# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_a
_audit_block_doi                 10.5517/ccdc.csd.cc1zly7r
_database_code_depnum_ccdc_archive 'CCDC 1835455'
_audit_update_record             
;
2018-06-13 deposited with the CCDC.
2018-07-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C57 H45 Dy2 F36 N6 O18'
_chemical_formula_weight         2110.99

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_H-M_alt        'P 2/c'
_space_group_name_Hall           '-P 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'

_cell_length_a                   10.927(3)
_cell_length_b                   12.297(3)
_cell_length_c                   30.796(7)
_cell_angle_alpha                90
_cell_angle_beta                 100.219(2)
_cell_angle_gamma                90
_cell_volume                     4072.5(16)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    6768
_cell_measurement_theta_min      2.51
_cell_measurement_theta_max      24.07

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.721
_exptl_crystal_F_000             2058
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.230
_exptl_absorpt_coefficient_mu    1.966
_shelx_estimated_absorpt_T_min   0.609
_shelx_estimated_absorpt_T_max   0.661
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5079
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            18851
_diffrn_reflns_av_unetI/netI     0.1318
_diffrn_reflns_av_R_equivalents  0.0556
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_theta_min         1.344
_diffrn_reflns_theta_max         27.568
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.747
_diffrn_measured_fraction_theta_full 0.698
_diffrn_reflns_Laue_measured_fraction_max 0.747
_diffrn_reflns_Laue_measured_fraction_full 0.698
_diffrn_reflns_point_group_measured_fraction_max 0.747
_diffrn_reflns_point_group_measured_fraction_full 0.698
_reflns_number_total             7042
_reflns_number_gt                3981
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0400P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7042
_refine_ls_number_parameters     572
_refine_ls_number_restraints     627
_refine_ls_R_factor_all          0.0970
_refine_ls_R_factor_gt           0.0572
_refine_ls_wR_factor_ref         0.1430
_refine_ls_wR_factor_gt          0.1330
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_restrained_S_all      1.068
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.57838(4) 0.77135(3) 0.38528(2) 0.04098(14) Uani 1 1 d . U . . .
O5 O 0.5057(5) 0.5905(4) 0.3705(2) 0.0516(14) Uani 1 1 d . U . . .
N2 N 0.7515(6) 0.5639(5) 0.3449(2) 0.0371(13) Uani 1 1 d . U . . .
O4 O 0.4353(6) 0.7350(5) 0.4330(2) 0.0630(14) Uani 1 1 d . U . . .
O8 O 0.7372(5) 0.6629(4) 0.35934(16) 0.0419(11) Uani 1 1 d . U . . .
O1 O 0.6947(6) 0.7161(4) 0.45238(18) 0.0540(14) Uani 1 1 d . U . . .
O2 O 0.7547(6) 0.8803(4) 0.39846(18) 0.0552(15) Uani 1 1 d . U . . .
O7 O 0.6013(6) 0.8881(4) 0.32260(17) 0.0497(14) Uani 1 1 d . U . . .
O3 O 0.5096(7) 0.9373(5) 0.4073(2) 0.0654(16) Uani 1 1 d . U . . .
N1 N 0.5457(6) 0.9210(5) 0.28444(19) 0.0436(15) Uani 1 1 d . U . . .
N3 N 0.7330(6) 0.4149(5) 0.3054(2) 0.0470(16) Uani 1 1 d . U . . .
C21 C 0.6004(7) 0.6818(6) 0.2736(2) 0.0365(16) Uani 1 1 d . U . . .
H21 H 0.6707 0.7187 0.2876 0.044 Uiso 1 1 calc R U . . .
O6 O 0.3853(6) 0.7822(5) 0.3377(2) 0.0595(15) Uani 1 1 d . U . . .
O9 O 0.6962(6) 0.3457(4) 0.2737(2) 0.069(2) Uani 1 1 d . U . . .
C24 C 0.6924(7) 0.5169(6) 0.3083(2) 0.0368(15) Uani 1 1 d . U . . .
C4 C 0.8471(9) 0.8863(7) 0.4275(3) 0.060(2) Uani 1 1 d . U . . .
F15 F 0.4657(9) 0.3751(6) 0.3421(3) 0.121(3) Uani 1 1 d . U . . .
C3 C 0.8751(9) 0.8235(8) 0.4663(3) 0.062(2) Uani 1 1 d . U . . .
H3 H 0.9470 0.8375 0.4866 0.075 Uiso 1 1 calc R U . . .
C28 C 0.8410(7) 0.4839(6) 0.3723(3) 0.0437(16) Uani 1 1 d . U . . .
F18 F 0.1905(8) 0.8220(9) 0.2726(3) 0.158(3) Uani 1 1 d . U . . .
C12 C 0.4062(9) 0.5529(8) 0.3588(3) 0.064(2) Uani 1 1 d . U . . .
C19 C 0.5000 0.8592(8) 0.2500 0.042(2) Uani 1 2 d S TU P . .
C13 C 0.2959(10) 0.6122(9) 0.3404(4) 0.080(3) Uani 1 1 d . U . . .
H13 H 0.2206 0.5751 0.3351 0.096 Uiso 1 1 calc R U . . .
C7 C 0.3642(12) 0.7924(10) 0.4527(4) 0.079(2) Uani 1 1 d . U . . .
F14 F 0.2837(7) 0.3882(6) 0.3600(4) 0.146(3) Uani 1 1 d . U . . .
C25 C 0.8499(9) 0.3935(7) 0.3372(3) 0.0559(19) Uani 1 1 d . U . . .
C9 C 0.4262(13) 0.9655(9) 0.4300(4) 0.084(2) Uani 1 1 d . U . . .
C2 C 0.7963(10) 0.7419(7) 0.4740(3) 0.0564(19) Uani 1 1 d . U . . .
C17 C 0.5479(9) 1.0400(6) 0.2721(3) 0.055(2) Uani 1 1 d . U . . .
F3A F 0.864(2) 0.7335(15) 0.5514(5) 0.107(4) Uani 0.55(2) 1 d D U P A 1
C20 C 0.5000 0.7403(8) 0.2500 0.039(2) Uani 1 2 d S TU P . .
F5 F 0.8950(11) 1.0690(8) 0.4296(4) 0.168(3) Uani 1 1 d . U . . .
F4 F 1.0371(8) 0.9824(8) 0.4479(3) 0.155(4) Uani 1 1 d . U . . .
F2A F 0.7419(18) 0.6146(16) 0.5281(6) 0.101(4) Uani 0.55(2) 1 d . U P A 1
C22 C 0.5960(7) 0.5701(6) 0.2762(2) 0.0358(15) Uani 1 1 d . U . . .
C14 C 0.2962(10) 0.7172(9) 0.3306(4) 0.079(2) Uani 1 1 d . U . . .
C5 C 0.9459(14) 0.9639(12) 0.4188(5) 0.104(3) Uani 1 1 d . U . . .
C30 C 0.7739(11) 0.4464(9) 0.4085(3) 0.077(3) Uani 1 1 d . U . . .
H30A H 0.8317 0.4108 0.4312 0.116 Uiso 1 1 calc R U . . .
H30B H 0.7092 0.3964 0.3965 0.116 Uiso 1 1 calc R U . . .
H30C H 0.7382 0.5080 0.4208 0.116 Uiso 1 1 calc R U . . .
C23 C 0.5000 0.5131(8) 0.2500 0.041(2) Uani 1 2 d S TU P . .
H23 H 0.5000 0.4375 0.2500 0.049 Uiso 1 2 calc R U P . .
C1 C 0.8372(12) 0.6754(9) 0.5160(3) 0.077(2) Uani 1 1 d D U . . .
F13 F 0.4441(9) 0.3986(6) 0.4073(3) 0.134(3) Uani 1 1 d . U . . .
F9 F 0.3218(14) 1.1184(7) 0.3998(4) 0.190(4) Uani 1 1 d . U . . .
C27 C 0.8564(11) 0.2774(7) 0.3550(4) 0.088(3) Uani 1 1 d . U . . .
H27A H 0.7847 0.2633 0.3682 0.132 Uiso 1 1 calc R U . . .
H27B H 0.9303 0.2689 0.3768 0.132 Uiso 1 1 calc R U . . .
H27C H 0.8581 0.2272 0.3313 0.132 Uiso 1 1 calc R U . . .
C15 C 0.1692(15) 0.7662(14) 0.3085(6) 0.122(3) Uani 1 1 d . U . . .
F10 F 0.2196(11) 0.7772(9) 0.5011(4) 0.168(4) Uani 1 1 d . U . . .
C10 C 0.394(2) 1.0834(12) 0.4314(6) 0.126(3) Uani 1 1 d . U . . .
F11 F 0.3445(10) 0.6509(9) 0.5021(4) 0.162(3) Uani 1 1 d . U . . .
C26 C 0.9642(11) 0.4157(10) 0.3106(4) 0.092(3) Uani 1 1 d . U . . .
H26A H 1.0389 0.4303 0.3313 0.139 Uiso 1 1 calc R U . . .
H26B H 0.9445 0.4772 0.2914 0.139 Uiso 1 1 calc R U . . .
H26C H 0.9763 0.3528 0.2934 0.139 Uiso 1 1 calc R U . . .
F7 F 0.3688(13) 1.1199(7) 0.4661(3) 0.182(4) Uani 1 1 d . U . . .
F16 F 0.0919(9) 0.7081(10) 0.2957(5) 0.208(4) Uani 1 1 d . U . . .
C16 C 0.5140(13) 1.1078(7) 0.3078(3) 0.083(3) Uani 1 1 d . U . . .
H16A H 0.4256 1.1050 0.3066 0.125 Uiso 1 1 calc R U . . .
H16B H 0.5389 1.1817 0.3043 0.125 Uiso 1 1 calc R U . . .
H16C H 0.5554 1.0807 0.3359 0.125 Uiso 1 1 calc R U . . .
C18 C 0.6776(11) 1.0653(8) 0.2658(4) 0.085(3) Uani 1 1 d . U . . .
H18A H 0.7357 1.0249 0.2867 0.128 Uiso 1 1 calc R U . . .
H18B H 0.6932 1.1417 0.2701 0.128 Uiso 1 1 calc R U . . .
H18C H 0.6872 1.0456 0.2364 0.128 Uiso 1 1 calc R U . . .
F8 F 0.5004(13) 1.1405(7) 0.4280(4) 0.180(4) Uani 1 1 d . U . . .
C8 C 0.3578(12) 0.8990(10) 0.4537(4) 0.089(3) Uani 1 1 d . U . . .
H8 H 0.3059 0.9315 0.4708 0.107 Uiso 1 1 calc R U . . .
C11 C 0.3893(13) 0.4259(10) 0.3653(5) 0.091(3) Uani 1 1 d . U . . .
C29 C 0.9592(9) 0.5466(8) 0.3901(4) 0.070(3) Uani 1 1 d . U . . .
H29A H 0.9906 0.5796 0.3660 0.106 Uiso 1 1 calc R U . . .
H29B H 1.0205 0.4976 0.4055 0.106 Uiso 1 1 calc R U . . .
H29C H 0.9414 0.6020 0.4100 0.106 Uiso 1 1 calc R U . . .
C6 C 0.2851(16) 0.7227(14) 0.4749(5) 0.107(3) Uani 1 1 d . U . . .
F12 F 0.2028(11) 0.6719(11) 0.4501(4) 0.189(4) Uani 1 1 d . U . . .
F17 F 0.1405(11) 0.8500(12) 0.3241(5) 0.207(4) Uani 1 1 d . U . . .
F6 F 0.9450(10) 0.9976(9) 0.3831(3) 0.171(4) Uani 1 1 d . U . . .
F2B F 0.856(3) 0.5735(15) 0.5065(6) 0.099(5) Uani 0.45(2) 1 d . U P A 2
F1B F 0.928(2) 0.7184(18) 0.5440(7) 0.103(5) Uani 0.45(2) 1 d . U P A 2
F3B F 0.738(3) 0.669(2) 0.5369(8) 0.111(5) Uani 0.45(2) 1 d . U P A 2
F1A F 0.931(2) 0.6090(15) 0.5100(6) 0.105(4) Uani 0.55(2) 1 d . U P A 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O3 2.317(6) . ?
Dy1 O2 2.323(6) . ?
Dy1 O1 2.327(5) . ?
Dy1 O6 2.349(5) . ?
Dy1 O4 2.371(7) . ?
Dy1 O5 2.379(5) . ?
Dy1 O8 2.433(6) . ?
Dy1 O7 2.454(5) . ?
O5 C12 1.177(10) . ?
N2 O8 1.316(7) . ?
N2 C24 1.326(8) . ?
N2 C28 1.531(9) . ?
O4 C7 1.280(13) . ?
O1 C2 1.231(10) . ?
O2 C4 1.227(9) . ?
O7 N1 1.288(7) . ?
O3 C9 1.290(14) . ?
N1 C19 1.328(8) . ?
N1 C17 1.514(9) . ?
N3 O9 1.303(8) . ?
N3 C24 1.339(9) . ?
N3 C25 1.489(10) . ?
C21 C22 1.376(10) . ?
C21 C20 1.403(8) . ?
C21 H21 0.9300 . ?
O6 C14 1.248(12) . ?
C24 C22 1.465(9) . ?
C4 C3 1.409(12) . ?
C4 C5 1.500(15) . ?
F15 C11 1.345(16) . ?
C3 C2 1.370(13) . ?
C3 H3 0.9300 . ?
C28 C30 1.510(13) . ?
C28 C29 1.520(11) . ?
C28 C25 1.567(12) . ?
F18 C15 1.36(2) . ?
C12 C13 1.436(14) . ?
C12 C11 1.590(15) . ?
C19 N1 1.328(8) 2_655 ?
C19 C20 1.462(14) . ?
C13 C14 1.326(14) . ?
C13 H13 0.9300 . ?
C7 C8 1.314(15) . ?
C7 C6 1.468(19) . ?
F14 C11 1.228(14) . ?
C25 C27 1.526(13) . ?
C25 C26 1.633(16) . ?
C9 C8 1.398(17) . ?
C9 C10 1.494(17) . ?
C2 C1 1.528(13) . ?
C17 C16 1.480(13) . ?
C17 C18 1.497(14) . ?
C17 C17 1.562(15) 2_655 ?
F3A C1 1.294(9) . ?
C20 C21 1.403(8) 2_655 ?
F5 C5 1.47(2) . ?
F4 C5 1.236(12) . ?
F2A C1 1.39(2) . ?
C22 C23 1.394(8) . ?
C14 C15 1.555(17) . ?
C5 F6 1.175(14) . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C23 C22 1.394(8) 2_655 ?
C23 H23 0.9300 . ?
C1 F1B 1.31(2) . ?
C1 F2B 1.31(2) . ?
C1 F1A 1.350(19) . ?
C1 F3B 1.36(3) . ?
F13 C11 1.368(15) . ?
F9 C10 1.218(19) . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C15 F16 1.122(17) . ?
C15 F17 1.202(19) . ?
F10 C6 1.348(17) . ?
C10 F7 1.237(18) . ?
C10 F8 1.38(2) . ?
F11 C6 1.307(17) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C8 H8 0.9300 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C6 F12 1.241(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Dy1 O2 75.1(2) . . ?
O3 Dy1 O1 98.7(2) . . ?
O2 Dy1 O1 73.0(2) . . ?
O3 Dy1 O6 80.2(2) . . ?
O2 Dy1 O6 134.58(19) . . ?
O1 Dy1 O6 149.2(2) . . ?
O3 Dy1 O4 72.6(2) . . ?
O2 Dy1 O4 128.2(2) . . ?
O1 Dy1 O4 73.2(2) . . ?
O6 Dy1 O4 77.2(2) . . ?
O3 Dy1 O5 139.9(2) . . ?
O2 Dy1 O5 144.2(2) . . ?
O1 Dy1 O5 90.5(2) . . ?
O6 Dy1 O5 72.62(19) . . ?
O4 Dy1 O5 73.0(2) . . ?
O3 Dy1 O8 150.0(2) . . ?
O2 Dy1 O8 75.8(2) . . ?
O1 Dy1 O8 79.77(19) . . ?
O6 Dy1 O8 116.2(2) . . ?
O4 Dy1 O8 133.43(19) . . ?
O5 Dy1 O8 69.99(19) . . ?
O3 Dy1 O7 78.4(2) . . ?
O2 Dy1 O7 66.59(18) . . ?
O1 Dy1 O7 138.9(2) . . ?
O6 Dy1 O7 71.5(2) . . ?
O4 Dy1 O7 140.2(2) . . ?
O5 Dy1 O7 118.27(19) . . ?
O8 Dy1 O7 83.34(19) . . ?
C12 O5 Dy1 133.2(6) . . ?
O8 N2 C24 128.5(6) . . ?
O8 N2 C28 120.6(5) . . ?
C24 N2 C28 110.9(6) . . ?
C7 O4 Dy1 135.5(7) . . ?
N2 O8 Dy1 138.8(4) . . ?
C2 O1 Dy1 134.7(6) . . ?
C4 O2 Dy1 135.4(6) . . ?
N1 O7 Dy1 143.5(5) . . ?
C9 O3 Dy1 133.8(7) . . ?
O7 N1 C19 126.8(6) . . ?
O7 N1 C17 120.5(5) . . ?
C19 N1 C17 111.9(6) . . ?
O9 N3 C24 126.9(6) . . ?
O9 N3 C25 119.4(6) . . ?
C24 N3 C25 112.2(6) . . ?
C22 C21 C20 120.7(7) . . ?
C22 C21 H21 119.7 . . ?
C20 C21 H21 119.7 . . ?
C14 O6 Dy1 131.3(6) . . ?
N2 C24 N3 110.4(6) . . ?
N2 C24 C22 124.1(6) . . ?
N3 C24 C22 125.5(6) . . ?
O2 C4 C3 127.8(9) . . ?
O2 C4 C5 115.7(8) . . ?
C3 C4 C5 116.4(8) . . ?
C2 C3 C4 119.9(8) . . ?
C2 C3 H3 120.0 . . ?
C4 C3 H3 120.0 . . ?
C30 C28 C29 112.5(8) . . ?
C30 C28 N2 104.9(7) . . ?
C29 C28 N2 107.0(6) . . ?
C30 C28 C25 113.0(8) . . ?
C29 C28 C25 117.1(8) . . ?
N2 C28 C25 100.7(6) . . ?
O5 C12 C13 125.9(9) . . ?
O5 C12 C11 118.0(9) . . ?
C13 C12 C11 116.1(9) . . ?
N1 C19 N1 110.2(9) 2_655 . ?
N1 C19 C20 124.9(4) 2_655 . ?
N1 C19 C20 124.9(4) . . ?
C14 C13 C12 123.3(10) . . ?
C14 C13 H13 118.4 . . ?
C12 C13 H13 118.4 . . ?
O4 C7 C8 126.8(12) . . ?
O4 C7 C6 110.8(12) . . ?
C8 C7 C6 122.3(13) . . ?
N3 C25 C27 112.4(7) . . ?
N3 C25 C28 100.2(6) . . ?
C27 C25 C28 114.8(8) . . ?
N3 C25 C26 106.5(8) . . ?
C27 C25 C26 110.3(9) . . ?
C28 C25 C26 112.0(7) . . ?
O3 C9 C8 128.3(11) . . ?
O3 C9 C10 118.0(13) . . ?
C8 C9 C10 113.8(14) . . ?
O1 C2 C3 129.1(8) . . ?
O1 C2 C1 114.8(9) . . ?
C3 C2 C1 116.1(8) . . ?
C16 C17 C18 110.3(9) . . ?
C16 C17 N1 109.9(7) . . ?
C18 C17 N1 107.0(8) . . ?
C16 C17 C17 115.4(10) . 2_655 ?
C18 C17 C17 113.0(10) . 2_655 ?
N1 C17 C17 100.4(4) . 2_655 ?
C21 C20 C21 118.2(9) 2_655 . ?
C21 C20 C19 120.9(4) 2_655 . ?
C21 C20 C19 120.9(4) . . ?
C21 C22 C23 119.9(7) . . ?
C21 C22 C24 117.2(6) . . ?
C23 C22 C24 122.9(7) . . ?
O6 C14 C13 128.0(10) . . ?
O6 C14 C15 115.9(11) . . ?
C13 C14 C15 116.1(11) . . ?
F6 C5 F4 118.9(13) . . ?
F6 C5 F5 87.7(12) . . ?
F4 C5 F5 87.9(11) . . ?
F6 C5 C4 120.4(10) . . ?
F4 C5 C4 120.1(11) . . ?
F5 C5 C4 101.9(13) . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C22 C23 C22 119.6(9) 2_655 . ?
C22 C23 H23 120.2 2_655 . ?
C22 C23 H23 120.2 . . ?
F1B C1 F2B 113.8(15) . . ?
F3A C1 F1A 112.5(13) . . ?
F1B C1 F3B 106.7(17) . . ?
F2B C1 F3B 102.7(16) . . ?
F3A C1 F2A 98.1(15) . . ?
F1A C1 F2A 109.6(13) . . ?
F3A C1 C2 114.1(12) . . ?
F1B C1 C2 114.6(13) . . ?
F2B C1 C2 110.8(10) . . ?
F1A C1 C2 108.8(11) . . ?
F3B C1 C2 107.1(13) . . ?
F2A C1 C2 113.3(10) . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
F16 C15 F17 117(2) . . ?
F16 C15 F18 105.4(16) . . ?
F17 C15 F18 89.2(14) . . ?
F16 C15 C14 117.6(15) . . ?
F17 C15 C14 115.7(14) . . ?
F18 C15 C14 106.5(14) . . ?
F9 C10 F7 110.5(16) . . ?
F9 C10 F8 101.3(16) . . ?
F7 C10 F8 101.7(16) . . ?
F9 C10 C9 116.2(15) . . ?
F7 C10 C9 117.8(15) . . ?
F8 C10 C9 106.7(15) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C17 C16 H16A 109.5 . . ?
C17 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C17 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C7 C8 C9 122.5(12) . . ?
C7 C8 H8 118.7 . . ?
C9 C8 H8 118.7 . . ?
F14 C11 F15 114.4(12) . . ?
F14 C11 F13 106.0(13) . . ?
F15 C11 F13 100.4(11) . . ?
F14 C11 C12 118.8(11) . . ?
F15 C11 C12 107.0(11) . . ?
F13 C11 C12 108.5(10) . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
F12 C6 F11 106.1(15) . . ?
F12 C6 F10 102.4(14) . . ?
F11 C6 F10 102.1(13) . . ?
F12 C6 C7 115.4(13) . . ?
F11 C6 C7 115.2(14) . . ?
F10 C6 C7 114.0(14) . . ?

_refine_diff_density_max         0.993
_refine_diff_density_min         -0.654
_refine_diff_density_rms         0.114


# start Validation Reply Form
_vrf_PLAT601_1_a                 
;
PROBLEM:  Structure Contains Solvent Accessible VOIDS of .        141 Ang**3
RESPONSE: We have checked the model of the structure. Besides the Q peaks
 very close to the Dy3+ center, the remaining Q peaks are too weak
 (less than 0.73) to be identified as any possible solvent molecules.
;



###END


#==============================================================================

