# Supplementary Information (SI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelxl
_audit_block_doi                 10.5517/ccdc.csd.cc1pxqv5
_database_code_depnum_ccdc_archive 'CCDC 1576748'
loop_
_audit_author_name
_audit_author_address
'Yasuchika Hasegawa'
;Hokkaido University
Japan
;
_audit_update_record             
;
2025-04-10 deposited with the CCDC.	2025-07-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H70 Eu F9 O8 P2'
_chemical_formula_sum            'C72 H70 Eu F9 O8 P2'
_chemical_formula_weight         1448.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   12.8216(4)
_cell_length_b                   20.3431(5)
_cell_length_c                   13.1283(3)
_cell_angle_alpha                90
_cell_angle_beta                 91.2951(10)
_cell_angle_gamma                90
_cell_volume                     3423.39(15)
_cell_formula_units_Z            2
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    30471
_cell_measurement_theta_min      3.00
_cell_measurement_theta_max      27.47

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.405
_exptl_crystal_F_000             1480
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.409
_exptl_crystal_size_mid          0.346
_exptl_crystal_size_min          0.185
_exptl_absorpt_coefficient_mu    1.041
_shelx_estimated_absorpt_T_min   0.676
_shelx_estimated_absorpt_T_max   0.831
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.627
_exptl_absorpt_correction_T_max  0.825
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.000
_diffrn_reflns_number            32337
_diffrn_reflns_av_unetI/netI     0.0533
_diffrn_reflns_av_R_equivalents  0.0283
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         3.009
_diffrn_reflns_theta_max         27.468
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_point_group_measured_fraction_full 0.991
_reflns_number_total             15400
_reflns_number_gt                14200
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.923
_reflns_Friedel_fraction_max     0.970
_reflns_Friedel_fraction_full    0.986

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 6244 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.013(3)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         15400
_refine_ls_number_parameters     829
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0339
_refine_ls_R_factor_gt           0.0292
_refine_ls_wR_factor_ref         0.0880
_refine_ls_wR_factor_gt          0.0814
_refine_ls_goodness_of_fit_ref   0.676
_refine_ls_restrained_S_all      0.676
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.74923(2) 0.86197(2) 0.34060(2) 0.01988(6) Uani 1 1 d . . . . .
P1 P 0.87245(9) 0.78233(5) 0.56805(9) 0.0246(2) Uani 1 1 d . . . . .
P67 P 0.53937(9) 0.87158(6) 0.13537(9) 0.0268(3) Uani 1 1 d . . . . .
F18 F 1.0104(4) 0.84774(19) 0.0807(4) 0.093(2) Uani 1 1 d . . . . .
F61 F 1.0813(4) 0.9380(3) 0.4839(4) 0.098(2) Uani 1 1 d . . . . .
F63 F 0.9211(4) 0.7820(2) -0.0153(3) 0.0649(11) Uani 1 1 d . . . . .
F65 F 1.1419(4) 0.9452(5) 0.3441(5) 0.130(3) Uani 1 1 d . . . . .
F76 F 1.1000(6) 1.0291(3) 0.4125(7) 0.140(4) Uani 1 1 d . . . . .
F81 F 0.6455(5) 1.07361(17) 0.4815(3) 0.0711(14) Uani 1 1 d . . . . .
F84 F 0.7012(6) 1.0323(2) 0.6154(4) 0.107(3) Uani 1 1 d . . . . .
F86 F 0.5420(6) 1.0490(3) 0.5938(8) 0.157(4) Uani 1 1 d . . . . .
F90 F 1.0417(3) 0.7453(2) 0.0847(3) 0.0533(9) Uani 1 1 d . . . . .
O6 O 0.8726(3) 0.83089(16) 0.2178(3) 0.0311(7) Uani 1 1 d . . . . .
O8 O 0.6257(3) 0.84953(15) 0.2050(3) 0.0290(7) Uani 1 1 d . . . . .
O10 O 0.6858(3) 0.95066(16) 0.4346(3) 0.0286(7) Uani 1 1 d . . . . .
O15 O 0.7395(3) 0.74248(16) 0.3231(3) 0.0281(7) Uani 1 1 d . . . . .
O26 O 0.8015(3) 0.82136(15) 0.4996(3) 0.0293(7) Uani 1 1 d . . . . .
O34 O 0.9078(3) 0.91696(15) 0.3886(3) 0.0263(7) Uani 1 1 d . . . . .
O47 O 0.7642(2) 0.95404(15) 0.2269(2) 0.0246(6) Uani 1 1 d . . . . .
O52 O 0.5822(3) 0.82761(16) 0.4132(3) 0.0301(7) Uani 1 1 d . . . . .
C2 C 0.7403(5) 0.6335(2) 0.2437(4) 0.0346(11) Uani 1 1 d . . . . .
C3 C 0.2973(6) 0.7083(4) 0.1046(8) 0.070(2) Uani 1 1 d . . . . .
H3 H 0.2455 0.6749 0.1004 0.084 Uiso 1 1 calc R U . . .
C4 C 1.0265(5) 1.0217(3) 0.1085(4) 0.0429(13) Uani 1 1 d . . . . .
H4A H 1.0639 0.9798 0.1211 0.052 Uiso 1 1 calc R U . . .
H4B H 1.0717 1.0516 0.0697 0.052 Uiso 1 1 calc R U . . .
C5 C 0.9615(4) 0.9616(2) 0.3493(4) 0.0256(9) Uani 1 1 d . . . . .
C7 C 1.1269(5) 0.6777(3) 0.3923(5) 0.0461(15) Uani 1 1 d . . . . .
H7 H 1.1810 0.6567 0.3563 0.055 Uiso 1 1 calc R U . . .
C9 C 0.6881(3) 0.6138(2) 0.7105(4) 0.0251(9) Uani 1 1 d . . . . .
C11 C 0.6325(4) 0.5547(2) 0.7487(4) 0.0268(9) Uani 1 1 d . . . . .
C12 C 0.8853(4) 0.7807(2) 0.1630(4) 0.0281(9) Uani 1 1 d . . . . .
C13 C 0.9715(4) 0.7391(2) 0.5006(4) 0.0294(9) Uani 1 1 d . . . . .
C14 C 0.8139(4) 0.7010(2) 0.7335(4) 0.0292(10) Uani 1 1 d . . . . .
H14 H 0.8623 0.7240 0.7762 0.035 Uiso 1 1 calc R U . . .
C16 C 0.3408(4) 0.8674(4) 0.4744(5) 0.0456(12) Uani 1 1 d . . . . .
H16A H 0.3501 0.8738 0.4004 0.055 Uiso 1 1 calc R U . . .
H16B H 0.2712 0.8478 0.4852 0.055 Uiso 1 1 calc R U . . .
C17 C 0.7980(4) 0.7205(2) 0.6323(4) 0.0261(9) Uani 1 1 d . . . . .
C19 C 0.9369(4) 0.8354(2) 0.6594(4) 0.0271(10) Uani 1 1 d . . . . .
C20 C 0.6883(4) 0.5067(2) 0.8029(4) 0.0315(11) Uani 1 1 d . . . . .
H20 H 0.7607 0.5126 0.8168 0.038 Uiso 1 1 calc R U . . .
C21 C 0.6155(4) 0.9599(2) 0.5013(3) 0.0256(9) Uani 1 1 d . . . . .
C22 C 0.8464(6) 0.5978(3) 0.2698(5) 0.0451(17) Uani 1 1 d . . . . .
H22A H 0.8785 0.6157 0.3333 0.054 Uiso 1 1 calc R U . . .
H22B H 0.8356 0.5500 0.2782 0.054 Uiso 1 1 calc R U . . .
C23 C 0.6685(4) 0.6355(2) 0.6114(4) 0.0324(10) Uani 1 1 d . . . . .
H23 H 0.6170 0.6139 0.5705 0.039 Uiso 1 1 calc R U . . .
C24 C 0.4463(4) 0.8063(3) 0.1179(4) 0.0353(11) Uani 1 1 d . . . . .
C25 C 0.8405(6) 1.1305(3) 0.2609(6) 0.0471(17) Uani 1 1 d . . . . .
H25A H 0.8197 1.0967 0.3097 0.057 Uiso 1 1 calc R U . . .
H25B H 0.8857 1.1627 0.2955 0.057 Uiso 1 1 calc R U . . .
H25C H 0.7783 1.1526 0.2331 0.057 Uiso 1 1 calc R U . . .
C27 C 1.0694(5) 0.9709(3) 0.4024(5) 0.0362(12) Uani 1 1 d . . . . .
C28 C 0.8362(4) 0.7211(2) 0.1711(4) 0.0268(10) Uani 1 1 d . . . . .
C29 C 0.5285(3) 0.8530(3) 0.4797(3) 0.0275(10) Uani 1 1 d . . . . .
C30 C 0.6479(6) 0.6117(3) 0.3025(5) 0.0505(16) Uani 1 1 d . . . . .
H30A H 0.6360 0.5647 0.2911 0.061 Uiso 1 1 calc R U . . .
H30B H 0.6610 0.6197 0.3753 0.061 Uiso 1 1 calc R U . . .
H30C H 0.5861 0.6365 0.2796 0.061 Uiso 1 1 calc R U . . .
C31 C 0.9154(6) 0.6119(3) 0.1782(5) 0.0413(14) Uani 1 1 d . . . . .
H31A H 0.9809 0.6342 0.1998 0.050 Uiso 1 1 calc R U . . .
H31B H 0.9327 0.5709 0.1417 0.050 Uiso 1 1 calc R U . . .
C32 C 0.4305(6) 0.7658(3) 0.2009(5) 0.0492(16) Uani 1 1 d . . . . .
H32 H 0.4704 0.7716 0.2621 0.059 Uiso 1 1 calc R U . . .
C33 C 1.0167(4) 0.8127(3) 0.7242(4) 0.0360(11) Uani 1 1 d . . . . .
H33 H 1.0400 0.7685 0.7201 0.043 Uiso 1 1 calc R U . . .
C35 C 0.5386(5) 0.9442(3) -0.0458(4) 0.0398(13) Uani 1 1 d . . . . .
H35 H 0.4737 0.9620 -0.0259 0.048 Uiso 1 1 calc R U . . .
C36 C 0.8999(5) 1.0981(3) 0.1739(5) 0.0367(13) Uani 1 1 d . . . . .
C37 C 0.9051(5) 0.9005(3) 0.6642(5) 0.0382(14) Uani 1 1 d . . . . .
H37 H 0.8518 0.9162 0.6190 0.046 Uiso 1 1 calc R U . . .
C38 C 0.4355(5) 0.8477(3) 0.6329(4) 0.0439(16) Uani 1 1 d . . . . .
C39 C 0.7230(4) 0.6878(3) 0.5717(4) 0.0308(11) Uani 1 1 d . . . . .
H39 H 0.7096 0.7016 0.5035 0.037 Uiso 1 1 calc R U . . .
C40 C 0.7688(4) 0.7059(2) 0.2537(4) 0.0280(9) Uani 1 1 d . . . . .
C41 C 1.0623(4) 0.8562(4) 0.7961(4) 0.0459(13) Uani 1 1 d . . . . .
H41 H 1.1169 0.8415 0.8405 0.055 Uiso 1 1 calc R U . . .
C42 C 0.8392(4) 1.0411(3) 0.1229(4) 0.0311(11) Uani 1 1 d . . . . .
C43 C 1.0267(4) 0.7728(3) 0.4255(5) 0.0388(12) Uani 1 1 d . . . . .
H43 H 1.0111 0.8176 0.4116 0.047 Uiso 1 1 calc R U . . .
C44 C 1.0729(5) 0.6419(3) 0.4655(5) 0.0460(14) Uani 1 1 d . . . . .
H44 H 1.0892 0.5970 0.4783 0.055 Uiso 1 1 calc R U . . .
C45 C 0.6384(4) 0.4500(3) 0.8368(4) 0.0349(11) Uani 1 1 d . . . . .
H45 H 0.6771 0.4173 0.8729 0.042 Uiso 1 1 calc R U . . .
C46 C 0.7364(4) 0.6273(3) 0.1236(4) 0.0351(11) Uani 1 1 d . . . . .
C48 C 0.5411(4) 0.9161(2) 0.5298(4) 0.0295(10) Uani 1 1 d . . . . .
C49 C 0.9314(5) 1.1523(3) 0.0990(5) 0.0481(15) Uani 1 1 d . . . . .
H49A H 0.9695 1.1327 0.0427 0.058 Uiso 1 1 calc R U . . .
H49B H 0.8686 1.1743 0.0720 0.058 Uiso 1 1 calc R U . . .
H49C H 0.9761 1.1844 0.1344 0.058 Uiso 1 1 calc R U . . .
C50 C 0.6239(5) 1.0289(3) 0.5483(4) 0.0395(12) Uani 1 1 d . . . . .
C51 C 0.9200(5) 1.0099(3) 0.0513(4) 0.0411(12) Uani 1 1 d . . . . .
H51A H 0.9186 1.0317 -0.0161 0.049 Uiso 1 1 calc R U . . .
H51B H 0.9065 0.9623 0.0418 0.049 Uiso 1 1 calc R U . . .
C53 C 0.6484(5) 0.6683(3) 0.0735(5) 0.0511(15) Uani 1 1 d . . . . .
H53A H 0.6545 0.7141 0.0961 0.061 Uiso 1 1 calc R U . . .
H53B H 0.6540 0.6663 -0.0008 0.061 Uiso 1 1 calc R U . . .
H53C H 0.5807 0.6506 0.0933 0.061 Uiso 1 1 calc R U . . .
C54 C 0.8470(5) 0.6569(3) 0.1122(5) 0.0348(12) Uani 1 1 d . . . . .
H54 H 0.8699 0.6620 0.0404 0.042 Uiso 1 1 calc R U . . .
C55 C 0.9920(4) 1.0537(3) 0.2098(4) 0.0359(11) Uani 1 1 d . . . . .
H55 H 1.0486 1.0763 0.2500 0.043 Uiso 1 1 calc R U . . .
C56 C 0.4160(5) 0.7495(3) 0.5007(5) 0.0447(13) Uani 1 1 d . . . . .
H56A H 0.3502 0.7343 0.5291 0.054 Uiso 1 1 calc R U . . .
H56B H 0.4156 0.7412 0.4272 0.054 Uiso 1 1 calc R U . . .
H56C H 0.4743 0.7257 0.5333 0.054 Uiso 1 1 calc R U . . .
C57 C 0.4678(4) 0.9412(2) 0.1823(4) 0.0269(9) Uani 1 1 d . . . . .
C58 C 0.9662(5) 0.7898(3) 0.0791(5) 0.0427(13) Uani 1 1 d . . . . .
C59 C 0.4492(4) 0.9207(3) 0.6011(5) 0.0409(13) Uani 1 1 d . . . . .
H59 H 0.4591 0.9522 0.6590 0.049 Uiso 1 1 calc R U . . .
C60 C 0.8373(4) 0.9930(2) 0.2122(4) 0.0249(9) Uani 1 1 d . . . . .
C62 C 0.7593(4) 0.6480(2) 0.7713(4) 0.0296(10) Uani 1 1 d . . . . .
H62 H 0.7706 0.6349 0.8401 0.035 Uiso 1 1 calc R U . . .
C64 C 0.9960(5) 0.6731(2) 0.5187(4) 0.0367(11) Uani 1 1 d . . . . .
H64 H 0.9588 0.6493 0.5684 0.044 Uiso 1 1 calc R U . . .
C66 C 0.9337(4) 1.0000(2) 0.2667(4) 0.0293(10) Uani 1 1 d . . . . .
C68 C 1.0277(6) 0.9196(3) 0.8015(5) 0.0497(15) Uani 1 1 d . . . . .
H68 H 1.0568 0.9481 0.8519 0.060 Uiso 1 1 calc R U . . .
C70 C 0.5882(4) 0.8967(2) 0.0143(4) 0.0300(10) Uani 1 1 d . . . . .
C71 C 0.7271(5) 0.8906(3) -0.1068(5) 0.0469(14) Uani 1 1 d . . . . .
H71 H 0.7912 0.8721 -0.1279 0.056 Uiso 1 1 calc R U . . .
C72 C 0.7322(4) 1.0545(3) 0.0748(5) 0.0397(12) Uani 1 1 d . . . . .
H72A H 0.7391 1.0855 0.0183 0.048 Uiso 1 1 calc R U . . .
H72B H 0.7021 1.0132 0.0491 0.048 Uiso 1 1 calc R U . . .
H72C H 0.6864 1.0733 0.1260 0.048 Uiso 1 1 calc R U . . .
C73 C 0.5237(4) 0.9889(2) 0.2385(4) 0.0315(10) Uani 1 1 d . . . . .
H73 H 0.5961 0.9832 0.2528 0.038 Uiso 1 1 calc R U . . .
C74 C 0.3554(7) 0.7163(4) 0.1934(7) 0.063(2) Uani 1 1 d . . . . .
H74 H 0.3443 0.6880 0.2497 0.075 Uiso 1 1 calc R U . . .
C75 C 0.3889(6) 0.7976(4) 0.0267(6) 0.064(2) Uani 1 1 d . . . . .
H75 H 0.4007 0.8247 -0.0309 0.077 Uiso 1 1 calc R U . . .
C77 C 0.5285(6) 0.8182(3) 0.6934(5) 0.0518(15) Uani 1 1 d . . . . .
H77A H 0.5929 0.8263 0.6567 0.062 Uiso 1 1 calc R U . . .
H77B H 0.5334 0.8388 0.7608 0.062 Uiso 1 1 calc R U . . .
H77C H 0.5182 0.7707 0.7011 0.062 Uiso 1 1 calc R U . . .
C78 C 0.6824(4) 0.8695(3) -0.0169(4) 0.0390(11) Uani 1 1 d . . . . .
H78 H 0.7160 0.8366 0.0233 0.047 Uiso 1 1 calc R U . . .
C79 C 0.5278(4) 0.5447(2) 0.7270(4) 0.0312(10) Uani 1 1 d . . . . .
H79 H 0.4901 0.5764 0.6879 0.037 Uiso 1 1 calc R U . . .
C80 C 0.5845(5) 0.9655(3) -0.1356(4) 0.0458(14) Uani 1 1 d . . . . .
H80 H 0.5514 0.9985 -0.1760 0.055 Uiso 1 1 calc R U . . .
C82 C 0.3520(5) 0.9337(3) 0.5322(6) 0.0516(15) Uani 1 1 d . . . . .
H82A H 0.3637 0.9707 0.4848 0.062 Uiso 1 1 calc R U . . .
H82B H 0.2897 0.9431 0.5731 0.062 Uiso 1 1 calc R U . . .
C83 C 0.6781(6) 0.9385(3) -0.1656(4) 0.0505(15) Uani 1 1 d . . . . .
H83 H 0.7088 0.9530 -0.2269 0.061 Uiso 1 1 calc R U . . .
C85 C 0.9518(6) 0.9430(3) 0.7356(5) 0.0506(15) Uani 1 1 d . . . . .
H85 H 0.9311 0.9878 0.7384 0.061 Uiso 1 1 calc R U . . .
C87 C 0.3137(8) 0.7476(5) 0.0236(8) 0.086(3) Uani 1 1 d . . . . .
H87 H 0.2732 0.7413 -0.0371 0.103 Uiso 1 1 calc R U . . .
C88 C 1.1039(6) 0.7413(3) 0.3715(5) 0.0486(15) Uani 1 1 d . . . . .
H88 H 1.1404 0.7642 0.3203 0.058 Uiso 1 1 calc R U . . .
C89 C 0.3362(7) 0.8339(4) 0.6929(6) 0.068(2) Uani 1 1 d . . . . .
H89A H 0.2756 0.8522 0.6559 0.082 Uiso 1 1 calc R U . . .
H89B H 0.3272 0.7863 0.7006 0.082 Uiso 1 1 calc R U . . .
H89C H 0.3424 0.8544 0.7603 0.082 Uiso 1 1 calc R U . . .
C91 C 0.4284(4) 0.8226(3) 0.5202(4) 0.0355(11) Uani 1 1 d . . . . .
C92 C 0.7252(6) 0.5561(3) 0.0872(6) 0.0540(17) Uani 1 1 d . . . . .
H92A H 0.7808 0.5293 0.1184 0.065 Uiso 1 1 calc R U . . .
H92B H 0.6572 0.5389 0.1069 0.065 Uiso 1 1 calc R U . . .
H92C H 0.7305 0.5545 0.0129 0.065 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O26 2.329(3) . ?
Eu1 O10 2.342(3) . ?
Eu1 O8 2.370(3) . ?
Eu1 O6 2.371(3) . ?
Eu1 O34 2.392(3) . ?
Eu1 O47 2.406(3) . ?
Eu1 O15 2.444(3) . ?
Eu1 O52 2.464(3) . ?
P1 O26 1.493(3) . ?
P1 C13 1.795(5) . ?
P1 C17 1.800(5) . ?
P1 C19 1.801(5) . ?
P67 O8 1.488(3) . ?
P67 C70 1.796(6) . ?
P67 C24 1.797(5) . ?
P67 C57 1.804(5) . ?
F18 C58 1.309(7) . ?
F61 C27 1.268(7) . ?
F63 C58 1.365(8) . ?
F65 C27 1.325(9) . ?
F76 C27 1.253(7) . ?
F81 C50 1.299(7) . ?
F84 C50 1.314(8) . ?
F86 C50 1.286(7) . ?
F90 C58 1.326(7) . ?
O6 C12 1.262(6) . ?
O10 C21 1.283(6) . ?
O15 C40 1.241(6) . ?
O34 C5 1.257(6) . ?
O47 C60 1.245(6) . ?
O52 C29 1.238(6) . ?
C2 C30 1.495(8) . ?
C2 C40 1.522(6) . ?
C2 C22 1.574(9) . ?
C2 C46 1.582(7) . ?
C3 C87 1.352(14) . ?
C3 C74 1.379(13) . ?
C3 H3 0.9500 . ?
C4 C55 1.554(9) . ?
C4 C51 1.561(8) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C66 1.377(6) . ?
C5 C27 1.547(7) . ?
C7 C88 1.354(10) . ?
C7 C44 1.401(9) . ?
C7 H7 0.9500 . ?
C9 C62 1.386(7) . ?
C9 C23 1.390(7) . ?
C9 C11 1.490(6) . ?
C11 C79 1.382(7) . ?
C11 C20 1.397(7) . ?
C12 C28 1.370(7) . ?
C12 C58 1.541(7) . ?
C13 C64 1.398(7) . ?
C13 C43 1.406(7) . ?
C14 C62 1.384(7) . ?
C14 C17 1.398(7) . ?
C14 H14 0.9500 . ?
C16 C82 1.553(10) . ?
C16 C91 1.558(8) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C39 1.402(7) . ?
C19 C37 1.387(7) . ?
C19 C33 1.394(8) . ?
C20 C45 1.396(7) . ?
C20 H20 0.9500 . ?
C21 C48 1.364(7) . ?
C21 C50 1.536(7) . ?
C22 C31 1.536(10) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C39 1.382(7) . ?
C23 H23 0.9500 . ?
C24 C32 1.385(9) . ?
C24 C75 1.401(9) . ?
C25 C36 1.535(11) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C28 C40 1.435(7) . ?
C28 C54 1.527(7) . ?
C29 C48 1.450(7) . ?
C29 C91 1.530(7) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C54 1.524(9) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C74 1.395(9) . ?
C32 H32 0.9500 . ?
C33 C41 1.410(8) . ?
C33 H33 0.9500 . ?
C35 C70 1.392(7) . ?
C35 C80 1.398(9) . ?
C35 H35 0.9500 . ?
C36 C49 1.537(8) . ?
C36 C42 1.542(8) . ?
C36 C55 1.553(8) . ?
C37 C85 1.400(9) . ?
C37 H37 0.9500 . ?
C38 C89 1.538(8) . ?
C38 C77 1.538(9) . ?
C38 C59 1.555(9) . ?
C38 C91 1.566(8) . ?
C39 H39 0.9500 . ?
C41 C68 1.366(10) . ?
C41 H41 0.9500 . ?
C42 C72 1.522(7) . ?
C42 C60 1.528(7) . ?
C42 C51 1.551(8) . ?
C43 C88 1.388(9) . ?
C43 H43 0.9500 . ?
C44 C64 1.376(8) . ?
C44 H44 0.9500 . ?
C45 C57 1.390(7) 2_646 ?
C45 H45 0.9500 . ?
C46 C92 1.531(7) . ?
C46 C53 1.539(9) . ?
C46 C54 1.550(8) . ?
C48 C59 1.524(7) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54 1.0000 . ?
C55 C66 1.528(7) . ?
C55 H55 1.0000 . ?
C56 C91 1.517(8) . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C57 C45 1.390(7) 2_656 ?
C57 C73 1.405(7) . ?
C59 C82 1.547(9) . ?
C59 H59 1.0000 . ?
C60 C66 1.421(7) . ?
C62 H62 0.9500 . ?
C64 H64 0.9500 . ?
C68 C85 1.372(10) . ?
C68 H68 0.9500 . ?
C70 C78 1.398(7) . ?
C71 C83 1.386(9) . ?
C71 C78 1.391(8) . ?
C71 H71 0.9500 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 C79 1.394(7) 2_656 ?
C73 H73 0.9500 . ?
C74 H74 0.9500 . ?
C75 C87 1.402(11) . ?
C75 H75 0.9500 . ?
C77 H77A 0.9800 . ?
C77 H77B 0.9800 . ?
C77 H77C 0.9800 . ?
C78 H78 0.9500 . ?
C79 C73 1.394(7) 2_646 ?
C79 H79 0.9500 . ?
C80 C83 1.385(9) . ?
C80 H80 0.9500 . ?
C82 H82A 0.9900 . ?
C82 H82B 0.9900 . ?
C83 H83 0.9500 . ?
C85 H85 0.9500 . ?
C87 H87 0.9500 . ?
C88 H88 0.9500 . ?
C89 H89A 0.9800 . ?
C89 H89B 0.9800 . ?
C89 H89C 0.9800 . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O26 Eu1 O10 84.10(12) . . ?
O26 Eu1 O8 144.02(12) . . ?
O10 Eu1 O8 104.11(12) . . ?
O26 Eu1 O6 109.41(13) . . ?
O10 Eu1 O6 144.01(12) . . ?
O8 Eu1 O6 84.59(12) . . ?
O26 Eu1 O34 72.81(12) . . ?
O10 Eu1 O34 78.72(12) . . ?
O8 Eu1 O34 142.89(11) . . ?
O6 Eu1 O34 74.18(12) . . ?
O26 Eu1 O47 143.81(11) . . ?
O10 Eu1 O47 76.16(12) . . ?
O8 Eu1 O47 71.23(11) . . ?
O6 Eu1 O47 73.84(11) . . ?
O34 Eu1 O47 73.75(11) . . ?
O26 Eu1 O15 75.20(12) . . ?
O10 Eu1 O15 142.92(11) . . ?
O8 Eu1 O15 77.96(11) . . ?
O6 Eu1 O15 72.81(11) . . ?
O34 Eu1 O15 122.07(11) . . ?
O47 Eu1 O15 136.10(11) . . ?
O26 Eu1 O52 77.74(12) . . ?
O10 Eu1 O52 72.51(11) . . ?
O8 Eu1 O52 71.83(12) . . ?
O6 Eu1 O52 141.86(11) . . ?
O34 Eu1 O52 140.49(11) . . ?
O47 Eu1 O52 122.88(11) . . ?
O15 Eu1 O52 73.22(11) . . ?
O26 P1 C13 113.1(2) . . ?
O26 P1 C17 109.3(2) . . ?
C13 P1 C17 106.1(2) . . ?
O26 P1 C19 110.3(2) . . ?
C13 P1 C19 107.6(2) . . ?
C17 P1 C19 110.3(2) . . ?
O8 P67 C70 111.1(2) . . ?
O8 P67 C24 109.8(2) . . ?
C70 P67 C24 110.0(3) . . ?
O8 P67 C57 113.8(2) . . ?
C70 P67 C57 105.6(2) . . ?
C24 P67 C57 106.4(2) . . ?
C12 O6 Eu1 134.4(3) . . ?
P67 O8 Eu1 154.7(2) . . ?
C21 O10 Eu1 136.8(3) . . ?
C40 O15 Eu1 130.5(3) . . ?
P1 O26 Eu1 152.5(2) . . ?
C5 O34 Eu1 134.4(3) . . ?
C60 O47 Eu1 131.4(3) . . ?
C29 O52 Eu1 131.1(3) . . ?
C30 C2 C40 115.8(4) . . ?
C30 C2 C22 116.2(5) . . ?
C40 C2 C22 102.8(5) . . ?
C30 C2 C46 118.9(5) . . ?
C40 C2 C46 99.5(4) . . ?
C22 C2 C46 100.8(4) . . ?
C87 C3 C74 120.3(7) . . ?
C87 C3 H3 119.9 . . ?
C74 C3 H3 119.9 . . ?
C55 C4 C51 102.3(5) . . ?
C55 C4 H4A 111.3 . . ?
C51 C4 H4A 111.3 . . ?
C55 C4 H4B 111.3 . . ?
C51 C4 H4B 111.3 . . ?
H4A C4 H4B 109.2 . . ?
O34 C5 C66 126.8(4) . . ?
O34 C5 C27 113.3(4) . . ?
C66 C5 C27 119.9(4) . . ?
C88 C7 C44 121.8(6) . . ?
C88 C7 H7 119.1 . . ?
C44 C7 H7 119.1 . . ?
C62 C9 C23 118.9(4) . . ?
C62 C9 C11 121.6(4) . . ?
C23 C9 C11 119.5(4) . . ?
C79 C11 C20 119.0(4) . . ?
C79 C11 C9 121.4(4) . . ?
C20 C11 C9 119.5(4) . . ?
O6 C12 C28 127.3(4) . . ?
O6 C12 C58 114.0(4) . . ?
C28 C12 C58 118.7(4) . . ?
C64 C13 C43 118.3(5) . . ?
C64 C13 P1 123.1(4) . . ?
C43 C13 P1 118.7(4) . . ?
C62 C14 C17 119.9(4) . . ?
C62 C14 H14 120.0 . . ?
C17 C14 H14 120.0 . . ?
C82 C16 C91 105.2(5) . . ?
C82 C16 H16A 110.7 . . ?
C91 C16 H16A 110.7 . . ?
C82 C16 H16B 110.7 . . ?
C91 C16 H16B 110.7 . . ?
H16A C16 H16B 108.8 . . ?
C14 C17 C39 119.2(4) . . ?
C14 C17 P1 125.2(4) . . ?
C39 C17 P1 115.5(4) . . ?
C37 C19 C33 120.0(5) . . ?
C37 C19 P1 118.1(5) . . ?
C33 C19 P1 121.8(4) . . ?
C11 C20 C45 120.5(5) . . ?
C11 C20 H20 119.8 . . ?
C45 C20 H20 119.8 . . ?
O10 C21 C48 126.7(4) . . ?
O10 C21 C50 111.3(4) . . ?
C48 C21 C50 121.9(4) . . ?
C31 C22 C2 104.7(5) . . ?
C31 C22 H22A 110.8 . . ?
C2 C22 H22A 110.8 . . ?
C31 C22 H22B 110.8 . . ?
C2 C22 H22B 110.8 . . ?
H22A C22 H22B 108.9 . . ?
C39 C23 C9 121.0(5) . . ?
C39 C23 H23 119.5 . . ?
C9 C23 H23 119.5 . . ?
C32 C24 C75 121.0(6) . . ?
C32 C24 P67 116.6(4) . . ?
C75 C24 P67 122.4(5) . . ?
C36 C25 H25A 109.5 . . ?
C36 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C36 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
F76 C27 F61 112.1(6) . . ?
F76 C27 F65 102.2(8) . . ?
F61 C27 F65 101.9(6) . . ?
F76 C27 C5 116.0(5) . . ?
F61 C27 C5 114.0(5) . . ?
F65 C27 C5 108.9(5) . . ?
C12 C28 C40 122.4(4) . . ?
C12 C28 C54 132.1(5) . . ?
C40 C28 C54 105.1(4) . . ?
O52 C29 C48 129.1(5) . . ?
O52 C29 C91 124.1(5) . . ?
C48 C29 C91 106.6(4) . . ?
C2 C30 H30A 109.5 . . ?
C2 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C2 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C54 C31 C22 102.8(5) . . ?
C54 C31 H31A 111.2 . . ?
C22 C31 H31A 111.2 . . ?
C54 C31 H31B 111.2 . . ?
C22 C31 H31B 111.2 . . ?
H31A C31 H31B 109.1 . . ?
C24 C32 C74 119.1(7) . . ?
C24 C32 H32 120.4 . . ?
C74 C32 H32 120.4 . . ?
C19 C33 C41 119.2(5) . . ?
C19 C33 H33 120.4 . . ?
C41 C33 H33 120.4 . . ?
C70 C35 C80 119.8(6) . . ?
C70 C35 H35 120.1 . . ?
C80 C35 H35 120.1 . . ?
C25 C36 C49 108.1(5) . . ?
C25 C36 C42 113.0(5) . . ?
C49 C36 C42 113.5(5) . . ?
C25 C36 C55 114.2(5) . . ?
C49 C36 C55 113.8(5) . . ?
C42 C36 C55 93.8(4) . . ?
C19 C37 C85 119.9(6) . . ?
C19 C37 H37 120.1 . . ?
C85 C37 H37 120.1 . . ?
C89 C38 C77 107.8(6) . . ?
C89 C38 C59 114.3(5) . . ?
C77 C38 C59 114.8(5) . . ?
C89 C38 C91 113.1(5) . . ?
C77 C38 C91 112.8(5) . . ?
C59 C38 C91 93.5(4) . . ?
C23 C39 C17 119.8(5) . . ?
C23 C39 H39 120.1 . . ?
C17 C39 H39 120.1 . . ?
O15 C40 C28 128.5(4) . . ?
O15 C40 C2 124.5(4) . . ?
C28 C40 C2 107.0(4) . . ?
C68 C41 C33 119.8(6) . . ?
C68 C41 H41 120.1 . . ?
C33 C41 H41 120.1 . . ?
C72 C42 C60 113.8(4) . . ?
C72 C42 C36 119.1(5) . . ?
C60 C42 C36 99.5(4) . . ?
C72 C42 C51 115.5(5) . . ?
C60 C42 C51 103.0(4) . . ?
C36 C42 C51 103.5(5) . . ?
C88 C43 C13 120.6(5) . . ?
C88 C43 H43 119.7 . . ?
C13 C43 H43 119.7 . . ?
C64 C44 C7 118.6(5) . . ?
C64 C44 H44 120.7 . . ?
C7 C44 H44 120.7 . . ?
C57 C45 C20 120.2(5) 2_646 . ?
C57 C45 H45 119.9 2_646 . ?
C20 C45 H45 119.9 . . ?
C92 C46 C53 108.4(5) . . ?
C92 C46 C54 114.6(5) . . ?
C53 C46 C54 114.3(5) . . ?
C92 C46 C2 112.8(5) . . ?
C53 C46 C2 112.9(5) . . ?
C54 C46 C2 93.3(4) . . ?
C21 C48 C29 121.7(4) . . ?
C21 C48 C59 133.1(5) . . ?
C29 C48 C59 104.6(4) . . ?
C36 C49 H49A 109.5 . . ?
C36 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C36 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
F86 C50 F81 106.3(6) . . ?
F86 C50 F84 106.4(7) . . ?
F81 C50 F84 104.2(6) . . ?
F86 C50 C21 115.3(5) . . ?
F81 C50 C21 112.5(5) . . ?
F84 C50 C21 111.3(5) . . ?
C42 C51 C4 103.6(5) . . ?
C42 C51 H51A 111.0 . . ?
C4 C51 H51A 111.0 . . ?
C42 C51 H51B 111.0 . . ?
C4 C51 H51B 111.0 . . ?
H51A C51 H51B 109.0 . . ?
C46 C53 H53A 109.5 . . ?
C46 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C46 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C31 C54 C28 106.4(5) . . ?
C31 C54 C46 103.2(5) . . ?
C28 C54 C46 101.0(4) . . ?
C31 C54 H54 114.9 . . ?
C28 C54 H54 114.9 . . ?
C46 C54 H54 114.9 . . ?
C66 C55 C36 100.8(4) . . ?
C66 C55 C4 105.7(4) . . ?
C36 C55 C4 102.3(5) . . ?
C66 C55 H55 115.4 . . ?
C36 C55 H55 115.4 . . ?
C4 C55 H55 115.4 . . ?
C91 C56 H56A 109.5 . . ?
C91 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C91 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C45 C57 C73 119.5(5) 2_656 . ?
C45 C57 P67 122.9(4) 2_656 . ?
C73 C57 P67 117.6(4) . . ?
F18 C58 F90 107.4(5) . . ?
F18 C58 F63 107.1(5) . . ?
F90 C58 F63 105.4(5) . . ?
F18 C58 C12 113.3(4) . . ?
F90 C58 C12 112.4(5) . . ?
F63 C58 C12 110.9(5) . . ?
C48 C59 C82 106.0(5) . . ?
C48 C59 C38 101.5(4) . . ?
C82 C59 C38 103.1(5) . . ?
C48 C59 H59 114.9 . . ?
C82 C59 H59 114.9 . . ?
C38 C59 H59 114.9 . . ?
O47 C60 C66 129.4(4) . . ?
O47 C60 C42 123.4(4) . . ?
C66 C60 C42 107.1(4) . . ?
C14 C62 C9 121.1(4) . . ?
C14 C62 H62 119.5 . . ?
C9 C62 H62 119.5 . . ?
C44 C64 C13 121.2(5) . . ?
C44 C64 H64 119.4 . . ?
C13 C64 H64 119.4 . . ?
C5 C66 C60 123.1(4) . . ?
C5 C66 C55 132.0(4) . . ?
C60 C66 C55 104.8(4) . . ?
C41 C68 C85 121.4(5) . . ?
C41 C68 H68 119.3 . . ?
C85 C68 H68 119.3 . . ?
C35 C70 C78 119.7(5) . . ?
C35 C70 P67 122.3(4) . . ?
C78 C70 P67 117.9(4) . . ?
C83 C71 C78 119.9(6) . . ?
C83 C71 H71 120.0 . . ?
C78 C71 H71 120.0 . . ?
C42 C72 H72A 109.5 . . ?
C42 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C42 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
C79 C73 C57 119.5(5) 2_656 . ?
C79 C73 H73 120.2 2_656 . ?
C57 C73 H73 120.2 . . ?
C3 C74 C32 120.2(8) . . ?
C3 C74 H74 119.9 . . ?
C32 C74 H74 119.9 . . ?
C24 C75 C87 117.6(8) . . ?
C24 C75 H75 121.2 . . ?
C87 C75 H75 121.2 . . ?
C38 C77 H77A 109.5 . . ?
C38 C77 H77B 109.5 . . ?
H77A C77 H77B 109.5 . . ?
C38 C77 H77C 109.5 . . ?
H77A C77 H77C 109.5 . . ?
H77B C77 H77C 109.5 . . ?
C71 C78 C70 120.1(5) . . ?
C71 C78 H78 119.9 . . ?
C70 C78 H78 119.9 . . ?
C11 C79 C73 121.3(4) . 2_646 ?
C11 C79 H79 119.4 . . ?
C73 C79 H79 119.4 2_646 . ?
C83 C80 C35 120.1(5) . . ?
C83 C80 H80 120.0 . . ?
C35 C80 H80 120.0 . . ?
C59 C82 C16 101.6(5) . . ?
C59 C82 H82A 111.5 . . ?
C16 C82 H82A 111.5 . . ?
C59 C82 H82B 111.5 . . ?
C16 C82 H82B 111.5 . . ?
H82A C82 H82B 109.3 . . ?
C80 C83 C71 120.3(6) . . ?
C80 C83 H83 119.8 . . ?
C71 C83 H83 119.8 . . ?
C68 C85 C37 119.6(6) . . ?
C68 C85 H85 120.2 . . ?
C37 C85 H85 120.2 . . ?
C3 C87 C75 121.7(8) . . ?
C3 C87 H87 119.1 . . ?
C75 C87 H87 119.1 . . ?
C7 C88 C43 119.5(6) . . ?
C7 C88 H88 120.2 . . ?
C43 C88 H88 120.2 . . ?
C38 C89 H89A 109.5 . . ?
C38 C89 H89B 109.5 . . ?
H89A C89 H89B 109.5 . . ?
C38 C89 H89C 109.5 . . ?
H89A C89 H89C 109.5 . . ?
H89B C89 H89C 109.5 . . ?
C56 C91 C29 115.0(5) . . ?
C56 C91 C16 115.9(5) . . ?
C29 C91 C16 103.4(4) . . ?
C56 C91 C38 118.9(5) . . ?
C29 C91 C38 99.5(4) . . ?
C16 C91 C38 101.5(5) . . ?
C46 C92 H92A 109.5 . . ?
C46 C92 H92B 109.5 . . ?
H92A C92 H92B 109.5 . . ?
C46 C92 H92C 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C70 P67 O8 Eu1 99.8(5) . . . . ?
C24 P67 O8 Eu1 -138.3(5) . . . . ?
C57 P67 O8 Eu1 -19.2(6) . . . . ?
C13 P1 O26 Eu1 -3.8(5) . . . . ?
C17 P1 O26 Eu1 -121.7(4) . . . . ?
C19 P1 O26 Eu1 116.8(4) . . . . ?
Eu1 O34 C5 C66 9.8(8) . . . . ?
Eu1 O34 C5 C27 -169.5(3) . . . . ?
C62 C9 C11 C79 138.4(5) . . . . ?
C23 C9 C11 C79 -41.6(7) . . . . ?
C62 C9 C11 C20 -45.0(7) . . . . ?
C23 C9 C11 C20 135.0(5) . . . . ?
Eu1 O6 C12 C28 -11.7(8) . . . . ?
Eu1 O6 C12 C58 168.7(4) . . . . ?
O26 P1 C13 C64 -133.4(4) . . . . ?
C17 P1 C13 C64 -13.6(5) . . . . ?
C19 P1 C13 C64 104.5(5) . . . . ?
O26 P1 C13 C43 46.0(5) . . . . ?
C17 P1 C13 C43 165.9(4) . . . . ?
C19 P1 C13 C43 -76.0(5) . . . . ?
C62 C14 C17 C39 2.8(8) . . . . ?
C62 C14 C17 P1 -173.0(4) . . . . ?
O26 P1 C17 C14 -142.0(4) . . . . ?
C13 P1 C17 C14 95.8(5) . . . . ?
C19 P1 C17 C14 -20.6(5) . . . . ?
O26 P1 C17 C39 42.1(4) . . . . ?
C13 P1 C17 C39 -80.2(4) . . . . ?
C19 P1 C17 C39 163.5(4) . . . . ?
O26 P1 C19 C37 7.9(5) . . . . ?
C13 P1 C19 C37 131.7(5) . . . . ?
C17 P1 C19 C37 -112.9(5) . . . . ?
O26 P1 C19 C33 -172.1(4) . . . . ?
C13 P1 C19 C33 -48.3(5) . . . . ?
C17 P1 C19 C33 67.1(5) . . . . ?
C79 C11 C20 C45 -1.4(8) . . . . ?
C9 C11 C20 C45 -178.1(5) . . . . ?
Eu1 O10 C21 C48 -9.7(8) . . . . ?
Eu1 O10 C21 C50 170.4(3) . . . . ?
C30 C2 C22 C31 161.7(5) . . . . ?
C40 C2 C22 C31 -70.7(5) . . . . ?
C46 C2 C22 C31 31.8(5) . . . . ?
C62 C9 C23 C39 3.6(8) . . . . ?
C11 C9 C23 C39 -176.3(5) . . . . ?
O8 P67 C24 C32 34.4(5) . . . . ?
C70 P67 C24 C32 156.9(5) . . . . ?
C57 P67 C24 C32 -89.2(5) . . . . ?
O8 P67 C24 C75 -148.0(5) . . . . ?
C70 P67 C24 C75 -25.5(6) . . . . ?
C57 P67 C24 C75 88.4(6) . . . . ?
O34 C5 C27 F76 -140.7(7) . . . . ?
C66 C5 C27 F76 40.1(9) . . . . ?
O34 C5 C27 F61 -8.2(8) . . . . ?
C66 C5 C27 F61 172.5(6) . . . . ?
O34 C5 C27 F65 104.8(7) . . . . ?
C66 C5 C27 F65 -74.5(7) . . . . ?
O6 C12 C28 C40 -6.8(9) . . . . ?
C58 C12 C28 C40 172.8(5) . . . . ?
O6 C12 C28 C54 -178.0(5) . . . . ?
C58 C12 C28 C54 1.6(9) . . . . ?
Eu1 O52 C29 C48 7.5(8) . . . . ?
Eu1 O52 C29 C91 -176.5(3) . . . . ?
C2 C22 C31 C54 3.3(6) . . . . ?
C75 C24 C32 C74 -0.8(10) . . . . ?
P67 C24 C32 C74 176.8(5) . . . . ?
C37 C19 C33 C41 1.7(8) . . . . ?
P1 C19 C33 C41 -178.3(4) . . . . ?
C33 C19 C37 C85 -1.3(9) . . . . ?
P1 C19 C37 C85 178.7(5) . . . . ?
C9 C23 C39 C17 -1.0(8) . . . . ?
C14 C17 C39 C23 -2.2(8) . . . . ?
P1 C17 C39 C23 174.0(4) . . . . ?
Eu1 O15 C40 C28 13.7(8) . . . . ?
Eu1 O15 C40 C2 -168.3(4) . . . . ?
C12 C28 C40 O15 5.1(9) . . . . ?
C54 C28 C40 O15 178.3(5) . . . . ?
C12 C28 C40 C2 -173.2(5) . . . . ?
C54 C28 C40 C2 0.1(6) . . . . ?
C30 C2 C40 O15 18.5(8) . . . . ?
C22 C2 C40 O15 -109.3(6) . . . . ?
C46 C2 C40 O15 147.2(5) . . . . ?
C30 C2 C40 C28 -163.1(5) . . . . ?
C22 C2 C40 C28 69.1(5) . . . . ?
C46 C2 C40 C28 -34.4(5) . . . . ?
C19 C33 C41 C68 0.2(9) . . . . ?
C25 C36 C42 C72 58.8(7) . . . . ?
C49 C36 C42 C72 -64.8(7) . . . . ?
C55 C36 C42 C72 177.2(5) . . . . ?
C25 C36 C42 C60 -65.4(6) . . . . ?
C49 C36 C42 C60 171.0(5) . . . . ?
C55 C36 C42 C60 53.0(5) . . . . ?
C25 C36 C42 C51 -171.3(5) . . . . ?
C49 C36 C42 C51 65.1(6) . . . . ?
C55 C36 C42 C51 -53.0(5) . . . . ?
C64 C13 C43 C88 -0.5(9) . . . . ?
P1 C13 C43 C88 -180.0(5) . . . . ?
C88 C7 C44 C64 -1.2(11) . . . . ?
C11 C20 C45 C57 -0.7(9) . . . 2_646 ?
C30 C2 C46 C92 -62.1(7) . . . . ?
C40 C2 C46 C92 171.3(5) . . . . ?
C22 C2 C46 C92 66.1(6) . . . . ?
C30 C2 C46 C53 61.2(6) . . . . ?
C40 C2 C46 C53 -65.4(5) . . . . ?
C22 C2 C46 C53 -170.5(5) . . . . ?
C30 C2 C46 C54 179.4(5) . . . . ?
C40 C2 C46 C54 52.8(5) . . . . ?
C22 C2 C46 C54 -52.4(5) . . . . ?
O10 C21 C48 C29 -4.7(8) . . . . ?
C50 C21 C48 C29 175.2(5) . . . . ?
O10 C21 C48 C59 -175.3(5) . . . . ?
C50 C21 C48 C59 4.6(9) . . . . ?
O52 C29 C48 C21 5.1(8) . . . . ?
C91 C29 C48 C21 -171.4(4) . . . . ?
O52 C29 C48 C59 178.0(5) . . . . ?
C91 C29 C48 C59 1.4(5) . . . . ?
O10 C21 C50 F86 161.8(7) . . . . ?
C48 C21 C50 F86 -18.1(9) . . . . ?
O10 C21 C50 F81 39.7(7) . . . . ?
C48 C21 C50 F81 -140.2(6) . . . . ?
O10 C21 C50 F84 -76.9(6) . . . . ?
C48 C21 C50 F84 103.2(7) . . . . ?
C72 C42 C51 C4 163.4(5) . . . . ?
C60 C42 C51 C4 -71.9(5) . . . . ?
C36 C42 C51 C4 31.4(5) . . . . ?
C55 C4 C51 C42 4.1(5) . . . . ?
C22 C31 C54 C28 67.4(6) . . . . ?
C22 C31 C54 C46 -38.5(6) . . . . ?
C12 C28 C54 C31 100.1(7) . . . . ?
C40 C28 C54 C31 -72.2(6) . . . . ?
C12 C28 C54 C46 -152.4(6) . . . . ?
C40 C28 C54 C46 35.3(6) . . . . ?
C92 C46 C54 C31 -60.5(7) . . . . ?
C53 C46 C54 C31 173.5(5) . . . . ?
C2 C46 C54 C31 56.5(5) . . . . ?
C92 C46 C54 C28 -170.5(5) . . . . ?
C53 C46 C54 C28 63.5(6) . . . . ?
C2 C46 C54 C28 -53.5(5) . . . . ?
C25 C36 C55 C66 64.1(6) . . . . ?
C49 C36 C55 C66 -171.1(5) . . . . ?
C42 C36 C55 C66 -53.3(5) . . . . ?
C25 C36 C55 C4 173.0(5) . . . . ?
C49 C36 C55 C4 -62.2(6) . . . . ?
C42 C36 C55 C4 55.6(5) . . . . ?
C51 C4 C55 C66 67.1(5) . . . . ?
C51 C4 C55 C36 -38.0(5) . . . . ?
O8 P67 C57 C45 -146.6(4) . . . 2_656 ?
C70 P67 C57 C45 91.3(5) . . . 2_656 ?
C24 P67 C57 C45 -25.6(5) . . . 2_656 ?
O8 P67 C57 C73 34.9(5) . . . . ?
C70 P67 C57 C73 -87.2(4) . . . . ?
C24 P67 C57 C73 155.9(4) . . . . ?
O6 C12 C58 F18 1.8(8) . . . . ?
C28 C12 C58 F18 -177.9(6) . . . . ?
O6 C12 C58 F90 123.7(5) . . . . ?
C28 C12 C58 F90 -55.9(7) . . . . ?
O6 C12 C58 F63 -118.6(5) . . . . ?
C28 C12 C58 F63 61.7(6) . . . . ?
C21 C48 C59 C82 98.1(7) . . . . ?
C29 C48 C59 C82 -73.6(5) . . . . ?
C21 C48 C59 C38 -154.5(6) . . . . ?
C29 C48 C59 C38 33.8(5) . . . . ?
C89 C38 C59 C48 -170.7(6) . . . . ?
C77 C38 C59 C48 63.9(6) . . . . ?
C91 C38 C59 C48 -53.3(5) . . . . ?
C89 C38 C59 C82 -61.1(7) . . . . ?
C77 C38 C59 C82 173.5(5) . . . . ?
C91 C38 C59 C82 56.3(5) . . . . ?
Eu1 O47 C60 C66 -7.5(8) . . . . ?
Eu1 O47 C60 C42 168.5(3) . . . . ?
C72 C42 C60 O47 19.8(7) . . . . ?
C36 C42 C60 O47 147.6(5) . . . . ?
C51 C42 C60 O47 -106.0(5) . . . . ?
C72 C42 C60 C66 -163.4(5) . . . . ?
C36 C42 C60 C66 -35.5(5) . . . . ?
C51 C42 C60 C66 70.8(5) . . . . ?
C17 C14 C62 C9 -0.2(8) . . . . ?
C23 C9 C62 C14 -3.0(7) . . . . ?
C11 C9 C62 C14 176.9(5) . . . . ?
C7 C44 C64 C13 -0.1(10) . . . . ?
C43 C13 C64 C44 0.9(9) . . . . ?
P1 C13 C64 C44 -179.6(5) . . . . ?
O34 C5 C66 C60 -1.1(8) . . . . ?
C27 C5 C66 C60 178.1(5) . . . . ?
O34 C5 C66 C55 -177.7(5) . . . . ?
C27 C5 C66 C55 1.5(9) . . . . ?
O47 C60 C66 C5 0.1(9) . . . . ?
C42 C60 C66 C5 -176.4(5) . . . . ?
O47 C60 C66 C55 177.6(5) . . . . ?
C42 C60 C66 C55 1.0(6) . . . . ?
C36 C55 C66 C5 -149.1(6) . . . . ?
C4 C55 C66 C5 104.7(6) . . . . ?
C36 C55 C66 C60 33.8(5) . . . . ?
C4 C55 C66 C60 -72.4(5) . . . . ?
C33 C41 C68 C85 -2.6(10) . . . . ?
C80 C35 C70 C78 -1.6(8) . . . . ?
C80 C35 C70 P67 175.0(4) . . . . ?
O8 P67 C70 C35 -150.9(4) . . . . ?
C24 P67 C70 C35 87.3(5) . . . . ?
C57 P67 C70 C35 -27.1(5) . . . . ?
O8 P67 C70 C78 25.8(5) . . . . ?
C24 P67 C70 C78 -96.0(5) . . . . ?
C57 P67 C70 C78 149.6(4) . . . . ?
C45 C57 C73 C79 -0.9(8) 2_656 . . 2_656 ?
P67 C57 C73 C79 177.7(4) . . . 2_656 ?
C87 C3 C74 C32 1.0(13) . . . . ?
C24 C32 C74 C3 -0.4(11) . . . . ?
C32 C24 C75 C87 1.5(11) . . . . ?
P67 C24 C75 C87 -176.1(6) . . . . ?
C83 C71 C78 C70 -0.1(10) . . . . ?
C35 C70 C78 C71 1.0(9) . . . . ?
P67 C70 C78 C71 -175.8(5) . . . . ?
C20 C11 C79 C73 2.4(8) . . . 2_646 ?
C9 C11 C79 C73 179.1(5) . . . 2_646 ?
C70 C35 C80 C83 1.3(9) . . . . ?
C48 C59 C82 C16 68.5(6) . . . . ?
C38 C59 C82 C16 -37.8(6) . . . . ?
C91 C16 C82 C59 3.0(6) . . . . ?
C35 C80 C83 C71 -0.3(10) . . . . ?
C78 C71 C83 C80 -0.3(10) . . . . ?
C41 C68 C85 C37 3.0(11) . . . . ?
C19 C37 C85 C68 -1.0(10) . . . . ?
C74 C3 C87 C75 -0.3(15) . . . . ?
C24 C75 C87 C3 -0.9(14) . . . . ?
C44 C7 C88 C43 1.6(11) . . . . ?
C13 C43 C88 C7 -0.7(10) . . . . ?
O52 C29 C91 C56 19.4(7) . . . . ?
C48 C29 C91 C56 -163.9(5) . . . . ?
O52 C29 C91 C16 -108.1(6) . . . . ?
C48 C29 C91 C16 68.7(5) . . . . ?
O52 C29 C91 C38 147.6(5) . . . . ?
C48 C29 C91 C38 -35.7(5) . . . . ?
C82 C16 C91 C56 162.5(5) . . . . ?
C82 C16 C91 C29 -70.6(5) . . . . ?
C82 C16 C91 C38 32.2(5) . . . . ?
C89 C38 C91 C56 -62.9(8) . . . . ?
C77 C38 C91 C56 59.8(7) . . . . ?
C59 C38 C91 C56 178.7(5) . . . . ?
C89 C38 C91 C29 171.5(6) . . . . ?
C77 C38 C91 C29 -65.8(6) . . . . ?
C59 C38 C91 C29 53.1(5) . . . . ?
C89 C38 C91 C16 65.5(7) . . . . ?
C77 C38 C91 C16 -171.7(5) . . . . ?
C59 C38 C91 C16 -52.8(5) . . . . ?

_refine_diff_density_max         1.204
_refine_diff_density_min         -0.398
_refine_diff_density_rms         0.066

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelxl_CCDC1
_audit_block_doi                 10.5517/ccdc.csd.cc1pxrmz
_database_code_depnum_ccdc_archive 'CCDC 1576772'
loop_
_audit_author_name
_audit_author_address
'Yasuchika Hasegawa'
;Hokkaido University
Japan
;
_audit_update_record             
;
2025-04-10 deposited with the CCDC.	2025-07-09 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H70 Eu F9 O8 P2'
_chemical_formula_sum            'C72 H70 Eu F9 O8 P2'
_chemical_formula_weight         1448.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   12.8098(3)
_cell_length_b                   20.3347(5)
_cell_length_c                   13.1288(4)
_cell_angle_alpha                90
_cell_angle_beta                 91.3301(9)
_cell_angle_gamma                90
_cell_volume                     3418.91(15)
_cell_formula_units_Z            2
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    29628
_cell_measurement_theta_min      3.01
_cell_measurement_theta_max      27.48

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.407
_exptl_crystal_F_000             1480
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.826
_exptl_crystal_size_mid          0.327
_exptl_crystal_size_min          0.173
_exptl_absorpt_coefficient_mu    1.042
_shelx_estimated_absorpt_T_min   0.480
_shelx_estimated_absorpt_T_max   0.840
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.290
_exptl_absorpt_correction_T_max  0.835
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.000
_diffrn_reflns_number            32463
_diffrn_reflns_av_unetI/netI     0.0656
_diffrn_reflns_av_R_equivalents  0.0399
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         3.011
_diffrn_reflns_theta_max         27.475
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_point_group_measured_fraction_full 0.991
_reflns_number_total             15296
_reflns_number_gt                13791
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.906
_reflns_Friedel_fraction_max     0.954
_reflns_Friedel_fraction_full    0.983

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0337P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 5787 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.011(4)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         15296
_refine_ls_number_parameters     829
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0407
_refine_ls_R_factor_gt           0.0343
_refine_ls_wR_factor_ref         0.0777
_refine_ls_wR_factor_gt          0.0742
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_restrained_S_all      1.007
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.25055(2) 0.86091(2) 0.15899(2) 0.01905(6) Uani 1 1 d . . . . .
P1 P 0.46038(9) 0.85158(7) 0.36445(10) 0.0253(3) Uani 1 1 d . . . . .
P92 P 0.12769(9) 0.94038(6) -0.06870(11) 0.0232(3) Uani 1 1 d . . . . .
F4 F -0.0825(3) 0.7843(3) 0.0158(4) 0.096(2) Uani 1 1 d . . . . .
F41 F -0.1422(4) 0.7788(4) 0.1550(5) 0.125(3) Uani 1 1 d . . . . .
F42 F 0.4588(4) 0.6741(2) -0.0933(6) 0.149(4) Uani 1 1 d . . . . .
F45 F 0.3539(4) 0.64888(17) 0.0179(3) 0.0716(14) Uani 1 1 d . . . . .
F56 F 0.2982(6) 0.6901(2) -0.1150(5) 0.107(2) Uani 1 1 d . . . . .
F65 F -0.1011(5) 0.6936(2) 0.0875(6) 0.132(3) Uani 1 1 d . . . . .
F73 F -0.0110(4) 0.87512(18) 0.4181(4) 0.0885(18) Uani 1 1 d . . . . .
F77 F -0.0421(3) 0.97791(18) 0.4151(3) 0.0507(10) Uani 1 1 d . . . . .
F109 F 0.0779(3) 0.9410(2) 0.5150(3) 0.0602(11) Uani 1 1 d . . . . .
O5 O 0.1264(3) 0.89196(16) 0.2811(3) 0.0292(8) Uani 1 1 d . . . . .
O52 O 0.4175(3) 0.89486(16) 0.0860(3) 0.0284(8) Uani 1 1 d . . . . .
O66 O 0.2361(2) 0.76872(16) 0.2723(3) 0.0245(7) Uani 1 1 d . . . . .
O83 O 0.0920(2) 0.80600(15) 0.1108(3) 0.0234(7) Uani 1 1 d . . . . .
O91 O 0.1981(3) 0.90110(16) 0.0001(3) 0.0275(8) Uani 1 1 d . . . . .
O95 O 0.3144(2) 0.77214(15) 0.0647(3) 0.0251(8) Uani 1 1 d . . . . .
O97 O 0.3741(2) 0.87362(15) 0.2940(3) 0.0259(8) Uani 1 1 d . . . . .
O103 O 0.2600(3) 0.98019(16) 0.1757(3) 0.0271(8) Uani 1 1 d . . . . .
C2 C 0.5504(4) 0.8024(3) -0.1019(5) 0.0372(14) Uani 1 1 d . . . . .
H2 H 0.5403 0.7709 -0.1598 0.045 Uiso 1 1 calc R U . . .
C3 C 0.2771(4) 1.0349(3) -0.0718(5) 0.0299(13) Uani 1 1 d . . . . .
H3 H 0.2912 1.0209 -0.0039 0.036 Uiso 1 1 calc R U . . .
C6 C 0.6876(4) 0.7161(3) 0.3035(5) 0.0323(14) Uani 1 1 d . . . . .
H6 H 0.7599 0.7102 0.3182 0.039 Uiso 1 1 calc R U . . .
C7 C 0.0376(3) 0.7611(2) 0.1514(4) 0.0235(10) Uani 1 1 d . . . . .
C8 C 0.5714(4) 0.9006(3) -0.0210(5) 0.0343(13) Uani 1 1 d . . . . .
C9 C 0.1619(4) 0.7298(2) 0.2882(4) 0.0229(12) Uani 1 1 d . . . . .
C10 C 0.4607(4) 0.7793(3) 0.5461(5) 0.0359(13) Uani 1 1 d . . . . .
H10 H 0.5255 0.7612 0.5260 0.043 Uiso 1 1 calc R U . . .
C12 C 0.0800(4) 0.7128(3) 0.4488(5) 0.0378(13) Uani 1 1 d . . . . .
H12A H 0.0934 0.7603 0.4593 0.045 Uiso 1 1 calc R U . . .
H12B H 0.0814 0.6904 0.5159 0.045 Uiso 1 1 calc R U . . .
C13 C 0.0284(4) 0.9836(2) -0.0002(4) 0.0269(11) Uani 1 1 d . . . . .
C14 C -0.1263(5) 1.0454(3) 0.1077(6) 0.0427(17) Uani 1 1 d . . . . .
H14 H -0.1802 1.0663 0.1441 0.051 Uiso 1 1 calc R U . . .
C15 C 0.2018(4) 1.0022(2) -0.1325(4) 0.0239(11) Uani 1 1 d . . . . .
C16 C 0.4717(3) 0.8700(3) 0.0205(4) 0.0263(12) Uani 1 1 d . . . . .
C17 C 0.0842(5) 1.1111(3) 0.3211(6) 0.0394(17) Uani 1 1 d . . . . .
H17A H 0.0189 1.0887 0.2989 0.047 Uiso 1 1 calc R U . . .
H17B H 0.0666 1.1520 0.3578 0.047 Uiso 1 1 calc R U . . .
C18 C -0.0624(4) 0.8665(4) -0.2960(5) 0.0445(14) Uani 1 1 d . . . . .
H18 H -0.1168 0.8816 -0.3405 0.053 Uiso 1 1 calc R U . . .
C19 C 0.3842(4) 0.7630(2) -0.0013(4) 0.0259(11) Uani 1 1 d . . . . .
C20 C 0.6593(3) 0.8560(4) 0.0256(5) 0.0445(14) Uani 1 1 d . . . . .
H20A H 0.7289 0.8757 0.0151 0.053 Uiso 1 1 calc R U . . .
H20B H 0.6496 0.8496 0.0995 0.053 Uiso 1 1 calc R U . . .
C21 C 0.5315(4) 0.7819(3) 0.3171(4) 0.0256(11) Uani 1 1 d . . . . .
C22 C 0.1531(4) 1.0657(3) 0.3878(5) 0.0322(14) Uani 1 1 d . . . . .
H22 H 0.1303 1.0604 0.4597 0.039 Uiso 1 1 calc R U . . .
C23 C 0.5642(4) 0.8757(3) -0.1332(5) 0.0409(17) Uani 1 1 d . . . . .
C24 C -0.0293(5) 0.8031(3) -0.3020(6) 0.0459(16) Uani 1 1 d . . . . .
H24 H -0.0593 0.7746 -0.3518 0.055 Uiso 1 1 calc R U . . .
C25 C 0.2408(4) 1.0749(2) -0.2727(4) 0.0279(11) Uani 1 1 d . . . . .
H25 H 0.2293 1.0880 -0.3415 0.033 Uiso 1 1 calc R U . . .
C26 C 0.5689(5) 0.9568(3) 0.2989(6) 0.0431(17) Uani 1 1 d . . . . .
H26 H 0.5291 0.9505 0.2377 0.052 Uiso 1 1 calc R U . . .
C27 C 0.5847(5) 0.9737(3) -0.0009(5) 0.0430(15) Uani 1 1 d . . . . .
H27A H 0.6503 0.9888 -0.0300 0.052 Uiso 1 1 calc R U . . .
H27B H 0.5261 0.9977 -0.0325 0.052 Uiso 1 1 calc R U . . .
H27C H 0.5864 0.9816 0.0727 0.052 Uiso 1 1 calc R U . . .
C28 C 0.1637(4) 1.0020(3) 0.3286(5) 0.0256(13) Uani 1 1 d . . . . .
C29 C -0.0260(4) 0.7015(3) 0.3917(5) 0.0394(14) Uani 1 1 d . . . . .
H29A H -0.0716 0.6717 0.4305 0.047 Uiso 1 1 calc R U . . .
H29B H -0.0630 0.7435 0.3793 0.047 Uiso 1 1 calc R U . . .
C30 C 0.5533(4) 0.9168(3) 0.3819(5) 0.0328(13) Uani 1 1 d . . . . .
C31 C 0.3125(3) 1.1090(2) -0.2102(4) 0.0239(11) Uani 1 1 d . . . . .
C32 C 0.0479(5) 0.7801(3) -0.2357(6) 0.0478(17) Uani 1 1 d . . . . .
H32 H 0.0694 0.7354 -0.2387 0.057 Uiso 1 1 calc R U . . .
C33 C 0.4768(4) 0.7344(2) 0.2609(4) 0.0293(12) Uani 1 1 d . . . . .
H33 H 0.4047 0.7405 0.2455 0.035 Uiso 1 1 calc R U . . .
C34 C 0.3769(4) 0.6946(3) -0.0488(5) 0.0346(13) Uani 1 1 d . . . . .
C35 C 0.6375(4) 0.7728(2) 0.3368(5) 0.0320(12) Uani 1 1 d . . . . .
H35 H 0.6762 0.8054 0.3731 0.038 Uiso 1 1 calc R U . . .
C37 C 0.0048(5) 1.0493(3) -0.0185(5) 0.0372(14) Uani 1 1 d . . . . .
H37 H 0.0425 1.0730 -0.0681 0.045 Uiso 1 1 calc R U . . .
C39 C 0.3310(4) 1.0879(2) -0.1120(4) 0.0298(12) Uani 1 1 d . . . . .
H39 H 0.3816 1.1101 -0.0706 0.036 Uiso 1 1 calc R U . . .
C40 C 0.0998(5) 0.6247(3) 0.3269(6) 0.0315(15) Uani 1 1 d . . . . .
C43 C 0.2644(4) 1.0956(3) 0.3756(5) 0.0325(12) Uani 1 1 d . . . . .
C46 C 0.0676(5) 0.5711(3) 0.4017(5) 0.0422(15) Uani 1 1 d . . . . .
H46A H 0.0298 0.5910 0.4579 0.051 Uiso 1 1 calc R U . . .
H46B H 0.0224 0.5391 0.3663 0.051 Uiso 1 1 calc R U . . .
H46C H 0.1301 0.5487 0.4287 0.051 Uiso 1 1 calc R U . . .
C47 C 0.0076(4) 0.6693(3) 0.2900(5) 0.0367(13) Uani 1 1 d . . . . .
H47 H -0.0493 0.6465 0.2501 0.044 Uiso 1 1 calc R U . . .
C48 C -0.0267(4) 0.9495(3) 0.0736(5) 0.0395(15) Uani 1 1 d . . . . .
H48 H -0.0118 0.9044 0.0865 0.047 Uiso 1 1 calc R U . . .
C49 C 0.4593(4) 0.8073(2) -0.0297(4) 0.0266(11) Uani 1 1 d . . . . .
C50 C 0.1616(4) 0.6822(3) 0.3771(5) 0.0264(12) Uani 1 1 d . . . . .
C53 C -0.0688(5) 0.7520(3) 0.0978(5) 0.0334(14) Uani 1 1 d . . . . .
C54 C 0.0659(4) 0.7231(2) 0.2327(4) 0.0277(11) Uani 1 1 d . . . . .
C55 C 0.4111(4) 0.8266(2) 0.4860(4) 0.0277(11) Uani 1 1 d . . . . .
C57 C 0.6485(4) 0.7895(3) -0.0324(6) 0.0471(16) Uani 1 1 d . . . . .
H57A H 0.6368 0.7525 0.0151 0.057 Uiso 1 1 calc R U . . .
H57B H 0.7109 0.7802 -0.0731 0.057 Uiso 1 1 calc R U . . .
C59 C 0.0341(5) 0.9333(3) 0.4208(5) 0.0410(15) Uani 1 1 d . . . . .
C60 C 0.2681(4) 0.6680(3) 0.4259(5) 0.0371(14) Uani 1 1 d . . . . .
H60A H 0.2602 0.6369 0.4823 0.045 Uiso 1 1 calc R U . . .
H60B H 0.3139 0.6489 0.3750 0.045 Uiso 1 1 calc R U . . .
H60C H 0.2988 0.7090 0.4519 0.045 Uiso 1 1 calc R U . . .
C61 C -0.0731(5) 1.0810(3) 0.0347(5) 0.0454(16) Uani 1 1 d . . . . .
H61 H -0.0897 1.1258 0.0217 0.054 Uiso 1 1 calc R U . . .
C64 C 0.2747(5) 1.1667(3) 0.4130(6) 0.0497(17) Uani 1 1 d . . . . .
H64A H 0.2192 1.1935 0.3815 0.060 Uiso 1 1 calc R U . . .
H64B H 0.2686 1.1679 0.4873 0.060 Uiso 1 1 calc R U . . .
H64C H 0.3429 1.1842 0.3943 0.060 Uiso 1 1 calc R U . . .
C68 C 0.2595(4) 1.0892(2) 0.2568(5) 0.0314(12) Uani 1 1 d . . . . .
C70 C -0.1032(5) 0.9815(3) 0.1282(6) 0.0454(17) Uani 1 1 d . . . . .
H70 H -0.1394 0.9587 0.1799 0.054 Uiso 1 1 calc R U . . .
C71 C 0.2726(5) 0.8324(3) 0.6062(5) 0.0449(16) Uani 1 1 d . . . . .
H71 H 0.2084 0.8508 0.6272 0.054 Uiso 1 1 calc R U . . .
C75 C 0.3521(5) 1.0549(3) 0.4262(5) 0.0465(16) Uani 1 1 d . . . . .
H75A H 0.3467 1.0092 0.4031 0.056 Uiso 1 1 calc R U . . .
H75B H 0.4199 1.0729 0.4074 0.056 Uiso 1 1 calc R U . . .
H75C H 0.3456 1.0566 0.5004 0.056 Uiso 1 1 calc R U . . .
C78 C 0.7022(6) 1.0144(4) 0.3956(8) 0.065(2) Uani 1 1 d . . . . .
H78 H 0.7554 1.0469 0.3998 0.079 Uiso 1 1 calc R U . . .
C79 C 0.6645(5) 0.8890(4) -0.1936(6) 0.062(2) Uani 1 1 d . . . . .
H79A H 0.7250 0.8707 -0.1564 0.074 Uiso 1 1 calc R U . . .
H79B H 0.6581 0.8682 -0.2608 0.074 Uiso 1 1 calc R U . . .
H79C H 0.6738 0.9365 -0.2019 0.074 Uiso 1 1 calc R U . . .
C80 C 0.1592(6) 0.5924(3) 0.2389(6) 0.0425(19) Uani 1 1 d . . . . .
H80A H 0.1802 0.6263 0.1905 0.051 Uiso 1 1 calc R U . . .
H80B H 0.2214 0.5699 0.2664 0.051 Uiso 1 1 calc R U . . .
H80C H 0.1137 0.5604 0.2041 0.051 Uiso 1 1 calc R U . . .
C82 C 0.0622(4) 0.8872(3) -0.1599(5) 0.0258(13) Uani 1 1 d . . . . .
C86 C 0.4720(5) 0.9051(3) -0.1941(5) 0.0502(16) Uani 1 1 d . . . . .
H86A H 0.4073 0.8974 -0.1576 0.060 Uiso 1 1 calc R U . . .
H86B H 0.4827 0.9525 -0.2024 0.060 Uiso 1 1 calc R U . . .
H86C H 0.4671 0.8842 -0.2613 0.060 Uiso 1 1 calc R U . . .
C93 C 0.0941(5) 0.8225(3) -0.1648(6) 0.0352(15) Uani 1 1 d . . . . .
H93 H 0.1477 0.8069 -0.1197 0.042 Uiso 1 1 calc R U . . .
C94 C -0.0167(4) 0.9099(3) -0.2245(5) 0.0342(13) Uani 1 1 d . . . . .
H94 H -0.0397 0.9542 -0.2205 0.041 Uiso 1 1 calc R U . . .
C96 C 0.3169(4) 0.8537(4) 0.5161(4) 0.0362(13) Uani 1 1 d . . . . .
H96 H 0.2832 0.8865 0.4756 0.043 Uiso 1 1 calc R U . . .
C98 C 0.5270(4) 0.6783(2) 0.2273(5) 0.0316(12) Uani 1 1 d . . . . .
H98 H 0.4889 0.6464 0.1889 0.038 Uiso 1 1 calc R U . . .
C99 C 0.6327(4) 0.6682(2) 0.2491(4) 0.0241(10) Uani 1 1 d . . . . .
C100 C 0.6105(5) 0.9259(3) 0.4728(6) 0.0571(19) Uani 1 1 d . . . . .
H100 H 0.5995 0.8984 0.5301 0.069 Uiso 1 1 calc R U . . .
C101 C 0.6838(7) 0.9763(4) 0.4771(8) 0.082(3) Uani 1 1 d . . . . .
H101 H 0.7218 0.9839 0.5390 0.098 Uiso 1 1 calc R U . . .
C102 C 0.6443(6) 1.0069(4) 0.3055(7) 0.059(2) Uani 1 1 d . . . . .
H102 H 0.6555 1.0352 0.2492 0.071 Uiso 1 1 calc R U . . .
C104 C 0.1139(4) 0.9422(2) 0.3369(4) 0.0268(11) Uani 1 1 d . . . . .
C105 C 0.2310(4) 1.0168(2) 0.2466(4) 0.0264(11) Uani 1 1 d . . . . .
C106 C 0.1861(4) 1.0214(2) -0.2331(4) 0.0269(11) Uani 1 1 d . . . . .
H106 H 0.1378 0.9981 -0.2756 0.032 Uiso 1 1 calc R U . . .
C107 C 0.4155(5) 0.7585(3) 0.6356(5) 0.0432(15) Uani 1 1 d . . . . .
H107 H 0.4494 0.7261 0.6767 0.052 Uiso 1 1 calc R U . . .
C108 C 0.3217(5) 0.7845(3) 0.6653(5) 0.0463(15) Uani 1 1 d . . . . .
H108 H 0.2907 0.7697 0.7262 0.056 Uiso 1 1 calc R U . . .
C110 C 0.3522(5) 1.1108(3) 0.1972(5) 0.0455(16) Uani 1 1 d . . . . .
H11A H 0.3646 1.1578 0.2084 0.055 Uiso 1 1 calc R U . . .
H11B H 0.4140 1.0858 0.2198 0.055 Uiso 1 1 calc R U . . .
H11C H 0.3385 1.1028 0.1245 0.055 Uiso 1 1 calc R U . . .
C111 C 0.1538(6) 1.1253(3) 0.2309(6) 0.0408(19) Uani 1 1 d . . . . .
H11D H 0.1651 1.1732 0.2233 0.049 Uiso 1 1 calc R U . . .
H11E H 0.1219 1.1080 0.1669 0.049 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O91 2.325(4) . ?
Eu1 O95 2.347(3) . ?
Eu1 O97 2.362(3) . ?
Eu1 O5 2.370(3) . ?
Eu1 O83 2.390(3) . ?
Eu1 O66 2.403(3) . ?
Eu1 O103 2.438(3) . ?
Eu1 O52 2.463(3) . ?
P1 O97 1.494(3) . ?
P1 C30 1.793(5) . ?
P1 C21 1.803(5) . ?
P1 C55 1.804(6) . ?
P92 O91 1.493(4) . ?
P92 C15 1.794(5) . ?
P92 C13 1.804(5) . ?
P92 C82 1.806(6) . ?
F4 C53 1.269(7) . ?
F41 C53 1.333(8) . ?
F42 C34 1.282(7) . ?
F45 C34 1.316(7) . ?
F56 C34 1.319(8) . ?
F65 C53 1.264(7) . ?
F73 C59 1.316(6) . ?
F77 C59 1.334(7) . ?
F109 C59 1.355(8) . ?
O5 C104 1.269(6) . ?
O52 C16 1.226(6) . ?
O66 C9 1.258(6) . ?
O83 C7 1.273(6) . ?
O95 C19 1.273(6) . ?
O103 C105 1.255(6) . ?
C2 C49 1.524(7) . ?
C2 C23 1.557(9) . ?
C2 C57 1.558(9) . ?
C2 H2 1.0000 . ?
C3 C39 1.390(7) . ?
C3 C15 1.405(8) . ?
C3 H3 0.9500 . ?
C6 C99 1.390(7) . ?
C6 C35 1.393(7) . ?
C6 H6 0.9500 . ?
C7 C54 1.359(7) . ?
C7 C53 1.531(7) . ?
C8 C27 1.517(8) . ?
C8 C16 1.532(7) . ?
C8 C20 1.560(8) . ?
C8 C23 1.559(8) . ?
C9 C54 1.421(7) . ?
C9 C50 1.517(7) . ?
C10 C107 1.389(9) . ?
C10 C55 1.389(7) . ?
C10 H10 0.9500 . ?
C12 C50 1.553(8) . ?
C12 C29 1.553(8) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C37 1.390(7) . ?
C13 C48 1.397(8) . ?
C14 C70 1.357(9) . ?
C14 C61 1.391(9) . ?
C14 H14 0.9500 . ?
C15 C106 1.388(7) . ?
C16 C49 1.443(8) . ?
C17 C111 1.527(11) . ?
C17 C22 1.537(9) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C24 1.358(10) . ?
C18 C94 1.406(8) . ?
C18 H18 0.9500 . ?
C19 C49 1.375(7) . ?
C19 C34 1.526(7) . ?
C20 C57 1.556(10) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C35 1.389(7) . ?
C21 C33 1.394(7) . ?
C22 C28 1.517(7) . ?
C22 C43 1.562(7) . ?
C22 H22 1.0000 . ?
C23 C86 1.532(9) . ?
C23 C79 1.549(8) . ?
C24 C32 1.384(9) . ?
C24 H24 0.9500 . ?
C25 C106 1.399(7) . ?
C25 C31 1.402(7) . ?
C25 H25 0.9500 . ?
C26 C30 1.378(9) . ?
C26 C102 1.405(9) . ?
C26 H26 0.9500 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 C104 1.380(7) . ?
C28 C105 1.426(8) . ?
C29 C47 1.557(9) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C100 1.399(9) . ?
C31 C39 1.373(7) . ?
C31 C99 1.489(6) 2_655 ?
C32 C93 1.392(9) . ?
C32 H32 0.9500 . ?
C33 C98 1.387(7) . ?
C33 H33 0.9500 . ?
C35 H35 0.9500 . ?
C37 C61 1.389(8) . ?
C37 H37 0.9500 . ?
C39 H39 0.9500 . ?
C40 C46 1.530(8) . ?
C40 C80 1.545(10) . ?
C40 C50 1.550(8) . ?
C40 C47 1.557(8) . ?
C43 C64 1.531(7) . ?
C43 C75 1.535(9) . ?
C43 C68 1.565(8) . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 C54 1.532(7) . ?
C47 H47 1.0000 . ?
C48 C70 1.390(9) . ?
C48 H48 0.9500 . ?
C50 C60 1.522(8) . ?
C55 C96 1.391(7) . ?
C57 H57A 0.9900 . ?
C57 H57B 0.9900 . ?
C59 C104 1.530(8) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61 0.9500 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C68 C110 1.504(8) . ?
C68 C105 1.522(7) . ?
C68 C111 1.571(9) . ?
C70 H70 0.9500 . ?
C71 C108 1.387(9) . ?
C71 C96 1.393(8) . ?
C71 H71 0.9500 . ?
C75 H75A 0.9800 . ?
C75 H75B 0.9800 . ?
C75 H75C 0.9800 . ?
C78 C101 1.347(13) . ?
C78 C102 1.390(12) . ?
C78 H78 0.9500 . ?
C79 H79A 0.9800 . ?
C79 H79B 0.9800 . ?
C79 H79C 0.9800 . ?
C80 H80A 0.9800 . ?
C80 H80B 0.9800 . ?
C80 H80C 0.9800 . ?
C82 C93 1.378(7) . ?
C82 C94 1.383(8) . ?
C86 H86A 0.9800 . ?
C86 H86B 0.9800 . ?
C86 H86C 0.9800 . ?
C93 H93 0.9500 . ?
C94 H94 0.9500 . ?
C96 H96 0.9500 . ?
C98 C99 1.393(7) . ?
C98 H98 0.9500 . ?
C99 C31 1.489(6) 2_645 ?
C100 C101 1.389(10) . ?
C100 H100 0.9500 . ?
C101 H101 0.9500 . ?
C102 H102 0.9500 . ?
C106 H106 0.9500 . ?
C107 C108 1.378(9) . ?
C107 H107 0.9500 . ?
C108 H108 0.9500 . ?
C110 H11A 0.9800 . ?
C110 H11B 0.9800 . ?
C110 H11C 0.9800 . ?
C111 H11D 0.9900 . ?
C111 H11E 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O91 Eu1 O95 83.90(12) . . ?
O91 Eu1 O97 144.01(12) . . ?
O95 Eu1 O97 104.15(11) . . ?
O91 Eu1 O5 109.22(13) . . ?
O95 Eu1 O5 144.03(11) . . ?
O97 Eu1 O5 84.92(12) . . ?
O91 Eu1 O83 72.59(12) . . ?
O95 Eu1 O83 78.78(11) . . ?
O97 Eu1 O83 143.11(12) . . ?
O5 Eu1 O83 73.98(12) . . ?
O91 Eu1 O66 143.60(12) . . ?
O95 Eu1 O66 76.07(12) . . ?
O97 Eu1 O66 71.37(11) . . ?
O5 Eu1 O66 74.13(11) . . ?
O83 Eu1 O66 73.88(11) . . ?
O91 Eu1 O103 75.17(12) . . ?
O95 Eu1 O103 142.70(11) . . ?
O97 Eu1 O103 78.02(12) . . ?
O5 Eu1 O103 72.95(11) . . ?
O83 Eu1 O103 121.93(11) . . ?
O66 Eu1 O103 136.45(12) . . ?
O91 Eu1 O52 77.73(12) . . ?
O95 Eu1 O52 72.17(11) . . ?
O97 Eu1 O52 71.87(12) . . ?
O5 Eu1 O52 142.29(12) . . ?
O83 Eu1 O52 140.20(12) . . ?
O66 Eu1 O52 122.65(11) . . ?
O103 Eu1 O52 73.40(11) . . ?
O97 P1 C30 109.7(2) . . ?
O97 P1 C21 113.3(2) . . ?
C30 P1 C21 106.6(2) . . ?
O97 P1 C55 111.3(2) . . ?
C30 P1 C55 109.9(3) . . ?
C21 P1 C55 105.9(3) . . ?
O91 P92 C15 109.8(2) . . ?
O91 P92 C13 112.5(2) . . ?
C15 P92 C13 106.2(2) . . ?
O91 P92 C82 110.2(2) . . ?
C15 P92 C82 110.6(3) . . ?
C13 P92 C82 107.5(2) . . ?
C104 O5 Eu1 134.5(3) . . ?
C16 O52 Eu1 131.9(3) . . ?
C9 O66 Eu1 131.5(3) . . ?
C7 O83 Eu1 133.9(3) . . ?
P92 O91 Eu1 152.7(2) . . ?
C19 O95 Eu1 136.9(3) . . ?
P1 O97 Eu1 154.8(2) . . ?
C105 O103 Eu1 130.0(3) . . ?
C49 C2 C23 101.2(4) . . ?
C49 C2 C57 105.4(5) . . ?
C23 C2 C57 102.8(5) . . ?
C49 C2 H2 115.2 . . ?
C23 C2 H2 115.2 . . ?
C57 C2 H2 115.2 . . ?
C39 C3 C15 119.5(5) . . ?
C39 C3 H3 120.2 . . ?
C15 C3 H3 120.2 . . ?
C99 C6 C35 120.7(5) . . ?
C99 C6 H6 119.7 . . ?
C35 C6 H6 119.7 . . ?
O83 C7 C54 126.7(4) . . ?
O83 C7 C53 112.5(4) . . ?
C54 C7 C53 120.7(4) . . ?
C27 C8 C16 115.3(5) . . ?
C27 C8 C20 115.1(5) . . ?
C16 C8 C20 103.0(5) . . ?
C27 C8 C23 119.1(5) . . ?
C16 C8 C23 99.9(4) . . ?
C20 C8 C23 102.0(5) . . ?
O66 C9 C54 128.6(5) . . ?
O66 C9 C50 123.0(5) . . ?
C54 C9 C50 108.4(4) . . ?
C107 C10 C55 119.8(5) . . ?
C107 C10 H10 120.1 . . ?
C55 C10 H10 120.1 . . ?
C50 C12 C29 104.0(5) . . ?
C50 C12 H12A 111.0 . . ?
C29 C12 H12A 111.0 . . ?
C50 C12 H12B 111.0 . . ?
C29 C12 H12B 111.0 . . ?
H12A C12 H12B 109.0 . . ?
C37 C13 C48 119.1(5) . . ?
C37 C13 P92 122.4(4) . . ?
C48 C13 P92 118.5(4) . . ?
C70 C14 C61 121.8(6) . . ?
C70 C14 H14 119.1 . . ?
C61 C14 H14 119.1 . . ?
C106 C15 C3 119.2(5) . . ?
C106 C15 P92 125.2(4) . . ?
C3 C15 P92 115.5(4) . . ?
O52 C16 C49 128.8(5) . . ?
O52 C16 C8 124.9(5) . . ?
C49 C16 C8 106.3(4) . . ?
C111 C17 C22 102.6(5) . . ?
C111 C17 H17A 111.2 . . ?
C22 C17 H17A 111.2 . . ?
C111 C17 H17B 111.2 . . ?
C22 C17 H17B 111.2 . . ?
H17A C17 H17B 109.2 . . ?
C24 C18 C94 120.5(6) . . ?
C24 C18 H18 119.7 . . ?
C94 C18 H18 119.7 . . ?
O95 C19 C49 126.5(5) . . ?
O95 C19 C34 112.0(4) . . ?
C49 C19 C34 121.5(5) . . ?
C57 C20 C8 105.0(5) . . ?
C57 C20 H20A 110.7 . . ?
C8 C20 H20A 110.7 . . ?
C57 C20 H20B 110.7 . . ?
C8 C20 H20B 110.7 . . ?
H20A C20 H20B 108.8 . . ?
C35 C21 C33 118.9(5) . . ?
C35 C21 P1 122.7(4) . . ?
C33 C21 P1 118.4(4) . . ?
C28 C22 C17 106.1(5) . . ?
C28 C22 C43 100.8(4) . . ?
C17 C22 C43 102.7(5) . . ?
C28 C22 H22 115.2 . . ?
C17 C22 H22 115.2 . . ?
C43 C22 H22 115.2 . . ?
C86 C23 C79 107.6(6) . . ?
C86 C23 C2 114.9(5) . . ?
C79 C23 C2 113.7(5) . . ?
C86 C23 C8 113.2(5) . . ?
C79 C23 C8 113.3(5) . . ?
C2 C23 C8 93.8(5) . . ?
C18 C24 C32 120.3(6) . . ?
C18 C24 H24 119.9 . . ?
C32 C24 H24 119.9 . . ?
C106 C25 C31 119.6(5) . . ?
C106 C25 H25 120.2 . . ?
C31 C25 H25 120.2 . . ?
C30 C26 C102 119.4(7) . . ?
C30 C26 H26 120.3 . . ?
C102 C26 H26 120.3 . . ?
C8 C27 H27A 109.5 . . ?
C8 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C8 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C104 C28 C105 122.3(5) . . ?
C104 C28 C22 131.6(5) . . ?
C105 C28 C22 105.7(4) . . ?
C47 C29 C12 102.7(5) . . ?
C47 C29 H29A 111.2 . . ?
C12 C29 H29A 111.2 . . ?
C47 C29 H29B 111.2 . . ?
C12 C29 H29B 111.2 . . ?
H29A C29 H29B 109.1 . . ?
C26 C30 C100 121.0(6) . . ?
C26 C30 P1 116.3(5) . . ?
C100 C30 P1 122.7(5) . . ?
C39 C31 C25 119.4(4) . . ?
C39 C31 C99 120.1(4) . 2_655 ?
C25 C31 C99 120.5(5) . 2_655 ?
C24 C32 C93 119.8(6) . . ?
C24 C32 H32 120.1 . . ?
C93 C32 H32 120.1 . . ?
C98 C33 C21 120.5(5) . . ?
C98 C33 H33 119.7 . . ?
C21 C33 H33 119.7 . . ?
F42 C34 F45 105.7(5) . . ?
F42 C34 F56 107.3(7) . . ?
F45 C34 F56 102.2(5) . . ?
F42 C34 C19 116.1(5) . . ?
F45 C34 C19 112.6(5) . . ?
F56 C34 C19 111.8(5) . . ?
C21 C35 C6 120.5(5) . . ?
C21 C35 H35 119.8 . . ?
C6 C35 H35 119.8 . . ?
C13 C37 C61 120.9(6) . . ?
C13 C37 H37 119.5 . . ?
C61 C37 H37 119.5 . . ?
C31 C39 C3 121.5(5) . . ?
C31 C39 H39 119.3 . . ?
C3 C39 H39 119.3 . . ?
C46 C40 C80 108.7(5) . . ?
C46 C40 C50 114.0(5) . . ?
C80 C40 C50 112.5(5) . . ?
C46 C40 C47 113.7(5) . . ?
C80 C40 C47 113.5(6) . . ?
C50 C40 C47 94.0(4) . . ?
C64 C43 C75 108.3(5) . . ?
C64 C43 C22 114.1(5) . . ?
C75 C43 C22 113.9(5) . . ?
C64 C43 C68 113.6(5) . . ?
C75 C43 C68 113.4(5) . . ?
C22 C43 C68 93.1(4) . . ?
C40 C46 H46A 109.5 . . ?
C40 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C40 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C54 C47 C29 105.6(5) . . ?
C54 C47 C40 101.2(4) . . ?
C29 C47 C40 101.5(5) . . ?
C54 C47 H47 115.5 . . ?
C29 C47 H47 115.5 . . ?
C40 C47 H47 115.5 . . ?
C70 C48 C13 119.9(5) . . ?
C70 C48 H48 120.0 . . ?
C13 C48 H48 120.0 . . ?
C19 C49 C16 121.7(5) . . ?
C19 C49 C2 132.6(5) . . ?
C16 C49 C2 105.3(4) . . ?
C9 C50 C60 115.2(5) . . ?
C9 C50 C40 99.5(5) . . ?
C60 C50 C40 118.7(5) . . ?
C9 C50 C12 103.0(4) . . ?
C60 C50 C12 115.5(5) . . ?
C40 C50 C12 102.4(5) . . ?
F65 C53 F4 110.9(7) . . ?
F65 C53 F41 102.2(7) . . ?
F4 C53 F41 100.4(6) . . ?
F65 C53 C7 116.6(5) . . ?
F4 C53 C7 115.6(5) . . ?
F41 C53 C7 108.9(5) . . ?
C7 C54 C9 124.0(5) . . ?
C7 C54 C47 131.8(4) . . ?
C9 C54 C47 104.1(4) . . ?
C96 C55 C10 120.1(5) . . ?
C96 C55 P1 117.6(4) . . ?
C10 C55 P1 122.2(4) . . ?
C20 C57 C2 101.6(4) . . ?
C20 C57 H57A 111.4 . . ?
C2 C57 H57A 111.4 . . ?
C20 C57 H57B 111.4 . . ?
C2 C57 H57B 111.4 . . ?
H57A C57 H57B 109.3 . . ?
F73 C59 F77 106.8(5) . . ?
F73 C59 F109 107.5(6) . . ?
F77 C59 F109 105.0(5) . . ?
F73 C59 C104 112.7(5) . . ?
F77 C59 C104 112.3(5) . . ?
F109 C59 C104 112.0(5) . . ?
C50 C60 H60A 109.5 . . ?
C50 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C50 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C37 C61 C14 118.3(6) . . ?
C37 C61 H61 120.9 . . ?
C14 C61 H61 120.9 . . ?
C43 C64 H64A 109.5 . . ?
C43 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C43 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
C110 C68 C105 115.3(4) . . ?
C110 C68 C111 116.0(5) . . ?
C105 C68 C111 103.3(4) . . ?
C110 C68 C43 118.7(5) . . ?
C105 C68 C43 100.0(4) . . ?
C111 C68 C43 101.0(5) . . ?
C14 C70 C48 119.9(6) . . ?
C14 C70 H70 120.1 . . ?
C48 C70 H70 120.1 . . ?
C108 C71 C96 120.3(6) . . ?
C108 C71 H71 119.9 . . ?
C96 C71 H71 119.9 . . ?
C43 C75 H75A 109.5 . . ?
C43 C75 H75B 109.5 . . ?
H75A C75 H75B 109.5 . . ?
C43 C75 H75C 109.5 . . ?
H75A C75 H75C 109.5 . . ?
H75B C75 H75C 109.5 . . ?
C101 C78 C102 120.9(7) . . ?
C101 C78 H78 119.6 . . ?
C102 C78 H78 119.6 . . ?
C23 C79 H79A 109.5 . . ?
C23 C79 H79B 109.5 . . ?
H79A C79 H79B 109.5 . . ?
C23 C79 H79C 109.5 . . ?
H79A C79 H79C 109.5 . . ?
H79B C79 H79C 109.5 . . ?
C40 C80 H80A 109.5 . . ?
C40 C80 H80B 109.5 . . ?
H80A C80 H80B 109.5 . . ?
C40 C80 H80C 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C93 C82 C94 120.2(6) . . ?
C93 C82 P92 117.9(5) . . ?
C94 C82 P92 121.9(4) . . ?
C23 C86 H86A 109.5 . . ?
C23 C86 H86B 109.5 . . ?
H86A C86 H86B 109.5 . . ?
C23 C86 H86C 109.5 . . ?
H86A C86 H86C 109.5 . . ?
H86B C86 H86C 109.5 . . ?
C82 C93 C32 120.0(7) . . ?
C82 C93 H93 120.0 . . ?
C32 C93 H93 120.0 . . ?
C82 C94 C18 119.1(6) . . ?
C82 C94 H94 120.4 . . ?
C18 C94 H94 120.4 . . ?
C55 C96 C71 119.4(6) . . ?
C55 C96 H96 120.3 . . ?
C71 C96 H96 120.3 . . ?
C33 C98 C99 120.7(5) . . ?
C33 C98 H98 119.6 . . ?
C99 C98 H98 119.6 . . ?
C6 C99 C98 118.7(5) . . ?
C6 C99 C31 120.5(4) . 2_645 ?
C98 C99 C31 120.8(5) . 2_645 ?
C101 C100 C30 118.2(8) . . ?
C101 C100 H100 120.9 . . ?
C30 C100 H100 120.9 . . ?
C78 C101 C100 121.5(8) . . ?
C78 C101 H101 119.2 . . ?
C100 C101 H101 119.2 . . ?
C78 C102 C26 119.0(8) . . ?
C78 C102 H102 120.5 . . ?
C26 C102 H102 120.5 . . ?
O5 C104 C28 126.8(5) . . ?
O5 C104 C59 114.6(4) . . ?
C28 C104 C59 118.6(5) . . ?
O103 C105 C28 129.0(5) . . ?
O103 C105 C68 124.4(5) . . ?
C28 C105 C68 106.5(4) . . ?
C15 C106 C25 120.7(5) . . ?
C15 C106 H106 119.7 . . ?
C25 C106 H106 119.7 . . ?
C108 C107 C10 120.4(6) . . ?
C108 C107 H107 119.8 . . ?
C10 C107 H107 119.8 . . ?
C107 C108 C71 119.9(6) . . ?
C107 C108 H108 120.0 . . ?
C71 C108 H108 120.0 . . ?
C68 C110 H11A 109.5 . . ?
C68 C110 H11B 109.5 . . ?
H11A C110 H11B 109.5 . . ?
C68 C110 H11C 109.5 . . ?
H11A C110 H11C 109.5 . . ?
H11B C110 H11C 109.5 . . ?
C17 C111 C68 105.0(6) . . ?
C17 C111 H11D 110.8 . . ?
C68 C111 H11D 110.8 . . ?
C17 C111 H11E 110.8 . . ?
C68 C111 H11E 110.8 . . ?
H11D C111 H11E 108.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C15 P92 O91 Eu1 120.6(4) . . . . ?
C13 P92 O91 Eu1 2.6(5) . . . . ?
C82 P92 O91 Eu1 -117.3(5) . . . . ?
C30 P1 O97 Eu1 139.1(5) . . . . ?
C21 P1 O97 Eu1 20.1(6) . . . . ?
C55 P1 O97 Eu1 -99.0(5) . . . . ?
Eu1 O83 C7 C54 -10.9(8) . . . . ?
Eu1 O83 C7 C53 169.6(4) . . . . ?
Eu1 O66 C9 C54 9.5(8) . . . . ?
Eu1 O66 C9 C50 -168.4(4) . . . . ?
O91 P92 C13 C37 133.8(5) . . . . ?
C15 P92 C13 C37 13.7(5) . . . . ?
C82 P92 C13 C37 -104.7(5) . . . . ?
O91 P92 C13 C48 -46.4(5) . . . . ?
C15 P92 C13 C48 -166.5(5) . . . . ?
C82 P92 C13 C48 75.1(5) . . . . ?
C39 C3 C15 C106 3.1(8) . . . . ?
C39 C3 C15 P92 -173.6(4) . . . . ?
O91 P92 C15 C106 141.7(4) . . . . ?
C13 P92 C15 C106 -96.5(5) . . . . ?
C82 P92 C15 C106 19.8(5) . . . . ?
O91 P92 C15 C3 -41.8(5) . . . . ?
C13 P92 C15 C3 80.0(4) . . . . ?
C82 P92 C15 C3 -163.7(4) . . . . ?
Eu1 O52 C16 C49 -6.7(8) . . . . ?
Eu1 O52 C16 C8 175.9(4) . . . . ?
C27 C8 C16 O52 -17.8(8) . . . . ?
C20 C8 C16 O52 108.4(6) . . . . ?
C23 C8 C16 O52 -146.8(5) . . . . ?
C27 C8 C16 C49 164.3(5) . . . . ?
C20 C8 C16 C49 -69.5(5) . . . . ?
C23 C8 C16 C49 35.3(5) . . . . ?
Eu1 O95 C19 C49 9.5(8) . . . . ?
Eu1 O95 C19 C34 -170.4(4) . . . . ?
C27 C8 C20 C57 -162.5(5) . . . . ?
C16 C8 C20 C57 71.3(5) . . . . ?
C23 C8 C20 C57 -32.0(5) . . . . ?
O97 P1 C21 C35 147.0(5) . . . . ?
C30 P1 C21 C35 26.3(6) . . . . ?
C55 P1 C21 C35 -90.8(5) . . . . ?
O97 P1 C21 C33 -34.9(5) . . . . ?
C30 P1 C21 C33 -155.6(5) . . . . ?
C55 P1 C21 C33 87.4(5) . . . . ?
C111 C17 C22 C28 -67.6(6) . . . . ?
C111 C17 C22 C43 37.8(6) . . . . ?
C49 C2 C23 C86 -65.1(6) . . . . ?
C57 C2 C23 C86 -173.9(5) . . . . ?
C49 C2 C23 C79 170.3(5) . . . . ?
C57 C2 C23 C79 61.5(7) . . . . ?
C49 C2 C23 C8 52.7(5) . . . . ?
C57 C2 C23 C8 -56.1(5) . . . . ?
C27 C8 C23 C86 -60.0(6) . . . . ?
C16 C8 C23 C86 66.4(6) . . . . ?
C20 C8 C23 C86 172.0(5) . . . . ?
C27 C8 C23 C79 62.9(7) . . . . ?
C16 C8 C23 C79 -170.7(5) . . . . ?
C20 C8 C23 C79 -65.0(6) . . . . ?
C27 C8 C23 C2 -179.2(5) . . . . ?
C16 C8 C23 C2 -52.8(5) . . . . ?
C20 C8 C23 C2 52.9(5) . . . . ?
C94 C18 C24 C32 1.8(10) . . . . ?
C17 C22 C28 C104 -100.5(8) . . . . ?
C43 C22 C28 C104 152.8(6) . . . . ?
C17 C22 C28 C105 72.2(6) . . . . ?
C43 C22 C28 C105 -34.6(6) . . . . ?
C50 C12 C29 C47 -3.3(6) . . . . ?
C102 C26 C30 C100 0.7(9) . . . . ?
C102 C26 C30 P1 -176.9(5) . . . . ?
O97 P1 C30 C26 -34.3(5) . . . . ?
C21 P1 C30 C26 88.7(5) . . . . ?
C55 P1 C30 C26 -157.0(4) . . . . ?
O97 P1 C30 C100 148.1(5) . . . . ?
C21 P1 C30 C100 -88.9(5) . . . . ?
C55 P1 C30 C100 25.4(6) . . . . ?
C106 C25 C31 C39 2.4(7) . . . . ?
C106 C25 C31 C99 -176.7(5) . . . 2_655 ?
C18 C24 C32 C93 -2.0(11) . . . . ?
C35 C21 C33 C98 1.5(9) . . . . ?
P1 C21 C33 C98 -176.7(5) . . . . ?
O95 C19 C34 F42 -161.1(6) . . . . ?
C49 C19 C34 F42 18.9(9) . . . . ?
O95 C19 C34 F45 -39.1(7) . . . . ?
C49 C19 C34 F45 141.0(6) . . . . ?
O95 C19 C34 F56 75.3(7) . . . . ?
C49 C19 C34 F56 -104.7(6) . . . . ?
C33 C21 C35 C6 -2.0(9) . . . . ?
P1 C21 C35 C6 176.2(5) . . . . ?
C99 C6 C35 C21 0.8(10) . . . . ?
C48 C13 C37 C61 -0.7(9) . . . . ?
P92 C13 C37 C61 179.2(5) . . . . ?
C25 C31 C39 C3 -2.5(8) . . . . ?
C99 C31 C39 C3 176.7(5) 2_655 . . . ?
C15 C3 C39 C31 -0.3(8) . . . . ?
C28 C22 C43 C64 170.5(6) . . . . ?
C17 C22 C43 C64 61.1(7) . . . . ?
C28 C22 C43 C75 -64.4(6) . . . . ?
C17 C22 C43 C75 -173.8(5) . . . . ?
C28 C22 C43 C68 53.0(5) . . . . ?
C17 C22 C43 C68 -56.4(5) . . . . ?
C12 C29 C47 C54 -67.5(5) . . . . ?
C12 C29 C47 C40 37.7(5) . . . . ?
C46 C40 C47 C54 171.1(5) . . . . ?
C80 C40 C47 C54 -64.0(6) . . . . ?
C50 C40 C47 C54 52.7(5) . . . . ?
C46 C40 C47 C29 62.5(6) . . . . ?
C80 C40 C47 C29 -172.6(5) . . . . ?
C50 C40 C47 C29 -56.0(5) . . . . ?
C37 C13 C48 C70 -0.6(9) . . . . ?
P92 C13 C48 C70 179.6(5) . . . . ?
O95 C19 C49 C16 5.0(8) . . . . ?
C34 C19 C49 C16 -175.1(5) . . . . ?
O95 C19 C49 C2 176.1(6) . . . . ?
C34 C19 C49 C2 -4.0(9) . . . . ?
O52 C16 C49 C19 -5.8(9) . . . . ?
C8 C16 C49 C19 172.0(5) . . . . ?
O52 C16 C49 C2 -179.0(5) . . . . ?
C8 C16 C49 C2 -1.2(6) . . . . ?
C23 C2 C49 C19 154.3(6) . . . . ?
C57 C2 C49 C19 -98.9(7) . . . . ?
C23 C2 C49 C16 -33.5(6) . . . . ?
C57 C2 C49 C16 73.3(5) . . . . ?
O66 C9 C50 C60 -19.0(8) . . . . ?
C54 C9 C50 C60 162.8(5) . . . . ?
O66 C9 C50 C40 -147.1(5) . . . . ?
C54 C9 C50 C40 34.7(6) . . . . ?
O66 C9 C50 C12 107.6(6) . . . . ?
C54 C9 C50 C12 -70.6(5) . . . . ?
C46 C40 C50 C9 -170.0(5) . . . . ?
C80 C40 C50 C9 65.5(6) . . . . ?
C47 C40 C50 C9 -51.9(5) . . . . ?
C46 C40 C50 C60 64.2(8) . . . . ?
C80 C40 C50 C60 -60.3(7) . . . . ?
C47 C40 C50 C60 -177.7(5) . . . . ?
C46 C40 C50 C12 -64.3(6) . . . . ?
C80 C40 C50 C12 171.3(5) . . . . ?
C47 C40 C50 C12 53.8(5) . . . . ?
C29 C12 C50 C9 70.7(5) . . . . ?
C29 C12 C50 C60 -162.8(5) . . . . ?
C29 C12 C50 C40 -32.3(6) . . . . ?
O83 C7 C53 F65 140.6(7) . . . . ?
C54 C7 C53 F65 -38.9(10) . . . . ?
O83 C7 C53 F4 7.6(8) . . . . ?
C54 C7 C53 F4 -171.9(6) . . . . ?
O83 C7 C53 F41 -104.5(6) . . . . ?
C54 C7 C53 F41 76.0(7) . . . . ?
O83 C7 C54 C9 2.4(9) . . . . ?
C53 C7 C54 C9 -178.1(5) . . . . ?
O83 C7 C54 C47 178.2(5) . . . . ?
C53 C7 C54 C47 -2.4(10) . . . . ?
O66 C9 C54 C7 -1.9(9) . . . . ?
C50 C9 C54 C7 176.1(5) . . . . ?
O66 C9 C54 C47 -178.7(5) . . . . ?
C50 C9 C54 C47 -0.6(6) . . . . ?
C29 C47 C54 C7 -104.6(7) . . . . ?
C40 C47 C54 C7 149.9(6) . . . . ?
C29 C47 C54 C9 71.7(5) . . . . ?
C40 C47 C54 C9 -33.7(6) . . . . ?
C107 C10 C55 C96 0.9(9) . . . . ?
C107 C10 C55 P1 -175.4(5) . . . . ?
O97 P1 C55 C96 -25.5(5) . . . . ?
C30 P1 C55 C96 96.2(5) . . . . ?
C21 P1 C55 C96 -149.0(5) . . . . ?
O97 P1 C55 C10 150.9(4) . . . . ?
C30 P1 C55 C10 -87.4(5) . . . . ?
C21 P1 C55 C10 27.4(5) . . . . ?
C8 C20 C57 C2 -3.2(6) . . . . ?
C49 C2 C57 C20 -68.0(5) . . . . ?
C23 C2 C57 C20 37.6(6) . . . . ?
C13 C37 C61 C14 0.7(10) . . . . ?
C70 C14 C61 C37 0.6(11) . . . . ?
C64 C43 C68 C110 63.0(6) . . . . ?
C75 C43 C68 C110 -61.2(6) . . . . ?
C22 C43 C68 C110 -179.0(5) . . . . ?
C64 C43 C68 C105 -170.7(4) . . . . ?
C75 C43 C68 C105 65.1(5) . . . . ?
C22 C43 C68 C105 -52.7(4) . . . . ?
C64 C43 C68 C111 -65.0(6) . . . . ?
C75 C43 C68 C111 170.8(5) . . . . ?
C22 C43 C68 C111 53.0(5) . . . . ?
C61 C14 C70 C48 -1.9(11) . . . . ?
C13 C48 C70 C14 1.8(11) . . . . ?
O91 P92 C82 C93 -8.8(6) . . . . ?
C15 P92 C82 C93 112.8(5) . . . . ?
C13 P92 C82 C93 -131.7(5) . . . . ?
O91 P92 C82 C94 172.1(4) . . . . ?
C15 P92 C82 C94 -66.3(5) . . . . ?
C13 P92 C82 C94 49.2(5) . . . . ?
C94 C82 C93 C32 0.9(9) . . . . ?
P92 C82 C93 C32 -178.3(5) . . . . ?
C24 C32 C93 C82 0.6(10) . . . . ?
C93 C82 C94 C18 -1.1(9) . . . . ?
P92 C82 C94 C18 178.0(5) . . . . ?
C24 C18 C94 C82 -0.2(9) . . . . ?
C10 C55 C96 C71 -0.8(9) . . . . ?
P1 C55 C96 C71 175.7(5) . . . . ?
C108 C71 C96 C55 -0.1(10) . . . . ?
C21 C33 C98 C99 0.1(9) . . . . ?
C35 C6 C99 C98 0.8(9) . . . . ?
C35 C6 C99 C31 177.6(6) . . . 2_645 ?
C33 C98 C99 C6 -1.3(9) . . . . ?
C33 C98 C99 C31 -178.0(5) . . . 2_645 ?
C26 C30 C100 C101 -0.2(10) . . . . ?
P1 C30 C100 C101 177.3(6) . . . . ?
C102 C78 C101 C100 3.4(14) . . . . ?
C30 C100 C101 C78 -1.9(13) . . . . ?
C101 C78 C102 C26 -2.7(12) . . . . ?
C30 C26 C102 C78 0.7(10) . . . . ?
Eu1 O5 C104 C28 12.7(9) . . . . ?
Eu1 O5 C104 C59 -167.6(4) . . . . ?
C105 C28 C104 O5 6.2(9) . . . . ?
C22 C28 C104 O5 177.8(6) . . . . ?
C105 C28 C104 C59 -173.5(5) . . . . ?
C22 C28 C104 C59 -1.8(10) . . . . ?
F73 C59 C104 O5 -2.4(8) . . . . ?
F77 C59 C104 O5 -123.1(5) . . . . ?
F109 C59 C104 O5 119.0(5) . . . . ?
F73 C59 C104 C28 177.3(6) . . . . ?
F77 C59 C104 C28 56.6(7) . . . . ?
F109 C59 C104 C28 -61.3(7) . . . . ?
Eu1 O103 C105 C28 -15.0(8) . . . . ?
Eu1 O103 C105 C68 168.0(4) . . . . ?
C104 C28 C105 O103 -4.2(9) . . . . ?
C22 C28 C105 O103 -177.8(5) . . . . ?
C104 C28 C105 C68 173.1(5) . . . . ?
C22 C28 C105 C68 -0.4(6) . . . . ?
C110 C68 C105 O103 -18.9(8) . . . . ?
C111 C68 C105 O103 108.6(6) . . . . ?
C43 C68 C105 O103 -147.4(5) . . . . ?
C110 C68 C105 C28 163.6(5) . . . . ?
C111 C68 C105 C28 -68.9(6) . . . . ?
C43 C68 C105 C28 35.0(5) . . . . ?
C3 C15 C106 C25 -3.2(8) . . . . ?
P92 C15 C106 C25 173.2(4) . . . . ?
C31 C25 C106 C15 0.4(8) . . . . ?
C55 C10 C107 C108 -0.1(9) . . . . ?
C10 C107 C108 C71 -0.8(10) . . . . ?
C96 C71 C108 C107 0.9(10) . . . . ?
C22 C17 C111 C68 -2.7(7) . . . . ?
C110 C68 C111 C17 -162.6(5) . . . . ?
C105 C68 C111 C17 70.3(6) . . . . ?
C43 C68 C111 C17 -32.8(6) . . . . ?

_refine_diff_density_max         1.415
_refine_diff_density_min         -1.128
_refine_diff_density_rms         0.076

