani 1 1 d . . . . .
F006 F -0.27762(19) 0.85270(9) 1.26874(11) 0.0493(4) Uani 1 1 d . . . . .
F007 F -0.2242(2) 0.57721(11) 1.15532(10) 0.0500(4) Uani 1 1 d . . . . .
F008 F 0.12753(19) 0.65993(11) 1.12775(10) 0.0509(4) Uani 1 1 d . . . . .
O00 O 0.2445(2) 0.60891(12) 0.41831(12) 0.0420(4) Uani 1 1 d G . . . .
H00A H 0.147320 0.613261 0.453267 0.063 Uiso 1 1 d G U . . .
H00B H 0.246679 0.544692 0.422546 0.063 Uiso 1 1 d G U . . .
C00A C 0.2627(3) 0.81958(14) 0.68676(14) 0.0257(4) Uani 1 1 d . . . . .
C00B C 0.2171(3) 0.83550(13) 0.87841(14) 0.0250(4) Uani 1 1 d . . . . .
C00C C -0.0493(3) 0.94051(13) 0.73308(14) 0.0246(4) Uani 1 1 d . . . . .
C00D C -0.0652(3) 0.71316(13) 0.81949(14) 0.0250(4) Uani 1 1 d . . . . .
C00E C 0.2589(3) 0.74621(14) 0.63947(14) 0.0287(4) Uani 1 1 d . . . . .
H00E H 0.160097 0.695109 0.655207 0.034 Uiso 1 1 calc R U . . .
C00F C 0.4105(3) 0.89436(15) 0.66311(15) 0.0296(4) Uani 1 1 d . . . . .
H00F H 0.414873 0.944221 0.695590 0.035 Uiso 1 1 calc R U . . .
C00G C -0.1760(3) 0.69507(14) 0.75070(14) 0.0278(4) Uani 1 1 d . . . . .
H00G H -0.164421 0.740427 0.684626 0.033 Uiso 1 1 calc R U . . .
C00H C 0.0002(3) 1.02027(14) 0.64549(15) 0.0300(4) Uani 1 1 d . . . . .
H00H H 0.106155 1.012792 0.605925 0.036 Uiso 1 1 calc R U . . .
C00I C 0.1824(3) 0.91575(14) 0.91633(15) 0.0283(4) Uani 1 1 d . . . . .
H00I H 0.087790 0.965564 0.891294 0.034 Uiso 1 1 calc R U . . .
C00J C -0.0854(3) 0.64865(14) 0.91724(14) 0.0287(4) Uani 1 1 d . . . . .
H00J H -0.012357 0.661671 0.964259 0.034 Uiso 1 1 calc R U . . .
C00K C -0.2068(3) 0.95027(14) 0.79065(15) 0.0284(4) Uani 1 1 d . . . . .
H00K H -0.242390 0.895101 0.849768 0.034 Uiso 1 1 calc R U . . .
C00L C 0.5490(3) 0.89535(15) 0.59281(16) 0.0322(4) Uani 1 1 d . . . . .
H00L H 0.648124 0.946300 0.576466 0.039 Uiso 1 1 calc R U . . .
C00M C -0.3020(3) 0.61121(15) 0.77908(16) 0.0322(4) Uani 1 1 d . . . . .
H00M H -0.375267 0.597753 0.732353 0.039 Uiso 1 1 calc R U . . .
C00N C 0.3996(3) 0.74791(14) 0.56942(15) 0.0316(4) Uani 1 1 d . . . . .
H00N H 0.396999 0.697746 0.537205 0.038 Uiso 1 1 calc R U . . .
C00O C -0.2143(3) 0.56486(15) 0.94486(15) 0.0324(4) Uani 1 1 d . . . . .
H00O H -0.228961 0.520015 1.011036 0.039 Uiso 1 1 calc R U . . .
C00P C 0.5438(3) 0.82208(15) 0.54597(15) 0.0320(4) Uani 1 1 d . . . . .
H00P H 0.639504 0.822815 0.497640 0.038 Uiso 1 1 calc R U . . .
C00Q C 0.4604(3) 0.77018(15) 0.98969(15) 0.0319(4) Uani 1 1 d . . . . .
H00Q H 0.554702 0.720315 1.015174 0.038 Uiso 1 1 calc R U . . .
C00R C 0.4254(3) 0.85016(15) 1.02772(15) 0.0321(4) Uani 1 1 d . . . . .
H00R H 0.496416 0.855186 1.078905 0.039 Uiso 1 1 calc R U . . .
C00S C -0.2514(3) 0.56670(14) 1.32159(15) 0.0313(4) Uani 1 1 d . . . . .
H00S H -0.177072 0.548459 1.380764 0.038 Uiso 1 1 calc R U . . .
C00T C 0.3580(3) 0.76327(14) 0.91493(14) 0.0288(4) Uani 1 1 d . . . . .
H00T H 0.383451 0.709341 0.888248 0.035 Uiso 1 1 calc R U . . .
C00U C -0.3455(3) 0.67073(15) 1.30835(15) 0.0310(4) Uani 1 1 d . . . . .
H00U H -0.417709 0.666874 1.370287 0.037 Uiso 1 1 calc R U . . .
C00V C -0.3110(3) 1.04145(15) 0.76064(16) 0.0323(4) Uani 1 1 d . . . . .
H00V H -0.417835 1.048994 0.799629 0.039 Uiso 1 1 calc R U . . .
C00W C -0.1939(3) 0.75497(14) 1.28478(16) 0.0325(4) Uani 1 1 d . . . . .
H00W H -0.116794 0.739833 1.342733 0.039 Uiso 1 1 calc R U . . .
C00X C -0.3212(3) 0.54691(15) 0.87581(16) 0.0329(4) Uani 1 1 d . . . . .
H00X H -0.408740 0.489648 0.895212 0.039 Uiso 1 1 calc R U . . .
C00Y C 0.2873(3) 0.92236(15) 0.99101(16) 0.0337(5) Uani 1 1 d . . . . .
H00Y H 0.264067 0.976938 1.017109 0.040 Uiso 1 1 calc R U . . .
C00Z C -0.1214(3) 0.56635(15) 1.23628(16) 0.0349(5) Uani 1 1 d . . . . .
H00Z H -0.054136 0.498050 1.254173 0.042 Uiso 1 1 calc R U . . .
C010 C -0.0632(3) 0.76224(15) 1.19725(15) 0.0320(4) Uani 1 1 d . . . . .
H010 H 0.040151 0.814042 1.191854 0.038 Uiso 1 1 calc R U . . .
C011 C -0.1057(3) 1.11112(15) 0.61583(16) 0.0359(5) Uani 1 1 d . . . . .
H011 H -0.072430 1.165776 0.555993 0.043 Uiso 1 1 calc R U . . .
C012 C -0.2596(3) 1.12133(15) 0.67404(17) 0.0358(5) Uani 1 1 d . . . . .
H012 H -0.330718 1.183774 0.654383 0.043 Uiso 1 1 calc R U . . .
C013 C 0.0212(3) 0.65538(16) 1.21220(16) 0.0336(4) Uani 1 1 d . . . . .
H013 H 0.106905 0.639520 1.266836 0.040 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P001 C00A 1.789(2) . ?
P001 C00D 1.7909(18) . ?
P001 C00B 1.7983(19) . ?
P001 C00C 1.8000(18) . ?
F003 C00U 1.395(2) . ?
F004 C010 1.397(2) . ?
F005 C00S 1.390(2) . ?
F006 C00W 1.400(2) . ?
F007 C00Z 1.396(2) . ?
F008 C013 1.392(2) . ?
O00 H00A 0.8501 . ?
O00 H00B 0.8497 . ?
C00A C00E 1.391(3) . ?
C00A C00F 1.407(3) . ?
C00B C00I 1.393(3) . ?
C00B C00T 1.398(3) . ?
C00C C00H 1.390(3) . ?
C00C C00K 1.396(3) . ?
C00D C00J 1.396(3) . ?
C00D C00G 1.401(3) . ?
C00E C00N 1.384(3) . ?
C00E H00E 0.9500 . ?
C00F C00L 1.379(3) . ?
C00F H00F 0.9500 . ?
C00G C00M 1.381(3) . ?
C00G H00G 0.9500 . ?
C00H C011 1.392(3) . ?
C00H H00H 0.9500 . ?
C00I C00Y 1.389(3) . ?
C00I H00I 0.9500 . ?
C00J C00O 1.394(3) . ?
C00J H00J 0.9500 . ?
C00K C00V 1.390(3) . ?
C00K H00K 0.9500 . ?
C00L C00P 1.386(3) . ?
C00L H00L 0.9500 . ?
C00M C00X 1.383(3) . ?
C00M H00M 0.9500 . ?
C00N C00P 1.383(3) . ?
C00N H00N 0.9500 . ?
C00O C00X 1.387(3) . ?
C00O H00O 0.9500 . ?
C00P H00P 0.9500 . ?
C00Q C00T 1.380(3) . ?
C00Q C00R 1.391(3) . ?
C00Q H00Q 0.9500 . ?
C00R C00Y 1.383(3) . ?
C00R H00R 0.9500 . ?
C00S C00Z 1.510(3) . ?
C00S C00U 1.514(3) . ?
C00S H00S 1.0000 . ?
C00T H00T 0.9500 . ?
C00U C00W 1.511(3) . ?
C00U H00U 1.0000 . ?
C00V C012 1.384(3) . ?
C00V H00V 0.9500 . ?
C00W C010 1.512(3) . ?
C00W H00W 1.0000 . ?
C00X H00X 0.9500 . ?
C00Y H00Y 0.9500 . ?
C00Z C013 1.512(3) . ?
C00Z H00Z 1.0000 . ?
C010 C013 1.515(3) . ?
C010 H010 1.0000 . ?
C011 C012 1.384(3) . ?
C011 H011 0.9500 . ?
C012 H012 0.9500 . ?
C013 H013 1.0000 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C00A P001 C00D 112.60(8) . . ?
C00A P001 C00B 106.91(9) . . ?
C00D P001 C00B 110.95(9) . . ?
C00A P001 C00C 109.95(9) . . ?
C00D P001 C00C 107.60(8) . . ?
C00B P001 C00C 108.78(8) . . ?
H00A O00 H00B 104.5 . . ?
C00E C00A C00F 119.46(18) . . ?
C00E C00A P001 124.22(15) . . ?
C00F C00A P001 116.31(14) . . ?
C00I C00B C00T 119.87(17) . . ?
C00I C00B P001 121.52(14) . . ?
C00T C00B P001 118.56(14) . . ?
C00H C00C C00K 120.29(17) . . ?
C00H C00C P001 121.91(15) . . ?
C00K C00C P001 117.74(14) . . ?
C00J C00D C00G 120.32(17) . . ?
C00J C00D P001 121.66(14) . . ?
C00G C00D P001 117.92(14) . . ?
C00N C00E C00A 119.78(18) . . ?
C00N C00E H00E 120.1 . . ?
C00A C00E H00E 120.1 . . ?
C00L C00F C00A 120.04(18) . . ?
C00L C00F H00F 120.0 . . ?
C00A C00F H00F 120.0 . . ?
C00M C00G C00D 119.92(19) . . ?
C00M C00G H00G 120.0 . . ?
C00D C00G H00G 120.0 . . ?
C00C C00H C011 119.90(19) . . ?
C00C C00H H00H 120.0 . . ?
C011 C00H H00H 120.0 . . ?
C00Y C00I C00B 119.46(18) . . ?
C00Y C00I H00I 120.3 . . ?
C00B C00I H00I 120.3 . . ?
C00O C00J C00D 119.05(18) . . ?
C00O C00J H00J 120.5 . . ?
C00D C00J H00J 120.5 . . ?
C00V C00K C00C 119.36(18) . . ?
C00V C00K H00K 120.3 . . ?
C00C C00K H00K 120.3 . . ?
C00F C00L C00P 120.06(18) . . ?
C00F C00L H00L 120.0 . . ?
C00P C00L H00L 120.0 . . ?
C00G C00M C00X 119.73(19) . . ?
C00G C00M H00M 120.1 . . ?
C00X C00M H00M 120.1 . . ?
C00P C00N C00E 120.51(18) . . ?
C00P C00N H00N 119.7 . . ?
C00E C00N H00N 119.7 . . ?
C00X C00O C00J 120.05(19) . . ?
C00X C00O H00O 120.0 . . ?
C00J C00O H00O 120.0 . . ?
C00N C00P C00L 120.15(19) . . ?
C00N C00P H00P 119.9 . . ?
C00L C00P H00P 119.9 . . ?
C00T C00Q C00R 120.00(18) . . ?
C00T C00Q H00Q 120.0 . . ?
C00R C00Q H00Q 120.0 . . ?
C00Y C00R C00Q 119.98(18) . . ?
C00Y C00R H00R 120.0 . . ?
C00Q C00R H00R 120.0 . . ?
F005 C00S C00Z 108.69(16) . . ?
F005 C00S C00U 108.58(16) . . ?
C00Z C00S C00U 114.35(17) . . ?
F005 C00S H00S 108.4 . . ?
C00Z C00S H00S 108.4 . . ?
C00U C00S H00S 108.4 . . ?
C00Q C00T C00B 120.11(17) . . ?
C00Q C00T H00T 119.9 . . ?
C00B C00T H00T 119.9 . . ?
F003 C00U C00W 109.92(16) . . ?
F003 C00U C00S 110.65(16) . . ?
C00W C00U C00S 108.02(16) . . ?
F003 C00U H00U 109.4 . . ?
C00W C00U H00U 109.4 . . ?
C00S C00U H00U 109.4 . . ?
C012 C00V C00K 120.16(19) . . ?
C012 C00V H00V 119.9 . . ?
C00K C00V H00V 119.9 . . ?
F006 C00W C00U 109.15(16) . . ?
F006 C00W C010 108.61(16) . . ?
C00U C00W C010 114.62(17) . . ?
F006 C00W H00W 108.1 . . ?
C00U C00W H00W 108.1 . . ?
C010 C00W H00W 108.1 . . ?
C00M C00X C00O 120.92(18) . . ?
C00M C00X H00X 119.5 . . ?
C00O C00X H00X 119.5 . . ?
C00R C00Y C00I 120.57(18) . . ?
C00R C00Y H00Y 119.7 . . ?
C00I C00Y H00Y 119.7 . . ?
F007 C00Z C00S 110.13(17) . . ?
F007 C00Z C013 109.89(17) . . ?
C00S C00Z C013 109.74(16) . . ?
F007 C00Z H00Z 109.0 . . ?
C00S C00Z H00Z 109.0 . . ?
C013 C00Z H00Z 109.0 . . ?
F004 C010 C00W 110.84(16) . . ?
F004 C010 C013 110.52(17) . . ?
C00W C010 C013 108.85(16) . . ?
F004 C010 H010 108.9 . . ?
C00W C010 H010 108.9 . . ?
C013 C010 H010 108.9 . . ?
C012 C011 C00H 119.6(2) . . ?
C012 C011 H011 120.2 . . ?
C00H C011 H011 120.2 . . ?
C011 C012 C00V 120.66(19) . . ?
C011 C012 H012 119.7 . . ?
C00V C012 H012 119.7 . . ?
F008 C013 C00Z 108.73(16) . . ?
F008 C013 C010 108.63(17) . . ?
C00Z C013 C010 114.32(17) . . ?
F008 C013 H013 108.3 . . ?
C00Z C013 H013 108.3 . . ?
C010 C013 H013 108.3 . . ?

_refine_diff_density_max         0.515
_refine_diff_density_min         -0.325
_refine_diff_density_rms         0.062


_exptl_crystal_recrystallization_method 
'Solvent layering/ Acetone+chloroform/n-hexane'
