# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_sns09m
_database_code_depnum_ccdc_archive 'CCDC 1585659'
_audit_update_record             
;
2017-11-14 deposited with the CCDC.
2018-03-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C36 H60 Cl2 Ge2 N4 Pt, C H2 Cl2'
_chemical_formula_sum            'C37 H62 Cl4 Ge2 N4 Pt'
_chemical_formula_weight         1045.01

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.8516(18)
_cell_length_b                   13.4971(14)
_cell_length_c                   19.508(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 112.457(2)
_cell_angle_gamma                90.00
_cell_volume                     4343.9(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    5883
_cell_measurement_theta_min      2.259
_cell_measurement_theta_max      27.248

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.340
_exptl_crystal_size_mid          0.265
_exptl_crystal_size_min          0.153
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.598
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2088.0
_exptl_absorpt_coefficient_mu    4.863
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.232
_exptl_absorpt_correction_T_max  0.475
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18479
_diffrn_reflns_av_R_equivalents  0.0356
_diffrn_reflns_av_sigmaI/netI    0.0478
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.23
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7642
_reflns_number_gt                6429
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0480P)²+1.3881P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7642
_refine_ls_number_parameters     451
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0433
_refine_ls_R_factor_gt           0.0328
_refine_ls_wR_factor_ref         0.0928
_refine_ls_wR_factor_gt          0.0775
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_restrained_S_all      1.074
_refine_ls_shift/su_max          0.083
_refine_ls_shift/su_mean         0.021

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.253465(11) 0.204774(15) 0.811442(10) 0.02386(8) Uani 1 1 d . . .
Ge1 Ge 0.20886(3) 0.09645(4) 0.88061(3) 0.02372(13) Uani 1 1 d . . .
Ge2 Ge 0.29218(3) 0.34302(4) 0.88847(3) 0.02307(13) Uani 1 1 d . . .
Cl1 Cl 0.20087(8) 0.08412(11) 0.71379(7) 0.0387(3) Uani 1 1 d . . .
Cl2 Cl 0.31418(9) 0.29115(11) 0.73888(8) 0.0378(3) Uani 1 1 d . . .
Cl4 Cl 0.63337(16) 0.2856(2) 0.75553(13) 0.1133(11) Uani 1 1 d . . .
Cl5 Cl 0.8054(3) 0.2680(3) 0.8235(3) 0.205(2) Uani 1 1 d . . .
N1 N 0.0960(2) 0.0979(3) 0.8642(2) 0.0277(10) Uani 1 1 d . . .
N2 N 0.2207(2) 0.1170(3) 0.9814(2) 0.0241(9) Uani 1 1 d . . .
N3 N 0.4021(2) 0.3522(3) 0.9570(2) 0.0244(10) Uani 1 1 d . . .
N4 N 0.2698(2) 0.3661(3) 0.9766(2) 0.0231(9) Uani 1 1 d . . .
C1 C 0.0784(3) 0.1094(4) 0.9243(3) 0.0270(12) Uani 1 1 d . . .
C2 C -0.0014(3) 0.1067(4) 0.9207(3) 0.0390(14) Uani 1 1 d . . .
H2 H -0.0397 0.0898 0.8743 0.047 Uiso 1 1 calc R . .
C3 C -0.0335(4) 0.1247(5) 0.9737(4) 0.0480(17) Uani 1 1 d . . .
H3 H -0.0895 0.1184 0.9571 0.058 Uiso 1 1 calc R . .
C4 C 0.0043(4) 0.1505(5) 1.0470(4) 0.0517(18) Uani 1 1 d . . .
H4 H -0.0290 0.1628 1.0729 0.062 Uiso 1 1 calc R . .
C5 C 0.0864(4) 0.1597(5) 1.0859(4) 0.0468(16) Uani 1 1 d . . .
H5 H 0.1016 0.1789 1.1352 0.056 Uiso 1 1 calc R . .
C6 C 0.1495(3) 0.1448(4) 1.0627(3) 0.0356(14) Uani 1 1 d . . .
H6 H 0.2006 0.1507 1.1003 0.043 Uiso 1 1 calc R . .
C7 C 0.1512(3) 0.1226(4) 0.9934(3) 0.0272(12) Uani 1 1 d . . .
C8 C 0.0350(3) 0.0897(4) 0.7881(3) 0.0340(13) Uani 1 1 d . . .
H8A H -0.0050 0.0407 0.7874 0.041 Uiso 1 1 calc R . .
H8B H 0.0613 0.0661 0.7559 0.041 Uiso 1 1 calc R . .
C9 C 0.3007(3) 0.1407(4) 1.0388(3) 0.0264(12) Uani 1 1 d . . .
H9A H 0.2924 0.1821 1.0760 0.032 Uiso 1 1 calc R . .
H9B H 0.3308 0.1794 1.0161 0.032 Uiso 1 1 calc R . .
C10 C -0.0091(5) 0.1886(6) 0.7565(4) 0.081(3) Uani 1 1 d . . .
H10 H -0.0505 0.1995 0.7772 0.097 Uiso 1 1 calc R . .
C11 C 0.3530(3) 0.0514(4) 1.0783(3) 0.0287(12) Uani 1 1 d . . .
H11 H 0.3587 0.0077 1.0405 0.034 Uiso 1 1 calc R . .
C12 C -0.0538(7) 0.1625(7) 0.6704(5) 0.139(6) Uani 1 1 d . . .
H12A H -0.0955 0.2106 0.6472 0.208 Uiso 1 1 calc R . .
H12B H -0.0777 0.0978 0.6653 0.208 Uiso 1 1 calc R . .
H12C H -0.0152 0.1635 0.6471 0.208 Uiso 1 1 calc R . .
C13 C 0.0362(5) 0.2760(6) 0.7654(5) 0.079(3) Uani 1 1 d . . .
H13A H 0.0643 0.2894 0.8173 0.119 Uiso 1 1 calc R . .
H13B H 0.0005 0.3301 0.7425 0.119 Uiso 1 1 calc R . .
H13C H 0.0748 0.2682 0.7425 0.119 Uiso 1 1 calc R . .
C14 C 0.3170(4) -0.0082(4) 1.1240(3) 0.0390(14) Uani 1 1 d . . .
H14A H 0.3171 0.0310 1.1651 0.058 Uiso 1 1 calc R . .
H14B H 0.3488 -0.0669 1.1423 0.058 Uiso 1 1 calc R . .
H14C H 0.2624 -0.0265 1.0937 0.058 Uiso 1 1 calc R . .
C15 C 0.4370(3) 0.0925(5) 1.1256(3) 0.0436(16) Uani 1 1 d . . .
H15A H 0.4323 0.1379 1.1616 0.065 Uiso 1 1 calc R . .
H15B H 0.4590 0.1264 1.0943 0.065 Uiso 1 1 calc R . .
H15C H 0.4722 0.0389 1.1506 0.065 Uiso 1 1 calc R . .
C16 C 0.2316(3) -0.0460(4) 0.8725(3) 0.0323(13) Uani 1 1 d . . .
H16 H 0.197(3) -0.066(4) 0.822(3) 0.039 Uiso 1 1 calc . . .
C17 C 0.2066(4) -0.1119(4) 0.9239(4) 0.0496(17) Uani 1 1 d . . .
H17A H 0.2108 -0.1802 0.9122 0.074 Uiso 1 1 calc R . .
H17B H 0.1517 -0.0973 0.9174 0.074 Uiso 1 1 calc R . .
H17C H 0.2417 -0.0995 0.9745 0.074 Uiso 1 1 calc R . .
C18 C 0.3186(3) -0.0640(5) 0.8806(3) 0.0422(15) Uani 1 1 d . . .
H18A H 0.3547 -0.0475 0.9301 0.063 Uiso 1 1 calc R . .
H18B H 0.3307 -0.0233 0.8458 0.063 Uiso 1 1 calc R . .
H18C H 0.3254 -0.1324 0.8710 0.063 Uiso 1 1 calc R . .
C19 C 0.4119(3) 0.3752(4) 1.0270(3) 0.0236(11) Uani 1 1 d . . .
C20 C 0.4895(3) 0.3923(4) 1.0815(3) 0.0320(13) Uani 1 1 d . . .
H20 H 0.5309 0.3906 1.0637 0.038 Uiso 1 1 calc R . .
C21 C 0.5155(3) 0.4113(5) 1.1563(3) 0.0409(15) Uani 1 1 d . . .
H21 H 0.5711 0.4204 1.1805 0.049 Uiso 1 1 calc R . .
C22 C 0.4719(4) 0.4189(5) 1.2004(3) 0.0458(16) Uani 1 1 d . . .
H22 H 0.5011 0.4304 1.2506 0.055 Uiso 1 1 calc R . .
C23 C 0.3886(4) 0.4112(4) 1.1778(3) 0.0396(14) Uani 1 1 d . . .
H23 H 0.3690 0.4173 1.2155 0.048 Uiso 1 1 calc R . .
C24 C 0.3298(3) 0.3957(4) 1.1077(3) 0.0316(13) Uani 1 1 d . . .
H24 H 0.2770 0.3954 1.1059 0.038 Uiso 1 1 calc R . .
C25 C 0.3360(3) 0.3805(4) 1.0390(3) 0.0245(11) Uani 1 1 d . . .
C26 C 0.4692(3) 0.3420(4) 0.9320(3) 0.0295(12) Uani 1 1 d . . .
H26A H 0.5043 0.3993 0.9491 0.035 Uiso 1 1 calc R . .
H26B H 0.4472 0.3432 0.8782 0.035 Uiso 1 1 calc R . .
C27 C 0.1871(3) 0.3552(4) 0.9751(3) 0.0319(13) Uani 1 1 d . . .
H27A H 0.1912 0.3317 1.0234 0.038 Uiso 1 1 calc R . .
H27B H 0.1598 0.3039 0.9394 0.038 Uiso 1 1 calc R . .
C28 C 0.5208(3) 0.2492(5) 0.9576(3) 0.0349(13) Uani 1 1 d . . .
H28 H 0.5413 0.2464 1.0119 0.042 Uiso 1 1 calc R . .
C29 C 0.1338(3) 0.4464(4) 0.9563(3) 0.0360(14) Uani 1 1 d . . .
H29 H 0.1303 0.4707 0.9078 0.043 Uiso 1 1 calc R . .
C30 C 0.5931(4) 0.2571(6) 0.9344(4) 0.0581(19) Uani 1 1 d . . .
H30A H 0.5745 0.2540 0.8813 0.087 Uiso 1 1 calc R . .
H30B H 0.6299 0.2034 0.9558 0.087 Uiso 1 1 calc R . .
H30C H 0.6205 0.3190 0.9514 0.087 Uiso 1 1 calc R . .
C31 C 0.4717(4) 0.1568(5) 0.9270(4) 0.0485(17) Uani 1 1 d . . .
H31A H 0.4549 0.1557 0.8740 0.073 Uiso 1 1 calc R . .
H31B H 0.4247 0.1566 0.9397 0.073 Uiso 1 1 calc R . .
H31C H 0.5041 0.0994 0.9479 0.073 Uiso 1 1 calc R . .
C32 C 0.1647(4) 0.5300(4) 1.0117(3) 0.0431(15) Uani 1 1 d . . .
H32A H 0.1289 0.5858 0.9953 0.065 Uiso 1 1 calc R . .
H32B H 0.2181 0.5487 1.0157 0.065 Uiso 1 1 calc R . .
H32C H 0.1666 0.5084 1.0592 0.065 Uiso 1 1 calc R . .
C33 C 0.0486(3) 0.4169(6) 0.9497(4) 0.062(2) Uani 1 1 d . . .
H33A H 0.0507 0.3926 0.9966 0.093 Uiso 1 1 calc R . .
H33B H 0.0279 0.3661 0.9128 0.093 Uiso 1 1 calc R . .
H33C H 0.0136 0.4737 0.9354 0.093 Uiso 1 1 calc R . .
C34 C 0.2755(3) 0.4744(4) 0.8382(3) 0.0318(13) Uani 1 1 d . . .
H34 H 0.317(3) 0.479(4) 0.817(3) 0.038 Uiso 1 1 calc . . .
C35 C 0.2912(3) 0.5607(4) 0.8908(3) 0.0353(13) Uani 1 1 d . . .
H35A H 0.2961 0.6203 0.8660 0.053 Uiso 1 1 calc R . .
H35B H 0.3406 0.5495 0.9330 0.053 Uiso 1 1 calc R . .
H35C H 0.2470 0.5672 0.9070 0.053 Uiso 1 1 calc R . .
C36 C 0.1943(3) 0.4804(4) 0.7732(3) 0.0401(15) Uani 1 1 d . . .
H36A H 0.1513 0.4754 0.7911 0.060 Uiso 1 1 calc R . .
H36B H 0.1900 0.4270 0.7394 0.060 Uiso 1 1 calc R . .
H36C H 0.1903 0.5425 0.7481 0.060 Uiso 1 1 calc R . .
C37 C 0.7255(5) 0.3402(6) 0.8128(4) 0.066(2) Uani 1 1 d . . .
H37A H 0.7319 0.4030 0.7914 0.079 Uiso 1 1 calc R . .
H37B H 0.7239 0.3536 0.8611 0.079 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ge1 2.3267(6) . ?
Pt1 Ge2 2.3290(6) . ?
Pt1 Cl2 2.3894(14) . ?
Pt1 Cl1 2.4075(14) . ?
Ge1 N1 1.915(4) . ?
Ge1 N2 1.916(4) . ?
Ge1 C16 1.984(6) . ?
Ge2 N3 1.910(4) . ?
Ge2 N4 1.933(4) . ?
Ge2 C34 1.992(6) . ?
Cl4 C37 1.759(7) . ?
Cl5 C37 1.673(9) . ?
N1 C1 1.335(6) . ?
N1 C8 1.473(6) . ?
N2 C7 1.350(6) . ?
N2 C9 1.474(6) . ?
N3 C19 1.346(6) . ?
N3 C26 1.462(6) . ?
N4 C25 1.348(6) . ?
N4 C27 1.474(6) . ?
C1 C2 1.399(7) . ?
C1 C7 1.484(7) . ?
C2 C3 1.382(8) . ?
C2 H2 0.9300 . ?
C3 C4 1.372(9) . ?
C3 H3 0.9300 . ?
C4 C5 1.374(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.381(8) . ?
C5 H5 0.9300 . ?
C6 C7 1.395(7) . ?
C6 H6 0.9300 . ?
C8 C10 1.552(10) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C11 1.539(7) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C13 1.403(10) . ?
C10 C12 1.599(11) . ?
C10 H10 0.9800 . ?
C11 C14 1.514(7) . ?
C11 C15 1.533(7) . ?
C11 H11 0.9800 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 C18 1.521(8) . ?
C16 C17 1.529(9) . ?
C16 H16 0.98(5) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.406(7) . ?
C19 C25 1.463(7) . ?
C20 C21 1.376(8) . ?
C20 H20 0.9300 . ?
C21 C22 1.367(8) . ?
C21 H21 0.9300 . ?
C22 C23 1.384(8) . ?
C22 H22 0.9300 . ?
C23 C24 1.385(8) . ?
C23 H23 0.9300 . ?
C24 C25 1.401(7) . ?
C24 H24 0.9300 . ?
C26 C28 1.521(8) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C29 1.512(7) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 C31 1.511(8) . ?
C28 C30 1.526(8) . ?
C28 H28 0.9800 . ?
C29 C32 1.513(8) . ?
C29 C33 1.530(8) . ?
C29 H29 0.9800 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C34 C35 1.506(8) . ?
C34 C36 1.521(7) . ?
C34 H34 0.93(6) . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge1 Pt1 Ge2 102.25(2) . . ?
Ge1 Pt1 Cl2 169.52(4) . . ?
Ge2 Pt1 Cl2 84.34(4) . . ?
Ge1 Pt1 Cl1 85.27(4) . . ?
Ge2 Pt1 Cl1 169.23(4) . . ?
Cl2 Pt1 Cl1 89.39(5) . . ?
N1 Ge1 N2 82.34(17) . . ?
N1 Ge1 C16 103.3(2) . . ?
N2 Ge1 C16 106.0(2) . . ?
N1 Ge1 Pt1 117.88(13) . . ?
N2 Ge1 Pt1 125.18(13) . . ?
C16 Ge1 Pt1 115.93(17) . . ?
N3 Ge2 N4 82.72(17) . . ?
N3 Ge2 C34 101.9(2) . . ?
N4 Ge2 C34 104.6(2) . . ?
N3 Ge2 Pt1 118.42(13) . . ?
N4 Ge2 Pt1 126.27(12) . . ?
C34 Ge2 Pt1 116.33(17) . . ?
C1 N1 C8 124.2(4) . . ?
C1 N1 Ge1 116.1(3) . . ?
C8 N1 Ge1 119.6(3) . . ?
C7 N2 C9 122.9(4) . . ?
C7 N2 Ge1 116.0(3) . . ?
C9 N2 Ge1 120.4(3) . . ?
C19 N3 C26 123.6(4) . . ?
C19 N3 Ge2 115.2(3) . . ?
C26 N3 Ge2 121.0(3) . . ?
C25 N4 C27 123.9(4) . . ?
C25 N4 Ge2 114.8(3) . . ?
C27 N4 Ge2 120.8(3) . . ?
N1 C1 C2 122.0(5) . . ?
N1 C1 C7 113.2(4) . . ?
C2 C1 C7 124.8(5) . . ?
C3 C2 C1 131.5(6) . . ?
C3 C2 H2 114.3 . . ?
C1 C2 H2 114.3 . . ?
C4 C3 C2 130.2(6) . . ?
C4 C3 H3 114.9 . . ?
C2 C3 H3 114.9 . . ?
C3 C4 C5 126.4(6) . . ?
C3 C4 H4 116.8 . . ?
C5 C4 H4 116.8 . . ?
C4 C5 C6 129.6(6) . . ?
C4 C5 H5 115.2 . . ?
C6 C5 H5 115.2 . . ?
C5 C6 C7 132.1(6) . . ?
C5 C6 H6 113.9 . . ?
C7 C6 H6 113.9 . . ?
N2 C7 C6 122.8(5) . . ?
N2 C7 C1 112.3(4) . . ?
C6 C7 C1 124.8(5) . . ?
N1 C8 C10 113.8(5) . . ?
N1 C8 H8A 108.8 . . ?
C10 C8 H8A 108.8 . . ?
N1 C8 H8B 108.8 . . ?
C10 C8 H8B 108.8 . . ?
H8A C8 H8B 107.7 . . ?
N2 C9 C11 115.9(4) . . ?
N2 C9 H9A 108.3 . . ?
C11 C9 H9A 108.3 . . ?
N2 C9 H9B 108.3 . . ?
C11 C9 H9B 108.3 . . ?
H9A C9 H9B 107.4 . . ?
C13 C10 C8 119.5(6) . . ?
C13 C10 C12 110.4(7) . . ?
C8 C10 C12 101.6(7) . . ?
C13 C10 H10 108.2 . . ?
C8 C10 H10 108.2 . . ?
C12 C10 H10 108.2 . . ?
C14 C11 C15 112.0(5) . . ?
C14 C11 C9 113.4(4) . . ?
C15 C11 C9 106.6(4) . . ?
C14 C11 H11 108.2 . . ?
C15 C11 H11 108.2 . . ?
C9 C11 H11 108.2 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C10 C13 H13A 109.5 . . ?
C10 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C10 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C11 C14 H14A 109.5 . . ?
C11 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C11 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C11 C15 H15A 109.5 . . ?
C11 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C11 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C18 C16 C17 112.5(5) . . ?
C18 C16 Ge1 112.2(4) . . ?
C17 C16 Ge1 113.1(4) . . ?
C18 C16 H16 111(3) . . ?
C17 C16 H16 104(3) . . ?
Ge1 C16 H16 104(3) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N3 C19 C20 121.0(5) . . ?
N3 C19 C25 113.8(4) . . ?
C20 C19 C25 125.2(5) . . ?
C21 C20 C19 132.0(5) . . ?
C21 C20 H20 114.0 . . ?
C19 C20 H20 114.0 . . ?
C22 C21 C20 129.7(5) . . ?
C22 C21 H21 115.2 . . ?
C20 C21 H21 115.2 . . ?
C21 C22 C23 126.5(6) . . ?
C21 C22 H22 116.7 . . ?
C23 C22 H22 116.7 . . ?
C22 C23 C24 129.9(6) . . ?
C22 C23 H23 115.0 . . ?
C24 C23 H23 115.0 . . ?
C23 C24 C25 131.3(5) . . ?
C23 C24 H24 114.3 . . ?
C25 C24 H24 114.3 . . ?
N4 C25 C24 121.6(4) . . ?
N4 C25 C19 113.3(4) . . ?
C24 C25 C19 125.2(5) . . ?
N3 C26 C28 116.1(4) . . ?
N3 C26 H26A 108.3 . . ?
C28 C26 H26A 108.3 . . ?
N3 C26 H26B 108.3 . . ?
C28 C26 H26B 108.3 . . ?
H26A C26 H26B 107.4 . . ?
N4 C27 C29 117.1(4) . . ?
N4 C27 H27A 108.0 . . ?
C29 C27 H27A 108.0 . . ?
N4 C27 H27B 108.0 . . ?
C29 C27 H27B 108.0 . . ?
H27A C27 H27B 107.3 . . ?
C31 C28 C26 111.2(4) . . ?
C31 C28 C30 111.7(5) . . ?
C26 C28 C30 108.6(5) . . ?
C31 C28 H28 108.4 . . ?
C26 C28 H28 108.4 . . ?
C30 C28 H28 108.4 . . ?
C27 C29 C32 114.2(5) . . ?
C27 C29 C33 108.8(5) . . ?
C32 C29 C33 109.4(5) . . ?
C27 C29 H29 108.1 . . ?
C32 C29 H29 108.1 . . ?
C33 C29 H29 108.1 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C28 C31 H31A 109.5 . . ?
C28 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C28 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C29 C32 H32A 109.5 . . ?
C29 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C29 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C29 C33 H33A 109.5 . . ?
C29 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C29 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C35 C34 C36 113.4(5) . . ?
C35 C34 Ge2 113.5(4) . . ?
C36 C34 Ge2 111.9(4) . . ?
C35 C34 H34 105(3) . . ?
C36 C34 H34 110(3) . . ?
Ge2 C34 H34 106(3) . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
Cl5 C37 Cl4 112.4(5) . . ?
Cl5 C37 H37A 109.1 . . ?
Cl4 C37 H37A 109.1 . . ?
Cl5 C37 H37B 109.1 . . ?
Cl4 C37 H37B 109.1 . . ?
H37A C37 H37B 107.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ge2 Pt1 Ge1 N1 92.28(15) . . . . ?
Cl2 Pt1 Ge1 N1 -139.5(3) . . . . ?
Cl1 Pt1 Ge1 N1 -79.92(15) . . . . ?
Ge2 Pt1 Ge1 N2 -8.58(15) . . . . ?
Cl2 Pt1 Ge1 N2 119.7(3) . . . . ?
Cl1 Pt1 Ge1 N2 179.22(15) . . . . ?
Ge2 Pt1 Ge1 C16 -144.53(18) . . . . ?
Cl2 Pt1 Ge1 C16 -16.3(3) . . . . ?
Cl1 Pt1 Ge1 C16 43.27(19) . . . . ?
Ge1 Pt1 Ge2 N3 91.45(14) . . . . ?
Cl2 Pt1 Ge2 N3 -80.30(15) . . . . ?
Cl1 Pt1 Ge2 N3 -134.9(2) . . . . ?
Ge1 Pt1 Ge2 N4 -11.17(15) . . . . ?
Cl2 Pt1 Ge2 N4 177.08(15) . . . . ?
Cl1 Pt1 Ge2 N4 122.5(2) . . . . ?
Ge1 Pt1 Ge2 C34 -146.54(18) . . . . ?
Cl2 Pt1 Ge2 C34 41.71(18) . . . . ?
Cl1 Pt1 Ge2 C34 -12.9(3) . . . . ?
N2 Ge1 N1 C1 -1.2(4) . . . . ?
C16 Ge1 N1 C1 103.6(4) . . . . ?
Pt1 Ge1 N1 C1 -127.1(4) . . . . ?
N2 Ge1 N1 C8 177.0(4) . . . . ?
C16 Ge1 N1 C8 -78.3(4) . . . . ?
Pt1 Ge1 N1 C8 51.1(4) . . . . ?
N1 Ge1 N2 C7 0.0(4) . . . . ?
C16 Ge1 N2 C7 -101.8(4) . . . . ?
Pt1 Ge1 N2 C7 118.8(3) . . . . ?
N1 Ge1 N2 C9 -170.9(4) . . . . ?
C16 Ge1 N2 C9 87.4(4) . . . . ?
Pt1 Ge1 N2 C9 -52.0(4) . . . . ?
N4 Ge2 N3 C19 -4.1(4) . . . . ?
C34 Ge2 N3 C19 99.4(4) . . . . ?
Pt1 Ge2 N3 C19 -131.6(3) . . . . ?
N4 Ge2 N3 C26 -179.7(4) . . . . ?
C34 Ge2 N3 C26 -76.3(4) . . . . ?
Pt1 Ge2 N3 C26 52.7(4) . . . . ?
N3 Ge2 N4 C25 2.3(4) . . . . ?
C34 Ge2 N4 C25 -98.2(4) . . . . ?
Pt1 Ge2 N4 C25 122.4(3) . . . . ?
N3 Ge2 N4 C27 -170.2(4) . . . . ?
C34 Ge2 N4 C27 89.3(4) . . . . ?
Pt1 Ge2 N4 C27 -50.1(4) . . . . ?
C8 N1 C1 C2 5.2(8) . . . . ?
Ge1 N1 C1 C2 -176.7(4) . . . . ?
C8 N1 C1 C7 -176.0(5) . . . . ?
Ge1 N1 C1 C7 2.1(6) . . . . ?
N1 C1 C2 C3 -173.9(6) . . . . ?
C7 C1 C2 C3 7.5(10) . . . . ?
C1 C2 C3 C4 -0.4(13) . . . . ?
C2 C3 C4 C5 -3.4(13) . . . . ?
C3 C4 C5 C6 -1.0(13) . . . . ?
C4 C5 C6 C7 4.8(13) . . . . ?
C9 N2 C7 C6 -4.4(8) . . . . ?
Ge1 N2 C7 C6 -175.0(4) . . . . ?
C9 N2 C7 C1 171.7(4) . . . . ?
Ge1 N2 C7 C1 1.1(6) . . . . ?
C5 C6 C7 N2 175.7(6) . . . . ?
C5 C6 C7 C1 0.0(11) . . . . ?
N1 C1 C7 N2 -2.0(7) . . . . ?
C2 C1 C7 N2 176.7(5) . . . . ?
N1 C1 C7 C6 174.0(5) . . . . ?
C2 C1 C7 C6 -7.3(9) . . . . ?
C1 N1 C8 C10 72.2(7) . . . . ?
Ge1 N1 C8 C10 -105.9(5) . . . . ?
C7 N2 C9 C11 100.8(6) . . . . ?
Ge1 N2 C9 C11 -89.0(5) . . . . ?
N1 C8 C10 C13 45.7(10) . . . . ?
N1 C8 C10 C12 167.4(6) . . . . ?
N2 C9 C11 C14 -65.1(6) . . . . ?
N2 C9 C11 C15 171.1(4) . . . . ?
N1 Ge1 C16 C18 177.5(4) . . . . ?
N2 Ge1 C16 C18 -96.8(4) . . . . ?
Pt1 Ge1 C16 C18 47.0(5) . . . . ?
N1 Ge1 C16 C17 -54.0(4) . . . . ?
N2 Ge1 C16 C17 31.7(5) . . . . ?
Pt1 Ge1 C16 C17 175.5(4) . . . . ?
C26 N3 C19 C20 0.9(8) . . . . ?
Ge2 N3 C19 C20 -174.6(4) . . . . ?
C26 N3 C19 C25 -179.5(5) . . . . ?
Ge2 N3 C19 C25 5.0(6) . . . . ?
N3 C19 C20 C21 -176.1(6) . . . . ?
C25 C19 C20 C21 4.4(10) . . . . ?
C19 C20 C21 C22 0.2(12) . . . . ?
C20 C21 C22 C23 -1.8(12) . . . . ?
C21 C22 C23 C24 -0.9(12) . . . . ?
C22 C23 C24 C25 2.0(11) . . . . ?
C27 N4 C25 C24 -6.2(8) . . . . ?
Ge2 N4 C25 C24 -178.4(4) . . . . ?
C27 N4 C25 C19 171.9(4) . . . . ?
Ge2 N4 C25 C19 -0.3(5) . . . . ?
C23 C24 C25 N4 179.6(6) . . . . ?
C23 C24 C25 C19 1.6(10) . . . . ?
N3 C19 C25 N4 -3.0(6) . . . . ?
C20 C19 C25 N4 176.6(5) . . . . ?
N3 C19 C25 C24 175.0(5) . . . . ?
C20 C19 C25 C24 -5.4(8) . . . . ?
C19 N3 C26 C28 73.3(7) . . . . ?
Ge2 N3 C26 C28 -111.4(5) . . . . ?
C25 N4 C27 C29 97.8(6) . . . . ?
Ge2 N4 C27 C29 -90.4(5) . . . . ?
N3 C26 C28 C31 63.3(6) . . . . ?
N3 C26 C28 C30 -173.3(5) . . . . ?
N4 C27 C29 C32 -63.4(7) . . . . ?
N4 C27 C29 C33 174.1(5) . . . . ?
N3 Ge2 C34 C35 -57.4(4) . . . . ?
N4 Ge2 C34 C35 28.1(4) . . . . ?
Pt1 Ge2 C34 C35 172.3(3) . . . . ?
N3 Ge2 C34 C36 172.7(4) . . . . ?
N4 Ge2 C34 C36 -101.8(4) . . . . ?
Pt1 Ge2 C34 C36 42.4(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.145
_refine_diff_density_min         -0.828
_refine_diff_density_rms         0.179
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_msha20m
_database_code_depnum_ccdc_archive 'CCDC 1585663'
_audit_update_record             
;
2017-11-14 deposited with the CCDC.
2018-03-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C36 H60 Ge2 N10 Pt, C4 H8 O'
_chemical_formula_sum            'C40 H68 Ge2 N10 O Pt'
_chemical_formula_weight         1045.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.510(2)
_cell_length_b                   13.7732(18)
_cell_length_c                   20.114(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 113.278(2)
_cell_angle_gamma                90.00
_cell_volume                     4455.9(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    3347
_cell_measurement_theta_min      2.469
_cell_measurement_theta_max      23.629

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.345
_exptl_crystal_size_mid          0.275
_exptl_crystal_size_min          0.163
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.558
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2112.0
_exptl_absorpt_coefficient_mu    4.514
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.234
_exptl_absorpt_correction_T_max  0.479
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            23033
_diffrn_reflns_av_R_equivalents  0.0632
_diffrn_reflns_av_sigmaI/netI    0.0740
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.27
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7824
_reflns_number_gt                6142
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0324P)²+8.4041P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7824
_refine_ls_number_parameters     502
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0694
_refine_ls_R_factor_gt           0.0490
_refine_ls_wR_factor_ref         0.0992
_refine_ls_wR_factor_gt          0.0919
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_restrained_S_all      1.051
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.003

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.241834(16) 0.70009(2) 0.180528(14) 0.02389(9) Uani 1 1 d . . .
Ge1 Ge 0.28732(4) 0.59933(5) 0.11077(4) 0.02353(18) Uani 1 1 d . . .
Ge2 Ge 0.20308(4) 0.83849(5) 0.10768(4) 0.02227(18) Uani 1 1 d . . .
N1 N 0.2727(3) 0.6219(4) 0.0128(3) 0.0236(13) Uani 1 1 d . . .
N4 N 0.0934(3) 0.8513(4) 0.0337(3) 0.0215(13) Uani 1 1 d . . .
N3 N 0.2359(3) 0.8629(4) 0.0289(3) 0.0243(13) Uani 1 1 d . . .
N5 N 0.2061(4) 0.7695(5) 0.2589(3) 0.0312(15) Uani 1 1 d . . .
N6 N 0.1389(5) 0.7887(5) 0.2457(3) 0.0440(18) Uani 1 1 d . . .
N2 N 0.4023(3) 0.6078(4) 0.1276(3) 0.0267(14) Uani 1 1 d . . .
N9 N 0.3299(4) 0.5995(5) 0.3131(4) 0.0335(15) Uani 1 1 d . . .
N8 N 0.2850(4) 0.5832(5) 0.2543(3) 0.0396(17) Uani 1 1 d . . .
N10 N 0.3752(5) 0.6110(6) 0.3736(4) 0.056(2) Uani 1 1 d . . .
N7 N 0.0697(5) 0.8115(7) 0.2356(4) 0.071(3) Uani 1 1 d . . .
C26 C 0.3228(4) 0.8572(5) 0.0378(4) 0.0263(17) Uani 1 1 d . . .
H26A H 0.3237 0.8380 -0.0083 0.032 Uiso 1 1 calc R . .
H26B H 0.3492 0.8057 0.0721 0.032 Uiso 1 1 calc R . .
C25 C 0.0904(4) 0.8731(5) -0.0318(4) 0.0237(16) Uani 1 1 d . . .
C8 C 0.1888(4) 0.6422(5) -0.0421(4) 0.0278(17) Uani 1 1 d . . .
H8A H 0.1941 0.6824 -0.0796 0.033 Uiso 1 1 calc R . .
H8B H 0.1585 0.6794 -0.0195 0.033 Uiso 1 1 calc R . .
C31 C -0.0314(4) 0.7549(6) 0.0304(4) 0.0333(18) Uani 1 1 d . . .
H31 H -0.0512 0.7475 -0.0222 0.040 Uiso 1 1 calc R . .
C6 C 0.4998(4) 0.6155(5) 0.0719(4) 0.0322(18) Uani 1 1 d . . .
H6 H 0.5401 0.6025 0.1177 0.039 Uiso 1 1 calc R . .
C9 C 0.1376(4) 0.5524(5) -0.0776(4) 0.0326(18) Uani 1 1 d . . .
H9 H 0.1397 0.5077 -0.0390 0.039 Uiso 1 1 calc R . .
C34 C 0.2146(4) 0.9614(5) 0.1612(4) 0.0269(17) Uani 1 1 d . . .
H34 H 0.1691 0.9626 0.1779 0.032 Uiso 1 1 calc R . .
C35 C 0.2028(4) 1.0512(5) 0.1127(4) 0.0319(18) Uani 1 1 d . . .
H35A H 0.1975 1.1080 0.1383 0.048 Uiso 1 1 calc R . .
H35B H 0.1534 1.0435 0.0694 0.048 Uiso 1 1 calc R . .
H35C H 0.2500 1.0582 0.1002 0.048 Uiso 1 1 calc R . .
C19 C 0.1723(4) 0.8795(5) -0.0356(4) 0.0222(16) Uani 1 1 d . . .
C13 C 0.5127(4) 0.6941(6) 0.2322(4) 0.0354(19) Uani 1 1 d . . .
H13 H 0.5372 0.7190 0.1994 0.043 Uiso 1 1 calc R . .
C30 C 0.0207(4) 0.8462(5) 0.0522(4) 0.0270(17) Uani 1 1 d . . .
H30A H -0.0149 0.9011 0.0299 0.032 Uiso 1 1 calc R . .
H30B H 0.0395 0.8537 0.1042 0.032 Uiso 1 1 calc R . .
C27 C 0.3760(4) 0.9485(6) 0.0633(4) 0.0339(19) Uani 1 1 d . . .
H27 H 0.3740 0.9693 0.1092 0.041 Uiso 1 1 calc R . .
C20 C 0.1851(4) 0.8964(5) -0.0991(3) 0.0257(16) Uani 1 1 d . . .
H20 H 0.2407 0.8958 -0.0927 0.031 Uiso 1 1 calc R . .
C1 C 0.3428(4) 0.6288(5) 0.0012(4) 0.0284(17) Uani 1 1 d . . .
C12 C 0.4663(4) 0.6002(5) 0.2004(4) 0.0301(18) Uani 1 1 d . . .
H12A H 0.5065 0.5520 0.2000 0.036 Uiso 1 1 calc R . .
H12B H 0.4408 0.5766 0.2322 0.036 Uiso 1 1 calc R . .
C16 C 0.2719(5) 0.4583(5) 0.1195(4) 0.0325(18) Uani 1 1 d . . .
H16 H 0.310(4) 0.440(5) 0.169(4) 0.039 Uiso 1 1 calc . . .
C2 C 0.3430(5) 0.6485(5) -0.0677(4) 0.0318(18) Uani 1 1 d . . .
H2 H 0.2904 0.6537 -0.1046 0.038 Uiso 1 1 calc R . .
C7 C 0.4183(4) 0.6164(5) 0.0679(3) 0.0246(16) Uani 1 1 d . . .
C3 C 0.4061(5) 0.6612(6) -0.0891(4) 0.041(2) Uani 1 1 d . . .
H3 H 0.3892 0.6781 -0.1376 0.049 Uiso 1 1 calc R . .
C29 C 0.4653(4) 0.9233(6) 0.0771(5) 0.049(2) Uani 1 1 d . . .
H29A H 0.4686 0.9025 0.0327 0.073 Uiso 1 1 calc R . .
H29B H 0.4841 0.8719 0.1121 0.073 Uiso 1 1 calc R . .
H29C H 0.4998 0.9794 0.0953 0.073 Uiso 1 1 calc R . .
C24 C 0.0137(4) 0.8886(5) -0.0901(4) 0.0300(17) Uani 1 1 d . . .
H24 H -0.0322 0.8821 -0.0782 0.036 Uiso 1 1 calc R . .
C28 C 0.3459(5) 1.0320(6) 0.0100(4) 0.041(2) Uani 1 1 d . . .
H28A H 0.3779 1.0891 0.0307 0.061 Uiso 1 1 calc R . .
H28B H 0.2883 1.0444 -0.0008 0.061 Uiso 1 1 calc R . .
H28C H 0.3525 1.0154 -0.0338 0.061 Uiso 1 1 calc R . .
C36 C 0.2952(5) 0.9672(6) 0.2292(4) 0.042(2) Uani 1 1 d . . .
H36A H 0.3419 0.9683 0.2156 0.062 Uiso 1 1 calc R . .
H36B H 0.2993 0.9117 0.2593 0.062 Uiso 1 1 calc R . .
H36C H 0.2950 1.0254 0.2555 0.062 Uiso 1 1 calc R . .
C10 C 0.0468(4) 0.5853(6) -0.1176(4) 0.042(2) Uani 1 1 d . . .
H10A H 0.0435 0.6313 -0.1545 0.063 Uiso 1 1 calc R . .
H10B H 0.0277 0.6151 -0.0838 0.063 Uiso 1 1 calc R . .
H10C H 0.0127 0.5301 -0.1394 0.063 Uiso 1 1 calc R . .
C14 C 0.4571(5) 0.7706(6) 0.2415(4) 0.046(2) Uani 1 1 d . . .
H14A H 0.4357 0.7489 0.2761 0.069 Uiso 1 1 calc R . .
H14B H 0.4118 0.7824 0.1959 0.069 Uiso 1 1 calc R . .
H14C H 0.4881 0.8294 0.2585 0.069 Uiso 1 1 calc R . .
C32 C 0.0181(5) 0.6660(6) 0.0655(4) 0.040(2) Uani 1 1 d . . .
H32A H 0.0326 0.6685 0.1167 0.060 Uiso 1 1 calc R . .
H32B H 0.0678 0.6638 0.0563 0.060 Uiso 1 1 calc R . .
H32C H -0.0146 0.6090 0.0458 0.060 Uiso 1 1 calc R . .
C5 C 0.5307(5) 0.6308(6) 0.0192(5) 0.045(2) Uani 1 1 d . . .
H5 H 0.5880 0.6246 0.0350 0.054 Uiso 1 1 calc R . .
C11 C 0.1687(5) 0.4994(6) -0.1266(4) 0.042(2) Uani 1 1 d . . .
H11A H 0.1648 0.5408 -0.1662 0.064 Uiso 1 1 calc R . .
H11B H 0.1357 0.4422 -0.1449 0.064 Uiso 1 1 calc R . .
H11C H 0.2257 0.4812 -0.1001 0.064 Uiso 1 1 calc R . .
C21 C 0.1301(5) 0.9140(6) -0.1696(4) 0.038(2) Uani 1 1 d . . .
H21 H 0.1547 0.9216 -0.2026 0.046 Uiso 1 1 calc R . .
C33 C -0.1060(5) 0.7663(7) 0.0498(5) 0.052(2) Uani 1 1 d . . .
H33A H -0.1391 0.7082 0.0368 0.078 Uiso 1 1 calc R . .
H33B H -0.1388 0.8205 0.0239 0.078 Uiso 1 1 calc R . .
H33C H -0.0876 0.7773 0.1009 0.078 Uiso 1 1 calc R . .
C18 C 0.2965(5) 0.3976(6) 0.0681(4) 0.046(2) Uani 1 1 d . . .
H18A H 0.2961 0.3301 0.0799 0.070 Uiso 1 1 calc R . .
H18B H 0.3513 0.4158 0.0726 0.070 Uiso 1 1 calc R . .
H18C H 0.2577 0.4086 0.0193 0.070 Uiso 1 1 calc R . .
C17 C 0.1845(5) 0.4351(6) 0.1143(4) 0.043(2) Uani 1 1 d . . .
H17A H 0.1447 0.4518 0.0669 0.065 Uiso 1 1 calc R . .
H17B H 0.1733 0.4719 0.1500 0.065 Uiso 1 1 calc R . .
H17C H 0.1805 0.3671 0.1227 0.065 Uiso 1 1 calc R . .
C4 C 0.4897(5) 0.6539(6) -0.0532(4) 0.044(2) Uani 1 1 d . . .
H4 H 0.5222 0.6654 -0.0794 0.052 Uiso 1 1 calc R . .
C15 C 0.5817(7) 0.6731(8) 0.3042(6) 0.103(5) Uani 1 1 d . . .
H15A H 0.6134 0.7312 0.3225 0.155 Uiso 1 1 calc R . .
H15B H 0.6173 0.6237 0.2984 0.155 Uiso 1 1 calc R . .
H15C H 0.5586 0.6511 0.3375 0.155 Uiso 1 1 calc R . .
C23 C -0.0059(5) 0.9117(6) -0.1621(4) 0.039(2) Uani 1 1 d . . .
H23 H -0.0622 0.9217 -0.1897 0.047 Uiso 1 1 calc R . .
C22 C 0.0448(5) 0.9220(7) -0.1987(4) 0.046(2) Uani 1 1 d . . .
H22 H 0.0193 0.9357 -0.2479 0.055 Uiso 1 1 calc R . .
O1 O 0.8491(6) 0.7874(9) 0.2316(6) 0.132(4) Uani 1 1 d . . .
C40 C 0.7991(7) 0.7172(9) 0.2419(8) 0.106(5) Uani 1 1 d . . .
H40A H 0.8031 0.7210 0.2913 0.128 Uiso 1 1 calc R . .
H40B H 0.8194 0.6539 0.2354 0.128 Uiso 1 1 calc R . .
C37 C 0.7773(11) 0.8457(13) 0.1740(11) 0.165(8) Uani 1 1 d . . .
H37A H 0.7846 0.9139 0.1870 0.198 Uiso 1 1 calc R . .
H37B H 0.7818 0.8388 0.1277 0.198 Uiso 1 1 calc R . .
C39 C 0.7143(10) 0.7257(12) 0.1939(12) 0.206(12) Uani 1 1 d D . .
H39A H 0.7014 0.6789 0.1549 0.247 Uiso 1 1 calc R . .
H39B H 0.6788 0.7126 0.2197 0.247 Uiso 1 1 calc R . .
C38 C 0.7002(10) 0.8188(13) 0.1660(10) 0.159(8) Uani 1 1 d D . .
H38A H 0.6787 0.8605 0.1934 0.191 Uiso 1 1 calc R . .
H38B H 0.6621 0.8190 0.1155 0.191 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N8 2.116(6) . ?
Pt1 N5 2.137(6) . ?
Pt1 Ge1 2.3263(8) . ?
Pt1 Ge2 2.3356(8) . ?
Ge1 N2 1.908(5) . ?
Ge1 N1 1.910(5) . ?
Ge1 C16 1.978(7) . ?
Ge2 N4 1.917(5) . ?
Ge2 N3 1.918(5) . ?
Ge2 C34 1.973(7) . ?
N1 C1 1.340(8) . ?
N1 C8 1.474(8) . ?
N4 C25 1.332(8) . ?
N4 C30 1.461(8) . ?
N3 C19 1.353(8) . ?
N3 C26 1.461(8) . ?
N5 N6 1.131(9) . ?
N6 N7 1.190(10) . ?
N2 C7 1.342(8) . ?
N2 C12 1.453(8) . ?
N9 N8 1.155(8) . ?
N9 N10 1.171(9) . ?
C26 C27 1.528(10) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C25 C24 1.407(9) . ?
C25 C19 1.469(9) . ?
C8 C9 1.529(9) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C31 C32 1.504(10) . ?
C31 C33 1.513(10) . ?
C31 C30 1.513(10) . ?
C31 H31 0.9800 . ?
C6 C5 1.383(10) . ?
C6 C7 1.397(9) . ?
C6 H6 0.9300 . ?
C9 C11 1.491(10) . ?
C9 C10 1.539(10) . ?
C9 H9 0.9800 . ?
C34 C36 1.532(9) . ?
C34 C35 1.538(9) . ?
C34 H34 0.9800 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C19 C20 1.401(9) . ?
C13 C14 1.496(10) . ?
C13 C15 1.502(11) . ?
C13 C12 1.526(10) . ?
C13 H13 0.9800 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C27 C29 1.517(10) . ?
C27 C28 1.518(10) . ?
C27 H27 0.9800 . ?
C20 C21 1.386(9) . ?
C20 H20 0.9300 . ?
C1 C2 1.412(10) . ?
C1 C7 1.475(9) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C16 C18 1.520(11) . ?
C16 C17 1.525(10) . ?
C16 H16 1.01(7) . ?
C2 C3 1.347(10) . ?
C2 H2 0.9300 . ?
C3 C4 1.356(11) . ?
C3 H3 0.9300 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C24 C23 1.387(10) . ?
C24 H24 0.9300 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C5 C4 1.382(11) . ?
C5 H5 0.9300 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C21 C22 1.376(10) . ?
C21 H21 0.9300 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C4 H4 0.9300 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C23 C22 1.367(10) . ?
C23 H23 0.9300 . ?
C22 H22 0.9300 . ?
O1 C40 1.374(13) . ?
O1 C37 1.554(16) . ?
C40 C39 1.420(17) . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C37 C38 1.347(19) . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?
C39 C38 1.382(14) . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Pt1 N5 87.2(2) . . ?
N8 Pt1 Ge1 81.76(18) . . ?
N5 Pt1 Ge1 168.88(16) . . ?
N8 Pt1 Ge2 174.55(19) . . ?
N5 Pt1 Ge2 90.03(16) . . ?
Ge1 Pt1 Ge2 101.09(3) . . ?
N2 Ge1 N1 82.8(2) . . ?
N2 Ge1 C16 102.5(3) . . ?
N1 Ge1 C16 106.5(3) . . ?
N2 Ge1 Pt1 116.42(17) . . ?
N1 Ge1 Pt1 125.97(17) . . ?
C16 Ge1 Pt1 116.1(2) . . ?
N4 Ge2 N3 83.0(2) . . ?
N4 Ge2 C34 101.5(3) . . ?
N3 Ge2 C34 107.5(3) . . ?
N4 Ge2 Pt1 121.03(17) . . ?
N3 Ge2 Pt1 123.66(16) . . ?
C34 Ge2 Pt1 114.6(2) . . ?
C1 N1 C8 124.5(6) . . ?
C1 N1 Ge1 115.7(4) . . ?
C8 N1 Ge1 119.4(4) . . ?
C25 N4 C30 124.4(5) . . ?
C25 N4 Ge2 115.0(4) . . ?
C30 N4 Ge2 120.3(4) . . ?
C19 N3 C26 123.3(6) . . ?
C19 N3 Ge2 114.8(4) . . ?
C26 N3 Ge2 121.8(4) . . ?
N6 N5 Pt1 120.8(5) . . ?
N5 N6 N7 176.1(8) . . ?
C7 N2 C12 123.8(6) . . ?
C7 N2 Ge1 115.2(4) . . ?
C12 N2 Ge1 120.9(5) . . ?
N8 N9 N10 176.6(8) . . ?
N9 N8 Pt1 118.7(6) . . ?
N3 C26 C27 117.7(6) . . ?
N3 C26 H26A 107.9 . . ?
C27 C26 H26A 107.9 . . ?
N3 C26 H26B 107.9 . . ?
C27 C26 H26B 107.9 . . ?
H26A C26 H26B 107.2 . . ?
N4 C25 C24 120.7(6) . . ?
N4 C25 C19 114.1(6) . . ?
C24 C25 C19 125.2(6) . . ?
N1 C8 C9 115.0(6) . . ?
N1 C8 H8A 108.5 . . ?
C9 C8 H8A 108.5 . . ?
N1 C8 H8B 108.5 . . ?
C9 C8 H8B 108.5 . . ?
H8A C8 H8B 107.5 . . ?
C32 C31 C33 111.0(6) . . ?
C32 C31 C30 111.8(6) . . ?
C33 C31 C30 108.8(7) . . ?
C32 C31 H31 108.4 . . ?
C33 C31 H31 108.4 . . ?
C30 C31 H31 108.4 . . ?
C5 C6 C7 130.9(7) . . ?
C5 C6 H6 114.6 . . ?
C7 C6 H6 114.6 . . ?
C11 C9 C8 113.8(6) . . ?
C11 C9 C10 111.7(6) . . ?
C8 C9 C10 107.4(6) . . ?
C11 C9 H9 107.9 . . ?
C8 C9 H9 107.9 . . ?
C10 C9 H9 107.9 . . ?
C36 C34 C35 111.7(6) . . ?
C36 C34 Ge2 113.1(5) . . ?
C35 C34 Ge2 112.6(5) . . ?
C36 C34 H34 106.3 . . ?
C35 C34 H34 106.3 . . ?
Ge2 C34 H34 106.3 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
N3 C19 C20 122.2(6) . . ?
N3 C19 C25 113.0(6) . . ?
C20 C19 C25 124.7(6) . . ?
C14 C13 C15 109.2(7) . . ?
C14 C13 C12 112.5(6) . . ?
C15 C13 C12 109.5(7) . . ?
C14 C13 H13 108.5 . . ?
C15 C13 H13 108.5 . . ?
C12 C13 H13 108.5 . . ?
N4 C30 C31 116.9(6) . . ?
N4 C30 H30A 108.1 . . ?
C31 C30 H30A 108.1 . . ?
N4 C30 H30B 108.1 . . ?
C31 C30 H30B 108.1 . . ?
H30A C30 H30B 107.3 . . ?
C29 C27 C28 110.4(6) . . ?
C29 C27 C26 108.7(6) . . ?
C28 C27 C26 113.0(6) . . ?
C29 C27 H27 108.2 . . ?
C28 C27 H27 108.2 . . ?
C26 C27 H27 108.2 . . ?
C21 C20 C19 131.7(7) . . ?
C21 C20 H20 114.2 . . ?
C19 C20 H20 114.2 . . ?
N1 C1 C2 122.8(6) . . ?
N1 C1 C7 112.7(6) . . ?
C2 C1 C7 124.5(7) . . ?
N2 C12 C13 115.6(6) . . ?
N2 C12 H12A 108.4 . . ?
C13 C12 H12A 108.4 . . ?
N2 C12 H12B 108.4 . . ?
C13 C12 H12B 108.4 . . ?
H12A C12 H12B 107.4 . . ?
C18 C16 C17 112.6(6) . . ?
C18 C16 Ge1 113.2(5) . . ?
C17 C16 Ge1 111.6(5) . . ?
C18 C16 H16 102(4) . . ?
C17 C16 H16 110(4) . . ?
Ge1 C16 H16 106(4) . . ?
C3 C2 C1 131.3(7) . . ?
C3 C2 H2 114.4 . . ?
C1 C2 H2 114.4 . . ?
N2 C7 C6 121.2(6) . . ?
N2 C7 C1 113.3(6) . . ?
C6 C7 C1 125.5(7) . . ?
C2 C3 C4 132.0(8) . . ?
C2 C3 H3 114.0 . . ?
C4 C3 H3 114.0 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C23 C24 C25 131.8(7) . . ?
C23 C24 H24 114.1 . . ?
C25 C24 H24 114.1 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C4 C5 C6 130.2(7) . . ?
C4 C5 H5 114.9 . . ?
C6 C5 H5 114.9 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C22 C21 C20 130.4(7) . . ?
C22 C21 H21 114.8 . . ?
C20 C21 H21 114.8 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C3 C4 C5 125.5(7) . . ?
C3 C4 H4 117.3 . . ?
C5 C4 H4 117.3 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C22 C23 C24 129.9(7) . . ?
C22 C23 H23 115.1 . . ?
C24 C23 H23 115.1 . . ?
C23 C22 C21 126.1(7) . . ?
C23 C22 H22 116.9 . . ?
C21 C22 H22 117.0 . . ?
C40 O1 C37 95.7(10) . . ?
O1 C40 C39 113.4(10) . . ?
O1 C40 H40A 108.9 . . ?
C39 C40 H40A 108.9 . . ?
O1 C40 H40B 108.9 . . ?
C39 C40 H40B 108.9 . . ?
H40A C40 H40B 107.7 . . ?
C38 C37 O1 115.1(12) . . ?
C38 C37 H37A 108.2 . . ?
O1 C37 H37A 108.4 . . ?
C38 C37 H37B 108.7 . . ?
O1 C37 H37B 108.6 . . ?
H37A C37 H37B 107.5 . . ?
C38 C39 C40 108.8(14) . . ?
C38 C39 H39A 110.1 . . ?
C40 C39 H39A 109.9 . . ?
C38 C39 H39B 109.8 . . ?
C40 C39 H39B 109.9 . . ?
H39A C39 H39B 108.3 . . ?
C39 C38 C37 101.4(14) . . ?
C39 C38 H38A 111.6 . . ?
C37 C38 H38A 111.8 . . ?
C39 C38 H38B 111.3 . . ?
C37 C38 H38B 111.3 . . ?
H38A C38 H38B 109.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N8 Pt1 Ge1 N2 -85.3(3) . . . . ?
N5 Pt1 Ge1 N2 -90.3(9) . . . . ?
Ge2 Pt1 Ge1 N2 90.03(19) . . . . ?
N8 Pt1 Ge1 N1 173.9(3) . . . . ?
N5 Pt1 Ge1 N1 168.9(9) . . . . ?
Ge2 Pt1 Ge1 N1 -10.8(2) . . . . ?
N8 Pt1 Ge1 C16 35.6(3) . . . . ?
N5 Pt1 Ge1 C16 30.6(9) . . . . ?
Ge2 Pt1 Ge1 C16 -149.1(2) . . . . ?
N8 Pt1 Ge2 N4 -151.3(19) . . . . ?
N5 Pt1 Ge2 N4 -92.4(3) . . . . ?
Ge1 Pt1 Ge2 N4 87.60(19) . . . . ?
N8 Pt1 Ge2 N3 105.4(19) . . . . ?
N5 Pt1 Ge2 N3 164.4(3) . . . . ?
Ge1 Pt1 Ge2 N3 -15.7(2) . . . . ?
N8 Pt1 Ge2 C34 -29.2(19) . . . . ?
N5 Pt1 Ge2 C34 29.7(3) . . . . ?
Ge1 Pt1 Ge2 C34 -150.3(2) . . . . ?
N2 Ge1 N1 C1 2.4(5) . . . . ?
C16 Ge1 N1 C1 -98.6(5) . . . . ?
Pt1 Ge1 N1 C1 119.9(5) . . . . ?
N2 Ge1 N1 C8 -170.2(5) . . . . ?
C16 Ge1 N1 C8 88.8(5) . . . . ?
Pt1 Ge1 N1 C8 -52.7(5) . . . . ?
N3 Ge2 N4 C25 -2.4(5) . . . . ?
C34 Ge2 N4 C25 104.2(5) . . . . ?
Pt1 Ge2 N4 C25 -127.7(4) . . . . ?
N3 Ge2 N4 C30 -176.7(5) . . . . ?
C34 Ge2 N4 C30 -70.2(5) . . . . ?
Pt1 Ge2 N4 C30 58.0(5) . . . . ?
N4 Ge2 N3 C19 1.9(5) . . . . ?
C34 Ge2 N3 C19 -98.0(5) . . . . ?
Pt1 Ge2 N3 C19 124.8(4) . . . . ?
N4 Ge2 N3 C26 -174.1(5) . . . . ?
C34 Ge2 N3 C26 86.0(5) . . . . ?
Pt1 Ge2 N3 C26 -51.2(6) . . . . ?
N8 Pt1 N5 N6 -119.2(7) . . . . ?
Ge1 Pt1 N5 N6 -114.2(9) . . . . ?
Ge2 Pt1 N5 N6 65.5(7) . . . . ?
Pt1 N5 N6 N7 -175(14) . . . . ?
N1 Ge1 N2 C7 -5.1(5) . . . . ?
C16 Ge1 N2 C7 100.3(5) . . . . ?
Pt1 Ge1 N2 C7 -131.8(4) . . . . ?
N1 Ge1 N2 C12 177.9(6) . . . . ?
C16 Ge1 N2 C12 -76.7(6) . . . . ?
Pt1 Ge1 N2 C12 51.2(6) . . . . ?
N10 N9 N8 Pt1 176(100) . . . . ?
N5 Pt1 N8 N9 -52.0(6) . . . . ?
Ge1 Pt1 N8 N9 129.0(6) . . . . ?
Ge2 Pt1 N8 N9 7(2) . . . . ?
C19 N3 C26 C27 97.0(8) . . . . ?
Ge2 N3 C26 C27 -87.3(7) . . . . ?
C30 N4 C25 C24 -3.1(10) . . . . ?
Ge2 N4 C25 C24 -177.3(5) . . . . ?
C30 N4 C25 C19 176.4(6) . . . . ?
Ge2 N4 C25 C19 2.3(7) . . . . ?
C1 N1 C8 C9 101.2(8) . . . . ?
Ge1 N1 C8 C9 -86.9(7) . . . . ?
N1 C8 C9 C11 -69.8(8) . . . . ?
N1 C8 C9 C10 165.9(6) . . . . ?
N4 Ge2 C34 C36 174.6(5) . . . . ?
N3 Ge2 C34 C36 -99.1(5) . . . . ?
Pt1 Ge2 C34 C36 42.4(6) . . . . ?
N4 Ge2 C34 C35 -57.6(5) . . . . ?
N3 Ge2 C34 C35 28.7(5) . . . . ?
Pt1 Ge2 C34 C35 170.2(4) . . . . ?
C26 N3 C19 C20 -2.6(10) . . . . ?
Ge2 N3 C19 C20 -178.6(5) . . . . ?
C26 N3 C19 C25 174.8(6) . . . . ?
Ge2 N3 C19 C25 -1.2(7) . . . . ?
N4 C25 C19 N3 -0.7(9) . . . . ?
C24 C25 C19 N3 178.8(6) . . . . ?
N4 C25 C19 C20 176.6(6) . . . . ?
C24 C25 C19 C20 -3.9(11) . . . . ?
C25 N4 C30 C31 79.2(8) . . . . ?
Ge2 N4 C30 C31 -107.0(6) . . . . ?
C32 C31 C30 N4 60.6(8) . . . . ?
C33 C31 C30 N4 -176.4(6) . . . . ?
N3 C26 C27 C29 173.5(6) . . . . ?
N3 C26 C27 C28 -63.6(8) . . . . ?
N3 C19 C20 C21 179.5(8) . . . . ?
C25 C19 C20 C21 2.5(12) . . . . ?
C8 N1 C1 C2 -5.7(11) . . . . ?
Ge1 N1 C1 C2 -177.8(6) . . . . ?
C8 N1 C1 C7 172.7(6) . . . . ?
Ge1 N1 C1 C7 0.5(8) . . . . ?
C7 N2 C12 C13 74.1(9) . . . . ?
Ge1 N2 C12 C13 -109.2(6) . . . . ?
C14 C13 C12 N2 63.5(9) . . . . ?
C15 C13 C12 N2 -174.8(7) . . . . ?
N2 Ge1 C16 C18 -56.6(6) . . . . ?
N1 Ge1 C16 C18 29.5(6) . . . . ?
Pt1 Ge1 C16 C18 175.4(4) . . . . ?
N2 Ge1 C16 C17 175.1(5) . . . . ?
N1 Ge1 C16 C17 -98.8(5) . . . . ?
Pt1 Ge1 C16 C17 47.1(6) . . . . ?
N1 C1 C2 C3 177.5(8) . . . . ?
C7 C1 C2 C3 -0.7(13) . . . . ?
C12 N2 C7 C6 2.1(11) . . . . ?
Ge1 N2 C7 C6 -174.8(5) . . . . ?
C12 N2 C7 C1 -176.5(6) . . . . ?
Ge1 N2 C7 C1 6.6(8) . . . . ?
C5 C6 C7 N2 -174.2(8) . . . . ?
C5 C6 C7 C1 4.3(13) . . . . ?
N1 C1 C7 N2 -4.6(9) . . . . ?
C2 C1 C7 N2 173.7(7) . . . . ?
N1 C1 C7 C6 176.9(7) . . . . ?
C2 C1 C7 C6 -4.8(12) . . . . ?
C1 C2 C3 C4 4.3(16) . . . . ?
N4 C25 C24 C23 180.0(8) . . . . ?
C19 C25 C24 C23 0.5(13) . . . . ?
C7 C6 C5 C4 1.7(15) . . . . ?
C19 C20 C21 C22 1.4(15) . . . . ?
C2 C3 C4 C5 -0.6(16) . . . . ?
C6 C5 C4 C3 -4.0(16) . . . . ?
C25 C24 C23 C22 3.4(15) . . . . ?
C24 C23 C22 C21 -2.2(16) . . . . ?
C20 C21 C22 C23 -1.5(16) . . . . ?
C37 O1 C40 C39 5.3(19) . . . . ?
C40 O1 C37 C38 10(2) . . . . ?
O1 C40 C39 C38 -19(3) . . . . ?
C40 C39 C38 C37 23(3) . . . . ?
O1 C37 C38 C39 -21(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.653
_refine_diff_density_min         -0.221
_refine_diff_density_rms         0.145
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_msha33m
_database_code_depnum_ccdc_archive 'CCDC 1585661'
_audit_update_record             
;
2017-11-14 deposited with the CCDC.
2018-03-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H120 Cl2 Ge4 N8 Pt2, 2(C F3 O3 S)'
_chemical_formula_sum            'C74 H120 Cl2 F6 Ge4 N8 O6 Pt2 S2'
_chemical_formula_weight         2147.40

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.799(2)
_cell_length_b                   17.921(3)
_cell_length_c                   22.042(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.711(4)
_cell_angle_gamma                90.00
_cell_volume                     4263.9(13)
_cell_formula_units_Z            2
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    1723
_cell_measurement_theta_min      2.164
_cell_measurement_theta_max      20.669

_exptl_crystal_description       blockshape
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.345
_exptl_crystal_size_mid          0.275
_exptl_crystal_size_min          0.157
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.673
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2144.0
_exptl_absorpt_coefficient_mu    4.837
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.221
_exptl_absorpt_correction_T_max  0.468
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            22043
_diffrn_reflns_av_R_equivalents  0.0950
_diffrn_reflns_av_sigmaI/netI    0.1132
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         1.85
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7497
_reflns_number_gt                5274
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0501P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7497
_refine_ls_number_parameters     475
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0867
_refine_ls_R_factor_gt           0.0522
_refine_ls_wR_factor_ref         0.1271
_refine_ls_wR_factor_gt          0.1069
_refine_ls_goodness_of_fit_ref   0.983
_refine_ls_restrained_S_all      0.983
_refine_ls_shift/su_max          0.014
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.04208(3) 0.58850(2) 0.036377(16) 0.01578(12) Uani 1 1 d . . .
Ge1 Ge 0.07407(8) 0.70478(5) -0.00838(4) 0.0155(2) Uani 1 1 d . . .
Ge2 Ge 0.07890(8) 0.61840(6) 0.13838(4) 0.0173(2) Uani 1 1 d . . .
S1 S 0.3771(2) 0.05939(15) 0.15806(12) 0.0276(6) Uani 1 1 d . . .
O3 O 0.2964(6) -0.0038(4) 0.1494(3) 0.042(2) Uani 1 1 d . . .
O1 O 0.3734(7) 0.1135(4) 0.1101(3) 0.047(2) Uani 1 1 d . . .
O2 O 0.3784(6) 0.0895(5) 0.2182(3) 0.046(2) Uani 1 1 d . . .
F1 F 0.6205(5) 0.0694(3) 0.1601(3) 0.0365(15) Uani 1 1 d . . .
F2 F 0.5503(6) -0.0323(4) 0.1962(3) 0.0493(18) Uani 1 1 d . . .
F3 F 0.5473(5) -0.0138(4) 0.1000(3) 0.0414(16) Uani 1 1 d . . .
N1 N -0.0671(6) 0.7665(5) -0.0220(3) 0.0208(19) Uani 1 1 d . . .
N2 N 0.1399(6) 0.7890(4) 0.0332(3) 0.0143(16) Uani 1 1 d . . .
N4 N 0.2437(7) 0.6197(4) 0.1688(3) 0.0220(18) Uani 1 1 d . . .
N3 N 0.0747(6) 0.7161(4) 0.1712(3) 0.0172(17) Uani 1 1 d . . .
C8 C -0.1687(8) 0.7433(5) -0.0637(4) 0.020(2) Uani 1 1 d . . .
H8A H -0.1401 0.7015 -0.0875 0.025 Uiso 1 1 calc R . .
H8B H -0.1864 0.7840 -0.0916 0.025 Uiso 1 1 calc R . .
C7 C 0.0606(8) 0.8471(5) 0.0378(4) 0.017(2) Uani 1 1 d . . .
C37 C 0.5303(9) 0.0182(6) 0.1527(5) 0.029(3) Uani 1 1 d . . .
C6 C 0.0896(8) 0.9119(5) 0.0704(4) 0.024(2) Uani 1 1 d . . .
H6 H 0.1715 0.9145 0.0846 0.029 Uiso 1 1 calc R . .
C32 C 0.5287(9) 0.5044(6) 0.1341(4) 0.029(2) Uani 1 1 d . . .
H32A H 0.4901 0.4562 0.1314 0.043 Uiso 1 1 calc R . .
H32B H 0.5637 0.5115 0.1742 0.043 Uiso 1 1 calc R . .
H32C H 0.5930 0.5075 0.1050 0.043 Uiso 1 1 calc R . .
C4 C -0.1029(9) 0.9901(5) 0.0692(4) 0.026(2) Uani 1 1 d . . .
H4 H -0.1362 1.0326 0.0866 0.031 Uiso 1 1 calc R . .
C31 C 0.4322(8) 0.5646(5) 0.1206(4) 0.019(2) Uani 1 1 d . . .
H31 H 0.4708 0.6132 0.1289 0.023 Uiso 1 1 calc R . .
C12 C 0.2593(7) 0.7858(5) 0.0665(4) 0.021(2) Uani 1 1 d . . .
H12A H 0.2709 0.7353 0.0815 0.025 Uiso 1 1 calc R . .
H12B H 0.2546 0.8182 0.1016 0.025 Uiso 1 1 calc R . .
C19 C 0.1800(8) 0.7389(5) 0.1983(4) 0.016(2) Uani 1 1 d . . .
C9 C -0.2900(8) 0.7205(6) -0.0342(5) 0.0314(18) Uani 1 1 d . . .
H9 H -0.3253 0.7649 -0.0153 0.038 Uiso 1 1 calc R . .
C14 C 0.3685(8) 0.8852(5) 0.0050(4) 0.022(2) Uani 1 1 d . . .
H14A H 0.3617 0.9212 0.0370 0.033 Uiso 1 1 calc R . .
H14B H 0.2979 0.8892 -0.0223 0.033 Uiso 1 1 calc R . .
H14C H 0.4427 0.8944 -0.0167 0.033 Uiso 1 1 calc R . .
C15 C 0.4833(8) 0.7994(5) 0.0747(4) 0.022(2) Uani 1 1 d . . .
H15A H 0.4693 0.8272 0.1110 0.032 Uiso 1 1 calc R . .
H15B H 0.5558 0.8182 0.0557 0.032 Uiso 1 1 calc R . .
H15C H 0.4951 0.7477 0.0846 0.032 Uiso 1 1 calc R . .
C10 C -0.3778(10) 0.6946(7) -0.0829(5) 0.047(3) Uani 1 1 d . . .
H10A H -0.3445 0.6513 -0.1021 0.070 Uiso 1 1 calc R . .
H10B H -0.3898 0.7336 -0.1124 0.070 Uiso 1 1 calc R . .
H10C H -0.4557 0.6823 -0.0656 0.070 Uiso 1 1 calc R . .
C21 C 0.2998(9) 0.8491(5) 0.2439(4) 0.022(2) Uani 1 1 d . . .
H21 H 0.2906 0.9003 0.2488 0.027 Uiso 1 1 calc R . .
C5 C 0.0186(9) 0.9727(5) 0.0851(4) 0.025(2) Uani 1 1 d . . .
H5 H 0.0588 1.0077 0.1098 0.031 Uiso 1 1 calc R . .
C25 C 0.2771(8) 0.6825(5) 0.1998(4) 0.023(2) Uani 1 1 d . . .
C20 C 0.1992(8) 0.8129(5) 0.2183(4) 0.022(2) Uani 1 1 d . . .
H20 H 0.1298 0.8432 0.2131 0.027 Uiso 1 1 calc R . .
C24 C 0.3928(8) 0.6875(5) 0.2310(4) 0.019(2) Uani 1 1 d . . .
H24 H 0.4371 0.6430 0.2326 0.023 Uiso 1 1 calc R . .
C22 C 0.4134(9) 0.8200(6) 0.2635(4) 0.027(2) Uani 1 1 d . . .
H22 H 0.4695 0.8534 0.2813 0.032 Uiso 1 1 calc R . .
C13 C 0.3735(8) 0.8074(5) 0.0320(4) 0.019(2) Uani 1 1 d . . .
H13 H 0.3828 0.7717 -0.0012 0.023 Uiso 1 1 calc R . .
C1 C -0.0603(8) 0.8331(5) 0.0041(4) 0.019(2) Uani 1 1 d . . .
C23 C 0.4518(9) 0.7466(6) 0.2594(4) 0.027(2) Uani 1 1 d . . .
H23 H 0.5277 0.7356 0.2784 0.032 Uiso 1 1 calc R . .
C33 C 0.3869(9) 0.5642(6) 0.0564(4) 0.027(2) Uani 1 1 d . . .
H33A H 0.4515 0.5815 0.0308 0.040 Uiso 1 1 calc R . .
H33B H 0.3164 0.5965 0.0519 0.040 Uiso 1 1 calc R . .
H33C H 0.3637 0.5144 0.0448 0.040 Uiso 1 1 calc R . .
C30 C 0.3263(8) 0.5543(5) 0.1648(4) 0.022(2) Uani 1 1 d . . .
H30A H 0.2773 0.5114 0.1521 0.027 Uiso 1 1 calc R . .
H30B H 0.3615 0.5436 0.2049 0.027 Uiso 1 1 calc R . .
C35 C 0.0204(11) 0.5743(6) 0.2608(5) 0.043(3) Uani 1 1 d . . .
H35A H -0.0108 0.6237 0.2675 0.064 Uiso 1 1 calc R . .
H35B H 0.1083 0.5736 0.2684 0.064 Uiso 1 1 calc R . .
H35C H -0.0186 0.5400 0.2877 0.064 Uiso 1 1 calc R . .
C2 C -0.1599(8) 0.8835(5) -0.0001(4) 0.020(2) Uani 1 1 d . . .
H2 H -0.2227 0.8696 -0.0276 0.025 Uiso 1 1 calc R . .
C3 C -0.1801(9) 0.9493(6) 0.0293(4) 0.027(2) Uani 1 1 d . . .
H3 H -0.2576 0.9704 0.0214 0.032 Uiso 1 1 calc R . .
C34 C -0.0076(10) 0.5516(6) 0.1961(4) 0.031(3) Uani 1 1 d . . .
H34 H 0.0282 0.5018 0.1912 0.037 Uiso 1 1 calc R . .
C11 C -0.2730(8) 0.6615(6) 0.0138(4) 0.0314(18) Uani 1 1 d . . .
H11A H -0.3495 0.6544 0.0341 0.047 Uiso 1 1 calc R . .
H11B H -0.2099 0.6769 0.0427 0.047 Uiso 1 1 calc R . .
H11C H -0.2488 0.6155 -0.0047 0.047 Uiso 1 1 calc R . .
C36 C -0.1435(10) 0.5444(7) 0.1801(5) 0.045(3) Uani 1 1 d . . .
H36A H -0.1789 0.5058 0.2043 0.067 Uiso 1 1 calc R . .
H36B H -0.1540 0.5321 0.1379 0.067 Uiso 1 1 calc R . .
H36C H -0.1843 0.5909 0.1880 0.067 Uiso 1 1 calc R . .
Cl1 Cl 0.0225(2) 0.45720(13) 0.06389(10) 0.0242(6) Uani 1 1 d . . .
C18 C 0.2623(8) 0.6456(5) -0.0862(4) 0.018(2) Uani 1 1 d . . .
H18A H 0.2887 0.6368 -0.1268 0.028 Uiso 1 1 calc R . .
H18B H 0.2399 0.5991 -0.0679 0.028 Uiso 1 1 calc R . .
H18C H 0.3287 0.6681 -0.0627 0.028 Uiso 1 1 calc R . .
C16 C 0.1488(8) 0.6985(5) -0.0880(4) 0.020(2) Uani 1 1 d . . .
H16 H 0.0867 0.6750 -0.1151 0.024 Uiso 1 1 calc R . .
C17 C 0.1775(9) 0.7737(5) -0.1160(4) 0.023(2) Uani 1 1 d . . .
H17A H 0.2397 0.7987 -0.0915 0.035 Uiso 1 1 calc R . .
H17B H 0.1036 0.8034 -0.1181 0.035 Uiso 1 1 calc R . .
H17C H 0.2074 0.7664 -0.1562 0.035 Uiso 1 1 calc R . .
C26 C -0.0339(8) 0.7650(5) 0.1599(4) 0.024(2) Uani 1 1 d . . .
H26A H -0.0729 0.7508 0.1214 0.029 Uiso 1 1 calc R . .
H26B H -0.0046 0.8159 0.1557 0.029 Uiso 1 1 calc R . .
C27 C -0.1316(9) 0.7640(6) 0.2077(4) 0.032(3) Uani 1 1 d . . .
H27 H -0.1578 0.7123 0.2138 0.039 Uiso 1 1 calc R . .
C28 C -0.0893(10) 0.7960(7) 0.2686(5) 0.047(3) Uani 1 1 d . . .
H28A H -0.0191 0.7684 0.2840 0.070 Uiso 1 1 calc R . .
H28B H -0.1555 0.7925 0.2965 0.070 Uiso 1 1 calc R . .
H28C H -0.0667 0.8474 0.2636 0.070 Uiso 1 1 calc R . .
C29 C -0.2431(9) 0.8088(7) 0.1813(5) 0.048(3) Uani 1 1 d . . .
H29A H -0.2174 0.8588 0.1726 0.072 Uiso 1 1 calc R . .
H29B H -0.3076 0.8099 0.2103 0.072 Uiso 1 1 calc R . .
H29C H -0.2735 0.7853 0.1446 0.072 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ge2 2.3339(11) . ?
Pt1 Ge1 2.3357(11) . ?
Pt1 Cl1 2.439(2) 3_565 ?
Pt1 Cl1 2.441(2) . ?
Ge1 N2 1.894(7) . ?
Ge1 N1 1.899(8) . ?
Ge1 C16 1.956(9) . ?
Ge2 N4 1.883(7) . ?
Ge2 N3 1.896(7) . ?
Ge2 C34 2.000(10) . ?
S1 O2 1.430(7) . ?
S1 O1 1.435(7) . ?
S1 O3 1.438(7) . ?
S1 C37 1.819(11) . ?
F1 C37 1.345(11) . ?
F2 C37 1.331(11) . ?
F3 C37 1.312(11) . ?
N1 C1 1.327(12) . ?
N1 C8 1.470(11) . ?
N2 C7 1.353(11) . ?
N2 C12 1.466(10) . ?
N4 C25 1.359(12) . ?
N4 C30 1.478(12) . ?
N3 C19 1.332(11) . ?
N3 C26 1.479(11) . ?
C8 C9 1.536(12) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C7 C6 1.396(12) . ?
C7 C1 1.504(12) . ?
C6 C5 1.376(13) . ?
C6 H6 0.9300 . ?
C32 C31 1.523(12) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C4 C5 1.383(13) . ?
C4 C3 1.400(13) . ?
C4 H4 0.9300 . ?
C31 C33 1.484(12) . ?
C31 C30 1.536(12) . ?
C31 H31 0.9800 . ?
C12 C13 1.519(12) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C19 C20 1.412(12) . ?
C19 C25 1.457(12) . ?
C9 C10 1.485(13) . ?
C9 C11 1.503(14) . ?
C9 H9 0.9800 . ?
C14 C13 1.517(12) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 C13 1.497(12) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C21 C20 1.371(12) . ?
C21 C22 1.391(13) . ?
C21 H21 0.9300 . ?
C5 H5 0.9300 . ?
C25 C24 1.411(12) . ?
C20 H20 0.9300 . ?
C24 C23 1.376(13) . ?
C24 H24 0.9300 . ?
C22 C23 1.384(13) . ?
C22 H22 0.9300 . ?
C13 H13 0.9800 . ?
C1 C2 1.405(12) . ?
C23 H23 0.9300 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C35 C34 1.503(14) . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C2 C3 1.366(13) . ?
C2 H2 0.9300 . ?
C3 H3 0.9300 . ?
C34 C36 1.504(14) . ?
C34 H34 0.9800 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
Cl1 Pt1 2.439(2) 3_565 ?
C18 C16 1.550(12) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C16 C17 1.517(12) . ?
C16 H16 0.9800 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C26 C27 1.514(12) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.516(14) . ?
C27 C29 1.545(13) . ?
C27 H27 0.9800 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge2 Pt1 Ge1 100.31(4) . . ?
Ge2 Pt1 Cl1 170.35(6) . 3_565 ?
Ge1 Pt1 Cl1 87.64(6) . 3_565 ?
Ge2 Pt1 Cl1 89.75(6) . . ?
Ge1 Pt1 Cl1 168.55(6) . . ?
Cl1 Pt1 Cl1 82.93(8) 3_565 . ?
N2 Ge1 N1 84.3(3) . . ?
N2 Ge1 C16 108.7(3) . . ?
N1 Ge1 C16 104.0(3) . . ?
N2 Ge1 Pt1 124.4(2) . . ?
N1 Ge1 Pt1 117.3(2) . . ?
C16 Ge1 Pt1 113.4(3) . . ?
N4 Ge2 N3 83.4(3) . . ?
N4 Ge2 C34 103.6(4) . . ?
N3 Ge2 C34 107.0(4) . . ?
N4 Ge2 Pt1 118.6(2) . . ?
N3 Ge2 Pt1 125.0(2) . . ?
C34 Ge2 Pt1 114.0(3) . . ?
O2 S1 O1 115.3(5) . . ?
O2 S1 O3 114.1(5) . . ?
O1 S1 O3 115.5(5) . . ?
O2 S1 C37 103.3(5) . . ?
O1 S1 C37 103.4(5) . . ?
O3 S1 C37 102.7(5) . . ?
C1 N1 C8 123.8(8) . . ?
C1 N1 Ge1 114.9(6) . . ?
C8 N1 Ge1 121.0(6) . . ?
C7 N2 C12 122.8(7) . . ?
C7 N2 Ge1 114.8(6) . . ?
C12 N2 Ge1 121.5(6) . . ?
C25 N4 C30 122.4(8) . . ?
C25 N4 Ge2 115.0(6) . . ?
C30 N4 Ge2 122.3(6) . . ?
C19 N3 C26 123.8(8) . . ?
C19 N3 Ge2 115.1(6) . . ?
C26 N3 Ge2 120.7(6) . . ?
N1 C8 C9 116.1(7) . . ?
N1 C8 H8A 108.3 . . ?
C9 C8 H8A 108.3 . . ?
N1 C8 H8B 108.3 . . ?
C9 C8 H8B 108.3 . . ?
H8A C8 H8B 107.4 . . ?
N2 C7 C6 123.1(8) . . ?
N2 C7 C1 112.1(7) . . ?
C6 C7 C1 124.8(8) . . ?
F3 C37 F2 108.5(9) . . ?
F3 C37 F1 106.6(8) . . ?
F2 C37 F1 106.0(8) . . ?
F3 C37 S1 112.7(7) . . ?
F2 C37 S1 111.0(7) . . ?
F1 C37 S1 111.8(7) . . ?
C5 C6 C7 131.4(9) . . ?
C5 C6 H6 114.3 . . ?
C7 C6 H6 114.3 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C5 C4 C3 125.7(9) . . ?
C5 C4 H4 117.1 . . ?
C3 C4 H4 117.1 . . ?
C33 C31 C32 112.7(8) . . ?
C33 C31 C30 112.0(7) . . ?
C32 C31 C30 108.0(8) . . ?
C33 C31 H31 108.0 . . ?
C32 C31 H31 108.0 . . ?
C30 C31 H31 108.0 . . ?
N2 C12 C13 117.1(7) . . ?
N2 C12 H12A 108.0 . . ?
C13 C12 H12A 108.0 . . ?
N2 C12 H12B 108.0 . . ?
C13 C12 H12B 108.0 . . ?
H12A C12 H12B 107.3 . . ?
N3 C19 C20 122.9(8) . . ?
N3 C19 C25 113.7(8) . . ?
C20 C19 C25 123.1(8) . . ?
C10 C9 C11 110.5(9) . . ?
C10 C9 C8 108.1(9) . . ?
C11 C9 C8 113.4(8) . . ?
C10 C9 H9 108.2 . . ?
C11 C9 H9 108.2 . . ?
C8 C9 H9 108.2 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C20 C21 C22 129.2(9) . . ?
C20 C21 H21 115.4 . . ?
C22 C21 H21 115.4 . . ?
C6 C5 C4 130.5(9) . . ?
C6 C5 H5 114.8 . . ?
C4 C5 H5 114.8 . . ?
N4 C25 C24 121.0(9) . . ?
N4 C25 C19 112.5(8) . . ?
C24 C25 C19 126.4(9) . . ?
C21 C20 C19 132.8(9) . . ?
C21 C20 H20 113.6 . . ?
C19 C20 H20 113.6 . . ?
C23 C24 C25 131.5(9) . . ?
C23 C24 H24 114.3 . . ?
C25 C24 H24 114.3 . . ?
C23 C22 C21 126.8(9) . . ?
C23 C22 H22 116.6 . . ?
C21 C22 H22 116.6 . . ?
C15 C13 C14 110.6(7) . . ?
C15 C13 C12 107.5(7) . . ?
C14 C13 C12 114.2(7) . . ?
C15 C13 H13 108.1 . . ?
C14 C13 H13 108.1 . . ?
C12 C13 H13 108.1 . . ?
N1 C1 C2 121.1(9) . . ?
N1 C1 C7 113.6(8) . . ?
C2 C1 C7 125.2(9) . . ?
C24 C23 C22 128.8(9) . . ?
C24 C23 H23 115.6 . . ?
C22 C23 H23 115.6 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N4 C30 C31 113.8(8) . . ?
N4 C30 H30A 108.8 . . ?
C31 C30 H30A 108.8 . . ?
N4 C30 H30B 108.8 . . ?
C31 C30 H30B 108.8 . . ?
H30A C30 H30B 107.7 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C3 C2 C1 131.0(9) . . ?
C3 C2 H2 114.5 . . ?
C1 C2 H2 114.5 . . ?
C2 C3 C4 130.4(9) . . ?
C2 C3 H3 114.8 . . ?
C4 C3 H3 114.8 . . ?
C35 C34 C36 114.4(9) . . ?
C35 C34 Ge2 110.9(7) . . ?
C36 C34 Ge2 111.9(7) . . ?
C35 C34 H34 106.4 . . ?
C36 C34 H34 106.4 . . ?
Ge2 C34 H34 106.4 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
Pt1 Cl1 Pt1 97.07(8) 3_565 . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C16 C18 112.5(7) . . ?
C17 C16 Ge1 114.1(6) . . ?
C18 C16 Ge1 111.1(6) . . ?
C17 C16 H16 106.2 . . ?
C18 C16 H16 106.2 . . ?
Ge1 C16 H16 106.2 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N3 C26 C27 116.2(8) . . ?
N3 C26 H26A 108.2 . . ?
C27 C26 H26A 108.2 . . ?
N3 C26 H26B 108.2 . . ?
C27 C26 H26B 108.2 . . ?
H26A C26 H26B 107.4 . . ?
C26 C27 C28 114.5(9) . . ?
C26 C27 C29 106.4(8) . . ?
C28 C27 C29 110.3(9) . . ?
C26 C27 H27 108.5 . . ?
C28 C27 H27 108.5 . . ?
C29 C27 H27 108.5 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ge2 Pt1 Ge1 N2 9.3(3) . . . . ?
Cl1 Pt1 Ge1 N2 -176.2(3) 3_565 . . . ?
Cl1 Pt1 Ge1 N2 -141.8(4) . . . . ?
Ge2 Pt1 Ge1 N1 -93.3(3) . . . . ?
Cl1 Pt1 Ge1 N1 81.2(3) 3_565 . . . ?
Cl1 Pt1 Ge1 N1 115.7(4) . . . . ?
Ge2 Pt1 Ge1 C16 145.4(3) . . . . ?
Cl1 Pt1 Ge1 C16 -40.1(3) 3_565 . . . ?
Cl1 Pt1 Ge1 C16 -5.7(4) . . . . ?
Ge1 Pt1 Ge2 N4 -83.6(3) . . . . ?
Cl1 Pt1 Ge2 N4 131.4(5) 3_565 . . . ?
Cl1 Pt1 Ge2 N4 90.9(3) . . . . ?
Ge1 Pt1 Ge2 N3 19.3(3) . . . . ?
Cl1 Pt1 Ge2 N3 -125.8(5) 3_565 . . . ?
Cl1 Pt1 Ge2 N3 -166.2(3) . . . . ?
Ge1 Pt1 Ge2 C34 154.0(3) . . . . ?
Cl1 Pt1 Ge2 C34 9.0(5) 3_565 . . . ?
Cl1 Pt1 Ge2 C34 -31.5(4) . . . . ?
N2 Ge1 N1 C1 -3.5(6) . . . . ?
C16 Ge1 N1 C1 -111.4(7) . . . . ?
Pt1 Ge1 N1 C1 122.5(6) . . . . ?
N2 Ge1 N1 C8 170.7(7) . . . . ?
C16 Ge1 N1 C8 62.7(7) . . . . ?
Pt1 Ge1 N1 C8 -63.4(7) . . . . ?
N1 Ge1 N2 C7 4.4(6) . . . . ?
C16 Ge1 N2 C7 107.2(6) . . . . ?
Pt1 Ge1 N2 C7 -114.9(6) . . . . ?
N1 Ge1 N2 C12 174.4(7) . . . . ?
C16 Ge1 N2 C12 -82.8(7) . . . . ?
Pt1 Ge1 N2 C12 55.0(7) . . . . ?
N3 Ge2 N4 C25 3.0(7) . . . . ?
C34 Ge2 N4 C25 -103.0(7) . . . . ?
Pt1 Ge2 N4 C25 129.6(6) . . . . ?
N3 Ge2 N4 C30 176.9(7) . . . . ?
C34 Ge2 N4 C30 70.9(7) . . . . ?
Pt1 Ge2 N4 C30 -56.5(7) . . . . ?
N4 Ge2 N3 C19 -0.1(6) . . . . ?
C34 Ge2 N3 C19 102.2(7) . . . . ?
Pt1 Ge2 N3 C19 -120.6(6) . . . . ?
N4 Ge2 N3 C26 172.7(7) . . . . ?
C34 Ge2 N3 C26 -85.1(7) . . . . ?
Pt1 Ge2 N3 C26 52.2(7) . . . . ?
C1 N1 C8 C9 -78.1(11) . . . . ?
Ge1 N1 C8 C9 108.3(8) . . . . ?
C12 N2 C7 C6 5.7(13) . . . . ?
Ge1 N2 C7 C6 175.6(7) . . . . ?
C12 N2 C7 C1 -174.2(7) . . . . ?
Ge1 N2 C7 C1 -4.3(9) . . . . ?
O2 S1 C37 F3 179.2(7) . . . . ?
O1 S1 C37 F3 -60.3(8) . . . . ?
O3 S1 C37 F3 60.3(8) . . . . ?
O2 S1 C37 F2 57.3(9) . . . . ?
O1 S1 C37 F2 177.8(7) . . . . ?
O3 S1 C37 F2 -61.6(8) . . . . ?
O2 S1 C37 F1 -60.7(8) . . . . ?
O1 S1 C37 F1 59.8(8) . . . . ?
O3 S1 C37 F1 -179.7(6) . . . . ?
N2 C7 C6 C5 -172.6(10) . . . . ?
C1 C7 C6 C5 7.2(16) . . . . ?
C7 N2 C12 C13 -99.2(10) . . . . ?
Ge1 N2 C12 C13 91.6(9) . . . . ?
C26 N3 C19 C20 -0.9(13) . . . . ?
Ge2 N3 C19 C20 171.6(7) . . . . ?
C26 N3 C19 C25 -175.1(8) . . . . ?
Ge2 N3 C19 C25 -2.6(10) . . . . ?
N1 C8 C9 C10 -176.5(9) . . . . ?
N1 C8 C9 C11 -53.6(12) . . . . ?
C7 C6 C5 C4 -4.1(19) . . . . ?
C3 C4 C5 C6 -4.7(18) . . . . ?
C30 N4 C25 C24 -1.2(14) . . . . ?
Ge2 N4 C25 C24 172.7(7) . . . . ?
C30 N4 C25 C19 -179.0(8) . . . . ?
Ge2 N4 C25 C19 -5.1(10) . . . . ?
N3 C19 C25 N4 5.0(12) . . . . ?
C20 C19 C25 N4 -169.2(8) . . . . ?
N3 C19 C25 C24 -172.6(9) . . . . ?
C20 C19 C25 C24 13.2(15) . . . . ?
C22 C21 C20 C19 -7.0(18) . . . . ?
N3 C19 C20 C21 -176.2(10) . . . . ?
C25 C19 C20 C21 -2.5(16) . . . . ?
N4 C25 C24 C23 172.1(10) . . . . ?
C19 C25 C24 C23 -10.5(17) . . . . ?
C20 C21 C22 C23 2.5(17) . . . . ?
N2 C12 C13 C15 -179.7(8) . . . . ?
N2 C12 C13 C14 57.2(11) . . . . ?
C8 N1 C1 C2 8.6(13) . . . . ?
Ge1 N1 C1 C2 -177.5(7) . . . . ?
C8 N1 C1 C7 -172.0(7) . . . . ?
Ge1 N1 C1 C7 2.0(10) . . . . ?
N2 C7 C1 N1 1.5(11) . . . . ?
C6 C7 C1 N1 -178.3(8) . . . . ?
N2 C7 C1 C2 -179.0(8) . . . . ?
C6 C7 C1 C2 1.1(14) . . . . ?
C25 C24 C23 C22 -2.3(17) . . . . ?
C21 C22 C23 C24 6.1(17) . . . . ?
C25 N4 C30 C31 -75.8(11) . . . . ?
Ge2 N4 C30 C31 110.7(8) . . . . ?
C33 C31 C30 N4 -71.3(10) . . . . ?
C32 C31 C30 N4 164.1(7) . . . . ?
N1 C1 C2 C3 170.0(9) . . . . ?
C7 C1 C2 C3 -9.5(16) . . . . ?
C1 C2 C3 C4 5.9(18) . . . . ?
C5 C4 C3 C2 4.0(18) . . . . ?
N4 Ge2 C34 C35 49.8(8) . . . . ?
N3 Ge2 C34 C35 -37.4(8) . . . . ?
Pt1 Ge2 C34 C35 -180.0(7) . . . . ?
N4 Ge2 C34 C36 178.8(8) . . . . ?
N3 Ge2 C34 C36 91.6(8) . . . . ?
Pt1 Ge2 C34 C36 -51.0(9) . . . . ?
Ge2 Pt1 Cl1 Pt1 173.71(7) . . . 3_565 ?
Ge1 Pt1 Cl1 Pt1 -34.7(4) . . . 3_565 ?
Cl1 Pt1 Cl1 Pt1 0.0 3_565 . . 3_565 ?
N2 Ge1 C16 C17 -33.6(7) . . . . ?
N1 Ge1 C16 C17 55.1(7) . . . . ?
Pt1 Ge1 C16 C17 -176.4(5) . . . . ?
N2 Ge1 C16 C18 94.9(6) . . . . ?
N1 Ge1 C16 C18 -176.5(6) . . . . ?
Pt1 Ge1 C16 C18 -48.0(6) . . . . ?
C19 N3 C26 C27 -93.8(11) . . . . ?
Ge2 N3 C26 C27 94.1(9) . . . . ?
N3 C26 C27 C28 66.6(12) . . . . ?
N3 C26 C27 C29 -171.2(9) . . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.995
_refine_diff_density_min         -1.062
_refine_diff_density_rms         0.208
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_msha41m
_database_code_depnum_ccdc_archive 'CCDC 1585662'
_audit_update_record             
;
2017-11-14 deposited with the CCDC.
2018-03-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C43 H70 Cl Ge2 N6 Pt, C F3 O3 S'
_chemical_formula_sum            'C44 H70 Cl F3 Ge2 N6 O3 Pt S'
_chemical_formula_weight         1195.87

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   14.300(4)
_cell_length_b                   17.928(4)
_cell_length_c                   20.470(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 105.098(5)
_cell_angle_gamma                90.00
_cell_volume                     5067(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    2632
_cell_measurement_theta_min      2.293
_cell_measurement_theta_max      21.750

_exptl_crystal_description       block-shape
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.347
_exptl_crystal_size_mid          0.285
_exptl_crystal_size_min          0.152
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.568
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2408.0
_exptl_absorpt_coefficient_mu    4.080
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.258
_exptl_absorpt_correction_T_max  0.538
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            26256
_diffrn_reflns_av_R_equivalents  0.0864
_diffrn_reflns_av_sigmaI/netI    0.1152
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.53
_diffrn_reflns_theta_max         25.00
_reflns_number_total             8897
_reflns_number_gt                6434
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0615P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8897
_refine_ls_number_parameters     564
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0859
_refine_ls_R_factor_gt           0.0576
_refine_ls_wR_factor_ref         0.1516
_refine_ls_wR_factor_gt          0.1332
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.066
_refine_ls_shift/su_mean         0.003

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.10424(2) 0.87457(2) 0.260063(16) 0.02033(13) Uani 1 1 d . . .
Ge1 Ge 0.16160(6) 0.99334(5) 0.24236(4) 0.0201(2) Uani 1 1 d . . .
Ge2 Ge -0.05572(7) 0.90420(5) 0.25869(5) 0.0215(2) Uani 1 1 d . . .
Cl1 Cl 0.05373(17) 0.74778(13) 0.26148(13) 0.0354(6) Uani 1 1 d . . .
F1 F 0.5997(9) 0.3153(6) 0.4131(5) 0.139(5) Uani 1 1 d . . .
F2 F 0.6502(5) 0.2544(4) 0.5116(3) 0.065(2) Uani 1 1 d . . .
F3 F 0.6209(5) 0.1926(4) 0.4192(3) 0.0595(18) Uani 1 1 d . . .
S1 S 0.4680(3) 0.2531(3) 0.44551(18) 0.0859(15) Uani 1 1 d . . .
O1 O 0.4524(5) 0.3137(4) 0.4840(3) 0.048(2) Uani 1 1 d . . .
O2 O 0.4147(6) 0.2419(5) 0.3799(4) 0.067(3) Uani 1 1 d . . .
O3 O 0.4696(11) 0.1763(6) 0.4867(5) 0.131(5) Uani 1 1 d . . .
N1 N 0.2665(5) 1.0300(4) 0.3138(3) 0.0256(17) Uani 1 1 d . . .
N2 N 0.2636(5) 0.9765(4) 0.1988(3) 0.0209(16) Uani 1 1 d . . .
N3 N -0.1572(5) 0.8926(4) 0.1780(4) 0.0244(17) Uani 1 1 d . . .
N4 N -0.1081(5) 1.0026(4) 0.2574(3) 0.0204(16) Uani 1 1 d . . .
N5 N 0.2468(5) 0.8308(4) 0.2744(3) 0.0212(16) Uani 1 1 d . . .
N6 N 0.5205(5) 0.7320(5) 0.3087(4) 0.0307(19) Uani 1 1 d . . .
C1 C 0.3535(6) 1.0160(5) 0.3057(4) 0.028(2) Uani 1 1 d . . .
C2 C 0.4373(7) 1.0364(6) 0.3565(5) 0.033(2) Uani 1 1 d . . .
H2 H 0.4261 1.0661 0.3910 0.040 Uiso 1 1 calc R . .
C3 C 0.5334(7) 1.0188(6) 0.3625(6) 0.046(3) Uani 1 1 d . . .
H3 H 0.5773 1.0390 0.4001 0.056 Uiso 1 1 calc R . .
C4 C 0.5740(7) 0.9758(7) 0.3212(6) 0.050(3) Uani 1 1 d . . .
H4 H 0.6400 0.9662 0.3372 0.060 Uiso 1 1 calc R . .
C5 C 0.5287(7) 0.9450(6) 0.2588(5) 0.042(3) Uani 1 1 d . . .
H5 H 0.5684 0.9178 0.2381 0.050 Uiso 1 1 calc R . .
C6 C 0.4345(7) 0.9496(6) 0.2241(5) 0.031(2) Uani 1 1 d . . .
H6 H 0.4214 0.9290 0.1809 0.037 Uiso 1 1 calc R . .
C7 C 0.3516(6) 0.9794(5) 0.2404(4) 0.0207(19) Uani 1 1 d . . .
C8 C 0.2516(7) 1.0690(5) 0.3739(4) 0.029(2) Uani 1 1 d . . .
H8A H 0.1863 1.0891 0.3629 0.035 Uiso 1 1 calc R . .
H8B H 0.2963 1.1106 0.3846 0.035 Uiso 1 1 calc R . .
C9 C 0.2662(8) 1.0182(6) 0.4381(4) 0.035(2) Uani 1 1 d . . .
H9 H 0.3268 0.9903 0.4436 0.042 Uiso 1 1 calc R . .
C10 C 0.2774(10) 1.0709(7) 0.5002(5) 0.061(4) Uani 1 1 d . . .
H10A H 0.2217 1.1028 0.4930 0.092 Uiso 1 1 calc R . .
H10B H 0.3346 1.1008 0.5054 0.092 Uiso 1 1 calc R . .
H10C H 0.2827 1.0416 0.5402 0.092 Uiso 1 1 calc R . .
C11 C 0.1846(9) 0.9629(7) 0.4324(5) 0.049(3) Uani 1 1 d . . .
H11A H 0.2038 0.9255 0.4669 0.074 Uiso 1 1 calc R . .
H11B H 0.1698 0.9396 0.3887 0.074 Uiso 1 1 calc R . .
H11C H 0.1283 0.9885 0.4381 0.074 Uiso 1 1 calc R . .
C12 C 0.2397(7) 0.9409(5) 0.1322(4) 0.027(2) Uani 1 1 d . . .
H12A H 0.1770 0.9172 0.1252 0.032 Uiso 1 1 calc R . .
H12B H 0.2869 0.9019 0.1327 0.032 Uiso 1 1 calc R . .
C13 C 0.2368(7) 0.9919(6) 0.0718(4) 0.031(2) Uani 1 1 d . . .
H13 H 0.1907 1.0323 0.0724 0.037 Uiso 1 1 calc R . .
C14 C 0.1992(7) 0.9478(6) 0.0070(4) 0.036(2) Uani 1 1 d . . .
H14A H 0.2000 0.9787 -0.0311 0.053 Uiso 1 1 calc R . .
H14B H 0.1341 0.9317 0.0037 0.053 Uiso 1 1 calc R . .
H14C H 0.2398 0.9050 0.0074 0.053 Uiso 1 1 calc R . .
C15 C 0.3350(7) 1.0271(6) 0.0750(4) 0.033(2) Uani 1 1 d . . .
H15A H 0.3784 0.9895 0.0666 0.049 Uiso 1 1 calc R . .
H15B H 0.3612 1.0483 0.1190 0.049 Uiso 1 1 calc R . .
H15C H 0.3273 1.0654 0.0413 0.049 Uiso 1 1 calc R . .
C16 C 0.0952(6) 1.0851(5) 0.2004(4) 0.023(2) Uani 1 1 d . . .
H16 H 0.0637 1.1069 0.2330 0.028 Uiso 1 1 calc R . .
C17 C 0.1660(7) 1.1435(5) 0.1874(5) 0.033(2) Uani 1 1 d . . .
H17A H 0.2031 1.1226 0.1590 0.050 Uiso 1 1 calc R . .
H17B H 0.2088 1.1586 0.2297 0.050 Uiso 1 1 calc R . .
H17C H 0.1306 1.1860 0.1654 0.050 Uiso 1 1 calc R . .
C18 C 0.0152(6) 1.0677(5) 0.1366(4) 0.031(2) Uani 1 1 d . . .
H18A H -0.0169 1.1131 0.1185 0.046 Uiso 1 1 calc R . .
H18B H -0.0308 1.0342 0.1477 0.046 Uiso 1 1 calc R . .
H18C H 0.0430 1.0448 0.1036 0.046 Uiso 1 1 calc R . .
C19 C -0.2202(6) 0.9495(5) 0.1645(4) 0.020(2) Uani 1 1 d . . .
C20 C -0.3116(6) 0.9422(5) 0.1180(4) 0.026(2) Uani 1 1 d . . .
H20 H -0.3266 0.8939 0.1021 0.031 Uiso 1 1 calc R . .
C21 C -0.3827(6) 0.9936(6) 0.0919(4) 0.028(2) Uani 1 1 d . . .
H21 H -0.4393 0.9744 0.0637 0.033 Uiso 1 1 calc R . .
C22 C -0.3820(7) 1.0714(6) 0.1018(4) 0.034(2) Uani 1 1 d . . .
H22 H -0.4364 1.0976 0.0781 0.041 Uiso 1 1 calc R . .
C23 C -0.3087(7) 1.1122(6) 0.1432(4) 0.032(2) Uani 1 1 d . . .
H23 H -0.3163 1.1637 0.1393 0.038 Uiso 1 1 calc R . .
C24 C -0.2252(7) 1.0885(5) 0.1897(4) 0.028(2) Uani 1 1 d . . .
H24 H -0.1881 1.1265 0.2146 0.033 Uiso 1 1 calc R . .
C25 C -0.1870(6) 1.0157(5) 0.2055(4) 0.023(2) Uani 1 1 d . . .
C26 C -0.1718(7) 0.8235(5) 0.1376(5) 0.030(2) Uani 1 1 d . . .
H26A H -0.2367 0.8052 0.1340 0.036 Uiso 1 1 calc R . .
H26B H -0.1267 0.7861 0.1615 0.036 Uiso 1 1 calc R . .
C27 C -0.1583(7) 0.8323(6) 0.0674(5) 0.036(2) Uani 1 1 d . . .
H27 H -0.1999 0.8736 0.0458 0.043 Uiso 1 1 calc R . .
C28 C -0.0546(7) 0.8538(6) 0.0696(5) 0.036(2) Uani 1 1 d . . .
H28A H -0.0112 0.8158 0.0927 0.054 Uiso 1 1 calc R . .
H28B H -0.0389 0.9004 0.0931 0.054 Uiso 1 1 calc R . .
H28C H -0.0482 0.8589 0.0243 0.054 Uiso 1 1 calc R . .
C29 C -0.1898(8) 0.7644(6) 0.0245(6) 0.050(3) Uani 1 1 d . . .
H29A H -0.1782 0.7719 -0.0192 0.075 Uiso 1 1 calc R . .
H29B H -0.2576 0.7559 0.0193 0.075 Uiso 1 1 calc R . .
H29C H -0.1536 0.7219 0.0459 0.075 Uiso 1 1 calc R . .
C30 C -0.0623(6) 1.0588(5) 0.3082(4) 0.025(2) Uani 1 1 d . . .
H30A H -0.0683 1.1070 0.2861 0.030 Uiso 1 1 calc R . .
H30B H 0.0063 1.0474 0.3236 0.030 Uiso 1 1 calc R . .
C31 C -0.1014(7) 1.0657(6) 0.3698(4) 0.029(2) Uani 1 1 d . . .
H31 H -0.0966 1.0173 0.3926 0.035 Uiso 1 1 calc R . .
C32 C -0.0374(8) 1.1243(7) 0.4188(6) 0.053(3) Uani 1 1 d . . .
H32A H 0.0277 1.1060 0.4341 0.079 Uiso 1 1 calc R . .
H32B H -0.0634 1.1321 0.4570 0.079 Uiso 1 1 calc R . .
H32C H -0.0375 1.1706 0.3953 0.079 Uiso 1 1 calc R . .
C33 C -0.2053(8) 1.0922(6) 0.3530(5) 0.041(3) Uani 1 1 d . . .
H33A H -0.2088 1.1425 0.3364 0.061 Uiso 1 1 calc R . .
H33B H -0.2285 1.0905 0.3930 0.061 Uiso 1 1 calc R . .
H33C H -0.2446 1.0604 0.3189 0.061 Uiso 1 1 calc R . .
C34 C -0.1045(7) 0.8459(5) 0.3246(5) 0.031(2) Uani 1 1 d . . .
H34 H -0.1095 0.7944 0.3080 0.037 Uiso 1 1 calc R . .
C35 C -0.0340(8) 0.8435(6) 0.3948(5) 0.045(3) Uani 1 1 d . . .
H35A H -0.0283 0.8924 0.4146 0.067 Uiso 1 1 calc R . .
H35B H 0.0284 0.8272 0.3911 0.067 Uiso 1 1 calc R . .
H35C H -0.0576 0.8094 0.4230 0.067 Uiso 1 1 calc R . .
C36 C -0.2068(7) 0.8680(6) 0.3266(6) 0.044(3) Uani 1 1 d . . .
H36A H -0.2288 0.8351 0.3565 0.065 Uiso 1 1 calc R . .
H36B H -0.2495 0.8645 0.2820 0.065 Uiso 1 1 calc R . .
H36C H -0.2064 0.9183 0.3427 0.065 Uiso 1 1 calc R . .
C37 C 0.3167(6) 0.8403(5) 0.3336(4) 0.024(2) Uani 1 1 d . . .
H37 H 0.3020 0.8696 0.3671 0.028 Uiso 1 1 calc R . .
C38 C 0.2715(7) 0.7865(5) 0.2294(4) 0.028(2) Uani 1 1 d . . .
H38 H 0.2251 0.7775 0.1890 0.034 Uiso 1 1 calc R . .
C39 C 0.4074(6) 0.8093(5) 0.3466(4) 0.024(2) Uani 1 1 d . . .
H39 H 0.4521 0.8180 0.3878 0.029 Uiso 1 1 calc R . .
C40 C 0.3591(7) 0.7536(5) 0.2379(4) 0.029(2) Uani 1 1 d . . .
H40 H 0.3706 0.7235 0.2039 0.035 Uiso 1 1 calc R . .
C41 C 0.4330(6) 0.7646(5) 0.2980(4) 0.0209(19) Uani 1 1 d . . .
C42 C 0.5940(7) 0.7437(6) 0.3714(4) 0.035(2) Uani 1 1 d . . .
H42A H 0.6000 0.7961 0.3814 0.053 Uiso 1 1 calc R . .
H42B H 0.6549 0.7247 0.3671 0.053 Uiso 1 1 calc R . .
H42C H 0.5760 0.7180 0.4074 0.053 Uiso 1 1 calc R . .
C43 C 0.5378(7) 0.6758(6) 0.2617(5) 0.039(3) Uani 1 1 d . . .
H43A H 0.4906 0.6367 0.2571 0.059 Uiso 1 1 calc R . .
H43B H 0.6016 0.6553 0.2788 0.059 Uiso 1 1 calc R . .
H43C H 0.5327 0.6983 0.2184 0.059 Uiso 1 1 calc R . .
C44 C 0.5869(9) 0.2491(9) 0.4503(6) 0.074(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N5 2.132(7) . ?
Pt1 Ge2 2.3412(11) . ?
Pt1 Ge1 2.3437(11) . ?
Pt1 Cl1 2.388(2) . ?
Ge1 N1 1.918(7) . ?
Ge1 N2 1.921(7) . ?
Ge1 C16 1.981(9) . ?
Ge2 N3 1.905(7) . ?
Ge2 N4 1.914(7) . ?
Ge2 C34 1.972(8) . ?
F1 C44 1.448(18) . ?
F2 C44 1.345(13) . ?
F3 C44 1.352(14) . ?
S1 O2 1.375(7) . ?
S1 O1 1.392(8) . ?
S1 O3 1.612(11) . ?
S1 C44 1.679(13) . ?
N1 C1 1.321(11) . ?
N1 C8 1.477(11) . ?
N2 C7 1.325(11) . ?
N2 C12 1.463(10) . ?
N3 C19 1.341(10) . ?
N3 C26 1.473(11) . ?
N4 C25 1.353(11) . ?
N4 C30 1.474(11) . ?
N5 C38 1.331(11) . ?
N5 C37 1.367(11) . ?
N6 C41 1.346(11) . ?
N6 C42 1.447(11) . ?
N6 C43 1.458(12) . ?
C1 C2 1.414(12) . ?
C1 C7 1.483(12) . ?
C2 C3 1.385(14) . ?
C2 H2 0.9300 . ?
C3 C4 1.379(15) . ?
C3 H3 0.9300 . ?
C4 C5 1.388(14) . ?
C4 H4 0.9300 . ?
C5 C6 1.352(13) . ?
C5 H5 0.9300 . ?
C6 C7 1.417(12) . ?
C6 H6 0.9300 . ?
C8 C9 1.567(12) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C11 1.513(15) . ?
C9 C10 1.559(13) . ?
C9 H9 0.9800 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 C13 1.530(12) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.518(12) . ?
C13 C15 1.526(13) . ?
C13 H13 0.9800 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 C17 1.526(12) . ?
C16 C18 1.527(12) . ?
C16 H16 0.9800 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.409(12) . ?
C19 C25 1.460(12) . ?
C20 C21 1.372(12) . ?
C20 H20 0.9300 . ?
C21 C22 1.408(14) . ?
C21 H21 0.9300 . ?
C22 C23 1.374(13) . ?
C22 H22 0.9300 . ?
C23 C24 1.386(13) . ?
C23 H23 0.9300 . ?
C24 C25 1.420(12) . ?
C24 H24 0.9300 . ?
C26 C27 1.507(13) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C29 1.501(13) . ?
C27 C28 1.521(13) . ?
C27 H27 0.9800 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 C31 1.511(11) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 C33 1.512(13) . ?
C31 C32 1.572(13) . ?
C31 H31 0.9800 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C34 C36 1.526(13) . ?
C34 C35 1.528(14) . ?
C34 H34 0.9800 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C37 C39 1.373(12) . ?
C37 H37 0.9300 . ?
C38 C40 1.353(12) . ?
C38 H38 0.9300 . ?
C39 C41 1.397(12) . ?
C39 H39 0.9300 . ?
C40 C41 1.411(12) . ?
C40 H40 0.9300 . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N5 Pt1 Ge2 168.89(18) . . ?
N5 Pt1 Ge1 89.73(19) . . ?
Ge2 Pt1 Ge1 99.92(4) . . ?
N5 Pt1 Cl1 85.9(2) . . ?
Ge2 Pt1 Cl1 85.32(6) . . ?
Ge1 Pt1 Cl1 170.41(6) . . ?
N1 Ge1 N2 82.5(3) . . ?
N1 Ge1 C16 103.7(3) . . ?
N2 Ge1 C16 105.4(3) . . ?
N1 Ge1 Pt1 115.4(2) . . ?
N2 Ge1 Pt1 105.5(2) . . ?
C16 Ge1 Pt1 132.4(3) . . ?
N3 Ge2 N4 83.2(3) . . ?
N3 Ge2 C34 102.1(4) . . ?
N4 Ge2 C34 106.9(3) . . ?
N3 Ge2 Pt1 120.5(2) . . ?
N4 Ge2 Pt1 125.9(2) . . ?
C34 Ge2 Pt1 113.0(3) . . ?
O2 S1 O1 122.4(5) . . ?
O2 S1 O3 108.3(7) . . ?
O1 S1 O3 110.7(6) . . ?
O2 S1 C44 110.3(6) . . ?
O1 S1 C44 108.0(6) . . ?
O3 S1 C44 93.2(9) . . ?
C1 N1 C8 122.6(7) . . ?
C1 N1 Ge1 114.5(6) . . ?
C8 N1 Ge1 122.8(6) . . ?
C7 N2 C12 124.6(7) . . ?
C7 N2 Ge1 113.9(5) . . ?
C12 N2 Ge1 118.7(5) . . ?
C19 N3 C26 122.3(7) . . ?
C19 N3 Ge2 114.5(6) . . ?
C26 N3 Ge2 122.9(6) . . ?
C25 N4 C30 124.1(7) . . ?
C25 N4 Ge2 114.5(6) . . ?
C30 N4 Ge2 121.3(5) . . ?
C38 N5 C37 115.1(7) . . ?
C38 N5 Pt1 122.8(6) . . ?
C37 N5 Pt1 121.9(5) . . ?
C41 N6 C42 120.8(8) . . ?
C41 N6 C43 120.2(8) . . ?
C42 N6 C43 118.4(8) . . ?
N1 C1 C2 120.3(8) . . ?
N1 C1 C7 113.6(8) . . ?
C2 C1 C7 126.1(8) . . ?
C3 C2 C1 129.6(9) . . ?
C3 C2 H2 115.2 . . ?
C1 C2 H2 115.2 . . ?
C4 C3 C2 129.8(10) . . ?
C4 C3 H3 115.1 . . ?
C2 C3 H3 115.1 . . ?
C3 C4 C5 128.1(10) . . ?
C3 C4 H4 116.0 . . ?
C5 C4 H4 116.0 . . ?
C6 C5 C4 128.5(10) . . ?
C6 C5 H5 115.8 . . ?
C4 C5 H5 115.8 . . ?
C5 C6 C7 132.8(9) . . ?
C5 C6 H6 113.6 . . ?
C7 C6 H6 113.6 . . ?
N2 C7 C6 123.1(8) . . ?
N2 C7 C1 112.8(7) . . ?
C6 C7 C1 124.1(8) . . ?
N1 C8 C9 114.0(8) . . ?
N1 C8 H8A 108.8 . . ?
C9 C8 H8A 108.8 . . ?
N1 C8 H8B 108.8 . . ?
C9 C8 H8B 108.8 . . ?
H8A C8 H8B 107.7 . . ?
C11 C9 C10 111.9(9) . . ?
C11 C9 C8 112.6(8) . . ?
C10 C9 C8 107.1(8) . . ?
C11 C9 H9 108.4 . . ?
C10 C9 H9 108.4 . . ?
C8 C9 H9 108.4 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N2 C12 C13 116.3(8) . . ?
N2 C12 H12A 108.2 . . ?
C13 C12 H12A 108.2 . . ?
N2 C12 H12B 108.2 . . ?
C13 C12 H12B 108.2 . . ?
H12A C12 H12B 107.4 . . ?
C14 C13 C15 111.4(8) . . ?
C14 C13 C12 108.9(8) . . ?
C15 C13 C12 112.4(7) . . ?
C14 C13 H13 108.0 . . ?
C15 C13 H13 108.0 . . ?
C12 C13 H13 108.0 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C17 C16 C18 112.0(7) . . ?
C17 C16 Ge1 112.4(6) . . ?
C18 C16 Ge1 111.6(6) . . ?
C17 C16 H16 106.8 . . ?
C18 C16 H16 106.8 . . ?
Ge1 C16 H16 106.8 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N3 C19 C20 121.6(8) . . ?
N3 C19 C25 113.6(8) . . ?
C20 C19 C25 124.7(8) . . ?
C21 C20 C19 131.5(9) . . ?
C21 C20 H20 114.2 . . ?
C19 C20 H20 114.2 . . ?
C20 C21 C22 129.2(9) . . ?
C20 C21 H21 115.4 . . ?
C22 C21 H21 115.4 . . ?
C23 C22 C21 126.3(9) . . ?
C23 C22 H22 116.9 . . ?
C21 C22 H22 116.9 . . ?
C22 C23 C24 130.0(10) . . ?
C22 C23 H23 115.0 . . ?
C24 C23 H23 115.0 . . ?
C23 C24 C25 130.5(9) . . ?
C23 C24 H24 114.7 . . ?
C25 C24 H24 114.7 . . ?
N4 C25 C24 122.1(8) . . ?
N4 C25 C19 112.9(8) . . ?
C24 C25 C19 124.6(8) . . ?
N3 C26 C27 114.4(8) . . ?
N3 C26 H26A 108.7 . . ?
C27 C26 H26A 108.7 . . ?
N3 C26 H26B 108.7 . . ?
C27 C26 H26B 108.7 . . ?
H26A C26 H26B 107.6 . . ?
C29 C27 C26 112.3(9) . . ?
C29 C27 C28 111.4(8) . . ?
C26 C27 C28 111.4(8) . . ?
C29 C27 H27 107.2 . . ?
C26 C27 H27 107.2 . . ?
C28 C27 H27 107.2 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
N4 C30 C31 116.9(7) . . ?
N4 C30 H30A 108.1 . . ?
C31 C30 H30A 108.1 . . ?
N4 C30 H30B 108.1 . . ?
C31 C30 H30B 108.1 . . ?
H30A C30 H30B 107.3 . . ?
C30 C31 C33 113.0(8) . . ?
C30 C31 C32 107.8(8) . . ?
C33 C31 C32 108.0(8) . . ?
C30 C31 H31 109.3 . . ?
C33 C31 H31 109.3 . . ?
C32 C31 H31 109.3 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C36 C34 C35 112.6(8) . . ?
C36 C34 Ge2 113.2(6) . . ?
C35 C34 Ge2 113.2(7) . . ?
C36 C34 H34 105.7 . . ?
C35 C34 H34 105.7 . . ?
Ge2 C34 H34 105.7 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N5 C37 C39 123.8(8) . . ?
N5 C37 H37 118.1 . . ?
C39 C37 H37 118.1 . . ?
N5 C38 C40 125.0(9) . . ?
N5 C38 H38 117.5 . . ?
C40 C38 H38 117.5 . . ?
C37 C39 C41 120.3(8) . . ?
C37 C39 H39 119.9 . . ?
C41 C39 H39 119.9 . . ?
C38 C40 C41 120.6(8) . . ?
C38 C40 H40 119.7 . . ?
C41 C40 H40 119.7 . . ?
N6 C41 C39 122.5(8) . . ?
N6 C41 C40 122.3(8) . . ?
C39 C41 C40 115.1(8) . . ?
N6 C42 H42A 109.5 . . ?
N6 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
N6 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
N6 C43 H43A 109.5 . . ?
N6 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
N6 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
F2 C44 F3 104.8(12) . . ?
F2 C44 F1 106.6(10) . . ?
F3 C44 F1 104.8(9) . . ?
F2 C44 S1 118.5(8) . . ?
F3 C44 S1 119.2(9) . . ?
F1 C44 S1 101.5(11) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N5 Pt1 Ge1 N1 -55.9(3) . . . . ?
Ge2 Pt1 Ge1 N1 118.6(2) . . . . ?
Cl1 Pt1 Ge1 N1 -118.9(4) . . . . ?
N5 Pt1 Ge1 N2 33.1(3) . . . . ?
Ge2 Pt1 Ge1 N2 -152.4(2) . . . . ?
Cl1 Pt1 Ge1 N2 -29.9(4) . . . . ?
N5 Pt1 Ge1 C16 161.9(4) . . . . ?
Ge2 Pt1 Ge1 C16 -23.7(3) . . . . ?
Cl1 Pt1 Ge1 C16 98.8(5) . . . . ?
N5 Pt1 Ge2 N3 -113.6(10) . . . . ?
Ge1 Pt1 Ge2 N3 96.5(3) . . . . ?
Cl1 Pt1 Ge2 N3 -75.4(3) . . . . ?
N5 Pt1 Ge2 N4 141.6(10) . . . . ?
Ge1 Pt1 Ge2 N4 -8.3(2) . . . . ?
Cl1 Pt1 Ge2 N4 179.8(3) . . . . ?
N5 Pt1 Ge2 C34 7.3(10) . . . . ?
Ge1 Pt1 Ge2 C34 -142.6(3) . . . . ?
Cl1 Pt1 Ge2 C34 45.5(3) . . . . ?
N2 Ge1 N1 C1 -10.3(7) . . . . ?
C16 Ge1 N1 C1 -114.4(7) . . . . ?
Pt1 Ge1 N1 C1 93.4(6) . . . . ?
N2 Ge1 N1 C8 171.2(7) . . . . ?
C16 Ge1 N1 C8 67.1(7) . . . . ?
Pt1 Ge1 N1 C8 -85.1(7) . . . . ?
N1 Ge1 N2 C7 15.2(6) . . . . ?
C16 Ge1 N2 C7 117.5(6) . . . . ?
Pt1 Ge1 N2 C7 -99.2(6) . . . . ?
N1 Ge1 N2 C12 177.1(7) . . . . ?
C16 Ge1 N2 C12 -80.6(7) . . . . ?
Pt1 Ge1 N2 C12 62.8(6) . . . . ?
N4 Ge2 N3 C19 -8.2(6) . . . . ?
C34 Ge2 N3 C19 97.7(6) . . . . ?
Pt1 Ge2 N3 C19 -136.2(5) . . . . ?
N4 Ge2 N3 C26 178.0(7) . . . . ?
C34 Ge2 N3 C26 -76.0(7) . . . . ?
Pt1 Ge2 N3 C26 50.1(7) . . . . ?
N3 Ge2 N4 C25 1.6(6) . . . . ?
C34 Ge2 N4 C25 -99.0(6) . . . . ?
Pt1 Ge2 N4 C25 124.6(5) . . . . ?
N3 Ge2 N4 C30 -176.5(6) . . . . ?
C34 Ge2 N4 C30 82.9(7) . . . . ?
Pt1 Ge2 N4 C30 -53.6(6) . . . . ?
Ge2 Pt1 N5 C38 100.8(11) . . . . ?
Ge1 Pt1 N5 C38 -108.8(7) . . . . ?
Cl1 Pt1 N5 C38 62.7(7) . . . . ?
Ge2 Pt1 N5 C37 -72.5(13) . . . . ?
Ge1 Pt1 N5 C37 77.9(6) . . . . ?
Cl1 Pt1 N5 C37 -110.7(6) . . . . ?
C8 N1 C1 C2 1.9(14) . . . . ?
Ge1 N1 C1 C2 -176.6(7) . . . . ?
C8 N1 C1 C7 -177.4(8) . . . . ?
Ge1 N1 C1 C7 4.1(10) . . . . ?
N1 C1 C2 C3 170.6(10) . . . . ?
C7 C1 C2 C3 -10.1(18) . . . . ?
C1 C2 C3 C4 -1(2) . . . . ?
C2 C3 C4 C5 7(2) . . . . ?
C3 C4 C5 C6 -1(2) . . . . ?
C4 C5 C6 C7 -6(2) . . . . ?
C12 N2 C7 C6 1.8(14) . . . . ?
Ge1 N2 C7 C6 162.4(7) . . . . ?
C12 N2 C7 C1 -177.4(8) . . . . ?
Ge1 N2 C7 C1 -16.7(10) . . . . ?
C5 C6 C7 N2 -178.3(11) . . . . ?
C5 C6 C7 C1 0.8(17) . . . . ?
N1 C1 C7 N2 8.3(12) . . . . ?
C2 C1 C7 N2 -171.0(9) . . . . ?
N1 C1 C7 C6 -170.8(8) . . . . ?
C2 C1 C7 C6 9.9(15) . . . . ?
C1 N1 C8 C9 -78.8(11) . . . . ?
Ge1 N1 C8 C9 99.5(8) . . . . ?
N1 C8 C9 C11 -72.6(10) . . . . ?
N1 C8 C9 C10 164.1(8) . . . . ?
C7 N2 C12 C13 -95.2(10) . . . . ?
Ge1 N2 C12 C13 105.0(8) . . . . ?
N2 C12 C13 C14 -173.2(7) . . . . ?
N2 C12 C13 C15 62.9(11) . . . . ?
N1 Ge1 C16 C17 46.8(7) . . . . ?
N2 Ge1 C16 C17 -39.1(7) . . . . ?
Pt1 Ge1 C16 C17 -168.0(5) . . . . ?
N1 Ge1 C16 C18 173.6(6) . . . . ?
N2 Ge1 C16 C18 87.7(6) . . . . ?
Pt1 Ge1 C16 C18 -41.1(7) . . . . ?
C26 N3 C19 C20 10.6(12) . . . . ?
Ge2 N3 C19 C20 -163.2(6) . . . . ?
C26 N3 C19 C25 -173.5(7) . . . . ?
Ge2 N3 C19 C25 12.7(9) . . . . ?
N3 C19 C20 C21 -173.1(8) . . . . ?
C25 C19 C20 C21 11.5(14) . . . . ?
C19 C20 C21 C22 3.9(15) . . . . ?
C20 C21 C22 C23 -2.8(15) . . . . ?
C21 C22 C23 C24 -8.0(16) . . . . ?
C22 C23 C24 C25 4.7(16) . . . . ?
C30 N4 C25 C24 9.3(12) . . . . ?
Ge2 N4 C25 C24 -168.9(6) . . . . ?
C30 N4 C25 C19 -177.3(7) . . . . ?
Ge2 N4 C25 C19 4.6(9) . . . . ?
C23 C24 C25 N4 -173.9(8) . . . . ?
C23 C24 C25 C19 13.5(15) . . . . ?
N3 C19 C25 N4 -11.2(10) . . . . ?
C20 C19 C25 N4 164.5(7) . . . . ?
N3 C19 C25 C24 162.0(8) . . . . ?
C20 C19 C25 C24 -22.2(13) . . . . ?
C19 N3 C26 C27 70.9(11) . . . . ?
Ge2 N3 C26 C27 -115.8(8) . . . . ?
N3 C26 C27 C29 -170.4(8) . . . . ?
N3 C26 C27 C28 63.9(11) . . . . ?
C25 N4 C30 C31 87.7(10) . . . . ?
Ge2 N4 C30 C31 -94.3(8) . . . . ?
N4 C30 C31 C33 -64.6(11) . . . . ?
N4 C30 C31 C32 176.1(8) . . . . ?
N3 Ge2 C34 C36 -52.3(8) . . . . ?
N4 Ge2 C34 C36 34.2(8) . . . . ?
Pt1 Ge2 C34 C36 176.8(6) . . . . ?
N3 Ge2 C34 C35 178.0(7) . . . . ?
N4 Ge2 C34 C35 -95.5(7) . . . . ?
Pt1 Ge2 C34 C35 47.2(8) . . . . ?
C38 N5 C37 C39 2.0(12) . . . . ?
Pt1 N5 C37 C39 175.8(6) . . . . ?
C37 N5 C38 C40 -1.9(13) . . . . ?
Pt1 N5 C38 C40 -175.7(7) . . . . ?
N5 C37 C39 C41 -0.3(13) . . . . ?
N5 C38 C40 C41 0.2(15) . . . . ?
C42 N6 C41 C39 -1.6(13) . . . . ?
C43 N6 C41 C39 169.1(8) . . . . ?
C42 N6 C41 C40 -179.0(8) . . . . ?
C43 N6 C41 C40 -8.3(13) . . . . ?
C37 C39 C41 N6 -179.0(8) . . . . ?
C37 C39 C41 C40 -1.4(12) . . . . ?
C38 C40 C41 N6 179.1(8) . . . . ?
C38 C40 C41 C39 1.5(13) . . . . ?
O2 S1 C44 F2 -176.1(11) . . . . ?
O1 S1 C44 F2 47.8(15) . . . . ?
O3 S1 C44 F2 -65.2(13) . . . . ?
O2 S1 C44 F3 -46.7(15) . . . . ?
O1 S1 C44 F3 177.2(10) . . . . ?
O3 S1 C44 F3 64.2(12) . . . . ?
O2 S1 C44 F1 67.6(9) . . . . ?
O1 S1 C44 F1 -68.5(8) . . . . ?
O3 S1 C44 F1 178.5(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         2.524
_refine_diff_density_min         -2.284
_refine_diff_density_rms         0.191
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_msha27m
_database_code_depnum_ccdc_archive 'CCDC 1585660'
_audit_update_record             
;
2017-11-14 deposited with the CCDC.
2018-03-06 downloaded from the CCDC.
;
_audit_creation_date             2017-11-13
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5337)
;
_shelxl_version_number           2013-4
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C38 H60 Ge2 N6 Pt'
_chemical_formula_sum            'C38 H60 Ge2 N6 Pt'
_chemical_formula_weight         941.22
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.9108(16)
_cell_length_b                   12.3525(16)
_cell_length_c                   17.527(2)
_cell_angle_alpha                72.036(2)
_cell_angle_beta                 80.201(2)
_cell_angle_gamma                75.546(3)
_cell_volume                     2363.2(5)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    2966
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      24.88
_cell_measurement_theta_min      2.26
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    4.244
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  0.714604
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS v.2.03 (Bruker,200?) was used for absorption correction.
R(int) was 0.0552 before and 0.0347 after correction.
The Ratio of minimum to maximum transmission is 0.7146.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.323
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             944
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.15
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   0.529
_exptl_transmission_factor_min   0.445
_diffrn_reflns_av_R_equivalents  0.0430
_diffrn_reflns_av_unetI/netI     0.0935
_diffrn_reflns_Laue_measured_fraction_full 0.956
_diffrn_reflns_Laue_measured_fraction_max 0.978
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            12332
_diffrn_reflns_point_group_measured_fraction_full 0.956
_diffrn_reflns_point_group_measured_fraction_max 0.978
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.032
_diffrn_reflns_theta_min         1.775
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.956
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6362
_reflns_number_total             8173
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v6.28A (Bruker, 2002)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v6.28A (Bruker, 2002)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    
;
Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
Palatinus et al., 2012)
;
_refine_diff_density_max         2.356
_refine_diff_density_min         -4.112
_refine_diff_density_rms         0.186
_refine_ls_extinction_coef       0.00048(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     422
_refine_ls_number_reflns         8173
_refine_ls_number_restraints     373
_refine_ls_R_factor_all          0.0798
_refine_ls_R_factor_gt           0.0608
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0574P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1260
_refine_ls_wR_factor_ref         0.1327
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C16-C17
 1.65 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C17) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C16) = Uanis(C18)
Uanis(C31) = Uanis(C32)
Uanis(C27) = Uanis(C31)
4. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5.a Ternary CH refined with riding coordinates:
 C32(H32), C28(H28), C13(H13), C9(H9), C35(H35), C16(H16)
5.b Secondary CH2 refined with riding coordinates:
 C12(H12A,H12B), C31(H31A,H31B), C8(H8A,H8B), C27(H27A,H27B)
5.c Aromatic/amide H refined with riding coordinates:
 C6(H6), C21(H21), C2(H2), C5(H5), C4(H4), C23(H23), C3(H3), C22(H22),
 C25(H25), C24(H24)
5.d Idealised Me refined as rotating group:
 C37(H37A,H37B,H37C), C34(H34A,H34B,H34C), C29(H29A,H29B,H29C), C36(H36A,H36B,
 H36C), C10(H10A,H10B,H10C), C33(H33A,H33B,H33C), C15(H15A,H15B,H15C), C30(H30A,
 H30B,H30C), C11(H11A,H11B,H11C), C14(H14A,H14B,H14C), C18(H18A,H18B,H18C),
 C17(H17A,H17B,H17C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt2 Pt 0.5000 1.0000 0.5000 0.01107(15) Uani 1 2 d S TU P . .
Pt1 Pt 0.0000 0.5000 0.0000 0.01898(16) Uani 1 2 d S TU P . .
Ge1 Ge 0.20259(8) 0.47000(8) 0.01488(6) 0.0200(2) Uani 1 1 d . U . . .
Ge2 Ge 0.39772(7) 0.84469(7) 0.52840(5) 0.0127(2) Uani 1 1 d . U . . .
N5 N 0.2898(6) 0.8514(6) 0.4569(4) 0.0136(14) Uani 1 1 d . U . . .
N4 N 0.2626(6) 0.8410(6) 0.6057(4) 0.0124(14) Uani 1 1 d . U . . .
N2 N 0.2726(6) 0.3521(6) 0.1033(4) 0.0198(16) Uani 1 1 d . U . . .
N1 N 0.3074(6) 0.3753(6) -0.0467(4) 0.0190(16) Uani 1 1 d . U . . .
N6 N 0.6198(7) 0.8584(6) 0.6574(5) 0.0233(18) Uani 1 1 d . U . . .
N3 N -0.0613(7) 0.3270(7) 0.1660(5) 0.031(2) Uani 1 1 d . U . . .
C37 C 0.6065(7) 0.6645(8) 0.5132(6) 0.026(2) Uani 1 1 d . U . . .
H37A H 0.5932 0.6659 0.4603 0.039 Uiso 1 1 calc GR . . . .
H37B H 0.6547 0.5910 0.5377 0.039 Uiso 1 1 calc GR . . . .
H37C H 0.6448 0.7262 0.5090 0.039 Uiso 1 1 calc GR . . . .
C12 C 0.2265(9) 0.3488(8) 0.1866(5) 0.028(2) Uani 1 1 d . U . . .
H12A H 0.2653 0.2769 0.2221 0.034 Uiso 1 1 calc R . . . .
H12B H 0.1442 0.3482 0.1932 0.034 Uiso 1 1 calc R . . . .
C31 C 0.3270(8) 0.8684(8) 0.3703(5) 0.0209(11) Uani 1 1 d . U . . .
H31A H 0.3857 0.9154 0.3547 0.025 Uiso 1 1 calc R . . . .
H31B H 0.2608 0.9116 0.3404 0.025 Uiso 1 1 calc R . . . .
C1 C 0.3816(7) 0.2851(7) -0.0051(5) 0.0183(18) Uani 1 1 d . U . . .
C26 C 0.1820(7) 0.8491(7) 0.4910(5) 0.0144(17) Uani 1 1 d . U . . .
C7 C 0.3600(8) 0.2715(7) 0.0820(5) 0.0213(19) Uani 1 1 d . U . . .
C8 C 0.3051(8) 0.4043(8) -0.1341(5) 0.022(2) Uani 1 1 d . U . . .
H8A H 0.3833 0.4097 -0.1594 0.027 Uiso 1 1 calc R . . . .
H8B H 0.2556 0.4809 -0.1516 0.027 Uiso 1 1 calc R . . . .
C27 C 0.2686(8) 0.8350(8) 0.6897(5) 0.0209(11) Uani 1 1 d . U . . .
H27A H 0.3498 0.8166 0.6997 0.025 Uiso 1 1 calc R . . . .
H27B H 0.2330 0.7722 0.7247 0.025 Uiso 1 1 calc R . . . .
C34 C 0.4264(9) 0.7888(9) 0.2584(6) 0.038(3) Uani 1 1 d . U . . .
H34A H 0.3657 0.8350 0.2251 0.057 Uiso 1 1 calc GR . . . .
H34B H 0.4597 0.7186 0.2427 0.057 Uiso 1 1 calc GR . . . .
H34C H 0.4857 0.8320 0.2519 0.057 Uiso 1 1 calc GR . . . .
C29 C 0.2697(8) 1.0477(8) 0.6694(6) 0.025(2) Uani 1 1 d . U . . .
H29A H 0.3466 1.0285 0.6862 0.037 Uiso 1 1 calc GR . . . .
H29B H 0.2263 1.1170 0.6831 0.037 Uiso 1 1 calc GR . . . .
H29C H 0.2752 1.0606 0.6122 0.037 Uiso 1 1 calc GR . . . .
C6 C 0.4208(8) 0.1772(8) 0.1415(6) 0.026(2) Uani 1 1 d . U . . .
H6 H 0.3940 0.1767 0.1946 0.032 Uiso 1 1 calc R . . . .
C20 C 0.1656(7) 0.8393(7) 0.5781(5) 0.0161(17) Uani 1 1 d . U . . .
C36 C 0.4188(8) 0.5888(8) 0.5730(6) 0.029(2) Uani 1 1 d . U . . .
H36A H 0.3476 0.6031 0.6069 0.044 Uiso 1 1 calc GR . . . .
H36B H 0.4637 0.5128 0.5965 0.044 Uiso 1 1 calc GR . . . .
H36C H 0.4011 0.5928 0.5206 0.044 Uiso 1 1 calc GR . . . .
C21 C 0.0642(7) 0.8205(7) 0.6302(6) 0.022(2) Uani 1 1 d . U . . .
H21 H 0.0734 0.8041 0.6845 0.027 Uiso 1 1 calc R . . . .
C10 C 0.2575(12) 0.3695(12) -0.2567(7) 0.067(4) Uani 1 1 d . U . . .
H10A H 0.1971 0.4386 -0.2676 0.100 Uiso 1 1 calc GR . . . .
H10B H 0.2411 0.3127 -0.2778 0.100 Uiso 1 1 calc GR . . . .
H10C H 0.3311 0.3882 -0.2817 0.100 Uiso 1 1 calc GR . . . .
C33 C 0.2883(8) 0.6803(8) 0.3589(6) 0.029(2) Uani 1 1 d . U . . .
H33A H 0.2589 0.6588 0.4147 0.044 Uiso 1 1 calc GR . . . .
H33B H 0.3263 0.6114 0.3427 0.044 Uiso 1 1 calc GR . . . .
H33C H 0.2249 0.7220 0.3269 0.044 Uiso 1 1 calc GR . . . .
C2 C 0.4726(8) 0.2168(8) -0.0421(6) 0.030(2) Uani 1 1 d . U . . .
H2 H 0.4762 0.2407 -0.0981 0.037 Uiso 1 1 calc R . . . .
C5 C 0.5128(8) 0.0870(8) 0.1325(6) 0.028(2) Uani 1 1 d . U . . .
H5 H 0.5361 0.0350 0.1809 0.034 Uiso 1 1 calc R . . . .
C32 C 0.3757(8) 0.7579(8) 0.3466(5) 0.0209(11) Uani 1 1 d . U . . .
H32 H 0.4398 0.7131 0.3793 0.025 Uiso 1 1 calc R . . . .
C15 C 0.1703(13) 0.4502(11) 0.2963(7) 0.067(4) Uani 1 1 d . U . . .
H15A H 0.0891 0.4594 0.2915 0.100 Uiso 1 1 calc GR . . . .
H15B H 0.1812 0.5131 0.3135 0.100 Uiso 1 1 calc GR . . . .
H15C H 0.1966 0.3776 0.3352 0.100 Uiso 1 1 calc GR . . . .
C4 C 0.5758(8) 0.0600(8) 0.0657(6) 0.033(2) Uani 1 1 d . U . . .
H4 H 0.6360 -0.0056 0.0742 0.039 Uiso 1 1 calc R . . . .
C23 C -0.0918(8) 0.8443(8) 0.5438(6) 0.024(2) Uani 1 1 d . U . . .
H23 H -0.1710 0.8466 0.5465 0.029 Uiso 1 1 calc R . . . .
C30 C 0.1956(8) 0.9246(10) 0.8044(6) 0.038(3) Uani 1 1 d . U . . .
H30A H 0.1472 0.8690 0.8289 0.056 Uiso 1 1 calc GR . . . .
H30B H 0.1607 0.9960 0.8180 0.056 Uiso 1 1 calc GR . . . .
H30C H 0.2712 0.8945 0.8237 0.056 Uiso 1 1 calc GR . . . .
C3 C 0.5588(9) 0.1204(8) -0.0124(6) 0.034(2) Uani 1 1 d . U . . .
H3 H 0.6122 0.0933 -0.0512 0.041 Uiso 1 1 calc R . . . .
C22 C -0.0457(8) 0.8220(8) 0.6153(6) 0.023(2) Uani 1 1 d . U . . .
H22 H -0.0977 0.8052 0.6612 0.028 Uiso 1 1 calc R . . . .
C28 C 0.2082(7) 0.9478(8) 0.7118(5) 0.0216(19) Uani 1 1 d . U . . .
H28 H 0.1295 0.9706 0.6946 0.026 Uiso 1 1 calc R . . . .
C25 C 0.0876(7) 0.8628(7) 0.4460(5) 0.0189(19) Uani 1 1 d . U . . .
H25 H 0.1092 0.8734 0.3911 0.023 Uiso 1 1 calc R . . . .
C24 C -0.0298(8) 0.8635(7) 0.4681(6) 0.024(2) Uani 1 1 d . U . . .
H24 H -0.0740 0.8793 0.4255 0.028 Uiso 1 1 calc R . . . .
C11 C 0.1478(10) 0.2976(11) -0.1267(7) 0.055(3) Uani 1 1 d . U . . .
H11A H 0.1466 0.2804 -0.0693 0.082 Uiso 1 1 calc GR . . . .
H11B H 0.1335 0.2324 -0.1396 0.082 Uiso 1 1 calc GR . . . .
H11C H 0.0884 0.3651 -0.1457 0.082 Uiso 1 1 calc GR . . . .
C38 C 0.5754(7) 0.9114(7) 0.5995(5) 0.0162(19) Uani 1 1 d . U . . .
C19 C -0.0370(8) 0.3900(7) 0.1047(5) 0.023(2) Uani 1 1 d . U . . .
C13 C 0.2421(11) 0.4507(10) 0.2124(7) 0.045(3) Uani 1 1 d . U . . .
H13 H 0.2139 0.5239 0.1723 0.054 Uiso 1 1 calc R . . . .
C9 C 0.2625(10) 0.3201(10) -0.1656(6) 0.042(3) Uani 1 1 d . U . . .
H9 H 0.3193 0.2459 -0.1554 0.050 Uiso 1 1 calc R . . . .
C14 C 0.3745(11) 0.4368(11) 0.2178(7) 0.059(3) Uani 1 1 d . U . . .
H14A H 0.3990 0.3723 0.2631 0.089 Uiso 1 1 calc GR . . . .
H14B H 0.3878 0.5067 0.2245 0.089 Uiso 1 1 calc GR . . . .
H14C H 0.4182 0.4228 0.1693 0.089 Uiso 1 1 calc GR . . . .
C35 C 0.4895(7) 0.6811(7) 0.5650(5) 0.0109(17) Uani 1 1 d . U . . .
H35 H 0.5083 0.6709 0.6195 0.013 Uiso 1 1 calc R . . . .
C18 C 0.1881(9) 0.7108(8) 0.0146(7) 0.0374(19) Uani 1 1 d . U . . .
H18A H 0.1212 0.7308 -0.0146 0.056 Uiso 1 1 calc GR . . . .
H18B H 0.2251 0.7761 0.0002 0.056 Uiso 1 1 calc GR . . . .
H18C H 0.1641 0.6909 0.0715 0.056 Uiso 1 1 calc GR . . . .
C16 C 0.2737(9) 0.6074(8) -0.0063(7) 0.0374(19) Uani 1 1 d D U . . .
H16 H 0.3277 0.5823 0.0353 0.045 Uiso 1 1 calc R . . . .
C17 C 0.3527(14) 0.6314(13) -0.0834(10) 0.102(6) Uani 1 1 d D U . . .
H17A H 0.4115 0.5627 -0.0849 0.153 Uiso 1 1 calc GR . . . .
H17B H 0.3891 0.6938 -0.0861 0.153 Uiso 1 1 calc GR . . . .
H17C H 0.3079 0.6530 -0.1285 0.153 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt2 Ge2 2.4049(9) 2_676 ?
Pt2 Ge2 2.4049(9) . ?
Pt2 C38 1.977(9) 2_676 ?
Pt2 C38 1.977(9) . ?
Pt1 Ge1 2.3950(10) 2_565 ?
Pt1 Ge1 2.3950(10) . ?
Pt1 C19 1.974(9) 2_565 ?
Pt1 C19 1.974(9) . ?
Ge1 N2 1.912(7) . ?
Ge1 N1 1.920(7) . ?
Ge1 C16 1.989(10) . ?
Ge2 N5 1.914(7) . ?
Ge2 N4 1.920(6) . ?
Ge2 C35 2.006(7) . ?
N5 C31 1.471(10) . ?
N5 C26 1.324(10) . ?
N4 C27 1.464(10) . ?
N4 C20 1.334(11) . ?
N2 C12 1.462(11) . ?
N2 C7 1.340(11) . ?
N1 C1 1.334(10) . ?
N1 C8 1.464(11) . ?
N6 C38 1.157(10) . ?
N3 C19 1.155(11) . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C37 C35 1.533(11) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 C13 1.523(14) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C31 C32 1.498(12) . ?
C1 C7 1.467(12) . ?
C1 C2 1.396(12) . ?
C26 C20 1.477(12) . ?
C26 C25 1.428(12) . ?
C7 C6 1.433(12) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 C9 1.536(14) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C27 C28 1.531(12) . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C34 C32 1.528(12) . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C29 C28 1.521(12) . ?
C6 H6 0.9300 . ?
C6 C5 1.381(13) . ?
C20 C21 1.406(11) . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C36 C35 1.539(12) . ?
C21 H21 0.9300 . ?
C21 C22 1.372(13) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C10 C9 1.528(14) . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C33 C32 1.531(13) . ?
C2 H2 0.9300 . ?
C2 C3 1.391(12) . ?
C5 H5 0.9300 . ?
C5 C4 1.365(14) . ?
C32 H32 0.9800 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C15 C13 1.569(14) . ?
C4 H4 0.9300 . ?
C4 C3 1.364(13) . ?
C23 H23 0.9300 . ?
C23 C22 1.377(13) . ?
C23 C24 1.385(12) . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C30 C28 1.545(13) . ?
C3 H3 0.9300 . ?
C22 H22 0.9300 . ?
C28 H28 0.9800 . ?
C25 H25 0.9300 . ?
C25 C24 1.385(12) . ?
C24 H24 0.9300 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C11 C9 1.473(15) . ?
C13 H13 0.9800 . ?
C13 C14 1.560(16) . ?
C9 H9 0.9800 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C35 H35 0.9800 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C18 C16 1.522(13) . ?
C16 H16 0.9800 . ?
C16 C17 1.504(13) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge2 Pt2 Ge2 180.00(3) . 2_676 ?
C38 Pt2 Ge2 86.5(2) . . ?
C38 Pt2 Ge2 86.5(2) 2_676 2_676 ?
C38 Pt2 Ge2 93.5(2) 2_676 . ?
C38 Pt2 Ge2 93.5(2) . 2_676 ?
C38 Pt2 C38 180.0 . 2_676 ?
Ge1 Pt1 Ge1 180.0 . 2_565 ?
C19 Pt1 Ge1 95.4(3) . . ?
C19 Pt1 Ge1 84.6(3) . 2_565 ?
C19 Pt1 Ge1 84.6(3) 2_565 . ?
C19 Pt1 Ge1 95.4(3) 2_565 2_565 ?
C19 Pt1 C19 180.0 2_565 . ?
N2 Ge1 Pt1 121.3(2) . . ?
N2 Ge1 N1 82.5(3) . . ?
N2 Ge1 C16 107.5(4) . . ?
N1 Ge1 Pt1 115.6(2) . . ?
N1 Ge1 C16 103.8(4) . . ?
C16 Ge1 Pt1 119.2(3) . . ?
N5 Ge2 Pt2 119.7(2) . . ?
N5 Ge2 N4 83.0(3) . . ?
N5 Ge2 C35 109.5(3) . . ?
N4 Ge2 Pt2 119.6(2) . . ?
N4 Ge2 C35 101.6(3) . . ?
C35 Ge2 Pt2 117.5(2) . . ?
C31 N5 Ge2 120.0(5) . . ?
C26 N5 Ge2 114.5(6) . . ?
C26 N5 C31 125.3(7) . . ?
C27 N4 Ge2 121.6(6) . . ?
C20 N4 Ge2 115.2(6) . . ?
C20 N4 C27 123.1(7) . . ?
C12 N2 Ge1 121.1(6) . . ?
C7 N2 Ge1 114.6(6) . . ?
C7 N2 C12 124.1(7) . . ?
C1 N1 Ge1 115.8(6) . . ?
C1 N1 C8 123.6(7) . . ?
C8 N1 Ge1 120.6(5) . . ?
H37A C37 H37B 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C35 C37 H37A 109.5 . . ?
C35 C37 H37B 109.5 . . ?
C35 C37 H37C 109.5 . . ?
N2 C12 H12A 108.8 . . ?
N2 C12 H12B 108.8 . . ?
N2 C12 C13 113.8(8) . . ?
H12A C12 H12B 107.7 . . ?
C13 C12 H12A 108.8 . . ?
C13 C12 H12B 108.8 . . ?
N5 C31 H31A 108.6 . . ?
N5 C31 H31B 108.6 . . ?
N5 C31 C32 114.5(7) . . ?
H31A C31 H31B 107.6 . . ?
C32 C31 H31A 108.6 . . ?
C32 C31 H31B 108.6 . . ?
N1 C1 C7 112.3(8) . . ?
N1 C1 C2 122.7(8) . . ?
C2 C1 C7 124.9(8) . . ?
N5 C26 C20 114.8(8) . . ?
N5 C26 C25 122.5(8) . . ?
C25 C26 C20 122.6(8) . . ?
N2 C7 C1 114.4(8) . . ?
N2 C7 C6 121.2(8) . . ?
C6 C7 C1 124.3(8) . . ?
N1 C8 H8A 108.1 . . ?
N1 C8 H8B 108.1 . . ?
N1 C8 C9 116.8(8) . . ?
H8A C8 H8B 107.3 . . ?
C9 C8 H8A 108.1 . . ?
C9 C8 H8B 108.1 . . ?
N4 C27 H27A 108.8 . . ?
N4 C27 H27B 108.8 . . ?
N4 C27 C28 113.7(7) . . ?
H27A C27 H27B 107.7 . . ?
C28 C27 H27A 108.8 . . ?
C28 C27 H27B 108.8 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C32 C34 H34A 109.5 . . ?
C32 C34 H34B 109.5 . . ?
C32 C34 H34C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
C7 C6 H6 114.9 . . ?
C5 C6 C7 130.3(9) . . ?
C5 C6 H6 114.9 . . ?
N4 C20 C26 112.4(7) . . ?
N4 C20 C21 121.5(8) . . ?
C21 C20 C26 125.9(8) . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
C20 C21 H21 114.2 . . ?
C22 C21 C20 131.7(9) . . ?
C22 C21 H21 114.2 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33B 109.5 . . ?
C32 C33 H33C 109.5 . . ?
C1 C2 H2 113.4 . . ?
C3 C2 C1 133.1(10) . . ?
C3 C2 H2 113.4 . . ?
C6 C5 H5 114.0 . . ?
C4 C5 C6 131.9(9) . . ?
C4 C5 H5 114.0 . . ?
C31 C32 C34 108.6(7) . . ?
C31 C32 C33 114.7(7) . . ?
C31 C32 H32 107.9 . . ?
C34 C32 C33 109.8(8) . . ?
C34 C32 H32 107.9 . . ?
C33 C32 H32 107.9 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
C5 C4 H4 117.0 . . ?
C5 C4 C3 126.1(9) . . ?
C3 C4 H4 117.0 . . ?
C22 C23 H23 117.3 . . ?
C22 C23 C24 125.3(9) . . ?
C24 C23 H23 117.3 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
C2 C3 H3 115.5 . . ?
C4 C3 C2 128.9(10) . . ?
C4 C3 H3 115.5 . . ?
C21 C22 C23 130.7(9) . . ?
C21 C22 H22 114.7 . . ?
C23 C22 H22 114.7 . . ?
C27 C28 C30 109.6(8) . . ?
C27 C28 H28 107.6 . . ?
C29 C28 C27 112.8(7) . . ?
C29 C28 C30 111.5(8) . . ?
C29 C28 H28 107.6 . . ?
C30 C28 H28 107.6 . . ?
C26 C25 H25 113.7 . . ?
C24 C25 C26 132.6(9) . . ?
C24 C25 H25 113.7 . . ?
C23 C24 H24 114.9 . . ?
C25 C24 C23 130.1(9) . . ?
C25 C24 H24 114.9 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
N6 C38 Pt2 179.3(8) . . ?
N3 C19 Pt1 178.4(8) . . ?
C12 C13 C15 109.0(8) . . ?
C12 C13 H13 109.6 . . ?
C12 C13 C14 108.2(10) . . ?
C15 C13 H13 109.6 . . ?
C14 C13 C15 110.8(10) . . ?
C14 C13 H13 109.6 . . ?
C8 C9 H9 108.3 . . ?
C10 C9 C8 109.1(9) . . ?
C10 C9 H9 108.3 . . ?
C11 C9 C8 113.3(9) . . ?
C11 C9 C10 109.5(10) . . ?
C11 C9 H9 108.3 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Ge2 C35 H35 106.2 . . ?
C37 C35 Ge2 111.0(5) . . ?
C37 C35 C36 113.6(7) . . ?
C37 C35 H35 106.2 . . ?
C36 C35 Ge2 113.0(6) . . ?
C36 C35 H35 106.2 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
Ge1 C16 H16 103.0 . . ?
C18 C16 Ge1 112.8(7) . . ?
C18 C16 H16 103.0 . . ?
C17 C16 Ge1 115.1(9) . . ?
C17 C16 C18 117.5(10) . . ?
C17 C16 H16 103.0 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ge1 N2 C12 C13 -67.3(11) . . . . ?
Ge1 N2 C7 C1 -3.1(10) . . . . ?
Ge1 N2 C7 C6 -179.7(7) . . . . ?
Ge1 N1 C1 C7 5.1(10) . . . . ?
Ge1 N1 C1 C2 -171.8(7) . . . . ?
Ge1 N1 C8 C9 -112.0(8) . . . . ?
Ge2 N5 C31 C32 90.1(8) . . . . ?
Ge2 N5 C26 C20 -1.2(9) . . . . ?
Ge2 N5 C26 C25 174.8(6) . . . . ?
Ge2 N4 C27 C28 109.2(7) . . . . ?
Ge2 N4 C20 C26 -4.1(9) . . . . ?
Ge2 N4 C20 C21 171.2(6) . . . . ?
N5 C31 C32 C34 -172.0(8) . . . . ?
N5 C31 C32 C33 64.8(10) . . . . ?
N5 C26 C20 N4 3.5(10) . . . . ?
N5 C26 C20 C21 -171.5(8) . . . . ?
N5 C26 C25 C24 -180.0(9) . . . . ?
N4 C27 C28 C29 -67.5(10) . . . . ?
N4 C27 C28 C30 167.7(7) . . . . ?
N4 C20 C21 C22 175.5(9) . . . . ?
N2 C12 C13 C15 169.8(9) . . . . ?
N2 C12 C13 C14 -69.5(11) . . . . ?
N2 C7 C6 C5 -179.2(10) . . . . ?
N1 C1 C7 N2 -1.2(11) . . . . ?
N1 C1 C7 C6 175.2(8) . . . . ?
N1 C1 C2 C3 -179.6(11) . . . . ?
N1 C8 C9 C10 175.7(9) . . . . ?
N1 C8 C9 C11 53.4(13) . . . . ?
C12 N2 C7 C1 172.8(8) . . . . ?
C12 N2 C7 C6 -3.8(14) . . . . ?
C31 N5 C26 C20 -175.8(7) . . . . ?
C31 N5 C26 C25 0.2(12) . . . . ?
C1 N1 C8 C9 69.3(12) . . . . ?
C1 C7 C6 C5 4.5(16) . . . . ?
C1 C2 C3 C4 3(2) . . . . ?
C26 N5 C31 C32 -95.6(10) . . . . ?
C26 C20 C21 C22 -9.9(16) . . . . ?
C26 C25 C24 C23 -4.0(17) . . . . ?
C7 N2 C12 C13 117.0(10) . . . . ?
C7 C1 C2 C3 3.9(18) . . . . ?
C7 C6 C5 C4 1.4(19) . . . . ?
C8 N1 C1 C7 -176.2(8) . . . . ?
C8 N1 C1 C2 6.9(14) . . . . ?
C27 N4 C20 C26 178.7(7) . . . . ?
C27 N4 C20 C21 -6.1(12) . . . . ?
C6 C5 C4 C3 -1.1(19) . . . . ?
C20 N4 C27 C28 -73.8(10) . . . . ?
C20 C26 C25 C24 -4.3(15) . . . . ?
C20 C21 C22 C23 -1.0(17) . . . . ?
C2 C1 C7 N2 175.6(9) . . . . ?
C2 C1 C7 C6 -8.0(15) . . . . ?
C5 C4 C3 C2 -3.7(19) . . . . ?
C22 C23 C24 C25 1.6(16) . . . . ?
C25 C26 C20 N4 -172.5(7) . . . . ?
C25 C26 C20 C21 12.5(13) . . . . ?
C24 C23 C22 C21 4.7(16) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.000 -0.154 0.154 519.3 270.0 ?

_olex2_submission_special_instructions 'No special instructions were received'
