# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AX1363abs
_database_code_depnum_ccdc_archive 'CCDC 1816554'
_audit_update_record             
;
2018-01-12 deposited with the CCDC.
2018-05-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H56 Cl2 P2 Rh2 S2'
_chemical_formula_weight         867.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x+1/2, -y, z+1/2'

_cell_length_a                   14.1210(5)
_cell_length_b                   14.5253(5)
_cell_length_c                   18.8086(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3857.9(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    9997
_cell_measurement_theta_min      3.85
_cell_measurement_theta_max      69.54

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.494
_exptl_crystal_F_000             1784
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.16
_exptl_absorpt_coefficient_mu    10.148
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4966
_exptl_absorpt_correction_T_max  0.7533
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   microfocus
_diffrn_radiation_monochromator  multilayer
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean 8.3333
_diffrn_reflns_number            24056
_diffrn_reflns_av_unetI/netI     0.0371
_diffrn_reflns_av_R_equivalents  0.0320
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.845
_diffrn_reflns_theta_max         66.595
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.972
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.972
_diffrn_reflns_point_group_measured_fraction_max 0.967
_diffrn_reflns_point_group_measured_fraction_full 0.943
_reflns_number_total             6590
_reflns_number_gt                6377
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.739
_reflns_Friedel_fraction_max     0.932
_reflns_Friedel_fraction_full    0.907

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_reduction        'SAINT (Bruker, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0648P)²+3.6434P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 2655 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.017(4)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         6590
_refine_ls_number_parameters     377
_refine_ls_number_restraints     111
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0357
_refine_ls_wR_factor_ref         0.0958
_refine_ls_wR_factor_gt          0.0947
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.33873(3) 0.33715(3) 1.09036(3) 0.03236(14) Uani 1 1 d . . . . .
Rh2 Rh 0.31200(3) 0.97352(3) 0.78810(2) 0.02813(13) Uani 1 1 d . . . . .
Cl1 Cl 0.17864(14) 0.31351(14) 1.12211(12) 0.0534(5) Uani 1 1 d . . . . .
Cl2 Cl 0.14605(11) 0.97318(14) 0.77311(9) 0.0413(4) Uani 1 1 d . . . . .
P1 P 0.31297(13) 0.49215(12) 1.10241(11) 0.0406(4) Uani 1 1 d D . . . .
P2 P 0.29151(10) 0.89111(11) 0.89162(8) 0.0273(3) Uani 1 1 d . . . . .
S1 S 0.43527(13) 0.56504(13) 1.07659(19) 0.0667(8) Uani 1 1 d . . . . .
S2 S 0.41402(11) 0.90650(12) 0.95579(9) 0.0322(3) Uani 1 1 d . . . . .
C1 C 0.4202(4) 0.6863(5) 1.0891(5) 0.0385(16) Uani 1 1 d . . . . .
C2 C 0.4252(5) 0.7278(5) 1.1551(4) 0.0387(16) Uani 1 1 d . . . . .
H2 H 0.4326 0.6913 1.1967 0.046 Uiso 1 1 calc R U . . .
C3 C 0.4192(5) 0.8234(6) 1.1605(4) 0.0397(16) Uani 1 1 d . . . . .
H3 H 0.4209 0.8521 1.2059 0.048 Uiso 1 1 calc R U . . .
C4 C 0.4107(4) 0.8766(4) 1.0992(4) 0.0320(13) Uani 1 1 d . . . . .
H4 H 0.4061 0.9417 1.1029 0.038 Uiso 1 1 calc R U . . .
C5 C 0.4091(4) 0.8348(5) 1.0330(3) 0.0287(13) Uani 1 1 d . . . . .
C6 C 0.4154(4) 0.7386(5) 1.0276(4) 0.0325(14) Uani 1 1 d . . . . .
H6 H 0.4165 0.7096 0.9823 0.039 Uiso 1 1 calc R U . . .
C7 C 0.3043(8) 0.5254(7) 1.2014(7) 0.082(4) Uani 1 1 d D . . . .
H7 H 0.3070 0.5942 1.2033 0.098 Uiso 1 1 calc R U . . .
C8 C 0.3906(9) 0.4900(10) 1.2453(7) 0.087(4) Uani 1 1 d . . . . .
H8A H 0.4495 0.5079 1.2215 0.130 Uiso 1 1 calc R U . . .
H8B H 0.3889 0.5169 1.2930 0.130 Uiso 1 1 calc R U . . .
H8C H 0.3877 0.4227 1.2490 0.130 Uiso 1 1 calc R U . . .
C9 C 0.2202(12) 0.4999(9) 1.2353(7) 0.099(5) Uani 1 1 d . . . . .
H9A H 0.1661 0.5223 1.2076 0.148 Uiso 1 1 calc R U . . .
H9B H 0.2172 0.4327 1.2389 0.148 Uiso 1 1 calc R U . . .
H9C H 0.2185 0.5269 1.2830 0.148 Uiso 1 1 calc R U . . .
C10 C 0.2043(11) 0.5344(13) 1.0665(9) 0.079(3) Uani 0.682(18) 1 d D . P A 1
H10 H 0.1511 0.4931 1.0812 0.095 Uiso 0.682(18) 1 calc R U P A 1
C11 C 0.1828(14) 0.6346(12) 1.0905(11) 0.079(3) Uani 0.682(18) 1 d D . P A 1
H11A H 0.1721 0.6358 1.1419 0.118 Uiso 0.682(18) 1 calc R U P A 1
H11B H 0.2367 0.6743 1.0786 0.118 Uiso 0.682(18) 1 calc R U P A 1
H11C H 0.1260 0.6570 1.0659 0.118 Uiso 0.682(18) 1 calc R U P A 1
C12 C 0.2221(11) 0.5237(12) 0.9880(8) 0.079(3) Uani 0.682(18) 1 d D . P A 1
H12A H 0.2350 0.4589 0.9773 0.118 Uiso 0.682(18) 1 calc R U P A 1
H12B H 0.1661 0.5439 0.9615 0.118 Uiso 0.682(18) 1 calc R U P A 1
H12C H 0.2767 0.5612 0.9742 0.118 Uiso 0.682(18) 1 calc R U P A 1
C10' C 0.217(2) 0.539(3) 1.050(2) 0.079(3) Uani 0.318(18) 1 d D . P A 2
H10' H 0.2624 0.5572 1.0112 0.095 Uiso 0.318(18) 1 calc R U P A 2
C11' C 0.187(3) 0.641(2) 1.061(2) 0.079(3) Uani 0.318(18) 1 d D . P A 2
H11D H 0.2301 0.6696 1.0958 0.118 Uiso 0.318(18) 1 calc R U P A 2
H11E H 0.1908 0.6738 1.0160 0.118 Uiso 0.318(18) 1 calc R U P A 2
H11F H 0.1224 0.6426 1.0794 0.118 Uiso 0.318(18) 1 calc R U P A 2
C12' C 0.148(2) 0.500(2) 0.996(2) 0.079(3) Uani 0.318(18) 1 d D . P A 2
H12D H 0.1640 0.4352 0.9869 0.118 Uiso 0.318(18) 1 calc R U P A 2
H12E H 0.0838 0.5038 1.0153 0.118 Uiso 0.318(18) 1 calc R U P A 2
H12F H 0.1522 0.5350 0.9519 0.118 Uiso 0.318(18) 1 calc R U P A 2
C13 C 0.1894(5) 0.9275(5) 0.9457(3) 0.0346(14) Uani 1 1 d . . . . .
H13 H 0.1331 0.9260 0.9134 0.041 Uiso 1 1 calc R U . . .
C14 C 0.1649(5) 0.8667(6) 1.0091(4) 0.0423(17) Uani 1 1 d . . . . .
H14A H 0.1570 0.8029 0.9931 0.064 Uiso 1 1 calc R U . . .
H14B H 0.2161 0.8697 1.0442 0.064 Uiso 1 1 calc R U . . .
H14C H 0.1058 0.8882 1.0308 0.064 Uiso 1 1 calc R U . . .
C15 C 0.2024(6) 1.0276(6) 0.9676(4) 0.0470(18) Uani 1 1 d . . . . .
H15A H 0.2181 1.0647 0.9257 0.071 Uiso 1 1 calc R U . . .
H15B H 0.1437 1.0506 0.9889 0.071 Uiso 1 1 calc R U . . .
H15C H 0.2539 1.0321 1.0024 0.071 Uiso 1 1 calc R U . . .
C16 C 0.2748(5) 0.7669(5) 0.8789(4) 0.0360(15) Uani 1 1 d . . . . .
H16 H 0.2752 0.7371 0.9268 0.043 Uiso 1 1 calc R U . . .
C17 C 0.3562(6) 0.7254(5) 0.8353(5) 0.0475(19) Uani 1 1 d . . . . .
H17A H 0.4167 0.7396 0.8585 0.071 Uiso 1 1 calc R U . . .
H17B H 0.3483 0.6585 0.8324 0.071 Uiso 1 1 calc R U . . .
H17C H 0.3557 0.7516 0.7873 0.071 Uiso 1 1 calc R U . . .
C18 C 0.1795(6) 0.7456(6) 0.8439(4) 0.0448(17) Uani 1 1 d . . . . .
H18A H 0.1283 0.7725 0.8723 0.067 Uiso 1 1 calc R U . . .
H18B H 0.1783 0.7719 0.7959 0.067 Uiso 1 1 calc R U . . .
H18C H 0.1709 0.6788 0.8410 0.067 Uiso 1 1 calc R U . . .
C21 C 0.4889(6) 0.3440(6) 1.0926(6) 0.055(2) Uani 1 1 d . U . . .
H21 H 0.5146 0.4032 1.1118 0.066 Uiso 1 1 calc R U . . .
C22 C 0.4558(6) 0.3499(5) 1.0214(5) 0.049(2) Uani 1 1 d . U . . .
H22 H 0.4623 0.4130 1.0007 0.059 Uiso 1 1 calc R U . . .
C23 C 0.4574(8) 0.2757(6) 0.9665(6) 0.072(3) Uani 1 1 d D U . . .
H23A H 0.5242 0.2627 0.9542 0.086 Uiso 1 1 calc R U . . .
H23B H 0.4259 0.2992 0.9231 0.086 Uiso 1 1 calc R U . . .
C24 C 0.4102(11) 0.1858(7) 0.9876(7) 0.092(4) Uani 1 1 d D U . . .
H24A H 0.3755 0.1612 0.9460 0.111 Uiso 1 1 calc R U . . .
H24B H 0.4600 0.1407 1.0003 0.111 Uiso 1 1 calc R U . . .
C25 C 0.3427(8) 0.1941(5) 1.0486(5) 0.061(2) Uani 1 1 d . U . . .
H25 H 0.2789 0.1668 1.0394 0.073 Uiso 1 1 calc R U . . .
C26 C 0.3693(8) 0.1923(6) 1.1179(6) 0.064(3) Uani 1 1 d . U . . .
H26 H 0.3206 0.1642 1.1498 0.076 Uiso 1 1 calc R U . . .
C27 C 0.4675(8) 0.1847(8) 1.1464(9) 0.098(4) Uani 1 1 d D U . . .
H27A H 0.4930 0.1236 1.1331 0.118 Uiso 1 1 calc R U . . .
H27B H 0.4641 0.1869 1.1990 0.118 Uiso 1 1 calc R U . . .
C28 C 0.5374(8) 0.2583(7) 1.1216(8) 0.086(4) Uani 1 1 d D U . . .
H28A H 0.5784 0.2760 1.1620 0.104 Uiso 1 1 calc R U . . .
H28B H 0.5784 0.2319 1.0841 0.104 Uiso 1 1 calc R U . . .
C31 C 0.4581(5) 0.9397(7) 0.7793(4) 0.0450(19) Uani 1 1 d . U . . .
H31 H 0.4786 0.8911 0.8137 0.054 Uiso 1 1 calc R U . . .
C32 C 0.4501(5) 1.0253(7) 0.8097(4) 0.0459(18) Uani 1 1 d . U . . .
H32 H 0.4658 1.0255 0.8616 0.055 Uiso 1 1 calc R U . . .
C33 C 0.4690(8) 1.1162(9) 0.7742(6) 0.086(4) Uani 1 1 d D U . . .
H33A H 0.5345 1.1156 0.7554 0.103 Uiso 1 1 calc R U . . .
H33B H 0.4655 1.1653 0.8107 0.103 Uiso 1 1 calc R U . . .
C34 C 0.4018(8) 1.1407(7) 0.7138(7) 0.082(4) Uani 1 1 d D U . . .
H34A H 0.3762 1.2031 0.7229 0.099 Uiso 1 1 calc R U . . .
H34B H 0.4390 1.1439 0.6692 0.099 Uiso 1 1 calc R U . . .
C35 C 0.3216(5) 1.0778(5) 0.7022(4) 0.0429(16) Uani 1 1 d . U . . .
H35 H 0.2604 1.1100 0.6922 0.051 Uiso 1 1 calc R U . . .
C36 C 0.3283(6) 0.9936(5) 0.6720(3) 0.0406(16) Uani 1 1 d . U . . .
H36 H 0.2710 0.9756 0.6439 0.049 Uiso 1 1 calc R U . . .
C37 C 0.4175(7) 0.9486(8) 0.6469(4) 0.065(3) Uani 1 1 d D U . . .
H37A H 0.4508 0.9918 0.6148 0.078 Uiso 1 1 calc R U . . .
H37B H 0.4004 0.8936 0.6186 0.078 Uiso 1 1 calc R U . . .
C38 C 0.4857(7) 0.9193(11) 0.7050(4) 0.085(4) Uani 1 1 d D U . . .
H38A H 0.4956 0.8521 0.7009 0.102 Uiso 1 1 calc R U . . .
H38B H 0.5475 0.9493 0.6958 0.102 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C22 2.110(7) . ?
Rh1 C21 2.124(8) . ?
Rh1 C26 2.210(8) . ?
Rh1 C25 2.222(8) . ?
Rh1 P1 2.2918(18) . ?
Rh1 Cl1 2.3633(19) . ?
Rh2 C31 2.127(7) . ?
Rh2 C32 2.129(7) . ?
Rh2 C35 2.219(7) . ?
Rh2 C36 2.216(6) . ?
Rh2 P2 2.3038(16) . ?
Rh2 Cl2 2.3603(16) . ?
P1 C10 1.785(14) . ?
P1 C10' 1.81(2) . ?
P1 C7 1.928(13) . ?
P1 S1 2.083(3) . ?
P2 C16 1.836(7) . ?
P2 C13 1.842(7) . ?
P2 S2 2.121(2) . ?
S1 C1 1.790(7) . ?
S2 C5 1.788(7) . ?
C1 C2 1.382(12) . ?
C1 C6 1.384(11) . ?
C2 C3 1.395(12) . ?
C2 H2 0.9500 . ?
C3 C4 1.393(10) . ?
C3 H3 0.9500 . ?
C4 C5 1.387(10) . ?
C4 H4 0.9500 . ?
C5 C6 1.404(10) . ?
C6 H6 0.9500 . ?
C7 C9 1.397(19) . ?
C7 C8 1.560(17) . ?
C7 H7 1.0000 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 C12 1.505(18) . ?
C10 C11 1.554(17) . ?
C10 H10 1.0000 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C10' C12' 1.52(2) . ?
C10' C11' 1.55(2) . ?
C10' H10' 1.0000 . ?
C11' H11D 0.9800 . ?
C11' H11E 0.9800 . ?
C11' H11F 0.9800 . ?
C12' H12D 0.9800 . ?
C12' H12E 0.9800 . ?
C12' H12F 0.9800 . ?
C13 C15 1.524(11) . ?
C13 C14 1.524(10) . ?
C13 H13 1.0000 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C18 1.530(10) . ?
C16 C17 1.535(10) . ?
C16 H16 1.0000 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C21 C22 1.421(14) . ?
C21 C28 1.522(12) . ?
C21 H21 1.0000 . ?
C22 C23 1.491(13) . ?
C22 H22 1.0000 . ?
C23 C24 1.519(6) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 C25 1.497(13) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.356(16) . ?
C25 H25 1.0000 . ?
C26 C27 1.490(16) . ?
C26 H26 1.0000 . ?
C27 C28 1.528(6) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C31 C32 1.373(13) . ?
C31 C38 1.480(10) . ?
C31 H31 1.0000 . ?
C32 C33 1.503(13) . ?
C32 H32 1.0000 . ?
C33 C34 1.524(6) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 C35 1.472(11) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.353(11) . ?
C35 H35 1.0000 . ?
C36 C37 1.496(11) . ?
C36 H36 1.0000 . ?
C37 C38 1.518(6) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C22 Rh1 C21 39.2(4) . . ?
C22 Rh1 C26 94.3(3) . . ?
C21 Rh1 C26 81.1(4) . . ?
C22 Rh1 C25 81.1(3) . . ?
C21 Rh1 C25 91.5(4) . . ?
C26 Rh1 C25 35.6(4) . . ?
C22 Rh1 P1 95.7(2) . . ?
C21 Rh1 P1 96.3(2) . . ?
C26 Rh1 P1 160.6(3) . . ?
C25 Rh1 P1 163.3(3) . . ?
C22 Rh1 Cl1 156.6(3) . . ?
C21 Rh1 Cl1 163.2(3) . . ?
C26 Rh1 Cl1 89.4(3) . . ?
C25 Rh1 Cl1 88.7(3) . . ?
P1 Rh1 Cl1 88.05(7) . . ?
C31 Rh2 C32 37.6(4) . . ?
C31 Rh2 C35 92.4(3) . . ?
C32 Rh2 C35 80.9(3) . . ?
C31 Rh2 C36 81.6(3) . . ?
C32 Rh2 C36 92.7(3) . . ?
C35 Rh2 C36 35.5(3) . . ?
C31 Rh2 P2 93.9(2) . . ?
C32 Rh2 P2 97.9(2) . . ?
C35 Rh2 P2 167.9(2) . . ?
C36 Rh2 P2 156.1(2) . . ?
C31 Rh2 Cl2 162.4(2) . . ?
C32 Rh2 Cl2 158.9(3) . . ?
C35 Rh2 Cl2 88.6(2) . . ?
C36 Rh2 Cl2 89.2(2) . . ?
P2 Rh2 Cl2 88.58(6) . . ?
C10 P1 C7 103.0(7) . . ?
C10' P1 C7 112.7(15) . . ?
C10 P1 S1 116.7(6) . . ?
C10' P1 S1 107.4(13) . . ?
C7 P1 S1 98.7(4) . . ?
C10 P1 Rh1 115.9(7) . . ?
C10' P1 Rh1 115.8(13) . . ?
C7 P1 Rh1 110.6(3) . . ?
S1 P1 Rh1 110.16(9) . . ?
C16 P2 C13 104.7(3) . . ?
C16 P2 S2 106.4(2) . . ?
C13 P2 S2 107.1(2) . . ?
C16 P2 Rh2 114.6(2) . . ?
C13 P2 Rh2 114.6(2) . . ?
S2 P2 Rh2 108.88(8) . . ?
C1 S1 P1 111.8(2) . . ?
C5 S2 P2 111.6(2) . . ?
C2 C1 C6 121.0(6) . . ?
C2 C1 S1 122.7(6) . . ?
C6 C1 S1 115.8(6) . . ?
C1 C2 C3 119.7(7) . . ?
C1 C2 H2 120.1 . . ?
C3 C2 H2 120.1 . . ?
C2 C3 C4 119.8(7) . . ?
C2 C3 H3 120.1 . . ?
C4 C3 H3 120.1 . . ?
C5 C4 C3 120.1(6) . . ?
C5 C4 H4 119.9 . . ?
C3 C4 H4 119.9 . . ?
C4 C5 C6 120.0(6) . . ?
C4 C5 S2 118.3(5) . . ?
C6 C5 S2 121.2(5) . . ?
C1 C6 C5 119.2(7) . . ?
C1 C6 H6 120.4 . . ?
C5 C6 H6 120.4 . . ?
C9 C7 C8 109.6(12) . . ?
C9 C7 P1 115.3(9) . . ?
C8 C7 P1 112.2(8) . . ?
C9 C7 H7 106.4 . . ?
C8 C7 H7 106.4 . . ?
P1 C7 H7 106.4 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C12 C10 C11 114.5(14) . . ?
C12 C10 P1 101.1(10) . . ?
C11 C10 P1 112.3(13) . . ?
C12 C10 H10 109.5 . . ?
C11 C10 H10 109.5 . . ?
P1 C10 H10 109.5 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C12' C10' C11' 106(2) . . ?
C12' C10' P1 135(3) . . ?
C11' C10' P1 119(3) . . ?
C12' C10' H10' 91.4 . . ?
C11' C10' H10' 91.4 . . ?
P1 C10' H10' 91.4 . . ?
C10' C11' H11D 109.5 . . ?
C10' C11' H11E 109.5 . . ?
H11D C11' H11E 109.5 . . ?
C10' C11' H11F 109.5 . . ?
H11D C11' H11F 109.5 . . ?
H11E C11' H11F 109.5 . . ?
C10' C12' H12D 109.5 . . ?
C10' C12' H12E 109.5 . . ?
H12D C12' H12E 109.5 . . ?
C10' C12' H12F 109.5 . . ?
H12D C12' H12F 109.5 . . ?
H12E C12' H12F 109.5 . . ?
C15 C13 C14 111.6(6) . . ?
C15 C13 P2 109.2(5) . . ?
C14 C13 P2 116.3(5) . . ?
C15 C13 H13 106.3 . . ?
C14 C13 H13 106.3 . . ?
P2 C13 H13 106.3 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C18 C16 C17 110.5(6) . . ?
C18 C16 P2 111.6(5) . . ?
C17 C16 P2 111.0(5) . . ?
C18 C16 H16 107.9 . . ?
C17 C16 H16 107.9 . . ?
P2 C16 H16 107.9 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C22 C21 C28 122.3(10) . . ?
C22 C21 Rh1 69.9(4) . . ?
C28 C21 Rh1 114.7(6) . . ?
C22 C21 H21 114.2 . . ?
C28 C21 H21 114.2 . . ?
Rh1 C21 H21 114.2 . . ?
C21 C22 C23 127.1(9) . . ?
C21 C22 Rh1 70.9(5) . . ?
C23 C22 Rh1 111.9(6) . . ?
C21 C22 H22 113.0 . . ?
C23 C22 H22 113.0 . . ?
Rh1 C22 H22 113.0 . . ?
C22 C23 C24 115.8(8) . . ?
C22 C23 H23A 108.3 . . ?
C24 C23 H23A 108.3 . . ?
C22 C23 H23B 108.3 . . ?
C24 C23 H23B 108.3 . . ?
H23A C23 H23B 107.4 . . ?
C25 C24 C23 114.2(8) . . ?
C25 C24 H24A 108.7 . . ?
C23 C24 H24A 108.7 . . ?
C25 C24 H24B 108.7 . . ?
C23 C24 H24B 108.7 . . ?
H24A C24 H24B 107.6 . . ?
C26 C25 C24 124.0(12) . . ?
C26 C25 Rh1 71.7(5) . . ?
C24 C25 Rh1 111.2(6) . . ?
C26 C25 H25 114.1 . . ?
C24 C25 H25 114.1 . . ?
Rh1 C25 H25 114.1 . . ?
C25 C26 C27 127.3(11) . . ?
C25 C26 Rh1 72.7(5) . . ?
C27 C26 Rh1 109.6(7) . . ?
C25 C26 H26 113.2 . . ?
C27 C26 H26 113.2 . . ?
Rh1 C26 H26 113.2 . . ?
C26 C27 C28 116.1(9) . . ?
C26 C27 H27A 108.3 . . ?
C28 C27 H27A 108.3 . . ?
C26 C27 H27B 108.3 . . ?
C28 C27 H27B 108.3 . . ?
H27A C27 H27B 107.4 . . ?
C21 C28 C27 113.0(8) . . ?
C21 C28 H28A 109.0 . . ?
C27 C28 H28A 109.0 . . ?
C21 C28 H28B 109.0 . . ?
C27 C28 H28B 109.0 . . ?
H28A C28 H28B 107.8 . . ?
C32 C31 C38 126.6(10) . . ?
C32 C31 Rh2 71.2(4) . . ?
C38 C31 Rh2 112.0(5) . . ?
C32 C31 H31 113.2 . . ?
C38 C31 H31 113.1 . . ?
Rh2 C31 H31 113.2 . . ?
C31 C32 C33 126.5(8) . . ?
C31 C32 Rh2 71.1(4) . . ?
C33 C32 Rh2 112.9(6) . . ?
C31 C32 H32 113.0 . . ?
C33 C32 H32 113.0 . . ?
Rh2 C32 H32 113.0 . . ?
C32 C33 C34 115.2(7) . . ?
C32 C33 H33A 108.5 . . ?
C34 C33 H33A 108.5 . . ?
C32 C33 H33B 108.5 . . ?
C34 C33 H33B 108.5 . . ?
H33A C33 H33B 107.5 . . ?
C35 C34 C33 116.4(8) . . ?
C35 C34 H34A 108.2 . . ?
C33 C34 H34A 108.2 . . ?
C35 C34 H34B 108.2 . . ?
C33 C34 H34B 108.2 . . ?
H34A C34 H34B 107.3 . . ?
C36 C35 C34 124.7(9) . . ?
C36 C35 Rh2 72.1(4) . . ?
C34 C35 Rh2 111.3(5) . . ?
C36 C35 H35 113.8 . . ?
C34 C35 H35 113.8 . . ?
Rh2 C35 H35 113.8 . . ?
C35 C36 C37 125.9(9) . . ?
C35 C36 Rh2 72.4(4) . . ?
C37 C36 Rh2 109.9(5) . . ?
C35 C36 H36 113.7 . . ?
C37 C36 H36 113.7 . . ?
Rh2 C36 H36 113.7 . . ?
C36 C37 C38 115.5(7) . . ?
C36 C37 H37A 108.4 . . ?
C38 C37 H37A 108.4 . . ?
C36 C37 H37B 108.4 . . ?
C38 C37 H37B 108.4 . . ?
H37A C37 H37B 107.5 . . ?
C31 C38 C37 117.2(7) . . ?
C31 C38 H38A 108.0 . . ?
C37 C38 H38A 108.0 . . ?
C31 C38 H38B 108.0 . . ?
C37 C38 H38B 108.0 . . ?
H38A C38 H38B 107.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 S1 C1 C2 79.1(6) . . . . ?
P1 S1 C1 C6 -108.9(5) . . . . ?
C6 C1 C2 C3 4.1(10) . . . . ?
S1 C1 C2 C3 175.6(5) . . . . ?
C1 C2 C3 C4 -1.6(11) . . . . ?
C2 C3 C4 C5 -0.6(10) . . . . ?
C3 C4 C5 C6 0.3(10) . . . . ?
C3 C4 C5 S2 -171.8(5) . . . . ?
P2 S2 C5 C4 -119.0(5) . . . . ?
P2 S2 C5 C6 69.0(5) . . . . ?
C2 C1 C6 C5 -4.3(10) . . . . ?
S1 C1 C6 C5 -176.4(5) . . . . ?
C4 C5 C6 C1 2.1(10) . . . . ?
S2 C5 C6 C1 174.0(5) . . . . ?
C10' P1 C10 C12 23(8) . . . . ?
C7 P1 C10 C12 169.6(11) . . . . ?
S1 P1 C10 C12 62.8(13) . . . . ?
Rh1 P1 C10 C12 -69.5(13) . . . . ?
C10' P1 C10 C11 -100(9) . . . . ?
C7 P1 C10 C11 47.1(12) . . . . ?
S1 P1 C10 C11 -59.6(12) . . . . ?
Rh1 P1 C10 C11 168.0(9) . . . . ?
C10 P1 C10' C12' -95(10) . . . . ?
C7 P1 C10' C12' -130(4) . . . . ?
S1 P1 C10' C12' 122(4) . . . . ?
Rh1 P1 C10' C12' -2(5) . . . . ?
C10 P1 C10' C11' 80(8) . . . . ?
C7 P1 C10' C11' 44(3) . . . . ?
S1 P1 C10' C11' -64(3) . . . . ?
Rh1 P1 C10' C11' 173(2) . . . . ?
C16 P2 C13 C15 172.8(5) . . . . ?
S2 P2 C13 C15 60.1(5) . . . . ?
Rh2 P2 C13 C15 -60.8(5) . . . . ?
C16 P2 C13 C14 45.4(6) . . . . ?
S2 P2 C13 C14 -67.4(5) . . . . ?
Rh2 P2 C13 C14 171.8(4) . . . . ?
C13 P2 C16 C18 57.3(6) . . . . ?
S2 P2 C16 C18 170.5(5) . . . . ?
Rh2 P2 C16 C18 -69.1(6) . . . . ?
C13 P2 C16 C17 -179.0(5) . . . . ?
S2 P2 C16 C17 -65.8(6) . . . . ?
Rh2 P2 C16 C17 54.7(6) . . . . ?
C28 C21 C22 C23 3.6(13) . . . . ?
Rh1 C21 C22 C23 -103.5(8) . . . . ?
C28 C21 C22 Rh1 107.1(8) . . . . ?
C21 C22 C23 C24 54.7(16) . . . . ?
Rh1 C22 C23 C24 -27.4(15) . . . . ?
C22 C23 C24 C25 19.2(19) . . . . ?
C23 C24 C25 C26 -83.7(16) . . . . ?
C23 C24 C25 Rh1 -2.0(17) . . . . ?
C24 C25 C26 C27 1.9(15) . . . . ?
Rh1 C25 C26 C27 -101.8(10) . . . . ?
C24 C25 C26 Rh1 103.7(8) . . . . ?
C25 C26 C27 C28 56.5(19) . . . . ?
Rh1 C26 C27 C28 -26.2(17) . . . . ?
C22 C21 C28 C27 -83.2(15) . . . . ?
Rh1 C21 C28 C27 -2.3(16) . . . . ?
C26 C27 C28 C21 20(2) . . . . ?
C38 C31 C32 C33 -0.9(13) . . . . ?
Rh2 C31 C32 C33 -104.9(8) . . . . ?
C38 C31 C32 Rh2 104.0(8) . . . . ?
C31 C32 C33 C34 65.5(16) . . . . ?
Rh2 C32 C33 C34 -17.3(15) . . . . ?
C32 C33 C34 C35 5.9(19) . . . . ?
C33 C34 C35 C36 -74.7(16) . . . . ?
C33 C34 C35 Rh2 7.8(15) . . . . ?
C34 C35 C36 C37 1.8(12) . . . . ?
Rh2 C35 C36 C37 -102.2(7) . . . . ?
C34 C35 C36 Rh2 103.9(8) . . . . ?
C35 C36 C37 C38 69.4(14) . . . . ?
Rh2 C36 C37 C38 -12.8(13) . . . . ?
C32 C31 C38 C37 -67.1(16) . . . . ?
Rh2 C31 C38 C37 15.4(16) . . . . ?
C36 C37 C38 C31 -1.2(19) . . . . ?

_refine_diff_density_max         1.535
_refine_diff_density_min         -0.899
_refine_diff_density_rms         0.103

_shelxl_version_number           2014-3

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ax1402abs1
_database_code_depnum_ccdc_archive 'CCDC 1816556'
_audit_update_record             
;
2018-01-12 deposited with the CCDC.
2018-05-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C76 H70 Cl6 P4 Rh4 S4'
_chemical_formula_weight         1859.78

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.0429(3)
_cell_length_b                   13.0157(3)
_cell_length_c                   45.0034(12)
_cell_angle_alpha                90
_cell_angle_beta                 90.9850(10)
_cell_angle_gamma                90
_cell_volume                     7053.1(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    9892
_cell_measurement_theta_min      3.67
_cell_measurement_theta_max      70.12

_exptl_crystal_description       prism
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.751
_exptl_crystal_F_000             3728
_exptl_crystal_size_min          0.115
_exptl_crystal_size_mid          0.132
_exptl_crystal_size_max          0.195
_exptl_absorpt_coefficient_mu    11.848
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4753
_exptl_absorpt_correction_T_max  0.7533
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   microfocus
_diffrn_radiation_monochromator  multilayer
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean 8.3333
_diffrn_reflns_number            38252
_diffrn_reflns_av_unetI/netI     0.0414
_diffrn_reflns_av_R_equivalents  0.0431
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -50
_diffrn_reflns_limit_l_max       51
_diffrn_reflns_theta_min         1.964
_diffrn_reflns_theta_max         61.165
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.846
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.846
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.846
_reflns_number_total             10806
_reflns_number_gt                9315
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_reduction        'SAINT (Bruker, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0503P)²+14.0513P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10806
_refine_ls_number_parameters     847
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0486
_refine_ls_R_factor_gt           0.0398
_refine_ls_wR_factor_ref         0.1040
_refine_ls_wR_factor_gt          0.0990
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_restrained_S_all      1.069
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.76723(3) 0.88531(3) 0.80471(2) 0.02443(10) Uani 1 1 d . . . . .
Rh2 Rh 0.49179(3) 0.95055(3) 0.82227(2) 0.02856(10) Uani 1 1 d . . . . .
Rh3 Rh 0.24272(3) 0.35516(3) 0.94209(2) 0.02550(10) Uani 1 1 d . . . . .
Rh4 Rh 0.52293(3) 0.31736(3) 0.91690(2) 0.02956(11) Uani 1 1 d . . . . .
Cl1 Cl 0.59386(10) 0.80122(9) 0.80734(3) 0.0295(3) Uani 1 1 d . . . . .
Cl2 Cl 0.66751(10) 1.04143(10) 0.82427(3) 0.0316(3) Uani 1 1 d . . . . .
Cl3 Cl 0.94189(10) 0.96228(10) 0.80283(3) 0.0313(3) Uani 1 1 d . . . . .
Cl4 Cl 0.41563(10) 0.44546(10) 0.94250(3) 0.0308(3) Uani 1 1 d . . . . .
Cl5 Cl 0.35317(10) 0.21814(10) 0.91613(3) 0.0300(3) Uani 1 1 d . . . . .
Cl6 Cl 0.07314(11) 0.26846(12) 0.94116(3) 0.0396(3) Uani 1 1 d . . . . .
S1 S 0.82507(11) 0.83919(11) 0.73042(3) 0.0333(3) Uani 1 1 d . . . . .
S2 S 0.85109(15) 0.66983(11) 0.84518(3) 0.0438(4) Uani 1 1 d . . . . .
S3 S 0.08130(15) 0.54569(13) 0.90848(3) 0.0484(4) Uani 1 1 d . . . . .
S4 S 0.24989(12) 0.40435(12) 1.01826(3) 0.0369(3) Uani 1 1 d . . . . .
P1 P 0.73264(11) 0.93964(10) 0.75627(3) 0.0263(3) Uani 1 1 d . . . . .
P2 P 0.80635(11) 0.82213(10) 0.85217(3) 0.0282(3) Uani 1 1 d . . . . .
P3 P 0.18505(11) 0.42427(11) 0.89722(3) 0.0298(3) Uani 1 1 d . . . . .
P4 P 0.29064(11) 0.28916(11) 0.98828(3) 0.0282(3) Uani 1 1 d . . . . .
C1 C 0.8345(4) 0.7558(4) 0.78807(11) 0.0270(11) Uani 1 1 d . . . . .
C2 C 0.8522(4) 0.7415(4) 0.75745(11) 0.0284(11) Uani 1 1 d . . . . .
C3 C 0.8960(4) 0.6526(4) 0.74608(11) 0.0301(11) Uani 1 1 d . . . . .
H3 H 0.9063 0.6466 0.7253 0.036 Uiso 1 1 calc R U . . .
C4 C 0.9250(4) 0.5722(4) 0.76444(12) 0.0313(11) Uani 1 1 d . . . . .
H4 H 0.9551 0.5108 0.7565 0.038 Uiso 1 1 calc R U . . .
C5 C 0.9098(5) 0.5826(4) 0.79445(12) 0.0329(12) Uani 1 1 d . . . . .
H5 H 0.9299 0.5280 0.8075 0.040 Uiso 1 1 calc R U . . .
C6 C 0.8652(4) 0.6722(4) 0.80583(11) 0.0299(11) Uani 1 1 d . . . . .
C7 C 0.7771(4) 1.0633(4) 0.74236(12) 0.0306(11) Uani 1 1 d . . . . .
C8 C 0.7843(5) 1.0769(5) 0.71148(13) 0.0377(13) Uani 1 1 d . . . . .
H8 H 0.7611 1.0234 0.6984 0.045 Uiso 1 1 calc R U . . .
C9 C 0.8250(5) 1.1675(5) 0.70000(14) 0.0441(15) Uani 1 1 d . . . . .
H9 H 0.8299 1.1760 0.6791 0.053 Uiso 1 1 calc R U . . .
C10 C 0.8584(5) 1.2452(5) 0.71873(15) 0.0454(15) Uani 1 1 d . . . . .
H10 H 0.8891 1.3064 0.7108 0.055 Uiso 1 1 calc R U . . .
C11 C 0.8474(5) 1.2348(4) 0.74913(15) 0.0421(14) Uani 1 1 d . . . . .
H11 H 0.8677 1.2898 0.7620 0.050 Uiso 1 1 calc R U . . .
C12 C 0.8065(4) 1.1437(4) 0.76083(13) 0.0349(12) Uani 1 1 d . . . . .
H12 H 0.7987 1.1369 0.7817 0.042 Uiso 1 1 calc R U . . .
C13 C 0.5888(4) 0.9302(4) 0.74238(11) 0.0296(11) Uani 1 1 d . . . . .
C14 C 0.5240(5) 1.0177(5) 0.73939(12) 0.0356(12) Uani 1 1 d . . . . .
H14 H 0.5548 1.0831 0.7440 0.043 Uiso 1 1 calc R U . . .
C15 C 0.4143(5) 1.0102(5) 0.72963(12) 0.0411(14) Uani 1 1 d . . . . .
H15 H 0.3699 1.0703 0.7277 0.049 Uiso 1 1 calc R U . . .
C16 C 0.3700(5) 0.9148(6) 0.72278(13) 0.0458(16) Uani 1 1 d . . . . .
H16 H 0.2951 0.9094 0.7159 0.055 Uiso 1 1 calc R U . . .
C17 C 0.4344(5) 0.8272(5) 0.72590(13) 0.0427(14) Uani 1 1 d . . . . .
H17 H 0.4037 0.7618 0.7213 0.051 Uiso 1 1 calc R U . . .
C18 C 0.5436(5) 0.8350(5) 0.73580(11) 0.0357(13) Uani 1 1 d . . . . .
H18 H 0.5875 0.7748 0.7381 0.043 Uiso 1 1 calc R U . . .
C19 C 0.6991(5) 0.8131(4) 0.88029(11) 0.0314(12) Uani 1 1 d . . . . .
C20 C 0.6484(5) 0.9033(5) 0.89027(13) 0.0446(15) Uani 1 1 d . . . . .
H20 H 0.6679 0.9673 0.8817 0.054 Uiso 1 1 calc R U . . .
C21 C 0.5700(6) 0.9002(5) 0.91247(13) 0.0463(15) Uani 1 1 d . . . . .
H21 H 0.5359 0.9620 0.9189 0.056 Uiso 1 1 calc R U . . .
C22 C 0.5416(5) 0.8095(5) 0.92506(12) 0.0417(14) Uani 1 1 d . . . . .
H22 H 0.4884 0.8080 0.9404 0.050 Uiso 1 1 calc R U . . .
C23 C 0.5895(6) 0.7205(5) 0.91577(14) 0.0504(16) Uani 1 1 d . . . . .
H23 H 0.5690 0.6571 0.9246 0.060 Uiso 1 1 calc R U . . .
C24 C 0.6688(5) 0.7220(5) 0.89331(13) 0.0433(14) Uani 1 1 d . . . . .
H24 H 0.7018 0.6595 0.8870 0.052 Uiso 1 1 calc R U . . .
C25 C 0.9175(5) 0.8805(5) 0.87405(11) 0.0351(13) Uani 1 1 d . . . . .
C26 C 0.9970(5) 0.8227(6) 0.88923(13) 0.0480(16) Uani 1 1 d . . . . .
H26 H 0.9980 0.7501 0.8871 0.058 Uiso 1 1 calc R U . . .
C27 C 1.0748(6) 0.8707(7) 0.90747(15) 0.062(2) Uani 1 1 d . . . . .
H27 H 1.1295 0.8311 0.9177 0.075 Uiso 1 1 calc R U . . .
C28 C 1.0730(6) 0.9744(8) 0.91079(15) 0.070(3) Uani 1 1 d . . . . .
H28 H 1.1270 1.0062 0.9234 0.084 Uiso 1 1 calc R U . . .
C29 C 0.9947(6) 1.0347(6) 0.89638(13) 0.0546(19) Uani 1 1 d . . . . .
H29 H 0.9940 1.1071 0.8992 0.066 Uiso 1 1 calc R U . . .
C30 C 0.9168(5) 0.9879(5) 0.87759(12) 0.0423(14) Uani 1 1 d . . . . .
H30 H 0.8632 1.0284 0.8672 0.051 Uiso 1 1 calc R U . . .
C31 C 0.2569(5) 0.9899(5) 0.79904(13) 0.0402(13) Uani 1 1 d . . . . .
H31A H 0.1965 0.9833 0.8135 0.048 Uiso 1 1 calc R U . . .
H31B H 0.2236 0.9847 0.7788 0.048 Uiso 1 1 calc R U . . .
C32 C 0.3121(5) 1.0945(5) 0.80272(13) 0.0396(13) Uani 1 1 d . . . . .
H32A H 0.3376 1.1185 0.7831 0.048 Uiso 1 1 calc R U . . .
H32B H 0.2567 1.1444 0.8099 0.048 Uiso 1 1 calc R U . . .
C33 C 0.4091(4) 1.0920(4) 0.82403(12) 0.0336(12) Uani 1 1 d . . . . .
H33 H 0.4592 1.1530 0.8227 0.040 Uiso 1 1 calc R U . . .
C34 C 0.4082(5) 1.0458(4) 0.85223(12) 0.0356(13) Uani 1 1 d . . . . .
H34 H 0.4585 1.0800 0.8671 0.043 Uiso 1 1 calc R U . . .
C35 C 0.3067(5) 0.9958(5) 0.86589(13) 0.0419(14) Uani 1 1 d . . . . .
H35A H 0.2387 1.0289 0.8578 0.050 Uiso 1 1 calc R U . . .
H35B H 0.3089 1.0068 0.8877 0.050 Uiso 1 1 calc R U . . .
C36 C 0.3021(5) 0.8802(5) 0.85940(13) 0.0429(14) Uani 1 1 d . . . . .
H36A H 0.3395 0.8425 0.8759 0.051 Uiso 1 1 calc R U . . .
H36B H 0.2236 0.8577 0.8585 0.051 Uiso 1 1 calc R U . . .
C37 C 0.3571(4) 0.8535(4) 0.83055(12) 0.0330(12) Uani 1 1 d . . . . .
H37 H 0.3747 0.7788 0.8284 0.040 Uiso 1 1 calc R U . . .
C38 C 0.3390(4) 0.9034(4) 0.80371(13) 0.0324(12) Uani 1 1 d . . . . .
H38 H 0.3465 0.8577 0.7860 0.039 Uiso 1 1 calc R U . . .
C41 C 0.1680(4) 0.4725(4) 0.96276(11) 0.0298(11) Uani 1 1 d . . . . .
C42 C 0.1058(4) 0.5480(4) 0.94752(11) 0.0325(12) Uani 1 1 d . . . . .
C43 C 0.0543(5) 0.6309(5) 0.96164(13) 0.0374(13) Uani 1 1 d . . . . .
H43 H 0.0148 0.6809 0.9503 0.045 Uiso 1 1 calc R U . . .
C44 C 0.0614(5) 0.6393(5) 0.99231(13) 0.0388(13) Uani 1 1 d . . . . .
H44 H 0.0263 0.6946 1.0022 0.047 Uiso 1 1 calc R U . . .
C45 C 0.1196(4) 0.5669(4) 1.00814(12) 0.0347(13) Uani 1 1 d . . . . .
H45 H 0.1236 0.5717 1.0292 0.042 Uiso 1 1 calc R U . . .
C46 C 0.1732(4) 0.4862(4) 0.99389(11) 0.0302(11) Uani 1 1 d . . . . .
C47 C 0.2928(5) 0.4787(4) 0.87433(11) 0.0340(12) Uani 1 1 d . . . . .
C48 C 0.3321(6) 0.5769(5) 0.87953(14) 0.0465(15) Uani 1 1 d . . . . .
H48 H 0.2978 0.6190 0.8940 0.056 Uiso 1 1 calc R U . . .
C49 C 0.4214(6) 0.6143(5) 0.86378(14) 0.0492(16) Uani 1 1 d . . . . .
H49 H 0.4478 0.6820 0.8674 0.059 Uiso 1 1 calc R U . . .
C50 C 0.4719(6) 0.5537(6) 0.84284(14) 0.0530(17) Uani 1 1 d . . . . .
H50 H 0.5324 0.5797 0.8318 0.064 Uiso 1 1 calc R U . . .
C51 C 0.4342(5) 0.4552(6) 0.83801(14) 0.0499(16) Uani 1 1 d . . . . .
H51 H 0.4695 0.4129 0.8238 0.060 Uiso 1 1 calc R U . . .
C52 C 0.3453(5) 0.4171(5) 0.85362(12) 0.0430(14) Uani 1 1 d . . . . .
H52 H 0.3201 0.3489 0.8502 0.052 Uiso 1 1 calc R U . . .
C53 C 0.1010(4) 0.3495(4) 0.87070(11) 0.0306(11) Uani 1 1 d . . . . .
C54 C 0.0136(5) 0.3947(5) 0.85516(13) 0.0418(14) Uani 1 1 d . . . . .
H54 H -0.0041 0.4649 0.8584 0.050 Uiso 1 1 calc R U . . .
C55 C -0.0481(5) 0.3368(5) 0.83485(14) 0.0456(15) Uani 1 1 d . . . . .
H55 H -0.1091 0.3672 0.8245 0.055 Uiso 1 1 calc R U . . .
C56 C -0.0214(5) 0.2363(5) 0.82976(12) 0.0409(14) Uani 1 1 d . . . . .
H56 H -0.0635 0.1974 0.8157 0.049 Uiso 1 1 calc R U . . .
C57 C 0.0643(5) 0.1923(5) 0.84459(12) 0.0404(14) Uani 1 1 d . . . . .
H57 H 0.0824 0.1224 0.8410 0.048 Uiso 1 1 calc R U . . .
C58 C 0.1266(5) 0.2490(5) 0.86526(13) 0.0395(13) Uani 1 1 d . . . . .
H58 H 0.1871 0.2176 0.8756 0.047 Uiso 1 1 calc R U . . .
C59 C 0.2235(4) 0.1725(4) 1.00128(11) 0.0307(11) Uani 1 1 d . . . . .
C60 C 0.2005(5) 0.1587(5) 1.03115(12) 0.0408(14) Uani 1 1 d . . . . .
H60 H 0.2152 0.2127 1.0449 0.049 Uiso 1 1 calc R U . . .
C61 C 0.1568(5) 0.0676(6) 1.04099(13) 0.0470(16) Uani 1 1 d . . . . .
H61 H 0.1444 0.0578 1.0616 0.056 Uiso 1 1 calc R U . . .
C62 C 0.1310(5) -0.0094(5) 1.02118(14) 0.0467(15) Uani 1 1 d . . . . .
H62 H 0.0984 -0.0714 1.0279 0.056 Uiso 1 1 calc R U . . .
C63 C 0.1526(5) 0.0039(5) 0.99133(13) 0.0428(14) Uani 1 1 d . . . . .
H63 H 0.1352 -0.0495 0.9776 0.051 Uiso 1 1 calc R U . . .
C64 C 0.1989(5) 0.0935(5) 0.98139(12) 0.0394(13) Uani 1 1 d . . . . .
H64 H 0.2143 0.1016 0.9609 0.047 Uiso 1 1 calc R U . . .
C65 C 0.4370(4) 0.2625(4) 0.99679(11) 0.0290(11) Uani 1 1 d . . . . .
C66 C 0.5072(5) 0.3375(5) 1.00840(11) 0.0330(12) Uani 1 1 d . . . . .
H66 H 0.4796 0.4045 1.0123 0.040 Uiso 1 1 calc R U . . .
C67 C 0.6181(5) 0.3142(5) 1.01435(12) 0.0375(13) Uani 1 1 d . . . . .
H67 H 0.6661 0.3653 1.0225 0.045 Uiso 1 1 calc R U . . .
C68 C 0.6589(5) 0.2175(5) 1.00851(13) 0.0400(13) Uani 1 1 d . . . . .
H68 H 0.7347 0.2021 1.0126 0.048 Uiso 1 1 calc R U . . .
C69 C 0.5896(5) 0.1429(5) 0.99670(13) 0.0404(14) Uani 1 1 d . . . . .
H69 H 0.6179 0.0763 0.9927 0.048 Uiso 1 1 calc R U . . .
C70 C 0.4791(5) 0.1649(5) 0.99072(12) 0.0353(12) Uani 1 1 d . . . . .
H70 H 0.4318 0.1136 0.9825 0.042 Uiso 1 1 calc R U . . .
C71 C 0.6796(5) 0.3600(5) 0.93413(14) 0.0433(15) Uani 1 1 d . . . . .
H71 H 0.6764 0.3950 0.9539 0.052 Uiso 1 1 calc R U . . .
C72 C 0.6519(5) 0.4230(5) 0.91059(15) 0.0460(16) Uani 1 1 d . . . . .
H72 H 0.6335 0.4951 0.9163 0.055 Uiso 1 1 calc R U . . .
C73 C 0.7027(6) 0.4125(6) 0.87990(16) 0.0559(18) Uani 1 1 d . . . . .
H73A H 0.6661 0.4618 0.8662 0.067 Uiso 1 1 calc R U . . .
H73B H 0.7825 0.4308 0.8813 0.067 Uiso 1 1 calc R U . . .
C74 C 0.6917(7) 0.3058(6) 0.86717(16) 0.062(2) Uani 1 1 d . . . . .
H74A H 0.7617 0.2677 0.8709 0.074 Uiso 1 1 calc R U . . .
H74B H 0.6802 0.3107 0.8454 0.074 Uiso 1 1 calc R U . . .
C75 C 0.5955(5) 0.2459(5) 0.88042(13) 0.0384(13) Uani 1 1 d . . . . .
H75 H 0.5413 0.2176 0.8655 0.046 Uiso 1 1 calc R U . . .
C76 C 0.6110(5) 0.1852(5) 0.90549(12) 0.0374(13) Uani 1 1 d . . . . .
H76 H 0.5642 0.1218 0.9053 0.045 Uiso 1 1 calc R U . . .
C77 C 0.7173(6) 0.1730(6) 0.92303(17) 0.0585(19) Uani 1 1 d . . . . .
H77A H 0.7723 0.1367 0.9107 0.070 Uiso 1 1 calc R U . . .
H77B H 0.7034 0.1301 0.9407 0.070 Uiso 1 1 calc R U . . .
C78 C 0.7654(5) 0.2756(6) 0.93294(15) 0.0490(16) Uani 1 1 d . . . . .
H78A H 0.8001 0.2674 0.9529 0.059 Uiso 1 1 calc R U . . .
H78B H 0.8243 0.2961 0.9191 0.059 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 2.019(5) . ?
Rh1 P1 2.3229(13) . ?
Rh1 P2 2.3293(13) . ?
Rh1 Cl3 2.3327(13) . ?
Rh1 Cl1 2.3620(13) . ?
Rh1 Cl2 2.5263(13) . ?
Rh2 C33 2.095(5) . ?
Rh2 C37 2.094(5) . ?
Rh2 C38 2.099(5) . ?
Rh2 C34 2.101(5) . ?
Rh2 Cl1 2.4019(13) . ?
Rh2 Cl2 2.4247(13) . ?
Rh3 C41 2.009(5) . ?
Rh3 P3 2.3068(14) . ?
Rh3 P4 2.3131(13) . ?
Rh3 Cl6 2.3330(15) . ?
Rh3 Cl4 2.3909(14) . ?
Rh3 Cl5 2.5237(12) . ?
Rh4 C76 2.089(5) . ?
Rh4 C75 2.091(5) . ?
Rh4 C72 2.097(6) . ?
Rh4 C71 2.102(6) . ?
Rh4 Cl4 2.4142(12) . ?
Rh4 Cl5 2.4178(13) . ?
S1 C2 1.785(5) . ?
S1 P1 2.0847(19) . ?
S2 C6 1.782(5) . ?
S2 P2 2.080(2) . ?
S3 C42 1.777(5) . ?
S3 P3 2.083(2) . ?
S4 C46 1.776(6) . ?
S4 P4 2.0814(19) . ?
P1 C7 1.812(5) . ?
P1 C13 1.835(5) . ?
P2 C25 1.815(6) . ?
P2 C19 1.828(5) . ?
P3 C47 1.815(6) . ?
P3 C53 1.832(6) . ?
P4 C59 1.821(6) . ?
P4 C65 1.831(5) . ?
C1 C6 1.397(7) . ?
C1 C2 1.411(7) . ?
C2 C3 1.374(8) . ?
C3 C4 1.375(8) . ?
C3 H3 0.9500 . ?
C4 C5 1.373(8) . ?
C4 H4 0.9500 . ?
C5 C6 1.386(8) . ?
C5 H5 0.9500 . ?
C7 C12 1.379(8) . ?
C7 C8 1.405(8) . ?
C8 C9 1.381(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.373(9) . ?
C9 H9 0.9500 . ?
C10 C11 1.384(9) . ?
C10 H10 0.9500 . ?
C11 C12 1.391(8) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.384(8) . ?
C13 C14 1.385(8) . ?
C14 C15 1.389(8) . ?
C14 H14 0.9500 . ?
C15 C16 1.384(9) . ?
C15 H15 0.9500 . ?
C16 C17 1.385(9) . ?
C16 H16 0.9500 . ?
C17 C18 1.385(8) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C24 1.375(8) . ?
C19 C20 1.400(8) . ?
C20 C21 1.387(8) . ?
C20 H20 0.9500 . ?
C21 C22 1.355(9) . ?
C21 H21 0.9500 . ?
C22 C23 1.363(9) . ?
C22 H22 0.9500 . ?
C23 C24 1.403(9) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.388(9) . ?
C25 C30 1.408(9) . ?
C26 C27 1.384(10) . ?
C26 H26 0.9500 . ?
C27 C28 1.358(12) . ?
C27 H27 0.9500 . ?
C28 C29 1.380(12) . ?
C28 H28 0.9500 . ?
C29 C30 1.393(9) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C38 1.510(7) . ?
C31 C32 1.523(8) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C33 1.499(8) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C34 1.404(8) . ?
C33 H33 1.0000 . ?
C34 C35 1.524(8) . ?
C34 H34 1.0000 . ?
C35 C36 1.534(8) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 C37 1.508(7) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C37 C38 1.385(8) . ?
C37 H37 1.0000 . ?
C38 H38 1.0000 . ?
C41 C42 1.407(8) . ?
C41 C46 1.413(7) . ?
C42 C43 1.403(8) . ?
C43 C44 1.386(8) . ?
C43 H43 0.9500 . ?
C44 C45 1.366(8) . ?
C44 H44 0.9500 . ?
C45 C46 1.395(8) . ?
C45 H45 0.9500 . ?
C47 C48 1.383(9) . ?
C47 C52 1.389(8) . ?
C48 C49 1.386(9) . ?
C48 H48 0.9500 . ?
C49 C50 1.379(10) . ?
C49 H49 0.9500 . ?
C50 C51 1.377(10) . ?
C50 H50 0.9500 . ?
C51 C52 1.382(9) . ?
C51 H51 0.9500 . ?
C52 H52 0.9500 . ?
C53 C58 1.366(8) . ?
C53 C54 1.385(8) . ?
C54 C55 1.390(9) . ?
C54 H54 0.9500 . ?
C55 C56 1.367(9) . ?
C55 H55 0.9500 . ?
C56 C57 1.348(8) . ?
C56 H56 0.9500 . ?
C57 C58 1.396(8) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C59 C60 1.389(8) . ?
C59 C64 1.393(8) . ?
C60 C61 1.374(9) . ?
C60 H60 0.9500 . ?
C61 C62 1.373(10) . ?
C61 H61 0.9500 . ?
C62 C63 1.383(9) . ?
C62 H62 0.9500 . ?
C63 C64 1.371(9) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C65 C66 1.386(8) . ?
C65 C70 1.396(8) . ?
C66 C67 1.392(8) . ?
C66 H66 0.9500 . ?
C67 C68 1.378(9) . ?
C67 H67 0.9500 . ?
C68 C69 1.380(9) . ?
C68 H68 0.9500 . ?
C69 C70 1.383(8) . ?
C69 H69 0.9500 . ?
C70 H70 0.9500 . ?
C71 C72 1.377(9) . ?
C71 C78 1.509(9) . ?
C71 H71 1.0000 . ?
C72 C73 1.526(9) . ?
C72 H72 1.0000 . ?
C73 C74 1.507(10) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 C75 1.527(9) . ?
C74 H74A 0.9900 . ?
C74 H74B 0.9900 . ?
C75 C76 1.387(8) . ?
C75 H75 1.0000 . ?
C76 C77 1.501(8) . ?
C76 H76 1.0000 . ?
C77 C78 1.520(10) . ?
C77 H77A 0.9900 . ?
C77 H77B 0.9900 . ?
C78 H78A 0.9900 . ?
C78 H78B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 P1 88.42(15) . . ?
C1 Rh1 P2 88.25(15) . . ?
P1 Rh1 P2 176.67(5) . . ?
C1 Rh1 Cl3 88.71(15) . . ?
P1 Rh1 Cl3 88.99(5) . . ?
P2 Rh1 Cl3 90.95(5) . . ?
C1 Rh1 Cl1 89.56(15) . . ?
P1 Rh1 Cl1 92.50(5) . . ?
P2 Rh1 Cl1 87.46(5) . . ?
Cl3 Rh1 Cl1 177.68(5) . . ?
C1 Rh1 Cl2 175.24(15) . . ?
P1 Rh1 Cl2 90.20(4) . . ?
P2 Rh1 Cl2 93.11(5) . . ?
Cl3 Rh1 Cl2 95.82(4) . . ?
Cl1 Rh1 Cl2 85.95(4) . . ?
C33 Rh2 C37 98.8(2) . . ?
C33 Rh2 C38 81.8(2) . . ?
C37 Rh2 C38 38.6(2) . . ?
C33 Rh2 C34 39.1(2) . . ?
C37 Rh2 C34 82.0(2) . . ?
C38 Rh2 C34 90.1(2) . . ?
C33 Rh2 Cl1 165.34(16) . . ?
C37 Rh2 Cl1 87.91(16) . . ?
C38 Rh2 Cl1 95.83(15) . . ?
C34 Rh2 Cl1 155.54(16) . . ?
C33 Rh2 Cl2 89.14(16) . . ?
C37 Rh2 Cl2 164.97(16) . . ?
C38 Rh2 Cl2 156.32(16) . . ?
C34 Rh2 Cl2 96.64(17) . . ?
Cl1 Rh2 Cl2 87.40(4) . . ?
C41 Rh3 P3 88.76(16) . . ?
C41 Rh3 P4 88.46(16) . . ?
P3 Rh3 P4 176.57(5) . . ?
C41 Rh3 Cl6 88.70(15) . . ?
P3 Rh3 Cl6 85.56(5) . . ?
P4 Rh3 Cl6 92.36(5) . . ?
C41 Rh3 Cl4 91.12(15) . . ?
P3 Rh3 Cl4 93.68(5) . . ?
P4 Rh3 Cl4 88.39(5) . . ?
Cl6 Rh3 Cl4 179.22(5) . . ?
C41 Rh3 Cl5 174.51(15) . . ?
P3 Rh3 Cl5 91.34(4) . . ?
P4 Rh3 Cl5 91.62(4) . . ?
Cl6 Rh3 Cl5 96.78(5) . . ?
Cl4 Rh3 Cl5 83.40(4) . . ?
C76 Rh4 C75 38.8(2) . . ?
C76 Rh4 C72 97.2(2) . . ?
C75 Rh4 C72 82.2(2) . . ?
C76 Rh4 C71 81.5(2) . . ?
C75 Rh4 C71 91.3(2) . . ?
C72 Rh4 C71 38.3(3) . . ?
C76 Rh4 Cl4 164.58(17) . . ?
C75 Rh4 Cl4 156.37(18) . . ?
C72 Rh4 Cl4 90.90(17) . . ?
C71 Rh4 Cl4 97.25(17) . . ?
C76 Rh4 Cl5 89.41(18) . . ?
C75 Rh4 Cl5 96.64(17) . . ?
C72 Rh4 Cl5 167.5(2) . . ?
C71 Rh4 Cl5 154.11(19) . . ?
Cl4 Rh4 Cl5 85.21(4) . . ?
Rh1 Cl1 Rh2 95.52(4) . . ?
Rh2 Cl2 Rh1 90.83(4) . . ?
Rh3 Cl4 Rh4 97.47(5) . . ?
Rh4 Cl5 Rh3 93.90(4) . . ?
C2 S1 P1 99.18(18) . . ?
C6 S2 P2 99.40(19) . . ?
C42 S3 P3 99.40(19) . . ?
C46 S4 P4 99.06(18) . . ?
C7 P1 C13 103.0(2) . . ?
C7 P1 S1 101.57(18) . . ?
C13 P1 S1 106.15(18) . . ?
C7 P1 Rh1 123.06(18) . . ?
C13 P1 Rh1 116.88(17) . . ?
S1 P1 Rh1 104.12(7) . . ?
C25 P2 C19 100.1(2) . . ?
C25 P2 S2 106.9(2) . . ?
C19 P2 S2 103.4(2) . . ?
C25 P2 Rh1 119.05(19) . . ?
C19 P2 Rh1 121.56(18) . . ?
S2 P2 Rh1 104.27(7) . . ?
C47 P3 C53 103.3(2) . . ?
C47 P3 S3 106.3(2) . . ?
C53 P3 S3 103.58(19) . . ?
C47 P3 Rh3 116.21(18) . . ?
C53 P3 Rh3 121.19(18) . . ?
S3 P3 Rh3 104.81(7) . . ?
C59 P4 C65 101.9(2) . . ?
C59 P4 S4 106.33(18) . . ?
C65 P4 S4 103.74(18) . . ?
C59 P4 Rh3 119.55(17) . . ?
C65 P4 Rh3 118.87(16) . . ?
S4 P4 Rh3 104.90(7) . . ?
C6 C1 C2 114.4(5) . . ?
C6 C1 Rh1 122.9(4) . . ?
C2 C1 Rh1 122.8(4) . . ?
C3 C2 C1 122.7(5) . . ?
C3 C2 S1 114.4(4) . . ?
C1 C2 S1 122.9(4) . . ?
C2 C3 C4 120.8(5) . . ?
C2 C3 H3 119.6 . . ?
C4 C3 H3 119.6 . . ?
C5 C4 C3 118.7(5) . . ?
C5 C4 H4 120.7 . . ?
C3 C4 H4 120.7 . . ?
C4 C5 C6 120.3(5) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C5 C6 C1 123.1(5) . . ?
C5 C6 S2 113.4(4) . . ?
C1 C6 S2 123.6(4) . . ?
C12 C7 C8 118.8(5) . . ?
C12 C7 P1 122.7(4) . . ?
C8 C7 P1 118.5(4) . . ?
C9 C8 C7 120.4(6) . . ?
C9 C8 H8 119.8 . . ?
C7 C8 H8 119.8 . . ?
C10 C9 C8 120.1(6) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C9 C10 C11 120.2(6) . . ?
C9 C10 H10 119.9 . . ?
C11 C10 H10 119.9 . . ?
C10 C11 C12 119.9(6) . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C7 C12 C11 120.5(6) . . ?
C7 C12 H12 119.7 . . ?
C11 C12 H12 119.7 . . ?
C18 C13 C14 119.8(5) . . ?
C18 C13 P1 119.9(4) . . ?
C14 C13 P1 120.3(4) . . ?
C13 C14 C15 120.3(6) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 H14 119.9 . . ?
C16 C15 C14 119.6(6) . . ?
C16 C15 H15 120.2 . . ?
C14 C15 H15 120.2 . . ?
C15 C16 C17 120.2(6) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 H16 119.9 . . ?
C18 C17 C16 120.0(6) . . ?
C18 C17 H17 120.0 . . ?
C16 C17 H17 120.0 . . ?
C13 C18 C17 120.2(6) . . ?
C13 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C24 C19 C20 117.8(5) . . ?
C24 C19 P2 123.1(5) . . ?
C20 C19 P2 119.0(4) . . ?
C21 C20 C19 120.9(6) . . ?
C21 C20 H20 119.6 . . ?
C19 C20 H20 119.6 . . ?
C22 C21 C20 120.3(6) . . ?
C22 C21 H21 119.8 . . ?
C20 C21 H21 119.8 . . ?
C21 C22 C23 120.1(6) . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 C24 120.4(6) . . ?
C22 C23 H23 119.8 . . ?
C24 C23 H23 119.8 . . ?
C19 C24 C23 120.5(6) . . ?
C19 C24 H24 119.8 . . ?
C23 C24 H24 119.8 . . ?
C26 C25 C30 119.2(6) . . ?
C26 C25 P2 122.4(5) . . ?
C30 C25 P2 118.1(5) . . ?
C27 C26 C25 120.1(7) . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C28 C27 C26 120.2(8) . . ?
C28 C27 H27 119.9 . . ?
C26 C27 H27 119.9 . . ?
C27 C28 C29 121.7(7) . . ?
C27 C28 H28 119.1 . . ?
C29 C28 H28 119.1 . . ?
C28 C29 C30 118.9(8) . . ?
C28 C29 H29 120.5 . . ?
C30 C29 H29 120.5 . . ?
C29 C30 C25 119.8(7) . . ?
C29 C30 H30 120.1 . . ?
C25 C30 H30 120.1 . . ?
C38 C31 C32 111.6(5) . . ?
C38 C31 H31A 109.3 . . ?
C32 C31 H31A 109.3 . . ?
C38 C31 H31B 109.3 . . ?
C32 C31 H31B 109.3 . . ?
H31A C31 H31B 108.0 . . ?
C33 C32 C31 112.6(5) . . ?
C33 C32 H32A 109.1 . . ?
C31 C32 H32A 109.1 . . ?
C33 C32 H32B 109.1 . . ?
C31 C32 H32B 109.1 . . ?
H32A C32 H32B 107.8 . . ?
C34 C33 C32 124.7(5) . . ?
C34 C33 Rh2 70.7(3) . . ?
C32 C33 Rh2 111.1(4) . . ?
C34 C33 H33 114.1 . . ?
C32 C33 H33 114.1 . . ?
Rh2 C33 H33 114.1 . . ?
C33 C34 C35 124.5(5) . . ?
C33 C34 Rh2 70.2(3) . . ?
C35 C34 Rh2 113.8(4) . . ?
C33 C34 H34 113.6 . . ?
C35 C34 H34 113.6 . . ?
Rh2 C34 H34 113.6 . . ?
C34 C35 C36 111.7(5) . . ?
C34 C35 H35A 109.3 . . ?
C36 C35 H35A 109.3 . . ?
C34 C35 H35B 109.3 . . ?
C36 C35 H35B 109.3 . . ?
H35A C35 H35B 107.9 . . ?
C37 C36 C35 112.0(5) . . ?
C37 C36 H36A 109.2 . . ?
C35 C36 H36A 109.2 . . ?
C37 C36 H36B 109.2 . . ?
C35 C36 H36B 109.2 . . ?
H36A C36 H36B 107.9 . . ?
C38 C37 C36 125.3(5) . . ?
C38 C37 Rh2 70.9(3) . . ?
C36 C37 Rh2 111.6(4) . . ?
C38 C37 H37 113.8 . . ?
C36 C37 H37 113.8 . . ?
Rh2 C37 H37 113.8 . . ?
C37 C38 C31 124.3(5) . . ?
C37 C38 Rh2 70.5(3) . . ?
C31 C38 Rh2 113.9(4) . . ?
C37 C38 H38 113.6 . . ?
C31 C38 H38 113.6 . . ?
Rh2 C38 H38 113.6 . . ?
C42 C41 C46 114.2(5) . . ?
C42 C41 Rh3 123.0(4) . . ?
C46 C41 Rh3 122.9(4) . . ?
C43 C42 C41 123.5(5) . . ?
C43 C42 S3 113.2(4) . . ?
C41 C42 S3 123.2(4) . . ?
C44 C43 C42 119.4(6) . . ?
C44 C43 H43 120.3 . . ?
C42 C43 H43 120.3 . . ?
C45 C44 C43 119.2(5) . . ?
C45 C44 H44 120.4 . . ?
C43 C44 H44 120.4 . . ?
C44 C45 C46 121.1(5) . . ?
C44 C45 H45 119.5 . . ?
C46 C45 H45 119.5 . . ?
C45 C46 C41 122.5(5) . . ?
C45 C46 S4 114.1(4) . . ?
C41 C46 S4 123.4(4) . . ?
C48 C47 C52 119.3(6) . . ?
C48 C47 P3 120.7(5) . . ?
C52 C47 P3 119.6(5) . . ?
C47 C48 C49 120.3(6) . . ?
C47 C48 H48 119.9 . . ?
C49 C48 H48 119.9 . . ?
C50 C49 C48 120.3(6) . . ?
C50 C49 H49 119.9 . . ?
C48 C49 H49 119.9 . . ?
C51 C50 C49 119.5(6) . . ?
C51 C50 H50 120.2 . . ?
C49 C50 H50 120.2 . . ?
C50 C51 C52 120.7(7) . . ?
C50 C51 H51 119.7 . . ?
C52 C51 H51 119.7 . . ?
C51 C52 C47 120.0(6) . . ?
C51 C52 H52 120.0 . . ?
C47 C52 H52 120.0 . . ?
C58 C53 C54 119.2(5) . . ?
C58 C53 P3 120.1(4) . . ?
C54 C53 P3 120.7(5) . . ?
C53 C54 C55 119.7(6) . . ?
C53 C54 H54 120.2 . . ?
C55 C54 H54 120.2 . . ?
C56 C55 C54 120.3(6) . . ?
C56 C55 H55 119.9 . . ?
C54 C55 H55 119.9 . . ?
C57 C56 C55 120.3(6) . . ?
C57 C56 H56 119.9 . . ?
C55 C56 H56 119.9 . . ?
C56 C57 C58 120.2(6) . . ?
C56 C57 H57 119.9 . . ?
C58 C57 H57 119.9 . . ?
C53 C58 C57 120.3(6) . . ?
C53 C58 H58 119.8 . . ?
C57 C58 H58 119.8 . . ?
C60 C59 C64 118.8(5) . . ?
C60 C59 P4 121.1(4) . . ?
C64 C59 P4 120.0(4) . . ?
C61 C60 C59 120.5(6) . . ?
C61 C60 H60 119.7 . . ?
C59 C60 H60 119.7 . . ?
C62 C61 C60 120.3(6) . . ?
C62 C61 H61 119.9 . . ?
C60 C61 H61 119.9 . . ?
C61 C62 C63 119.7(6) . . ?
C61 C62 H62 120.2 . . ?
C63 C62 H62 120.2 . . ?
C64 C63 C62 120.5(6) . . ?
C64 C63 H63 119.8 . . ?
C62 C63 H63 119.8 . . ?
C63 C64 C59 120.1(5) . . ?
C63 C64 H64 119.9 . . ?
C59 C64 H64 119.9 . . ?
C66 C65 C70 119.5(5) . . ?
C66 C65 P4 121.6(4) . . ?
C70 C65 P4 118.9(4) . . ?
C65 C66 C67 119.7(5) . . ?
C65 C66 H66 120.1 . . ?
C67 C66 H66 120.1 . . ?
C68 C67 C66 120.4(6) . . ?
C68 C67 H67 119.8 . . ?
C66 C67 H67 119.8 . . ?
C69 C68 C67 120.1(5) . . ?
C69 C68 H68 120.0 . . ?
C67 C68 H68 120.0 . . ?
C68 C69 C70 120.1(6) . . ?
C68 C69 H69 119.9 . . ?
C70 C69 H69 119.9 . . ?
C69 C70 C65 120.1(6) . . ?
C69 C70 H70 119.9 . . ?
C65 C70 H70 119.9 . . ?
C72 C71 C78 124.3(6) . . ?
C72 C71 Rh4 70.7(3) . . ?
C78 C71 Rh4 113.9(4) . . ?
C72 C71 H71 113.6 . . ?
C78 C71 H71 113.6 . . ?
Rh4 C71 H71 113.6 . . ?
C71 C72 C73 123.2(6) . . ?
C71 C72 Rh4 71.1(3) . . ?
C73 C72 Rh4 111.9(4) . . ?
C71 C72 H72 114.3 . . ?
C73 C72 H72 114.3 . . ?
Rh4 C72 H72 114.3 . . ?
C74 C73 C72 113.1(5) . . ?
C74 C73 H73A 109.0 . . ?
C72 C73 H73A 109.0 . . ?
C74 C73 H73B 109.0 . . ?
C72 C73 H73B 109.0 . . ?
H73A C73 H73B 107.8 . . ?
C73 C74 C75 112.6(5) . . ?
C73 C74 H74A 109.1 . . ?
C75 C74 H74A 109.1 . . ?
C73 C74 H74B 109.1 . . ?
C75 C74 H74B 109.1 . . ?
H74A C74 H74B 107.8 . . ?
C76 C75 C74 121.1(6) . . ?
C76 C75 Rh4 70.5(3) . . ?
C74 C75 Rh4 114.2(4) . . ?
C76 C75 H75 114.6 . . ?
C74 C75 H75 114.6 . . ?
Rh4 C75 H75 114.6 . . ?
C75 C76 C77 126.2(6) . . ?
C75 C76 Rh4 70.7(3) . . ?
C77 C76 Rh4 113.0(4) . . ?
C75 C76 H76 113.2 . . ?
C77 C76 H76 113.2 . . ?
Rh4 C76 H76 113.2 . . ?
C76 C77 C78 112.2(6) . . ?
C76 C77 H77A 109.2 . . ?
C78 C77 H77A 109.2 . . ?
C76 C77 H77B 109.2 . . ?
C78 C77 H77B 109.2 . . ?
H77A C77 H77B 107.9 . . ?
C71 C78 C77 113.1(5) . . ?
C71 C78 H78A 109.0 . . ?
C77 C78 H78A 109.0 . . ?
C71 C78 H78B 109.0 . . ?
C77 C78 H78B 109.0 . . ?
H78A C78 H78B 107.8 . . ?

_refine_diff_density_max         1.179
_refine_diff_density_min         -0.608
_refine_diff_density_rms         0.115

_shelxl_version_number           2014-3

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ax1481absn
_database_code_depnum_ccdc_archive 'CCDC 1837751'
_audit_update_record             
;
2018-04-17 deposited with the CCDC.
2018-05-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H56 Cl2 O2 P2 Rh2'
_chemical_formula_weight         835.44

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'
'x-1/2, y, -z-1/2'

_cell_length_a                   16.0812(7)
_cell_length_b                   15.1354(7)
_cell_length_c                   29.4358(13)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     7164.5(6)
_cell_formula_units_Z            8
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    9917
_cell_measurement_theta_min      2.31
_cell_measurement_theta_max      29.86

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.549
_exptl_crystal_F_000             3440
_exptl_crystal_size_max          0.331
_exptl_crystal_size_mid          0.145
_exptl_crystal_size_min          0.130
_exptl_absorpt_coefficient_mu    1.189
_shelx_estimated_absorpt_T_min   0.694
_shelx_estimated_absorpt_T_max   0.861
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.69
_exptl_absorpt_correction_T_max  0.86
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            68470
_diffrn_reflns_av_unetI/netI     0.0296
_diffrn_reflns_av_R_equivalents  0.0529
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_theta_min         1.384
_diffrn_reflns_theta_max         27.996
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             8637
_reflns_number_gt                6882
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_reduction        'SAINT (Bruker, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0352P)²+9.6888P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8637
_refine_ls_number_parameters     387
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0467
_refine_ls_R_factor_gt           0.0327
_refine_ls_wR_factor_ref         0.0826
_refine_ls_wR_factor_gt          0.0744
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.11500(2) 0.45419(2) 0.19605(2) 0.02138(6) Uani 1 1 d . . . . .
Rh2 Rh 0.62409(2) 0.29734(2) 0.09420(2) 0.01796(6) Uani 1 1 d . . . . .
Cl1 Cl -0.02595(5) 0.49097(6) 0.20435(3) 0.03688(18) Uani 1 1 d . . . . .
Cl2 Cl 0.66121(4) 0.44406(5) 0.07534(3) 0.02705(15) Uani 1 1 d . . . . .
P1 P 0.08002(4) 0.34793(5) 0.14595(2) 0.02105(15) Uani 1 1 d . . . . .
P2 P 0.48770(4) 0.33176(5) 0.09005(2) 0.01744(14) Uani 1 1 d . . . . .
O1 O 0.15172(12) 0.27053(13) 0.14013(6) 0.0222(4) Uani 1 1 d . . . . .
O2 O 0.43092(11) 0.24153(13) 0.08647(7) 0.0214(4) Uani 1 1 d . . . . .
C1 C 0.20514(16) 0.24722(18) 0.10539(9) 0.0189(5) Uani 1 1 d . . . . .
C2 C 0.28918(16) 0.26125(17) 0.11248(9) 0.0190(5) Uani 1 1 d . . . . .
H2 H 0.3079 0.2902 0.1392 0.023 Uiso 1 1 calc R U . . .
C3 C 0.34580(16) 0.23249(18) 0.08002(9) 0.0188(5) Uani 1 1 d . . . . .
C4 C 0.31910(18) 0.18789(19) 0.04167(10) 0.0246(6) Uani 1 1 d . . . . .
H4 H 0.3581 0.1676 0.0198 0.030 Uiso 1 1 calc R U . . .
C5 C 0.23458(18) 0.1730(2) 0.03550(10) 0.0263(6) Uani 1 1 d . . . . .
H5 H 0.2158 0.1421 0.0093 0.032 Uiso 1 1 calc R U . . .
C6 C 0.17729(17) 0.2030(2) 0.06727(10) 0.0247(6) Uani 1 1 d . . . . .
H6 H 0.1195 0.1932 0.0628 0.030 Uiso 1 1 calc R U . . .
C7 C 0.0547(2) 0.3849(2) 0.08800(11) 0.0313(7) Uani 1 1 d . . . . .
H7 H 0.0525 0.3317 0.0679 0.038 Uiso 1 1 calc R U . . .
C8 C 0.1210(2) 0.4468(3) 0.06970(12) 0.0436(9) Uani 1 1 d . . . . .
H8A H 0.1062 0.4652 0.0388 0.065 Uiso 1 1 calc R U . . .
H8B H 0.1747 0.4162 0.0691 0.065 Uiso 1 1 calc R U . . .
H8C H 0.1250 0.4989 0.0893 0.065 Uiso 1 1 calc R U . . .
C9 C -0.0305(2) 0.4301(3) 0.08673(13) 0.0445(9) Uani 1 1 d . . . . .
H9A H -0.0299 0.4820 0.1066 0.067 Uiso 1 1 calc R U . . .
H9B H -0.0732 0.3886 0.0972 0.067 Uiso 1 1 calc R U . . .
H9C H -0.0430 0.4485 0.0556 0.067 Uiso 1 1 calc R U . . .
C10 C -0.00607(18) 0.2771(2) 0.16414(11) 0.0304(7) Uani 1 1 d . . . . .
H10 H -0.0550 0.3162 0.1702 0.036 Uiso 1 1 calc R U . . .
C11 C -0.0323(2) 0.2095(2) 0.12873(13) 0.0393(8) Uani 1 1 d . . . . .
H11A H 0.0157 0.1733 0.1202 0.059 Uiso 1 1 calc R U . . .
H11B H -0.0537 0.2401 0.1018 0.059 Uiso 1 1 calc R U . . .
H11C H -0.0760 0.1715 0.1414 0.059 Uiso 1 1 calc R U . . .
C12 C 0.0175(2) 0.2332(2) 0.20881(12) 0.0428(9) Uani 1 1 d . . . . .
H12A H -0.0305 0.2009 0.2208 0.064 Uiso 1 1 calc R U . . .
H12B H 0.0346 0.2785 0.2307 0.064 Uiso 1 1 calc R U . . .
H12C H 0.0635 0.1920 0.2037 0.064 Uiso 1 1 calc R U . . .
C13 C 0.45778(17) 0.40055(19) 0.04153(10) 0.0232(6) Uani 1 1 d . . . . .
H13 H 0.4956 0.4530 0.0423 0.028 Uiso 1 1 calc R U . . .
C14 C 0.4786(2) 0.3512(2) -0.00232(10) 0.0333(7) Uani 1 1 d . . . . .
H14A H 0.4415 0.3002 -0.0055 0.050 Uiso 1 1 calc R U . . .
H14B H 0.5364 0.3310 -0.0012 0.050 Uiso 1 1 calc R U . . .
H14C H 0.4711 0.3909 -0.0283 0.050 Uiso 1 1 calc R U . . .
C15 C 0.36941(19) 0.4376(2) 0.04106(11) 0.0286(6) Uani 1 1 d . . . . .
H15A H 0.3621 0.4753 0.0143 0.043 Uiso 1 1 calc R U . . .
H15B H 0.3601 0.4725 0.0686 0.043 Uiso 1 1 calc R U . . .
H15C H 0.3294 0.3888 0.0400 0.043 Uiso 1 1 calc R U . . .
C16 C 0.44875(17) 0.3907(2) 0.14010(10) 0.0237(6) Uani 1 1 d . . . . .
H16 H 0.3875 0.3994 0.1363 0.028 Uiso 1 1 calc R U . . .
C17 C 0.4892(2) 0.4814(2) 0.14400(12) 0.0343(7) Uani 1 1 d . . . . .
H17A H 0.4696 0.5107 0.1717 0.051 Uiso 1 1 calc R U . . .
H17B H 0.4743 0.5172 0.1175 0.051 Uiso 1 1 calc R U . . .
H17C H 0.5498 0.4747 0.1454 0.051 Uiso 1 1 calc R U . . .
C18 C 0.4628(2) 0.3362(3) 0.18313(10) 0.0360(8) Uani 1 1 d . . . . .
H18A H 0.5226 0.3275 0.1878 0.054 Uiso 1 1 calc R U . . .
H18B H 0.4355 0.2786 0.1799 0.054 Uiso 1 1 calc R U . . .
H18C H 0.4393 0.3675 0.2093 0.054 Uiso 1 1 calc R U . . .
C19 C 0.23407(18) 0.4017(2) 0.21017(10) 0.0284(7) Uani 1 1 d . . . . .
H19 H 0.2398 0.3375 0.2028 0.034 Uiso 1 1 calc R U . . .
C20 C 0.23835(18) 0.4572(2) 0.17223(11) 0.0280(6) Uani 1 1 d . . . . .
H20 H 0.2463 0.4247 0.1430 0.034 Uiso 1 1 calc R U . . .
C21 C 0.2695(2) 0.5519(2) 0.17072(13) 0.0396(8) Uani 1 1 d . . . . .
H21A H 0.2485 0.5804 0.1427 0.048 Uiso 1 1 calc R U . . .
H21B H 0.3310 0.5514 0.1691 0.048 Uiso 1 1 calc R U . . .
C22 C 0.2427(2) 0.6067(2) 0.21158(12) 0.0364(8) Uani 1 1 d . . . . .
H22A H 0.2828 0.5976 0.2366 0.044 Uiso 1 1 calc R U . . .
H22B H 0.2439 0.6701 0.2033 0.044 Uiso 1 1 calc R U . . .
C23 C 0.1568(2) 0.5831(2) 0.22788(11) 0.0328(7) Uani 1 1 d . . . . .
H23 H 0.1155 0.6321 0.2251 0.039 Uiso 1 1 calc R U . . .
C24 C 0.1394(2) 0.5239(2) 0.26183(10) 0.0305(7) Uani 1 1 d . . . . .
H24 H 0.0881 0.5381 0.2796 0.037 Uiso 1 1 calc R U . . .
C25 C 0.2005(2) 0.4670(2) 0.28683(11) 0.0367(8) Uani 1 1 d . . . . .
H25A H 0.1697 0.4189 0.3023 0.044 Uiso 1 1 calc R U . . .
H25B H 0.2278 0.5030 0.3106 0.044 Uiso 1 1 calc R U . . .
C26 C 0.2667(2) 0.4266(2) 0.25692(12) 0.0371(8) Uani 1 1 d . . . . .
H26A H 0.2890 0.3731 0.2719 0.044 Uiso 1 1 calc R U . . .
H26B H 0.3130 0.4691 0.2534 0.044 Uiso 1 1 calc R U . . .
C27 C 0.6068(2) 0.1631(2) 0.07877(15) 0.0408(9) Uani 1 1 d . . . . .
H27 H 0.5528 0.1506 0.0631 0.049 Uiso 1 1 calc R U . . .
C28 C 0.5989(2) 0.1737(2) 0.12565(15) 0.0435(10) Uani 1 1 d . . . . .
H28 H 0.5409 0.1671 0.1375 0.052 Uiso 1 1 calc R U . . .
C29 C 0.6665(3) 0.1470(3) 0.15868(18) 0.0684(15) Uani 1 1 d . . . . .
H29A H 0.6401 0.1313 0.1880 0.082 Uiso 1 1 calc R U . . .
H29B H 0.6939 0.0931 0.1469 0.082 Uiso 1 1 calc R U . . .
C30 C 0.7307(2) 0.2138(3) 0.16739(12) 0.0469(10) Uani 1 1 d . . . . .
H30A H 0.7837 0.1830 0.1739 0.056 Uiso 1 1 calc R U . . .
H30B H 0.7150 0.2471 0.1950 0.056 Uiso 1 1 calc R U . . .
C31 C 0.74540(18) 0.2788(2) 0.12951(10) 0.0286(7) Uani 1 1 d . . . . .
H31 H 0.7726 0.3351 0.1393 0.034 Uiso 1 1 calc R U . . .
C32 C 0.75808(17) 0.2578(2) 0.08486(10) 0.0258(6) Uani 1 1 d . . . . .
H32 H 0.7922 0.3020 0.0678 0.031 Uiso 1 1 calc R U . . .
C33 C 0.7623(2) 0.1662(2) 0.06594(14) 0.0434(9) Uani 1 1 d . . . . .
H33A H 0.7986 0.1669 0.0388 0.052 Uiso 1 1 calc R U . . .
H33B H 0.7887 0.1273 0.0888 0.052 Uiso 1 1 calc R U . . .
C34 C 0.6822(2) 0.1281(3) 0.0532(2) 0.0737(16) Uani 1 1 d . . . . .
H34A H 0.6852 0.0634 0.0579 0.088 Uiso 1 1 calc R U . . .
H34B H 0.6735 0.1385 0.0204 0.088 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C20 2.104(3) . ?
Rh1 C19 2.114(3) . ?
Rh1 C24 2.240(3) . ?
Rh1 P1 2.2535(8) . ?
Rh1 C23 2.266(3) . ?
Rh1 Cl1 2.3469(8) . ?
Rh2 C27 2.100(3) . ?
Rh2 C28 2.126(3) . ?
Rh2 C31 2.228(3) . ?
Rh2 C32 2.253(3) . ?
Rh2 P2 2.2576(7) . ?
Rh2 Cl2 2.3656(7) . ?
P1 O1 1.653(2) . ?
P1 C10 1.831(3) . ?
P1 C7 1.841(3) . ?
P2 O2 1.646(2) . ?
P2 C16 1.832(3) . ?
P2 C13 1.832(3) . ?
O1 C1 1.381(3) . ?
O2 C3 1.389(3) . ?
C1 C6 1.381(4) . ?
C1 C2 1.384(4) . ?
C2 C3 1.390(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.383(4) . ?
C4 C5 1.390(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.389(4) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.518(5) . ?
C7 C9 1.532(4) . ?
C7 H7 1.0000 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 C12 1.521(5) . ?
C10 C11 1.521(5) . ?
C10 H10 1.0000 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.528(4) . ?
C13 C15 1.528(4) . ?
C13 H13 1.0000 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.525(4) . ?
C16 C18 1.528(4) . ?
C16 H16 1.0000 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.399(4) . ?
C19 C26 1.520(4) . ?
C19 H19 1.0000 . ?
C20 C21 1.519(4) . ?
C20 H20 1.0000 . ?
C21 C22 1.523(5) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 C23 1.505(5) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C24 1.371(4) . ?
C23 H23 1.0000 . ?
C24 C25 1.499(5) . ?
C24 H24 1.0000 . ?
C25 C26 1.511(5) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.395(6) . ?
C27 C34 1.523(5) . ?
C27 H27 1.0000 . ?
C28 C29 1.514(5) . ?
C28 H28 1.0000 . ?
C29 C30 1.468(5) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.506(4) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.367(4) . ?
C31 H31 1.0000 . ?
C32 C33 1.496(5) . ?
C32 H32 1.0000 . ?
C33 C34 1.459(5) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C20 Rh1 C19 38.74(12) . . ?
C20 Rh1 C24 96.46(12) . . ?
C19 Rh1 C24 81.28(12) . . ?
C20 Rh1 P1 91.88(9) . . ?
C19 Rh1 P1 94.96(8) . . ?
C24 Rh1 P1 161.04(8) . . ?
C20 Rh1 C23 80.75(12) . . ?
C19 Rh1 C23 88.48(12) . . ?
C24 Rh1 C23 35.42(11) . . ?
P1 Rh1 C23 163.54(9) . . ?
C20 Rh1 Cl1 160.05(9) . . ?
C19 Rh1 Cl1 160.63(9) . . ?
C24 Rh1 Cl1 88.15(9) . . ?
P1 Rh1 Cl1 89.79(3) . . ?
C23 Rh1 Cl1 92.26(9) . . ?
C27 Rh2 C28 38.54(16) . . ?
C27 Rh2 C31 95.46(13) . . ?
C28 Rh2 C31 81.55(12) . . ?
C27 Rh2 C32 81.01(12) . . ?
C28 Rh2 C32 90.11(12) . . ?
C31 Rh2 C32 35.53(11) . . ?
C27 Rh2 P2 94.74(9) . . ?
C28 Rh2 P2 92.37(9) . . ?
C31 Rh2 P2 154.81(9) . . ?
C32 Rh2 P2 169.67(8) . . ?
C27 Rh2 Cl2 152.97(12) . . ?
C28 Rh2 Cl2 167.47(12) . . ?
C31 Rh2 Cl2 90.39(8) . . ?
C32 Rh2 Cl2 88.81(8) . . ?
P2 Rh2 Cl2 90.90(3) . . ?
O1 P1 C10 98.21(12) . . ?
O1 P1 C7 105.88(13) . . ?
C10 P1 C7 106.37(15) . . ?
O1 P1 Rh1 113.55(8) . . ?
C10 P1 Rh1 114.53(11) . . ?
C7 P1 Rh1 116.41(11) . . ?
O2 P2 C16 105.39(12) . . ?
O2 P2 C13 106.01(12) . . ?
C16 P2 C13 105.11(14) . . ?
O2 P2 Rh2 110.54(7) . . ?
C16 P2 Rh2 113.63(9) . . ?
C13 P2 Rh2 115.38(9) . . ?
C1 O1 P1 133.75(18) . . ?
C3 O2 P2 129.58(17) . . ?
O1 C1 C6 121.6(2) . . ?
O1 C1 C2 117.2(2) . . ?
C6 C1 C2 120.9(3) . . ?
C1 C2 C3 119.2(3) . . ?
C1 C2 H2 120.4 . . ?
C3 C2 H2 120.4 . . ?
C4 C3 O2 117.7(2) . . ?
C4 C3 C2 120.7(3) . . ?
O2 C3 C2 121.4(2) . . ?
C3 C4 C5 119.3(3) . . ?
C3 C4 H4 120.4 . . ?
C5 C4 H4 120.4 . . ?
C4 C5 C6 120.5(3) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
C1 C6 C5 119.4(3) . . ?
C1 C6 H6 120.3 . . ?
C5 C6 H6 120.3 . . ?
C8 C7 C9 110.2(3) . . ?
C8 C7 P1 111.2(2) . . ?
C9 C7 P1 110.8(2) . . ?
C8 C7 H7 108.2 . . ?
C9 C7 H7 108.2 . . ?
P1 C7 H7 108.2 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C12 C10 C11 111.6(3) . . ?
C12 C10 P1 108.7(2) . . ?
C11 C10 P1 113.8(2) . . ?
C12 C10 H10 107.5 . . ?
C11 C10 H10 107.5 . . ?
P1 C10 H10 107.5 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 C13 C15 112.0(2) . . ?
C14 C13 P2 108.9(2) . . ?
C15 C13 P2 117.4(2) . . ?
C14 C13 H13 105.9 . . ?
C15 C13 H13 105.9 . . ?
P2 C13 H13 105.9 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C17 C16 C18 111.1(3) . . ?
C17 C16 P2 110.7(2) . . ?
C18 C16 P2 110.7(2) . . ?
C17 C16 H16 108.1 . . ?
C18 C16 H16 108.1 . . ?
P2 C16 H16 108.1 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 C26 123.8(3) . . ?
C20 C19 Rh1 70.24(17) . . ?
C26 C19 Rh1 113.4(2) . . ?
C20 C19 H19 113.9 . . ?
C26 C19 H19 113.9 . . ?
Rh1 C19 H19 113.9 . . ?
C19 C20 C21 127.3(3) . . ?
C19 C20 Rh1 71.02(17) . . ?
C21 C20 Rh1 109.9(2) . . ?
C19 C20 H20 113.4 . . ?
C21 C20 H20 113.4 . . ?
Rh1 C20 H20 113.4 . . ?
C20 C21 C22 113.4(3) . . ?
C20 C21 H21A 108.9 . . ?
C22 C21 H21A 108.9 . . ?
C20 C21 H21B 108.9 . . ?
C22 C21 H21B 108.9 . . ?
H21A C21 H21B 107.7 . . ?
C23 C22 C21 112.4(3) . . ?
C23 C22 H22A 109.1 . . ?
C21 C22 H22A 109.1 . . ?
C23 C22 H22B 109.1 . . ?
C21 C22 H22B 109.1 . . ?
H22A C22 H22B 107.8 . . ?
C24 C23 C22 125.1(3) . . ?
C24 C23 Rh1 71.22(18) . . ?
C22 C23 Rh1 110.2(2) . . ?
C24 C23 H23 114.1 . . ?
C22 C23 H23 114.1 . . ?
Rh1 C23 H23 114.1 . . ?
C23 C24 C25 126.8(3) . . ?
C23 C24 Rh1 73.36(18) . . ?
C25 C24 Rh1 105.6(2) . . ?
C23 C24 H24 114.1 . . ?
C25 C24 H24 114.1 . . ?
Rh1 C24 H24 114.1 . . ?
C24 C25 C26 114.1(3) . . ?
C24 C25 H25A 108.7 . . ?
C26 C25 H25A 108.7 . . ?
C24 C25 H25B 108.7 . . ?
C26 C25 H25B 108.7 . . ?
H25A C25 H25B 107.6 . . ?
C25 C26 C19 112.6(3) . . ?
C25 C26 H26A 109.1 . . ?
C19 C26 H26A 109.1 . . ?
C25 C26 H26B 109.1 . . ?
C19 C26 H26B 109.1 . . ?
H26A C26 H26B 107.8 . . ?
C28 C27 C34 126.9(4) . . ?
C28 C27 Rh2 71.75(19) . . ?
C34 C27 Rh2 109.7(2) . . ?
C28 C27 H27 113.5 . . ?
C34 C27 H27 113.5 . . ?
Rh2 C27 H27 113.5 . . ?
C27 C28 C29 122.6(4) . . ?
C27 C28 Rh2 69.71(19) . . ?
C29 C28 Rh2 112.2(2) . . ?
C27 C28 H28 114.7 . . ?
C29 C28 H28 114.7 . . ?
Rh2 C28 H28 114.7 . . ?
C30 C29 C28 115.6(3) . . ?
C30 C29 H29A 108.4 . . ?
C28 C29 H29A 108.4 . . ?
C30 C29 H29B 108.4 . . ?
C28 C29 H29B 108.4 . . ?
H29A C29 H29B 107.4 . . ?
C29 C30 C31 115.5(3) . . ?
C29 C30 H30A 108.4 . . ?
C31 C30 H30A 108.4 . . ?
C29 C30 H30B 108.4 . . ?
C31 C30 H30B 108.4 . . ?
H30A C30 H30B 107.5 . . ?
C32 C31 C30 125.7(3) . . ?
C32 C31 Rh2 73.23(17) . . ?
C30 C31 Rh2 106.9(2) . . ?
C32 C31 H31 114.2 . . ?
C30 C31 H31 114.2 . . ?
Rh2 C31 H31 114.2 . . ?
C31 C32 C33 125.5(3) . . ?
C31 C32 Rh2 71.24(16) . . ?
C33 C32 Rh2 109.5(2) . . ?
C31 C32 H32 114.1 . . ?
C33 C32 H32 114.1 . . ?
Rh2 C32 H32 114.1 . . ?
C34 C33 C32 115.0(3) . . ?
C34 C33 H33A 108.5 . . ?
C32 C33 H33A 108.5 . . ?
C34 C33 H33B 108.5 . . ?
C32 C33 H33B 108.5 . . ?
H33A C33 H33B 107.5 . . ?
C33 C34 C27 116.0(3) . . ?
C33 C34 H34A 108.3 . . ?
C27 C34 H34A 108.3 . . ?
C33 C34 H34B 108.3 . . ?
C27 C34 H34B 108.3 . . ?
H34A C34 H34B 107.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C10 P1 O1 C1 127.8(3) . . . . ?
C7 P1 O1 C1 18.1(3) . . . . ?
Rh1 P1 O1 C1 -110.8(2) . . . . ?
C16 P2 O2 C3 62.1(2) . . . . ?
C13 P2 O2 C3 -49.1(2) . . . . ?
Rh2 P2 O2 C3 -174.77(19) . . . . ?
P1 O1 C1 C6 -74.8(3) . . . . ?
P1 O1 C1 C2 112.1(3) . . . . ?
O1 C1 C2 C3 175.0(2) . . . . ?
C6 C1 C2 C3 1.8(4) . . . . ?
P2 O2 C3 C4 119.2(3) . . . . ?
P2 O2 C3 C2 -65.5(3) . . . . ?
C1 C2 C3 C4 -2.0(4) . . . . ?
C1 C2 C3 O2 -177.1(2) . . . . ?
O2 C3 C4 C5 176.2(3) . . . . ?
C2 C3 C4 C5 0.9(4) . . . . ?
C3 C4 C5 C6 0.4(5) . . . . ?
O1 C1 C6 C5 -173.4(3) . . . . ?
C2 C1 C6 C5 -0.5(4) . . . . ?
C4 C5 C6 C1 -0.6(5) . . . . ?
O1 P1 C7 C8 -77.9(3) . . . . ?
C10 P1 C7 C8 178.3(2) . . . . ?
Rh1 P1 C7 C8 49.4(3) . . . . ?
O1 P1 C7 C9 159.2(2) . . . . ?
C10 P1 C7 C9 55.5(3) . . . . ?
Rh1 P1 C7 C9 -73.5(3) . . . . ?
O1 P1 C10 C12 62.1(2) . . . . ?
C7 P1 C10 C12 171.4(2) . . . . ?
Rh1 P1 C10 C12 -58.6(2) . . . . ?
O1 P1 C10 C11 -62.9(2) . . . . ?
C7 P1 C10 C11 46.4(3) . . . . ?
Rh1 P1 C10 C11 176.4(2) . . . . ?
O2 P2 C13 C14 -62.0(2) . . . . ?
C16 P2 C13 C14 -173.3(2) . . . . ?
Rh2 P2 C13 C14 60.7(2) . . . . ?
O2 P2 C13 C15 66.6(2) . . . . ?
C16 P2 C13 C15 -44.7(3) . . . . ?
Rh2 P2 C13 C15 -170.69(19) . . . . ?
O2 P2 C16 C17 -173.1(2) . . . . ?
C13 P2 C16 C17 -61.3(2) . . . . ?
Rh2 P2 C16 C17 65.7(2) . . . . ?
O2 P2 C16 C18 63.2(2) . . . . ?
C13 P2 C16 C18 175.0(2) . . . . ?
Rh2 P2 C16 C18 -58.0(2) . . . . ?
C26 C19 C20 C21 -4.5(5) . . . . ?
Rh1 C19 C20 C21 101.0(3) . . . . ?
C26 C19 C20 Rh1 -105.5(3) . . . . ?
C19 C20 C21 C22 -40.1(5) . . . . ?
Rh1 C20 C21 C22 40.8(4) . . . . ?
C20 C21 C22 C23 -35.8(4) . . . . ?
C21 C22 C23 C24 94.4(4) . . . . ?
C21 C22 C23 Rh1 13.6(4) . . . . ?
C22 C23 C24 C25 -4.7(5) . . . . ?
Rh1 C23 C24 C25 97.3(3) . . . . ?
C22 C23 C24 Rh1 -101.9(3) . . . . ?
C23 C24 C25 C26 -41.3(5) . . . . ?
Rh1 C24 C25 C26 39.3(3) . . . . ?
C24 C25 C26 C19 -35.6(4) . . . . ?
C20 C19 C26 C25 93.2(4) . . . . ?
Rh1 C19 C26 C25 12.0(4) . . . . ?
C34 C27 C28 C29 -2.7(6) . . . . ?
Rh2 C27 C28 C29 -104.0(3) . . . . ?
C34 C27 C28 Rh2 101.3(4) . . . . ?
C27 C28 C29 C30 86.6(6) . . . . ?
Rh2 C28 C29 C30 7.1(6) . . . . ?
C28 C29 C30 C31 -27.0(6) . . . . ?
C29 C30 C31 C32 -49.6(5) . . . . ?
C29 C30 C31 Rh2 31.6(5) . . . . ?
C30 C31 C32 C33 -2.0(5) . . . . ?
Rh2 C31 C32 C33 -101.1(3) . . . . ?
C30 C31 C32 Rh2 99.0(3) . . . . ?
C31 C32 C33 C34 87.0(5) . . . . ?
Rh2 C32 C33 C34 6.6(5) . . . . ?
C32 C33 C34 C27 -26.7(6) . . . . ?
C28 C27 C34 C33 -47.8(6) . . . . ?
Rh2 C27 C34 C33 33.8(6) . . . . ?

_refine_diff_density_max         1.170
_refine_diff_density_min         -0.850
_refine_diff_density_rms         0.092

_shelxl_version_number           2014-3

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ax1507abs
_database_code_depnum_ccdc_archive 'CCDC 1842313'
_audit_update_record             
;
2018-05-09 deposited with the CCDC.
2018-05-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C78 H76 Cl8 O4 P4 Rh4'
_chemical_formula_weight         1896.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.2267(3)
_cell_length_b                   13.3049(4)
_cell_length_c                   13.5035(4)
_cell_angle_alpha                73.9060(10)
_cell_angle_beta                 69.5690(10)
_cell_angle_gamma                68.3040(10)
_cell_volume                     1884.77(9)
_cell_formula_units_Z            1
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    9932
_cell_measurement_theta_min      3.63
_cell_measurement_theta_max      69.64

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.671
_exptl_crystal_F_000             952
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.135
_exptl_crystal_size_mid          0.116
_exptl_crystal_size_min          0.074
_exptl_absorpt_coefficient_mu    10.766
_shelx_estimated_absorpt_T_min   0.324
_shelx_estimated_absorpt_T_max   0.503
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.30
_exptl_absorpt_correction_T_max  0.50
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   microfocus
_diffrn_radiation_monochromator  multilayer
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean 8.3333
_diffrn_reflns_number            28462
_diffrn_reflns_av_unetI/netI     0.0266
_diffrn_reflns_av_R_equivalents  0.0328
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         3.544
_diffrn_reflns_theta_max         65.082
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.941
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.941
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.941
_reflns_number_total             6417
_reflns_number_gt                5895
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_reduction        'SAINT (Bruker, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0395P)²+2.9988P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6417
_refine_ls_number_parameters     500
_refine_ls_number_restraints     16
_refine_ls_R_factor_all          0.0321
_refine_ls_R_factor_gt           0.0292
_refine_ls_wR_factor_ref         0.0776
_refine_ls_wR_factor_gt          0.0754
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.82962(2) 0.82939(2) 0.73144(2) 0.01994(8) Uani 1 1 d . . . . .
Rh2 Rh 0.81715(2) 0.63204(2) 0.65177(2) 0.02820(8) Uani 1 1 d . . . . .
Cl1 Cl 0.82314(9) 0.81235(7) 0.55982(7) 0.0395(2) Uani 1 1 d . . . . .
Cl2 Cl 0.95602(8) 0.63879(6) 0.73586(7) 0.03458(19) Uani 1 1 d . . . . .
P1 P 0.86971(7) 0.84790(6) 0.86821(6) 0.02176(16) Uani 1 1 d . . . . .
P2 P 0.31357(7) 1.01385(6) 1.27120(6) 0.02081(16) Uani 1 1 d . . . . .
O1 O 0.78169(19) 0.8311(2) 0.99075(18) 0.0317(5) Uani 1 1 d . . . . .
O2 O 0.35683(18) 0.96684(17) 1.15927(17) 0.0242(4) Uani 1 1 d . . . . .
C1 C 0.6667(3) 0.8169(3) 1.0227(2) 0.0242(6) Uani 1 1 d . . . . .
C2 C 0.5718(3) 0.8956(2) 1.0770(2) 0.0228(6) Uani 1 1 d . . . . .
H2 H 0.5857 0.9575 1.0866 0.027 Uiso 1 1 calc R U . . .
C3 C 0.4565(3) 0.8823(2) 1.1170(2) 0.0226(6) Uani 1 1 d . . . . .
C4 C 0.4350(3) 0.7919(3) 1.1042(3) 0.0268(7) Uani 1 1 d . . . . .
H4 H 0.3555 0.7832 1.1322 0.032 Uiso 1 1 calc R U . . .
C5 C 0.5322(3) 0.7149(3) 1.0496(3) 0.0315(7) Uani 1 1 d . . . . .
H5 H 0.5190 0.6524 1.0407 0.038 Uiso 1 1 calc R U . . .
C6 C 0.6491(3) 0.7267(3) 1.0075(3) 0.0304(7) Uani 1 1 d . . . . .
H6 H 0.7149 0.6738 0.9692 0.037 Uiso 1 1 calc R U . . .
C7 C 1.0107(3) 0.7470(2) 0.8934(3) 0.0232(6) Uani 1 1 d . . . . .
C8 C 1.0081(3) 0.6599(3) 0.9778(3) 0.0385(8) Uani 1 1 d . . . . .
H8 H 0.9318 0.6543 1.0262 0.046 Uiso 1 1 calc R U . . .
C9 C 1.1153(4) 0.5811(3) 0.9925(4) 0.0495(10) Uani 1 1 d . . . . .
H9 H 1.1123 0.5208 1.0499 0.059 Uiso 1 1 calc R U . . .
C10 C 1.2270(3) 0.5897(3) 0.9239(4) 0.0447(9) Uani 1 1 d . . . . .
H10 H 1.3009 0.5368 0.9353 0.054 Uiso 1 1 calc R U . . .
C11 C 1.2304(3) 0.6744(3) 0.8399(3) 0.0397(9) Uani 1 1 d . . . . .
H11 H 1.3071 0.6796 0.7919 0.048 Uiso 1 1 calc R U . . .
C12 C 1.1234(3) 0.7533(3) 0.8236(3) 0.0300(7) Uani 1 1 d . . . . .
H12 H 1.1271 0.8118 0.7644 0.036 Uiso 1 1 calc R U . . .
C13 C 0.8946(3) 0.9762(3) 0.8643(3) 0.0286(7) Uani 1 1 d . . . . .
C15 C 0.8860(4) 1.1180(4) 0.9472(4) 0.0525(11) Uani 1 1 d . . . . .
H15 H 0.8623 1.1493 1.0096 0.063 Uiso 1 1 calc R U . . .
C16 C 0.9435(4) 1.1692(3) 0.8499(4) 0.0540(11) Uani 1 1 d . . . . .
H16 H 0.9600 1.2349 0.8456 0.065 Uiso 1 1 calc R U . . .
C17 C 0.9772(4) 1.1249(3) 0.7591(4) 0.0517(11) Uani 1 1 d . . . . .
H17 H 1.0176 1.1596 0.6920 0.062 Uiso 1 1 calc R U . . .
C18 C 0.9519(3) 1.0293(3) 0.7661(3) 0.0368(8) Uani 1 1 d . . . . .
H18 H 0.9740 0.9995 0.7030 0.044 Uiso 1 1 calc R U . . .
C19 C 0.4520(3) 1.0285(3) 1.2808(3) 0.0266(7) Uani 1 1 d . . . . .
C20 C 0.5097(4) 0.9689(4) 1.3594(4) 0.0501(11) Uani 1 1 d . . . . .
H20 H 0.4773 0.9162 1.4135 0.060 Uiso 1 1 calc R U . . .
C21 C 0.6159(5) 0.9858(5) 1.3598(5) 0.0727(16) Uani 1 1 d . . . . .
H21 H 0.6557 0.9442 1.4140 0.087 Uiso 1 1 calc R U . . .
C22 C 0.6625(4) 1.0620(4) 1.2827(5) 0.0606(13) Uani 1 1 d . . . . .
H22 H 0.7353 1.0725 1.2826 0.073 Uiso 1 1 calc R U . . .
C23 C 0.6041(4) 1.1238(3) 1.2049(3) 0.0440(9) Uani 1 1 d . . . . .
H23 H 0.6363 1.1770 1.1513 0.053 Uiso 1 1 calc R U . . .
C24 C 0.4983(3) 1.1080(3) 1.2051(3) 0.0330(7) Uani 1 1 d . . . . .
H24 H 0.4569 1.1521 1.1527 0.040 Uiso 1 1 calc R U . . .
C25 C 0.2849(3) 0.8999(3) 1.3766(3) 0.0248(6) Uani 1 1 d . . . . .
C26 C 0.1721(3) 0.9173(3) 1.4541(3) 0.0299(7) Uani 1 1 d . . . . .
H26 H 0.1123 0.9873 1.4501 0.036 Uiso 1 1 calc R U . . .
C27 C 0.1464(3) 0.8333(3) 1.5367(3) 0.0349(8) Uani 1 1 d . . . . .
H27 H 0.0684 0.8453 1.5880 0.042 Uiso 1 1 calc R U . . .
C28 C 0.2340(4) 0.7320(3) 1.5448(3) 0.0370(8) Uani 1 1 d . . . . .
H28 H 0.2172 0.6751 1.6028 0.044 Uiso 1 1 calc R U . . .
C29 C 0.3461(4) 0.7138(3) 1.4683(3) 0.0387(8) Uani 1 1 d . . . . .
H29 H 0.4061 0.6439 1.4737 0.046 Uiso 1 1 calc R U . . .
C30 C 0.3716(3) 0.7966(3) 1.3838(3) 0.0324(7) Uani 1 1 d . . . . .
H30 H 0.4484 0.7830 1.3308 0.039 Uiso 1 1 calc R U . . .
C31 C 0.8484(11) 0.4637(19) 0.6956(15) 0.047(3) Uani 0.556(10) 1 d D . P A 1
H31 H 0.9166 0.4304 0.7306 0.056 Uiso 0.556(10) 1 calc R U P A 1
C32 C 0.7393(11) 0.5232(10) 0.7676(9) 0.051(3) Uani 0.556(10) 1 d D . P A 1
H32 H 0.7511 0.5169 0.8390 0.061 Uiso 0.556(10) 1 calc R U P A 1
C33 C 0.6068(13) 0.544(2) 0.7742(11) 0.083(5) Uani 0.556(10) 1 d D . P A 1
H33A H 0.5530 0.5927 0.8270 0.099 Uiso 0.556(10) 1 calc R U P A 1
H33B H 0.5876 0.4732 0.7997 0.099 Uiso 0.556(10) 1 calc R U P A 1
C34 C 0.5805(11) 0.5958(12) 0.6658(9) 0.074(3) Uani 0.556(10) 1 d D . P A 1
H34A H 0.5857 0.5371 0.6310 0.089 Uiso 0.556(10) 1 calc R U P A 1
H34B H 0.4954 0.6457 0.6781 0.089 Uiso 0.556(10) 1 calc R U P A 1
C35 C 0.6639(10) 0.6583(12) 0.5913(8) 0.054(3) Uani 0.556(10) 1 d D . P A 1
H35 H 0.6224 0.7368 0.5655 0.065 Uiso 0.556(10) 1 calc R U P A 1
C36 C 0.7792(10) 0.6116(10) 0.5221(10) 0.045(2) Uani 0.556(10) 1 d D . P A 1
H36 H 0.8042 0.6612 0.4535 0.053 Uiso 0.556(10) 1 calc R U P A 1
C37 C 0.8256(11) 0.4912(7) 0.5145(7) 0.047(2) Uani 0.556(10) 1 d D . P A 1
H37A H 0.7568 0.4719 0.5104 0.056 Uiso 0.556(10) 1 calc R U P A 1
H37B H 0.8889 0.4831 0.4450 0.056 Uiso 0.556(10) 1 calc R U P A 1
C38 C 0.8785(12) 0.4062(14) 0.5977(12) 0.077(5) Uani 0.556(10) 1 d D . P A 1
H38A H 0.9682 0.3757 0.5688 0.093 Uiso 0.556(10) 1 calc R U P A 1
H38B H 0.8419 0.3455 0.6205 0.093 Uiso 0.556(10) 1 calc R U P A 1
C31' C 0.8905(13) 0.456(2) 0.6704(19) 0.045(4) Uani 0.444(10) 1 d D . P A 2
H31' H 0.9767 0.4181 0.6742 0.054 Uiso 0.444(10) 1 calc R U P A 2
C32' C 0.7944(14) 0.4841(11) 0.7639(13) 0.049(3) Uani 0.444(10) 1 d D . P A 2
H32' H 0.8227 0.4710 0.8288 0.059 Uiso 0.444(10) 1 calc R U P A 2
C33' C 0.6686(13) 0.4748(12) 0.7884(15) 0.099(7) Uani 0.444(10) 1 d D . P A 2
H33C H 0.6337 0.4604 0.8671 0.118 Uiso 0.444(10) 1 calc R U P A 2
H33D H 0.6748 0.4117 0.7594 0.118 Uiso 0.444(10) 1 calc R U P A 2
C34' C 0.5824(15) 0.5788(18) 0.741(2) 0.115(12) Uani 0.444(10) 1 d D . P A 2
H34C H 0.5252 0.5579 0.7192 0.138 Uiso 0.444(10) 1 calc R U P A 2
H34D H 0.5332 0.6253 0.7965 0.138 Uiso 0.444(10) 1 calc R U P A 2
C35' C 0.6495(13) 0.6444(12) 0.6449(16) 0.084(6) Uani 0.444(10) 1 d D . P A 2
H35' H 0.5985 0.7224 0.6298 0.101 Uiso 0.444(10) 1 calc R U P A 2
C36' C 0.7347(14) 0.6055(11) 0.5502(17) 0.064(6) Uani 0.444(10) 1 d D . P A 2
H36' H 0.7320 0.6626 0.4841 0.077 Uiso 0.444(10) 1 calc R U P A 2
C37' C 0.7684(16) 0.4946(12) 0.5297(17) 0.085(6) Uani 0.444(10) 1 d D . P A 2
H37C H 0.8205 0.4893 0.4552 0.101 Uiso 0.444(10) 1 calc R U P A 2
H37D H 0.6940 0.4755 0.5391 0.101 Uiso 0.444(10) 1 calc R U P A 2
C38' C 0.8366(13) 0.4181(13) 0.6072(15) 0.054(4) Uani 0.444(10) 1 d D . P A 2
H38C H 0.9051 0.3633 0.5668 0.065 Uiso 0.444(10) 1 calc R U P A 2
H38D H 0.7808 0.3780 0.6603 0.065 Uiso 0.444(10) 1 calc R U P A 2
C14 C 0.8619(3) 1.0214(3) 0.9554(3) 0.0394(8) Uani 1 1 d . . . . .
H14 H 0.8232 0.9863 1.0232 0.047 Uiso 1 1 calc R U . . .
C39 C 0.7638(4) 0.5851(4) 0.2389(4) 0.0626(13) Uani 1 1 d . . . . .
H39A H 0.8330 0.5247 0.2598 0.075 Uiso 1 1 calc R U . . .
H39B H 0.7753 0.5886 0.1618 0.075 Uiso 1 1 calc R U . . .
Cl3 Cl 0.76840(17) 0.70812(14) 0.25640(12) 0.0838(4) Uani 1 1 d . . . . .
Cl4 Cl 0.62751(10) 0.55435(10) 0.31268(10) 0.0639(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.1646(8) . ?
Rh1 P2 2.1723(8) 2_677 ?
Rh1 Cl1 2.4210(8) . ?
Rh1 Cl2 2.4301(8) . ?
Rh2 C35' 2.028(13) . ?
Rh2 C32 2.043(10) . ?
Rh2 C36 2.070(12) . ?
Rh2 C31 2.07(2) . ?
Rh2 C36' 2.126(16) . ?
Rh2 C31' 2.15(3) . ?
Rh2 C32' 2.168(12) . ?
Rh2 C35 2.173(11) . ?
Rh2 Cl2 2.3865(8) . ?
Rh2 Cl1 2.3911(9) . ?
P1 O1 1.636(2) . ?
P1 C13 1.825(3) . ?
P1 C7 1.825(3) . ?
P2 O2 1.636(2) . ?
P2 C25 1.815(3) . ?
P2 C19 1.825(3) . ?
P2 Rh1 2.1723(8) 2_677 ?
O1 C1 1.388(4) . ?
O2 C3 1.390(4) . ?
C1 C6 1.373(5) . ?
C1 C2 1.384(4) . ?
C2 C3 1.382(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.389(5) . ?
C4 C5 1.383(5) . ?
C4 H4 0.9500 . ?
C5 C6 1.392(5) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.383(5) . ?
C7 C12 1.389(4) . ?
C8 C9 1.381(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.382(6) . ?
C9 H9 0.9500 . ?
C10 C11 1.361(6) . ?
C10 H10 0.9500 . ?
C11 C12 1.386(5) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.387(5) . ?
C13 C18 1.395(5) . ?
C15 C16 1.377(7) . ?
C15 C14 1.390(6) . ?
C15 H15 0.9500 . ?
C16 C17 1.373(7) . ?
C16 H16 0.9500 . ?
C17 C18 1.389(5) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.376(5) . ?
C19 C24 1.386(5) . ?
C20 C21 1.400(6) . ?
C20 H20 0.9500 . ?
C21 C22 1.366(7) . ?
C21 H21 0.9500 . ?
C22 C23 1.379(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.384(5) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.394(5) . ?
C25 C30 1.394(5) . ?
C26 C27 1.385(5) . ?
C26 H26 0.9500 . ?
C27 C28 1.380(5) . ?
C27 H27 0.9500 . ?
C28 C29 1.381(5) . ?
C28 H28 0.9500 . ?
C29 C30 1.387(5) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C32 1.447(13) . ?
C31 C38 1.575(15) . ?
C31 H31 1.0000 . ?
C32 C33 1.515(14) . ?
C32 H32 1.0000 . ?
C33 C34 1.526(9) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 C35 1.480(14) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.414(13) . ?
C35 H35 1.0000 . ?
C36 C37 1.508(14) . ?
C36 H36 1.0000 . ?
C37 C38 1.490(9) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C31' C32' 1.421(15) . ?
C31' C38' 1.514(17) . ?
C31' H31' 1.0000 . ?
C32' C33' 1.501(14) . ?
C32' H32' 1.0000 . ?
C33' C34' 1.530(10) . ?
C33' H33C 0.9900 . ?
C33' H33D 0.9900 . ?
C34' C35' 1.508(17) . ?
C34' H34C 0.9900 . ?
C34' H34D 0.9900 . ?
C35' C36' 1.424(17) . ?
C35' H35' 1.0000 . ?
C36' C37' 1.46(2) . ?
C36' H36' 1.0000 . ?
C37' C38' 1.489(9) . ?
C37' H37C 0.9900 . ?
C37' H37D 0.9900 . ?
C38' H38C 0.9900 . ?
C38' H38D 0.9900 . ?
C14 H14 0.9500 . ?
C39 Cl3 1.741(6) . ?
C39 Cl4 1.748(5) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 P2 93.19(3) . 2_677 ?
P1 Rh1 Cl1 169.05(3) . . ?
P2 Rh1 Cl1 90.94(3) 2_677 . ?
P1 Rh1 Cl2 93.96(3) . . ?
P2 Rh1 Cl2 167.82(3) 2_677 . ?
Cl1 Rh1 Cl2 83.83(3) . . ?
C32 Rh2 C36 98.8(5) . . ?
C32 Rh2 C31 41.1(4) . . ?
C36 Rh2 C31 83.9(6) . . ?
C35' Rh2 C36' 40.0(5) . . ?
C35' Rh2 C31' 97.3(6) . . ?
C36' Rh2 C31' 81.4(7) . . ?
C35' Rh2 C32' 81.8(6) . . ?
C36' Rh2 C32' 91.6(6) . . ?
C31' Rh2 C32' 38.4(5) . . ?
C32 Rh2 C35 82.1(4) . . ?
C36 Rh2 C35 38.9(4) . . ?
C31 Rh2 C35 94.0(5) . . ?
C35' Rh2 Cl2 154.1(5) . . ?
C32 Rh2 Cl2 99.2(3) . . ?
C36 Rh2 Cl2 151.5(3) . . ?
C31 Rh2 Cl2 95.3(4) . . ?
C36' Rh2 Cl2 165.6(4) . . ?
C31' Rh2 Cl2 90.8(5) . . ?
C32' Rh2 Cl2 89.7(4) . . ?
C35 Rh2 Cl2 167.1(4) . . ?
C35' Rh2 Cl1 98.1(5) . . ?
C32 Rh2 Cl1 153.7(4) . . ?
C36 Rh2 Cl1 88.2(3) . . ?
C31 Rh2 Cl1 164.9(4) . . ?
C36' Rh2 Cl1 95.8(5) . . ?
C31' Rh2 Cl1 152.0(5) . . ?
C32' Rh2 Cl1 168.3(4) . . ?
C35 Rh2 Cl1 87.9(4) . . ?
Cl2 Rh2 Cl1 85.42(3) . . ?
Rh2 Cl1 Rh1 82.42(3) . . ?
Rh2 Cl2 Rh1 82.32(3) . . ?
O1 P1 C13 100.00(15) . . ?
O1 P1 C7 97.12(13) . . ?
C13 P1 C7 101.48(14) . . ?
O1 P1 Rh1 122.90(9) . . ?
C13 P1 Rh1 118.19(11) . . ?
C7 P1 Rh1 113.27(10) . . ?
O2 P2 C25 104.97(13) . . ?
O2 P2 C19 104.55(13) . . ?
C25 P2 C19 104.51(15) . . ?
O2 P2 Rh1 111.71(8) . 2_677 ?
C25 P2 Rh1 119.07(11) . 2_677 ?
C19 P2 Rh1 110.81(11) . 2_677 ?
C1 O1 P1 127.2(2) . . ?
C3 O2 P2 132.3(2) . . ?
C6 C1 C2 121.8(3) . . ?
C6 C1 O1 122.2(3) . . ?
C2 C1 O1 115.9(3) . . ?
C3 C2 C1 118.7(3) . . ?
C3 C2 H2 120.6 . . ?
C1 C2 H2 120.6 . . ?
C2 C3 C4 121.4(3) . . ?
C2 C3 O2 119.7(3) . . ?
C4 C3 O2 118.5(3) . . ?
C5 C4 C3 118.2(3) . . ?
C5 C4 H4 120.9 . . ?
C3 C4 H4 120.9 . . ?
C4 C5 C6 121.7(3) . . ?
C4 C5 H5 119.1 . . ?
C6 C5 H5 119.1 . . ?
C1 C6 C5 118.2(3) . . ?
C1 C6 H6 120.9 . . ?
C5 C6 H6 120.9 . . ?
C8 C7 C12 118.5(3) . . ?
C8 C7 P1 121.4(2) . . ?
C12 C7 P1 120.0(2) . . ?
C9 C8 C7 120.7(3) . . ?
C9 C8 H8 119.6 . . ?
C7 C8 H8 119.6 . . ?
C8 C9 C10 120.1(4) . . ?
C8 C9 H9 119.9 . . ?
C10 C9 H9 119.9 . . ?
C11 C10 C9 119.6(3) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C10 C11 C12 120.8(3) . . ?
C10 C11 H11 119.6 . . ?
C12 C11 H11 119.6 . . ?
C11 C12 C7 120.2(3) . . ?
C11 C12 H12 119.9 . . ?
C7 C12 H12 119.9 . . ?
C14 C13 C18 118.7(3) . . ?
C14 C13 P1 122.7(3) . . ?
C18 C13 P1 118.6(3) . . ?
C16 C15 C14 121.0(4) . . ?
C16 C15 H15 119.5 . . ?
C14 C15 H15 119.5 . . ?
C17 C16 C15 119.9(4) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
C16 C17 C18 119.6(4) . . ?
C16 C17 H17 120.2 . . ?
C18 C17 H17 120.2 . . ?
C17 C18 C13 121.0(4) . . ?
C17 C18 H18 119.5 . . ?
C13 C18 H18 119.5 . . ?
C20 C19 C24 118.8(3) . . ?
C20 C19 P2 124.4(3) . . ?
C24 C19 P2 116.7(3) . . ?
C19 C20 C21 120.2(4) . . ?
C19 C20 H20 119.9 . . ?
C21 C20 H20 119.9 . . ?
C22 C21 C20 120.2(4) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C21 C22 C23 120.1(4) . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 C24 119.7(4) . . ?
C22 C23 H23 120.1 . . ?
C24 C23 H23 120.1 . . ?
C23 C24 C19 120.9(4) . . ?
C23 C24 H24 119.6 . . ?
C19 C24 H24 119.6 . . ?
C26 C25 C30 118.9(3) . . ?
C26 C25 P2 118.4(2) . . ?
C30 C25 P2 122.7(2) . . ?
C27 C26 C25 120.6(3) . . ?
C27 C26 H26 119.7 . . ?
C25 C26 H26 119.7 . . ?
C28 C27 C26 120.1(3) . . ?
C28 C27 H27 119.9 . . ?
C26 C27 H27 119.9 . . ?
C27 C28 C29 119.8(3) . . ?
C27 C28 H28 120.1 . . ?
C29 C28 H28 120.1 . . ?
C28 C29 C30 120.5(3) . . ?
C28 C29 H29 119.8 . . ?
C30 C29 H29 119.8 . . ?
C29 C30 C25 120.1(3) . . ?
C29 C30 H30 120.0 . . ?
C25 C30 H30 120.0 . . ?
C32 C31 C38 136.5(11) . . ?
C32 C31 Rh2 68.3(10) . . ?
C38 C31 Rh2 112.6(14) . . ?
C32 C31 H31 109.9 . . ?
C38 C31 H31 109.9 . . ?
Rh2 C31 H31 109.9 . . ?
C31 C32 C33 128.2(13) . . ?
C31 C32 Rh2 70.6(11) . . ?
C33 C32 Rh2 113.4(8) . . ?
C31 C32 H32 112.4 . . ?
C33 C32 H32 112.4 . . ?
Rh2 C32 H32 112.4 . . ?
C32 C33 C34 111.8(10) . . ?
C32 C33 H33A 109.3 . . ?
C34 C33 H33A 109.3 . . ?
C32 C33 H33B 109.3 . . ?
C34 C33 H33B 109.3 . . ?
H33A C33 H33B 107.9 . . ?
C35 C34 C33 114.7(11) . . ?
C35 C34 H34A 108.6 . . ?
C33 C34 H34A 108.6 . . ?
C35 C34 H34B 108.6 . . ?
C33 C34 H34B 108.6 . . ?
H34A C34 H34B 107.6 . . ?
C36 C35 C34 124.6(13) . . ?
C36 C35 Rh2 66.6(7) . . ?
C34 C35 Rh2 111.2(7) . . ?
C36 C35 H35 114.8 . . ?
C34 C35 H35 114.8 . . ?
Rh2 C35 H35 114.8 . . ?
C35 C36 C37 121.8(10) . . ?
C35 C36 Rh2 74.5(7) . . ?
C37 C36 Rh2 109.1(7) . . ?
C35 C36 H36 114.8 . . ?
C37 C36 H36 114.8 . . ?
Rh2 C36 H36 114.8 . . ?
C38 C37 C36 121.6(10) . . ?
C38 C37 H37A 106.9 . . ?
C36 C37 H37A 106.9 . . ?
C38 C37 H37B 106.9 . . ?
C36 C37 H37B 106.9 . . ?
H37A C37 H37B 106.7 . . ?
C37 C38 C31 107.2(13) . . ?
C37 C38 H38A 110.3 . . ?
C31 C38 H38A 110.3 . . ?
C37 C38 H38B 110.3 . . ?
C31 C38 H38B 110.3 . . ?
H38A C38 H38B 108.5 . . ?
C32' C31' C38' 105.4(14) . . ?
C32' C31' Rh2 71.4(12) . . ?
C38' C31' Rh2 107.4(15) . . ?
C32' C31' H31' 120.7 . . ?
C38' C31' H31' 120.7 . . ?
Rh2 C31' H31' 120.7 . . ?
C31' C32' C33' 124.1(14) . . ?
C31' C32' Rh2 70.2(15) . . ?
C33' C32' Rh2 112.2(10) . . ?
C31' C32' H32' 114.2 . . ?
C33' C32' H32' 114.2 . . ?
Rh2 C32' H32' 114.2 . . ?
C32' C33' C34' 112.3(12) . . ?
C32' C33' H33C 109.1 . . ?
C34' C33' H33C 109.1 . . ?
C32' C33' H33D 109.1 . . ?
C34' C33' H33D 109.1 . . ?
H33C C33' H33D 107.9 . . ?
C35' C34' C33' 112.8(13) . . ?
C35' C34' H34C 109.0 . . ?
C33' C34' H34C 109.0 . . ?
C35' C34' H34D 109.0 . . ?
C33' C34' H34D 109.0 . . ?
H34C C34' H34D 107.8 . . ?
C36' C35' C34' 126.5(16) . . ?
C36' C35' Rh2 73.7(8) . . ?
C34' C35' Rh2 113.3(11) . . ?
C36' C35' H35' 112.4 . . ?
C34' C35' H35' 112.4 . . ?
Rh2 C35' H35' 112.4 . . ?
C35' C36' C37' 124.6(17) . . ?
C35' C36' Rh2 66.3(8) . . ?
C37' C36' Rh2 118.4(10) . . ?
C35' C36' H36' 113.2 . . ?
C37' C36' H36' 113.2 . . ?
Rh2 C36' H36' 113.2 . . ?
C36' C37' C38' 107.8(14) . . ?
C36' C37' H37C 110.1 . . ?
C38' C37' H37C 110.1 . . ?
C36' C37' H37D 110.1 . . ?
C38' C37' H37D 110.1 . . ?
H37C C37' H37D 108.5 . . ?
C37' C38' C31' 123.1(16) . . ?
C37' C38' H38C 106.5 . . ?
C31' C38' H38C 106.5 . . ?
C37' C38' H38D 106.5 . . ?
C31' C38' H38D 106.5 . . ?
H38C C38' H38D 106.5 . . ?
C13 C14 C15 119.7(4) . . ?
C13 C14 H14 120.1 . . ?
C15 C14 H14 120.1 . . ?
Cl3 C39 Cl4 114.0(3) . . ?
Cl3 C39 H39A 108.8 . . ?
Cl4 C39 H39A 108.8 . . ?
Cl3 C39 H39B 108.8 . . ?
Cl4 C39 H39B 108.8 . . ?
H39A C39 H39B 107.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 P1 O1 C1 124.9(3) . . . . ?
C7 P1 O1 C1 -132.0(3) . . . . ?
Rh1 P1 O1 C1 -8.3(3) . . . . ?
C25 P2 O2 C3 -62.3(3) . . . . ?
C19 P2 O2 C3 47.4(3) . . . . ?
Rh1 P2 O2 C3 167.3(2) 2_677 . . . ?
P1 O1 C1 C6 64.4(4) . . . . ?
P1 O1 C1 C2 -119.6(3) . . . . ?
C6 C1 C2 C3 0.2(5) . . . . ?
O1 C1 C2 C3 -175.9(3) . . . . ?
C1 C2 C3 C4 0.4(5) . . . . ?
C1 C2 C3 O2 -171.6(3) . . . . ?
P2 O2 C3 C2 -73.3(4) . . . . ?
P2 O2 C3 C4 114.5(3) . . . . ?
C2 C3 C4 C5 -0.3(5) . . . . ?
O2 C3 C4 C5 171.8(3) . . . . ?
C3 C4 C5 C6 -0.4(5) . . . . ?
C2 C1 C6 C5 -0.9(5) . . . . ?
O1 C1 C6 C5 175.0(3) . . . . ?
C4 C5 C6 C1 1.0(5) . . . . ?
O1 P1 C7 C8 24.8(3) . . . . ?
C13 P1 C7 C8 126.6(3) . . . . ?
Rh1 P1 C7 C8 -105.7(3) . . . . ?
O1 P1 C7 C12 -158.8(3) . . . . ?
C13 P1 C7 C12 -57.1(3) . . . . ?
Rh1 P1 C7 C12 70.7(3) . . . . ?
C12 C7 C8 C9 0.2(6) . . . . ?
P1 C7 C8 C9 176.6(3) . . . . ?
C7 C8 C9 C10 1.3(7) . . . . ?
C8 C9 C10 C11 -2.0(7) . . . . ?
C9 C10 C11 C12 1.2(6) . . . . ?
C10 C11 C12 C7 0.3(6) . . . . ?
C8 C7 C12 C11 -1.0(5) . . . . ?
P1 C7 C12 C11 -177.4(3) . . . . ?
O1 P1 C13 C14 11.3(3) . . . . ?
C7 P1 C13 C14 -88.2(3) . . . . ?
Rh1 P1 C13 C14 147.4(2) . . . . ?
O1 P1 C13 C18 -170.5(3) . . . . ?
C7 P1 C13 C18 90.0(3) . . . . ?
Rh1 P1 C13 C18 -34.5(3) . . . . ?
C14 C15 C16 C17 0.5(7) . . . . ?
C15 C16 C17 C18 0.5(7) . . . . ?
C16 C17 C18 C13 -1.1(6) . . . . ?
C14 C13 C18 C17 0.7(5) . . . . ?
P1 C13 C18 C17 -177.6(3) . . . . ?
O2 P2 C19 C20 -115.0(3) . . . . ?
C25 P2 C19 C20 -5.0(4) . . . . ?
Rh1 P2 C19 C20 124.5(3) 2_677 . . . ?
O2 P2 C19 C24 67.1(3) . . . . ?
C25 P2 C19 C24 177.2(3) . . . . ?
Rh1 P2 C19 C24 -53.4(3) 2_677 . . . ?
C24 C19 C20 C21 -2.4(7) . . . . ?
P2 C19 C20 C21 179.8(4) . . . . ?
C19 C20 C21 C22 0.4(9) . . . . ?
C20 C21 C22 C23 0.9(9) . . . . ?
C21 C22 C23 C24 -0.2(8) . . . . ?
C22 C23 C24 C19 -1.8(6) . . . . ?
C20 C19 C24 C23 3.1(6) . . . . ?
P2 C19 C24 C23 -178.9(3) . . . . ?
O2 P2 C25 C26 -127.1(3) . . . . ?
C19 P2 C25 C26 123.2(3) . . . . ?
Rh1 P2 C25 C26 -1.1(3) 2_677 . . . ?
O2 P2 C25 C30 53.8(3) . . . . ?
C19 P2 C25 C30 -55.9(3) . . . . ?
Rh1 P2 C25 C30 179.7(2) 2_677 . . . ?
C30 C25 C26 C27 -0.1(5) . . . . ?
P2 C25 C26 C27 -179.3(3) . . . . ?
C25 C26 C27 C28 1.8(6) . . . . ?
C26 C27 C28 C29 -1.9(6) . . . . ?
C27 C28 C29 C30 0.4(6) . . . . ?
C28 C29 C30 C25 1.2(6) . . . . ?
C26 C25 C30 C29 -1.4(5) . . . . ?
P2 C25 C30 C29 177.8(3) . . . . ?
C38 C31 C32 C33 4(4) . . . . ?
Rh2 C31 C32 C33 104.9(15) . . . . ?
C38 C31 C32 Rh2 -100(3) . . . . ?
C31 C32 C33 C34 -54(3) . . . . ?
Rh2 C32 C33 C34 29(2) . . . . ?
C32 C33 C34 C35 -25(3) . . . . ?
C33 C34 C35 C36 85(2) . . . . ?
C33 C34 C35 Rh2 10(2) . . . . ?
C34 C35 C36 C37 2.8(17) . . . . ?
Rh2 C35 C36 C37 103.2(11) . . . . ?
C34 C35 C36 Rh2 -100.4(10) . . . . ?
C35 C36 C37 C38 -78.1(15) . . . . ?
Rh2 C36 C37 C38 5.2(13) . . . . ?
C36 C37 C38 C31 11.7(17) . . . . ?
C32 C31 C38 C37 58(3) . . . . ?
Rh2 C31 C38 C37 -23.3(14) . . . . ?
C38' C31' C32' C33' 0(3) . . . . ?
Rh2 C31' C32' C33' 103.9(17) . . . . ?
C38' C31' C32' Rh2 -103.5(18) . . . . ?
C31' C32' C33' C34' -88(3) . . . . ?
Rh2 C32' C33' C34' -8(2) . . . . ?
C32' C33' C34' C35' 25(3) . . . . ?
C33' C34' C35' C36' 55(3) . . . . ?
C33' C34' C35' Rh2 -31(2) . . . . ?
C34' C35' C36' C37' 2(2) . . . . ?
Rh2 C35' C36' C37' 109.1(14) . . . . ?
C34' C35' C36' Rh2 -107.3(15) . . . . ?
C35' C36' C37' C38' -67.2(19) . . . . ?
Rh2 C36' C37' C38' 12(2) . . . . ?
C36' C37' C38' C31' -16(2) . . . . ?
C32' C31' C38' C37' 87(3) . . . . ?
Rh2 C31' C38' C37' 12(2) . . . . ?
C18 C13 C14 C15 0.4(5) . . . . ?
P1 C13 C14 C15 178.5(3) . . . . ?
C16 C15 C14 C13 -0.9(6) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C39 H39A Cl2 0.99 2.70 3.665(5) 165.8 2_766

_refine_diff_density_max         1.600
_refine_diff_density_min         -0.666
_refine_diff_density_rms         0.080

_shelxl_version_number           2014-3


_chemical_properties_physical    Air-sensitive,Moisture-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AX1356abs
_database_code_depnum_ccdc_archive 'CCDC 1816555'
_audit_update_record             
;
2018-01-12 deposited with the CCDC.
2018-05-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C76 H72 Cl4 P4 Rh4 S4'
_chemical_formula_weight         1790.89

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.7617(13)
_cell_length_b                   17.854(2)
_cell_length_c                   19.459(2)
_cell_angle_alpha                78.973(2)
_cell_angle_beta                 84.819(2)
_cell_angle_gamma                78.382(2)
_cell_volume                     3589.5(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    9983
_cell_measurement_theta_min      2.25
_cell_measurement_theta_max      27.50

_exptl_crystal_description       part
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.657
_exptl_crystal_F_000             1800
_exptl_crystal_size_max          0.241
_exptl_crystal_size_mid          0.229
_exptl_crystal_size_min          0.128
_exptl_absorpt_coefficient_mu    1.302
_shelx_estimated_absorpt_T_min   0.744
_shelx_estimated_absorpt_T_max   0.851
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6877
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean 8.3333
_diffrn_reflns_number            48210
_diffrn_reflns_av_unetI/netI     0.0380
_diffrn_reflns_av_R_equivalents  0.0325
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.068
_diffrn_reflns_theta_max         27.103
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             15834
_reflns_number_gt                12245
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_reduction        'SAINT (Bruker, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0331P)²+5.5749P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15834
_refine_ls_number_parameters     866
_refine_ls_number_restraints     37
_refine_ls_R_factor_all          0.0545
_refine_ls_R_factor_gt           0.0347
_refine_ls_wR_factor_ref         0.0857
_refine_ls_wR_factor_gt          0.0752
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.48463(2) 0.73504(2) 0.36843(2) 0.02147(6) Uani 1 1 d D . . . .
H1 H 0.482(5) 0.777(3) 0.2792(12) 0.098(19) Uiso 1 1 d D . . . .
Rh2 Rh 0.28389(2) 0.75185(2) 0.52660(2) 0.02438(7) Uani 1 1 d . . . . .
Rh3 Rh 0.94500(2) 0.74619(2) 0.86829(2) 0.01906(6) Uani 1 1 d D . . . .
H2 H 0.955(5) 0.780(3) 0.7772(11) 0.080(16) Uiso 1 1 d D . . . .
Cl1 Cl 0.28425(8) 0.81599(5) 0.40593(4) 0.02658(17) Uani 1 1 d . . . . .
Cl2 Cl 0.48441(7) 0.67414(4) 0.49637(4) 0.02384(16) Uani 1 1 d . . . . .
Cl3 Cl 0.71674(8) 0.80192(7) 0.88805(4) 0.0439(3) Uani 1 1 d . . . . .
Cl4 Cl 0.92968(9) 0.69770(6) 0.99842(4) 0.0385(2) Uani 1 1 d . . . . .
S1 S 0.78619(9) 0.78318(5) 0.34119(6) 0.0377(2) Uani 1 1 d . . . . .
S2 S 0.51255(10) 0.55121(6) 0.32520(6) 0.0399(2) Uani 1 1 d . . . . .
S3 S 1.18976(9) 0.83360(5) 0.89869(5) 0.0377(2) Uani 1 1 d . . . . .
S4 S 1.08253(10) 0.56797(5) 0.82231(5) 0.0390(2) Uani 1 1 d . . . . .
P1 P 0.60072(8) 0.82763(5) 0.37475(4) 0.02398(18) Uani 1 1 d . . . . .
P2 P 0.37598(9) 0.64713(5) 0.34317(4) 0.02611(19) Uani 1 1 d . . . . .
P3 P 0.99821(9) 0.86114(5) 0.87528(4) 0.02651(19) Uani 1 1 d . . . . .
P4 P 0.90508(9) 0.63587(5) 0.84000(5) 0.02665(19) Uani 1 1 d D . . . .
C1 C 0.6456(3) 0.6685(2) 0.33543(15) 0.0267(7) Uani 1 1 d . . . . .
C2 C 0.7645(3) 0.6923(2) 0.32575(17) 0.0286(7) Uani 1 1 d . . . . .
C3 C 0.8751(4) 0.6470(3) 0.3027(2) 0.0455(10) Uani 1 1 d . . . . .
H3 H 0.9525 0.6658 0.2966 0.055 Uiso 1 1 calc R U . . .
C4 C 0.8721(4) 0.5747(3) 0.2886(3) 0.0609(14) Uani 1 1 d . . . . .
H4 H 0.9479 0.5430 0.2737 0.073 Uiso 1 1 calc R U . . .
C5 C 0.7592(4) 0.5486(3) 0.2962(2) 0.0502(11) Uani 1 1 d . . . . .
H5 H 0.7566 0.4989 0.2862 0.060 Uiso 1 1 calc R U . . .
C6 C 0.6484(3) 0.5948(2) 0.31841(18) 0.0331(8) Uani 1 1 d . . . . .
C7 C 0.6199(3) 0.85991(19) 0.45621(17) 0.0277(7) Uani 1 1 d . . . . .
C8 C 0.7359(4) 0.8662(3) 0.4775(2) 0.0486(11) Uani 1 1 d . . . . .
H8 H 0.8117 0.8489 0.4513 0.058 Uiso 1 1 calc R U . . .
C9 C 0.7425(5) 0.8977(3) 0.5368(2) 0.0595(13) Uani 1 1 d . . . . .
H9 H 0.8226 0.9026 0.5506 0.071 Uiso 1 1 calc R U . . .
C10 C 0.6335(5) 0.9216(2) 0.5757(2) 0.0508(11) Uani 1 1 d . . . . .
H10 H 0.6380 0.9433 0.6162 0.061 Uiso 1 1 calc R U . . .
C11 C 0.5185(4) 0.9142(2) 0.5557(2) 0.0463(10) Uani 1 1 d . . . . .
H11 H 0.4433 0.9298 0.5830 0.056 Uiso 1 1 calc R U . . .
C12 C 0.5108(4) 0.8841(2) 0.49605(19) 0.0359(8) Uani 1 1 d . . . . .
H12 H 0.4303 0.8799 0.4823 0.043 Uiso 1 1 calc R U . . .
C13 C 0.5628(3) 0.92087(19) 0.31508(16) 0.0259(7) Uani 1 1 d . . . . .
C14 C 0.6390(3) 0.97588(19) 0.31033(18) 0.0303(8) Uani 1 1 d . . . . .
H14 H 0.7070 0.9666 0.3406 0.036 Uiso 1 1 calc R U . . .
C15 C 0.6171(4) 1.0441(2) 0.2620(2) 0.0372(9) Uani 1 1 d . . . . .
H15 H 0.6709 1.0809 0.2588 0.045 Uiso 1 1 calc R U . . .
C16 C 0.5178(4) 1.0590(2) 0.2188(2) 0.0417(10) Uani 1 1 d . . . . .
H16 H 0.5034 1.1056 0.1852 0.050 Uiso 1 1 calc R U . . .
C17 C 0.4392(4) 1.0060(3) 0.2242(2) 0.0503(11) Uani 1 1 d . . . . .
H17 H 0.3689 1.0168 0.1953 0.060 Uiso 1 1 calc R U . . .
C18 C 0.4621(4) 0.9362(2) 0.2721(2) 0.0425(10) Uani 1 1 d . . . . .
H18 H 0.4084 0.8994 0.2750 0.051 Uiso 1 1 calc R U . . .
C19 C 0.2687(4) 0.6053(2) 0.41044(17) 0.0309(8) Uani 1 1 d . . . . .
C20 C 0.1424(4) 0.6417(3) 0.4155(2) 0.0422(10) Uani 1 1 d . . . . .
H20 H 0.1119 0.6867 0.3824 0.051 Uiso 1 1 calc R U . . .
C21 C 0.0607(4) 0.6132(3) 0.4685(2) 0.0570(13) Uani 1 1 d . . . . .
H21 H -0.0258 0.6382 0.4715 0.068 Uiso 1 1 calc R U . . .
C22 C 0.1055(5) 0.5482(3) 0.5170(2) 0.0624(15) Uani 1 1 d . . . . .
H22 H 0.0496 0.5290 0.5538 0.075 Uiso 1 1 calc R U . . .
C23 C 0.2297(5) 0.5112(3) 0.5126(2) 0.0553(13) Uani 1 1 d . . . . .
H23 H 0.2591 0.4660 0.5459 0.066 Uiso 1 1 calc R U . . .
C24 C 0.3125(4) 0.5390(2) 0.46010(19) 0.0420(10) Uani 1 1 d . . . . .
H24 H 0.3988 0.5135 0.4575 0.050 Uiso 1 1 calc R U . . .
C25 C 0.2794(3) 0.6751(2) 0.26658(16) 0.0311(8) Uani 1 1 d . . . . .
C26 C 0.2264(4) 0.7524(2) 0.24412(19) 0.0424(10) Uani 1 1 d . . . . .
H26 H 0.2427 0.7913 0.2674 0.051 Uiso 1 1 calc R U . . .
C27 C 0.1492(4) 0.7728(3) 0.1874(2) 0.0497(11) Uani 1 1 d . . . . .
H27 H 0.1132 0.8259 0.1719 0.060 Uiso 1 1 calc R U . . .
C28 C 0.1244(4) 0.7170(3) 0.1534(2) 0.0493(11) Uani 1 1 d . . . . .
H28 H 0.0707 0.7315 0.1150 0.059 Uiso 1 1 calc R U . . .
C29 C 0.1770(4) 0.6405(3) 0.1750(2) 0.0471(11) Uani 1 1 d . . . . .
H29 H 0.1605 0.6018 0.1515 0.057 Uiso 1 1 calc R U . . .
C30 C 0.2546(4) 0.6199(2) 0.23148(19) 0.0402(9) Uani 1 1 d . . . . .
H30 H 0.2912 0.5668 0.2462 0.048 Uiso 1 1 calc R U . . .
C31 C 0.1623(4) 0.8476(2) 0.5590(2) 0.0404(9) Uani 1 1 d . . . . .
H31 H 0.1593 0.8975 0.5250 0.048 Uiso 1 1 calc R U . . .
C32 C 0.0900(4) 0.7975(2) 0.5418(2) 0.0416(10) Uani 1 1 d . . . . .
H32 H 0.0448 0.8178 0.4974 0.050 Uiso 1 1 calc R U . . .
C33 C 0.0231(5) 0.7444(3) 0.5955(3) 0.0702(15) Uani 1 1 d . . . . .
H33A H -0.0347 0.7763 0.6259 0.084 Uiso 1 1 calc R U . . .
H33B H -0.0299 0.7199 0.5708 0.084 Uiso 1 1 calc R U . . .
C34 C 0.1082(4) 0.6818(3) 0.6410(2) 0.0540(12) Uani 1 1 d . . . . .
H34A H 0.0825 0.6316 0.6410 0.065 Uiso 1 1 calc R U . . .
H34B H 0.0956 0.6920 0.6897 0.065 Uiso 1 1 calc R U . . .
C35 C 0.2480(4) 0.6745(2) 0.61902(18) 0.0372(9) Uani 1 1 d . . . . .
H35 H 0.2940 0.6198 0.6198 0.045 Uiso 1 1 calc R U . . .
C36 C 0.3229(4) 0.7242(2) 0.63366(17) 0.0382(9) Uani 1 1 d . . . . .
H36 H 0.4128 0.6984 0.6425 0.046 Uiso 1 1 calc R U . . .
C37 C 0.2772(5) 0.7918(3) 0.6697(2) 0.0602(13) Uani 1 1 d . . . . .
H37A H 0.2426 0.7725 0.7172 0.072 Uiso 1 1 calc R U . . .
H37B H 0.3510 0.8150 0.6752 0.072 Uiso 1 1 calc R U . . .
C38 C 0.1798(5) 0.8531(3) 0.6343(3) 0.0700(16) Uani 1 1 d . . . . .
H38A H 0.2023 0.9040 0.6349 0.084 Uiso 1 1 calc R U . . .
H38B H 0.0977 0.8514 0.6614 0.084 Uiso 1 1 calc R U . . .
C41 C 1.1327(3) 0.70459(18) 0.85494(15) 0.0227(7) Uani 1 1 d . . . . .
C42 C 1.2271(3) 0.7453(2) 0.86512(17) 0.0277(7) Uani 1 1 d . . . . .
C43 C 1.3565(3) 0.7191(2) 0.85109(19) 0.0380(9) Uani 1 1 d . . . . .
H43 H 1.4165 0.7485 0.8592 0.046 Uiso 1 1 calc R U . . .
C44 C 1.3974(4) 0.6513(3) 0.8257(2) 0.0461(11) Uani 1 1 d . . . . .
H44 H 1.4851 0.6344 0.8145 0.055 Uiso 1 1 calc R U . . .
C45 C 1.3104(4) 0.6082(2) 0.81683(19) 0.0423(10) Uani 1 1 d . . . . .
H45 H 1.3382 0.5604 0.8005 0.051 Uiso 1 1 calc R U . . .
C46 C 1.1809(3) 0.6337(2) 0.83151(17) 0.0285(7) Uani 1 1 d . . . . .
C47 C 0.9210(4) 0.9140(2) 0.94332(19) 0.0374(9) Uani 1 1 d . . . . .
C48 C 0.8286(4) 0.9801(2) 0.9275(2) 0.0411(9) Uani 1 1 d . . . . .
H48 H 0.8115 1.0016 0.8800 0.049 Uiso 1 1 calc R U . . .
C49 C 0.7609(4) 1.0149(3) 0.9812(2) 0.0525(11) Uani 1 1 d . . . . .
H49 H 0.6984 1.0606 0.9701 0.063 Uiso 1 1 calc R U . . .
C50 C 0.7837(5) 0.9836(3) 1.0501(2) 0.0611(13) Uani 1 1 d . . . . .
H50 H 0.7348 1.0061 1.0868 0.073 Uiso 1 1 calc R U . . .
C51 C 0.8783(6) 0.9195(3) 1.0655(2) 0.082(2) Uani 1 1 d . . . . .
H51 H 0.8964 0.8987 1.1130 0.098 Uiso 1 1 calc R U . . .
C52 C 0.9474(6) 0.8848(3) 1.0126(2) 0.0687(16) Uani 1 1 d . . . . .
H52 H 1.0131 0.8409 1.0240 0.082 Uiso 1 1 calc R U . . .
C53 C 0.9851(3) 0.93585(19) 0.79718(18) 0.0284(7) Uani 1 1 d . . . . .
C54 C 1.0550(4) 0.9942(2) 0.7886(2) 0.0396(9) Uani 1 1 d . . . . .
H54 H 1.1141 0.9932 0.8224 0.047 Uiso 1 1 calc R U . . .
C55 C 1.0400(4) 1.0541(2) 0.7316(2) 0.0484(11) Uani 1 1 d . . . . .
H55 H 1.0883 1.0941 0.7266 0.058 Uiso 1 1 calc R U . . .
C56 C 0.9562(4) 1.0562(2) 0.6822(2) 0.0497(11) Uani 1 1 d . . . . .
H56 H 0.9465 1.0974 0.6430 0.060 Uiso 1 1 calc R U . . .
C57 C 0.8856(4) 0.9983(2) 0.6897(2) 0.0496(11) Uani 1 1 d . . . . .
H57 H 0.8268 0.9998 0.6556 0.059 Uiso 1 1 calc R U . . .
C58 C 0.9003(4) 0.9376(2) 0.7471(2) 0.0385(9) Uani 1 1 d . . . . .
H58 H 0.8523 0.8975 0.7518 0.046 Uiso 1 1 calc R U . . .
C59 C 0.8371(6) 0.5634(4) 0.8973(4) 0.022(2) Uani 0.506(10) 1 d DG . P A 3
C60 C 0.9024(5) 0.5004(4) 0.9420(5) 0.029(2) Uani 0.506(10) 1 d G . P A 3
H60 H 0.9925 0.4914 0.9413 0.035 Uiso 0.506(10) 1 calc R U P A 3
C61 C 0.8358(6) 0.4508(4) 0.9878(4) 0.039(3) Uani 0.506(10) 1 d G . P A 3
H61 H 0.8804 0.4077 1.0183 0.046 Uiso 0.506(10) 1 calc R U P A 3
C62 C 0.7039(6) 0.4640(4) 0.9888(3) 0.038(2) Uani 0.506(10) 1 d G . P A 3
H62 H 0.6584 0.4301 1.0201 0.045 Uiso 0.506(10) 1 calc R U P A 3
C63 C 0.6386(5) 0.5270(5) 0.9441(4) 0.053(3) Uani 0.506(10) 1 d G . P A 3
H63 H 0.5485 0.5361 0.9448 0.064 Uiso 0.506(10) 1 calc R U P A 3
C64 C 0.7052(6) 0.5767(4) 0.8984(4) 0.046(3) Uani 0.506(10) 1 d G . P A 3
H64 H 0.6606 0.6197 0.8678 0.055 Uiso 0.506(10) 1 calc R U P A 3
C59' C 0.8078(7) 0.5801(4) 0.9093(4) 0.022(2) Uani 0.494(10) 1 d DG . P A 4
C60' C 0.8618(6) 0.5066(4) 0.9434(5) 0.029(2) Uani 0.494(10) 1 d G . P A 4
H60' H 0.9464 0.4839 0.9308 0.034 Uiso 0.494(10) 1 calc R U P A 4
C61' C 0.7919(7) 0.4662(3) 0.9961(4) 0.034(3) Uani 0.494(10) 1 d G . P A 4
H61' H 0.8288 0.4159 1.0194 0.041 Uiso 0.494(10) 1 calc R U P A 4
C62' C 0.6681(6) 0.4993(4) 1.0146(3) 0.047(3) Uani 0.494(10) 1 d G . P A 4
H62' H 0.6203 0.4717 1.0506 0.056 Uiso 0.494(10) 1 calc R U P A 4
C63' C 0.6142(4) 0.5729(4) 0.9804(4) 0.044(3) Uani 0.494(10) 1 d G . P A 4
H63' H 0.5296 0.5955 0.9930 0.053 Uiso 0.494(10) 1 calc R U P A 4
C64' C 0.6840(6) 0.6133(3) 0.9277(3) 0.039(2) Uani 0.494(10) 1 d G . P A 4
H64' H 0.6472 0.6635 0.9044 0.047 Uiso 0.494(10) 1 calc R U P A 4
C65 C 0.8214(4) 0.6440(2) 0.76035(19) 0.0337(8) Uani 1 1 d . . . . .
C66 C 0.7528(4) 0.7141(2) 0.7291(2) 0.0382(9) Uani 1 1 d . . . . .
H66 H 0.7475 0.7593 0.7491 0.046 Uiso 1 1 calc R U . . .
C67 C 0.6913(4) 0.7183(3) 0.6681(2) 0.0491(11) Uani 1 1 d . . . . .
H67 H 0.6434 0.7665 0.6467 0.059 Uiso 1 1 calc R U . . .
C68 C 0.6994(4) 0.6538(3) 0.6388(2) 0.0532(12) Uani 1 1 d . . . . .
H68 H 0.6579 0.6573 0.5970 0.064 Uiso 1 1 calc R U . . .
C69 C 0.7674(5) 0.5837(3) 0.6697(3) 0.0639(14) Uani 1 1 d . . . . .
H69 H 0.7745 0.5389 0.6489 0.077 Uiso 1 1 calc R U . . .
C70 C 0.8255(5) 0.5788(2) 0.7314(2) 0.0575(13) Uani 1 1 d . . . . .
H70 H 0.8688 0.5299 0.7541 0.069 Uiso 1 1 calc R U . . .
Rh4A Rh 0.71289(8) 0.73529(15) 1.01205(4) 0.0286(3) Uani 0.541(5) 1 d D . P B 1
C71 C 0.5414(8) 0.8121(6) 1.0325(4) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H71 H 0.5185 0.8573 0.9938 0.062 Uiso 0.541(5) 1 calc R U P B 1
C72 C 0.5146(7) 0.7442(6) 1.0209(4) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H72 H 0.4745 0.7483 0.9756 0.062 Uiso 0.541(5) 1 calc R U P B 1
C73 C 0.4709(7) 0.6838(5) 1.0817(4) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H73A H 0.4261 0.7110 1.1192 0.062 Uiso 0.541(5) 1 calc R U P B 1
H73B H 0.4103 0.6577 1.0643 0.062 Uiso 0.541(5) 1 calc R U P B 1
C74 C 0.5814(7) 0.6234(5) 1.1117(4) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H74A H 0.5620 0.6066 1.1623 0.062 Uiso 0.541(5) 1 calc R U P B 1
H74B H 0.5907 0.5775 1.0887 0.062 Uiso 0.541(5) 1 calc R U P B 1
C75 C 0.7045(8) 0.6515(6) 1.1026(4) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H75 H 0.7809 0.6088 1.1075 0.062 Uiso 0.541(5) 1 calc R U P B 1
C76 C 0.7227(8) 0.7201(6) 1.1219(4) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H76 H 0.8094 0.7176 1.1379 0.062 Uiso 0.541(5) 1 calc R U P B 1
C77 C 0.6175(7) 0.7733(5) 1.1561(4) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H77A H 0.5615 0.7413 1.1862 0.062 Uiso 0.541(5) 1 calc R U P B 1
H77B H 0.6559 0.7998 1.1867 0.062 Uiso 0.541(5) 1 calc R U P B 1
C78 C 0.5378(8) 0.8339(5) 1.1047(3) 0.0519(10) Uani 0.541(5) 1 d D . P B 1
H78A H 0.5681 0.8835 1.0997 0.062 Uiso 0.541(5) 1 calc R U P B 1
H78B H 0.4487 0.8422 1.1238 0.062 Uiso 0.541(5) 1 calc R U P B 1
Rh4B Rh 0.70498(10) 0.77177(17) 1.01384(4) 0.0270(4) Uani 0.459(5) 1 d D . P B
2
C81 C 0.5529(9) 0.8601(7) 1.0304(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H81 H 0.5452 0.9072 0.9927 0.071 Uiso 0.459(5) 1 calc R U P B 2
C82 C 0.5084(9) 0.8001(8) 1.0142(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H82 H 0.4762 0.8119 0.9660 0.071 Uiso 0.459(5) 1 calc R U P B 2
C83 C 0.4431(9) 0.7410(7) 1.0641(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H83A H 0.3633 0.7684 1.0846 0.071 Uiso 0.459(5) 1 calc R U P B 2
H83B H 0.4210 0.7040 1.0374 0.071 Uiso 0.459(5) 1 calc R U P B 2
C84 C 0.5268(8) 0.6965(7) 1.1226(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H84A H 0.5166 0.6416 1.1310 0.071 Uiso 0.459(5) 1 calc R U P B 2
H84B H 0.4958 0.7174 1.1659 0.071 Uiso 0.459(5) 1 calc R U P B 2
C85 C 0.6684(9) 0.6988(7) 1.1099(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H85 H 0.7263 0.6469 1.1181 0.071 Uiso 0.459(5) 1 calc R U P B 2
C86 C 0.7195(10) 0.7604(7) 1.1225(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H86 H 0.8086 0.7452 1.1380 0.071 Uiso 0.459(5) 1 calc R U P B 2
C87 C 0.6415(9) 0.8285(7) 1.1516(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H87A H 0.6991 0.8621 1.1603 0.071 Uiso 0.459(5) 1 calc R U P B 2
H87B H 0.6003 0.8089 1.1972 0.071 Uiso 0.459(5) 1 calc R U P B 2
C88 C 0.5399(9) 0.8773(7) 1.1042(5) 0.0591(13) Uani 0.459(5) 1 d D . P B 2
H88A H 0.4557 0.8687 1.1254 0.071 Uiso 0.459(5) 1 calc R U P B 2
H88B H 0.5426 0.9329 1.1017 0.071 Uiso 0.459(5) 1 calc R U P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 H1 1.754(19) . ?
Rh1 C1 2.021(3) . ?
Rh1 P2 2.2826(9) . ?
Rh1 P1 2.2904(9) . ?
Rh1 Cl1 2.4770(9) . ?
Rh1 Cl2 2.5188(8) . ?
Rh1 H1 1.754(19) . ?
Rh2 C31 2.095(4) . ?
Rh2 C32 2.097(4) . ?
Rh2 C35 2.105(3) . ?
Rh2 C36 2.107(3) . ?
Rh2 Cl1 2.4076(8) . ?
Rh2 Cl2 2.4093(8) . ?
Rh3 H2 1.761(19) . ?
Rh3 C41 2.018(3) . ?
Rh3 P3 2.2700(9) . ?
Rh3 P4 2.2728(9) . ?
Rh3 Cl3 2.4827(9) . ?
Rh3 Cl4 2.5165(9) . ?
Rh3 H2 1.761(19) . ?
Cl3 Rh4B 2.4011(12) . ?
Cl3 Rh4A 2.4785(12) . ?
Cl4 Rh4A 2.2998(13) . ?
Cl4 Rh4B 2.534(2) . ?
S1 C2 1.769(4) . ?
S1 P1 2.0892(13) . ?
S2 C6 1.773(4) . ?
S2 P2 2.0827(14) . ?
S3 C42 1.779(4) . ?
S3 P3 2.0915(13) . ?
S4 C46 1.774(4) . ?
S4 P4 2.0841(13) . ?
P1 C7 1.829(3) . ?
P1 C13 1.833(3) . ?
P2 C19 1.818(3) . ?
P2 C25 1.827(3) . ?
P3 C53 1.816(3) . ?
P3 C47 1.816(4) . ?
P4 C59 1.770(4) . ?
P4 C65 1.830(3) . ?
P4 C59' 1.885(4) . ?
C1 C6 1.412(5) . ?
C1 C2 1.413(5) . ?
C2 C3 1.388(5) . ?
C3 C4 1.377(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.373(6) . ?
C4 H4 0.9500 . ?
C5 C6 1.391(5) . ?
C5 H5 0.9500 . ?
C7 C8 1.383(5) . ?
C7 C12 1.387(5) . ?
C8 C9 1.390(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.377(7) . ?
C9 H9 0.9500 . ?
C10 C11 1.369(6) . ?
C10 H10 0.9500 . ?
C11 C12 1.385(5) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.380(5) . ?
C13 C14 1.386(5) . ?
C14 C15 1.382(5) . ?
C14 H14 0.9500 . ?
C15 C16 1.373(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.375(6) . ?
C16 H16 0.9500 . ?
C17 C18 1.398(5) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.386(6) . ?
C19 C24 1.406(5) . ?
C20 C21 1.382(5) . ?
C20 H20 0.9500 . ?
C21 C22 1.381(7) . ?
C21 H21 0.9500 . ?
C22 C23 1.370(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.380(6) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C30 1.382(5) . ?
C25 C26 1.384(5) . ?
C26 C27 1.389(5) . ?
C26 H26 0.9500 . ?
C27 C28 1.375(6) . ?
C27 H27 0.9500 . ?
C28 C29 1.369(6) . ?
C28 H28 0.9500 . ?
C29 C30 1.387(5) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C32 1.399(6) . ?
C31 C38 1.519(6) . ?
C31 H31 1.0000 . ?
C32 C33 1.506(6) . ?
C32 H32 1.0000 . ?
C33 C34 1.493(7) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 C35 1.514(6) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.394(6) . ?
C35 H35 1.0000 . ?
C36 C37 1.486(6) . ?
C36 H36 1.0000 . ?
C37 C38 1.466(7) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C41 C42 1.410(5) . ?
C41 C46 1.411(5) . ?
C42 C43 1.397(5) . ?
C43 C44 1.371(6) . ?
C43 H43 0.9500 . ?
C44 C45 1.366(6) . ?
C44 H44 0.9500 . ?
C45 C46 1.398(5) . ?
C45 H45 0.9500 . ?
C47 C52 1.383(6) . ?
C47 C48 1.385(5) . ?
C48 C49 1.392(5) . ?
C48 H48 0.9500 . ?
C49 C50 1.375(6) . ?
C49 H49 0.9500 . ?
C50 C51 1.375(7) . ?
C50 H50 0.9500 . ?
C51 C52 1.384(6) . ?
C51 H51 0.9500 . ?
C52 H52 0.9500 . ?
C53 C54 1.381(5) . ?
C53 C58 1.386(5) . ?
C54 C55 1.383(5) . ?
C54 H54 0.9500 . ?
C55 C56 1.366(6) . ?
C55 H55 0.9500 . ?
C56 C57 1.382(6) . ?
C56 H56 0.9500 . ?
C57 C58 1.396(5) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C59 C60 1.3900 . ?
C59 C64 1.3900 . ?
C60 C61 1.3900 . ?
C60 H60 0.9500 . ?
C61 C62 1.3900 . ?
C61 H61 0.9500 . ?
C62 C63 1.3900 . ?
C62 H62 0.9500 . ?
C63 C64 1.3900 . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C59' C60' 1.3900 . ?
C59' C64' 1.3900 . ?
C60' C61' 1.3900 . ?
C60' H60' 0.9500 . ?
C61' C62' 1.3900 . ?
C61' H61' 0.9500 . ?
C62' C63' 1.3900 . ?
C62' H62' 0.9500 . ?
C63' C64' 1.3900 . ?
C63' H63' 0.9500 . ?
C64' H64' 0.9500 . ?
C65 C66 1.377(5) . ?
C65 C70 1.379(5) . ?
C66 C67 1.394(5) . ?
C66 H66 0.9500 . ?
C67 C68 1.364(6) . ?
C67 H67 0.9500 . ?
C68 C69 1.374(6) . ?
C68 H68 0.9500 . ?
C69 C70 1.382(6) . ?
C69 H69 0.9500 . ?
C70 H70 0.9500 . ?
Rh4A C75 2.090(7) . ?
Rh4A C72 2.102(8) . ?
Rh4A C76 2.111(7) . ?
Rh4A C71 2.122(9) . ?
C71 C72 1.365(13) . ?
C71 C78 1.522(10) . ?
C71 H71 1.0000 . ?
C72 C73 1.547(10) . ?
C72 H72 1.0000 . ?
C73 C74 1.511(8) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 C75 1.493(10) . ?
C74 H74A 0.9900 . ?
C74 H74B 0.9900 . ?
C75 C76 1.402(12) . ?
C75 H75 1.0000 . ?
C76 C77 1.516(10) . ?
C76 H76 1.0000 . ?
C77 C78 1.508(7) . ?
C77 H77A 0.9900 . ?
C77 H77B 0.9900 . ?
C78 H78A 0.9900 . ?
C78 H78B 0.9900 . ?
Rh4B C82 2.073(10) . ?
Rh4B C81 2.080(10) . ?
Rh4B C86 2.102(9) . ?
Rh4B C85 2.119(9) . ?
C81 C82 1.356(15) . ?
C81 C88 1.513(11) . ?
C81 H81 1.0000 . ?
C82 C83 1.527(13) . ?
C82 H82 1.0000 . ?
C83 C84 1.512(8) . ?
C83 H83A 0.9900 . ?
C83 H83B 0.9900 . ?
C84 C85 1.529(12) . ?
C84 H84A 0.9900 . ?
C84 H84B 0.9900 . ?
C85 C86 1.395(14) . ?
C85 H85 1.0000 . ?
C86 C87 1.507(12) . ?
C86 H86 1.0000 . ?
C87 C88 1.516(8) . ?
C87 H87A 0.9900 . ?
C87 H87B 0.9900 . ?
C88 H88A 0.9900 . ?
C88 H88B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
H1 Rh1 C1 82.2(18) . . ?
H1 Rh1 P2 87.3(18) . . ?
C1 Rh1 P2 87.74(10) . . ?
H1 Rh1 P1 83.9(18) . . ?
C1 Rh1 P1 88.56(10) . . ?
P2 Rh1 P1 170.79(3) . . ?
H1 Rh1 Cl1 96.6(18) . . ?
C1 Rh1 Cl1 178.33(9) . . ?
P2 Rh1 Cl1 91.02(3) . . ?
P1 Rh1 Cl1 92.49(3) . . ?
H1 Rh1 Cl2 178.8(18) . . ?
C1 Rh1 Cl2 98.28(9) . . ?
P2 Rh1 Cl2 91.65(3) . . ?
P1 Rh1 Cl2 97.23(3) . . ?
Cl1 Rh1 Cl2 82.88(3) . . ?
H1 Rh1 H1 0(3) . . ?
C1 Rh1 H1 82.2(18) . . ?
P2 Rh1 H1 87.3(18) . . ?
P1 Rh1 H1 83.9(18) . . ?
Cl1 Rh1 H1 96.6(18) . . ?
Cl2 Rh1 H1 178.8(18) . . ?
C31 Rh2 C32 38.99(16) . . ?
C31 Rh2 C35 93.96(15) . . ?
C32 Rh2 C35 82.44(15) . . ?
C31 Rh2 C36 82.28(16) . . ?
C32 Rh2 C36 96.11(16) . . ?
C35 Rh2 C36 38.65(15) . . ?
C31 Rh2 Cl1 92.03(11) . . ?
C32 Rh2 Cl1 91.22(11) . . ?
C35 Rh2 Cl1 161.28(12) . . ?
C36 Rh2 Cl1 160.06(12) . . ?
C31 Rh2 Cl2 156.34(12) . . ?
C32 Rh2 Cl2 164.53(13) . . ?
C35 Rh2 Cl2 94.73(11) . . ?
C36 Rh2 Cl2 90.92(11) . . ?
Cl1 Rh2 Cl2 86.70(3) . . ?
H2 Rh3 C41 84.3(16) . . ?
H2 Rh3 P3 84.4(16) . . ?
C41 Rh3 P3 87.04(10) . . ?
H2 Rh3 P4 85.4(16) . . ?
C41 Rh3 P4 88.91(10) . . ?
P3 Rh3 P4 169.28(3) . . ?
H2 Rh3 Cl3 96.8(16) . . ?
C41 Rh3 Cl3 177.18(10) . . ?
P3 Rh3 Cl3 90.47(4) . . ?
P4 Rh3 Cl3 93.77(4) . . ?
H2 Rh3 Cl4 179.6(17) . . ?
C41 Rh3 Cl4 95.95(8) . . ?
P3 Rh3 Cl4 95.97(3) . . ?
P4 Rh3 Cl4 94.31(3) . . ?
Cl3 Rh3 Cl4 82.98(3) . . ?
H2 Rh3 H2 0(3) . . ?
C41 Rh3 H2 84.3(16) . . ?
P3 Rh3 H2 84.4(16) . . ?
P4 Rh3 H2 85.4(16) . . ?
Cl3 Rh3 H2 96.8(16) . . ?
Cl4 Rh3 H2 179.6(17) . . ?
Rh2 Cl1 Rh1 95.72(3) . . ?
Rh2 Cl2 Rh1 94.59(3) . . ?
Rh4B Cl3 Rh3 98.06(5) . . ?
Rh4A Cl3 Rh3 92.43(4) . . ?
Rh4A Cl4 Rh3 95.98(4) . . ?
Rh3 Cl4 Rh4B 93.82(4) . . ?
C2 S1 P1 99.53(12) . . ?
C6 S2 P2 98.04(13) . . ?
C42 S3 P3 96.63(12) . . ?
C46 S4 P4 99.48(12) . . ?
C7 P1 C13 101.13(15) . . ?
C7 P1 S1 103.97(12) . . ?
C13 P1 S1 102.99(11) . . ?
C7 P1 Rh1 123.54(11) . . ?
C13 P1 Rh1 117.19(12) . . ?
S1 P1 Rh1 105.63(4) . . ?
C19 P2 C25 102.41(16) . . ?
C19 P2 S2 103.24(13) . . ?
C25 P2 S2 106.26(13) . . ?
C19 P2 Rh1 118.98(11) . . ?
C25 P2 Rh1 118.32(12) . . ?
S2 P2 Rh1 106.09(5) . . ?
C53 P3 C47 102.71(16) . . ?
C53 P3 S3 106.87(12) . . ?
C47 P3 S3 104.17(14) . . ?
C53 P3 Rh3 117.50(12) . . ?
C47 P3 Rh3 119.17(13) . . ?
S3 P3 Rh3 105.18(4) . . ?
C59 P4 C65 101.0(3) . . ?
C65 P4 C59' 102.9(3) . . ?
C59 P4 S4 97.6(2) . . ?
C65 P4 S4 104.84(13) . . ?
C59' P4 S4 110.3(2) . . ?
C59 P4 Rh3 125.9(3) . . ?
C65 P4 Rh3 118.29(12) . . ?
C59' P4 Rh3 114.4(3) . . ?
S4 P4 Rh3 105.68(5) . . ?
C6 C1 C2 114.0(3) . . ?
C6 C1 Rh1 122.8(3) . . ?
C2 C1 Rh1 123.2(2) . . ?
C3 C2 C1 123.3(3) . . ?
C3 C2 S1 113.6(3) . . ?
C1 C2 S1 123.1(3) . . ?
C4 C3 C2 119.8(4) . . ?
C4 C3 H3 120.1 . . ?
C2 C3 H3 120.1 . . ?
C5 C4 C3 119.7(4) . . ?
C5 C4 H4 120.2 . . ?
C3 C4 H4 120.2 . . ?
C4 C5 C6 120.2(4) . . ?
C4 C5 H5 119.9 . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C1 123.0(3) . . ?
C5 C6 S2 113.6(3) . . ?
C1 C6 S2 123.4(3) . . ?
C8 C7 C12 118.7(3) . . ?
C8 C7 P1 123.4(3) . . ?
C12 C7 P1 117.7(3) . . ?
C7 C8 C9 120.4(4) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 H8 119.8 . . ?
C10 C9 C8 120.2(4) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C11 C10 C9 119.6(4) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C10 C11 C12 120.6(4) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 H11 119.7 . . ?
C11 C12 C7 120.4(4) . . ?
C11 C12 H12 119.8 . . ?
C7 C12 H12 119.8 . . ?
C18 C13 C14 118.9(3) . . ?
C18 C13 P1 121.0(3) . . ?
C14 C13 P1 120.0(3) . . ?
C15 C14 C13 120.7(3) . . ?
C15 C14 H14 119.6 . . ?
C13 C14 H14 119.6 . . ?
C16 C15 C14 120.3(4) . . ?
C16 C15 H15 119.9 . . ?
C14 C15 H15 119.9 . . ?
C15 C16 C17 119.7(3) . . ?
C15 C16 H16 120.2 . . ?
C17 C16 H16 120.2 . . ?
C16 C17 C18 120.4(4) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C13 C18 C17 120.0(4) . . ?
C13 C18 H18 120.0 . . ?
C17 C18 H18 120.0 . . ?
C20 C19 C24 119.0(3) . . ?
C20 C19 P2 119.6(3) . . ?
C24 C19 P2 121.3(3) . . ?
C21 C20 C19 120.5(4) . . ?
C21 C20 H20 119.7 . . ?
C19 C20 H20 119.7 . . ?
C20 C21 C22 119.7(5) . . ?
C20 C21 H21 120.2 . . ?
C22 C21 H21 120.2 . . ?
C23 C22 C21 120.6(4) . . ?
C23 C22 H22 119.7 . . ?
C21 C22 H22 119.7 . . ?
C22 C23 C24 120.4(4) . . ?
C22 C23 H23 119.8 . . ?
C24 C23 H23 119.8 . . ?
C23 C24 C19 119.8(4) . . ?
C23 C24 H24 120.1 . . ?
C19 C24 H24 120.1 . . ?
C30 C25 C26 118.8(3) . . ?
C30 C25 P2 121.0(3) . . ?
C26 C25 P2 120.2(3) . . ?
C25 C26 C27 119.8(4) . . ?
C25 C26 H26 120.1 . . ?
C27 C26 H26 120.1 . . ?
C28 C27 C26 120.7(4) . . ?
C28 C27 H27 119.7 . . ?
C26 C27 H27 119.7 . . ?
C29 C28 C27 119.9(4) . . ?
C29 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C28 C29 C30 119.6(4) . . ?
C28 C29 H29 120.2 . . ?
C30 C29 H29 120.2 . . ?
C25 C30 C29 121.2(4) . . ?
C25 C30 H30 119.4 . . ?
C29 C30 H30 119.4 . . ?
C32 C31 C38 122.4(4) . . ?
C32 C31 Rh2 70.6(2) . . ?
C38 C31 Rh2 112.4(3) . . ?
C32 C31 H31 114.6 . . ?
C38 C31 H31 114.6 . . ?
Rh2 C31 H31 114.6 . . ?
C31 C32 C33 123.6(4) . . ?
C31 C32 Rh2 70.4(2) . . ?
C33 C32 Rh2 112.6(3) . . ?
C31 C32 H32 114.2 . . ?
C33 C32 H32 114.2 . . ?
Rh2 C32 H32 114.2 . . ?
C34 C33 C32 115.2(4) . . ?
C34 C33 H33A 108.5 . . ?
C32 C33 H33A 108.5 . . ?
C34 C33 H33B 108.5 . . ?
C32 C33 H33B 108.5 . . ?
H33A C33 H33B 107.5 . . ?
C33 C34 C35 114.5(3) . . ?
C33 C34 H34A 108.6 . . ?
C35 C34 H34A 108.6 . . ?
C33 C34 H34B 108.6 . . ?
C35 C34 H34B 108.6 . . ?
H34A C34 H34B 107.6 . . ?
C36 C35 C34 123.0(4) . . ?
C36 C35 Rh2 70.8(2) . . ?
C34 C35 Rh2 113.1(3) . . ?
C36 C35 H35 114.2 . . ?
C34 C35 H35 114.2 . . ?
Rh2 C35 H35 114.2 . . ?
C35 C36 C37 125.6(4) . . ?
C35 C36 Rh2 70.6(2) . . ?
C37 C36 Rh2 111.7(3) . . ?
C35 C36 H36 113.7 . . ?
C37 C36 H36 113.7 . . ?
Rh2 C36 H36 113.7 . . ?
C38 C37 C36 115.6(4) . . ?
C38 C37 H37A 108.4 . . ?
C36 C37 H37A 108.4 . . ?
C38 C37 H37B 108.4 . . ?
C36 C37 H37B 108.4 . . ?
H37A C37 H37B 107.4 . . ?
C37 C38 C31 114.8(4) . . ?
C37 C38 H38A 108.6 . . ?
C31 C38 H38A 108.6 . . ?
C37 C38 H38B 108.6 . . ?
C31 C38 H38B 108.6 . . ?
H38A C38 H38B 107.5 . . ?
C42 C41 C46 114.0(3) . . ?
C42 C41 Rh3 123.0(2) . . ?
C46 C41 Rh3 122.9(2) . . ?
C43 C42 C41 123.0(3) . . ?
C43 C42 S3 114.8(3) . . ?
C41 C42 S3 122.2(3) . . ?
C44 C43 C42 120.3(4) . . ?
C44 C43 H43 119.8 . . ?
C42 C43 H43 119.8 . . ?
C45 C44 C43 119.2(4) . . ?
C45 C44 H44 120.4 . . ?
C43 C44 H44 120.4 . . ?
C44 C45 C46 120.7(4) . . ?
C44 C45 H45 119.7 . . ?
C46 C45 H45 119.7 . . ?
C45 C46 C41 122.7(3) . . ?
C45 C46 S4 114.7(3) . . ?
C41 C46 S4 122.5(3) . . ?
C52 C47 C48 119.2(4) . . ?
C52 C47 P3 119.7(3) . . ?
C48 C47 P3 120.9(3) . . ?
C47 C48 C49 120.0(4) . . ?
C47 C48 H48 120.0 . . ?
C49 C48 H48 120.0 . . ?
C50 C49 C48 120.5(4) . . ?
C50 C49 H49 119.8 . . ?
C48 C49 H49 119.8 . . ?
C49 C50 C51 119.2(4) . . ?
C49 C50 H50 120.4 . . ?
C51 C50 H50 120.4 . . ?
C50 C51 C52 120.8(4) . . ?
C50 C51 H51 119.6 . . ?
C52 C51 H51 119.6 . . ?
C47 C52 C51 120.1(4) . . ?
C47 C52 H52 120.0 . . ?
C51 C52 H52 120.0 . . ?
C54 C53 C58 119.0(3) . . ?
C54 C53 P3 120.2(3) . . ?
C58 C53 P3 120.7(3) . . ?
C53 C54 C55 120.8(4) . . ?
C53 C54 H54 119.6 . . ?
C55 C54 H54 119.6 . . ?
C56 C55 C54 120.4(4) . . ?
C56 C55 H55 119.8 . . ?
C54 C55 H55 119.8 . . ?
C55 C56 C57 119.7(4) . . ?
C55 C56 H56 120.1 . . ?
C57 C56 H56 120.1 . . ?
C56 C57 C58 120.2(4) . . ?
C56 C57 H57 119.9 . . ?
C58 C57 H57 119.9 . . ?
C53 C58 C57 119.9(4) . . ?
C53 C58 H58 120.1 . . ?
C57 C58 H58 120.1 . . ?
C60 C59 C64 120.0 . . ?
C60 C59 P4 126.1(4) . . ?
C64 C59 P4 113.7(4) . . ?
C59 C60 C61 120.0 . . ?
C59 C60 H60 120.0 . . ?
C61 C60 H60 120.0 . . ?
C62 C61 C60 120.0 . . ?
C62 C61 H61 120.0 . . ?
C60 C61 H61 120.0 . . ?
C61 C62 C63 120.0 . . ?
C61 C62 H62 120.0 . . ?
C63 C62 H62 120.0 . . ?
C64 C63 C62 120.0 . . ?
C64 C63 H63 120.0 . . ?
C62 C63 H63 120.0 . . ?
C63 C64 C59 120.0 . . ?
C63 C64 H64 120.0 . . ?
C59 C64 H64 120.0 . . ?
C60' C59' C64' 120.0 . . ?
C60' C59' P4 119.7(4) . . ?
C64' C59' P4 120.2(4) . . ?
C59' C60' C61' 120.0 . . ?
C59' C60' H60' 120.0 . . ?
C61' C60' H60' 120.0 . . ?
C62' C61' C60' 120.0 . . ?
C62' C61' H61' 120.0 . . ?
C60' C61' H61' 120.0 . . ?
C63' C62' C61' 120.0 . . ?
C63' C62' H62' 120.0 . . ?
C61' C62' H62' 120.0 . . ?
C62' C63' C64' 120.0 . . ?
C62' C63' H63' 120.0 . . ?
C64' C63' H63' 120.0 . . ?
C63' C64' C59' 120.0 . . ?
C63' C64' H64' 120.0 . . ?
C59' C64' H64' 120.0 . . ?
C66 C65 C70 119.2(3) . . ?
C66 C65 P4 121.2(3) . . ?
C70 C65 P4 119.6(3) . . ?
C65 C66 C67 119.6(4) . . ?
C65 C66 H66 120.2 . . ?
C67 C66 H66 120.2 . . ?
C68 C67 C66 120.5(4) . . ?
C68 C67 H67 119.7 . . ?
C66 C67 H67 119.7 . . ?
C67 C68 C69 120.2(4) . . ?
C67 C68 H68 119.9 . . ?
C69 C68 H68 119.9 . . ?
C68 C69 C70 119.4(4) . . ?
C68 C69 H69 120.3 . . ?
C70 C69 H69 120.3 . . ?
C65 C70 C69 121.0(4) . . ?
C65 C70 H70 119.5 . . ?
C69 C70 H70 119.5 . . ?
C75 Rh4A C72 82.6(3) . . ?
C75 Rh4A C76 39.0(3) . . ?
C72 Rh4A C76 91.7(3) . . ?
C75 Rh4A C71 97.8(3) . . ?
C72 Rh4A C71 37.7(4) . . ?
C76 Rh4A C71 82.3(3) . . ?
C75 Rh4A Cl4 91.7(2) . . ?
C72 Rh4A Cl4 167.1(3) . . ?
C76 Rh4A Cl4 91.1(2) . . ?
C71 Rh4A Cl4 155.2(3) . . ?
C75 Rh4A Cl3 162.9(3) . . ?
C72 Rh4A Cl3 94.4(2) . . ?
C76 Rh4A Cl3 158.1(3) . . ?
C71 Rh4A Cl3 89.7(2) . . ?
Cl4 Rh4A Cl3 87.68(4) . . ?
C72 C71 C78 124.2(8) . . ?
C72 C71 Rh4A 70.3(5) . . ?
C78 C71 Rh4A 111.2(5) . . ?
C72 C71 H71 114.3 . . ?
C78 C71 H71 114.3 . . ?
Rh4A C71 H71 114.3 . . ?
C71 C72 C73 121.5(7) . . ?
C71 C72 Rh4A 72.0(5) . . ?
C73 C72 Rh4A 112.6(5) . . ?
C71 C72 H72 114.6 . . ?
C73 C72 H72 114.6 . . ?
Rh4A C72 H72 114.6 . . ?
C74 C73 C72 112.0(6) . . ?
C74 C73 H73A 109.2 . . ?
C72 C73 H73A 109.2 . . ?
C74 C73 H73B 109.2 . . ?
C72 C73 H73B 109.2 . . ?
H73A C73 H73B 107.9 . . ?
C75 C74 C73 113.7(7) . . ?
C75 C74 H74A 108.8 . . ?
C73 C74 H74A 108.8 . . ?
C75 C74 H74B 108.8 . . ?
C73 C74 H74B 108.8 . . ?
H74A C74 H74B 107.7 . . ?
C76 C75 C74 124.6(8) . . ?
C76 C75 Rh4A 71.3(4) . . ?
C74 C75 Rh4A 111.8(5) . . ?
C76 C75 H75 113.9 . . ?
C74 C75 H75 113.9 . . ?
Rh4A C75 H75 113.9 . . ?
C75 C76 C77 122.7(8) . . ?
C75 C76 Rh4A 69.7(4) . . ?
C77 C76 Rh4A 113.4(5) . . ?
C75 C76 H76 114.4 . . ?
C77 C76 H76 114.4 . . ?
Rh4A C76 H76 114.4 . . ?
C78 C77 C76 113.9(6) . . ?
C78 C77 H77A 108.8 . . ?
C76 C77 H77A 108.8 . . ?
C78 C77 H77B 108.8 . . ?
C76 C77 H77B 108.8 . . ?
H77A C77 H77B 107.7 . . ?
C77 C78 C71 113.5(7) . . ?
C77 C78 H78A 108.9 . . ?
C71 C78 H78A 108.9 . . ?
C77 C78 H78B 108.9 . . ?
C71 C78 H78B 108.9 . . ?
H78A C78 H78B 107.7 . . ?
C82 Rh4B C81 38.1(4) . . ?
C82 Rh4B C86 96.8(4) . . ?
C81 Rh4B C86 82.9(4) . . ?
C82 Rh4B C85 83.1(4) . . ?
C81 Rh4B C85 94.0(4) . . ?
C86 Rh4B C85 38.6(4) . . ?
C82 Rh4B Cl3 90.0(3) . . ?
C81 Rh4B Cl3 97.2(3) . . ?
C86 Rh4B Cl3 168.8(3) . . ?
C85 Rh4B Cl3 152.0(3) . . ?
C82 Rh4B Cl4 160.4(3) . . ?
C81 Rh4B Cl4 161.3(3) . . ?
C86 Rh4B Cl4 92.1(3) . . ?
C85 Rh4B Cl4 93.2(3) . . ?
Cl3 Rh4B Cl4 84.27(5) . . ?
C82 C81 C88 121.9(10) . . ?
C82 C81 Rh4B 70.7(7) . . ?
C88 C81 Rh4B 113.7(6) . . ?
C82 C81 H81 114.4 . . ?
C88 C81 H81 114.4 . . ?
Rh4B C81 H81 114.4 . . ?
C81 C82 C83 127.4(9) . . ?
C81 C82 Rh4B 71.2(6) . . ?
C83 C82 Rh4B 113.1(7) . . ?
C81 C82 H82 112.6 . . ?
C83 C82 H82 112.6 . . ?
Rh4B C82 H82 112.6 . . ?
C84 C83 C82 111.9(8) . . ?
C84 C83 H83A 109.2 . . ?
C82 C83 H83A 109.2 . . ?
C84 C83 H83B 109.2 . . ?
C82 C83 H83B 109.2 . . ?
H83A C83 H83B 107.9 . . ?
C83 C84 C85 115.8(8) . . ?
C83 C84 H84A 108.3 . . ?
C85 C84 H84A 108.3 . . ?
C83 C84 H84B 108.3 . . ?
C85 C84 H84B 108.3 . . ?
H84A C84 H84B 107.4 . . ?
C86 C85 C84 122.2(10) . . ?
C86 C85 Rh4B 70.0(5) . . ?
C84 C85 Rh4B 111.3(7) . . ?
C86 C85 H85 115.0 . . ?
C84 C85 H85 115.0 . . ?
Rh4B C85 H85 115.0 . . ?
C85 C86 C87 123.1(9) . . ?
C85 C86 Rh4B 71.4(5) . . ?
C87 C86 Rh4B 112.5(6) . . ?
C85 C86 H86 114.2 . . ?
C87 C86 H86 114.2 . . ?
Rh4B C86 H86 114.2 . . ?
C86 C87 C88 114.1(8) . . ?
C86 C87 H87A 108.7 . . ?
C88 C87 H87A 108.7 . . ?
C86 C87 H87B 108.7 . . ?
C88 C87 H87B 108.7 . . ?
H87A C87 H87B 107.6 . . ?
C81 C88 C87 114.2(8) . . ?
C81 C88 H88A 108.7 . . ?
C87 C88 H88A 108.7 . . ?
C81 C88 H88B 108.7 . . ?
C87 C88 H88B 108.7 . . ?
H88A C88 H88B 107.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -1.0(5) . . . . ?
Rh1 C1 C2 C3 -179.6(3) . . . . ?
C6 C1 C2 S1 178.4(3) . . . . ?
Rh1 C1 C2 S1 -0.2(4) . . . . ?
P1 S1 C2 C3 -179.4(3) . . . . ?
P1 S1 C2 C1 1.1(3) . . . . ?
C1 C2 C3 C4 -0.6(6) . . . . ?
S1 C2 C3 C4 180.0(4) . . . . ?
C2 C3 C4 C5 1.3(7) . . . . ?
C3 C4 C5 C6 -0.4(8) . . . . ?
C4 C5 C6 C1 -1.3(7) . . . . ?
C4 C5 C6 S2 -179.9(4) . . . . ?
C2 C1 C6 C5 1.9(5) . . . . ?
Rh1 C1 C6 C5 -179.5(3) . . . . ?
C2 C1 C6 S2 -179.6(3) . . . . ?
Rh1 C1 C6 S2 -1.0(4) . . . . ?
P2 S2 C6 C5 -171.4(3) . . . . ?
P2 S2 C6 C1 9.9(3) . . . . ?
C13 P1 C7 C8 -94.5(3) . . . . ?
S1 P1 C7 C8 12.0(3) . . . . ?
Rh1 P1 C7 C8 131.9(3) . . . . ?
C13 P1 C7 C12 81.1(3) . . . . ?
S1 P1 C7 C12 -172.3(2) . . . . ?
Rh1 P1 C7 C12 -52.5(3) . . . . ?
C12 C7 C8 C9 -1.3(6) . . . . ?
P1 C7 C8 C9 174.3(4) . . . . ?
C7 C8 C9 C10 1.1(7) . . . . ?
C8 C9 C10 C11 0.2(7) . . . . ?
C9 C10 C11 C12 -1.2(6) . . . . ?
C10 C11 C12 C7 1.0(6) . . . . ?
C8 C7 C12 C11 0.3(5) . . . . ?
P1 C7 C12 C11 -175.5(3) . . . . ?
C7 P1 C13 C18 -132.5(3) . . . . ?
S1 P1 C13 C18 120.2(3) . . . . ?
Rh1 P1 C13 C18 4.7(3) . . . . ?
C7 P1 C13 C14 50.4(3) . . . . ?
S1 P1 C13 C14 -56.9(3) . . . . ?
Rh1 P1 C13 C14 -172.4(2) . . . . ?
C18 C13 C14 C15 -1.8(5) . . . . ?
P1 C13 C14 C15 175.3(3) . . . . ?
C13 C14 C15 C16 1.1(6) . . . . ?
C14 C15 C16 C17 0.7(6) . . . . ?
C15 C16 C17 C18 -1.9(7) . . . . ?
C14 C13 C18 C17 0.7(6) . . . . ?
P1 C13 C18 C17 -176.4(3) . . . . ?
C16 C17 C18 C13 1.2(7) . . . . ?
C25 P2 C19 C20 -42.7(3) . . . . ?
S2 P2 C19 C20 -153.0(3) . . . . ?
Rh1 P2 C19 C20 89.9(3) . . . . ?
C25 P2 C19 C24 141.0(3) . . . . ?
S2 P2 C19 C24 30.7(3) . . . . ?
Rh1 P2 C19 C24 -86.4(3) . . . . ?
C24 C19 C20 C21 -0.2(6) . . . . ?
P2 C19 C20 C21 -176.6(3) . . . . ?
C19 C20 C21 C22 0.5(6) . . . . ?
C20 C21 C22 C23 -0.8(7) . . . . ?
C21 C22 C23 C24 1.0(7) . . . . ?
C22 C23 C24 C19 -0.7(6) . . . . ?
C20 C19 C24 C23 0.4(6) . . . . ?
P2 C19 C24 C23 176.7(3) . . . . ?
C19 P2 C25 C30 -73.7(3) . . . . ?
S2 P2 C25 C30 34.3(3) . . . . ?
Rh1 P2 C25 C30 153.3(3) . . . . ?
C19 P2 C25 C26 104.2(3) . . . . ?
S2 P2 C25 C26 -147.9(3) . . . . ?
Rh1 P2 C25 C26 -28.8(3) . . . . ?
C30 C25 C26 C27 0.3(6) . . . . ?
P2 C25 C26 C27 -177.6(3) . . . . ?
C25 C26 C27 C28 0.3(7) . . . . ?
C26 C27 C28 C29 -0.7(7) . . . . ?
C27 C28 C29 C30 0.4(6) . . . . ?
C26 C25 C30 C29 -0.6(6) . . . . ?
P2 C25 C30 C29 177.3(3) . . . . ?
C28 C29 C30 C25 0.2(6) . . . . ?
C38 C31 C32 C33 -0.1(6) . . . . ?
Rh2 C31 C32 C33 104.7(4) . . . . ?
C38 C31 C32 Rh2 -104.8(4) . . . . ?
C31 C32 C33 C34 -65.2(6) . . . . ?
Rh2 C32 C33 C34 15.6(6) . . . . ?
C32 C33 C34 C35 -8.4(7) . . . . ?
C33 C34 C35 C36 78.7(5) . . . . ?
C33 C34 C35 Rh2 -2.7(5) . . . . ?
C34 C35 C36 C37 -2.3(6) . . . . ?
Rh2 C35 C36 C37 103.3(4) . . . . ?
C34 C35 C36 Rh2 -105.6(3) . . . . ?
C35 C36 C37 C38 -61.0(6) . . . . ?
Rh2 C36 C37 C38 20.0(6) . . . . ?
C36 C37 C38 C31 -13.5(7) . . . . ?
C32 C31 C38 C37 80.9(6) . . . . ?
Rh2 C31 C38 C37 0.3(6) . . . . ?
C46 C41 C42 C43 2.0(5) . . . . ?
Rh3 C41 C42 C43 -175.3(3) . . . . ?
C46 C41 C42 S3 -176.7(2) . . . . ?
Rh3 C41 C42 S3 6.0(4) . . . . ?
P3 S3 C42 C43 161.3(2) . . . . ?
P3 S3 C42 C41 -19.9(3) . . . . ?
C41 C42 C43 C44 0.5(5) . . . . ?
S3 C42 C43 C44 179.3(3) . . . . ?
C42 C43 C44 C45 -2.4(6) . . . . ?
C43 C44 C45 C46 1.7(6) . . . . ?
C44 C45 C46 C41 1.0(6) . . . . ?
C44 C45 C46 S4 -176.3(3) . . . . ?
C42 C41 C46 C45 -2.7(5) . . . . ?
Rh3 C41 C46 C45 174.6(3) . . . . ?
C42 C41 C46 S4 174.3(2) . . . . ?
Rh3 C41 C46 S4 -8.4(4) . . . . ?
P4 S4 C46 C45 -174.9(2) . . . . ?
P4 S4 C46 C41 7.8(3) . . . . ?
C53 P3 C47 C52 -158.6(4) . . . . ?
S3 P3 C47 C52 -47.3(4) . . . . ?
Rh3 P3 C47 C52 69.5(4) . . . . ?
C53 P3 C47 C48 26.4(4) . . . . ?
S3 P3 C47 C48 137.7(3) . . . . ?
Rh3 P3 C47 C48 -105.5(3) . . . . ?
C52 C47 C48 C49 -2.0(7) . . . . ?
P3 C47 C48 C49 173.0(3) . . . . ?
C47 C48 C49 C50 -0.8(7) . . . . ?
C48 C49 C50 C51 2.9(8) . . . . ?
C49 C50 C51 C52 -2.1(9) . . . . ?
C48 C47 C52 C51 2.8(8) . . . . ?
P3 C47 C52 C51 -172.3(5) . . . . ?
C50 C51 C52 C47 -0.7(10) . . . . ?
C47 P3 C53 C54 70.1(3) . . . . ?
S3 P3 C53 C54 -39.2(3) . . . . ?
Rh3 P3 C53 C54 -157.0(3) . . . . ?
C47 P3 C53 C58 -106.6(3) . . . . ?
S3 P3 C53 C58 144.1(3) . . . . ?
Rh3 P3 C53 C58 26.3(3) . . . . ?
C58 C53 C54 C55 0.8(6) . . . . ?
P3 C53 C54 C55 -175.9(3) . . . . ?
C53 C54 C55 C56 -0.5(6) . . . . ?
C54 C55 C56 C57 0.3(7) . . . . ?
C55 C56 C57 C58 -0.4(7) . . . . ?
C54 C53 C58 C57 -0.9(6) . . . . ?
P3 C53 C58 C57 175.8(3) . . . . ?
C56 C57 C58 C53 0.7(6) . . . . ?
C65 P4 C59 C60 135.8(4) . . . . ?
C59' P4 C59 C60 -125(2) . . . . ?
S4 P4 C59 C60 29.0(5) . . . . ?
Rh3 P4 C59 C60 -86.7(5) . . . . ?
C65 P4 C59 C64 -48.3(5) . . . . ?
C59' P4 C59 C64 50.9(18) . . . . ?
S4 P4 C59 C64 -155.1(4) . . . . ?
Rh3 P4 C59 C64 89.2(5) . . . . ?
C64 C59 C60 C61 0.0 . . . . ?
P4 C59 C60 C61 175.6(6) . . . . ?
C59 C60 C61 C62 0.0 . . . . ?
C60 C61 C62 C63 0.0 . . . . ?
C61 C62 C63 C64 0.0 . . . . ?
C62 C63 C64 C59 0.0 . . . . ?
C60 C59 C64 C63 0.0 . . . . ?
P4 C59 C64 C63 -176.2(5) . . . . ?
C59 P4 C59' C60' 32(2) . . . . ?
C65 P4 C59' C60' 115.7(3) . . . . ?
S4 P4 C59' C60' 4.3(4) . . . . ?
Rh3 P4 C59' C60' -114.6(3) . . . . ?
C59 P4 C59' C64' -150(2) . . . . ?
C65 P4 C59' C64' -66.3(5) . . . . ?
S4 P4 C59' C64' -177.7(4) . . . . ?
Rh3 P4 C59' C64' 63.3(5) . . . . ?
C64' C59' C60' C61' 0.0 . . . . ?
P4 C59' C60' C61' 178.0(6) . . . . ?
C59' C60' C61' C62' 0.0 . . . . ?
C60' C61' C62' C63' 0.0 . . . . ?
C61' C62' C63' C64' 0.0 . . . . ?
C62' C63' C64' C59' 0.0 . . . . ?
C60' C59' C64' C63' 0.0 . . . . ?
P4 C59' C64' C63' -177.9(6) . . . . ?
C59 P4 C65 C66 123.3(4) . . . . ?
C59' P4 C65 C66 108.9(4) . . . . ?
S4 P4 C65 C66 -135.7(3) . . . . ?
Rh3 P4 C65 C66 -18.3(4) . . . . ?
C59 P4 C65 C70 -55.9(4) . . . . ?
C59' P4 C65 C70 -70.3(4) . . . . ?
S4 P4 C65 C70 45.2(4) . . . . ?
Rh3 P4 C65 C70 162.6(3) . . . . ?
C70 C65 C66 C67 -1.5(6) . . . . ?
P4 C65 C66 C67 179.4(3) . . . . ?
C65 C66 C67 C68 -0.5(6) . . . . ?
C66 C67 C68 C69 0.6(7) . . . . ?
C67 C68 C69 C70 1.2(8) . . . . ?
C66 C65 C70 C69 3.4(7) . . . . ?
P4 C65 C70 C69 -177.4(4) . . . . ?
C68 C69 C70 C65 -3.2(8) . . . . ?
C78 C71 C72 C73 3.1(12) . . . . ?
Rh4A C71 C72 C73 105.9(7) . . . . ?
C78 C71 C72 Rh4A -102.8(8) . . . . ?
C71 C72 C73 C74 -92.6(10) . . . . ?
Rh4A C72 C73 C74 -10.6(9) . . . . ?
C72 C73 C74 C75 26.6(10) . . . . ?
C73 C74 C75 C76 51.5(10) . . . . ?
C73 C74 C75 Rh4A -30.2(9) . . . . ?
C74 C75 C76 C77 1.4(11) . . . . ?
Rh4A C75 C76 C77 105.4(7) . . . . ?
C74 C75 C76 Rh4A -104.0(7) . . . . ?
C75 C76 C77 C78 -88.1(10) . . . . ?
Rh4A C76 C77 C78 -8.0(11) . . . . ?
C76 C77 C78 C71 22.7(12) . . . . ?
C72 C71 C78 C77 53.6(11) . . . . ?
Rh4A C71 C78 C77 -26.5(10) . . . . ?
C88 C81 C82 C83 -1.3(17) . . . . ?
Rh4B C81 C82 C83 105.2(11) . . . . ?
C88 C81 C82 Rh4B -106.5(9) . . . . ?
C81 C82 C83 C84 -59.0(15) . . . . ?
Rh4B C82 C83 C84 24.5(11) . . . . ?
C82 C83 C84 C85 -18.1(14) . . . . ?
C83 C84 C85 C86 82.8(13) . . . . ?
C83 C84 C85 Rh4B 3.7(13) . . . . ?
C84 C85 C86 C87 2.0(14) . . . . ?
Rh4B C85 C86 C87 105.2(9) . . . . ?
C84 C85 C86 Rh4B -103.1(9) . . . . ?
C85 C86 C87 C88 -63.9(13) . . . . ?
Rh4B C86 C87 C88 17.9(12) . . . . ?
C82 C81 C88 C87 82.6(13) . . . . ?
Rh4B C81 C88 C87 1.4(13) . . . . ?
C86 C87 C88 C81 -12.7(14) . . . . ?

_refine_diff_density_max         0.993
_refine_diff_density_min         -0.802
_refine_diff_density_rms         0.096

_shelxl_version_number           2014-3

