# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_GeRu_dimer
_database_code_depnum_ccdc_archive 'CCDC 1827996'
_audit_update_record             
;
2018-03-07 deposited with the CCDC.
2018-05-22 downloaded from the CCDC.
;
_audit_creation_method           SHELXL-2016/6

_chemical_name_systematic        GeRu_dimer
_chemical_name_common            GeRu_dimer
_chemical_melting_point          472
_chemical_formula_moiety         'C38 H56 Ge2 Ru2'
_chemical_formula_sum            'C38 H56 Ge2 Ru2'
_chemical_formula_weight         860.14

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge -0.1018 2.2119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C -0.0020 0.0021 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.1448 1.0405 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.4301(2)
_cell_length_b                   11.9637(2)
_cell_length_c                   13.1386(2)
_cell_angle_alpha                87.8950(10)
_cell_angle_beta                 84.2490(10)
_cell_angle_gamma                88.7100(10)
_cell_volume                     1786.09(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    74278
_cell_measurement_theta_min      1.755
_cell_measurement_theta_max      28.750

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_F_000             872
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.040
_exptl_crystal_size_mid          0.020
_exptl_crystal_size_min          0.010
_exptl_absorpt_coefficient_mu    3.438
_shelx_estimated_absorpt_T_min   0.875
_shelx_estimated_absorpt_T_max   0.966
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.87639
_exptl_absorpt_correction_T_max  0.95334
_exptl_absorpt_process_details   
;
 MULABS - Empirical Correction for Absorption Anisotropy.
 Blessing, R. H., Acta Cryst., A51, 33-38 (1995).
;
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.800
_diffrn_radiation_type           synchrotron
_diffrn_source                   ?
_diffrn_measurement_device_type  'Rayonix MX225HE'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            60400
_diffrn_reflns_av_unetI/netI     0.0252
_diffrn_reflns_av_R_equivalents  0.0708
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.755
_diffrn_reflns_theta_max         28.750
_diffrn_reflns_theta_full        28.685
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             6488
_reflns_number_gt                5773
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrystalClear (Rigaku, 1999)'
_computing_cell_refinement       'HKL2000 (Otwinowski & Minor, 1997)'
_computing_data_reduction        'HKL2000 (Otwinowski & Minor, 1997)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL2016 (Sheldrick, 2015)'
_computing_molecular_graphics    
;
Yadokari-XG (Wakita, 2001; Kabuto et al., 2009)
Mercury (Macrae et al., 2008)
Crystal Maker (Palmer, 2007)
;
_computing_publication_material  
;
Yadokari-XG (Wakita, 2001; Kabuto et al., 2009)
;

_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0832P)²+1.9329P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6488
_refine_ls_number_parameters     421
_refine_ls_number_restraints     10
_refine_ls_R_factor_all          0.0487
_refine_ls_R_factor_gt           0.0444
_refine_ls_wR_factor_ref         0.1303
_refine_ls_wR_factor_gt          0.1276
_refine_ls_goodness_of_fit_ref   1.116
_refine_ls_restrained_S_all      1.115
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.80379(4) 0.23637(4) 0.19867(4) 0.03644(15) Uani 1 1 d . . . . .
C1 C 0.7514(4) 0.2277(4) 0.0610(4) 0.0411(11) Uani 1 1 d . . . . .
C2 C 0.7518(5) 0.3279(4) 0.0131(4) 0.0452(12) Uani 1 1 d . . . . .
H2 H 0.718561 0.333228 -0.050436 0.054 Uiso 1 1 calc R U . . .
C3 C 0.7989(5) 0.4307(4) 0.0496(4) 0.0440(12) Uani 1 1 d . . . . .
H52 H 0.792106 0.496851 0.001578 0.053 Uiso 1 1 calc R U . . .
C4 C 0.9087(5) 0.4250(4) 0.0953(4) 0.0421(11) Uani 1 1 d . . . . .
H49 H 0.970592 0.473554 0.070679 0.051 Uiso 1 1 calc R U . . .
C5 C 0.9241(4) 0.3479(4) 0.1761(4) 0.0387(10) Uani 1 1 d . . . . .
H50 H 0.997996 0.343208 0.210997 0.046 Uiso 1 1 calc R U . . .
Ge2 Ge 0.63834(4) 0.34198(4) 0.29404(4) 0.03623(15) Uani 1 1 d . . . . .
C6 C 0.5018(4) 0.2668(4) 0.2483(4) 0.0410(11) Uani 1 1 d . . . . .
C7 C 0.4956(4) 0.1611(5) 0.2843(4) 0.0447(12) Uani 1 1 d . . . . .
H7 H 0.438931 0.115294 0.259002 0.054 Uiso 1 1 calc R U . . .
C8 C 0.5684(4) 0.1094(4) 0.3595(4) 0.0450(12) Uani 1 1 d . . . . .
H53 H 0.548769 0.029505 0.377240 0.054 Uiso 1 1 calc R U . . .
C9 C 0.5906(4) 0.1723(4) 0.4473(4) 0.0427(11) Uani 1 1 d . . . . .
H51 H 0.572617 0.141927 0.514755 0.051 Uiso 1 1 calc R U . . .
C10 C 0.6390(4) 0.2783(4) 0.4313(4) 0.0407(11) Uani 1 1 d . . . . .
H10 H 0.659385 0.323473 0.489368 0.049 Uiso 1 1 calc R U . . .
Ru1 Ru 0.78315(3) 0.47513(3) 0.21449(3) 0.03359(13) Uani 1 1 d . . . . .
Ru2 Ru 0.75662(3) 0.14562(3) 0.36715(3) 0.03498(13) Uani 1 1 d . . . . .
C11 C 0.7294(5) 0.1177(5) 0.0118(4) 0.0484(12) Uani 1 1 d . . . . .
C12 C 0.8476(6) 0.0537(6) -0.0024(6) 0.076(2) Uani 1 1 d . . . . .
H12 H 0.837272 -0.016303 -0.036702 0.113 Uiso 1 1 calc R U . . .
H12A H 0.875598 0.036793 0.064673 0.113 Uiso 1 1 calc R U . . .
H12B H 0.905235 0.099660 -0.044177 0.113 Uiso 1 1 calc R U . . .
C13 C 0.6815(8) 0.1339(6) -0.0902(5) 0.082(2) Uani 1 1 d . . . . .
H13 H 0.602331 0.167500 -0.080568 0.123 Uiso 1 1 calc R U . . .
H13A H 0.677877 0.061334 -0.121896 0.123 Uiso 1 1 calc R U . . .
H13B H 0.732966 0.183444 -0.134648 0.123 Uiso 1 1 calc R U . . .
C14 C 0.6464(6) 0.0419(5) 0.0810(5) 0.0599(15) Uani 1 1 d . . . . .
H14 H 0.568226 0.077502 0.090551 0.090 Uiso 1 1 calc R U . . .
H14A H 0.677259 0.030027 0.147574 0.090 Uiso 1 1 calc R U . . .
H14B H 0.640776 -0.030290 0.049038 0.090 Uiso 1 1 calc R U . . .
C15 C 0.4083(4) 0.3278(5) 0.1912(4) 0.0483(12) Uani 1 1 d . . . . .
C16 C 0.4642(5) 0.3975(5) 0.1002(5) 0.0569(15) Uani 1 1 d . . . . .
H16 H 0.504592 0.347726 0.049861 0.085 Uiso 1 1 calc R U . . .
H16A H 0.521084 0.448370 0.123768 0.085 Uiso 1 1 calc R U . . .
H16B H 0.402966 0.441046 0.068639 0.085 Uiso 1 1 calc R U . . .
C17 C 0.3397(7) 0.4059(8) 0.2654(6) 0.091(3) Uani 1 1 d . . . . .
H17 H 0.282052 0.449672 0.229348 0.137 Uiso 1 1 calc R U . . .
H17A H 0.394071 0.456617 0.292641 0.137 Uiso 1 1 calc R U . . .
H17B H 0.298768 0.361766 0.321782 0.137 Uiso 1 1 calc R U . . .
C18 C 0.3228(6) 0.2480(6) 0.1522(5) 0.0713(19) Uani 1 1 d . . . . .
H18 H 0.365858 0.197009 0.104486 0.107 Uiso 1 1 calc R U . . .
H18A H 0.263886 0.290810 0.116962 0.107 Uiso 1 1 calc R U . . .
H18B H 0.283591 0.204685 0.210070 0.107 Uiso 1 1 calc R U . . .
C19 C 0.8108(5) 0.5687(4) 0.3531(4) 0.0446(12) Uani 1 1 d . . . . .
C20 C 0.8938(5) 0.6011(4) 0.2704(4) 0.0443(11) Uani 1 1 d . . . . .
C21 C 0.8303(5) 0.6506(4) 0.1912(4) 0.0425(11) Uani 1 1 d . . . . .
C22 C 0.7087(5) 0.6485(4) 0.2244(4) 0.0430(11) Uani 1 1 d . . . . .
C23 C 0.6972(5) 0.5990(4) 0.3240(4) 0.0426(11) Uani 1 1 d . . . . .
C24 C 0.8378(7) 0.5260(5) 0.4564(5) 0.0659(17) Uani 1 1 d . . . . .
H24 H 0.908042 0.477342 0.449534 0.099 Uiso 1 1 calc R U . . .
H24A H 0.771047 0.483437 0.489003 0.099 Uiso 1 1 calc R U . . .
H24B H 0.851957 0.589221 0.498662 0.099 Uiso 1 1 calc R U . . .
C25 C 1.0249(5) 0.5916(5) 0.2692(5) 0.0613(15) Uani 1 1 d . . . . .
H25 H 1.055416 0.662145 0.290344 0.092 Uiso 1 1 calc R U . . .
H25A H 1.059604 0.575794 0.199811 0.092 Uiso 1 1 calc R U . . .
H25B H 1.045486 0.530797 0.316526 0.092 Uiso 1 1 calc R U . . .
C26 C 0.8847(6) 0.7046(5) 0.0928(4) 0.0586(15) Uani 1 1 d . . . . .
H26 H 0.847551 0.676178 0.035128 0.088 Uiso 1 1 calc R U . . .
H26A H 0.969119 0.686785 0.084440 0.088 Uiso 1 1 calc R U . . .
H26B H 0.872710 0.785859 0.094981 0.088 Uiso 1 1 calc R U . . .
C27 C 0.6127(6) 0.7013(5) 0.1682(5) 0.0583(15) Uani 1 1 d . . . . .
H27 H 0.539190 0.661695 0.187325 0.087 Uiso 1 1 calc R U . . .
H27A H 0.633910 0.696923 0.094302 0.087 Uiso 1 1 calc R U . . .
H27B H 0.602122 0.779939 0.186228 0.087 Uiso 1 1 calc R U . . .
C28 C 0.5871(6) 0.5964(5) 0.3954(5) 0.0629(17) Uani 1 1 d . . . . .
H28 H 0.585977 0.659070 0.441485 0.094 Uiso 1 1 calc R U . . .
H28A H 0.584272 0.525748 0.435635 0.094 Uiso 1 1 calc R U . . .
H28B H 0.518807 0.602716 0.355880 0.094 Uiso 1 1 calc R U . . .
C29 C 0.8681(7) -0.0099(7) 0.3652(7) 0.048(2) Uani 0.817(6) 1 d D . P A 1
C30 C 0.8059(11) 0.0027(7) 0.4642(9) 0.053(3) Uani 0.817(6) 1 d D . P A 1
C31 C 0.8426(8) 0.1012(8) 0.5063(6) 0.053(2) Uani 0.817(6) 1 d D . P A 1
C32 C 0.9304(7) 0.1491(6) 0.4352(8) 0.0459(17) Uani 0.817(6) 1 d D . P A 1
C33 C 0.9454(6) 0.0825(7) 0.3487(7) 0.0414(17) Uani 0.817(6) 1 d D . P A 1
C34 C 0.8639(10) -0.1051(7) 0.2944(9) 0.093(4) Uani 0.817(6) 1 d . . P A 1
H34 H 0.803545 -0.157682 0.322757 0.140 Uiso 0.817(6) 1 calc R U P A 1
H34A H 0.844746 -0.076095 0.227261 0.140 Uiso 0.817(6) 1 calc R U P A 1
H34B H 0.940630 -0.143738 0.287139 0.140 Uiso 0.817(6) 1 calc R U P A 1
C35 C 0.7181(8) -0.0796(10) 0.5148(10) 0.100(5) Uani 0.817(6) 1 d . . P A 1
H35 H 0.708947 -0.140440 0.468481 0.150 Uiso 0.817(6) 1 calc R U P A 1
H35A H 0.746293 -0.110387 0.578282 0.150 Uiso 0.817(6) 1 calc R U P A 1
H35B H 0.642060 -0.041359 0.530605 0.150 Uiso 0.817(6) 1 calc R U P A 1
C36 C 0.8009(10) 0.1421(10) 0.6111(6) 0.099(4) Uani 0.817(6) 1 d . . P A 1
H36 H 0.839567 0.212333 0.622035 0.148 Uiso 0.817(6) 1 calc R U P A 1
H36A H 0.715516 0.154656 0.616382 0.148 Uiso 0.817(6) 1 calc R U P A 1
H36B H 0.820465 0.085847 0.663191 0.148 Uiso 0.817(6) 1 calc R U P A 1
C37 C 0.9994(8) 0.2488(7) 0.4550(9) 0.082(3) Uani 0.817(6) 1 d . . P A 1
H37 H 0.969768 0.278840 0.521274 0.122 Uiso 0.817(6) 1 calc R U P A 1
H37A H 1.082451 0.227052 0.455946 0.122 Uiso 0.817(6) 1 calc R U P A 1
H37B H 0.991354 0.306130 0.400781 0.122 Uiso 0.817(6) 1 calc R U P A 1
C38 C 1.0416(7) 0.0973(8) 0.2662(6) 0.071(2) Uani 0.817(6) 1 d . . P A 1
H38 H 1.034983 0.041998 0.213958 0.106 Uiso 0.817(6) 1 calc R U P A 1
H38A H 1.036358 0.172797 0.235215 0.106 Uiso 0.817(6) 1 calc R U P A 1
H38B H 1.117354 0.086993 0.294523 0.106 Uiso 0.817(6) 1 calc R U P A 1
C39 C 0.917(3) 0.048(4) 0.328(2) 0.0414(17) Uani 0.183(6) 1 d D . P A 2
C40 C 0.826(3) -0.015(3) 0.385(4) 0.048(2) Uani 0.183(6) 1 d D . P A 2
C41 C 0.802(6) 0.033(5) 0.481(4) 0.053(3) Uani 0.183(6) 1 d D . P A 2
C42 C 0.881(5) 0.122(5) 0.485(3) 0.053(2) Uani 0.183(6) 1 d D . P A 2
C43 C 0.939(3) 0.141(3) 0.387(3) 0.0459(17) Uani 0.183(6) 1 d D . P A 2
C44 C 0.979(3) 0.017(4) 0.224(3) 0.071(2) Uani 0.183(6) 1 d . . P A 2
H44 H 0.945707 -0.051498 0.201143 0.106 Uiso 0.183(6) 1 calc R U P A 2
H44A H 0.968152 0.078133 0.173460 0.106 Uiso 0.183(6) 1 calc R U P A 2
H44B H 1.063270 0.004974 0.229529 0.106 Uiso 0.183(6) 1 calc R U P A 2
C45 C 0.771(4) -0.125(3) 0.350(4) 0.093(4) Uani 0.183(6) 1 d . . P A 2
H45 H 0.802634 -0.139561 0.279132 0.140 Uiso 0.183(6) 1 calc R U P A 2
H45A H 0.790796 -0.188383 0.394670 0.140 Uiso 0.183(6) 1 calc R U P A 2
H45B H 0.685196 -0.115965 0.352804 0.140 Uiso 0.183(6) 1 calc R U P A 2
C46 C 0.724(4) -0.011(5) 0.580(5) 0.100(5) Uani 0.183(6) 1 d . . P A 2
H46 H 0.725727 0.042501 0.634122 0.150 Uiso 0.183(6) 1 calc R U P A 2
H46A H 0.642777 -0.019052 0.563466 0.150 Uiso 0.183(6) 1 calc R U P A 2
H46B H 0.754844 -0.083765 0.602500 0.150 Uiso 0.183(6) 1 calc R U P A 2
C47 C 0.880(5) 0.195(5) 0.567(3) 0.099(4) Uani 0.183(6) 1 d . . P A 2
H47 H 0.832880 0.163143 0.627042 0.148 Uiso 0.183(6) 1 calc R U P A 2
H47A H 0.960925 0.204874 0.583649 0.148 Uiso 0.183(6) 1 calc R U P A 2
H47B H 0.846307 0.267978 0.547808 0.148 Uiso 0.183(6) 1 calc R U P A 2
C48 C 1.039(4) 0.226(3) 0.372(4) 0.082(3) Uani 0.183(6) 1 d . . P A 2
H48 H 1.070538 0.229697 0.299555 0.122 Uiso 0.183(6) 1 calc R U P A 2
H48A H 1.007846 0.300260 0.391546 0.122 Uiso 0.183(6) 1 calc R U P A 2
H48B H 1.101274 0.203173 0.414254 0.122 Uiso 0.183(6) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C5 1.932(5) . ?
Ge1 C1 1.968(5) . ?
Ge1 Ru2 2.4454(6) . ?
Ge1 Ge2 2.5053(7) . ?
Ge1 Ru1 2.8744(6) . ?
C1 C2 1.333(7) . ?
C1 C11 1.526(7) . ?
C2 C3 1.470(7) . ?
C2 H2 0.9500 . ?
C3 C4 1.444(8) . ?
C3 Ru1 2.239(5) . ?
C3 H52 1.0000 . ?
C4 C5 1.401(7) . ?
C4 Ru1 2.109(5) . ?
C4 H49 0.9500 . ?
C5 Ru1 2.225(4) . ?
C5 H50 1.0000 . ?
Ge2 C10 1.932(5) . ?
Ge2 C6 1.974(5) . ?
Ge2 Ru1 2.4534(6) . ?
Ge2 Ru2 2.8671(6) . ?
C6 C7 1.335(7) . ?
C6 C15 1.524(7) . ?
C7 C8 1.465(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.447(8) . ?
C8 Ru2 2.217(5) . ?
C8 H53 1.0000 . ?
C9 C10 1.395(7) . ?
C9 Ru2 2.100(5) . ?
C9 H51 0.9500 . ?
C10 Ru2 2.194(5) . ?
C10 H10 1.0000 . ?
Ru1 C21 2.182(5) . ?
Ru1 C20 2.183(5) . ?
Ru1 C19 2.225(5) . ?
Ru1 C22 2.227(5) . ?
Ru1 C23 2.245(4) . ?
Ru2 C40 2.08(5) . ?
Ru2 C41 2.08(7) . ?
Ru2 C43 2.12(4) . ?
Ru2 C39 2.18(4) . ?
Ru2 C30 2.192(12) . ?
Ru2 C42 2.20(5) . ?
Ru2 C31 2.204(9) . ?
Ru2 C29 2.231(7) . ?
Ru2 C32 2.260(7) . ?
C11 C13 1.502(8) . ?
C11 C14 1.534(8) . ?
C11 C12 1.536(9) . ?
C12 H12 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C13 H13 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C14 H14 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C15 C18 1.519(9) . ?
C15 C17 1.522(9) . ?
C15 C16 1.527(8) . ?
C16 H16 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C17 H17 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C18 H18 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C19 C20 1.417(7) . ?
C19 C23 1.426(8) . ?
C19 C24 1.492(8) . ?
C20 C21 1.432(7) . ?
C20 C25 1.498(8) . ?
C21 C22 1.414(7) . ?
C21 C26 1.507(7) . ?
C22 C23 1.412(7) . ?
C22 C27 1.499(8) . ?
C23 C28 1.492(7) . ?
C24 H24 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C25 H25 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C26 H26 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C27 H27 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C28 H28 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C29 C33 1.428(11) . ?
C29 C30 1.429(12) . ?
C29 C34 1.501(11) . ?
C30 C31 1.410(14) . ?
C30 C35 1.511(13) . ?
C31 C32 1.416(11) . ?
C31 C36 1.507(11) . ?
C32 C33 1.407(11) . ?
C32 C37 1.489(11) . ?
C33 C38 1.473(10) . ?
C34 H34 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C35 H35 0.9800 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C36 H36 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C37 H37 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C38 H38 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C39 C43 1.42(2) . ?
C39 C40 1.44(2) . ?
C39 C44 1.53(5) . ?
C40 C41 1.40(2) . ?
C40 C45 1.58(5) . ?
C41 C42 1.42(2) . ?
C41 C46 1.57(6) . ?
C42 C43 1.40(2) . ?
C42 C47 1.41(6) . ?
C43 C48 1.54(5) . ?
C44 H44 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C45 H45 0.9800 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C46 H46 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C47 H47 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C48 H48 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C5 Ge1 C1 101.6(2) . . ?
C5 Ge1 Ru2 121.32(15) . . ?
C1 Ge1 Ru2 137.07(15) . . ?
C5 Ge1 Ge2 102.25(13) . . ?
C1 Ge1 Ge2 102.87(15) . . ?
Ru2 Ge1 Ge2 70.768(19) . . ?
C5 Ge1 Ru1 50.63(13) . . ?
C1 Ge1 Ru1 97.39(15) . . ?
Ru2 Ge1 Ru1 109.81(2) . . ?
Ge2 Ge1 Ru1 53.735(16) . . ?
C2 C1 C11 124.8(5) . . ?
C2 C1 Ge1 111.4(4) . . ?
C11 C1 Ge1 123.4(4) . . ?
C1 C2 C3 125.9(5) . . ?
C1 C2 H2 117.1 . . ?
C3 C2 H2 117.1 . . ?
C4 C3 C2 119.1(4) . . ?
C4 C3 Ru1 65.8(3) . . ?
C2 C3 Ru1 123.4(3) . . ?
C4 C3 H52 113.4 . . ?
C2 C3 H52 113.4 . . ?
Ru1 C3 H52 113.4 . . ?
C5 C4 C3 120.2(5) . . ?
C5 C4 Ru1 75.7(3) . . ?
C3 C4 Ru1 75.5(3) . . ?
C5 C4 H49 119.9 . . ?
C3 C4 H49 119.9 . . ?
Ru1 C4 H49 119.9 . . ?
C4 C5 Ge1 114.5(4) . . ?
C4 C5 Ru1 66.7(3) . . ?
Ge1 C5 Ru1 87.19(18) . . ?
C4 C5 H50 122.4 . . ?
Ge1 C5 H50 122.4 . . ?
Ru1 C5 H50 122.4 . . ?
C10 Ge2 C6 100.7(2) . . ?
C10 Ge2 Ru1 124.44(16) . . ?
C6 Ge2 Ru1 134.84(14) . . ?
C10 Ge2 Ge1 102.21(14) . . ?
C6 Ge2 Ge1 100.55(15) . . ?
Ru1 Ge2 Ge1 70.844(19) . . ?
C10 Ge2 Ru2 49.88(14) . . ?
C6 Ge2 Ru2 97.42(14) . . ?
Ru1 Ge2 Ru2 109.80(2) . . ?
Ge1 Ge2 Ru2 53.639(16) . . ?
C7 C6 C15 125.1(5) . . ?
C7 C6 Ge2 111.2(4) . . ?
C15 C6 Ge2 123.2(4) . . ?
C6 C7 C8 125.8(5) . . ?
C6 C7 H7 117.1 . . ?
C8 C7 H7 117.1 . . ?
C9 C8 C7 118.7(5) . . ?
C9 C8 Ru2 66.1(3) . . ?
C7 C8 Ru2 124.4(3) . . ?
C9 C8 H53 113.2 . . ?
C7 C8 H53 113.2 . . ?
Ru2 C8 H53 113.2 . . ?
C10 C9 C8 118.9(4) . . ?
C10 C9 Ru2 74.7(3) . . ?
C8 C9 Ru2 74.9(3) . . ?
C10 C9 H51 120.6 . . ?
C8 C9 H51 120.6 . . ?
Ru2 C9 H51 121.0 . . ?
C9 C10 Ge2 115.5(4) . . ?
C9 C10 Ru2 67.4(3) . . ?
Ge2 C10 Ru2 87.79(19) . . ?
C9 C10 H10 121.8 . . ?
Ge2 C10 H10 121.8 . . ?
Ru2 C10 H10 121.8 . . ?
C4 Ru1 C21 92.37(19) . . ?
C4 Ru1 C20 95.0(2) . . ?
C21 Ru1 C20 38.29(19) . . ?
C4 Ru1 C19 128.6(2) . . ?
C21 Ru1 C19 62.95(18) . . ?
C20 Ru1 C19 37.50(19) . . ?
C4 Ru1 C5 37.61(18) . . ?
C21 Ru1 C5 117.12(19) . . ?
C20 Ru1 C5 97.42(19) . . ?
C19 Ru1 C5 112.90(19) . . ?
C4 Ru1 C22 123.03(19) . . ?
C21 Ru1 C22 37.40(19) . . ?
C20 Ru1 C22 63.2(2) . . ?
C19 Ru1 C22 62.66(19) . . ?
C5 Ru1 C22 154.43(19) . . ?
C4 Ru1 C3 38.6(2) . . ?
C21 Ru1 C3 97.50(18) . . ?
C20 Ru1 C3 121.7(2) . . ?
C19 Ru1 C3 158.78(19) . . ?
C5 Ru1 C3 67.09(18) . . ?
C22 Ru1 C3 107.51(18) . . ?
C4 Ru1 C23 153.7(2) . . ?
C21 Ru1 C23 61.79(18) . . ?
C20 Ru1 C23 62.2(2) . . ?
C19 Ru1 C23 37.2(2) . . ?
C5 Ru1 C23 149.5(2) . . ?
C22 Ru1 C23 36.80(19) . . ?
C3 Ru1 C23 142.22(19) . . ?
C4 Ru1 Ge2 120.23(14) . . ?
C21 Ru1 Ge2 146.17(14) . . ?
C20 Ru1 Ge2 135.23(14) . . ?
C19 Ru1 Ge2 98.31(14) . . ?
C5 Ru1 Ge2 95.76(13) . . ?
C22 Ru1 Ge2 109.73(14) . . ?
C3 Ru1 Ge2 102.82(14) . . ?
C23 Ru1 Ge2 86.04(13) . . ?
C4 Ru1 Ge1 66.84(14) . . ?
C21 Ru1 Ge1 158.41(14) . . ?
C20 Ru1 Ge1 133.62(14) . . ?
C19 Ru1 Ge1 125.11(13) . . ?
C5 Ru1 Ge1 42.18(13) . . ?
C22 Ru1 Ge1 162.20(14) . . ?
C3 Ru1 Ge1 70.26(12) . . ?
C23 Ru1 Ge1 138.07(13) . . ?
Ge2 Ru1 Ge1 55.421(17) . . ?
C40 Ru2 C41 39.5(10) . . ?
C40 Ru2 C9 114.4(11) . . ?
C41 Ru2 C9 90.4(14) . . ?
C40 Ru2 C43 66.3(11) . . ?
C41 Ru2 C43 66.1(14) . . ?
C9 Ru2 C43 141.9(13) . . ?
C40 Ru2 C39 39.4(7) . . ?
C41 Ru2 C39 65.4(14) . . ?
C9 Ru2 C39 153.4(12) . . ?
C43 Ru2 C39 38.6(8) . . ?
C9 Ru2 C30 95.3(3) . . ?
C40 Ru2 C10 147.3(14) . . ?
C41 Ru2 C10 110.9(14) . . ?
C9 Ru2 C10 37.8(2) . . ?
C43 Ru2 C10 121.6(13) . . ?
C39 Ru2 C10 160.2(10) . . ?
C30 Ru2 C10 120.3(3) . . ?
C40 Ru2 C42 64.1(14) . . ?
C41 Ru2 C42 38.6(10) . . ?
C9 Ru2 C42 105.8(13) . . ?
C43 Ru2 C42 37.7(8) . . ?
C39 Ru2 C42 62.5(12) . . ?
C10 Ru2 C42 101.8(12) . . ?
C9 Ru2 C31 94.0(3) . . ?
C30 Ru2 C31 37.4(4) . . ?
C10 Ru2 C31 97.7(3) . . ?
C40 Ru2 C8 100.7(9) . . ?
C41 Ru2 C8 102.1(17) . . ?
C9 Ru2 C8 39.1(2) . . ?
C43 Ru2 C8 166.7(9) . . ?
C39 Ru2 C8 132.0(11) . . ?
C30 Ru2 C8 99.7(4) . . ?
C10 Ru2 C8 67.4(2) . . ?
C42 Ru2 C8 135.0(15) . . ?
C31 Ru2 C8 120.6(3) . . ?
C9 Ru2 C29 128.0(3) . . ?
C30 Ru2 C29 37.7(3) . . ?
C10 Ru2 C29 157.9(3) . . ?
C31 Ru2 C29 62.8(3) . . ?
C8 Ru2 C29 112.0(3) . . ?
C9 Ru2 C32 125.4(3) . . ?
C30 Ru2 C32 61.5(4) . . ?
C10 Ru2 C32 109.8(3) . . ?
C31 Ru2 C32 37.0(3) . . ?
C8 Ru2 C32 157.5(3) . . ?
C29 Ru2 C32 61.6(3) . . ?
C13 C11 C1 113.0(5) . . ?
C13 C11 C14 108.7(5) . . ?
C1 C11 C14 112.4(4) . . ?
C13 C11 C12 109.2(6) . . ?
C1 C11 C12 107.3(5) . . ?
C14 C11 C12 105.9(5) . . ?
C11 C12 H12 109.5 . . ?
C11 C12 H12A 109.5 . . ?
H12 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
H12 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C11 C13 H13 109.5 . . ?
C11 C13 H13A 109.5 . . ?
H13 C13 H13A 109.5 . . ?
C11 C13 H13B 109.5 . . ?
H13 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C11 C14 H14 109.5 . . ?
C11 C14 H14A 109.5 . . ?
H14 C14 H14A 109.5 . . ?
C11 C14 H14B 109.5 . . ?
H14 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C18 C15 C17 108.6(6) . . ?
C18 C15 C6 112.3(5) . . ?
C17 C15 C6 107.8(5) . . ?
C18 C15 C16 108.3(5) . . ?
C17 C15 C16 108.7(6) . . ?
C6 C15 C16 111.1(4) . . ?
C15 C16 H16 109.5 . . ?
C15 C16 H16A 109.5 . . ?
H16 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C17 H17 109.5 . . ?
C15 C17 H17A 109.5 . . ?
H17 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C18 H18 109.5 . . ?
C15 C18 H18A 109.5 . . ?
H18 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
H18 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C20 C19 C23 107.1(4) . . ?
C20 C19 C24 126.3(5) . . ?
C23 C19 C24 126.0(5) . . ?
C20 C19 Ru1 69.6(3) . . ?
C23 C19 Ru1 72.2(3) . . ?
C24 C19 Ru1 129.8(4) . . ?
C19 C20 C21 107.7(5) . . ?
C19 C20 C25 125.9(5) . . ?
C21 C20 C25 126.2(5) . . ?
C19 C20 Ru1 72.9(3) . . ?
C21 C20 Ru1 70.8(3) . . ?
C25 C20 Ru1 124.8(4) . . ?
C22 C21 C20 108.6(4) . . ?
C22 C21 C26 125.8(5) . . ?
C20 C21 C26 125.4(5) . . ?
C22 C21 Ru1 73.0(3) . . ?
C20 C21 Ru1 70.9(3) . . ?
C26 C21 Ru1 125.9(3) . . ?
C23 C22 C21 107.1(5) . . ?
C23 C22 C27 126.9(5) . . ?
C21 C22 C27 125.6(5) . . ?
C23 C22 Ru1 72.3(3) . . ?
C21 C22 Ru1 69.6(3) . . ?
C27 C22 Ru1 128.5(4) . . ?
C22 C23 C19 109.4(5) . . ?
C22 C23 C28 125.7(5) . . ?
C19 C23 C28 124.2(5) . . ?
C22 C23 Ru1 70.9(3) . . ?
C19 C23 Ru1 70.6(3) . . ?
C28 C23 Ru1 132.7(4) . . ?
C19 C24 H24 109.5 . . ?
C19 C24 H24A 109.5 . . ?
H24 C24 H24A 109.5 . . ?
C19 C24 H24B 109.5 . . ?
H24 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C20 C25 H25 109.5 . . ?
C20 C25 H25A 109.5 . . ?
H25 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
H25 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C21 C26 H26 109.5 . . ?
C21 C26 H26A 109.5 . . ?
H26 C26 H26A 109.5 . . ?
C21 C26 H26B 109.5 . . ?
H26 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C22 C27 H27 109.5 . . ?
C22 C27 H27A 109.5 . . ?
H27 C27 H27A 109.5 . . ?
C22 C27 H27B 109.5 . . ?
H27 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C23 C28 H28 109.5 . . ?
C23 C28 H28A 109.5 . . ?
H28 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
H28 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C33 C29 C30 106.4(7) . . ?
C33 C29 C34 125.1(9) . . ?
C30 C29 C34 128.3(9) . . ?
C33 C29 Ru2 72.7(4) . . ?
C30 C29 Ru2 69.7(5) . . ?
C34 C29 Ru2 126.6(6) . . ?
C31 C30 C29 109.0(8) . . ?
C31 C30 C35 126.5(10) . . ?
C29 C30 C35 124.4(10) . . ?
C31 C30 Ru2 71.7(6) . . ?
C29 C30 Ru2 72.6(6) . . ?
C35 C30 Ru2 123.2(9) . . ?
C30 C31 C32 107.4(7) . . ?
C30 C31 C36 125.4(10) . . ?
C32 C31 C36 127.0(10) . . ?
C30 C31 Ru2 70.9(6) . . ?
C32 C31 Ru2 73.7(5) . . ?
C36 C31 Ru2 124.1(6) . . ?
C33 C32 C31 108.6(7) . . ?
C33 C32 C37 127.1(9) . . ?
C31 C32 C37 124.2(10) . . ?
C33 C32 Ru2 72.0(4) . . ?
C31 C32 Ru2 69.4(5) . . ?
C37 C32 Ru2 127.8(5) . . ?
C32 C33 C29 108.5(7) . . ?
C32 C33 C38 123.4(9) . . ?
C29 C33 C38 127.1(9) . . ?
C32 C33 Ru2 71.7(4) . . ?
C29 C33 Ru2 70.2(4) . . ?
C38 C33 Ru2 132.6(5) . . ?
C29 C34 H34 109.5 . . ?
C29 C34 H34A 109.5 . . ?
H34 C34 H34A 109.5 . . ?
C29 C34 H34B 109.5 . . ?
H34 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C30 C35 H35 109.5 . . ?
C30 C35 H35A 109.5 . . ?
H35 C35 H35A 109.5 . . ?
C30 C35 H35B 109.5 . . ?
H35 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C31 C36 H36 109.5 . . ?
C31 C36 H36A 109.5 . . ?
H36 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C32 C37 H37 109.5 . . ?
C32 C37 H37A 109.5 . . ?
H37 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C33 C38 H38 109.5 . . ?
C33 C38 H38A 109.5 . . ?
H38 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C43 C39 C40 106.9(19) . . ?
C43 C39 C44 127(4) . . ?
C40 C39 C44 126(4) . . ?
C43 C39 Ru2 68.5(19) . . ?
C40 C39 Ru2 66(2) . . ?
C44 C39 Ru2 131(2) . . ?
C41 C40 C39 108(2) . . ?
C41 C40 C45 126(5) . . ?
C39 C40 C45 125(4) . . ?
C41 C40 Ru2 70(3) . . ?
C39 C40 Ru2 74(2) . . ?
C45 C40 Ru2 125(3) . . ?
C40 C41 C42 107(2) . . ?
C40 C41 C46 130(5) . . ?
C42 C41 C46 122(5) . . ?
C40 C41 Ru2 70(3) . . ?
C42 C41 Ru2 75(3) . . ?
C46 C41 Ru2 129(4) . . ?
C43 C42 C47 125(5) . . ?
C43 C42 C41 109(2) . . ?
C47 C42 C41 124(5) . . ?
C43 C42 Ru2 68(2) . . ?
C47 C42 Ru2 122(4) . . ?
C41 C42 Ru2 66(3) . . ?
C42 C43 C39 107(2) . . ?
C42 C43 C48 119(4) . . ?
C39 C43 C48 130(4) . . ?
C42 C43 Ru2 74(3) . . ?
C39 C43 Ru2 72.9(19) . . ?
C48 C43 Ru2 135(3) . . ?
C39 C44 H44 109.5 . . ?
C39 C44 H44A 109.5 . . ?
H44 C44 H44A 109.5 . . ?
C39 C44 H44B 109.5 . . ?
H44 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C40 C45 H45 109.5 . . ?
C40 C45 H45A 109.5 . . ?
H45 C45 H45A 109.5 . . ?
C40 C45 H45B 109.5 . . ?
H45 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C41 C46 H46 109.5 . . ?
C41 C46 H46A 109.5 . . ?
H46 C46 H46A 109.5 . . ?
C41 C46 H46B 109.5 . . ?
H46 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C42 C47 H47 109.5 . . ?
C42 C47 H47A 109.5 . . ?
H47 C47 H47A 109.5 . . ?
C42 C47 H47B 109.5 . . ?
H47 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C43 C48 H48 109.5 . . ?
C43 C48 H48A 109.5 . . ?
H48 C48 H48A 109.5 . . ?
C43 C48 H48B 109.5 . . ?
H48 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C11 C1 C2 C3 -164.8(5) . . . . ?
Ge1 C1 C2 C3 7.6(7) . . . . ?
C1 C2 C3 C4 41.4(8) . . . . ?
C1 C2 C3 Ru1 -37.4(7) . . . . ?
C2 C3 C4 C5 -52.7(6) . . . . ?
Ru1 C3 C4 C5 63.5(4) . . . . ?
C2 C3 C4 Ru1 -116.2(4) . . . . ?
C3 C4 C5 Ge1 11.8(6) . . . . ?
Ru1 C4 C5 Ge1 75.3(3) . . . . ?
C3 C4 C5 Ru1 -63.5(4) . . . . ?
C15 C6 C7 C8 -164.3(5) . . . . ?
Ge2 C6 C7 C8 8.2(7) . . . . ?
C6 C7 C8 C9 42.6(7) . . . . ?
C6 C7 C8 Ru2 -36.7(8) . . . . ?
C7 C8 C9 C10 -54.9(6) . . . . ?
Ru2 C8 C9 C10 62.6(4) . . . . ?
C7 C8 C9 Ru2 -117.5(4) . . . . ?
C8 C9 C10 Ge2 13.2(6) . . . . ?
Ru2 C9 C10 Ge2 75.8(3) . . . . ?
C8 C9 C10 Ru2 -62.6(4) . . . . ?
C2 C1 C11 C13 -12.8(8) . . . . ?
Ge1 C1 C11 C13 175.7(5) . . . . ?
C2 C1 C11 C14 -136.3(6) . . . . ?
Ge1 C1 C11 C14 52.2(6) . . . . ?
C2 C1 C11 C12 107.6(6) . . . . ?
Ge1 C1 C11 C12 -63.9(6) . . . . ?
C7 C6 C15 C18 -16.4(8) . . . . ?
Ge2 C6 C15 C18 172.0(4) . . . . ?
C7 C6 C15 C17 103.2(7) . . . . ?
Ge2 C6 C15 C17 -68.4(6) . . . . ?
C7 C6 C15 C16 -137.9(6) . . . . ?
Ge2 C6 C15 C16 50.5(6) . . . . ?
C23 C19 C20 C21 -0.2(5) . . . . ?
C24 C19 C20 C21 -172.3(5) . . . . ?
Ru1 C19 C20 C21 62.6(3) . . . . ?
C23 C19 C20 C25 176.2(5) . . . . ?
C24 C19 C20 C25 4.2(8) . . . . ?
Ru1 C19 C20 C25 -120.9(5) . . . . ?
C23 C19 C20 Ru1 -62.9(3) . . . . ?
C24 C19 C20 Ru1 125.1(5) . . . . ?
C19 C20 C21 C22 -0.2(5) . . . . ?
C25 C20 C21 C22 -176.7(5) . . . . ?
Ru1 C20 C21 C22 63.7(3) . . . . ?
C19 C20 C21 C26 175.1(5) . . . . ?
C25 C20 C21 C26 -1.4(8) . . . . ?
Ru1 C20 C21 C26 -121.0(5) . . . . ?
C19 C20 C21 Ru1 -64.0(3) . . . . ?
C25 C20 C21 Ru1 119.6(5) . . . . ?
C20 C21 C22 C23 0.6(5) . . . . ?
C26 C21 C22 C23 -174.7(5) . . . . ?
Ru1 C21 C22 C23 62.9(3) . . . . ?
C20 C21 C22 C27 174.2(5) . . . . ?
C26 C21 C22 C27 -1.1(8) . . . . ?
Ru1 C21 C22 C27 -123.4(5) . . . . ?
C20 C21 C22 Ru1 -62.3(3) . . . . ?
C26 C21 C22 Ru1 122.4(5) . . . . ?
C21 C22 C23 C19 -0.7(5) . . . . ?
C27 C22 C23 C19 -174.2(5) . . . . ?
Ru1 C22 C23 C19 60.4(3) . . . . ?
C21 C22 C23 C28 169.3(5) . . . . ?
C27 C22 C23 C28 -4.2(8) . . . . ?
Ru1 C22 C23 C28 -129.5(5) . . . . ?
C21 C22 C23 Ru1 -61.2(3) . . . . ?
C27 C22 C23 Ru1 125.3(5) . . . . ?
C20 C19 C23 C22 0.6(5) . . . . ?
C24 C19 C23 C22 172.7(5) . . . . ?
Ru1 C19 C23 C22 -60.6(3) . . . . ?
C20 C19 C23 C28 -169.7(5) . . . . ?
C24 C19 C23 C28 2.4(8) . . . . ?
Ru1 C19 C23 C28 129.1(5) . . . . ?
C20 C19 C23 Ru1 61.2(3) . . . . ?
C24 C19 C23 Ru1 -126.7(5) . . . . ?
C33 C29 C30 C31 1.1(12) . . . . ?
C34 C29 C30 C31 175.8(9) . . . . ?
Ru2 C29 C30 C31 -62.9(8) . . . . ?
C33 C29 C30 C35 -177.3(11) . . . . ?
C34 C29 C30 C35 -2.5(18) . . . . ?
Ru2 C29 C30 C35 118.7(13) . . . . ?
C33 C29 C30 Ru2 64.0(6) . . . . ?
C34 C29 C30 Ru2 -121.2(9) . . . . ?
C29 C30 C31 C32 -1.6(13) . . . . ?
C35 C30 C31 C32 176.7(11) . . . . ?
Ru2 C30 C31 C32 -65.1(6) . . . . ?
C29 C30 C31 C36 -177.8(9) . . . . ?
C35 C30 C31 C36 0.5(19) . . . . ?
Ru2 C30 C31 C36 118.7(9) . . . . ?
C29 C30 C31 Ru2 63.5(8) . . . . ?
C35 C30 C31 Ru2 -118.2(13) . . . . ?
C30 C31 C32 C33 1.6(11) . . . . ?
C36 C31 C32 C33 177.7(8) . . . . ?
Ru2 C31 C32 C33 -61.7(5) . . . . ?
C30 C31 C32 C37 -174.3(8) . . . . ?
C36 C31 C32 C37 1.8(14) . . . . ?
Ru2 C31 C32 C37 122.5(7) . . . . ?
C30 C31 C32 Ru2 63.2(8) . . . . ?
C36 C31 C32 Ru2 -120.7(9) . . . . ?
C31 C32 C33 C29 -0.9(8) . . . . ?
C37 C32 C33 C29 174.8(7) . . . . ?
Ru2 C32 C33 C29 -60.9(5) . . . . ?
C31 C32 C33 C38 -170.5(7) . . . . ?
C37 C32 C33 C38 5.3(11) . . . . ?
Ru2 C32 C33 C38 129.5(7) . . . . ?
C31 C32 C33 Ru2 60.0(5) . . . . ?
C37 C32 C33 Ru2 -124.3(7) . . . . ?
C30 C29 C33 C32 -0.1(9) . . . . ?
C34 C29 C33 C32 -175.1(8) . . . . ?
Ru2 C29 C33 C32 61.9(5) . . . . ?
C30 C29 C33 C38 169.0(9) . . . . ?
C34 C29 C33 C38 -6.0(12) . . . . ?
Ru2 C29 C33 C38 -129.1(7) . . . . ?
C30 C29 C33 Ru2 -62.0(7) . . . . ?
C34 C29 C33 Ru2 123.1(9) . . . . ?
C43 C39 C40 C41 -6(6) . . . . ?
C44 C39 C40 C41 173(5) . . . . ?
Ru2 C39 C40 C41 -63(4) . . . . ?
C43 C39 C40 C45 179(4) . . . . ?
C44 C39 C40 C45 -2(7) . . . . ?
Ru2 C39 C40 C45 123(5) . . . . ?
C43 C39 C40 Ru2 57(3) . . . . ?
C44 C39 C40 Ru2 -124(4) . . . . ?
C39 C40 C41 C42 -2(7) . . . . ?
C45 C40 C41 C42 173(5) . . . . ?
Ru2 C40 C41 C42 -67(5) . . . . ?
C39 C40 C41 C46 -170(6) . . . . ?
C45 C40 C41 C46 4(11) . . . . ?
Ru2 C40 C41 C46 124(8) . . . . ?
C39 C40 C41 Ru2 65(3) . . . . ?
C45 C40 C41 Ru2 -120(5) . . . . ?
C40 C41 C42 C43 9(8) . . . . ?
C46 C41 C42 C43 179(5) . . . . ?
Ru2 C41 C42 C43 -54(4) . . . . ?
C40 C41 C42 C47 177(5) . . . . ?
C46 C41 C42 C47 -14(10) . . . . ?
Ru2 C41 C42 C47 113(5) . . . . ?
C40 C41 C42 Ru2 63(5) . . . . ?
C46 C41 C42 Ru2 -127(6) . . . . ?
C47 C42 C43 C39 180(4) . . . . ?
C41 C42 C43 C39 -13(6) . . . . ?
Ru2 C42 C43 C39 -66(3) . . . . ?
C47 C42 C43 C48 19(8) . . . . ?
C41 C42 C43 C48 -174(5) . . . . ?
Ru2 C42 C43 C48 133(4) . . . . ?
C47 C42 C43 Ru2 -114(5) . . . . ?
C41 C42 C43 Ru2 53(5) . . . . ?
C40 C39 C43 C42 11(5) . . . . ?
C44 C39 C43 C42 -167(4) . . . . ?
Ru2 C39 C43 C42 67(3) . . . . ?
C40 C39 C43 C48 170(4) . . . . ?
C44 C39 C43 C48 -9(6) . . . . ?
Ru2 C39 C43 C48 -135(4) . . . . ?
C40 C39 C43 Ru2 -55(3) . . . . ?
C44 C39 C43 Ru2 126(4) . . . . ?

_refine_diff_density_max         1.502
_refine_diff_density_min         -1.233
_refine_diff_density_rms         0.117




_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: hexane'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_GeRu_trimer
_database_code_depnum_ccdc_archive 'CCDC 1827997'
_audit_update_record             
;
2018-03-07 deposited with the CCDC.
2018-05-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_chemical_name_systematic        GeRu_trimer
_chemical_name_common            GeRu_trimer
_chemical_melting_point          420
_chemical_formula_moiety         'C57 H84 Ge3 Ru3, 0.5(C6 H6)'
_chemical_formula_sum            'C60 H87 Ge3 Ru3'
_chemical_formula_weight         1329.27

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.3082(2)
_cell_length_b                   13.0253(2)
_cell_length_c                   19.5207(3)
_cell_angle_alpha                74.599(2)
_cell_angle_beta                 89.9930(10)
_cell_angle_gamma                71.829(2)
_cell_volume                     2854.97(9)
_cell_formula_units_Z            2
_cell_measurement_temperature    103(2)
_cell_measurement_reflns_used    28419
_cell_measurement_theta_min      2.0770
_cell_measurement_theta_max      30.7470

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.546
_exptl_crystal_F_000             1350
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.030
_exptl_absorpt_coefficient_mu    2.368
_shelx_estimated_absorpt_T_min   0.689
_shelx_estimated_absorpt_T_max   0.932
_exptl_absorpt_correction_T_min  0.69079
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_diffrn_ambient_temperature      103(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            30484
_diffrn_reflns_av_unetI/netI     0.0153
_diffrn_reflns_av_R_equivalents  0.0168
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.271
_diffrn_reflns_theta_max         25.246
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measured_fraction_theta_full 0.973
_diffrn_reflns_Laue_measured_fraction_max 0.973
_diffrn_reflns_Laue_measured_fraction_full 0.973
_diffrn_reflns_point_group_measured_fraction_max 0.973
_diffrn_reflns_point_group_measured_fraction_full 0.973
_reflns_number_total             10073
_reflns_number_gt                9402
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrystalClear (Rigaku, 1999)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015a)'
_computing_structure_refinement  'SHELXL2016 (Sheldrick, 2015b)'
_computing_molecular_graphics    
;
Yadokari-XG (Wakita, 2001; Kabuto et al., 2009)
Mercury (Macrae et al., 2008)
Crystal Maker (Palmer, 2007)
;
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0366P)²+7.8791P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10073
_refine_ls_number_parameters     619
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0325
_refine_ls_R_factor_gt           0.0300
_refine_ls_wR_factor_ref         0.0809
_refine_ls_wR_factor_gt          0.0797
_refine_ls_goodness_of_fit_ref   1.113
_refine_ls_restrained_S_all      1.113
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.60914(3) 0.83103(3) 0.76428(2) 0.01478(9) Uani 1 1 d . . . . .
C1 C 0.7250(3) 0.8876(3) 0.78995(17) 0.0173(7) Uani 1 1 d . . . . .
C2 C 0.7011(3) 1.0040(3) 0.77092(19) 0.0207(7) Uani 1 1 d . . . . .
H1 H 0.761720 1.027939 0.783682 0.025 Uiso 1 1 calc R U . . .
C3 C 0.6026(3) 1.0910(3) 0.7362(2) 0.0238(8) Uani 1 1 d . . . . .
H2 H 0.602644 1.166243 0.728068 0.029 Uiso 1 1 calc R U . . .
C4 C 0.5039(3) 1.0742(3) 0.71261(19) 0.0219(7) Uani 1 1 d . . . . .
H3 H 0.440962 1.138740 0.689538 0.026 Uiso 1 1 calc R U . . .
C5 C 0.4921(3) 0.9693(3) 0.72079(18) 0.0196(7) Uani 1 1 d . . . . .
H4 H 0.421167 0.966405 0.703615 0.024 Uiso 1 1 calc R U . . .
C6 C 0.8442(3) 0.8170(3) 0.83010(18) 0.0190(7) Uani 1 1 d . . . . .
C7 C 0.8603(3) 0.6903(3) 0.85350(19) 0.0211(7) Uani 1 1 d . . . . .
H5 H 0.803970 0.676071 0.887073 0.032 Uiso 1 1 calc R U . . .
H6 H 0.938022 0.648549 0.876727 0.032 Uiso 1 1 calc R U . . .
H7 H 0.849246 0.665434 0.811588 0.032 Uiso 1 1 calc R U . . .
C8 C 0.9394(3) 0.8346(3) 0.7817(2) 0.0259(8) Uani 1 1 d . . . . .
H8 H 0.929799 0.812690 0.738349 0.039 Uiso 1 1 calc R U . . .
H9 H 1.014591 0.788263 0.807163 0.039 Uiso 1 1 calc R U . . .
H10 H 0.934401 0.914077 0.768717 0.039 Uiso 1 1 calc R U . . .
C9 C 0.8604(4) 0.8508(3) 0.8983(2) 0.0260(8) Uani 1 1 d . . . . .
H11 H 0.849646 0.931506 0.885841 0.039 Uiso 1 1 calc R U . . .
H12 H 0.937923 0.808255 0.921502 0.039 Uiso 1 1 calc R U . . .
H13 H 0.803755 0.834002 0.930968 0.039 Uiso 1 1 calc R U . . .
Ru1 Ru 0.55523(2) 0.65975(2) 0.79787(2) 0.01211(7) Uani 1 1 d . . . . .
C10 C 0.5398(3) 0.6858(3) 0.90767(17) 0.0172(7) Uani 1 1 d . . . . .
C11 C 0.4291(3) 0.7355(3) 0.86728(18) 0.0187(7) Uani 1 1 d . . . . .
C12 C 0.3958(3) 0.6469(3) 0.85239(18) 0.0186(7) Uani 1 1 d . . . . .
C13 C 0.4865(3) 0.5421(3) 0.88175(17) 0.0157(7) Uani 1 1 d . . . . .
C14 C 0.5760(3) 0.5676(3) 0.91554(17) 0.0161(7) Uani 1 1 d . . . . .
C15 C 0.5929(3) 0.7476(3) 0.94614(19) 0.0218(7) Uani 1 1 d . . . . .
H14 H 0.544865 0.768178 0.983559 0.033 Uiso 1 1 calc R U . . .
H15 H 0.598440 0.815816 0.912097 0.033 Uiso 1 1 calc R U . . .
H16 H 0.669837 0.698731 0.967691 0.033 Uiso 1 1 calc R U . . .
C16 C 0.3508(3) 0.8538(3) 0.8585(2) 0.0266(8) Uani 1 1 d . . . . .
H17 H 0.294111 0.875908 0.817582 0.040 Uiso 1 1 calc R U . . .
H18 H 0.396164 0.905154 0.850384 0.040 Uiso 1 1 calc R U . . .
H19 H 0.311209 0.857368 0.901772 0.040 Uiso 1 1 calc R U . . .
C17 C 0.2764(3) 0.6599(3) 0.8259(2) 0.0250(8) Uani 1 1 d . . . . .
H20 H 0.222718 0.683420 0.860180 0.038 Uiso 1 1 calc R U . . .
H21 H 0.273965 0.587821 0.820722 0.038 Uiso 1 1 calc R U . . .
H22 H 0.254621 0.716891 0.779597 0.038 Uiso 1 1 calc R U . . .
C18 C 0.4774(3) 0.4262(3) 0.89071(19) 0.0205(7) Uani 1 1 d . . . . .
H23 H 0.498915 0.402766 0.847538 0.031 Uiso 1 1 calc R U . . .
H24 H 0.398213 0.428245 0.898654 0.031 Uiso 1 1 calc R U . . .
H25 H 0.529094 0.372633 0.931753 0.031 Uiso 1 1 calc R U . . .
C19 C 0.6785(3) 0.4818(3) 0.96335(18) 0.0207(7) Uani 1 1 d . . . . .
H26 H 0.726341 0.520374 0.979062 0.031 Uiso 1 1 calc R U . . .
H27 H 0.723520 0.431118 0.936957 0.031 Uiso 1 1 calc R U . . .
H28 H 0.652138 0.438113 1.005048 0.031 Uiso 1 1 calc R U . . .
Ge2 Ge 0.70523(3) 0.51336(3) 0.76657(2) 0.01287(8) Uani 1 1 d . . . . .
C20 C 0.8089(3) 0.4695(3) 0.69577(17) 0.0153(7) Uani 1 1 d . . . . .
C21 C 0.8400(3) 0.3595(3) 0.68669(18) 0.0182(7) Uani 1 1 d . . . . .
H29 H 0.882038 0.348505 0.646962 0.022 Uiso 1 1 calc R U . . .
C22 C 0.8157(3) 0.2641(3) 0.72995(19) 0.0190(7) Uani 1 1 d . . . . .
H30 H 0.836702 0.197222 0.715089 0.023 Uiso 1 1 calc R U . . .
C23 C 0.7620(3) 0.2637(3) 0.79388(19) 0.0183(7) Uani 1 1 d . . . . .
H31 H 0.751846 0.195781 0.821348 0.022 Uiso 1 1 calc R U . . .
C24 C 0.7230(3) 0.3599(3) 0.81843(18) 0.0162(7) Uani 1 1 d . . . . .
H32 H 0.702995 0.347915 0.866239 0.019 Uiso 1 1 calc R U . . .
C25 C 0.8480(3) 0.5544(3) 0.63762(18) 0.0181(7) Uani 1 1 d . . . . .
C26 C 0.8354(4) 0.6629(3) 0.6584(2) 0.0269(8) Uani 1 1 d . . . . .
H33 H 0.853096 0.717473 0.618552 0.040 Uiso 1 1 calc R U . . .
H34 H 0.888656 0.645981 0.700284 0.040 Uiso 1 1 calc R U . . .
H35 H 0.756495 0.694566 0.669663 0.040 Uiso 1 1 calc R U . . .
C27 C 0.7693(3) 0.5841(3) 0.56878(19) 0.0262(8) Uani 1 1 d . . . . .
H36 H 0.689063 0.614552 0.578092 0.039 Uiso 1 1 calc R U . . .
H37 H 0.779960 0.516217 0.553323 0.039 Uiso 1 1 calc R U . . .
H38 H 0.789074 0.640486 0.531232 0.039 Uiso 1 1 calc R U . . .
C28 C 0.9736(3) 0.5075(3) 0.6215(2) 0.0277(8) Uani 1 1 d . . . . .
H39 H 0.983469 0.440667 0.604966 0.042 Uiso 1 1 calc R U . . .
H40 H 1.024646 0.487162 0.664914 0.042 Uiso 1 1 calc R U . . .
H41 H 0.992564 0.564926 0.584324 0.042 Uiso 1 1 calc R U . . .
Ru2 Ru 0.91030(2) 0.32191(2) 0.79903(2) 0.01513(7) Uani 1 1 d . . . . .
C29 C 1.0090(3) 0.3222(3) 0.89345(19) 0.0203(7) Uani 1 1 d . . . . .
C30 C 0.9937(3) 0.2139(3) 0.90211(19) 0.0216(7) Uani 1 1 d . . . . .
C31 C 1.0498(3) 0.1685(3) 0.8474(2) 0.0255(8) Uani 1 1 d . . . . .
C32 C 1.0996(3) 0.2469(3) 0.8046(2) 0.0258(8) Uani 1 1 d . . . . .
C33 C 1.0734(3) 0.3428(3) 0.8332(2) 0.0250(8) Uani 1 1 d . . . . .
C34 C 0.9805(3) 0.3919(3) 0.94557(19) 0.0231(8) Uani 1 1 d . . . . .
H42 H 1.051134 0.383084 0.973022 0.035 Uiso 1 1 calc R U . . .
H43 H 0.927522 0.366720 0.978131 0.035 Uiso 1 1 calc R U . . .
H44 H 0.944433 0.471328 0.919409 0.035 Uiso 1 1 calc R U . . .
C35 C 0.9334(4) 0.1570(3) 0.9598(2) 0.0272(8) Uani 1 1 d . . . . .
H45 H 0.898141 0.110777 0.941260 0.041 Uiso 1 1 calc R U . . .
H46 H 0.873812 0.214108 0.975168 0.041 Uiso 1 1 calc R U . . .
H47 H 0.989126 0.109036 1.000469 0.041 Uiso 1 1 calc R U . . .
C36 C 1.0598(4) 0.0543(3) 0.8391(2) 0.0336(9) Uani 1 1 d . . . . .
H48 H 1.076678 0.052658 0.790221 0.050 Uiso 1 1 calc R U . . .
H49 H 0.987366 0.039101 0.848809 0.050 Uiso 1 1 calc R U . . .
H50 H 1.121980 -0.003304 0.872757 0.050 Uiso 1 1 calc R U . . .
C37 C 1.1747(4) 0.2281(4) 0.7454(3) 0.0401(10) Uani 1 1 d . . . . .
H51 H 1.252485 0.180075 0.765704 0.060 Uiso 1 1 calc R U . . .
H52 H 1.177307 0.300681 0.715466 0.060 Uiso 1 1 calc R U . . .
H53 H 1.143244 0.191432 0.716278 0.060 Uiso 1 1 calc R U . . .
C38 C 1.1192(4) 0.4395(4) 0.8123(2) 0.0313(9) Uani 1 1 d . . . . .
H54 H 1.059236 0.508800 0.813954 0.047 Uiso 1 1 calc R U . . .
H55 H 1.143079 0.447531 0.763808 0.047 Uiso 1 1 calc R U . . .
H56 H 1.185356 0.425511 0.845514 0.047 Uiso 1 1 calc R U . . .
Ge3 Ge 0.49046(3) 0.70425(3) 0.67227(2) 0.01299(8) Uani 1 1 d . . . . .
C39 C 0.4404(3) 0.6322(3) 0.60712(18) 0.0156(7) Uani 1 1 d . . . . .
C40 C 0.4423(3) 0.6703(3) 0.53215(18) 0.0194(7) Uani 1 1 d . . . . .
H57 H 0.424870 0.625229 0.505490 0.023 Uiso 1 1 calc R U . . .
C41 C 0.4671(3) 0.7673(3) 0.49175(18) 0.0196(7) Uani 1 1 d . . . . .
H58 H 0.466886 0.780858 0.441464 0.024 Uiso 1 1 calc R U . . .
C42 C 0.4921(3) 0.8445(3) 0.52305(18) 0.0196(7) Uani 1 1 d . . . . .
H59 H 0.505108 0.908993 0.492592 0.024 Uiso 1 1 calc R U . . .
C43 C 0.4986(3) 0.8307(3) 0.59681(18) 0.0184(7) Uani 1 1 d . . . . .
H60 H 0.508349 0.891509 0.611439 0.022 Uiso 1 1 calc R U . . .
C44 C 0.4118(3) 0.5211(3) 0.63416(18) 0.0197(7) Uani 1 1 d . . . . .
C45 C 0.3588(4) 0.5145(3) 0.7055(2) 0.0291(9) Uani 1 1 d . . . . .
H61 H 0.349186 0.440527 0.724150 0.044 Uiso 1 1 calc R U . . .
H62 H 0.283749 0.573282 0.698487 0.044 Uiso 1 1 calc R U . . .
H63 H 0.409454 0.525617 0.739647 0.044 Uiso 1 1 calc R U . . .
C46 C 0.5252(3) 0.4239(3) 0.6453(2) 0.0266(8) Uani 1 1 d . . . . .
H64 H 0.575806 0.427456 0.682806 0.040 Uiso 1 1 calc R U . . .
H65 H 0.562559 0.430015 0.600761 0.040 Uiso 1 1 calc R U . . .
H66 H 0.509872 0.352083 0.659594 0.040 Uiso 1 1 calc R U . . .
C47 C 0.3289(3) 0.5042(3) 0.5818(2) 0.0264(8) Uani 1 1 d . . . . .
H67 H 0.300469 0.442959 0.606556 0.040 Uiso 1 1 calc R U . . .
H68 H 0.369714 0.485005 0.541488 0.040 Uiso 1 1 calc R U . . .
H69 H 0.264007 0.573738 0.564261 0.040 Uiso 1 1 calc R U . . .
Ru3 Ru 0.32739(2) 0.82371(2) 0.55669(2) 0.01641(8) Uani 1 1 d . . . . .
C48 C 0.1446(3) 0.8444(3) 0.5737(2) 0.0267(8) Uani 1 1 d . . . . .
C49 C 0.1768(3) 0.9267(3) 0.59733(19) 0.0192(7) Uani 1 1 d . . . . .
C50 C 0.2135(3) 0.9957(3) 0.5376(2) 0.0256(8) Uani 1 1 d . . . . .
C51 C 0.2013(4) 0.9568(4) 0.4766(2) 0.0407(12) Uani 1 1 d . . . . .
C52 C 0.1599(4) 0.8633(4) 0.4990(2) 0.0385(11) Uani 1 1 d . . . . .
C53 C 0.0896(4) 0.7632(4) 0.6175(3) 0.0457(12) Uani 1 1 d . . . . .
H70 H 0.005965 0.798136 0.611353 0.069 Uiso 1 1 calc R U . . .
H71 H 0.116615 0.743910 0.667975 0.069 Uiso 1 1 calc R U . . .
H72 H 0.110564 0.694716 0.601681 0.069 Uiso 1 1 calc R U . . .
C54 C 0.1611(3) 0.9479(3) 0.66918(19) 0.0247(8) Uani 1 1 d . . . . .
H73 H 0.087577 1.006830 0.667157 0.037 Uiso 1 1 calc R U . . .
H74 H 0.223788 0.972145 0.682600 0.037 Uiso 1 1 calc R U . . .
H75 H 0.161647 0.878502 0.704682 0.037 Uiso 1 1 calc R U . . .
C55 C 0.2460(4) 1.0971(3) 0.5393(3) 0.0415(11) Uani 1 1 d . . . . .
H76 H 0.176401 1.160442 0.537649 0.062 Uiso 1 1 calc R U . . .
H77 H 0.288354 1.117051 0.498068 0.062 Uiso 1 1 calc R U . . .
H78 H 0.294515 1.080007 0.583358 0.062 Uiso 1 1 calc R U . . .
C56 C 0.2267(5) 1.0077(5) 0.4018(2) 0.077(2) Uani 1 1 d . . . . .
H79 H 0.256153 0.948299 0.378112 0.115 Uiso 1 1 calc R U . . .
H80 H 0.284292 1.044705 0.404017 0.115 Uiso 1 1 calc R U . . .
H81 H 0.156097 1.063201 0.374901 0.115 Uiso 1 1 calc R U . . .
C57 C 0.1274(5) 0.7995(5) 0.4519(3) 0.068(2) Uani 1 1 d . . . . .
H82 H 0.138032 0.722092 0.480060 0.101 Uiso 1 1 calc R U . . .
H83 H 0.176429 0.798716 0.412320 0.101 Uiso 1 1 calc R U . . .
H84 H 0.046875 0.836679 0.432846 0.101 Uiso 1 1 calc R U . . .
C58 C 0.6128(7) 0.9665(7) 1.0253(5) 0.084(2) Uani 1 1 d . . . . .
H85 H 0.691143 0.942356 1.043169 0.101 Uiso 1 1 calc R U . . .
C59 C 0.5801(8) 1.0270(6) 0.9556(5) 0.081(2) Uani 1 1 d . . . . .
H86 H 0.635397 1.046054 0.925249 0.097 Uiso 1 1 calc R U . . .
C60 C 0.4688(8) 1.0599(6) 0.9297(4) 0.078(2) Uani 1 1 d . . . . .
H87 H 0.446245 1.100891 0.881022 0.093 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C5 1.900(3) . ?
Ge1 C1 1.918(3) . ?
Ge1 Ru1 2.4482(4) . ?
C1 C2 1.395(5) . ?
C1 C6 1.545(5) . ?
C2 C3 1.396(5) . ?
C2 H1 0.9500 . ?
C3 C4 1.398(5) . ?
C3 H2 0.9500 . ?
C4 C5 1.386(5) . ?
C4 H3 0.9500 . ?
C5 H4 0.9500 . ?
C6 C7 1.539(5) . ?
C6 C8 1.540(5) . ?
C6 C9 1.540(5) . ?
C7 H5 0.9800 . ?
C7 H6 0.9800 . ?
C7 H7 0.9800 . ?
C8 H8 0.9800 . ?
C8 H9 0.9800 . ?
C8 H10 0.9800 . ?
C9 H11 0.9800 . ?
C9 H12 0.9800 . ?
C9 H13 0.9800 . ?
Ru1 C11 2.230(3) . ?
Ru1 C10 2.256(3) . ?
Ru1 C12 2.263(3) . ?
Ru1 C14 2.264(3) . ?
Ru1 C13 2.285(3) . ?
Ru1 Ge2 2.4167(4) . ?
Ru1 Ge3 2.4374(4) . ?
C10 C14 1.428(5) . ?
C10 C11 1.441(5) . ?
C10 C15 1.512(5) . ?
C11 C12 1.435(5) . ?
C11 C16 1.505(5) . ?
C12 C13 1.439(5) . ?
C12 C17 1.501(5) . ?
C13 C14 1.450(5) . ?
C13 C18 1.512(5) . ?
C14 C19 1.510(5) . ?
C15 H14 0.9800 . ?
C15 H15 0.9800 . ?
C15 H16 0.9800 . ?
C16 H17 0.9800 . ?
C16 H18 0.9800 . ?
C16 H19 0.9800 . ?
C17 H20 0.9800 . ?
C17 H21 0.9800 . ?
C17 H22 0.9800 . ?
C18 H23 0.9800 . ?
C18 H24 0.9800 . ?
C18 H25 0.9800 . ?
C19 H26 0.9800 . ?
C19 H27 0.9800 . ?
C19 H28 0.9800 . ?
Ge2 C24 1.929(3) . ?
Ge2 C20 1.957(3) . ?
Ge2 Ru2 2.8682(4) . ?
C20 C21 1.423(5) . ?
C20 C25 1.552(4) . ?
C20 Ru2 2.401(3) . ?
C21 C22 1.422(5) . ?
C21 Ru2 2.228(3) . ?
C21 H29 0.9500 . ?
C22 C23 1.412(5) . ?
C22 Ru2 2.197(3) . ?
C22 H30 0.9500 . ?
C23 C24 1.405(5) . ?
C23 Ru2 2.196(3) . ?
C23 H31 0.9500 . ?
C24 Ru2 2.256(3) . ?
C24 H32 0.9500 . ?
C25 C26 1.534(5) . ?
C25 C28 1.541(5) . ?
C25 C27 1.544(5) . ?
C26 H33 0.9800 . ?
C26 H34 0.9800 . ?
C26 H35 0.9800 . ?
C27 H36 0.9800 . ?
C27 H37 0.9800 . ?
C27 H38 0.9800 . ?
C28 H39 0.9800 . ?
C28 H40 0.9800 . ?
C28 H41 0.9800 . ?
Ru2 C30 2.163(3) . ?
Ru2 C31 2.166(3) . ?
Ru2 C29 2.209(3) . ?
Ru2 C32 2.218(4) . ?
Ru2 C33 2.233(4) . ?
C29 C33 1.430(6) . ?
C29 C30 1.448(5) . ?
C29 C34 1.508(5) . ?
C30 C31 1.431(5) . ?
C30 C35 1.505(5) . ?
C31 C32 1.433(6) . ?
C31 C36 1.506(5) . ?
C32 C33 1.447(5) . ?
C32 C37 1.504(6) . ?
C33 C38 1.498(5) . ?
C34 H42 0.9800 . ?
C34 H43 0.9800 . ?
C34 H44 0.9800 . ?
C35 H45 0.9800 . ?
C35 H46 0.9800 . ?
C35 H47 0.9800 . ?
C36 H48 0.9800 . ?
C36 H49 0.9800 . ?
C36 H50 0.9800 . ?
C37 H51 0.9800 . ?
C37 H52 0.9800 . ?
C37 H53 0.9800 . ?
C38 H54 0.9800 . ?
C38 H55 0.9800 . ?
C38 H56 0.9800 . ?
Ge3 C43 1.925(3) . ?
Ge3 C39 1.968(3) . ?
Ge3 Ru3 2.7800(4) . ?
C39 C40 1.418(5) . ?
C39 C44 1.552(5) . ?
C39 Ru3 2.378(3) . ?
C40 C41 1.423(5) . ?
C40 Ru3 2.229(3) . ?
C40 H57 0.9500 . ?
C41 C42 1.414(5) . ?
C41 Ru3 2.193(3) . ?
C41 H58 0.9500 . ?
C42 C43 1.402(5) . ?
C42 Ru3 2.205(3) . ?
C42 H59 0.9500 . ?
C43 Ru3 2.285(3) . ?
C43 H60 0.9500 . ?
C44 C45 1.532(5) . ?
C44 C46 1.534(5) . ?
C44 C47 1.548(5) . ?
C45 H61 0.9800 . ?
C45 H62 0.9800 . ?
C45 H63 0.9800 . ?
C46 H64 0.9800 . ?
C46 H65 0.9800 . ?
C46 H66 0.9800 . ?
C47 H67 0.9800 . ?
C47 H68 0.9800 . ?
C47 H69 0.9800 . ?
Ru3 C50 2.173(4) . ?
Ru3 C51 2.178(4) . ?
Ru3 C52 2.194(4) . ?
Ru3 C49 2.209(3) . ?
Ru3 C48 2.217(4) . ?
C48 C49 1.430(5) . ?
C48 C52 1.436(6) . ?
C48 C53 1.508(6) . ?
C49 C50 1.439(5) . ?
C49 C54 1.501(5) . ?
C50 C51 1.438(6) . ?
C50 C55 1.503(6) . ?
C51 C52 1.428(7) . ?
C51 C56 1.510(6) . ?
C52 C57 1.520(6) . ?
C53 H70 0.9800 . ?
C53 H71 0.9800 . ?
C53 H72 0.9800 . ?
C54 H73 0.9800 . ?
C54 H74 0.9800 . ?
C54 H75 0.9800 . ?
C55 H76 0.9800 . ?
C55 H77 0.9800 . ?
C55 H78 0.9800 . ?
C56 H79 0.9800 . ?
C56 H80 0.9800 . ?
C56 H81 0.9800 . ?
C57 H82 0.9800 . ?
C57 H83 0.9800 . ?
C57 H84 0.9800 . ?
C58 C59 1.367(12) . ?
C58 C60 1.399(11) 2_677 ?
C58 H85 0.9500 . ?
C59 C60 1.354(11) . ?
C59 H86 0.9500 . ?
C60 H87 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C5 Ge1 C1 99.64(15) . . ?
C5 Ge1 Ru1 117.84(11) . . ?
C1 Ge1 Ru1 139.57(10) . . ?
C2 C1 C6 115.6(3) . . ?
C2 C1 Ge1 117.8(3) . . ?
C6 C1 Ge1 126.6(2) . . ?
C1 C2 C3 130.5(3) . . ?
C1 C2 H1 114.7 . . ?
C3 C2 H1 114.7 . . ?
C2 C3 C4 124.0(3) . . ?
C2 C3 H2 118.0 . . ?
C4 C3 H2 118.0 . . ?
C5 C4 C3 124.2(3) . . ?
C5 C4 H3 117.9 . . ?
C3 C4 H3 117.9 . . ?
C4 C5 Ge1 123.9(3) . . ?
C4 C5 H4 118.0 . . ?
Ge1 C5 H4 118.0 . . ?
C7 C6 C8 107.8(3) . . ?
C7 C6 C9 106.8(3) . . ?
C8 C6 C9 109.2(3) . . ?
C7 C6 C1 112.2(3) . . ?
C8 C6 C1 110.0(3) . . ?
C9 C6 C1 110.7(3) . . ?
C6 C7 H5 109.5 . . ?
C6 C7 H6 109.5 . . ?
H5 C7 H6 109.5 . . ?
C6 C7 H7 109.5 . . ?
H5 C7 H7 109.5 . . ?
H6 C7 H7 109.5 . . ?
C6 C8 H8 109.5 . . ?
C6 C8 H9 109.5 . . ?
H8 C8 H9 109.5 . . ?
C6 C8 H10 109.5 . . ?
H8 C8 H10 109.5 . . ?
H9 C8 H10 109.5 . . ?
C6 C9 H11 109.5 . . ?
C6 C9 H12 109.5 . . ?
H11 C9 H12 109.5 . . ?
C6 C9 H13 109.5 . . ?
H11 C9 H13 109.5 . . ?
H12 C9 H13 109.5 . . ?
C11 Ru1 C10 37.46(13) . . ?
C11 Ru1 C12 37.25(13) . . ?
C10 Ru1 C12 61.99(12) . . ?
C11 Ru1 C14 62.12(12) . . ?
C10 Ru1 C14 36.82(12) . . ?
C12 Ru1 C14 61.77(12) . . ?
C11 Ru1 C13 62.18(12) . . ?
C10 Ru1 C13 61.93(12) . . ?
C12 Ru1 C13 36.89(12) . . ?
C14 Ru1 C13 37.18(12) . . ?
C11 Ru1 Ge2 156.18(9) . . ?
C10 Ru1 Ge2 125.15(9) . . ?
C12 Ru1 Ge2 128.36(9) . . ?
C14 Ru1 Ge2 94.77(8) . . ?
C13 Ru1 Ge2 96.24(8) . . ?
C11 Ru1 Ge3 117.05(9) . . ?
C10 Ru1 Ge3 153.39(9) . . ?
C12 Ru1 Ge3 102.37(9) . . ?
C14 Ru1 Ge3 156.27(9) . . ?
C13 Ru1 Ge3 119.60(8) . . ?
Ge2 Ru1 Ge3 81.447(13) . . ?
C11 Ru1 Ge1 89.59(9) . . ?
C10 Ru1 Ge1 86.10(9) . . ?
C12 Ru1 Ge1 124.20(9) . . ?
C14 Ru1 Ge1 116.97(9) . . ?
C13 Ru1 Ge1 147.58(8) . . ?
Ge2 Ru1 Ge1 107.393(15) . . ?
Ge3 Ru1 Ge1 86.317(14) . . ?
C14 C10 C11 107.9(3) . . ?
C14 C10 C15 127.3(3) . . ?
C11 C10 C15 123.8(3) . . ?
C14 C10 Ru1 71.89(18) . . ?
C11 C10 Ru1 70.28(19) . . ?
C15 C10 Ru1 132.5(2) . . ?
C12 C11 C10 108.0(3) . . ?
C12 C11 C16 125.4(3) . . ?
C10 C11 C16 125.0(3) . . ?
C12 C11 Ru1 72.61(19) . . ?
C10 C11 Ru1 72.25(19) . . ?
C16 C11 Ru1 132.1(2) . . ?
C11 C12 C13 108.4(3) . . ?
C11 C12 C17 124.2(3) . . ?
C13 C12 C17 126.0(3) . . ?
C11 C12 Ru1 70.14(19) . . ?
C13 C12 Ru1 72.38(19) . . ?
C17 C12 Ru1 133.8(2) . . ?
C12 C13 C14 107.1(3) . . ?
C12 C13 C18 125.5(3) . . ?
C14 C13 C18 126.0(3) . . ?
C12 C13 Ru1 70.73(18) . . ?
C14 C13 Ru1 70.64(18) . . ?
C18 C13 Ru1 134.4(2) . . ?
C10 C14 C13 108.6(3) . . ?
C10 C14 C19 125.1(3) . . ?
C13 C14 C19 125.3(3) . . ?
C10 C14 Ru1 71.30(18) . . ?
C13 C14 Ru1 72.18(18) . . ?
C19 C14 Ru1 131.5(2) . . ?
C10 C15 H14 109.5 . . ?
C10 C15 H15 109.5 . . ?
H14 C15 H15 109.5 . . ?
C10 C15 H16 109.5 . . ?
H14 C15 H16 109.5 . . ?
H15 C15 H16 109.5 . . ?
C11 C16 H17 109.5 . . ?
C11 C16 H18 109.5 . . ?
H17 C16 H18 109.5 . . ?
C11 C16 H19 109.5 . . ?
H17 C16 H19 109.5 . . ?
H18 C16 H19 109.5 . . ?
C12 C17 H20 109.5 . . ?
C12 C17 H21 109.5 . . ?
H20 C17 H21 109.5 . . ?
C12 C17 H22 109.5 . . ?
H20 C17 H22 109.5 . . ?
H21 C17 H22 109.5 . . ?
C13 C18 H23 109.5 . . ?
C13 C18 H24 109.5 . . ?
H23 C18 H24 109.5 . . ?
C13 C18 H25 109.5 . . ?
H23 C18 H25 109.5 . . ?
H24 C18 H25 109.5 . . ?
C14 C19 H26 109.5 . . ?
C14 C19 H27 109.5 . . ?
H26 C19 H27 109.5 . . ?
C14 C19 H28 109.5 . . ?
H26 C19 H28 109.5 . . ?
H27 C19 H28 109.5 . . ?
C24 Ge2 C20 93.53(14) . . ?
C24 Ge2 Ru1 117.16(10) . . ?
C20 Ge2 Ru1 147.63(10) . . ?
C24 Ge2 Ru2 51.71(10) . . ?
C20 Ge2 Ru2 55.90(10) . . ?
Ru1 Ge2 Ru2 152.974(16) . . ?
C21 C20 C25 114.1(3) . . ?
C21 C20 Ge2 121.8(2) . . ?
C25 C20 Ge2 123.4(2) . . ?
C21 C20 Ru2 65.58(18) . . ?
C25 C20 Ru2 132.2(2) . . ?
Ge2 C20 Ru2 81.64(11) . . ?
C22 C21 C20 127.8(3) . . ?
C22 C21 Ru2 70.10(19) . . ?
C20 C21 Ru2 78.9(2) . . ?
C22 C21 H29 116.1 . . ?
C20 C21 H29 116.1 . . ?
Ru2 C21 H29 127.3 . . ?
C23 C22 C21 123.2(3) . . ?
C23 C22 Ru2 71.18(19) . . ?
C21 C22 Ru2 72.42(19) . . ?
C23 C22 H30 118.4 . . ?
C21 C22 H30 118.4 . . ?
Ru2 C22 H30 131.1 . . ?
C24 C23 C22 122.5(3) . . ?
C24 C23 Ru2 73.97(19) . . ?
C22 C23 Ru2 71.32(19) . . ?
C24 C23 H31 118.7 . . ?
C22 C23 H31 118.7 . . ?
Ru2 C23 H31 128.3 . . ?
C23 C24 Ge2 127.7(3) . . ?
C23 C24 Ru2 69.27(19) . . ?
Ge2 C24 Ru2 86.14(13) . . ?
C23 C24 H32 116.1 . . ?
Ge2 C24 H32 116.1 . . ?
Ru2 C24 H32 118.6 . . ?
C26 C25 C28 107.3(3) . . ?
C26 C25 C27 108.6(3) . . ?
C28 C25 C27 108.5(3) . . ?
C26 C25 C20 111.7(3) . . ?
C28 C25 C20 113.6(3) . . ?
C27 C25 C20 107.0(3) . . ?
C25 C26 H33 109.5 . . ?
C25 C26 H34 109.5 . . ?
H33 C26 H34 109.5 . . ?
C25 C26 H35 109.5 . . ?
H33 C26 H35 109.5 . . ?
H34 C26 H35 109.5 . . ?
C25 C27 H36 109.5 . . ?
C25 C27 H37 109.5 . . ?
H36 C27 H37 109.5 . . ?
C25 C27 H38 109.5 . . ?
H36 C27 H38 109.5 . . ?
H37 C27 H38 109.5 . . ?
C25 C28 H39 109.5 . . ?
C25 C28 H40 109.5 . . ?
H39 C28 H40 109.5 . . ?
C25 C28 H41 109.5 . . ?
H39 C28 H41 109.5 . . ?
H40 C28 H41 109.5 . . ?
C30 Ru2 C31 38.62(14) . . ?
C30 Ru2 C23 99.92(13) . . ?
C31 Ru2 C23 103.59(13) . . ?
C30 Ru2 C22 121.41(13) . . ?
C31 Ru2 C22 101.10(13) . . ?
C23 Ru2 C22 37.49(13) . . ?
C30 Ru2 C29 38.65(13) . . ?
C31 Ru2 C29 64.17(13) . . ?
C23 Ru2 C29 129.23(13) . . ?
C22 Ru2 C29 159.96(13) . . ?
C30 Ru2 C32 64.20(15) . . ?
C31 Ru2 C32 38.15(15) . . ?
C23 Ru2 C32 136.18(13) . . ?
C22 Ru2 C32 114.08(13) . . ?
C29 Ru2 C32 63.53(14) . . ?
C30 Ru2 C21 155.16(13) . . ?
C31 Ru2 C21 120.46(14) . . ?
C23 Ru2 C21 68.62(13) . . ?
C22 Ru2 C21 37.48(13) . . ?
C29 Ru2 C21 161.58(13) . . ?
C32 Ru2 C21 108.06(14) . . ?
C30 Ru2 C33 63.92(14) . . ?
C31 Ru2 C33 63.72(14) . . ?
C23 Ru2 C33 163.82(13) . . ?
C22 Ru2 C33 149.86(14) . . ?
C29 Ru2 C33 37.56(14) . . ?
C32 Ru2 C33 37.94(14) . . ?
C21 Ru2 C33 125.75(14) . . ?
C30 Ru2 C24 101.91(13) . . ?
C31 Ru2 C24 127.34(14) . . ?
C23 Ru2 C24 36.76(12) . . ?
C22 Ru2 C24 67.34(13) . . ?
C29 Ru2 C24 109.63(13) . . ?
C32 Ru2 C24 165.08(14) . . ?
C21 Ru2 C24 82.19(12) . . ?
C33 Ru2 C24 142.77(13) . . ?
C30 Ru2 C20 169.14(12) . . ?
C31 Ru2 C20 150.58(13) . . ?
C23 Ru2 C20 83.70(12) . . ?
C22 Ru2 C20 67.33(12) . . ?
C29 Ru2 C20 132.14(12) . . ?
C32 Ru2 C20 119.86(13) . . ?
C21 Ru2 C20 35.55(12) . . ?
C33 Ru2 C20 112.32(13) . . ?
C24 Ru2 C20 74.82(12) . . ?
C30 Ru2 Ge2 128.95(10) . . ?
C31 Ru2 Ge2 166.73(11) . . ?
C23 Ru2 Ge2 71.31(9) . . ?
C22 Ru2 Ge2 82.38(9) . . ?
C29 Ru2 Ge2 109.01(9) . . ?
C32 Ru2 Ge2 151.10(10) . . ?
C21 Ru2 Ge2 69.83(9) . . ?
C33 Ru2 Ge2 118.64(10) . . ?
C24 Ru2 Ge2 42.15(8) . . ?
C20 Ru2 Ge2 42.45(8) . . ?
C33 C29 C30 107.9(3) . . ?
C33 C29 C34 125.3(3) . . ?
C30 C29 C34 126.0(3) . . ?
C33 C29 Ru2 72.1(2) . . ?
C30 C29 Ru2 68.94(19) . . ?
C34 C29 Ru2 132.3(2) . . ?
C31 C30 C29 107.7(3) . . ?
C31 C30 C35 126.0(3) . . ?
C29 C30 C35 126.3(3) . . ?
C31 C30 Ru2 70.8(2) . . ?
C29 C30 Ru2 72.41(19) . . ?
C35 C30 Ru2 124.0(3) . . ?
C30 C31 C32 108.7(3) . . ?
C30 C31 C36 125.2(4) . . ?
C32 C31 C36 126.0(4) . . ?
C30 C31 Ru2 70.58(19) . . ?
C32 C31 Ru2 72.9(2) . . ?
C36 C31 Ru2 125.0(3) . . ?
C31 C32 C33 107.5(3) . . ?
C31 C32 C37 126.1(4) . . ?
C33 C32 C37 126.2(4) . . ?
C31 C32 Ru2 69.0(2) . . ?
C33 C32 Ru2 71.6(2) . . ?
C37 C32 Ru2 129.0(3) . . ?
C29 C33 C32 108.2(3) . . ?
C29 C33 C38 124.1(3) . . ?
C32 C33 C38 127.1(4) . . ?
C29 C33 Ru2 70.3(2) . . ?
C32 C33 Ru2 70.5(2) . . ?
C38 C33 Ru2 131.9(3) . . ?
C29 C34 H42 109.5 . . ?
C29 C34 H43 109.5 . . ?
H42 C34 H43 109.5 . . ?
C29 C34 H44 109.5 . . ?
H42 C34 H44 109.5 . . ?
H43 C34 H44 109.5 . . ?
C30 C35 H45 109.5 . . ?
C30 C35 H46 109.5 . . ?
H45 C35 H46 109.5 . . ?
C30 C35 H47 109.5 . . ?
H45 C35 H47 109.5 . . ?
H46 C35 H47 109.5 . . ?
C31 C36 H48 109.5 . . ?
C31 C36 H49 109.5 . . ?
H48 C36 H49 109.5 . . ?
C31 C36 H50 109.5 . . ?
H48 C36 H50 109.5 . . ?
H49 C36 H50 109.5 . . ?
C32 C37 H51 109.5 . . ?
C32 C37 H52 109.5 . . ?
H51 C37 H52 109.5 . . ?
C32 C37 H53 109.5 . . ?
H51 C37 H53 109.5 . . ?
H52 C37 H53 109.5 . . ?
C33 C38 H54 109.5 . . ?
C33 C38 H55 109.5 . . ?
H54 C38 H55 109.5 . . ?
C33 C38 H56 109.5 . . ?
H54 C38 H56 109.5 . . ?
H55 C38 H56 109.5 . . ?
C43 Ge3 C39 94.07(14) . . ?
C43 Ge3 Ru1 126.56(10) . . ?
C39 Ge3 Ru1 138.70(10) . . ?
C43 Ge3 Ru3 54.52(10) . . ?
C39 Ge3 Ru3 57.09(9) . . ?
Ru1 Ge3 Ru3 150.969(17) . . ?
C40 C39 C44 115.1(3) . . ?
C40 C39 Ge3 121.9(2) . . ?
C44 C39 Ge3 122.5(2) . . ?
C40 C39 Ru3 66.43(18) . . ?
C44 C39 Ru3 133.9(2) . . ?
Ge3 C39 Ru3 78.91(11) . . ?
C39 C40 C41 128.3(3) . . ?
C39 C40 Ru3 77.92(19) . . ?
C41 C40 Ru3 69.87(19) . . ?
C39 C40 H57 115.9 . . ?
C41 C40 H57 115.9 . . ?
Ru3 C40 H57 129.4 . . ?
C42 C41 C40 123.0(3) . . ?
C42 C41 Ru3 71.7(2) . . ?
C40 C41 Ru3 72.6(2) . . ?
C42 C41 H58 118.5 . . ?
C40 C41 H58 118.5 . . ?
Ru3 C41 H58 129.9 . . ?
C43 C42 C41 123.2(3) . . ?
C43 C42 Ru3 74.9(2) . . ?
C41 C42 Ru3 70.8(2) . . ?
C43 C42 H59 118.4 . . ?
C41 C42 H59 118.4 . . ?
Ru3 C42 H59 128.3 . . ?
C42 C43 Ge3 128.3(3) . . ?
C42 C43 Ru3 68.7(2) . . ?
Ge3 C43 Ru3 82.15(12) . . ?
C42 C43 H60 115.8 . . ?
Ge3 C43 H60 115.8 . . ?
Ru3 C43 H60 124.9 . . ?
C45 C44 C46 108.7(3) . . ?
C45 C44 C47 107.8(3) . . ?
C46 C44 C47 107.9(3) . . ?
C45 C44 C39 110.8(3) . . ?
C46 C44 C39 107.2(3) . . ?
C47 C44 C39 114.2(3) . . ?
C44 C45 H61 109.5 . . ?
C44 C45 H62 109.5 . . ?
H61 C45 H62 109.5 . . ?
C44 C45 H63 109.5 . . ?
H61 C45 H63 109.5 . . ?
H62 C45 H63 109.5 . . ?
C44 C46 H64 109.5 . . ?
C44 C46 H65 109.5 . . ?
H64 C46 H65 109.5 . . ?
C44 C46 H66 109.5 . . ?
H64 C46 H66 109.5 . . ?
H65 C46 H66 109.5 . . ?
C44 C47 H67 109.5 . . ?
C44 C47 H68 109.5 . . ?
H67 C47 H68 109.5 . . ?
C44 C47 H69 109.5 . . ?
H67 C47 H69 109.5 . . ?
H68 C47 H69 109.5 . . ?
C50 Ru3 C51 38.59(16) . . ?
C50 Ru3 C41 125.13(14) . . ?
C51 Ru3 C41 101.51(14) . . ?
C50 Ru3 C52 64.14(16) . . ?
C51 Ru3 C52 38.13(19) . . ?
C41 Ru3 C52 110.73(15) . . ?
C50 Ru3 C42 103.38(14) . . ?
C51 Ru3 C42 103.23(16) . . ?
C41 Ru3 C42 37.49(13) . . ?
C52 Ru3 C42 133.34(16) . . ?
C50 Ru3 C49 38.32(13) . . ?
C51 Ru3 C49 63.88(14) . . ?
C41 Ru3 C49 163.33(13) . . ?
C52 Ru3 C49 63.42(14) . . ?
C42 Ru3 C49 134.28(13) . . ?
C50 Ru3 C48 63.95(14) . . ?
C51 Ru3 C48 63.78(17) . . ?
C41 Ru3 C48 145.03(14) . . ?
C52 Ru3 C48 37.98(16) . . ?
C42 Ru3 C48 166.28(14) . . ?
C49 Ru3 C48 37.70(13) . . ?
C50 Ru3 C40 158.51(13) . . ?
C51 Ru3 C40 121.95(15) . . ?
C41 Ru3 C40 37.52(13) . . ?
C52 Ru3 C40 106.20(14) . . ?
C42 Ru3 C40 68.39(13) . . ?
C49 Ru3 C40 156.84(13) . . ?
C48 Ru3 C40 121.35(14) . . ?
C50 Ru3 C43 103.43(14) . . ?
C51 Ru3 C43 125.93(17) . . ?
C41 Ru3 C43 67.13(13) . . ?
C52 Ru3 C43 164.04(16) . . ?
C42 Ru3 C43 36.33(13) . . ?
C49 Ru3 C43 113.80(13) . . ?
C48 Ru3 C43 147.66(13) . . ?
C40 Ru3 C43 81.82(13) . . ?
C50 Ru3 C39 165.80(13) . . ?
C51 Ru3 C39 152.02(16) . . ?
C41 Ru3 C39 67.85(12) . . ?
C52 Ru3 C39 119.31(15) . . ?
C42 Ru3 C39 84.06(12) . . ?
C49 Ru3 C39 128.82(12) . . ?
C48 Ru3 C39 109.47(13) . . ?
C40 Ru3 C39 35.65(12) . . ?
C43 Ru3 C39 75.29(12) . . ?
C50 Ru3 Ge3 126.14(11) . . ?
C51 Ru3 Ge3 163.97(14) . . ?
C41 Ru3 Ge3 85.06(9) . . ?
C52 Ru3 Ge3 151.98(14) . . ?
C42 Ru3 Ge3 73.07(9) . . ?
C49 Ru3 Ge3 107.08(9) . . ?
C48 Ru3 Ge3 118.08(11) . . ?
C40 Ru3 Ge3 71.84(9) . . ?
C43 Ru3 Ge3 43.32(8) . . ?
C39 Ru3 Ge3 44.00(8) . . ?
C49 C48 C52 107.7(4) . . ?
C49 C48 C53 125.5(4) . . ?
C52 C48 C53 126.4(4) . . ?
C49 C48 Ru3 70.8(2) . . ?
C52 C48 Ru3 70.1(2) . . ?
C53 C48 Ru3 130.6(3) . . ?
C48 C49 C50 108.3(3) . . ?
C48 C49 C54 126.2(3) . . ?
C50 C49 C54 125.0(3) . . ?
C48 C49 Ru3 71.5(2) . . ?
C50 C49 Ru3 69.5(2) . . ?
C54 C49 Ru3 130.6(2) . . ?
C51 C50 C49 107.6(4) . . ?
C51 C50 C55 127.6(4) . . ?
C49 C50 C55 124.6(4) . . ?
C51 C50 Ru3 70.9(2) . . ?
C49 C50 Ru3 72.2(2) . . ?
C55 C50 Ru3 127.2(3) . . ?
C52 C51 C50 108.0(4) . . ?
C52 C51 C56 126.5(5) . . ?
C50 C51 C56 125.5(5) . . ?
C52 C51 Ru3 71.6(2) . . ?
C50 C51 Ru3 70.5(2) . . ?
C56 C51 Ru3 124.2(3) . . ?
C51 C52 C48 108.4(4) . . ?
C51 C52 C57 126.7(5) . . ?
C48 C52 C57 124.8(5) . . ?
C51 C52 Ru3 70.3(2) . . ?
C48 C52 Ru3 71.9(2) . . ?
C57 C52 Ru3 127.4(3) . . ?
C48 C53 H70 109.5 . . ?
C48 C53 H71 109.5 . . ?
H70 C53 H71 109.5 . . ?
C48 C53 H72 109.5 . . ?
H70 C53 H72 109.5 . . ?
H71 C53 H72 109.5 . . ?
C49 C54 H73 109.5 . . ?
C49 C54 H74 109.5 . . ?
H73 C54 H74 109.5 . . ?
C49 C54 H75 109.5 . . ?
H73 C54 H75 109.5 . . ?
H74 C54 H75 109.5 . . ?
C50 C55 H76 109.5 . . ?
C50 C55 H77 109.5 . . ?
H76 C55 H77 109.5 . . ?
C50 C55 H78 109.5 . . ?
H76 C55 H78 109.5 . . ?
H77 C55 H78 109.5 . . ?
C51 C56 H79 109.5 . . ?
C51 C56 H80 109.5 . . ?
H79 C56 H80 109.5 . . ?
C51 C56 H81 109.5 . . ?
H79 C56 H81 109.5 . . ?
H80 C56 H81 109.5 . . ?
C52 C57 H82 109.5 . . ?
C52 C57 H83 109.5 . . ?
H82 C57 H83 109.5 . . ?
C52 C57 H84 109.5 . . ?
H82 C57 H84 109.5 . . ?
H83 C57 H84 109.5 . . ?
C59 C58 C60 120.1(8) . 2_677 ?
C59 C58 H85 120.0 . . ?
C60 C58 H85 120.0 2_677 . ?
C60 C59 C58 120.0(7) . . ?
C60 C59 H86 120.0 . . ?
C58 C59 H86 120.0 . . ?
C59 C60 C58 119.9(8) . 2_677 ?
C59 C60 H87 120.1 . . ?
C58 C60 H87 120.1 2_677 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -178.5(4) . . . . ?
Ge1 C1 C2 C3 1.5(5) . . . . ?
C1 C2 C3 C4 -0.3(7) . . . . ?
C2 C3 C4 C5 -0.1(6) . . . . ?
C3 C4 C5 Ge1 -0.9(5) . . . . ?
C2 C1 C6 C7 176.1(3) . . . . ?
Ge1 C1 C6 C7 -3.9(4) . . . . ?
C2 C1 C6 C8 -63.9(4) . . . . ?
Ge1 C1 C6 C8 116.1(3) . . . . ?
C2 C1 C6 C9 56.9(4) . . . . ?
Ge1 C1 C6 C9 -123.1(3) . . . . ?
C14 C10 C11 C12 1.8(4) . . . . ?
C15 C10 C11 C12 -167.1(3) . . . . ?
Ru1 C10 C11 C12 64.3(2) . . . . ?
C14 C10 C11 C16 168.1(3) . . . . ?
C15 C10 C11 C16 -0.9(5) . . . . ?
Ru1 C10 C11 C16 -129.5(3) . . . . ?
C14 C10 C11 Ru1 -62.4(2) . . . . ?
C15 C10 C11 Ru1 128.6(3) . . . . ?
C10 C11 C12 C13 -1.4(4) . . . . ?
C16 C11 C12 C13 -167.6(3) . . . . ?
Ru1 C11 C12 C13 62.6(2) . . . . ?
C10 C11 C12 C17 165.9(3) . . . . ?
C16 C11 C12 C17 -0.3(5) . . . . ?
Ru1 C11 C12 C17 -130.1(3) . . . . ?
C10 C11 C12 Ru1 -64.0(2) . . . . ?
C16 C11 C12 Ru1 129.8(3) . . . . ?
C11 C12 C13 C14 0.5(4) . . . . ?
C17 C12 C13 C14 -166.6(3) . . . . ?
Ru1 C12 C13 C14 61.7(2) . . . . ?
C11 C12 C13 C18 167.4(3) . . . . ?
C17 C12 C13 C18 0.4(5) . . . . ?
Ru1 C12 C13 C18 -131.4(3) . . . . ?
C11 C12 C13 Ru1 -61.2(2) . . . . ?
C17 C12 C13 Ru1 131.8(3) . . . . ?
C11 C10 C14 C13 -1.6(4) . . . . ?
C15 C10 C14 C13 166.9(3) . . . . ?
Ru1 C10 C14 C13 -63.0(2) . . . . ?
C11 C10 C14 C19 -170.4(3) . . . . ?
C15 C10 C14 C19 -2.0(5) . . . . ?
Ru1 C10 C14 C19 128.2(3) . . . . ?
C11 C10 C14 Ru1 61.4(2) . . . . ?
C15 C10 C14 Ru1 -130.1(3) . . . . ?
C12 C13 C14 C10 0.7(4) . . . . ?
C18 C13 C14 C10 -166.2(3) . . . . ?
Ru1 C13 C14 C10 62.4(2) . . . . ?
C12 C13 C14 C19 169.5(3) . . . . ?
C18 C13 C14 C19 2.7(5) . . . . ?
Ru1 C13 C14 C19 -128.8(3) . . . . ?
C12 C13 C14 Ru1 -61.7(2) . . . . ?
C18 C13 C14 Ru1 131.4(3) . . . . ?
C25 C20 C21 C22 -179.1(3) . . . . ?
Ge2 C20 C21 C22 -8.3(5) . . . . ?
Ru2 C20 C21 C22 53.7(3) . . . . ?
C25 C20 C21 Ru2 127.2(3) . . . . ?
Ge2 C20 C21 Ru2 -62.0(2) . . . . ?
C20 C21 C22 C23 -5.0(6) . . . . ?
Ru2 C21 C22 C23 52.2(3) . . . . ?
C20 C21 C22 Ru2 -57.3(3) . . . . ?
C21 C22 C23 C24 3.1(5) . . . . ?
Ru2 C22 C23 C24 55.9(3) . . . . ?
C21 C22 C23 Ru2 -52.8(3) . . . . ?
C22 C23 C24 Ge2 12.8(5) . . . . ?
Ru2 C23 C24 Ge2 67.4(3) . . . . ?
C22 C23 C24 Ru2 -54.7(3) . . . . ?
C21 C20 C25 C26 -167.8(3) . . . . ?
Ge2 C20 C25 C26 21.5(4) . . . . ?
Ru2 C20 C25 C26 -89.7(4) . . . . ?
C21 C20 C25 C28 -46.3(4) . . . . ?
Ge2 C20 C25 C28 143.1(3) . . . . ?
Ru2 C20 C25 C28 31.9(4) . . . . ?
C21 C20 C25 C27 73.4(4) . . . . ?
Ge2 C20 C25 C27 -97.2(3) . . . . ?
Ru2 C20 C25 C27 151.6(3) . . . . ?
C33 C29 C30 C31 0.5(4) . . . . ?
C34 C29 C30 C31 -169.9(3) . . . . ?
Ru2 C29 C30 C31 62.4(2) . . . . ?
C33 C29 C30 C35 178.5(3) . . . . ?
C34 C29 C30 C35 8.1(6) . . . . ?
Ru2 C29 C30 C35 -119.6(4) . . . . ?
C33 C29 C30 Ru2 -61.9(2) . . . . ?
C34 C29 C30 Ru2 127.7(3) . . . . ?
C29 C30 C31 C32 -0.1(4) . . . . ?
C35 C30 C31 C32 -178.1(3) . . . . ?
Ru2 C30 C31 C32 63.3(3) . . . . ?
C29 C30 C31 C36 176.8(3) . . . . ?
C35 C30 C31 C36 -1.2(6) . . . . ?
Ru2 C30 C31 C36 -119.7(4) . . . . ?
C29 C30 C31 Ru2 -63.5(2) . . . . ?
C35 C30 C31 Ru2 118.6(4) . . . . ?
C30 C31 C32 C33 -0.3(4) . . . . ?
C36 C31 C32 C33 -177.2(3) . . . . ?
Ru2 C31 C32 C33 61.6(3) . . . . ?
C30 C31 C32 C37 174.5(4) . . . . ?
C36 C31 C32 C37 -2.4(6) . . . . ?
Ru2 C31 C32 C37 -123.6(4) . . . . ?
C30 C31 C32 Ru2 -61.9(2) . . . . ?
C36 C31 C32 Ru2 121.3(4) . . . . ?
C30 C29 C33 C32 -0.7(4) . . . . ?
C34 C29 C33 C32 169.8(3) . . . . ?
Ru2 C29 C33 C32 -60.6(2) . . . . ?
C30 C29 C33 C38 -172.2(3) . . . . ?
C34 C29 C33 C38 -1.7(6) . . . . ?
Ru2 C29 C33 C38 127.9(4) . . . . ?
C30 C29 C33 Ru2 59.9(2) . . . . ?
C34 C29 C33 Ru2 -129.6(3) . . . . ?
C31 C32 C33 C29 0.6(4) . . . . ?
C37 C32 C33 C29 -174.2(4) . . . . ?
Ru2 C32 C33 C29 60.5(2) . . . . ?
C31 C32 C33 C38 171.8(4) . . . . ?
C37 C32 C33 C38 -3.0(6) . . . . ?
Ru2 C32 C33 C38 -128.3(4) . . . . ?
C31 C32 C33 Ru2 -59.9(2) . . . . ?
C37 C32 C33 Ru2 125.3(4) . . . . ?
C44 C39 C40 C41 -179.0(3) . . . . ?
Ge3 C39 C40 C41 -6.8(5) . . . . ?
Ru3 C39 C40 C41 51.9(3) . . . . ?
C44 C39 C40 Ru3 129.1(3) . . . . ?
Ge3 C39 C40 Ru3 -58.7(2) . . . . ?
C39 C40 C41 C42 -1.5(6) . . . . ?
Ru3 C40 C41 C42 53.5(3) . . . . ?
C39 C40 C41 Ru3 -55.0(3) . . . . ?
C40 C41 C42 C43 2.3(5) . . . . ?
Ru3 C41 C42 C43 56.1(3) . . . . ?
C40 C41 C42 Ru3 -53.9(3) . . . . ?
C41 C42 C43 Ge3 6.1(5) . . . . ?
Ru3 C42 C43 Ge3 60.4(3) . . . . ?
C41 C42 C43 Ru3 -54.3(3) . . . . ?
C40 C39 C44 C45 -154.2(3) . . . . ?
Ge3 C39 C44 C45 33.7(4) . . . . ?
Ru3 C39 C44 C45 -73.5(4) . . . . ?
C40 C39 C44 C46 87.4(3) . . . . ?
Ge3 C39 C44 C46 -84.8(3) . . . . ?
Ru3 C39 C44 C46 168.0(3) . . . . ?
C40 C39 C44 C47 -32.1(4) . . . . ?
Ge3 C39 C44 C47 155.7(3) . . . . ?
Ru3 C39 C44 C47 48.5(4) . . . . ?
C52 C48 C49 C50 -0.7(4) . . . . ?
C53 C48 C49 C50 -173.3(4) . . . . ?
Ru3 C48 C49 C50 60.0(2) . . . . ?
C52 C48 C49 C54 172.0(3) . . . . ?
C53 C48 C49 C54 -0.6(6) . . . . ?
Ru3 C48 C49 C54 -127.3(3) . . . . ?
C52 C48 C49 Ru3 -60.7(3) . . . . ?
C53 C48 C49 Ru3 126.7(4) . . . . ?
C48 C49 C50 C51 1.2(4) . . . . ?
C54 C49 C50 C51 -171.6(3) . . . . ?
Ru3 C49 C50 C51 62.4(2) . . . . ?
C48 C49 C50 C55 175.3(3) . . . . ?
C54 C49 C50 C55 2.5(6) . . . . ?
Ru3 C49 C50 C55 -123.4(4) . . . . ?
C48 C49 C50 Ru3 -61.3(2) . . . . ?
C54 C49 C50 Ru3 125.9(3) . . . . ?
C49 C50 C51 C52 -1.2(4) . . . . ?
C55 C50 C51 C52 -175.1(4) . . . . ?
Ru3 C50 C51 C52 62.1(3) . . . . ?
C49 C50 C51 C56 178.0(4) . . . . ?
C55 C50 C51 C56 4.1(7) . . . . ?
Ru3 C50 C51 C56 -118.7(4) . . . . ?
C49 C50 C51 Ru3 -63.3(2) . . . . ?
C55 C50 C51 Ru3 122.8(4) . . . . ?
C50 C51 C52 C48 0.8(4) . . . . ?
C56 C51 C52 C48 -178.5(4) . . . . ?
Ru3 C51 C52 C48 62.2(3) . . . . ?
C50 C51 C52 C57 176.1(4) . . . . ?
C56 C51 C52 C57 -3.2(7) . . . . ?
Ru3 C51 C52 C57 -122.5(4) . . . . ?
C50 C51 C52 Ru3 -61.4(3) . . . . ?
C56 C51 C52 Ru3 119.3(4) . . . . ?
C49 C48 C52 C51 0.0(4) . . . . ?
C53 C48 C52 C51 172.5(4) . . . . ?
Ru3 C48 C52 C51 -61.2(3) . . . . ?
C49 C48 C52 C57 -175.4(4) . . . . ?
C53 C48 C52 C57 -2.9(6) . . . . ?
Ru3 C48 C52 C57 123.4(4) . . . . ?
C49 C48 C52 Ru3 61.2(2) . . . . ?
C53 C48 C52 Ru3 -126.3(4) . . . . ?
C60 C58 C59 C60 -1.1(10) 2_677 . . . ?
C58 C59 C60 C58 1.1(10) . . . 2_677 ?

_refine_diff_density_max         1.888
_refine_diff_density_min         -0.803
_refine_diff_density_rms         0.092




_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: benzene'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
