# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2136lm
_audit_block_doi                 10.5517/cc14grcq
_database_code_depnum_ccdc_archive 'CCDC 1056863'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1039/C5CC07018J 2015
_audit_update_record             
;
2015-03-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'compound 8' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_formula_weight         1057.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 2'
_symmetry_space_group_name_Hall  'P 2 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'

_cell_length_a                   10.8177(7)
_cell_length_b                   18.8289(12)
_cell_length_c                   7.6272(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     1553.55(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    3738
_cell_measurement_theta_min      2.16
_cell_measurement_theta_max      28.50

_exptl_crystal_description       prism
_exptl_crystal_colour            brown-yellow
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.260
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1004
_exptl_absorpt_coefficient_mu    10.535
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.0844
_exptl_absorpt_correction_T_max  0.5311
_exptl_absorpt_process_details   'SADABS, Bruker 2008'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            15326
_diffrn_reflns_av_R_equivalents  0.0366
_diffrn_reflns_av_sigmaI/netI    0.0427
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_theta_min         2.16
_diffrn_reflns_theta_max         28.50
_reflns_number_total             3939
_reflns_number_gt                3738
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0001P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00043(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.006(5)
_refine_ls_number_reflns         3939
_refine_ls_number_parameters     203
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0217
_refine_ls_R_factor_gt           0.0192
_refine_ls_wR_factor_ref         0.0394
_refine_ls_wR_factor_gt          0.0389
_refine_ls_goodness_of_fit_ref   0.922
_refine_ls_restrained_S_all      0.923
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 1.097782(14) 0.961465(7) 0.85003(2) 0.01070(4) Uani 1 1 d . . .
Fe1 Fe 0.98138(5) 0.78284(3) 0.84086(9) 0.01294(11) Uani 1 1 d . . .
Cl1 Cl 1.28621(10) 0.89454(5) 0.88317(15) 0.0238(2) Uani 1 1 d . . .
C1 C 0.8689(4) 0.86182(19) 0.9230(5) 0.0135(8) Uani 1 1 d . . .
O1 O 0.6866(3) 0.85663(14) 0.7505(4) 0.0178(6) Uani 1 1 d . . .
N1 N 0.7919(3) 0.95870(17) 0.7412(4) 0.0144(6) Uani 1 1 d . . .
C2 C 0.9978(4) 0.8823(2) 0.9548(5) 0.0118(8) Uani 1 1 d . . .
C3 C 1.0458(4) 0.82974(19) 1.0695(5) 0.0156(9) Uani 1 1 d . . .
H3 H 1.1278 0.8289 1.1141 0.019 Uiso 1 1 calc R . .
C4 C 0.9532(4) 0.7784(2) 1.1078(5) 0.0175(9) Uani 1 1 d . . .
H4 H 0.9632 0.7383 1.1820 0.021 Uiso 1 1 calc R . .
C5 C 0.8436(4) 0.79697(19) 1.0171(5) 0.0154(9) Uani 1 1 d . . .
H5 H 0.7677 0.7715 1.0182 0.018 Uiso 1 1 calc R . .
C6 C 0.9198(5) 0.7472(2) 0.6018(6) 0.0261(11) Uani 1 1 d . . .
H6 H 0.8442 0.7597 0.5465 0.031 Uiso 1 1 calc R . .
C7 C 1.0339(5) 0.7826(2) 0.5824(5) 0.0226(10) Uani 1 1 d . . .
H7 H 1.0483 0.8233 0.5117 0.027 Uiso 1 1 calc R . .
C8 C 1.1232(4) 0.7473(2) 0.6862(5) 0.0191(9) Uani 1 1 d . . .
H8 H 1.2078 0.7601 0.6962 0.023 Uiso 1 1 calc R . .
C9 C 1.0653(5) 0.6893(2) 0.7730(6) 0.0242(11) Uani 1 1 d . . .
H9 H 1.1034 0.6568 0.8515 0.029 Uiso 1 1 calc R . .
C10 C 0.9382(5) 0.6894(2) 0.7188(6) 0.0274(12) Uani 1 1 d . . .
H10 H 0.8768 0.6564 0.7550 0.033 Uiso 1 1 calc R . .
C11 C 0.7837(4) 0.89543(19) 0.8029(5) 0.0125(8) Uani 1 1 d . . .
C12 C 0.6093(4) 0.90409(18) 0.6454(6) 0.0212(8) Uani 1 1 d . . .
H12A H 0.5336 0.9175 0.7103 0.025 Uiso 1 1 calc R . .
H12B H 0.5852 0.8811 0.5338 0.025 Uiso 1 1 calc R . .
C13 C 0.6900(4) 0.96913(19) 0.6113(5) 0.0178(9) Uani 1 1 d . C .
H13 H 0.6425 1.0128 0.6435 0.021 Uiso 1 1 calc R . .
C14 C 0.7379(5) 0.9772(2) 0.4256(6) 0.0283(11) Uani 1 1 d . . .
H14 H 0.6690 0.9777 0.3436 0.034 Uiso 0.60 1 d P A 1
H14A H 0.7841 1.0210 0.4249 0.034 Uiso 0.40 1 d P B 2
C15 C 0.8248(6) 0.9213(3) 0.3741(9) 0.0614(19) Uani 1 1 d . C .
H15A H 0.7862 0.8747 0.3913 0.092 Uiso 1 1 calc R . .
H15B H 0.8996 0.9246 0.4462 0.092 Uiso 1 1 calc R . .
H15C H 0.8469 0.9271 0.2503 0.092 Uiso 1 1 calc R . .
C16 C 0.8066(9) 1.0491(4) 0.4043(11) 0.036(2) Uani 0.60 1 d PU C 1
H16A H 0.8955 1.0418 0.4209 0.054 Uiso 0.60 1 calc PR C 1
H16B H 0.7761 1.0828 0.4920 0.054 Uiso 0.60 1 calc PR C 1
H16C H 0.7915 1.0680 0.2865 0.054 Uiso 0.60 1 calc PR C 1
C16A C 0.6317(12) 0.9906(6) 0.2998(15) 0.030(3) Uani 0.40 1 d PU C 2
H16D H 0.6557 0.9756 0.1816 0.045 Uiso 0.40 1 calc PR C 2
H16E H 0.6118 1.0414 0.2990 0.045 Uiso 0.40 1 calc PR C 2
H16F H 0.5591 0.9635 0.3377 0.045 Uiso 0.40 1 calc PR C 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C2 2.007(4) . ?
Au1 N1 2.091(3) 2_775 ?
Au1 Cl1 2.4097(11) . ?
Au1 Au1 2.5654(3) 2_775 ?
Fe1 C1 2.021(4) . ?
Fe1 C5 2.025(4) . ?
Fe1 C10 2.045(4) . ?
Fe1 C8 2.048(4) . ?
Fe1 C9 2.049(4) . ?
Fe1 C7 2.052(4) . ?
Fe1 C6 2.054(4) . ?
Fe1 C4 2.060(4) . ?
Fe1 C2 2.072(4) . ?
Fe1 C3 2.075(4) . ?
C1 C5 1.443(5) . ?
C1 C11 1.445(6) . ?
C1 C2 1.467(6) . ?
O1 C11 1.340(5) . ?
O1 C12 1.463(5) . ?
N1 C11 1.284(5) . ?
N1 C13 1.495(5) . ?
N1 Au1 2.091(3) 2_775 ?
C2 C3 1.419(5) . ?
C3 C4 1.422(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.417(6) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.412(7) . ?
C6 C10 1.421(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.415(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.422(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.436(7) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.526(5) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.516(6) . ?
C13 H13 1.0000 . ?
C14 C15 1.465(7) . ?
C14 C16A 1.518(12) . ?
C14 C16 1.553(9) . ?
C14 H14 0.9731 . ?
C14 H14A 0.9650 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H14A 0.6028 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C16A H14 0.5771 . ?
C16A H16D 0.9800 . ?
C16A H16E 0.9800 . ?
C16A H16F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Au1 N1 177.70(15) . 2_775 ?
C2 Au1 Cl1 91.46(12) . . ?
N1 Au1 Cl1 86.25(10) 2_775 . ?
C2 Au1 Au1 88.62(12) . 2_775 ?
N1 Au1 Au1 93.68(9) 2_775 2_775 ?
Cl1 Au1 Au1 173.39(3) . 2_775 ?
C1 Fe1 C5 41.79(15) . . ?
C1 Fe1 C10 129.55(19) . . ?
C5 Fe1 C10 104.30(18) . . ?
C1 Fe1 C8 150.49(16) . . ?
C5 Fe1 C8 167.65(15) . . ?
C10 Fe1 C8 68.11(18) . . ?
C1 Fe1 C9 167.97(18) . . ?
C5 Fe1 C9 127.38(17) . . ?
C10 Fe1 C9 41.08(19) . . ?
C8 Fe1 C9 40.62(17) . . ?
C1 Fe1 C7 117.77(16) . . ?
C5 Fe1 C7 147.36(19) . . ?
C10 Fe1 C7 67.93(19) . . ?
C8 Fe1 C7 40.39(17) . . ?
C9 Fe1 C7 68.46(18) . . ?
C1 Fe1 C6 108.69(18) . . ?
C5 Fe1 C6 113.16(19) . . ?
C10 Fe1 C6 40.57(19) . . ?
C8 Fe1 C6 67.95(18) . . ?
C9 Fe1 C6 68.79(18) . . ?
C7 Fe1 C6 40.22(19) . . ?
C1 Fe1 C4 68.55(16) . . ?
C5 Fe1 C4 40.56(17) . . ?
C10 Fe1 C4 112.42(18) . . ?
C8 Fe1 C4 131.83(18) . . ?
C9 Fe1 C4 106.30(18) . . ?
C7 Fe1 C4 172.1(2) . . ?
C6 Fe1 C4 144.7(2) . . ?
C1 Fe1 C2 41.99(16) . . ?
C5 Fe1 C2 70.50(16) . . ?
C10 Fe1 C2 171.2(2) . . ?
C8 Fe1 C2 118.23(16) . . ?
C9 Fe1 C2 147.68(18) . . ?
C7 Fe1 C2 112.39(16) . . ?
C6 Fe1 C2 134.09(17) . . ?
C4 Fe1 C2 68.57(15) . . ?
C1 Fe1 C3 68.20(16) . . ?
C5 Fe1 C3 68.50(18) . . ?
C10 Fe1 C3 145.64(18) . . ?
C8 Fe1 C3 111.83(18) . . ?
C9 Fe1 C3 115.43(18) . . ?
C7 Fe1 C3 135.66(19) . . ?
C6 Fe1 C3 173.70(18) . . ?
C4 Fe1 C3 40.22(16) . . ?
C2 Fe1 C3 40.02(15) . . ?
C5 C1 C11 124.4(4) . . ?
C5 C1 C2 108.7(4) . . ?
C11 C1 C2 126.6(3) . . ?
C5 C1 Fe1 69.3(2) . . ?
C11 C1 Fe1 120.7(3) . . ?
C2 C1 Fe1 70.9(2) . . ?
C11 O1 C12 106.2(3) . . ?
C11 N1 C13 108.3(3) . . ?
C11 N1 Au1 124.1(3) . 2_775 ?
C13 N1 Au1 126.1(2) . 2_775 ?
C3 C2 C1 105.5(3) . . ?
C3 C2 Au1 124.5(3) . . ?
C1 C2 Au1 129.9(3) . . ?
C3 C2 Fe1 70.1(2) . . ?
C1 C2 Fe1 67.1(2) . . ?
Au1 C2 Fe1 123.40(19) . . ?
C2 C3 C4 110.0(4) . . ?
C2 C3 Fe1 69.9(2) . . ?
C4 C3 Fe1 69.3(2) . . ?
C2 C3 H3 125.0 . . ?
C4 C3 H3 125.0 . . ?
Fe1 C3 H3 127.4 . . ?
C5 C4 C3 108.8(3) . . ?
C5 C4 Fe1 68.4(2) . . ?
C3 C4 Fe1 70.5(2) . . ?
C5 C4 H4 125.6 . . ?
C3 C4 H4 125.6 . . ?
Fe1 C4 H4 127.1 . . ?
C4 C5 C1 107.0(4) . . ?
C4 C5 Fe1 71.0(2) . . ?
C1 C5 Fe1 68.9(2) . . ?
C4 C5 H5 126.5 . . ?
C1 C5 H5 126.5 . . ?
Fe1 C5 H5 125.1 . . ?
C7 C6 C10 107.8(4) . . ?
C7 C6 Fe1 69.8(2) . . ?
C10 C6 Fe1 69.4(2) . . ?
C7 C6 H6 126.1 . . ?
C10 C6 H6 126.1 . . ?
Fe1 C6 H6 126.3 . . ?
C6 C7 C8 108.4(4) . . ?
C6 C7 Fe1 70.0(3) . . ?
C8 C7 Fe1 69.7(2) . . ?
C6 C7 H7 125.8 . . ?
C8 C7 H7 125.8 . . ?
Fe1 C7 H7 126.1 . . ?
C7 C8 C9 108.8(4) . . ?
C7 C8 Fe1 70.0(3) . . ?
C9 C8 Fe1 69.7(2) . . ?
C7 C8 H8 125.6 . . ?
C9 C8 H8 125.6 . . ?
Fe1 C8 H8 126.3 . . ?
C8 C9 C10 106.6(4) . . ?
C8 C9 Fe1 69.6(2) . . ?
C10 C9 Fe1 69.3(3) . . ?
C8 C9 H9 126.7 . . ?
C10 C9 H9 126.7 . . ?
Fe1 C9 H9 125.9 . . ?
C6 C10 C9 108.4(4) . . ?
C6 C10 Fe1 70.1(2) . . ?
C9 C10 Fe1 69.6(2) . . ?
C6 C10 H10 125.8 . . ?
C9 C10 H10 125.8 . . ?
Fe1 C10 H10 126.1 . . ?
N1 C11 O1 116.7(4) . . ?
N1 C11 C1 126.5(4) . . ?
O1 C11 C1 116.8(3) . . ?
O1 C12 C13 104.9(3) . . ?
O1 C12 H12A 110.8 . . ?
C13 C12 H12A 110.8 . . ?
O1 C12 H12B 110.8 . . ?
C13 C12 H12B 110.8 . . ?
H12A C12 H12B 108.8 . . ?
N1 C13 C14 112.4(4) . . ?
N1 C13 C12 101.7(3) . . ?
C14 C13 C12 115.8(4) . . ?
N1 C13 H13 108.9 . . ?
C14 C13 H13 108.9 . . ?
C12 C13 H13 108.9 . . ?
C15 C14 C13 113.5(4) . . ?
C15 C14 C16A 115.9(6) . . ?
C13 C14 C16A 110.4(6) . . ?
C15 C14 C16 106.9(5) . . ?
C13 C14 C16 110.4(4) . . ?
C16A C14 C16 98.6(6) . . ?
C15 C14 H14 109.1 . . ?
C13 C14 H14 109.9 . . ?
C16A C14 H14 9.0 . . ?
C16 C14 H14 106.9 . . ?
C15 C14 H14A 106.3 . . ?
C13 C14 H14A 105.5 . . ?
C16A C14 H14A 104.2 . . ?
C16 C14 H14A 6.2 . . ?
H14 C14 H14A 112.6 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H14A 9.9 . . ?
C14 C16 H16A 109.5 . . ?
H14A C16 H16A 103.8 . . ?
C14 C16 H16B 109.5 . . ?
H14A C16 H16B 104.8 . . ?
C14 C16 H16C 109.5 . . ?
H14A C16 H16C 119.4 . . ?
C14 C16A H14 15.3 . . ?
C14 C16A H16D 109.5 . . ?
C14 C16A H16E 109.5 . . ?
H16D C16A H16E 109.5 . . ?
C14 C16A H16F 109.5 . . ?
H16D C16A H16F 109.5 . . ?
H16E C16A H16F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C10 Fe1 C1 C5 63.7(3) . . . . ?
C8 Fe1 C1 C5 -177.8(3) . . . . ?
C9 Fe1 C1 C5 28.3(10) . . . . ?
C7 Fe1 C1 C5 147.0(3) . . . . ?
C6 Fe1 C1 C5 104.2(3) . . . . ?
C4 Fe1 C1 C5 -38.3(3) . . . . ?
C2 Fe1 C1 C5 -119.6(3) . . . . ?
C3 Fe1 C1 C5 -81.7(3) . . . . ?
C5 Fe1 C1 C11 -118.5(4) . . . . ?
C10 Fe1 C1 C11 -54.8(4) . . . . ?
C8 Fe1 C1 C11 63.7(5) . . . . ?
C9 Fe1 C1 C11 -90.2(9) . . . . ?
C7 Fe1 C1 C11 28.5(4) . . . . ?
C6 Fe1 C1 C11 -14.4(4) . . . . ?
C4 Fe1 C1 C11 -156.8(4) . . . . ?
C2 Fe1 C1 C11 121.9(4) . . . . ?
C3 Fe1 C1 C11 159.8(4) . . . . ?
C5 Fe1 C1 C2 119.6(3) . . . . ?
C10 Fe1 C1 C2 -176.7(3) . . . . ?
C8 Fe1 C1 C2 -58.2(4) . . . . ?
C9 Fe1 C1 C2 148.0(8) . . . . ?
C7 Fe1 C1 C2 -93.4(3) . . . . ?
C6 Fe1 C1 C2 -136.2(2) . . . . ?
C4 Fe1 C1 C2 81.4(2) . . . . ?
C3 Fe1 C1 C2 37.9(2) . . . . ?
C5 C1 C2 C3 -0.9(4) . . . . ?
C11 C1 C2 C3 -174.5(4) . . . . ?
Fe1 C1 C2 C3 -60.0(3) . . . . ?
C5 C1 C2 Au1 174.4(3) . . . . ?
C11 C1 C2 Au1 0.7(6) . . . . ?
Fe1 C1 C2 Au1 115.2(3) . . . . ?
C5 C1 C2 Fe1 59.1(3) . . . . ?
C11 C1 C2 Fe1 -114.5(4) . . . . ?
N1 Au1 C2 C3 30(4) 2_775 . . . ?
Cl1 Au1 C2 C3 23.9(3) . . . . ?
Au1 Au1 C2 C3 -149.5(3) 2_775 . . . ?
N1 Au1 C2 C1 -145(3) 2_775 . . . ?
Cl1 Au1 C2 C1 -150.5(3) . . . . ?
Au1 Au1 C2 C1 36.1(3) 2_775 . . . ?
N1 Au1 C2 Fe1 -58(4) 2_775 . . . ?
Cl1 Au1 C2 Fe1 -63.7(2) . . . . ?
Au1 Au1 C2 Fe1 122.9(2) 2_775 . . . ?
C1 Fe1 C2 C3 117.4(3) . . . . ?
C5 Fe1 C2 C3 79.5(3) . . . . ?
C10 Fe1 C2 C3 134.3(11) . . . . ?
C8 Fe1 C2 C3 -91.0(3) . . . . ?
C9 Fe1 C2 C3 -50.7(4) . . . . ?
C7 Fe1 C2 C3 -135.4(3) . . . . ?
C6 Fe1 C2 C3 -176.8(3) . . . . ?
C4 Fe1 C2 C3 36.1(3) . . . . ?
C5 Fe1 C2 C1 -37.9(2) . . . . ?
C10 Fe1 C2 C1 16.9(13) . . . . ?
C8 Fe1 C2 C1 151.6(2) . . . . ?
C9 Fe1 C2 C1 -168.1(3) . . . . ?
C7 Fe1 C2 C1 107.2(3) . . . . ?
C6 Fe1 C2 C1 65.8(3) . . . . ?
C4 Fe1 C2 C1 -81.3(2) . . . . ?
C3 Fe1 C2 C1 -117.4(3) . . . . ?
C1 Fe1 C2 Au1 -123.7(3) . . . . ?
C5 Fe1 C2 Au1 -161.7(3) . . . . ?
C10 Fe1 C2 Au1 -106.8(12) . . . . ?
C8 Fe1 C2 Au1 27.9(3) . . . . ?
C9 Fe1 C2 Au1 68.2(4) . . . . ?
C7 Fe1 C2 Au1 -16.6(3) . . . . ?
C6 Fe1 C2 Au1 -57.9(4) . . . . ?
C4 Fe1 C2 Au1 155.0(3) . . . . ?
C3 Fe1 C2 Au1 118.9(4) . . . . ?
C1 C2 C3 C4 0.4(4) . . . . ?
Au1 C2 C3 C4 -175.2(3) . . . . ?
Fe1 C2 C3 C4 -57.7(3) . . . . ?
C1 C2 C3 Fe1 58.1(2) . . . . ?
Au1 C2 C3 Fe1 -117.5(3) . . . . ?
C1 Fe1 C3 C2 -39.8(2) . . . . ?
C5 Fe1 C3 C2 -84.9(3) . . . . ?
C10 Fe1 C3 C2 -168.8(3) . . . . ?
C8 Fe1 C3 C2 108.4(3) . . . . ?
C9 Fe1 C3 C2 152.7(3) . . . . ?
C7 Fe1 C3 C2 68.2(3) . . . . ?
C6 Fe1 C3 C2 21.7(17) . . . . ?
C4 Fe1 C3 C2 -121.9(4) . . . . ?
C1 Fe1 C3 C4 82.1(3) . . . . ?
C5 Fe1 C3 C4 37.0(2) . . . . ?
C10 Fe1 C3 C4 -46.9(4) . . . . ?
C8 Fe1 C3 C4 -129.7(3) . . . . ?
C9 Fe1 C3 C4 -85.4(3) . . . . ?
C7 Fe1 C3 C4 -169.9(3) . . . . ?
C6 Fe1 C3 C4 143.6(16) . . . . ?
C2 Fe1 C3 C4 121.9(4) . . . . ?
C2 C3 C4 C5 0.3(5) . . . . ?
Fe1 C3 C4 C5 -57.7(3) . . . . ?
C2 C3 C4 Fe1 58.1(3) . . . . ?
C1 Fe1 C4 C5 39.4(2) . . . . ?
C10 Fe1 C4 C5 -85.9(3) . . . . ?
C8 Fe1 C4 C5 -166.0(2) . . . . ?
C9 Fe1 C4 C5 -129.1(2) . . . . ?
C7 Fe1 C4 C5 -176.9(11) . . . . ?
C6 Fe1 C4 C5 -53.0(4) . . . . ?
C2 Fe1 C4 C5 84.7(2) . . . . ?
C3 Fe1 C4 C5 120.6(3) . . . . ?
C1 Fe1 C4 C3 -81.2(2) . . . . ?
C5 Fe1 C4 C3 -120.6(3) . . . . ?
C10 Fe1 C4 C3 153.5(3) . . . . ?
C8 Fe1 C4 C3 73.4(3) . . . . ?
C9 Fe1 C4 C3 110.3(3) . . . . ?
C7 Fe1 C4 C3 62.6(13) . . . . ?
C6 Fe1 C4 C3 -173.5(3) . . . . ?
C2 Fe1 C4 C3 -35.9(2) . . . . ?
C3 C4 C5 C1 -0.9(4) . . . . ?
Fe1 C4 C5 C1 -59.9(3) . . . . ?
C3 C4 C5 Fe1 59.0(3) . . . . ?
C11 C1 C5 C4 174.9(4) . . . . ?
C2 C1 C5 C4 1.1(4) . . . . ?
Fe1 C1 C5 C4 61.2(3) . . . . ?
C11 C1 C5 Fe1 113.7(4) . . . . ?
C2 C1 C5 Fe1 -60.1(3) . . . . ?
C1 Fe1 C5 C4 -117.6(3) . . . . ?
C10 Fe1 C5 C4 107.9(3) . . . . ?
C8 Fe1 C5 C4 57.3(9) . . . . ?
C9 Fe1 C5 C4 69.6(3) . . . . ?
C7 Fe1 C5 C4 179.2(3) . . . . ?
C6 Fe1 C5 C4 149.9(3) . . . . ?
C2 Fe1 C5 C4 -79.5(2) . . . . ?
C3 Fe1 C5 C4 -36.7(2) . . . . ?
C10 Fe1 C5 C1 -134.5(3) . . . . ?
C8 Fe1 C5 C1 174.9(7) . . . . ?
C9 Fe1 C5 C1 -172.8(3) . . . . ?
C7 Fe1 C5 C1 -63.2(4) . . . . ?
C6 Fe1 C5 C1 -92.5(3) . . . . ?
C4 Fe1 C5 C1 117.6(3) . . . . ?
C2 Fe1 C5 C1 38.1(2) . . . . ?
C3 Fe1 C5 C1 80.9(2) . . . . ?
C1 Fe1 C6 C7 111.2(3) . . . . ?
C5 Fe1 C6 C7 155.9(2) . . . . ?
C10 Fe1 C6 C7 -119.1(4) . . . . ?
C8 Fe1 C6 C7 -37.5(2) . . . . ?
C9 Fe1 C6 C7 -81.3(3) . . . . ?
C4 Fe1 C6 C7 -169.8(3) . . . . ?
C2 Fe1 C6 C7 71.1(3) . . . . ?
C3 Fe1 C6 C7 51.8(17) . . . . ?
C1 Fe1 C6 C10 -129.7(3) . . . . ?
C5 Fe1 C6 C10 -85.0(3) . . . . ?
C8 Fe1 C6 C10 81.6(3) . . . . ?
C9 Fe1 C6 C10 37.8(3) . . . . ?
C7 Fe1 C6 C10 119.1(4) . . . . ?
C4 Fe1 C6 C10 -50.7(4) . . . . ?
C2 Fe1 C6 C10 -169.8(3) . . . . ?
C3 Fe1 C6 C10 170.9(15) . . . . ?
C10 C6 C7 C8 0.1(5) . . . . ?
Fe1 C6 C7 C8 59.3(3) . . . . ?
C10 C6 C7 Fe1 -59.2(3) . . . . ?
C1 Fe1 C7 C6 -86.5(3) . . . . ?
C5 Fe1 C7 C6 -44.2(4) . . . . ?
C10 Fe1 C7 C6 37.8(3) . . . . ?
C8 Fe1 C7 C6 119.5(3) . . . . ?
C9 Fe1 C7 C6 82.2(3) . . . . ?
C4 Fe1 C7 C6 132.0(12) . . . . ?
C2 Fe1 C7 C6 -132.7(3) . . . . ?
C3 Fe1 C7 C6 -172.9(3) . . . . ?
C1 Fe1 C7 C8 154.0(2) . . . . ?
C5 Fe1 C7 C8 -163.7(3) . . . . ?
C10 Fe1 C7 C8 -81.7(3) . . . . ?
C9 Fe1 C7 C8 -37.3(3) . . . . ?
C6 Fe1 C7 C8 -119.5(3) . . . . ?
C4 Fe1 C7 C8 12.5(13) . . . . ?
C2 Fe1 C7 C8 107.8(3) . . . . ?
C3 Fe1 C7 C8 67.6(3) . . . . ?
C6 C7 C8 C9 -0.4(5) . . . . ?
Fe1 C7 C8 C9 59.1(3) . . . . ?
C6 C7 C8 Fe1 -59.5(3) . . . . ?
C1 Fe1 C8 C7 -51.9(4) . . . . ?
C5 Fe1 C8 C7 135.0(8) . . . . ?
C10 Fe1 C8 C7 81.2(3) . . . . ?
C9 Fe1 C8 C7 120.0(4) . . . . ?
C6 Fe1 C8 C7 37.3(3) . . . . ?
C4 Fe1 C8 C7 -177.7(3) . . . . ?
C2 Fe1 C8 C7 -92.1(3) . . . . ?
C3 Fe1 C8 C7 -135.9(3) . . . . ?
C1 Fe1 C8 C9 -171.9(3) . . . . ?
C5 Fe1 C8 C9 15.0(9) . . . . ?
C10 Fe1 C8 C9 -38.8(3) . . . . ?
C7 Fe1 C8 C9 -120.0(4) . . . . ?
C6 Fe1 C8 C9 -82.7(3) . . . . ?
C4 Fe1 C8 C9 62.3(3) . . . . ?
C2 Fe1 C8 C9 147.9(3) . . . . ?
C3 Fe1 C8 C9 104.1(3) . . . . ?
C7 C8 C9 C10 0.5(5) . . . . ?
Fe1 C8 C9 C10 59.7(3) . . . . ?
C7 C8 C9 Fe1 -59.2(3) . . . . ?
C1 Fe1 C9 C8 160.5(8) . . . . ?
C5 Fe1 C9 C8 -176.0(3) . . . . ?
C10 Fe1 C9 C8 117.8(4) . . . . ?
C7 Fe1 C9 C8 37.1(3) . . . . ?
C6 Fe1 C9 C8 80.4(3) . . . . ?
C4 Fe1 C9 C8 -136.6(3) . . . . ?
C2 Fe1 C9 C8 -61.1(4) . . . . ?
C3 Fe1 C9 C8 -94.5(3) . . . . ?
C1 Fe1 C9 C10 42.8(10) . . . . ?
C5 Fe1 C9 C10 66.2(3) . . . . ?
C8 Fe1 C9 C10 -117.8(4) . . . . ?
C7 Fe1 C9 C10 -80.7(3) . . . . ?
C6 Fe1 C9 C10 -37.4(3) . . . . ?
C4 Fe1 C9 C10 105.6(3) . . . . ?
C2 Fe1 C9 C10 -178.8(3) . . . . ?
C3 Fe1 C9 C10 147.7(3) . . . . ?
C7 C6 C10 C9 0.2(5) . . . . ?
Fe1 C6 C10 C9 -59.2(3) . . . . ?
C7 C6 C10 Fe1 59.4(3) . . . . ?
C8 C9 C10 C6 -0.4(5) . . . . ?
Fe1 C9 C10 C6 59.5(3) . . . . ?
C8 C9 C10 Fe1 -60.0(3) . . . . ?
C1 Fe1 C10 C6 71.0(3) . . . . ?
C5 Fe1 C10 C6 109.1(3) . . . . ?
C8 Fe1 C10 C6 -81.2(3) . . . . ?
C9 Fe1 C10 C6 -119.6(4) . . . . ?
C7 Fe1 C10 C6 -37.5(3) . . . . ?
C4 Fe1 C10 C6 151.1(3) . . . . ?
C2 Fe1 C10 C6 56.4(13) . . . . ?
C3 Fe1 C10 C6 -178.2(3) . . . . ?
C1 Fe1 C10 C9 -169.4(3) . . . . ?
C5 Fe1 C10 C9 -131.4(3) . . . . ?
C8 Fe1 C10 C9 38.4(3) . . . . ?
C7 Fe1 C10 C9 82.1(3) . . . . ?
C6 Fe1 C10 C9 119.6(4) . . . . ?
C4 Fe1 C10 C9 -89.4(3) . . . . ?
C2 Fe1 C10 C9 176.0(11) . . . . ?
C3 Fe1 C10 C9 -58.7(4) . . . . ?
C13 N1 C11 O1 -4.4(5) . . . . ?
Au1 N1 C11 O1 162.5(3) 2_775 . . . ?
C13 N1 C11 C1 175.4(4) . . . . ?
Au1 N1 C11 C1 -17.7(6) 2_775 . . . ?
C12 O1 C11 N1 -5.5(5) . . . . ?
C12 O1 C11 C1 174.6(3) . . . . ?
C5 C1 C11 N1 166.4(4) . . . . ?
C2 C1 C11 N1 -20.9(6) . . . . ?
Fe1 C1 C11 N1 -109.0(4) . . . . ?
C5 C1 C11 O1 -13.7(6) . . . . ?
C2 C1 C11 O1 158.9(4) . . . . ?
Fe1 C1 C11 O1 70.9(4) . . . . ?
C11 O1 C12 C13 12.6(4) . . . . ?
C11 N1 C13 C14 -112.7(4) . . . . ?
Au1 N1 C13 C14 80.7(4) 2_775 . . . ?
C11 N1 C13 C12 11.7(4) . . . . ?
Au1 N1 C13 C12 -154.8(3) 2_775 . . . ?
O1 C12 C13 N1 -14.3(4) . . . . ?
O1 C12 C13 C14 107.8(4) . . . . ?
N1 C13 C14 C15 50.3(5) . . . . ?
C12 C13 C14 C15 -65.9(6) . . . . ?
N1 C13 C14 C16A -177.7(6) . . . . ?
C12 C13 C14 C16A 66.1(7) . . . . ?
N1 C13 C14 C16 -69.7(5) . . . . ?
C12 C13 C14 C16 174.1(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        28.50
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         1.191
_refine_diff_density_min         -0.650
_refine_diff_density_rms         0.114
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2116lm
_audit_block_doi                 10.5517/cc14grfs
_database_code_depnum_ccdc_archive 'CCDC 1056865'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1039/C5CC07018J 2015
_audit_update_record             
;
2015-03-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'compound 8'' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_formula_weight         1057.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   10.0819(5)
_cell_length_b                   15.2950(6)
_cell_length_c                   20.4679(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3156.2(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    6634
_cell_measurement_theta_min      1.66
_cell_measurement_theta_max      28.34

_exptl_crystal_description       needle
_exptl_crystal_colour            brown-yellow
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.225
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2008
_exptl_absorpt_coefficient_mu    10.371
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.3324
_exptl_absorpt_correction_T_max  0.8012
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            30871
_diffrn_reflns_av_R_equivalents  0.0663
_diffrn_reflns_av_sigmaI/netI    0.0767
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         1.66
_diffrn_reflns_theta_max         28.34
_reflns_number_total             7791
_reflns_number_gt                6634
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0382P)²+18.3844P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.012(11)
_refine_ls_number_reflns         7791
_refine_ls_number_parameters     341
_refine_ls_number_restraints     54
_refine_ls_R_factor_all          0.0623
_refine_ls_R_factor_gt           0.0478
_refine_ls_wR_factor_ref         0.0992
_refine_ls_wR_factor_gt          0.0955
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_restrained_S_all      1.050
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.41229(3) 0.50341(2) 1.015347(19) 0.01127(9) Uani 1 1 d . . .
Cl1 Cl 0.8563(3) 0.45621(16) 0.92423(19) 0.0289(8) Uani 1 1 d . . .
Fe1 Fe 0.65680(16) 0.53141(10) 1.14979(9) 0.0203(4) Uani 1 1 d . . .
Au2 Au 0.63854(4) 0.47907(2) 0.96465(2) 0.01176(9) Uani 1 1 d . . .
Cl2 Cl 0.1996(3) 0.52905(17) 1.06408(15) 0.0189(6) Uani 1 1 d . . .
Fe2 Fe 0.61302(15) 0.26606(10) 0.88235(8) 0.0151(3) Uani 1 1 d . . .
O1 O 0.7373(8) 0.7318(5) 1.0280(5) 0.0215(18) Uani 1 1 d . . .
N1 N 0.6869(8) 0.6119(5) 0.9741(5) 0.015(2) Uani 1 1 d . . .
C1 C 0.5028(11) 0.5652(7) 1.0888(6) 0.015(2) Uani 1 1 d . . .
O2 O 0.2693(7) 0.3209(5) 0.8772(4) 0.0187(18) Uani 1 1 d . . .
N2 N 0.3208(9) 0.4382(6) 0.9369(5) 0.0168(15) Uani 1 1 d U . .
C2 C 0.6076(10) 0.6287(7) 1.0864(6) 0.014(2) Uani 1 1 d . . .
C3 C 0.6283(12) 0.6645(7) 1.1501(6) 0.018(2) Uani 1 1 d U . .
H3 H 0.6906 0.7085 1.1614 0.021 Uiso 1 1 calc R . .
C4 C 0.5382(12) 0.6218(7) 1.1936(6) 0.021(3) Uani 1 1 d . . .
H4 H 0.5320 0.6311 1.2394 0.025 Uiso 1 1 calc R . .
C5 C 0.4604(11) 0.5636(8) 1.1564(6) 0.020(3) Uani 1 1 d . . .
H5 H 0.3905 0.5285 1.1732 0.024 Uiso 1 1 calc R . .
C6 C 0.6762(13) 0.4089(8) 1.1882(7) 0.027(2) Uani 1 1 d . . .
H6 H 0.6064 0.3736 1.2049 0.032 Uiso 1 1 calc R . .
C7 C 0.7213(13) 0.4100(8) 1.1225(7) 0.027(2) Uani 1 1 d U . .
H7 H 0.6887 0.3751 1.0876 0.032 Uiso 1 1 calc R . .
C8 C 0.8230(15) 0.4723(9) 1.1187(8) 0.043(3) Uani 1 1 d . . .
H8 H 0.8692 0.4894 1.0803 0.052 Uiso 1 1 calc R . .
C9 C 0.8441(13) 0.5047(9) 1.1817(6) 0.035(3) Uani 1 1 d U . .
H9 H 0.9108 0.5453 1.1941 0.042 Uiso 1 1 calc R . .
C10 C 0.7501(15) 0.4669(9) 1.2234(8) 0.043(3) Uani 1 1 d . . .
H10 H 0.7395 0.4796 1.2685 0.052 Uiso 1 1 calc R . .
C11 C 0.6783(10) 0.6552(6) 1.0285(6) 0.0143(16) Uani 1 1 d U . .
C12 C 0.7559(11) 0.6652(7) 0.9247(6) 0.0143(16) Uani 1 1 d . . .
H12 H 0.8335 0.6312 0.9080 0.017 Uiso 1 1 calc R . .
C13 C 0.8077(12) 0.7418(7) 0.9653(7) 0.025(3) Uani 1 1 d . . .
H13A H 0.9049 0.7379 0.9714 0.030 Uiso 1 1 calc R . .
H13B H 0.7859 0.7984 0.9444 0.030 Uiso 1 1 calc R . .
C14 C 0.6658(11) 0.6878(8) 0.8669(6) 0.019(3) Uani 1 1 d . . .
H14 H 0.6413 0.6321 0.8443 0.023 Uiso 1 1 calc R . .
C15 C 0.7403(14) 0.7443(8) 0.8193(7) 0.027(3) Uani 1 1 d . . .
H15A H 0.7483 0.8036 0.8370 0.040 Uiso 1 1 calc R . .
H15B H 0.6922 0.7463 0.7777 0.040 Uiso 1 1 calc R . .
H15C H 0.8290 0.7199 0.8122 0.040 Uiso 1 1 calc R . .
C16 C 0.5335(11) 0.7348(9) 0.8893(7) 0.025(3) Uani 1 1 d . . .
H16A H 0.5555 0.7892 0.9121 0.038 Uiso 1 1 calc R . .
H16B H 0.4841 0.6962 0.9188 0.038 Uiso 1 1 calc R . .
H16C H 0.4790 0.7479 0.8509 0.038 Uiso 1 1 calc R . .
C17 C 0.5919(10) 0.3526(6) 0.9592(6) 0.013(2) Uani 1 1 d . . .
C18 C 0.4692(10) 0.3119(7) 0.9425(5) 0.013(2) Uani 1 1 d . . .
C19 C 0.4805(11) 0.2189(7) 0.9462(6) 0.018(3) Uani 1 1 d . . .
H19 H 0.4139 0.1775 0.9352 0.022 Uiso 1 1 calc R . .
C20 C 0.6098(10) 0.2001(7) 0.9694(6) 0.0166(16) Uani 1 1 d . . .
H20 H 0.6439 0.1439 0.9796 0.020 Uiso 1 1 calc R . .
C21 C 0.6805(11) 0.2823(7) 0.9746(6) 0.0166(16) Uani 1 1 d U . .
H21 H 0.7711 0.2885 0.9864 0.020 Uiso 1 1 calc R . .
C22 C 0.5684(13) 0.2036(8) 0.7970(6) 0.027(3) Uani 1 1 d . . .
H22 H 0.4933 0.1673 0.7899 0.032 Uiso 1 1 calc R . .
C23 C 0.6935(15) 0.1759(10) 0.8199(6) 0.032(3) Uani 1 1 d . . .
H23 H 0.7178 0.1173 0.8293 0.039 Uiso 1 1 calc R . .
C24 C 0.7774(14) 0.2503(9) 0.8265(8) 0.033(3) Uani 1 1 d U . .
H24 H 0.8659 0.2511 0.8424 0.040 Uiso 1 1 calc R . .
C25 C 0.7008(14) 0.3242(9) 0.8044(7) 0.032(2) Uani 1 1 d . . .
H25 H 0.7313 0.3830 0.8023 0.039 Uiso 1 1 calc R . .
C26 C 0.5746(14) 0.2953(9) 0.7864(7) 0.032(2) Uani 1 1 d . . .
H26 H 0.5048 0.3308 0.7700 0.039 Uiso 1 1 calc R . .
C27 C 0.3517(11) 0.3592(7) 0.9209(6) 0.018(2) Uani 1 1 d . . .
C28 C 0.2036(10) 0.4679(7) 0.9030(6) 0.017(2) Uani 1 1 d U . .
H28 H 0.1351 0.4886 0.9348 0.021 Uiso 1 1 calc R . .
C29 C 0.1581(11) 0.3810(7) 0.8694(6) 0.0168(15) Uani 1 1 d . . .
H29A H 0.0776 0.3576 0.8908 0.020 Uiso 1 1 calc R . .
H29B H 0.1388 0.3909 0.8225 0.020 Uiso 1 1 calc R . .
C30 C 0.2421(12) 0.5411(8) 0.8562(7) 0.0248(18) Uani 1 1 d U . .
H30 H 0.2795 0.5893 0.8836 0.030 Uiso 1 1 calc R . .
C31 C 0.3501(11) 0.5151(8) 0.8082(6) 0.0248(18) Uani 1 1 d . . .
H31A H 0.3288 0.4580 0.7892 0.037 Uiso 1 1 calc R . .
H31B H 0.4353 0.5116 0.8310 0.037 Uiso 1 1 calc R . .
H31C H 0.3557 0.5589 0.7733 0.037 Uiso 1 1 calc R . .
C32 C 0.1206(13) 0.5778(8) 0.8230(7) 0.030(3) Uani 1 1 d . . .
H32A H 0.1468 0.6249 0.7933 0.045 Uiso 1 1 calc R . .
H32B H 0.0594 0.6008 0.8560 0.045 Uiso 1 1 calc R . .
H32C H 0.0765 0.5313 0.7982 0.045 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.996(11) . ?
Au1 N2 2.103(10) . ?
Au1 Cl2 2.397(3) . ?
Au1 Au2 2.5333(5) . ?
Cl1 Au2 2.372(3) . ?
Fe1 C8 2.007(14) . ?
Fe1 C10 2.031(15) . ?
Fe1 C2 2.036(11) . ?
Fe1 C4 2.036(11) . ?
Fe1 C9 2.040(13) . ?
Fe1 C6 2.042(13) . ?
Fe1 C5 2.045(11) . ?
Fe1 C7 2.046(13) . ?
Fe1 C3 2.055(11) . ?
Fe1 C1 2.058(11) . ?
Au2 C17 1.994(9) . ?
Au2 N1 2.099(8) . ?
Fe2 C19 2.003(11) . ?
Fe2 C21 2.022(12) . ?
Fe2 C18 2.027(11) . ?
Fe2 C24 2.027(15) . ?
Fe2 C25 2.030(14) . ?
Fe2 C22 2.041(12) . ?
Fe2 C20 2.047(12) . ?
Fe2 C23 2.048(13) . ?
Fe2 C26 2.050(14) . ?
Fe2 C17 2.067(11) . ?
O1 C11 1.314(12) . ?
O1 C13 1.475(15) . ?
N1 C11 1.298(14) . ?
N1 C12 1.472(14) . ?
C1 C2 1.436(14) . ?
C1 C5 1.449(17) . ?
O2 C27 1.355(13) . ?
O2 C29 1.459(12) . ?
N2 C27 1.290(14) . ?
N2 C28 1.444(14) . ?
C2 C3 1.429(16) . ?
C2 C11 1.441(16) . ?
C3 C4 1.429(16) . ?
C3 H3 0.9500 . ?
C4 C5 1.410(17) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C10 1.364(19) . ?
C6 C7 1.420(19) . ?
C6 H6 0.9500 . ?
C7 C8 1.40(2) . ?
C7 H7 0.9500 . ?
C8 C9 1.40(2) . ?
C8 H8 0.9500 . ?
C9 C10 1.40(2) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.528(15) . ?
C12 C14 1.531(16) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.504(16) . ?
C14 C16 1.583(16) . ?
C14 H14 1.0000 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.427(15) . ?
C17 C21 1.433(14) . ?
C18 C19 1.429(15) . ?
C18 C27 1.457(15) . ?
C19 C20 1.417(15) . ?
C19 H19 0.9500 . ?
C20 C21 1.448(14) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C23 1.410(18) . ?
C22 C26 1.420(18) . ?
C22 H22 0.9500 . ?
C23 C24 1.42(2) . ?
C23 H23 0.9500 . ?
C24 C25 1.44(2) . ?
C24 H24 0.9500 . ?
C25 C26 1.40(2) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C28 C30 1.524(16) . ?
C28 C29 1.565(15) . ?
C28 H28 1.0000 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C32 1.509(17) . ?
C30 C31 1.521(16) . ?
C30 H30 1.0000 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 178.8(4) . . ?
C1 Au1 Cl2 91.1(3) . . ?
N2 Au1 Cl2 90.2(3) . . ?
C1 Au1 Au2 88.1(3) . . ?
N2 Au1 Au2 90.7(3) . . ?
Cl2 Au1 Au2 178.93(7) . . ?
C8 Fe1 C10 68.3(6) . . ?
C8 Fe1 C2 109.3(6) . . ?
C10 Fe1 C2 160.1(5) . . ?
C8 Fe1 C4 159.3(6) . . ?
C10 Fe1 C4 106.0(6) . . ?
C2 Fe1 C4 69.0(5) . . ?
C8 Fe1 C9 40.4(6) . . ?
C10 Fe1 C9 40.2(6) . . ?
C2 Fe1 C9 125.2(5) . . ?
C4 Fe1 C9 122.6(5) . . ?
C8 Fe1 C6 68.2(6) . . ?
C10 Fe1 C6 39.1(5) . . ?
C2 Fe1 C6 160.0(5) . . ?
C4 Fe1 C6 120.7(5) . . ?
C9 Fe1 C6 66.7(5) . . ?
C8 Fe1 C5 159.7(6) . . ?
C10 Fe1 C5 121.1(6) . . ?
C2 Fe1 C5 68.3(5) . . ?
C4 Fe1 C5 40.4(5) . . ?
C9 Fe1 C5 157.5(5) . . ?
C6 Fe1 C5 106.7(5) . . ?
C8 Fe1 C7 40.5(6) . . ?
C10 Fe1 C7 67.3(6) . . ?
C2 Fe1 C7 124.5(5) . . ?
C4 Fe1 C7 157.5(5) . . ?
C9 Fe1 C7 67.1(5) . . ?
C6 Fe1 C7 40.6(5) . . ?
C5 Fe1 C7 123.0(5) . . ?
C8 Fe1 C3 124.3(6) . . ?
C10 Fe1 C3 122.9(5) . . ?
C2 Fe1 C3 40.9(4) . . ?
C4 Fe1 C3 40.9(5) . . ?
C9 Fe1 C3 109.1(5) . . ?
C6 Fe1 C3 157.1(5) . . ?
C5 Fe1 C3 68.1(5) . . ?
C7 Fe1 C3 160.8(5) . . ?
C8 Fe1 C1 123.4(6) . . ?
C10 Fe1 C1 157.1(6) . . ?
C2 Fe1 C1 41.1(4) . . ?
C4 Fe1 C1 69.7(5) . . ?
C9 Fe1 C1 160.6(5) . . ?
C6 Fe1 C1 122.4(5) . . ?
C5 Fe1 C1 41.4(5) . . ?
C7 Fe1 C1 107.6(5) . . ?
C3 Fe1 C1 69.4(4) . . ?
C17 Au2 N1 177.9(4) . . ?
C17 Au2 Cl1 93.2(3) . . ?
N1 Au2 Cl1 87.7(2) . . ?
C17 Au2 Au1 87.3(3) . . ?
N1 Au2 Au1 91.7(2) . . ?
Cl1 Au2 Au1 176.23(9) . . ?
C19 Fe2 C21 70.1(5) . . ?
C19 Fe2 C18 41.5(4) . . ?
C21 Fe2 C18 68.4(4) . . ?
C19 Fe2 C24 150.5(5) . . ?
C21 Fe2 C24 105.4(5) . . ?
C18 Fe2 C24 165.5(5) . . ?
C19 Fe2 C25 164.0(6) . . ?
C21 Fe2 C25 122.3(5) . . ?
C18 Fe2 C25 129.6(5) . . ?
C24 Fe2 C25 41.6(6) . . ?
C19 Fe2 C22 104.0(5) . . ?
C21 Fe2 C22 158.5(5) . . ?
C18 Fe2 C22 121.6(5) . . ?
C24 Fe2 C22 69.0(6) . . ?
C25 Fe2 C22 68.2(6) . . ?
C19 Fe2 C20 40.9(4) . . ?
C21 Fe2 C20 41.7(4) . . ?
C18 Fe2 C20 68.3(4) . . ?
C24 Fe2 C20 116.4(5) . . ?
C25 Fe2 C20 155.1(5) . . ?
C22 Fe2 C20 120.7(5) . . ?
C19 Fe2 C23 115.4(5) . . ?
C21 Fe2 C23 122.2(5) . . ?
C18 Fe2 C23 153.6(6) . . ?
C24 Fe2 C23 40.9(6) . . ?
C25 Fe2 C23 68.4(6) . . ?
C22 Fe2 C23 40.3(5) . . ?
C20 Fe2 C23 102.6(5) . . ?
C19 Fe2 C26 125.2(5) . . ?
C21 Fe2 C26 158.6(5) . . ?
C18 Fe2 C26 111.7(5) . . ?
C24 Fe2 C26 68.9(6) . . ?
C25 Fe2 C26 40.0(5) . . ?
C22 Fe2 C26 40.6(5) . . ?
C20 Fe2 C26 159.6(5) . . ?
C23 Fe2 C26 67.9(6) . . ?
C19 Fe2 C17 70.4(4) . . ?
C21 Fe2 C17 41.0(4) . . ?
C18 Fe2 C17 40.8(4) . . ?
C24 Fe2 C17 126.1(5) . . ?
C25 Fe2 C17 111.3(5) . . ?
C22 Fe2 C17 158.2(5) . . ?
C20 Fe2 C17 69.6(4) . . ?
C23 Fe2 C17 161.3(5) . . ?
C26 Fe2 C17 124.8(5) . . ?
C11 O1 C13 108.5(9) . . ?
C11 N1 C12 109.8(8) . . ?
C11 N1 Au2 123.8(7) . . ?
C12 N1 Au2 125.7(7) . . ?
C2 C1 C5 105.2(10) . . ?
C2 C1 Au1 129.1(9) . . ?
C5 C1 Au1 125.2(8) . . ?
C2 C1 Fe1 68.6(6) . . ?
C5 C1 Fe1 68.8(6) . . ?
Au1 C1 Fe1 133.1(6) . . ?
C27 O2 C29 105.7(8) . . ?
C27 N2 C28 111.7(10) . . ?
C27 N2 Au1 122.2(8) . . ?
C28 N2 Au1 125.2(7) . . ?
C3 C2 C1 109.6(10) . . ?
C3 C2 C11 124.8(10) . . ?
C1 C2 C11 125.6(10) . . ?
C3 C2 Fe1 70.3(6) . . ?
C1 C2 Fe1 70.3(6) . . ?
C11 C2 Fe1 127.5(7) . . ?
C2 C3 C4 107.5(10) . . ?
C2 C3 Fe1 68.8(6) . . ?
C4 C3 Fe1 68.8(6) . . ?
C2 C3 H3 126.2 . . ?
C4 C3 H3 126.2 . . ?
Fe1 C3 H3 127.7 . . ?
C5 C4 C3 107.8(11) . . ?
C5 C4 Fe1 70.1(7) . . ?
C3 C4 Fe1 70.3(6) . . ?
C5 C4 H4 126.1 . . ?
C3 C4 H4 126.1 . . ?
Fe1 C4 H4 125.1 . . ?
C4 C5 C1 109.9(11) . . ?
C4 C5 Fe1 69.4(7) . . ?
C1 C5 Fe1 69.8(6) . . ?
C4 C5 H5 125.0 . . ?
C1 C5 H5 125.0 . . ?
Fe1 C5 H5 127.3 . . ?
C10 C6 C7 108.5(13) . . ?
C10 C6 Fe1 70.0(8) . . ?
C7 C6 Fe1 69.8(7) . . ?
C10 C6 H6 125.8 . . ?
C7 C6 H6 125.8 . . ?
Fe1 C6 H6 126.0 . . ?
C8 C7 C6 107.1(13) . . ?
C8 C7 Fe1 68.3(7) . . ?
C6 C7 Fe1 69.5(7) . . ?
C8 C7 H7 126.4 . . ?
C6 C7 H7 126.4 . . ?
Fe1 C7 H7 127.3 . . ?
C9 C8 C7 107.6(14) . . ?
C9 C8 Fe1 71.0(8) . . ?
C7 C8 Fe1 71.2(8) . . ?
C9 C8 H8 126.2 . . ?
C7 C8 H8 126.2 . . ?
Fe1 C8 H8 123.2 . . ?
C8 C9 C10 108.2(13) . . ?
C8 C9 Fe1 68.6(8) . . ?
C10 C9 Fe1 69.5(8) . . ?
C8 C9 H9 125.9 . . ?
C10 C9 H9 125.9 . . ?
Fe1 C9 H9 127.6 . . ?
C6 C10 C9 108.5(14) . . ?
C6 C10 Fe1 70.9(9) . . ?
C9 C10 Fe1 70.2(8) . . ?
C6 C10 H10 125.8 . . ?
C9 C10 H10 125.8 . . ?
Fe1 C10 H10 124.7 . . ?
N1 C11 O1 114.7(10) . . ?
N1 C11 C2 126.6(9) . . ?
O1 C11 C2 118.7(10) . . ?
N1 C12 C13 102.3(9) . . ?
N1 C12 C14 112.0(9) . . ?
C13 C12 C14 116.7(9) . . ?
N1 C12 H12 108.5 . . ?
C13 C12 H12 108.5 . . ?
C14 C12 H12 108.5 . . ?
O1 C13 C12 103.2(8) . . ?
O1 C13 H13A 111.1 . . ?
C12 C13 H13A 111.1 . . ?
O1 C13 H13B 111.1 . . ?
C12 C13 H13B 111.1 . . ?
H13A C13 H13B 109.1 . . ?
C15 C14 C12 109.5(10) . . ?
C15 C14 C16 110.3(10) . . ?
C12 C14 C16 112.2(9) . . ?
C15 C14 H14 108.2 . . ?
C12 C14 H14 108.2 . . ?
C16 C14 H14 108.2 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C21 105.4(9) . . ?
C18 C17 Au2 129.9(7) . . ?
C21 C17 Au2 124.7(8) . . ?
C18 C17 Fe2 68.1(6) . . ?
C21 C17 Fe2 67.8(6) . . ?
Au2 C17 Fe2 129.7(6) . . ?
C17 C18 C19 110.6(9) . . ?
C17 C18 C27 124.2(9) . . ?
C19 C18 C27 125.1(10) . . ?
C17 C18 Fe2 71.1(6) . . ?
C19 C18 Fe2 68.3(6) . . ?
C27 C18 Fe2 124.7(8) . . ?
C20 C19 C18 107.0(9) . . ?
C20 C19 Fe2 71.2(6) . . ?
C18 C19 Fe2 70.1(6) . . ?
C20 C19 H19 126.5 . . ?
C18 C19 H19 126.5 . . ?
Fe2 C19 H19 123.8 . . ?
C19 C20 C21 107.5(9) . . ?
C19 C20 Fe2 67.9(7) . . ?
C21 C20 Fe2 68.2(6) . . ?
C19 C20 H20 126.2 . . ?
C21 C20 H20 126.2 . . ?
Fe2 C20 H20 129.2 . . ?
C17 C21 C20 109.2(9) . . ?
C17 C21 Fe2 71.2(7) . . ?
C20 C21 Fe2 70.1(6) . . ?
C17 C21 H21 125.4 . . ?
C20 C21 H21 125.4 . . ?
Fe2 C21 H21 124.9 . . ?
C23 C22 C26 107.9(13) . . ?
C23 C22 Fe2 70.1(8) . . ?
C26 C22 Fe2 70.0(8) . . ?
C23 C22 H22 126.0 . . ?
C26 C22 H22 126.0 . . ?
Fe2 C22 H22 125.4 . . ?
C22 C23 C24 108.8(12) . . ?
C22 C23 Fe2 69.6(7) . . ?
C24 C23 Fe2 68.8(8) . . ?
C22 C23 H23 125.6 . . ?
C24 C23 H23 125.6 . . ?
Fe2 C23 H23 127.7 . . ?
C23 C24 C25 106.2(13) . . ?
C23 C24 Fe2 70.3(8) . . ?
C25 C24 Fe2 69.3(8) . . ?
C23 C24 H24 126.9 . . ?
C25 C24 H24 126.9 . . ?
Fe2 C24 H24 125.0 . . ?
C26 C25 C24 108.8(13) . . ?
C26 C25 Fe2 70.7(8) . . ?
C24 C25 Fe2 69.1(8) . . ?
C26 C25 H25 125.6 . . ?
C24 C25 H25 125.6 . . ?
Fe2 C25 H25 126.2 . . ?
C25 C26 C22 108.2(13) . . ?
C25 C26 Fe2 69.2(8) . . ?
C22 C26 Fe2 69.4(8) . . ?
C25 C26 H26 125.9 . . ?
C22 C26 H26 125.9 . . ?
Fe2 C26 H26 127.1 . . ?
N2 C27 O2 115.2(10) . . ?
N2 C27 C18 125.8(10) . . ?
O2 C27 C18 118.9(10) . . ?
N2 C28 C30 108.9(9) . . ?
N2 C28 C29 100.6(8) . . ?
C30 C28 C29 115.0(10) . . ?
N2 C28 H28 110.6 . . ?
C30 C28 H28 110.6 . . ?
C29 C28 H28 110.6 . . ?
O2 C29 C28 105.2(8) . . ?
O2 C29 H29A 110.7 . . ?
C28 C29 H29A 110.7 . . ?
O2 C29 H29B 110.7 . . ?
C28 C29 H29B 110.7 . . ?
H29A C29 H29B 108.8 . . ?
C32 C30 C31 112.8(11) . . ?
C32 C30 C28 110.4(10) . . ?
C31 C30 C28 113.3(10) . . ?
C32 C30 H30 106.6 . . ?
C31 C30 H30 106.6 . . ?
C28 C30 H30 106.6 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C17 127.4(5) . . . . ?
N2 Au1 Au2 C17 -52.7(4) . . . . ?
Cl2 Au1 Au2 C17 162(4) . . . . ?
C1 Au1 Au2 N1 -50.7(4) . . . . ?
N2 Au1 Au2 N1 129.1(4) . . . . ?
Cl2 Au1 Au2 N1 -16(4) . . . . ?
C1 Au1 Au2 Cl1 29.6(10) . . . . ?
N2 Au1 Au2 Cl1 -150.6(10) . . . . ?
Cl2 Au1 Au2 Cl1 64(4) . . . . ?
C17 Au2 N1 C11 -8(11) . . . . ?
Cl1 Au2 N1 C11 -123.5(8) . . . . ?
Au1 Au2 N1 C11 52.8(8) . . . . ?
C17 Au2 N1 C12 161(10) . . . . ?
Cl1 Au2 N1 C12 45.3(8) . . . . ?
Au1 Au2 N1 C12 -138.5(8) . . . . ?
N2 Au1 C1 C2 37(20) . . . . ?
Cl2 Au1 C1 C2 -135.1(10) . . . . ?
Au2 Au1 C1 C2 44.2(10) . . . . ?
N2 Au1 C1 C5 -153(19) . . . . ?
Cl2 Au1 C1 C5 35.0(9) . . . . ?
Au2 Au1 C1 C5 -145.6(9) . . . . ?
N2 Au1 C1 Fe1 -60(20) . . . . ?
Cl2 Au1 C1 Fe1 128.1(7) . . . . ?
Au2 Au1 C1 Fe1 -52.5(7) . . . . ?
C8 Fe1 C1 C2 -81.1(9) . . . . ?
C10 Fe1 C1 C2 164.0(12) . . . . ?
C4 Fe1 C1 C2 80.9(7) . . . . ?
C9 Fe1 C1 C2 -51.9(17) . . . . ?
C6 Fe1 C1 C2 -164.9(7) . . . . ?
C5 Fe1 C1 C2 116.9(9) . . . . ?
C7 Fe1 C1 C2 -122.8(7) . . . . ?
C3 Fe1 C1 C2 37.1(6) . . . . ?
C8 Fe1 C1 C5 162.0(8) . . . . ?
C10 Fe1 C1 C5 47.1(15) . . . . ?
C2 Fe1 C1 C5 -116.9(9) . . . . ?
C4 Fe1 C1 C5 -36.0(7) . . . . ?
C9 Fe1 C1 C5 -168.8(14) . . . . ?
C6 Fe1 C1 C5 78.2(8) . . . . ?
C7 Fe1 C1 C5 120.3(7) . . . . ?
C3 Fe1 C1 C5 -79.8(7) . . . . ?
C8 Fe1 C1 Au1 43.0(11) . . . . ?
C10 Fe1 C1 Au1 -71.9(17) . . . . ?
C2 Fe1 C1 Au1 124.1(11) . . . . ?
C4 Fe1 C1 Au1 -155.0(9) . . . . ?
C9 Fe1 C1 Au1 72.2(17) . . . . ?
C6 Fe1 C1 Au1 -40.8(10) . . . . ?
C5 Fe1 C1 Au1 -119.0(11) . . . . ?
C7 Fe1 C1 Au1 1.3(10) . . . . ?
C3 Fe1 C1 Au1 161.2(9) . . . . ?
C1 Au1 N2 C27 64(19) . . . . ?
Cl2 Au1 N2 C27 -123.9(9) . . . . ?
Au2 Au1 N2 C27 56.7(9) . . . . ?
C1 Au1 N2 C28 -128(19) . . . . ?
Cl2 Au1 N2 C28 44.2(8) . . . . ?
Au2 Au1 N2 C28 -135.2(8) . . . . ?
C5 C1 C2 C3 0.0(12) . . . . ?
Au1 C1 C2 C3 171.7(8) . . . . ?
Fe1 C1 C2 C3 -59.5(8) . . . . ?
C5 C1 C2 C11 -177.8(10) . . . . ?
Au1 C1 C2 C11 -6.2(16) . . . . ?
Fe1 C1 C2 C11 122.7(10) . . . . ?
C5 C1 C2 Fe1 59.5(7) . . . . ?
Au1 C1 C2 Fe1 -128.8(9) . . . . ?
C8 Fe1 C2 C3 -120.5(8) . . . . ?
C10 Fe1 C2 C3 -41.2(18) . . . . ?
C4 Fe1 C2 C3 37.5(7) . . . . ?
C9 Fe1 C2 C3 -78.3(8) . . . . ?
C6 Fe1 C2 C3 160.3(14) . . . . ?
C5 Fe1 C2 C3 81.1(7) . . . . ?
C7 Fe1 C2 C3 -163.0(7) . . . . ?
C1 Fe1 C2 C3 120.4(9) . . . . ?
C8 Fe1 C2 C1 119.1(7) . . . . ?
C10 Fe1 C2 C1 -161.6(15) . . . . ?
C4 Fe1 C2 C1 -82.9(7) . . . . ?
C9 Fe1 C2 C1 161.3(7) . . . . ?
C6 Fe1 C2 C1 39.9(17) . . . . ?
C5 Fe1 C2 C1 -39.4(6) . . . . ?
C7 Fe1 C2 C1 76.6(8) . . . . ?
C3 Fe1 C2 C1 -120.4(9) . . . . ?
C8 Fe1 C2 C11 -1.2(11) . . . . ?
C10 Fe1 C2 C11 78.1(19) . . . . ?
C4 Fe1 C2 C11 156.8(11) . . . . ?
C9 Fe1 C2 C11 41.0(12) . . . . ?
C6 Fe1 C2 C11 -80.4(17) . . . . ?
C5 Fe1 C2 C11 -159.7(11) . . . . ?
C7 Fe1 C2 C11 -43.7(12) . . . . ?
C3 Fe1 C2 C11 119.3(12) . . . . ?
C1 Fe1 C2 C11 -120.3(13) . . . . ?
C1 C2 C3 C4 1.4(12) . . . . ?
C11 C2 C3 C4 179.3(10) . . . . ?
Fe1 C2 C3 C4 -58.1(8) . . . . ?
C1 C2 C3 Fe1 59.5(8) . . . . ?
C11 C2 C3 Fe1 -122.6(10) . . . . ?
C8 Fe1 C3 C2 79.8(8) . . . . ?
C10 Fe1 C3 C2 164.5(7) . . . . ?
C4 Fe1 C3 C2 -119.7(10) . . . . ?
C9 Fe1 C3 C2 122.1(7) . . . . ?
C6 Fe1 C3 C2 -162.8(12) . . . . ?
C5 Fe1 C3 C2 -81.8(7) . . . . ?
C7 Fe1 C3 C2 47.1(18) . . . . ?
C1 Fe1 C3 C2 -37.2(6) . . . . ?
C8 Fe1 C3 C4 -160.4(8) . . . . ?
C10 Fe1 C3 C4 -75.7(9) . . . . ?
C2 Fe1 C3 C4 119.7(10) . . . . ?
C9 Fe1 C3 C4 -118.1(8) . . . . ?
C6 Fe1 C3 C4 -43.0(16) . . . . ?
C5 Fe1 C3 C4 38.0(7) . . . . ?
C7 Fe1 C3 C4 166.8(14) . . . . ?
C1 Fe1 C3 C4 82.5(8) . . . . ?
C2 C3 C4 C5 -2.3(13) . . . . ?
Fe1 C3 C4 C5 -60.4(8) . . . . ?
C2 C3 C4 Fe1 58.1(7) . . . . ?
C8 Fe1 C4 C5 170.0(15) . . . . ?
C10 Fe1 C4 C5 -119.5(8) . . . . ?
C2 Fe1 C4 C5 80.8(8) . . . . ?
C9 Fe1 C4 C5 -160.0(8) . . . . ?
C6 Fe1 C4 C5 -79.6(9) . . . . ?
C7 Fe1 C4 C5 -50.4(17) . . . . ?
C3 Fe1 C4 C5 118.3(10) . . . . ?
C1 Fe1 C4 C5 36.8(7) . . . . ?
C8 Fe1 C4 C3 51.6(19) . . . . ?
C10 Fe1 C4 C3 122.2(8) . . . . ?
C2 Fe1 C4 C3 -37.5(7) . . . . ?
C9 Fe1 C4 C3 81.6(9) . . . . ?
C6 Fe1 C4 C3 162.0(7) . . . . ?
C5 Fe1 C4 C3 -118.3(11) . . . . ?
C7 Fe1 C4 C3 -168.7(13) . . . . ?
C1 Fe1 C4 C3 -81.5(7) . . . . ?
C3 C4 C5 C1 2.3(13) . . . . ?
Fe1 C4 C5 C1 -58.1(8) . . . . ?
C3 C4 C5 Fe1 60.5(8) . . . . ?
C2 C1 C5 C4 -1.5(12) . . . . ?
Au1 C1 C5 C4 -173.5(8) . . . . ?
Fe1 C1 C5 C4 57.9(8) . . . . ?
C2 C1 C5 Fe1 -59.4(7) . . . . ?
Au1 C1 C5 Fe1 128.6(8) . . . . ?
C8 Fe1 C5 C4 -169.8(16) . . . . ?
C10 Fe1 C5 C4 77.8(9) . . . . ?
C2 Fe1 C5 C4 -82.6(8) . . . . ?
C9 Fe1 C5 C4 48.6(16) . . . . ?
C6 Fe1 C5 C4 117.9(8) . . . . ?
C7 Fe1 C5 C4 159.4(8) . . . . ?
C3 Fe1 C5 C4 -38.4(7) . . . . ?
C1 Fe1 C5 C4 -121.7(10) . . . . ?
C8 Fe1 C5 C1 -48.1(19) . . . . ?
C10 Fe1 C5 C1 -160.5(7) . . . . ?
C2 Fe1 C5 C1 39.1(6) . . . . ?
C4 Fe1 C5 C1 121.7(10) . . . . ?
C9 Fe1 C5 C1 170.3(12) . . . . ?
C6 Fe1 C5 C1 -120.4(7) . . . . ?
C7 Fe1 C5 C1 -78.9(8) . . . . ?
C3 Fe1 C5 C1 83.3(7) . . . . ?
C8 Fe1 C6 C10 81.9(10) . . . . ?
C2 Fe1 C6 C10 168.6(13) . . . . ?
C4 Fe1 C6 C10 -77.2(10) . . . . ?
C9 Fe1 C6 C10 38.1(9) . . . . ?
C5 Fe1 C6 C10 -119.0(9) . . . . ?
C7 Fe1 C6 C10 119.6(12) . . . . ?
C3 Fe1 C6 C10 -45.9(17) . . . . ?
C1 Fe1 C6 C10 -161.4(9) . . . . ?
C8 Fe1 C6 C7 -37.6(8) . . . . ?
C10 Fe1 C6 C7 -119.6(12) . . . . ?
C2 Fe1 C6 C7 49.1(17) . . . . ?
C4 Fe1 C6 C7 163.3(8) . . . . ?
C9 Fe1 C6 C7 -81.5(8) . . . . ?
C5 Fe1 C6 C7 121.5(8) . . . . ?
C3 Fe1 C6 C7 -165.4(12) . . . . ?
C1 Fe1 C6 C7 79.0(9) . . . . ?
C10 C6 C7 C8 -1.4(15) . . . . ?
Fe1 C6 C7 C8 58.1(9) . . . . ?
C10 C6 C7 Fe1 -59.5(9) . . . . ?
C10 Fe1 C7 C8 -82.6(10) . . . . ?
C2 Fe1 C7 C8 79.1(10) . . . . ?
C4 Fe1 C7 C8 -159.4(13) . . . . ?
C9 Fe1 C7 C8 -38.8(9) . . . . ?
C6 Fe1 C7 C8 -119.1(12) . . . . ?
C5 Fe1 C7 C8 164.1(9) . . . . ?
C3 Fe1 C7 C8 43.5(19) . . . . ?
C1 Fe1 C7 C8 121.2(9) . . . . ?
C8 Fe1 C7 C6 119.1(12) . . . . ?
C10 Fe1 C7 C6 36.5(8) . . . . ?
C2 Fe1 C7 C6 -161.7(7) . . . . ?
C4 Fe1 C7 C6 -40.2(17) . . . . ?
C9 Fe1 C7 C6 80.3(8) . . . . ?
C5 Fe1 C7 C6 -76.8(9) . . . . ?
C3 Fe1 C7 C6 162.7(14) . . . . ?
C1 Fe1 C7 C6 -119.6(8) . . . . ?
C6 C7 C8 C9 3.2(14) . . . . ?
Fe1 C7 C8 C9 62.1(9) . . . . ?
C6 C7 C8 Fe1 -58.9(9) . . . . ?
C10 Fe1 C8 C9 -36.9(9) . . . . ?
C2 Fe1 C8 C9 122.0(9) . . . . ?
C4 Fe1 C8 C9 41(2) . . . . ?
C6 Fe1 C8 C9 -79.2(9) . . . . ?
C5 Fe1 C8 C9 -158.4(14) . . . . ?
C7 Fe1 C8 C9 -117.0(13) . . . . ?
C3 Fe1 C8 C9 79.0(10) . . . . ?
C1 Fe1 C8 C9 165.5(8) . . . . ?
C10 Fe1 C8 C7 80.1(9) . . . . ?
C2 Fe1 C8 C7 -121.0(8) . . . . ?
C4 Fe1 C8 C7 157.5(14) . . . . ?
C9 Fe1 C8 C7 117.0(13) . . . . ?
C6 Fe1 C8 C7 37.8(8) . . . . ?
C5 Fe1 C8 C7 -41(2) . . . . ?
C3 Fe1 C8 C7 -164.1(8) . . . . ?
C1 Fe1 C8 C7 -77.5(10) . . . . ?
C7 C8 C9 C10 -3.9(15) . . . . ?
Fe1 C8 C9 C10 58.4(9) . . . . ?
C7 C8 C9 Fe1 -62.3(9) . . . . ?
C10 Fe1 C9 C8 120.3(13) . . . . ?
C2 Fe1 C9 C8 -78.2(10) . . . . ?
C4 Fe1 C9 C8 -164.2(9) . . . . ?
C6 Fe1 C9 C8 83.2(10) . . . . ?
C5 Fe1 C9 C8 160.5(12) . . . . ?
C7 Fe1 C9 C8 38.9(9) . . . . ?
C3 Fe1 C9 C8 -120.9(9) . . . . ?
C1 Fe1 C9 C8 -39.0(19) . . . . ?
C8 Fe1 C9 C10 -120.3(13) . . . . ?
C2 Fe1 C9 C10 161.5(8) . . . . ?
C4 Fe1 C9 C10 75.5(9) . . . . ?
C6 Fe1 C9 C10 -37.0(8) . . . . ?
C5 Fe1 C9 C10 40.2(17) . . . . ?
C7 Fe1 C9 C10 -81.4(9) . . . . ?
C3 Fe1 C9 C10 118.8(8) . . . . ?
C1 Fe1 C9 C10 -159.3(13) . . . . ?
C7 C6 C10 C9 -1.0(15) . . . . ?
Fe1 C6 C10 C9 -60.4(9) . . . . ?
C7 C6 C10 Fe1 59.4(9) . . . . ?
C8 C9 C10 C6 3.1(15) . . . . ?
Fe1 C9 C10 C6 60.8(10) . . . . ?
C8 C9 C10 Fe1 -57.8(9) . . . . ?
C8 Fe1 C10 C6 -81.7(9) . . . . ?
C2 Fe1 C10 C6 -168.6(13) . . . . ?
C4 Fe1 C10 C6 119.3(9) . . . . ?
C9 Fe1 C10 C6 -118.8(12) . . . . ?
C5 Fe1 C10 C6 78.0(10) . . . . ?
C7 Fe1 C10 C6 -37.9(8) . . . . ?
C3 Fe1 C10 C6 160.6(8) . . . . ?
C1 Fe1 C10 C6 43.6(18) . . . . ?
C8 Fe1 C10 C9 37.0(8) . . . . ?
C2 Fe1 C10 C9 -49.8(19) . . . . ?
C4 Fe1 C10 C9 -121.9(8) . . . . ?
C6 Fe1 C10 C9 118.8(12) . . . . ?
C5 Fe1 C10 C9 -163.2(8) . . . . ?
C7 Fe1 C10 C9 80.9(9) . . . . ?
C3 Fe1 C10 C9 -80.7(9) . . . . ?
C1 Fe1 C10 C9 162.4(11) . . . . ?
C12 N1 C11 O1 -3.4(13) . . . . ?
Au2 N1 C11 O1 166.9(7) . . . . ?
C12 N1 C11 C2 174.1(10) . . . . ?
Au2 N1 C11 C2 -15.6(15) . . . . ?
C13 O1 C11 N1 -5.1(12) . . . . ?
C13 O1 C11 C2 177.2(9) . . . . ?
C3 C2 C11 N1 162.2(11) . . . . ?
C1 C2 C11 N1 -20.3(17) . . . . ?
Fe1 C2 C11 N1 71.3(14) . . . . ?
C3 C2 C11 O1 -20.4(16) . . . . ?
C1 C2 C11 O1 157.1(10) . . . . ?
Fe1 C2 C11 O1 -111.3(10) . . . . ?
C11 N1 C12 C13 9.8(11) . . . . ?
Au2 N1 C12 C13 -160.3(7) . . . . ?
C11 N1 C12 C14 -116.0(10) . . . . ?
Au2 N1 C12 C14 73.9(11) . . . . ?
C11 O1 C13 C12 10.8(11) . . . . ?
N1 C12 C13 O1 -11.9(10) . . . . ?
C14 C12 C13 O1 110.7(11) . . . . ?
N1 C12 C14 C15 178.3(9) . . . . ?
C13 C12 C14 C15 60.9(13) . . . . ?
N1 C12 C14 C16 55.4(12) . . . . ?
C13 C12 C14 C16 -62.0(13) . . . . ?
N1 Au2 C17 C18 101(11) . . . . ?
Cl1 Au2 C17 C18 -143.8(10) . . . . ?
Au1 Au2 C17 C18 39.9(10) . . . . ?
N1 Au2 C17 C21 -77(11) . . . . ?
Cl1 Au2 C17 C21 38.5(10) . . . . ?
Au1 Au2 C17 C21 -137.8(10) . . . . ?
N1 Au2 C17 Fe2 -166(10) . . . . ?
Cl1 Au2 C17 Fe2 -50.3(7) . . . . ?
Au1 Au2 C17 Fe2 133.5(6) . . . . ?
C19 Fe2 C17 C18 -36.4(6) . . . . ?
C21 Fe2 C17 C18 -118.2(9) . . . . ?
C24 Fe2 C17 C18 171.5(7) . . . . ?
C25 Fe2 C17 C18 126.6(7) . . . . ?
C22 Fe2 C17 C18 42.4(15) . . . . ?
C20 Fe2 C17 C18 -80.1(6) . . . . ?
C23 Fe2 C17 C18 -148.2(16) . . . . ?
C26 Fe2 C17 C18 83.5(8) . . . . ?
C19 Fe2 C17 C21 81.8(7) . . . . ?
C18 Fe2 C17 C21 118.2(9) . . . . ?
C24 Fe2 C17 C21 -70.3(8) . . . . ?
C25 Fe2 C17 C21 -115.2(7) . . . . ?
C22 Fe2 C17 C21 160.6(12) . . . . ?
C20 Fe2 C17 C21 38.1(6) . . . . ?
C23 Fe2 C17 C21 -30.0(18) . . . . ?
C26 Fe2 C17 C21 -158.3(7) . . . . ?
C19 Fe2 C17 Au2 -160.8(8) . . . . ?
C21 Fe2 C17 Au2 117.4(10) . . . . ?
C18 Fe2 C17 Au2 -124.3(10) . . . . ?
C24 Fe2 C17 Au2 47.1(10) . . . . ?
C25 Fe2 C17 Au2 2.3(9) . . . . ?
C22 Fe2 C17 Au2 -82.0(15) . . . . ?
C20 Fe2 C17 Au2 155.6(8) . . . . ?
C23 Fe2 C17 Au2 87.5(17) . . . . ?
C26 Fe2 C17 Au2 -40.9(9) . . . . ?
C21 C17 C18 C19 -0.8(13) . . . . ?
Au2 C17 C18 C19 -178.9(8) . . . . ?
Fe2 C17 C18 C19 56.9(8) . . . . ?
C21 C17 C18 C27 -177.5(11) . . . . ?
Au2 C17 C18 C27 4.4(17) . . . . ?
Fe2 C17 C18 C27 -119.7(11) . . . . ?
C21 C17 C18 Fe2 -57.8(8) . . . . ?
Au2 C17 C18 Fe2 124.2(10) . . . . ?
C19 Fe2 C18 C17 122.4(9) . . . . ?
C21 Fe2 C18 C17 38.4(6) . . . . ?
C24 Fe2 C18 C17 -29(2) . . . . ?
C25 Fe2 C18 C17 -76.2(8) . . . . ?
C22 Fe2 C18 C17 -162.9(6) . . . . ?
C20 Fe2 C18 C17 83.5(6) . . . . ?
C23 Fe2 C18 C17 157.7(10) . . . . ?
C26 Fe2 C18 C17 -118.5(7) . . . . ?
C21 Fe2 C18 C19 -84.0(7) . . . . ?
C24 Fe2 C18 C19 -151(2) . . . . ?
C25 Fe2 C18 C19 161.4(8) . . . . ?
C22 Fe2 C18 C19 74.7(8) . . . . ?
C20 Fe2 C18 C19 -39.0(7) . . . . ?
C23 Fe2 C18 C19 35.3(14) . . . . ?
C26 Fe2 C18 C19 119.1(7) . . . . ?
C17 Fe2 C18 C19 -122.4(9) . . . . ?
C19 Fe2 C18 C27 -118.6(12) . . . . ?
C21 Fe2 C18 C27 157.4(10) . . . . ?
C24 Fe2 C18 C27 90(2) . . . . ?
C25 Fe2 C18 C27 42.8(12) . . . . ?
C22 Fe2 C18 C27 -43.9(11) . . . . ?
C20 Fe2 C18 C27 -157.5(10) . . . . ?
C23 Fe2 C18 C27 -83.3(14) . . . . ?
C26 Fe2 C18 C27 0.5(11) . . . . ?
C17 Fe2 C18 C27 119.0(12) . . . . ?
C17 C18 C19 C20 3.4(13) . . . . ?
C27 C18 C19 C20 -179.9(11) . . . . ?
Fe2 C18 C19 C20 62.0(8) . . . . ?
C17 C18 C19 Fe2 -58.6(8) . . . . ?
C27 C18 C19 Fe2 118.1(11) . . . . ?
C21 Fe2 C19 C20 -37.4(6) . . . . ?
C18 Fe2 C19 C20 -116.9(9) . . . . ?
C24 Fe2 C19 C20 48.9(13) . . . . ?
C25 Fe2 C19 C20 179.8(17) . . . . ?
C22 Fe2 C19 C20 121.0(7) . . . . ?
C23 Fe2 C19 C20 79.7(8) . . . . ?
C26 Fe2 C19 C20 159.6(7) . . . . ?
C17 Fe2 C19 C20 -81.1(6) . . . . ?
C21 Fe2 C19 C18 79.5(7) . . . . ?
C24 Fe2 C19 C18 165.8(10) . . . . ?
C25 Fe2 C19 C18 -63(2) . . . . ?
C22 Fe2 C19 C18 -122.1(7) . . . . ?
C20 Fe2 C19 C18 116.9(9) . . . . ?
C23 Fe2 C19 C18 -163.5(7) . . . . ?
C26 Fe2 C19 C18 -83.5(8) . . . . ?
C17 Fe2 C19 C18 35.8(6) . . . . ?
C18 C19 C20 C21 -4.6(13) . . . . ?
Fe2 C19 C20 C21 56.7(8) . . . . ?
C18 C19 C20 Fe2 -61.3(8) . . . . ?
C21 Fe2 C20 C19 120.8(9) . . . . ?
C18 Fe2 C20 C19 39.5(6) . . . . ?
C24 Fe2 C20 C19 -155.5(7) . . . . ?
C25 Fe2 C20 C19 -179.9(11) . . . . ?
C22 Fe2 C20 C19 -75.3(8) . . . . ?
C23 Fe2 C20 C19 -114.4(7) . . . . ?
C26 Fe2 C20 C19 -54.8(16) . . . . ?
C17 Fe2 C20 C19 83.3(6) . . . . ?
C19 Fe2 C20 C21 -120.8(9) . . . . ?
C18 Fe2 C20 C21 -81.3(6) . . . . ?
C24 Fe2 C20 C21 83.6(7) . . . . ?
C25 Fe2 C20 C21 59.3(14) . . . . ?
C22 Fe2 C20 C21 163.8(7) . . . . ?
C23 Fe2 C20 C21 124.7(7) . . . . ?
C26 Fe2 C20 C21 -175.7(13) . . . . ?
C17 Fe2 C20 C21 -37.5(6) . . . . ?
C18 C17 C21 C20 -2.1(13) . . . . ?
Au2 C17 C21 C20 176.1(8) . . . . ?
Fe2 C17 C21 C20 -60.0(8) . . . . ?
C18 C17 C21 Fe2 58.0(8) . . . . ?
Au2 C17 C21 Fe2 -123.9(8) . . . . ?
C19 C20 C21 C17 4.2(13) . . . . ?
Fe2 C20 C21 C17 60.7(8) . . . . ?
C19 C20 C21 Fe2 -56.5(8) . . . . ?
C19 Fe2 C21 C17 -82.8(7) . . . . ?
C18 Fe2 C21 C17 -38.2(6) . . . . ?
C24 Fe2 C21 C17 127.9(7) . . . . ?
C25 Fe2 C21 C17 85.9(8) . . . . ?
C22 Fe2 C21 C17 -160.3(13) . . . . ?
C20 Fe2 C21 C17 -119.5(9) . . . . ?
C23 Fe2 C21 C17 169.1(7) . . . . ?
C26 Fe2 C21 C17 56.4(16) . . . . ?
C19 Fe2 C21 C20 36.8(6) . . . . ?
C18 Fe2 C21 C20 81.3(6) . . . . ?
C24 Fe2 C21 C20 -112.6(7) . . . . ?
C25 Fe2 C21 C20 -154.6(7) . . . . ?
C22 Fe2 C21 C20 -40.8(16) . . . . ?
C23 Fe2 C21 C20 -71.4(8) . . . . ?
C26 Fe2 C21 C20 175.9(13) . . . . ?
C17 Fe2 C21 C20 119.5(9) . . . . ?
C19 Fe2 C22 C23 -112.9(9) . . . . ?
C21 Fe2 C22 C23 -41.7(18) . . . . ?
C18 Fe2 C22 C23 -154.1(8) . . . . ?
C24 Fe2 C22 C23 37.0(8) . . . . ?
C25 Fe2 C22 C23 81.8(9) . . . . ?
C20 Fe2 C22 C23 -72.1(9) . . . . ?
C26 Fe2 C22 C23 118.7(12) . . . . ?
C17 Fe2 C22 C23 174.8(12) . . . . ?
C19 Fe2 C22 C26 128.4(8) . . . . ?
C21 Fe2 C22 C26 -160.4(12) . . . . ?
C18 Fe2 C22 C26 87.2(9) . . . . ?
C24 Fe2 C22 C26 -81.7(9) . . . . ?
C25 Fe2 C22 C26 -36.9(8) . . . . ?
C20 Fe2 C22 C26 169.2(7) . . . . ?
C23 Fe2 C22 C26 -118.7(12) . . . . ?
C17 Fe2 C22 C26 56.1(16) . . . . ?
C26 C22 C23 C24 2.5(16) . . . . ?
Fe2 C22 C23 C24 -57.6(10) . . . . ?
C26 C22 C23 Fe2 60.1(9) . . . . ?
C19 Fe2 C23 C22 81.7(9) . . . . ?
C21 Fe2 C23 C22 163.3(7) . . . . ?
C18 Fe2 C23 C22 56.6(15) . . . . ?
C24 Fe2 C23 C22 -121.0(12) . . . . ?
C25 Fe2 C23 C22 -81.3(9) . . . . ?
C20 Fe2 C23 C22 123.0(8) . . . . ?
C26 Fe2 C23 C22 -38.0(8) . . . . ?
C17 Fe2 C23 C22 -174.0(13) . . . . ?
C19 Fe2 C23 C24 -157.3(8) . . . . ?
C21 Fe2 C23 C24 -75.8(10) . . . . ?
C18 Fe2 C23 C24 177.6(10) . . . . ?
C25 Fe2 C23 C24 39.6(9) . . . . ?
C22 Fe2 C23 C24 121.0(12) . . . . ?
C20 Fe2 C23 C24 -116.0(9) . . . . ?
C26 Fe2 C23 C24 82.9(9) . . . . ?
C17 Fe2 C23 C24 -53.0(19) . . . . ?
C22 C23 C24 C25 -2.3(16) . . . . ?
Fe2 C23 C24 C25 -60.4(10) . . . . ?
C22 C23 C24 Fe2 58.1(10) . . . . ?
C19 Fe2 C24 C23 44.9(15) . . . . ?
C21 Fe2 C24 C23 121.7(8) . . . . ?
C18 Fe2 C24 C23 -175.7(19) . . . . ?
C25 Fe2 C24 C23 -116.8(12) . . . . ?
C22 Fe2 C24 C23 -36.5(8) . . . . ?
C20 Fe2 C24 C23 78.4(9) . . . . ?
C26 Fe2 C24 C23 -80.1(9) . . . . ?
C17 Fe2 C24 C23 161.5(7) . . . . ?
C19 Fe2 C24 C25 161.7(10) . . . . ?
C21 Fe2 C24 C25 -121.5(8) . . . . ?
C18 Fe2 C24 C25 -59(3) . . . . ?
C22 Fe2 C24 C25 80.3(9) . . . . ?
C20 Fe2 C24 C25 -164.8(8) . . . . ?
C23 Fe2 C24 C25 116.8(12) . . . . ?
C26 Fe2 C24 C25 36.7(8) . . . . ?
C17 Fe2 C24 C25 -81.7(10) . . . . ?
C23 C24 C25 C26 1.2(16) . . . . ?
Fe2 C24 C25 C26 -59.8(10) . . . . ?
C23 C24 C25 Fe2 61.1(10) . . . . ?
C19 Fe2 C25 C26 -26(2) . . . . ?
C21 Fe2 C25 C26 -163.8(7) . . . . ?
C18 Fe2 C25 C26 -76.3(10) . . . . ?
C24 Fe2 C25 C26 119.9(12) . . . . ?
C22 Fe2 C25 C26 37.4(8) . . . . ?
C20 Fe2 C25 C26 153.7(11) . . . . ?
C23 Fe2 C25 C26 80.9(9) . . . . ?
C17 Fe2 C25 C26 -119.2(8) . . . . ?
C19 Fe2 C25 C24 -145.9(17) . . . . ?
C21 Fe2 C25 C24 76.3(9) . . . . ?
C18 Fe2 C25 C24 163.8(8) . . . . ?
C22 Fe2 C25 C24 -82.5(9) . . . . ?
C20 Fe2 C25 C24 33.8(16) . . . . ?
C23 Fe2 C25 C24 -38.9(8) . . . . ?
C26 Fe2 C25 C24 -119.9(12) . . . . ?
C17 Fe2 C25 C24 120.9(8) . . . . ?
C24 C25 C26 C22 0.2(16) . . . . ?
Fe2 C25 C26 C22 -58.5(9) . . . . ?
C24 C25 C26 Fe2 58.8(10) . . . . ?
C23 C22 C26 C25 -1.7(15) . . . . ?
Fe2 C22 C26 C25 58.4(10) . . . . ?
C23 C22 C26 Fe2 -60.1(9) . . . . ?
C19 Fe2 C26 C25 171.5(8) . . . . ?
C21 Fe2 C26 C25 40.3(18) . . . . ?
C18 Fe2 C26 C25 126.3(8) . . . . ?
C24 Fe2 C26 C25 -38.1(8) . . . . ?
C22 Fe2 C26 C25 -120.0(12) . . . . ?
C20 Fe2 C26 C25 -147.5(13) . . . . ?
C23 Fe2 C26 C25 -82.2(9) . . . . ?
C17 Fe2 C26 C25 82.0(9) . . . . ?
C19 Fe2 C26 C22 -68.5(9) . . . . ?
C21 Fe2 C26 C22 160.4(12) . . . . ?
C18 Fe2 C26 C22 -113.6(8) . . . . ?
C24 Fe2 C26 C22 81.9(9) . . . . ?
C25 Fe2 C26 C22 120.0(12) . . . . ?
C20 Fe2 C26 C22 -27.5(18) . . . . ?
C23 Fe2 C26 C22 37.8(8) . . . . ?
C17 Fe2 C26 C22 -158.0(7) . . . . ?
C28 N2 C27 O2 -0.6(14) . . . . ?
Au1 N2 C27 O2 169.1(7) . . . . ?
C28 N2 C27 C18 175.3(11) . . . . ?
Au1 N2 C27 C18 -15.0(16) . . . . ?
C29 O2 C27 N2 -7.8(13) . . . . ?
C29 O2 C27 C18 176.0(10) . . . . ?
C17 C18 C27 N2 -28.7(19) . . . . ?
C19 C18 C27 N2 155.1(12) . . . . ?
Fe2 C18 C27 N2 -118.4(12) . . . . ?
C17 C18 C27 O2 147.1(11) . . . . ?
C19 C18 C27 O2 -29.1(17) . . . . ?
Fe2 C18 C27 O2 57.3(14) . . . . ?
C27 N2 C28 C30 -113.3(11) . . . . ?
Au1 N2 C28 C30 77.4(11) . . . . ?
C27 N2 C28 C29 7.9(12) . . . . ?
Au1 N2 C28 C29 -161.3(7) . . . . ?
C27 O2 C29 C28 12.1(11) . . . . ?
N2 C28 C29 O2 -11.9(11) . . . . ?
C30 C28 C29 O2 105.0(10) . . . . ?
N2 C28 C30 C32 -176.4(10) . . . . ?
C29 C28 C30 C32 71.6(13) . . . . ?
N2 C28 C30 C31 56.0(13) . . . . ?
C29 C28 C30 C31 -56.1(13) . . . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        28.34
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         5.672
_refine_diff_density_min         -2.707
_refine_diff_density_rms         0.281
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2120lm
_audit_block_doi                 10.5517/cc14grbp
_database_code_depnum_ccdc_archive 'CCDC 1056862'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1039/C5CC07018J 2015
_audit_update_record             
;
2015-03-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'compound 7' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C64 H72 Au4 Fe4 N4 O4, 2.5(C H2 Cl2)'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C66.50 H77 Au4 Cl5 Fe4 N4 O4'
_chemical_formula_weight         2184.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_H-M   'P 41 21 2'
_symmetry_space_group_name_Hall  'P 4abw 2nw'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'-y+1/2, x+1/2, z+1/4'
'y+1/2, -x+1/2, z+3/4'
'-x+1/2, y+1/2, -z+1/4'
'x+1/2, -y+1/2, -z+3/4'
'y, x, -z'
'-y, -x, -z+1/2'

_cell_length_a                   19.7785(10)
_cell_length_b                   19.7785(10)
_cell_length_c                   35.613(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     13931.4(14)
_cell_formula_units_Z            8
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    15923
_cell_measurement_theta_min      1.46
_cell_measurement_theta_max      28.36

_exptl_crystal_description       needle
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.083
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             8328
_exptl_absorpt_coefficient_mu    9.439
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.0488
_exptl_absorpt_correction_T_max  0.5423
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            350477
_diffrn_reflns_av_R_equivalents  0.0524
_diffrn_reflns_av_sigmaI/netI    0.0274
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -47
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_theta_min         1.46
_diffrn_reflns_theta_max         28.36
_reflns_number_total             17390
_reflns_number_gt                15923
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0271P)²+32.7854P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.012(4)
_refine_ls_number_reflns         17390
_refine_ls_number_parameters     900
_refine_ls_number_restraints     171
_refine_ls_R_factor_all          0.0316
_refine_ls_R_factor_gt           0.0244
_refine_ls_wR_factor_ref         0.0561
_refine_ls_wR_factor_gt          0.0538
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_restrained_S_all      1.057
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.060650(9) 0.561145(9) 0.899913(5) 0.01554(4) Uani 1 1 d . . .
Au2 Au -0.022778(9) 0.649192(9) 0.959476(5) 0.01635(4) Uani 1 1 d . . .
Au3 Au 0.093377(10) 0.556574(10) 1.081099(5) 0.01845(4) Uani 1 1 d . . .
Au4 Au 0.091247(10) 0.644058(10) 1.017691(5) 0.01857(4) Uani 1 1 d . . .
Fe1 Fe -0.14971(4) 0.42754(3) 0.941026(19) 0.01798(14) Uani 1 1 d . . .
Fe2 Fe -0.00346(3) 0.81473(3) 0.91523(2) 0.01735(14) Uani 1 1 d . . .
Fe3 Fe 0.14296(4) 0.39636(4) 1.04402(2) 0.02615(17) Uani 1 1 d . . .
Fe4 Fe 0.09940(4) 0.81504(4) 1.05739(2) 0.02238(16) Uani 1 1 d . . .
O1 O -0.11092(18) 0.50135(17) 1.03194(9) 0.0216(8) Uani 1 1 d . . .
O2 O -0.06586(19) 0.74021(16) 0.83306(9) 0.0214(7) Uani 1 1 d . . .
O3 O 0.1309(2) 0.47160(19) 0.95036(10) 0.0294(9) Uani 1 1 d . . .
O4 O 0.12723(19) 0.73588(19) 1.14496(10) 0.0260(8) Uani 1 1 d . . .
N1 N -0.0697(2) 0.5870(2) 0.99852(11) 0.0179(8) Uani 1 1 d . . .
N2 N -0.0746(2) 0.6425(2) 0.86391(11) 0.0175(8) Uani 1 1 d . . .
N3 N 0.1246(2) 0.5683(2) 0.98245(11) 0.0229(9) Uani 1 1 d . . .
N4 N 0.1192(2) 0.6354(2) 1.11623(11) 0.0191(9) Uani 1 1 d . . .
C1 C -0.0582(2) 0.4782(2) 0.93180(13) 0.0182(9) Uani 1 1 d . . .
C2 C -0.0732(2) 0.4712(2) 0.97123(12) 0.0168(9) Uani 1 1 d . . .
C3 C -0.0807(2) 0.4006(2) 0.97979(14) 0.0203(10) Uani 1 1 d . . .
H3 H -0.0914 0.3821 1.0037 0.024 Uiso 1 1 calc R . .
C4 C -0.0692(3) 0.3632(3) 0.94654(15) 0.0241(11) Uani 1 1 d . . .
H4 H -0.0704 0.3154 0.9441 0.029 Uiso 1 1 calc R . .
C5 C -0.0556(3) 0.4107(3) 0.91756(14) 0.0221(10) Uani 1 1 d . . .
H5 H -0.0461 0.3991 0.8922 0.026 Uiso 1 1 calc R . .
C6 C -0.2278(3) 0.4908(3) 0.92783(15) 0.0253(11) Uani 1 1 d . . .
H6 H -0.2251 0.5385 0.9253 0.030 Uiso 1 1 calc R . .
C7 C -0.2417(3) 0.4555(3) 0.96140(17) 0.0307(13) Uani 1 1 d . . .
H7 H -0.2500 0.4754 0.9852 0.037 Uiso 1 1 calc R . .
C8 C -0.2411(3) 0.3850(3) 0.95351(17) 0.0315(13) Uani 1 1 d . . .
H8 H -0.2488 0.3497 0.9711 0.038 Uiso 1 1 calc R . .
C9 C -0.2272(3) 0.3771(3) 0.91482(16) 0.0311(13) Uani 1 1 d . . .
H9 H -0.2242 0.3353 0.9018 0.037 Uiso 1 1 calc R . .
C10 C -0.2183(3) 0.4431(3) 0.89848(16) 0.0285(12) Uani 1 1 d . . .
H10 H -0.2081 0.4529 0.8730 0.034 Uiso 1 1 calc R . .
C11 C -0.0836(2) 0.5236(3) 0.99927(13) 0.0191(10) Uani 1 1 d . . .
C12 C -0.1073(3) 0.5570(3) 1.05880(14) 0.0261(11) Uani 1 1 d . . .
H12A H -0.0705 0.5497 1.0772 0.031 Uiso 1 1 calc R . .
H12B H -0.1506 0.5622 1.0725 0.031 Uiso 1 1 calc R . .
C13 C -0.0929(3) 0.6190(3) 1.03400(14) 0.0251(11) Uani 1 1 d . . .
H13 H -0.0546 0.6452 1.0452 0.030 Uiso 1 1 calc R . .
C14 C -0.1522(3) 0.6667(3) 1.02729(16) 0.0330(13) Uani 1 1 d . . .
H14 H -0.1371 0.7014 1.0087 0.040 Uiso 1 1 calc R . .
C15 C -0.2142(3) 0.6296(3) 1.0100(2) 0.0443(17) Uani 1 1 d . . .
H15A H -0.2315 0.5963 1.0280 0.066 Uiso 1 1 calc R . .
H15B H -0.2004 0.6066 0.9869 0.066 Uiso 1 1 calc R . .
H15C H -0.2497 0.6626 1.0043 0.066 Uiso 1 1 calc R . .
C16 C -0.1712(4) 0.7039(3) 1.06342(19) 0.0472(18) Uani 1 1 d . . .
H16A H -0.2045 0.7392 1.0577 0.071 Uiso 1 1 calc R . .
H16B H -0.1307 0.7247 1.0743 0.071 Uiso 1 1 calc R . .
H16C H -0.1907 0.6718 1.0814 0.071 Uiso 1 1 calc R . .
C17 C 0.0222(2) 0.7137(2) 0.92421(13) 0.0183(10) Uani 1 1 d . . .
C18 C 0.0074(3) 0.7281(3) 0.88556(14) 0.0206(10) Uani 1 1 d . . .
C19 C 0.0524(3) 0.7802(2) 0.87186(14) 0.0202(10) Uani 1 1 d . . .
H19 H 0.0530 0.7991 0.8473 0.024 Uiso 1 1 calc R . .
C20 C 0.0956(3) 0.7976(2) 0.90212(15) 0.0219(11) Uani 1 1 d . . .
H20 H 0.1308 0.8303 0.9014 0.026 Uiso 1 1 calc R . .
C21 C 0.0772(2) 0.7582(2) 0.93342(15) 0.0198(10) Uani 1 1 d . . .
H21 H 0.0984 0.7606 0.9573 0.024 Uiso 1 1 calc R . .
C22 C -0.0843(3) 0.8369(3) 0.94901(14) 0.0219(11) Uani 1 1 d . . .
H22 H -0.1046 0.8075 0.9668 0.026 Uiso 1 1 calc R . .
C23 C -0.1025(3) 0.8425(3) 0.91047(15) 0.0264(12) Uani 1 1 d . . .
H23 H -0.1366 0.8174 0.8979 0.032 Uiso 1 1 calc R . .
C24 C -0.0598(3) 0.8927(3) 0.89423(16) 0.0280(12) Uani 1 1 d . . .
H24 H -0.0610 0.9074 0.8688 0.034 Uiso 1 1 calc R . .
C25 C -0.0154(3) 0.9170(3) 0.92228(16) 0.0258(12) Uani 1 1 d . . .
H25 H 0.0187 0.9504 0.9190 0.031 Uiso 1 1 calc R . .
C26 C -0.0310(3) 0.8824(3) 0.95631(16) 0.0267(12) Uani 1 1 d . . .
H26 H -0.0093 0.8888 0.9798 0.032 Uiso 1 1 calc R . .
C27 C -0.0459(2) 0.7008(3) 0.86214(13) 0.0190(10) Uani 1 1 d . . .
C28 C -0.1189(3) 0.7045(3) 0.81311(13) 0.0220(11) Uani 1 1 d . . .
H28A H -0.1063 0.6974 0.7865 0.026 Uiso 1 1 calc R . .
H28B H -0.1619 0.7299 0.8141 0.026 Uiso 1 1 calc R . .
C29 C -0.1253(2) 0.6367(2) 0.83373(13) 0.0192(10) Uani 1 1 d . . .
H29 H -0.1111 0.5997 0.8163 0.023 Uiso 1 1 calc R . .
C30 C -0.1957(3) 0.6200(3) 0.84914(14) 0.0205(10) Uani 1 1 d . . .
H30 H -0.1928 0.5743 0.8610 0.025 Uiso 1 1 calc R . .
C31 C -0.2462(3) 0.6148(3) 0.81673(15) 0.0286(12) Uani 1 1 d . . .
H31A H -0.2565 0.6602 0.8073 0.043 Uiso 1 1 calc R . .
H31B H -0.2878 0.5933 0.8256 0.043 Uiso 1 1 calc R . .
H31C H -0.2266 0.5876 0.7965 0.043 Uiso 1 1 calc R . .
C32 C -0.2191(3) 0.6689(3) 0.87935(14) 0.0255(12) Uani 1 1 d . . .
H32A H -0.1842 0.6727 0.8988 0.038 Uiso 1 1 calc R . .
H32B H -0.2611 0.6521 0.8906 0.038 Uiso 1 1 calc R . .
H32C H -0.2272 0.7134 0.8681 0.038 Uiso 1 1 calc R . .
C33 C 0.0730(2) 0.4748(3) 1.05072(14) 0.0211(10) Uani 1 1 d . . .
C34 C 0.0870(2) 0.4599(3) 1.01141(13) 0.0207(10) Uani 1 1 d . . .
C35 C 0.0708(3) 0.3906(3) 1.00385(14) 0.0224(11) Uani 1 1 d . . .
H35 H 0.0754 0.3681 0.9804 0.027 Uiso 1 1 calc R . .
C36 C 0.0464(3) 0.3618(3) 1.03801(14) 0.0258(11) Uani 1 1 d . . .
H36 H 0.0318 0.3165 1.0414 0.031 Uiso 1 1 calc R . .
C37 C 0.0480(2) 0.4126(3) 1.06588(13) 0.0209(10) Uani 1 1 d . . .
H37 H 0.0343 0.4064 1.0912 0.025 Uiso 1 1 calc R . .
C38 C 0.2351(3) 0.4299(5) 1.0620(2) 0.051(2) Uani 1 1 d . . .
H38 H 0.2471 0.4754 1.0673 0.061 Uiso 1 1 calc R . .
C39 C 0.2074(3) 0.3812(4) 1.08793(18) 0.0460(18) Uani 1 1 d . . .
H39 H 0.1974 0.3885 1.1137 0.055 Uiso 1 1 calc R . .
C40 C 0.1979(4) 0.3200(4) 1.06752(19) 0.0494(19) Uani 1 1 d . . .
H40 H 0.1804 0.2791 1.0775 0.059 Uiso 1 1 calc R . .
C41 C 0.2185(4) 0.3301(5) 1.0304(2) 0.061(2) Uani 1 1 d . . .
H41 H 0.2174 0.2971 1.0110 0.073 Uiso 1 1 calc R . .
C42 C 0.2408(3) 0.3956(6) 1.0266(2) 0.067(3) Uani 1 1 d . . .
H42 H 0.2573 0.4152 1.0040 0.081 Uiso 1 1 calc R . .
C43 C 0.1140(3) 0.5041(3) 0.98278(13) 0.0218(10) Uani 1 1 d . . .
C44 C 0.1440(3) 0.5243(3) 0.92264(15) 0.0312(12) Uani 1 1 d . . .
H44A H 0.1045 0.5311 0.9060 0.037 Uiso 1 1 calc R . .
H44B H 0.1840 0.5131 0.9071 0.037 Uiso 1 1 calc R . .
C45 C 0.1570(3) 0.5866(3) 0.94647(14) 0.0287(12) Uani 1 1 d . C .
H45 H 0.1328 0.6261 0.9353 0.034 Uiso 1 1 calc R . .
C46 C 0.2311(4) 0.6041(3) 0.95115(17) 0.0407(16) Uani 1 1 d . . .
H46 H 0.2313 0.6436 0.9672 0.049 Uiso 0.50 1 d P A 1
H46A H 0.2529 0.5629 0.9580 0.049 Uiso 0.50 1 d P B 2
C47 C 0.2627(4) 0.6272(4) 0.91353(19) 0.0520(19) Uani 1 1 d . C .
H47A H 0.2467 0.6728 0.9074 0.078 Uiso 1 1 calc R . .
H47B H 0.2494 0.5959 0.8935 0.078 Uiso 1 1 calc R . .
H47C H 0.3121 0.6276 0.9158 0.078 Uiso 1 1 calc R . .
C48 C 0.2723(6) 0.5571(8) 0.9710(4) 0.048(4) Uani 0.50 1 d P C 1
H48A H 0.3160 0.5780 0.9768 0.072 Uiso 0.50 1 calc PR C 1
H48B H 0.2795 0.5168 0.9555 0.072 Uiso 0.50 1 calc PR C 1
H48C H 0.2497 0.5442 0.9945 0.072 Uiso 0.50 1 calc PR C 1
C48A C 0.2518(8) 0.6523(8) 0.9788(4) 0.052(3) Uani 0.50 1 d PU C 2
H48D H 0.2369 0.6373 1.0036 0.078 Uiso 0.50 1 calc PR C 2
H48E H 0.2315 0.6963 0.9731 0.078 Uiso 0.50 1 calc PR C 2
H48F H 0.3012 0.6564 0.9785 0.078 Uiso 0.50 1 calc PR C 2
C49 C 0.0556(2) 0.7199(2) 1.04863(13) 0.0180(9) Uani 1 1 d . . .
C50 C 0.0648(3) 0.7350(2) 1.08774(14) 0.0202(10) Uani 1 1 d . . .
C51 C 0.0289(3) 0.7969(3) 1.09665(16) 0.0247(11) Uani 1 1 d . . .
H51 H 0.0275 0.8186 1.1204 0.030 Uiso 1 1 calc R . .
C52 C -0.0031(3) 0.8185(3) 1.06396(16) 0.0250(11) Uani 1 1 d . . .
H52 H -0.0313 0.8572 1.0616 0.030 Uiso 1 1 calc R . .
C53 C 0.0138(2) 0.7729(2) 1.03478(15) 0.0208(10) Uani 1 1 d . . .
H53 H -0.0008 0.7771 1.0095 0.025 Uiso 1 1 calc R . .
C54 C 0.1886(3) 0.8171(4) 1.0286(2) 0.0482(17) Uani 1 1 d U . .
H54 H 0.2061 0.7816 1.0135 0.058 Uiso 1 1 calc R . .
C55 C 0.2003(4) 0.8265(4) 1.0673(2) 0.058(2) Uani 1 1 d U . .
H55 H 0.2276 0.7985 1.0828 0.070 Uiso 1 1 calc R . .
C56 C 0.1659(4) 0.8829(4) 1.0790(2) 0.059(2) Uani 1 1 d U . .
H56 H 0.1646 0.9002 1.1038 0.071 Uiso 1 1 calc R . .
C57 C 0.1330(4) 0.9103(3) 1.04770(19) 0.0464(17) Uani 1 1 d . . .
H57 H 0.1061 0.9500 1.0477 0.056 Uiso 1 1 calc R . .
C58 C 0.1463(3) 0.8697(3) 1.01637(18) 0.0420(16) Uani 1 1 d . . .
H58 H 0.1299 0.8764 0.9916 0.050 Uiso 1 1 calc R . .
C59 C 0.1051(3) 0.6987(3) 1.11576(13) 0.0207(10) Uani 1 1 d . . .
C60 C 0.1659(3) 0.6905(3) 1.16946(15) 0.0268(12) Uani 1 1 d . . .
H60A H 0.1456 0.6885 1.1948 0.032 Uiso 1 1 calc R . .
H60B H 0.2134 0.7058 1.1717 0.032 Uiso 1 1 calc R . .
C61 C 0.1619(3) 0.6209(3) 1.14974(13) 0.0233(11) Uani 1 1 d . . .
H61 H 0.1367 0.5891 1.1665 0.028 Uiso 1 1 calc R . .
C62 C 0.2292(3) 0.5885(3) 1.13929(17) 0.0312(13) Uani 1 1 d . . .
H62 H 0.2193 0.5439 1.1272 0.037 Uiso 1 1 calc R . .
C63 C 0.2688(3) 0.6309(4) 1.1112(2) 0.0468(18) Uani 1 1 d . . .
H63A H 0.2438 0.6332 1.0875 0.070 Uiso 1 1 calc R . .
H63B H 0.3131 0.6101 1.1068 0.070 Uiso 1 1 calc R . .
H63C H 0.2750 0.6766 1.1212 0.070 Uiso 1 1 calc R . .
C64 C 0.2698(3) 0.5748(3) 1.17459(18) 0.0383(15) Uani 1 1 d . . .
H64A H 0.3080 0.5452 1.1686 0.057 Uiso 1 1 calc R . .
H64B H 0.2409 0.5527 1.1933 0.057 Uiso 1 1 calc R . .
H64C H 0.2868 0.6176 1.1847 0.057 Uiso 1 1 calc R . .
C1X C 0.4517(9) 0.5813(11) 1.0069(5) 0.095(6) Uani 0.50 1 d PDU D 2
H1X1 H 0.4689 0.5355 1.0010 0.114 Uiso 0.50 1 calc PR D 2
H1X2 H 0.4830 0.6017 1.0254 0.114 Uiso 0.50 1 calc PR D 2
Cl1X Cl 0.4542(4) 0.6300(3) 0.96586(15) 0.0995(18) Uani 0.50 1 d PDU D 2
Cl2X Cl 0.3722(4) 0.5730(4) 1.0280(2) 0.120(2) Uani 0.50 1 d PDU D 2
Cl1Y Cl 0.5450(7) 0.6081(9) 1.1002(3) 0.0896(12) Uani 0.50 1 d PDU E 2
Cl2Y Cl 0.4550(3) 0.6359(3) 1.16053(17) 0.0802(14) Uani 0.50 1 d PDU E 2
C1Y C 0.4618(8) 0.6145(11) 1.1143(4) 0.078(4) Uani 0.50 1 d PDU E 2
H1Y1 H 0.4387 0.6490 1.0988 0.094 Uiso 0.50 1 calc PR E 2
H1Y2 H 0.4388 0.5707 1.1100 0.094 Uiso 0.50 1 calc PR E 2
C1Z C 0.434(2) 0.6602(11) 1.2282(5) 0.078(4) Uani 0.25 1 d PDU F 1
H1Z1 H 0.3957 0.6906 1.2335 0.094 Uiso 0.25 1 calc PR F 1
H1Z2 H 0.4746 0.6801 1.2405 0.094 Uiso 0.25 1 calc PR F 1
Cl1Z Cl 0.4178(4) 0.5822(4) 1.2500 0.097(2) Uani 0.50 2 d SPDU F 1
Cl2Z Cl 0.4479(4) 0.6611(4) 1.1811(2) 0.0523(18) Uani 0.25 1 d PDU F 1
C1U C 0.3976(8) 0.3981(7) 0.9268(5) 0.061(4) Uani 0.50 1 d PDU G 3
H1U1 H 0.3623 0.3795 0.9101 0.073 Uiso 0.50 1 calc PR G 3
H1U2 H 0.4055 0.3653 0.9473 0.073 Uiso 0.50 1 calc PR G 3
Cl1U Cl 0.3709(4) 0.4726(4) 0.9452(2) 0.121(2) Uani 0.50 1 d PDU G 3
Cl2U Cl 0.4726(6) 0.4101(6) 0.9014(3) 0.170(4) Uani 0.50 1 d PDU G 3
C1T C 0.399(3) 0.4183(14) 0.9522(8) 0.115(8) Uani 0.25 1 d PDU H 4
H1T1 H 0.3544 0.4009 0.9446 0.138 Uiso 0.25 1 calc PR H 4
H1T2 H 0.4267 0.3805 0.9621 0.138 Uiso 0.25 1 calc PR H 4
Cl1T Cl 0.3917(8) 0.4827(9) 0.9849(4) 0.125(5) Uani 0.25 1 d PDU H 4
Cl2T Cl 0.4405(5) 0.4588(6) 0.9141(3) 0.080(3) Uani 0.25 1 d PDU H 4
C1V C 0.4736(11) 0.5877(19) 1.0701(12) 0.115(8) Uani 0.25 1 d PDU I 5
H1V1 H 0.4506 0.6308 1.0761 0.138 Uiso 0.25 1 calc PR I 5
H1V2 H 0.4664 0.5779 1.0431 0.138 Uiso 0.25 1 calc PR I 5
Cl1V Cl 0.4397(6) 0.5240(5) 1.0966(3) 0.081(3) Uani 0.25 1 d PDU I 5
Cl2V Cl 0.5596(7) 0.5955(7) 1.0789(4) 0.0896(12) Uani 0.25 1 d PDU I 5
C1W C 0.5145(12) 0.6018(16) 1.0519(5) 0.050(6) Uani 0.25 1 d PDU J 6
H1W1 H 0.4972 0.5554 1.0477 0.060 Uiso 0.25 1 calc PR J 6
H1W2 H 0.4759 0.6334 1.0493 0.060 Uiso 0.25 1 calc PR J 6
Cl1W Cl 0.5730(6) 0.6199(6) 1.0181(3) 0.096(3) Uani 0.25 1 d PDU J 6
Cl2W Cl 0.5471(14) 0.6077(18) 1.0976(6) 0.0896(12) Uani 0.25 1 d PDU J 6


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.996(5) . ?
Au1 N2 2.076(4) . ?
Au1 Au2 2.8449(3) . ?
Au2 C17 2.000(5) . ?
Au2 N1 2.075(4) . ?
Au2 Au4 3.0651(3) . ?
Au3 C33 1.986(5) . ?
Au3 N4 2.064(4) . ?
Au3 Au4 2.8452(3) . ?
Au4 C49 1.991(5) . ?
Au4 N3 2.064(4) . ?
Fe1 C3 2.014(5) . ?
Fe1 C7 2.035(6) . ?
Fe1 C6 2.042(5) . ?
Fe1 C8 2.043(6) . ?
Fe1 C4 2.047(5) . ?
Fe1 C2 2.047(5) . ?
Fe1 C9 2.053(6) . ?
Fe1 C10 2.057(5) . ?
Fe1 C5 2.068(5) . ?
Fe1 C1 2.094(5) . ?
Fe2 C19 2.018(5) . ?
Fe2 C18 2.024(5) . ?
Fe2 C23 2.041(5) . ?
Fe2 C20 2.042(5) . ?
Fe2 C24 2.045(5) . ?
Fe2 C22 2.049(5) . ?
Fe2 C25 2.052(5) . ?
Fe2 C21 2.054(5) . ?
Fe2 C26 2.056(5) . ?
Fe2 C17 2.086(5) . ?
Fe3 C35 2.024(5) . ?
Fe3 C42 2.031(7) . ?
Fe3 C34 2.037(5) . ?
Fe3 C36 2.039(6) . ?
Fe3 C40 2.040(6) . ?
Fe3 C39 2.040(6) . ?
Fe3 C38 2.042(7) . ?
Fe3 C41 2.046(6) . ?
Fe3 C37 2.059(5) . ?
Fe3 C33 2.093(5) . ?
Fe4 C51 2.007(5) . ?
Fe4 C57 2.027(6) . ?
Fe4 C56 2.030(8) . ?
Fe4 C50 2.036(5) . ?
Fe4 C54 2.040(6) . ?
Fe4 C58 2.040(6) . ?
Fe4 C55 2.040(7) . ?
Fe4 C52 2.042(5) . ?
Fe4 C53 2.052(5) . ?
Fe4 C49 2.094(5) . ?
O1 C11 1.356(6) . ?
O1 C12 1.460(6) . ?
O2 C27 1.355(6) . ?
O2 C28 1.451(6) . ?
O3 C43 1.363(6) . ?
O3 C44 1.460(6) . ?
O4 C59 1.347(6) . ?
O4 C60 1.467(6) . ?
N1 C11 1.284(6) . ?
N1 C13 1.486(6) . ?
N2 C27 1.287(6) . ?
N2 C29 1.474(6) . ?
N3 C43 1.286(7) . ?
N3 C45 1.478(6) . ?
N4 C59 1.283(7) . ?
N4 C61 1.490(6) . ?
C1 C5 1.429(7) . ?
C1 C2 1.442(6) . ?
C2 C3 1.437(7) . ?
C2 C11 1.454(7) . ?
C3 C4 1.414(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.420(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.412(8) . ?
C6 C10 1.420(8) . ?
C6 H6 0.9500 . ?
C7 C8 1.421(8) . ?
C7 H7 0.9500 . ?
C8 C9 1.414(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.440(8) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.538(7) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.524(8) . ?
C13 H13 1.0000 . ?
C14 C16 1.530(8) . ?
C14 C15 1.554(9) . ?
C14 H14 1.0000 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.436(7) . ?
C17 C21 1.437(7) . ?
C18 C19 1.446(7) . ?
C18 C27 1.450(7) . ?
C19 C20 1.417(7) . ?
C19 H19 0.9500 . ?
C20 C21 1.408(7) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C26 1.409(8) . ?
C22 C23 1.423(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.426(8) . ?
C23 H23 0.9500 . ?
C24 C25 1.415(8) . ?
C24 H24 0.9500 . ?
C25 C26 1.426(8) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C28 C29 1.533(7) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.533(7) . ?
C29 H29 1.0000 . ?
C30 C32 1.518(7) . ?
C30 C31 1.530(7) . ?
C30 H30 1.0000 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C37 1.432(7) . ?
C33 C34 1.457(7) . ?
C34 C35 1.432(7) . ?
C34 C43 1.446(7) . ?
C35 C36 1.427(7) . ?
C35 H35 0.9500 . ?
C36 C37 1.413(7) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
C38 C42 1.437(11) . ?
C38 C39 1.442(11) . ?
C38 H38 0.9500 . ?
C39 C40 1.423(11) . ?
C39 H39 0.9500 . ?
C40 C41 1.399(10) . ?
C40 H40 0.9500 . ?
C41 C42 1.375(13) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C44 C45 1.517(8) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C46 1.515(9) . ?
C45 H45 1.0000 . ?
C46 C48 1.424(15) . ?
C46 C48A 1.429(15) . ?
C46 C47 1.548(9) . ?
C46 H46 0.9681 . ?
C46 H46A 0.9531 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H46A 0.6134 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C48A H46 0.6028 . ?
C48A H48D 0.9800 . ?
C48A H48E 0.9800 . ?
C48A H48F 0.9800 . ?
C49 C53 1.424(7) . ?
C49 C50 1.436(7) . ?
C50 C51 1.450(7) . ?
C50 C59 1.464(7) . ?
C51 C52 1.393(8) . ?
C51 H51 0.9500 . ?
C52 C53 1.416(7) . ?
C52 H52 0.9500 . ?
C53 H53 0.9500 . ?
C54 C58 1.404(10) . ?
C54 C55 1.411(11) . ?
C54 H54 0.9500 . ?
C55 C56 1.369(12) . ?
C55 H55 0.9500 . ?
C56 C57 1.399(11) . ?
C56 H56 0.9500 . ?
C57 C58 1.399(10) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C60 C61 1.548(8) . ?
C60 H60A 0.9900 . ?
C60 H60B 0.9900 . ?
C61 C62 1.524(8) . ?
C61 H61 1.0000 . ?
C62 C64 1.516(8) . ?
C62 C63 1.522(8) . ?
C62 H62 1.0000 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C1X Cl2X 1.749(15) . ?
C1X Cl1X 1.752(15) . ?
C1X H1X1 0.9900 . ?
C1X H1X2 0.9900 . ?
Cl1Y C1Y 1.724(16) . ?
Cl2Y C1Y 1.706(14) . ?
C1Y H1Y1 0.9900 . ?
C1Y H1Y2 0.9900 . ?
C1Z Cl2Z 1.700(18) . ?
C1Z Cl1Z 1.757(18) . ?
C1Z H1Z1 0.9900 . ?
C1Z H1Z2 0.9900 . ?
Cl1Z C1Z 1.757(18) 8_667 ?
C1U Cl1U 1.696(14) . ?
C1U Cl2U 1.755(14) . ?
C1U H1U1 0.9900 . ?
C1U H1U2 0.9900 . ?
C1T Cl1T 1.732(19) . ?
C1T Cl2T 1.773(19) . ?
C1T H1T1 0.9900 . ?
C1T H1T2 0.9900 . ?
C1V Cl1V 1.712(19) . ?
C1V Cl2V 1.735(19) . ?
C1V H1V1 0.9900 . ?
C1V H1V2 0.9900 . ?
C1W Cl1W 1.708(17) . ?
C1W Cl2W 1.758(18) . ?
C1W H1W1 0.9900 . ?
C1W H1W2 0.9900 . ?
Cl1W Cl1W 1.84(2) 7_557 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 172.65(18) . . ?
C1 Au1 Au2 94.17(14) . . ?
N2 Au1 Au2 91.22(11) . . ?
C17 Au2 N1 176.45(18) . . ?
C17 Au2 Au1 92.27(14) . . ?
N1 Au2 Au1 91.10(11) . . ?
C17 Au2 Au4 96.79(14) . . ?
N1 Au2 Au4 81.72(11) . . ?
Au1 Au2 Au4 132.672(8) . . ?
C33 Au3 N4 174.49(18) . . ?
C33 Au3 Au4 93.42(14) . . ?
N4 Au3 Au4 91.46(11) . . ?
C49 Au4 N3 175.99(18) . . ?
C49 Au4 Au3 91.40(14) . . ?
N3 Au4 Au3 92.07(11) . . ?
C49 Au4 Au2 95.11(14) . . ?
N3 Au4 Au2 81.25(12) . . ?
Au3 Au4 Au2 124.603(9) . . ?
C3 Fe1 C7 115.7(2) . . ?
C3 Fe1 C6 146.4(2) . . ?
C7 Fe1 C6 40.5(2) . . ?
C3 Fe1 C8 110.0(2) . . ?
C7 Fe1 C8 40.8(2) . . ?
C6 Fe1 C8 68.5(2) . . ?
C3 Fe1 C4 40.7(2) . . ?
C7 Fe1 C4 146.1(2) . . ?
C6 Fe1 C4 172.2(2) . . ?
C8 Fe1 C4 114.3(2) . . ?
C3 Fe1 C2 41.45(19) . . ?
C7 Fe1 C2 111.0(2) . . ?
C6 Fe1 C2 114.9(2) . . ?
C8 Fe1 C2 135.5(2) . . ?
C4 Fe1 C2 68.7(2) . . ?
C3 Fe1 C9 133.6(2) . . ?
C7 Fe1 C9 68.1(2) . . ?
C6 Fe1 C9 68.2(2) . . ?
C8 Fe1 C9 40.4(2) . . ?
C4 Fe1 C9 108.8(2) . . ?
C2 Fe1 C9 174.5(2) . . ?
C3 Fe1 C10 172.7(2) . . ?
C7 Fe1 C10 68.4(2) . . ?
C6 Fe1 C10 40.5(2) . . ?
C8 Fe1 C10 68.8(2) . . ?
C4 Fe1 C10 132.6(2) . . ?
C2 Fe1 C10 144.2(2) . . ?
C9 Fe1 C10 41.0(2) . . ?
C3 Fe1 C5 67.9(2) . . ?
C7 Fe1 C5 173.1(2) . . ?
C6 Fe1 C5 133.4(2) . . ?
C8 Fe1 C5 144.9(2) . . ?
C4 Fe1 C5 40.4(2) . . ?
C2 Fe1 C5 67.37(19) . . ?
C9 Fe1 C5 114.2(2) . . ?
C10 Fe1 C5 108.7(2) . . ?
C3 Fe1 C1 69.39(19) . . ?
C7 Fe1 C1 134.3(2) . . ?
C6 Fe1 C1 108.9(2) . . ?
C8 Fe1 C1 174.7(2) . . ?
C4 Fe1 C1 68.9(2) . . ?
C2 Fe1 C1 40.73(18) . . ?
C9 Fe1 C1 143.7(2) . . ?
C10 Fe1 C1 112.5(2) . . ?
C5 Fe1 C1 40.16(19) . . ?
C19 Fe2 C18 41.93(19) . . ?
C19 Fe2 C23 123.6(2) . . ?
C18 Fe2 C23 106.6(2) . . ?
C19 Fe2 C20 40.8(2) . . ?
C18 Fe2 C20 68.8(2) . . ?
C23 Fe2 C20 161.1(2) . . ?
C19 Fe2 C24 105.9(2) . . ?
C18 Fe2 C24 120.4(2) . . ?
C23 Fe2 C24 40.9(2) . . ?
C20 Fe2 C24 124.4(2) . . ?
C19 Fe2 C22 161.7(2) . . ?
C18 Fe2 C22 124.8(2) . . ?
C23 Fe2 C22 40.7(2) . . ?
C20 Fe2 C22 156.7(2) . . ?
C24 Fe2 C22 68.2(2) . . ?
C19 Fe2 C25 119.3(2) . . ?
C18 Fe2 C25 155.6(2) . . ?
C23 Fe2 C25 68.6(2) . . ?
C20 Fe2 C25 107.6(2) . . ?
C24 Fe2 C25 40.4(2) . . ?
C22 Fe2 C25 68.1(2) . . ?
C19 Fe2 C21 68.4(2) . . ?
C18 Fe2 C21 67.7(2) . . ?
C23 Fe2 C21 156.7(2) . . ?
C20 Fe2 C21 40.2(2) . . ?
C24 Fe2 C21 161.8(2) . . ?
C22 Fe2 C21 122.5(2) . . ?
C25 Fe2 C21 126.0(2) . . ?
C19 Fe2 C26 155.5(2) . . ?
C18 Fe2 C26 161.9(2) . . ?
C23 Fe2 C26 68.3(2) . . ?
C20 Fe2 C26 121.7(2) . . ?
C24 Fe2 C26 68.0(2) . . ?
C22 Fe2 C26 40.2(2) . . ?
C25 Fe2 C26 40.6(2) . . ?
C21 Fe2 C26 109.6(2) . . ?
C19 Fe2 C17 70.13(19) . . ?
C18 Fe2 C17 40.86(19) . . ?
C23 Fe2 C17 120.3(2) . . ?
C20 Fe2 C17 69.05(19) . . ?
C24 Fe2 C17 155.7(2) . . ?
C22 Fe2 C17 107.8(2) . . ?
C25 Fe2 C17 162.4(2) . . ?
C21 Fe2 C17 40.60(19) . . ?
C26 Fe2 C17 125.4(2) . . ?
C35 Fe3 C42 117.1(3) . . ?
C35 Fe3 C34 41.3(2) . . ?
C42 Fe3 C34 110.3(3) . . ?
C35 Fe3 C36 41.1(2) . . ?
C42 Fe3 C36 149.0(3) . . ?
C34 Fe3 C36 68.8(2) . . ?
C35 Fe3 C40 128.6(3) . . ?
C42 Fe3 C40 67.2(4) . . ?
C34 Fe3 C40 168.4(3) . . ?
C36 Fe3 C40 107.1(3) . . ?
C35 Fe3 C39 167.0(3) . . ?
C42 Fe3 C39 68.8(3) . . ?
C34 Fe3 C39 150.1(3) . . ?
C36 Fe3 C39 128.0(3) . . ?
C40 Fe3 C39 40.8(3) . . ?
C35 Fe3 C38 150.4(3) . . ?
C42 Fe3 C38 41.3(3) . . ?
C34 Fe3 C38 117.6(3) . . ?
C36 Fe3 C38 167.7(2) . . ?
C40 Fe3 C38 68.7(3) . . ?
C39 Fe3 C38 41.4(3) . . ?
C35 Fe3 C41 108.1(3) . . ?
C42 Fe3 C41 39.4(4) . . ?
C34 Fe3 C41 131.0(2) . . ?
C36 Fe3 C41 116.4(3) . . ?
C40 Fe3 C41 40.0(3) . . ?
C39 Fe3 C41 68.4(3) . . ?
C38 Fe3 C41 68.3(3) . . ?
C35 Fe3 C37 68.4(2) . . ?
C42 Fe3 C37 170.2(3) . . ?
C34 Fe3 C37 67.89(19) . . ?
C36 Fe3 C37 40.3(2) . . ?
C40 Fe3 C37 116.5(3) . . ?
C39 Fe3 C37 107.7(2) . . ?
C38 Fe3 C37 130.1(2) . . ?
C41 Fe3 C37 148.9(3) . . ?
C35 Fe3 C33 69.88(19) . . ?
C42 Fe3 C33 132.0(4) . . ?
C34 Fe3 C33 41.30(18) . . ?
C36 Fe3 C33 69.0(2) . . ?
C40 Fe3 C33 148.7(2) . . ?
C39 Fe3 C33 115.8(2) . . ?
C38 Fe3 C33 108.2(3) . . ?
C41 Fe3 C33 170.0(3) . . ?
C37 Fe3 C33 40.3(2) . . ?
C51 Fe4 C57 120.9(3) . . ?
C51 Fe4 C56 107.8(3) . . ?
C57 Fe4 C56 40.3(3) . . ?
C51 Fe4 C50 42.0(2) . . ?
C57 Fe4 C50 157.4(2) . . ?
C56 Fe4 C50 122.1(3) . . ?
C51 Fe4 C54 162.6(3) . . ?
C57 Fe4 C54 67.2(3) . . ?
C56 Fe4 C54 67.4(3) . . ?
C50 Fe4 C54 125.0(3) . . ?
C51 Fe4 C58 155.4(3) . . ?
C57 Fe4 C58 40.2(3) . . ?
C56 Fe4 C58 68.0(3) . . ?
C50 Fe4 C58 160.9(2) . . ?
C54 Fe4 C58 40.3(3) . . ?
C51 Fe4 C55 125.4(3) . . ?
C57 Fe4 C55 66.7(3) . . ?
C56 Fe4 C55 39.3(3) . . ?
C50 Fe4 C55 108.9(3) . . ?
C54 Fe4 C55 40.5(3) . . ?
C58 Fe4 C55 67.7(3) . . ?
C51 Fe4 C52 40.2(2) . . ?
C57 Fe4 C52 108.3(3) . . ?
C56 Fe4 C52 125.3(3) . . ?
C50 Fe4 C52 68.4(2) . . ?
C54 Fe4 C52 156.2(3) . . ?
C58 Fe4 C52 121.0(3) . . ?
C55 Fe4 C52 161.4(3) . . ?
C51 Fe4 C53 68.1(2) . . ?
C57 Fe4 C53 125.5(3) . . ?
C56 Fe4 C53 162.1(3) . . ?
C50 Fe4 C53 67.4(2) . . ?
C54 Fe4 C53 121.7(3) . . ?
C58 Fe4 C53 108.0(2) . . ?
C55 Fe4 C53 157.1(3) . . ?
C52 Fe4 C53 40.5(2) . . ?
C51 Fe4 C49 69.9(2) . . ?
C57 Fe4 C49 160.9(2) . . ?
C56 Fe4 C49 156.6(3) . . ?
C50 Fe4 C49 40.66(19) . . ?
C54 Fe4 C49 107.5(3) . . ?
C58 Fe4 C49 123.9(2) . . ?
C55 Fe4 C49 122.0(3) . . ?
C52 Fe4 C49 68.7(2) . . ?
C53 Fe4 C49 40.17(19) . . ?
C11 O1 C12 107.3(4) . . ?
C27 O2 C28 107.7(4) . . ?
C43 O3 C44 106.2(4) . . ?
C59 O4 C60 107.2(4) . . ?
C11 N1 C13 109.4(4) . . ?
C11 N1 Au2 133.5(3) . . ?
C13 N1 Au2 117.1(3) . . ?
C27 N2 C29 109.5(4) . . ?
C27 N2 Au1 131.8(3) . . ?
C29 N2 Au1 118.8(3) . . ?
C43 N3 C45 108.7(4) . . ?
C43 N3 Au4 131.2(4) . . ?
C45 N3 Au4 119.2(3) . . ?
C59 N4 C61 108.8(4) . . ?
C59 N4 Au3 132.5(3) . . ?
C61 N4 Au3 118.7(3) . . ?
C5 C1 C2 105.3(4) . . ?
C5 C1 Au1 124.6(3) . . ?
C2 C1 Au1 128.9(4) . . ?
C5 C1 Fe1 68.9(3) . . ?
C2 C1 Fe1 67.9(3) . . ?
Au1 C1 Fe1 117.5(2) . . ?
C3 C2 C1 108.7(4) . . ?
C3 C2 C11 122.2(4) . . ?
C1 C2 C11 129.0(4) . . ?
C3 C2 Fe1 68.0(3) . . ?
C1 C2 Fe1 71.4(3) . . ?
C11 C2 Fe1 123.9(3) . . ?
C4 C3 C2 108.3(4) . . ?
C4 C3 Fe1 70.9(3) . . ?
C2 C3 Fe1 70.5(3) . . ?
C4 C3 H3 125.9 . . ?
C2 C3 H3 125.9 . . ?
Fe1 C3 H3 124.3 . . ?
C3 C4 C5 107.1(4) . . ?
C3 C4 Fe1 68.4(3) . . ?
C5 C4 Fe1 70.6(3) . . ?
C3 C4 H4 126.5 . . ?
C5 C4 H4 126.5 . . ?
Fe1 C4 H4 126.2 . . ?
C4 C5 C1 110.6(4) . . ?
C4 C5 Fe1 69.0(3) . . ?
C1 C5 Fe1 70.9(3) . . ?
C4 C5 H5 124.7 . . ?
C1 C5 H5 124.7 . . ?
Fe1 C5 H5 127.0 . . ?
C7 C6 C10 108.7(5) . . ?
C7 C6 Fe1 69.5(3) . . ?
C10 C6 Fe1 70.3(3) . . ?
C7 C6 H6 125.7 . . ?
C10 C6 H6 125.7 . . ?
Fe1 C6 H6 126.1 . . ?
C6 C7 C8 108.4(5) . . ?
C6 C7 Fe1 70.0(3) . . ?
C8 C7 Fe1 69.9(3) . . ?
C6 C7 H7 125.8 . . ?
C8 C7 H7 125.8 . . ?
Fe1 C7 H7 125.9 . . ?
C9 C8 C7 107.6(5) . . ?
C9 C8 Fe1 70.2(3) . . ?
C7 C8 Fe1 69.3(3) . . ?
C9 C8 H8 126.2 . . ?
C7 C8 H8 126.2 . . ?
Fe1 C8 H8 125.9 . . ?
C8 C9 C10 108.5(5) . . ?
C8 C9 Fe1 69.4(3) . . ?
C10 C9 Fe1 69.6(3) . . ?
C8 C9 H9 125.8 . . ?
C10 C9 H9 125.8 . . ?
Fe1 C9 H9 126.7 . . ?
C6 C10 C9 106.8(5) . . ?
C6 C10 Fe1 69.1(3) . . ?
C9 C10 Fe1 69.3(3) . . ?
C6 C10 H10 126.6 . . ?
C9 C10 H10 126.6 . . ?
Fe1 C10 H10 126.5 . . ?
N1 C11 O1 114.9(4) . . ?
N1 C11 C2 130.7(4) . . ?
O1 C11 C2 114.5(4) . . ?
O1 C12 C13 103.5(4) . . ?
O1 C12 H12A 111.1 . . ?
C13 C12 H12A 111.1 . . ?
O1 C12 H12B 111.1 . . ?
C13 C12 H12B 111.1 . . ?
H12A C12 H12B 109.0 . . ?
N1 C13 C14 111.6(4) . . ?
N1 C13 C12 101.9(4) . . ?
C14 C13 C12 116.2(5) . . ?
N1 C13 H13 108.9 . . ?
C14 C13 H13 108.9 . . ?
C12 C13 H13 108.9 . . ?
C13 C14 C16 110.8(5) . . ?
C13 C14 C15 112.2(5) . . ?
C16 C14 C15 111.5(5) . . ?
C13 C14 H14 107.4 . . ?
C16 C14 H14 107.4 . . ?
C15 C14 H14 107.4 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C21 104.6(4) . . ?
C18 C17 Au2 129.6(4) . . ?
C21 C17 Au2 125.8(4) . . ?
C18 C17 Fe2 67.2(3) . . ?
C21 C17 Fe2 68.5(3) . . ?
Au2 C17 Fe2 126.8(2) . . ?
C17 C18 C19 109.8(4) . . ?
C17 C18 C27 128.7(5) . . ?
C19 C18 C27 121.3(5) . . ?
C17 C18 Fe2 71.9(3) . . ?
C19 C18 Fe2 68.8(3) . . ?
C27 C18 Fe2 122.6(4) . . ?
C20 C19 C18 106.7(4) . . ?
C20 C19 Fe2 70.5(3) . . ?
C18 C19 Fe2 69.2(3) . . ?
C20 C19 H19 126.7 . . ?
C18 C19 H19 126.7 . . ?
Fe2 C19 H19 125.2 . . ?
C21 C20 C19 108.2(4) . . ?
C21 C20 Fe2 70.4(3) . . ?
C19 C20 Fe2 68.7(3) . . ?
C21 C20 H20 125.9 . . ?
C19 C20 H20 125.9 . . ?
Fe2 C20 H20 126.6 . . ?
C20 C21 C17 110.7(5) . . ?
C20 C21 Fe2 69.4(3) . . ?
C17 C21 Fe2 70.9(3) . . ?
C20 C21 H21 124.6 . . ?
C17 C21 H21 124.6 . . ?
Fe2 C21 H21 126.6 . . ?
C26 C22 C23 108.5(5) . . ?
C26 C22 Fe2 70.2(3) . . ?
C23 C22 Fe2 69.3(3) . . ?
C26 C22 H22 125.7 . . ?
C23 C22 H22 125.7 . . ?
Fe2 C22 H22 126.3 . . ?
C22 C23 C24 107.2(5) . . ?
C22 C23 Fe2 69.9(3) . . ?
C24 C23 Fe2 69.7(3) . . ?
C22 C23 H23 126.4 . . ?
C24 C23 H23 126.4 . . ?
Fe2 C23 H23 125.5 . . ?
C25 C24 C23 108.5(5) . . ?
C25 C24 Fe2 70.1(3) . . ?
C23 C24 Fe2 69.4(3) . . ?
C25 C24 H24 125.7 . . ?
C23 C24 H24 125.7 . . ?
Fe2 C24 H24 126.3 . . ?
C24 C25 C26 107.6(5) . . ?
C24 C25 Fe2 69.5(3) . . ?
C26 C25 Fe2 69.8(3) . . ?
C24 C25 H25 126.2 . . ?
C26 C25 H25 126.2 . . ?
Fe2 C25 H25 126.0 . . ?
C22 C26 C25 108.2(5) . . ?
C22 C26 Fe2 69.6(3) . . ?
C25 C26 Fe2 69.5(3) . . ?
C22 C26 H26 125.9 . . ?
C25 C26 H26 125.9 . . ?
Fe2 C26 H26 126.5 . . ?
N2 C27 O2 115.1(4) . . ?
N2 C27 C18 128.9(5) . . ?
O2 C27 C18 115.9(4) . . ?
O2 C28 C29 104.5(4) . . ?
O2 C28 H28A 110.8 . . ?
C29 C28 H28A 110.8 . . ?
O2 C28 H28B 110.8 . . ?
C29 C28 H28B 110.8 . . ?
H28A C28 H28B 108.9 . . ?
N2 C29 C28 103.1(4) . . ?
N2 C29 C30 111.9(4) . . ?
C28 C29 C30 115.8(4) . . ?
N2 C29 H29 108.6 . . ?
C28 C29 H29 108.6 . . ?
C30 C29 H29 108.6 . . ?
C32 C30 C31 112.2(4) . . ?
C32 C30 C29 113.2(4) . . ?
C31 C30 C29 109.7(4) . . ?
C32 C30 H30 107.1 . . ?
C31 C30 H30 107.1 . . ?
C29 C30 H30 107.1 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C37 C33 C34 104.7(4) . . ?
C37 C33 Au3 124.3(4) . . ?
C34 C33 Au3 130.5(4) . . ?
C37 C33 Fe3 68.6(3) . . ?
C34 C33 Fe3 67.3(3) . . ?
Au3 C33 Fe3 122.1(2) . . ?
C35 C34 C43 121.9(4) . . ?
C35 C34 C33 109.4(4) . . ?
C43 C34 C33 128.7(5) . . ?
C35 C34 Fe3 68.9(3) . . ?
C43 C34 Fe3 125.1(4) . . ?
C33 C34 Fe3 71.4(3) . . ?
C36 C35 C34 107.3(4) . . ?
C36 C35 Fe3 70.0(3) . . ?
C34 C35 Fe3 69.8(3) . . ?
C36 C35 H35 126.4 . . ?
C34 C35 H35 126.4 . . ?
Fe3 C35 H35 125.4 . . ?
C37 C36 C35 107.9(5) . . ?
C37 C36 Fe3 70.6(3) . . ?
C35 C36 Fe3 68.9(3) . . ?
C37 C36 H36 126.0 . . ?
C35 C36 H36 126.0 . . ?
Fe3 C36 H36 126.0 . . ?
C36 C37 C33 110.7(4) . . ?
C36 C37 Fe3 69.1(3) . . ?
C33 C37 Fe3 71.1(3) . . ?
C36 C37 H37 124.6 . . ?
C33 C37 H37 124.6 . . ?
Fe3 C37 H37 126.8 . . ?
C42 C38 C39 106.0(8) . . ?
C42 C38 Fe3 68.9(4) . . ?
C39 C38 Fe3 69.2(4) . . ?
C42 C38 H38 127.0 . . ?
C39 C38 H38 127.0 . . ?
Fe3 C38 H38 126.4 . . ?
C40 C39 C38 106.9(6) . . ?
C40 C39 Fe3 69.6(3) . . ?
C38 C39 Fe3 69.4(3) . . ?
C40 C39 H39 126.5 . . ?
C38 C39 H39 126.5 . . ?
Fe3 C39 H39 126.1 . . ?
C41 C40 C39 108.9(8) . . ?
C41 C40 Fe3 70.2(4) . . ?
C39 C40 Fe3 69.6(4) . . ?
C41 C40 H40 125.6 . . ?
C39 C40 H40 125.6 . . ?
Fe3 C40 H40 126.2 . . ?
C42 C41 C40 108.7(7) . . ?
C42 C41 Fe3 69.7(4) . . ?
C40 C41 Fe3 69.7(4) . . ?
C42 C41 H41 125.7 . . ?
C40 C41 H41 125.7 . . ?
Fe3 C41 H41 126.5 . . ?
C41 C42 C38 109.5(8) . . ?
C41 C42 Fe3 70.9(4) . . ?
C38 C42 Fe3 69.7(4) . . ?
C41 C42 H42 125.3 . . ?
C38 C42 H42 125.3 . . ?
Fe3 C42 H42 125.7 . . ?
N3 C43 O3 114.7(4) . . ?
N3 C43 C34 131.6(5) . . ?
O3 C43 C34 113.7(4) . . ?
O3 C44 C45 103.4(4) . . ?
O3 C44 H44A 111.1 . . ?
C45 C44 H44A 111.1 . . ?
O3 C44 H44B 111.1 . . ?
C45 C44 H44B 111.1 . . ?
H44A C44 H44B 109.0 . . ?
N3 C45 C46 112.4(5) . . ?
N3 C45 C44 102.2(4) . . ?
C46 C45 C44 114.3(5) . . ?
N3 C45 H45 109.2 . . ?
C46 C45 H45 109.2 . . ?
C44 C45 H45 109.2 . . ?
C48 C46 C48A 86.0(10) . . ?
C48 C46 C45 117.3(7) . . ?
C48A C46 C45 120.3(8) . . ?
C48 C46 C47 113.1(8) . . ?
C48A C46 C47 106.4(8) . . ?
C45 C46 C47 111.3(5) . . ?
C48 C46 H46 103.4 . . ?
C48A C46 H46 19.0 . . ?
C45 C46 H46 104.6 . . ?
C47 C46 H46 105.7 . . ?
C48 C46 H46A 19.4 . . ?
C48A C46 H46A 105.4 . . ?
C45 C46 H46A 105.6 . . ?
C47 C46 H46A 107.0 . . ?
H46 C46 H46A 122.5 . . ?
C46 C47 H47A 109.5 . . ?
C46 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C46 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C46 C48 H46A 31.1 . . ?
C46 C48 H48A 109.5 . . ?
H46A C48 H48A 129.2 . . ?
C46 C48 H48B 109.5 . . ?
H46A C48 H48B 79.4 . . ?
C46 C48 H48C 109.5 . . ?
H46A C48 H48C 114.1 . . ?
C46 C48A H46 31.5 . . ?
C46 C48A H48D 109.5 . . ?
C46 C48A H48E 109.5 . . ?
H48D C48A H48E 109.5 . . ?
C46 C48A H48F 109.5 . . ?
H48D C48A H48F 109.5 . . ?
H48E C48A H48F 109.5 . . ?
C53 C49 C50 104.9(4) . . ?
C53 C49 Au4 124.7(4) . . ?
C50 C49 Au4 130.4(4) . . ?
C53 C49 Fe4 68.3(3) . . ?
C50 C49 Fe4 67.5(3) . . ?
Au4 C49 Fe4 127.8(2) . . ?
C49 C50 C51 109.0(4) . . ?
C49 C50 C59 128.9(5) . . ?
C51 C50 C59 122.0(5) . . ?
C49 C50 Fe4 71.8(3) . . ?
C51 C50 Fe4 67.9(3) . . ?
C59 C50 Fe4 124.0(4) . . ?
C52 C51 C50 107.4(5) . . ?
C52 C51 Fe4 71.2(3) . . ?
C50 C51 Fe4 70.1(3) . . ?
C52 C51 H51 126.3 . . ?
C50 C51 H51 126.3 . . ?
Fe4 C51 H51 124.1 . . ?
C51 C52 C53 108.1(5) . . ?
C51 C52 Fe4 68.5(3) . . ?
C53 C52 Fe4 70.1(3) . . ?
C51 C52 H52 126.0 . . ?
C53 C52 H52 126.0 . . ?
Fe4 C52 H52 126.9 . . ?
C52 C53 C49 110.6(5) . . ?
C52 C53 Fe4 69.4(3) . . ?
C49 C53 Fe4 71.5(3) . . ?
C52 C53 H53 124.7 . . ?
C49 C53 H53 124.7 . . ?
Fe4 C53 H53 126.0 . . ?
C58 C54 C55 107.7(7) . . ?
C58 C54 Fe4 69.9(4) . . ?
C55 C54 Fe4 69.8(4) . . ?
C58 C54 H54 126.1 . . ?
C55 C54 H54 126.1 . . ?
Fe4 C54 H54 125.8 . . ?
C56 C55 C54 108.7(7) . . ?
C56 C55 Fe4 69.9(5) . . ?
C54 C55 Fe4 69.8(4) . . ?
C56 C55 H55 125.7 . . ?
C54 C55 H55 125.7 . . ?
Fe4 C55 H55 126.2 . . ?
C55 C56 C57 107.8(8) . . ?
C55 C56 Fe4 70.8(5) . . ?
C57 C56 Fe4 69.7(4) . . ?
C55 C56 H56 126.1 . . ?
C57 C56 H56 126.1 . . ?
Fe4 C56 H56 125.0 . . ?
C56 C57 C58 109.0(7) . . ?
C56 C57 Fe4 69.9(4) . . ?
C58 C57 Fe4 70.4(4) . . ?
C56 C57 H57 125.5 . . ?
C58 C57 H57 125.5 . . ?
Fe4 C57 H57 125.8 . . ?
C57 C58 C54 106.8(6) . . ?
C57 C58 Fe4 69.4(4) . . ?
C54 C58 Fe4 69.9(4) . . ?
C57 C58 H58 126.6 . . ?
C54 C58 H58 126.6 . . ?
Fe4 C58 H58 125.7 . . ?
N4 C59 O4 116.8(5) . . ?
N4 C59 C50 127.3(5) . . ?
O4 C59 C50 115.9(4) . . ?
O4 C60 C61 104.3(4) . . ?
O4 C60 H60A 110.9 . . ?
C61 C60 H60A 110.9 . . ?
O4 C60 H60B 110.9 . . ?
C61 C60 H60B 110.9 . . ?
H60A C60 H60B 108.9 . . ?
N4 C61 C62 112.4(4) . . ?
N4 C61 C60 102.8(4) . . ?
C62 C61 C60 116.1(4) . . ?
N4 C61 H61 108.4 . . ?
C62 C61 H61 108.4 . . ?
C60 C61 H61 108.4 . . ?
C64 C62 C63 111.8(5) . . ?
C64 C62 C61 109.6(5) . . ?
C63 C62 C61 112.2(5) . . ?
C64 C62 H62 107.7 . . ?
C63 C62 H62 107.7 . . ?
C61 C62 H62 107.7 . . ?
C62 C63 H63A 109.5 . . ?
C62 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C62 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C62 C64 H64A 109.5 . . ?
C62 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C62 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
Cl2X C1X Cl1X 115.8(11) . . ?
Cl2X C1X H1X1 108.3 . . ?
Cl1X C1X H1X1 108.3 . . ?
Cl2X C1X H1X2 108.3 . . ?
Cl1X C1X H1X2 108.3 . . ?
H1X1 C1X H1X2 107.4 . . ?
Cl2Y C1Y Cl1Y 112.0(10) . . ?
Cl2Y C1Y H1Y1 109.2 . . ?
Cl1Y C1Y H1Y1 109.2 . . ?
Cl2Y C1Y H1Y2 109.2 . . ?
Cl1Y C1Y H1Y2 109.2 . . ?
H1Y1 C1Y H1Y2 107.9 . . ?
Cl2Z C1Z Cl1Z 118.3(14) . . ?
Cl2Z C1Z H1Z1 107.7 . . ?
Cl1Z C1Z H1Z1 107.7 . . ?
Cl2Z C1Z H1Z2 107.7 . . ?
Cl1Z C1Z H1Z2 107.7 . . ?
H1Z1 C1Z H1Z2 107.1 . . ?
C1Z Cl1Z C1Z 121(3) . 8_667 ?
Cl1U C1U Cl2U 110.1(9) . . ?
Cl1U C1U H1U1 109.6 . . ?
Cl2U C1U H1U1 109.6 . . ?
Cl1U C1U H1U2 109.6 . . ?
Cl2U C1U H1U2 109.6 . . ?
H1U1 C1U H1U2 108.1 . . ?
Cl1T C1T Cl2T 102.8(14) . . ?
Cl1T C1T H1T1 111.2 . . ?
Cl2T C1T H1T1 111.2 . . ?
Cl1T C1T H1T2 111.2 . . ?
Cl2T C1T H1T2 111.2 . . ?
H1T1 C1T H1T2 109.1 . . ?
Cl1V C1V Cl2V 110.5(15) . . ?
Cl1V C1V H1V1 109.6 . . ?
Cl2V C1V H1V1 109.6 . . ?
Cl1V C1V H1V2 109.5 . . ?
Cl2V C1V H1V2 109.5 . . ?
H1V1 C1V H1V2 108.1 . . ?
Cl1W C1W Cl2W 113.0(16) . . ?
Cl1W C1W H1W1 109.0 . . ?
Cl2W C1W H1W1 109.0 . . ?
Cl1W C1W H1W2 109.0 . . ?
Cl2W C1W H1W2 109.0 . . ?
H1W1 C1W H1W2 107.8 . . ?
C1W Cl1W Cl1W 136.8(12) . 7_557 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C17 150.6(2) . . . . ?
N2 Au1 Au2 C17 -34.42(18) . . . . ?
C1 Au1 Au2 N1 -30.54(18) . . . . ?
N2 Au1 Au2 N1 144.46(15) . . . . ?
C1 Au1 Au2 Au4 49.19(14) . . . . ?
N2 Au1 Au2 Au4 -135.81(11) . . . . ?
C33 Au3 Au4 C49 147.53(19) . . . . ?
N4 Au3 Au4 C49 -35.03(18) . . . . ?
C33 Au3 Au4 N3 -30.46(19) . . . . ?
N4 Au3 Au4 N3 146.98(17) . . . . ?
C33 Au3 Au4 Au2 50.34(14) . . . . ?
N4 Au3 Au4 Au2 -132.22(11) . . . . ?
C17 Au2 Au4 C49 90.79(19) . . . . ?
N1 Au2 Au4 C49 -85.96(18) . . . . ?
Au1 Au2 Au4 C49 -169.77(14) . . . . ?
C17 Au2 Au4 N3 -87.50(18) . . . . ?
N1 Au2 Au4 N3 95.75(17) . . . . ?
Au1 Au2 Au4 N3 11.94(12) . . . . ?
C17 Au2 Au4 Au3 -173.97(14) . . . . ?
N1 Au2 Au4 Au3 9.28(11) . . . . ?
Au1 Au2 Au4 Au3 -74.524(14) . . . . ?
C17 Au2 N1 C11 -173(3) . . . . ?
Au1 Au2 N1 C11 25.9(5) . . . . ?
Au4 Au2 N1 C11 -107.1(5) . . . . ?
C17 Au2 N1 C13 7(3) . . . . ?
Au1 Au2 N1 C13 -154.7(3) . . . . ?
Au4 Au2 N1 C13 72.3(3) . . . . ?
C1 Au1 N2 C27 167.7(12) . . . . ?
Au2 Au1 N2 C27 30.5(4) . . . . ?
C1 Au1 N2 C29 -12.9(15) . . . . ?
Au2 Au1 N2 C29 -150.1(3) . . . . ?
C49 Au4 N3 C43 -117(3) . . . . ?
Au3 Au4 N3 C43 33.2(5) . . . . ?
Au2 Au4 N3 C43 -91.5(5) . . . . ?
C49 Au4 N3 C45 51(3) . . . . ?
Au3 Au4 N3 C45 -158.8(4) . . . . ?
Au2 Au4 N3 C45 76.5(4) . . . . ?
C33 Au3 N4 C59 -175.5(17) . . . . ?
Au4 Au3 N4 C59 32.1(5) . . . . ?
C33 Au3 N4 C61 4(2) . . . . ?
Au4 Au3 N4 C61 -148.7(3) . . . . ?
N2 Au1 C1 C5 59.9(16) . . . . ?
Au2 Au1 C1 C5 -163.0(4) . . . . ?
N2 Au1 C1 C2 -105.1(14) . . . . ?
Au2 Au1 C1 C2 32.0(4) . . . . ?
N2 Au1 C1 Fe1 -22.4(15) . . . . ?
Au2 Au1 C1 Fe1 114.7(2) . . . . ?
C3 Fe1 C1 C5 79.8(3) . . . . ?
C7 Fe1 C1 C5 -174.0(3) . . . . ?
C6 Fe1 C1 C5 -136.0(3) . . . . ?
C8 Fe1 C1 C5 164(2) . . . . ?
C4 Fe1 C1 C5 36.0(3) . . . . ?
C2 Fe1 C1 C5 117.5(4) . . . . ?
C9 Fe1 C1 C5 -57.3(5) . . . . ?
C10 Fe1 C1 C5 -92.7(3) . . . . ?
C3 Fe1 C1 C2 -37.8(3) . . . . ?
C7 Fe1 C1 C2 68.5(4) . . . . ?
C6 Fe1 C1 C2 106.5(3) . . . . ?
C8 Fe1 C1 C2 47(2) . . . . ?
C4 Fe1 C1 C2 -81.5(3) . . . . ?
C9 Fe1 C1 C2 -174.8(4) . . . . ?
C10 Fe1 C1 C2 149.8(3) . . . . ?
C5 Fe1 C1 C2 -117.5(4) . . . . ?
C3 Fe1 C1 Au1 -161.3(3) . . . . ?
C7 Fe1 C1 Au1 -55.0(4) . . . . ?
C6 Fe1 C1 Au1 -17.0(3) . . . . ?
C8 Fe1 C1 Au1 -77(2) . . . . ?
C4 Fe1 C1 Au1 155.0(3) . . . . ?
C2 Fe1 C1 Au1 -123.5(4) . . . . ?
C9 Fe1 C1 Au1 61.7(5) . . . . ?
C10 Fe1 C1 Au1 26.3(3) . . . . ?
C5 Fe1 C1 Au1 119.0(4) . . . . ?
C5 C1 C2 C3 -1.1(5) . . . . ?
Au1 C1 C2 C3 166.1(4) . . . . ?
Fe1 C1 C2 C3 58.0(3) . . . . ?
C5 C1 C2 C11 -178.0(5) . . . . ?
Au1 C1 C2 C11 -10.8(7) . . . . ?
Fe1 C1 C2 C11 -119.0(5) . . . . ?
C5 C1 C2 Fe1 -59.1(3) . . . . ?
Au1 C1 C2 Fe1 108.2(4) . . . . ?
C7 Fe1 C2 C3 105.5(3) . . . . ?
C6 Fe1 C2 C3 149.5(3) . . . . ?
C8 Fe1 C2 C3 65.5(4) . . . . ?
C4 Fe1 C2 C3 -38.0(3) . . . . ?
C9 Fe1 C2 C3 26(2) . . . . ?
C10 Fe1 C2 C3 -172.6(4) . . . . ?
C5 Fe1 C2 C3 -81.7(3) . . . . ?
C1 Fe1 C2 C3 -120.0(4) . . . . ?
C3 Fe1 C2 C1 120.0(4) . . . . ?
C7 Fe1 C2 C1 -134.5(3) . . . . ?
C6 Fe1 C2 C1 -90.5(3) . . . . ?
C8 Fe1 C2 C1 -174.5(3) . . . . ?
C4 Fe1 C2 C1 82.0(3) . . . . ?
C9 Fe1 C2 C1 146(2) . . . . ?
C10 Fe1 C2 C1 -52.6(5) . . . . ?
C5 Fe1 C2 C1 38.3(3) . . . . ?
C3 Fe1 C2 C11 -114.9(5) . . . . ?
C7 Fe1 C2 C11 -9.4(5) . . . . ?
C6 Fe1 C2 C11 34.6(5) . . . . ?
C8 Fe1 C2 C11 -49.4(5) . . . . ?
C4 Fe1 C2 C11 -153.0(4) . . . . ?
C9 Fe1 C2 C11 -89(2) . . . . ?
C10 Fe1 C2 C11 72.5(5) . . . . ?
C5 Fe1 C2 C11 163.4(5) . . . . ?
C1 Fe1 C2 C11 125.1(5) . . . . ?
C1 C2 C3 C4 1.1(5) . . . . ?
C11 C2 C3 C4 178.3(4) . . . . ?
Fe1 C2 C3 C4 61.2(3) . . . . ?
C1 C2 C3 Fe1 -60.0(3) . . . . ?
C11 C2 C3 Fe1 117.1(4) . . . . ?
C7 Fe1 C3 C4 148.4(3) . . . . ?
C6 Fe1 C3 C4 -174.7(4) . . . . ?
C8 Fe1 C3 C4 104.4(3) . . . . ?
C2 Fe1 C3 C4 -118.3(4) . . . . ?
C9 Fe1 C3 C4 65.0(4) . . . . ?
C10 Fe1 C3 C4 25.4(18) . . . . ?
C5 Fe1 C3 C4 -38.0(3) . . . . ?
C1 Fe1 C3 C4 -81.2(3) . . . . ?
C7 Fe1 C3 C2 -93.2(3) . . . . ?
C6 Fe1 C3 C2 -56.3(5) . . . . ?
C8 Fe1 C3 C2 -137.3(3) . . . . ?
C4 Fe1 C3 C2 118.3(4) . . . . ?
C9 Fe1 C3 C2 -176.7(3) . . . . ?
C10 Fe1 C3 C2 143.7(16) . . . . ?
C5 Fe1 C3 C2 80.4(3) . . . . ?
C1 Fe1 C3 C2 37.1(3) . . . . ?
C2 C3 C4 C5 -0.7(6) . . . . ?
Fe1 C3 C4 C5 60.3(4) . . . . ?
C2 C3 C4 Fe1 -60.9(3) . . . . ?
C7 Fe1 C4 C3 -57.6(5) . . . . ?
C6 Fe1 C4 C3 157.8(15) . . . . ?
C8 Fe1 C4 C3 -92.9(3) . . . . ?
C2 Fe1 C4 C3 38.7(3) . . . . ?
C9 Fe1 C4 C3 -136.1(3) . . . . ?
C10 Fe1 C4 C3 -175.8(3) . . . . ?
C5 Fe1 C4 C3 118.4(4) . . . . ?
C1 Fe1 C4 C3 82.5(3) . . . . ?
C3 Fe1 C4 C5 -118.4(4) . . . . ?
C7 Fe1 C4 C5 -176.0(4) . . . . ?
C6 Fe1 C4 C5 39.5(17) . . . . ?
C8 Fe1 C4 C5 148.7(3) . . . . ?
C2 Fe1 C4 C5 -79.7(3) . . . . ?
C9 Fe1 C4 C5 105.6(3) . . . . ?
C10 Fe1 C4 C5 65.9(4) . . . . ?
C1 Fe1 C4 C5 -35.8(3) . . . . ?
C3 C4 C5 C1 -0.1(6) . . . . ?
Fe1 C4 C5 C1 58.8(4) . . . . ?
C3 C4 C5 Fe1 -58.8(3) . . . . ?
C2 C1 C5 C4 0.7(6) . . . . ?
Au1 C1 C5 C4 -167.2(4) . . . . ?
Fe1 C1 C5 C4 -57.7(4) . . . . ?
C2 C1 C5 Fe1 58.4(3) . . . . ?
Au1 C1 C5 Fe1 -109.5(4) . . . . ?
C3 Fe1 C5 C4 38.3(3) . . . . ?
C7 Fe1 C5 C4 161.1(18) . . . . ?
C6 Fe1 C5 C4 -173.2(3) . . . . ?
C8 Fe1 C5 C4 -55.4(5) . . . . ?
C2 Fe1 C5 C4 83.3(3) . . . . ?
C9 Fe1 C5 C4 -91.0(3) . . . . ?
C10 Fe1 C5 C4 -134.8(3) . . . . ?
C1 Fe1 C5 C4 122.1(4) . . . . ?
C3 Fe1 C5 C1 -83.8(3) . . . . ?
C7 Fe1 C5 C1 39(2) . . . . ?
C6 Fe1 C5 C1 64.7(4) . . . . ?
C8 Fe1 C5 C1 -177.5(4) . . . . ?
C4 Fe1 C5 C1 -122.1(4) . . . . ?
C2 Fe1 C5 C1 -38.8(3) . . . . ?
C9 Fe1 C5 C1 146.9(3) . . . . ?
C10 Fe1 C5 C1 103.1(3) . . . . ?
C3 Fe1 C6 C7 -56.3(5) . . . . ?
C8 Fe1 C6 C7 37.7(4) . . . . ?
C4 Fe1 C6 C7 150.1(15) . . . . ?
C2 Fe1 C6 C7 -93.7(4) . . . . ?
C9 Fe1 C6 C7 81.3(4) . . . . ?
C10 Fe1 C6 C7 119.8(5) . . . . ?
C5 Fe1 C6 C7 -175.4(3) . . . . ?
C1 Fe1 C6 C7 -137.4(3) . . . . ?
C3 Fe1 C6 C10 -176.2(4) . . . . ?
C7 Fe1 C6 C10 -119.8(5) . . . . ?
C8 Fe1 C6 C10 -82.1(4) . . . . ?
C4 Fe1 C6 C10 30.3(17) . . . . ?
C2 Fe1 C6 C10 146.4(3) . . . . ?
C9 Fe1 C6 C10 -38.5(3) . . . . ?
C5 Fe1 C6 C10 64.8(4) . . . . ?
C1 Fe1 C6 C10 102.8(3) . . . . ?
C10 C6 C7 C8 0.0(6) . . . . ?
Fe1 C6 C7 C8 -59.6(4) . . . . ?
C10 C6 C7 Fe1 59.6(4) . . . . ?
C3 Fe1 C7 C6 149.3(3) . . . . ?
C8 Fe1 C7 C6 -119.4(5) . . . . ?
C4 Fe1 C7 C6 -173.0(4) . . . . ?
C2 Fe1 C7 C6 104.2(3) . . . . ?
C9 Fe1 C7 C6 -81.6(4) . . . . ?
C10 Fe1 C7 C6 -37.3(3) . . . . ?
C5 Fe1 C7 C6 29(2) . . . . ?
C1 Fe1 C7 C6 63.6(4) . . . . ?
C3 Fe1 C7 C8 -91.3(4) . . . . ?
C6 Fe1 C7 C8 119.4(5) . . . . ?
C4 Fe1 C7 C8 -53.6(6) . . . . ?
C2 Fe1 C7 C8 -136.4(3) . . . . ?
C9 Fe1 C7 C8 37.8(3) . . . . ?
C10 Fe1 C7 C8 82.1(4) . . . . ?
C5 Fe1 C7 C8 148.5(18) . . . . ?
C1 Fe1 C7 C8 -177.0(3) . . . . ?
C6 C7 C8 C9 -0.3(7) . . . . ?
Fe1 C7 C8 C9 -60.0(4) . . . . ?
C6 C7 C8 Fe1 59.6(4) . . . . ?
C3 Fe1 C8 C9 -134.7(3) . . . . ?
C7 Fe1 C8 C9 118.7(5) . . . . ?
C6 Fe1 C8 C9 81.2(4) . . . . ?
C4 Fe1 C8 C9 -90.8(4) . . . . ?
C2 Fe1 C8 C9 -174.6(3) . . . . ?
C10 Fe1 C8 C9 37.6(4) . . . . ?
C5 Fe1 C8 C9 -55.0(5) . . . . ?
C1 Fe1 C8 C9 143(2) . . . . ?
C3 Fe1 C8 C7 106.5(4) . . . . ?
C6 Fe1 C8 C7 -37.5(3) . . . . ?
C4 Fe1 C8 C7 150.4(3) . . . . ?
C2 Fe1 C8 C7 66.7(4) . . . . ?
C9 Fe1 C8 C7 -118.7(5) . . . . ?
C10 Fe1 C8 C7 -81.2(4) . . . . ?
C5 Fe1 C8 C7 -173.7(4) . . . . ?
C1 Fe1 C8 C7 24(2) . . . . ?
C7 C8 C9 C10 0.5(7) . . . . ?
Fe1 C8 C9 C10 -58.9(4) . . . . ?
C7 C8 C9 Fe1 59.4(4) . . . . ?
C3 Fe1 C9 C8 67.1(5) . . . . ?
C7 Fe1 C9 C8 -38.1(4) . . . . ?
C6 Fe1 C9 C8 -82.0(4) . . . . ?
C4 Fe1 C9 C8 105.7(4) . . . . ?
C2 Fe1 C9 C8 43(3) . . . . ?
C10 Fe1 C9 C8 -120.0(5) . . . . ?
C5 Fe1 C9 C8 148.9(3) . . . . ?
C1 Fe1 C9 C8 -174.6(3) . . . . ?
C3 Fe1 C9 C10 -172.9(3) . . . . ?
C7 Fe1 C9 C10 81.9(4) . . . . ?
C6 Fe1 C9 C10 38.1(3) . . . . ?
C8 Fe1 C9 C10 120.0(5) . . . . ?
C4 Fe1 C9 C10 -134.3(3) . . . . ?
C2 Fe1 C9 C10 163(2) . . . . ?
C5 Fe1 C9 C10 -91.1(4) . . . . ?
C1 Fe1 C9 C10 -54.6(5) . . . . ?
C7 C6 C10 C9 0.3(6) . . . . ?
Fe1 C6 C10 C9 59.4(4) . . . . ?
C7 C6 C10 Fe1 -59.1(4) . . . . ?
C8 C9 C10 C6 -0.5(6) . . . . ?
Fe1 C9 C10 C6 -59.3(4) . . . . ?
C8 C9 C10 Fe1 58.7(4) . . . . ?
C3 Fe1 C10 C6 163.0(16) . . . . ?
C7 Fe1 C10 C6 37.3(3) . . . . ?
C8 Fe1 C10 C6 81.3(4) . . . . ?
C4 Fe1 C10 C6 -174.7(3) . . . . ?
C2 Fe1 C10 C6 -59.1(5) . . . . ?
C9 Fe1 C10 C6 118.3(5) . . . . ?
C5 Fe1 C10 C6 -136.0(3) . . . . ?
C1 Fe1 C10 C6 -93.2(3) . . . . ?
C3 Fe1 C10 C9 44.7(18) . . . . ?
C7 Fe1 C10 C9 -81.0(4) . . . . ?
C6 Fe1 C10 C9 -118.3(5) . . . . ?
C8 Fe1 C10 C9 -37.0(4) . . . . ?
C4 Fe1 C10 C9 67.1(4) . . . . ?
C2 Fe1 C10 C9 -177.3(4) . . . . ?
C5 Fe1 C10 C9 105.7(4) . . . . ?
C1 Fe1 C10 C9 148.5(3) . . . . ?
C13 N1 C11 O1 -4.1(6) . . . . ?
Au2 N1 C11 O1 175.4(3) . . . . ?
C13 N1 C11 C2 177.9(5) . . . . ?
Au2 N1 C11 C2 -2.7(8) . . . . ?
C12 O1 C11 N1 -7.8(6) . . . . ?
C12 O1 C11 C2 170.6(4) . . . . ?
C3 C2 C11 N1 168.1(5) . . . . ?
C1 C2 C11 N1 -15.3(9) . . . . ?
Fe1 C2 C11 N1 -108.2(6) . . . . ?
C3 C2 C11 O1 -9.9(6) . . . . ?
C1 C2 C11 O1 166.6(5) . . . . ?
Fe1 C2 C11 O1 73.8(5) . . . . ?
C11 O1 C12 C13 15.3(5) . . . . ?
C11 N1 C13 C14 -111.4(5) . . . . ?
Au2 N1 C13 C14 69.1(5) . . . . ?
C11 N1 C13 C12 13.2(5) . . . . ?
Au2 N1 C13 C12 -166.3(3) . . . . ?
O1 C12 C13 N1 -16.7(5) . . . . ?
O1 C12 C13 C14 104.8(5) . . . . ?
N1 C13 C14 C16 -174.8(5) . . . . ?
C12 C13 C14 C16 69.0(6) . . . . ?
N1 C13 C14 C15 59.8(6) . . . . ?
C12 C13 C14 C15 -56.4(6) . . . . ?
N1 Au2 C17 C18 -132(3) . . . . ?
Au1 Au2 C17 C18 29.1(4) . . . . ?
Au4 Au2 C17 C18 162.6(4) . . . . ?
N1 Au2 C17 C21 46(3) . . . . ?
Au1 Au2 C17 C21 -152.8(4) . . . . ?
Au4 Au2 C17 C21 -19.3(4) . . . . ?
N1 Au2 C17 Fe2 -43(3) . . . . ?
Au1 Au2 C17 Fe2 118.7(3) . . . . ?
Au4 Au2 C17 Fe2 -107.9(3) . . . . ?
C19 Fe2 C17 C18 -37.7(3) . . . . ?
C23 Fe2 C17 C18 80.3(3) . . . . ?
C20 Fe2 C17 C18 -81.4(3) . . . . ?
C24 Fe2 C17 C18 47.0(6) . . . . ?
C22 Fe2 C17 C18 123.1(3) . . . . ?
C25 Fe2 C17 C18 -163.4(6) . . . . ?
C21 Fe2 C17 C18 -117.3(4) . . . . ?
C26 Fe2 C17 C18 163.9(3) . . . . ?
C19 Fe2 C17 C21 79.6(3) . . . . ?
C18 Fe2 C17 C21 117.3(4) . . . . ?
C23 Fe2 C17 C21 -162.4(3) . . . . ?
C20 Fe2 C17 C21 35.9(3) . . . . ?
C24 Fe2 C17 C21 164.3(5) . . . . ?
C22 Fe2 C17 C21 -119.6(3) . . . . ?
C25 Fe2 C17 C21 -46.1(8) . . . . ?
C26 Fe2 C17 C21 -78.8(4) . . . . ?
C19 Fe2 C17 Au2 -161.1(4) . . . . ?
C18 Fe2 C17 Au2 -123.4(4) . . . . ?
C23 Fe2 C17 Au2 -43.0(4) . . . . ?
C20 Fe2 C17 Au2 155.2(4) . . . . ?
C24 Fe2 C17 Au2 -76.4(6) . . . . ?
C22 Fe2 C17 Au2 -0.3(4) . . . . ?
C25 Fe2 C17 Au2 73.2(8) . . . . ?
C21 Fe2 C17 Au2 119.3(4) . . . . ?
C26 Fe2 C17 Au2 40.5(4) . . . . ?
C21 C17 C18 C19 -0.1(5) . . . . ?
Au2 C17 C18 C19 178.3(4) . . . . ?
Fe2 C17 C18 C19 58.5(3) . . . . ?
C21 C17 C18 C27 -176.3(5) . . . . ?
Au2 C17 C18 C27 2.1(8) . . . . ?
Fe2 C17 C18 C27 -117.7(5) . . . . ?
C21 C17 C18 Fe2 -58.7(3) . . . . ?
Au2 C17 C18 Fe2 119.7(4) . . . . ?
C19 Fe2 C18 C17 120.6(4) . . . . ?
C23 Fe2 C18 C17 -117.3(3) . . . . ?
C20 Fe2 C18 C17 82.1(3) . . . . ?
C24 Fe2 C18 C17 -159.6(3) . . . . ?
C22 Fe2 C18 C17 -76.4(3) . . . . ?
C25 Fe2 C18 C17 168.0(5) . . . . ?
C21 Fe2 C18 C17 38.7(3) . . . . ?
C26 Fe2 C18 C17 -46.5(8) . . . . ?
C23 Fe2 C18 C19 122.1(3) . . . . ?
C20 Fe2 C18 C19 -38.5(3) . . . . ?
C24 Fe2 C18 C19 79.8(4) . . . . ?
C22 Fe2 C18 C19 163.0(3) . . . . ?
C25 Fe2 C18 C19 47.3(6) . . . . ?
C21 Fe2 C18 C19 -82.0(3) . . . . ?
C26 Fe2 C18 C19 -167.2(6) . . . . ?
C17 Fe2 C18 C19 -120.6(4) . . . . ?
C19 Fe2 C18 C27 -114.5(5) . . . . ?
C23 Fe2 C18 C27 7.6(5) . . . . ?
C20 Fe2 C18 C27 -153.0(5) . . . . ?
C24 Fe2 C18 C27 -34.7(5) . . . . ?
C22 Fe2 C18 C27 48.6(5) . . . . ?
C25 Fe2 C18 C27 -67.1(7) . . . . ?
C21 Fe2 C18 C27 163.6(5) . . . . ?
C26 Fe2 C18 C27 78.4(8) . . . . ?
C17 Fe2 C18 C27 124.9(5) . . . . ?
C17 C18 C19 C20 0.5(6) . . . . ?
C27 C18 C19 C20 177.0(4) . . . . ?
Fe2 C18 C19 C20 60.9(3) . . . . ?
C17 C18 C19 Fe2 -60.4(3) . . . . ?
C27 C18 C19 Fe2 116.1(5) . . . . ?
C18 Fe2 C19 C20 -117.4(4) . . . . ?
C23 Fe2 C19 C20 165.6(3) . . . . ?
C24 Fe2 C19 C20 124.6(3) . . . . ?
C22 Fe2 C19 C20 -167.2(6) . . . . ?
C25 Fe2 C19 C20 83.1(3) . . . . ?
C21 Fe2 C19 C20 -37.1(3) . . . . ?
C26 Fe2 C19 C20 53.0(6) . . . . ?
C17 Fe2 C19 C20 -80.6(3) . . . . ?
C23 Fe2 C19 C18 -77.0(4) . . . . ?
C20 Fe2 C19 C18 117.4(4) . . . . ?
C24 Fe2 C19 C18 -118.0(3) . . . . ?
C22 Fe2 C19 C18 -49.8(8) . . . . ?
C25 Fe2 C19 C18 -159.6(3) . . . . ?
C21 Fe2 C19 C18 80.3(3) . . . . ?
C26 Fe2 C19 C18 170.4(5) . . . . ?
C17 Fe2 C19 C18 36.8(3) . . . . ?
C18 C19 C20 C21 -0.6(6) . . . . ?
Fe2 C19 C20 C21 59.5(3) . . . . ?
C18 C19 C20 Fe2 -60.1(3) . . . . ?
C19 Fe2 C20 C21 -119.7(4) . . . . ?
C18 Fe2 C20 C21 -80.2(3) . . . . ?
C23 Fe2 C20 C21 -159.5(6) . . . . ?
C24 Fe2 C20 C21 166.8(3) . . . . ?
C22 Fe2 C20 C21 50.2(6) . . . . ?
C25 Fe2 C20 C21 125.5(3) . . . . ?
C26 Fe2 C20 C21 83.2(3) . . . . ?
C17 Fe2 C20 C21 -36.2(3) . . . . ?
C18 Fe2 C20 C19 39.5(3) . . . . ?
C23 Fe2 C20 C19 -39.8(8) . . . . ?
C24 Fe2 C20 C19 -73.5(4) . . . . ?
C22 Fe2 C20 C19 169.9(5) . . . . ?
C25 Fe2 C20 C19 -114.8(3) . . . . ?
C21 Fe2 C20 C19 119.7(4) . . . . ?
C26 Fe2 C20 C19 -157.1(3) . . . . ?
C17 Fe2 C20 C19 83.5(3) . . . . ?
C19 C20 C21 C17 0.6(6) . . . . ?
Fe2 C20 C21 C17 59.0(4) . . . . ?
C19 C20 C21 Fe2 -58.4(3) . . . . ?
C18 C17 C21 C20 -0.3(5) . . . . ?
Au2 C17 C21 C20 -178.7(3) . . . . ?
Fe2 C17 C21 C20 -58.1(4) . . . . ?
C18 C17 C21 Fe2 57.8(3) . . . . ?
Au2 C17 C21 Fe2 -120.6(4) . . . . ?
C19 Fe2 C21 C20 37.7(3) . . . . ?
C18 Fe2 C21 C20 83.0(3) . . . . ?
C23 Fe2 C21 C20 163.3(5) . . . . ?
C24 Fe2 C21 C20 -37.1(8) . . . . ?
C22 Fe2 C21 C20 -158.9(3) . . . . ?
C25 Fe2 C21 C20 -73.6(4) . . . . ?
C26 Fe2 C21 C20 -116.2(3) . . . . ?
C17 Fe2 C21 C20 122.0(4) . . . . ?
C19 Fe2 C21 C17 -84.3(3) . . . . ?
C18 Fe2 C21 C17 -38.9(3) . . . . ?
C23 Fe2 C21 C17 41.4(6) . . . . ?
C20 Fe2 C21 C17 -122.0(4) . . . . ?
C24 Fe2 C21 C17 -159.1(6) . . . . ?
C22 Fe2 C21 C17 79.1(3) . . . . ?
C25 Fe2 C21 C17 164.4(3) . . . . ?
C26 Fe2 C21 C17 121.8(3) . . . . ?
C19 Fe2 C22 C26 -155.4(6) . . . . ?
C18 Fe2 C22 C26 166.1(3) . . . . ?
C23 Fe2 C22 C26 -119.7(5) . . . . ?
C20 Fe2 C22 C26 46.0(6) . . . . ?
C24 Fe2 C22 C26 -81.3(3) . . . . ?
C25 Fe2 C22 C26 -37.6(3) . . . . ?
C21 Fe2 C22 C26 82.1(4) . . . . ?
C17 Fe2 C22 C26 124.2(3) . . . . ?
C19 Fe2 C22 C23 -35.7(8) . . . . ?
C18 Fe2 C22 C23 -74.1(4) . . . . ?
C20 Fe2 C22 C23 165.8(5) . . . . ?
C24 Fe2 C22 C23 38.5(3) . . . . ?
C25 Fe2 C22 C23 82.2(3) . . . . ?
C21 Fe2 C22 C23 -158.2(3) . . . . ?
C26 Fe2 C22 C23 119.7(5) . . . . ?
C17 Fe2 C22 C23 -116.0(3) . . . . ?
C26 C22 C23 C24 -0.5(6) . . . . ?
Fe2 C22 C23 C24 -60.0(3) . . . . ?
C26 C22 C23 Fe2 59.5(4) . . . . ?
C19 Fe2 C23 C22 167.3(3) . . . . ?
C18 Fe2 C23 C22 124.5(3) . . . . ?
C20 Fe2 C23 C22 -162.6(6) . . . . ?
C24 Fe2 C23 C22 -118.1(5) . . . . ?
C25 Fe2 C23 C22 -80.9(3) . . . . ?
C21 Fe2 C23 C22 52.3(7) . . . . ?
C26 Fe2 C23 C22 -37.1(3) . . . . ?
C17 Fe2 C23 C22 82.2(3) . . . . ?
C19 Fe2 C23 C24 -74.6(4) . . . . ?
C18 Fe2 C23 C24 -117.4(3) . . . . ?
C20 Fe2 C23 C24 -44.5(8) . . . . ?
C22 Fe2 C23 C24 118.1(5) . . . . ?
C25 Fe2 C23 C24 37.2(3) . . . . ?
C21 Fe2 C23 C24 170.4(5) . . . . ?
C26 Fe2 C23 C24 81.0(3) . . . . ?
C17 Fe2 C23 C24 -159.7(3) . . . . ?
C22 C23 C24 C25 0.8(6) . . . . ?
Fe2 C23 C24 C25 -59.4(4) . . . . ?
C22 C23 C24 Fe2 60.2(3) . . . . ?
C19 Fe2 C24 C25 -116.8(3) . . . . ?
C18 Fe2 C24 C25 -160.0(3) . . . . ?
C23 Fe2 C24 C25 119.8(4) . . . . ?
C20 Fe2 C24 C25 -76.1(4) . . . . ?
C22 Fe2 C24 C25 81.5(3) . . . . ?
C21 Fe2 C24 C25 -48.0(8) . . . . ?
C26 Fe2 C24 C25 38.0(3) . . . . ?
C17 Fe2 C24 C25 166.4(4) . . . . ?
C19 Fe2 C24 C23 123.4(3) . . . . ?
C18 Fe2 C24 C23 80.2(4) . . . . ?
C20 Fe2 C24 C23 164.1(3) . . . . ?
C22 Fe2 C24 C23 -38.3(3) . . . . ?
C25 Fe2 C24 C23 -119.8(4) . . . . ?
C21 Fe2 C24 C23 -167.8(6) . . . . ?
C26 Fe2 C24 C23 -81.8(3) . . . . ?
C17 Fe2 C24 C23 46.6(6) . . . . ?
C23 C24 C25 C26 -0.8(6) . . . . ?
Fe2 C24 C25 C26 -59.7(4) . . . . ?
C23 C24 C25 Fe2 59.0(4) . . . . ?
C19 Fe2 C25 C24 79.9(4) . . . . ?
C18 Fe2 C25 C24 45.6(6) . . . . ?
C23 Fe2 C25 C24 -37.6(3) . . . . ?
C20 Fe2 C25 C24 122.8(3) . . . . ?
C22 Fe2 C25 C24 -81.5(3) . . . . ?
C21 Fe2 C25 C24 163.3(3) . . . . ?
C26 Fe2 C25 C24 -118.7(5) . . . . ?
C17 Fe2 C25 C24 -161.3(6) . . . . ?
C19 Fe2 C25 C26 -161.4(3) . . . . ?
C18 Fe2 C25 C26 164.3(5) . . . . ?
C23 Fe2 C25 C26 81.1(3) . . . . ?
C20 Fe2 C25 C26 -118.5(3) . . . . ?
C24 Fe2 C25 C26 118.7(5) . . . . ?
C22 Fe2 C25 C26 37.2(3) . . . . ?
C21 Fe2 C25 C26 -78.0(4) . . . . ?
C17 Fe2 C25 C26 -42.6(8) . . . . ?
C23 C22 C26 C25 0.1(6) . . . . ?
Fe2 C22 C26 C25 59.0(4) . . . . ?
C23 C22 C26 Fe2 -58.9(3) . . . . ?
C24 C25 C26 C22 0.4(6) . . . . ?
Fe2 C25 C26 C22 -59.1(4) . . . . ?
C24 C25 C26 Fe2 59.5(4) . . . . ?
C19 Fe2 C26 C22 161.7(5) . . . . ?
C18 Fe2 C26 C22 -39.3(8) . . . . ?
C23 Fe2 C26 C22 37.6(3) . . . . ?
C20 Fe2 C26 C22 -160.5(3) . . . . ?
C24 Fe2 C26 C22 81.8(3) . . . . ?
C25 Fe2 C26 C22 119.6(5) . . . . ?
C21 Fe2 C26 C22 -117.6(3) . . . . ?
C17 Fe2 C26 C22 -74.9(4) . . . . ?
C19 Fe2 C26 C25 42.1(7) . . . . ?
C18 Fe2 C26 C25 -158.9(6) . . . . ?
C23 Fe2 C26 C25 -82.0(3) . . . . ?
C20 Fe2 C26 C25 79.9(4) . . . . ?
C24 Fe2 C26 C25 -37.8(3) . . . . ?
C22 Fe2 C26 C25 -119.6(5) . . . . ?
C21 Fe2 C26 C25 122.8(3) . . . . ?
C17 Fe2 C26 C25 165.5(3) . . . . ?
C29 N2 C27 O2 -3.0(6) . . . . ?
Au1 N2 C27 O2 176.4(3) . . . . ?
C29 N2 C27 C18 -178.8(5) . . . . ?
Au1 N2 C27 C18 0.6(8) . . . . ?
C28 O2 C27 N2 3.4(6) . . . . ?
C28 O2 C27 C18 179.8(4) . . . . ?
C17 C18 C27 N2 -29.7(9) . . . . ?
C19 C18 C27 N2 154.5(5) . . . . ?
Fe2 C18 C27 N2 -122.0(5) . . . . ?
C17 C18 C27 O2 154.5(5) . . . . ?
C19 C18 C27 O2 -21.4(7) . . . . ?
Fe2 C18 C27 O2 62.2(5) . . . . ?
C27 O2 C28 C29 -2.3(5) . . . . ?
C27 N2 C29 C28 1.2(5) . . . . ?
Au1 N2 C29 C28 -178.3(3) . . . . ?
C27 N2 C29 C30 -123.8(4) . . . . ?
Au1 N2 C29 C30 56.6(5) . . . . ?
O2 C28 C29 N2 0.7(5) . . . . ?
O2 C28 C29 C30 123.2(4) . . . . ?
N2 C29 C30 C32 53.7(6) . . . . ?
C28 C29 C30 C32 -64.0(5) . . . . ?
N2 C29 C30 C31 179.9(4) . . . . ?
C28 C29 C30 C31 62.2(6) . . . . ?
N4 Au3 C33 C37 46(2) . . . . ?
Au4 Au3 C33 C37 -161.8(4) . . . . ?
N4 Au3 C33 C34 -125.1(18) . . . . ?
Au4 Au3 C33 C34 27.2(4) . . . . ?
N4 Au3 C33 Fe3 -39(2) . . . . ?
Au4 Au3 C33 Fe3 113.6(3) . . . . ?
C35 Fe3 C33 C37 80.0(3) . . . . ?
C42 Fe3 C33 C37 -171.2(4) . . . . ?
C34 Fe3 C33 C37 117.4(4) . . . . ?
C36 Fe3 C33 C37 36.0(3) . . . . ?
C40 Fe3 C33 C37 -52.6(6) . . . . ?
C39 Fe3 C33 C37 -87.2(4) . . . . ?
C38 Fe3 C33 C37 -131.3(3) . . . . ?
C41 Fe3 C33 C37 160.3(16) . . . . ?
C35 Fe3 C33 C34 -37.3(3) . . . . ?
C42 Fe3 C33 C34 71.5(4) . . . . ?
C36 Fe3 C33 C34 -81.4(3) . . . . ?
C40 Fe3 C33 C34 -169.9(5) . . . . ?
C39 Fe3 C33 C34 155.4(4) . . . . ?
C38 Fe3 C33 C34 111.3(4) . . . . ?
C41 Fe3 C33 C34 43.0(17) . . . . ?
C37 Fe3 C33 C34 -117.4(4) . . . . ?
C35 Fe3 C33 Au3 -162.0(3) . . . . ?
C42 Fe3 C33 Au3 -53.2(4) . . . . ?
C34 Fe3 C33 Au3 -124.7(4) . . . . ?
C36 Fe3 C33 Au3 153.9(3) . . . . ?
C40 Fe3 C33 Au3 65.4(6) . . . . ?
C39 Fe3 C33 Au3 30.7(4) . . . . ?
C38 Fe3 C33 Au3 -13.4(4) . . . . ?
C41 Fe3 C33 Au3 -81.7(16) . . . . ?
C37 Fe3 C33 Au3 118.0(4) . . . . ?
C37 C33 C34 C35 -0.2(5) . . . . ?
Au3 C33 C34 C35 172.2(4) . . . . ?
Fe3 C33 C34 C35 58.5(3) . . . . ?
C37 C33 C34 C43 -179.2(5) . . . . ?
Au3 C33 C34 C43 -6.8(8) . . . . ?
Fe3 C33 C34 C43 -120.4(5) . . . . ?
C37 C33 C34 Fe3 -58.7(3) . . . . ?
Au3 C33 C34 Fe3 113.6(4) . . . . ?
C42 Fe3 C34 C35 108.3(4) . . . . ?
C36 Fe3 C34 C35 -38.5(3) . . . . ?
C40 Fe3 C34 C35 32.7(15) . . . . ?
C39 Fe3 C34 C35 -169.2(5) . . . . ?
C38 Fe3 C34 C35 153.0(3) . . . . ?
C41 Fe3 C34 C35 68.6(5) . . . . ?
C37 Fe3 C34 C35 -82.0(3) . . . . ?
C33 Fe3 C34 C35 -120.4(4) . . . . ?
C35 Fe3 C34 C43 -114.9(5) . . . . ?
C42 Fe3 C34 C43 -6.6(6) . . . . ?
C36 Fe3 C34 C43 -153.4(5) . . . . ?
C40 Fe3 C34 C43 -82.2(15) . . . . ?
C39 Fe3 C34 C43 75.9(6) . . . . ?
C38 Fe3 C34 C43 38.1(5) . . . . ?
C41 Fe3 C34 C43 -46.3(6) . . . . ?
C37 Fe3 C34 C43 163.0(5) . . . . ?
C33 Fe3 C34 C43 124.7(6) . . . . ?
C35 Fe3 C34 C33 120.4(4) . . . . ?
C42 Fe3 C34 C33 -131.3(4) . . . . ?
C36 Fe3 C34 C33 81.9(3) . . . . ?
C40 Fe3 C34 C33 153.1(13) . . . . ?
C39 Fe3 C34 C33 -48.8(6) . . . . ?
C38 Fe3 C34 C33 -86.6(4) . . . . ?
C41 Fe3 C34 C33 -171.0(5) . . . . ?
C37 Fe3 C34 C33 38.4(3) . . . . ?
C43 C34 C35 C36 179.2(5) . . . . ?
C33 C34 C35 C36 0.2(6) . . . . ?
Fe3 C34 C35 C36 60.3(4) . . . . ?
C43 C34 C35 Fe3 119.0(5) . . . . ?
C33 C34 C35 Fe3 -60.1(3) . . . . ?
C42 Fe3 C35 C36 151.4(5) . . . . ?
C34 Fe3 C35 C36 -118.1(4) . . . . ?
C40 Fe3 C35 C36 69.9(4) . . . . ?
C39 Fe3 C35 C36 37.4(11) . . . . ?
C38 Fe3 C35 C36 -172.5(5) . . . . ?
C41 Fe3 C35 C36 109.6(4) . . . . ?
C37 Fe3 C35 C36 -37.5(3) . . . . ?
C33 Fe3 C35 C36 -80.7(3) . . . . ?
C42 Fe3 C35 C34 -90.5(5) . . . . ?
C36 Fe3 C35 C34 118.1(4) . . . . ?
C40 Fe3 C35 C34 -172.0(3) . . . . ?
C39 Fe3 C35 C34 155.5(10) . . . . ?
C38 Fe3 C35 C34 -54.4(6) . . . . ?
C41 Fe3 C35 C34 -132.3(4) . . . . ?
C37 Fe3 C35 C34 80.6(3) . . . . ?
C33 Fe3 C35 C34 37.3(3) . . . . ?
C34 C35 C36 C37 -0.1(6) . . . . ?
Fe3 C35 C36 C37 60.1(4) . . . . ?
C34 C35 C36 Fe3 -60.2(3) . . . . ?
C35 Fe3 C36 C37 -119.1(4) . . . . ?
C42 Fe3 C36 C37 -174.9(6) . . . . ?
C34 Fe3 C36 C37 -80.4(3) . . . . ?
C40 Fe3 C36 C37 111.1(3) . . . . ?
C39 Fe3 C36 C37 71.0(4) . . . . ?
C38 Fe3 C36 C37 43.2(14) . . . . ?
C41 Fe3 C36 C37 153.2(3) . . . . ?
C33 Fe3 C36 C37 -36.0(3) . . . . ?
C42 Fe3 C36 C35 -55.8(7) . . . . ?
C34 Fe3 C36 C35 38.7(3) . . . . ?
C40 Fe3 C36 C35 -129.9(3) . . . . ?
C39 Fe3 C36 C35 -170.0(3) . . . . ?
C38 Fe3 C36 C35 162.3(13) . . . . ?
C41 Fe3 C36 C35 -87.7(4) . . . . ?
C37 Fe3 C36 C35 119.1(4) . . . . ?
C33 Fe3 C36 C35 83.1(3) . . . . ?
C35 C36 C37 C33 0.0(6) . . . . ?
Fe3 C36 C37 C33 59.0(4) . . . . ?
C35 C36 C37 Fe3 -59.0(4) . . . . ?
C34 C33 C37 C36 0.1(6) . . . . ?
Au3 C33 C37 C36 -172.8(4) . . . . ?
Fe3 C33 C37 C36 -57.8(4) . . . . ?
C34 C33 C37 Fe3 57.9(3) . . . . ?
Au3 C33 C37 Fe3 -115.1(4) . . . . ?
C35 Fe3 C37 C36 38.2(3) . . . . ?
C42 Fe3 C37 C36 164.2(16) . . . . ?
C34 Fe3 C37 C36 82.8(3) . . . . ?
C40 Fe3 C37 C36 -85.4(4) . . . . ?
C39 Fe3 C37 C36 -128.6(4) . . . . ?
C38 Fe3 C37 C36 -169.0(4) . . . . ?
C41 Fe3 C37 C36 -51.4(6) . . . . ?
C33 Fe3 C37 C36 122.1(4) . . . . ?
C35 Fe3 C37 C33 -83.9(3) . . . . ?
C42 Fe3 C37 C33 42.1(17) . . . . ?
C34 Fe3 C37 C33 -39.3(3) . . . . ?
C36 Fe3 C37 C33 -122.1(4) . . . . ?
C40 Fe3 C37 C33 152.5(3) . . . . ?
C39 Fe3 C37 C33 109.3(4) . . . . ?
C38 Fe3 C37 C33 68.9(4) . . . . ?
C41 Fe3 C37 C33 -173.5(5) . . . . ?
C35 Fe3 C38 C42 -52.7(8) . . . . ?
C34 Fe3 C38 C42 -89.9(6) . . . . ?
C36 Fe3 C38 C42 151.2(12) . . . . ?
C40 Fe3 C38 C42 79.3(6) . . . . ?
C39 Fe3 C38 C42 117.6(7) . . . . ?
C41 Fe3 C38 C42 36.1(5) . . . . ?
C37 Fe3 C38 C42 -173.3(5) . . . . ?
C33 Fe3 C38 C42 -133.9(5) . . . . ?
C35 Fe3 C38 C39 -170.2(4) . . . . ?
C42 Fe3 C38 C39 -117.6(7) . . . . ?
C34 Fe3 C38 C39 152.5(4) . . . . ?
C36 Fe3 C38 C39 33.7(15) . . . . ?
C40 Fe3 C38 C39 -38.2(4) . . . . ?
C41 Fe3 C38 C39 -81.4(5) . . . . ?
C37 Fe3 C38 C39 69.1(5) . . . . ?
C33 Fe3 C38 C39 108.6(4) . . . . ?
C42 C38 C39 C40 0.3(7) . . . . ?
Fe3 C38 C39 C40 59.7(4) . . . . ?
C42 C38 C39 Fe3 -59.4(4) . . . . ?
C35 Fe3 C39 C40 40.0(12) . . . . ?
C42 Fe3 C39 C40 -79.3(5) . . . . ?
C34 Fe3 C39 C40 -173.4(5) . . . . ?
C36 Fe3 C39 C40 70.5(5) . . . . ?
C38 Fe3 C39 C40 -118.2(6) . . . . ?
C41 Fe3 C39 C40 -36.8(5) . . . . ?
C37 Fe3 C39 C40 110.4(4) . . . . ?
C33 Fe3 C39 C40 153.1(4) . . . . ?
C35 Fe3 C39 C38 158.2(9) . . . . ?
C42 Fe3 C39 C38 38.9(5) . . . . ?
C34 Fe3 C39 C38 -55.3(6) . . . . ?
C36 Fe3 C39 C38 -171.4(4) . . . . ?
C40 Fe3 C39 C38 118.2(6) . . . . ?
C41 Fe3 C39 C38 81.4(5) . . . . ?
C37 Fe3 C39 C38 -131.4(4) . . . . ?
C33 Fe3 C39 C38 -88.7(4) . . . . ?
C38 C39 C40 C41 -0.2(7) . . . . ?
Fe3 C39 C40 C41 59.4(5) . . . . ?
C38 C39 C40 Fe3 -59.6(4) . . . . ?
C35 Fe3 C40 C41 70.6(6) . . . . ?
C42 Fe3 C40 C41 -36.6(5) . . . . ?
C34 Fe3 C40 C41 43.5(17) . . . . ?
C36 Fe3 C40 C41 110.9(5) . . . . ?
C39 Fe3 C40 C41 -120.0(7) . . . . ?
C38 Fe3 C40 C41 -81.3(6) . . . . ?
C37 Fe3 C40 C41 153.4(5) . . . . ?
C33 Fe3 C40 C41 -171.6(5) . . . . ?
C35 Fe3 C40 C39 -169.3(4) . . . . ?
C42 Fe3 C40 C39 83.5(5) . . . . ?
C34 Fe3 C40 C39 163.5(12) . . . . ?
C36 Fe3 C40 C39 -129.1(4) . . . . ?
C38 Fe3 C40 C39 38.7(4) . . . . ?
C41 Fe3 C40 C39 120.0(7) . . . . ?
C37 Fe3 C40 C39 -86.6(5) . . . . ?
C33 Fe3 C40 C39 -51.5(7) . . . . ?
C39 C40 C41 C42 0.0(8) . . . . ?
Fe3 C40 C41 C42 59.0(5) . . . . ?
C39 C40 C41 Fe3 -59.0(4) . . . . ?
C35 Fe3 C41 C42 110.8(5) . . . . ?
C34 Fe3 C41 C42 70.5(6) . . . . ?
C36 Fe3 C41 C42 154.6(4) . . . . ?
C40 Fe3 C41 C42 -120.0(7) . . . . ?
C39 Fe3 C41 C42 -82.5(5) . . . . ?
C38 Fe3 C41 C42 -37.8(5) . . . . ?
C37 Fe3 C41 C42 -171.0(4) . . . . ?
C33 Fe3 C41 C42 33.9(18) . . . . ?
C35 Fe3 C41 C40 -129.1(5) . . . . ?
C42 Fe3 C41 C40 120.0(7) . . . . ?
C34 Fe3 C41 C40 -169.4(4) . . . . ?
C36 Fe3 C41 C40 -85.4(5) . . . . ?
C39 Fe3 C41 C40 37.5(5) . . . . ?
C38 Fe3 C41 C40 82.2(5) . . . . ?
C37 Fe3 C41 C40 -51.0(8) . . . . ?
C33 Fe3 C41 C40 154.0(14) . . . . ?
C40 C41 C42 C38 0.2(8) . . . . ?
Fe3 C41 C42 C38 59.2(5) . . . . ?
C40 C41 C42 Fe3 -59.0(5) . . . . ?
C39 C38 C42 C41 -0.3(8) . . . . ?
Fe3 C38 C42 C41 -59.9(5) . . . . ?
C39 C38 C42 Fe3 59.6(4) . . . . ?
C35 Fe3 C42 C41 -85.9(5) . . . . ?
C34 Fe3 C42 C41 -130.6(4) . . . . ?
C36 Fe3 C42 C41 -48.3(8) . . . . ?
C40 Fe3 C42 C41 37.2(4) . . . . ?
C39 Fe3 C42 C41 81.3(5) . . . . ?
C38 Fe3 C42 C41 120.3(7) . . . . ?
C37 Fe3 C42 C41 151.7(15) . . . . ?
C33 Fe3 C42 C41 -172.5(4) . . . . ?
C35 Fe3 C42 C38 153.8(5) . . . . ?
C34 Fe3 C42 C38 109.1(5) . . . . ?
C36 Fe3 C42 C38 -168.5(5) . . . . ?
C40 Fe3 C42 C38 -83.1(5) . . . . ?
C39 Fe3 C42 C38 -39.0(5) . . . . ?
C41 Fe3 C42 C38 -120.3(7) . . . . ?
C37 Fe3 C42 C38 31.4(19) . . . . ?
C33 Fe3 C42 C38 67.2(6) . . . . ?
C45 N3 C43 O3 -3.7(6) . . . . ?
Au4 N3 C43 O3 165.3(3) . . . . ?
C45 N3 C43 C34 176.6(5) . . . . ?
Au4 N3 C43 C34 -14.3(9) . . . . ?
C44 O3 C43 N3 -10.7(6) . . . . ?
C44 O3 C43 C34 169.0(4) . . . . ?
C35 C34 C43 N3 171.1(5) . . . . ?
C33 C34 C43 N3 -10.1(9) . . . . ?
Fe3 C34 C43 N3 -103.6(6) . . . . ?
C35 C34 C43 O3 -8.6(7) . . . . ?
C33 C34 C43 O3 170.3(5) . . . . ?
Fe3 C34 C43 O3 76.8(5) . . . . ?
C43 O3 C44 C45 19.6(6) . . . . ?
C43 N3 C45 C46 -107.2(5) . . . . ?
Au4 N3 C45 C46 82.2(5) . . . . ?
C43 N3 C45 C44 15.7(6) . . . . ?
Au4 N3 C45 C44 -154.8(4) . . . . ?
O3 C44 C45 N3 -20.9(6) . . . . ?
O3 C44 C45 C46 100.8(5) . . . . ?
N3 C45 C46 C48 51.0(10) . . . . ?
C44 C45 C46 C48 -65.0(10) . . . . ?
N3 C45 C46 C48A -51.2(10) . . . . ?
C44 C45 C46 C48A -167.1(9) . . . . ?
N3 C45 C46 C47 -176.6(5) . . . . ?
C44 C45 C46 C47 67.5(7) . . . . ?
N3 Au4 C49 C53 -1(3) . . . . ?
Au3 Au4 C49 C53 -150.8(4) . . . . ?
Au2 Au4 C49 C53 -25.8(4) . . . . ?
N3 Au4 C49 C50 180(100) . . . . ?
Au3 Au4 C49 C50 29.6(5) . . . . ?
Au2 Au4 C49 C50 154.5(4) . . . . ?
N3 Au4 C49 Fe4 -89(3) . . . . ?
Au3 Au4 C49 Fe4 121.0(3) . . . . ?
Au2 Au4 C49 Fe4 -114.0(3) . . . . ?
C51 Fe4 C49 C53 79.6(3) . . . . ?
C57 Fe4 C49 C53 -48.0(9) . . . . ?
C56 Fe4 C49 C53 167.9(7) . . . . ?
C50 Fe4 C49 C53 117.6(4) . . . . ?
C54 Fe4 C49 C53 -118.6(3) . . . . ?
C58 Fe4 C49 C53 -77.4(4) . . . . ?
C55 Fe4 C49 C53 -160.6(4) . . . . ?
C52 Fe4 C49 C53 36.4(3) . . . . ?
C51 Fe4 C49 C50 -38.1(3) . . . . ?
C57 Fe4 C49 C50 -165.7(8) . . . . ?
C56 Fe4 C49 C50 50.2(8) . . . . ?
C54 Fe4 C49 C50 123.7(4) . . . . ?
C58 Fe4 C49 C50 164.9(3) . . . . ?
C55 Fe4 C49 C50 81.8(4) . . . . ?
C52 Fe4 C49 C50 -81.2(3) . . . . ?
C53 Fe4 C49 C50 -117.6(4) . . . . ?
C51 Fe4 C49 Au4 -162.6(4) . . . . ?
C57 Fe4 C49 Au4 69.8(9) . . . . ?
C56 Fe4 C49 Au4 -74.3(8) . . . . ?
C50 Fe4 C49 Au4 -124.6(4) . . . . ?
C54 Fe4 C49 Au4 -0.8(4) . . . . ?
C58 Fe4 C49 Au4 40.4(4) . . . . ?
C55 Fe4 C49 Au4 -42.8(4) . . . . ?
C52 Fe4 C49 Au4 154.3(4) . . . . ?
C53 Fe4 C49 Au4 117.8(4) . . . . ?
C53 C49 C50 C51 -0.5(5) . . . . ?
Au4 C49 C50 C51 179.2(4) . . . . ?
Fe4 C49 C50 C51 57.9(3) . . . . ?
C53 C49 C50 C59 -177.9(5) . . . . ?
Au4 C49 C50 C59 1.8(8) . . . . ?
Fe4 C49 C50 C59 -119.5(5) . . . . ?
C53 C49 C50 Fe4 -58.4(3) . . . . ?
Au4 C49 C50 Fe4 121.3(4) . . . . ?
C51 Fe4 C50 C49 120.2(4) . . . . ?
C57 Fe4 C50 C49 167.8(7) . . . . ?
C56 Fe4 C50 C49 -158.9(4) . . . . ?
C54 Fe4 C50 C49 -75.5(4) . . . . ?
C58 Fe4 C50 C49 -41.4(9) . . . . ?
C55 Fe4 C50 C49 -117.6(4) . . . . ?
C52 Fe4 C50 C49 82.1(3) . . . . ?
C53 Fe4 C50 C49 38.3(3) . . . . ?
C57 Fe4 C50 C51 47.7(8) . . . . ?
C56 Fe4 C50 C51 80.9(5) . . . . ?
C54 Fe4 C50 C51 164.4(4) . . . . ?
C58 Fe4 C50 C51 -161.5(7) . . . . ?
C55 Fe4 C50 C51 122.3(4) . . . . ?
C52 Fe4 C50 C51 -38.1(3) . . . . ?
C53 Fe4 C50 C51 -81.9(3) . . . . ?
C49 Fe4 C50 C51 -120.2(4) . . . . ?
C51 Fe4 C50 C59 -114.6(5) . . . . ?
C57 Fe4 C50 C59 -67.0(9) . . . . ?
C56 Fe4 C50 C59 -33.7(6) . . . . ?
C54 Fe4 C50 C59 49.7(5) . . . . ?
C58 Fe4 C50 C59 83.9(9) . . . . ?
C55 Fe4 C50 C59 7.6(5) . . . . ?
C52 Fe4 C50 C59 -152.7(5) . . . . ?
C53 Fe4 C50 C59 163.5(5) . . . . ?
C49 Fe4 C50 C59 125.2(5) . . . . ?
C49 C50 C51 C52 1.5(6) . . . . ?
C59 C50 C51 C52 179.1(5) . . . . ?
Fe4 C50 C51 C52 61.8(4) . . . . ?
C49 C50 C51 Fe4 -60.3(3) . . . . ?
C59 C50 C51 Fe4 117.3(5) . . . . ?
C57 Fe4 C51 C52 81.9(4) . . . . ?
C56 Fe4 C51 C52 124.1(4) . . . . ?
C50 Fe4 C51 C52 -117.4(4) . . . . ?
C54 Fe4 C51 C52 -164.8(9) . . . . ?
C58 Fe4 C51 C52 48.2(7) . . . . ?
C55 Fe4 C51 C52 163.9(4) . . . . ?
C53 Fe4 C51 C52 -37.4(3) . . . . ?
C49 Fe4 C51 C52 -80.5(3) . . . . ?
C57 Fe4 C51 C50 -160.7(4) . . . . ?
C56 Fe4 C51 C50 -118.5(4) . . . . ?
C54 Fe4 C51 C50 -47.4(10) . . . . ?
C58 Fe4 C51 C50 165.6(5) . . . . ?
C55 Fe4 C51 C50 -78.8(4) . . . . ?
C52 Fe4 C51 C50 117.4(4) . . . . ?
C53 Fe4 C51 C50 80.0(3) . . . . ?
C49 Fe4 C51 C50 36.9(3) . . . . ?
C50 C51 C52 C53 -1.8(6) . . . . ?
Fe4 C51 C52 C53 59.2(4) . . . . ?
C50 C51 C52 Fe4 -61.0(4) . . . . ?
C57 Fe4 C52 C51 -116.5(4) . . . . ?
C56 Fe4 C52 C51 -75.0(4) . . . . ?
C50 Fe4 C52 C51 39.7(3) . . . . ?
C54 Fe4 C52 C51 168.8(6) . . . . ?
C58 Fe4 C52 C51 -158.8(3) . . . . ?
C55 Fe4 C52 C51 -45.3(9) . . . . ?
C53 Fe4 C52 C51 119.8(4) . . . . ?
C49 Fe4 C52 C51 83.6(3) . . . . ?
C51 Fe4 C52 C53 -119.8(4) . . . . ?
C57 Fe4 C52 C53 123.7(3) . . . . ?
C56 Fe4 C52 C53 165.2(4) . . . . ?
C50 Fe4 C52 C53 -80.0(3) . . . . ?
C54 Fe4 C52 C53 49.0(7) . . . . ?
C58 Fe4 C52 C53 81.4(4) . . . . ?
C55 Fe4 C52 C53 -165.1(8) . . . . ?
C49 Fe4 C52 C53 -36.2(3) . . . . ?
C51 C52 C53 C49 1.6(6) . . . . ?
Fe4 C52 C53 C49 59.8(4) . . . . ?
C51 C52 C53 Fe4 -58.2(4) . . . . ?
C50 C49 C53 C52 -0.7(6) . . . . ?
Au4 C49 C53 C52 179.6(4) . . . . ?
Fe4 C49 C53 C52 -58.5(4) . . . . ?
C50 C49 C53 Fe4 57.9(3) . . . . ?
Au4 C49 C53 Fe4 -121.8(4) . . . . ?
C51 Fe4 C53 C52 37.2(3) . . . . ?
C57 Fe4 C53 C52 -75.9(4) . . . . ?
C56 Fe4 C53 C52 -42.8(10) . . . . ?
C50 Fe4 C53 C52 82.8(3) . . . . ?
C54 Fe4 C53 C52 -159.1(4) . . . . ?
C58 Fe4 C53 C52 -117.0(4) . . . . ?
C55 Fe4 C53 C52 167.8(6) . . . . ?
C49 Fe4 C53 C52 121.5(4) . . . . ?
C51 Fe4 C53 C49 -84.3(3) . . . . ?
C57 Fe4 C53 C49 162.6(3) . . . . ?
C56 Fe4 C53 C49 -164.2(8) . . . . ?
C50 Fe4 C53 C49 -38.7(3) . . . . ?
C54 Fe4 C53 C49 79.5(4) . . . . ?
C58 Fe4 C53 C49 121.6(3) . . . . ?
C55 Fe4 C53 C49 46.3(8) . . . . ?
C52 Fe4 C53 C49 -121.5(4) . . . . ?
C51 Fe4 C54 C58 -159.5(8) . . . . ?
C57 Fe4 C54 C58 -38.3(4) . . . . ?
C56 Fe4 C54 C58 -82.2(5) . . . . ?
C50 Fe4 C54 C58 163.5(4) . . . . ?
C55 Fe4 C54 C58 -118.7(7) . . . . ?
C52 Fe4 C54 C58 45.3(9) . . . . ?
C53 Fe4 C54 C58 80.5(5) . . . . ?
C49 Fe4 C54 C58 122.1(4) . . . . ?
C51 Fe4 C54 C55 -40.8(11) . . . . ?
C57 Fe4 C54 C55 80.4(5) . . . . ?
C56 Fe4 C54 C55 36.5(5) . . . . ?
C50 Fe4 C54 C55 -77.8(5) . . . . ?
C58 Fe4 C54 C55 118.7(7) . . . . ?
C52 Fe4 C54 C55 164.0(6) . . . . ?
C53 Fe4 C54 C55 -160.9(4) . . . . ?
C49 Fe4 C54 C55 -119.2(5) . . . . ?
C58 C54 C55 C56 0.6(8) . . . . ?
Fe4 C54 C55 C56 -59.3(5) . . . . ?
C58 C54 C55 Fe4 59.9(4) . . . . ?
C51 Fe4 C55 C56 -74.0(5) . . . . ?
C57 Fe4 C55 C56 38.3(5) . . . . ?
C50 Fe4 C55 C56 -117.9(5) . . . . ?
C54 Fe4 C55 C56 119.9(7) . . . . ?
C58 Fe4 C55 C56 82.1(5) . . . . ?
C52 Fe4 C55 C56 -39.7(11) . . . . ?
C53 Fe4 C55 C56 165.7(6) . . . . ?
C49 Fe4 C55 C56 -160.9(4) . . . . ?
C51 Fe4 C55 C54 166.1(4) . . . . ?
C57 Fe4 C55 C54 -81.6(5) . . . . ?
C56 Fe4 C55 C54 -119.9(7) . . . . ?
C50 Fe4 C55 C54 122.2(4) . . . . ?
C58 Fe4 C55 C54 -37.8(4) . . . . ?
C52 Fe4 C55 C54 -159.6(7) . . . . ?
C53 Fe4 C55 C54 45.8(9) . . . . ?
C49 Fe4 C55 C54 79.2(5) . . . . ?
C54 C55 C56 C57 -1.0(8) . . . . ?
Fe4 C55 C56 C57 -60.1(5) . . . . ?
C54 C55 C56 Fe4 59.2(5) . . . . ?
C51 Fe4 C56 C55 124.6(5) . . . . ?
C57 Fe4 C56 C55 -118.3(7) . . . . ?
C50 Fe4 C56 C55 80.6(5) . . . . ?
C54 Fe4 C56 C55 -37.5(5) . . . . ?
C58 Fe4 C56 C55 -81.2(5) . . . . ?
C52 Fe4 C56 C55 165.5(4) . . . . ?
C53 Fe4 C56 C55 -161.8(7) . . . . ?
C49 Fe4 C56 C55 44.4(9) . . . . ?
C51 Fe4 C56 C57 -117.1(5) . . . . ?
C50 Fe4 C56 C57 -161.0(4) . . . . ?
C54 Fe4 C56 C57 80.8(5) . . . . ?
C58 Fe4 C56 C57 37.2(5) . . . . ?
C55 Fe4 C56 C57 118.3(7) . . . . ?
C52 Fe4 C56 C57 -76.1(5) . . . . ?
C53 Fe4 C56 C57 -43.4(11) . . . . ?
C49 Fe4 C56 C57 162.8(6) . . . . ?
C55 C56 C57 C58 1.0(8) . . . . ?
Fe4 C56 C57 C58 -59.8(5) . . . . ?
C55 C56 C57 Fe4 60.8(5) . . . . ?
C51 Fe4 C57 C56 81.1(5) . . . . ?
C50 Fe4 C57 C56 45.9(10) . . . . ?
C54 Fe4 C57 C56 -81.5(5) . . . . ?
C58 Fe4 C57 C56 -119.8(7) . . . . ?
C55 Fe4 C57 C56 -37.4(5) . . . . ?
C52 Fe4 C57 C56 123.4(5) . . . . ?
C53 Fe4 C57 C56 165.0(5) . . . . ?
C49 Fe4 C57 C56 -158.9(7) . . . . ?
C51 Fe4 C57 C58 -159.1(4) . . . . ?
C56 Fe4 C57 C58 119.8(7) . . . . ?
C50 Fe4 C57 C58 165.7(6) . . . . ?
C54 Fe4 C57 C58 38.3(4) . . . . ?
C55 Fe4 C57 C58 82.5(5) . . . . ?
C52 Fe4 C57 C58 -116.7(4) . . . . ?
C53 Fe4 C57 C58 -75.2(5) . . . . ?
C49 Fe4 C57 C58 -39.1(10) . . . . ?
C56 C57 C58 C54 -0.7(7) . . . . ?
Fe4 C57 C58 C54 -60.1(4) . . . . ?
C56 C57 C58 Fe4 59.5(5) . . . . ?
C55 C54 C58 C57 0.1(7) . . . . ?
Fe4 C54 C58 C57 59.8(4) . . . . ?
C55 C54 C58 Fe4 -59.8(5) . . . . ?
C51 Fe4 C58 C57 47.5(8) . . . . ?
C56 Fe4 C58 C57 -37.3(5) . . . . ?
C50 Fe4 C58 C57 -163.2(7) . . . . ?
C54 Fe4 C58 C57 -117.8(6) . . . . ?
C55 Fe4 C58 C57 -79.8(5) . . . . ?
C52 Fe4 C58 C57 81.7(5) . . . . ?
C53 Fe4 C58 C57 124.2(4) . . . . ?
C49 Fe4 C58 C57 165.6(4) . . . . ?
C51 Fe4 C58 C54 165.4(6) . . . . ?
C57 Fe4 C58 C54 117.8(6) . . . . ?
C56 Fe4 C58 C54 80.6(5) . . . . ?
C50 Fe4 C58 C54 -45.3(9) . . . . ?
C55 Fe4 C58 C54 38.0(5) . . . . ?
C52 Fe4 C58 C54 -160.5(4) . . . . ?
C53 Fe4 C58 C54 -118.0(4) . . . . ?
C49 Fe4 C58 C54 -76.6(5) . . . . ?
C61 N4 C59 O4 -3.4(6) . . . . ?
Au3 N4 C59 O4 175.9(3) . . . . ?
C61 N4 C59 C50 179.5(5) . . . . ?
Au3 N4 C59 C50 -1.3(8) . . . . ?
C60 O4 C59 N4 2.5(6) . . . . ?
C60 O4 C59 C50 179.9(4) . . . . ?
C49 C50 C59 N4 -28.9(9) . . . . ?
C51 C50 C59 N4 154.0(5) . . . . ?
Fe4 C50 C59 N4 -122.4(5) . . . . ?
C49 C50 C59 O4 154.0(5) . . . . ?
C51 C50 C59 O4 -23.1(7) . . . . ?
Fe4 C50 C59 O4 60.4(6) . . . . ?
C59 O4 C60 C61 -0.5(5) . . . . ?
C59 N4 C61 C62 -122.9(5) . . . . ?
Au3 N4 C61 C62 57.7(5) . . . . ?
C59 N4 C61 C60 2.7(5) . . . . ?
Au3 N4 C61 C60 -176.7(3) . . . . ?
O4 C60 C61 N4 -1.2(5) . . . . ?
O4 C60 C61 C62 121.9(5) . . . . ?
N4 C61 C62 C64 -179.7(4) . . . . ?
C60 C61 C62 C64 62.4(6) . . . . ?
N4 C61 C62 C63 55.5(6) . . . . ?
C60 C61 C62 C63 -62.4(6) . . . . ?
Cl2Z C1Z Cl1Z C1Z -116(3) . . . 8_667 ?
Cl2W C1W Cl1W Cl1W 110(2) . . . 7_557 ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        28.36
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.223
_refine_diff_density_min         -1.735
_refine_diff_density_rms         0.129
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2394lm
_database_code_depnum_ccdc_archive 'CCDC 1588453'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'iPrFOTMSAu(I)' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C38 H52 Au2 Fe2 N2 O2 Si2, 2(C6 H6)'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C50 H64 Au2 Fe2 N2 O2 Si2'
_chemical_formula_weight         1286.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 2'
_symmetry_space_group_name_Hall  'C 2y'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'

_cell_length_a                   35.198(2)
_cell_length_b                   10.8799(7)
_cell_length_c                   6.5582(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 100.146(3)
_cell_angle_gamma                90.00
_cell_volume                     2472.2(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    5711
_cell_measurement_theta_min      1.96
_cell_measurement_theta_max      28.41

_exptl_crystal_description       prism
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.729
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1264
_exptl_absorpt_coefficient_mu    6.579
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.3149
_exptl_absorpt_correction_T_max  0.6390
_exptl_absorpt_process_details   'SADABS (Bruker, 2008'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            26279
_diffrn_reflns_av_R_equivalents  0.0330
_diffrn_reflns_av_sigmaI/netI    0.0431
_diffrn_reflns_limit_h_min       -46
_diffrn_reflns_limit_h_max       46
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_theta_min         1.96
_diffrn_reflns_theta_max         28.41
_reflns_number_total             6103
_reflns_number_gt                5711
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0290P)²+0.3100P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.012(6)
_refine_ls_number_reflns         6103
_refine_ls_number_parameters     276
_refine_ls_number_restraints     7
_refine_ls_R_factor_all          0.0293
_refine_ls_R_factor_gt           0.0261
_refine_ls_wR_factor_ref         0.0582
_refine_ls_wR_factor_gt          0.0575
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.999808(4) 0.02738(2) 0.71661(2) 0.01667(5) Uani 1 1 d . . .
Fe1 Fe 0.914556(19) 0.23556(6) 0.55103(10) 0.01883(14) Uani 1 1 d . . .
Si1 Si 0.82543(4) 0.08149(14) 0.4311(2) 0.0243(3) Uani 1 1 d . . .
C1 C 0.94498(12) 0.0803(4) 0.6819(7) 0.0181(9) Uani 1 1 d . . .
O1 O 0.88324(10) -0.0849(3) 0.2539(5) 0.0274(8) Uani 1 1 d . . .
N1 N 0.94440(11) -0.0410(3) 0.2369(6) 0.0200(8) Uani 1 1 d . . .
C2 C 0.91310(13) 0.0493(4) 0.5177(7) 0.0192(11) Uani 1 1 d . . .
C3 C 0.87635(13) 0.0942(4) 0.5665(7) 0.0216(9) Uani 1 1 d . . .
C4 C 0.88692(14) 0.1545(4) 0.7622(8) 0.0244(10) Uani 1 1 d . . .
H4 H 0.8695 0.1945 0.8356 0.029 Uiso 1 1 calc R . .
C5 C 0.92733(14) 0.1453(4) 0.8300(7) 0.0230(10) Uani 1 1 d . . .
H5 H 0.9409 0.1779 0.9566 0.028 Uiso 1 1 calc R . .
C6 C 0.94950(17) 0.3321(5) 0.3898(11) 0.0272(14) Uani 1 1 d . . .
H6 H 0.9722 0.3019 0.3474 0.033 Uiso 1 1 calc R . .
C7 C 0.91161(15) 0.3269(4) 0.2742(8) 0.0289(11) Uani 1 1 d . . .
H7 H 0.9043 0.2921 0.1401 0.035 Uiso 1 1 calc R . .
C8 C 0.88654(15) 0.3825(4) 0.3932(8) 0.0282(11) Uani 1 1 d . . .
H8 H 0.8594 0.3920 0.3522 0.034 Uiso 1 1 calc R . .
C9 C 0.90838(15) 0.4213(4) 0.5820(8) 0.0304(12) Uani 1 1 d . . .
H9 H 0.8987 0.4611 0.6912 0.036 Uiso 1 1 calc R . .
C10 C 0.94733(15) 0.3909(4) 0.5809(9) 0.0303(11) Uani 1 1 d . . .
H10 H 0.9685 0.4069 0.6893 0.036 Uiso 1 1 calc R . .
C11 C 0.79715(15) 0.2019(5) 0.5435(9) 0.0336(12) Uani 1 1 d . . .
H11A H 0.7980 0.1852 0.6911 0.050 Uiso 1 1 calc R . .
H11B H 0.7703 0.2006 0.4712 0.050 Uiso 1 1 calc R . .
H11C H 0.8084 0.2829 0.5272 0.050 Uiso 1 1 calc R . .
C12 C 0.80649(17) -0.0726(5) 0.4908(9) 0.0355(13) Uani 1 1 d . . .
H12A H 0.8222 -0.1372 0.4431 0.053 Uiso 1 1 calc R . .
H12B H 0.7797 -0.0810 0.4200 0.053 Uiso 1 1 calc R . .
H12C H 0.8076 -0.0803 0.6407 0.053 Uiso 1 1 calc R . .
C13 C 0.81768(15) 0.1111(5) 0.1472(8) 0.0333(12) Uani 1 1 d . . .
H13A H 0.8275 0.1929 0.1218 0.050 Uiso 1 1 calc R . .
H13B H 0.7900 0.1068 0.0903 0.050 Uiso 1 1 calc R . .
H13C H 0.8315 0.0490 0.0801 0.050 Uiso 1 1 calc R . .
C14 C 0.91483(14) -0.0187(4) 0.3273(8) 0.0236(10) Uani 1 1 d U . .
C15 C 0.89016(15) -0.1449(5) 0.0659(8) 0.0295(11) Uani 1 1 d . . .
H15A H 0.8770 -0.1006 -0.0587 0.035 Uiso 1 1 calc R . .
H15B H 0.8810 -0.2310 0.0596 0.035 Uiso 1 1 calc R . .
C16 C 0.93364(14) -0.1392(4) 0.0827(7) 0.0217(10) Uani 1 1 d . . .
H16 H 0.9401 -0.1130 -0.0532 0.026 Uiso 1 1 calc R . .
C17 C 0.95563(16) -0.2582(4) 0.1551(8) 0.0278(11) Uani 1 1 d . . .
H17 H 0.9839 -0.2410 0.1698 0.033 Uiso 1 1 calc R . .
C18 C 0.94536(18) -0.3600(5) -0.0081(10) 0.0436(15) Uani 1 1 d . . .
H18A H 0.9621 -0.4312 0.0303 0.065 Uiso 1 1 calc R . .
H18B H 0.9490 -0.3293 -0.1437 0.065 Uiso 1 1 calc R . .
H18C H 0.9184 -0.3844 -0.0148 0.065 Uiso 1 1 calc R . .
C19 C 0.9474(3) -0.2994(6) 0.3676(13) 0.046(2) Uani 1 1 d . . .
H19A H 0.9524 -0.2310 0.4659 0.069 Uiso 1 1 calc R . .
H19B H 0.9642 -0.3688 0.4183 0.069 Uiso 1 1 calc R . .
H19C H 0.9203 -0.3245 0.3539 0.069 Uiso 1 1 calc R . .
C1X C 0.6995(2) 0.0142(9) 0.1755(11) 0.0564(18) Uani 1 1 d . . .
H1X H 0.6948 -0.0222 0.3004 0.068 Uiso 1 1 calc R . .
C2X C 0.6933(2) 0.1400(7) 0.1400(12) 0.059(2) Uani 1 1 d . . .
H2X H 0.6839 0.1892 0.2401 0.071 Uiso 1 1 calc R . .
C3X C 0.70071(19) 0.1927(6) -0.0407(13) 0.056(2) Uani 1 1 d . . .
H3X H 0.6968 0.2783 -0.0640 0.067 Uiso 1 1 calc R . .
C4X C 0.7137(2) 0.1214(8) -0.1858(13) 0.055(2) Uani 1 1 d . . .
H4X H 0.7189 0.1572 -0.3100 0.066 Uiso 1 1 calc R . .
C5X C 0.71921(19) -0.0044(6) -0.1501(13) 0.053(2) Uani 1 1 d . . .
H5X H 0.7278 -0.0550 -0.2510 0.064 Uiso 1 1 calc R . .
C6X C 0.7122(2) -0.0545(7) 0.0316(13) 0.060(2) Uani 1 1 d . . .
H6X H 0.7164 -0.1399 0.0560 0.073 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.988(4) . ?
Au1 N1 2.072(4) 2_756 ?
Au1 Au1 2.8436(3) 2_756 ?
Fe1 C4 2.029(5) . ?
Fe1 C10 2.036(5) . ?
Fe1 C2 2.037(4) . ?
Fe1 C9 2.047(5) . ?
Fe1 C6 2.048(6) . ?
Fe1 C5 2.055(5) . ?
Fe1 C7 2.056(5) . ?
Fe1 C3 2.057(5) . ?
Fe1 C8 2.059(5) . ?
Fe1 C1 2.101(4) . ?
Si1 C3 1.860(5) . ?
Si1 C13 1.862(5) . ?
Si1 C12 1.871(5) . ?
Si1 C11 1.873(6) . ?
C1 C5 1.429(6) . ?
C1 C2 1.451(6) . ?
O1 C14 1.341(5) . ?
O1 C15 1.452(6) . ?
N1 C14 1.308(6) . ?
N1 C16 1.474(5) . ?
N1 Au1 2.072(4) 2_756 ?
C2 C14 1.462(6) . ?
C2 C3 1.470(6) . ?
C3 C4 1.431(7) . ?
C4 C5 1.417(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.414(8) . ?
C6 C10 1.421(9) . ?
C6 H6 0.9500 . ?
C7 C8 1.413(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.403(7) . ?
C8 H8 0.9500 . ?
C9 C10 1.412(7) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C15 C16 1.516(7) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C17 1.540(7) . ?
C16 H16 1.0000 . ?
C17 C18 1.538(7) . ?
C17 C19 1.539(9) . ?
C17 H17 1.0000 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C1X C6X 1.341(11) . ?
C1X C2X 1.399(11) . ?
C1X H1X 0.9500 . ?
C2X C3X 1.383(10) . ?
C2X H2X 0.9500 . ?
C3X C4X 1.367(11) . ?
C3X H3X 0.9500 . ?
C4X C5X 1.397(11) . ?
C4X H4X 0.9500 . ?
C5X C6X 1.372(11) . ?
C5X H5X 0.9500 . ?
C6X H6X 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N1 175.30(17) . 2_756 ?
C1 Au1 Au1 93.49(13) . 2_756 ?
N1 Au1 Au1 88.62(11) 2_756 2_756 ?
C4 Fe1 C10 128.8(2) . . ?
C4 Fe1 C2 68.58(19) . . ?
C10 Fe1 C2 147.01(19) . . ?
C4 Fe1 C9 106.8(2) . . ?
C10 Fe1 C9 40.5(2) . . ?
C2 Fe1 C9 172.5(2) . . ?
C4 Fe1 C6 168.3(2) . . ?
C10 Fe1 C6 40.7(2) . . ?
C2 Fe1 C6 117.4(2) . . ?
C9 Fe1 C6 68.2(2) . . ?
C4 Fe1 C5 40.60(19) . . ?
C10 Fe1 C5 106.2(2) . . ?
C2 Fe1 C5 67.53(18) . . ?
C9 Fe1 C5 113.2(2) . . ?
C6 Fe1 C5 130.4(2) . . ?
C4 Fe1 C7 149.0(2) . . ?
C10 Fe1 C7 67.9(2) . . ?
C2 Fe1 C7 112.9(2) . . ?
C9 Fe1 C7 67.7(2) . . ?
C6 Fe1 C7 40.3(2) . . ?
C5 Fe1 C7 170.4(2) . . ?
C4 Fe1 C3 40.98(19) . . ?
C10 Fe1 C3 168.5(2) . . ?
C2 Fe1 C3 42.07(18) . . ?
C9 Fe1 C3 130.7(2) . . ?
C6 Fe1 C3 150.0(2) . . ?
C5 Fe1 C3 68.98(19) . . ?
C7 Fe1 C3 118.2(2) . . ?
C4 Fe1 C8 115.8(2) . . ?
C10 Fe1 C8 67.5(2) . . ?
C2 Fe1 C8 135.84(19) . . ?
C9 Fe1 C8 40.0(2) . . ?
C6 Fe1 C8 67.7(2) . . ?
C5 Fe1 C8 146.0(2) . . ?
C7 Fe1 C8 40.17(19) . . ?
C3 Fe1 C8 110.2(2) . . ?
C4 Fe1 C1 69.07(18) . . ?
C10 Fe1 C1 112.87(18) . . ?
C2 Fe1 C1 41.02(17) . . ?
C9 Fe1 C1 143.99(19) . . ?
C6 Fe1 C1 108.3(2) . . ?
C5 Fe1 C1 40.21(17) . . ?
C7 Fe1 C1 133.78(19) . . ?
C3 Fe1 C1 70.69(18) . . ?
C8 Fe1 C1 173.8(2) . . ?
C3 Si1 C13 115.1(2) . . ?
C3 Si1 C12 108.4(2) . . ?
C13 Si1 C12 111.7(3) . . ?
C3 Si1 C11 107.1(2) . . ?
C13 Si1 C11 106.2(2) . . ?
C12 Si1 C11 108.1(3) . . ?
C5 C1 C2 104.3(4) . . ?
C5 C1 Au1 126.5(3) . . ?
C2 C1 Au1 128.8(3) . . ?
C5 C1 Fe1 68.2(2) . . ?
C2 C1 Fe1 67.1(2) . . ?
Au1 C1 Fe1 134.0(2) . . ?
C14 O1 C15 107.1(4) . . ?
C14 N1 C16 108.5(4) . . ?
C14 N1 Au1 132.5(3) . 2_756 ?
C16 N1 Au1 118.9(3) . 2_756 ?
C1 C2 C14 127.4(4) . . ?
C1 C2 C3 110.9(4) . . ?
C14 C2 C3 121.6(4) . . ?
C1 C2 Fe1 71.8(2) . . ?
C14 C2 Fe1 126.2(3) . . ?
C3 C2 Fe1 69.7(3) . . ?
C4 C3 C2 104.3(4) . . ?
C4 C3 Si1 122.6(4) . . ?
C2 C3 Si1 133.0(4) . . ?
C4 C3 Fe1 68.5(3) . . ?
C2 C3 Fe1 68.2(2) . . ?
Si1 C3 Fe1 128.0(3) . . ?
C5 C4 C3 109.7(4) . . ?
C5 C4 Fe1 70.7(3) . . ?
C3 C4 Fe1 70.6(3) . . ?
C5 C4 H4 125.1 . . ?
C3 C4 H4 125.1 . . ?
Fe1 C4 H4 125.2 . . ?
C4 C5 C1 110.7(4) . . ?
C4 C5 Fe1 68.7(3) . . ?
C1 C5 Fe1 71.6(3) . . ?
C4 C5 H5 124.6 . . ?
C1 C5 H5 124.6 . . ?
Fe1 C5 H5 126.6 . . ?
C7 C6 C10 107.4(5) . . ?
C7 C6 Fe1 70.2(3) . . ?
C10 C6 Fe1 69.2(3) . . ?
C7 C6 H6 126.3 . . ?
C10 C6 H6 126.3 . . ?
Fe1 C6 H6 125.9 . . ?
C6 C7 C8 108.0(5) . . ?
C6 C7 Fe1 69.5(3) . . ?
C8 C7 Fe1 70.0(3) . . ?
C6 C7 H7 126.0 . . ?
C8 C7 H7 126.0 . . ?
Fe1 C7 H7 126.0 . . ?
C9 C8 C7 108.6(5) . . ?
C9 C8 Fe1 69.6(3) . . ?
C7 C8 Fe1 69.8(3) . . ?
C9 C8 H8 125.7 . . ?
C7 C8 H8 125.7 . . ?
Fe1 C8 H8 126.5 . . ?
C8 C9 C10 107.8(5) . . ?
C8 C9 Fe1 70.5(3) . . ?
C10 C9 Fe1 69.4(3) . . ?
C8 C9 H9 126.1 . . ?
C10 C9 H9 126.1 . . ?
Fe1 C9 H9 125.7 . . ?
C9 C10 C6 108.3(5) . . ?
C9 C10 Fe1 70.2(3) . . ?
C6 C10 Fe1 70.1(3) . . ?
C9 C10 H10 125.9 . . ?
C6 C10 H10 125.9 . . ?
Fe1 C10 H10 125.4 . . ?
Si1 C11 H11A 109.5 . . ?
Si1 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si1 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si1 C12 H12A 109.5 . . ?
Si1 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si1 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si1 C13 H13A 109.5 . . ?
Si1 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si1 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N1 C14 O1 114.4(4) . . ?
N1 C14 C2 129.6(4) . . ?
O1 C14 C2 115.0(4) . . ?
O1 C15 C16 103.8(4) . . ?
O1 C15 H15A 111.0 . . ?
C16 C15 H15A 111.0 . . ?
O1 C15 H15B 111.0 . . ?
C16 C15 H15B 111.0 . . ?
H15A C15 H15B 109.0 . . ?
N1 C16 C15 102.3(4) . . ?
N1 C16 C17 110.1(4) . . ?
C15 C16 C17 115.8(4) . . ?
N1 C16 H16 109.5 . . ?
C15 C16 H16 109.5 . . ?
C17 C16 H16 109.5 . . ?
C18 C17 C16 110.3(4) . . ?
C18 C17 C19 111.2(5) . . ?
C16 C17 C19 111.0(5) . . ?
C18 C17 H17 108.1 . . ?
C16 C17 H17 108.1 . . ?
C19 C17 H17 108.1 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C6X C1X C2X 119.3(7) . . ?
C6X C1X H1X 120.3 . . ?
C2X C1X H1X 120.3 . . ?
C3X C2X C1X 120.0(7) . . ?
C3X C2X H2X 120.0 . . ?
C1X C2X H2X 120.0 . . ?
C4X C3X C2X 119.9(7) . . ?
C4X C3X H3X 120.1 . . ?
C2X C3X H3X 120.1 . . ?
C3X C4X C5X 119.5(8) . . ?
C3X C4X H4X 120.2 . . ?
C5X C4X H4X 120.2 . . ?
C6X C5X C4X 119.6(7) . . ?
C6X C5X H5X 120.2 . . ?
C4X C5X H5X 120.2 . . ?
C1X C6X C5X 121.6(7) . . ?
C1X C6X H6X 119.2 . . ?
C5X C6X H6X 119.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Au1 C1 C5 89(2) 2_756 . . . ?
Au1 Au1 C1 C5 -154.1(4) 2_756 . . . ?
N1 Au1 C1 C2 -82(2) 2_756 . . . ?
Au1 Au1 C1 C2 34.7(4) 2_756 . . . ?
N1 Au1 C1 Fe1 -176.6(18) 2_756 . . . ?
Au1 Au1 C1 Fe1 -60.1(3) 2_756 . . . ?
C4 Fe1 C1 C5 -36.2(3) . . . . ?
C10 Fe1 C1 C5 88.3(3) . . . . ?
C2 Fe1 C1 C5 -117.2(4) . . . . ?
C9 Fe1 C1 C5 53.8(4) . . . . ?
C6 Fe1 C1 C5 131.7(3) . . . . ?
C7 Fe1 C1 C5 169.0(3) . . . . ?
C3 Fe1 C1 C5 -80.0(3) . . . . ?
C8 Fe1 C1 C5 -180(100) . . . . ?
C4 Fe1 C1 C2 81.0(3) . . . . ?
C10 Fe1 C1 C2 -154.4(3) . . . . ?
C9 Fe1 C1 C2 171.1(3) . . . . ?
C6 Fe1 C1 C2 -111.0(3) . . . . ?
C5 Fe1 C1 C2 117.2(4) . . . . ?
C7 Fe1 C1 C2 -73.7(4) . . . . ?
C3 Fe1 C1 C2 37.3(3) . . . . ?
C8 Fe1 C1 C2 -62.4(19) . . . . ?
C4 Fe1 C1 Au1 -156.5(4) . . . . ?
C10 Fe1 C1 Au1 -31.9(4) . . . . ?
C2 Fe1 C1 Au1 122.5(4) . . . . ?
C9 Fe1 C1 Au1 -66.4(5) . . . . ?
C6 Fe1 C1 Au1 11.5(4) . . . . ?
C5 Fe1 C1 Au1 -120.3(4) . . . . ?
C7 Fe1 C1 Au1 48.8(4) . . . . ?
C3 Fe1 C1 Au1 159.8(4) . . . . ?
C8 Fe1 C1 Au1 60.1(19) . . . . ?
C5 C1 C2 C14 -179.4(4) . . . . ?
Au1 C1 C2 C14 -6.7(7) . . . . ?
Fe1 C1 C2 C14 122.2(5) . . . . ?
C5 C1 C2 C3 -0.5(5) . . . . ?
Au1 C1 C2 C3 172.2(3) . . . . ?
Fe1 C1 C2 C3 -58.9(3) . . . . ?
C5 C1 C2 Fe1 58.4(3) . . . . ?
Au1 C1 C2 Fe1 -128.9(4) . . . . ?
C4 Fe1 C2 C1 -82.3(3) . . . . ?
C10 Fe1 C2 C1 46.9(5) . . . . ?
C9 Fe1 C2 C1 -135.5(15) . . . . ?
C6 Fe1 C2 C1 86.7(3) . . . . ?
C5 Fe1 C2 C1 -38.4(3) . . . . ?
C7 Fe1 C2 C1 131.2(3) . . . . ?
C3 Fe1 C2 C1 -121.5(4) . . . . ?
C8 Fe1 C2 C1 172.1(3) . . . . ?
C4 Fe1 C2 C14 154.1(4) . . . . ?
C10 Fe1 C2 C14 -76.7(5) . . . . ?
C9 Fe1 C2 C14 101.0(16) . . . . ?
C6 Fe1 C2 C14 -36.9(5) . . . . ?
C5 Fe1 C2 C14 -162.0(4) . . . . ?
C7 Fe1 C2 C14 7.6(5) . . . . ?
C3 Fe1 C2 C14 115.0(5) . . . . ?
C8 Fe1 C2 C14 48.6(5) . . . . ?
C1 Fe1 C2 C14 -123.6(5) . . . . ?
C4 Fe1 C2 C3 39.1(3) . . . . ?
C10 Fe1 C2 C3 168.3(4) . . . . ?
C9 Fe1 C2 C3 -14.0(17) . . . . ?
C6 Fe1 C2 C3 -151.8(3) . . . . ?
C5 Fe1 C2 C3 83.1(3) . . . . ?
C7 Fe1 C2 C3 -107.3(3) . . . . ?
C8 Fe1 C2 C3 -66.4(4) . . . . ?
C1 Fe1 C2 C3 121.5(4) . . . . ?
C1 C2 C3 C4 0.9(5) . . . . ?
C14 C2 C3 C4 179.8(4) . . . . ?
Fe1 C2 C3 C4 -59.3(3) . . . . ?
C1 C2 C3 Si1 -177.5(4) . . . . ?
C14 C2 C3 Si1 1.4(7) . . . . ?
Fe1 C2 C3 Si1 122.3(4) . . . . ?
C1 C2 C3 Fe1 60.2(3) . . . . ?
C14 C2 C3 Fe1 -120.8(4) . . . . ?
C13 Si1 C3 C4 137.1(4) . . . . ?
C12 Si1 C3 C4 -97.1(4) . . . . ?
C11 Si1 C3 C4 19.3(5) . . . . ?
C13 Si1 C3 C2 -44.8(6) . . . . ?
C12 Si1 C3 C2 81.1(5) . . . . ?
C11 Si1 C3 C2 -162.5(5) . . . . ?
C13 Si1 C3 Fe1 50.2(4) . . . . ?
C12 Si1 C3 Fe1 176.0(3) . . . . ?
C11 Si1 C3 Fe1 -67.6(4) . . . . ?
C10 Fe1 C3 C4 -30.1(11) . . . . ?
C2 Fe1 C3 C4 116.4(4) . . . . ?
C9 Fe1 C3 C4 -66.0(4) . . . . ?
C6 Fe1 C3 C4 173.3(4) . . . . ?
C5 Fe1 C3 C4 37.1(3) . . . . ?
C7 Fe1 C3 C4 -149.9(3) . . . . ?
C8 Fe1 C3 C4 -106.5(3) . . . . ?
C1 Fe1 C3 C4 80.0(3) . . . . ?
C4 Fe1 C3 C2 -116.4(4) . . . . ?
C10 Fe1 C3 C2 -146.5(9) . . . . ?
C9 Fe1 C3 C2 177.6(3) . . . . ?
C6 Fe1 C3 C2 57.0(5) . . . . ?
C5 Fe1 C3 C2 -79.3(3) . . . . ?
C7 Fe1 C3 C2 93.7(3) . . . . ?
C8 Fe1 C3 C2 137.1(3) . . . . ?
C1 Fe1 C3 C2 -36.4(3) . . . . ?
C4 Fe1 C3 Si1 115.3(4) . . . . ?
C10 Fe1 C3 Si1 85.1(10) . . . . ?
C2 Fe1 C3 Si1 -128.4(4) . . . . ?
C9 Fe1 C3 Si1 49.2(4) . . . . ?
C6 Fe1 C3 Si1 -71.4(5) . . . . ?
C5 Fe1 C3 Si1 152.3(4) . . . . ?
C7 Fe1 C3 Si1 -34.7(4) . . . . ?
C8 Fe1 C3 Si1 8.7(4) . . . . ?
C1 Fe1 C3 Si1 -164.8(4) . . . . ?
C2 C3 C4 C5 -0.9(5) . . . . ?
Si1 C3 C4 C5 177.7(3) . . . . ?
Fe1 C3 C4 C5 -60.1(3) . . . . ?
C2 C3 C4 Fe1 59.2(3) . . . . ?
Si1 C3 C4 Fe1 -122.2(4) . . . . ?
C10 Fe1 C4 C5 -67.2(3) . . . . ?
C2 Fe1 C4 C5 80.0(3) . . . . ?
C9 Fe1 C4 C5 -106.2(3) . . . . ?
C6 Fe1 C4 C5 -43.2(12) . . . . ?
C7 Fe1 C4 C5 179.2(4) . . . . ?
C3 Fe1 C4 C5 120.2(4) . . . . ?
C8 Fe1 C4 C5 -148.2(3) . . . . ?
C1 Fe1 C4 C5 35.9(3) . . . . ?
C10 Fe1 C4 C3 172.6(3) . . . . ?
C2 Fe1 C4 C3 -40.2(3) . . . . ?
C9 Fe1 C4 C3 133.6(3) . . . . ?
C6 Fe1 C4 C3 -163.3(10) . . . . ?
C5 Fe1 C4 C3 -120.2(4) . . . . ?
C7 Fe1 C4 C3 59.0(5) . . . . ?
C8 Fe1 C4 C3 91.6(3) . . . . ?
C1 Fe1 C4 C3 -84.3(3) . . . . ?
C3 C4 C5 C1 0.6(6) . . . . ?
Fe1 C4 C5 C1 -59.4(3) . . . . ?
C3 C4 C5 Fe1 60.0(3) . . . . ?
C2 C1 C5 C4 -0.1(5) . . . . ?
Au1 C1 C5 C4 -173.0(3) . . . . ?
Fe1 C1 C5 C4 57.7(3) . . . . ?
C2 C1 C5 Fe1 -57.7(3) . . . . ?
Au1 C1 C5 Fe1 129.4(4) . . . . ?
C10 Fe1 C5 C4 131.6(3) . . . . ?
C2 Fe1 C5 C4 -82.8(3) . . . . ?
C9 Fe1 C5 C4 89.1(3) . . . . ?
C6 Fe1 C5 C4 169.5(3) . . . . ?
C7 Fe1 C5 C4 -177.5(11) . . . . ?
C3 Fe1 C5 C4 -37.4(3) . . . . ?
C8 Fe1 C5 C4 57.9(5) . . . . ?
C1 Fe1 C5 C4 -122.0(4) . . . . ?
C4 Fe1 C5 C1 122.0(4) . . . . ?
C10 Fe1 C5 C1 -106.4(3) . . . . ?
C2 Fe1 C5 C1 39.2(3) . . . . ?
C9 Fe1 C5 C1 -148.9(3) . . . . ?
C6 Fe1 C5 C1 -68.5(4) . . . . ?
C7 Fe1 C5 C1 -55.5(13) . . . . ?
C3 Fe1 C5 C1 84.6(3) . . . . ?
C8 Fe1 C5 C1 179.9(3) . . . . ?
C4 Fe1 C6 C7 -147.6(10) . . . . ?
C10 Fe1 C6 C7 -118.5(5) . . . . ?
C2 Fe1 C6 C7 93.8(3) . . . . ?
C9 Fe1 C6 C7 -80.8(3) . . . . ?
C5 Fe1 C6 C7 176.7(3) . . . . ?
C3 Fe1 C6 C7 54.5(6) . . . . ?
C8 Fe1 C6 C7 -37.5(3) . . . . ?
C1 Fe1 C6 C7 137.4(3) . . . . ?
C4 Fe1 C6 C10 -29.1(12) . . . . ?
C2 Fe1 C6 C10 -147.7(3) . . . . ?
C9 Fe1 C6 C10 37.7(3) . . . . ?
C5 Fe1 C6 C10 -64.8(4) . . . . ?
C7 Fe1 C6 C10 118.5(5) . . . . ?
C3 Fe1 C6 C10 173.0(4) . . . . ?
C8 Fe1 C6 C10 80.9(3) . . . . ?
C1 Fe1 C6 C10 -104.1(3) . . . . ?
C10 C6 C7 C8 0.3(6) . . . . ?
Fe1 C6 C7 C8 59.7(3) . . . . ?
C10 C6 C7 Fe1 -59.4(4) . . . . ?
C4 Fe1 C7 C6 167.9(4) . . . . ?
C10 Fe1 C7 C6 38.3(3) . . . . ?
C2 Fe1 C7 C6 -106.0(4) . . . . ?
C9 Fe1 C7 C6 82.1(4) . . . . ?
C5 Fe1 C7 C6 -15.3(14) . . . . ?
C3 Fe1 C7 C6 -152.5(3) . . . . ?
C8 Fe1 C7 C6 119.1(5) . . . . ?
C1 Fe1 C7 C6 -62.8(4) . . . . ?
C4 Fe1 C7 C8 48.8(5) . . . . ?
C10 Fe1 C7 C8 -80.8(3) . . . . ?
C2 Fe1 C7 C8 135.0(3) . . . . ?
C9 Fe1 C7 C8 -37.0(3) . . . . ?
C6 Fe1 C7 C8 -119.1(5) . . . . ?
C5 Fe1 C7 C8 -134.4(11) . . . . ?
C3 Fe1 C7 C8 88.4(3) . . . . ?
C1 Fe1 C7 C8 178.1(3) . . . . ?
C6 C7 C8 C9 -0.5(6) . . . . ?
Fe1 C7 C8 C9 58.9(3) . . . . ?
C6 C7 C8 Fe1 -59.4(4) . . . . ?
C4 Fe1 C8 C9 85.6(4) . . . . ?
C10 Fe1 C8 C9 -38.0(3) . . . . ?
C2 Fe1 C8 C9 170.8(3) . . . . ?
C6 Fe1 C8 C9 -82.3(4) . . . . ?
C5 Fe1 C8 C9 47.8(5) . . . . ?
C7 Fe1 C8 C9 -119.9(5) . . . . ?
C3 Fe1 C8 C9 129.9(3) . . . . ?
C1 Fe1 C8 C9 -132.6(17) . . . . ?
C4 Fe1 C8 C7 -154.5(3) . . . . ?
C10 Fe1 C8 C7 81.9(3) . . . . ?
C2 Fe1 C8 C7 -69.3(4) . . . . ?
C9 Fe1 C8 C7 119.9(5) . . . . ?
C6 Fe1 C8 C7 37.7(3) . . . . ?
C5 Fe1 C8 C7 167.7(3) . . . . ?
C3 Fe1 C8 C7 -110.2(3) . . . . ?
C1 Fe1 C8 C7 -13(2) . . . . ?
C7 C8 C9 C10 0.5(6) . . . . ?
Fe1 C8 C9 C10 59.5(3) . . . . ?
C7 C8 C9 Fe1 -59.1(3) . . . . ?
C4 Fe1 C9 C8 -110.4(3) . . . . ?
C10 Fe1 C9 C8 118.7(5) . . . . ?
C2 Fe1 C9 C8 -59.3(17) . . . . ?
C6 Fe1 C9 C8 80.8(4) . . . . ?
C5 Fe1 C9 C8 -153.2(3) . . . . ?
C7 Fe1 C9 C8 37.2(3) . . . . ?
C3 Fe1 C9 C8 -71.6(4) . . . . ?
C1 Fe1 C9 C8 172.3(3) . . . . ?
C4 Fe1 C9 C10 130.9(3) . . . . ?
C2 Fe1 C9 C10 -178.0(14) . . . . ?
C6 Fe1 C9 C10 -37.9(3) . . . . ?
C5 Fe1 C9 C10 88.1(3) . . . . ?
C7 Fe1 C9 C10 -81.6(3) . . . . ?
C3 Fe1 C9 C10 169.6(3) . . . . ?
C8 Fe1 C9 C10 -118.7(5) . . . . ?
C1 Fe1 C9 C10 53.5(5) . . . . ?
C8 C9 C10 C6 -0.3(6) . . . . ?
Fe1 C9 C10 C6 60.0(4) . . . . ?
C8 C9 C10 Fe1 -60.3(3) . . . . ?
C7 C6 C10 C9 0.0(6) . . . . ?
Fe1 C6 C10 C9 -60.1(4) . . . . ?
C7 C6 C10 Fe1 60.0(4) . . . . ?
C4 Fe1 C10 C9 -68.2(4) . . . . ?
C2 Fe1 C10 C9 179.5(3) . . . . ?
C6 Fe1 C10 C9 119.0(5) . . . . ?
C5 Fe1 C10 C9 -106.9(3) . . . . ?
C7 Fe1 C10 C9 81.1(3) . . . . ?
C3 Fe1 C10 C9 -43.3(11) . . . . ?
C8 Fe1 C10 C9 37.6(3) . . . . ?
C1 Fe1 C10 C9 -149.1(3) . . . . ?
C4 Fe1 C10 C6 172.8(3) . . . . ?
C2 Fe1 C10 C6 60.5(5) . . . . ?
C9 Fe1 C10 C6 -119.0(5) . . . . ?
C5 Fe1 C10 C6 134.1(3) . . . . ?
C7 Fe1 C10 C6 -37.9(3) . . . . ?
C3 Fe1 C10 C6 -162.3(9) . . . . ?
C8 Fe1 C10 C6 -81.4(4) . . . . ?
C1 Fe1 C10 C6 91.9(4) . . . . ?
C16 N1 C14 O1 -2.3(6) . . . . ?
Au1 N1 C14 O1 -178.7(3) 2_756 . . . ?
C16 N1 C14 C2 165.2(5) . . . . ?
Au1 N1 C14 C2 -11.1(8) 2_756 . . . ?
C15 O1 C14 N1 -10.8(6) . . . . ?
C15 O1 C14 C2 179.7(4) . . . . ?
C1 C2 C14 N1 -18.3(8) . . . . ?
C3 C2 C14 N1 162.9(5) . . . . ?
Fe1 C2 C14 N1 76.0(7) . . . . ?
C1 C2 C14 O1 149.2(5) . . . . ?
C3 C2 C14 O1 -29.6(7) . . . . ?
Fe1 C2 C14 O1 -116.5(4) . . . . ?
C14 O1 C15 C16 18.6(5) . . . . ?
C14 N1 C16 C15 13.7(5) . . . . ?
Au1 N1 C16 C15 -169.4(3) 2_756 . . . ?
C14 N1 C16 C17 -110.0(5) . . . . ?
Au1 N1 C16 C17 67.0(4) 2_756 . . . ?
O1 C15 C16 N1 -19.0(5) . . . . ?
O1 C15 C16 C17 100.7(5) . . . . ?
N1 C16 C17 C18 -178.4(4) . . . . ?
C15 C16 C17 C18 66.2(6) . . . . ?
N1 C16 C17 C19 57.8(6) . . . . ?
C15 C16 C17 C19 -57.6(6) . . . . ?
C6X C1X C2X C3X -1.0(11) . . . . ?
C1X C2X C3X C4X 0.9(11) . . . . ?
C2X C3X C4X C5X 0.2(11) . . . . ?
C3X C4X C5X C6X -1.2(12) . . . . ?
C2X C1X C6X C5X 0.0(11) . . . . ?
C4X C5X C6X C1X 1.1(11) . . . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        28.41
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         3.685
_refine_diff_density_min         -0.938
_refine_diff_density_rms         0.134
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2408lm
_database_code_depnum_ccdc_archive 'CCDC 1588454'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'Me2FOAu(I)' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H32 Au2 Fe2 N2 O2'
_chemical_formula_sum            'C30 H32 Au2 Fe2 N2 O2'
_chemical_formula_weight         958.21

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.2325(8)
_cell_length_b                   16.4711(10)
_cell_length_c                   13.7540(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 102.392(4)
_cell_angle_gamma                90.00
_cell_volume                     2706.6(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    6514
_cell_measurement_theta_min      1.96
_cell_measurement_theta_max      30.54

_exptl_crystal_description       needle
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.09
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.351
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1808
_exptl_absorpt_coefficient_mu    11.889
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.0712
_exptl_absorpt_correction_T_max  0.4582
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            58541
_diffrn_reflns_av_R_equivalents  0.0461
_diffrn_reflns_av_sigmaI/netI    0.0313
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.96
_diffrn_reflns_theta_max         30.54
_reflns_number_total             8259
_reflns_number_gt                6514
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0461P)²+35.9815P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8259
_refine_ls_number_parameters     347
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0566
_refine_ls_R_factor_gt           0.0377
_refine_ls_wR_factor_ref         0.1039
_refine_ls_wR_factor_gt          0.0908
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.682352(19) 0.018127(15) 0.458223(18) 0.01579(6) Uani 1 1 d . . .
Au2 Au 0.727744(19) 0.182273(15) 0.414181(18) 0.01615(6) Uani 1 1 d . . .
Fe1 Fe 0.73355(8) 0.01897(6) 0.20052(7) 0.01911(19) Uani 1 1 d . . .
Fe2 Fe 0.54884(8) 0.30536(6) 0.52686(7) 0.01814(18) Uani 1 1 d . . .
C1 C 0.7536(6) -0.0213(4) 0.3492(5) 0.0193(12) Uani 1 1 d . . .
O1 O 1.0337(4) 0.0693(3) 0.3906(4) 0.0216(10) Uani 1 1 d . . .
N1 N 0.8894(5) 0.1466(4) 0.4085(4) 0.0184(11) Uani 1 1 d . . .
O2 O 0.5354(4) 0.1382(3) 0.6734(4) 0.0204(9) Uani 1 1 d . . .
N2 N 0.6207(5) 0.0611(4) 0.5771(4) 0.0185(11) Uani 1 1 d . . .
C2 C 0.8559(5) 0.0124(4) 0.3279(5) 0.0184(12) Uani 1 1 d . . .
C3 C 0.8862(5) -0.0350(4) 0.2472(5) 0.0169(12) Uani 1 1 d . . .
H3 H 0.9498 -0.0265 0.2192 0.020 Uiso 1 1 calc R . .
C4 C 0.8038(6) -0.0956(4) 0.2187(5) 0.0218(13) Uani 1 1 d . . .
H4 H 0.8014 -0.1348 0.1677 0.026 Uiso 1 1 calc R . .
C5 C 0.7237(6) -0.0869(4) 0.2815(5) 0.0216(13) Uani 1 1 d . . .
H5 H 0.6598 -0.1205 0.2780 0.026 Uiso 1 1 calc R . .
C6 C 0.6076(6) 0.1041(5) 0.1770(6) 0.0261(15) Uani 1 1 d . . .
H6 H 0.5661 0.1212 0.2243 0.031 Uiso 1 1 calc R . .
C7 C 0.7107(7) 0.1391(5) 0.1613(6) 0.0319(17) Uani 1 1 d . . .
H7 H 0.7493 0.1835 0.1972 0.038 Uiso 1 1 calc R . .
C8 C 0.7439(6) 0.0971(5) 0.0849(6) 0.0289(16) Uani 1 1 d . . .
H8 H 0.8079 0.1091 0.0587 0.035 Uiso 1 1 calc R . .
C9 C 0.6646(7) 0.0319(5) 0.0518(6) 0.0265(15) Uani 1 1 d . . .
H9 H 0.6682 -0.0078 0.0024 0.032 Uiso 1 1 calc R . .
C10 C 0.5806(6) 0.0396(5) 0.1086(5) 0.0258(15) Uani 1 1 d . . .
H10 H 0.5160 0.0063 0.1015 0.031 Uiso 1 1 calc R . .
C11 C 0.9224(5) 0.0803(4) 0.3762(5) 0.0189(12) Uani 1 1 d . . .
C12 C 0.9898(6) 0.1929(4) 0.4630(5) 0.0212(13) Uani 1 1 d . . .
C13 C 1.0862(6) 0.1438(5) 0.4351(6) 0.0244(14) Uani 1 1 d . . .
H13A H 1.1202 0.1742 0.3870 0.029 Uiso 1 1 calc R . .
H13B H 1.1449 0.1317 0.4949 0.029 Uiso 1 1 calc R . .
C14 C 0.9921(7) 0.1891(5) 0.5736(6) 0.0285(16) Uani 1 1 d . . .
H14A H 0.9259 0.2166 0.5872 0.043 Uiso 1 1 calc R . .
H14B H 1.0599 0.2159 0.6106 0.043 Uiso 1 1 calc R . .
H14C H 0.9919 0.1322 0.5945 0.043 Uiso 1 1 calc R . .
C15 C 0.9856(7) 0.2802(5) 0.4257(6) 0.0306(16) Uani 1 1 d . . .
H15A H 0.9210 0.3080 0.4421 0.046 Uiso 1 1 calc R . .
H15B H 0.9786 0.2803 0.3534 0.046 Uiso 1 1 calc R . .
H15C H 1.0545 0.3084 0.4577 0.046 Uiso 1 1 calc R . .
C16 C 0.5754(5) 0.2142(4) 0.4297(5) 0.0167(11) Uani 1 1 d . . .
C17 C 0.5196(5) 0.1850(4) 0.5068(5) 0.0176(12) Uani 1 1 d . . .
C18 C 0.4164(6) 0.2277(5) 0.5028(5) 0.0224(13) Uani 1 1 d . . .
H18 H 0.3658 0.2205 0.5458 0.027 Uiso 1 1 calc R . .
C19 C 0.4048(6) 0.2830(5) 0.4220(5) 0.0232(14) Uani 1 1 d . . .
H19 H 0.3437 0.3191 0.4006 0.028 Uiso 1 1 calc R . .
C20 C 0.5010(6) 0.2754(4) 0.3780(5) 0.0195(12) Uani 1 1 d . . .
H20 H 0.5135 0.3062 0.3230 0.023 Uiso 1 1 calc R . .
C21 C 0.7064(7) 0.3486(5) 0.5869(6) 0.0304(16) Uani 1 1 d . . .
H21 H 0.7751 0.3308 0.5724 0.036 Uiso 1 1 calc R . .
C22 C 0.6543(7) 0.3169(5) 0.6626(6) 0.0305(16) Uani 1 1 d . . .
H22 H 0.6823 0.2739 0.7070 0.037 Uiso 1 1 calc R . .
C23 C 0.5535(7) 0.3607(5) 0.6600(6) 0.0282(15) Uani 1 1 d . . .
H23 H 0.5024 0.3520 0.7021 0.034 Uiso 1 1 calc R . .
C24 C 0.5428(7) 0.4192(5) 0.5840(6) 0.0285(16) Uani 1 1 d . . .
H24 H 0.4835 0.4573 0.5666 0.034 Uiso 1 1 calc R . .
C25 C 0.6365(7) 0.4117(5) 0.5374(6) 0.0270(15) Uani 1 1 d . . .
H25 H 0.6496 0.4432 0.4831 0.032 Uiso 1 1 calc R . .
C26 C 0.5617(5) 0.1253(4) 0.5831(5) 0.0169(12) Uani 1 1 d . . .
C27 C 0.6550(6) 0.0249(4) 0.6797(5) 0.0200(13) Uani 1 1 d . . .
C28 C 0.5721(6) 0.0663(5) 0.7326(5) 0.0234(14) Uani 1 1 d . . .
H28A H 0.5080 0.0301 0.7346 0.028 Uiso 1 1 calc R . .
H28B H 0.6089 0.0813 0.8015 0.028 Uiso 1 1 calc R . .
C29 C 0.7770(6) 0.0501(5) 0.7226(6) 0.0270(15) Uani 1 1 d . . .
H29A H 0.8260 0.0252 0.6832 0.040 Uiso 1 1 calc R . .
H29B H 0.7992 0.0317 0.7918 0.040 Uiso 1 1 calc R . .
H29C H 0.7835 0.1093 0.7201 0.040 Uiso 1 1 calc R . .
C30 C 0.6404(7) -0.0661(5) 0.6763(6) 0.0257(15) Uani 1 1 d . . .
H30A H 0.5628 -0.0794 0.6450 0.039 Uiso 1 1 calc R . .
H30B H 0.6583 -0.0879 0.7442 0.039 Uiso 1 1 calc R . .
H30C H 0.6907 -0.0901 0.6375 0.039 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.998(7) . ?
Au1 N2 2.067(6) . ?
Au1 Au2 2.8512(4) . ?
Au2 C16 1.991(6) . ?
Au2 N1 2.080(5) . ?
Fe1 C3 2.043(6) . ?
Fe1 C2 2.048(7) . ?
Fe1 C10 2.049(7) . ?
Fe1 C9 2.049(7) . ?
Fe1 C7 2.054(8) . ?
Fe1 C6 2.057(7) . ?
Fe1 C4 2.066(7) . ?
Fe1 C8 2.071(8) . ?
Fe1 C5 2.087(8) . ?
Fe1 C1 2.113(7) . ?
Fe2 C17 2.023(7) . ?
Fe2 C22 2.037(8) . ?
Fe2 C23 2.035(7) . ?
Fe2 C18 2.035(7) . ?
Fe2 C24 2.041(8) . ?
Fe2 C25 2.043(8) . ?
Fe2 C19 2.056(7) . ?
Fe2 C21 2.055(8) . ?
Fe2 C20 2.065(7) . ?
Fe2 C16 2.082(6) . ?
C1 C5 1.421(10) . ?
C1 C2 1.455(9) . ?
O1 C11 1.345(8) . ?
O1 C13 1.457(9) . ?
N1 C11 1.278(9) . ?
N1 C12 1.502(9) . ?
O2 C26 1.365(8) . ?
O2 C28 1.453(8) . ?
N2 C26 1.293(8) . ?
N2 C27 1.506(9) . ?
C2 C11 1.457(10) . ?
C2 C3 1.468(9) . ?
C3 C4 1.412(10) . ?
C3 H3 0.9500 . ?
C4 C5 1.445(10) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C10 1.410(11) . ?
C6 C7 1.444(12) . ?
C6 H6 0.9500 . ?
C7 C8 1.389(12) . ?
C7 H7 0.9500 . ?
C8 C9 1.454(11) . ?
C8 H8 0.9500 . ?
C9 C10 1.425(11) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C14 1.516(10) . ?
C12 C15 1.524(10) . ?
C12 C13 1.545(10) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C20 1.440(9) . ?
C16 C17 1.461(9) . ?
C17 C18 1.437(9) . ?
C17 C26 1.449(9) . ?
C18 C19 1.420(10) . ?
C18 H18 0.9500 . ?
C19 C20 1.440(9) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C21 C25 1.423(12) . ?
C21 C22 1.430(12) . ?
C21 H21 0.9500 . ?
C22 C23 1.422(12) . ?
C22 H22 0.9500 . ?
C23 C24 1.406(11) . ?
C23 H23 0.9500 . ?
C24 C25 1.434(11) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
C27 C30 1.509(10) . ?
C27 C28 1.529(10) . ?
C27 C29 1.539(10) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 175.6(3) . . ?
C1 Au1 Au2 90.7(2) . . ?
N2 Au1 Au2 87.96(16) . . ?
C16 Au2 N1 176.0(2) . . ?
C16 Au2 Au1 89.90(19) . . ?
N1 Au2 Au1 88.30(16) . . ?
C3 Fe1 C2 42.0(3) . . ?
C3 Fe1 C10 156.6(3) . . ?
C2 Fe1 C10 159.9(3) . . ?
C3 Fe1 C9 120.7(3) . . ?
C2 Fe1 C9 158.1(3) . . ?
C10 Fe1 C9 40.7(3) . . ?
C3 Fe1 C7 124.4(3) . . ?
C2 Fe1 C7 108.0(3) . . ?
C10 Fe1 C7 67.9(3) . . ?
C9 Fe1 C7 68.5(3) . . ?
C3 Fe1 C6 161.7(3) . . ?
C2 Fe1 C6 123.8(3) . . ?
C10 Fe1 C6 40.2(3) . . ?
C9 Fe1 C6 68.8(3) . . ?
C7 Fe1 C6 41.1(3) . . ?
C3 Fe1 C4 40.2(3) . . ?
C2 Fe1 C4 68.9(3) . . ?
C10 Fe1 C4 121.8(3) . . ?
C9 Fe1 C4 106.7(3) . . ?
C7 Fe1 C4 160.2(3) . . ?
C6 Fe1 C4 156.9(3) . . ?
C3 Fe1 C8 108.0(3) . . ?
C2 Fe1 C8 122.4(3) . . ?
C10 Fe1 C8 67.8(3) . . ?
C9 Fe1 C8 41.3(3) . . ?
C7 Fe1 C8 39.4(3) . . ?
C6 Fe1 C8 67.8(3) . . ?
C4 Fe1 C8 124.6(3) . . ?
C3 Fe1 C5 67.8(3) . . ?
C2 Fe1 C5 67.3(3) . . ?
C10 Fe1 C5 108.6(3) . . ?
C9 Fe1 C5 124.1(3) . . ?
C7 Fe1 C5 157.7(3) . . ?
C6 Fe1 C5 121.8(3) . . ?
C4 Fe1 C5 40.7(3) . . ?
C8 Fe1 C5 161.7(3) . . ?
C3 Fe1 C1 69.5(3) . . ?
C2 Fe1 C1 40.9(3) . . ?
C10 Fe1 C1 123.4(3) . . ?
C9 Fe1 C1 159.4(3) . . ?
C7 Fe1 C1 122.5(3) . . ?
C6 Fe1 C1 107.1(3) . . ?
C4 Fe1 C1 68.7(3) . . ?
C8 Fe1 C1 157.6(3) . . ?
C5 Fe1 C1 39.6(3) . . ?
C17 Fe2 C22 106.0(3) . . ?
C17 Fe2 C23 122.1(3) . . ?
C22 Fe2 C23 40.9(3) . . ?
C17 Fe2 C18 41.5(3) . . ?
C22 Fe2 C18 122.2(3) . . ?
C23 Fe2 C18 107.2(3) . . ?
C17 Fe2 C24 158.9(3) . . ?
C22 Fe2 C24 68.2(3) . . ?
C23 Fe2 C24 40.4(3) . . ?
C18 Fe2 C24 123.1(3) . . ?
C17 Fe2 C25 157.6(3) . . ?
C22 Fe2 C25 68.6(3) . . ?
C23 Fe2 C25 68.9(3) . . ?
C18 Fe2 C25 159.7(3) . . ?
C24 Fe2 C25 41.1(3) . . ?
C17 Fe2 C19 68.2(3) . . ?
C22 Fe2 C19 159.7(3) . . ?
C23 Fe2 C19 124.4(3) . . ?
C18 Fe2 C19 40.6(3) . . ?
C24 Fe2 C19 109.8(3) . . ?
C25 Fe2 C19 124.1(3) . . ?
C17 Fe2 C21 121.2(3) . . ?
C22 Fe2 C21 40.9(3) . . ?
C23 Fe2 C21 68.9(3) . . ?
C18 Fe2 C21 158.3(3) . . ?
C24 Fe2 C21 68.6(3) . . ?
C25 Fe2 C21 40.6(3) . . ?
C19 Fe2 C21 158.9(3) . . ?
C17 Fe2 C20 68.1(3) . . ?
C22 Fe2 C20 156.9(3) . . ?
C23 Fe2 C20 161.1(3) . . ?
C18 Fe2 C20 69.0(3) . . ?
C24 Fe2 C20 125.1(3) . . ?
C25 Fe2 C20 107.9(3) . . ?
C19 Fe2 C20 40.9(3) . . ?
C21 Fe2 C20 121.6(3) . . ?
C17 Fe2 C16 41.7(3) . . ?
C22 Fe2 C16 120.0(3) . . ?
C23 Fe2 C16 157.3(3) . . ?
C18 Fe2 C16 70.8(3) . . ?
C24 Fe2 C16 159.0(3) . . ?
C25 Fe2 C16 120.8(3) . . ?
C19 Fe2 C16 69.5(3) . . ?
C21 Fe2 C16 104.2(3) . . ?
C20 Fe2 C16 40.6(3) . . ?
C5 C1 C2 105.7(6) . . ?
C5 C1 Au1 130.3(5) . . ?
C2 C1 Au1 124.0(5) . . ?
C5 C1 Fe1 69.2(4) . . ?
C2 C1 Fe1 67.1(4) . . ?
Au1 C1 Fe1 130.2(3) . . ?
C11 O1 C13 106.9(5) . . ?
C11 N1 C12 108.8(5) . . ?
C11 N1 Au2 129.0(5) . . ?
C12 N1 Au2 121.3(4) . . ?
C26 O2 C28 106.1(5) . . ?
C26 N2 C27 108.1(5) . . ?
C26 N2 Au1 129.3(5) . . ?
C27 N2 Au1 122.0(4) . . ?
C1 C2 C11 128.4(6) . . ?
C1 C2 C3 108.5(6) . . ?
C11 C2 C3 123.1(6) . . ?
C1 C2 Fe1 72.0(4) . . ?
C11 C2 Fe1 125.7(5) . . ?
C3 C2 Fe1 68.8(4) . . ?
C4 C3 C2 107.7(6) . . ?
C4 C3 Fe1 70.8(4) . . ?
C2 C3 Fe1 69.1(3) . . ?
C4 C3 H3 126.1 . . ?
C2 C3 H3 126.1 . . ?
Fe1 C3 H3 125.5 . . ?
C3 C4 C5 107.4(6) . . ?
C3 C4 Fe1 69.0(4) . . ?
C5 C4 Fe1 70.4(4) . . ?
C3 C4 H4 126.3 . . ?
C5 C4 H4 126.3 . . ?
Fe1 C4 H4 125.8 . . ?
C1 C5 C4 110.7(6) . . ?
C1 C5 Fe1 71.2(4) . . ?
C4 C5 Fe1 68.9(4) . . ?
C1 C5 H5 124.6 . . ?
C4 C5 H5 124.6 . . ?
Fe1 C5 H5 126.9 . . ?
C10 C6 C7 106.7(7) . . ?
C10 C6 Fe1 69.6(4) . . ?
C7 C6 Fe1 69.3(4) . . ?
C10 C6 H6 126.6 . . ?
C7 C6 H6 126.6 . . ?
Fe1 C6 H6 126.0 . . ?
C8 C7 C6 108.8(7) . . ?
C8 C7 Fe1 71.0(5) . . ?
C6 C7 Fe1 69.5(4) . . ?
C8 C7 H7 125.6 . . ?
C6 C7 H7 125.6 . . ?
Fe1 C7 H7 125.4 . . ?
C7 C8 C9 108.7(7) . . ?
C7 C8 Fe1 69.7(4) . . ?
C9 C8 Fe1 68.6(4) . . ?
C7 C8 H8 125.6 . . ?
C9 C8 H8 125.6 . . ?
Fe1 C8 H8 127.7 . . ?
C10 C9 C8 105.9(7) . . ?
C10 C9 Fe1 69.6(4) . . ?
C8 C9 Fe1 70.1(4) . . ?
C10 C9 H9 127.1 . . ?
C8 C9 H9 127.1 . . ?
Fe1 C9 H9 124.8 . . ?
C6 C10 C9 109.9(7) . . ?
C6 C10 Fe1 70.2(4) . . ?
C9 C10 Fe1 69.7(4) . . ?
C6 C10 H10 125.1 . . ?
C9 C10 H10 125.1 . . ?
Fe1 C10 H10 126.7 . . ?
N1 C11 O1 116.7(6) . . ?
N1 C11 C2 128.9(6) . . ?
O1 C11 C2 114.4(6) . . ?
N1 C12 C14 108.5(6) . . ?
N1 C12 C15 110.2(6) . . ?
C14 C12 C15 111.6(7) . . ?
N1 C12 C13 101.3(5) . . ?
C14 C12 C13 112.1(6) . . ?
C15 C12 C13 112.5(6) . . ?
O1 C13 C12 104.7(5) . . ?
O1 C13 H13A 110.8 . . ?
C12 C13 H13A 110.8 . . ?
O1 C13 H13B 110.8 . . ?
C12 C13 H13B 110.8 . . ?
H13A C13 H13B 108.9 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C20 C16 C17 104.1(6) . . ?
C20 C16 Au2 129.8(5) . . ?
C17 C16 Au2 125.8(5) . . ?
C20 C16 Fe2 69.0(4) . . ?
C17 C16 Fe2 67.0(4) . . ?
Au2 C16 Fe2 122.5(3) . . ?
C18 C17 C26 122.2(6) . . ?
C18 C17 C16 110.8(6) . . ?
C26 C17 C16 126.9(6) . . ?
C18 C17 Fe2 69.7(4) . . ?
C26 C17 Fe2 122.7(5) . . ?
C16 C17 Fe2 71.3(4) . . ?
C19 C18 C17 106.4(6) . . ?
C19 C18 Fe2 70.5(4) . . ?
C17 C18 Fe2 68.8(4) . . ?
C19 C18 H18 126.8 . . ?
C17 C18 H18 126.8 . . ?
Fe2 C18 H18 125.5 . . ?
C18 C19 C20 108.7(6) . . ?
C18 C19 Fe2 68.9(4) . . ?
C20 C19 Fe2 69.9(4) . . ?
C18 C19 H19 125.7 . . ?
C20 C19 H19 125.7 . . ?
Fe2 C19 H19 127.2 . . ?
C16 C20 C19 109.9(6) . . ?
C16 C20 Fe2 70.3(4) . . ?
C19 C20 Fe2 69.2(4) . . ?
C16 C20 H20 125.0 . . ?
C19 C20 H20 125.0 . . ?
Fe2 C20 H20 127.0 . . ?
C25 C21 C22 107.4(7) . . ?
C25 C21 Fe2 69.2(4) . . ?
C22 C21 Fe2 68.9(4) . . ?
C25 C21 H21 126.3 . . ?
C22 C21 H21 126.3 . . ?
Fe2 C21 H21 127.2 . . ?
C21 C22 C23 108.4(7) . . ?
C21 C22 Fe2 70.2(4) . . ?
C23 C22 Fe2 69.5(4) . . ?
C21 C22 H22 125.8 . . ?
C23 C22 H22 125.8 . . ?
Fe2 C22 H22 126.1 . . ?
C24 C23 C22 107.9(7) . . ?
C24 C23 Fe2 70.0(4) . . ?
C22 C23 Fe2 69.6(4) . . ?
C24 C23 H23 126.0 . . ?
C22 C23 H23 126.0 . . ?
Fe2 C23 H23 125.9 . . ?
C23 C24 C25 108.5(7) . . ?
C23 C24 Fe2 69.6(4) . . ?
C25 C24 Fe2 69.5(4) . . ?
C23 C24 H24 125.7 . . ?
C25 C24 H24 125.7 . . ?
Fe2 C24 H24 126.7 . . ?
C21 C25 C24 107.7(7) . . ?
C21 C25 Fe2 70.1(4) . . ?
C24 C25 Fe2 69.4(4) . . ?
C21 C25 H25 126.1 . . ?
C24 C25 H25 126.1 . . ?
Fe2 C25 H25 125.9 . . ?
N2 C26 O2 115.4(6) . . ?
N2 C26 C17 128.7(6) . . ?
O2 C26 C17 115.9(6) . . ?
C30 C27 N2 110.9(6) . . ?
C30 C27 C28 111.8(6) . . ?
N2 C27 C28 100.9(5) . . ?
C30 C27 C29 112.2(6) . . ?
N2 C27 C29 107.8(6) . . ?
C28 C27 C29 112.7(6) . . ?
O2 C28 C27 104.7(5) . . ?
O2 C28 H28A 110.8 . . ?
C27 C28 H28A 110.8 . . ?
O2 C28 H28B 110.8 . . ?
C27 C28 H28B 110.8 . . ?
H28A C28 H28B 108.9 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C16 137.3(3) . . . . ?
N2 Au1 Au2 C16 -46.8(2) . . . . ?
C1 Au1 Au2 N1 -46.3(3) . . . . ?
N2 Au1 Au2 N1 129.6(2) . . . . ?
N2 Au1 C1 C5 145(3) . . . . ?
Au2 Au1 C1 C5 -142.8(6) . . . . ?
N2 Au1 C1 C2 -32(4) . . . . ?
Au2 Au1 C1 C2 40.8(5) . . . . ?
N2 Au1 C1 Fe1 -119(3) . . . . ?
Au2 Au1 C1 Fe1 -46.7(4) . . . . ?
C3 Fe1 C1 C5 -79.5(4) . . . . ?
C2 Fe1 C1 C5 -118.2(5) . . . . ?
C10 Fe1 C1 C5 78.5(5) . . . . ?
C9 Fe1 C1 C5 44.4(9) . . . . ?
C7 Fe1 C1 C5 161.9(4) . . . . ?
C6 Fe1 C1 C5 119.6(4) . . . . ?
C4 Fe1 C1 C5 -36.4(4) . . . . ?
C8 Fe1 C1 C5 -167.3(7) . . . . ?
C3 Fe1 C1 C2 38.7(4) . . . . ?
C10 Fe1 C1 C2 -163.2(4) . . . . ?
C9 Fe1 C1 C2 162.6(8) . . . . ?
C7 Fe1 C1 C2 -79.8(5) . . . . ?
C6 Fe1 C1 C2 -122.2(4) . . . . ?
C4 Fe1 C1 C2 81.9(4) . . . . ?
C8 Fe1 C1 C2 -49.1(8) . . . . ?
C5 Fe1 C1 C2 118.2(5) . . . . ?
C3 Fe1 C1 Au1 154.7(5) . . . . ?
C2 Fe1 C1 Au1 116.0(6) . . . . ?
C10 Fe1 C1 Au1 -47.2(6) . . . . ?
C9 Fe1 C1 Au1 -81.4(10) . . . . ?
C7 Fe1 C1 Au1 36.2(6) . . . . ?
C6 Fe1 C1 Au1 -6.2(6) . . . . ?
C4 Fe1 C1 Au1 -162.1(5) . . . . ?
C8 Fe1 C1 Au1 66.9(9) . . . . ?
C5 Fe1 C1 Au1 -125.8(7) . . . . ?
C16 Au2 N1 C11 100(4) . . . . ?
Au1 Au2 N1 C11 36.1(6) . . . . ?
C16 Au2 N1 C12 -68(4) . . . . ?
Au1 Au2 N1 C12 -131.5(5) . . . . ?
C1 Au1 N2 C26 111(3) . . . . ?
Au2 Au1 N2 C26 38.7(6) . . . . ?
C1 Au1 N2 C27 -59(3) . . . . ?
Au2 Au1 N2 C27 -131.9(5) . . . . ?
C5 C1 C2 C11 -179.5(6) . . . . ?
Au1 C1 C2 C11 -2.3(10) . . . . ?
Fe1 C1 C2 C11 121.7(7) . . . . ?
C5 C1 C2 C3 -0.6(7) . . . . ?
Au1 C1 C2 C3 176.6(4) . . . . ?
Fe1 C1 C2 C3 -59.4(4) . . . . ?
C5 C1 C2 Fe1 58.8(5) . . . . ?
Au1 C1 C2 Fe1 -124.1(5) . . . . ?
C3 Fe1 C2 C1 -118.9(5) . . . . ?
C10 Fe1 C2 C1 44.6(10) . . . . ?
C9 Fe1 C2 C1 -163.6(7) . . . . ?
C7 Fe1 C2 C1 119.2(4) . . . . ?
C6 Fe1 C2 C1 76.6(5) . . . . ?
C4 Fe1 C2 C1 -81.5(4) . . . . ?
C8 Fe1 C2 C1 160.1(4) . . . . ?
C5 Fe1 C2 C1 -37.4(4) . . . . ?
C3 Fe1 C2 C11 116.3(7) . . . . ?
C10 Fe1 C2 C11 -80.2(11) . . . . ?
C9 Fe1 C2 C11 71.5(10) . . . . ?
C7 Fe1 C2 C11 -5.6(7) . . . . ?
C6 Fe1 C2 C11 -48.2(7) . . . . ?
C4 Fe1 C2 C11 153.7(6) . . . . ?
C8 Fe1 C2 C11 35.3(7) . . . . ?
C5 Fe1 C2 C11 -162.3(6) . . . . ?
C1 Fe1 C2 C11 -124.8(7) . . . . ?
C10 Fe1 C2 C3 163.5(8) . . . . ?
C9 Fe1 C2 C3 -44.7(9) . . . . ?
C7 Fe1 C2 C3 -121.8(4) . . . . ?
C6 Fe1 C2 C3 -164.5(4) . . . . ?
C4 Fe1 C2 C3 37.4(4) . . . . ?
C8 Fe1 C2 C3 -81.0(5) . . . . ?
C5 Fe1 C2 C3 81.5(4) . . . . ?
C1 Fe1 C2 C3 118.9(5) . . . . ?
C1 C2 C3 C4 0.8(7) . . . . ?
C11 C2 C3 C4 179.8(6) . . . . ?
Fe1 C2 C3 C4 -60.5(5) . . . . ?
C1 C2 C3 Fe1 61.4(4) . . . . ?
C11 C2 C3 Fe1 -119.7(6) . . . . ?
C2 Fe1 C3 C4 118.5(6) . . . . ?
C10 Fe1 C3 C4 -47.2(9) . . . . ?
C9 Fe1 C3 C4 -79.3(5) . . . . ?
C7 Fe1 C3 C4 -163.0(4) . . . . ?
C6 Fe1 C3 C4 163.5(8) . . . . ?
C8 Fe1 C3 C4 -122.8(4) . . . . ?
C5 Fe1 C3 C4 38.3(4) . . . . ?
C1 Fe1 C3 C4 80.8(4) . . . . ?
C10 Fe1 C3 C2 -165.8(7) . . . . ?
C9 Fe1 C3 C2 162.2(4) . . . . ?
C7 Fe1 C3 C2 78.4(5) . . . . ?
C6 Fe1 C3 C2 44.9(10) . . . . ?
C4 Fe1 C3 C2 -118.5(6) . . . . ?
C8 Fe1 C3 C2 118.7(4) . . . . ?
C5 Fe1 C3 C2 -80.3(4) . . . . ?
C1 Fe1 C3 C2 -37.7(4) . . . . ?
C2 C3 C4 C5 -0.7(8) . . . . ?
Fe1 C3 C4 C5 -60.2(5) . . . . ?
C2 C3 C4 Fe1 59.5(4) . . . . ?
C2 Fe1 C4 C3 -39.1(4) . . . . ?
C10 Fe1 C4 C3 160.0(4) . . . . ?
C9 Fe1 C4 C3 118.2(4) . . . . ?
C7 Fe1 C4 C3 45.4(11) . . . . ?
C6 Fe1 C4 C3 -166.8(7) . . . . ?
C8 Fe1 C4 C3 76.4(5) . . . . ?
C5 Fe1 C4 C3 -118.5(6) . . . . ?
C1 Fe1 C4 C3 -83.1(4) . . . . ?
C3 Fe1 C4 C5 118.5(6) . . . . ?
C2 Fe1 C4 C5 79.4(4) . . . . ?
C10 Fe1 C4 C5 -81.6(5) . . . . ?
C9 Fe1 C4 C5 -123.3(4) . . . . ?
C7 Fe1 C4 C5 163.8(8) . . . . ?
C6 Fe1 C4 C5 -48.3(9) . . . . ?
C8 Fe1 C4 C5 -165.1(4) . . . . ?
C1 Fe1 C4 C5 35.3(4) . . . . ?
C2 C1 C5 C4 0.1(8) . . . . ?
Au1 C1 C5 C4 -176.8(5) . . . . ?
Fe1 C1 C5 C4 57.6(5) . . . . ?
C2 C1 C5 Fe1 -57.5(4) . . . . ?
Au1 C1 C5 Fe1 125.6(6) . . . . ?
C3 C4 C5 C1 0.4(8) . . . . ?
Fe1 C4 C5 C1 -59.0(5) . . . . ?
C3 C4 C5 Fe1 59.4(5) . . . . ?
C3 Fe1 C5 C1 84.4(4) . . . . ?
C2 Fe1 C5 C1 38.7(4) . . . . ?
C10 Fe1 C5 C1 -120.3(4) . . . . ?
C9 Fe1 C5 C1 -162.7(4) . . . . ?
C7 Fe1 C5 C1 -43.5(9) . . . . ?
C6 Fe1 C5 C1 -78.0(5) . . . . ?
C4 Fe1 C5 C1 122.2(6) . . . . ?
C8 Fe1 C5 C1 164.5(8) . . . . ?
C3 Fe1 C5 C4 -37.8(4) . . . . ?
C2 Fe1 C5 C4 -83.5(4) . . . . ?
C10 Fe1 C5 C4 117.5(4) . . . . ?
C9 Fe1 C5 C4 75.2(5) . . . . ?
C7 Fe1 C5 C4 -165.7(7) . . . . ?
C6 Fe1 C5 C4 159.8(4) . . . . ?
C8 Fe1 C5 C4 42.4(10) . . . . ?
C1 Fe1 C5 C4 -122.2(6) . . . . ?
C3 Fe1 C6 C10 161.7(8) . . . . ?
C2 Fe1 C6 C10 -163.6(4) . . . . ?
C9 Fe1 C6 C10 36.7(5) . . . . ?
C7 Fe1 C6 C10 117.9(6) . . . . ?
C4 Fe1 C6 C10 -46.2(9) . . . . ?
C8 Fe1 C6 C10 81.3(5) . . . . ?
C5 Fe1 C6 C10 -81.2(5) . . . . ?
C1 Fe1 C6 C10 -121.8(4) . . . . ?
C3 Fe1 C6 C7 43.8(11) . . . . ?
C2 Fe1 C6 C7 78.5(5) . . . . ?
C10 Fe1 C6 C7 -117.9(6) . . . . ?
C9 Fe1 C6 C7 -81.2(5) . . . . ?
C4 Fe1 C6 C7 -164.1(7) . . . . ?
C8 Fe1 C6 C7 -36.6(5) . . . . ?
C5 Fe1 C6 C7 160.9(4) . . . . ?
C1 Fe1 C6 C7 120.2(5) . . . . ?
C10 C6 C7 C8 0.5(8) . . . . ?
Fe1 C6 C7 C8 60.4(5) . . . . ?
C10 C6 C7 Fe1 -59.9(5) . . . . ?
C3 Fe1 C7 C8 75.8(5) . . . . ?
C2 Fe1 C7 C8 119.5(5) . . . . ?
C10 Fe1 C7 C8 -81.5(5) . . . . ?
C9 Fe1 C7 C8 -37.5(5) . . . . ?
C6 Fe1 C7 C8 -119.5(7) . . . . ?
C4 Fe1 C7 C8 42.0(11) . . . . ?
C5 Fe1 C7 C8 -166.6(7) . . . . ?
C1 Fe1 C7 C8 162.1(4) . . . . ?
C3 Fe1 C7 C6 -164.7(4) . . . . ?
C2 Fe1 C7 C6 -121.1(5) . . . . ?
C10 Fe1 C7 C6 38.0(4) . . . . ?
C9 Fe1 C7 C6 81.9(5) . . . . ?
C4 Fe1 C7 C6 161.5(8) . . . . ?
C8 Fe1 C7 C6 119.5(7) . . . . ?
C5 Fe1 C7 C6 -47.1(10) . . . . ?
C1 Fe1 C7 C6 -78.4(5) . . . . ?
C6 C7 C8 C9 -2.0(8) . . . . ?
Fe1 C7 C8 C9 57.5(5) . . . . ?
C6 C7 C8 Fe1 -59.5(5) . . . . ?
C3 Fe1 C8 C7 -122.8(5) . . . . ?
C2 Fe1 C8 C7 -78.7(5) . . . . ?
C10 Fe1 C8 C7 81.8(5) . . . . ?
C9 Fe1 C8 C7 120.9(6) . . . . ?
C6 Fe1 C8 C7 38.2(5) . . . . ?
C4 Fe1 C8 C7 -164.0(5) . . . . ?
C5 Fe1 C8 C7 163.6(8) . . . . ?
C1 Fe1 C8 C7 -42.8(9) . . . . ?
C3 Fe1 C8 C9 116.4(4) . . . . ?
C2 Fe1 C8 C9 160.5(4) . . . . ?
C10 Fe1 C8 C9 -39.1(4) . . . . ?
C7 Fe1 C8 C9 -120.9(6) . . . . ?
C6 Fe1 C8 C9 -82.7(5) . . . . ?
C4 Fe1 C8 C9 75.1(5) . . . . ?
C5 Fe1 C8 C9 42.8(10) . . . . ?
C1 Fe1 C8 C9 -163.7(6) . . . . ?
C7 C8 C9 C10 2.7(8) . . . . ?
Fe1 C8 C9 C10 60.8(5) . . . . ?
C7 C8 C9 Fe1 -58.2(5) . . . . ?
C3 Fe1 C9 C10 161.2(5) . . . . ?
C2 Fe1 C9 C10 -165.6(7) . . . . ?
C7 Fe1 C9 C10 -80.6(5) . . . . ?
C6 Fe1 C9 C10 -36.3(5) . . . . ?
C4 Fe1 C9 C10 119.7(5) . . . . ?
C8 Fe1 C9 C10 -116.4(7) . . . . ?
C5 Fe1 C9 C10 78.5(5) . . . . ?
C1 Fe1 C9 C10 46.0(10) . . . . ?
C3 Fe1 C9 C8 -82.5(5) . . . . ?
C2 Fe1 C9 C8 -49.2(10) . . . . ?
C10 Fe1 C9 C8 116.4(7) . . . . ?
C7 Fe1 C9 C8 35.8(5) . . . . ?
C6 Fe1 C9 C8 80.1(5) . . . . ?
C4 Fe1 C9 C8 -123.9(4) . . . . ?
C5 Fe1 C9 C8 -165.1(4) . . . . ?
C1 Fe1 C9 C8 162.4(7) . . . . ?
C7 C6 C10 C9 1.2(8) . . . . ?
Fe1 C6 C10 C9 -58.5(5) . . . . ?
C7 C6 C10 Fe1 59.7(5) . . . . ?
C8 C9 C10 C6 -2.4(8) . . . . ?
Fe1 C9 C10 C6 58.8(5) . . . . ?
C8 C9 C10 Fe1 -61.2(5) . . . . ?
C3 Fe1 C10 C6 -165.6(6) . . . . ?
C2 Fe1 C10 C6 43.1(11) . . . . ?
C9 Fe1 C10 C6 -121.2(7) . . . . ?
C7 Fe1 C10 C6 -38.9(5) . . . . ?
C4 Fe1 C10 C6 160.5(4) . . . . ?
C8 Fe1 C10 C6 -81.5(5) . . . . ?
C5 Fe1 C10 C6 117.6(4) . . . . ?
C1 Fe1 C10 C6 76.4(5) . . . . ?
C3 Fe1 C10 C9 -44.4(10) . . . . ?
C2 Fe1 C10 C9 164.3(8) . . . . ?
C7 Fe1 C10 C9 82.4(5) . . . . ?
C6 Fe1 C10 C9 121.2(7) . . . . ?
C4 Fe1 C10 C9 -78.2(5) . . . . ?
C8 Fe1 C10 C9 39.7(5) . . . . ?
C5 Fe1 C10 C9 -121.2(5) . . . . ?
C1 Fe1 C10 C9 -162.3(4) . . . . ?
C12 N1 C11 O1 -4.6(8) . . . . ?
Au2 N1 C11 O1 -173.4(4) . . . . ?
C12 N1 C11 C2 173.4(6) . . . . ?
Au2 N1 C11 C2 4.6(11) . . . . ?
C13 O1 C11 N1 -4.2(8) . . . . ?
C13 O1 C11 C2 177.5(6) . . . . ?
C1 C2 C11 N1 -37.6(11) . . . . ?
C3 C2 C11 N1 143.6(7) . . . . ?
Fe1 C2 C11 N1 57.2(10) . . . . ?
C1 C2 C11 O1 140.4(7) . . . . ?
C3 C2 C11 O1 -38.4(9) . . . . ?
Fe1 C2 C11 O1 -124.8(6) . . . . ?
C11 N1 C12 C14 -107.6(7) . . . . ?
Au2 N1 C12 C14 62.2(7) . . . . ?
C11 N1 C12 C15 129.9(7) . . . . ?
Au2 N1 C12 C15 -60.3(7) . . . . ?
C11 N1 C12 C13 10.6(7) . . . . ?
Au2 N1 C12 C13 -179.6(4) . . . . ?
C11 O1 C13 C12 10.6(7) . . . . ?
N1 C12 C13 O1 -12.4(7) . . . . ?
C14 C12 C13 O1 103.1(7) . . . . ?
C15 C12 C13 O1 -130.1(6) . . . . ?
N1 Au2 C16 C20 150(3) . . . . ?
Au1 Au2 C16 C20 -146.2(6) . . . . ?
N1 Au2 C16 C17 -22(4) . . . . ?
Au1 Au2 C16 C17 41.4(5) . . . . ?
N1 Au2 C16 Fe2 62(4) . . . . ?
Au1 Au2 C16 Fe2 125.0(3) . . . . ?
C17 Fe2 C16 C20 116.5(5) . . . . ?
C22 Fe2 C16 C20 -163.3(4) . . . . ?
C23 Fe2 C16 C20 168.6(7) . . . . ?
C18 Fe2 C16 C20 79.9(4) . . . . ?
C24 Fe2 C16 C20 -55.3(10) . . . . ?
C25 Fe2 C16 C20 -81.7(5) . . . . ?
C19 Fe2 C16 C20 36.6(4) . . . . ?
C21 Fe2 C16 C20 -122.2(4) . . . . ?
C22 Fe2 C16 C17 80.2(5) . . . . ?
C23 Fe2 C16 C17 52.1(9) . . . . ?
C18 Fe2 C16 C17 -36.7(4) . . . . ?
C24 Fe2 C16 C17 -171.8(8) . . . . ?
C25 Fe2 C16 C17 161.8(4) . . . . ?
C19 Fe2 C16 C17 -79.9(4) . . . . ?
C21 Fe2 C16 C17 121.2(4) . . . . ?
C20 Fe2 C16 C17 -116.5(5) . . . . ?
C17 Fe2 C16 Au2 -118.9(5) . . . . ?
C22 Fe2 C16 Au2 -38.7(5) . . . . ?
C23 Fe2 C16 Au2 -66.8(9) . . . . ?
C18 Fe2 C16 Au2 -155.5(5) . . . . ?
C24 Fe2 C16 Au2 69.3(10) . . . . ?
C25 Fe2 C16 Au2 42.9(5) . . . . ?
C19 Fe2 C16 Au2 161.2(5) . . . . ?
C21 Fe2 C16 Au2 2.4(5) . . . . ?
C20 Fe2 C16 Au2 124.6(6) . . . . ?
C20 C16 C17 C18 -0.9(7) . . . . ?
Au2 C16 C17 C18 173.1(5) . . . . ?
Fe2 C16 C17 C18 58.6(5) . . . . ?
C20 C16 C17 C26 -176.9(6) . . . . ?
Au2 C16 C17 C26 -2.9(10) . . . . ?
Fe2 C16 C17 C26 -117.4(7) . . . . ?
C20 C16 C17 Fe2 -59.5(4) . . . . ?
Au2 C16 C17 Fe2 114.5(5) . . . . ?
C22 Fe2 C17 C18 120.9(5) . . . . ?
C23 Fe2 C17 C18 79.4(5) . . . . ?
C24 Fe2 C17 C18 50.2(10) . . . . ?
C25 Fe2 C17 C18 -166.6(7) . . . . ?
C19 Fe2 C17 C18 -38.5(4) . . . . ?
C21 Fe2 C17 C18 162.7(4) . . . . ?
C20 Fe2 C17 C18 -82.7(4) . . . . ?
C16 Fe2 C17 C18 -121.7(5) . . . . ?
C22 Fe2 C17 C26 5.0(6) . . . . ?
C23 Fe2 C17 C26 -36.5(6) . . . . ?
C18 Fe2 C17 C26 -115.9(7) . . . . ?
C24 Fe2 C17 C26 -65.7(10) . . . . ?
C25 Fe2 C17 C26 77.5(10) . . . . ?
C19 Fe2 C17 C26 -154.4(6) . . . . ?
C21 Fe2 C17 C26 46.8(7) . . . . ?
C20 Fe2 C17 C26 161.3(6) . . . . ?
C16 Fe2 C17 C26 122.4(7) . . . . ?
C22 Fe2 C17 C16 -117.4(4) . . . . ?
C23 Fe2 C17 C16 -158.9(4) . . . . ?
C18 Fe2 C17 C16 121.7(5) . . . . ?
C24 Fe2 C17 C16 171.8(8) . . . . ?
C25 Fe2 C17 C16 -44.9(9) . . . . ?
C19 Fe2 C17 C16 83.1(4) . . . . ?
C21 Fe2 C17 C16 -75.6(5) . . . . ?
C20 Fe2 C17 C16 38.9(4) . . . . ?
C26 C17 C18 C19 177.5(6) . . . . ?
C16 C17 C18 C19 1.2(8) . . . . ?
Fe2 C17 C18 C19 60.8(5) . . . . ?
C26 C17 C18 Fe2 116.6(6) . . . . ?
C16 C17 C18 Fe2 -59.6(5) . . . . ?
C17 Fe2 C18 C19 -117.3(6) . . . . ?
C22 Fe2 C18 C19 165.5(4) . . . . ?
C23 Fe2 C18 C19 123.3(4) . . . . ?
C24 Fe2 C18 C19 81.9(5) . . . . ?
C25 Fe2 C18 C19 47.9(10) . . . . ?
C21 Fe2 C18 C19 -160.7(8) . . . . ?
C20 Fe2 C18 C19 -37.2(4) . . . . ?
C16 Fe2 C18 C19 -80.5(4) . . . . ?
C22 Fe2 C18 C17 -77.2(5) . . . . ?
C23 Fe2 C18 C17 -119.4(4) . . . . ?
C24 Fe2 C18 C17 -160.8(4) . . . . ?
C25 Fe2 C18 C17 165.3(8) . . . . ?
C19 Fe2 C18 C17 117.3(6) . . . . ?
C21 Fe2 C18 C17 -43.4(10) . . . . ?
C20 Fe2 C18 C17 80.2(4) . . . . ?
C16 Fe2 C18 C17 36.8(4) . . . . ?
C17 C18 C19 C20 -1.1(8) . . . . ?
Fe2 C18 C19 C20 58.7(5) . . . . ?
C17 C18 C19 Fe2 -59.7(5) . . . . ?
C17 Fe2 C19 C18 39.3(4) . . . . ?
C22 Fe2 C19 C18 -37.7(11) . . . . ?
C23 Fe2 C19 C18 -75.6(5) . . . . ?
C24 Fe2 C19 C18 -118.2(4) . . . . ?
C25 Fe2 C19 C18 -161.9(4) . . . . ?
C21 Fe2 C19 C18 160.2(8) . . . . ?
C20 Fe2 C19 C18 120.5(6) . . . . ?
C16 Fe2 C19 C18 84.1(4) . . . . ?
C17 Fe2 C19 C20 -81.2(4) . . . . ?
C22 Fe2 C19 C20 -158.2(8) . . . . ?
C23 Fe2 C19 C20 164.0(4) . . . . ?
C18 Fe2 C19 C20 -120.5(6) . . . . ?
C24 Fe2 C19 C20 121.3(4) . . . . ?
C25 Fe2 C19 C20 77.6(5) . . . . ?
C21 Fe2 C19 C20 39.7(10) . . . . ?
C16 Fe2 C19 C20 -36.4(4) . . . . ?
C17 C16 C20 C19 0.2(7) . . . . ?
Au2 C16 C20 C19 -173.5(5) . . . . ?
Fe2 C16 C20 C19 -58.0(5) . . . . ?
C17 C16 C20 Fe2 58.2(4) . . . . ?
Au2 C16 C20 Fe2 -115.5(5) . . . . ?
C18 C19 C20 C16 0.6(8) . . . . ?
Fe2 C19 C20 C16 58.6(5) . . . . ?
C18 C19 C20 Fe2 -58.1(5) . . . . ?
C17 Fe2 C20 C16 -39.9(4) . . . . ?
C22 Fe2 C20 C16 39.3(9) . . . . ?
C23 Fe2 C20 C16 -166.4(9) . . . . ?
C18 Fe2 C20 C16 -84.6(4) . . . . ?
C24 Fe2 C20 C16 158.9(4) . . . . ?
C25 Fe2 C20 C16 116.7(4) . . . . ?
C19 Fe2 C20 C16 -121.5(6) . . . . ?
C21 Fe2 C20 C16 74.2(5) . . . . ?
C17 Fe2 C20 C19 81.7(4) . . . . ?
C22 Fe2 C20 C19 160.8(7) . . . . ?
C23 Fe2 C20 C19 -44.8(11) . . . . ?
C18 Fe2 C20 C19 36.9(4) . . . . ?
C24 Fe2 C20 C19 -79.6(5) . . . . ?
C25 Fe2 C20 C19 -121.8(5) . . . . ?
C21 Fe2 C20 C19 -164.3(5) . . . . ?
C16 Fe2 C20 C19 121.5(6) . . . . ?
C17 Fe2 C21 C25 162.6(4) . . . . ?
C22 Fe2 C21 C25 -119.3(7) . . . . ?
C23 Fe2 C21 C25 -81.7(5) . . . . ?
C18 Fe2 C21 C25 -165.2(7) . . . . ?
C24 Fe2 C21 C25 -38.2(5) . . . . ?
C19 Fe2 C21 C25 51.3(10) . . . . ?
C20 Fe2 C21 C25 80.7(5) . . . . ?
C16 Fe2 C21 C25 121.0(5) . . . . ?
C17 Fe2 C21 C22 -78.1(5) . . . . ?
C23 Fe2 C21 C22 37.6(5) . . . . ?
C18 Fe2 C21 C22 -45.9(10) . . . . ?
C24 Fe2 C21 C22 81.1(5) . . . . ?
C25 Fe2 C21 C22 119.3(7) . . . . ?
C19 Fe2 C21 C22 170.6(8) . . . . ?
C20 Fe2 C21 C22 -159.9(4) . . . . ?
C16 Fe2 C21 C22 -119.7(5) . . . . ?
C25 C21 C22 C23 -0.5(9) . . . . ?
Fe2 C21 C22 C23 -59.2(5) . . . . ?
C25 C21 C22 Fe2 58.7(5) . . . . ?
C17 Fe2 C22 C21 119.5(5) . . . . ?
C23 Fe2 C22 C21 -119.6(7) . . . . ?
C18 Fe2 C22 C21 161.7(4) . . . . ?
C24 Fe2 C22 C21 -82.0(5) . . . . ?
C25 Fe2 C22 C21 -37.6(5) . . . . ?
C19 Fe2 C22 C21 -170.3(8) . . . . ?
C20 Fe2 C22 C21 48.1(10) . . . . ?
C16 Fe2 C22 C21 76.5(5) . . . . ?
C17 Fe2 C22 C23 -121.0(5) . . . . ?
C18 Fe2 C22 C23 -78.8(5) . . . . ?
C24 Fe2 C22 C23 37.6(5) . . . . ?
C25 Fe2 C22 C23 82.0(5) . . . . ?
C19 Fe2 C22 C23 -50.7(11) . . . . ?
C21 Fe2 C22 C23 119.6(7) . . . . ?
C20 Fe2 C22 C23 167.7(7) . . . . ?
C16 Fe2 C22 C23 -163.9(4) . . . . ?
C21 C22 C23 C24 -0.2(9) . . . . ?
Fe2 C22 C23 C24 -59.8(6) . . . . ?
C21 C22 C23 Fe2 59.6(5) . . . . ?
C17 Fe2 C23 C24 -164.3(5) . . . . ?
C22 Fe2 C23 C24 118.9(7) . . . . ?
C18 Fe2 C23 C24 -121.3(5) . . . . ?
C25 Fe2 C23 C24 37.6(5) . . . . ?
C19 Fe2 C23 C24 -80.0(6) . . . . ?
C21 Fe2 C23 C24 81.3(5) . . . . ?
C20 Fe2 C23 C24 -46.0(12) . . . . ?
C16 Fe2 C23 C24 157.5(7) . . . . ?
C17 Fe2 C23 C22 76.8(5) . . . . ?
C18 Fe2 C23 C22 119.7(5) . . . . ?
C24 Fe2 C23 C22 -118.9(7) . . . . ?
C25 Fe2 C23 C22 -81.3(5) . . . . ?
C19 Fe2 C23 C22 161.0(5) . . . . ?
C21 Fe2 C23 C22 -37.6(5) . . . . ?
C20 Fe2 C23 C22 -164.9(8) . . . . ?
C16 Fe2 C23 C22 38.5(10) . . . . ?
C22 C23 C24 C25 0.8(9) . . . . ?
Fe2 C23 C24 C25 -58.8(5) . . . . ?
C22 C23 C24 Fe2 59.6(5) . . . . ?
C17 Fe2 C24 C23 39.7(11) . . . . ?
C22 Fe2 C24 C23 -38.1(5) . . . . ?
C18 Fe2 C24 C23 77.1(6) . . . . ?
C25 Fe2 C24 C23 -120.0(7) . . . . ?
C19 Fe2 C24 C23 120.3(5) . . . . ?
C21 Fe2 C24 C23 -82.2(5) . . . . ?
C20 Fe2 C24 C23 163.5(5) . . . . ?
C16 Fe2 C24 C23 -155.6(7) . . . . ?
C17 Fe2 C24 C25 159.7(7) . . . . ?
C22 Fe2 C24 C25 82.0(5) . . . . ?
C23 Fe2 C24 C25 120.0(7) . . . . ?
C18 Fe2 C24 C25 -162.9(5) . . . . ?
C19 Fe2 C24 C25 -119.6(5) . . . . ?
C21 Fe2 C24 C25 37.8(5) . . . . ?
C20 Fe2 C24 C25 -76.5(6) . . . . ?
C16 Fe2 C24 C25 -35.6(11) . . . . ?
C22 C21 C25 C24 0.9(9) . . . . ?
Fe2 C21 C25 C24 59.4(5) . . . . ?
C22 C21 C25 Fe2 -58.5(5) . . . . ?
C23 C24 C25 C21 -1.1(9) . . . . ?
Fe2 C24 C25 C21 -59.9(5) . . . . ?
C23 C24 C25 Fe2 58.8(6) . . . . ?
C17 Fe2 C25 C21 -42.1(10) . . . . ?
C22 Fe2 C25 C21 37.8(5) . . . . ?
C23 Fe2 C25 C21 81.9(5) . . . . ?
C18 Fe2 C25 C21 164.2(8) . . . . ?
C24 Fe2 C25 C21 118.8(7) . . . . ?
C19 Fe2 C25 C21 -160.1(5) . . . . ?
C20 Fe2 C25 C21 -117.9(5) . . . . ?
C16 Fe2 C25 C21 -75.2(5) . . . . ?
C17 Fe2 C25 C24 -160.9(7) . . . . ?
C22 Fe2 C25 C24 -81.0(5) . . . . ?
C23 Fe2 C25 C24 -36.9(5) . . . . ?
C18 Fe2 C25 C24 45.4(11) . . . . ?
C19 Fe2 C25 C24 81.1(5) . . . . ?
C21 Fe2 C25 C24 -118.8(7) . . . . ?
C20 Fe2 C25 C24 123.3(5) . . . . ?
C16 Fe2 C25 C24 166.0(5) . . . . ?
C27 N2 C26 O2 -7.1(8) . . . . ?
Au1 N2 C26 O2 -178.7(4) . . . . ?
C27 N2 C26 C17 173.2(6) . . . . ?
Au1 N2 C26 C17 1.6(10) . . . . ?
C28 O2 C26 N2 -7.5(8) . . . . ?
C28 O2 C26 C17 172.3(6) . . . . ?
C18 C17 C26 N2 148.6(7) . . . . ?
C16 C17 C26 N2 -35.8(11) . . . . ?
Fe2 C17 C26 N2 -126.2(7) . . . . ?
C18 C17 C26 O2 -31.1(9) . . . . ?
C16 C17 C26 O2 144.5(6) . . . . ?
Fe2 C17 C26 O2 54.1(7) . . . . ?
C26 N2 C27 C30 136.1(6) . . . . ?
Au1 N2 C27 C30 -51.5(7) . . . . ?
C26 N2 C27 C28 17.5(7) . . . . ?
Au1 N2 C27 C28 -170.1(4) . . . . ?
C26 N2 C27 C29 -100.8(6) . . . . ?
Au1 N2 C27 C29 71.6(7) . . . . ?
C26 O2 C28 C27 18.2(7) . . . . ?
C30 C27 C28 O2 -139.1(6) . . . . ?
N2 C27 C28 O2 -21.1(7) . . . . ?
C29 C27 C28 O2 93.5(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        30.54
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         10.116
_refine_diff_density_min         -1.318
_refine_diff_density_rms         0.266
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2339lm
_database_code_depnum_ccdc_archive 'CCDC 1588451'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'Ph2FOMeAu(II)Cl' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C52 H44 Au2 Cl2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C52 H44 Au2 Cl2 Fe2 N2 O2'
_chemical_formula_weight         1305.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21'
_symmetry_space_group_name_Hall  'P 2yb'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   9.0018(5)
_cell_length_b                   35.4443(17)
_cell_length_c                   14.1240(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.394(3)
_cell_angle_gamma                90.00
_cell_volume                     4506.3(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    15755
_cell_measurement_theta_min      1.44
_cell_measurement_theta_max      26.50

_exptl_crystal_description       block
_exptl_crystal_colour            black
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.924
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2520
_exptl_absorpt_coefficient_mu    7.284
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.4287
_exptl_absorpt_correction_T_max  0.7459
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            61501
_diffrn_reflns_av_R_equivalents  0.0377
_diffrn_reflns_av_sigmaI/netI    0.0553
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -44
_diffrn_reflns_limit_k_max       43
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.44
_diffrn_reflns_theta_max         26.50
_reflns_number_total             16796
_reflns_number_gt                15755
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0305P)²+98.3356P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00027(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.040(7)
_refine_ls_number_reflns         16796
_refine_ls_number_parameters     1116
_refine_ls_number_restraints     721
_refine_ls_R_factor_all          0.0527
_refine_ls_R_factor_gt           0.0481
_refine_ls_wR_factor_ref         0.1086
_refine_ls_wR_factor_gt          0.1071
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_restrained_S_all      1.031
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1A Au 0.84420(5) 0.890740(13) -0.00001(3) 0.01186(10) Uani 1 1 d . . .
Au2A Au 0.73055(5) 0.913429(13) 0.15151(3) 0.01324(11) Uani 1 1 d . . .
Fe1A Fe 0.8717(2) 0.81129(5) 0.18167(13) 0.0171(4) Uani 1 1 d . . .
Fe2A Fe 0.42768(19) 0.87473(5) -0.00994(13) 0.0146(4) Uani 1 1 d . . .
Cl1A Cl 0.9417(3) 0.86512(9) -0.1445(2) 0.0164(6) Uani 1 1 d . . .
Cl2A Cl 0.6037(4) 0.93080(10) 0.2930(2) 0.0231(7) Uani 1 1 d . . .
O1A O 1.1242(9) 0.8853(2) 0.2989(6) 0.0163(18) Uani 1 1 d U . .
N1A N 0.9357(11) 0.9147(3) 0.2229(7) 0.016(2) Uani 1 1 d U . .
C1A C 0.9374(13) 0.8496(4) 0.0803(8) 0.014(2) Uani 1 1 d U . .
O2A O 0.5537(9) 0.9642(3) -0.1478(6) 0.0151(18) Uani 1 1 d U . .
N2A N 0.7446(11) 0.9343(3) -0.0803(7) 0.011(2) Uani 1 1 d U . .
C2A C 1.0204(15) 0.8532(4) 0.1664(9) 0.019(3) Uani 1 1 d U . .
C3A C 1.0982(13) 0.8179(4) 0.1833(9) 0.016(3) Uani 1 1 d U . .
C4A C 1.0558(14) 0.7928(4) 0.1111(9) 0.019(3) Uani 1 1 d U . .
H4A H 1.0872 0.7673 0.1054 0.023 Uiso 1 1 calc R . .
C5A C 0.9563(13) 0.8123(4) 0.0469(9) 0.015(3) Uani 1 1 d U . .
H5A H 0.9113 0.8019 -0.0083 0.018 Uiso 1 1 calc R . .
C6A C 0.6491(14) 0.8167(4) 0.2118(10) 0.021(3) Uani 1 1 d U . .
H6A H 0.5813 0.8338 0.1833 0.025 Uiso 1 1 calc R . .
C7A C 0.7355(17) 0.8234(5) 0.2907(11) 0.031(3) Uani 1 1 d U . .
H7A H 0.7372 0.8466 0.3246 0.038 Uiso 1 1 calc R . .
C8A C 0.8208(16) 0.7917(4) 0.3142(10) 0.028(3) Uani 1 1 d U . .
H8A H 0.8889 0.7892 0.3655 0.033 Uiso 1 1 calc R . .
C9A C 0.7834(15) 0.7640(4) 0.2447(10) 0.025(3) Uani 1 1 d U . .
H9A H 0.8226 0.7391 0.2421 0.030 Uiso 1 1 calc R . .
C10A C 0.6794(17) 0.7793(5) 0.1808(11) 0.032(3) Uani 1 1 d U . .
H10A H 0.6374 0.7671 0.1270 0.039 Uiso 1 1 calc R . .
C11A C 1.2016(15) 0.8071(4) 0.2622(10) 0.025(3) Uani 1 1 d U . .
H11A H 1.2025 0.7796 0.2690 0.037 Uiso 1 1 calc R . .
H11B H 1.1680 0.8186 0.3214 0.037 Uiso 1 1 calc R . .
H11C H 1.3021 0.8160 0.2478 0.037 Uiso 1 1 calc R . .
C12A C 1.0242(12) 0.8852(3) 0.2298(7) 0.010(2) Uani 1 1 d U . .
C13A C 0.9678(13) 0.9382(3) 0.3076(8) 0.011(2) Uani 1 1 d U . .
H13A H 0.8879 0.9333 0.3549 0.013 Uiso 1 1 calc R . .
C14A C 1.1147(16) 0.9214(4) 0.3480(11) 0.031(3) Uani 1 1 d U . .
H14A H 1.1994 0.9376 0.3273 0.037 Uiso 1 1 calc R . .
C15A C 1.1220(16) 0.9172(4) 0.4532(9) 0.026(3) Uani 1 1 d U . .
C16A C 1.0493(17) 0.8880(5) 0.4988(10) 0.032(3) Uani 1 1 d U . .
H16A H 1.0042 0.8686 0.4620 0.039 Uiso 1 1 calc R . .
C17A C 1.0405(15) 0.8863(5) 0.5983(10) 0.030(3) Uani 1 1 d U . .
H17A H 0.9893 0.8665 0.6297 0.036 Uiso 1 1 calc R . .
C18A C 1.1108(16) 0.9152(5) 0.6482(10) 0.033(3) Uani 1 1 d U . .
H18A H 1.1130 0.9143 0.7154 0.040 Uiso 1 1 calc R . .
C19A C 1.176(2) 0.9445(6) 0.6036(12) 0.044(4) Uani 1 1 d U . .
H19A H 1.2175 0.9643 0.6404 0.053 Uiso 1 1 calc R . .
C20A C 1.1837(15) 0.9466(4) 0.5035(11) 0.027(3) Uani 1 1 d U . .
H20A H 1.2295 0.9673 0.4726 0.033 Uiso 1 1 calc R . .
C21A C 0.9792(14) 0.9804(4) 0.2952(9) 0.018(3) Uani 1 1 d U . .
C22A C 1.0800(17) 0.9964(4) 0.2299(10) 0.030(3) Uani 1 1 d U . .
H22A H 1.1308 0.9806 0.1865 0.036 Uiso 1 1 calc R . .
C23A C 1.1052(18) 1.0355(5) 0.2289(11) 0.034(4) Uani 1 1 d U . .
H23A H 1.1747 1.0461 0.1860 0.040 Uiso 1 1 calc R . .
C24A C 1.031(2) 1.0579(5) 0.2887(13) 0.043(4) Uani 1 1 d U . .
H24A H 1.0505 1.0842 0.2894 0.052 Uiso 1 1 calc R . .
C25A C 0.9257(18) 1.0431(5) 0.3493(11) 0.033(4) Uani 1 1 d U . .
H25A H 0.8695 1.0594 0.3885 0.040 Uiso 1 1 calc R . .
C26A C 0.9021(15) 1.0043(4) 0.3529(10) 0.026(3) Uani 1 1 d U . .
H26A H 0.8316 0.9943 0.3959 0.031 Uiso 1 1 calc R . .
C27A C 0.5002(15) 0.9286(4) -0.0092(9) 0.015(3) Uani 1 1 d U . .
C28A C 0.5353(13) 0.9112(4) 0.0785(8) 0.016(2) Uani 1 1 d U . .
C29A C 0.3388(13) 0.9279(4) -0.0227(9) 0.0155(18) Uani 1 1 d U . .
C30A C 0.2838(13) 0.9100(4) 0.0588(8) 0.014(2) Uani 1 1 d U . .
H30A H 0.1817 0.9055 0.0711 0.016 Uiso 1 1 calc R . .
C31A C 0.4030(13) 0.8996(4) 0.1202(9) 0.0155(18) Uani 1 1 d U . .
H31A H 0.3939 0.8870 0.1792 0.019 Uiso 1 1 calc R . .
C32A C 0.4086(15) 0.8177(4) 0.0033(10) 0.024(3) Uani 1 1 d U . .
H32A H 0.3902 0.8046 0.0607 0.028 Uiso 1 1 calc R . .
C33A C 0.5496(14) 0.8265(4) -0.0318(9) 0.017(3) Uani 1 1 d U . .
H33A H 0.6418 0.8203 -0.0025 0.020 Uiso 1 1 calc R . .
C34A C 0.5311(15) 0.8458(4) -0.1173(10) 0.024(3) Uani 1 1 d U . .
H34A H 0.6084 0.8552 -0.1562 0.029 Uiso 1 1 calc R . .
C35A C 0.3714(15) 0.8490(4) -0.1365(9) 0.019(3) Uani 1 1 d U . .
H35A H 0.3256 0.8607 -0.1897 0.022 Uiso 1 1 calc R . .
C36A C 0.2985(14) 0.8312(4) -0.0592(9) 0.020(3) Uani 1 1 d U . .
H36A H 0.1942 0.8288 -0.0514 0.024 Uiso 1 1 calc R . .
C37A C 0.2482(14) 0.9434(4) -0.1022(9) 0.020(3) Uani 1 1 d U . .
H37A H 0.1476 0.9329 -0.0996 0.029 Uiso 1 1 calc R . .
H37B H 0.2941 0.9366 -0.1625 0.029 Uiso 1 1 calc R . .
H37C H 0.2433 0.9710 -0.0968 0.029 Uiso 1 1 calc R . .
C38A C 0.6048(13) 0.9419(3) -0.0764(8) 0.012(2) Uani 1 1 d U . .
C39A C 0.8118(13) 0.9549(4) -0.1599(8) 0.011(2) Uani 1 1 d U . .
H39A H 0.8698 0.9365 -0.1984 0.014 Uiso 1 1 calc R . .
C40A C 0.6744(14) 0.9665(4) -0.2176(9) 0.018(3) Uani 1 1 d U . .
H40A H 0.6858 0.9933 -0.2386 0.022 Uiso 1 1 calc R . .
C41A C 0.6367(13) 0.9409(4) -0.3066(8) 0.013(2) Uani 1 1 d U . .
C42A C 0.5317(18) 0.9135(5) -0.2977(11) 0.038(4) Uani 1 1 d U . .
H42A H 0.4800 0.9105 -0.2397 0.045 Uiso 1 1 calc R . .
C43A C 0.502(2) 0.8906(6) -0.3721(13) 0.047(4) Uani 1 1 d U . .
H43A H 0.4294 0.8711 -0.3678 0.057 Uiso 1 1 calc R . .
C44A C 0.5814(16) 0.8968(5) -0.4556(10) 0.030(3) Uani 1 1 d U . .
H44A H 0.5564 0.8821 -0.5096 0.037 Uiso 1 1 calc R . .
C45A C 0.688(2) 0.9216(5) -0.4636(12) 0.043(4) Uani 1 1 d U . .
H45A H 0.7434 0.9237 -0.5204 0.052 Uiso 1 1 calc R . .
C46A C 0.7189(18) 0.9451(5) -0.3860(11) 0.034(4) Uani 1 1 d U . .
H46A H 0.7955 0.9635 -0.3890 0.040 Uiso 1 1 calc R . .
C47A C 0.9137(13) 0.9864(4) -0.1323(8) 0.013(2) Uani 1 1 d U . .
C48A C 0.9255(15) 1.0005(4) -0.0422(9) 0.018(3) Uani 1 1 d U . .
H48A H 0.8681 0.9895 0.0067 0.022 Uiso 1 1 calc R . .
C49A C 1.0188(15) 1.0304(4) -0.0205(10) 0.025(3) Uani 1 1 d U . .
H49A H 1.0291 1.0389 0.0429 0.029 Uiso 1 1 calc R . .
C50A C 1.0964(16) 1.0475(4) -0.0925(11) 0.029(3) Uani 1 1 d U . .
H50A H 1.1583 1.0685 -0.0784 0.035 Uiso 1 1 calc R . .
C51A C 1.0863(16) 1.0349(4) -0.1836(10) 0.026(3) Uani 1 1 d U . .
H51A H 1.1440 1.0465 -0.2315 0.031 Uiso 1 1 calc R . .
C52A C 0.9908(16) 1.0048(4) -0.2073(10) 0.025(3) Uani 1 1 d U . .
H52A H 0.9781 0.9969 -0.2712 0.030 Uiso 1 1 calc R . .
Au1B Au 0.24002(5) 0.660273(13) -0.33879(3) 0.01199(11) Uani 1 1 d . . .
Au2B Au 0.35758(5) 0.684402(13) -0.18930(3) 0.01131(10) Uani 1 1 d . . .
Fe1B Fe -0.05890(19) 0.70127(5) -0.18107(12) 0.0137(4) Uani 1 1 d . . .
Fe2B Fe 0.3722(2) 0.76081(5) -0.37952(13) 0.0159(4) Uani 1 1 d . . .
Cl1B Cl 0.1083(3) 0.63781(10) -0.4749(2) 0.0209(7) Uani 1 1 d . . .
Cl2B Cl 0.4583(3) 0.71030(9) -0.0451(2) 0.0172(6) Uani 1 1 d . . .
C1B C 0.0532(14) 0.6634(4) -0.2571(9) 0.019(3) Uani 1 1 d U . .
O1B O 0.0765(8) 0.6129(2) -0.0361(6) 0.0131(17) Uani 1 1 d U . .
N1B N 0.2637(11) 0.6401(3) -0.1088(7) 0.014(2) Uani 1 1 d U . .
O2B O 0.6366(9) 0.6877(3) -0.4832(6) 0.0183(19) Uani 1 1 d U . .
C2B C 0.0159(11) 0.6469(3) -0.1774(7) 0.005(2) Uani 1 1 d U . .
N2B N 0.4404(9) 0.6597(3) -0.4101(6) 0.0062(18) Uani 1 1 d U . .
C3B C -0.1434(12) 0.6482(3) -0.1589(8) 0.008(2) Uani 1 1 d U . .
C4B C -0.2068(14) 0.6642(4) -0.2430(9) 0.023(3) Uani 1 1 d U . .
H4B H -0.3099 0.6681 -0.2541 0.027 Uiso 1 1 calc R . .
C5B C -0.0897(13) 0.6736(4) -0.3087(9) 0.017(3) Uani 1 1 d U . .
H5B H -0.1000 0.6839 -0.3705 0.020 Uiso 1 1 calc R . .
C6B C 0.0563(14) 0.7522(4) -0.1693(9) 0.019(3) Uani 1 1 d U . .
H6B H 0.1422 0.7599 -0.2030 0.022 Uiso 1 1 calc R . .
C7B C 0.0556(16) 0.7333(4) -0.0803(11) 0.027(3) Uani 1 1 d U . .
H7B H 0.1389 0.7254 -0.0437 0.032 Uiso 1 1 calc R . .
C8B C -0.1004(14) 0.7286(4) -0.0580(9) 0.019(3) Uani 1 1 d U . .
H8B H -0.1368 0.7168 -0.0024 0.023 Uiso 1 1 calc R . .
C9B C -0.1913(14) 0.7442(4) -0.1308(9) 0.018(3) Uani 1 1 d U . .
H9B H -0.2968 0.7452 -0.1323 0.021 Uiso 1 1 calc R . .
C10B C -0.0948(14) 0.7579(4) -0.1993(9) 0.019(3) Uani 1 1 d U . .
H10B H -0.1245 0.7692 -0.2574 0.023 Uiso 1 1 calc R . .
C11B C -0.2315(14) 0.6341(4) -0.0777(9) 0.018(3) Uani 1 1 d U . .
H11D H -0.3242 0.6485 -0.0734 0.027 Uiso 1 1 calc R . .
H11E H -0.1740 0.6372 -0.0191 0.027 Uiso 1 1 calc R . .
H11F H -0.2544 0.6073 -0.0872 0.027 Uiso 1 1 calc R . .
C12B C 0.1253(12) 0.6345(3) -0.1026(8) 0.010(2) Uani 1 1 d U . .
C13B C 0.3375(13) 0.6177(4) -0.0337(8) 0.011(2) Uani 1 1 d U . .
H13B H 0.4123 0.6331 0.0020 0.014 Uiso 1 1 calc R . .
C14B C 0.2008(14) 0.6077(4) 0.0290(9) 0.017(3) Uani 1 1 d U . .
H14B H 0.2069 0.5802 0.0447 0.020 Uiso 1 1 calc R . .
C15B C 0.1791(14) 0.6297(4) 0.1236(9) 0.016(3) Uani 1 1 d U . .
C16B C 0.1841(15) 0.6105(4) 0.2059(9) 0.023(3) Uani 1 1 d U . .
H16B H 0.2044 0.5842 0.2067 0.028 Uiso 1 1 calc R . .
C17B C 0.1594(15) 0.6298(4) 0.2889(9) 0.024(3) Uani 1 1 d U . .
H17B H 0.1651 0.6168 0.3476 0.029 Uiso 1 1 calc R . .
C18B C 0.1270(15) 0.6672(4) 0.2877(10) 0.026(3) Uani 1 1 d U . .
H18B H 0.1078 0.6800 0.3454 0.031 Uiso 1 1 calc R . .
C19B C 0.1219(14) 0.6870(5) 0.2015(9) 0.024(3) Uani 1 1 d U . .
H19B H 0.0979 0.7131 0.2006 0.028 Uiso 1 1 calc R . .
C20B C 0.1517(17) 0.6685(5) 0.1190(10) 0.033(4) Uani 1 1 d U . .
H20B H 0.1537 0.6815 0.0603 0.039 Uiso 1 1 calc R . .
C21B C 0.4042(13) 0.5818(4) -0.0704(8) 0.015(3) Uani 1 1 d U . .
C22B C 0.5134(14) 0.5632(4) -0.0144(9) 0.020(3) Uani 1 1 d U . .
H22B H 0.5515 0.5747 0.0415 0.024 Uiso 1 1 calc R . .
C23B C 0.5639(16) 0.5277(4) -0.0423(11) 0.029(3) Uani 1 1 d U . .
H23B H 0.6403 0.5158 -0.0065 0.035 Uiso 1 1 calc R . .
C24B C 0.5061(17) 0.5095(5) -0.1208(11) 0.032(3) Uani 1 1 d U . .
H24B H 0.5411 0.4852 -0.1383 0.038 Uiso 1 1 calc R . .
C25B C 0.3959(16) 0.5272(4) -0.1736(10) 0.028(3) Uani 1 1 d U . .
H25B H 0.3524 0.5145 -0.2260 0.034 Uiso 1 1 calc R . .
C26B C 0.3485(15) 0.5633(4) -0.1509(10) 0.023(3) Uani 1 1 d U . .
H26B H 0.2776 0.5757 -0.1903 0.028 Uiso 1 1 calc R . .
C27B C 0.4425(14) 0.7256(4) -0.2680(9) 0.016(3) Uani 1 1 d U . .
C28B C 0.5313(12) 0.7211(3) -0.3537(8) 0.009(2) Uani 1 1 d U . .
C29B C 0.5974(14) 0.7577(4) -0.3767(9) 0.018(3) Uani 1 1 d U . .
C30B C 0.5507(14) 0.7826(4) -0.3070(8) 0.019(3) Uani 1 1 d U . .
H30B H 0.5787 0.8084 -0.3030 0.023 Uiso 1 1 calc R . .
C31B C 0.4554(13) 0.7640(4) -0.2426(9) 0.014(2) Uani 1 1 d U . .
H31B H 0.4076 0.7756 -0.1904 0.017 Uiso 1 1 calc R . .
C32B C 0.1502(15) 0.7528(4) -0.4107(10) 0.024(3) Uani 1 1 d U . .
H32B H 0.0842 0.7369 -0.3768 0.028 Uiso 1 1 calc R . .
C33B C 0.2367(14) 0.7420(4) -0.4877(9) 0.018(3) Uani 1 1 d U . .
H33B H 0.2381 0.7175 -0.5153 0.022 Uiso 1 1 calc R . .
C34B C 0.3210(16) 0.7729(4) -0.5179(10) 0.027(3) Uani 1 1 d U . .
H34B H 0.3908 0.7731 -0.5681 0.033 Uiso 1 1 calc R . .
C35B C 0.2821(15) 0.8038(4) -0.4593(10) 0.025(3) Uani 1 1 d U . .
H35B H 0.3201 0.8287 -0.4648 0.030 Uiso 1 1 calc R . .
C36B C 0.1778(16) 0.7917(4) -0.3915(11) 0.030(3) Uani 1 1 d U . .
H36B H 0.1346 0.8065 -0.3428 0.037 Uiso 1 1 calc R . .
C37B C 0.7043(15) 0.7673(4) -0.4543(9) 0.024(3) Uani 1 1 d U . .
H37D H 0.7077 0.7948 -0.4627 0.036 Uiso 1 1 calc R . .
H37E H 0.6714 0.7554 -0.5135 0.036 Uiso 1 1 calc R . .
H37F H 0.8035 0.7580 -0.4374 0.036 Uiso 1 1 calc R . .
C38B C 0.5320(13) 0.6886(4) -0.4147(8) 0.018(3) Uani 1 1 d U . .
C39B C 0.4812(13) 0.6350(4) -0.4952(9) 0.015(3) Uani 1 1 d U . .
H39B H 0.4039 0.6393 -0.5452 0.018 Uiso 1 1 calc R . .
C40B C 0.6267(14) 0.6511(4) -0.5319(9) 0.017(3) Uani 1 1 d U . .
H40B H 0.7109 0.6346 -0.5108 0.020 Uiso 1 1 calc R . .
C41B C 0.6345(13) 0.6567(4) -0.6363(8) 0.017(3) Uani 1 1 d U . .
C42B C 0.5313(14) 0.6783(4) -0.6839(9) 0.023(3) Uani 1 1 d U . .
H42B H 0.4538 0.6902 -0.6499 0.027 Uiso 1 1 calc R . .
C43B C 0.5399(17) 0.6826(5) -0.7795(10) 0.033(3) Uani 1 1 d U . .
H43B H 0.4677 0.6975 -0.8113 0.040 Uiso 1 1 calc R . .
C44B C 0.6508(16) 0.6657(5) -0.8309(10) 0.030(3) Uani 1 1 d U . .
H44B H 0.6529 0.6686 -0.8977 0.036 Uiso 1 1 calc R . .
C45B C 0.7599(19) 0.6445(5) -0.7854(11) 0.038(4) Uani 1 1 d U . .
H45B H 0.8405 0.6337 -0.8190 0.046 Uiso 1 1 calc R . .
C46B C 0.7445(15) 0.6398(4) -0.6873(10) 0.025(3) Uani 1 1 d U . .
H46B H 0.8137 0.6241 -0.6548 0.030 Uiso 1 1 calc R . .
C47B C 0.4834(16) 0.5940(4) -0.4747(10) 0.027(3) Uani 1 1 d U . .
C48B C 0.435(3) 0.5697(7) -0.5430(17) 0.065(6) Uani 1 1 d U . .
H48B H 0.3956 0.5799 -0.6000 0.078 Uiso 1 1 calc R . .
C49B C 0.441(3) 0.5309(7) -0.5334(16) 0.066(6) Uani 1 1 d U . .
H49B H 0.4010 0.5150 -0.5813 0.079 Uiso 1 1 calc R . .
C50B C 0.5055(19) 0.5156(5) -0.4547(13) 0.043(4) Uani 1 1 d U . .
H50B H 0.5140 0.4891 -0.4478 0.052 Uiso 1 1 calc R . .
C51B C 0.557(2) 0.5394(6) -0.3857(14) 0.054(5) Uani 1 1 d U . .
H51B H 0.6006 0.5291 -0.3299 0.065 Uiso 1 1 calc R . .
C52B C 0.548(2) 0.5790(5) -0.3954(12) 0.041(4) Uani 1 1 d U . .
H52B H 0.5869 0.5950 -0.3473 0.049 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1A C1A 2.024(12) . ?
Au1A N2A 2.112(10) . ?
Au1A Cl1A 2.405(3) . ?
Au1A Au2A 2.5106(6) . ?
Au2A C28A 2.033(11) . ?
Au2A N1A 2.098(10) . ?
Au2A Cl2A 2.389(3) . ?
Fe1A C2A 2.011(14) . ?
Fe1A C7A 2.021(15) . ?
Fe1A C4A 2.048(13) . ?
Fe1A C8A 2.051(15) . ?
Fe1A C3A 2.052(12) . ?
Fe1A C5A 2.056(13) . ?
Fe1A C9A 2.061(14) . ?
Fe1A C6A 2.060(13) . ?
Fe1A C1A 2.064(12) . ?
Fe1A C10A 2.069(15) . ?
Fe2A C27A 2.017(14) . ?
Fe2A C32A 2.037(15) . ?
Fe2A C28A 2.038(12) . ?
Fe2A C30A 2.050(12) . ?
Fe2A C36A 2.052(13) . ?
Fe2A C29A 2.056(13) . ?
Fe2A C33A 2.057(13) . ?
Fe2A C31A 2.052(12) . ?
Fe2A C34A 2.058(14) . ?
Fe2A C35A 2.066(12) . ?
O1A C12A 1.324(13) . ?
O1A C14A 1.457(17) . ?
N1A C12A 1.318(16) . ?
N1A C13A 1.485(15) . ?
C1A C5A 1.414(17) . ?
C1A C2A 1.428(16) . ?
O2A C38A 1.358(14) . ?
O2A C40A 1.474(14) . ?
N2A C38A 1.288(15) . ?
N2A C39A 1.474(15) . ?
C2A C12A 1.447(18) . ?
C2A C3A 1.451(18) . ?
C3A C4A 1.405(18) . ?
C3A C11A 1.497(17) . ?
C4A C5A 1.447(18) . ?
C4A H4A 0.9500 . ?
C5A H5A 0.9500 . ?
C6A C7A 1.37(2) . ?
C6A C10A 1.42(2) . ?
C6A H6A 0.9500 . ?
C7A C8A 1.40(2) . ?
C7A H7A 0.9500 . ?
C8A C9A 1.43(2) . ?
C8A H8A 0.9500 . ?
C9A C10A 1.41(2) . ?
C9A H9A 0.9500 . ?
C10A H10A 0.9500 . ?
C11A H11A 0.9800 . ?
C11A H11B 0.9800 . ?
C11A H11C 0.9800 . ?
C13A C21A 1.508(17) . ?
C13A C14A 1.556(18) . ?
C13A H13A 1.0000 . ?
C14A C15A 1.49(2) . ?
C14A H14A 1.0000 . ?
C15A C20A 1.38(2) . ?
C15A C16A 1.39(2) . ?
C16A C17A 1.41(2) . ?
C16A H16A 0.9500 . ?
C17A C18A 1.39(2) . ?
C17A H17A 0.9500 . ?
C18A C19A 1.35(3) . ?
C18A H18A 0.9500 . ?
C19A C20A 1.42(2) . ?
C19A H19A 0.9500 . ?
C20A H20A 0.9500 . ?
C21A C26A 1.37(2) . ?
C21A C22A 1.42(2) . ?
C22A C23A 1.40(2) . ?
C22A H22A 0.9500 . ?
C23A C24A 1.34(2) . ?
C23A H23A 0.9500 . ?
C24A C25A 1.38(2) . ?
C24A H24A 0.9500 . ?
C25A C26A 1.39(2) . ?
C25A H25A 0.9500 . ?
C26A H26A 0.9500 . ?
C27A C28A 1.417(17) . ?
C27A C38A 1.423(18) . ?
C27A C29A 1.464(17) . ?
C28A C31A 1.394(17) . ?
C29A C30A 1.408(17) . ?
C29A C37A 1.488(17) . ?
C30A C31A 1.423(16) . ?
C30A H30A 0.9500 . ?
C31A H31A 0.9500 . ?
C32A C33A 1.400(18) . ?
C32A C36A 1.406(19) . ?
C32A H32A 0.9500 . ?
C33A C34A 1.40(2) . ?
C33A H33A 0.9500 . ?
C34A C35A 1.466(18) . ?
C34A H34A 0.9500 . ?
C35A C36A 1.425(19) . ?
C35A H35A 0.9500 . ?
C36A H36A 0.9500 . ?
C37A H37A 0.9800 . ?
C37A H37B 0.9800 . ?
C37A H37C 0.9800 . ?
C39A C47A 1.494(17) . ?
C39A C40A 1.532(16) . ?
C39A H39A 1.0000 . ?
C40A C41A 1.584(18) . ?
C40A H40A 1.0000 . ?
C41A C46A 1.356(19) . ?
C41A C42A 1.36(2) . ?
C42A C43A 1.35(2) . ?
C42A H42A 0.9500 . ?
C43A C44A 1.40(2) . ?
C43A H43A 0.9500 . ?
C44A C45A 1.31(2) . ?
C44A H44A 0.9500 . ?
C45A C46A 1.40(2) . ?
C45A H45A 0.9500 . ?
C46A H46A 0.9500 . ?
C47A C48A 1.371(17) . ?
C47A C52A 1.426(18) . ?
C48A C49A 1.384(19) . ?
C48A H48A 0.9500 . ?
C49A C50A 1.38(2) . ?
C49A H49A 0.9500 . ?
C50A C51A 1.36(2) . ?
C50A H50A 0.9500 . ?
C51A C52A 1.41(2) . ?
C51A H51A 0.9500 . ?
C52A H52A 0.9500 . ?
Au1B C1B 2.049(13) . ?
Au1B N2B 2.073(8) . ?
Au1B Cl1B 2.388(3) . ?
Au1B Au2B 2.5057(6) . ?
Au2B C27B 1.991(13) . ?
Au2B N1B 2.118(10) . ?
Au2B Cl2B 2.406(3) . ?
Fe1B C1B 1.998(14) . ?
Fe1B C8B 2.028(13) . ?
Fe1B C2B 2.042(11) . ?
Fe1B C10B 2.048(14) . ?
Fe1B C3B 2.054(12) . ?
Fe1B C4B 2.061(13) . ?
Fe1B C9B 2.063(13) . ?
Fe1B C5B 2.069(13) . ?
Fe1B C7B 2.087(14) . ?
Fe1B C6B 2.089(13) . ?
Fe2B C29B 2.031(13) . ?
Fe2B C28B 2.038(12) . ?
Fe2B C30B 2.051(13) . ?
Fe2B C34B 2.051(14) . ?
Fe2B C35B 2.059(14) . ?
Fe2B C33B 2.059(13) . ?
Fe2B C32B 2.062(13) . ?
Fe2B C36B 2.070(15) . ?
Fe2B C31B 2.072(12) . ?
Fe2B C27B 2.104(13) . ?
C1B C2B 1.313(17) . ?
C1B C5B 1.519(17) . ?
O1B C12B 1.290(14) . ?
O1B C14B 1.456(14) . ?
N1B C12B 1.265(15) . ?
N1B C13B 1.479(15) . ?
O2B C38B 1.355(14) . ?
O2B C40B 1.473(15) . ?
C2B C3B 1.460(15) . ?
C2B C12B 1.506(15) . ?
N2B C38B 1.314(16) . ?
N2B C39B 1.533(15) . ?
C3B C4B 1.432(17) . ?
C3B C11B 1.485(16) . ?
C4B C5B 1.448(18) . ?
C4B H4B 0.9500 . ?
C5B H5B 0.9500 . ?
C6B C7B 1.43(2) . ?
C6B C10B 1.436(18) . ?
C6B H6B 0.9500 . ?
C7B C8B 1.451(19) . ?
C7B H7B 0.9500 . ?
C8B C9B 1.422(18) . ?
C8B H8B 0.9500 . ?
C9B C10B 1.392(18) . ?
C9B H9B 0.9500 . ?
C10B H10B 0.9500 . ?
C11B H11D 0.9800 . ?
C11B H11E 0.9800 . ?
C11B H11F 0.9800 . ?
C13B C21B 1.500(17) . ?
C13B C14B 1.562(16) . ?
C13B H13B 1.0000 . ?
C14B C15B 1.560(18) . ?
C14B H14B 1.0000 . ?
C15B C16B 1.346(18) . ?
C15B C20B 1.40(2) . ?
C16B C17B 1.38(2) . ?
C16B H16B 0.9500 . ?
C17B C18B 1.36(2) . ?
C17B H17B 0.9500 . ?
C18B C19B 1.406(19) . ?
C18B H18B 0.9500 . ?
C19B C20B 1.366(19) . ?
C19B H19B 0.9500 . ?
C20B H20B 0.9500 . ?
C21B C26B 1.402(19) . ?
C21B C22B 1.421(17) . ?
C22B C23B 1.39(2) . ?
C22B H22B 0.9500 . ?
C23B C24B 1.38(2) . ?
C23B H23B 0.9500 . ?
C24B C25B 1.39(2) . ?
C24B H24B 0.9500 . ?
C25B C26B 1.39(2) . ?
C25B H25B 0.9500 . ?
C26B H26B 0.9500 . ?
C27B C31B 1.413(18) . ?
C27B C28B 1.464(16) . ?
C28B C38B 1.441(18) . ?
C28B C29B 1.464(17) . ?
C29B C30B 1.390(18) . ?
C29B C37B 1.502(18) . ?
C30B C31B 1.417(17) . ?
C30B H30B 0.9500 . ?
C31B H31B 0.9500 . ?
C32B C33B 1.39(2) . ?
C32B C36B 1.43(2) . ?
C32B H32B 0.9500 . ?
C33B C34B 1.40(2) . ?
C33B H33B 0.9500 . ?
C34B C35B 1.42(2) . ?
C34B H34B 0.9500 . ?
C35B C36B 1.41(2) . ?
C35B H35B 0.9500 . ?
C36B H36B 0.9500 . ?
C37B H37D 0.9800 . ?
C37B H37E 0.9800 . ?
C37B H37F 0.9800 . ?
C39B C47B 1.48(2) . ?
C39B C40B 1.524(17) . ?
C39B H39B 1.0000 . ?
C40B C41B 1.490(17) . ?
C40B H40B 1.0000 . ?
C41B C46B 1.368(18) . ?
C41B C42B 1.374(18) . ?
C42B C43B 1.361(19) . ?
C42B H42B 0.9500 . ?
C43B C44B 1.38(2) . ?
C43B H43B 0.9500 . ?
C44B C45B 1.39(2) . ?
C44B H44B 0.9500 . ?
C45B C46B 1.40(2) . ?
C45B H45B 0.9500 . ?
C46B H46B 0.9500 . ?
C47B C48B 1.36(3) . ?
C47B C52B 1.37(2) . ?
C48B C49B 1.39(3) . ?
C48B H48B 0.9500 . ?
C49B C50B 1.36(3) . ?
C49B H49B 0.9500 . ?
C50B C51B 1.37(3) . ?
C50B H50B 0.9500 . ?
C51B C52B 1.41(3) . ?
C51B H51B 0.9500 . ?
C52B H52B 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1A Au1A N2A 178.4(5) . . ?
C1A Au1A Cl1A 92.9(4) . . ?
N2A Au1A Cl1A 88.6(3) . . ?
C1A Au1A Au2A 85.6(3) . . ?
N2A Au1A Au2A 92.9(3) . . ?
Cl1A Au1A Au2A 175.90(8) . . ?
C28A Au2A N1A 178.0(5) . . ?
C28A Au2A Cl2A 91.0(4) . . ?
N1A Au2A Cl2A 90.9(3) . . ?
C28A Au2A Au1A 84.9(3) . . ?
N1A Au2A Au1A 93.1(3) . . ?
Cl2A Au2A Au1A 174.53(9) . . ?
C2A Fe1A C7A 109.4(6) . . ?
C2A Fe1A C4A 69.0(5) . . ?
C7A Fe1A C4A 159.4(6) . . ?
C2A Fe1A C8A 120.0(6) . . ?
C7A Fe1A C8A 40.2(6) . . ?
C4A Fe1A C8A 121.5(6) . . ?
C2A Fe1A C3A 41.8(5) . . ?
C7A Fe1A C3A 125.1(6) . . ?
C4A Fe1A C3A 40.1(5) . . ?
C8A Fe1A C3A 104.9(5) . . ?
C2A Fe1A C5A 68.7(5) . . ?
C7A Fe1A C5A 158.8(6) . . ?
C4A Fe1A C5A 41.3(5) . . ?
C8A Fe1A C5A 159.7(6) . . ?
C3A Fe1A C5A 68.5(5) . . ?
C2A Fe1A C9A 155.0(5) . . ?
C7A Fe1A C9A 66.8(6) . . ?
C4A Fe1A C9A 105.4(6) . . ?
C8A Fe1A C9A 40.7(6) . . ?
C3A Fe1A C9A 118.3(5) . . ?
C5A Fe1A C9A 124.1(5) . . ?
C2A Fe1A C6A 127.1(6) . . ?
C7A Fe1A C6A 39.4(6) . . ?
C4A Fe1A C6A 157.2(5) . . ?
C8A Fe1A C6A 67.6(6) . . ?
C3A Fe1A C6A 162.7(5) . . ?
C5A Fe1A C6A 123.8(5) . . ?
C9A Fe1A C6A 66.9(5) . . ?
C2A Fe1A C1A 41.0(5) . . ?
C7A Fe1A C1A 124.5(6) . . ?
C4A Fe1A C1A 68.7(5) . . ?
C8A Fe1A C1A 157.3(6) . . ?
C3A Fe1A C1A 69.1(5) . . ?
C5A Fe1A C1A 40.2(5) . . ?
C9A Fe1A C1A 161.6(5) . . ?
C6A Fe1A C1A 111.5(5) . . ?
C2A Fe1A C10A 163.9(6) . . ?
C7A Fe1A C10A 67.0(6) . . ?
C4A Fe1A C10A 120.1(6) . . ?
C8A Fe1A C10A 68.2(6) . . ?
C3A Fe1A C10A 153.4(6) . . ?
C5A Fe1A C10A 108.6(6) . . ?
C9A Fe1A C10A 39.8(6) . . ?
C6A Fe1A C10A 40.3(6) . . ?
C1A Fe1A C10A 126.9(6) . . ?
C27A Fe2A C32A 165.0(5) . . ?
C27A Fe2A C28A 40.9(5) . . ?
C32A Fe2A C28A 127.8(5) . . ?
C27A Fe2A C30A 68.0(5) . . ?
C32A Fe2A C30A 120.5(5) . . ?
C28A Fe2A C30A 67.8(5) . . ?
C27A Fe2A C36A 153.7(5) . . ?
C32A Fe2A C36A 40.2(5) . . ?
C28A Fe2A C36A 162.0(5) . . ?
C30A Fe2A C36A 105.1(5) . . ?
C27A Fe2A C29A 42.1(5) . . ?
C32A Fe2A C29A 152.3(5) . . ?
C28A Fe2A C29A 69.8(5) . . ?
C30A Fe2A C29A 40.1(5) . . ?
C36A Fe2A C29A 116.2(5) . . ?
C27A Fe2A C33A 127.9(5) . . ?
C32A Fe2A C33A 40.0(5) . . ?
C28A Fe2A C33A 111.6(5) . . ?
C30A Fe2A C33A 156.6(5) . . ?
C36A Fe2A C33A 68.0(5) . . ?
C29A Fe2A C33A 163.2(5) . . ?
C27A Fe2A C31A 68.0(5) . . ?
C32A Fe2A C31A 109.6(5) . . ?
C28A Fe2A C31A 39.9(5) . . ?
C30A Fe2A C31A 40.6(4) . . ?
C36A Fe2A C31A 124.3(5) . . ?
C29A Fe2A C31A 68.9(5) . . ?
C33A Fe2A C31A 123.6(5) . . ?
C27A Fe2A C34A 109.1(5) . . ?
C32A Fe2A C34A 67.1(6) . . ?
C28A Fe2A C34A 123.5(5) . . ?
C30A Fe2A C34A 160.6(5) . . ?
C36A Fe2A C34A 68.5(5) . . ?
C29A Fe2A C34A 124.8(6) . . ?
C33A Fe2A C34A 39.7(5) . . ?
C31A Fe2A C34A 157.9(5) . . ?
C27A Fe2A C35A 120.0(5) . . ?
C32A Fe2A C35A 67.8(5) . . ?
C28A Fe2A C35A 157.3(5) . . ?
C30A Fe2A C35A 121.8(5) . . ?
C36A Fe2A C35A 40.5(5) . . ?
C29A Fe2A C35A 103.6(5) . . ?
C33A Fe2A C35A 68.4(5) . . ?
C31A Fe2A C35A 159.5(5) . . ?
C34A Fe2A C35A 41.6(5) . . ?
C12A O1A C14A 108.1(10) . . ?
C12A N1A C13A 105.8(9) . . ?
C12A N1A Au2A 123.2(8) . . ?
C13A N1A Au2A 124.5(7) . . ?
C5A C1A C2A 107.6(11) . . ?
C5A C1A Au1A 122.4(9) . . ?
C2A C1A Au1A 128.8(10) . . ?
C5A C1A Fe1A 69.6(7) . . ?
C2A C1A Fe1A 67.5(7) . . ?
Au1A C1A Fe1A 138.0(6) . . ?
C38A O2A C40A 106.3(9) . . ?
C38A N2A C39A 109.6(10) . . ?
C38A N2A Au1A 122.8(8) . . ?
C39A N2A Au1A 126.7(7) . . ?
C1A C2A C12A 127.3(12) . . ?
C1A C2A C3A 108.3(11) . . ?
C12A C2A C3A 124.4(11) . . ?
C1A C2A Fe1A 71.5(7) . . ?
C12A C2A Fe1A 121.7(9) . . ?
C3A C2A Fe1A 70.6(8) . . ?
C4A C3A C2A 107.3(11) . . ?
C4A C3A C11A 122.8(12) . . ?
C2A C3A C11A 129.8(12) . . ?
C4A C3A Fe1A 69.8(7) . . ?
C2A C3A Fe1A 67.6(7) . . ?
C11A C3A Fe1A 126.3(9) . . ?
C3A C4A C5A 108.4(12) . . ?
C3A C4A Fe1A 70.2(7) . . ?
C5A C4A Fe1A 69.7(7) . . ?
C3A C4A H4A 125.8 . . ?
C5A C4A H4A 125.8 . . ?
Fe1A C4A H4A 126.0 . . ?
C1A C5A C4A 108.3(11) . . ?
C1A C5A Fe1A 70.2(7) . . ?
C4A C5A Fe1A 69.0(7) . . ?
C1A C5A H5A 125.9 . . ?
C4A C5A H5A 125.9 . . ?
Fe1A C5A H5A 126.4 . . ?
C7A C6A C10A 107.7(13) . . ?
C7A C6A Fe1A 68.8(8) . . ?
C10A C6A Fe1A 70.2(8) . . ?
C7A C6A H6A 126.2 . . ?
C10A C6A H6A 126.2 . . ?
Fe1A C6A H6A 126.5 . . ?
C6A C7A C8A 111.1(14) . . ?
C6A C7A Fe1A 71.9(9) . . ?
C8A C7A Fe1A 71.1(9) . . ?
C6A C7A H7A 124.5 . . ?
C8A C7A H7A 124.5 . . ?
Fe1A C7A H7A 124.1 . . ?
C7A C8A C9A 105.3(13) . . ?
C7A C8A Fe1A 68.7(9) . . ?
C9A C8A Fe1A 70.0(8) . . ?
C7A C8A H8A 127.4 . . ?
C9A C8A H8A 127.4 . . ?
Fe1A C8A H8A 125.5 . . ?
C10A C9A C8A 109.1(13) . . ?
C10A C9A Fe1A 70.4(9) . . ?
C8A C9A Fe1A 69.3(8) . . ?
C10A C9A H9A 125.5 . . ?
C8A C9A H9A 125.5 . . ?
Fe1A C9A H9A 126.5 . . ?
C9A C10A C6A 106.9(14) . . ?
C9A C10A Fe1A 69.8(9) . . ?
C6A C10A Fe1A 69.5(8) . . ?
C9A C10A H10A 126.5 . . ?
C6A C10A H10A 126.5 . . ?
Fe1A C10A H10A 125.7 . . ?
C3A C11A H11A 109.5 . . ?
C3A C11A H11B 109.5 . . ?
H11A C11A H11B 109.5 . . ?
C3A C11A H11C 109.5 . . ?
H11A C11A H11C 109.5 . . ?
H11B C11A H11C 109.5 . . ?
N1A C12A O1A 117.4(10) . . ?
N1A C12A C2A 124.5(10) . . ?
O1A C12A C2A 118.1(10) . . ?
N1A C13A C21A 118.4(10) . . ?
N1A C13A C14A 103.9(10) . . ?
C21A C13A C14A 111.5(11) . . ?
N1A C13A H13A 107.6 . . ?
C21A C13A H13A 107.6 . . ?
C14A C13A H13A 107.6 . . ?
O1A C14A C15A 112.6(12) . . ?
O1A C14A C13A 102.5(11) . . ?
C15A C14A C13A 115.7(12) . . ?
O1A C14A H14A 108.6 . . ?
C15A C14A H14A 108.6 . . ?
C13A C14A H14A 108.6 . . ?
C20A C15A C16A 121.1(14) . . ?
C20A C15A C14A 117.0(14) . . ?
C16A C15A C14A 121.2(14) . . ?
C15A C16A C17A 121.7(15) . . ?
C15A C16A H16A 119.2 . . ?
C17A C16A H16A 119.2 . . ?
C18A C17A C16A 116.4(15) . . ?
C18A C17A H17A 121.8 . . ?
C16A C17A H17A 121.8 . . ?
C19A C18A C17A 121.8(15) . . ?
C19A C18A H18A 119.1 . . ?
C17A C18A H18A 119.1 . . ?
C18A C19A C20A 122.0(16) . . ?
C18A C19A H19A 119.0 . . ?
C20A C19A H19A 119.0 . . ?
C15A C20A C19A 116.9(15) . . ?
C15A C20A H20A 121.6 . . ?
C19A C20A H20A 121.6 . . ?
C26A C21A C22A 117.9(13) . . ?
C26A C21A C13A 120.7(12) . . ?
C22A C21A C13A 121.2(13) . . ?
C23A C22A C21A 120.4(15) . . ?
C23A C22A H22A 119.8 . . ?
C21A C22A H22A 119.8 . . ?
C24A C23A C22A 119.7(16) . . ?
C24A C23A H23A 120.1 . . ?
C22A C23A H23A 120.1 . . ?
C23A C24A C25A 120.8(17) . . ?
C23A C24A H24A 119.6 . . ?
C25A C24A H24A 119.6 . . ?
C24A C25A C26A 120.2(16) . . ?
C24A C25A H25A 119.9 . . ?
C26A C25A H25A 119.9 . . ?
C21A C26A C25A 120.8(15) . . ?
C21A C26A H26A 119.6 . . ?
C25A C26A H26A 119.6 . . ?
C28A C27A C38A 125.6(12) . . ?
C28A C27A C29A 108.8(11) . . ?
C38A C27A C29A 125.4(11) . . ?
C28A C27A Fe2A 70.4(8) . . ?
C38A C27A Fe2A 121.8(9) . . ?
C29A C27A Fe2A 70.4(8) . . ?
C31A C28A C27A 108.1(11) . . ?
C31A C28A Au2A 122.4(9) . . ?
C27A C28A Au2A 127.9(10) . . ?
C31A C28A Fe2A 70.6(7) . . ?
C27A C28A Fe2A 68.7(7) . . ?
Au2A C28A Fe2A 137.8(7) . . ?
C30A C29A C27A 104.8(10) . . ?
C30A C29A C37A 126.1(11) . . ?
C27A C29A C37A 129.1(11) . . ?
C30A C29A Fe2A 69.7(7) . . ?
C27A C29A Fe2A 67.5(7) . . ?
C37A C29A Fe2A 128.0(9) . . ?
C29A C30A C31A 110.3(11) . . ?
C29A C30A Fe2A 70.2(7) . . ?
C31A C30A Fe2A 69.8(7) . . ?
C29A C30A H30A 124.9 . . ?
C31A C30A H30A 124.9 . . ?
Fe2A C30A H30A 126.8 . . ?
C28A C31A C30A 108.1(11) . . ?
C28A C31A Fe2A 69.5(7) . . ?
C30A C31A Fe2A 69.6(7) . . ?
C28A C31A H31A 126.0 . . ?
C30A C31A H31A 126.0 . . ?
Fe2A C31A H31A 126.4 . . ?
C33A C32A C36A 109.8(13) . . ?
C33A C32A Fe2A 70.8(8) . . ?
C36A C32A Fe2A 70.4(8) . . ?
C33A C32A H32A 125.1 . . ?
C36A C32A H32A 125.1 . . ?
Fe2A C32A H32A 125.3 . . ?
C34A C33A C32A 108.1(12) . . ?
C34A C33A Fe2A 70.2(8) . . ?
C32A C33A Fe2A 69.2(8) . . ?
C34A C33A H33A 125.9 . . ?
C32A C33A H33A 125.9 . . ?
Fe2A C33A H33A 126.2 . . ?
C33A C34A C35A 108.0(12) . . ?
C33A C34A Fe2A 70.1(8) . . ?
C35A C34A Fe2A 69.5(7) . . ?
C33A C34A H34A 126.0 . . ?
C35A C34A H34A 126.0 . . ?
Fe2A C34A H34A 126.0 . . ?
C36A C35A C34A 106.2(11) . . ?
C36A C35A Fe2A 69.2(7) . . ?
C34A C35A Fe2A 68.9(7) . . ?
C36A C35A H35A 126.9 . . ?
C34A C35A H35A 126.9 . . ?
Fe2A C35A H35A 126.5 . . ?
C32A C36A C35A 107.8(12) . . ?
C32A C36A Fe2A 69.3(8) . . ?
C35A C36A Fe2A 70.3(7) . . ?
C32A C36A H36A 126.1 . . ?
C35A C36A H36A 126.1 . . ?
Fe2A C36A H36A 125.8 . . ?
C29A C37A H37A 109.5 . . ?
C29A C37A H37B 109.5 . . ?
H37A C37A H37B 109.5 . . ?
C29A C37A H37C 109.5 . . ?
H37A C37A H37C 109.5 . . ?
H37B C37A H37C 109.5 . . ?
N2A C38A O2A 114.6(10) . . ?
N2A C38A C27A 127.6(11) . . ?
O2A C38A C27A 117.8(10) . . ?
N2A C39A C47A 115.3(9) . . ?
N2A C39A C40A 101.7(9) . . ?
C47A C39A C40A 115.5(11) . . ?
N2A C39A H39A 108.0 . . ?
C47A C39A H39A 108.0 . . ?
C40A C39A H39A 108.0 . . ?
O2A C40A C39A 103.1(9) . . ?
O2A C40A C41A 110.1(10) . . ?
C39A C40A C41A 115.9(10) . . ?
O2A C40A H40A 109.1 . . ?
C39A C40A H40A 109.1 . . ?
C41A C40A H40A 109.1 . . ?
C46A C41A C42A 122.5(13) . . ?
C46A C41A C40A 118.6(12) . . ?
C42A C41A C40A 118.7(12) . . ?
C43A C42A C41A 119.5(15) . . ?
C43A C42A H42A 120.3 . . ?
C41A C42A H42A 120.3 . . ?
C42A C43A C44A 117.2(17) . . ?
C42A C43A H43A 121.4 . . ?
C44A C43A H43A 121.4 . . ?
C45A C44A C43A 123.9(16) . . ?
C45A C44A H44A 118.0 . . ?
C43A C44A H44A 118.0 . . ?
C44A C45A C46A 118.2(16) . . ?
C44A C45A H45A 120.9 . . ?
C46A C45A H45A 120.9 . . ?
C41A C46A C45A 118.4(15) . . ?
C41A C46A H46A 120.8 . . ?
C45A C46A H46A 120.8 . . ?
C48A C47A C52A 119.1(12) . . ?
C48A C47A C39A 123.9(11) . . ?
C52A C47A C39A 116.6(11) . . ?
C47A C48A C49A 121.9(13) . . ?
C47A C48A H48A 119.1 . . ?
C49A C48A H48A 119.1 . . ?
C50A C49A C48A 118.9(13) . . ?
C50A C49A H49A 120.6 . . ?
C48A C49A H49A 120.6 . . ?
C51A C50A C49A 121.4(14) . . ?
C51A C50A H50A 119.3 . . ?
C49A C50A H50A 119.3 . . ?
C50A C51A C52A 120.5(13) . . ?
C50A C51A H51A 119.7 . . ?
C52A C51A H51A 119.7 . . ?
C51A C52A C47A 117.9(13) . . ?
C51A C52A H52A 121.0 . . ?
C47A C52A H52A 121.0 . . ?
C1B Au1B N2B 174.2(4) . . ?
C1B Au1B Cl1B 93.8(4) . . ?
N2B Au1B Cl1B 92.0(2) . . ?
C1B Au1B Au2B 81.4(4) . . ?
N2B Au1B Au2B 92.8(2) . . ?
Cl1B Au1B Au2B 175.18(8) . . ?
C27B Au2B N1B 178.4(5) . . ?
C27B Au2B Cl2B 92.8(4) . . ?
N1B Au2B Cl2B 88.7(3) . . ?
C27B Au2B Au1B 86.7(4) . . ?
N1B Au2B Au1B 91.8(3) . . ?
Cl2B Au2B Au1B 176.52(8) . . ?
C1B Fe1B C8B 151.5(5) . . ?
C1B Fe1B C2B 37.9(5) . . ?
C8B Fe1B C2B 119.5(5) . . ?
C1B Fe1B C10B 132.2(5) . . ?
C8B Fe1B C10B 67.0(5) . . ?
C2B Fe1B C10B 168.4(5) . . ?
C1B Fe1B C3B 69.8(5) . . ?
C8B Fe1B C3B 103.7(5) . . ?
C2B Fe1B C3B 41.8(4) . . ?
C10B Fe1B C3B 149.1(5) . . ?
C1B Fe1B C4B 70.8(5) . . ?
C8B Fe1B C4B 123.1(5) . . ?
C2B Fe1B C4B 67.7(5) . . ?
C10B Fe1B C4B 118.0(5) . . ?
C3B Fe1B C4B 40.7(5) . . ?
C1B Fe1B C9B 167.6(5) . . ?
C8B Fe1B C9B 40.7(5) . . ?
C2B Fe1B C9B 151.5(5) . . ?
C10B Fe1B C9B 39.6(5) . . ?
C3B Fe1B C9B 114.1(5) . . ?
C4B Fe1B C9B 104.1(5) . . ?
C1B Fe1B C5B 43.8(5) . . ?
C8B Fe1B C5B 161.7(5) . . ?
C2B Fe1B C5B 67.5(4) . . ?
C10B Fe1B C5B 109.5(5) . . ?
C3B Fe1B C5B 69.6(5) . . ?
C4B Fe1B C5B 41.0(5) . . ?
C9B Fe1B C5B 125.1(5) . . ?
C1B Fe1B C7B 118.9(6) . . ?
C8B Fe1B C7B 41.3(5) . . ?
C2B Fe1B C7B 109.6(5) . . ?
C10B Fe1B C7B 68.3(6) . . ?
C3B Fe1B C7B 125.1(5) . . ?
C4B Fe1B C7B 161.9(6) . . ?
C9B Fe1B C7B 69.4(5) . . ?
C5B Fe1B C7B 156.1(5) . . ?
C1B Fe1B C6B 111.8(5) . . ?
C8B Fe1B C6B 67.2(5) . . ?
C2B Fe1B C6B 130.6(5) . . ?
C10B Fe1B C6B 40.6(5) . . ?
C3B Fe1B C6B 164.6(5) . . ?
C4B Fe1B C6B 154.7(5) . . ?
C9B Fe1B C6B 67.8(5) . . ?
C5B Fe1B C6B 122.9(5) . . ?
C7B Fe1B C6B 39.9(6) . . ?
C29B Fe2B C28B 42.2(5) . . ?
C29B Fe2B C30B 39.8(5) . . ?
C28B Fe2B C30B 67.9(5) . . ?
C29B Fe2B C34B 104.3(5) . . ?
C28B Fe2B C34B 117.9(5) . . ?
C30B Fe2B C34B 124.6(5) . . ?
C29B Fe2B C35B 116.1(6) . . ?
C28B Fe2B C35B 151.9(5) . . ?
C30B Fe2B C35B 107.4(6) . . ?
C34B Fe2B C35B 40.4(6) . . ?
C29B Fe2B C33B 125.7(5) . . ?
C28B Fe2B C33B 108.7(5) . . ?
C30B Fe2B C33B 161.9(5) . . ?
C34B Fe2B C33B 39.9(5) . . ?
C35B Fe2B C33B 66.7(5) . . ?
C29B Fe2B C32B 164.2(6) . . ?
C28B Fe2B C32B 128.4(5) . . ?
C30B Fe2B C32B 155.9(5) . . ?
C34B Fe2B C32B 67.3(6) . . ?
C35B Fe2B C32B 66.9(6) . . ?
C33B Fe2B C32B 39.6(5) . . ?
C29B Fe2B C36B 150.9(6) . . ?
C28B Fe2B C36B 166.4(6) . . ?
C30B Fe2B C36B 120.0(6) . . ?
C34B Fe2B C36B 68.2(6) . . ?
C35B Fe2B C36B 40.1(6) . . ?
C33B Fe2B C36B 67.3(6) . . ?
C32B Fe2B C36B 40.4(6) . . ?
C29B Fe2B C31B 68.3(5) . . ?
C28B Fe2B C31B 67.8(5) . . ?
C30B Fe2B C31B 40.2(5) . . ?
C34B Fe2B C31B 162.9(6) . . ?
C35B Fe2B C31B 127.5(5) . . ?
C33B Fe2B C31B 156.7(5) . . ?
C32B Fe2B C31B 123.4(5) . . ?
C36B Fe2B C31B 110.3(6) . . ?
C29B Fe2B C27B 70.0(5) . . ?
C28B Fe2B C27B 41.3(5) . . ?
C30B Fe2B C27B 67.6(5) . . ?
C34B Fe2B C27B 154.4(6) . . ?
C35B Fe2B C27B 164.7(5) . . ?
C33B Fe2B C27B 122.5(5) . . ?
C32B Fe2B C27B 111.3(5) . . ?
C36B Fe2B C27B 128.7(6) . . ?
C31B Fe2B C27B 39.6(5) . . ?
C2B C1B C5B 107.3(11) . . ?
C2B C1B Fe1B 72.9(8) . . ?
C5B C1B Fe1B 70.6(7) . . ?
C2B C1B Au1B 132.4(10) . . ?
C5B C1B Au1B 116.0(8) . . ?
Fe1B C1B Au1B 139.3(7) . . ?
C12B O1B C14B 105.7(9) . . ?
C12B N1B C13B 107.7(10) . . ?
C12B N1B Au2B 123.4(8) . . ?
C13B N1B Au2B 127.2(8) . . ?
C38B O2B C40B 108.2(10) . . ?
C1B C2B C3B 113.4(10) . . ?
C1B C2B C12B 124.1(10) . . ?
C3B C2B C12B 121.5(9) . . ?
C1B C2B Fe1B 69.2(8) . . ?
C3B C2B Fe1B 69.6(6) . . ?
C12B C2B Fe1B 120.5(8) . . ?
C38B N2B C39B 104.6(9) . . ?
C38B N2B Au1B 124.4(8) . . ?
C39B N2B Au1B 126.9(7) . . ?
C4B C3B C2B 104.5(10) . . ?
C4B C3B C11B 124.2(10) . . ?
C2B C3B C11B 131.2(10) . . ?
C4B C3B Fe1B 69.9(7) . . ?
C2B C3B Fe1B 68.7(6) . . ?
C11B C3B Fe1B 128.8(9) . . ?
C3B C4B C5B 109.6(10) . . ?
C3B C4B Fe1B 69.4(7) . . ?
C5B C4B Fe1B 69.8(7) . . ?
C3B C4B H4B 125.2 . . ?
C5B C4B H4B 125.2 . . ?
Fe1B C4B H4B 127.3 . . ?
C4B C5B C1B 104.8(10) . . ?
C4B C5B Fe1B 69.2(7) . . ?
C1B C5B Fe1B 65.6(7) . . ?
C4B C5B H5B 127.6 . . ?
C1B C5B H5B 127.6 . . ?
Fe1B C5B H5B 129.0 . . ?
C7B C6B C10B 108.4(12) . . ?
C7B C6B Fe1B 70.0(8) . . ?
C10B C6B Fe1B 68.1(7) . . ?
C7B C6B H6B 125.8 . . ?
C10B C6B H6B 125.8 . . ?
Fe1B C6B H6B 127.7 . . ?
C6B C7B C8B 104.8(12) . . ?
C6B C7B Fe1B 70.1(8) . . ?
C8B C7B Fe1B 67.2(7) . . ?
C6B C7B H7B 127.6 . . ?
C8B C7B H7B 127.6 . . ?
Fe1B C7B H7B 126.6 . . ?
C9B C8B C7B 110.6(12) . . ?
C9B C8B Fe1B 71.0(7) . . ?
C7B C8B Fe1B 71.6(8) . . ?
C9B C8B H8B 124.7 . . ?
C7B C8B H8B 124.7 . . ?
Fe1B C8B H8B 124.3 . . ?
C10B C9B C8B 106.2(11) . . ?
C10B C9B Fe1B 69.6(8) . . ?
C8B C9B Fe1B 68.3(7) . . ?
C10B C9B H9B 126.9 . . ?
C8B C9B H9B 126.9 . . ?
Fe1B C9B H9B 126.7 . . ?
C9B C10B C6B 110.0(12) . . ?
C9B C10B Fe1B 70.8(8) . . ?
C6B C10B Fe1B 71.3(8) . . ?
C9B C10B H10B 125.0 . . ?
C6B C10B H10B 125.0 . . ?
Fe1B C10B H10B 124.5 . . ?
C3B C11B H11D 109.5 . . ?
C3B C11B H11E 109.5 . . ?
H11D C11B H11E 109.5 . . ?
C3B C11B H11F 109.5 . . ?
H11D C11B H11F 109.5 . . ?
H11E C11B H11F 109.5 . . ?
N1B C12B O1B 118.9(10) . . ?
N1B C12B C2B 123.0(10) . . ?
O1B C12B C2B 117.4(10) . . ?
N1B C13B C21B 112.7(10) . . ?
N1B C13B C14B 100.2(9) . . ?
C21B C13B C14B 108.8(10) . . ?
N1B C13B H13B 111.5 . . ?
C21B C13B H13B 111.5 . . ?
C14B C13B H13B 111.5 . . ?
O1B C14B C15B 112.2(10) . . ?
O1B C14B C13B 102.6(9) . . ?
C15B C14B C13B 118.5(11) . . ?
O1B C14B H14B 107.7 . . ?
C15B C14B H14B 107.7 . . ?
C13B C14B H14B 107.7 . . ?
C16B C15B C20B 122.7(13) . . ?
C16B C15B C14B 119.0(12) . . ?
C20B C15B C14B 118.3(12) . . ?
C15B C16B C17B 118.7(14) . . ?
C15B C16B H16B 120.6 . . ?
C17B C16B H16B 120.6 . . ?
C18B C17B C16B 120.7(13) . . ?
C18B C17B H17B 119.6 . . ?
C16B C17B H17B 119.6 . . ?
C17B C18B C19B 120.2(13) . . ?
C17B C18B H18B 119.9 . . ?
C19B C18B H18B 119.9 . . ?
C20B C19B C18B 119.5(15) . . ?
C20B C19B H19B 120.2 . . ?
C18B C19B H19B 120.2 . . ?
C19B C20B C15B 118.0(14) . . ?
C19B C20B H20B 121.0 . . ?
C15B C20B H20B 121.0 . . ?
C26B C21B C22B 118.5(13) . . ?
C26B C21B C13B 122.3(11) . . ?
C22B C21B C13B 118.6(11) . . ?
C23B C22B C21B 119.2(13) . . ?
C23B C22B H22B 120.4 . . ?
C21B C22B H22B 120.4 . . ?
C24B C23B C22B 121.8(14) . . ?
C24B C23B H23B 119.1 . . ?
C22B C23B H23B 119.1 . . ?
C23B C24B C25B 118.9(15) . . ?
C23B C24B H24B 120.6 . . ?
C25B C24B H24B 120.6 . . ?
C24B C25B C26B 120.9(14) . . ?
C24B C25B H25B 119.5 . . ?
C26B C25B H25B 119.5 . . ?
C25B C26B C21B 120.6(13) . . ?
C25B C26B H26B 119.7 . . ?
C21B C26B H26B 119.7 . . ?
C31B C27B C28B 105.6(11) . . ?
C31B C27B Au2B 126.6(9) . . ?
C28B C27B Au2B 126.6(9) . . ?
C31B C27B Fe2B 69.0(7) . . ?
C28B C27B Fe2B 66.9(7) . . ?
Au2B C27B Fe2B 137.6(6) . . ?
C38B C28B C29B 125.0(11) . . ?
C38B C28B C27B 125.8(11) . . ?
C29B C28B C27B 108.2(11) . . ?
C38B C28B Fe2B 116.9(8) . . ?
C29B C28B Fe2B 68.6(7) . . ?
C27B C28B Fe2B 71.7(7) . . ?
C30B C29B C28B 106.2(11) . . ?
C30B C29B C37B 124.9(13) . . ?
C28B C29B C37B 128.7(12) . . ?
C30B C29B Fe2B 70.9(8) . . ?
C28B C29B Fe2B 69.2(7) . . ?
C37B C29B Fe2B 128.2(9) . . ?
C29B C30B C31B 110.3(12) . . ?
C29B C30B Fe2B 69.3(8) . . ?
C31B C30B Fe2B 70.7(7) . . ?
C29B C30B H30B 124.9 . . ?
C31B C30B H30B 124.9 . . ?
Fe2B C30B H30B 126.8 . . ?
C27B C31B C30B 109.6(11) . . ?
C27B C31B Fe2B 71.5(7) . . ?
C30B C31B Fe2B 69.1(7) . . ?
C27B C31B H31B 125.2 . . ?
C30B C31B H31B 125.2 . . ?
Fe2B C31B H31B 125.8 . . ?
C33B C32B C36B 108.4(13) . . ?
C33B C32B Fe2B 70.1(8) . . ?
C36B C32B Fe2B 70.1(8) . . ?
C33B C32B H32B 125.8 . . ?
C36B C32B H32B 125.8 . . ?
Fe2B C32B H32B 125.6 . . ?
C32B C33B C34B 109.3(13) . . ?
C32B C33B Fe2B 70.3(8) . . ?
C34B C33B Fe2B 69.7(8) . . ?
C32B C33B H33B 125.4 . . ?
C34B C33B H33B 125.4 . . ?
Fe2B C33B H33B 126.1 . . ?
C33B C34B C35B 106.8(13) . . ?
C33B C34B Fe2B 70.4(8) . . ?
C35B C34B Fe2B 70.1(8) . . ?
C33B C34B H34B 126.6 . . ?
C35B C34B H34B 126.6 . . ?
Fe2B C34B H34B 124.5 . . ?
C36B C35B C34B 109.2(13) . . ?
C36B C35B Fe2B 70.4(8) . . ?
C34B C35B Fe2B 69.5(8) . . ?
C36B C35B H35B 125.4 . . ?
C34B C35B H35B 125.4 . . ?
Fe2B C35B H35B 126.3 . . ?
C35B C36B C32B 106.3(14) . . ?
C35B C36B Fe2B 69.6(8) . . ?
C32B C36B Fe2B 69.5(8) . . ?
C35B C36B H36B 126.9 . . ?
C32B C36B H36B 126.9 . . ?
Fe2B C36B H36B 125.6 . . ?
C29B C37B H37D 109.5 . . ?
C29B C37B H37E 109.5 . . ?
H37D C37B H37E 109.5 . . ?
C29B C37B H37F 109.5 . . ?
H37D C37B H37F 109.5 . . ?
H37E C37B H37F 109.5 . . ?
N2B C38B O2B 117.3(11) . . ?
N2B C38B C28B 126.0(11) . . ?
O2B C38B C28B 116.7(11) . . ?
C47B C39B C40B 115.0(11) . . ?
C47B C39B N2B 114.2(10) . . ?
C40B C39B N2B 105.3(10) . . ?
C47B C39B H39B 107.3 . . ?
C40B C39B H39B 107.3 . . ?
N2B C39B H39B 107.3 . . ?
O2B C40B C41B 110.0(10) . . ?
O2B C40B C39B 102.7(10) . . ?
C41B C40B C39B 115.7(10) . . ?
O2B C40B H40B 109.4 . . ?
C41B C40B H40B 109.4 . . ?
C39B C40B H40B 109.4 . . ?
C46B C41B C42B 118.4(12) . . ?
C46B C41B C40B 120.1(12) . . ?
C42B C41B C40B 121.5(11) . . ?
C43B C42B C41B 120.3(13) . . ?
C43B C42B H42B 119.9 . . ?
C41B C42B H42B 119.9 . . ?
C42B C43B C44B 121.4(15) . . ?
C42B C43B H43B 119.3 . . ?
C44B C43B H43B 119.3 . . ?
C43B C44B C45B 120.3(14) . . ?
C43B C44B H44B 119.9 . . ?
C45B C44B H44B 119.9 . . ?
C44B C45B C46B 116.5(14) . . ?
C44B C45B H45B 121.7 . . ?
C46B C45B H45B 121.7 . . ?
C41B C46B C45B 123.0(14) . . ?
C41B C46B H46B 118.5 . . ?
C45B C46B H46B 118.5 . . ?
C48B C47B C52B 117.7(17) . . ?
C48B C47B C39B 118.5(16) . . ?
C52B C47B C39B 123.2(15) . . ?
C47B C48B C49B 123(2) . . ?
C47B C48B H48B 118.4 . . ?
C49B C48B H48B 118.4 . . ?
C50B C49B C48B 119(2) . . ?
C50B C49B H49B 120.3 . . ?
C48B C49B H49B 120.3 . . ?
C49B C50B C51B 119(2) . . ?
C49B C50B H50B 120.7 . . ?
C51B C50B H50B 120.7 . . ?
C50B C51B C52B 121.5(19) . . ?
C50B C51B H51B 119.2 . . ?
C52B C51B H51B 119.2 . . ?
C47B C52B C51B 119.5(17) . . ?
C47B C52B H52B 120.3 . . ?
C51B C52B H52B 120.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1A Au1A Au2A C28A -127.4(5) . . . . ?
N2A Au1A Au2A C28A 52.7(5) . . . . ?
Cl1A Au1A Au2A C28A -58.6(11) . . . . ?
C1A Au1A Au2A N1A 52.3(5) . . . . ?
N2A Au1A Au2A N1A -127.6(4) . . . . ?
Cl1A Au1A Au2A N1A 121.1(11) . . . . ?
C1A Au1A Au2A Cl2A -85.4(10) . . . . ?
N2A Au1A Au2A Cl2A 94.8(10) . . . . ?
Cl1A Au1A Au2A Cl2A -16.6(14) . . . . ?
C28A Au2A N1A C12A -46(15) . . . . ?
Cl2A Au2A N1A C12A 120.6(9) . . . . ?
Au1A Au2A N1A C12A -55.7(9) . . . . ?
C28A Au2A N1A C13A 166(14) . . . . ?
Cl2A Au2A N1A C13A -26.7(9) . . . . ?
Au1A Au2A N1A C13A 156.9(9) . . . . ?
N2A Au1A C1A C5A 148(16) . . . . ?
Cl1A Au1A C1A C5A -32.8(10) . . . . ?
Au2A Au1A C1A C5A 143.4(10) . . . . ?
N2A Au1A C1A C2A -46(17) . . . . ?
Cl1A Au1A C1A C2A 133.1(11) . . . . ?
Au2A Au1A C1A C2A -50.8(11) . . . . ?
N2A Au1A C1A Fe1A 53(17) . . . . ?
Cl1A Au1A C1A Fe1A -127.8(9) . . . . ?
Au2A Au1A C1A Fe1A 48.3(9) . . . . ?
C2A Fe1A C1A C5A 120.2(10) . . . . ?
C7A Fe1A C1A C5A -159.9(8) . . . . ?
C4A Fe1A C1A C5A 38.0(7) . . . . ?
C8A Fe1A C1A C5A 159.5(13) . . . . ?
C3A Fe1A C1A C5A 81.1(8) . . . . ?
C9A Fe1A C1A C5A -36.3(19) . . . . ?
C6A Fe1A C1A C5A -117.5(8) . . . . ?
C10A Fe1A C1A C5A -74.3(9) . . . . ?
C7A Fe1A C1A C2A 79.9(10) . . . . ?
C4A Fe1A C1A C2A -82.2(8) . . . . ?
C8A Fe1A C1A C2A 39.3(17) . . . . ?
C3A Fe1A C1A C2A -39.1(8) . . . . ?
C5A Fe1A C1A C2A -120.2(10) . . . . ?
C9A Fe1A C1A C2A -156.5(15) . . . . ?
C6A Fe1A C1A C2A 122.3(8) . . . . ?
C10A Fe1A C1A C2A 165.5(8) . . . . ?
C2A Fe1A C1A Au1A -123.6(13) . . . . ?
C7A Fe1A C1A Au1A -43.7(12) . . . . ?
C4A Fe1A C1A Au1A 154.3(11) . . . . ?
C8A Fe1A C1A Au1A -84.3(16) . . . . ?
C3A Fe1A C1A Au1A -162.7(11) . . . . ?
C5A Fe1A C1A Au1A 116.2(12) . . . . ?
C9A Fe1A C1A Au1A 80(2) . . . . ?
C6A Fe1A C1A Au1A -1.2(11) . . . . ?
C10A Fe1A C1A Au1A 41.9(13) . . . . ?
C1A Au1A N2A C38A -55(17) . . . . ?
Cl1A Au1A N2A C38A 125.7(9) . . . . ?
Au2A Au1A N2A C38A -50.5(9) . . . . ?
C1A Au1A N2A C39A 138(16) . . . . ?
Cl1A Au1A N2A C39A -41.6(9) . . . . ?
Au2A Au1A N2A C39A 142.2(9) . . . . ?
C5A C1A C2A C12A -174.4(12) . . . . ?
Au1A C1A C2A C12A 18(2) . . . . ?
Fe1A C1A C2A C12A -116.2(14) . . . . ?
C5A C1A C2A C3A 3.1(15) . . . . ?
Au1A C1A C2A C3A -164.3(9) . . . . ?
Fe1A C1A C2A C3A 61.3(9) . . . . ?
C5A C1A C2A Fe1A -58.2(9) . . . . ?
Au1A C1A C2A Fe1A 134.3(10) . . . . ?
C7A Fe1A C2A C1A -120.7(8) . . . . ?
C4A Fe1A C2A C1A 81.2(8) . . . . ?
C8A Fe1A C2A C1A -163.6(8) . . . . ?
C3A Fe1A C2A C1A 118.0(11) . . . . ?
C5A Fe1A C2A C1A 36.8(7) . . . . ?
C9A Fe1A C2A C1A 162.7(12) . . . . ?
C6A Fe1A C2A C1A -80.3(9) . . . . ?
C10A Fe1A C2A C1A -46(2) . . . . ?
C7A Fe1A C2A C12A 2.3(12) . . . . ?
C4A Fe1A C2A C12A -155.9(12) . . . . ?
C8A Fe1A C2A C12A -40.7(12) . . . . ?
C3A Fe1A C2A C12A -119.1(13) . . . . ?
C5A Fe1A C2A C12A 159.7(12) . . . . ?
C9A Fe1A C2A C12A -74.4(18) . . . . ?
C6A Fe1A C2A C12A 42.7(13) . . . . ?
C1A Fe1A C2A C12A 123.0(14) . . . . ?
C10A Fe1A C2A C12A 76(2) . . . . ?
C7A Fe1A C2A C3A 121.3(8) . . . . ?
C4A Fe1A C2A C3A -36.8(7) . . . . ?
C8A Fe1A C2A C3A 78.4(9) . . . . ?
C5A Fe1A C2A C3A -81.2(8) . . . . ?
C9A Fe1A C2A C3A 44.7(16) . . . . ?
C6A Fe1A C2A C3A 161.8(7) . . . . ?
C1A Fe1A C2A C3A -118.0(11) . . . . ?
C10A Fe1A C2A C3A -164.5(19) . . . . ?
C1A C2A C3A C4A -3.2(15) . . . . ?
C12A C2A C3A C4A 174.4(12) . . . . ?
Fe1A C2A C3A C4A 58.7(9) . . . . ?
C1A C2A C3A C11A 178.8(13) . . . . ?
C12A C2A C3A C11A -4(2) . . . . ?
Fe1A C2A C3A C11A -119.3(14) . . . . ?
C1A C2A C3A Fe1A -61.9(9) . . . . ?
C12A C2A C3A Fe1A 115.8(13) . . . . ?
C2A Fe1A C3A C4A -119.7(11) . . . . ?
C7A Fe1A C3A C4A 160.5(8) . . . . ?
C8A Fe1A C3A C4A 121.7(8) . . . . ?
C5A Fe1A C3A C4A -38.1(8) . . . . ?
C9A Fe1A C3A C4A 80.1(9) . . . . ?
C6A Fe1A C3A C4A -176.6(16) . . . . ?
C1A Fe1A C3A C4A -81.3(8) . . . . ?
C10A Fe1A C3A C4A 50.8(15) . . . . ?
C7A Fe1A C3A C2A -79.9(9) . . . . ?
C4A Fe1A C3A C2A 119.7(11) . . . . ?
C8A Fe1A C3A C2A -118.7(8) . . . . ?
C5A Fe1A C3A C2A 81.5(8) . . . . ?
C9A Fe1A C3A C2A -160.2(7) . . . . ?
C6A Fe1A C3A C2A -57(2) . . . . ?
C1A Fe1A C3A C2A 38.3(7) . . . . ?
C10A Fe1A C3A C2A 170.5(12) . . . . ?
C2A Fe1A C3A C11A 123.8(15) . . . . ?
C7A Fe1A C3A C11A 44.0(14) . . . . ?
C4A Fe1A C3A C11A -116.5(15) . . . . ?
C8A Fe1A C3A C11A 5.2(13) . . . . ?
C5A Fe1A C3A C11A -154.6(13) . . . . ?
C9A Fe1A C3A C11A -36.4(14) . . . . ?
C6A Fe1A C3A C11A 67(2) . . . . ?
C1A Fe1A C3A C11A 162.2(13) . . . . ?
C10A Fe1A C3A C11A -65.7(18) . . . . ?
C2A C3A C4A C5A 2.1(14) . . . . ?
C11A C3A C4A C5A -179.8(12) . . . . ?
Fe1A C3A C4A C5A 59.3(9) . . . . ?
C2A C3A C4A Fe1A -57.3(9) . . . . ?
C11A C3A C4A Fe1A 120.8(13) . . . . ?
C2A Fe1A C4A C3A 38.4(8) . . . . ?
C7A Fe1A C4A C3A -51(2) . . . . ?
C8A Fe1A C4A C3A -74.8(9) . . . . ?
C5A Fe1A C4A C3A 119.5(11) . . . . ?
C9A Fe1A C4A C3A -115.9(8) . . . . ?
C6A Fe1A C4A C3A 177.4(13) . . . . ?
C1A Fe1A C4A C3A 82.5(8) . . . . ?
C10A Fe1A C4A C3A -156.3(8) . . . . ?
C2A Fe1A C4A C5A -81.1(8) . . . . ?
C7A Fe1A C4A C5A -170.7(16) . . . . ?
C8A Fe1A C4A C5A 165.7(8) . . . . ?
C3A Fe1A C4A C5A -119.5(11) . . . . ?
C9A Fe1A C4A C5A 124.6(8) . . . . ?
C6A Fe1A C4A C5A 57.9(17) . . . . ?
C1A Fe1A C4A C5A -37.0(7) . . . . ?
C10A Fe1A C4A C5A 84.2(9) . . . . ?
C2A C1A C5A C4A -1.9(14) . . . . ?
Au1A C1A C5A C4A 166.6(9) . . . . ?
Fe1A C1A C5A C4A -58.8(9) . . . . ?
C2A C1A C5A Fe1A 56.9(9) . . . . ?
Au1A C1A C5A Fe1A -134.7(9) . . . . ?
C3A C4A C5A C1A -0.2(14) . . . . ?
Fe1A C4A C5A C1A 59.5(9) . . . . ?
C3A C4A C5A Fe1A -59.7(9) . . . . ?
C2A Fe1A C5A C1A -37.5(7) . . . . ?
C7A Fe1A C5A C1A 51.3(18) . . . . ?
C4A Fe1A C5A C1A -119.6(10) . . . . ?
C8A Fe1A C5A C1A -157.0(14) . . . . ?
C3A Fe1A C5A C1A -82.6(8) . . . . ?
C9A Fe1A C5A C1A 167.0(7) . . . . ?
C6A Fe1A C5A C1A 83.6(9) . . . . ?
C10A Fe1A C5A C1A 125.6(8) . . . . ?
C2A Fe1A C5A C4A 82.1(8) . . . . ?
C7A Fe1A C5A C4A 170.9(15) . . . . ?
C8A Fe1A C5A C4A -37.4(18) . . . . ?
C3A Fe1A C5A C4A 37.0(8) . . . . ?
C9A Fe1A C5A C4A -73.4(9) . . . . ?
C6A Fe1A C5A C4A -156.7(8) . . . . ?
C1A Fe1A C5A C4A 119.6(10) . . . . ?
C10A Fe1A C5A C4A -114.8(8) . . . . ?
C2A Fe1A C6A C7A -74.7(11) . . . . ?
C4A Fe1A C6A C7A 155.5(14) . . . . ?
C8A Fe1A C6A C7A 36.8(9) . . . . ?
C3A Fe1A C6A C7A -30(2) . . . . ?
C5A Fe1A C6A C7A -162.2(9) . . . . ?
C9A Fe1A C6A C7A 81.1(10) . . . . ?
C1A Fe1A C6A C7A -118.7(9) . . . . ?
C10A Fe1A C6A C7A 119.1(13) . . . . ?
C2A Fe1A C6A C10A 166.2(8) . . . . ?
C7A Fe1A C6A C10A -119.1(13) . . . . ?
C4A Fe1A C6A C10A 36.4(18) . . . . ?
C8A Fe1A C6A C10A -82.3(10) . . . . ?
C3A Fe1A C6A C10A -149.3(17) . . . . ?
C5A Fe1A C6A C10A 78.7(10) . . . . ?
C9A Fe1A C6A C10A -38.0(9) . . . . ?
C1A Fe1A C6A C10A 122.2(9) . . . . ?
C10A C6A C7A C8A -0.9(17) . . . . ?
Fe1A C6A C7A C8A -60.6(11) . . . . ?
C10A C6A C7A Fe1A 59.6(10) . . . . ?
C2A Fe1A C7A C6A 125.3(9) . . . . ?
C4A Fe1A C7A C6A -152.8(15) . . . . ?
C8A Fe1A C7A C6A -120.8(13) . . . . ?
C3A Fe1A C7A C6A 169.4(8) . . . . ?
C5A Fe1A C7A C6A 44(2) . . . . ?
C9A Fe1A C7A C6A -81.3(9) . . . . ?
C1A Fe1A C7A C6A 82.1(10) . . . . ?
C10A Fe1A C7A C6A -37.8(9) . . . . ?
C2A Fe1A C7A C8A -113.9(9) . . . . ?
C4A Fe1A C7A C8A -32(2) . . . . ?
C3A Fe1A C7A C8A -69.8(11) . . . . ?
C5A Fe1A C7A C8A 165.2(14) . . . . ?
C9A Fe1A C7A C8A 39.5(9) . . . . ?
C6A Fe1A C7A C8A 120.8(13) . . . . ?
C1A Fe1A C7A C8A -157.1(8) . . . . ?
C10A Fe1A C7A C8A 82.9(10) . . . . ?
C6A C7A C8A C9A 0.1(17) . . . . ?
Fe1A C7A C8A C9A -60.9(10) . . . . ?
C6A C7A C8A Fe1A 61.0(11) . . . . ?
C2A Fe1A C8A C7A 84.9(10) . . . . ?
C4A Fe1A C8A C7A 167.4(9) . . . . ?
C3A Fe1A C8A C7A 127.4(9) . . . . ?
C5A Fe1A C8A C7A -164.5(14) . . . . ?
C9A Fe1A C8A C7A -116.3(12) . . . . ?
C6A Fe1A C8A C7A -36.1(9) . . . . ?
C1A Fe1A C8A C7A 56.2(17) . . . . ?
C10A Fe1A C8A C7A -79.7(10) . . . . ?
C2A Fe1A C8A C9A -158.9(8) . . . . ?
C7A Fe1A C8A C9A 116.3(12) . . . . ?
C4A Fe1A C8A C9A -76.4(9) . . . . ?
C3A Fe1A C8A C9A -116.4(8) . . . . ?
C5A Fe1A C8A C9A -48.3(19) . . . . ?
C6A Fe1A C8A C9A 80.1(9) . . . . ?
C1A Fe1A C8A C9A 172.5(12) . . . . ?
C10A Fe1A C8A C9A 36.5(8) . . . . ?
C7A C8A C9A C10A 0.8(16) . . . . ?
Fe1A C8A C9A C10A -59.3(10) . . . . ?
C7A C8A C9A Fe1A 60.1(10) . . . . ?
C2A Fe1A C9A C10A 167.8(12) . . . . ?
C7A Fe1A C9A C10A 81.4(10) . . . . ?
C4A Fe1A C9A C10A -118.8(9) . . . . ?
C8A Fe1A C9A C10A 120.4(12) . . . . ?
C3A Fe1A C9A C10A -160.0(9) . . . . ?
C5A Fe1A C9A C10A -77.8(10) . . . . ?
C6A Fe1A C9A C10A 38.4(9) . . . . ?
C1A Fe1A C9A C10A -50(2) . . . . ?
C2A Fe1A C9A C8A 47.5(16) . . . . ?
C7A Fe1A C9A C8A -39.0(9) . . . . ?
C4A Fe1A C9A C8A 120.8(8) . . . . ?
C3A Fe1A C9A C8A 79.7(9) . . . . ?
C5A Fe1A C9A C8A 161.8(8) . . . . ?
C6A Fe1A C9A C8A -82.0(9) . . . . ?
C1A Fe1A C9A C8A -170.8(15) . . . . ?
C10A Fe1A C9A C8A -120.4(12) . . . . ?
C8A C9A C10A C6A -1.3(16) . . . . ?
Fe1A C9A C10A C6A -59.9(10) . . . . ?
C8A C9A C10A Fe1A 58.6(10) . . . . ?
C7A C6A C10A C9A 1.4(16) . . . . ?
Fe1A C6A C10A C9A 60.1(10) . . . . ?
C7A C6A C10A Fe1A -58.7(10) . . . . ?
C2A Fe1A C10A C9A -161.2(18) . . . . ?
C7A Fe1A C10A C9A -80.9(10) . . . . ?
C4A Fe1A C10A C9A 77.5(10) . . . . ?
C8A Fe1A C10A C9A -37.3(9) . . . . ?
C3A Fe1A C10A C9A 42.3(17) . . . . ?
C5A Fe1A C10A C9A 121.4(9) . . . . ?
C6A Fe1A C10A C9A -117.9(13) . . . . ?
C1A Fe1A C10A C9A 162.3(8) . . . . ?
C2A Fe1A C10A C6A -43(2) . . . . ?
C7A Fe1A C10A C6A 37.0(8) . . . . ?
C4A Fe1A C10A C6A -164.6(8) . . . . ?
C8A Fe1A C10A C6A 80.6(9) . . . . ?
C3A Fe1A C10A C6A 160.2(11) . . . . ?
C5A Fe1A C10A C6A -120.7(8) . . . . ?
C9A Fe1A C10A C6A 117.9(13) . . . . ?
C1A Fe1A C10A C6A -79.8(10) . . . . ?
C13A N1A C12A O1A -6.7(14) . . . . ?
Au2A N1A C12A O1A -159.2(8) . . . . ?
C13A N1A C12A C2A 174.1(11) . . . . ?
Au2A N1A C12A C2A 21.6(16) . . . . ?
C14A O1A C12A N1A -3.8(14) . . . . ?
C14A O1A C12A C2A 175.5(11) . . . . ?
C1A C2A C12A N1A 9(2) . . . . ?
C3A C2A C12A N1A -168.4(12) . . . . ?
Fe1A C2A C12A N1A -81.3(14) . . . . ?
C1A C2A C12A O1A -170.4(12) . . . . ?
C3A C2A C12A O1A 12.4(19) . . . . ?
Fe1A C2A C12A O1A 99.5(12) . . . . ?
C12A N1A C13A C21A 137.5(11) . . . . ?
Au2A N1A C13A C21A -70.5(13) . . . . ?
C12A N1A C13A C14A 13.4(13) . . . . ?
Au2A N1A C13A C14A 165.4(8) . . . . ?
C12A O1A C14A C15A 136.7(11) . . . . ?
C12A O1A C14A C13A 11.8(13) . . . . ?
N1A C13A C14A O1A -15.0(13) . . . . ?
C21A C13A C14A O1A -143.5(11) . . . . ?
N1A C13A C14A C15A -137.9(12) . . . . ?
C21A C13A C14A C15A 93.6(15) . . . . ?
O1A C14A C15A C20A 149.8(13) . . . . ?
C13A C14A C15A C20A -92.9(16) . . . . ?
O1A C14A C15A C16A -40.1(19) . . . . ?
C13A C14A C15A C16A 77.3(18) . . . . ?
C20A C15A C16A C17A -3(2) . . . . ?
C14A C15A C16A C17A -172.3(14) . . . . ?
C15A C16A C17A C18A -1(2) . . . . ?
C16A C17A C18A C19A 4(2) . . . . ?
C17A C18A C19A C20A -4(3) . . . . ?
C16A C15A C20A C19A 3(2) . . . . ?
C14A C15A C20A C19A 173.3(14) . . . . ?
C18A C19A C20A C15A 0(2) . . . . ?
N1A C13A C21A C26A 130.2(13) . . . . ?
C14A C13A C21A C26A -109.5(14) . . . . ?
N1A C13A C21A C22A -55.8(16) . . . . ?
C14A C13A C21A C22A 64.5(15) . . . . ?
C26A C21A C22A C23A 4(2) . . . . ?
C13A C21A C22A C23A -170.6(13) . . . . ?
C21A C22A C23A C24A -2(2) . . . . ?
C22A C23A C24A C25A -2(3) . . . . ?
C23A C24A C25A C26A 4(3) . . . . ?
C22A C21A C26A C25A -2(2) . . . . ?
C13A C21A C26A C25A 172.2(12) . . . . ?
C24A C25A C26A C21A -2(2) . . . . ?
C32A Fe2A C27A C28A -47(2) . . . . ?
C30A Fe2A C27A C28A 81.0(7) . . . . ?
C36A Fe2A C27A C28A 160.6(11) . . . . ?
C29A Fe2A C27A C28A 119.4(10) . . . . ?
C33A Fe2A C27A C28A -79.2(9) . . . . ?
C31A Fe2A C27A C28A 37.1(7) . . . . ?
C34A Fe2A C27A C28A -119.5(8) . . . . ?
C35A Fe2A C27A C28A -164.0(7) . . . . ?
C32A Fe2A C27A C38A 74(2) . . . . ?
C28A Fe2A C27A C38A 120.4(14) . . . . ?
C30A Fe2A C27A C38A -158.6(12) . . . . ?
C36A Fe2A C27A C38A -79.0(16) . . . . ?
C29A Fe2A C27A C38A -120.2(13) . . . . ?
C33A Fe2A C27A C38A 41.3(13) . . . . ?
C31A Fe2A C27A C38A 157.5(12) . . . . ?
C34A Fe2A C27A C38A 1.0(12) . . . . ?
C35A Fe2A C27A C38A -43.6(12) . . . . ?
C32A Fe2A C27A C29A -165.9(19) . . . . ?
C28A Fe2A C27A C29A -119.4(10) . . . . ?
C30A Fe2A C27A C29A -38.4(7) . . . . ?
C36A Fe2A C27A C29A 41.2(14) . . . . ?
C33A Fe2A C27A C29A 161.4(7) . . . . ?
C31A Fe2A C27A C29A -82.3(7) . . . . ?
C34A Fe2A C27A C29A 121.1(7) . . . . ?
C35A Fe2A C27A C29A 76.6(8) . . . . ?
C38A C27A C28A C31A -175.5(12) . . . . ?
C29A C27A C28A C31A 0.2(15) . . . . ?
Fe2A C27A C28A C31A -59.9(9) . . . . ?
C38A C27A C28A Au2A 19(2) . . . . ?
C29A C27A C28A Au2A -165.1(9) . . . . ?
Fe2A C27A C28A Au2A 134.8(11) . . . . ?
C38A C27A C28A Fe2A -115.6(13) . . . . ?
C29A C27A C28A Fe2A 60.1(9) . . . . ?
N1A Au2A C28A C31A 133(14) . . . . ?
Cl2A Au2A C28A C31A -33.8(11) . . . . ?
Au1A Au2A C28A C31A 142.5(11) . . . . ?
N1A Au2A C28A C27A -64(15) . . . . ?
Cl2A Au2A C28A C27A 129.6(11) . . . . ?
Au1A Au2A C28A C27A -54.1(11) . . . . ?
N1A Au2A C28A Fe2A 36(15) . . . . ?
Cl2A Au2A C28A Fe2A -130.4(9) . . . . ?
Au1A Au2A C28A Fe2A 46.0(9) . . . . ?
C27A Fe2A C28A C31A 119.3(11) . . . . ?
C32A Fe2A C28A C31A -74.5(9) . . . . ?
C30A Fe2A C28A C31A 37.7(7) . . . . ?
C36A Fe2A C28A C31A -32(2) . . . . ?
C29A Fe2A C28A C31A 80.8(8) . . . . ?
C33A Fe2A C28A C31A -117.1(8) . . . . ?
C34A Fe2A C28A C31A -160.1(8) . . . . ?
C35A Fe2A C28A C31A 157.6(13) . . . . ?
C32A Fe2A C28A C27A 166.2(8) . . . . ?
C30A Fe2A C28A C27A -81.6(8) . . . . ?
C36A Fe2A C28A C27A -151.5(16) . . . . ?
C29A Fe2A C28A C27A -38.5(7) . . . . ?
C33A Fe2A C28A C27A 123.6(8) . . . . ?
C31A Fe2A C28A C27A -119.3(11) . . . . ?
C34A Fe2A C28A C27A 80.5(9) . . . . ?
C35A Fe2A C28A C27A 38.3(17) . . . . ?
C27A Fe2A C28A Au2A -123.5(13) . . . . ?
C32A Fe2A C28A Au2A 42.7(12) . . . . ?
C30A Fe2A C28A Au2A 154.9(11) . . . . ?
C36A Fe2A C28A Au2A 85.1(19) . . . . ?
C29A Fe2A C28A Au2A -162.0(11) . . . . ?
C33A Fe2A C28A Au2A 0.1(11) . . . . ?
C31A Fe2A C28A Au2A 117.2(13) . . . . ?
C34A Fe2A C28A Au2A -42.9(12) . . . . ?
C35A Fe2A C28A Au2A -85.2(17) . . . . ?
C28A C27A C29A C30A 0.1(14) . . . . ?
C38A C27A C29A C30A 175.8(12) . . . . ?
Fe2A C27A C29A C30A 60.2(9) . . . . ?
C28A C27A C29A C37A 178.4(13) . . . . ?
C38A C27A C29A C37A -6(2) . . . . ?
Fe2A C27A C29A C37A -121.4(14) . . . . ?
C28A C27A C29A Fe2A -60.1(9) . . . . ?
C38A C27A C29A Fe2A 115.6(13) . . . . ?
C27A Fe2A C29A C30A -116.6(10) . . . . ?
C32A Fe2A C29A C30A 55.7(14) . . . . ?
C28A Fe2A C29A C30A -79.1(7) . . . . ?
C36A Fe2A C29A C30A 82.4(8) . . . . ?
C33A Fe2A C29A C30A -177.0(16) . . . . ?
C31A Fe2A C29A C30A -36.4(7) . . . . ?
C34A Fe2A C29A C30A 163.4(7) . . . . ?
C35A Fe2A C29A C30A 123.6(7) . . . . ?
C32A Fe2A C29A C27A 172.2(10) . . . . ?
C28A Fe2A C29A C27A 37.4(7) . . . . ?
C30A Fe2A C29A C27A 116.6(10) . . . . ?
C36A Fe2A C29A C27A -161.0(7) . . . . ?
C33A Fe2A C29A C27A -60(2) . . . . ?
C31A Fe2A C29A C27A 80.1(7) . . . . ?
C34A Fe2A C29A C27A -80.0(8) . . . . ?
C35A Fe2A C29A C27A -119.9(7) . . . . ?
C27A Fe2A C29A C37A 122.9(14) . . . . ?
C32A Fe2A C29A C37A -64.9(17) . . . . ?
C28A Fe2A C29A C37A 160.3(13) . . . . ?
C30A Fe2A C29A C37A -120.6(14) . . . . ?
C36A Fe2A C29A C37A -38.2(13) . . . . ?
C33A Fe2A C29A C37A 62(2) . . . . ?
C31A Fe2A C29A C37A -157.0(13) . . . . ?
C34A Fe2A C29A C37A 42.8(13) . . . . ?
C35A Fe2A C29A C37A 3.0(12) . . . . ?
C27A C29A C30A C31A -0.3(14) . . . . ?
C37A C29A C30A C31A -178.8(12) . . . . ?
Fe2A C29A C30A C31A 58.4(9) . . . . ?
C27A C29A C30A Fe2A -58.7(8) . . . . ?
C37A C29A C30A Fe2A 122.8(14) . . . . ?
C27A Fe2A C30A C29A 40.3(7) . . . . ?
C32A Fe2A C30A C29A -153.5(7) . . . . ?
C28A Fe2A C30A C29A 84.6(8) . . . . ?
C36A Fe2A C30A C29A -112.9(8) . . . . ?
C33A Fe2A C30A C29A 177.8(11) . . . . ?
C31A Fe2A C30A C29A 121.7(10) . . . . ?
C34A Fe2A C30A C29A -45.0(19) . . . . ?
C35A Fe2A C30A C29A -72.2(9) . . . . ?
C27A Fe2A C30A C31A -81.4(8) . . . . ?
C32A Fe2A C30A C31A 84.8(8) . . . . ?
C28A Fe2A C30A C31A -37.1(7) . . . . ?
C36A Fe2A C30A C31A 125.5(8) . . . . ?
C29A Fe2A C30A C31A -121.7(10) . . . . ?
C33A Fe2A C30A C31A 56.2(15) . . . . ?
C34A Fe2A C30A C31A -166.6(15) . . . . ?
C35A Fe2A C30A C31A 166.1(7) . . . . ?
C27A C28A C31A C30A -0.5(15) . . . . ?
Au2A C28A C31A C30A 165.8(9) . . . . ?
Fe2A C28A C31A C30A -59.2(9) . . . . ?
C27A C28A C31A Fe2A 58.7(9) . . . . ?
Au2A C28A C31A Fe2A -135.0(10) . . . . ?
C29A C30A C31A C28A 0.5(15) . . . . ?
Fe2A C30A C31A C28A 59.1(9) . . . . ?
C29A C30A C31A Fe2A -58.6(9) . . . . ?
C27A Fe2A C31A C28A -38.0(8) . . . . ?
C32A Fe2A C31A C28A 126.1(8) . . . . ?
C30A Fe2A C31A C28A -119.4(11) . . . . ?
C36A Fe2A C31A C28A 168.6(8) . . . . ?
C29A Fe2A C31A C28A -83.4(8) . . . . ?
C33A Fe2A C31A C28A 83.9(9) . . . . ?
C34A Fe2A C31A C28A 48.8(17) . . . . ?
C35A Fe2A C31A C28A -155.2(14) . . . . ?
C27A Fe2A C31A C30A 81.4(8) . . . . ?
C32A Fe2A C31A C30A -114.4(8) . . . . ?
C28A Fe2A C31A C30A 119.4(11) . . . . ?
C36A Fe2A C31A C30A -72.0(9) . . . . ?
C29A Fe2A C31A C30A 36.0(7) . . . . ?
C33A Fe2A C31A C30A -156.7(7) . . . . ?
C34A Fe2A C31A C30A 168.3(14) . . . . ?
C35A Fe2A C31A C30A -35.8(18) . . . . ?
C27A Fe2A C32A C33A -41(2) . . . . ?
C28A Fe2A C32A C33A -78.4(10) . . . . ?
C30A Fe2A C32A C33A -162.8(7) . . . . ?
C36A Fe2A C32A C33A 120.4(12) . . . . ?
C29A Fe2A C32A C33A 159.1(10) . . . . ?
C31A Fe2A C32A C33A -119.3(8) . . . . ?
C34A Fe2A C32A C33A 37.2(8) . . . . ?
C35A Fe2A C32A C33A 82.4(8) . . . . ?
C27A Fe2A C32A C36A -161.8(18) . . . . ?
C28A Fe2A C32A C36A 161.2(8) . . . . ?
C30A Fe2A C32A C36A 76.8(9) . . . . ?
C29A Fe2A C32A C36A 38.7(15) . . . . ?
C33A Fe2A C32A C36A -120.4(12) . . . . ?
C31A Fe2A C32A C36A 120.3(8) . . . . ?
C34A Fe2A C32A C36A -83.2(9) . . . . ?
C35A Fe2A C32A C36A -37.9(8) . . . . ?
C36A C32A C33A C34A 0.1(16) . . . . ?
Fe2A C32A C33A C34A -59.7(10) . . . . ?
C36A C32A C33A Fe2A 59.8(10) . . . . ?
C27A Fe2A C33A C34A -73.2(10) . . . . ?
C32A Fe2A C33A C34A 119.4(12) . . . . ?
C28A Fe2A C33A C34A -117.0(8) . . . . ?
C30A Fe2A C33A C34A 159.3(11) . . . . ?
C36A Fe2A C33A C34A 82.4(9) . . . . ?
C29A Fe2A C33A C34A -25(2) . . . . ?
C31A Fe2A C33A C34A -160.2(8) . . . . ?
C35A Fe2A C33A C34A 38.6(8) . . . . ?
C27A Fe2A C33A C32A 167.4(8) . . . . ?
C28A Fe2A C33A C32A 123.7(8) . . . . ?
C30A Fe2A C33A C32A 40.0(16) . . . . ?
C36A Fe2A C33A C32A -37.0(8) . . . . ?
C29A Fe2A C33A C32A -144.9(16) . . . . ?
C31A Fe2A C33A C32A 80.4(9) . . . . ?
C34A Fe2A C33A C32A -119.4(12) . . . . ?
C35A Fe2A C33A C32A -80.7(8) . . . . ?
C32A C33A C34A C35A -0.3(16) . . . . ?
Fe2A C33A C34A C35A -59.3(9) . . . . ?
C32A C33A C34A Fe2A 59.1(10) . . . . ?
C27A Fe2A C34A C33A 127.0(8) . . . . ?
C32A Fe2A C34A C33A -37.4(8) . . . . ?
C28A Fe2A C34A C33A 83.8(9) . . . . ?
C30A Fe2A C34A C33A -155.1(14) . . . . ?
C36A Fe2A C34A C33A -81.0(9) . . . . ?
C29A Fe2A C34A C33A 171.3(7) . . . . ?
C31A Fe2A C34A C33A 48.5(18) . . . . ?
C35A Fe2A C34A C33A -119.1(11) . . . . ?
C27A Fe2A C34A C35A -113.9(8) . . . . ?
C32A Fe2A C34A C35A 81.7(8) . . . . ?
C28A Fe2A C34A C35A -157.0(8) . . . . ?
C30A Fe2A C34A C35A -36(2) . . . . ?
C36A Fe2A C34A C35A 38.1(8) . . . . ?
C29A Fe2A C34A C35A -69.6(9) . . . . ?
C33A Fe2A C34A C35A 119.1(11) . . . . ?
C31A Fe2A C34A C35A 167.6(13) . . . . ?
C33A C34A C35A C36A 0.3(15) . . . . ?
Fe2A C34A C35A C36A -59.4(9) . . . . ?
C33A C34A C35A Fe2A 59.7(9) . . . . ?
C27A Fe2A C35A C36A -156.7(8) . . . . ?
C32A Fe2A C35A C36A 37.7(8) . . . . ?
C28A Fe2A C35A C36A 175.4(12) . . . . ?
C30A Fe2A C35A C36A -75.4(9) . . . . ?
C29A Fe2A C35A C36A -114.5(8) . . . . ?
C33A Fe2A C35A C36A 81.0(8) . . . . ?
C31A Fe2A C35A C36A -48.8(18) . . . . ?
C34A Fe2A C35A C36A 117.8(11) . . . . ?
C27A Fe2A C35A C34A 85.5(9) . . . . ?
C32A Fe2A C35A C34A -80.1(9) . . . . ?
C28A Fe2A C35A C34A 57.5(17) . . . . ?
C30A Fe2A C35A C34A 166.8(8) . . . . ?
C36A Fe2A C35A C34A -117.8(12) . . . . ?
C29A Fe2A C35A C34A 127.6(8) . . . . ?
C33A Fe2A C35A C34A -36.9(8) . . . . ?
C31A Fe2A C35A C34A -166.7(14) . . . . ?
C33A C32A C36A C35A 0.0(16) . . . . ?
Fe2A C32A C36A C35A 60.0(9) . . . . ?
C33A C32A C36A Fe2A -60.0(10) . . . . ?
C34A C35A C36A C32A -0.2(15) . . . . ?
Fe2A C35A C36A C32A -59.4(10) . . . . ?
C34A C35A C36A Fe2A 59.2(9) . . . . ?
C27A Fe2A C36A C32A 169.5(11) . . . . ?
C28A Fe2A C36A C32A -55(2) . . . . ?
C30A Fe2A C36A C32A -119.7(8) . . . . ?
C29A Fe2A C36A C32A -161.1(8) . . . . ?
C33A Fe2A C36A C32A 36.7(8) . . . . ?
C31A Fe2A C36A C32A -79.8(9) . . . . ?
C34A Fe2A C36A C32A 79.6(9) . . . . ?
C35A Fe2A C36A C32A 118.8(11) . . . . ?
C27A Fe2A C36A C35A 50.7(15) . . . . ?
C32A Fe2A C36A C35A -118.8(11) . . . . ?
C28A Fe2A C36A C35A -174.2(15) . . . . ?
C30A Fe2A C36A C35A 121.5(8) . . . . ?
C29A Fe2A C36A C35A 80.1(9) . . . . ?
C33A Fe2A C36A C35A -82.0(8) . . . . ?
C31A Fe2A C36A C35A 161.4(8) . . . . ?
C34A Fe2A C36A C35A -39.2(8) . . . . ?
C39A N2A C38A O2A 4.2(14) . . . . ?
Au1A N2A C38A O2A -165.1(8) . . . . ?
C39A N2A C38A C27A -178.5(12) . . . . ?
Au1A N2A C38A C27A 12.3(18) . . . . ?
C40A O2A C38A N2A 10.5(14) . . . . ?
C40A O2A C38A C27A -167.2(11) . . . . ?
C28A C27A C38A N2A 15(2) . . . . ?
C29A C27A C38A N2A -159.8(12) . . . . ?
Fe2A C27A C38A N2A -72.4(16) . . . . ?
C28A C27A C38A O2A -167.6(12) . . . . ?
C29A C27A C38A O2A 17.4(18) . . . . ?
Fe2A C27A C38A O2A 104.9(12) . . . . ?
C38A N2A C39A C47A 109.7(11) . . . . ?
Au1A N2A C39A C47A -81.5(12) . . . . ?
C38A N2A C39A C40A -16.1(13) . . . . ?
Au1A N2A C39A C40A 152.7(8) . . . . ?
C38A O2A C40A C39A -19.5(12) . . . . ?
C38A O2A C40A C41A 104.8(11) . . . . ?
N2A C39A C40A O2A 20.9(12) . . . . ?
C47A C39A C40A O2A -104.7(11) . . . . ?
N2A C39A C40A C41A -99.5(11) . . . . ?
C47A C39A C40A C41A 134.9(11) . . . . ?
O2A C40A C41A C46A 167.0(12) . . . . ?
C39A C40A C41A C46A -76.5(16) . . . . ?
O2A C40A C41A C42A -18.6(17) . . . . ?
C39A C40A C41A C42A 97.9(15) . . . . ?
C46A C41A C42A C43A -4(3) . . . . ?
C40A C41A C42A C43A -177.8(15) . . . . ?
C41A C42A C43A C44A 0(3) . . . . ?
C42A C43A C44A C45A 4(3) . . . . ?
C43A C44A C45A C46A -4(3) . . . . ?
C42A C41A C46A C45A 4(2) . . . . ?
C40A C41A C46A C45A 178.0(14) . . . . ?
C44A C45A C46A C41A 0(2) . . . . ?
N2A C39A C47A C48A -11.9(17) . . . . ?
C40A C39A C47A C48A 106.5(14) . . . . ?
N2A C39A C47A C52A 174.6(11) . . . . ?
C40A C39A C47A C52A -67.0(15) . . . . ?
C52A C47A C48A C49A -5(2) . . . . ?
C39A C47A C48A C49A -178.3(12) . . . . ?
C47A C48A C49A C50A 3(2) . . . . ?
C48A C49A C50A C51A -2(2) . . . . ?
C49A C50A C51A C52A 3(2) . . . . ?
C50A C51A C52A C47A -4(2) . . . . ?
C48A C47A C52A C51A 5(2) . . . . ?
C39A C47A C52A C51A 179.2(12) . . . . ?
C1B Au1B Au2B C27B -126.5(5) . . . . ?
N2B Au1B Au2B C27B 52.9(5) . . . . ?
Cl1B Au1B Au2B C27B -121.7(11) . . . . ?
C1B Au1B Au2B N1B 53.3(5) . . . . ?
N2B Au1B Au2B N1B -127.3(4) . . . . ?
Cl1B Au1B Au2B N1B 58.1(11) . . . . ?
C1B Au1B Au2B Cl2B -45.6(14) . . . . ?
N2B Au1B Au2B Cl2B 133.9(13) . . . . ?
Cl1B Au1B Au2B Cl2B -40.8(17) . . . . ?
C8B Fe1B C1B C2B 46.6(14) . . . . ?
C10B Fe1B C1B C2B 171.0(7) . . . . ?
C3B Fe1B C1B C2B -34.8(7) . . . . ?
C4B Fe1B C1B C2B -78.2(8) . . . . ?
C9B Fe1B C1B C2B -145(2) . . . . ?
C5B Fe1B C1B C2B -116.0(10) . . . . ?
C7B Fe1B C1B C2B 85.0(9) . . . . ?
C6B Fe1B C1B C2B 128.8(7) . . . . ?
C8B Fe1B C1B C5B 162.6(10) . . . . ?
C2B Fe1B C1B C5B 116.0(10) . . . . ?
C10B Fe1B C1B C5B -73.0(9) . . . . ?
C3B Fe1B C1B C5B 81.2(7) . . . . ?
C4B Fe1B C1B C5B 37.8(7) . . . . ?
C9B Fe1B C1B C5B -29(3) . . . . ?
C7B Fe1B C1B C5B -159.0(7) . . . . ?
C6B Fe1B C1B C5B -115.3(7) . . . . ?
C8B Fe1B C1B Au1B -89.8(15) . . . . ?
C2B Fe1B C1B Au1B -136.4(14) . . . . ?
C10B Fe1B C1B Au1B 34.6(13) . . . . ?
C3B Fe1B C1B Au1B -171.2(11) . . . . ?
C4B Fe1B C1B Au1B 145.4(11) . . . . ?
C9B Fe1B C1B Au1B 78(3) . . . . ?
C5B Fe1B C1B Au1B 107.6(13) . . . . ?
C7B Fe1B C1B Au1B -51.4(12) . . . . ?
C6B Fe1B C1B Au1B -7.7(12) . . . . ?
N2B Au1B C1B C2B -66(5) . . . . ?
Cl1B Au1B C1B C2B 120.0(13) . . . . ?
Au2B Au1B C1B C2B -60.4(13) . . . . ?
N2B Au1B C1B C5B 140(4) . . . . ?
Cl1B Au1B C1B C5B -33.2(10) . . . . ?
Au2B Au1B C1B C5B 146.4(10) . . . . ?
N2B Au1B C1B Fe1B 51(5) . . . . ?
Cl1B Au1B C1B Fe1B -123.2(9) . . . . ?
Au2B Au1B C1B Fe1B 56.4(9) . . . . ?
C27B Au2B N1B C12B -52(18) . . . . ?
Cl2B Au2B N1B C12B 117.0(10) . . . . ?
Au1B Au2B N1B C12B -59.5(10) . . . . ?
C27B Au2B N1B C13B 145(17) . . . . ?
Cl2B Au2B N1B C13B -46.0(9) . . . . ?
Au1B Au2B N1B C13B 137.5(9) . . . . ?
C5B C1B C2B C3B -7.5(15) . . . . ?
Fe1B C1B C2B C3B 55.2(9) . . . . ?
Au1B C1B C2B C3B -162.4(10) . . . . ?
C5B C1B C2B C12B -176.1(11) . . . . ?
Fe1B C1B C2B C12B -113.5(12) . . . . ?
Au1B C1B C2B C12B 29(2) . . . . ?
C5B C1B C2B Fe1B -62.6(9) . . . . ?
Au1B C1B C2B Fe1B 142.5(13) . . . . ?
C8B Fe1B C2B C1B -156.5(8) . . . . ?
C10B Fe1B C2B C1B -35(3) . . . . ?
C3B Fe1B C2B C1B 126.5(10) . . . . ?
C4B Fe1B C2B C1B 86.9(8) . . . . ?
C9B Fe1B C2B C1B 165.2(10) . . . . ?
C5B Fe1B C2B C1B 42.4(7) . . . . ?
C7B Fe1B C2B C1B -112.2(8) . . . . ?
C6B Fe1B C2B C1B -72.4(9) . . . . ?
C1B Fe1B C2B C3B -126.5(10) . . . . ?
C8B Fe1B C2B C3B 76.9(7) . . . . ?
C10B Fe1B C2B C3B -162(2) . . . . ?
C4B Fe1B C2B C3B -39.6(7) . . . . ?
C9B Fe1B C2B C3B 38.7(12) . . . . ?
C5B Fe1B C2B C3B -84.2(7) . . . . ?
C7B Fe1B C2B C3B 121.3(7) . . . . ?
C6B Fe1B C2B C3B 161.1(7) . . . . ?
C1B Fe1B C2B C12B 118.2(12) . . . . ?
C8B Fe1B C2B C12B -38.3(10) . . . . ?
C10B Fe1B C2B C12B 83(2) . . . . ?
C3B Fe1B C2B C12B -115.3(11) . . . . ?
C4B Fe1B C2B C12B -154.9(10) . . . . ?
C9B Fe1B C2B C12B -76.6(13) . . . . ?
C5B Fe1B C2B C12B 160.6(10) . . . . ?
C7B Fe1B C2B C12B 6.0(10) . . . . ?
C6B Fe1B C2B C12B 45.9(11) . . . . ?
C1B Au1B N2B C38B -46(5) . . . . ?
Cl1B Au1B N2B C38B 128.0(9) . . . . ?
Au2B Au1B N2B C38B -51.5(9) . . . . ?
C1B Au1B N2B C39B 161(4) . . . . ?
Cl1B Au1B N2B C39B -25.5(9) . . . . ?
Au2B Au1B N2B C39B 154.9(9) . . . . ?
C1B C2B C3B C4B 6.2(15) . . . . ?
C12B C2B C3B C4B 175.2(11) . . . . ?
Fe1B C2B C3B C4B 61.2(8) . . . . ?
C1B C2B C3B C11B -178.5(13) . . . . ?
C12B C2B C3B C11B -9.5(19) . . . . ?
Fe1B C2B C3B C11B -123.5(13) . . . . ?
C1B C2B C3B Fe1B -55.0(10) . . . . ?
C12B C2B C3B Fe1B 114.0(10) . . . . ?
C1B Fe1B C3B C4B -83.6(8) . . . . ?
C8B Fe1B C3B C4B 125.4(8) . . . . ?
C2B Fe1B C3B C4B -115.3(10) . . . . ?
C10B Fe1B C3B C4B 57.5(12) . . . . ?
C9B Fe1B C3B C4B 83.7(8) . . . . ?
C5B Fe1B C3B C4B -36.7(7) . . . . ?
C7B Fe1B C3B C4B 164.6(8) . . . . ?
C6B Fe1B C3B C4B 177.3(17) . . . . ?
C1B Fe1B C3B C2B 31.7(6) . . . . ?
C8B Fe1B C3B C2B -119.2(7) . . . . ?
C10B Fe1B C3B C2B 172.9(8) . . . . ?
C4B Fe1B C3B C2B 115.3(10) . . . . ?
C9B Fe1B C3B C2B -161.0(6) . . . . ?
C5B Fe1B C3B C2B 78.6(7) . . . . ?
C7B Fe1B C3B C2B -80.0(8) . . . . ?
C6B Fe1B C3B C2B -67(2) . . . . ?
C1B Fe1B C3B C11B 158.1(11) . . . . ?
C8B Fe1B C3B C11B 7.1(11) . . . . ?
C2B Fe1B C3B C11B 126.4(13) . . . . ?
C10B Fe1B C3B C11B -60.8(14) . . . . ?
C4B Fe1B C3B C11B -118.3(13) . . . . ?
C9B Fe1B C3B C11B -34.6(11) . . . . ?
C5B Fe1B C3B C11B -155.0(11) . . . . ?
C7B Fe1B C3B C11B 46.4(12) . . . . ?
C6B Fe1B C3B C11B 59(2) . . . . ?
C2B C3B C4B C5B -2.1(14) . . . . ?
C11B C3B C4B C5B -177.8(12) . . . . ?
Fe1B C3B C4B C5B 58.3(9) . . . . ?
C2B C3B C4B Fe1B -60.4(8) . . . . ?
C11B C3B C4B Fe1B 123.9(12) . . . . ?
C1B Fe1B C4B C3B 81.1(8) . . . . ?
C8B Fe1B C4B C3B -71.0(9) . . . . ?
C2B Fe1B C4B C3B 40.6(7) . . . . ?
C10B Fe1B C4B C3B -150.6(7) . . . . ?
C9B Fe1B C4B C3B -110.7(8) . . . . ?
C5B Fe1B C4B C3B 121.4(11) . . . . ?
C7B Fe1B C4B C3B -44(2) . . . . ?
C6B Fe1B C4B C3B -178.3(11) . . . . ?
C1B Fe1B C4B C5B -40.3(7) . . . . ?
C8B Fe1B C4B C5B 167.6(7) . . . . ?
C2B Fe1B C4B C5B -80.8(8) . . . . ?
C10B Fe1B C4B C5B 88.0(8) . . . . ?
C3B Fe1B C4B C5B -121.4(11) . . . . ?
C9B Fe1B C4B C5B 128.0(8) . . . . ?
C7B Fe1B C4B C5B -165.7(16) . . . . ?
C6B Fe1B C4B C5B 60.3(15) . . . . ?
C3B C4B C5B C1B -1.9(15) . . . . ?
Fe1B C4B C5B C1B 56.1(8) . . . . ?
C3B C4B C5B Fe1B -58.0(9) . . . . ?
C2B C1B C5B C4B 5.7(15) . . . . ?
Fe1B C1B C5B C4B -58.4(9) . . . . ?
Au1B C1B C5B C4B 165.3(9) . . . . ?
C2B C1B C5B Fe1B 64.1(9) . . . . ?
Au1B C1B C5B Fe1B -136.3(9) . . . . ?
C1B Fe1B C5B C4B 118.2(10) . . . . ?
C8B Fe1B C5B C4B -35(2) . . . . ?
C2B Fe1B C5B C4B 81.5(8) . . . . ?
C10B Fe1B C5B C4B -110.6(8) . . . . ?
C3B Fe1B C5B C4B 36.5(7) . . . . ?
C9B Fe1B C5B C4B -69.2(9) . . . . ?
C7B Fe1B C5B C4B 169.0(13) . . . . ?
C6B Fe1B C5B C4B -153.7(8) . . . . ?
C8B Fe1B C5B C1B -153.0(16) . . . . ?
C2B Fe1B C5B C1B -36.7(7) . . . . ?
C10B Fe1B C5B C1B 131.2(7) . . . . ?
C3B Fe1B C5B C1B -81.7(7) . . . . ?
C4B Fe1B C5B C1B -118.2(10) . . . . ?
C9B Fe1B C5B C1B 172.6(8) . . . . ?
C7B Fe1B C5B C1B 50.9(16) . . . . ?
C6B Fe1B C5B C1B 88.1(8) . . . . ?
C1B Fe1B C6B C7B -109.4(9) . . . . ?
C8B Fe1B C6B C7B 39.8(8) . . . . ?
C2B Fe1B C6B C7B -70.3(10) . . . . ?
C10B Fe1B C6B C7B 120.6(11) . . . . ?
C3B Fe1B C6B C7B -16(2) . . . . ?
C4B Fe1B C6B C7B 159.7(12) . . . . ?
C9B Fe1B C6B C7B 84.0(9) . . . . ?
C5B Fe1B C6B C7B -157.6(8) . . . . ?
C1B Fe1B C6B C10B 130.1(8) . . . . ?
C8B Fe1B C6B C10B -80.8(8) . . . . ?
C2B Fe1B C6B C10B 169.2(7) . . . . ?
C3B Fe1B C6B C10B -136.8(17) . . . . ?
C4B Fe1B C6B C10B 39.1(15) . . . . ?
C9B Fe1B C6B C10B -36.6(7) . . . . ?
C5B Fe1B C6B C10B 81.9(9) . . . . ?
C7B Fe1B C6B C10B -120.6(11) . . . . ?
C10B C6B C7B C8B -1.2(15) . . . . ?
Fe1B C6B C7B C8B -58.5(9) . . . . ?
C10B C6B C7B Fe1B 57.4(9) . . . . ?
C1B Fe1B C7B C6B 90.2(9) . . . . ?
C8B Fe1B C7B C6B -116.5(11) . . . . ?
C2B Fe1B C7B C6B 130.7(8) . . . . ?
C10B Fe1B C7B C6B -37.1(8) . . . . ?
C3B Fe1B C7B C6B 174.8(7) . . . . ?
C4B Fe1B C7B C6B -151.4(16) . . . . ?
C9B Fe1B C7B C6B -79.7(8) . . . . ?
C5B Fe1B C7B C6B 52.3(17) . . . . ?
C1B Fe1B C7B C8B -153.3(8) . . . . ?
C2B Fe1B C7B C8B -112.8(8) . . . . ?
C10B Fe1B C7B C8B 79.4(8) . . . . ?
C3B Fe1B C7B C8B -68.7(9) . . . . ?
C4B Fe1B C7B C8B -35(2) . . . . ?
C9B Fe1B C7B C8B 36.9(8) . . . . ?
C5B Fe1B C7B C8B 168.9(12) . . . . ?
C6B Fe1B C7B C8B 116.5(11) . . . . ?
C6B C7B C8B C9B 0.0(16) . . . . ?
Fe1B C7B C8B C9B -60.5(10) . . . . ?
C6B C7B C8B Fe1B 60.5(9) . . . . ?
C1B Fe1B C8B C9B 176.1(11) . . . . ?
C2B Fe1B C8B C9B -153.1(7) . . . . ?
C10B Fe1B C8B C9B 37.7(8) . . . . ?
C3B Fe1B C8B C9B -111.2(8) . . . . ?
C4B Fe1B C8B C9B -71.7(9) . . . . ?
C5B Fe1B C8B C9B -45(2) . . . . ?
C7B Fe1B C8B C9B 120.5(12) . . . . ?
C6B Fe1B C8B C9B 82.0(8) . . . . ?
C1B Fe1B C8B C7B 55.6(15) . . . . ?
C2B Fe1B C8B C7B 86.5(9) . . . . ?
C10B Fe1B C8B C7B -82.8(9) . . . . ?
C3B Fe1B C8B C7B 128.4(8) . . . . ?
C4B Fe1B C8B C7B 167.8(8) . . . . ?
C9B Fe1B C8B C7B -120.5(12) . . . . ?
C5B Fe1B C8B C7B -165.6(15) . . . . ?
C6B Fe1B C8B C7B -38.5(8) . . . . ?
C7B C8B C9B C10B 1.3(15) . . . . ?
Fe1B C8B C9B C10B -59.6(9) . . . . ?
C7B C8B C9B Fe1B 60.9(10) . . . . ?
C1B Fe1B C9B C10B -53(3) . . . . ?
C8B Fe1B C9B C10B 117.9(11) . . . . ?
C2B Fe1B C9B C10B 173.7(9) . . . . ?
C3B Fe1B C9B C10B -159.2(7) . . . . ?
C4B Fe1B C9B C10B -117.2(8) . . . . ?
C5B Fe1B C9B C10B -77.9(9) . . . . ?
C7B Fe1B C9B C10B 80.5(8) . . . . ?
C6B Fe1B C9B C10B 37.5(8) . . . . ?
C1B Fe1B C9B C8B -171(2) . . . . ?
C2B Fe1B C9B C8B 55.8(13) . . . . ?
C10B Fe1B C9B C8B -117.9(11) . . . . ?
C3B Fe1B C9B C8B 82.9(8) . . . . ?
C4B Fe1B C9B C8B 124.9(8) . . . . ?
C5B Fe1B C9B C8B 164.2(7) . . . . ?
C7B Fe1B C9B C8B -37.4(8) . . . . ?
C6B Fe1B C9B C8B -80.4(8) . . . . ?
C8B C9B C10B C6B -2.0(15) . . . . ?
Fe1B C9B C10B C6B -60.8(9) . . . . ?
C8B C9B C10B Fe1B 58.8(9) . . . . ?
C7B C6B C10B C9B 2.0(16) . . . . ?
Fe1B C6B C10B C9B 60.5(10) . . . . ?
C7B C6B C10B Fe1B -58.5(10) . . . . ?
C1B Fe1B C10B C9B 166.6(7) . . . . ?
C8B Fe1B C10B C9B -38.7(7) . . . . ?
C2B Fe1B C10B C9B -165(2) . . . . ?
C3B Fe1B C10B C9B 39.2(13) . . . . ?
C4B Fe1B C10B C9B 77.8(9) . . . . ?
C5B Fe1B C10B C9B 121.9(7) . . . . ?
C7B Fe1B C10B C9B -83.5(8) . . . . ?
C6B Fe1B C10B C9B -120.0(11) . . . . ?
C1B Fe1B C10B C6B -73.5(10) . . . . ?
C8B Fe1B C10B C6B 81.3(8) . . . . ?
C2B Fe1B C10B C6B -45(3) . . . . ?
C3B Fe1B C10B C6B 159.2(9) . . . . ?
C4B Fe1B C10B C6B -162.2(8) . . . . ?
C9B Fe1B C10B C6B 120.0(11) . . . . ?
C5B Fe1B C10B C6B -118.1(8) . . . . ?
C7B Fe1B C10B C6B 36.5(8) . . . . ?
C13B N1B C12B O1B 1.7(15) . . . . ?
Au2B N1B C12B O1B -164.1(8) . . . . ?
C13B N1B C12B C2B -168.8(11) . . . . ?
Au2B N1B C12B C2B 25.4(16) . . . . ?
C14B O1B C12B N1B 13.1(15) . . . . ?
C14B O1B C12B C2B -175.9(10) . . . . ?
C1B C2B C12B N1B 3(2) . . . . ?
C3B C2B C12B N1B -165.3(11) . . . . ?
Fe1B C2B C12B N1B -81.8(13) . . . . ?
C1B C2B C12B O1B -168.1(12) . . . . ?
C3B C2B C12B O1B 24.1(16) . . . . ?
Fe1B C2B C12B O1B 107.5(11) . . . . ?
C12B N1B C13B C21B 101.1(12) . . . . ?
Au2B N1B C13B C21B -93.7(12) . . . . ?
C12B N1B C13B C14B -14.4(13) . . . . ?
Au2B N1B C13B C14B 150.8(8) . . . . ?
C12B O1B C14B C15B 107.7(11) . . . . ?
C12B O1B C14B C13B -20.6(12) . . . . ?
N1B C13B C14B O1B 20.6(12) . . . . ?
C21B C13B C14B O1B -97.8(11) . . . . ?
N1B C13B C14B C15B -103.6(12) . . . . ?
C21B C13B C14B C15B 138.0(11) . . . . ?
O1B C14B C15B C16B 123.6(13) . . . . ?
C13B C14B C15B C16B -117.1(14) . . . . ?
O1B C14B C15B C20B -55.0(16) . . . . ?
C13B C14B C15B C20B 64.3(16) . . . . ?
C20B C15B C16B C17B 1(2) . . . . ?
C14B C15B C16B C17B -177.6(12) . . . . ?
C15B C16B C17B C18B 2(2) . . . . ?
C16B C17B C18B C19B -2(2) . . . . ?
C17B C18B C19B C20B -1(2) . . . . ?
C18B C19B C20B C15B 3(2) . . . . ?
C16B C15B C20B C19B -3(2) . . . . ?
C14B C15B C20B C19B 175.3(12) . . . . ?
N1B C13B C21B C26B -27.1(16) . . . . ?
C14B C13B C21B C26B 83.0(14) . . . . ?
N1B C13B C21B C22B 162.0(11) . . . . ?
C14B C13B C21B C22B -87.9(13) . . . . ?
C26B C21B C22B C23B 1.6(19) . . . . ?
C13B C21B C22B C23B 172.8(12) . . . . ?
C21B C22B C23B C24B -3(2) . . . . ?
C22B C23B C24B C25B 1(2) . . . . ?
C23B C24B C25B C26B 3(2) . . . . ?
C24B C25B C26B C21B -4(2) . . . . ?
C22B C21B C26B C25B 2(2) . . . . ?
C13B C21B C26B C25B -169.1(12) . . . . ?
N1B Au2B C27B C31B 132(17) . . . . ?
Cl2B Au2B C27B C31B -36.9(11) . . . . ?
Au1B Au2B C27B C31B 139.7(11) . . . . ?
N1B Au2B C27B C28B -62(18) . . . . ?
Cl2B Au2B C27B C28B 129.3(10) . . . . ?
Au1B Au2B C27B C28B -54.1(10) . . . . ?
N1B Au2B C27B Fe2B 33(18) . . . . ?
Cl2B Au2B C27B Fe2B -135.6(9) . . . . ?
Au1B Au2B C27B Fe2B 41.0(9) . . . . ?
C29B Fe2B C27B C31B 79.8(8) . . . . ?
C28B Fe2B C27B C31B 118.5(10) . . . . ?
C30B Fe2B C27B C31B 37.0(7) . . . . ?
C34B Fe2B C27B C31B 161.1(12) . . . . ?
C35B Fe2B C27B C31B -37(2) . . . . ?
C33B Fe2B C27B C31B -160.0(7) . . . . ?
C32B Fe2B C27B C31B -117.1(8) . . . . ?
C36B Fe2B C27B C31B -74.3(10) . . . . ?
C29B Fe2B C27B C28B -38.7(7) . . . . ?
C30B Fe2B C27B C28B -81.5(7) . . . . ?
C34B Fe2B C27B C28B 42.6(15) . . . . ?
C35B Fe2B C27B C28B -155.1(18) . . . . ?
C33B Fe2B C27B C28B 81.5(8) . . . . ?
C32B Fe2B C27B C28B 124.4(7) . . . . ?
C36B Fe2B C27B C28B 167.2(8) . . . . ?
C31B Fe2B C27B C28B -118.5(10) . . . . ?
C29B Fe2B C27B Au2B -158.4(11) . . . . ?
C28B Fe2B C27B Au2B -119.7(13) . . . . ?
C30B Fe2B C27B Au2B 158.8(11) . . . . ?
C34B Fe2B C27B Au2B -77.1(16) . . . . ?
C35B Fe2B C27B Au2B 85(2) . . . . ?
C33B Fe2B C27B Au2B -38.1(12) . . . . ?
C32B Fe2B C27B Au2B 4.8(12) . . . . ?
C36B Fe2B C27B Au2B 47.5(13) . . . . ?
C31B Fe2B C27B Au2B 121.8(13) . . . . ?
C31B C27B C28B C38B -168.8(11) . . . . ?
Au2B C27B C28B C38B 22.6(17) . . . . ?
Fe2B C27B C28B C38B -110.4(11) . . . . ?
C31B C27B C28B C29B 0.8(13) . . . . ?
Au2B C27B C28B C29B -167.8(9) . . . . ?
Fe2B C27B C28B C29B 59.2(8) . . . . ?
C31B C27B C28B Fe2B -58.4(8) . . . . ?
Au2B C27B C28B Fe2B 133.1(9) . . . . ?
C29B Fe2B C28B C38B -119.5(12) . . . . ?
C30B Fe2B C28B C38B -157.6(10) . . . . ?
C34B Fe2B C28B C38B -39.1(11) . . . . ?
C35B Fe2B C28B C38B -72.0(15) . . . . ?
C33B Fe2B C28B C38B 3.4(10) . . . . ?
C32B Fe2B C28B C38B 43.0(12) . . . . ?
C36B Fe2B C28B C38B 74(3) . . . . ?
C31B Fe2B C28B C38B 158.8(10) . . . . ?
C27B Fe2B C28B C38B 121.6(12) . . . . ?
C30B Fe2B C28B C29B -38.1(7) . . . . ?
C34B Fe2B C28B C29B 80.4(8) . . . . ?
C35B Fe2B C28B C29B 47.5(13) . . . . ?
C33B Fe2B C28B C29B 122.9(7) . . . . ?
C32B Fe2B C28B C29B 162.5(7) . . . . ?
C36B Fe2B C28B C29B -166(2) . . . . ?
C31B Fe2B C28B C29B -81.7(7) . . . . ?
C27B Fe2B C28B C29B -118.9(10) . . . . ?
C29B Fe2B C28B C27B 118.9(10) . . . . ?
C30B Fe2B C28B C27B 80.7(7) . . . . ?
C34B Fe2B C28B C27B -160.7(7) . . . . ?
C35B Fe2B C28B C27B 166.3(10) . . . . ?
C33B Fe2B C28B C27B -118.2(7) . . . . ?
C32B Fe2B C28B C27B -78.6(9) . . . . ?
C36B Fe2B C28B C27B -47(3) . . . . ?
C31B Fe2B C28B C27B 37.2(7) . . . . ?
C38B C28B C29B C30B 170.2(11) . . . . ?
C27B C28B C29B C30B 0.5(13) . . . . ?
Fe2B C28B C29B C30B 61.6(9) . . . . ?
C38B C28B C29B C37B -14(2) . . . . ?
C27B C28B C29B C37B 176.0(12) . . . . ?
Fe2B C28B C29B C37B -122.8(13) . . . . ?
C38B C28B C29B Fe2B 108.6(11) . . . . ?
C27B C28B C29B Fe2B -61.1(8) . . . . ?
C28B Fe2B C29B C30B -116.7(10) . . . . ?
C34B Fe2B C29B C30B 127.5(8) . . . . ?
C35B Fe2B C29B C30B 86.1(9) . . . . ?
C33B Fe2B C29B C30B 165.1(8) . . . . ?
C32B Fe2B C29B C30B -176.5(18) . . . . ?
C36B Fe2B C29B C30B 56.8(14) . . . . ?
C31B Fe2B C29B C30B -36.2(8) . . . . ?
C27B Fe2B C29B C30B -78.7(8) . . . . ?
C30B Fe2B C29B C28B 116.7(10) . . . . ?
C34B Fe2B C29B C28B -115.9(7) . . . . ?
C35B Fe2B C29B C28B -157.3(7) . . . . ?
C33B Fe2B C29B C28B -78.2(8) . . . . ?
C32B Fe2B C29B C28B -60(2) . . . . ?
C36B Fe2B C29B C28B 173.4(11) . . . . ?
C31B Fe2B C29B C28B 80.4(7) . . . . ?
C27B Fe2B C29B C28B 38.0(7) . . . . ?
C28B Fe2B C29B C37B 123.5(15) . . . . ?
C30B Fe2B C29B C37B -119.8(16) . . . . ?
C34B Fe2B C29B C37B 7.7(14) . . . . ?
C35B Fe2B C29B C37B -33.7(14) . . . . ?
C33B Fe2B C29B C37B 45.3(15) . . . . ?
C32B Fe2B C29B C37B 64(3) . . . . ?
C36B Fe2B C29B C37B -63.0(18) . . . . ?
C31B Fe2B C29B C37B -156.1(14) . . . . ?
C27B Fe2B C29B C37B 161.5(14) . . . . ?
C28B C29B C30B C31B -1.6(14) . . . . ?
C37B C29B C30B C31B -177.4(12) . . . . ?
Fe2B C29B C30B C31B 58.9(9) . . . . ?
C28B C29B C30B Fe2B -60.5(8) . . . . ?
C37B C29B C30B Fe2B 123.7(13) . . . . ?
C28B Fe2B C30B C29B 40.4(8) . . . . ?
C34B Fe2B C30B C29B -69.0(10) . . . . ?
C35B Fe2B C30B C29B -110.2(9) . . . . ?
C33B Fe2B C30B C29B -42(2) . . . . ?
C32B Fe2B C30B C29B 177.7(12) . . . . ?
C36B Fe2B C30B C29B -151.9(8) . . . . ?
C31B Fe2B C30B C29B 121.7(12) . . . . ?
C27B Fe2B C30B C29B 85.2(8) . . . . ?
C29B Fe2B C30B C31B -121.7(12) . . . . ?
C28B Fe2B C30B C31B -81.3(8) . . . . ?
C34B Fe2B C30B C31B 169.3(8) . . . . ?
C35B Fe2B C30B C31B 128.2(8) . . . . ?
C33B Fe2B C30B C31B -163.9(16) . . . . ?
C32B Fe2B C30B C31B 56.0(17) . . . . ?
C36B Fe2B C30B C31B 86.4(9) . . . . ?
C27B Fe2B C30B C31B -36.4(8) . . . . ?
C28B C27B C31B C30B -1.7(14) . . . . ?
Au2B C27B C31B C30B 166.8(9) . . . . ?
Fe2B C27B C31B C30B -58.8(9) . . . . ?
C28B C27B C31B Fe2B 57.1(8) . . . . ?
Au2B C27B C31B Fe2B -134.4(10) . . . . ?
C29B C30B C31B C27B 2.1(15) . . . . ?
Fe2B C30B C31B C27B 60.2(9) . . . . ?
C29B C30B C31B Fe2B -58.1(9) . . . . ?
C29B Fe2B C31B C27B -84.5(8) . . . . ?
C28B Fe2B C31B C27B -38.8(7) . . . . ?
C30B Fe2B C31B C27B -120.4(11) . . . . ?
C34B Fe2B C31B C27B -151.7(18) . . . . ?
C35B Fe2B C31B C27B 168.6(8) . . . . ?
C33B Fe2B C31B C27B 47.0(16) . . . . ?
C32B Fe2B C31B C27B 83.5(9) . . . . ?
C36B Fe2B C31B C27B 126.7(8) . . . . ?
C29B Fe2B C31B C30B 35.9(8) . . . . ?
C28B Fe2B C31B C30B 81.6(8) . . . . ?
C34B Fe2B C31B C30B -31(2) . . . . ?
C35B Fe2B C31B C30B -71.0(10) . . . . ?
C33B Fe2B C31B C30B 167.4(12) . . . . ?
C32B Fe2B C31B C30B -156.1(8) . . . . ?
C36B Fe2B C31B C30B -112.9(9) . . . . ?
C27B Fe2B C31B C30B 120.4(11) . . . . ?
C29B Fe2B C32B C33B -24(2) . . . . ?
C28B Fe2B C32B C33B -71.5(10) . . . . ?
C30B Fe2B C32B C33B 161.8(12) . . . . ?
C34B Fe2B C32B C33B 36.8(8) . . . . ?
C35B Fe2B C32B C33B 80.8(9) . . . . ?
C36B Fe2B C32B C33B 119.3(12) . . . . ?
C31B Fe2B C32B C33B -158.4(8) . . . . ?
C27B Fe2B C32B C33B -115.6(8) . . . . ?
C29B Fe2B C32B C36B -143.0(19) . . . . ?
C28B Fe2B C32B C36B 169.2(8) . . . . ?
C30B Fe2B C32B C36B 42.5(17) . . . . ?
C34B Fe2B C32B C36B -82.4(10) . . . . ?
C35B Fe2B C32B C36B -38.4(9) . . . . ?
C33B Fe2B C32B C36B -119.3(12) . . . . ?
C31B Fe2B C32B C36B 82.4(10) . . . . ?
C27B Fe2B C32B C36B 125.1(9) . . . . ?
C36B C32B C33B C34B 0.8(15) . . . . ?
Fe2B C32B C33B C34B -59.0(9) . . . . ?
C36B C32B C33B Fe2B 59.8(9) . . . . ?
C29B Fe2B C33B C32B 172.3(8) . . . . ?
C28B Fe2B C33B C32B 128.3(8) . . . . ?
C30B Fe2B C33B C32B -155.8(16) . . . . ?
C34B Fe2B C33B C32B -120.4(12) . . . . ?
C35B Fe2B C33B C32B -81.5(9) . . . . ?
C36B Fe2B C33B C32B -37.8(9) . . . . ?
C31B Fe2B C33B C32B 51.2(17) . . . . ?
C27B Fe2B C33B C32B 84.7(9) . . . . ?
C29B Fe2B C33B C34B -67.4(10) . . . . ?
C28B Fe2B C33B C34B -111.3(9) . . . . ?
C30B Fe2B C33B C34B -35(2) . . . . ?
C35B Fe2B C33B C34B 38.9(9) . . . . ?
C32B Fe2B C33B C34B 120.4(12) . . . . ?
C36B Fe2B C33B C34B 82.6(9) . . . . ?
C31B Fe2B C33B C34B 171.5(12) . . . . ?
C27B Fe2B C33B C34B -155.0(8) . . . . ?
C32B C33B C34B C35B -1.6(15) . . . . ?
Fe2B C33B C34B C35B -61.0(9) . . . . ?
C32B C33B C34B Fe2B 59.4(9) . . . . ?
C29B Fe2B C34B C33B 129.3(8) . . . . ?
C28B Fe2B C34B C33B 86.2(9) . . . . ?
C30B Fe2B C34B C33B 167.4(8) . . . . ?
C35B Fe2B C34B C33B -117.1(12) . . . . ?
C32B Fe2B C34B C33B -36.6(8) . . . . ?
C36B Fe2B C34B C33B -80.4(9) . . . . ?
C31B Fe2B C34B C33B -168.6(16) . . . . ?
C27B Fe2B C34B C33B 55.8(16) . . . . ?
C29B Fe2B C34B C35B -113.6(9) . . . . ?
C28B Fe2B C34B C35B -156.7(8) . . . . ?
C30B Fe2B C34B C35B -75.5(10) . . . . ?
C33B Fe2B C34B C35B 117.1(12) . . . . ?
C32B Fe2B C34B C35B 80.5(9) . . . . ?
C36B Fe2B C34B C35B 36.7(9) . . . . ?
C31B Fe2B C34B C35B -51(2) . . . . ?
C27B Fe2B C34B C35B 172.9(11) . . . . ?
C33B C34B C35B C36B 1.8(15) . . . . ?
Fe2B C34B C35B C36B -59.4(10) . . . . ?
C33B C34B C35B Fe2B 61.2(9) . . . . ?
C29B Fe2B C35B C36B -158.3(9) . . . . ?
C28B Fe2B C35B C36B 168.3(10) . . . . ?
C30B Fe2B C35B C36B -116.3(9) . . . . ?
C34B Fe2B C35B C36B 120.4(12) . . . . ?
C33B Fe2B C35B C36B 82.0(9) . . . . ?
C32B Fe2B C35B C36B 38.8(9) . . . . ?
C31B Fe2B C35B C36B -76.5(10) . . . . ?
C27B Fe2B C35B C36B -48(2) . . . . ?
C29B Fe2B C35B C34B 81.4(9) . . . . ?
C28B Fe2B C35B C34B 47.9(14) . . . . ?
C30B Fe2B C35B C34B 123.4(8) . . . . ?
C33B Fe2B C35B C34B -38.4(8) . . . . ?
C32B Fe2B C35B C34B -81.6(9) . . . . ?
C36B Fe2B C35B C34B -120.4(12) . . . . ?
C31B Fe2B C35B C34B 163.1(8) . . . . ?
C27B Fe2B C35B C34B -168.3(18) . . . . ?
C34B C35B C36B C32B -1.3(16) . . . . ?
Fe2B C35B C36B C32B -60.2(9) . . . . ?
C34B C35B C36B Fe2B 58.8(10) . . . . ?
C33B C32B C36B C35B 0.3(15) . . . . ?
Fe2B C32B C36B C35B 60.2(9) . . . . ?
C33B C32B C36B Fe2B -59.8(9) . . . . ?
C29B Fe2B C36B C35B 43.1(16) . . . . ?
C28B Fe2B C36B C35B -156(2) . . . . ?
C30B Fe2B C36B C35B 81.3(10) . . . . ?
C34B Fe2B C36B C35B -37.1(9) . . . . ?
C33B Fe2B C36B C35B -80.3(9) . . . . ?
C32B Fe2B C36B C35B -117.3(12) . . . . ?
C31B Fe2B C36B C35B 124.6(8) . . . . ?
C27B Fe2B C36B C35B 165.5(8) . . . . ?
C29B Fe2B C36B C32B 160.3(10) . . . . ?
C28B Fe2B C36B C32B -39(3) . . . . ?
C30B Fe2B C36B C32B -161.4(8) . . . . ?
C34B Fe2B C36B C32B 80.2(9) . . . . ?
C35B Fe2B C36B C32B 117.3(12) . . . . ?
C33B Fe2B C36B C32B 37.0(8) . . . . ?
C31B Fe2B C36B C32B -118.1(9) . . . . ?
C27B Fe2B C36B C32B -77.2(10) . . . . ?
C39B N2B C38B O2B -4.3(13) . . . . ?
Au1B N2B C38B O2B -162.7(7) . . . . ?
C39B N2B C38B C28B 175.5(11) . . . . ?
Au1B N2B C38B C28B 17.1(16) . . . . ?
C40B O2B C38B N2B -4.9(14) . . . . ?
C40B O2B C38B C28B 175.3(10) . . . . ?
C29B C28B C38B N2B -158.9(12) . . . . ?
C27B C28B C38B N2B 9.1(19) . . . . ?
Fe2B C28B C38B N2B -77.1(14) . . . . ?
C29B C28B C38B O2B 20.9(17) . . . . ?
C27B C28B C38B O2B -171.2(11) . . . . ?
Fe2B C28B C38B O2B 102.7(11) . . . . ?
C38B N2B C39B C47B 138.5(11) . . . . ?
Au1B N2B C39B C47B -63.9(13) . . . . ?
C38B N2B C39B C40B 11.3(12) . . . . ?
Au1B N2B C39B C40B 169.0(7) . . . . ?
C38B O2B C40B C41B 135.3(10) . . . . ?
C38B O2B C40B C39B 11.6(12) . . . . ?
C47B C39B C40B O2B -140.3(11) . . . . ?
N2B C39B C40B O2B -13.6(12) . . . . ?
C47B C39B C40B C41B 99.9(14) . . . . ?
N2B C39B C40B C41B -133.4(11) . . . . ?
O2B C40B C41B C46B 121.1(14) . . . . ?
C39B C40B C41B C46B -123.1(14) . . . . ?
O2B C40B C41B C42B -59.9(16) . . . . ?
C39B C40B C41B C42B 55.9(18) . . . . ?
C46B C41B C42B C43B 0(2) . . . . ?
C40B C41B C42B C43B -179.2(13) . . . . ?
C41B C42B C43B C44B 0(2) . . . . ?
C42B C43B C44B C45B -2(3) . . . . ?
C43B C44B C45B C46B 3(2) . . . . ?
C42B C41B C46B C45B 2(2) . . . . ?
C40B C41B C46B C45B -178.7(13) . . . . ?
C44B C45B C46B C41B -4(2) . . . . ?
C40B C39B C47B C48B -94.6(18) . . . . ?
N2B C39B C47B C48B 143.5(15) . . . . ?
C40B C39B C47B C52B 77.0(18) . . . . ?
N2B C39B C47B C52B -45.0(18) . . . . ?
C52B C47B C48B C49B 4(3) . . . . ?
C39B C47B C48B C49B 175.8(19) . . . . ?
C47B C48B C49B C50B -4(4) . . . . ?
C48B C49B C50B C51B 2(3) . . . . ?
C49B C50B C51B C52B -1(3) . . . . ?
C48B C47B C52B C51B -3(3) . . . . ?
C39B C47B C52B C51B -174.2(15) . . . . ?
C50B C51B C52B C47B 1(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        26.50
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         2.034
_refine_diff_density_min         -3.806
_refine_diff_density_rms         0.232
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2341lc1
_database_code_depnum_ccdc_archive 'CCDC 1588452'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'IndFOMeAu(II)Cl' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C42 H38 Au2 Cl2 Fe2 N2 O2, C H2 Cl2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C43 H38 Au2 Cl4 Fe2 N2 O2'
_chemical_formula_weight         1262.19

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe -1.1336 3.1974 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21'
_symmetry_space_group_name_Hall  'P 2yb'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   15.339(2)
_cell_length_b                   9.3952(11)
_cell_length_c                   27.543(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 95.049(14)
_cell_angle_gamma                90.00
_cell_volume                     3954.0(11)
_cell_formula_units_Z            4
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    7086
_cell_measurement_theta_min      3.18
_cell_measurement_theta_max      63.97

_exptl_crystal_description       needle
_exptl_crystal_colour            black
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.01
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.120
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2416
_exptl_absorpt_coefficient_mu    22.216
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.5707
_exptl_absorpt_correction_T_max  0.9811
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         I\mS
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            32602
_diffrn_reflns_av_R_equivalents  0.1931
_diffrn_reflns_av_sigmaI/netI    0.2320
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         3.18
_diffrn_reflns_theta_max         63.97
_reflns_number_total             12095
_reflns_number_gt                7086
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0361P)²+299.9015P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00112(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.04(3)
_refine_ls_number_reflns         12095
_refine_ls_number_parameters     972
_refine_ls_number_restraints     1160
_refine_ls_R_factor_all          0.1860
_refine_ls_R_factor_gt           0.1124
_refine_ls_wR_factor_ref         0.2615
_refine_ls_wR_factor_gt          0.2335
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_restrained_S_all      1.018
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1A Au 0.27219(9) 0.75383(15) 0.58007(6) 0.0099(3) Uani 1 1 d U . .
Fe1A Fe 0.3003(4) 1.0383(6) 0.6755(2) 0.0136(9) Uani 1 1 d U . .
Cl1A Cl 0.2847(6) 0.8735(10) 0.5037(3) 0.017(2) Uani 1 1 d U . .
Au2A Au 0.27118(9) 0.63503(15) 0.66191(6) 0.0099(3) Uani 1 1 d U . .
Fe2A Fe 0.5002(4) 0.5924(6) 0.6221(2) 0.0136(9) Uani 1 1 d U . .
Cl2A Cl 0.2739(6) 0.5255(10) 0.7405(3) 0.016(2) Uani 1 1 d . . .
N1A N 0.158(2) 0.729(3) 0.6739(11) 0.018(5) Uani 1 1 d U . .
O1A O 0.0515(17) 0.901(3) 0.6854(10) 0.024(7) Uani 1 1 d U . .
O2A O 0.3598(18) 0.356(3) 0.5270(10) 0.023(6) Uani 1 1 d U . .
N2A N 0.288(2) 0.560(3) 0.5438(11) 0.015(5) Uani 1 1 d U . .
C1A C 0.245(2) 0.935(3) 0.6152(11) 0.006(3) Uani 1 1 d DU . .
C2A C 0.189(2) 0.971(3) 0.6482(11) 0.006(3) Uani 1 1 d DU . .
C3A C 0.186(2) 1.113(3) 0.6569(11) 0.006(3) Uani 1 1 d DU . .
C4A C 0.237(2) 1.182(3) 0.6283(11) 0.006(3) Uani 1 1 d DU . .
H4A H 0.2436 1.2822 0.6253 0.008 Uiso 1 1 calc R . .
C5A C 0.280(2) 1.078(3) 0.6040(12) 0.006(3) Uani 1 1 d DU . .
H5A H 0.3251 1.0955 0.5832 0.008 Uiso 1 1 calc R . .
C6A C 0.398(2) 0.917(4) 0.7123(13) 0.020(4) Uani 1 1 d DU . .
H6A H 0.4223 0.8298 0.7026 0.024 Uiso 1 1 calc R . .
C7A C 0.328(2) 0.938(4) 0.7446(13) 0.020(4) Uani 1 1 d DU . .
H7A H 0.2953 0.8663 0.7592 0.024 Uiso 1 1 calc R . .
C8A C 0.319(2) 1.084(4) 0.7491(13) 0.020(4) Uani 1 1 d DU . .
H8A H 0.2772 1.1273 0.7679 0.024 Uiso 1 1 calc R . .
C9A C 0.377(2) 1.160(4) 0.7237(13) 0.020(4) Uani 1 1 d DU . .
H9A H 0.3835 1.2600 0.7236 0.024 Uiso 1 1 calc R . .
C10A C 0.423(2) 1.062(4) 0.6983(14) 0.020(4) Uani 1 1 d DU . .
H10A H 0.4638 1.0846 0.6755 0.024 Uiso 1 1 calc R . .
C11A C 0.122(2) 1.193(4) 0.6880(12) 0.007(3) Uani 1 1 d U . .
H11A H 0.1113 1.1343 0.7164 0.010 Uiso 1 1 calc R . .
H11B H 0.0670 1.2106 0.6684 0.010 Uiso 1 1 calc R . .
H11C H 0.1485 1.2835 0.6991 0.010 Uiso 1 1 calc R . .
C12A C 0.131(2) 0.864(3) 0.6650(12) 0.006(3) Uani 1 1 d U . .
C13A C 0.078(2) 0.647(4) 0.6902(14) 0.018(3) Uani 1 1 d U . .
H13A H 0.0962 0.5793 0.7171 0.021 Uiso 1 1 calc R . .
C14A C 0.021(2) 0.767(4) 0.7078(14) 0.018(3) Uani 1 1 d U . .
H14A H 0.0261 0.7732 0.7442 0.021 Uiso 1 1 calc R . .
C15A C -0.073(2) 0.738(4) 0.6884(14) 0.018(3) Uani 1 1 d U . .
H15A H -0.0996 0.8235 0.6722 0.021 Uiso 1 1 calc R . .
H15B H -0.1085 0.7087 0.7149 0.021 Uiso 1 1 calc R . .
C16A C -0.066(2) 0.617(4) 0.6518(14) 0.018(3) Uani 1 1 d U . .
C17A C 0.023(3) 0.580(4) 0.6523(14) 0.018(3) Uani 1 1 d U . .
C18A C 0.047(3) 0.487(4) 0.6158(14) 0.018(3) Uani 1 1 d U . .
H18A H 0.1069 0.4659 0.6142 0.021 Uiso 1 1 calc R . .
C19A C -0.012(2) 0.427(4) 0.5832(14) 0.018(3) Uani 1 1 d U . .
H19A H 0.0074 0.3589 0.5609 0.021 Uiso 1 1 calc R . .
C20A C -0.105(3) 0.464(4) 0.5815(14) 0.018(3) Uani 1 1 d U . .
H20A H -0.1476 0.4289 0.5573 0.021 Uiso 1 1 calc R . .
C21A C -0.126(3) 0.557(4) 0.6192(14) 0.018(3) Uani 1 1 d U . .
H21A H -0.1857 0.5782 0.6217 0.021 Uiso 1 1 calc R . .
C22A C 0.383(2) 0.535(4) 0.6503(12) 0.010(3) Uani 1 1 d U . .
C23A C 0.401(2) 0.460(4) 0.6051(13) 0.010(3) Uani 1 1 d U . .
C24A C 0.481(2) 0.375(4) 0.6164(13) 0.010(3) Uani 1 1 d U . .
C25A C 0.515(2) 0.414(4) 0.6640(12) 0.010(3) Uani 1 1 d U . .
H25A H 0.5669 0.3782 0.6806 0.012 Uiso 1 1 calc R . .
C26A C 0.454(2) 0.519(4) 0.6837(13) 0.010(3) Uani 1 1 d U . .
H26A H 0.4630 0.5666 0.7142 0.012 Uiso 1 1 calc R . .
C27A C 0.502(3) 0.798(5) 0.6003(16) 0.028(4) Uani 1 1 d U . .
H27A H 0.4541 0.8620 0.6019 0.033 Uiso 1 1 calc R . .
C28A C 0.510(3) 0.715(4) 0.5572(16) 0.028(4) Uani 1 1 d U . .
H28A H 0.4749 0.7127 0.5269 0.033 Uiso 1 1 calc R . .
C29A C 0.589(3) 0.636(5) 0.5749(15) 0.028(4) Uani 1 1 d U . .
H29A H 0.6153 0.5659 0.5561 0.033 Uiso 1 1 calc R . .
C30A C 0.620(3) 0.672(4) 0.6202(15) 0.028(4) Uani 1 1 d U . .
H30A H 0.6702 0.6322 0.6380 0.033 Uiso 1 1 calc R . .
C31A C 0.561(3) 0.786(4) 0.6377(16) 0.028(4) Uani 1 1 d U . .
H31A H 0.5658 0.8361 0.6677 0.033 Uiso 1 1 calc R . .
C32A C 0.522(2) 0.271(4) 0.5864(12) 0.010(3) Uani 1 1 d U . .
H32A H 0.5787 0.2433 0.6026 0.015 Uiso 1 1 calc R . .
H32B H 0.5302 0.3134 0.5546 0.015 Uiso 1 1 calc R . .
H32C H 0.4840 0.1875 0.5819 0.015 Uiso 1 1 calc R . .
C33A C 0.344(2) 0.458(4) 0.5591(13) 0.010(3) Uani 1 1 d U . .
C34A C 0.255(2) 0.531(4) 0.4926(13) 0.012(2) Uani 1 1 d U . .
H34A H 0.2723 0.6078 0.4704 0.014 Uiso 1 1 calc R . .
C35A C 0.301(2) 0.391(4) 0.4829(13) 0.012(2) Uani 1 1 d U . .
H35A H 0.3315 0.3923 0.4523 0.014 Uiso 1 1 calc R . .
C36A C 0.228(2) 0.271(4) 0.4833(13) 0.011(2) Uani 1 1 d U . .
H36A H 0.2311 0.2220 0.5152 0.014 Uiso 1 1 calc R . .
H36B H 0.2341 0.2004 0.4573 0.014 Uiso 1 1 calc R . .
C37A C 0.137(2) 0.362(4) 0.4735(13) 0.012(2) Uani 1 1 d U . .
C38A C 0.162(2) 0.498(4) 0.4840(13) 0.012(2) Uani 1 1 d U . .
C39A C 0.102(2) 0.604(4) 0.4769(12) 0.012(2) Uani 1 1 d U . .
H39A H 0.1191 0.7008 0.4808 0.014 Uiso 1 1 calc R . .
C40A C 0.013(2) 0.564(4) 0.4632(13) 0.012(2) Uani 1 1 d U . .
H40A H -0.0316 0.6354 0.4601 0.014 Uiso 1 1 calc R . .
C41A C -0.010(2) 0.420(4) 0.4545(13) 0.012(2) Uani 1 1 d U . .
H41A H -0.0688 0.3929 0.4469 0.014 Uiso 1 1 calc R . .
C42A C 0.061(2) 0.314(4) 0.4573(13) 0.012(2) Uani 1 1 d U . .
H42A H 0.0514 0.2170 0.4480 0.014 Uiso 1 1 calc R . .
Au1B Au 0.27305(17) 0.9756(2) 0.08142(8) 0.0416(7) Uani 1 1 d . . .
Fe1B Fe 0.2967(6) 1.2530(9) 0.1802(3) 0.046(2) Uani 1 1 d . . .
Cl1B Cl 0.2857(10) 1.1050(12) 0.0064(5) 0.049(4) Uani 1 1 d . . .
Au2B Au 0.27343(17) 0.8512(2) 0.16282(8) 0.0434(7) Uani 1 1 d . . .
Fe2B Fe 0.5003(6) 0.8027(8) 0.1232(3) 0.047(2) Uani 1 1 d . . .
Cl2B Cl 0.2810(10) 0.7474(14) 0.2422(4) 0.053(4) Uani 1 1 d . . .
N1B N 0.152(2) 0.936(3) 0.1727(12) 0.018(5) Uani 1 1 d U . .
O1B O 0.056(2) 1.109(3) 0.1895(11) 0.034(8) Uani 1 1 d U . .
N2B N 0.292(2) 0.790(3) 0.0445(10) 0.015(5) Uani 1 1 d DU . .
O2B O 0.3575(19) 0.578(3) 0.0251(10) 0.028(7) Uani 1 1 d U . .
C1B C 0.250(2) 1.168(3) 0.1199(13) 0.040(4) Uani 1 1 d DU . .
C2B C 0.174(2) 1.178(3) 0.1481(13) 0.040(4) Uani 1 1 d DU . .
C3B C 0.165(2) 1.329(4) 0.1672(13) 0.040(4) Uani 1 1 d DU . .
C4B C 0.243(3) 1.409(3) 0.1521(15) 0.040(4) Uani 1 1 d DU . .
H4B H 0.2607 1.5012 0.1619 0.048 Uiso 1 1 d . . .
C5B C 0.290(2) 1.314(3) 0.1185(14) 0.040(4) Uani 1 1 d DU . .
H5B H 0.3315 1.3404 0.0976 0.048 Uiso 1 1 d . . .
C6B C 0.395(3) 1.137(6) 0.2184(17) 0.050(5) Uani 1 1 d DU . .
H6B H 0.4143 1.0451 0.2104 0.060 Uiso 1 1 calc R . .
C7B C 0.323(3) 1.157(6) 0.2460(17) 0.050(5) Uani 1 1 d DU . .
H7B H 0.2884 1.0848 0.2586 0.060 Uiso 1 1 calc R . .
C8B C 0.313(4) 1.300(6) 0.2515(18) 0.050(5) Uani 1 1 d DU . .
H8B H 0.2680 1.3444 0.2681 0.060 Uiso 1 1 calc R . .
C9B C 0.383(3) 1.376(6) 0.2273(18) 0.050(5) Uani 1 1 d DU . .
H9B H 0.3918 1.4761 0.2273 0.060 Uiso 1 1 calc R . .
C10B C 0.437(3) 1.266(6) 0.2024(18) 0.050(5) Uani 1 1 d DU . .
H10B H 0.4844 1.2784 0.1826 0.060 Uiso 1 1 calc R . .
C11B C 0.107(3) 1.421(5) 0.1889(18) 0.040(4) Uani 1 1 d U . .
H11D H 0.1087 1.5156 0.1738 0.060 Uiso 1 1 calc R . .
H11E H 0.1246 1.4292 0.2239 0.060 Uiso 1 1 calc R . .
H11F H 0.0475 1.3830 0.1841 0.060 Uiso 1 1 calc R . .
C12B C 0.136(3) 1.066(5) 0.1750(18) 0.040(4) Uani 1 1 d U . .
C13B C 0.081(4) 0.862(6) 0.195(2) 0.048(4) Uani 1 1 d U . .
H13B H 0.1025 0.7941 0.2213 0.058 Uiso 1 1 calc R . .
C14B C 0.026(4) 0.976(6) 0.213(2) 0.048(4) Uani 1 1 d U . .
H14B H 0.0368 0.9842 0.2495 0.058 Uiso 1 1 calc R . .
C15B C -0.074(3) 0.937(6) 0.198(2) 0.048(4) Uani 1 1 d U . .
H15C H -0.1020 0.8891 0.2246 0.058 Uiso 1 1 calc R . .
H15D H -0.1091 1.0220 0.1872 0.058 Uiso 1 1 calc R . .
C16B C -0.064(4) 0.839(6) 0.157(2) 0.048(4) Uani 1 1 d U . .
C17B C 0.020(4) 0.789(6) 0.154(2) 0.048(4) Uani 1 1 d U . .
C18B C 0.045(4) 0.706(6) 0.1158(19) 0.048(4) Uani 1 1 d U . .
H18B H 0.1048 0.6917 0.1118 0.058 Uiso 1 1 calc R . .
C19B C -0.022(3) 0.641(6) 0.0818(19) 0.048(4) Uani 1 1 d U . .
H19B H -0.0090 0.5732 0.0579 0.058 Uiso 1 1 calc R . .
C20B C -0.103(4) 0.683(6) 0.087(2) 0.048(4) Uani 1 1 d U . .
H20B H -0.1507 0.6441 0.0670 0.058 Uiso 1 1 calc R . .
C21B C -0.119(4) 0.791(5) 0.124(2) 0.048(4) Uani 1 1 d U . .
H21B H -0.1770 0.8276 0.1236 0.058 Uiso 1 1 calc R . .
C22B C 0.381(3) 0.753(5) 0.1487(17) 0.038(4) Uani 1 1 d U . .
C23B C 0.392(3) 0.675(5) 0.1044(18) 0.038(4) Uani 1 1 d U . .
C24B C 0.477(3) 0.589(5) 0.1127(18) 0.038(4) Uani 1 1 d U . .
C25B C 0.507(3) 0.614(5) 0.1604(17) 0.038(4) Uani 1 1 d U . .
H25B H 0.5584 0.5685 0.1749 0.045 Uiso 1 1 calc R . .
C26B C 0.458(3) 0.710(5) 0.1877(18) 0.038(4) Uani 1 1 d U . .
H26B H 0.4687 0.7408 0.2206 0.045 Uiso 1 1 calc R . .
C27B C 0.502(4) 1.030(7) 0.108(2) 0.057(5) Uani 1 1 d U . .
H27B H 0.4581 1.1017 0.1098 0.068 Uiso 1 1 calc R . .
C28B C 0.524(4) 0.932(6) 0.067(2) 0.057(5) Uani 1 1 d U . .
H28B H 0.4917 0.9256 0.0362 0.068 Uiso 1 1 calc R . .
C29B C 0.597(4) 0.855(6) 0.082(2) 0.057(5) Uani 1 1 d U . .
H29B H 0.6289 0.7982 0.0607 0.068 Uiso 1 1 calc R . .
C30B C 0.618(4) 0.871(6) 0.131(2) 0.057(5) Uani 1 1 d U . .
H30B H 0.6588 0.8163 0.1517 0.068 Uiso 1 1 calc R . .
C31B C 0.571(4) 0.977(6) 0.144(2) 0.057(5) Uani 1 1 d U . .
H31B H 0.5813 1.0186 0.1756 0.068 Uiso 1 1 calc R . .
C32B C 0.526(3) 0.493(5) 0.0792(18) 0.038(4) Uani 1 1 d U . .
H32D H 0.5833 0.4687 0.0952 0.057 Uiso 1 1 calc R . .
H32E H 0.5329 0.5433 0.0486 0.057 Uiso 1 1 calc R . .
H32F H 0.4917 0.4061 0.0723 0.057 Uiso 1 1 calc R . .
C33B C 0.349(3) 0.695(5) 0.0586(18) 0.038(4) Uani 1 1 d U . .
C34B C 0.259(3) 0.754(6) -0.0056(12) 0.049(4) Uani 1 1 d DU . .
H34B H 0.2796 0.8300 -0.0275 0.059 Uiso 1 1 calc R . .
C35B C 0.311(4) 0.604(6) -0.018(2) 0.049(4) Uani 1 1 d U . .
H35B H 0.3472 0.6125 -0.0458 0.059 Uiso 1 1 calc R . .
C36B C 0.223(3) 0.501(6) -0.029(2) 0.049(4) Uani 1 1 d U . .
H36C H 0.2240 0.4565 -0.0615 0.059 Uiso 1 1 calc R . .
H36D H 0.2232 0.4247 -0.0042 0.059 Uiso 1 1 calc R . .
C37B C 0.149(4) 0.588(6) -0.027(2) 0.049(4) Uani 1 1 d U . .
C38B C 0.163(3) 0.745(6) -0.0150(19) 0.049(4) Uani 1 1 d U . .
C39B C 0.085(4) 0.831(6) -0.018(2) 0.049(4) Uani 1 1 d U . .
H39B H 0.0909 0.9262 -0.0067 0.059 Uiso 1 1 calc R . .
C40B C 0.007(4) 0.788(6) -0.035(2) 0.049(4) Uani 1 1 d U . .
H40B H -0.0407 0.8524 -0.0370 0.059 Uiso 1 1 calc R . .
C41B C -0.005(4) 0.653(6) -0.0507(19) 0.049(4) Uani 1 1 d U . .
H41B H -0.0595 0.6302 -0.0678 0.059 Uiso 1 1 calc R . .
C42B C 0.055(4) 0.547(6) -0.0440(19) 0.049(4) Uani 1 1 d U . .
H42B H 0.0382 0.4509 -0.0496 0.059 Uiso 1 1 calc R . .
C1X C 0.213(3) 0.676(5) 0.358(2) 0.047(13) Uani 1 1 d U . .
H1X1 H 0.2432 0.7497 0.3406 0.056 Uiso 1 1 calc R . .
H1X2 H 0.2053 0.7119 0.3913 0.056 Uiso 1 1 calc R . .
Cl1X Cl 0.2756(11) 0.5255(13) 0.3626(5) 0.060(4) Uani 1 1 d . . .
Cl2X Cl 0.1090(10) 0.6463(19) 0.3277(8) 0.085(6) Uani 1 1 d . . .
C1Y C 0.845(4) 0.366(6) 0.135(2) 0.054(15) Uani 1 1 d U . .
H1Y1 H 0.8982 0.3175 0.1257 0.064 Uiso 1 1 calc R . .
H1Y2 H 0.8269 0.4378 0.1097 0.064 Uiso 1 1 calc R . .
Cl1Y Cl 0.7537(13) 0.2322(18) 0.1404(6) 0.080(5) Uani 1 1 d . . .
Cl2Y Cl 0.8649(8) 0.4469(15) 0.1908(5) 0.054(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1A C1A 2.02(3) . ?
Au1A N2A 2.10(3) . ?
Au1A Cl1A 2.407(10) . ?
Au1A Au2A 2.517(2) . ?
Fe1A C2A 1.92(3) . ?
Fe1A C3A 1.92(3) . ?
Fe1A C10A 1.94(4) . ?
Fe1A C5A 2.00(3) . ?
Fe1A C1A 2.05(3) . ?
Fe1A C9A 2.04(4) . ?
Fe1A C4A 2.05(3) . ?
Fe1A C8A 2.07(4) . ?
Fe1A C6A 2.07(3) . ?
Fe1A C7A 2.13(4) . ?
Au2A N1A 2.00(3) . ?
Au2A C22A 2.01(4) . ?
Au2A Cl2A 2.394(9) . ?
Fe2A C23A 1.99(3) . ?
Fe2A C30A 1.99(4) . ?
Fe2A C29A 2.00(5) . ?
Fe2A C26A 2.02(4) . ?
Fe2A C27A 2.03(4) . ?
Fe2A C25A 2.04(4) . ?
Fe2A C24A 2.06(3) . ?
Fe2A C31A 2.07(4) . ?
Fe2A C22A 2.09(4) . ?
Fe2A C28A 2.15(4) . ?
N1A C12A 1.35(4) . ?
N1A C13A 1.54(5) . ?
O1A C12A 1.43(4) . ?
O1A C14A 1.50(5) . ?
O2A C33A 1.34(4) . ?
O2A C35A 1.49(4) . ?
N2A C33A 1.33(4) . ?
N2A C34A 1.48(4) . ?
C1A C2A 1.35(5) . ?
C1A C5A 1.50(5) . ?
C2A C3A 1.36(4) . ?
C2A C12A 1.44(5) . ?
C3A C4A 1.33(5) . ?
C3A C11A 1.54(5) . ?
C4A C5A 1.38(5) . ?
C4A H4A 0.9500 . ?
C5A H5A 0.9500 . ?
C6A C7A 1.47(6) . ?
C6A C10A 1.47(6) . ?
C6A H6A 0.9500 . ?
C7A C8A 1.38(6) . ?
C7A H7A 0.9500 . ?
C8A C9A 1.37(6) . ?
C8A H8A 0.9500 . ?
C9A C10A 1.39(6) . ?
C9A H9A 0.9500 . ?
C10A H10A 0.9500 . ?
C11A H11A 0.9800 . ?
C11A H11B 0.9800 . ?
C11A H11C 0.9800 . ?
C13A C17A 1.44(5) . ?
C13A C14A 1.53(5) . ?
C13A H13A 1.0000 . ?
C14A C15A 1.51(5) . ?
C14A H14A 1.0000 . ?
C15A C16A 1.53(5) . ?
C15A H15A 0.9900 . ?
C15A H15B 0.9900 . ?
C16A C21A 1.35(5) . ?
C16A C17A 1.41(5) . ?
C17A C18A 1.40(6) . ?
C18A C19A 1.33(5) . ?
C18A H18A 0.9500 . ?
C19A C20A 1.47(5) . ?
C19A H19A 0.9500 . ?
C20A C21A 1.41(5) . ?
C20A H20A 0.9500 . ?
C21A H21A 0.9500 . ?
C22A C26A 1.37(5) . ?
C22A C23A 1.48(5) . ?
C23A C24A 1.47(5) . ?
C23A C33A 1.48(4) . ?
C24A C25A 1.41(5) . ?
C24A C32A 1.46(5) . ?
C25A C26A 1.49(5) . ?
C25A H25A 0.9500 . ?
C26A H26A 0.9500 . ?
C27A C31A 1.32(6) . ?
C27A C28A 1.43(6) . ?
C27A H27A 0.9500 . ?
C28A C29A 1.47(6) . ?
C28A H28A 0.9500 . ?
C29A C30A 1.34(6) . ?
C29A H29A 0.9500 . ?
C30A C31A 1.51(6) . ?
C30A H30A 0.9500 . ?
C31A H31A 0.9500 . ?
C32A H32A 0.9800 . ?
C32A H32B 0.9800 . ?
C32A H32C 0.9800 . ?
C34A C38A 1.45(5) . ?
C34A C35A 1.52(5) . ?
C34A H34A 1.0000 . ?
C35A C36A 1.59(5) . ?
C35A H35A 1.0000 . ?
C36A C37A 1.64(5) . ?
C36A H36A 0.9900 . ?
C36A H36B 0.9900 . ?
C37A C42A 1.29(5) . ?
C37A C38A 1.36(5) . ?
C38A C39A 1.36(5) . ?
C39A C40A 1.45(5) . ?
C39A H39A 0.9500 . ?
C40A C41A 1.41(5) . ?
C40A H40A 0.9500 . ?
C41A C42A 1.47(5) . ?
C41A H41A 0.9500 . ?
C42A H42A 0.9500 . ?
Au1B N2B 2.05(3) . ?
Au1B C1B 2.14(2) . ?
Au1B Cl1B 2.420(13) . ?
Au1B Au2B 2.528(3) . ?
Fe1B C5B 1.79(4) . ?
Fe1B C4B 1.82(4) . ?
Fe1B C1B 1.93(3) . ?
Fe1B C8B 2.01(5) . ?
Fe1B C7B 2.03(5) . ?
Fe1B C6B 2.06(5) . ?
Fe1B C9B 2.11(5) . ?
Fe1B C2B 2.13(3) . ?
Fe1B C3B 2.14(3) . ?
Fe1B C10B 2.19(5) . ?
Au2B C22B 1.95(5) . ?
Au2B N1B 2.06(3) . ?
Au2B Cl2B 2.387(12) . ?
Fe2B C30B 1.92(6) . ?
Fe2B C29B 2.01(7) . ?
Fe2B C28B 2.02(6) . ?
Fe2B C31B 2.02(6) . ?
Fe2B C25B 2.05(5) . ?
Fe2B C24B 2.05(5) . ?
Fe2B C23B 2.07(5) . ?
Fe2B C22B 2.08(5) . ?
Fe2B C26B 2.13(5) . ?
Fe2B C27B 2.18(6) . ?
N1B C12B 1.26(6) . ?
N1B C13B 1.48(6) . ?
O1B C12B 1.39(6) . ?
O1B C14B 1.50(6) . ?
N2B C33B 1.29(5) . ?
N2B C34B 1.468(8) . ?
O2B C35B 1.35(6) . ?
O2B C33B 1.45(6) . ?
C1B C2B 1.460(9) . ?
C1B C5B 1.507(16) . ?
C2B C12B 1.44(6) . ?
C2B C3B 1.521(15) . ?
C3B C11B 1.41(6) . ?
C3B C4B 1.494(16) . ?
C4B C5B 1.510(16) . ?
C4B H4B 0.9440 . ?
C5B H5B 0.9293 . ?
C6B C7B 1.40(8) . ?
C6B C10B 1.46(8) . ?
C6B H6B 0.9500 . ?
C7B C8B 1.36(7) . ?
C7B H7B 0.9500 . ?
C8B C9B 1.50(8) . ?
C8B H8B 0.9500 . ?
C9B C10B 1.53(8) . ?
C9B H9B 0.9500 . ?
C10B H10B 0.9500 . ?
C11B H11D 0.9800 . ?
C11B H11E 0.9800 . ?
C11B H11F 0.9800 . ?
C13B C14B 1.47(7) . ?
C13B C17B 1.57(7) . ?
C13B H13B 1.0000 . ?
C14B C15B 1.61(7) . ?
C14B H14B 1.0000 . ?
C15B C16B 1.47(8) . ?
C15B H15C 0.9900 . ?
C15B H15D 0.9900 . ?
C16B C21B 1.27(7) . ?
C16B C17B 1.38(8) . ?
C17B C18B 1.38(8) . ?
C18B C19B 1.46(7) . ?
C18B H18B 0.9500 . ?
C19B C20B 1.32(7) . ?
C19B H19B 0.9500 . ?
C20B C21B 1.48(7) . ?
C20B H20B 0.9500 . ?
C21B H21B 0.9500 . ?
C22B C23B 1.44(7) . ?
C22B C26B 1.58(6) . ?
C23B C33B 1.38(6) . ?
C23B C24B 1.54(7) . ?
C24B C25B 1.37(6) . ?
C24B C32B 1.53(7) . ?
C25B C26B 1.44(7) . ?
C25B H25B 0.9500 . ?
C26B H26B 0.9500 . ?
C27B C31B 1.48(8) . ?
C27B C28B 1.51(8) . ?
C27B H27B 0.9500 . ?
C28B C29B 1.37(8) . ?
C28B H28B 0.9500 . ?
C29B C30B 1.39(8) . ?
C29B H29B 0.9500 . ?
C30B C31B 1.29(8) . ?
C30B H30B 0.9500 . ?
C31B H31B 0.9500 . ?
C32B H32D 0.9800 . ?
C32B H32E 0.9800 . ?
C32B H32F 0.9800 . ?
C34B C38B 1.47(7) . ?
C34B C35B 1.66(7) . ?
C34B H34B 1.0000 . ?
C35B C36B 1.66(7) . ?
C35B H35B 1.0000 . ?
C36B C37B 1.41(7) . ?
C36B H36C 0.9900 . ?
C36B H36D 0.9900 . ?
C37B C38B 1.52(8) . ?
C37B C42B 1.53(7) . ?
C38B C39B 1.44(7) . ?
C39B C40B 1.31(7) . ?
C39B H39B 0.9500 . ?
C40B C41B 1.35(7) . ?
C40B H40B 0.9500 . ?
C41B C42B 1.35(7) . ?
C41B H41B 0.9500 . ?
C42B H42B 0.9500 . ?
C1X Cl1X 1.71(5) . ?
C1X Cl2X 1.75(5) . ?
C1X H1X1 0.9900 . ?
C1X H1X2 0.9900 . ?
C1Y Cl2Y 1.72(6) . ?
C1Y Cl1Y 1.90(6) . ?
C1Y H1Y1 0.9900 . ?
C1Y H1Y2 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1A Au1A N2A 174.4(13) . . ?
C1A Au1A Cl1A 93.6(9) . . ?
N2A Au1A Cl1A 88.2(9) . . ?
C1A Au1A Au2A 85.7(9) . . ?
N2A Au1A Au2A 92.9(8) . . ?
Cl1A Au1A Au2A 175.5(2) . . ?
C2A Fe1A C3A 41.6(13) . . ?
C2A Fe1A C10A 166.1(15) . . ?
C3A Fe1A C10A 151.8(15) . . ?
C2A Fe1A C5A 67.7(13) . . ?
C3A Fe1A C5A 67.1(14) . . ?
C10A Fe1A C5A 111.0(16) . . ?
C2A Fe1A C1A 39.7(14) . . ?
C3A Fe1A C1A 69.7(13) . . ?
C10A Fe1A C1A 129.7(16) . . ?
C5A Fe1A C1A 43.4(13) . . ?
C2A Fe1A C9A 151.9(16) . . ?
C3A Fe1A C9A 115.3(14) . . ?
C10A Fe1A C9A 40.7(16) . . ?
C5A Fe1A C9A 124.5(15) . . ?
C1A Fe1A C9A 165.7(16) . . ?
C2A Fe1A C4A 67.4(13) . . ?
C3A Fe1A C4A 39.0(14) . . ?
C10A Fe1A C4A 121.2(15) . . ?
C5A Fe1A C4A 39.8(13) . . ?
C1A Fe1A C4A 70.2(12) . . ?
C9A Fe1A C4A 104.8(14) . . ?
C2A Fe1A C8A 119.7(15) . . ?
C3A Fe1A C8A 103.3(14) . . ?
C10A Fe1A C8A 67.2(17) . . ?
C5A Fe1A C8A 157.2(14) . . ?
C1A Fe1A C8A 155.0(15) . . ?
C9A Fe1A C8A 39.1(16) . . ?
C4A Fe1A C8A 120.0(14) . . ?
C2A Fe1A C6A 126.4(15) . . ?
C3A Fe1A C6A 159.5(16) . . ?
C10A Fe1A C6A 42.8(16) . . ?
C5A Fe1A C6A 128.7(15) . . ?
C1A Fe1A C6A 111.5(14) . . ?
C9A Fe1A C6A 68.8(14) . . ?
C4A Fe1A C6A 161.5(15) . . ?
C8A Fe1A C6A 66.6(15) . . ?
C2A Fe1A C7A 107.7(14) . . ?
C3A Fe1A C7A 120.3(15) . . ?
C10A Fe1A C7A 69.6(16) . . ?
C5A Fe1A C7A 164.2(14) . . ?
C1A Fe1A C7A 123.3(14) . . ?
C9A Fe1A C7A 66.9(15) . . ?
C4A Fe1A C7A 154.1(15) . . ?
C8A Fe1A C7A 38.4(15) . . ?
C6A Fe1A C7A 40.9(16) . . ?
N1A Au2A C22A 178.3(14) . . ?
N1A Au2A Cl2A 89.2(9) . . ?
C22A Au2A Cl2A 89.8(10) . . ?
N1A Au2A Au1A 91.5(9) . . ?
C22A Au2A Au1A 89.5(10) . . ?
Cl2A Au2A Au1A 178.4(2) . . ?
C23A Fe2A C30A 156.5(17) . . ?
C23A Fe2A C29A 121.5(16) . . ?
C30A Fe2A C29A 39.1(17) . . ?
C23A Fe2A C26A 70.5(14) . . ?
C30A Fe2A C26A 123.0(16) . . ?
C29A Fe2A C26A 157.5(15) . . ?
C23A Fe2A C27A 123.9(15) . . ?
C30A Fe2A C27A 66.4(18) . . ?
C29A Fe2A C27A 65.6(19) . . ?
C26A Fe2A C27A 126.2(17) . . ?
C23A Fe2A C25A 70.0(13) . . ?
C30A Fe2A C25A 105.7(15) . . ?
C29A Fe2A C25A 119.3(16) . . ?
C26A Fe2A C25A 43.2(14) . . ?
C27A Fe2A C25A 162.0(15) . . ?
C23A Fe2A C24A 42.4(14) . . ?
C30A Fe2A C24A 119.6(16) . . ?
C29A Fe2A C24A 104.6(17) . . ?
C26A Fe2A C24A 70.6(14) . . ?
C27A Fe2A C24A 157.8(15) . . ?
C25A Fe2A C24A 40.3(13) . . ?
C23A Fe2A C31A 157.0(16) . . ?
C30A Fe2A C31A 43.6(17) . . ?
C29A Fe2A C31A 68.6(19) . . ?
C26A Fe2A C31A 108.2(16) . . ?
C27A Fe2A C31A 37.5(16) . . ?
C25A Fe2A C31A 125.6(15) . . ?
C24A Fe2A C31A 160.3(15) . . ?
C23A Fe2A C22A 42.5(14) . . ?
C30A Fe2A C22A 159.0(16) . . ?
C29A Fe2A C22A 161.5(14) . . ?
C26A Fe2A C22A 38.9(13) . . ?
C27A Fe2A C22A 112.9(17) . . ?
C25A Fe2A C22A 68.4(14) . . ?
C24A Fe2A C22A 69.7(14) . . ?
C31A Fe2A C22A 122.4(16) . . ?
C23A Fe2A C28A 104.3(15) . . ?
C30A Fe2A C28A 69.2(16) . . ?
C29A Fe2A C28A 41.4(16) . . ?
C26A Fe2A C28A 160.1(15) . . ?
C27A Fe2A C28A 40.1(17) . . ?
C25A Fe2A C28A 154.7(16) . . ?
C24A Fe2A C28A 119.2(15) . . ?
C31A Fe2A C28A 68.7(17) . . ?
C22A Fe2A C28A 124.9(15) . . ?
C12A N1A C13A 106(3) . . ?
C12A N1A Au2A 130(3) . . ?
C13A N1A Au2A 123(2) . . ?
C12A O1A C14A 106(3) . . ?
C33A O2A C35A 104(3) . . ?
C33A N2A C34A 109(3) . . ?
C33A N2A Au1A 125(2) . . ?
C34A N2A Au1A 124(2) . . ?
C2A C1A C5A 100(3) . . ?
C2A C1A Au1A 135(3) . . ?
C5A C1A Au1A 124(3) . . ?
C2A C1A Fe1A 65.0(15) . . ?
C5A C1A Fe1A 66.8(16) . . ?
Au1A C1A Fe1A 134.5(15) . . ?
C1A C2A C3A 114(3) . . ?
C1A C2A C12A 119(3) . . ?
C3A C2A C12A 127(3) . . ?
C1A C2A Fe1A 75.3(17) . . ?
C3A C2A Fe1A 69.5(16) . . ?
C12A C2A Fe1A 131(2) . . ?
C4A C3A C2A 110(3) . . ?
C4A C3A C11A 122(3) . . ?
C2A C3A C11A 127(3) . . ?
C4A C3A Fe1A 75.9(18) . . ?
C2A C3A Fe1A 69.0(16) . . ?
C11A C3A Fe1A 129(2) . . ?
C3A C4A C5A 106(3) . . ?
C3A C4A Fe1A 65.2(16) . . ?
C5A C4A Fe1A 68.1(17) . . ?
C3A C4A H4A 126.9 . . ?
C5A C4A H4A 126.9 . . ?
Fe1A C4A H4A 131.3 . . ?
C4A C5A C1A 110(3) . . ?
C4A C5A Fe1A 72.1(18) . . ?
C1A C5A Fe1A 69.8(17) . . ?
C4A C5A H5A 125.0 . . ?
C1A C5A H5A 125.0 . . ?
Fe1A C5A H5A 124.6 . . ?
C7A C6A C10A 105(3) . . ?
C7A C6A Fe1A 71.7(18) . . ?
C10A C6A Fe1A 63.8(18) . . ?
C7A C6A H6A 127.6 . . ?
C10A C6A H6A 127.6 . . ?
Fe1A C6A H6A 128.3 . . ?
C8A C7A C6A 106(4) . . ?
C8A C7A Fe1A 68.3(19) . . ?
C6A C7A Fe1A 67.5(19) . . ?
C8A C7A H7A 127.2 . . ?
C6A C7A H7A 127.2 . . ?
Fe1A C7A H7A 128.6 . . ?
C9A C8A C7A 113(4) . . ?
C9A C8A Fe1A 69(2) . . ?
C7A C8A Fe1A 73(2) . . ?
C9A C8A H8A 123.4 . . ?
C7A C8A H8A 123.4 . . ?
Fe1A C8A H8A 125.6 . . ?
C8A C9A C10A 107(4) . . ?
C8A C9A Fe1A 72(2) . . ?
C10A C9A Fe1A 66(2) . . ?
C8A C9A H9A 126.4 . . ?
C10A C9A H9A 126.4 . . ?
Fe1A C9A H9A 127.6 . . ?
C9A C10A C6A 109(4) . . ?
C9A C10A Fe1A 73(2) . . ?
C6A C10A Fe1A 73(2) . . ?
C9A C10A H10A 125.6 . . ?
C6A C10A H10A 125.6 . . ?
Fe1A C10A H10A 119.4 . . ?
C3A C11A H11A 109.5 . . ?
C3A C11A H11B 109.5 . . ?
H11A C11A H11B 109.5 . . ?
C3A C11A H11C 109.5 . . ?
H11A C11A H11C 109.5 . . ?
H11B C11A H11C 109.5 . . ?
N1A C12A O1A 115(3) . . ?
N1A C12A C2A 122(3) . . ?
O1A C12A C2A 122(3) . . ?
C17A C13A C14A 103(3) . . ?
C17A C13A N1A 116(3) . . ?
C14A C13A N1A 103(3) . . ?
C17A C13A H13A 111.2 . . ?
C14A C13A H13A 111.2 . . ?
N1A C13A H13A 111.2 . . ?
O1A C14A C15A 109(3) . . ?
O1A C14A C13A 106(3) . . ?
C15A C14A C13A 108(3) . . ?
O1A C14A H14A 111.1 . . ?
C15A C14A H14A 111.1 . . ?
C13A C14A H14A 111.1 . . ?
C14A C15A C16A 104(3) . . ?
C14A C15A H15A 110.9 . . ?
C16A C15A H15A 110.9 . . ?
C14A C15A H15B 110.9 . . ?
C16A C15A H15B 110.9 . . ?
H15A C15A H15B 108.9 . . ?
C21A C16A C17A 120(4) . . ?
C21A C16A C15A 132(4) . . ?
C17A C16A C15A 108(3) . . ?
C18A C17A C16A 117(3) . . ?
C18A C17A C13A 128(4) . . ?
C16A C17A C13A 114(4) . . ?
C19A C18A C17A 123(4) . . ?
C19A C18A H18A 118.5 . . ?
C17A C18A H18A 118.5 . . ?
C18A C19A C20A 121(4) . . ?
C18A C19A H19A 119.5 . . ?
C20A C19A H19A 119.5 . . ?
C21A C20A C19A 114(3) . . ?
C21A C20A H20A 123.1 . . ?
C19A C20A H20A 123.1 . . ?
C16A C21A C20A 124(4) . . ?
C16A C21A H21A 117.8 . . ?
C20A C21A H21A 117.8 . . ?
C26A C22A C23A 108(3) . . ?
C26A C22A Au2A 126(3) . . ?
C23A C22A Au2A 126(2) . . ?
C26A C22A Fe2A 68(2) . . ?
C23A C22A Fe2A 65(2) . . ?
Au2A C22A Fe2A 135.7(18) . . ?
C24A C23A C33A 127(3) . . ?
C24A C23A C22A 107(3) . . ?
C33A C23A C22A 126(3) . . ?
C24A C23A Fe2A 71.7(19) . . ?
C33A C23A Fe2A 126(3) . . ?
C22A C23A Fe2A 72.5(19) . . ?
C25A C24A C32A 124(3) . . ?
C25A C24A C23A 107(3) . . ?
C32A C24A C23A 129(3) . . ?
C25A C24A Fe2A 68.9(19) . . ?
C32A C24A Fe2A 130(3) . . ?
C23A C24A Fe2A 66.0(18) . . ?
C24A C25A C26A 109(3) . . ?
C24A C25A Fe2A 71(2) . . ?
C26A C25A Fe2A 67.7(19) . . ?
C24A C25A H25A 125.7 . . ?
C26A C25A H25A 125.7 . . ?
Fe2A C25A H25A 127.4 . . ?
C22A C26A C25A 108(3) . . ?
C22A C26A Fe2A 73(2) . . ?
C25A C26A Fe2A 69(2) . . ?
C22A C26A H26A 125.9 . . ?
C25A C26A H26A 125.9 . . ?
Fe2A C26A H26A 123.2 . . ?
C31A C27A C28A 120(4) . . ?
C31A C27A Fe2A 73(3) . . ?
C28A C27A Fe2A 74(2) . . ?
C31A C27A H27A 120.1 . . ?
C28A C27A H27A 120.1 . . ?
Fe2A C27A H27A 123.8 . . ?
C27A C28A C29A 97(3) . . ?
C27A C28A Fe2A 66(2) . . ?
C29A C28A Fe2A 64(2) . . ?
C27A C28A H28A 131.4 . . ?
C29A C28A H28A 131.4 . . ?
Fe2A C28A H28A 130.1 . . ?
C30A C29A C28A 114(4) . . ?
C30A C29A Fe2A 70(3) . . ?
C28A C29A Fe2A 74(3) . . ?
C30A C29A H29A 123.2 . . ?
C28A C29A H29A 123.2 . . ?
Fe2A C29A H29A 124.0 . . ?
C29A C30A C31A 108(4) . . ?
C29A C30A Fe2A 71(3) . . ?
C31A C30A Fe2A 71(2) . . ?
C29A C30A H30A 126.2 . . ?
C31A C30A H30A 126.2 . . ?
Fe2A C30A H30A 123.2 . . ?
C27A C31A C30A 102(4) . . ?
C27A C31A Fe2A 69(3) . . ?
C30A C31A Fe2A 65(2) . . ?
C27A C31A H31A 129.1 . . ?
C30A C31A H31A 129.1 . . ?
Fe2A C31A H31A 127.7 . . ?
C24A C32A H32A 109.5 . . ?
C24A C32A H32B 109.5 . . ?
H32A C32A H32B 109.5 . . ?
C24A C32A H32C 109.5 . . ?
H32A C32A H32C 109.5 . . ?
H32B C32A H32C 109.5 . . ?
N2A C33A O2A 117(3) . . ?
N2A C33A C23A 126(3) . . ?
O2A C33A C23A 116(3) . . ?
C38A C34A N2A 116(3) . . ?
C38A C34A C35A 104(3) . . ?
N2A C34A C35A 102(3) . . ?
C38A C34A H34A 111.3 . . ?
N2A C34A H34A 111.3 . . ?
C35A C34A H34A 111.3 . . ?
O2A C35A C34A 108(3) . . ?
O2A C35A C36A 102(3) . . ?
C34A C35A C36A 106(3) . . ?
O2A C35A H35A 113.4 . . ?
C34A C35A H35A 113.4 . . ?
C36A C35A H35A 113.4 . . ?
C35A C36A C37A 103(3) . . ?
C35A C36A H36A 111.2 . . ?
C37A C36A H36A 111.2 . . ?
C35A C36A H36B 111.2 . . ?
C37A C36A H36B 111.2 . . ?
H36A C36A H36B 109.1 . . ?
C42A C37A C38A 130(3) . . ?
C42A C37A C36A 127(3) . . ?
C38A C37A C36A 103(3) . . ?
C39A C38A C37A 119(3) . . ?
C39A C38A C34A 120(3) . . ?
C37A C38A C34A 120(3) . . ?
C38A C39A C40A 118(3) . . ?
C38A C39A H39A 121.1 . . ?
C40A C39A H39A 121.1 . . ?
C41A C40A C39A 120(3) . . ?
C41A C40A H40A 120.0 . . ?
C39A C40A H40A 120.0 . . ?
C40A C41A C42A 119(3) . . ?
C40A C41A H41A 120.6 . . ?
C42A C41A H41A 120.6 . . ?
C37A C42A C41A 114(3) . . ?
C37A C42A H42A 122.8 . . ?
C41A C42A H42A 122.8 . . ?
N2B Au1B C1B 178.6(13) . . ?
N2B Au1B Cl1B 88.7(9) . . ?
C1B Au1B Cl1B 91.6(10) . . ?
N2B Au1B Au2B 93.3(8) . . ?
C1B Au1B Au2B 86.5(10) . . ?
Cl1B Au1B Au2B 174.6(3) . . ?
C5B Fe1B C4B 49.4(9) . . ?
C5B Fe1B C1B 47.7(9) . . ?
C4B Fe1B C1B 81.0(12) . . ?
C5B Fe1B C8B 148.2(19) . . ?
C4B Fe1B C8B 104.5(19) . . ?
C1B Fe1B C8B 160(2) . . ?
C5B Fe1B C7B 169(2) . . ?
C4B Fe1B C7B 141(2) . . ?
C1B Fe1B C7B 128.2(18) . . ?
C8B Fe1B C7B 39(2) . . ?
C5B Fe1B C6B 129(2) . . ?
C4B Fe1B C6B 157(2) . . ?
C1B Fe1B C6B 115.0(18) . . ?
C8B Fe1B C6B 66(2) . . ?
C7B Fe1B C6B 40(2) . . ?
C5B Fe1B C9B 112.8(19) . . ?
C4B Fe1B C9B 93.3(18) . . ?
C1B Fe1B C9B 157(2) . . ?
C8B Fe1B C9B 43(2) . . ?
C7B Fe1B C9B 68(2) . . ?
C6B Fe1B C9B 66(2) . . ?
C5B Fe1B C2B 74.6(11) . . ?
C4B Fe1B C2B 74.6(10) . . ?
C1B Fe1B C2B 41.8(6) . . ?
C8B Fe1B C2B 120(2) . . ?
C7B Fe1B C2B 109.0(18) . . ?
C6B Fe1B C2B 128.0(18) . . ?
C9B Fe1B C2B 156.6(19) . . ?
C5B Fe1B C3B 75.9(11) . . ?
C4B Fe1B C3B 43.4(8) . . ?
C1B Fe1B C3B 73.6(9) . . ?
C8B Fe1B C3B 97.0(19) . . ?
C7B Fe1B C3B 114.1(19) . . ?
C6B Fe1B C3B 153.4(19) . . ?
C9B Fe1B C3B 116.6(18) . . ?
C2B Fe1B C3B 41.7(7) . . ?
C5B Fe1B C10B 102.7(19) . . ?
C4B Fe1B C10B 118.1(18) . . ?
C1B Fe1B C10B 123.3(18) . . ?
C8B Fe1B C10B 72(2) . . ?
C7B Fe1B C10B 70(2) . . ?
C6B Fe1B C10B 40(2) . . ?
C9B Fe1B C10B 42(2) . . ?
C2B Fe1B C10B 161.4(18) . . ?
C3B Fe1B C10B 156.4(17) . . ?
C22B Au2B N1B 173.0(16) . . ?
C22B Au2B Cl2B 90.9(14) . . ?
N1B Au2B Cl2B 90.4(10) . . ?
C22B Au2B Au1B 88.8(14) . . ?
N1B Au2B Au1B 90.4(9) . . ?
Cl2B Au2B Au1B 175.7(4) . . ?
C30B Fe2B C29B 41(2) . . ?
C30B Fe2B C28B 70(2) . . ?
C29B Fe2B C28B 40(2) . . ?
C30B Fe2B C31B 38(2) . . ?
C29B Fe2B C31B 64(3) . . ?
C28B Fe2B C31B 67(2) . . ?
C30B Fe2B C25B 103(2) . . ?
C29B Fe2B C25B 119(2) . . ?
C28B Fe2B C25B 154(2) . . ?
C31B Fe2B C25B 124(2) . . ?
C30B Fe2B C24B 119(2) . . ?
C29B Fe2B C24B 106(2) . . ?
C28B Fe2B C24B 121(2) . . ?
C31B Fe2B C24B 156(2) . . ?
C25B Fe2B C24B 39.1(18) . . ?
C30B Fe2B C23B 162(2) . . ?
C29B Fe2B C23B 128(2) . . ?
C28B Fe2B C23B 111(2) . . ?
C31B Fe2B C23B 160(2) . . ?
C25B Fe2B C23B 68.3(18) . . ?
C24B Fe2B C23B 43.8(19) . . ?
C30B Fe2B C22B 153(2) . . ?
C29B Fe2B C22B 165(2) . . ?
C28B Fe2B C22B 128(2) . . ?
C31B Fe2B C22B 124(2) . . ?
C25B Fe2B C22B 69.1(19) . . ?
C24B Fe2B C22B 71(2) . . ?
C23B Fe2B C22B 40.8(19) . . ?
C30B Fe2B C26B 113(2) . . ?
C29B Fe2B C26B 150(2) . . ?
C28B Fe2B C26B 166(2) . . ?
C31B Fe2B C26B 107(2) . . ?
C25B Fe2B C26B 40.1(18) . . ?
C24B Fe2B C26B 70(2) . . ?
C23B Fe2B C26B 71.1(19) . . ?
C22B Fe2B C26B 44.1(17) . . ?
C30B Fe2B C27B 71(2) . . ?
C29B Fe2B C27B 68(2) . . ?
C28B Fe2B C27B 42(2) . . ?
C31B Fe2B C27B 41(2) . . ?
C25B Fe2B C27B 161(2) . . ?
C24B Fe2B C27B 159(2) . . ?
C23B Fe2B C27B 123(2) . . ?
C22B Fe2B C27B 108(2) . . ?
C26B Fe2B C27B 125(2) . . ?
C12B N1B C13B 106(4) . . ?
C12B N1B Au2B 125(3) . . ?
C13B N1B Au2B 126(3) . . ?
C12B O1B C14B 101(4) . . ?
C33B N2B C34B 107(4) . . ?
C33B N2B Au1B 124(3) . . ?
C34B N2B Au1B 127(3) . . ?
C35B O2B C33B 110(4) . . ?
C2B C1B C5B 107.5(7) . . ?
C2B C1B Fe1B 76.7(14) . . ?
C5B C1B Fe1B 61.4(15) . . ?
C2B C1B Au1B 119.6(19) . . ?
C5B C1B Au1B 132.2(19) . . ?
Fe1B C1B Au1B 135.2(18) . . ?
C12B C2B C1B 127(3) . . ?
C12B C2B C3B 117(3) . . ?
C1B C2B C3B 110.0(7) . . ?
C12B C2B Fe1B 114(3) . . ?
C1B C2B Fe1B 61.5(13) . . ?
C3B C2B Fe1B 69.5(13) . . ?
C11B C3B C4B 111(3) . . ?
C11B C3B C2B 142(3) . . ?
C4B C3B C2B 106.0(7) . . ?
C11B C3B Fe1B 139(3) . . ?
C4B C3B Fe1B 56.8(15) . . ?
C2B C3B Fe1B 68.8(12) . . ?
C3B C4B C5B 108.2(7) . . ?
C3B C4B Fe1B 79.8(16) . . ?
C5B C4B Fe1B 64.2(17) . . ?
C3B C4B H4B 126.9 . . ?
C5B C4B H4B 124.8 . . ?
Fe1B C4B H4B 120.5 . . ?
C1B C5B C4B 107.5(7) . . ?
C1B C5B Fe1B 70.9(16) . . ?
C4B C5B Fe1B 66.3(18) . . ?
C1B C5B H5B 124.0 . . ?
C4B C5B H5B 128.2 . . ?
Fe1B C5B H5B 133.2 . . ?
C7B C6B C10B 116(5) . . ?
C7B C6B Fe1B 69(2) . . ?
C10B C6B Fe1B 75(3) . . ?
C7B C6B H6B 121.8 . . ?
C10B C6B H6B 121.8 . . ?
Fe1B C6B H6B 126.5 . . ?
C8B C7B C6B 107(6) . . ?
C8B C7B Fe1B 69(3) . . ?
C6B C7B Fe1B 71(3) . . ?
C8B C7B H7B 126.3 . . ?
C6B C7B H7B 126.3 . . ?
Fe1B C7B H7B 124.7 . . ?
C7B C8B C9B 109(6) . . ?
C7B C8B Fe1B 71(3) . . ?
C9B C8B Fe1B 72(3) . . ?
C7B C8B H8B 125.6 . . ?
C9B C8B H8B 125.6 . . ?
Fe1B C8B H8B 122.4 . . ?
C8B C9B C10B 109(5) . . ?
C8B C9B Fe1B 65(2) . . ?
C10B C9B Fe1B 72(3) . . ?
C8B C9B H9B 125.6 . . ?
C10B C9B H9B 125.6 . . ?
Fe1B C9B H9B 128.8 . . ?
C6B C10B C9B 98(5) . . ?
C6B C10B Fe1B 65(3) . . ?
C9B C10B Fe1B 66(3) . . ?
C6B C10B H10B 130.8 . . ?
C9B C10B H10B 130.8 . . ?
Fe1B C10B H10B 128.8 . . ?
C3B C11B H11D 109.5 . . ?
C3B C11B H11E 109.5 . . ?
H11D C11B H11E 109.5 . . ?
C3B C11B H11F 109.5 . . ?
H11D C11B H11F 109.5 . . ?
H11E C11B H11F 109.5 . . ?
N1B C12B O1B 119(4) . . ?
N1B C12B C2B 127(5) . . ?
O1B C12B C2B 110(4) . . ?
N1B C13B C14B 106(4) . . ?
N1B C13B C17B 108(4) . . ?
C14B C13B C17B 104(5) . . ?
N1B C13B H13B 112.7 . . ?
C14B C13B H13B 112.7 . . ?
C17B C13B H13B 112.7 . . ?
C13B C14B O1B 105(5) . . ?
C13B C14B C15B 108(4) . . ?
O1B C14B C15B 113(4) . . ?
C13B C14B H14B 110.3 . . ?
O1B C14B H14B 110.3 . . ?
C15B C14B H14B 110.3 . . ?
C16B C15B C14B 100(4) . . ?
C16B C15B H15C 111.7 . . ?
C14B C15B H15C 111.7 . . ?
C16B C15B H15D 111.7 . . ?
C14B C15B H15D 111.7 . . ?
H15C C15B H15D 109.5 . . ?
C21B C16B C17B 114(6) . . ?
C21B C16B C15B 131(6) . . ?
C17B C16B C15B 116(5) . . ?
C16B C17B C18B 124(5) . . ?
C16B C17B C13B 107(5) . . ?
C18B C17B C13B 128(5) . . ?
C17B C18B C19B 120(5) . . ?
C17B C18B H18B 120.0 . . ?
C19B C18B H18B 120.0 . . ?
C20B C19B C18B 114(5) . . ?
C20B C19B H19B 122.8 . . ?
C18B C19B H19B 122.8 . . ?
C19B C20B C21B 120(5) . . ?
C19B C20B H20B 120.0 . . ?
C21B C20B H20B 120.0 . . ?
C16B C21B C20B 127(6) . . ?
C16B C21B H21B 116.7 . . ?
C20B C21B H21B 116.7 . . ?
C23B C22B C26B 108(4) . . ?
C23B C22B Au2B 125(3) . . ?
C26B C22B Au2B 125(3) . . ?
C23B C22B Fe2B 69(3) . . ?
C26B C22B Fe2B 70(3) . . ?
Au2B C22B Fe2B 138(3) . . ?
C33B C23B C22B 128(5) . . ?
C33B C23B C24B 122(5) . . ?
C22B C23B C24B 108(4) . . ?
C33B C23B Fe2B 117(4) . . ?
C22B C23B Fe2B 70(3) . . ?
C24B C23B Fe2B 67(3) . . ?
C25B C24B C32B 123(4) . . ?
C25B C24B C23B 105(4) . . ?
C32B C24B C23B 132(4) . . ?
C25B C24B Fe2B 70(3) . . ?
C32B C24B Fe2B 125(4) . . ?
C23B C24B Fe2B 69(3) . . ?
C24B C25B C26B 117(4) . . ?
C24B C25B Fe2B 71(3) . . ?
C26B C25B Fe2B 73(3) . . ?
C24B C25B H25B 121.3 . . ?
C26B C25B H25B 121.3 . . ?
Fe2B C25B H25B 127.0 . . ?
C25B C26B C22B 102(4) . . ?
C25B C26B Fe2B 67(3) . . ?
C22B C26B Fe2B 66(2) . . ?
C25B C26B H26B 129.2 . . ?
C22B C26B H26B 129.2 . . ?
Fe2B C26B H26B 129.2 . . ?
C31B C27B C28B 95(5) . . ?
C31B C27B Fe2B 64(3) . . ?
C28B C27B Fe2B 63(3) . . ?
C31B C27B H27B 132.3 . . ?
C28B C27B H27B 132.3 . . ?
Fe2B C27B H27B 131.5 . . ?
C29B C28B C27B 110(5) . . ?
C29B C28B Fe2B 70(4) . . ?
C27B C28B Fe2B 75(3) . . ?
C29B C28B H28B 125.0 . . ?
C27B C28B H28B 125.0 . . ?
Fe2B C28B H28B 122.1 . . ?
C28B C29B C30B 110(6) . . ?
C28B C29B Fe2B 70(4) . . ?
C30B C29B Fe2B 66(4) . . ?
C28B C29B H29B 124.9 . . ?
C30B C29B H29B 124.9 . . ?
Fe2B C29B H29B 130.7 . . ?
C31B C30B C29B 105(6) . . ?
C31B C30B Fe2B 75(4) . . ?
C29B C30B Fe2B 73(4) . . ?
C31B C30B H30B 127.3 . . ?
C29B C30B H30B 127.3 . . ?
Fe2B C30B H30B 116.7 . . ?
C30B C31B C27B 118(6) . . ?
C30B C31B Fe2B 66(4) . . ?
C27B C31B Fe2B 75(3) . . ?
C30B C31B H31B 121.2 . . ?
C27B C31B H31B 121.2 . . ?
Fe2B C31B H31B 129.3 . . ?
C24B C32B H32D 109.5 . . ?
C24B C32B H32E 109.5 . . ?
H32D C32B H32E 109.5 . . ?
C24B C32B H32F 109.5 . . ?
H32D C32B H32F 109.5 . . ?
H32E C32B H32F 109.5 . . ?
N2B C33B C23B 129(5) . . ?
N2B C33B O2B 115(4) . . ?
C23B C33B O2B 115(4) . . ?
N2B C34B C38B 116(4) . . ?
N2B C34B C35B 104(3) . . ?
C38B C34B C35B 113(4) . . ?
N2B C34B H34B 107.6 . . ?
C38B C34B H34B 107.6 . . ?
C35B C34B H34B 107.6 . . ?
O2B C35B C34B 102(4) . . ?
O2B C35B C36B 115(4) . . ?
C34B C35B C36B 98(4) . . ?
O2B C35B H35B 113.5 . . ?
C34B C35B H35B 113.5 . . ?
C36B C35B H35B 113.5 . . ?
C37B C36B C35B 107(4) . . ?
C37B C36B H36C 110.2 . . ?
C35B C36B H36C 110.2 . . ?
C37B C36B H36D 110.2 . . ?
C35B C36B H36D 110.2 . . ?
H36C C36B H36D 108.5 . . ?
C36B C37B C38B 118(5) . . ?
C36B C37B C42B 127(5) . . ?
C38B C37B C42B 115(5) . . ?
C39B C38B C34B 142(5) . . ?
C39B C38B C37B 116(5) . . ?
C34B C38B C37B 103(5) . . ?
C40B C39B C38B 125(5) . . ?
C40B C39B H39B 117.5 . . ?
C38B C39B H39B 117.5 . . ?
C39B C40B C41B 120(5) . . ?
C39B C40B H40B 120.1 . . ?
C41B C40B H40B 120.1 . . ?
C42B C41B C40B 125(5) . . ?
C42B C41B H41B 117.3 . . ?
C40B C41B H41B 117.3 . . ?
C41B C42B C37B 118(5) . . ?
C41B C42B H42B 121.0 . . ?
C37B C42B H42B 121.0 . . ?
Cl1X C1X Cl2X 113(3) . . ?
Cl1X C1X H1X1 109.0 . . ?
Cl2X C1X H1X1 109.0 . . ?
Cl1X C1X H1X2 109.0 . . ?
Cl2X C1X H1X2 109.0 . . ?
H1X1 C1X H1X2 107.8 . . ?
Cl2Y C1Y Cl1Y 107(3) . . ?
Cl2Y C1Y H1Y1 110.2 . . ?
Cl1Y C1Y H1Y1 110.2 . . ?
Cl2Y C1Y H1Y2 110.2 . . ?
Cl1Y C1Y H1Y2 110.2 . . ?
H1Y1 C1Y H1Y2 108.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1A Au1A Au2A N1A 47.9(12) . . . . ?
N2A Au1A Au2A N1A -126.7(12) . . . . ?
Cl1A Au1A Au2A N1A 129(3) . . . . ?
C1A Au1A Au2A C22A -133.5(13) . . . . ?
N2A Au1A Au2A C22A 51.9(13) . . . . ?
Cl1A Au1A Au2A C22A -52(3) . . . . ?
C1A Au1A Au2A Cl2A -69(9) . . . . ?
N2A Au1A Au2A Cl2A 116(9) . . . . ?
Cl1A Au1A Au2A Cl2A 12(10) . . . . ?
C22A Au2A N1A C12A -169(92) . . . . ?
Cl2A Au2A N1A C12A 136(3) . . . . ?
Au1A Au2A N1A C12A -42(3) . . . . ?
C22A Au2A N1A C13A 3(46) . . . . ?
Cl2A Au2A N1A C13A -52(3) . . . . ?
Au1A Au2A N1A C13A 130(3) . . . . ?
C1A Au1A N2A C33A -121(12) . . . . ?
Cl1A Au1A N2A C33A 130(3) . . . . ?
Au2A Au1A N2A C33A -45(3) . . . . ?
C1A Au1A N2A C34A 75(13) . . . . ?
Cl1A Au1A N2A C34A -34(3) . . . . ?
Au2A Au1A N2A C34A 150(3) . . . . ?
N2A Au1A C1A C2A 30(13) . . . . ?
Cl1A Au1A C1A C2A 139(2) . . . . ?
Au2A Au1A C1A C2A -46(2) . . . . ?
N2A Au1A C1A C5A -141(11) . . . . ?
Cl1A Au1A C1A C5A -32(2) . . . . ?
Au2A Au1A C1A C5A 143(2) . . . . ?
N2A Au1A C1A Fe1A 129(11) . . . . ?
Cl1A Au1A C1A Fe1A -123(2) . . . . ?
Au2A Au1A C1A Fe1A 53(2) . . . . ?
C3A Fe1A C1A C2A -36.5(19) . . . . ?
C10A Fe1A C1A C2A 167(2) . . . . ?
C5A Fe1A C1A C2A -114(2) . . . . ?
C9A Fe1A C1A C2A -150(5) . . . . ?
C4A Fe1A C1A C2A -78(2) . . . . ?
C8A Fe1A C1A C2A 41(4) . . . . ?
C6A Fe1A C1A C2A 122(2) . . . . ?
C7A Fe1A C1A C2A 77(2) . . . . ?
C2A Fe1A C1A C5A 114(2) . . . . ?
C3A Fe1A C1A C5A 78(2) . . . . ?
C10A Fe1A C1A C5A -78(2) . . . . ?
C9A Fe1A C1A C5A -36(6) . . . . ?
C4A Fe1A C1A C5A 36.1(18) . . . . ?
C8A Fe1A C1A C5A 155(3) . . . . ?
C6A Fe1A C1A C5A -124(2) . . . . ?
C7A Fe1A C1A C5A -169(2) . . . . ?
C2A Fe1A C1A Au1A -130(3) . . . . ?
C3A Fe1A C1A Au1A -166(3) . . . . ?
C10A Fe1A C1A Au1A 38(3) . . . . ?
C5A Fe1A C1A Au1A 116(3) . . . . ?
C9A Fe1A C1A Au1A 81(6) . . . . ?
C4A Fe1A C1A Au1A 152(3) . . . . ?
C8A Fe1A C1A Au1A -89(4) . . . . ?
C6A Fe1A C1A Au1A -8(3) . . . . ?
C7A Fe1A C1A Au1A -53(3) . . . . ?
C5A C1A C2A C3A 1.0(17) . . . . ?
Au1A C1A C2A C3A -172(2) . . . . ?
Fe1A C1A C2A C3A 59.3(14) . . . . ?
C5A C1A C2A C12A 172(3) . . . . ?
Au1A C1A C2A C12A 0(4) . . . . ?
Fe1A C1A C2A C12A -129(2) . . . . ?
C5A C1A C2A Fe1A -58.4(15) . . . . ?
Au1A C1A C2A Fe1A 129(2) . . . . ?
C3A Fe1A C2A C1A 123(3) . . . . ?
C10A Fe1A C2A C1A -45(7) . . . . ?
C5A Fe1A C2A C1A 42.6(19) . . . . ?
C9A Fe1A C2A C1A 165(3) . . . . ?
C4A Fe1A C2A C1A 86(2) . . . . ?
C8A Fe1A C2A C1A -161.4(19) . . . . ?
C6A Fe1A C2A C1A -80(2) . . . . ?
C7A Fe1A C2A C1A -121(2) . . . . ?
C10A Fe1A C2A C3A -168(6) . . . . ?
C5A Fe1A C2A C3A -80(2) . . . . ?
C1A Fe1A C2A C3A -123(3) . . . . ?
C9A Fe1A C2A C3A 42(4) . . . . ?
C4A Fe1A C2A C3A -36.9(19) . . . . ?
C8A Fe1A C2A C3A 76(2) . . . . ?
C6A Fe1A C2A C3A 157(2) . . . . ?
C7A Fe1A C2A C3A 116(2) . . . . ?
C3A Fe1A C2A C12A -121(4) . . . . ?
C10A Fe1A C2A C12A 71(8) . . . . ?
C5A Fe1A C2A C12A 159(4) . . . . ?
C1A Fe1A C2A C12A 116(4) . . . . ?
C9A Fe1A C2A C12A -79(4) . . . . ?
C4A Fe1A C2A C12A -158(4) . . . . ?
C8A Fe1A C2A C12A -45(4) . . . . ?
C6A Fe1A C2A C12A 36(4) . . . . ?
C7A Fe1A C2A C12A -5(4) . . . . ?
C1A C2A C3A C4A 3(2) . . . . ?
C12A C2A C3A C4A -168(3) . . . . ?
Fe1A C2A C3A C4A 65.3(18) . . . . ?
C1A C2A C3A C11A 173(3) . . . . ?
C12A C2A C3A C11A 2(4) . . . . ?
Fe1A C2A C3A C11A -124(3) . . . . ?
C1A C2A C3A Fe1A -62.7(15) . . . . ?
C12A C2A C3A Fe1A 127(3) . . . . ?
C2A Fe1A C3A C4A -118(3) . . . . ?
C10A Fe1A C3A C4A 55(4) . . . . ?
C5A Fe1A C3A C4A -36.5(19) . . . . ?
C1A Fe1A C3A C4A -83(2) . . . . ?
C9A Fe1A C3A C4A 82(2) . . . . ?
C8A Fe1A C3A C4A 122(2) . . . . ?
C6A Fe1A C3A C4A 179(4) . . . . ?
C7A Fe1A C3A C4A 159(2) . . . . ?
C10A Fe1A C3A C2A 174(3) . . . . ?
C5A Fe1A C3A C2A 82(2) . . . . ?
C1A Fe1A C3A C2A 35(2) . . . . ?
C9A Fe1A C3A C2A -160(2) . . . . ?
C4A Fe1A C3A C2A 118(3) . . . . ?
C8A Fe1A C3A C2A -120(2) . . . . ?
C6A Fe1A C3A C2A -62(5) . . . . ?
C7A Fe1A C3A C2A -83(2) . . . . ?
C2A Fe1A C3A C11A 122(4) . . . . ?
C10A Fe1A C3A C11A -65(5) . . . . ?
C5A Fe1A C3A C11A -157(3) . . . . ?
C1A Fe1A C3A C11A 157(3) . . . . ?
C9A Fe1A C3A C11A -38(4) . . . . ?
C4A Fe1A C3A C11A -120(4) . . . . ?
C8A Fe1A C3A C11A 2(3) . . . . ?
C6A Fe1A C3A C11A 59(6) . . . . ?
C7A Fe1A C3A C11A 39(4) . . . . ?
C2A C3A C4A C5A -5(3) . . . . ?
C11A C3A C4A C5A -176(3) . . . . ?
Fe1A C3A C4A C5A 55.8(19) . . . . ?
C2A C3A C4A Fe1A -61.0(15) . . . . ?
C11A C3A C4A Fe1A 128(3) . . . . ?
C2A Fe1A C4A C3A 39(2) . . . . ?
C10A Fe1A C4A C3A -153(2) . . . . ?
C5A Fe1A C4A C3A 121(3) . . . . ?
C1A Fe1A C4A C3A 82(2) . . . . ?
C9A Fe1A C4A C3A -112(2) . . . . ?
C8A Fe1A C4A C3A -73(2) . . . . ?
C6A Fe1A C4A C3A -179(4) . . . . ?
C7A Fe1A C4A C3A -45(4) . . . . ?
C2A Fe1A C4A C5A -82(2) . . . . ?
C3A Fe1A C4A C5A -121(3) . . . . ?
C10A Fe1A C4A C5A 86(2) . . . . ?
C1A Fe1A C4A C5A -39(2) . . . . ?
C9A Fe1A C4A C5A 127(2) . . . . ?
C8A Fe1A C4A C5A 166(2) . . . . ?
C6A Fe1A C4A C5A 60(5) . . . . ?
C7A Fe1A C4A C5A -166(3) . . . . ?
C3A C4A C5A C1A 6(3) . . . . ?
Fe1A C4A C5A C1A 59.9(18) . . . . ?
C3A C4A C5A Fe1A -54.0(18) . . . . ?
C2A C1A C5A C4A -4(2) . . . . ?
Au1A C1A C5A C4A 170(2) . . . . ?
Fe1A C1A C5A C4A -61(2) . . . . ?
C2A C1A C5A Fe1A 57.1(14) . . . . ?
Au1A C1A C5A Fe1A -129(2) . . . . ?
C2A Fe1A C5A C4A 81(2) . . . . ?
C3A Fe1A C5A C4A 35.8(19) . . . . ?
C10A Fe1A C5A C4A -114(2) . . . . ?
C1A Fe1A C5A C4A 120(3) . . . . ?
C9A Fe1A C5A C4A -70(2) . . . . ?
C8A Fe1A C5A C4A -33(5) . . . . ?
C6A Fe1A C5A C4A -159(2) . . . . ?
C7A Fe1A C5A C4A 157(5) . . . . ?
C2A Fe1A C5A C1A -39.0(18) . . . . ?
C3A Fe1A C5A C1A -84(2) . . . . ?
C10A Fe1A C5A C1A 126(2) . . . . ?
C9A Fe1A C5A C1A 170(2) . . . . ?
C4A Fe1A C5A C1A -120(3) . . . . ?
C8A Fe1A C5A C1A -153(4) . . . . ?
C6A Fe1A C5A C1A 81(2) . . . . ?
C7A Fe1A C5A C1A 37(6) . . . . ?
C2A Fe1A C6A C7A -74(3) . . . . ?
C3A Fe1A C6A C7A -27(5) . . . . ?
C10A Fe1A C6A C7A 118(3) . . . . ?
C5A Fe1A C6A C7A -163(2) . . . . ?
C1A Fe1A C6A C7A -117(2) . . . . ?
C9A Fe1A C6A C7A 79(2) . . . . ?
C4A Fe1A C6A C7A 152(4) . . . . ?
C8A Fe1A C6A C7A 36(2) . . . . ?
C2A Fe1A C6A C10A 168(2) . . . . ?
C3A Fe1A C6A C10A -145(4) . . . . ?
C5A Fe1A C6A C10A 79(3) . . . . ?
C1A Fe1A C6A C10A 126(2) . . . . ?
C9A Fe1A C6A C10A -39(2) . . . . ?
C4A Fe1A C6A C10A 34(5) . . . . ?
C8A Fe1A C6A C10A -81(2) . . . . ?
C7A Fe1A C6A C10A -118(3) . . . . ?
C10A C6A C7A C8A -2.6(17) . . . . ?
Fe1A C6A C7A C8A -57.9(14) . . . . ?
C10A C6A C7A Fe1A 55.3(16) . . . . ?
C2A Fe1A C7A C8A -116(2) . . . . ?
C3A Fe1A C7A C8A -72(3) . . . . ?
C10A Fe1A C7A C8A 79(3) . . . . ?
C5A Fe1A C7A C8A 174(5) . . . . ?
C1A Fe1A C7A C8A -156(2) . . . . ?
C9A Fe1A C7A C8A 35(2) . . . . ?
C4A Fe1A C7A C8A -41(4) . . . . ?
C6A Fe1A C7A C8A 119(3) . . . . ?
C2A Fe1A C7A C6A 126(2) . . . . ?
C3A Fe1A C7A C6A 169(2) . . . . ?
C10A Fe1A C7A C6A -40(2) . . . . ?
C5A Fe1A C7A C6A 55(6) . . . . ?
C1A Fe1A C7A C6A 85(2) . . . . ?
C9A Fe1A C7A C6A -84(2) . . . . ?
C4A Fe1A C7A C6A -160(3) . . . . ?
C8A Fe1A C7A C6A -119(3) . . . . ?
C6A C7A C8A C9A -0.7(18) . . . . ?
Fe1A C7A C8A C9A -58.0(19) . . . . ?
C6A C7A C8A Fe1A 57.3(14) . . . . ?
C2A Fe1A C8A C9A -155(2) . . . . ?
C3A Fe1A C8A C9A -114(2) . . . . ?
C10A Fe1A C8A C9A 38(2) . . . . ?
C5A Fe1A C8A C9A -52(5) . . . . ?
C1A Fe1A C8A C9A 176(3) . . . . ?
C4A Fe1A C8A C9A -76(3) . . . . ?
C6A Fe1A C8A C9A 85(2) . . . . ?
C7A Fe1A C8A C9A 124(3) . . . . ?
C2A Fe1A C8A C7A 81(3) . . . . ?
C3A Fe1A C8A C7A 122(2) . . . . ?
C10A Fe1A C8A C7A -85(2) . . . . ?
C5A Fe1A C8A C7A -176(3) . . . . ?
C1A Fe1A C8A C7A 52(4) . . . . ?
C9A Fe1A C8A C7A -124(3) . . . . ?
C4A Fe1A C8A C7A 161(2) . . . . ?
C6A Fe1A C8A C7A -39(2) . . . . ?
C7A C8A C9A C10A 4(3) . . . . ?
Fe1A C8A C9A C10A -56(2) . . . . ?
C7A C8A C9A Fe1A 60.3(17) . . . . ?
C2A Fe1A C9A C8A 50(4) . . . . ?
C3A Fe1A C9A C8A 80(2) . . . . ?
C10A Fe1A C9A C8A -119(3) . . . . ?
C5A Fe1A C9A C8A 158(2) . . . . ?
C1A Fe1A C9A C8A -173(5) . . . . ?
C4A Fe1A C9A C8A 120(2) . . . . ?
C6A Fe1A C9A C8A -79(2) . . . . ?
C7A Fe1A C9A C8A -34(2) . . . . ?
C2A Fe1A C9A C10A 170(3) . . . . ?
C3A Fe1A C9A C10A -161(2) . . . . ?
C5A Fe1A C9A C10A -82(3) . . . . ?
C1A Fe1A C9A C10A -53(6) . . . . ?
C4A Fe1A C9A C10A -121(2) . . . . ?
C8A Fe1A C9A C10A 119(3) . . . . ?
C6A Fe1A C9A C10A 41(2) . . . . ?
C7A Fe1A C9A C10A 85(2) . . . . ?
C8A C9A C10A C6A -5(3) . . . . ?
Fe1A C9A C10A C6A -65(2) . . . . ?
C8A C9A C10A Fe1A 60(2) . . . . ?
C7A C6A C10A C9A 5(3) . . . . ?
Fe1A C6A C10A C9A 65(2) . . . . ?
C7A C6A C10A Fe1A -60.4(16) . . . . ?
C2A Fe1A C10A C9A -159(6) . . . . ?
C3A Fe1A C10A C9A 39(4) . . . . ?
C5A Fe1A C10A C9A 119(2) . . . . ?
C1A Fe1A C10A C9A 165(2) . . . . ?
C4A Fe1A C10A C9A 76(3) . . . . ?
C8A Fe1A C10A C9A -37(2) . . . . ?
C6A Fe1A C10A C9A -116(3) . . . . ?
C7A Fe1A C10A C9A -78(2) . . . . ?
C2A Fe1A C10A C6A -43(7) . . . . ?
C3A Fe1A C10A C6A 155(3) . . . . ?
C5A Fe1A C10A C6A -125(2) . . . . ?
C1A Fe1A C10A C6A -79(3) . . . . ?
C9A Fe1A C10A C6A 116(3) . . . . ?
C4A Fe1A C10A C6A -168(2) . . . . ?
C8A Fe1A C10A C6A 80(2) . . . . ?
C7A Fe1A C10A C6A 38(2) . . . . ?
C13A N1A C12A O1A 17(4) . . . . ?
Au2A N1A C12A O1A -170(2) . . . . ?
C13A N1A C12A C2A -179(3) . . . . ?
Au2A N1A C12A C2A -6(5) . . . . ?
C14A O1A C12A N1A -4(4) . . . . ?
C14A O1A C12A C2A -168(3) . . . . ?
C1A C2A C12A N1A 39(4) . . . . ?
C3A C2A C12A N1A -150(3) . . . . ?
Fe1A C2A C12A N1A -57(5) . . . . ?
C1A C2A C12A O1A -158(2) . . . . ?
C3A C2A C12A O1A 13(4) . . . . ?
Fe1A C2A C12A O1A 107(3) . . . . ?
C12A N1A C13A C17A 90(4) . . . . ?
Au2A N1A C13A C17A -83(4) . . . . ?
C12A N1A C13A C14A -22(3) . . . . ?
Au2A N1A C13A C14A 165(2) . . . . ?
C12A O1A C14A C15A -127(3) . . . . ?
C12A O1A C14A C13A -10(3) . . . . ?
C17A C13A C14A O1A -102(3) . . . . ?
N1A C13A C14A O1A 19(3) . . . . ?
C17A C13A C14A C15A 15(4) . . . . ?
N1A C13A C14A C15A 136(3) . . . . ?
O1A C14A C15A C16A 104(3) . . . . ?
C13A C14A C15A C16A -10(4) . . . . ?
C14A C15A C16A C21A -172(4) . . . . ?
C14A C15A C16A C17A 2(4) . . . . ?
C21A C16A C17A C18A 5(6) . . . . ?
C15A C16A C17A C18A -170(3) . . . . ?
C21A C16A C17A C13A -177(4) . . . . ?
C15A C16A C17A C13A 8(5) . . . . ?
C14A C13A C17A C18A 163(4) . . . . ?
N1A C13A C17A C18A 52(5) . . . . ?
C14A C13A C17A C16A -14(5) . . . . ?
N1A C13A C17A C16A -126(4) . . . . ?
C16A C17A C18A C19A -4(6) . . . . ?
C13A C17A C18A C19A 178(4) . . . . ?
C17A C18A C19A C20A 5(6) . . . . ?
C18A C19A C20A C21A -5(5) . . . . ?
C17A C16A C21A C20A -5(6) . . . . ?
C15A C16A C21A C20A 167(4) . . . . ?
C19A C20A C21A C16A 5(6) . . . . ?
N1A Au2A C22A C26A -96(45) . . . . ?
Cl2A Au2A C22A C26A -42(3) . . . . ?
Au1A Au2A C22A C26A 137(3) . . . . ?
N1A Au2A C22A C23A 80(45) . . . . ?
Cl2A Au2A C22A C23A 134(3) . . . . ?
Au1A Au2A C22A C23A -47(3) . . . . ?
N1A Au2A C22A Fe2A 170(92) . . . . ?
Cl2A Au2A C22A Fe2A -136(2) . . . . ?
Au1A Au2A C22A Fe2A 43(2) . . . . ?
C23A Fe2A C22A C26A 124(3) . . . . ?
C30A Fe2A C22A C26A -36(5) . . . . ?
C29A Fe2A C22A C26A 159(5) . . . . ?
C27A Fe2A C22A C26A -120(2) . . . . ?
C25A Fe2A C22A C26A 41(2) . . . . ?
C24A Fe2A C22A C26A 84(2) . . . . ?
C31A Fe2A C22A C26A -79(3) . . . . ?
C28A Fe2A C22A C26A -164(2) . . . . ?
C30A Fe2A C22A C23A -161(4) . . . . ?
C29A Fe2A C22A C23A 35(6) . . . . ?
C26A Fe2A C22A C23A -124(3) . . . . ?
C27A Fe2A C22A C23A 116(2) . . . . ?
C25A Fe2A C22A C23A -84(2) . . . . ?
C24A Fe2A C22A C23A -40.4(19) . . . . ?
C31A Fe2A C22A C23A 157(2) . . . . ?
C28A Fe2A C22A C23A 72(2) . . . . ?
C23A Fe2A C22A Au2A -117(3) . . . . ?
C30A Fe2A C22A Au2A 83(5) . . . . ?
C29A Fe2A C22A Au2A -82(6) . . . . ?
C26A Fe2A C22A Au2A 119(3) . . . . ?
C27A Fe2A C22A Au2A -1(3) . . . . ?
C25A Fe2A C22A Au2A 160(3) . . . . ?
C24A Fe2A C22A Au2A -157(3) . . . . ?
C31A Fe2A C22A Au2A 40(3) . . . . ?
C28A Fe2A C22A Au2A -45(3) . . . . ?
C26A C22A C23A C24A 10(4) . . . . ?
Au2A C22A C23A C24A -167(3) . . . . ?
Fe2A C22A C23A C24A 64(2) . . . . ?
C26A C22A C23A C33A -176(3) . . . . ?
Au2A C22A C23A C33A 7(5) . . . . ?
Fe2A C22A C23A C33A -123(4) . . . . ?
C26A C22A C23A Fe2A -54(3) . . . . ?
Au2A C22A C23A Fe2A 130(3) . . . . ?
C30A Fe2A C23A C24A 47(5) . . . . ?
C29A Fe2A C23A C24A 77(2) . . . . ?
C26A Fe2A C23A C24A -82(2) . . . . ?
C27A Fe2A C23A C24A 157(2) . . . . ?
C25A Fe2A C23A C24A -36(2) . . . . ?
C31A Fe2A C23A C24A -173(4) . . . . ?
C22A Fe2A C23A C24A -116(3) . . . . ?
C28A Fe2A C23A C24A 118(2) . . . . ?
C30A Fe2A C23A C33A -76(5) . . . . ?
C29A Fe2A C23A C33A -46(4) . . . . ?
C26A Fe2A C23A C33A 155(4) . . . . ?
C27A Fe2A C23A C33A 34(4) . . . . ?
C25A Fe2A C23A C33A -159(4) . . . . ?
C24A Fe2A C23A C33A -123(4) . . . . ?
C31A Fe2A C23A C33A 64(6) . . . . ?
C22A Fe2A C23A C33A 122(4) . . . . ?
C28A Fe2A C23A C33A -5(4) . . . . ?
C30A Fe2A C23A C22A 163(4) . . . . ?
C29A Fe2A C23A C22A -168(2) . . . . ?
C26A Fe2A C23A C22A 33.3(19) . . . . ?
C27A Fe2A C23A C22A -88(2) . . . . ?
C25A Fe2A C23A C22A 79(2) . . . . ?
C24A Fe2A C23A C22A 116(3) . . . . ?
C31A Fe2A C23A C22A -57(5) . . . . ?
C28A Fe2A C23A C22A -127(2) . . . . ?
C33A C23A C24A C25A 179(3) . . . . ?
C22A C23A C24A C25A -7(4) . . . . ?
Fe2A C23A C24A C25A 57(2) . . . . ?
C33A C23A C24A C32A -1(6) . . . . ?
C22A C23A C24A C32A 173(4) . . . . ?
Fe2A C23A C24A C32A -123(4) . . . . ?
C33A C23A C24A Fe2A 122(4) . . . . ?
C22A C23A C24A Fe2A -64(2) . . . . ?
C23A Fe2A C24A C25A -121(3) . . . . ?
C30A Fe2A C24A C25A 79(3) . . . . ?
C29A Fe2A C24A C25A 118(2) . . . . ?
C26A Fe2A C24A C25A -39(2) . . . . ?
C27A Fe2A C24A C25A 179(4) . . . . ?
C31A Fe2A C24A C25A 51(6) . . . . ?
C22A Fe2A C24A C25A -80(2) . . . . ?
C28A Fe2A C24A C25A 160(2) . . . . ?
C23A Fe2A C24A C32A 122(4) . . . . ?
C30A Fe2A C24A C32A -38(4) . . . . ?
C29A Fe2A C24A C32A 1(3) . . . . ?
C26A Fe2A C24A C32A -156(3) . . . . ?
C27A Fe2A C24A C32A 62(6) . . . . ?
C25A Fe2A C24A C32A -117(4) . . . . ?
C31A Fe2A C24A C32A -66(6) . . . . ?
C22A Fe2A C24A C32A 163(3) . . . . ?
C28A Fe2A C24A C32A 43(4) . . . . ?
C30A Fe2A C24A C23A -160(2) . . . . ?
C29A Fe2A C24A C23A -121(2) . . . . ?
C26A Fe2A C24A C23A 82(2) . . . . ?
C27A Fe2A C24A C23A -61(5) . . . . ?
C25A Fe2A C24A C23A 121(3) . . . . ?
C31A Fe2A C24A C23A 172(5) . . . . ?
C22A Fe2A C24A C23A 41(2) . . . . ?
C28A Fe2A C24A C23A -79(2) . . . . ?
C32A C24A C25A C26A -178(3) . . . . ?
C23A C24A C25A C26A 2(4) . . . . ?
Fe2A C24A C25A C26A 57(2) . . . . ?
C32A C24A C25A Fe2A 125(4) . . . . ?
C23A C24A C25A Fe2A -55(2) . . . . ?
C23A Fe2A C25A C24A 38(2) . . . . ?
C30A Fe2A C25A C24A -118(2) . . . . ?
C29A Fe2A C25A C24A -78(3) . . . . ?
C26A Fe2A C25A C24A 121(3) . . . . ?
C27A Fe2A C25A C24A -179(5) . . . . ?
C31A Fe2A C25A C24A -161(2) . . . . ?
C22A Fe2A C25A C24A 84(2) . . . . ?
C28A Fe2A C25A C24A -43(4) . . . . ?
C23A Fe2A C25A C26A -82(2) . . . . ?
C30A Fe2A C25A C26A 122(2) . . . . ?
C29A Fe2A C25A C26A 162(2) . . . . ?
C27A Fe2A C25A C26A 61(6) . . . . ?
C24A Fe2A C25A C26A -121(3) . . . . ?
C31A Fe2A C25A C26A 78(3) . . . . ?
C22A Fe2A C25A C26A -36.8(19) . . . . ?
C28A Fe2A C25A C26A -164(3) . . . . ?
C23A C22A C26A C25A -9(4) . . . . ?
Au2A C22A C26A C25A 168(3) . . . . ?
Fe2A C22A C26A C25A -61(2) . . . . ?
C23A C22A C26A Fe2A 52(2) . . . . ?
Au2A C22A C26A Fe2A -131(3) . . . . ?
C24A C25A C26A C22A 4(4) . . . . ?
Fe2A C25A C26A C22A 63(3) . . . . ?
C24A C25A C26A Fe2A -59(3) . . . . ?
C23A Fe2A C26A C22A -36(2) . . . . ?
C30A Fe2A C26A C22A 165(2) . . . . ?
C29A Fe2A C26A C22A -163(4) . . . . ?
C27A Fe2A C26A C22A 82(3) . . . . ?
C25A Fe2A C26A C22A -117(3) . . . . ?
C24A Fe2A C26A C22A -81(2) . . . . ?
C31A Fe2A C26A C22A 119(2) . . . . ?
C28A Fe2A C26A C22A 42(5) . . . . ?
C23A Fe2A C26A C25A 81(2) . . . . ?
C30A Fe2A C26A C25A -77(2) . . . . ?
C29A Fe2A C26A C25A -45(5) . . . . ?
C27A Fe2A C26A C25A -160(2) . . . . ?
C24A Fe2A C26A C25A 36.1(19) . . . . ?
C31A Fe2A C26A C25A -123(2) . . . . ?
C22A Fe2A C26A C25A 117(3) . . . . ?
C28A Fe2A C26A C25A 159(4) . . . . ?
C23A Fe2A C27A C31A 161(3) . . . . ?
C30A Fe2A C27A C31A -43(3) . . . . ?
C29A Fe2A C27A C31A -86(3) . . . . ?
C26A Fe2A C27A C31A 71(3) . . . . ?
C25A Fe2A C27A C31A 24(7) . . . . ?
C24A Fe2A C27A C31A -154(4) . . . . ?
C22A Fe2A C27A C31A 114(3) . . . . ?
C28A Fe2A C27A C31A -129(4) . . . . ?
C23A Fe2A C27A C28A -70(3) . . . . ?
C30A Fe2A C27A C28A 85(3) . . . . ?
C29A Fe2A C27A C28A 42(2) . . . . ?
C26A Fe2A C27A C28A -160(2) . . . . ?
C25A Fe2A C27A C28A 152(5) . . . . ?
C24A Fe2A C27A C28A -25(6) . . . . ?
C31A Fe2A C27A C28A 129(4) . . . . ?
C22A Fe2A C27A C28A -118(2) . . . . ?
C31A C27A C28A C29A 2(5) . . . . ?
Fe2A C27A C28A C29A -57(3) . . . . ?
C31A C27A C28A Fe2A 60(4) . . . . ?
C23A Fe2A C28A C27A 126(3) . . . . ?
C30A Fe2A C28A C27A -78(3) . . . . ?
C29A Fe2A C28A C27A -112(3) . . . . ?
C26A Fe2A C28A C27A 54(5) . . . . ?
C25A Fe2A C28A C27A -160(3) . . . . ?
C24A Fe2A C28A C27A 169(2) . . . . ?
C31A Fe2A C28A C27A -31(3) . . . . ?
C22A Fe2A C28A C27A 85(3) . . . . ?
C23A Fe2A C28A C29A -122(2) . . . . ?
C30A Fe2A C28A C29A 35(3) . . . . ?
C26A Fe2A C28A C29A 166(4) . . . . ?
C27A Fe2A C28A C29A 112(3) . . . . ?
C25A Fe2A C28A C29A -48(4) . . . . ?
C24A Fe2A C28A C29A -79(3) . . . . ?
C31A Fe2A C28A C29A 81(3) . . . . ?
C22A Fe2A C28A C29A -163(2) . . . . ?
C27A C28A C29A C30A -1(5) . . . . ?
Fe2A C28A C29A C30A -59(3) . . . . ?
C27A C28A C29A Fe2A 58(3) . . . . ?
C23A Fe2A C29A C30A -162(2) . . . . ?
C26A Fe2A C29A C30A -45(6) . . . . ?
C27A Fe2A C29A C30A 82(3) . . . . ?
C25A Fe2A C29A C30A -79(3) . . . . ?
C24A Fe2A C29A C30A -119(3) . . . . ?
C31A Fe2A C29A C30A 41(3) . . . . ?
C22A Fe2A C29A C30A 171(4) . . . . ?
C28A Fe2A C29A C30A 123(4) . . . . ?
C23A Fe2A C29A C28A 75(3) . . . . ?
C30A Fe2A C29A C28A -123(4) . . . . ?
C26A Fe2A C29A C28A -168(4) . . . . ?
C27A Fe2A C29A C28A -41(2) . . . . ?
C25A Fe2A C29A C28A 159(2) . . . . ?
C24A Fe2A C29A C28A 118(2) . . . . ?
C31A Fe2A C29A C28A -82(3) . . . . ?
C22A Fe2A C29A C28A 48(6) . . . . ?
C28A C29A C30A C31A 0(5) . . . . ?
Fe2A C29A C30A C31A -62(3) . . . . ?
C28A C29A C30A Fe2A 62(3) . . . . ?
C23A Fe2A C30A C29A 42(5) . . . . ?
C26A Fe2A C30A C29A 161(3) . . . . ?
C27A Fe2A C30A C29A -80(3) . . . . ?
C25A Fe2A C30A C29A 117(3) . . . . ?
C24A Fe2A C30A C29A 76(3) . . . . ?
C31A Fe2A C30A C29A -117(4) . . . . ?
C22A Fe2A C30A C29A -172(4) . . . . ?
C28A Fe2A C30A C29A -36(3) . . . . ?
C23A Fe2A C30A C31A 159(3) . . . . ?
C29A Fe2A C30A C31A 117(4) . . . . ?
C26A Fe2A C30A C31A -82(3) . . . . ?
C27A Fe2A C30A C31A 37(2) . . . . ?
C25A Fe2A C30A C31A -126(2) . . . . ?
C24A Fe2A C30A C31A -167(2) . . . . ?
C22A Fe2A C30A C31A -55(5) . . . . ?
C28A Fe2A C30A C31A 81(2) . . . . ?
C28A C27A C31A C30A -3(5) . . . . ?
Fe2A C27A C31A C30A 58(3) . . . . ?
C28A C27A C31A Fe2A -60(4) . . . . ?
C29A C30A C31A C27A 2(5) . . . . ?
Fe2A C30A C31A C27A -60(3) . . . . ?
C29A C30A C31A Fe2A 62(3) . . . . ?
C23A Fe2A C31A C27A -44(6) . . . . ?
C30A Fe2A C31A C27A 114(4) . . . . ?
C29A Fe2A C31A C27A 77(3) . . . . ?
C26A Fe2A C31A C27A -126(3) . . . . ?
C25A Fe2A C31A C27A -171(3) . . . . ?
C24A Fe2A C31A C27A 150(4) . . . . ?
C22A Fe2A C31A C27A -86(3) . . . . ?
C28A Fe2A C31A C27A 33(3) . . . . ?
C23A Fe2A C31A C30A -158(4) . . . . ?
C29A Fe2A C31A C30A -37(2) . . . . ?
C26A Fe2A C31A C30A 119(2) . . . . ?
C27A Fe2A C31A C30A -114(4) . . . . ?
C25A Fe2A C31A C30A 74(3) . . . . ?
C24A Fe2A C31A C30A 36(6) . . . . ?
C22A Fe2A C31A C30A 160(2) . . . . ?
C28A Fe2A C31A C30A -82(3) . . . . ?
C34A N2A C33A O2A 1(4) . . . . ?
Au1A N2A C33A O2A -166(2) . . . . ?
C34A N2A C33A C23A 170(4) . . . . ?
Au1A N2A C33A C23A 4(5) . . . . ?
C35A O2A C33A N2A -3(4) . . . . ?
C35A O2A C33A C23A -173(3) . . . . ?
C24A C23A C33A N2A -160(4) . . . . ?
C22A C23A C33A N2A 28(6) . . . . ?
Fe2A C23A C33A N2A -66(5) . . . . ?
C24A C23A C33A O2A 10(5) . . . . ?
C22A C23A C33A O2A -163(3) . . . . ?
Fe2A C23A C33A O2A 103(3) . . . . ?
C33A N2A C34A C38A 115(4) . . . . ?
Au1A N2A C34A C38A -79(4) . . . . ?
C33A N2A C34A C35A 2(4) . . . . ?
Au1A N2A C34A C35A 168(2) . . . . ?
C33A O2A C35A C34A 4(4) . . . . ?
C33A O2A C35A C36A -107(3) . . . . ?
C38A C34A C35A O2A -125(3) . . . . ?
N2A C34A C35A O2A -3(4) . . . . ?
C38A C34A C35A C36A -16(4) . . . . ?
N2A C34A C35A C36A 105(3) . . . . ?
O2A C35A C36A C37A 133(3) . . . . ?
C34A C35A C36A C37A 20(3) . . . . ?
C35A C36A C37A C42A 159(4) . . . . ?
C35A C36A C37A C38A -18(4) . . . . ?
C42A C37A C38A C39A -1(6) . . . . ?
C36A C37A C38A C39A 176(3) . . . . ?
C42A C37A C38A C34A -168(4) . . . . ?
C36A C37A C38A C34A 9(4) . . . . ?
N2A C34A C38A C39A 86(4) . . . . ?
C35A C34A C38A C39A -163(3) . . . . ?
N2A C34A C38A C37A -107(4) . . . . ?
C35A C34A C38A C37A 4(5) . . . . ?
C37A C38A C39A C40A 6(5) . . . . ?
C34A C38A C39A C40A 173(3) . . . . ?
C38A C39A C40A C41A -4(5) . . . . ?
C39A C40A C41A C42A -3(5) . . . . ?
C38A C37A C42A C41A -6(6) . . . . ?
C36A C37A C42A C41A 177(3) . . . . ?
C40A C41A C42A C37A 8(5) . . . . ?
N2B Au1B Au2B C22B 48.7(16) . . . . ?
C1B Au1B Au2B C22B -132.7(17) . . . . ?
Cl1B Au1B Au2B C22B -63(4) . . . . ?
N2B Au1B Au2B N1B -124.3(12) . . . . ?
C1B Au1B Au2B N1B 54.3(13) . . . . ?
Cl1B Au1B Au2B N1B 124(4) . . . . ?
N2B Au1B Au2B Cl2B 134(5) . . . . ?
C1B Au1B Au2B Cl2B -47(5) . . . . ?
Cl1B Au1B Au2B Cl2B 23(7) . . . . ?
C22B Au2B N1B C12B -144(13) . . . . ?
Cl2B Au2B N1B C12B 115(4) . . . . ?
Au1B Au2B N1B C12B -61(4) . . . . ?
C22B Au2B N1B C13B 59(15) . . . . ?
Cl2B Au2B N1B C13B -42(3) . . . . ?
Au1B Au2B N1B C13B 142(3) . . . . ?
C1B Au1B N2B C33B -128(51) . . . . ?
Cl1B Au1B N2B C33B 129(4) . . . . ?
Au2B Au1B N2B C33B -46(4) . . . . ?
C1B Au1B N2B C34B 65(53) . . . . ?
Cl1B Au1B N2B C34B -38(4) . . . . ?
Au2B Au1B N2B C34B 147(4) . . . . ?
C5B Fe1B C1B C2B -118.7(13) . . . . ?
C4B Fe1B C1B C2B -77.0(13) . . . . ?
C8B Fe1B C1B C2B 31(6) . . . . ?
C7B Fe1B C1B C2B 75(2) . . . . ?
C6B Fe1B C1B C2B 120(2) . . . . ?
C9B Fe1B C1B C2B -154(5) . . . . ?
C3B Fe1B C1B C2B -33.1(8) . . . . ?
C10B Fe1B C1B C2B 165(2) . . . . ?
C4B Fe1B C1B C5B 41.8(11) . . . . ?
C8B Fe1B C1B C5B 150(6) . . . . ?
C7B Fe1B C1B C5B -166(3) . . . . ?
C6B Fe1B C1B C5B -121(2) . . . . ?
C9B Fe1B C1B C5B -35(5) . . . . ?
C2B Fe1B C1B C5B 118.7(13) . . . . ?
C3B Fe1B C1B C5B 85.7(13) . . . . ?
C10B Fe1B C1B C5B -76(2) . . . . ?
C5B Fe1B C1B Au1B 122(3) . . . . ?
C4B Fe1B C1B Au1B 164(3) . . . . ?
C8B Fe1B C1B Au1B -88(6) . . . . ?
C7B Fe1B C1B Au1B -44(4) . . . . ?
C6B Fe1B C1B Au1B 1(3) . . . . ?
C9B Fe1B C1B Au1B 88(5) . . . . ?
C2B Fe1B C1B Au1B -119(3) . . . . ?
C3B Fe1B C1B Au1B -152(3) . . . . ?
C10B Fe1B C1B Au1B 46(3) . . . . ?
N2B Au1B C1B C2B 25(53) . . . . ?
Cl1B Au1B C1B C2B 128(2) . . . . ?
Au2B Au1B C1B C2B -57(2) . . . . ?
N2B Au1B C1B C5B -144(50) . . . . ?
Cl1B Au1B C1B C5B -41(3) . . . . ?
Au2B Au1B C1B C5B 134(3) . . . . ?
N2B Au1B C1B Fe1B 126(51) . . . . ?
Cl1B Au1B C1B Fe1B -131(2) . . . . ?
Au2B Au1B C1B Fe1B 44(2) . . . . ?
C5B C1B C2B C12B -154(4) . . . . ?
Fe1B C1B C2B C12B -100(4) . . . . ?
Au1B C1B C2B C12B 35(4) . . . . ?
C5B C1B C2B C3B -2.2(17) . . . . ?
Fe1B C1B C2B C3B 51.6(14) . . . . ?
Au1B C1B C2B C3B -174(3) . . . . ?
C5B C1B C2B Fe1B -53.8(17) . . . . ?
Au1B C1B C2B Fe1B 135(2) . . . . ?
C5B Fe1B C2B C12B 163(3) . . . . ?
C4B Fe1B C2B C12B -146(3) . . . . ?
C1B Fe1B C2B C12B 120(3) . . . . ?
C8B Fe1B C2B C12B -48(4) . . . . ?
C7B Fe1B C2B C12B -6(4) . . . . ?
C6B Fe1B C2B C12B 35(4) . . . . ?
C9B Fe1B C2B C12B -85(5) . . . . ?
C3B Fe1B C2B C12B -111(3) . . . . ?
C10B Fe1B C2B C12B 78(6) . . . . ?
C5B Fe1B C2B C1B 42.3(11) . . . . ?
C4B Fe1B C2B C1B 93.7(14) . . . . ?
C8B Fe1B C2B C1B -168(2) . . . . ?
C7B Fe1B C2B C1B -127(2) . . . . ?
C6B Fe1B C2B C1B -86(2) . . . . ?
C9B Fe1B C2B C1B 154(5) . . . . ?
C3B Fe1B C2B C1B 128.1(12) . . . . ?
C10B Fe1B C2B C1B -42(6) . . . . ?
C5B Fe1B C2B C3B -85.9(13) . . . . ?
C4B Fe1B C2B C3B -34.5(11) . . . . ?
C1B Fe1B C2B C3B -128.1(12) . . . . ?
C8B Fe1B C2B C3B 64(2) . . . . ?
C7B Fe1B C2B C3B 105(2) . . . . ?
C6B Fe1B C2B C3B 146(2) . . . . ?
C9B Fe1B C2B C3B 26(5) . . . . ?
C10B Fe1B C2B C3B -170(6) . . . . ?
C12B C2B C3B C11B -38(6) . . . . ?
C1B C2B C3B C11B 167(6) . . . . ?
Fe1B C2B C3B C11B -145(6) . . . . ?
C12B C2B C3B C4B 151(4) . . . . ?
C1B C2B C3B C4B -3.6(17) . . . . ?
Fe1B C2B C3B C4B 43.8(18) . . . . ?
C12B C2B C3B Fe1B 107(3) . . . . ?
C1B C2B C3B Fe1B -47.3(14) . . . . ?
C5B Fe1B C3B C11B -129(5) . . . . ?
C4B Fe1B C3B C11B -84(5) . . . . ?
C1B Fe1B C3B C11B -179(5) . . . . ?
C8B Fe1B C3B C11B 19(5) . . . . ?
C7B Fe1B C3B C11B 56(5) . . . . ?
C6B Fe1B C3B C11B 68(7) . . . . ?
C9B Fe1B C3B C11B -20(5) . . . . ?
C2B Fe1B C3B C11B 148(5) . . . . ?
C10B Fe1B C3B C11B -40(7) . . . . ?
C5B Fe1B C3B C4B -44.7(12) . . . . ?
C1B Fe1B C3B C4B -94.2(15) . . . . ?
C8B Fe1B C3B C4B 104(2) . . . . ?
C7B Fe1B C3B C4B 141(2) . . . . ?
C6B Fe1B C3B C4B 153(4) . . . . ?
C9B Fe1B C3B C4B 64(2) . . . . ?
C2B Fe1B C3B C4B -127.3(15) . . . . ?
C10B Fe1B C3B C4B 45(5) . . . . ?
C5B Fe1B C3B C2B 82.6(12) . . . . ?
C4B Fe1B C3B C2B 127.3(15) . . . . ?
C1B Fe1B C3B C2B 33.1(8) . . . . ?
C8B Fe1B C3B C2B -129(2) . . . . ?
C7B Fe1B C3B C2B -92(2) . . . . ?
C6B Fe1B C3B C2B -80(4) . . . . ?
C9B Fe1B C3B C2B -169(2) . . . . ?
C10B Fe1B C3B C2B 172(4) . . . . ?
C11B C3B C4B C5B -166(4) . . . . ?
C2B C3B C4B C5B 8(3) . . . . ?
Fe1B C3B C4B C5B 58(2) . . . . ?
C11B C3B C4B Fe1B 136(3) . . . . ?
C2B C3B C4B Fe1B -50.5(17) . . . . ?
C5B Fe1B C4B C3B 116.1(15) . . . . ?
C1B Fe1B C4B C3B 75.6(13) . . . . ?
C8B Fe1B C4B C3B -85(2) . . . . ?
C7B Fe1B C4B C3B -68(3) . . . . ?
C6B Fe1B C4B C3B -148(5) . . . . ?
C9B Fe1B C4B C3B -126(2) . . . . ?
C2B Fe1B C4B C3B 33.3(10) . . . . ?
C10B Fe1B C4B C3B -161(2) . . . . ?
C1B Fe1B C4B C5B -40.4(11) . . . . ?
C8B Fe1B C4B C5B 159(2) . . . . ?
C7B Fe1B C4B C5B 176(3) . . . . ?
C6B Fe1B C4B C5B 96(5) . . . . ?
C9B Fe1B C4B C5B 118(2) . . . . ?
C2B Fe1B C4B C5B -82.8(12) . . . . ?
C3B Fe1B C4B C5B -116.1(15) . . . . ?
C10B Fe1B C4B C5B 83(2) . . . . ?
C2B C1B C5B C4B 7(3) . . . . ?
Fe1B C1B C5B C4B -56(2) . . . . ?
Au1B C1B C5B C4B 177(3) . . . . ?
C2B C1B C5B Fe1B 63.5(18) . . . . ?
Au1B C1B C5B Fe1B -127(3) . . . . ?
C3B C4B C5B C1B -9(3) . . . . ?
Fe1B C4B C5B C1B 59(2) . . . . ?
C3B C4B C5B Fe1B -69(2) . . . . ?
C4B Fe1B C5B C1B -120.0(14) . . . . ?
C8B Fe1B C5B C1B -161(4) . . . . ?
C7B Fe1B C5B C1B 73(10) . . . . ?
C6B Fe1B C5B C1B 90(2) . . . . ?
C9B Fe1B C5B C1B 166(2) . . . . ?
C2B Fe1B C5B C1B -37.3(8) . . . . ?
C3B Fe1B C5B C1B -80.5(10) . . . . ?
C10B Fe1B C5B C1B 123.7(19) . . . . ?
C1B Fe1B C5B C4B 120.0(14) . . . . ?
C8B Fe1B C5B C4B -41(4) . . . . ?
C7B Fe1B C5B C4B -167(10) . . . . ?
C6B Fe1B C5B C4B -150(2) . . . . ?
C9B Fe1B C5B C4B -74(2) . . . . ?
C2B Fe1B C5B C4B 82.7(12) . . . . ?
C3B Fe1B C5B C4B 39.5(9) . . . . ?
C10B Fe1B C5B C4B -116.3(19) . . . . ?
C5B Fe1B C6B C7B -175(3) . . . . ?
C4B Fe1B C6B C7B 108(5) . . . . ?
C1B Fe1B C6B C7B -120(3) . . . . ?
C8B Fe1B C6B C7B 38(3) . . . . ?
C9B Fe1B C6B C7B 85(3) . . . . ?
C2B Fe1B C6B C7B -73(4) . . . . ?
C3B Fe1B C6B C7B -17(6) . . . . ?
C10B Fe1B C6B C7B 127(4) . . . . ?
C5B Fe1B C6B C10B 58(4) . . . . ?
C4B Fe1B C6B C10B -19(7) . . . . ?
C1B Fe1B C6B C10B 113(3) . . . . ?
C8B Fe1B C6B C10B -89(3) . . . . ?
C7B Fe1B C6B C10B -127(4) . . . . ?
C9B Fe1B C6B C10B -42(3) . . . . ?
C2B Fe1B C6B C10B 160(3) . . . . ?
C3B Fe1B C6B C10B -144(4) . . . . ?
C10B C6B C7B C8B -1(2) . . . . ?
Fe1B C6B C7B C8B -60.2(19) . . . . ?
C10B C6B C7B Fe1B 59(2) . . . . ?
C5B Fe1B C7B C8B 138(9) . . . . ?
C4B Fe1B C7B C8B -26(5) . . . . ?
C1B Fe1B C7B C8B -158(3) . . . . ?
C6B Fe1B C7B C8B 118(5) . . . . ?
C9B Fe1B C7B C8B 40(3) . . . . ?
C2B Fe1B C7B C8B -115(3) . . . . ?
C3B Fe1B C7B C8B -70(4) . . . . ?
C10B Fe1B C7B C8B 85(4) . . . . ?
C5B Fe1B C7B C6B 20(11) . . . . ?
C4B Fe1B C7B C6B -144(3) . . . . ?
C1B Fe1B C7B C6B 84(4) . . . . ?
C8B Fe1B C7B C6B -118(5) . . . . ?
C9B Fe1B C7B C6B -78(3) . . . . ?
C2B Fe1B C7B C6B 127(3) . . . . ?
C3B Fe1B C7B C6B 172(3) . . . . ?
C10B Fe1B C7B C6B -33(3) . . . . ?
C6B C7B C8B C9B -1.7(19) . . . . ?
Fe1B C7B C8B C9B -63(2) . . . . ?
C6B C7B C8B Fe1B 61.4(18) . . . . ?
C5B Fe1B C8B C7B -166(3) . . . . ?
C4B Fe1B C8B C7B 163(3) . . . . ?
C1B Fe1B C8B C7B 60(7) . . . . ?
C6B Fe1B C8B C7B -38(3) . . . . ?
C9B Fe1B C8B C7B -118(5) . . . . ?
C2B Fe1B C8B C7B 83(4) . . . . ?
C3B Fe1B C8B C7B 120(3) . . . . ?
C10B Fe1B C8B C7B -81(4) . . . . ?
C5B Fe1B C8B C9B -48(5) . . . . ?
C4B Fe1B C8B C9B -79(3) . . . . ?
C1B Fe1B C8B C9B 177(5) . . . . ?
C7B Fe1B C8B C9B 118(5) . . . . ?
C6B Fe1B C8B C9B 79(3) . . . . ?
C2B Fe1B C8B C9B -159(3) . . . . ?
C3B Fe1B C8B C9B -122(3) . . . . ?
C10B Fe1B C8B C9B 36(3) . . . . ?
C7B C8B C9B C10B 4(3) . . . . ?
Fe1B C8B C9B C10B -59(3) . . . . ?
C7B C8B C9B Fe1B 62(2) . . . . ?
C5B Fe1B C9B C8B 155(3) . . . . ?
C4B Fe1B C9B C8B 108(3) . . . . ?
C1B Fe1B C9B C8B -178(4) . . . . ?
C7B Fe1B C9B C8B -37(3) . . . . ?
C6B Fe1B C9B C8B -81(3) . . . . ?
C2B Fe1B C9B C8B 50(6) . . . . ?
C3B Fe1B C9B C8B 70(3) . . . . ?
C10B Fe1B C9B C8B -122(4) . . . . ?
C5B Fe1B C9B C10B -83(3) . . . . ?
C4B Fe1B C9B C10B -130(3) . . . . ?
C1B Fe1B C9B C10B -56(6) . . . . ?
C8B Fe1B C9B C10B 122(4) . . . . ?
C7B Fe1B C9B C10B 84(3) . . . . ?
C6B Fe1B C9B C10B 41(3) . . . . ?
C2B Fe1B C9B C10B 172(4) . . . . ?
C3B Fe1B C9B C10B -169(3) . . . . ?
C7B C6B C10B C9B 3(3) . . . . ?
Fe1B C6B C10B C9B 59(2) . . . . ?
C7B C6B C10B Fe1B -56(2) . . . . ?
C8B C9B C10B C6B -4(3) . . . . ?
Fe1B C9B C10B C6B -58(2) . . . . ?
C8B C9B C10B Fe1B 55(2) . . . . ?
C5B Fe1B C10B C6B -138(3) . . . . ?
C4B Fe1B C10B C6B 172(3) . . . . ?
C1B Fe1B C10B C6B -90(3) . . . . ?
C8B Fe1B C10B C6B 75(3) . . . . ?
C7B Fe1B C10B C6B 33(3) . . . . ?
C9B Fe1B C10B C6B 112(4) . . . . ?
C2B Fe1B C10B C6B -58(7) . . . . ?
C3B Fe1B C10B C6B 139(4) . . . . ?
C5B Fe1B C10B C9B 110(3) . . . . ?
C4B Fe1B C10B C9B 60(3) . . . . ?
C1B Fe1B C10B C9B 158(3) . . . . ?
C8B Fe1B C10B C9B -37(3) . . . . ?
C7B Fe1B C10B C9B -79(3) . . . . ?
C6B Fe1B C10B C9B -112(4) . . . . ?
C2B Fe1B C10B C9B -170(5) . . . . ?
C3B Fe1B C10B C9B 26(6) . . . . ?
C13B N1B C12B O1B -9(6) . . . . ?
Au2B N1B C12B O1B -170(3) . . . . ?
C13B N1B C12B C2B -164(4) . . . . ?
Au2B N1B C12B C2B 36(6) . . . . ?
C14B O1B C12B N1B 18(5) . . . . ?
C14B O1B C12B C2B 176(4) . . . . ?
C1B C2B C12B N1B -13(7) . . . . ?
C3B C2B C12B N1B -162(4) . . . . ?
Fe1B C2B C12B N1B -84(5) . . . . ?
C1B C2B C12B O1B -169(3) . . . . ?
C3B C2B C12B O1B 41(4) . . . . ?
Fe1B C2B C12B O1B 120(3) . . . . ?
C12B N1B C13B C14B -4(5) . . . . ?
Au2B N1B C13B C14B 156(3) . . . . ?
C12B N1B C13B C17B 107(5) . . . . ?
Au2B N1B C13B C17B -93(4) . . . . ?
N1B C13B C14B O1B 14(5) . . . . ?
C17B C13B C14B O1B -100(5) . . . . ?
N1B C13B C14B C15B 135(4) . . . . ?
C17B C13B C14B C15B 21(6) . . . . ?
C12B O1B C14B C13B -18(5) . . . . ?
C12B O1B C14B C15B -135(4) . . . . ?
C13B C14B C15B C16B -22(6) . . . . ?
O1B C14B C15B C16B 94(5) . . . . ?
C14B C15B C16B C21B -166(6) . . . . ?
C14B C15B C16B C17B 15(6) . . . . ?
C21B C16B C17B C18B 6(9) . . . . ?
C15B C16B C17B C18B -175(5) . . . . ?
C21B C16B C17B C13B 178(5) . . . . ?
C15B C16B C17B C13B -3(7) . . . . ?
N1B C13B C17B C16B -124(5) . . . . ?
C14B C13B C17B C16B -12(6) . . . . ?
N1B C13B C17B C18B 47(7) . . . . ?
C14B C13B C17B C18B 160(6) . . . . ?
C16B C17B C18B C19B -13(9) . . . . ?
C13B C17B C18B C19B 177(5) . . . . ?
C17B C18B C19B C20B 8(8) . . . . ?
C18B C19B C20B C21B 1(8) . . . . ?
C17B C16B C21B C20B 5(9) . . . . ?
C15B C16B C21B C20B -174(6) . . . . ?
C19B C20B C21B C16B -9(9) . . . . ?
N1B Au2B C22B C23B 32(16) . . . . ?
Cl2B Au2B C22B C23B 133(4) . . . . ?
Au1B Au2B C22B C23B -51(4) . . . . ?
N1B Au2B C22B C26B -131(12) . . . . ?
Cl2B Au2B C22B C26B -30(4) . . . . ?
Au1B Au2B C22B C26B 146(4) . . . . ?
N1B Au2B C22B Fe2B 130(12) . . . . ?
Cl2B Au2B C22B Fe2B -129(3) . . . . ?
Au1B Au2B C22B Fe2B 47(3) . . . . ?
C30B Fe2B C22B C23B -158(5) . . . . ?
C29B Fe2B C22B C23B 46(10) . . . . ?
C28B Fe2B C22B C23B 77(4) . . . . ?
C31B Fe2B C22B C23B 162(3) . . . . ?
C25B Fe2B C22B C23B -81(3) . . . . ?
C24B Fe2B C22B C23B -39(3) . . . . ?
C26B Fe2B C22B C23B -119(4) . . . . ?
C27B Fe2B C22B C23B 119(3) . . . . ?
C30B Fe2B C22B C26B -39(6) . . . . ?
C29B Fe2B C22B C26B 165(8) . . . . ?
C28B Fe2B C22B C26B -164(3) . . . . ?
C31B Fe2B C22B C26B -79(3) . . . . ?
C25B Fe2B C22B C26B 39(3) . . . . ?
C24B Fe2B C22B C26B 80(3) . . . . ?
C23B Fe2B C22B C26B 119(4) . . . . ?
C27B Fe2B C22B C26B -121(3) . . . . ?
C30B Fe2B C22B Au2B 82(6) . . . . ?
C29B Fe2B C22B Au2B -75(10) . . . . ?
C28B Fe2B C22B Au2B -43(5) . . . . ?
C31B Fe2B C22B Au2B 42(4) . . . . ?
C25B Fe2B C22B Au2B 159(4) . . . . ?
C24B Fe2B C22B Au2B -159(4) . . . . ?
C23B Fe2B C22B Au2B -120(5) . . . . ?
C26B Fe2B C22B Au2B 121(5) . . . . ?
C27B Fe2B C22B Au2B -1(4) . . . . ?
C26B C22B C23B C33B -169(5) . . . . ?
Au2B C22B C23B C33B 26(8) . . . . ?
Fe2B C22B C23B C33B -109(5) . . . . ?
C26B C22B C23B C24B -3(5) . . . . ?
Au2B C22B C23B C24B -168(3) . . . . ?
Fe2B C22B C23B C24B 57(3) . . . . ?
C26B C22B C23B Fe2B -59(3) . . . . ?
Au2B C22B C23B Fe2B 135(4) . . . . ?
C30B Fe2B C23B C33B -90(8) . . . . ?
C29B Fe2B C23B C33B -43(5) . . . . ?
C28B Fe2B C23B C33B -1(5) . . . . ?
C31B Fe2B C23B C33B 76(8) . . . . ?
C25B Fe2B C23B C33B -154(5) . . . . ?
C24B Fe2B C23B C33B -116(5) . . . . ?
C22B Fe2B C23B C33B 124(5) . . . . ?
C26B Fe2B C23B C33B 164(5) . . . . ?
C27B Fe2B C23B C33B 44(5) . . . . ?
C30B Fe2B C23B C22B 147(7) . . . . ?
C29B Fe2B C23B C22B -166(3) . . . . ?
C28B Fe2B C23B C22B -125(3) . . . . ?
C31B Fe2B C23B C22B -47(7) . . . . ?
C25B Fe2B C23B C22B 83(3) . . . . ?
C24B Fe2B C23B C22B 120(4) . . . . ?
C26B Fe2B C23B C22B 40(3) . . . . ?
C27B Fe2B C23B C22B -80(3) . . . . ?
C30B Fe2B C23B C24B 26(8) . . . . ?
C29B Fe2B C23B C24B 73(4) . . . . ?
C28B Fe2B C23B C24B 114(3) . . . . ?
C31B Fe2B C23B C24B -168(6) . . . . ?
C25B Fe2B C23B C24B -38(3) . . . . ?
C22B Fe2B C23B C24B -120(4) . . . . ?
C26B Fe2B C23B C24B -81(3) . . . . ?
C27B Fe2B C23B C24B 160(3) . . . . ?
C33B C23B C24B C25B 170(5) . . . . ?
C22B C23B C24B C25B 3(6) . . . . ?
Fe2B C23B C24B C25B 61(3) . . . . ?
C33B C23B C24B C32B -10(8) . . . . ?
C22B C23B C24B C32B -177(5) . . . . ?
Fe2B C23B C24B C32B -119(6) . . . . ?
C33B C23B C24B Fe2B 109(5) . . . . ?
C22B C23B C24B Fe2B -58(3) . . . . ?
C30B Fe2B C24B C25B 73(4) . . . . ?
C29B Fe2B C24B C25B 116(3) . . . . ?
C28B Fe2B C24B C25B 157(3) . . . . ?
C31B Fe2B C24B C25B 54(7) . . . . ?
C23B Fe2B C24B C25B -116(4) . . . . ?
C22B Fe2B C24B C25B -79(3) . . . . ?
C26B Fe2B C24B C25B -33(3) . . . . ?
C27B Fe2B C24B C25B -171(6) . . . . ?
C30B Fe2B C24B C32B -43(5) . . . . ?
C29B Fe2B C24B C32B 0(4) . . . . ?
C28B Fe2B C24B C32B 40(5) . . . . ?
C31B Fe2B C24B C32B -63(7) . . . . ?
C25B Fe2B C24B C32B -117(5) . . . . ?
C23B Fe2B C24B C32B 128(5) . . . . ?
C22B Fe2B C24B C32B 164(4) . . . . ?
C26B Fe2B C24B C32B -149(4) . . . . ?
C27B Fe2B C24B C32B 72(8) . . . . ?
C30B Fe2B C24B C23B -171(3) . . . . ?
C29B Fe2B C24B C23B -128(3) . . . . ?
C28B Fe2B C24B C23B -88(3) . . . . ?
C31B Fe2B C24B C23B 170(5) . . . . ?
C25B Fe2B C24B C23B 116(4) . . . . ?
C22B Fe2B C24B C23B 36(3) . . . . ?
C26B Fe2B C24B C23B 83(3) . . . . ?
C27B Fe2B C24B C23B -56(8) . . . . ?
C32B C24B C25B C26B 178(4) . . . . ?
C23B C24B C25B C26B -3(6) . . . . ?
Fe2B C24B C25B C26B 58(4) . . . . ?
C32B C24B C25B Fe2B 120(5) . . . . ?
C23B C24B C25B Fe2B -60(3) . . . . ?
C30B Fe2B C25B C24B -121(3) . . . . ?
C29B Fe2B C25B C24B -80(4) . . . . ?
C28B Fe2B C25B C24B -50(6) . . . . ?
C31B Fe2B C25B C24B -156(3) . . . . ?
C23B Fe2B C25B C24B 42(3) . . . . ?
C22B Fe2B C25B C24B 86(3) . . . . ?
C26B Fe2B C25B C24B 128(4) . . . . ?
C27B Fe2B C25B C24B 171(6) . . . . ?
C30B Fe2B C25B C26B 111(3) . . . . ?
C29B Fe2B C25B C26B 152(3) . . . . ?
C28B Fe2B C25B C26B -179(4) . . . . ?
C31B Fe2B C25B C26B 75(4) . . . . ?
C24B Fe2B C25B C26B -128(4) . . . . ?
C23B Fe2B C25B C26B -86(3) . . . . ?
C22B Fe2B C25B C26B -42(3) . . . . ?
C27B Fe2B C25B C26B 43(8) . . . . ?
C24B C25B C26B C22B 1(6) . . . . ?
Fe2B C25B C26B C22B 57(3) . . . . ?
C24B C25B C26B Fe2B -57(4) . . . . ?
C23B C22B C26B C25B 1(5) . . . . ?
Au2B C22B C26B C25B 167(4) . . . . ?
Fe2B C22B C26B C25B -58(3) . . . . ?
C23B C22B C26B Fe2B 59(3) . . . . ?
Au2B C22B C26B Fe2B -135(4) . . . . ?
C30B Fe2B C26B C25B -83(3) . . . . ?
C29B Fe2B C26B C25B -57(5) . . . . ?
C28B Fe2B C26B C25B 178(8) . . . . ?
C31B Fe2B C26B C25B -123(3) . . . . ?
C24B Fe2B C26B C25B 32(3) . . . . ?
C23B Fe2B C26B C25B 78(3) . . . . ?
C22B Fe2B C26B C25B 115(4) . . . . ?
C27B Fe2B C26B C25B -164(3) . . . . ?
C30B Fe2B C26B C22B 162(3) . . . . ?
C29B Fe2B C26B C22B -172(4) . . . . ?
C28B Fe2B C26B C22B 62(9) . . . . ?
C31B Fe2B C26B C22B 122(3) . . . . ?
C25B Fe2B C26B C22B -115(4) . . . . ?
C24B Fe2B C26B C22B -84(3) . . . . ?
C23B Fe2B C26B C22B -37(3) . . . . ?
C27B Fe2B C26B C22B 80(3) . . . . ?
C30B Fe2B C27B C31B -30(4) . . . . ?
C29B Fe2B C27B C31B -74(4) . . . . ?
C28B Fe2B C27B C31B -111(5) . . . . ?
C25B Fe2B C27B C31B 43(8) . . . . ?
C24B Fe2B C27B C31B -154(6) . . . . ?
C23B Fe2B C27B C31B 164(4) . . . . ?
C22B Fe2B C27B C31B 121(4) . . . . ?
C26B Fe2B C27B C31B 75(4) . . . . ?
C30B Fe2B C27B C28B 81(4) . . . . ?
C29B Fe2B C27B C28B 37(3) . . . . ?
C31B Fe2B C27B C28B 111(5) . . . . ?
C25B Fe2B C27B C28B 155(6) . . . . ?
C24B Fe2B C27B C28B -42(8) . . . . ?
C23B Fe2B C27B C28B -85(4) . . . . ?
C22B Fe2B C27B C28B -127(3) . . . . ?
C26B Fe2B C27B C28B -173(3) . . . . ?
C31B C27B C28B C29B -4(6) . . . . ?
Fe2B C27B C28B C29B -61(4) . . . . ?
C31B C27B C28B Fe2B 57(4) . . . . ?
C30B Fe2B C28B C29B 36(4) . . . . ?
C31B Fe2B C28B C29B 77(4) . . . . ?
C25B Fe2B C28B C29B -43(6) . . . . ?
C24B Fe2B C28B C29B -77(4) . . . . ?
C23B Fe2B C28B C29B -125(4) . . . . ?
C22B Fe2B C28B C29B -168(3) . . . . ?
C26B Fe2B C28B C29B 141(8) . . . . ?
C27B Fe2B C28B C29B 119(5) . . . . ?
C30B Fe2B C28B C27B -83(3) . . . . ?
C29B Fe2B C28B C27B -119(5) . . . . ?
C31B Fe2B C28B C27B -42(3) . . . . ?
C25B Fe2B C28B C27B -161(4) . . . . ?
C24B Fe2B C28B C27B 164(3) . . . . ?
C23B Fe2B C28B C27B 116(3) . . . . ?
C22B Fe2B C28B C27B 74(4) . . . . ?
C26B Fe2B C28B C27B 22(10) . . . . ?
C27B C28B C29B C30B 11(7) . . . . ?
Fe2B C28B C29B C30B -53(4) . . . . ?
C27B C28B C29B Fe2B 64(4) . . . . ?
C30B Fe2B C29B C28B -124(5) . . . . ?
C31B Fe2B C29B C28B -84(4) . . . . ?
C25B Fe2B C29B C28B 160(3) . . . . ?
C24B Fe2B C29B C28B 120(3) . . . . ?
C23B Fe2B C29B C28B 76(4) . . . . ?
C22B Fe2B C29B C28B 40(10) . . . . ?
C26B Fe2B C29B C28B -162(4) . . . . ?
C27B Fe2B C29B C28B -39(3) . . . . ?
C28B Fe2B C29B C30B 124(5) . . . . ?
C31B Fe2B C29B C30B 40(3) . . . . ?
C25B Fe2B C29B C30B -76(4) . . . . ?
C24B Fe2B C29B C30B -116(4) . . . . ?
C23B Fe2B C29B C30B -160(3) . . . . ?
C22B Fe2B C29B C30B 164(8) . . . . ?
C26B Fe2B C29B C30B -38(6) . . . . ?
C27B Fe2B C29B C30B 85(4) . . . . ?
C28B C29B C30B C31B -13(7) . . . . ?
Fe2B C29B C30B C31B -69(4) . . . . ?
C28B C29B C30B Fe2B 56(5) . . . . ?
C29B Fe2B C30B C31B 111(5) . . . . ?
C28B Fe2B C30B C31B 77(4) . . . . ?
C25B Fe2B C30B C31B -129(4) . . . . ?
C24B Fe2B C30B C31B -167(4) . . . . ?
C23B Fe2B C30B C31B 172(6) . . . . ?
C22B Fe2B C30B C31B -60(7) . . . . ?
C26B Fe2B C30B C31B -88(4) . . . . ?
C27B Fe2B C30B C31B 32(4) . . . . ?
C28B Fe2B C30B C29B -34(3) . . . . ?
C31B Fe2B C30B C29B -111(5) . . . . ?
C25B Fe2B C30B C29B 120(4) . . . . ?
C24B Fe2B C30B C29B 81(4) . . . . ?
C23B Fe2B C30B C29B 61(9) . . . . ?
C22B Fe2B C30B C29B -171(4) . . . . ?
C26B Fe2B C30B C29B 161(3) . . . . ?
C27B Fe2B C30B C29B -79(4) . . . . ?
C29B C30B C31B C27B 10(8) . . . . ?
Fe2B C30B C31B C27B -57(5) . . . . ?
C29B C30B C31B Fe2B 67(4) . . . . ?
C28B C27B C31B C30B -4(7) . . . . ?
Fe2B C27B C31B C30B 53(5) . . . . ?
C28B C27B C31B Fe2B -57(4) . . . . ?
C29B Fe2B C31B C30B -43(4) . . . . ?
C28B Fe2B C31B C30B -87(4) . . . . ?
C25B Fe2B C31B C30B 66(5) . . . . ?
C24B Fe2B C31B C30B 28(8) . . . . ?
C23B Fe2B C31B C30B -173(6) . . . . ?
C22B Fe2B C31B C30B 152(4) . . . . ?
C26B Fe2B C31B C30B 106(4) . . . . ?
C27B Fe2B C31B C30B -130(6) . . . . ?
C30B Fe2B C31B C27B 130(6) . . . . ?
C29B Fe2B C31B C27B 87(4) . . . . ?
C28B Fe2B C31B C27B 43(4) . . . . ?
C25B Fe2B C31B C27B -164(3) . . . . ?
C24B Fe2B C31B C27B 158(5) . . . . ?
C23B Fe2B C31B C27B -43(8) . . . . ?
C22B Fe2B C31B C27B -78(4) . . . . ?
C26B Fe2B C31B C27B -124(3) . . . . ?
C34B N2B C33B C23B -173(5) . . . . ?
Au1B N2B C33B C23B 18(7) . . . . ?
C34B N2B C33B O2B -6(5) . . . . ?
Au1B N2B C33B O2B -175(3) . . . . ?
C22B C23B C33B N2B 3(9) . . . . ?
C24B C23B C33B N2B -161(5) . . . . ?
Fe2B C23B C33B N2B -82(6) . . . . ?
C22B C23B C33B O2B -164(5) . . . . ?
C24B C23B C33B O2B 32(7) . . . . ?
Fe2B C23B C33B O2B 111(4) . . . . ?
C35B O2B C33B N2B 8(6) . . . . ?
C35B O2B C33B C23B 177(5) . . . . ?
C33B N2B C34B C38B 127(5) . . . . ?
Au1B N2B C34B C38B -64(6) . . . . ?
C33B N2B C34B C35B 2(5) . . . . ?
Au1B N2B C34B C35B 170(3) . . . . ?
C33B O2B C35B C34B -6(5) . . . . ?
C33B O2B C35B C36B -111(4) . . . . ?
N2B C34B C35B O2B 3(5) . . . . ?
C38B C34B C35B O2B -124(4) . . . . ?
N2B C34B C35B C36B 120(4) . . . . ?
C38B C34B C35B C36B -7(5) . . . . ?
O2B C35B C36B C37B 112(5) . . . . ?
C34B C35B C36B C37B 5(5) . . . . ?
C35B C36B C37B C38B -2(7) . . . . ?
C35B C36B C37B C42B 168(5) . . . . ?
N2B C34B C38B C39B 69(9) . . . . ?
C35B C34B C38B C39B -170(7) . . . . ?
N2B C34B C38B C37B -115(5) . . . . ?
C35B C34B C38B C37B 6(5) . . . . ?
C36B C37B C38B C39B 175(5) . . . . ?
C42B C37B C38B C39B 3(7) . . . . ?
C36B C37B C38B C34B -3(7) . . . . ?
C42B C37B C38B C34B -174(4) . . . . ?
C34B C38B C39B C40B 168(6) . . . . ?
C37B C38B C39B C40B -8(8) . . . . ?
C38B C39B C40B C41B 2(9) . . . . ?
C39B C40B C41B C42B 10(9) . . . . ?
C40B C41B C42B C37B -13(9) . . . . ?
C36B C37B C42B C41B -164(6) . . . . ?
C38B C37B C42B C41B 6(8) . . . . ?

_diffrn_measured_fraction_theta_max 0.973
_diffrn_reflns_theta_full        63.97
_diffrn_measured_fraction_theta_full 0.973
_refine_diff_density_max         4.357
_refine_diff_density_min         -3.013
_refine_diff_density_rms         0.411
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2332lm
_database_code_depnum_ccdc_archive 'CCDC 1588449'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'iPrFOMeAu(II)Cl' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C34 H40 Au2 Cl2 Fe2 N2 O2, C H Cl3'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C35 H41 Au2 Cl5 Fe2 N2 O2'
_chemical_formula_weight         1204.58

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 2'
_symmetry_space_group_name_Hall  'P 2 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'

_cell_length_a                   19.1746(12)
_cell_length_b                   21.4485(11)
_cell_length_c                   9.1603(6)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3767.3(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    9960
_cell_measurement_theta_min      1.42
_cell_measurement_theta_max      30.55

_exptl_crystal_description       needle
_exptl_crystal_colour            black
_exptl_crystal_size_max          0.61
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.124
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2304
_exptl_absorpt_coefficient_mu    8.908
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.0650
_exptl_absorpt_correction_T_max  0.5056
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            61759
_diffrn_reflns_av_R_equivalents  0.0542
_diffrn_reflns_av_sigmaI/netI    0.0556
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         1.42
_diffrn_reflns_theta_max         30.55
_reflns_number_total             11485
_reflns_number_gt                9960
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0151P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00042(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.000(4)
_refine_ls_number_reflns         11485
_refine_ls_number_parameters     440
_refine_ls_number_restraints     24
_refine_ls_R_factor_all          0.0411
_refine_ls_R_factor_gt           0.0297
_refine_ls_wR_factor_ref         0.0543
_refine_ls_wR_factor_gt          0.0525
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_restrained_S_all      1.078
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.499728(10) 0.793840(7) 0.284124(18) 0.01164(4) Uani 1 1 d . . .
Cl1 Cl 0.60329(6) 0.83404(5) 0.39524(13) 0.0180(2) Uani 1 1 d . . .
Fe1 Fe 0.36681(4) 0.92605(3) 0.31775(8) 0.01433(15) Uani 1 1 d . . .
Au2 Au 0.388689(10) 0.760503(7) 0.16117(2) 0.01697(5) Uani 1 1 d . . .
Cl2 Cl 0.28125(8) 0.73811(7) 0.03867(18) 0.0392(4) Uani 1 1 d . . .
Fe2 Fe 0.51294(4) 0.82286(3) -0.12134(7) 0.01899(17) Uani 1 1 d . . .
O1 O 0.29446(17) 0.79190(16) 0.5740(4) 0.0232(8) Uani 1 1 d . . .
N1 N 0.3376(2) 0.75742(17) 0.3624(5) 0.0203(9) Uani 1 1 d . . .
C1 C 0.4422(3) 0.86249(19) 0.3742(5) 0.0137(10) Uani 1 1 d . . .
O2 O 0.6049(2) 0.66576(14) 0.0126(4) 0.0202(8) Uani 1 1 d . . .
N2 N 0.5562(2) 0.72013(15) 0.1954(4) 0.0138(9) Uani 1 1 d . . .
C2 C 0.3811(3) 0.85539(18) 0.4618(5) 0.0126(9) Uani 1 1 d . . .
C3 C 0.3677(3) 0.9125(2) 0.5405(5) 0.0156(10) Uani 1 1 d . . .
C4 C 0.4216(3) 0.9549(2) 0.4974(5) 0.0154(10) Uani 1 1 d . . .
H4 H 0.4262 0.9967 0.5307 0.019 Uiso 1 1 calc R . .
C5 C 0.4671(3) 0.9249(2) 0.3969(5) 0.0144(10) Uani 1 1 d . . .
H5 H 0.5070 0.9430 0.3526 0.017 Uiso 1 1 calc R . .
C6 C 0.3388(3) 0.9158(2) 0.1007(6) 0.0228(12) Uani 1 1 d . . .
H6 H 0.3570 0.8861 0.0339 0.027 Uiso 1 1 calc R . .
C7 C 0.2801(3) 0.9076(2) 0.1944(6) 0.0221(12) Uani 1 1 d . . .
H7 H 0.2521 0.8711 0.2003 0.026 Uiso 1 1 calc R . .
C8 C 0.2703(3) 0.9623(2) 0.2764(7) 0.0249(12) Uani 1 1 d . . .
H8 H 0.2349 0.9693 0.3471 0.030 Uiso 1 1 calc R . .
C9 C 0.3230(3) 1.0052(2) 0.2344(5) 0.0227(11) Uani 1 1 d . . .
H9 H 0.3292 1.0461 0.2725 0.027 Uiso 1 1 calc R . .
C10 C 0.3648(3) 0.9767(2) 0.1261(6) 0.0241(12) Uani 1 1 d . . .
H10 H 0.4037 0.9951 0.0785 0.029 Uiso 1 1 calc R . .
C11 C 0.3127(3) 0.9272(2) 0.6501(6) 0.0219(11) Uani 1 1 d . . .
H11A H 0.3061 0.9724 0.6552 0.033 Uiso 1 1 calc R . .
H11B H 0.3270 0.9115 0.7461 0.033 Uiso 1 1 calc R . .
H11C H 0.2688 0.9073 0.6212 0.033 Uiso 1 1 calc R . .
C12 C 0.3373(2) 0.8008(2) 0.4612(6) 0.0172(10) Uani 1 1 d . . .
C13 C 0.2598(4) 0.7327(3) 0.5528(8) 0.051(2) Uani 1 1 d . . .
H13A H 0.2086 0.7383 0.5484 0.061 Uiso 1 1 calc R . .
H13B H 0.2710 0.7036 0.6335 0.061 Uiso 1 1 calc R . .
C14 C 0.2880(3) 0.7073(2) 0.4053(7) 0.0274(13) Uani 1 1 d . . .
H14 H 0.2491 0.7053 0.3329 0.033 Uiso 1 1 calc R . .
C15 C 0.3232(3) 0.6439(2) 0.4152(7) 0.0255(13) Uani 1 1 d . . .
H15 H 0.3416 0.6333 0.3161 0.031 Uiso 1 1 calc R . .
C16 C 0.3844(3) 0.6440(3) 0.5209(7) 0.0399(15) Uani 1 1 d . . .
H16A H 0.4058 0.6025 0.5230 0.060 Uiso 1 1 calc R . .
H16B H 0.3679 0.6548 0.6189 0.060 Uiso 1 1 calc R . .
H16C H 0.4191 0.6747 0.4889 0.060 Uiso 1 1 calc R . .
C17 C 0.2699(3) 0.5946(2) 0.4566(8) 0.0386(17) Uani 1 1 d . . .
H17A H 0.2539 0.6019 0.5568 0.058 Uiso 1 1 calc R . .
H17B H 0.2913 0.5532 0.4499 0.058 Uiso 1 1 calc R . .
H17C H 0.2301 0.5969 0.3898 0.058 Uiso 1 1 calc R . .
C18 C 0.4439(3) 0.7612(2) -0.0261(5) 0.0192(11) Uani 1 1 d . . .
C19 C 0.5126(3) 0.7331(2) -0.0538(5) 0.0190(11) Uani 1 1 d . . .
C20 C 0.5270(3) 0.7357(2) -0.2083(5) 0.0245(12) Uani 1 1 d . . .
C21 C 0.4683(3) 0.7656(2) -0.2738(6) 0.0313(14) Uani 1 1 d . . .
H21 H 0.4632 0.7737 -0.3752 0.038 Uiso 1 1 calc R . .
C22 C 0.4186(3) 0.7813(2) -0.1646(6) 0.0266(12) Uani 1 1 d . . .
H22 H 0.3754 0.8019 -0.1813 0.032 Uiso 1 1 calc R . .
C23 C 0.5231(3) 0.9024(2) 0.0039(6) 0.0208(12) Uani 1 1 d . . .
H23 H 0.4990 0.9116 0.0919 0.025 Uiso 1 1 calc R . .
C24 C 0.5882(3) 0.8712(2) -0.0094(6) 0.0247(13) Uani 1 1 d . . .
H24 H 0.6153 0.8557 0.0693 0.030 Uiso 1 1 calc R . .
C25 C 0.6060(3) 0.8671(2) -0.1595(7) 0.0319(13) Uani 1 1 d . . .
H25 H 0.6471 0.8487 -0.1986 0.038 Uiso 1 1 calc R . .
C26 C 0.5518(4) 0.8953(2) -0.2398(6) 0.0323(15) Uani 1 1 d . . .
H26 H 0.5498 0.8988 -0.3431 0.039 Uiso 1 1 calc R . .
C27 C 0.5010(4) 0.91729(18) -0.1415(6) 0.0275(12) Uani 1 1 d . . .
H27 H 0.4592 0.9384 -0.1672 0.033 Uiso 1 1 calc R . .
C28 C 0.5903(4) 0.7117(2) -0.2836(6) 0.0374(16) Uani 1 1 d . . .
H28A H 0.5940 0.7310 -0.3803 0.056 Uiso 1 1 calc R . .
H28B H 0.5868 0.6664 -0.2942 0.056 Uiso 1 1 calc R . .
H28C H 0.6317 0.7221 -0.2258 0.056 Uiso 1 1 calc R . .
C29 C 0.5574(3) 0.7077(2) 0.0563(6) 0.0179(10) Uani 1 1 d . . .
C30 C 0.6471(3) 0.6527(2) 0.1405(6) 0.0221(12) Uani 1 1 d . . .
H30A H 0.6925 0.6745 0.1346 0.027 Uiso 1 1 calc R . .
H30B H 0.6557 0.6073 0.1500 0.027 Uiso 1 1 calc R . .
C31 C 0.6045(3) 0.67674(18) 0.2694(5) 0.0161(10) Uani 1 1 d . . .
H31 H 0.6355 0.7006 0.3370 0.019 Uiso 1 1 calc R . .
C32 C 0.5642(3) 0.6281(2) 0.3550(6) 0.0197(11) Uani 1 1 d . . .
H32 H 0.5358 0.6507 0.4296 0.024 Uiso 1 1 calc R . .
C33 C 0.5144(3) 0.5907(2) 0.2624(6) 0.0300(14) Uani 1 1 d . . .
H33A H 0.4825 0.6190 0.2113 0.045 Uiso 1 1 calc R . .
H33B H 0.4874 0.5625 0.3249 0.045 Uiso 1 1 calc R . .
H33C H 0.5407 0.5662 0.1908 0.045 Uiso 1 1 calc R . .
C34 C 0.6149(3) 0.5853(2) 0.4381(6) 0.0285(13) Uani 1 1 d . . .
H34A H 0.6412 0.5599 0.3682 0.043 Uiso 1 1 calc R . .
H34B H 0.5885 0.5580 0.5037 0.043 Uiso 1 1 calc R . .
H34C H 0.6474 0.6108 0.4953 0.043 Uiso 1 1 calc R . .
C1X C 0.3478(5) 0.5447(4) 0.9308(11) 0.078(3) Uani 1 1 d U . .
H1X H 0.3108 0.5512 0.8555 0.093 Uiso 1 1 calc R . .
Cl1X Cl 0.39880(17) 0.47627(11) 0.8773(3) 0.1066(10) Uani 1 1 d U . .
Cl2X Cl 0.4043(2) 0.60829(12) 0.9240(3) 0.1205(12) Uani 1 1 d U . .
Cl3X Cl 0.3086(2) 0.53317(14) 1.0904(4) 0.1204(11) Uani 1 1 d U . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.016(5) . ?
Au1 N2 2.082(3) . ?
Au1 Cl1 2.3922(12) . ?
Au1 Au2 2.5126(3) . ?
Fe1 C2 2.028(4) . ?
Fe1 C8 2.042(5) . ?
Fe1 C9 2.042(5) . ?
Fe1 C4 2.048(5) . ?
Fe1 C7 2.050(5) . ?
Fe1 C1 2.054(5) . ?
Fe1 C5 2.055(5) . ?
Fe1 C3 2.061(5) . ?
Fe1 C10 2.065(5) . ?
Fe1 C6 2.071(6) . ?
Au2 C18 2.016(5) . ?
Au2 N1 2.089(4) . ?
Au2 Cl2 2.3946(14) . ?
Fe2 C19 2.023(4) . ?
Fe2 C26 2.036(5) . ?
Fe2 C27 2.047(4) . ?
Fe2 C21 2.048(5) . ?
Fe2 C20 2.050(5) . ?
Fe2 C24 2.052(5) . ?
Fe2 C25 2.052(6) . ?
Fe2 C22 2.056(5) . ?
Fe2 C18 2.064(5) . ?
Fe2 C23 2.065(5) . ?
O1 C12 1.334(6) . ?
O1 C13 1.447(6) . ?
N1 C12 1.299(6) . ?
N1 C14 1.488(6) . ?
C1 C2 1.429(7) . ?
C1 C5 1.436(6) . ?
O2 C29 1.341(6) . ?
O2 C30 1.451(6) . ?
N2 C29 1.302(6) . ?
N2 C31 1.477(5) . ?
C2 C12 1.440(6) . ?
C2 C3 1.444(6) . ?
C3 C4 1.433(7) . ?
C3 C11 1.490(7) . ?
C4 C5 1.422(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C10 1.416(7) . ?
C6 C7 1.427(8) . ?
C6 H6 0.9500 . ?
C7 C8 1.406(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.420(7) . ?
C8 H8 0.9500 . ?
C9 C10 1.415(7) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C13 C14 1.554(8) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.521(7) . ?
C14 H14 1.0000 . ?
C15 C17 1.519(7) . ?
C15 C16 1.521(8) . ?
C15 H15 1.0000 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C22 1.426(7) . ?
C18 C19 1.471(7) . ?
C19 C29 1.432(7) . ?
C19 C20 1.444(7) . ?
C20 C21 1.427(7) . ?
C20 C28 1.486(8) . ?
C21 C22 1.423(8) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C24 1.420(8) . ?
C23 C27 1.434(7) . ?
C23 H23 0.9500 . ?
C24 C25 1.419(8) . ?
C24 H24 0.9500 . ?
C25 C26 1.411(8) . ?
C25 H25 0.9500 . ?
C26 C27 1.407(8) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C30 C31 1.525(7) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.516(6) . ?
C31 H31 1.0000 . ?
C32 C33 1.509(7) . ?
C32 C34 1.539(7) . ?
C32 H32 1.0000 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C1X Cl3X 1.662(10) . ?
C1X Cl2X 1.744(10) . ?
C1X Cl1X 1.830(10) . ?
C1X H1X 1.0000 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 177.50(17) . . ?
C1 Au1 Cl1 90.94(13) . . ?
N2 Au1 Cl1 90.46(11) . . ?
C1 Au1 Au2 85.87(13) . . ?
N2 Au1 Au2 92.85(10) . . ?
Cl1 Au1 Au2 175.35(3) . . ?
C2 Fe1 C8 121.8(2) . . ?
C2 Fe1 C9 156.9(2) . . ?
C8 Fe1 C9 40.7(2) . . ?
C2 Fe1 C4 68.52(18) . . ?
C8 Fe1 C4 119.9(2) . . ?
C9 Fe1 C4 105.0(2) . . ?
C2 Fe1 C7 108.92(19) . . ?
C8 Fe1 C7 40.2(2) . . ?
C9 Fe1 C7 67.73(19) . . ?
C4 Fe1 C7 156.6(2) . . ?
C2 Fe1 C1 40.98(19) . . ?
C8 Fe1 C1 159.62(19) . . ?
C9 Fe1 C1 159.3(2) . . ?
C4 Fe1 C1 68.73(18) . . ?
C7 Fe1 C1 125.61(18) . . ?
C2 Fe1 C5 68.58(19) . . ?
C8 Fe1 C5 156.58(19) . . ?
C9 Fe1 C5 121.8(2) . . ?
C4 Fe1 C5 40.57(19) . . ?
C7 Fe1 C5 162.1(2) . . ?
C1 Fe1 C5 40.90(17) . . ?
C2 Fe1 C3 41.33(17) . . ?
C8 Fe1 C3 104.2(2) . . ?
C9 Fe1 C3 119.41(19) . . ?
C4 Fe1 C3 40.81(18) . . ?
C7 Fe1 C3 121.7(2) . . ?
C1 Fe1 C3 69.58(18) . . ?
C5 Fe1 C3 68.97(19) . . ?
C2 Fe1 C10 161.6(2) . . ?
C8 Fe1 C10 68.0(2) . . ?
C9 Fe1 C10 40.3(2) . . ?
C4 Fe1 C10 122.3(2) . . ?
C7 Fe1 C10 67.5(2) . . ?
C1 Fe1 C10 125.2(2) . . ?
C5 Fe1 C10 108.9(2) . . ?
C3 Fe1 C10 156.39(19) . . ?
C2 Fe1 C6 125.50(18) . . ?
C8 Fe1 C6 68.1(2) . . ?
C9 Fe1 C6 67.8(2) . . ?
C4 Fe1 C6 159.4(2) . . ?
C7 Fe1 C6 40.5(2) . . ?
C1 Fe1 C6 110.74(19) . . ?
C5 Fe1 C6 125.5(2) . . ?
C3 Fe1 C6 159.6(2) . . ?
C10 Fe1 C6 40.05(19) . . ?
C18 Au2 N1 176.07(18) . . ?
C18 Au2 Cl2 93.14(14) . . ?
N1 Au2 Cl2 90.19(12) . . ?
C18 Au2 Au1 86.22(14) . . ?
N1 Au2 Au1 90.65(11) . . ?
Cl2 Au2 Au1 174.99(4) . . ?
C19 Fe2 C26 153.0(2) . . ?
C19 Fe2 C27 165.8(2) . . ?
C26 Fe2 C27 40.3(2) . . ?
C19 Fe2 C21 68.67(19) . . ?
C26 Fe2 C21 104.3(2) . . ?
C27 Fe2 C21 119.0(2) . . ?
C19 Fe2 C20 41.52(19) . . ?
C26 Fe2 C20 116.1(2) . . ?
C27 Fe2 C20 151.9(2) . . ?
C21 Fe2 C20 40.8(2) . . ?
C19 Fe2 C24 109.3(2) . . ?
C26 Fe2 C24 67.9(2) . . ?
C27 Fe2 C24 67.9(2) . . ?
C21 Fe2 C24 159.7(2) . . ?
C20 Fe2 C24 124.2(2) . . ?
C19 Fe2 C25 119.7(2) . . ?
C26 Fe2 C25 40.4(2) . . ?
C27 Fe2 C25 67.9(2) . . ?
C21 Fe2 C25 121.7(2) . . ?
C20 Fe2 C25 103.9(2) . . ?
C24 Fe2 C25 40.5(2) . . ?
C19 Fe2 C22 69.1(2) . . ?
C26 Fe2 C22 123.4(2) . . ?
C27 Fe2 C22 108.2(2) . . ?
C21 Fe2 C22 40.6(2) . . ?
C20 Fe2 C22 69.3(2) . . ?
C24 Fe2 C22 159.2(2) . . ?
C25 Fe2 C22 159.0(2) . . ?
C19 Fe2 C18 42.2(2) . . ?
C26 Fe2 C18 161.5(2) . . ?
C27 Fe2 C18 126.9(2) . . ?
C21 Fe2 C18 68.7(2) . . ?
C20 Fe2 C18 70.4(2) . . ?
C24 Fe2 C18 124.3(2) . . ?
C25 Fe2 C18 157.8(2) . . ?
C22 Fe2 C18 40.49(19) . . ?
C19 Fe2 C23 128.1(2) . . ?
C26 Fe2 C23 68.4(2) . . ?
C27 Fe2 C23 40.8(2) . . ?
C21 Fe2 C23 156.1(2) . . ?
C20 Fe2 C23 163.1(2) . . ?
C24 Fe2 C23 40.4(2) . . ?
C25 Fe2 C23 68.3(2) . . ?
C22 Fe2 C23 123.3(2) . . ?
C18 Fe2 C23 110.8(2) . . ?
C12 O1 C13 107.8(4) . . ?
C12 N1 C14 109.4(4) . . ?
C12 N1 Au2 126.4(3) . . ?
C14 N1 Au2 123.8(3) . . ?
C2 C1 C5 106.9(4) . . ?
C2 C1 Au1 126.9(3) . . ?
C5 C1 Au1 124.0(4) . . ?
C2 C1 Fe1 68.6(3) . . ?
C5 C1 Fe1 69.6(3) . . ?
Au1 C1 Fe1 140.1(2) . . ?
C29 O2 C30 105.5(4) . . ?
C29 N2 C31 108.0(4) . . ?
C29 N2 Au1 123.2(3) . . ?
C31 N2 Au1 128.7(3) . . ?
C1 C2 C12 124.2(4) . . ?
C1 C2 C3 109.6(4) . . ?
C12 C2 C3 126.0(5) . . ?
C1 C2 Fe1 70.5(2) . . ?
C12 C2 Fe1 121.7(3) . . ?
C3 C2 Fe1 70.6(3) . . ?
C4 C3 C2 105.8(4) . . ?
C4 C3 C11 124.2(4) . . ?
C2 C3 C11 129.9(4) . . ?
C4 C3 Fe1 69.1(3) . . ?
C2 C3 Fe1 68.1(3) . . ?
C11 C3 Fe1 129.1(4) . . ?
C5 C4 C3 109.4(4) . . ?
C5 C4 Fe1 70.0(3) . . ?
C3 C4 Fe1 70.1(3) . . ?
C5 C4 H4 125.3 . . ?
C3 C4 H4 125.3 . . ?
Fe1 C4 H4 126.2 . . ?
C4 C5 C1 108.2(4) . . ?
C4 C5 Fe1 69.4(3) . . ?
C1 C5 Fe1 69.5(3) . . ?
C4 C5 H5 125.9 . . ?
C1 C5 H5 125.9 . . ?
Fe1 C5 H5 126.8 . . ?
C10 C6 C7 107.1(5) . . ?
C10 C6 Fe1 69.7(3) . . ?
C7 C6 Fe1 68.9(3) . . ?
C10 C6 H6 126.5 . . ?
C7 C6 H6 126.5 . . ?
Fe1 C6 H6 126.4 . . ?
C8 C7 C6 108.8(5) . . ?
C8 C7 Fe1 69.6(3) . . ?
C6 C7 Fe1 70.5(3) . . ?
C8 C7 H7 125.6 . . ?
C6 C7 H7 125.6 . . ?
Fe1 C7 H7 125.8 . . ?
C7 C8 C9 107.6(5) . . ?
C7 C8 Fe1 70.2(3) . . ?
C9 C8 Fe1 69.7(3) . . ?
C7 C8 H8 126.2 . . ?
C9 C8 H8 126.2 . . ?
Fe1 C8 H8 125.5 . . ?
C10 C9 C8 108.2(5) . . ?
C10 C9 Fe1 70.7(3) . . ?
C8 C9 Fe1 69.6(3) . . ?
C10 C9 H9 125.9 . . ?
C8 C9 H9 125.9 . . ?
Fe1 C9 H9 125.3 . . ?
C9 C10 C6 108.3(5) . . ?
C9 C10 Fe1 69.0(3) . . ?
C6 C10 Fe1 70.2(3) . . ?
C9 C10 H10 125.8 . . ?
C6 C10 H10 125.8 . . ?
Fe1 C10 H10 126.5 . . ?
C3 C11 H11A 109.5 . . ?
C3 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C3 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N1 C12 O1 116.0(4) . . ?
N1 C12 C2 125.7(5) . . ?
O1 C12 C2 118.2(4) . . ?
O1 C13 C14 105.3(4) . . ?
O1 C13 H13A 110.7 . . ?
C14 C13 H13A 110.7 . . ?
O1 C13 H13B 110.7 . . ?
C14 C13 H13B 110.7 . . ?
H13A C13 H13B 108.8 . . ?
N1 C14 C15 112.3(4) . . ?
N1 C14 C13 101.5(4) . . ?
C15 C14 C13 114.6(5) . . ?
N1 C14 H14 109.4 . . ?
C15 C14 H14 109.4 . . ?
C13 C14 H14 109.4 . . ?
C17 C15 C14 109.8(5) . . ?
C17 C15 C16 111.2(5) . . ?
C14 C15 C16 112.3(4) . . ?
C17 C15 H15 107.8 . . ?
C14 C15 H15 107.8 . . ?
C16 C15 H15 107.8 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C22 C18 C19 106.0(4) . . ?
C22 C18 Au2 125.5(4) . . ?
C19 C18 Au2 127.9(3) . . ?
C22 C18 Fe2 69.4(3) . . ?
C19 C18 Fe2 67.4(3) . . ?
Au2 C18 Fe2 134.5(3) . . ?
C29 C19 C20 126.2(5) . . ?
C29 C19 C18 124.9(4) . . ?
C20 C19 C18 108.9(4) . . ?
C29 C19 Fe2 125.2(3) . . ?
C20 C19 Fe2 70.2(3) . . ?
C18 C19 Fe2 70.4(3) . . ?
C21 C20 C19 106.2(5) . . ?
C21 C20 C28 127.1(5) . . ?
C19 C20 C28 126.7(5) . . ?
C21 C20 Fe2 69.5(3) . . ?
C19 C20 Fe2 68.2(2) . . ?
C28 C20 Fe2 127.1(4) . . ?
C22 C21 C20 109.8(5) . . ?
C22 C21 Fe2 70.0(3) . . ?
C20 C21 Fe2 69.7(3) . . ?
C22 C21 H21 125.1 . . ?
C20 C21 H21 125.1 . . ?
Fe2 C21 H21 126.8 . . ?
C21 C22 C18 109.0(5) . . ?
C21 C22 Fe2 69.4(3) . . ?
C18 C22 Fe2 70.1(3) . . ?
C21 C22 H22 125.5 . . ?
C18 C22 H22 125.5 . . ?
Fe2 C22 H22 126.6 . . ?
C24 C23 C27 106.6(5) . . ?
C24 C23 Fe2 69.3(3) . . ?
C27 C23 Fe2 68.9(3) . . ?
C24 C23 H23 126.7 . . ?
C27 C23 H23 126.7 . . ?
Fe2 C23 H23 126.6 . . ?
C25 C24 C23 108.9(5) . . ?
C25 C24 Fe2 69.8(3) . . ?
C23 C24 Fe2 70.3(3) . . ?
C25 C24 H24 125.5 . . ?
C23 C24 H24 125.5 . . ?
Fe2 C24 H24 126.0 . . ?
C26 C25 C24 107.5(5) . . ?
C26 C25 Fe2 69.2(3) . . ?
C24 C25 Fe2 69.8(3) . . ?
C26 C25 H25 126.3 . . ?
C24 C25 H25 126.2 . . ?
Fe2 C25 H25 126.4 . . ?
C27 C26 C25 108.7(5) . . ?
C27 C26 Fe2 70.2(3) . . ?
C25 C26 Fe2 70.4(3) . . ?
C27 C26 H26 125.7 . . ?
C25 C26 H26 125.7 . . ?
Fe2 C26 H26 125.3 . . ?
C26 C27 C23 108.3(5) . . ?
C26 C27 Fe2 69.4(3) . . ?
C23 C27 Fe2 70.3(3) . . ?
C26 C27 H27 125.8 . . ?
C23 C27 H27 125.8 . . ?
Fe2 C27 H27 126.1 . . ?
C20 C28 H28A 109.5 . . ?
C20 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C20 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N2 C29 O2 116.2(4) . . ?
N2 C29 C19 126.9(5) . . ?
O2 C29 C19 116.9(4) . . ?
O2 C30 C31 105.1(4) . . ?
O2 C30 H30A 110.7 . . ?
C31 C30 H30A 110.7 . . ?
O2 C30 H30B 110.7 . . ?
C31 C30 H30B 110.7 . . ?
H30A C30 H30B 108.8 . . ?
N2 C31 C32 110.6(4) . . ?
N2 C31 C30 101.2(4) . . ?
C32 C31 C30 116.1(4) . . ?
N2 C31 H31 109.5 . . ?
C32 C31 H31 109.5 . . ?
C30 C31 H31 109.5 . . ?
C33 C32 C31 113.4(4) . . ?
C33 C32 C34 111.2(4) . . ?
C31 C32 C34 110.2(4) . . ?
C33 C32 H32 107.3 . . ?
C31 C32 H32 107.3 . . ?
C34 C32 H32 107.3 . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C32 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C32 C34 H34A 109.5 . . ?
C32 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C32 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
Cl3X C1X Cl2X 115.4(6) . . ?
Cl3X C1X Cl1X 111.0(5) . . ?
Cl2X C1X Cl1X 106.6(6) . . ?
Cl3X C1X H1X 107.9 . . ?
Cl2X C1X H1X 107.9 . . ?
Cl1X C1X H1X 107.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C18 128.92(19) . . . . ?
N2 Au1 Au2 C18 -53.23(17) . . . . ?
Cl1 Au1 Au2 C18 82.1(4) . . . . ?
C1 Au1 Au2 N1 -53.45(16) . . . . ?
N2 Au1 Au2 N1 124.40(14) . . . . ?
Cl1 Au1 Au2 N1 -100.2(4) . . . . ?
C1 Au1 Au2 Cl2 46.1(5) . . . . ?
N2 Au1 Au2 Cl2 -136.1(5) . . . . ?
Cl1 Au1 Au2 Cl2 -0.7(6) . . . . ?
C18 Au2 N1 C12 87(3) . . . . ?
Cl2 Au2 N1 C12 -125.4(4) . . . . ?
Au1 Au2 N1 C12 49.7(4) . . . . ?
C18 Au2 N1 C14 -101(3) . . . . ?
Cl2 Au2 N1 C14 46.5(4) . . . . ?
Au1 Au2 N1 C14 -138.4(4) . . . . ?
N2 Au1 C1 C2 -2(4) . . . . ?
Cl1 Au1 C1 C2 -126.1(4) . . . . ?
Au2 Au1 C1 C2 57.3(4) . . . . ?
N2 Au1 C1 C5 159(4) . . . . ?
Cl1 Au1 C1 C5 34.6(4) . . . . ?
Au2 Au1 C1 C5 -142.0(4) . . . . ?
N2 Au1 C1 Fe1 -103(4) . . . . ?
Cl1 Au1 C1 Fe1 133.3(4) . . . . ?
Au2 Au1 C1 Fe1 -43.3(3) . . . . ?
C8 Fe1 C1 C2 -37.9(7) . . . . ?
C9 Fe1 C1 C2 157.3(5) . . . . ?
C4 Fe1 C1 C2 81.3(3) . . . . ?
C7 Fe1 C1 C2 -77.5(3) . . . . ?
C5 Fe1 C1 C2 118.6(4) . . . . ?
C3 Fe1 C1 C2 37.5(3) . . . . ?
C10 Fe1 C1 C2 -163.5(3) . . . . ?
C6 Fe1 C1 C2 -120.7(3) . . . . ?
C2 Fe1 C1 C5 -118.6(4) . . . . ?
C8 Fe1 C1 C5 -156.5(6) . . . . ?
C9 Fe1 C1 C5 38.7(7) . . . . ?
C4 Fe1 C1 C5 -37.3(3) . . . . ?
C7 Fe1 C1 C5 163.9(3) . . . . ?
C3 Fe1 C1 C5 -81.1(3) . . . . ?
C10 Fe1 C1 C5 78.0(3) . . . . ?
C6 Fe1 C1 C5 120.7(3) . . . . ?
C2 Fe1 C1 Au1 122.4(5) . . . . ?
C8 Fe1 C1 Au1 84.5(7) . . . . ?
C9 Fe1 C1 Au1 -80.3(7) . . . . ?
C4 Fe1 C1 Au1 -156.3(4) . . . . ?
C7 Fe1 C1 Au1 44.9(5) . . . . ?
C5 Fe1 C1 Au1 -119.0(5) . . . . ?
C3 Fe1 C1 Au1 159.9(4) . . . . ?
C10 Fe1 C1 Au1 -41.0(5) . . . . ?
C6 Fe1 C1 Au1 1.7(4) . . . . ?
C1 Au1 N2 C29 112(4) . . . . ?
Cl1 Au1 N2 C29 -124.3(4) . . . . ?
Au2 Au1 N2 C29 52.4(4) . . . . ?
C1 Au1 N2 C31 -73(4) . . . . ?
Cl1 Au1 N2 C31 50.8(4) . . . . ?
Au2 Au1 N2 C31 -132.5(3) . . . . ?
C5 C1 C2 C12 175.0(4) . . . . ?
Au1 C1 C2 C12 -21.7(7) . . . . ?
Fe1 C1 C2 C12 115.7(5) . . . . ?
C5 C1 C2 C3 -0.6(5) . . . . ?
Au1 C1 C2 C3 162.8(3) . . . . ?
Fe1 C1 C2 C3 -59.9(3) . . . . ?
C5 C1 C2 Fe1 59.3(3) . . . . ?
Au1 C1 C2 Fe1 -137.3(4) . . . . ?
C8 Fe1 C2 C1 165.4(3) . . . . ?
C9 Fe1 C2 C1 -159.6(5) . . . . ?
C4 Fe1 C2 C1 -81.9(3) . . . . ?
C7 Fe1 C2 C1 123.0(3) . . . . ?
C5 Fe1 C2 C1 -38.1(3) . . . . ?
C3 Fe1 C2 C1 -120.2(4) . . . . ?
C10 Fe1 C2 C1 47.4(7) . . . . ?
C6 Fe1 C2 C1 80.9(3) . . . . ?
C8 Fe1 C2 C12 46.6(5) . . . . ?
C9 Fe1 C2 C12 81.5(6) . . . . ?
C4 Fe1 C2 C12 159.3(5) . . . . ?
C7 Fe1 C2 C12 4.1(5) . . . . ?
C1 Fe1 C2 C12 -118.9(5) . . . . ?
C5 Fe1 C2 C12 -157.0(4) . . . . ?
C3 Fe1 C2 C12 120.9(5) . . . . ?
C10 Fe1 C2 C12 -71.4(8) . . . . ?
C6 Fe1 C2 C12 -37.9(5) . . . . ?
C8 Fe1 C2 C3 -74.4(3) . . . . ?
C9 Fe1 C2 C3 -39.4(6) . . . . ?
C4 Fe1 C2 C3 38.4(3) . . . . ?
C7 Fe1 C2 C3 -116.8(3) . . . . ?
C1 Fe1 C2 C3 120.2(4) . . . . ?
C5 Fe1 C2 C3 82.1(3) . . . . ?
C10 Fe1 C2 C3 167.7(6) . . . . ?
C6 Fe1 C2 C3 -158.9(3) . . . . ?
C1 C2 C3 C4 0.8(5) . . . . ?
C12 C2 C3 C4 -174.7(5) . . . . ?
Fe1 C2 C3 C4 -59.1(3) . . . . ?
C1 C2 C3 C11 -176.8(5) . . . . ?
C12 C2 C3 C11 7.8(8) . . . . ?
Fe1 C2 C3 C11 123.4(6) . . . . ?
C1 C2 C3 Fe1 59.8(3) . . . . ?
C12 C2 C3 Fe1 -115.6(5) . . . . ?
C2 Fe1 C3 C4 117.9(4) . . . . ?
C8 Fe1 C3 C4 -119.6(3) . . . . ?
C9 Fe1 C3 C4 -78.6(3) . . . . ?
C7 Fe1 C3 C4 -159.2(3) . . . . ?
C1 Fe1 C3 C4 80.7(3) . . . . ?
C5 Fe1 C3 C4 36.9(3) . . . . ?
C10 Fe1 C3 C4 -52.4(6) . . . . ?
C6 Fe1 C3 C4 175.5(5) . . . . ?
C8 Fe1 C3 C2 122.5(3) . . . . ?
C9 Fe1 C3 C2 163.4(3) . . . . ?
C4 Fe1 C3 C2 -117.9(4) . . . . ?
C7 Fe1 C3 C2 82.8(3) . . . . ?
C1 Fe1 C3 C2 -37.2(3) . . . . ?
C5 Fe1 C3 C2 -81.1(3) . . . . ?
C10 Fe1 C3 C2 -170.3(5) . . . . ?
C6 Fe1 C3 C2 57.6(7) . . . . ?
C2 Fe1 C3 C11 -124.4(5) . . . . ?
C8 Fe1 C3 C11 -2.0(5) . . . . ?
C9 Fe1 C3 C11 39.0(5) . . . . ?
C4 Fe1 C3 C11 117.6(5) . . . . ?
C7 Fe1 C3 C11 -41.6(5) . . . . ?
C1 Fe1 C3 C11 -161.6(5) . . . . ?
C5 Fe1 C3 C11 154.5(5) . . . . ?
C10 Fe1 C3 C11 65.3(7) . . . . ?
C6 Fe1 C3 C11 -66.9(7) . . . . ?
C2 C3 C4 C5 -0.7(5) . . . . ?
C11 C3 C4 C5 177.0(5) . . . . ?
Fe1 C3 C4 C5 -59.1(3) . . . . ?
C2 C3 C4 Fe1 58.4(3) . . . . ?
C11 C3 C4 Fe1 -123.9(5) . . . . ?
C2 Fe1 C4 C5 81.7(3) . . . . ?
C8 Fe1 C4 C5 -162.9(3) . . . . ?
C9 Fe1 C4 C5 -121.6(3) . . . . ?
C7 Fe1 C4 C5 169.9(4) . . . . ?
C1 Fe1 C4 C5 37.6(3) . . . . ?
C3 Fe1 C4 C5 120.6(4) . . . . ?
C10 Fe1 C4 C5 -81.5(3) . . . . ?
C6 Fe1 C4 C5 -55.0(7) . . . . ?
C2 Fe1 C4 C3 -38.8(3) . . . . ?
C8 Fe1 C4 C3 76.5(3) . . . . ?
C9 Fe1 C4 C3 117.8(3) . . . . ?
C7 Fe1 C4 C3 49.4(6) . . . . ?
C1 Fe1 C4 C3 -83.0(3) . . . . ?
C5 Fe1 C4 C3 -120.6(4) . . . . ?
C10 Fe1 C4 C3 158.0(3) . . . . ?
C6 Fe1 C4 C3 -175.5(5) . . . . ?
C3 C4 C5 C1 0.3(6) . . . . ?
Fe1 C4 C5 C1 -58.8(3) . . . . ?
C3 C4 C5 Fe1 59.2(3) . . . . ?
C2 C1 C5 C4 0.2(5) . . . . ?
Au1 C1 C5 C4 -163.8(3) . . . . ?
Fe1 C1 C5 C4 58.8(3) . . . . ?
C2 C1 C5 Fe1 -58.7(3) . . . . ?
Au1 C1 C5 Fe1 137.4(3) . . . . ?
C2 Fe1 C5 C4 -81.6(3) . . . . ?
C8 Fe1 C5 C4 39.8(6) . . . . ?
C9 Fe1 C5 C4 75.3(3) . . . . ?
C7 Fe1 C5 C4 -166.9(6) . . . . ?
C1 Fe1 C5 C4 -119.8(4) . . . . ?
C3 Fe1 C5 C4 -37.1(3) . . . . ?
C10 Fe1 C5 C4 117.9(3) . . . . ?
C6 Fe1 C5 C4 159.3(3) . . . . ?
C2 Fe1 C5 C1 38.2(3) . . . . ?
C8 Fe1 C5 C1 159.6(5) . . . . ?
C9 Fe1 C5 C1 -164.9(3) . . . . ?
C4 Fe1 C5 C1 119.8(4) . . . . ?
C7 Fe1 C5 C1 -47.1(7) . . . . ?
C3 Fe1 C5 C1 82.7(3) . . . . ?
C10 Fe1 C5 C1 -122.3(3) . . . . ?
C6 Fe1 C5 C1 -80.9(3) . . . . ?
C2 Fe1 C6 C10 -164.3(3) . . . . ?
C8 Fe1 C6 C10 81.4(3) . . . . ?
C9 Fe1 C6 C10 37.3(3) . . . . ?
C4 Fe1 C6 C10 -35.9(7) . . . . ?
C7 Fe1 C6 C10 118.5(4) . . . . ?
C1 Fe1 C6 C10 -120.5(3) . . . . ?
C5 Fe1 C6 C10 -76.7(4) . . . . ?
C3 Fe1 C6 C10 152.5(5) . . . . ?
C2 Fe1 C6 C7 77.2(3) . . . . ?
C8 Fe1 C6 C7 -37.1(3) . . . . ?
C9 Fe1 C6 C7 -81.2(3) . . . . ?
C4 Fe1 C6 C7 -154.4(5) . . . . ?
C1 Fe1 C6 C7 121.0(3) . . . . ?
C5 Fe1 C6 C7 164.7(3) . . . . ?
C3 Fe1 C6 C7 34.0(7) . . . . ?
C10 Fe1 C6 C7 -118.5(4) . . . . ?
C10 C6 C7 C8 -0.3(6) . . . . ?
Fe1 C6 C7 C8 59.3(4) . . . . ?
C10 C6 C7 Fe1 -59.6(4) . . . . ?
C2 Fe1 C7 C8 117.3(3) . . . . ?
C9 Fe1 C7 C8 -38.3(3) . . . . ?
C4 Fe1 C7 C8 37.8(6) . . . . ?
C1 Fe1 C7 C8 159.9(3) . . . . ?
C5 Fe1 C7 C8 -163.9(6) . . . . ?
C3 Fe1 C7 C8 73.5(4) . . . . ?
C10 Fe1 C7 C8 -82.0(3) . . . . ?
C6 Fe1 C7 C8 -119.7(4) . . . . ?
C2 Fe1 C7 C6 -123.0(3) . . . . ?
C8 Fe1 C7 C6 119.7(4) . . . . ?
C9 Fe1 C7 C6 81.4(3) . . . . ?
C4 Fe1 C7 C6 157.6(4) . . . . ?
C1 Fe1 C7 C6 -80.4(3) . . . . ?
C5 Fe1 C7 C6 -44.2(7) . . . . ?
C3 Fe1 C7 C6 -166.8(3) . . . . ?
C10 Fe1 C7 C6 37.7(3) . . . . ?
C6 C7 C8 C9 0.0(6) . . . . ?
Fe1 C7 C8 C9 59.9(4) . . . . ?
C6 C7 C8 Fe1 -59.9(4) . . . . ?
C2 Fe1 C8 C7 -81.7(4) . . . . ?
C9 Fe1 C8 C7 118.4(5) . . . . ?
C4 Fe1 C8 C7 -163.7(3) . . . . ?
C1 Fe1 C8 C7 -53.4(7) . . . . ?
C5 Fe1 C8 C7 167.6(5) . . . . ?
C3 Fe1 C8 C7 -122.7(3) . . . . ?
C10 Fe1 C8 C7 80.8(3) . . . . ?
C6 Fe1 C8 C7 37.4(3) . . . . ?
C2 Fe1 C8 C9 159.9(3) . . . . ?
C4 Fe1 C8 C9 77.9(4) . . . . ?
C7 Fe1 C8 C9 -118.4(5) . . . . ?
C1 Fe1 C8 C9 -171.8(5) . . . . ?
C5 Fe1 C8 C9 49.2(7) . . . . ?
C3 Fe1 C8 C9 118.9(3) . . . . ?
C10 Fe1 C8 C9 -37.7(3) . . . . ?
C6 Fe1 C8 C9 -81.0(3) . . . . ?
C7 C8 C9 C10 0.2(6) . . . . ?
Fe1 C8 C9 C10 60.5(4) . . . . ?
C7 C8 C9 Fe1 -60.2(4) . . . . ?
C2 Fe1 C9 C10 -167.2(5) . . . . ?
C8 Fe1 C9 C10 -118.9(5) . . . . ?
C4 Fe1 C9 C10 122.5(3) . . . . ?
C7 Fe1 C9 C10 -81.0(3) . . . . ?
C1 Fe1 C9 C10 53.1(7) . . . . ?
C5 Fe1 C9 C10 81.9(4) . . . . ?
C3 Fe1 C9 C10 164.1(3) . . . . ?
C6 Fe1 C9 C10 -37.1(3) . . . . ?
C2 Fe1 C9 C8 -48.3(6) . . . . ?
C4 Fe1 C9 C8 -118.6(3) . . . . ?
C7 Fe1 C9 C8 37.8(3) . . . . ?
C1 Fe1 C9 C8 171.9(5) . . . . ?
C5 Fe1 C9 C8 -159.3(3) . . . . ?
C3 Fe1 C9 C8 -77.1(4) . . . . ?
C10 Fe1 C9 C8 118.9(5) . . . . ?
C6 Fe1 C9 C8 81.8(4) . . . . ?
C8 C9 C10 C6 -0.4(6) . . . . ?
Fe1 C9 C10 C6 59.4(4) . . . . ?
C8 C9 C10 Fe1 -59.8(4) . . . . ?
C7 C6 C10 C9 0.4(6) . . . . ?
Fe1 C6 C10 C9 -58.6(4) . . . . ?
C7 C6 C10 Fe1 59.1(4) . . . . ?
C2 Fe1 C10 C9 164.0(6) . . . . ?
C8 Fe1 C10 C9 38.0(3) . . . . ?
C4 Fe1 C10 C9 -74.3(4) . . . . ?
C7 Fe1 C10 C9 81.6(3) . . . . ?
C1 Fe1 C10 C9 -159.8(3) . . . . ?
C5 Fe1 C10 C9 -117.2(3) . . . . ?
C3 Fe1 C10 C9 -36.6(7) . . . . ?
C6 Fe1 C10 C9 119.7(5) . . . . ?
C2 Fe1 C10 C6 44.3(8) . . . . ?
C8 Fe1 C10 C6 -81.7(3) . . . . ?
C9 Fe1 C10 C6 -119.7(5) . . . . ?
C4 Fe1 C10 C6 165.9(3) . . . . ?
C7 Fe1 C10 C6 -38.1(3) . . . . ?
C1 Fe1 C10 C6 80.5(4) . . . . ?
C5 Fe1 C10 C6 123.1(3) . . . . ?
C3 Fe1 C10 C6 -156.4(5) . . . . ?
C14 N1 C12 O1 -0.5(6) . . . . ?
Au2 N1 C12 O1 172.4(3) . . . . ?
C14 N1 C12 C2 176.6(4) . . . . ?
Au2 N1 C12 C2 -10.6(7) . . . . ?
C13 O1 C12 N1 0.9(6) . . . . ?
C13 O1 C12 C2 -176.4(5) . . . . ?
C1 C2 C12 N1 -15.8(8) . . . . ?
C3 C2 C12 N1 159.1(5) . . . . ?
Fe1 C2 C12 N1 71.1(6) . . . . ?
C1 C2 C12 O1 161.2(4) . . . . ?
C3 C2 C12 O1 -23.9(7) . . . . ?
Fe1 C2 C12 O1 -111.9(4) . . . . ?
C12 O1 C13 C14 -1.0(6) . . . . ?
C12 N1 C14 C15 -123.0(5) . . . . ?
Au2 N1 C14 C15 63.9(6) . . . . ?
C12 N1 C14 C13 -0.2(6) . . . . ?
Au2 N1 C14 C13 -173.3(4) . . . . ?
O1 C13 C14 N1 0.7(6) . . . . ?
O1 C13 C14 C15 121.9(5) . . . . ?
N1 C14 C15 C17 -178.9(5) . . . . ?
C13 C14 C15 C17 66.0(6) . . . . ?
N1 C14 C15 C16 56.8(7) . . . . ?
C13 C14 C15 C16 -58.3(6) . . . . ?
N1 Au2 C18 C22 -179(100) . . . . ?
Cl2 Au2 C18 C22 33.0(4) . . . . ?
Au1 Au2 C18 C22 -142.0(4) . . . . ?
N1 Au2 C18 C19 11(3) . . . . ?
Cl2 Au2 C18 C19 -136.7(4) . . . . ?
Au1 Au2 C18 C19 48.2(4) . . . . ?
N1 Au2 C18 Fe2 -84(3) . . . . ?
Cl2 Au2 C18 Fe2 128.5(3) . . . . ?
Au1 Au2 C18 Fe2 -46.5(3) . . . . ?
C19 Fe2 C18 C22 -118.4(4) . . . . ?
C26 Fe2 C18 C22 33.5(8) . . . . ?
C27 Fe2 C18 C22 74.0(4) . . . . ?
C21 Fe2 C18 C22 -37.0(3) . . . . ?
C20 Fe2 C18 C22 -80.7(3) . . . . ?
C24 Fe2 C18 C22 160.6(3) . . . . ?
C25 Fe2 C18 C22 -159.4(5) . . . . ?
C23 Fe2 C18 C22 117.3(3) . . . . ?
C26 Fe2 C18 C19 151.9(6) . . . . ?
C27 Fe2 C18 C19 -167.7(3) . . . . ?
C21 Fe2 C18 C19 81.3(3) . . . . ?
C20 Fe2 C18 C19 37.7(3) . . . . ?
C24 Fe2 C18 C19 -81.0(3) . . . . ?
C25 Fe2 C18 C19 -41.0(6) . . . . ?
C22 Fe2 C18 C19 118.4(4) . . . . ?
C23 Fe2 C18 C19 -124.3(3) . . . . ?
C19 Fe2 C18 Au2 121.6(5) . . . . ?
C26 Fe2 C18 Au2 -86.5(7) . . . . ?
C27 Fe2 C18 Au2 -46.1(5) . . . . ?
C21 Fe2 C18 Au2 -157.1(4) . . . . ?
C20 Fe2 C18 Au2 159.3(4) . . . . ?
C24 Fe2 C18 Au2 40.6(5) . . . . ?
C25 Fe2 C18 Au2 80.6(7) . . . . ?
C22 Fe2 C18 Au2 -120.0(5) . . . . ?
C23 Fe2 C18 Au2 -2.7(4) . . . . ?
C22 C18 C19 C29 178.8(4) . . . . ?
Au2 C18 C19 C29 -9.8(7) . . . . ?
Fe2 C18 C19 C29 119.9(5) . . . . ?
C22 C18 C19 C20 -1.0(5) . . . . ?
Au2 C18 C19 C20 170.4(3) . . . . ?
Fe2 C18 C19 C20 -59.9(3) . . . . ?
C22 C18 C19 Fe2 59.0(3) . . . . ?
Au2 C18 C19 Fe2 -129.7(4) . . . . ?
C26 Fe2 C19 C29 79.7(6) . . . . ?
C27 Fe2 C19 C29 -75.3(11) . . . . ?
C21 Fe2 C19 C29 159.2(5) . . . . ?
C20 Fe2 C19 C29 121.0(6) . . . . ?
C24 Fe2 C19 C29 0.7(5) . . . . ?
C25 Fe2 C19 C29 44.0(5) . . . . ?
C22 Fe2 C19 C29 -157.1(5) . . . . ?
C18 Fe2 C19 C29 -119.4(5) . . . . ?
C23 Fe2 C19 C29 -40.6(5) . . . . ?
C26 Fe2 C19 C20 -41.3(6) . . . . ?
C27 Fe2 C19 C20 163.8(9) . . . . ?
C21 Fe2 C19 C20 38.2(3) . . . . ?
C24 Fe2 C19 C20 -120.3(3) . . . . ?
C25 Fe2 C19 C20 -77.0(4) . . . . ?
C22 Fe2 C19 C20 81.9(3) . . . . ?
C18 Fe2 C19 C20 119.6(4) . . . . ?
C23 Fe2 C19 C20 -161.6(3) . . . . ?
C26 Fe2 C19 C18 -160.8(5) . . . . ?
C27 Fe2 C19 C18 44.2(10) . . . . ?
C21 Fe2 C19 C18 -81.3(3) . . . . ?
C20 Fe2 C19 C18 -119.6(4) . . . . ?
C24 Fe2 C19 C18 120.2(3) . . . . ?
C25 Fe2 C19 C18 163.4(3) . . . . ?
C22 Fe2 C19 C18 -37.7(3) . . . . ?
C23 Fe2 C19 C18 78.9(4) . . . . ?
C29 C19 C20 C21 -179.2(4) . . . . ?
C18 C19 C20 C21 0.6(5) . . . . ?
Fe2 C19 C20 C21 -59.5(3) . . . . ?
C29 C19 C20 C28 1.1(8) . . . . ?
C18 C19 C20 C28 -179.1(5) . . . . ?
Fe2 C19 C20 C28 120.8(5) . . . . ?
C29 C19 C20 Fe2 -119.7(5) . . . . ?
C18 C19 C20 Fe2 60.0(3) . . . . ?
C19 Fe2 C20 C21 118.0(5) . . . . ?
C26 Fe2 C20 C21 -81.5(4) . . . . ?
C27 Fe2 C20 C21 -53.6(6) . . . . ?
C24 Fe2 C20 C21 -161.5(3) . . . . ?
C25 Fe2 C20 C21 -122.7(4) . . . . ?
C22 Fe2 C20 C21 36.5(3) . . . . ?
C18 Fe2 C20 C21 79.7(3) . . . . ?
C23 Fe2 C20 C21 176.9(7) . . . . ?
C26 Fe2 C20 C19 160.5(3) . . . . ?
C27 Fe2 C20 C19 -171.6(5) . . . . ?
C21 Fe2 C20 C19 -118.0(5) . . . . ?
C24 Fe2 C20 C19 80.5(4) . . . . ?
C25 Fe2 C20 C19 119.3(3) . . . . ?
C22 Fe2 C20 C19 -81.5(3) . . . . ?
C18 Fe2 C20 C19 -38.3(3) . . . . ?
C23 Fe2 C20 C19 58.9(8) . . . . ?
C19 Fe2 C20 C28 -120.3(6) . . . . ?
C26 Fe2 C20 C28 40.2(5) . . . . ?
C27 Fe2 C20 C28 68.1(7) . . . . ?
C21 Fe2 C20 C28 121.7(6) . . . . ?
C24 Fe2 C20 C28 -39.8(5) . . . . ?
C25 Fe2 C20 C28 -1.0(5) . . . . ?
C22 Fe2 C20 C28 158.2(5) . . . . ?
C18 Fe2 C20 C28 -158.6(5) . . . . ?
C23 Fe2 C20 C28 -61.4(9) . . . . ?
C19 C20 C21 C22 0.1(6) . . . . ?
C28 C20 C21 C22 179.7(5) . . . . ?
Fe2 C20 C21 C22 -58.6(4) . . . . ?
C19 C20 C21 Fe2 58.6(3) . . . . ?
C28 C20 C21 Fe2 -121.7(5) . . . . ?
C19 Fe2 C21 C22 82.4(3) . . . . ?
C26 Fe2 C21 C22 -125.1(3) . . . . ?
C27 Fe2 C21 C22 -84.4(4) . . . . ?
C20 Fe2 C21 C22 121.3(4) . . . . ?
C24 Fe2 C21 C22 170.5(5) . . . . ?
C25 Fe2 C21 C22 -165.0(3) . . . . ?
C18 Fe2 C21 C22 37.0(3) . . . . ?
C23 Fe2 C21 C22 -56.4(6) . . . . ?
C19 Fe2 C21 C20 -38.9(3) . . . . ?
C26 Fe2 C21 C20 113.6(3) . . . . ?
C27 Fe2 C21 C20 154.3(3) . . . . ?
C24 Fe2 C21 C20 49.2(7) . . . . ?
C25 Fe2 C21 C20 73.6(4) . . . . ?
C22 Fe2 C21 C20 -121.3(4) . . . . ?
C18 Fe2 C21 C20 -84.4(3) . . . . ?
C23 Fe2 C21 C20 -177.8(5) . . . . ?
C20 C21 C22 C18 -0.7(6) . . . . ?
Fe2 C21 C22 C18 -59.1(3) . . . . ?
C20 C21 C22 Fe2 58.4(4) . . . . ?
C19 C18 C22 C21 1.0(5) . . . . ?
Au2 C18 C22 C21 -170.6(4) . . . . ?
Fe2 C18 C22 C21 58.6(4) . . . . ?
C19 C18 C22 Fe2 -57.7(3) . . . . ?
Au2 C18 C22 Fe2 130.7(4) . . . . ?
C19 Fe2 C22 C21 -81.2(3) . . . . ?
C26 Fe2 C22 C21 71.7(4) . . . . ?
C27 Fe2 C22 C21 113.6(3) . . . . ?
C20 Fe2 C22 C21 -36.6(3) . . . . ?
C24 Fe2 C22 C21 -170.8(5) . . . . ?
C25 Fe2 C22 C21 37.8(7) . . . . ?
C18 Fe2 C22 C21 -120.4(4) . . . . ?
C23 Fe2 C22 C21 156.2(3) . . . . ?
C19 Fe2 C22 C18 39.2(3) . . . . ?
C26 Fe2 C22 C18 -167.9(3) . . . . ?
C27 Fe2 C22 C18 -126.0(3) . . . . ?
C21 Fe2 C22 C18 120.4(4) . . . . ?
C20 Fe2 C22 C18 83.8(3) . . . . ?
C24 Fe2 C22 C18 -50.4(7) . . . . ?
C25 Fe2 C22 C18 158.2(5) . . . . ?
C23 Fe2 C22 C18 -83.4(3) . . . . ?
C19 Fe2 C23 C24 74.1(4) . . . . ?
C26 Fe2 C23 C24 -80.9(3) . . . . ?
C27 Fe2 C23 C24 -118.2(5) . . . . ?
C21 Fe2 C23 C24 -157.0(5) . . . . ?
C20 Fe2 C23 C24 28.0(9) . . . . ?
C25 Fe2 C23 C24 -37.3(3) . . . . ?
C22 Fe2 C23 C24 162.6(3) . . . . ?
C18 Fe2 C23 C24 118.9(3) . . . . ?
C19 Fe2 C23 C27 -167.7(4) . . . . ?
C26 Fe2 C23 C27 37.3(4) . . . . ?
C21 Fe2 C23 C27 -38.8(7) . . . . ?
C20 Fe2 C23 C27 146.2(7) . . . . ?
C24 Fe2 C23 C27 118.2(5) . . . . ?
C25 Fe2 C23 C27 80.9(4) . . . . ?
C22 Fe2 C23 C27 -79.2(4) . . . . ?
C18 Fe2 C23 C27 -122.9(4) . . . . ?
C27 C23 C24 C25 0.2(5) . . . . ?
Fe2 C23 C24 C25 59.3(4) . . . . ?
C27 C23 C24 Fe2 -59.1(3) . . . . ?
C19 Fe2 C24 C25 113.4(3) . . . . ?
C26 Fe2 C24 C25 -37.8(3) . . . . ?
C27 Fe2 C24 C25 -81.4(3) . . . . ?
C21 Fe2 C24 C25 32.9(7) . . . . ?
C20 Fe2 C24 C25 69.6(4) . . . . ?
C22 Fe2 C24 C25 -164.7(5) . . . . ?
C18 Fe2 C24 C25 158.1(3) . . . . ?
C23 Fe2 C24 C25 -119.9(4) . . . . ?
C19 Fe2 C24 C23 -126.6(3) . . . . ?
C26 Fe2 C24 C23 82.2(3) . . . . ?
C27 Fe2 C24 C23 38.5(3) . . . . ?
C21 Fe2 C24 C23 152.8(5) . . . . ?
C20 Fe2 C24 C23 -170.5(3) . . . . ?
C25 Fe2 C24 C23 119.9(4) . . . . ?
C22 Fe2 C24 C23 -44.8(7) . . . . ?
C18 Fe2 C24 C23 -82.0(4) . . . . ?
C23 C24 C25 C26 -0.5(6) . . . . ?
Fe2 C24 C25 C26 59.1(4) . . . . ?
C23 C24 C25 Fe2 -59.6(3) . . . . ?
C19 Fe2 C25 C26 155.8(3) . . . . ?
C27 Fe2 C25 C26 -37.5(3) . . . . ?
C21 Fe2 C25 C26 73.9(4) . . . . ?
C20 Fe2 C25 C26 114.1(3) . . . . ?
C24 Fe2 C25 C26 -118.9(4) . . . . ?
C22 Fe2 C25 C26 45.9(7) . . . . ?
C18 Fe2 C25 C26 -173.7(5) . . . . ?
C23 Fe2 C25 C26 -81.7(3) . . . . ?
C19 Fe2 C25 C24 -85.3(3) . . . . ?
C26 Fe2 C25 C24 118.9(4) . . . . ?
C27 Fe2 C25 C24 81.3(3) . . . . ?
C21 Fe2 C25 C24 -167.2(3) . . . . ?
C20 Fe2 C25 C24 -127.0(3) . . . . ?
C22 Fe2 C25 C24 164.8(5) . . . . ?
C18 Fe2 C25 C24 -54.9(6) . . . . ?
C23 Fe2 C25 C24 37.2(3) . . . . ?
C24 C25 C26 C27 0.6(6) . . . . ?
Fe2 C25 C26 C27 60.1(4) . . . . ?
C24 C25 C26 Fe2 -59.5(4) . . . . ?
C19 Fe2 C26 C27 -170.8(4) . . . . ?
C21 Fe2 C26 C27 118.3(4) . . . . ?
C20 Fe2 C26 C27 160.1(3) . . . . ?
C24 Fe2 C26 C27 -81.4(4) . . . . ?
C25 Fe2 C26 C27 -119.3(5) . . . . ?
C22 Fe2 C26 C27 78.7(4) . . . . ?
C18 Fe2 C26 C27 53.3(8) . . . . ?
C23 Fe2 C26 C27 -37.8(3) . . . . ?
C19 Fe2 C26 C25 -51.5(6) . . . . ?
C27 Fe2 C26 C25 119.3(5) . . . . ?
C21 Fe2 C26 C25 -122.5(3) . . . . ?
C20 Fe2 C26 C25 -80.7(4) . . . . ?
C24 Fe2 C26 C25 37.8(3) . . . . ?
C22 Fe2 C26 C25 -162.1(3) . . . . ?
C18 Fe2 C26 C25 172.5(6) . . . . ?
C23 Fe2 C26 C25 81.5(3) . . . . ?
C25 C26 C27 C23 -0.5(6) . . . . ?
Fe2 C26 C27 C23 59.7(3) . . . . ?
C25 C26 C27 Fe2 -60.2(4) . . . . ?
C24 C23 C27 C26 0.2(6) . . . . ?
Fe2 C23 C27 C26 -59.2(3) . . . . ?
C24 C23 C27 Fe2 59.4(3) . . . . ?
C19 Fe2 C27 C26 162.7(9) . . . . ?
C21 Fe2 C27 C26 -77.4(4) . . . . ?
C20 Fe2 C27 C26 -40.5(7) . . . . ?
C24 Fe2 C27 C26 81.4(4) . . . . ?
C25 Fe2 C27 C26 37.6(4) . . . . ?
C22 Fe2 C27 C26 -120.4(4) . . . . ?
C18 Fe2 C27 C26 -161.5(3) . . . . ?
C23 Fe2 C27 C26 119.5(5) . . . . ?
C19 Fe2 C27 C23 43.2(11) . . . . ?
C26 Fe2 C27 C23 -119.5(5) . . . . ?
C21 Fe2 C27 C23 163.1(3) . . . . ?
C20 Fe2 C27 C23 -159.9(4) . . . . ?
C24 Fe2 C27 C23 -38.0(3) . . . . ?
C25 Fe2 C27 C23 -81.9(4) . . . . ?
C22 Fe2 C27 C23 120.1(4) . . . . ?
C18 Fe2 C27 C23 79.1(4) . . . . ?
C31 N2 C29 O2 -6.8(6) . . . . ?
Au1 N2 C29 O2 169.1(3) . . . . ?
C31 N2 C29 C19 171.9(5) . . . . ?
Au1 N2 C29 C19 -12.1(7) . . . . ?
C30 O2 C29 N2 -6.7(6) . . . . ?
C30 O2 C29 C19 174.4(4) . . . . ?
C20 C19 C29 N2 158.5(5) . . . . ?
C18 C19 C29 N2 -21.3(8) . . . . ?
Fe2 C19 C29 N2 68.3(7) . . . . ?
C20 C19 C29 O2 -22.7(7) . . . . ?
C18 C19 C29 O2 157.5(4) . . . . ?
Fe2 C19 C29 O2 -112.9(4) . . . . ?
C29 O2 C30 C31 16.6(5) . . . . ?
C29 N2 C31 C32 -107.3(5) . . . . ?
Au1 N2 C31 C32 77.0(5) . . . . ?
C29 N2 C31 C30 16.3(5) . . . . ?
Au1 N2 C31 C30 -159.4(3) . . . . ?
O2 C30 C31 N2 -19.6(4) . . . . ?
O2 C30 C31 C32 100.1(5) . . . . ?
N2 C31 C32 C33 57.6(5) . . . . ?
C30 C31 C32 C33 -56.9(6) . . . . ?
N2 C31 C32 C34 -177.0(4) . . . . ?
C30 C31 C32 C34 68.5(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        30.55
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         1.730
_refine_diff_density_min         -1.203
_refine_diff_density_rms         0.159
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2300lm1
_database_code_depnum_ccdc_archive 'CCDC 1588447'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'tBuFOMeAu(II)Cl' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C36 H44 Au2 Cl2 Fe2 N2 O2, 2(C H2 Cl2)'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C38 H48 Au2 Cl6 Fe2 N2 O2'
_chemical_formula_weight         1283.12

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   10.3753(7)
_cell_length_b                   16.1108(9)
_cell_length_c                   25.1352(14)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     4201.5(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    8908
_cell_measurement_theta_min      1.50
_cell_measurement_theta_max      28.29

_exptl_crystal_description       needle
_exptl_crystal_colour            dark-purple
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.029
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2472
_exptl_absorpt_coefficient_mu    8.056
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.3875
_exptl_absorpt_correction_T_max  0.8285
_exptl_absorpt_process_details   'SADABS, (Bruker 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            58987
_diffrn_reflns_av_R_equivalents  0.0503
_diffrn_reflns_av_sigmaI/netI    0.0599
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_theta_min         1.50
_diffrn_reflns_theta_max         28.29
_reflns_number_total             10368
_reflns_number_gt                8908
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0006P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.008(3)
_refine_ls_number_reflns         10368
_refine_ls_number_parameters     477
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0401
_refine_ls_R_factor_gt           0.0274
_refine_ls_wR_factor_ref         0.0382
_refine_ls_wR_factor_gt          0.0365
_refine_ls_goodness_of_fit_ref   0.915
_refine_ls_restrained_S_all      0.930
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.318213(14) 0.553830(11) 0.901912(6) 0.01328(4) Uani 1 1 d . . .
Au2 Au 0.148571(14) 0.451165(11) 0.872367(6) 0.01289(4) Uani 1 1 d . . .
Fe1 Fe 0.41743(6) 0.34147(4) 0.95064(2) 0.01384(14) Uani 1 1 d . . .
Fe2 Fe 0.03035(5) 0.55028(4) 1.00082(2) 0.01456(13) Uani 1 1 d . . .
Cl1 Cl 0.48330(11) 0.64346(7) 0.93564(5) 0.0252(3) Uani 1 1 d . . .
Cl2 Cl -0.01166(11) 0.34844(7) 0.85158(5) 0.0282(3) Uani 1 1 d . . .
O1 O 0.4422(3) 0.31739(18) 0.79398(12) 0.0204(8) Uani 1 1 d . . .
N1 N 0.2735(3) 0.3946(2) 0.81721(14) 0.0143(8) Uani 1 1 d . . .
C1 C 0.4326(4) 0.4545(3) 0.91343(16) 0.0146(9) Uani 1 1 d . . .
O2 O 0.0288(3) 0.73943(17) 0.90549(13) 0.0202(7) Uani 1 1 d . . .
N2 N 0.1979(3) 0.6571(2) 0.88831(13) 0.0145(8) Uani 1 1 d . . .
C2 C 0.4593(4) 0.3865(2) 0.87748(16) 0.0118(9) Uani 1 1 d . . .
C3 C 0.5685(4) 0.3396(3) 0.89720(18) 0.0164(10) Uani 1 1 d . . .
C4 C 0.6063(4) 0.3785(3) 0.94524(17) 0.0158(10) Uani 1 1 d . . .
H4 H 0.6753 0.3612 0.9675 0.019 Uiso 1 1 calc R . .
C5 C 0.5244(4) 0.4477(3) 0.95492(16) 0.0158(9) Uani 1 1 d . . .
H5 H 0.5303 0.4839 0.9847 0.019 Uiso 1 1 calc R . .
C6 C 0.2366(4) 0.3288(3) 0.98256(17) 0.0183(11) Uani 1 1 d . . .
H6 H 0.1682 0.3678 0.9802 0.022 Uiso 1 1 calc R . .
C7 C 0.2611(4) 0.2641(3) 0.94636(19) 0.0190(11) Uani 1 1 d . . .
H7 H 0.2128 0.2520 0.9152 0.023 Uiso 1 1 calc R . .
C8 C 0.3711(4) 0.2202(3) 0.96481(18) 0.0199(11) Uani 1 1 d . . .
H8 H 0.4091 0.1732 0.9481 0.024 Uiso 1 1 calc R . .
C9 C 0.4141(4) 0.2579(3) 1.01191(18) 0.0199(11) Uani 1 1 d . . .
H9 H 0.4860 0.2410 1.0326 0.024 Uiso 1 1 calc R . .
C10 C 0.3315(4) 0.3259(2) 1.02313(18) 0.0203(11) Uani 1 1 d . . .
H10 H 0.3385 0.3627 1.0525 0.024 Uiso 1 1 calc R . .
C11 C 0.3862(4) 0.3679(3) 0.82982(18) 0.0157(10) Uani 1 1 d . . .
C12 C 0.3477(4) 0.3018(3) 0.75263(18) 0.0241(11) Uani 1 1 d . . .
H12A H 0.3171 0.2436 0.7542 0.029 Uiso 1 1 calc R . .
H12B H 0.3850 0.3122 0.7170 0.029 Uiso 1 1 calc R . .
C13 C 0.2364(4) 0.3624(3) 0.76396(18) 0.0183(11) Uani 1 1 d . . .
H13 H 0.1543 0.3303 0.7673 0.022 Uiso 1 1 calc R . .
C14 C 0.2188(4) 0.4305(3) 0.72177(17) 0.0230(11) Uani 1 1 d . . .
C15 C 0.1052(5) 0.4875(3) 0.7377(2) 0.0399(15) Uani 1 1 d . . .
H15A H 0.0278 0.4537 0.7435 0.060 Uiso 1 1 calc R . .
H15B H 0.0889 0.5276 0.7092 0.060 Uiso 1 1 calc R . .
H15C H 0.1268 0.5171 0.7706 0.060 Uiso 1 1 calc R . .
C16 C 0.3405(5) 0.4827(3) 0.71499(18) 0.0314(13) Uani 1 1 d . . .
H16A H 0.3614 0.5100 0.7488 0.047 Uiso 1 1 calc R . .
H16B H 0.3259 0.5249 0.6875 0.047 Uiso 1 1 calc R . .
H16C H 0.4122 0.4468 0.7043 0.047 Uiso 1 1 calc R . .
C17 C 0.1845(5) 0.3877(3) 0.66898(17) 0.0333(13) Uani 1 1 d . . .
H17A H 0.2580 0.3545 0.6568 0.050 Uiso 1 1 calc R . .
H17B H 0.1637 0.4298 0.6422 0.050 Uiso 1 1 calc R . .
H17C H 0.1098 0.3514 0.6743 0.050 Uiso 1 1 calc R . .
C18 C 0.0288(4) 0.5097(3) 0.92297(18) 0.0137(10) Uani 1 1 d . . .
C19 C 0.0020(4) 0.5976(3) 0.92740(17) 0.0124(10) Uani 1 1 d . . .
C20 C -0.1126(4) 0.6092(3) 0.95897(17) 0.0158(10) Uani 1 1 d . . .
C21 C -0.1543(4) 0.5290(2) 0.97452(16) 0.0166(10) Uani 1 1 d . . .
H21 H -0.2278 0.5175 0.9958 0.020 Uiso 1 1 calc R . .
C22 C -0.0685(4) 0.4682(3) 0.95312(16) 0.0149(10) Uani 1 1 d . . .
H22 H -0.0750 0.4099 0.9581 0.018 Uiso 1 1 calc R . .
C23 C 0.2059(4) 0.5255(2) 1.03552(18) 0.0178(11) Uani 1 1 d . . .
H23 H 0.2765 0.4974 1.0195 0.021 Uiso 1 1 calc R . .
C24 C 0.1829(5) 0.6118(3) 1.03430(18) 0.0210(11) Uani 1 1 d . . .
H24 H 0.2355 0.6519 1.0171 0.025 Uiso 1 1 calc R . .
C25 C 0.0685(5) 0.6286(3) 1.06291(19) 0.0249(12) Uani 1 1 d . . .
H25 H 0.0310 0.6817 1.0684 0.030 Uiso 1 1 calc R . .
C26 C 0.0200(4) 0.5519(3) 1.08193(16) 0.0243(10) Uani 1 1 d . . .
H26 H -0.0560 0.5447 1.1025 0.029 Uiso 1 1 calc R . .
C27 C 0.1042(4) 0.4880(3) 1.06512(18) 0.0221(11) Uani 1 1 d . . .
H27 H 0.0946 0.4304 1.0723 0.027 Uiso 1 1 calc R . .
C28 C 0.0812(4) 0.6630(3) 0.90640(19) 0.0166(10) Uani 1 1 d . . .
C29 C 0.1319(4) 0.7961(2) 0.89022(18) 0.0198(11) Uani 1 1 d . . .
H29A H 0.1611 0.8289 0.9213 0.024 Uiso 1 1 calc R . .
H29B H 0.1021 0.8347 0.8622 0.024 Uiso 1 1 calc R . .
C30 C 0.2406(4) 0.7414(2) 0.86955(19) 0.0192(10) Uani 1 1 d . . .
H30 H 0.3222 0.7567 0.8884 0.023 Uiso 1 1 calc R . .
C31 C 0.2640(5) 0.7453(3) 0.8089(2) 0.0254(12) Uani 1 1 d . . .
C32 C 0.3068(5) 0.8343(3) 0.7961(2) 0.0368(14) Uani 1 1 d . . .
H32A H 0.3832 0.8481 0.8173 0.055 Uiso 1 1 calc R . .
H32B H 0.2369 0.8729 0.8048 0.055 Uiso 1 1 calc R . .
H32C H 0.3275 0.8386 0.7582 0.055 Uiso 1 1 calc R . .
C33 C 0.1420(5) 0.7245(3) 0.7777(2) 0.0368(14) Uani 1 1 d . . .
H33A H 0.1602 0.7274 0.7395 0.055 Uiso 1 1 calc R . .
H33B H 0.0741 0.7644 0.7867 0.055 Uiso 1 1 calc R . .
H33C H 0.1134 0.6683 0.7869 0.055 Uiso 1 1 calc R . .
C34 C 0.3714(5) 0.6857(3) 0.79429(19) 0.0305(13) Uani 1 1 d . . .
H34A H 0.3446 0.6288 0.8024 0.046 Uiso 1 1 calc R . .
H34B H 0.4489 0.6993 0.8148 0.046 Uiso 1 1 calc R . .
H34C H 0.3903 0.6904 0.7562 0.046 Uiso 1 1 calc R . .
C35 C 0.6343(4) 0.2665(3) 0.87268(19) 0.0252(11) Uani 1 1 d . . .
H35A H 0.6955 0.2856 0.8456 0.038 Uiso 1 1 calc R . .
H35B H 0.5699 0.2303 0.8561 0.038 Uiso 1 1 calc R . .
H35C H 0.6807 0.2355 0.9003 0.038 Uiso 1 1 calc R . .
C36 C -0.1809(4) 0.6889(3) 0.97131(18) 0.0210(11) Uani 1 1 d . . .
H36A H -0.2504 0.6782 0.9968 0.031 Uiso 1 1 calc R . .
H36B H -0.2173 0.7119 0.9385 0.031 Uiso 1 1 calc R . .
H36C H -0.1197 0.7285 0.9866 0.031 Uiso 1 1 calc R . .
C1X C 0.7362(4) 0.5462(3) 0.84179(18) 0.0314(12) Uani 1 1 d . . .
H1X1 H 0.7955 0.5020 0.8542 0.038 Uiso 1 1 calc R . .
H1X2 H 0.6832 0.5643 0.8724 0.038 Uiso 1 1 calc R . .
Cl1X Cl 0.63595(15) 0.50684(9) 0.79149(6) 0.0491(4) Uani 1 1 d . . .
Cl2X Cl 0.82632(16) 0.63088(9) 0.81747(6) 0.0589(5) Uani 1 1 d . . .
C1Y C 0.1623(7) 0.1046(4) 0.8345(2) 0.072(2) Uani 1 1 d U . .
H1Y1 H 0.1224 0.1604 0.8336 0.087 Uiso 1 1 calc R . .
H1Y2 H 0.1383 0.0750 0.8015 0.087 Uiso 1 1 calc R . .
Cl1Y Cl 0.33208(18) 0.11444(11) 0.83810(6) 0.0657(5) Uani 1 1 d . . .
Cl2Y Cl 0.1047(2) 0.04905(16) 0.89038(7) 0.1017(7) Uani 1 1 d U . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.013(4) . ?
Au1 N2 2.108(3) . ?
Au1 Cl1 2.3953(11) . ?
Au1 Au2 2.5269(2) . ?
Au2 C18 2.013(4) . ?
Au2 N1 2.105(3) . ?
Au2 Cl2 2.4032(11) . ?
Fe1 C2 2.024(4) . ?
Fe1 C5 2.043(4) . ?
Fe1 C8 2.044(4) . ?
Fe1 C10 2.044(4) . ?
Fe1 C9 2.046(4) . ?
Fe1 C7 2.048(4) . ?
Fe1 C6 2.050(4) . ?
Fe1 C4 2.053(4) . ?
Fe1 C1 2.053(4) . ?
Fe1 C3 2.064(4) . ?
Fe2 C19 2.019(4) . ?
Fe2 C26 2.042(4) . ?
Fe2 C25 2.046(5) . ?
Fe2 C24 2.048(4) . ?
Fe2 C27 2.051(4) . ?
Fe2 C20 2.052(4) . ?
Fe2 C21 2.055(4) . ?
Fe2 C23 2.059(4) . ?
Fe2 C22 2.059(4) . ?
Fe2 C18 2.063(4) . ?
O1 C11 1.346(5) . ?
O1 C12 1.451(5) . ?
N1 C11 1.285(5) . ?
N1 C13 1.486(5) . ?
C1 C5 1.416(5) . ?
C1 C2 1.447(6) . ?
O2 C28 1.346(5) . ?
O2 C29 1.458(5) . ?
N2 C28 1.297(5) . ?
N2 C30 1.504(5) . ?
C2 C11 1.449(6) . ?
C2 C3 1.449(5) . ?
C3 C4 1.416(6) . ?
C3 C35 1.495(6) . ?
C4 C5 1.423(6) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.406(6) . ?
C6 C10 1.418(6) . ?
C6 H6 0.9500 . ?
C7 C8 1.421(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.404(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.418(6) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.538(6) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.537(6) . ?
C13 H13 1.0000 . ?
C14 C16 1.527(6) . ?
C14 C17 1.538(6) . ?
C14 C15 1.548(6) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C22 1.429(6) . ?
C18 C19 1.448(5) . ?
C19 C28 1.437(6) . ?
C19 C20 1.442(6) . ?
C20 C21 1.418(6) . ?
C20 C36 1.498(6) . ?
C21 C22 1.430(5) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C24 1.411(6) . ?
C23 C27 1.425(6) . ?
C23 H23 0.9500 . ?
C24 C25 1.414(6) . ?
C24 H24 0.9500 . ?
C25 C26 1.417(6) . ?
C25 H25 0.9500 . ?
C26 C27 1.415(6) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C29 C30 1.522(6) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.545(7) . ?
C30 H30 1.0000 . ?
C31 C34 1.517(6) . ?
C31 C33 1.527(7) . ?
C31 C32 1.533(6) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C1X Cl1X 1.756(5) . ?
C1X Cl2X 1.764(5) . ?
C1X H1X1 0.9900 . ?
C1X H1X2 0.9900 . ?
C1Y Cl2Y 1.769(6) . ?
C1Y Cl1Y 1.771(7) . ?
C1Y H1Y1 0.9900 . ?
C1Y H1Y2 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 178.89(15) . . ?
C1 Au1 Cl1 90.39(12) . . ?
N2 Au1 Cl1 90.28(10) . . ?
C1 Au1 Au2 86.13(12) . . ?
N2 Au1 Au2 93.24(9) . . ?
Cl1 Au1 Au2 175.34(3) . . ?
C18 Au2 N1 177.44(16) . . ?
C18 Au2 Cl2 91.90(12) . . ?
N1 Au2 Cl2 89.14(10) . . ?
C18 Au2 Au1 86.41(12) . . ?
N1 Au2 Au1 92.74(10) . . ?
Cl2 Au2 Au1 175.19(3) . . ?
C2 Fe1 C5 68.33(16) . . ?
C2 Fe1 C8 123.49(17) . . ?
C5 Fe1 C8 156.91(18) . . ?
C2 Fe1 C10 161.36(17) . . ?
C5 Fe1 C10 107.04(17) . . ?
C8 Fe1 C10 67.94(17) . . ?
C2 Fe1 C9 157.45(17) . . ?
C5 Fe1 C9 121.39(17) . . ?
C8 Fe1 C9 40.16(17) . . ?
C10 Fe1 C9 40.59(16) . . ?
C2 Fe1 C7 109.90(18) . . ?
C5 Fe1 C7 160.50(17) . . ?
C8 Fe1 C7 40.64(17) . . ?
C10 Fe1 C7 68.08(18) . . ?
C9 Fe1 C7 68.04(18) . . ?
C2 Fe1 C6 125.97(17) . . ?
C5 Fe1 C6 124.03(17) . . ?
C8 Fe1 C6 67.76(17) . . ?
C10 Fe1 C6 40.54(17) . . ?
C9 Fe1 C6 67.95(18) . . ?
C7 Fe1 C6 40.14(17) . . ?
C2 Fe1 C4 68.34(17) . . ?
C5 Fe1 C4 40.67(16) . . ?
C8 Fe1 C4 120.93(17) . . ?
C10 Fe1 C4 120.73(18) . . ?
C9 Fe1 C4 104.90(18) . . ?
C7 Fe1 C4 158.32(18) . . ?
C6 Fe1 C4 158.14(18) . . ?
C2 Fe1 C1 41.55(15) . . ?
C5 Fe1 C1 40.45(15) . . ?
C8 Fe1 C1 160.99(18) . . ?
C10 Fe1 C1 123.27(17) . . ?
C9 Fe1 C1 158.09(18) . . ?
C7 Fe1 C1 125.20(17) . . ?
C6 Fe1 C1 109.67(16) . . ?
C4 Fe1 C1 68.83(16) . . ?
C2 Fe1 C3 41.52(16) . . ?
C5 Fe1 C3 68.54(17) . . ?
C8 Fe1 C3 106.14(17) . . ?
C10 Fe1 C3 155.42(18) . . ?
C9 Fe1 C3 119.54(17) . . ?
C7 Fe1 C3 123.93(18) . . ?
C6 Fe1 C3 161.39(18) . . ?
C4 Fe1 C3 40.23(16) . . ?
C1 Fe1 C3 70.02(16) . . ?
C19 Fe2 C26 154.21(19) . . ?
C19 Fe2 C25 119.50(18) . . ?
C26 Fe2 C25 40.58(18) . . ?
C19 Fe2 C24 107.79(18) . . ?
C26 Fe2 C24 67.92(18) . . ?
C25 Fe2 C24 40.41(18) . . ?
C19 Fe2 C27 163.72(18) . . ?
C26 Fe2 C27 40.45(17) . . ?
C25 Fe2 C27 68.19(18) . . ?
C24 Fe2 C27 67.93(18) . . ?
C19 Fe2 C20 41.48(17) . . ?
C26 Fe2 C20 117.91(18) . . ?
C25 Fe2 C20 104.21(18) . . ?
C24 Fe2 C20 123.06(17) . . ?
C27 Fe2 C20 154.25(18) . . ?
C19 Fe2 C21 68.47(17) . . ?
C26 Fe2 C21 105.93(17) . . ?
C25 Fe2 C21 121.91(18) . . ?
C24 Fe2 C21 158.92(17) . . ?
C27 Fe2 C21 121.33(18) . . ?
C20 Fe2 C21 40.38(16) . . ?
C19 Fe2 C23 126.14(18) . . ?
C26 Fe2 C23 68.03(18) . . ?
C25 Fe2 C23 68.00(18) . . ?
C24 Fe2 C23 40.20(16) . . ?
C27 Fe2 C23 40.59(17) . . ?
C20 Fe2 C23 161.24(17) . . ?
C21 Fe2 C23 158.21(16) . . ?
C19 Fe2 C22 68.77(17) . . ?
C26 Fe2 C22 124.31(18) . . ?
C25 Fe2 C22 159.56(18) . . ?
C24 Fe2 C22 159.21(17) . . ?
C27 Fe2 C22 109.29(18) . . ?
C20 Fe2 C22 68.83(17) . . ?
C21 Fe2 C22 40.67(15) . . ?
C23 Fe2 C22 124.22(16) . . ?
C19 Fe2 C18 41.54(15) . . ?
C26 Fe2 C18 161.9(2) . . ?
C25 Fe2 C18 156.99(19) . . ?
C24 Fe2 C18 123.28(18) . . ?
C27 Fe2 C18 126.53(18) . . ?
C20 Fe2 C18 69.81(17) . . ?
C21 Fe2 C18 68.60(16) . . ?
C23 Fe2 C18 110.30(18) . . ?
C22 Fe2 C18 40.56(16) . . ?
C11 O1 C12 107.0(3) . . ?
C11 N1 C13 109.9(4) . . ?
C11 N1 Au2 122.8(3) . . ?
C13 N1 Au2 125.8(3) . . ?
C5 C1 C2 105.8(4) . . ?
C5 C1 Au1 124.3(3) . . ?
C2 C1 Au1 128.7(3) . . ?
C5 C1 Fe1 69.4(2) . . ?
C2 C1 Fe1 68.1(2) . . ?
Au1 C1 Fe1 136.5(2) . . ?
C28 O2 C29 106.3(3) . . ?
C28 N2 C30 108.6(3) . . ?
C28 N2 Au1 123.6(3) . . ?
C30 N2 Au1 126.1(3) . . ?
C1 C2 C11 124.9(4) . . ?
C1 C2 C3 109.3(4) . . ?
C11 C2 C3 125.7(4) . . ?
C1 C2 Fe1 70.3(2) . . ?
C11 C2 Fe1 124.4(3) . . ?
C3 C2 Fe1 70.7(2) . . ?
C4 C3 C2 106.1(4) . . ?
C4 C3 C35 125.0(4) . . ?
C2 C3 C35 128.8(4) . . ?
C4 C3 Fe1 69.5(2) . . ?
C2 C3 Fe1 67.8(2) . . ?
C35 C3 Fe1 128.8(3) . . ?
C3 C4 C5 109.1(4) . . ?
C3 C4 Fe1 70.3(2) . . ?
C5 C4 Fe1 69.3(2) . . ?
C3 C4 H4 125.5 . . ?
C5 C4 H4 125.5 . . ?
Fe1 C4 H4 126.5 . . ?
C1 C5 C4 109.6(4) . . ?
C1 C5 Fe1 70.2(2) . . ?
C4 C5 Fe1 70.0(2) . . ?
C1 C5 H5 125.2 . . ?
C4 C5 H5 125.2 . . ?
Fe1 C5 H5 126.2 . . ?
C7 C6 C10 108.4(4) . . ?
C7 C6 Fe1 69.8(2) . . ?
C10 C6 Fe1 69.5(2) . . ?
C7 C6 H6 125.8 . . ?
C10 C6 H6 125.8 . . ?
Fe1 C6 H6 126.4 . . ?
C6 C7 C8 107.7(4) . . ?
C6 C7 Fe1 70.0(2) . . ?
C8 C7 Fe1 69.5(2) . . ?
C6 C7 H7 126.2 . . ?
C8 C7 H7 126.2 . . ?
Fe1 C7 H7 125.9 . . ?
C9 C8 C7 108.3(4) . . ?
C9 C8 Fe1 70.0(2) . . ?
C7 C8 Fe1 69.8(2) . . ?
C9 C8 H8 125.8 . . ?
C7 C8 H8 125.8 . . ?
Fe1 C8 H8 125.9 . . ?
C8 C9 C10 108.0(4) . . ?
C8 C9 Fe1 69.8(2) . . ?
C10 C9 Fe1 69.6(2) . . ?
C8 C9 H9 126.0 . . ?
C10 C9 H9 126.0 . . ?
Fe1 C9 H9 126.1 . . ?
C6 C10 C9 107.6(4) . . ?
C6 C10 Fe1 70.0(3) . . ?
C9 C10 Fe1 69.8(3) . . ?
C6 C10 H10 126.2 . . ?
C9 C10 H10 126.2 . . ?
Fe1 C10 H10 125.6 . . ?
N1 C11 O1 115.5(4) . . ?
N1 C11 C2 127.6(4) . . ?
O1 C11 C2 116.9(4) . . ?
O1 C12 C13 105.3(3) . . ?
O1 C12 H12A 110.7 . . ?
C13 C12 H12A 110.7 . . ?
O1 C12 H12B 110.7 . . ?
C13 C12 H12B 110.7 . . ?
H12A C12 H12B 108.8 . . ?
N1 C13 C14 113.7(4) . . ?
N1 C13 C12 101.2(3) . . ?
C14 C13 C12 114.5(4) . . ?
N1 C13 H13 109.0 . . ?
C14 C13 H13 109.0 . . ?
C12 C13 H13 109.0 . . ?
C16 C14 C13 111.9(4) . . ?
C16 C14 C17 110.1(4) . . ?
C13 C14 C17 107.6(4) . . ?
C16 C14 C15 109.4(4) . . ?
C13 C14 C15 109.6(4) . . ?
C17 C14 C15 108.3(4) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C14 C17 H17A 109.5 . . ?
C14 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C14 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C22 C18 C19 106.3(4) . . ?
C22 C18 Au2 123.5(3) . . ?
C19 C18 Au2 128.7(3) . . ?
C22 C18 Fe2 69.6(2) . . ?
C19 C18 Fe2 67.6(3) . . ?
Au2 C18 Fe2 138.0(2) . . ?
C28 C19 C20 125.4(4) . . ?
C28 C19 C18 125.4(4) . . ?
C20 C19 C18 109.1(4) . . ?
C28 C19 Fe2 122.0(3) . . ?
C20 C19 Fe2 70.5(2) . . ?
C18 C19 Fe2 70.9(3) . . ?
C21 C20 C19 106.6(4) . . ?
C21 C20 C36 125.4(4) . . ?
C19 C20 C36 128.0(4) . . ?
C21 C20 Fe2 69.9(3) . . ?
C19 C20 Fe2 68.0(2) . . ?
C36 C20 Fe2 129.2(3) . . ?
C20 C21 C22 109.4(4) . . ?
C20 C21 Fe2 69.7(2) . . ?
C22 C21 Fe2 69.8(2) . . ?
C20 C21 H21 125.3 . . ?
C22 C21 H21 125.3 . . ?
Fe2 C21 H21 126.8 . . ?
C21 C22 C18 108.6(4) . . ?
C21 C22 Fe2 69.5(2) . . ?
C18 C22 Fe2 69.9(2) . . ?
C21 C22 H22 125.7 . . ?
C18 C22 H22 125.7 . . ?
Fe2 C22 H22 126.4 . . ?
C24 C23 C27 107.7(4) . . ?
C24 C23 Fe2 69.5(3) . . ?
C27 C23 Fe2 69.4(2) . . ?
C24 C23 H23 126.2 . . ?
C27 C23 H23 126.2 . . ?
Fe2 C23 H23 126.5 . . ?
C23 C24 C25 108.7(4) . . ?
C23 C24 Fe2 70.3(3) . . ?
C25 C24 Fe2 69.7(3) . . ?
C23 C24 H24 125.7 . . ?
C25 C24 H24 125.7 . . ?
Fe2 C24 H24 125.9 . . ?
C24 C25 C26 107.6(4) . . ?
C24 C25 Fe2 69.9(2) . . ?
C26 C25 Fe2 69.6(2) . . ?
C24 C25 H25 126.2 . . ?
C26 C25 H25 126.2 . . ?
Fe2 C25 H25 125.9 . . ?
C27 C26 C25 108.4(4) . . ?
C27 C26 Fe2 70.1(2) . . ?
C25 C26 Fe2 69.9(3) . . ?
C27 C26 H26 125.8 . . ?
C25 C26 H26 125.8 . . ?
Fe2 C26 H26 125.8 . . ?
C26 C27 C23 107.7(4) . . ?
C26 C27 Fe2 69.4(2) . . ?
C23 C27 Fe2 70.0(3) . . ?
C26 C27 H27 126.1 . . ?
C23 C27 H27 126.1 . . ?
Fe2 C27 H27 126.0 . . ?
N2 C28 O2 116.0(4) . . ?
N2 C28 C19 127.5(4) . . ?
O2 C28 C19 116.5(4) . . ?
O2 C29 C30 105.7(3) . . ?
O2 C29 H29A 110.6 . . ?
C30 C29 H29A 110.6 . . ?
O2 C29 H29B 110.6 . . ?
C30 C29 H29B 110.6 . . ?
H29A C29 H29B 108.7 . . ?
N2 C30 C29 101.4(3) . . ?
N2 C30 C31 113.1(3) . . ?
C29 C30 C31 115.4(4) . . ?
N2 C30 H30 108.9 . . ?
C29 C30 H30 108.9 . . ?
C31 C30 H30 108.9 . . ?
C34 C31 C33 110.2(4) . . ?
C34 C31 C32 109.2(4) . . ?
C33 C31 C32 109.8(4) . . ?
C34 C31 C30 109.1(4) . . ?
C33 C31 C30 111.5(4) . . ?
C32 C31 C30 106.9(4) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C3 C35 H35A 109.5 . . ?
C3 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C3 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C20 C36 H36A 109.5 . . ?
C20 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C20 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
Cl1X C1X Cl2X 110.1(3) . . ?
Cl1X C1X H1X1 109.6 . . ?
Cl2X C1X H1X1 109.6 . . ?
Cl1X C1X H1X2 109.6 . . ?
Cl2X C1X H1X2 109.6 . . ?
H1X1 C1X H1X2 108.2 . . ?
Cl2Y C1Y Cl1Y 109.9(4) . . ?
Cl2Y C1Y H1Y1 109.7 . . ?
Cl1Y C1Y H1Y1 109.7 . . ?
Cl2Y C1Y H1Y2 109.7 . . ?
Cl1Y C1Y H1Y2 109.7 . . ?
H1Y1 C1Y H1Y2 108.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C18 130.09(17) . . . . ?
N2 Au1 Au2 C18 -50.83(16) . . . . ?
Cl1 Au1 Au2 C18 88.2(4) . . . . ?
C1 Au1 Au2 N1 -52.33(15) . . . . ?
N2 Au1 Au2 N1 126.75(13) . . . . ?
Cl1 Au1 Au2 N1 -94.2(4) . . . . ?
C1 Au1 Au2 Cl2 60.5(4) . . . . ?
N2 Au1 Au2 Cl2 -120.4(4) . . . . ?
Cl1 Au1 Au2 Cl2 18.7(5) . . . . ?
C18 Au2 N1 C11 123(3) . . . . ?
Cl2 Au2 N1 C11 -123.3(3) . . . . ?
Au1 Au2 N1 C11 52.3(3) . . . . ?
C18 Au2 N1 C13 -72(4) . . . . ?
Cl2 Au2 N1 C13 41.6(3) . . . . ?
Au1 Au2 N1 C13 -142.8(3) . . . . ?
N2 Au1 C1 C5 160(8) . . . . ?
Cl1 Au1 C1 C5 32.3(3) . . . . ?
Au2 Au1 C1 C5 -144.6(3) . . . . ?
N2 Au1 C1 C2 -6(8) . . . . ?
Cl1 Au1 C1 C2 -133.4(3) . . . . ?
Au2 Au1 C1 C2 49.7(3) . . . . ?
N2 Au1 C1 Fe1 -105(8) . . . . ?
Cl1 Au1 C1 Fe1 128.0(3) . . . . ?
Au2 Au1 C1 Fe1 -48.9(3) . . . . ?
C2 Fe1 C1 C5 -117.7(3) . . . . ?
C8 Fe1 C1 C5 -161.5(5) . . . . ?
C10 Fe1 C1 C5 76.7(3) . . . . ?
C9 Fe1 C1 C5 40.1(5) . . . . ?
C7 Fe1 C1 C5 161.9(3) . . . . ?
C6 Fe1 C1 C5 119.8(3) . . . . ?
C4 Fe1 C1 C5 -36.9(2) . . . . ?
C3 Fe1 C1 C5 -80.0(3) . . . . ?
C5 Fe1 C1 C2 117.7(3) . . . . ?
C8 Fe1 C1 C2 -43.8(6) . . . . ?
C10 Fe1 C1 C2 -165.5(2) . . . . ?
C9 Fe1 C1 C2 157.9(4) . . . . ?
C7 Fe1 C1 C2 -80.3(3) . . . . ?
C6 Fe1 C1 C2 -122.5(2) . . . . ?
C4 Fe1 C1 C2 80.8(2) . . . . ?
C3 Fe1 C1 C2 37.7(2) . . . . ?
C2 Fe1 C1 Au1 123.7(4) . . . . ?
C5 Fe1 C1 Au1 -118.6(4) . . . . ?
C8 Fe1 C1 Au1 79.9(6) . . . . ?
C10 Fe1 C1 Au1 -41.8(4) . . . . ?
C9 Fe1 C1 Au1 -78.4(5) . . . . ?
C7 Fe1 C1 Au1 43.4(4) . . . . ?
C6 Fe1 C1 Au1 1.2(4) . . . . ?
C4 Fe1 C1 Au1 -155.5(4) . . . . ?
C3 Fe1 C1 Au1 161.4(4) . . . . ?
C1 Au1 N2 C28 106(8) . . . . ?
Cl1 Au1 N2 C28 -126.6(3) . . . . ?
Au2 Au1 N2 C28 50.3(4) . . . . ?
C1 Au1 N2 C30 -90(8) . . . . ?
Cl1 Au1 N2 C30 36.8(3) . . . . ?
Au2 Au1 N2 C30 -146.2(3) . . . . ?
C5 C1 C2 C11 178.3(4) . . . . ?
Au1 C1 C2 C11 -14.0(6) . . . . ?
Fe1 C1 C2 C11 118.8(4) . . . . ?
C5 C1 C2 C3 -0.7(4) . . . . ?
Au1 C1 C2 C3 167.0(3) . . . . ?
Fe1 C1 C2 C3 -60.2(3) . . . . ?
C5 C1 C2 Fe1 59.5(3) . . . . ?
Au1 C1 C2 Fe1 -132.8(3) . . . . ?
C5 Fe1 C2 C1 -38.2(2) . . . . ?
C8 Fe1 C2 C1 164.3(2) . . . . ?
C10 Fe1 C2 C1 40.8(6) . . . . ?
C9 Fe1 C2 C1 -158.5(4) . . . . ?
C7 Fe1 C2 C1 121.0(2) . . . . ?
C6 Fe1 C2 C1 78.9(3) . . . . ?
C4 Fe1 C2 C1 -82.1(2) . . . . ?
C3 Fe1 C2 C1 -119.8(3) . . . . ?
C5 Fe1 C2 C11 -157.7(4) . . . . ?
C8 Fe1 C2 C11 44.8(4) . . . . ?
C10 Fe1 C2 C11 -78.7(7) . . . . ?
C9 Fe1 C2 C11 82.0(6) . . . . ?
C7 Fe1 C2 C11 1.6(4) . . . . ?
C6 Fe1 C2 C11 -40.6(4) . . . . ?
C4 Fe1 C2 C11 158.4(4) . . . . ?
C1 Fe1 C2 C11 -119.5(4) . . . . ?
C3 Fe1 C2 C11 120.7(5) . . . . ?
C5 Fe1 C2 C3 81.7(3) . . . . ?
C8 Fe1 C2 C3 -75.9(3) . . . . ?
C10 Fe1 C2 C3 160.6(5) . . . . ?
C9 Fe1 C2 C3 -38.7(5) . . . . ?
C7 Fe1 C2 C3 -119.1(3) . . . . ?
C6 Fe1 C2 C3 -161.2(2) . . . . ?
C4 Fe1 C2 C3 37.7(2) . . . . ?
C1 Fe1 C2 C3 119.8(3) . . . . ?
C1 C2 C3 C4 0.8(5) . . . . ?
C11 C2 C3 C4 -178.2(4) . . . . ?
Fe1 C2 C3 C4 -59.2(3) . . . . ?
C1 C2 C3 C35 -177.4(4) . . . . ?
C11 C2 C3 C35 3.6(7) . . . . ?
Fe1 C2 C3 C35 122.7(4) . . . . ?
C1 C2 C3 Fe1 59.9(3) . . . . ?
C11 C2 C3 Fe1 -119.1(4) . . . . ?
C2 Fe1 C3 C4 118.2(4) . . . . ?
C5 Fe1 C3 C4 37.1(2) . . . . ?
C8 Fe1 C3 C4 -119.1(3) . . . . ?
C10 Fe1 C3 C4 -47.0(5) . . . . ?
C9 Fe1 C3 C4 -77.7(3) . . . . ?
C7 Fe1 C3 C4 -159.9(3) . . . . ?
C6 Fe1 C3 C4 172.9(5) . . . . ?
C1 Fe1 C3 C4 80.5(3) . . . . ?
C5 Fe1 C3 C2 -81.1(2) . . . . ?
C8 Fe1 C3 C2 122.7(3) . . . . ?
C10 Fe1 C3 C2 -165.2(4) . . . . ?
C9 Fe1 C3 C2 164.0(2) . . . . ?
C7 Fe1 C3 C2 81.9(3) . . . . ?
C6 Fe1 C3 C2 54.7(6) . . . . ?
C4 Fe1 C3 C2 -118.2(4) . . . . ?
C1 Fe1 C3 C2 -37.8(2) . . . . ?
C2 Fe1 C3 C35 -122.7(5) . . . . ?
C5 Fe1 C3 C35 156.1(4) . . . . ?
C8 Fe1 C3 C35 -0.1(4) . . . . ?
C10 Fe1 C3 C35 72.0(6) . . . . ?
C9 Fe1 C3 C35 41.3(5) . . . . ?
C7 Fe1 C3 C35 -40.9(5) . . . . ?
C6 Fe1 C3 C35 -68.1(7) . . . . ?
C4 Fe1 C3 C35 119.0(5) . . . . ?
C1 Fe1 C3 C35 -160.5(4) . . . . ?
C2 C3 C4 C5 -0.5(5) . . . . ?
C35 C3 C4 C5 177.7(4) . . . . ?
Fe1 C3 C4 C5 -58.6(3) . . . . ?
C2 C3 C4 Fe1 58.1(3) . . . . ?
C35 C3 C4 Fe1 -123.7(4) . . . . ?
C2 Fe1 C4 C3 -38.9(2) . . . . ?
C5 Fe1 C4 C3 -120.4(4) . . . . ?
C8 Fe1 C4 C3 78.1(3) . . . . ?
C10 Fe1 C4 C3 159.3(2) . . . . ?
C9 Fe1 C4 C3 118.4(3) . . . . ?
C7 Fe1 C4 C3 50.6(6) . . . . ?
C6 Fe1 C4 C3 -173.9(4) . . . . ?
C1 Fe1 C4 C3 -83.7(3) . . . . ?
C2 Fe1 C4 C5 81.5(3) . . . . ?
C8 Fe1 C4 C5 -161.5(2) . . . . ?
C10 Fe1 C4 C5 -80.3(3) . . . . ?
C9 Fe1 C4 C5 -121.2(3) . . . . ?
C7 Fe1 C4 C5 171.1(4) . . . . ?
C6 Fe1 C4 C5 -53.5(5) . . . . ?
C1 Fe1 C4 C5 36.7(2) . . . . ?
C3 Fe1 C4 C5 120.4(4) . . . . ?
C2 C1 C5 C4 0.4(4) . . . . ?
Au1 C1 C5 C4 -168.0(3) . . . . ?
Fe1 C1 C5 C4 59.1(3) . . . . ?
C2 C1 C5 Fe1 -58.6(3) . . . . ?
Au1 C1 C5 Fe1 133.0(3) . . . . ?
C3 C4 C5 C1 0.1(5) . . . . ?
Fe1 C4 C5 C1 -59.1(3) . . . . ?
C3 C4 C5 Fe1 59.2(3) . . . . ?
C2 Fe1 C5 C1 39.2(2) . . . . ?
C8 Fe1 C5 C1 164.8(4) . . . . ?
C10 Fe1 C5 C1 -121.7(3) . . . . ?
C9 Fe1 C5 C1 -163.6(2) . . . . ?
C7 Fe1 C5 C1 -49.4(6) . . . . ?
C6 Fe1 C5 C1 -80.4(3) . . . . ?
C4 Fe1 C5 C1 120.7(4) . . . . ?
C3 Fe1 C5 C1 84.0(3) . . . . ?
C2 Fe1 C5 C4 -81.6(3) . . . . ?
C8 Fe1 C5 C4 44.0(5) . . . . ?
C10 Fe1 C5 C4 117.6(3) . . . . ?
C9 Fe1 C5 C4 75.6(3) . . . . ?
C7 Fe1 C5 C4 -170.1(5) . . . . ?
C6 Fe1 C5 C4 158.8(3) . . . . ?
C1 Fe1 C5 C4 -120.7(4) . . . . ?
C3 Fe1 C5 C4 -36.7(2) . . . . ?
C2 Fe1 C6 C7 78.0(3) . . . . ?
C5 Fe1 C6 C7 164.5(3) . . . . ?
C8 Fe1 C6 C7 -38.1(3) . . . . ?
C10 Fe1 C6 C7 -119.7(4) . . . . ?
C9 Fe1 C6 C7 -81.6(3) . . . . ?
C4 Fe1 C6 C7 -156.3(4) . . . . ?
C1 Fe1 C6 C7 121.7(3) . . . . ?
C3 Fe1 C6 C7 36.0(6) . . . . ?
C2 Fe1 C6 C10 -162.3(2) . . . . ?
C5 Fe1 C6 C10 -75.8(3) . . . . ?
C8 Fe1 C6 C10 81.6(3) . . . . ?
C9 Fe1 C6 C10 38.1(2) . . . . ?
C7 Fe1 C6 C10 119.7(4) . . . . ?
C4 Fe1 C6 C10 -36.6(6) . . . . ?
C1 Fe1 C6 C10 -118.6(2) . . . . ?
C3 Fe1 C6 C10 155.8(5) . . . . ?
C10 C6 C7 C8 0.6(5) . . . . ?
Fe1 C6 C7 C8 59.6(3) . . . . ?
C10 C6 C7 Fe1 -59.0(3) . . . . ?
C2 Fe1 C7 C6 -122.7(3) . . . . ?
C5 Fe1 C7 C6 -41.5(6) . . . . ?
C8 Fe1 C7 C6 118.7(4) . . . . ?
C10 Fe1 C7 C6 37.5(2) . . . . ?
C9 Fe1 C7 C6 81.4(3) . . . . ?
C4 Fe1 C7 C6 156.1(4) . . . . ?
C1 Fe1 C7 C6 -78.6(3) . . . . ?
C3 Fe1 C7 C6 -166.9(2) . . . . ?
C2 Fe1 C7 C8 118.6(3) . . . . ?
C5 Fe1 C7 C8 -160.2(5) . . . . ?
C10 Fe1 C7 C8 -81.2(3) . . . . ?
C9 Fe1 C7 C8 -37.3(3) . . . . ?
C6 Fe1 C7 C8 -118.7(4) . . . . ?
C4 Fe1 C7 C8 37.4(6) . . . . ?
C1 Fe1 C7 C8 162.7(3) . . . . ?
C3 Fe1 C7 C8 74.4(3) . . . . ?
C6 C7 C8 C9 -0.3(5) . . . . ?
Fe1 C7 C8 C9 59.6(3) . . . . ?
C6 C7 C8 Fe1 -59.9(3) . . . . ?
C2 Fe1 C8 C9 158.9(3) . . . . ?
C5 Fe1 C8 C9 43.9(6) . . . . ?
C10 Fe1 C8 C9 -37.8(3) . . . . ?
C7 Fe1 C8 C9 -119.4(4) . . . . ?
C6 Fe1 C8 C9 -81.7(3) . . . . ?
C4 Fe1 C8 C9 75.8(3) . . . . ?
C1 Fe1 C8 C9 -167.7(5) . . . . ?
C3 Fe1 C8 C9 116.9(3) . . . . ?
C2 Fe1 C8 C7 -81.7(3) . . . . ?
C5 Fe1 C8 C7 163.3(4) . . . . ?
C10 Fe1 C8 C7 81.6(3) . . . . ?
C9 Fe1 C8 C7 119.4(4) . . . . ?
C6 Fe1 C8 C7 37.7(3) . . . . ?
C4 Fe1 C8 C7 -164.8(3) . . . . ?
C1 Fe1 C8 C7 -48.3(6) . . . . ?
C3 Fe1 C8 C7 -123.7(3) . . . . ?
C7 C8 C9 C10 -0.2(5) . . . . ?
Fe1 C8 C9 C10 59.4(3) . . . . ?
C7 C8 C9 Fe1 -59.5(3) . . . . ?
C2 Fe1 C9 C8 -51.4(6) . . . . ?
C5 Fe1 C9 C8 -161.4(3) . . . . ?
C10 Fe1 C9 C8 119.2(4) . . . . ?
C7 Fe1 C9 C8 37.7(3) . . . . ?
C6 Fe1 C9 C8 81.2(3) . . . . ?
C4 Fe1 C9 C8 -120.6(3) . . . . ?
C1 Fe1 C9 C8 169.2(4) . . . . ?
C3 Fe1 C9 C8 -79.9(3) . . . . ?
C2 Fe1 C9 C10 -170.7(4) . . . . ?
C5 Fe1 C9 C10 79.4(3) . . . . ?
C8 Fe1 C9 C10 -119.2(4) . . . . ?
C7 Fe1 C9 C10 -81.5(3) . . . . ?
C6 Fe1 C9 C10 -38.0(3) . . . . ?
C4 Fe1 C9 C10 120.1(3) . . . . ?
C1 Fe1 C9 C10 50.0(6) . . . . ?
C3 Fe1 C9 C10 160.9(3) . . . . ?
C7 C6 C10 C9 -0.7(5) . . . . ?
Fe1 C6 C10 C9 -59.9(3) . . . . ?
C7 C6 C10 Fe1 59.2(3) . . . . ?
C8 C9 C10 C6 0.5(5) . . . . ?
Fe1 C9 C10 C6 60.0(3) . . . . ?
C8 C9 C10 Fe1 -59.5(3) . . . . ?
C2 Fe1 C10 C6 50.3(6) . . . . ?
C5 Fe1 C10 C6 122.8(3) . . . . ?
C8 Fe1 C10 C6 -81.1(3) . . . . ?
C9 Fe1 C10 C6 -118.5(4) . . . . ?
C7 Fe1 C10 C6 -37.1(2) . . . . ?
C4 Fe1 C10 C6 165.0(2) . . . . ?
C1 Fe1 C10 C6 81.5(3) . . . . ?
C3 Fe1 C10 C6 -161.6(4) . . . . ?
C2 Fe1 C10 C9 168.8(5) . . . . ?
C5 Fe1 C10 C9 -118.7(3) . . . . ?
C8 Fe1 C10 C9 37.4(3) . . . . ?
C7 Fe1 C10 C9 81.4(3) . . . . ?
C6 Fe1 C10 C9 118.5(4) . . . . ?
C4 Fe1 C10 C9 -76.5(3) . . . . ?
C1 Fe1 C10 C9 -160.0(3) . . . . ?
C3 Fe1 C10 C9 -43.1(5) . . . . ?
C13 N1 C11 O1 -1.3(5) . . . . ?
Au2 N1 C11 O1 165.7(3) . . . . ?
C13 N1 C11 C2 178.1(4) . . . . ?
Au2 N1 C11 C2 -14.9(6) . . . . ?
C12 O1 C11 N1 -5.7(5) . . . . ?
C12 O1 C11 C2 174.8(4) . . . . ?
C1 C2 C11 N1 -16.3(7) . . . . ?
C3 C2 C11 N1 162.5(4) . . . . ?
Fe1 C2 C11 N1 72.5(6) . . . . ?
C1 C2 C11 O1 163.1(4) . . . . ?
C3 C2 C11 O1 -18.1(6) . . . . ?
Fe1 C2 C11 O1 -108.0(4) . . . . ?
C11 O1 C12 C13 9.7(5) . . . . ?
C11 N1 C13 C14 -116.2(4) . . . . ?
Au2 N1 C13 C14 77.3(4) . . . . ?
C11 N1 C13 C12 7.1(5) . . . . ?
Au2 N1 C13 C12 -159.4(3) . . . . ?
O1 C12 C13 N1 -9.9(4) . . . . ?
O1 C12 C13 C14 112.9(4) . . . . ?
N1 C13 C14 C16 57.5(5) . . . . ?
C12 C13 C14 C16 -58.2(5) . . . . ?
N1 C13 C14 C17 178.5(4) . . . . ?
C12 C13 C14 C17 62.8(5) . . . . ?
N1 C13 C14 C15 -64.0(5) . . . . ?
C12 C13 C14 C15 -179.7(4) . . . . ?
N1 Au2 C18 C22 145(3) . . . . ?
Cl2 Au2 C18 C22 31.0(4) . . . . ?
Au1 Au2 C18 C22 -144.5(4) . . . . ?
N1 Au2 C18 C19 -20(4) . . . . ?
Cl2 Au2 C18 C19 -133.5(4) . . . . ?
Au1 Au2 C18 C19 51.0(4) . . . . ?
N1 Au2 C18 Fe2 -119(3) . . . . ?
Cl2 Au2 C18 Fe2 127.3(3) . . . . ?
Au1 Au2 C18 Fe2 -48.2(3) . . . . ?
C19 Fe2 C18 C22 -118.6(4) . . . . ?
C26 Fe2 C18 C22 38.1(7) . . . . ?
C25 Fe2 C18 C22 -159.3(4) . . . . ?
C24 Fe2 C18 C22 162.3(2) . . . . ?
C27 Fe2 C18 C22 76.5(3) . . . . ?
C20 Fe2 C18 C22 -80.7(3) . . . . ?
C21 Fe2 C18 C22 -37.4(2) . . . . ?
C23 Fe2 C18 C22 119.3(2) . . . . ?
C26 Fe2 C18 C19 156.7(5) . . . . ?
C25 Fe2 C18 C19 -40.7(6) . . . . ?
C24 Fe2 C18 C19 -79.1(3) . . . . ?
C27 Fe2 C18 C19 -164.9(3) . . . . ?
C20 Fe2 C18 C19 37.9(3) . . . . ?
C21 Fe2 C18 C19 81.3(3) . . . . ?
C23 Fe2 C18 C19 -122.1(3) . . . . ?
C22 Fe2 C18 C19 118.6(4) . . . . ?
C19 Fe2 C18 Au2 123.6(5) . . . . ?
C26 Fe2 C18 Au2 -79.7(7) . . . . ?
C25 Fe2 C18 Au2 82.9(6) . . . . ?
C24 Fe2 C18 Au2 44.6(4) . . . . ?
C27 Fe2 C18 Au2 -41.3(4) . . . . ?
C20 Fe2 C18 Au2 161.5(4) . . . . ?
C21 Fe2 C18 Au2 -155.1(4) . . . . ?
C23 Fe2 C18 Au2 1.6(4) . . . . ?
C22 Fe2 C18 Au2 -117.8(4) . . . . ?
C22 C18 C19 C28 175.2(4) . . . . ?
Au2 C18 C19 C28 -18.2(7) . . . . ?
Fe2 C18 C19 C28 116.2(5) . . . . ?
C22 C18 C19 C20 -1.4(5) . . . . ?
Au2 C18 C19 C20 165.2(3) . . . . ?
Fe2 C18 C19 C20 -60.4(3) . . . . ?
C22 C18 C19 Fe2 59.0(3) . . . . ?
Au2 C18 C19 Fe2 -134.4(4) . . . . ?
C26 Fe2 C19 C28 76.0(6) . . . . ?
C25 Fe2 C19 C28 42.6(4) . . . . ?
C24 Fe2 C19 C28 0.1(4) . . . . ?
C27 Fe2 C19 C28 -72.0(8) . . . . ?
C20 Fe2 C19 C28 120.2(5) . . . . ?
C21 Fe2 C19 C28 158.0(4) . . . . ?
C23 Fe2 C19 C28 -40.6(4) . . . . ?
C22 Fe2 C19 C28 -158.2(4) . . . . ?
C18 Fe2 C19 C28 -120.4(5) . . . . ?
C26 Fe2 C19 C20 -44.2(5) . . . . ?
C25 Fe2 C19 C20 -77.6(3) . . . . ?
C24 Fe2 C19 C20 -120.1(3) . . . . ?
C27 Fe2 C19 C20 167.8(6) . . . . ?
C21 Fe2 C19 C20 37.8(2) . . . . ?
C23 Fe2 C19 C20 -160.8(2) . . . . ?
C22 Fe2 C19 C20 81.6(3) . . . . ?
C18 Fe2 C19 C20 119.4(4) . . . . ?
C26 Fe2 C19 C18 -163.6(4) . . . . ?
C25 Fe2 C19 C18 163.0(3) . . . . ?
C24 Fe2 C19 C18 120.5(3) . . . . ?
C27 Fe2 C19 C18 48.4(8) . . . . ?
C20 Fe2 C19 C18 -119.4(4) . . . . ?
C21 Fe2 C19 C18 -81.6(3) . . . . ?
C23 Fe2 C19 C18 79.8(3) . . . . ?
C22 Fe2 C19 C18 -37.8(2) . . . . ?
C28 C19 C20 C21 -175.6(4) . . . . ?
C18 C19 C20 C21 1.0(5) . . . . ?
Fe2 C19 C20 C21 -59.6(3) . . . . ?
C28 C19 C20 C36 7.4(7) . . . . ?
C18 C19 C20 C36 -176.0(4) . . . . ?
Fe2 C19 C20 C36 123.4(5) . . . . ?
C28 C19 C20 Fe2 -115.9(4) . . . . ?
C18 C19 C20 Fe2 60.6(3) . . . . ?
C19 Fe2 C20 C21 118.3(3) . . . . ?
C26 Fe2 C20 C21 -81.7(3) . . . . ?
C25 Fe2 C20 C21 -122.9(3) . . . . ?
C24 Fe2 C20 C21 -162.4(2) . . . . ?
C27 Fe2 C20 C21 -53.9(5) . . . . ?
C23 Fe2 C20 C21 174.2(5) . . . . ?
C22 Fe2 C20 C21 36.9(2) . . . . ?
C18 Fe2 C20 C21 80.3(3) . . . . ?
C26 Fe2 C20 C19 159.9(3) . . . . ?
C25 Fe2 C20 C19 118.7(3) . . . . ?
C24 Fe2 C20 C19 79.3(3) . . . . ?
C27 Fe2 C20 C19 -172.2(4) . . . . ?
C21 Fe2 C20 C19 -118.3(3) . . . . ?
C23 Fe2 C20 C19 55.8(6) . . . . ?
C22 Fe2 C20 C19 -81.5(3) . . . . ?
C18 Fe2 C20 C19 -38.0(2) . . . . ?
C19 Fe2 C20 C36 -121.8(5) . . . . ?
C26 Fe2 C20 C36 38.1(5) . . . . ?
C25 Fe2 C20 C36 -3.1(4) . . . . ?
C24 Fe2 C20 C36 -42.5(5) . . . . ?
C27 Fe2 C20 C36 66.0(6) . . . . ?
C21 Fe2 C20 C36 119.9(5) . . . . ?
C23 Fe2 C20 C36 -66.0(7) . . . . ?
C22 Fe2 C20 C36 156.7(4) . . . . ?
C18 Fe2 C20 C36 -159.8(4) . . . . ?
C19 C20 C21 C22 -0.2(5) . . . . ?
C36 C20 C21 C22 176.9(4) . . . . ?
Fe2 C20 C21 C22 -58.6(3) . . . . ?
C19 C20 C21 Fe2 58.4(3) . . . . ?
C36 C20 C21 Fe2 -124.5(5) . . . . ?
C19 Fe2 C21 C20 -38.8(2) . . . . ?
C26 Fe2 C21 C20 114.6(3) . . . . ?
C25 Fe2 C21 C20 73.4(3) . . . . ?
C24 Fe2 C21 C20 44.8(6) . . . . ?
C27 Fe2 C21 C20 155.7(3) . . . . ?
C23 Fe2 C21 C20 -175.0(4) . . . . ?
C22 Fe2 C21 C20 -120.9(3) . . . . ?
C18 Fe2 C21 C20 -83.6(3) . . . . ?
C19 Fe2 C21 C22 82.1(3) . . . . ?
C26 Fe2 C21 C22 -124.6(3) . . . . ?
C25 Fe2 C21 C22 -165.7(3) . . . . ?
C24 Fe2 C21 C22 165.7(4) . . . . ?
C27 Fe2 C21 C22 -83.4(3) . . . . ?
C20 Fe2 C21 C22 120.9(3) . . . . ?
C23 Fe2 C21 C22 -54.1(6) . . . . ?
C18 Fe2 C21 C22 37.3(2) . . . . ?
C20 C21 C22 C18 -0.6(5) . . . . ?
Fe2 C21 C22 C18 -59.2(3) . . . . ?
C20 C21 C22 Fe2 58.6(3) . . . . ?
C19 C18 C22 C21 1.2(5) . . . . ?
Au2 C18 C22 C21 -166.3(3) . . . . ?
Fe2 C18 C22 C21 58.9(3) . . . . ?
C19 C18 C22 Fe2 -57.8(3) . . . . ?
Au2 C18 C22 Fe2 134.8(3) . . . . ?
C19 Fe2 C22 C21 -81.3(3) . . . . ?
C26 Fe2 C22 C21 73.5(3) . . . . ?
C25 Fe2 C22 C21 36.8(6) . . . . ?
C24 Fe2 C22 C21 -165.5(4) . . . . ?
C27 Fe2 C22 C21 116.0(3) . . . . ?
C20 Fe2 C22 C21 -36.6(2) . . . . ?
C23 Fe2 C22 C21 158.7(2) . . . . ?
C18 Fe2 C22 C21 -119.9(4) . . . . ?
C19 Fe2 C22 C18 38.7(3) . . . . ?
C26 Fe2 C22 C18 -166.6(3) . . . . ?
C25 Fe2 C22 C18 156.7(5) . . . . ?
C24 Fe2 C22 C18 -45.6(6) . . . . ?
C27 Fe2 C22 C18 -124.1(3) . . . . ?
C20 Fe2 C22 C18 83.3(3) . . . . ?
C21 Fe2 C22 C18 119.9(4) . . . . ?
C23 Fe2 C22 C18 -81.4(3) . . . . ?
C19 Fe2 C23 C24 73.8(3) . . . . ?
C26 Fe2 C23 C24 -81.3(3) . . . . ?
C25 Fe2 C23 C24 -37.4(3) . . . . ?
C27 Fe2 C23 C24 -119.1(4) . . . . ?
C20 Fe2 C23 C24 31.1(7) . . . . ?
C21 Fe2 C23 C24 -159.1(4) . . . . ?
C22 Fe2 C23 C24 161.2(3) . . . . ?
C18 Fe2 C23 C24 118.0(3) . . . . ?
C19 Fe2 C23 C27 -167.0(3) . . . . ?
C26 Fe2 C23 C27 37.8(3) . . . . ?
C25 Fe2 C23 C27 81.7(3) . . . . ?
C24 Fe2 C23 C27 119.1(4) . . . . ?
C20 Fe2 C23 C27 150.2(5) . . . . ?
C21 Fe2 C23 C27 -40.0(6) . . . . ?
C22 Fe2 C23 C27 -79.6(3) . . . . ?
C18 Fe2 C23 C27 -122.9(3) . . . . ?
C27 C23 C24 C25 0.2(5) . . . . ?
Fe2 C23 C24 C25 59.4(3) . . . . ?
C27 C23 C24 Fe2 -59.1(3) . . . . ?
C19 Fe2 C24 C23 -125.5(3) . . . . ?
C26 Fe2 C24 C23 81.6(3) . . . . ?
C25 Fe2 C24 C23 119.7(4) . . . . ?
C27 Fe2 C24 C23 37.8(3) . . . . ?
C20 Fe2 C24 C23 -168.6(3) . . . . ?
C21 Fe2 C24 C23 158.4(4) . . . . ?
C22 Fe2 C24 C23 -48.5(6) . . . . ?
C18 Fe2 C24 C23 -82.3(3) . . . . ?
C19 Fe2 C24 C25 114.9(3) . . . . ?
C26 Fe2 C24 C25 -38.0(3) . . . . ?
C27 Fe2 C24 C25 -81.8(3) . . . . ?
C20 Fe2 C24 C25 71.8(3) . . . . ?
C21 Fe2 C24 C25 38.7(6) . . . . ?
C23 Fe2 C24 C25 -119.7(4) . . . . ?
C22 Fe2 C24 C25 -168.2(4) . . . . ?
C18 Fe2 C24 C25 158.0(3) . . . . ?
C23 C24 C25 C26 -0.1(5) . . . . ?
Fe2 C24 C25 C26 59.6(3) . . . . ?
C23 C24 C25 Fe2 -59.7(3) . . . . ?
C19 Fe2 C25 C24 -82.9(3) . . . . ?
C26 Fe2 C25 C24 118.7(4) . . . . ?
C27 Fe2 C25 C24 81.1(3) . . . . ?
C20 Fe2 C25 C24 -124.8(3) . . . . ?
C21 Fe2 C25 C24 -164.6(2) . . . . ?
C23 Fe2 C25 C24 37.2(3) . . . . ?
C22 Fe2 C25 C24 168.0(4) . . . . ?
C18 Fe2 C25 C24 -53.1(6) . . . . ?
C19 Fe2 C25 C26 158.4(3) . . . . ?
C24 Fe2 C25 C26 -118.7(4) . . . . ?
C27 Fe2 C25 C26 -37.5(3) . . . . ?
C20 Fe2 C25 C26 116.5(3) . . . . ?
C21 Fe2 C25 C26 76.7(3) . . . . ?
C23 Fe2 C25 C26 -81.5(3) . . . . ?
C22 Fe2 C25 C26 49.3(6) . . . . ?
C18 Fe2 C25 C26 -171.8(4) . . . . ?
C24 C25 C26 C27 0.0(5) . . . . ?
Fe2 C25 C26 C27 59.8(3) . . . . ?
C24 C25 C26 Fe2 -59.8(3) . . . . ?
C19 Fe2 C26 C27 -166.7(4) . . . . ?
C25 Fe2 C26 C27 -119.3(4) . . . . ?
C24 Fe2 C26 C27 -81.4(3) . . . . ?
C20 Fe2 C26 C27 161.7(3) . . . . ?
C21 Fe2 C26 C27 119.9(3) . . . . ?
C23 Fe2 C26 C27 -37.9(3) . . . . ?
C22 Fe2 C26 C27 79.4(3) . . . . ?
C18 Fe2 C26 C27 50.4(6) . . . . ?
C19 Fe2 C26 C25 -47.5(5) . . . . ?
C24 Fe2 C26 C25 37.9(3) . . . . ?
C27 Fe2 C26 C25 119.3(4) . . . . ?
C20 Fe2 C26 C25 -79.0(3) . . . . ?
C21 Fe2 C26 C25 -120.8(3) . . . . ?
C23 Fe2 C26 C25 81.4(3) . . . . ?
C22 Fe2 C26 C25 -161.3(3) . . . . ?
C18 Fe2 C26 C25 169.6(5) . . . . ?
C25 C26 C27 C23 0.1(5) . . . . ?
Fe2 C26 C27 C23 59.8(3) . . . . ?
C25 C26 C27 Fe2 -59.6(3) . . . . ?
C24 C23 C27 C26 -0.2(5) . . . . ?
Fe2 C23 C27 C26 -59.4(3) . . . . ?
C24 C23 C27 Fe2 59.2(3) . . . . ?
C19 Fe2 C27 C26 159.1(6) . . . . ?
C25 Fe2 C27 C26 37.7(3) . . . . ?
C24 Fe2 C27 C26 81.4(3) . . . . ?
C20 Fe2 C27 C26 -39.6(5) . . . . ?
C21 Fe2 C27 C26 -77.4(3) . . . . ?
C23 Fe2 C27 C26 118.9(4) . . . . ?
C22 Fe2 C27 C26 -120.7(3) . . . . ?
C18 Fe2 C27 C26 -162.7(3) . . . . ?
C19 Fe2 C27 C23 40.3(8) . . . . ?
C26 Fe2 C27 C23 -118.9(4) . . . . ?
C25 Fe2 C27 C23 -81.2(3) . . . . ?
C24 Fe2 C27 C23 -37.5(3) . . . . ?
C20 Fe2 C27 C23 -158.4(4) . . . . ?
C21 Fe2 C27 C23 163.8(2) . . . . ?
C22 Fe2 C27 C23 120.5(3) . . . . ?
C18 Fe2 C27 C23 78.4(3) . . . . ?
C30 N2 C28 O2 -1.4(5) . . . . ?
Au1 N2 C28 O2 164.5(3) . . . . ?
C30 N2 C28 C19 178.8(4) . . . . ?
Au1 N2 C28 C19 -15.2(7) . . . . ?
C29 O2 C28 N2 -7.8(5) . . . . ?
C29 O2 C28 C19 171.9(4) . . . . ?
C20 C19 C28 N2 163.5(5) . . . . ?
C18 C19 C28 N2 -12.6(8) . . . . ?
Fe2 C19 C28 N2 75.7(6) . . . . ?
C20 C19 C28 O2 -16.3(7) . . . . ?
C18 C19 C28 O2 167.7(4) . . . . ?
Fe2 C19 C28 O2 -104.0(4) . . . . ?
C28 O2 C29 C30 13.4(5) . . . . ?
C28 N2 C30 C29 9.5(5) . . . . ?
Au1 N2 C30 C29 -156.0(3) . . . . ?
C28 N2 C30 C31 -114.7(4) . . . . ?
Au1 N2 C30 C31 79.8(4) . . . . ?
O2 C29 C30 N2 -13.5(4) . . . . ?
O2 C29 C30 C31 109.1(4) . . . . ?
N2 C30 C31 C34 -61.9(5) . . . . ?
C29 C30 C31 C34 -178.1(4) . . . . ?
N2 C30 C31 C33 60.1(5) . . . . ?
C29 C30 C31 C33 -56.0(5) . . . . ?
N2 C30 C31 C32 -179.9(4) . . . . ?
C29 C30 C31 C32 63.9(5) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        28.29
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.995
_refine_diff_density_min         -0.680
_refine_diff_density_rms         0.132
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2275lm
_database_code_depnum_ccdc_archive 'CCDC 1588446'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'iPrFOMeAu(I)' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C34 H40 Au2 Fe2 N2 O2, C4 H10 O'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C38 H50 Au2 Fe2 N2 O3'
_chemical_formula_weight         1088.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 2'
_symmetry_space_group_name_Hall  'C 2y'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'

_cell_length_a                   18.6557(10)
_cell_length_b                   14.9639(8)
_cell_length_c                   6.5471(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 100.348(4)
_cell_angle_gamma                90.00
_cell_volume                     1797.97(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    3882
_cell_measurement_theta_min      1.76
_cell_measurement_theta_max      28.46

_exptl_crystal_description       needle
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.010
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1052
_exptl_absorpt_coefficient_mu    8.964
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.2132
_exptl_absorpt_correction_T_max  0.7961
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            16550
_diffrn_reflns_av_R_equivalents  0.0497
_diffrn_reflns_av_sigmaI/netI    0.0629
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_theta_min         1.76
_diffrn_reflns_theta_max         28.46
_reflns_number_total             4468
_reflns_number_gt                3882
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0037P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.005(7)
_refine_ls_number_reflns         4468
_refine_ls_number_parameters     227
_refine_ls_number_restraints     29
_refine_ls_R_factor_all          0.0399
_refine_ls_R_factor_gt           0.0280
_refine_ls_wR_factor_ref         0.0485
_refine_ls_wR_factor_gt          0.0466
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.997003(10) 0.88931(2) 0.71634(3) 0.01227(5) Uani 1 1 d . . .
Fe1 Fe 0.83963(5) 1.04194(6) 0.54709(12) 0.01309(18) Uani 1 1 d . . .
O1 O 0.7797(2) 0.8138(3) 0.2296(6) 0.0154(10) Uani 1 1 d . . .
N1 N 0.8963(3) 0.8422(3) 0.2320(6) 0.0113(10) Uani 1 1 d . . .
C1 C 0.8932(3) 0.9261(4) 0.6754(8) 0.0148(13) Uani 1 1 d . . .
C2 C 0.8346(3) 0.9077(4) 0.5025(7) 0.0121(15) Uani 1 1 d . . .
C3 C 0.7660(3) 0.9408(4) 0.5476(9) 0.0147(13) Uani 1 1 d . . .
C4 C 0.7823(3) 0.9818(4) 0.7450(8) 0.0170(14) Uani 1 1 d . . .
H4 H 0.7481 1.0102 0.8147 0.020 Uiso 1 1 calc R . .
C5 C 0.8577(3) 0.9735(4) 0.8221(8) 0.0166(13) Uani 1 1 d . . .
H5 H 0.8818 0.9960 0.9521 0.020 Uiso 1 1 calc R . .
C6 C 0.9015(5) 1.1058(6) 0.3671(13) 0.0179(19) Uani 1 1 d . . .
H6 H 0.9403 1.0796 0.3117 0.021 Uiso 1 1 calc R . .
C7 C 0.8290(4) 1.1081(4) 0.2713(9) 0.0191(14) Uani 1 1 d . . .
H7 H 0.8095 1.0837 0.1390 0.023 Uiso 1 1 calc R . .
C8 C 0.7890(4) 1.1529(4) 0.4043(9) 0.0208(14) Uani 1 1 d . . .
H8 H 0.7381 1.1639 0.3774 0.025 Uiso 1 1 calc R . .
C9 C 0.8381(4) 1.1781(4) 0.5830(9) 0.0213(14) Uani 1 1 d . . .
H9 H 0.8263 1.2093 0.6990 0.026 Uiso 1 1 calc R . .
C10 C 0.9078(4) 1.1489(4) 0.5599(10) 0.0199(14) Uani 1 1 d . . .
H10 H 0.9516 1.1570 0.6577 0.024 Uiso 1 1 calc R . .
C11 C 0.6911(3) 0.9368(4) 0.4149(9) 0.0201(14) Uani 1 1 d . . .
H11A H 0.6703 0.8772 0.4257 0.030 Uiso 1 1 calc R . .
H11B H 0.6947 0.9487 0.2699 0.030 Uiso 1 1 calc R . .
H11C H 0.6596 0.9817 0.4628 0.030 Uiso 1 1 calc R . .
C12 C 0.8421(3) 0.8563(4) 0.3178(8) 0.0146(13) Uani 1 1 d . . .
C13 C 0.7948(3) 0.7691(4) 0.0453(8) 0.0181(14) Uani 1 1 d . . .
H13A H 0.7722 0.8014 -0.0820 0.022 Uiso 1 1 calc R . .
H13B H 0.7763 0.7069 0.0376 0.022 Uiso 1 1 calc R . .
C14 C 0.8776(3) 0.7708(4) 0.0723(8) 0.0126(12) Uani 1 1 d . . .
H14 H 0.8920 0.7906 -0.0604 0.015 Uiso 1 1 calc R . .
C15 C 0.9164(3) 0.6835(4) 0.1431(8) 0.0153(13) Uani 1 1 d . . .
H15 H 0.9700 0.6953 0.1632 0.018 Uiso 1 1 calc R . .
C16 C 0.8996(5) 0.6499(6) 0.3523(14) 0.026(2) Uani 1 1 d . . .
H16A H 0.9126 0.6962 0.4583 0.039 Uiso 1 1 calc R . .
H16B H 0.9279 0.5957 0.3944 0.039 Uiso 1 1 calc R . .
H16C H 0.8475 0.6364 0.3371 0.039 Uiso 1 1 calc R . .
C17 C 0.8990(4) 0.6096(4) -0.0232(10) 0.0237(15) Uani 1 1 d . . .
H17A H 0.9278 0.5561 0.0229 0.036 Uiso 1 1 calc RD . .
H17B H 0.9112 0.6308 -0.1544 0.036 Uiso 1 1 calc R . .
H17C H 0.8470 0.5949 -0.0434 0.036 Uiso 1 1 calc R . .
O1S O 1.0000 0.2795(8) 0.0000 0.105(4) Uani 1 2 d SDU . .
C1S C 0.9654(8) 0.3408(10) 0.108(3) 0.181(8) Uani 1 1 d DU . .
H1SA H 0.9518 0.3069 0.2282 0.217 Uiso 0.50 1 d P A 1
H1SB H 0.9200 0.3568 0.0249 0.217 Uiso 0.50 1 d P B 1
H2SA H 0.9681 0.3937 0.0408 0.217 Uiso 0.50 1 d P C 2
H2SB H 0.9983 0.3436 0.2400 0.217 Uiso 0.50 1 d P D 2
C2S C 1.0100(10) 0.4185(10) 0.186(3) 0.061(6) Uani 0.50 1 d PDU E 1
H2S1 H 1.0605 0.3994 0.2342 0.092 Uiso 0.50 1 calc PR E 1
H2S2 H 0.9909 0.4459 0.3006 0.092 Uiso 0.50 1 calc PR E 1
H2S3 H 1.0086 0.4621 0.0733 0.092 Uiso 0.50 1 calc PRD E 1
C2S1 C 0.8972(8) 0.3436(11) 0.176(2) 0.048(4) Uani 0.50 1 d PDU E 2
H2S4 H 0.8577 0.3416 0.0559 0.072 Uiso 0.50 1 calc PR E 2
H2S5 H 0.8938 0.3990 0.2541 0.072 Uiso 0.50 1 calc PR E 2
H2S6 H 0.8933 0.2922 0.2665 0.072 Uiso 0.50 1 calc PR E 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.984(6) . ?
Au1 N1 2.081(5) 2_756 ?
Au1 Au1 2.8549(4) 2_756 ?
Fe1 C2 2.030(5) . ?
Fe1 C6 2.031(8) . ?
Fe1 C4 2.032(6) . ?
Fe1 C7 2.037(6) . ?
Fe1 C10 2.037(6) . ?
Fe1 C3 2.044(6) . ?
Fe1 C5 2.046(6) . ?
Fe1 C8 2.050(6) . ?
Fe1 C9 2.052(6) . ?
Fe1 C1 2.100(6) . ?
O1 C12 1.360(6) . ?
O1 C13 1.451(6) . ?
N1 C12 1.260(7) . ?
N1 C14 1.492(7) . ?
N1 Au1 2.081(5) 2_756 ?
C1 C5 1.447(8) . ?
C1 C2 1.452(7) . ?
C2 C3 1.453(8) . ?
C2 C12 1.461(7) . ?
C3 C4 1.413(8) . ?
C3 C11 1.508(8) . ?
C4 C5 1.411(8) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.385(10) . ?
C6 C10 1.404(11) . ?
C6 H6 0.9500 . ?
C7 C8 1.412(8) . ?
C7 H7 0.9500 . ?
C8 C9 1.401(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.407(9) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C13 C14 1.523(8) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.524(8) . ?
C14 H14 1.0000 . ?
C15 C16 1.544(10) . ?
C15 C17 1.545(8) . ?
C15 H15 1.0000 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
O1S C1S 1.387(9) 2_755 ?
O1S C1S 1.387(9) . ?
C1S C2S1 1.422(9) . ?
C1S C2S 1.466(9) . ?
C1S H1SA 1.0042 . ?
C1S H1SB 0.9525 . ?
C1S H2SA 0.9127 . ?
C1S H2SB 0.9649 . ?
C2S H2SA 1.1752 . ?
C2S H2SB 1.2078 . ?
C2S H2S1 0.9800 . ?
C2S H2S2 0.9800 . ?
C2S H2S3 0.9800 . ?
C2S1 H1SA 1.1527 . ?
C2S1 H1SB 1.1643 . ?
C2S1 H2S4 0.9800 . ?
C2S1 H2S5 0.9800 . ?
C2S1 H2S6 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N1 175.9(2) . 2_756 ?
C1 Au1 Au1 94.43(15) . 2_756 ?
N1 Au1 Au1 87.39(11) 2_756 2_756 ?
C2 Fe1 C6 113.5(3) . . ?
C2 Fe1 C4 68.7(2) . . ?
C6 Fe1 C4 176.0(3) . . ?
C2 Fe1 C7 111.0(2) . . ?
C6 Fe1 C7 39.8(3) . . ?
C4 Fe1 C7 143.3(3) . . ?
C2 Fe1 C10 142.7(2) . . ?
C6 Fe1 C10 40.4(3) . . ?
C4 Fe1 C10 135.9(3) . . ?
C7 Fe1 C10 67.4(3) . . ?
C2 Fe1 C3 41.8(2) . . ?
C6 Fe1 C3 143.3(3) . . ?
C4 Fe1 C3 40.6(2) . . ?
C7 Fe1 C3 113.7(2) . . ?
C10 Fe1 C3 175.2(3) . . ?
C2 Fe1 C5 68.1(2) . . ?
C6 Fe1 C5 136.5(3) . . ?
C4 Fe1 C5 40.5(2) . . ?
C7 Fe1 C5 176.0(3) . . ?
C10 Fe1 C5 110.7(3) . . ?
C3 Fe1 C5 68.5(2) . . ?
C2 Fe1 C8 136.9(2) . . ?
C6 Fe1 C8 67.5(3) . . ?
C4 Fe1 C8 113.4(3) . . ?
C7 Fe1 C8 40.4(2) . . ?
C10 Fe1 C8 67.4(3) . . ?
C3 Fe1 C8 110.2(3) . . ?
C5 Fe1 C8 142.8(2) . . ?
C2 Fe1 C9 176.4(2) . . ?
C6 Fe1 C9 67.7(3) . . ?
C4 Fe1 C9 110.3(2) . . ?
C7 Fe1 C9 67.5(2) . . ?
C10 Fe1 C9 40.2(2) . . ?
C3 Fe1 C9 135.3(3) . . ?
C5 Fe1 C9 113.5(2) . . ?
C8 Fe1 C9 40.0(2) . . ?
C2 Fe1 C1 41.1(2) . . ?
C6 Fe1 C1 110.0(3) . . ?
C4 Fe1 C1 69.3(2) . . ?
C7 Fe1 C1 136.0(2) . . ?
C10 Fe1 C1 112.5(2) . . ?
C3 Fe1 C1 70.2(2) . . ?
C5 Fe1 C1 40.8(2) . . ?
C8 Fe1 C1 176.4(2) . . ?
C9 Fe1 C1 142.1(2) . . ?
C12 O1 C13 106.9(4) . . ?
C12 N1 C14 109.0(5) . . ?
C12 N1 Au1 133.8(4) . 2_756 ?
C14 N1 Au1 117.0(3) . 2_756 ?
C5 C1 C2 103.9(5) . . ?
C5 C1 Au1 126.8(4) . . ?
C2 C1 Au1 129.2(4) . . ?
C5 C1 Fe1 67.6(3) . . ?
C2 C1 Fe1 66.9(3) . . ?
Au1 C1 Fe1 131.8(3) . . ?
C1 C2 C3 110.2(5) . . ?
C1 C2 C12 125.1(5) . . ?
C3 C2 C12 124.5(5) . . ?
C1 C2 Fe1 72.0(3) . . ?
C3 C2 Fe1 69.6(3) . . ?
C12 C2 Fe1 129.1(4) . . ?
C4 C3 C2 106.3(5) . . ?
C4 C3 C11 124.8(5) . . ?
C2 C3 C11 128.9(5) . . ?
C4 C3 Fe1 69.3(3) . . ?
C2 C3 Fe1 68.6(3) . . ?
C11 C3 Fe1 125.6(4) . . ?
C5 C4 C3 109.1(5) . . ?
C5 C4 Fe1 70.3(3) . . ?
C3 C4 Fe1 70.2(3) . . ?
C5 C4 H4 125.5 . . ?
C3 C4 H4 125.5 . . ?
Fe1 C4 H4 125.7 . . ?
C4 C5 C1 110.6(5) . . ?
C4 C5 Fe1 69.2(3) . . ?
C1 C5 Fe1 71.6(3) . . ?
C4 C5 H5 124.7 . . ?
C1 C5 H5 124.7 . . ?
Fe1 C5 H5 126.0 . . ?
C7 C6 C10 108.3(7) . . ?
C7 C6 Fe1 70.3(4) . . ?
C10 C6 Fe1 70.1(4) . . ?
C7 C6 H6 125.9 . . ?
C10 C6 H6 125.9 . . ?
Fe1 C6 H6 125.3 . . ?
C6 C7 C8 108.2(6) . . ?
C6 C7 Fe1 69.8(4) . . ?
C8 C7 Fe1 70.3(3) . . ?
C6 C7 H7 125.9 . . ?
C8 C7 H7 125.9 . . ?
Fe1 C7 H7 125.6 . . ?
C9 C8 C7 107.8(6) . . ?
C9 C8 Fe1 70.1(4) . . ?
C7 C8 Fe1 69.3(4) . . ?
C9 C8 H8 126.1 . . ?
C7 C8 H8 126.1 . . ?
Fe1 C8 H8 126.1 . . ?
C8 C9 C10 107.7(6) . . ?
C8 C9 Fe1 70.0(4) . . ?
C10 C9 Fe1 69.3(4) . . ?
C8 C9 H9 126.1 . . ?
C10 C9 H9 126.1 . . ?
Fe1 C9 H9 126.1 . . ?
C6 C10 C9 108.0(6) . . ?
C6 C10 Fe1 69.6(4) . . ?
C9 C10 Fe1 70.4(4) . . ?
C6 C10 H10 126.0 . . ?
C9 C10 H10 126.0 . . ?
Fe1 C10 H10 125.6 . . ?
C3 C11 H11A 109.5 . . ?
C3 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C3 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N1 C12 O1 115.2(5) . . ?
N1 C12 C2 131.3(5) . . ?
O1 C12 C2 113.4(5) . . ?
O1 C13 C14 103.9(4) . . ?
O1 C13 H13A 111.0 . . ?
C14 C13 H13A 111.0 . . ?
O1 C13 H13B 111.0 . . ?
C14 C13 H13B 111.0 . . ?
H13A C13 H13B 109.0 . . ?
N1 C14 C13 101.5(4) . . ?
N1 C14 C15 111.2(4) . . ?
C13 C14 C15 116.0(5) . . ?
N1 C14 H14 109.3 . . ?
C13 C14 H14 109.3 . . ?
C15 C14 H14 109.3 . . ?
C14 C15 C16 112.8(5) . . ?
C14 C15 C17 111.8(5) . . ?
C16 C15 C17 109.9(6) . . ?
C14 C15 H15 107.3 . . ?
C16 C15 H15 107.3 . . ?
C17 C15 H15 107.3 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C1S O1S C1S 97.3(16) 2_755 . ?
O1S C1S C2S1 134.8(14) . . ?
O1S C1S C2S 114.4(13) . . ?
C2S1 C1S C2S 110.7(13) . . ?
O1S C1S H1SA 105.8 . . ?
C2S1 C1S H1SA 53.4 . . ?
C2S C1S H1SA 109.8 . . ?
O1S C1S H1SB 108.7 . . ?
C2S1 C1S H1SB 54.5 . . ?
C2S C1S H1SB 113.0 . . ?
H1SA C1S H1SB 104.6 . . ?
O1S C1S H2SA 104.7 . . ?
C2S1 C1S H2SA 104.9 . . ?
C2S C1S H2SA 53.3 . . ?
H1SA C1S H2SA 149.4 . . ?
H1SB C1S H2SA 67.9 . . ?
O1S C1S H2SB 101.9 . . ?
C2S1 C1S H2SB 100.4 . . ?
C2S C1S H2SB 55.0 . . ?
H1SA C1S H2SB 62.2 . . ?
H1SB C1S H2SB 149.2 . . ?
H2SA C1S H2SB 108.3 . . ?
C1S C2S H2SA 38.5 . . ?
C1S C2S H2SB 40.9 . . ?
H2SA C2S H2SB 79.4 . . ?
C1S C2S H2S1 109.5 . . ?
H2SA C2S H2S1 129.2 . . ?
H2SB C2S H2S1 81.2 . . ?
C1S C2S H2S2 109.5 . . ?
H2SA C2S H2S2 118.0 . . ?
H2SB C2S H2S2 92.9 . . ?
C1S C2S H2S3 109.5 . . ?
H2SA C2S H2S3 71.4 . . ?
H2SB C2S H2S3 149.1 . . ?
C1S C2S1 H1SA 44.4 . . ?
C1S C2S1 H1SB 41.8 . . ?
H1SA C2S1 H1SB 83.9 . . ?
C1S C2S1 H2S4 109.5 . . ?
C1S C2S1 H2S5 109.5 . . ?
H2S4 C2S1 H2S5 109.5 . . ?
C1S C2S1 H2S6 109.5 . . ?
H2S4 C2S1 H2S6 109.5 . . ?
H2S5 C2S1 H2S6 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Au1 C1 C5 90(3) 2_756 . . . ?
Au1 Au1 C1 C5 -153.8(5) 2_756 . . . ?
N1 Au1 C1 C2 -86(3) 2_756 . . . ?
Au1 Au1 C1 C2 30.7(5) 2_756 . . . ?
N1 Au1 C1 Fe1 -178(3) 2_756 . . . ?
Au1 Au1 C1 Fe1 -62.1(3) 2_756 . . . ?
C2 Fe1 C1 C5 -117.3(5) . . . . ?
C6 Fe1 C1 C5 139.5(4) . . . . ?
C4 Fe1 C1 C5 -36.3(3) . . . . ?
C7 Fe1 C1 C5 176.3(4) . . . . ?
C10 Fe1 C1 C5 96.1(4) . . . . ?
C3 Fe1 C1 C5 -79.7(4) . . . . ?
C8 Fe1 C1 C5 -176(4) . . . . ?
C9 Fe1 C1 C5 60.5(5) . . . . ?
C6 Fe1 C1 C2 -103.2(4) . . . . ?
C4 Fe1 C1 C2 81.0(4) . . . . ?
C7 Fe1 C1 C2 -66.4(5) . . . . ?
C10 Fe1 C1 C2 -146.6(3) . . . . ?
C3 Fe1 C1 C2 37.6(3) . . . . ?
C5 Fe1 C1 C2 117.3(5) . . . . ?
C8 Fe1 C1 C2 -59(4) . . . . ?
C9 Fe1 C1 C2 177.8(4) . . . . ?
C2 Fe1 C1 Au1 122.7(5) . . . . ?
C6 Fe1 C1 Au1 19.5(5) . . . . ?
C4 Fe1 C1 Au1 -156.3(4) . . . . ?
C7 Fe1 C1 Au1 56.3(5) . . . . ?
C10 Fe1 C1 Au1 -23.9(4) . . . . ?
C3 Fe1 C1 Au1 160.3(4) . . . . ?
C5 Fe1 C1 Au1 -120.0(5) . . . . ?
C8 Fe1 C1 Au1 64(4) . . . . ?
C9 Fe1 C1 Au1 -59.5(6) . . . . ?
C5 C1 C2 C3 -1.6(6) . . . . ?
Au1 C1 C2 C3 174.7(4) . . . . ?
Fe1 C1 C2 C3 -59.4(4) . . . . ?
C5 C1 C2 C12 -176.6(5) . . . . ?
Au1 C1 C2 C12 -0.3(9) . . . . ?
Fe1 C1 C2 C12 125.6(6) . . . . ?
C5 C1 C2 Fe1 57.8(4) . . . . ?
Au1 C1 C2 Fe1 -125.9(5) . . . . ?
C6 Fe1 C2 C1 93.9(4) . . . . ?
C4 Fe1 C2 C1 -82.5(3) . . . . ?
C7 Fe1 C2 C1 137.0(3) . . . . ?
C10 Fe1 C2 C1 57.1(5) . . . . ?
C3 Fe1 C2 C1 -120.5(4) . . . . ?
C5 Fe1 C2 C1 -38.8(3) . . . . ?
C8 Fe1 C2 C1 175.5(4) . . . . ?
C9 Fe1 C2 C1 -157(4) . . . . ?
C6 Fe1 C2 C3 -145.6(4) . . . . ?
C4 Fe1 C2 C3 38.0(3) . . . . ?
C7 Fe1 C2 C3 -102.5(3) . . . . ?
C10 Fe1 C2 C3 177.6(4) . . . . ?
C5 Fe1 C2 C3 81.7(3) . . . . ?
C8 Fe1 C2 C3 -64.0(4) . . . . ?
C9 Fe1 C2 C3 -37(4) . . . . ?
C1 Fe1 C2 C3 120.5(4) . . . . ?
C6 Fe1 C2 C12 -27.1(6) . . . . ?
C4 Fe1 C2 C12 156.5(6) . . . . ?
C7 Fe1 C2 C12 16.0(6) . . . . ?
C10 Fe1 C2 C12 -64.0(6) . . . . ?
C3 Fe1 C2 C12 118.5(6) . . . . ?
C5 Fe1 C2 C12 -159.8(6) . . . . ?
C8 Fe1 C2 C12 54.5(6) . . . . ?
C9 Fe1 C2 C12 82(4) . . . . ?
C1 Fe1 C2 C12 -121.0(6) . . . . ?
C1 C2 C3 C4 1.5(7) . . . . ?
C12 C2 C3 C4 176.5(5) . . . . ?
Fe1 C2 C3 C4 -59.3(4) . . . . ?
C1 C2 C3 C11 -180.0(6) . . . . ?
C12 C2 C3 C11 -5.0(10) . . . . ?
Fe1 C2 C3 C11 119.2(6) . . . . ?
C1 C2 C3 Fe1 60.8(4) . . . . ?
C12 C2 C3 Fe1 -124.2(5) . . . . ?
C2 Fe1 C3 C4 118.0(5) . . . . ?
C6 Fe1 C3 C4 178.1(5) . . . . ?
C7 Fe1 C3 C4 -146.4(4) . . . . ?
C10 Fe1 C3 C4 -44(3) . . . . ?
C5 Fe1 C3 C4 37.2(3) . . . . ?
C8 Fe1 C3 C4 -102.8(4) . . . . ?
C9 Fe1 C3 C4 -65.0(5) . . . . ?
C1 Fe1 C3 C4 81.0(4) . . . . ?
C6 Fe1 C3 C2 60.0(6) . . . . ?
C4 Fe1 C3 C2 -118.0(5) . . . . ?
C7 Fe1 C3 C2 95.5(3) . . . . ?
C10 Fe1 C3 C2 -162(3) . . . . ?
C5 Fe1 C3 C2 -80.8(3) . . . . ?
C8 Fe1 C3 C2 139.1(3) . . . . ?
C9 Fe1 C3 C2 177.0(3) . . . . ?
C1 Fe1 C3 C2 -37.1(3) . . . . ?
C2 Fe1 C3 C11 -123.3(6) . . . . ?
C6 Fe1 C3 C11 -63.3(7) . . . . ?
C4 Fe1 C3 C11 118.6(6) . . . . ?
C7 Fe1 C3 C11 -27.8(6) . . . . ?
C10 Fe1 C3 C11 75(3) . . . . ?
C5 Fe1 C3 C11 155.9(6) . . . . ?
C8 Fe1 C3 C11 15.8(6) . . . . ?
C9 Fe1 C3 C11 53.6(6) . . . . ?
C1 Fe1 C3 C11 -160.4(5) . . . . ?
C2 C3 C4 C5 -0.8(7) . . . . ?
C11 C3 C4 C5 -179.4(6) . . . . ?
Fe1 C3 C4 C5 -59.7(4) . . . . ?
C2 C3 C4 Fe1 58.9(4) . . . . ?
C11 C3 C4 Fe1 -119.7(6) . . . . ?
C2 Fe1 C4 C5 80.8(4) . . . . ?
C6 Fe1 C4 C5 -43(5) . . . . ?
C7 Fe1 C4 C5 177.8(4) . . . . ?
C10 Fe1 C4 C5 -64.8(5) . . . . ?
C3 Fe1 C4 C5 119.9(5) . . . . ?
C8 Fe1 C4 C5 -145.9(4) . . . . ?
C9 Fe1 C4 C5 -102.9(4) . . . . ?
C1 Fe1 C4 C5 36.6(3) . . . . ?
C2 Fe1 C4 C3 -39.1(3) . . . . ?
C6 Fe1 C4 C3 -163(4) . . . . ?
C7 Fe1 C4 C3 57.9(6) . . . . ?
C10 Fe1 C4 C3 175.2(4) . . . . ?
C5 Fe1 C4 C3 -119.9(5) . . . . ?
C8 Fe1 C4 C3 94.1(4) . . . . ?
C9 Fe1 C4 C3 137.2(4) . . . . ?
C1 Fe1 C4 C3 -83.3(4) . . . . ?
C3 C4 C5 C1 -0.2(7) . . . . ?
Fe1 C4 C5 C1 -59.8(4) . . . . ?
C3 C4 C5 Fe1 59.6(4) . . . . ?
C2 C1 C5 C4 1.1(7) . . . . ?
Au1 C1 C5 C4 -175.3(4) . . . . ?
Fe1 C1 C5 C4 58.4(4) . . . . ?
C2 C1 C5 Fe1 -57.3(4) . . . . ?
Au1 C1 C5 Fe1 126.2(5) . . . . ?
C2 Fe1 C5 C4 -82.4(4) . . . . ?
C6 Fe1 C5 C4 176.0(5) . . . . ?
C7 Fe1 C5 C4 -161(4) . . . . ?
C10 Fe1 C5 C4 137.7(4) . . . . ?
C3 Fe1 C5 C4 -37.3(4) . . . . ?
C8 Fe1 C5 C4 58.1(6) . . . . ?
C9 Fe1 C5 C4 94.2(4) . . . . ?
C1 Fe1 C5 C4 -121.5(5) . . . . ?
C2 Fe1 C5 C1 39.0(3) . . . . ?
C6 Fe1 C5 C1 -62.6(5) . . . . ?
C4 Fe1 C5 C1 121.5(5) . . . . ?
C7 Fe1 C5 C1 -39(4) . . . . ?
C10 Fe1 C5 C1 -100.9(4) . . . . ?
C3 Fe1 C5 C1 84.2(4) . . . . ?
C8 Fe1 C5 C1 179.6(4) . . . . ?
C9 Fe1 C5 C1 -144.4(4) . . . . ?
C2 Fe1 C6 C7 95.1(4) . . . . ?
C4 Fe1 C6 C7 -142(4) . . . . ?
C10 Fe1 C6 C7 -118.9(6) . . . . ?
C3 Fe1 C6 C7 56.1(7) . . . . ?
C5 Fe1 C6 C7 177.5(4) . . . . ?
C8 Fe1 C6 C7 -37.9(4) . . . . ?
C9 Fe1 C6 C7 -81.2(5) . . . . ?
C1 Fe1 C6 C7 139.4(4) . . . . ?
C2 Fe1 C6 C10 -145.9(4) . . . . ?
C4 Fe1 C6 C10 -23(5) . . . . ?
C7 Fe1 C6 C10 118.9(6) . . . . ?
C3 Fe1 C6 C10 175.1(4) . . . . ?
C5 Fe1 C6 C10 -63.5(6) . . . . ?
C8 Fe1 C6 C10 81.1(4) . . . . ?
C9 Fe1 C6 C10 37.7(4) . . . . ?
C1 Fe1 C6 C10 -101.7(4) . . . . ?
C10 C6 C7 C8 0.0(8) . . . . ?
Fe1 C6 C7 C8 60.0(5) . . . . ?
C10 C6 C7 Fe1 -60.1(5) . . . . ?
C2 Fe1 C7 C6 -101.9(5) . . . . ?
C4 Fe1 C7 C6 175.8(5) . . . . ?
C10 Fe1 C7 C6 37.9(5) . . . . ?
C3 Fe1 C7 C6 -147.2(5) . . . . ?
C5 Fe1 C7 C6 -25(4) . . . . ?
C8 Fe1 C7 C6 119.1(6) . . . . ?
C9 Fe1 C7 C6 81.6(5) . . . . ?
C1 Fe1 C7 C6 -61.7(6) . . . . ?
C2 Fe1 C7 C8 139.0(4) . . . . ?
C6 Fe1 C7 C8 -119.1(6) . . . . ?
C4 Fe1 C7 C8 56.8(6) . . . . ?
C10 Fe1 C7 C8 -81.2(4) . . . . ?
C3 Fe1 C7 C8 93.8(4) . . . . ?
C5 Fe1 C7 C8 -144(4) . . . . ?
C9 Fe1 C7 C8 -37.5(4) . . . . ?
C1 Fe1 C7 C8 179.3(4) . . . . ?
C6 C7 C8 C9 0.0(8) . . . . ?
Fe1 C7 C8 C9 59.8(4) . . . . ?
C6 C7 C8 Fe1 -59.8(5) . . . . ?
C2 Fe1 C8 C9 177.5(4) . . . . ?
C6 Fe1 C8 C9 -81.6(4) . . . . ?
C4 Fe1 C8 C9 94.1(4) . . . . ?
C7 Fe1 C8 C9 -118.9(6) . . . . ?
C10 Fe1 C8 C9 -37.8(4) . . . . ?
C3 Fe1 C8 C9 137.8(4) . . . . ?
C5 Fe1 C8 C9 57.2(6) . . . . ?
C1 Fe1 C8 C9 -127(4) . . . . ?
C2 Fe1 C8 C7 -63.6(5) . . . . ?
C6 Fe1 C8 C7 37.3(4) . . . . ?
C4 Fe1 C8 C7 -147.0(4) . . . . ?
C10 Fe1 C8 C7 81.2(4) . . . . ?
C3 Fe1 C8 C7 -103.3(4) . . . . ?
C5 Fe1 C8 C7 176.1(4) . . . . ?
C9 Fe1 C8 C7 118.9(6) . . . . ?
C1 Fe1 C8 C7 -8(4) . . . . ?
C7 C8 C9 C10 0.0(7) . . . . ?
Fe1 C8 C9 C10 59.3(4) . . . . ?
C7 C8 C9 Fe1 -59.3(4) . . . . ?
C2 Fe1 C9 C8 -29(4) . . . . ?
C6 Fe1 C9 C8 81.1(4) . . . . ?
C4 Fe1 C9 C8 -102.6(4) . . . . ?
C7 Fe1 C9 C8 37.9(4) . . . . ?
C10 Fe1 C9 C8 118.9(5) . . . . ?
C3 Fe1 C9 C8 -63.7(5) . . . . ?
C5 Fe1 C9 C8 -146.3(4) . . . . ?
C1 Fe1 C9 C8 175.3(4) . . . . ?
C2 Fe1 C9 C10 -148(4) . . . . ?
C6 Fe1 C9 C10 -37.8(4) . . . . ?
C4 Fe1 C9 C10 138.4(4) . . . . ?
C7 Fe1 C9 C10 -81.0(4) . . . . ?
C3 Fe1 C9 C10 177.3(4) . . . . ?
C5 Fe1 C9 C10 94.7(4) . . . . ?
C8 Fe1 C9 C10 -118.9(5) . . . . ?
C1 Fe1 C9 C10 56.4(5) . . . . ?
C7 C6 C10 C9 0.0(8) . . . . ?
Fe1 C6 C10 C9 -60.2(5) . . . . ?
C7 C6 C10 Fe1 60.2(5) . . . . ?
C8 C9 C10 C6 0.0(8) . . . . ?
Fe1 C9 C10 C6 59.7(5) . . . . ?
C8 C9 C10 Fe1 -59.7(4) . . . . ?
C2 Fe1 C10 C6 58.0(6) . . . . ?
C4 Fe1 C10 C6 177.7(5) . . . . ?
C7 Fe1 C10 C6 -37.4(4) . . . . ?
C3 Fe1 C10 C6 -142(3) . . . . ?
C5 Fe1 C10 C6 138.8(4) . . . . ?
C8 Fe1 C10 C6 -81.4(5) . . . . ?
C9 Fe1 C10 C6 -118.9(6) . . . . ?
C1 Fe1 C10 C6 94.7(5) . . . . ?
C2 Fe1 C10 C9 176.9(3) . . . . ?
C6 Fe1 C10 C9 118.9(6) . . . . ?
C4 Fe1 C10 C9 -63.4(5) . . . . ?
C7 Fe1 C10 C9 81.5(4) . . . . ?
C3 Fe1 C10 C9 -23(3) . . . . ?
C5 Fe1 C10 C9 -102.4(4) . . . . ?
C8 Fe1 C10 C9 37.5(3) . . . . ?
C1 Fe1 C10 C9 -146.4(3) . . . . ?
C14 N1 C12 O1 -8.0(7) . . . . ?
Au1 N1 C12 O1 177.5(4) 2_756 . . . ?
C14 N1 C12 C2 168.9(6) . . . . ?
Au1 N1 C12 C2 -5.6(10) 2_756 . . . ?
C13 O1 C12 N1 -4.7(7) . . . . ?
C13 O1 C12 C2 177.8(5) . . . . ?
C1 C2 C12 N1 -25.7(10) . . . . ?
C3 C2 C12 N1 160.1(6) . . . . ?
Fe1 C2 C12 N1 69.2(8) . . . . ?
C1 C2 C12 O1 151.3(5) . . . . ?
C3 C2 C12 O1 -23.0(8) . . . . ?
Fe1 C2 C12 O1 -113.8(5) . . . . ?
C12 O1 C13 C14 14.7(6) . . . . ?
C12 N1 C14 C13 16.3(6) . . . . ?
Au1 N1 C14 C13 -168.1(3) 2_756 . . . ?
C12 N1 C14 C15 -107.6(5) . . . . ?
Au1 N1 C14 C15 68.0(5) 2_756 . . . ?
O1 C13 C14 N1 -18.0(5) . . . . ?
O1 C13 C14 C15 102.6(5) . . . . ?
N1 C14 C15 C16 56.9(7) . . . . ?
C13 C14 C15 C16 -58.3(7) . . . . ?
N1 C14 C15 C17 -178.6(5) . . . . ?
C13 C14 C15 C17 66.2(6) . . . . ?
C1S O1S C1S C2S1 145(2) 2_755 . . . ?
C1S O1S C1S C2S -40.4(10) 2_755 . . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        28.46
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         1.311
_refine_diff_density_min         -1.125
_refine_diff_density_rms         0.154
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2409lm
_database_code_depnum_ccdc_archive 'CCDC 1588455'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'Me2FOMeAu(I)' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H36 Au2 Fe2 N2 O2'
_chemical_formula_sum            'C32 H36 Au2 Fe2 N2 O2'
_chemical_formula_weight         986.26

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.9929(13)
_cell_length_b                   17.6784(17)
_cell_length_c                   13.3992(13)
_cell_angle_alpha                90.00
_cell_angle_beta                 106.431(4)
_cell_angle_gamma                90.00
_cell_volume                     2952.0(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    6115
_cell_measurement_theta_min      1.93
_cell_measurement_theta_max      28.37

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.19
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.219
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1872
_exptl_absorpt_coefficient_mu    10.904
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.2733
_exptl_absorpt_correction_T_max  0.3877
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            40220
_diffrn_reflns_av_R_equivalents  0.0410
_diffrn_reflns_av_sigmaI/netI    0.0358
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.93
_diffrn_reflns_theta_max         28.27
_reflns_number_total             7233
_reflns_number_gt                6115
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0098P)²+9.4079P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000145(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         7233
_refine_ls_number_parameters     368
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0358
_refine_ls_R_factor_gt           0.0249
_refine_ls_wR_factor_ref         0.0470
_refine_ls_wR_factor_gt          0.0452
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_restrained_S_all      1.039
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.974352(12) 0.022770(9) 0.686117(12) 0.01238(4) Uani 1 1 d . . .
Au2 Au 0.928726(12) 0.172330(9) 0.737380(12) 0.01385(5) Uani 1 1 d . . .
Fe1 Fe 0.70865(5) 0.01138(4) 0.74101(5) 0.01701(13) Uani 1 1 d . . .
Fe2 Fe 1.01836(5) 0.29198(3) 0.55938(5) 0.01709(13) Uani 1 1 d . . .
O1 O 0.9062(2) 0.07126(17) 1.0179(2) 0.0200(7) Uani 1 1 d . . .
N1 N 0.9262(3) 0.1403(2) 0.8852(3) 0.0160(7) Uani 1 1 d . . .
C1 C 0.8693(3) -0.0164(2) 0.7571(3) 0.0128(8) Uani 1 1 d . . .
N2 N 1.0876(3) 0.0629(2) 0.6165(3) 0.0137(7) Uani 1 1 d . . .
O2 O 1.1726(2) 0.13609(17) 0.5287(2) 0.0194(7) Uani 1 1 d . . .
C2 C 0.8519(3) 0.0096(2) 0.8548(3) 0.0147(9) Uani 1 1 d . . .
C3 C 0.7753(3) -0.0403(2) 0.8825(3) 0.0173(9) Uani 1 1 d . . .
C4 C 0.7446(3) -0.0950(2) 0.8030(3) 0.0175(9) Uani 1 1 d . . .
H4 H 0.6946 -0.1347 0.7999 0.021 Uiso 1 1 calc R . .
C5 C 0.8009(3) -0.0807(2) 0.7285(3) 0.0150(9) Uani 1 1 d . . .
H5 H 0.7939 -0.1100 0.6675 0.018 Uiso 1 1 calc R . .
C6 C 0.6690(4) 0.0948(3) 0.6311(4) 0.0271(11) Uani 1 1 d . . .
H6 H 0.7158 0.1169 0.5961 0.033 Uiso 1 1 calc R . .
C7 C 0.6530(4) 0.1205(3) 0.7260(4) 0.0288(11) Uani 1 1 d . . .
H7 H 0.6878 0.1624 0.7661 0.035 Uiso 1 1 calc R . .
C8 C 0.5762(4) 0.0730(3) 0.7501(4) 0.0280(11) Uani 1 1 d . . .
H8 H 0.5492 0.0779 0.8087 0.034 Uiso 1 1 calc R . .
C9 C 0.5463(4) 0.0166(3) 0.6715(4) 0.0265(11) Uani 1 1 d . . .
H9 H 0.4967 -0.0234 0.6686 0.032 Uiso 1 1 calc R . .
C10 C 0.6045(4) 0.0314(3) 0.5979(4) 0.0273(11) Uani 1 1 d . . .
H10 H 0.6000 0.0030 0.5367 0.033 Uiso 1 1 calc R . .
C11 C 0.8971(3) 0.0767(2) 0.9157(3) 0.0144(8) Uani 1 1 d . . .
C12 C 0.9504(4) 0.1417(3) 1.0666(3) 0.0210(10) Uani 1 1 d . . .
H12A H 1.0213 0.1333 1.1175 0.025 Uiso 1 1 calc R . .
H12B H 0.9018 0.1652 1.1028 0.025 Uiso 1 1 calc R . .
C13 C 0.9613(3) 0.1922(3) 0.9762(3) 0.0190(9) Uani 1 1 d . . .
C14 C 1.0769(4) 0.2161(3) 0.9899(4) 0.0287(11) Uani 1 1 d . . .
H14A H 1.1224 0.1711 0.9976 0.043 Uiso 1 1 calc R . .
H14B H 1.1014 0.2478 1.0522 0.043 Uiso 1 1 calc R . .
H14C H 1.0813 0.2449 0.9288 0.043 Uiso 1 1 calc R . .
C15 C 0.8872(4) 0.2606(3) 0.9590(4) 0.0336(12) Uani 1 1 d . . .
H15A H 0.8917 0.2879 0.8967 0.050 Uiso 1 1 calc R . .
H15B H 0.9091 0.2942 1.0195 0.050 Uiso 1 1 calc R . .
H15C H 0.8132 0.2438 0.9497 0.050 Uiso 1 1 calc R . .
C16 C 0.7400(4) -0.0395(3) 0.9804(3) 0.0247(10) Uani 1 1 d . . .
H16A H 0.6766 -0.0717 0.9709 0.037 Uiso 1 1 calc R . .
H16B H 0.7223 0.0124 0.9953 0.037 Uiso 1 1 calc R . .
H16C H 0.7981 -0.0586 1.0386 0.037 Uiso 1 1 calc R . .
C17 C 0.9291(3) 0.2034(2) 0.5946(3) 0.0146(8) Uani 1 1 d . . .
C18 C 0.9993(3) 0.1798(2) 0.5330(3) 0.0143(8) Uani 1 1 d . . .
C19 C 0.9733(4) 0.2208(2) 0.4350(3) 0.0196(9) Uani 1 1 d . . .
C20 C 0.8870(4) 0.2692(3) 0.4365(3) 0.0225(10) Uani 1 1 d . . .
H20 H 0.8521 0.3032 0.3827 0.027 Uiso 1 1 calc R . .
C21 C 0.8610(3) 0.2586(2) 0.5320(3) 0.0192(9) Uani 1 1 d . . .
H21 H 0.8057 0.2849 0.5512 0.023 Uiso 1 1 calc R . .
C22 C 1.1769(4) 0.3103(3) 0.6360(4) 0.0339(12) Uani 1 1 d . . .
H22 H 1.2323 0.2734 0.6538 0.041 Uiso 1 1 calc R . .
C23 C 1.1462(4) 0.3524(3) 0.5429(4) 0.0291(11) Uani 1 1 d . . .
H23 H 1.1769 0.3488 0.4866 0.035 Uiso 1 1 calc R . .
C24 C 1.0609(4) 0.4014(3) 0.5483(4) 0.0333(12) Uani 1 1 d . . .
H24 H 1.0248 0.4361 0.4960 0.040 Uiso 1 1 calc R . .
C25 C 1.0390(4) 0.3896(3) 0.6440(4) 0.0373(14) Uani 1 1 d . . .
H25 H 0.9860 0.4149 0.6679 0.045 Uiso 1 1 calc R . .
C26 C 1.1106(5) 0.3328(3) 0.6985(4) 0.0402(14) Uani 1 1 d . . .
H26 H 1.1134 0.3133 0.7653 0.048 Uiso 1 1 calc R . .
C27 C 1.0843(3) 0.1237(2) 0.5628(3) 0.0153(9) Uani 1 1 d . . .
C28 C 1.2377(3) 0.0683(3) 0.5545(4) 0.0217(10) Uani 1 1 d . . .
H28A H 1.3145 0.0815 0.5832 0.026 Uiso 1 1 calc R . .
H28B H 1.2293 0.0362 0.4921 0.026 Uiso 1 1 calc R . .
C29 C 1.1965(3) 0.0274(2) 0.6357(3) 0.0156(9) Uani 1 1 d . . .
C30 C 1.2606(4) 0.0459(3) 0.7461(3) 0.0277(11) Uani 1 1 d . . .
H30A H 1.2646 0.1009 0.7554 0.042 Uiso 1 1 calc R . .
H30B H 1.3333 0.0252 0.7594 0.042 Uiso 1 1 calc R . .
H30C H 1.2255 0.0235 0.7948 0.042 Uiso 1 1 calc R . .
C31 C 1.1879(4) -0.0567(2) 0.6166(3) 0.0213(10) Uani 1 1 d . . .
H31A H 1.1609 -0.0810 0.6700 0.032 Uiso 1 1 calc R . .
H31B H 1.2589 -0.0772 0.6198 0.032 Uiso 1 1 calc R . .
H31C H 1.1385 -0.0667 0.5478 0.032 Uiso 1 1 calc R . .
C32 C 1.0197(4) 0.2118(3) 0.3448(3) 0.0273(11) Uani 1 1 d . . .
H32A H 1.0001 0.1621 0.3127 0.041 Uiso 1 1 calc R . .
H32B H 1.0980 0.2161 0.3695 0.041 Uiso 1 1 calc R . .
H32C H 0.9911 0.2515 0.2932 0.041 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.995(4) . ?
Au1 N2 2.077(3) . ?
Au1 Au2 2.8362(3) . ?
Au2 C17 1.992(4) . ?
Au2 N1 2.069(3) . ?
Fe1 C10 2.042(5) . ?
Fe1 C6 2.045(5) . ?
Fe1 C2 2.046(4) . ?
Fe1 C7 2.051(5) . ?
Fe1 C9 2.053(4) . ?
Fe1 C4 2.055(4) . ?
Fe1 C5 2.056(4) . ?
Fe1 C3 2.062(4) . ?
Fe1 C8 2.069(5) . ?
Fe1 C1 2.096(4) . ?
Fe2 C18 2.017(4) . ?
Fe2 C24 2.028(5) . ?
Fe2 C19 2.038(4) . ?
Fe2 C23 2.039(5) . ?
Fe2 C25 2.040(5) . ?
Fe2 C26 2.042(5) . ?
Fe2 C20 2.048(5) . ?
Fe2 C22 2.051(5) . ?
Fe2 C21 2.059(4) . ?
Fe2 C17 2.080(4) . ?
O1 C11 1.345(5) . ?
O1 C12 1.447(5) . ?
N1 C11 1.289(5) . ?
N1 C13 1.491(5) . ?
C1 C5 1.427(6) . ?
C1 C2 1.465(5) . ?
N2 C27 1.287(5) . ?
N2 C29 1.503(5) . ?
O2 C27 1.366(5) . ?
O2 C28 1.452(5) . ?
C2 C3 1.454(6) . ?
C2 C11 1.464(6) . ?
C3 C4 1.410(6) . ?
C3 C16 1.507(6) . ?
C4 C5 1.417(5) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C10 1.395(7) . ?
C6 C7 1.421(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.409(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.422(7) . ?
C8 H8 0.9500 . ?
C9 C10 1.427(6) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.543(6) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.520(6) . ?
C13 C15 1.521(6) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C21 1.420(6) . ?
C17 C18 1.454(5) . ?
C18 C19 1.454(6) . ?
C18 C27 1.454(6) . ?
C19 C20 1.415(6) . ?
C19 C32 1.504(6) . ?
C20 C21 1.425(6) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C23 1.411(7) . ?
C22 C26 1.419(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.425(7) . ?
C23 H23 0.9500 . ?
C24 C25 1.405(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.422(8) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C28 C29 1.524(6) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C31 1.508(6) . ?
C29 C30 1.513(6) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 178.17(14) . . ?
C1 Au1 Au2 89.43(12) . . ?
N2 Au1 Au2 90.76(9) . . ?
C17 Au2 N1 179.25(15) . . ?
C17 Au2 Au1 88.11(12) . . ?
N1 Au2 Au1 92.16(10) . . ?
C10 Fe1 C6 39.91(19) . . ?
C10 Fe1 C2 157.62(17) . . ?
C6 Fe1 C2 122.59(18) . . ?
C10 Fe1 C7 67.8(2) . . ?
C6 Fe1 C7 40.60(19) . . ?
C2 Fe1 C7 107.98(18) . . ?
C10 Fe1 C9 40.80(17) . . ?
C6 Fe1 C9 67.90(19) . . ?
C2 Fe1 C9 160.08(17) . . ?
C7 Fe1 C9 67.9(2) . . ?
C10 Fe1 C4 123.58(19) . . ?
C6 Fe1 C4 158.91(19) . . ?
C2 Fe1 C4 68.28(17) . . ?
C7 Fe1 C4 159.10(18) . . ?
C9 Fe1 C4 108.17(19) . . ?
C10 Fe1 C5 107.91(18) . . ?
C6 Fe1 C5 123.07(18) . . ?
C2 Fe1 C5 67.71(16) . . ?
C7 Fe1 C5 159.15(18) . . ?
C9 Fe1 C5 123.14(19) . . ?
C4 Fe1 C5 40.32(15) . . ?
C10 Fe1 C3 159.29(19) . . ?
C6 Fe1 C3 159.53(19) . . ?
C2 Fe1 C3 41.47(16) . . ?
C7 Fe1 C3 123.52(18) . . ?
C9 Fe1 C3 123.20(18) . . ?
C4 Fe1 C3 40.06(16) . . ?
C5 Fe1 C3 67.74(16) . . ?
C10 Fe1 C8 67.82(18) . . ?
C6 Fe1 C8 67.58(19) . . ?
C2 Fe1 C8 124.08(17) . . ?
C7 Fe1 C8 40.01(19) . . ?
C9 Fe1 C8 40.35(18) . . ?
C4 Fe1 C8 123.78(18) . . ?
C5 Fe1 C8 159.28(19) . . ?
C3 Fe1 C8 108.63(17) . . ?
C10 Fe1 C1 120.93(17) . . ?
C6 Fe1 C1 106.48(17) . . ?
C2 Fe1 C1 41.40(15) . . ?
C7 Fe1 C1 122.97(18) . . ?
C9 Fe1 C1 157.43(17) . . ?
C4 Fe1 C1 68.76(16) . . ?
C5 Fe1 C1 40.20(16) . . ?
C3 Fe1 C1 69.76(15) . . ?
C8 Fe1 C1 159.74(18) . . ?
C18 Fe2 C24 161.24(18) . . ?
C18 Fe2 C19 42.01(16) . . ?
C24 Fe2 C19 123.4(2) . . ?
C18 Fe2 C23 123.99(17) . . ?
C24 Fe2 C23 41.01(19) . . ?
C19 Fe2 C23 106.80(19) . . ?
C18 Fe2 C25 156.8(2) . . ?
C24 Fe2 C25 40.4(2) . . ?
C19 Fe2 C25 159.9(2) . . ?
C23 Fe2 C25 68.56(19) . . ?
C18 Fe2 C26 121.2(2) . . ?
C24 Fe2 C26 68.2(2) . . ?
C19 Fe2 C26 157.5(2) . . ?
C23 Fe2 C26 68.2(2) . . ?
C25 Fe2 C26 40.8(2) . . ?
C18 Fe2 C20 68.46(17) . . ?
C24 Fe2 C20 108.1(2) . . ?
C19 Fe2 C20 40.52(17) . . ?
C23 Fe2 C20 122.3(2) . . ?
C25 Fe2 C20 124.2(2) . . ?
C26 Fe2 C20 160.7(2) . . ?
C18 Fe2 C22 107.37(19) . . ?
C24 Fe2 C22 68.3(2) . . ?
C19 Fe2 C22 121.5(2) . . ?
C23 Fe2 C22 40.4(2) . . ?
C25 Fe2 C22 68.5(2) . . ?
C26 Fe2 C22 40.6(2) . . ?
C20 Fe2 C22 157.5(2) . . ?
C18 Fe2 C21 67.72(17) . . ?
C24 Fe2 C21 122.52(19) . . ?
C19 Fe2 C21 68.68(17) . . ?
C23 Fe2 C21 158.34(19) . . ?
C25 Fe2 C21 107.99(19) . . ?
C26 Fe2 C21 124.1(2) . . ?
C20 Fe2 C21 40.62(17) . . ?
C22 Fe2 C21 160.1(2) . . ?
C18 Fe2 C17 41.53(15) . . ?
C24 Fe2 C17 156.21(18) . . ?
C19 Fe2 C17 70.80(16) . . ?
C23 Fe2 C17 160.45(18) . . ?
C25 Fe2 C17 120.30(18) . . ?
C26 Fe2 C17 106.23(19) . . ?
C20 Fe2 C17 69.08(17) . . ?
C22 Fe2 C17 123.40(19) . . ?
C21 Fe2 C17 40.14(16) . . ?
C11 O1 C12 107.8(3) . . ?
C11 N1 C13 109.1(3) . . ?
C11 N1 Au2 128.8(3) . . ?
C13 N1 Au2 122.0(3) . . ?
C5 C1 C2 104.4(3) . . ?
C5 C1 Au1 127.3(3) . . ?
C2 C1 Au1 128.1(3) . . ?
C5 C1 Fe1 68.4(2) . . ?
C2 C1 Fe1 67.5(2) . . ?
Au1 C1 Fe1 131.7(2) . . ?
C27 N2 C29 108.9(3) . . ?
C27 N2 Au1 128.4(3) . . ?
C29 N2 Au1 122.2(2) . . ?
C27 O2 C28 106.0(3) . . ?
C3 C2 C11 123.0(3) . . ?
C3 C2 C1 109.1(4) . . ?
C11 C2 C1 127.8(4) . . ?
C3 C2 Fe1 69.9(2) . . ?
C11 C2 Fe1 122.7(3) . . ?
C1 C2 Fe1 71.1(2) . . ?
C4 C3 C2 106.9(3) . . ?
C4 C3 C16 125.0(4) . . ?
C2 C3 C16 127.9(4) . . ?
C4 C3 Fe1 69.7(2) . . ?
C2 C3 Fe1 68.7(2) . . ?
C16 C3 Fe1 130.0(3) . . ?
C3 C4 C5 108.6(4) . . ?
C3 C4 Fe1 70.2(2) . . ?
C5 C4 Fe1 69.9(2) . . ?
C3 C4 H4 125.7 . . ?
C5 C4 H4 125.7 . . ?
Fe1 C4 H4 125.8 . . ?
C4 C5 C1 111.0(4) . . ?
C4 C5 Fe1 69.8(2) . . ?
C1 C5 Fe1 71.4(2) . . ?
C4 C5 H5 124.5 . . ?
C1 C5 H5 124.5 . . ?
Fe1 C5 H5 125.9 . . ?
C10 C6 C7 108.4(4) . . ?
C10 C6 Fe1 69.9(3) . . ?
C7 C6 Fe1 69.9(3) . . ?
C10 C6 H6 125.8 . . ?
C7 C6 H6 125.8 . . ?
Fe1 C6 H6 125.9 . . ?
C8 C7 C6 107.9(4) . . ?
C8 C7 Fe1 70.7(3) . . ?
C6 C7 Fe1 69.5(3) . . ?
C8 C7 H7 126.1 . . ?
C6 C7 H7 126.1 . . ?
Fe1 C7 H7 125.4 . . ?
C7 C8 C9 108.1(4) . . ?
C7 C8 Fe1 69.3(3) . . ?
C9 C8 Fe1 69.2(3) . . ?
C7 C8 H8 125.9 . . ?
C9 C8 H8 125.9 . . ?
Fe1 C8 H8 127.1 . . ?
C8 C9 C10 107.2(4) . . ?
C8 C9 Fe1 70.4(3) . . ?
C10 C9 Fe1 69.2(3) . . ?
C8 C9 H9 126.4 . . ?
C10 C9 H9 126.4 . . ?
Fe1 C9 H9 125.6 . . ?
C6 C10 C9 108.4(4) . . ?
C6 C10 Fe1 70.2(3) . . ?
C9 C10 Fe1 70.0(3) . . ?
C6 C10 H10 125.8 . . ?
C9 C10 H10 125.8 . . ?
Fe1 C10 H10 125.6 . . ?
N1 C11 O1 115.8(4) . . ?
N1 C11 C2 129.6(4) . . ?
O1 C11 C2 114.5(4) . . ?
O1 C12 C13 104.9(3) . . ?
O1 C12 H12A 110.8 . . ?
C13 C12 H12A 110.8 . . ?
O1 C12 H12B 110.8 . . ?
C13 C12 H12B 110.8 . . ?
H12A C12 H12B 108.8 . . ?
N1 C13 C14 109.4(3) . . ?
N1 C13 C15 109.3(4) . . ?
C14 C13 C15 111.0(4) . . ?
N1 C13 C12 102.2(3) . . ?
C14 C13 C12 111.9(4) . . ?
C15 C13 C12 112.6(4) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C3 C16 H16A 109.5 . . ?
C3 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C3 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C21 C17 C18 104.4(4) . . ?
C21 C17 Au2 125.8(3) . . ?
C18 C17 Au2 129.7(3) . . ?
C21 C17 Fe2 69.1(2) . . ?
C18 C17 Fe2 66.9(2) . . ?
Au2 C17 Fe2 125.3(2) . . ?
C19 C18 C17 110.3(4) . . ?
C19 C18 C27 123.6(4) . . ?
C17 C18 C27 126.2(4) . . ?
C19 C18 Fe2 69.8(2) . . ?
C17 C18 Fe2 71.6(2) . . ?
C27 C18 Fe2 125.3(3) . . ?
C20 C19 C18 105.7(4) . . ?
C20 C19 C32 125.1(4) . . ?
C18 C19 C32 129.0(4) . . ?
C20 C19 Fe2 70.1(3) . . ?
C18 C19 Fe2 68.2(2) . . ?
C32 C19 Fe2 129.4(3) . . ?
C19 C20 C21 108.9(4) . . ?
C19 C20 Fe2 69.4(3) . . ?
C21 C20 Fe2 70.1(3) . . ?
C19 C20 H20 125.5 . . ?
C21 C20 H20 125.5 . . ?
Fe2 C20 H20 126.6 . . ?
C17 C21 C20 110.7(4) . . ?
C17 C21 Fe2 70.7(2) . . ?
C20 C21 Fe2 69.3(3) . . ?
C17 C21 H21 124.7 . . ?
C20 C21 H21 124.7 . . ?
Fe2 C21 H21 127.0 . . ?
C23 C22 C26 107.9(5) . . ?
C23 C22 Fe2 69.4(3) . . ?
C26 C22 Fe2 69.4(3) . . ?
C23 C22 H22 126.1 . . ?
C26 C22 H22 126.1 . . ?
Fe2 C22 H22 126.8 . . ?
C22 C23 C24 107.8(4) . . ?
C22 C23 Fe2 70.3(3) . . ?
C24 C23 Fe2 69.1(3) . . ?
C22 C23 H23 126.1 . . ?
C24 C23 H23 126.1 . . ?
Fe2 C23 H23 126.1 . . ?
C25 C24 C23 108.5(5) . . ?
C25 C24 Fe2 70.3(3) . . ?
C23 C24 Fe2 69.9(3) . . ?
C25 C24 H24 125.7 . . ?
C23 C24 H24 125.7 . . ?
Fe2 C24 H24 125.7 . . ?
C24 C25 C26 107.6(5) . . ?
C24 C25 Fe2 69.3(3) . . ?
C26 C25 Fe2 69.7(3) . . ?
C24 C25 H25 126.2 . . ?
C26 C25 H25 126.2 . . ?
Fe2 C25 H25 126.4 . . ?
C22 C26 C25 108.2(5) . . ?
C22 C26 Fe2 70.1(3) . . ?
C25 C26 Fe2 69.5(3) . . ?
C22 C26 H26 125.9 . . ?
C25 C26 H26 125.9 . . ?
Fe2 C26 H26 126.1 . . ?
N2 C27 O2 115.1(4) . . ?
N2 C27 C18 128.7(4) . . ?
O2 C27 C18 116.2(4) . . ?
O2 C28 C29 105.2(3) . . ?
O2 C28 H28A 110.7 . . ?
C29 C28 H28A 110.7 . . ?
O2 C28 H28B 110.7 . . ?
C29 C28 H28B 110.7 . . ?
H28A C28 H28B 108.8 . . ?
N2 C29 C31 111.2(3) . . ?
N2 C29 C30 108.0(3) . . ?
C31 C29 C30 111.8(4) . . ?
N2 C29 C28 100.6(3) . . ?
C31 C29 C28 111.8(3) . . ?
C30 C29 C28 112.8(4) . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C29 C31 H31A 109.5 . . ?
C29 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C29 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C19 C32 H32A 109.5 . . ?
C19 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C19 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C17 -137.88(16) . . . . ?
N2 Au1 Au2 C17 43.93(14) . . . . ?
C1 Au1 Au2 N1 41.42(14) . . . . ?
N2 Au1 Au2 N1 -136.76(13) . . . . ?
C17 Au2 N1 C11 80(12) . . . . ?
Au1 Au2 N1 C11 -32.0(4) . . . . ?
C17 Au2 N1 C13 -100(12) . . . . ?
Au1 Au2 N1 C13 147.6(3) . . . . ?
N2 Au1 C1 C5 -118(5) . . . . ?
Au2 Au1 C1 C5 145.6(4) . . . . ?
N2 Au1 C1 C2 56(5) . . . . ?
Au2 Au1 C1 C2 -40.4(4) . . . . ?
N2 Au1 C1 Fe1 148(5) . . . . ?
Au2 Au1 C1 Fe1 52.2(2) . . . . ?
C10 Fe1 C1 C5 -81.2(3) . . . . ?
C6 Fe1 C1 C5 -122.1(3) . . . . ?
C2 Fe1 C1 C5 117.0(3) . . . . ?
C7 Fe1 C1 C5 -163.4(2) . . . . ?
C9 Fe1 C1 C5 -50.2(5) . . . . ?
C4 Fe1 C1 C5 36.1(2) . . . . ?
C3 Fe1 C1 C5 79.1(2) . . . . ?
C8 Fe1 C1 C5 168.2(5) . . . . ?
C10 Fe1 C1 C2 161.9(3) . . . . ?
C6 Fe1 C1 C2 120.9(3) . . . . ?
C7 Fe1 C1 C2 79.7(3) . . . . ?
C9 Fe1 C1 C2 -167.2(4) . . . . ?
C4 Fe1 C1 C2 -80.8(2) . . . . ?
C5 Fe1 C1 C2 -117.0(3) . . . . ?
C3 Fe1 C1 C2 -37.9(2) . . . . ?
C8 Fe1 C1 C2 51.2(6) . . . . ?
C10 Fe1 C1 Au1 40.2(4) . . . . ?
C6 Fe1 C1 Au1 -0.7(3) . . . . ?
C2 Fe1 C1 Au1 -121.7(4) . . . . ?
C7 Fe1 C1 Au1 -42.0(3) . . . . ?
C9 Fe1 C1 Au1 71.2(6) . . . . ?
C4 Fe1 C1 Au1 157.5(3) . . . . ?
C5 Fe1 C1 Au1 121.4(4) . . . . ?
C3 Fe1 C1 Au1 -159.5(3) . . . . ?
C8 Fe1 C1 Au1 -70.4(6) . . . . ?
C1 Au1 N2 C27 -133(5) . . . . ?
Au2 Au1 N2 C27 -36.9(3) . . . . ?
C1 Au1 N2 C29 38(5) . . . . ?
Au2 Au1 N2 C29 134.4(3) . . . . ?
C5 C1 C2 C3 1.0(4) . . . . ?
Au1 C1 C2 C3 -174.1(3) . . . . ?
Fe1 C1 C2 C3 59.8(3) . . . . ?
C5 C1 C2 C11 -176.0(4) . . . . ?
Au1 C1 C2 C11 9.0(6) . . . . ?
Fe1 C1 C2 C11 -117.2(4) . . . . ?
C5 C1 C2 Fe1 -58.8(3) . . . . ?
Au1 C1 C2 Fe1 126.1(3) . . . . ?
C10 Fe1 C2 C3 -164.1(5) . . . . ?
C6 Fe1 C2 C3 162.9(3) . . . . ?
C7 Fe1 C2 C3 120.6(3) . . . . ?
C9 Fe1 C2 C3 46.0(6) . . . . ?
C4 Fe1 C2 C3 -37.5(2) . . . . ?
C5 Fe1 C2 C3 -81.1(2) . . . . ?
C8 Fe1 C2 C3 79.5(3) . . . . ?
C1 Fe1 C2 C3 -119.6(3) . . . . ?
C10 Fe1 C2 C11 78.9(6) . . . . ?
C6 Fe1 C2 C11 45.9(4) . . . . ?
C7 Fe1 C2 C11 3.6(4) . . . . ?
C9 Fe1 C2 C11 -71.1(7) . . . . ?
C4 Fe1 C2 C11 -154.5(4) . . . . ?
C5 Fe1 C2 C11 161.8(4) . . . . ?
C3 Fe1 C2 C11 -117.0(4) . . . . ?
C8 Fe1 C2 C11 -37.6(4) . . . . ?
C1 Fe1 C2 C11 123.4(4) . . . . ?
C10 Fe1 C2 C1 -44.5(6) . . . . ?
C6 Fe1 C2 C1 -77.5(3) . . . . ?
C7 Fe1 C2 C1 -119.8(3) . . . . ?
C9 Fe1 C2 C1 165.5(5) . . . . ?
C4 Fe1 C2 C1 82.1(2) . . . . ?
C5 Fe1 C2 C1 38.4(2) . . . . ?
C3 Fe1 C2 C1 119.6(3) . . . . ?
C8 Fe1 C2 C1 -161.0(3) . . . . ?
C11 C2 C3 C4 176.1(4) . . . . ?
C1 C2 C3 C4 -1.1(5) . . . . ?
Fe1 C2 C3 C4 59.5(3) . . . . ?
C11 C2 C3 C16 -8.3(7) . . . . ?
C1 C2 C3 C16 174.6(4) . . . . ?
Fe1 C2 C3 C16 -124.8(5) . . . . ?
C11 C2 C3 Fe1 116.6(4) . . . . ?
C1 C2 C3 Fe1 -60.6(3) . . . . ?
C10 Fe1 C3 C4 44.3(6) . . . . ?
C6 Fe1 C3 C4 -163.6(5) . . . . ?
C2 Fe1 C3 C4 -118.5(3) . . . . ?
C7 Fe1 C3 C4 162.4(3) . . . . ?
C9 Fe1 C3 C4 78.5(3) . . . . ?
C5 Fe1 C3 C4 -37.5(2) . . . . ?
C8 Fe1 C3 C4 120.7(3) . . . . ?
C1 Fe1 C3 C4 -80.7(2) . . . . ?
C10 Fe1 C3 C2 162.8(5) . . . . ?
C6 Fe1 C3 C2 -45.1(6) . . . . ?
C7 Fe1 C3 C2 -79.0(3) . . . . ?
C9 Fe1 C3 C2 -163.0(3) . . . . ?
C4 Fe1 C3 C2 118.5(3) . . . . ?
C5 Fe1 C3 C2 81.0(2) . . . . ?
C8 Fe1 C3 C2 -120.8(3) . . . . ?
C1 Fe1 C3 C2 37.8(2) . . . . ?
C10 Fe1 C3 C16 -74.9(7) . . . . ?
C6 Fe1 C3 C16 77.1(7) . . . . ?
C2 Fe1 C3 C16 122.2(5) . . . . ?
C7 Fe1 C3 C16 43.2(5) . . . . ?
C9 Fe1 C3 C16 -40.7(5) . . . . ?
C4 Fe1 C3 C16 -119.2(5) . . . . ?
C5 Fe1 C3 C16 -156.7(4) . . . . ?
C8 Fe1 C3 C16 1.5(5) . . . . ?
C1 Fe1 C3 C16 160.1(4) . . . . ?
C2 C3 C4 C5 0.8(5) . . . . ?
C16 C3 C4 C5 -175.1(4) . . . . ?
Fe1 C3 C4 C5 59.6(3) . . . . ?
C2 C3 C4 Fe1 -58.8(3) . . . . ?
C16 C3 C4 Fe1 125.3(4) . . . . ?
C10 Fe1 C4 C3 -162.8(2) . . . . ?
C6 Fe1 C4 C3 164.1(4) . . . . ?
C2 Fe1 C4 C3 38.8(2) . . . . ?
C7 Fe1 C4 C3 -44.8(6) . . . . ?
C9 Fe1 C4 C3 -120.4(3) . . . . ?
C5 Fe1 C4 C3 119.5(3) . . . . ?
C8 Fe1 C4 C3 -78.6(3) . . . . ?
C1 Fe1 C4 C3 83.4(3) . . . . ?
C10 Fe1 C4 C5 77.8(3) . . . . ?
C6 Fe1 C4 C5 44.6(6) . . . . ?
C2 Fe1 C4 C5 -80.7(3) . . . . ?
C7 Fe1 C4 C5 -164.3(5) . . . . ?
C9 Fe1 C4 C5 120.2(3) . . . . ?
C3 Fe1 C4 C5 -119.5(3) . . . . ?
C8 Fe1 C4 C5 162.0(3) . . . . ?
C1 Fe1 C4 C5 -36.1(2) . . . . ?
C3 C4 C5 C1 -0.2(5) . . . . ?
Fe1 C4 C5 C1 59.6(3) . . . . ?
C3 C4 C5 Fe1 -59.8(3) . . . . ?
C2 C1 C5 C4 -0.5(5) . . . . ?
Au1 C1 C5 C4 174.6(3) . . . . ?
Fe1 C1 C5 C4 -58.7(3) . . . . ?
C2 C1 C5 Fe1 58.2(3) . . . . ?
Au1 C1 C5 Fe1 -126.7(3) . . . . ?
C10 Fe1 C5 C4 -121.2(3) . . . . ?
C6 Fe1 C5 C4 -162.4(3) . . . . ?
C2 Fe1 C5 C4 82.2(3) . . . . ?
C7 Fe1 C5 C4 164.2(5) . . . . ?
C9 Fe1 C5 C4 -78.8(3) . . . . ?
C3 Fe1 C5 C4 37.3(2) . . . . ?
C8 Fe1 C5 C4 -46.6(6) . . . . ?
C1 Fe1 C5 C4 121.8(3) . . . . ?
C10 Fe1 C5 C1 117.0(2) . . . . ?
C6 Fe1 C5 C1 75.8(3) . . . . ?
C2 Fe1 C5 C1 -39.6(2) . . . . ?
C7 Fe1 C5 C1 42.4(6) . . . . ?
C9 Fe1 C5 C1 159.4(2) . . . . ?
C4 Fe1 C5 C1 -121.8(3) . . . . ?
C3 Fe1 C5 C1 -84.6(2) . . . . ?
C8 Fe1 C5 C1 -168.4(4) . . . . ?
C2 Fe1 C6 C10 161.1(3) . . . . ?
C7 Fe1 C6 C10 -119.4(4) . . . . ?
C9 Fe1 C6 C10 -38.0(3) . . . . ?
C4 Fe1 C6 C10 45.2(6) . . . . ?
C5 Fe1 C6 C10 78.1(3) . . . . ?
C3 Fe1 C6 C10 -165.0(4) . . . . ?
C8 Fe1 C6 C10 -81.8(3) . . . . ?
C1 Fe1 C6 C10 118.8(3) . . . . ?
C10 Fe1 C6 C7 119.4(4) . . . . ?
C2 Fe1 C6 C7 -79.5(3) . . . . ?
C9 Fe1 C6 C7 81.4(3) . . . . ?
C4 Fe1 C6 C7 164.6(4) . . . . ?
C5 Fe1 C6 C7 -162.5(3) . . . . ?
C3 Fe1 C6 C7 -45.6(6) . . . . ?
C8 Fe1 C6 C7 37.6(3) . . . . ?
C1 Fe1 C6 C7 -121.8(3) . . . . ?
C10 C6 C7 C8 -1.0(5) . . . . ?
Fe1 C6 C7 C8 -60.6(3) . . . . ?
C10 C6 C7 Fe1 59.6(3) . . . . ?
C10 Fe1 C7 C8 81.5(3) . . . . ?
C6 Fe1 C7 C8 118.6(4) . . . . ?
C2 Fe1 C7 C8 -122.0(3) . . . . ?
C9 Fe1 C7 C8 37.2(3) . . . . ?
C4 Fe1 C7 C8 -45.9(6) . . . . ?
C5 Fe1 C7 C8 163.6(4) . . . . ?
C3 Fe1 C7 C8 -78.9(3) . . . . ?
C1 Fe1 C7 C8 -165.1(2) . . . . ?
C10 Fe1 C7 C6 -37.1(3) . . . . ?
C2 Fe1 C7 C6 119.4(3) . . . . ?
C9 Fe1 C7 C6 -81.3(3) . . . . ?
C4 Fe1 C7 C6 -164.5(5) . . . . ?
C5 Fe1 C7 C6 45.0(6) . . . . ?
C3 Fe1 C7 C6 162.6(3) . . . . ?
C8 Fe1 C7 C6 -118.6(4) . . . . ?
C1 Fe1 C7 C6 76.3(3) . . . . ?
C6 C7 C8 C9 1.3(5) . . . . ?
Fe1 C7 C8 C9 -58.5(3) . . . . ?
C6 C7 C8 Fe1 59.8(3) . . . . ?
C10 Fe1 C8 C7 -81.5(3) . . . . ?
C6 Fe1 C8 C7 -38.2(3) . . . . ?
C2 Fe1 C8 C7 76.9(3) . . . . ?
C9 Fe1 C8 C7 -120.0(4) . . . . ?
C4 Fe1 C8 C7 162.0(3) . . . . ?
C5 Fe1 C8 C7 -163.5(4) . . . . ?
C3 Fe1 C8 C7 120.3(3) . . . . ?
C1 Fe1 C8 C7 38.4(6) . . . . ?
C10 Fe1 C8 C9 38.5(3) . . . . ?
C6 Fe1 C8 C9 81.8(3) . . . . ?
C2 Fe1 C8 C9 -163.1(3) . . . . ?
C7 Fe1 C8 C9 120.0(4) . . . . ?
C4 Fe1 C8 C9 -78.0(3) . . . . ?
C5 Fe1 C8 C9 -43.5(6) . . . . ?
C3 Fe1 C8 C9 -119.7(3) . . . . ?
C1 Fe1 C8 C9 158.4(4) . . . . ?
C7 C8 C9 C10 -1.1(5) . . . . ?
Fe1 C8 C9 C10 -59.6(3) . . . . ?
C7 C8 C9 Fe1 58.5(3) . . . . ?
C10 Fe1 C9 C8 -118.1(4) . . . . ?
C6 Fe1 C9 C8 -80.9(3) . . . . ?
C2 Fe1 C9 C8 44.9(7) . . . . ?
C7 Fe1 C9 C8 -36.9(3) . . . . ?
C4 Fe1 C9 C8 121.2(3) . . . . ?
C5 Fe1 C9 C8 163.1(3) . . . . ?
C3 Fe1 C9 C8 79.6(3) . . . . ?
C1 Fe1 C9 C8 -160.6(4) . . . . ?
C6 Fe1 C9 C10 37.2(3) . . . . ?
C2 Fe1 C9 C10 163.0(5) . . . . ?
C7 Fe1 C9 C10 81.2(3) . . . . ?
C4 Fe1 C9 C10 -120.7(3) . . . . ?
C5 Fe1 C9 C10 -78.8(3) . . . . ?
C3 Fe1 C9 C10 -162.3(3) . . . . ?
C8 Fe1 C9 C10 118.1(4) . . . . ?
C1 Fe1 C9 C10 -42.5(6) . . . . ?
C7 C6 C10 C9 0.3(5) . . . . ?
Fe1 C6 C10 C9 59.9(3) . . . . ?
C7 C6 C10 Fe1 -59.6(3) . . . . ?
C8 C9 C10 C6 0.5(5) . . . . ?
Fe1 C9 C10 C6 -59.9(3) . . . . ?
C8 C9 C10 Fe1 60.5(3) . . . . ?
C2 Fe1 C10 C6 -45.7(6) . . . . ?
C7 Fe1 C10 C6 37.8(3) . . . . ?
C9 Fe1 C10 C6 119.2(4) . . . . ?
C4 Fe1 C10 C6 -162.1(3) . . . . ?
C5 Fe1 C10 C6 -120.5(3) . . . . ?
C3 Fe1 C10 C6 165.2(4) . . . . ?
C8 Fe1 C10 C6 81.1(3) . . . . ?
C1 Fe1 C10 C6 -78.4(3) . . . . ?
C6 Fe1 C10 C9 -119.2(4) . . . . ?
C2 Fe1 C10 C9 -164.9(4) . . . . ?
C7 Fe1 C10 C9 -81.4(3) . . . . ?
C4 Fe1 C10 C9 78.7(3) . . . . ?
C5 Fe1 C10 C9 120.3(3) . . . . ?
C3 Fe1 C10 C9 46.0(6) . . . . ?
C8 Fe1 C10 C9 -38.1(3) . . . . ?
C1 Fe1 C10 C9 162.4(3) . . . . ?
C13 N1 C11 O1 -1.0(5) . . . . ?
Au2 N1 C11 O1 178.6(3) . . . . ?
C13 N1 C11 C2 176.7(4) . . . . ?
Au2 N1 C11 C2 -3.7(6) . . . . ?
C12 O1 C11 N1 -1.2(5) . . . . ?
C12 O1 C11 C2 -179.3(3) . . . . ?
C3 C2 C11 N1 -147.7(4) . . . . ?
C1 C2 C11 N1 28.9(7) . . . . ?
Fe1 C2 C11 N1 -61.7(5) . . . . ?
C3 C2 C11 O1 30.0(6) . . . . ?
C1 C2 C11 O1 -153.4(4) . . . . ?
Fe1 C2 C11 O1 116.0(3) . . . . ?
C11 O1 C12 C13 2.8(4) . . . . ?
C11 N1 C13 C14 121.3(4) . . . . ?
Au2 N1 C13 C14 -58.3(4) . . . . ?
C11 N1 C13 C15 -116.9(4) . . . . ?
Au2 N1 C13 C15 63.4(4) . . . . ?
C11 N1 C13 C12 2.6(4) . . . . ?
Au2 N1 C13 C12 -177.1(3) . . . . ?
O1 C12 C13 N1 -3.2(4) . . . . ?
O1 C12 C13 C14 -120.1(4) . . . . ?
O1 C12 C13 C15 114.0(4) . . . . ?
N1 Au2 C17 C21 32(12) . . . . ?
Au1 Au2 C17 C21 143.9(4) . . . . ?
N1 Au2 C17 C18 -152(12) . . . . ?
Au1 Au2 C17 C18 -39.7(4) . . . . ?
N1 Au2 C17 Fe2 120(12) . . . . ?
Au1 Au2 C17 Fe2 -127.6(2) . . . . ?
C18 Fe2 C17 C21 -116.9(3) . . . . ?
C24 Fe2 C17 C21 51.5(6) . . . . ?
C19 Fe2 C17 C21 -79.4(3) . . . . ?
C23 Fe2 C17 C21 -165.6(5) . . . . ?
C25 Fe2 C17 C21 82.1(3) . . . . ?
C26 Fe2 C17 C21 124.1(3) . . . . ?
C20 Fe2 C17 C21 -36.2(3) . . . . ?
C22 Fe2 C17 C21 165.0(3) . . . . ?
C24 Fe2 C17 C18 168.3(5) . . . . ?
C19 Fe2 C17 C18 37.5(2) . . . . ?
C23 Fe2 C17 C18 -48.7(6) . . . . ?
C25 Fe2 C17 C18 -161.1(3) . . . . ?
C26 Fe2 C17 C18 -119.1(3) . . . . ?
C20 Fe2 C17 C18 80.7(3) . . . . ?
C22 Fe2 C17 C18 -78.2(3) . . . . ?
C21 Fe2 C17 C18 116.9(3) . . . . ?
C18 Fe2 C17 Au2 123.3(4) . . . . ?
C24 Fe2 C17 Au2 -68.4(6) . . . . ?
C19 Fe2 C17 Au2 160.8(3) . . . . ?
C23 Fe2 C17 Au2 74.5(6) . . . . ?
C25 Fe2 C17 Au2 -37.8(3) . . . . ?
C26 Fe2 C17 Au2 4.2(3) . . . . ?
C20 Fe2 C17 Au2 -156.0(3) . . . . ?
C22 Fe2 C17 Au2 45.1(3) . . . . ?
C21 Fe2 C17 Au2 -119.9(4) . . . . ?
C21 C17 C18 C19 0.2(5) . . . . ?
Au2 C17 C18 C19 -176.8(3) . . . . ?
Fe2 C17 C18 C19 -59.2(3) . . . . ?
C21 C17 C18 C27 -180.0(4) . . . . ?
Au2 C17 C18 C27 3.1(6) . . . . ?
Fe2 C17 C18 C27 120.7(4) . . . . ?
C21 C17 C18 Fe2 59.4(3) . . . . ?
Au2 C17 C18 Fe2 -117.6(3) . . . . ?
C24 Fe2 C18 C19 -44.5(7) . . . . ?
C23 Fe2 C18 C19 -76.8(3) . . . . ?
C25 Fe2 C18 C19 166.2(5) . . . . ?
C26 Fe2 C18 C19 -160.2(3) . . . . ?
C20 Fe2 C18 C19 38.5(2) . . . . ?
C22 Fe2 C18 C19 -118.1(3) . . . . ?
C21 Fe2 C18 C19 82.4(3) . . . . ?
C17 Fe2 C18 C19 120.8(3) . . . . ?
C24 Fe2 C18 C17 -165.3(6) . . . . ?
C19 Fe2 C18 C17 -120.8(3) . . . . ?
C23 Fe2 C18 C17 162.3(3) . . . . ?
C25 Fe2 C18 C17 45.3(6) . . . . ?
C26 Fe2 C18 C17 78.9(3) . . . . ?
C20 Fe2 C18 C17 -82.3(3) . . . . ?
C22 Fe2 C18 C17 121.1(3) . . . . ?
C21 Fe2 C18 C17 -38.4(2) . . . . ?
C24 Fe2 C18 C27 73.0(7) . . . . ?
C19 Fe2 C18 C27 117.4(4) . . . . ?
C23 Fe2 C18 C27 40.6(4) . . . . ?
C25 Fe2 C18 C27 -76.4(6) . . . . ?
C26 Fe2 C18 C27 -42.8(4) . . . . ?
C20 Fe2 C18 C27 155.9(4) . . . . ?
C22 Fe2 C18 C27 -0.6(4) . . . . ?
C21 Fe2 C18 C27 -160.1(4) . . . . ?
C17 Fe2 C18 C27 -121.7(4) . . . . ?
C17 C18 C19 C20 -0.2(5) . . . . ?
C27 C18 C19 C20 179.9(4) . . . . ?
Fe2 C18 C19 C20 -60.5(3) . . . . ?
C17 C18 C19 C32 -175.9(4) . . . . ?
C27 C18 C19 C32 4.2(7) . . . . ?
Fe2 C18 C19 C32 123.8(5) . . . . ?
C17 C18 C19 Fe2 60.3(3) . . . . ?
C27 C18 C19 Fe2 -119.6(4) . . . . ?
C18 Fe2 C19 C20 117.0(3) . . . . ?
C24 Fe2 C19 C20 -78.6(3) . . . . ?
C23 Fe2 C19 C20 -120.5(3) . . . . ?
C25 Fe2 C19 C20 -47.1(6) . . . . ?
C26 Fe2 C19 C20 166.1(5) . . . . ?
C22 Fe2 C19 C20 -162.0(3) . . . . ?
C21 Fe2 C19 C20 37.1(3) . . . . ?
C17 Fe2 C19 C20 80.0(3) . . . . ?
C24 Fe2 C19 C18 164.4(2) . . . . ?
C23 Fe2 C19 C18 122.5(3) . . . . ?
C25 Fe2 C19 C18 -164.1(5) . . . . ?
C26 Fe2 C19 C18 49.1(6) . . . . ?
C20 Fe2 C19 C18 -117.0(3) . . . . ?
C22 Fe2 C19 C18 81.0(3) . . . . ?
C21 Fe2 C19 C18 -79.9(2) . . . . ?
C17 Fe2 C19 C18 -37.1(2) . . . . ?
C18 Fe2 C19 C32 -123.3(5) . . . . ?
C24 Fe2 C19 C32 41.0(5) . . . . ?
C23 Fe2 C19 C32 -0.8(5) . . . . ?
C25 Fe2 C19 C32 72.5(7) . . . . ?
C26 Fe2 C19 C32 -74.3(7) . . . . ?
C20 Fe2 C19 C32 119.6(5) . . . . ?
C22 Fe2 C19 C32 -42.4(5) . . . . ?
C21 Fe2 C19 C32 156.7(5) . . . . ?
C17 Fe2 C19 C32 -160.4(4) . . . . ?
C18 C19 C20 C21 0.1(5) . . . . ?
C32 C19 C20 C21 176.1(4) . . . . ?
Fe2 C19 C20 C21 -59.1(3) . . . . ?
C18 C19 C20 Fe2 59.2(3) . . . . ?
C32 C19 C20 Fe2 -124.8(5) . . . . ?
C18 Fe2 C20 C19 -39.9(2) . . . . ?
C24 Fe2 C20 C19 120.5(3) . . . . ?
C23 Fe2 C20 C19 77.6(3) . . . . ?
C25 Fe2 C20 C19 162.3(3) . . . . ?
C26 Fe2 C20 C19 -163.9(6) . . . . ?
C22 Fe2 C20 C19 43.6(6) . . . . ?
C21 Fe2 C20 C19 -120.3(4) . . . . ?
C17 Fe2 C20 C19 -84.6(3) . . . . ?
C18 Fe2 C20 C21 80.5(3) . . . . ?
C24 Fe2 C20 C21 -119.2(3) . . . . ?
C19 Fe2 C20 C21 120.3(4) . . . . ?
C23 Fe2 C20 C21 -162.1(3) . . . . ?
C25 Fe2 C20 C21 -77.4(3) . . . . ?
C26 Fe2 C20 C21 -43.6(7) . . . . ?
C22 Fe2 C20 C21 163.9(5) . . . . ?
C17 Fe2 C20 C21 35.7(2) . . . . ?
C18 C17 C21 C20 -0.1(5) . . . . ?
Au2 C17 C21 C20 177.0(3) . . . . ?
Fe2 C17 C21 C20 57.8(3) . . . . ?
C18 C17 C21 Fe2 -57.9(3) . . . . ?
Au2 C17 C21 Fe2 119.2(3) . . . . ?
C19 C20 C21 C17 0.0(5) . . . . ?
Fe2 C20 C21 C17 -58.7(3) . . . . ?
C19 C20 C21 Fe2 58.6(3) . . . . ?
C18 Fe2 C21 C17 39.7(2) . . . . ?
C24 Fe2 C21 C17 -158.0(3) . . . . ?
C19 Fe2 C21 C17 85.1(3) . . . . ?
C23 Fe2 C21 C17 167.0(5) . . . . ?
C25 Fe2 C21 C17 -116.0(3) . . . . ?
C26 Fe2 C21 C17 -73.8(3) . . . . ?
C20 Fe2 C21 C17 122.2(4) . . . . ?
C22 Fe2 C21 C17 -39.6(7) . . . . ?
C18 Fe2 C21 C20 -82.4(3) . . . . ?
C24 Fe2 C21 C20 79.8(3) . . . . ?
C19 Fe2 C21 C20 -37.0(3) . . . . ?
C23 Fe2 C21 C20 44.8(6) . . . . ?
C25 Fe2 C21 C20 121.9(3) . . . . ?
C26 Fe2 C21 C20 164.0(3) . . . . ?
C22 Fe2 C21 C20 -161.8(5) . . . . ?
C17 Fe2 C21 C20 -122.2(4) . . . . ?
C18 Fe2 C22 C23 122.4(3) . . . . ?
C24 Fe2 C22 C23 -38.2(3) . . . . ?
C19 Fe2 C22 C23 78.6(3) . . . . ?
C25 Fe2 C22 C23 -81.8(3) . . . . ?
C26 Fe2 C22 C23 -119.5(4) . . . . ?
C20 Fe2 C22 C23 46.9(6) . . . . ?
C21 Fe2 C22 C23 -165.2(5) . . . . ?
C17 Fe2 C22 C23 165.3(3) . . . . ?
C18 Fe2 C22 C26 -118.0(3) . . . . ?
C24 Fe2 C22 C26 81.3(3) . . . . ?
C19 Fe2 C22 C26 -161.9(3) . . . . ?
C23 Fe2 C22 C26 119.5(4) . . . . ?
C25 Fe2 C22 C26 37.7(3) . . . . ?
C20 Fe2 C22 C26 166.4(5) . . . . ?
C21 Fe2 C22 C26 -45.7(7) . . . . ?
C17 Fe2 C22 C26 -75.2(4) . . . . ?
C26 C22 C23 C24 0.3(5) . . . . ?
Fe2 C22 C23 C24 59.1(3) . . . . ?
C26 C22 C23 Fe2 -58.8(3) . . . . ?
C18 Fe2 C23 C22 -76.3(3) . . . . ?
C24 Fe2 C23 C22 118.9(4) . . . . ?
C19 Fe2 C23 C22 -119.2(3) . . . . ?
C25 Fe2 C23 C22 81.6(3) . . . . ?
C26 Fe2 C23 C22 37.5(3) . . . . ?
C20 Fe2 C23 C22 -160.7(3) . . . . ?
C21 Fe2 C23 C22 166.4(5) . . . . ?
C17 Fe2 C23 C22 -39.3(7) . . . . ?
C18 Fe2 C23 C24 164.8(3) . . . . ?
C19 Fe2 C23 C24 121.9(3) . . . . ?
C25 Fe2 C23 C24 -37.4(3) . . . . ?
C26 Fe2 C23 C24 -81.4(4) . . . . ?
C20 Fe2 C23 C24 80.4(4) . . . . ?
C22 Fe2 C23 C24 -118.9(4) . . . . ?
C21 Fe2 C23 C24 47.5(6) . . . . ?
C17 Fe2 C23 C24 -158.3(5) . . . . ?
C22 C23 C24 C25 0.0(6) . . . . ?
Fe2 C23 C24 C25 59.9(3) . . . . ?
C22 C23 C24 Fe2 -59.9(3) . . . . ?
C18 Fe2 C24 C25 -162.0(5) . . . . ?
C19 Fe2 C24 C25 163.9(3) . . . . ?
C23 Fe2 C24 C25 -119.4(5) . . . . ?
C26 Fe2 C24 C25 -38.0(3) . . . . ?
C20 Fe2 C24 C25 121.8(3) . . . . ?
C22 Fe2 C24 C25 -81.8(4) . . . . ?
C21 Fe2 C24 C25 79.4(4) . . . . ?
C17 Fe2 C24 C25 42.7(7) . . . . ?
C18 Fe2 C24 C23 -42.6(8) . . . . ?
C19 Fe2 C24 C23 -76.7(4) . . . . ?
C25 Fe2 C24 C23 119.4(5) . . . . ?
C26 Fe2 C24 C23 81.4(3) . . . . ?
C20 Fe2 C24 C23 -118.8(3) . . . . ?
C22 Fe2 C24 C23 37.6(3) . . . . ?
C21 Fe2 C24 C23 -161.2(3) . . . . ?
C17 Fe2 C24 C23 162.1(4) . . . . ?
C23 C24 C25 C26 -0.2(6) . . . . ?
Fe2 C24 C25 C26 59.4(3) . . . . ?
C23 C24 C25 Fe2 -59.6(3) . . . . ?
C18 Fe2 C25 C24 165.4(4) . . . . ?
C19 Fe2 C25 C24 -42.4(7) . . . . ?
C23 Fe2 C25 C24 37.9(3) . . . . ?
C26 Fe2 C25 C24 118.9(4) . . . . ?
C20 Fe2 C25 C24 -77.5(4) . . . . ?
C22 Fe2 C25 C24 81.4(3) . . . . ?
C21 Fe2 C25 C24 -119.4(3) . . . . ?
C17 Fe2 C25 C24 -161.5(3) . . . . ?
C18 Fe2 C25 C26 46.4(6) . . . . ?
C24 Fe2 C25 C26 -118.9(4) . . . . ?
C19 Fe2 C25 C26 -161.3(5) . . . . ?
C23 Fe2 C25 C26 -81.0(3) . . . . ?
C20 Fe2 C25 C26 163.6(3) . . . . ?
C22 Fe2 C25 C26 -37.5(3) . . . . ?
C21 Fe2 C25 C26 121.7(3) . . . . ?
C17 Fe2 C25 C26 79.5(3) . . . . ?
C23 C22 C26 C25 -0.4(6) . . . . ?
Fe2 C22 C26 C25 -59.3(3) . . . . ?
C23 C22 C26 Fe2 58.8(3) . . . . ?
C24 C25 C26 C22 0.4(6) . . . . ?
Fe2 C25 C26 C22 59.6(3) . . . . ?
C24 C25 C26 Fe2 -59.2(3) . . . . ?
C18 Fe2 C26 C22 80.1(3) . . . . ?
C24 Fe2 C26 C22 -81.7(3) . . . . ?
C19 Fe2 C26 C22 43.9(6) . . . . ?
C23 Fe2 C26 C22 -37.4(3) . . . . ?
C25 Fe2 C26 C22 -119.4(4) . . . . ?
C20 Fe2 C26 C22 -164.3(5) . . . . ?
C21 Fe2 C26 C22 162.9(3) . . . . ?
C17 Fe2 C26 C22 122.8(3) . . . . ?
C18 Fe2 C26 C25 -160.5(3) . . . . ?
C24 Fe2 C26 C25 37.7(3) . . . . ?
C19 Fe2 C26 C25 163.2(4) . . . . ?
C23 Fe2 C26 C25 82.0(3) . . . . ?
C20 Fe2 C26 C25 -44.9(7) . . . . ?
C22 Fe2 C26 C25 119.4(4) . . . . ?
C21 Fe2 C26 C25 -77.7(3) . . . . ?
C17 Fe2 C26 C25 -117.8(3) . . . . ?
C29 N2 C27 O2 6.3(5) . . . . ?
Au1 N2 C27 O2 178.5(2) . . . . ?
C29 N2 C27 C18 -174.4(4) . . . . ?
Au1 N2 C27 C18 -2.1(6) . . . . ?
C28 O2 C27 N2 7.5(5) . . . . ?
C28 O2 C27 C18 -171.9(4) . . . . ?
C19 C18 C27 N2 -145.9(4) . . . . ?
C17 C18 C27 N2 34.3(7) . . . . ?
Fe2 C18 C27 N2 126.4(4) . . . . ?
C19 C18 C27 O2 33.5(6) . . . . ?
C17 C18 C27 O2 -146.4(4) . . . . ?
Fe2 C18 C27 O2 -54.3(5) . . . . ?
C27 O2 C28 C29 -17.5(4) . . . . ?
C27 N2 C29 C31 -134.8(4) . . . . ?
Au1 N2 C29 C31 52.3(4) . . . . ?
C27 N2 C29 C30 102.1(4) . . . . ?
Au1 N2 C29 C30 -70.7(4) . . . . ?
C27 N2 C29 C28 -16.3(4) . . . . ?
Au1 N2 C29 C28 170.9(3) . . . . ?
O2 C28 C29 N2 19.9(4) . . . . ?
O2 C28 C29 C31 138.0(4) . . . . ?
O2 C28 C29 C30 -94.9(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.987
_diffrn_reflns_theta_full        28.27
_diffrn_measured_fraction_theta_full 0.987
_refine_diff_density_max         2.380
_refine_diff_density_min         -0.795
_refine_diff_density_rms         0.153
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2410lm
_database_code_depnum_ccdc_archive 'CCDC 1588461'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'H2FOAu(I)' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C26 H24 Au2 Fe2 N2 O2'
_chemical_formula_sum            'C26 H24 Au2 Fe2 N2 O2'
_chemical_formula_weight         902.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   18.0809(7)
_cell_length_b                   15.1860(6)
_cell_length_c                   16.7001(8)
_cell_angle_alpha                90.00
_cell_angle_beta                 98.796(2)
_cell_angle_gamma                90.00
_cell_volume                     4531.5(3)
_cell_formula_units_Z            8
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    5846
_cell_measurement_theta_min      1.76
_cell_measurement_theta_max      26.38

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.04
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.645
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3360
_exptl_absorpt_coefficient_mu    14.194
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.2947
_exptl_absorpt_correction_T_max  0.6554
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            34067
_diffrn_reflns_av_R_equivalents  0.0912
_diffrn_reflns_av_sigmaI/netI    0.1129
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.76
_diffrn_reflns_theta_max         26.38
_reflns_number_total             9268
_reflns_number_gt                5846
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9268
_refine_ls_number_parameters     613
_refine_ls_number_restraints     360
_refine_ls_R_factor_all          0.0991
_refine_ls_R_factor_gt           0.0433
_refine_ls_wR_factor_ref         0.0594
_refine_ls_wR_factor_gt          0.0487
_refine_ls_goodness_of_fit_ref   0.968
_refine_ls_restrained_S_all      0.958
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.27298(2) 0.70185(2) 0.62405(2) 0.01432(10) Uani 1 1 d . . .
Au2 Au 0.33783(2) 0.67025(2) 0.48076(2) 0.01653(10) Uani 1 1 d . . .
Au3 Au 0.16541(2) 0.85771(2) 0.52333(2) 0.01200(9) Uani 1 1 d . . .
Au4 Au 0.20952(2) 0.82838(2) 0.36651(2) 0.01273(10) Uani 1 1 d . . .
Fe1 Fe 0.46705(7) 0.75950(9) 0.71437(8) 0.0150(3) Uani 1 1 d . . .
Fe2 Fe 0.29667(8) 0.42753(9) 0.49734(8) 0.0174(3) Uani 1 1 d . . .
Fe3 Fe -0.02132(7) 0.81660(8) 0.41801(8) 0.0151(3) Uani 1 1 d . . .
Fe4 Fe 0.24222(7) 1.06905(8) 0.34147(8) 0.0128(3) Uani 1 1 d . . .
N1 N 0.3983(4) 0.7864(5) 0.4943(5) 0.020(2) Uani 1 1 d U . .
C1 C 0.3541(5) 0.7840(6) 0.6732(6) 0.015(2) Uani 1 1 d U . .
O1 O 0.4638(4) 0.9073(4) 0.5370(4) 0.0204(17) Uani 1 1 d U . .
O2 O 0.1091(4) 0.5066(4) 0.5398(4) 0.0218(17) Uani 1 1 d U . .
C2 C 0.4043(5) 0.8399(6) 0.6347(5) 0.013(2) Uani 1 1 d U . .
N2 N 0.1866(4) 0.6150(5) 0.5898(4) 0.0148(19) Uani 1 1 d U . .
O3 O 0.0628(3) 0.6072(4) 0.3405(4) 0.0172(16) Uani 1 1 d U . .
N3 N 0.1488(4) 0.7131(5) 0.3471(4) 0.0147(19) Uani 1 1 d U . .
C3 C 0.4493(5) 0.8920(6) 0.6981(5) 0.014(2) Uani 1 1 d U . .
H3 H 0.4857 0.9350 0.6902 0.017 Uiso 1 1 calc R . .
N4 N 0.2482(4) 0.9495(5) 0.5578(4) 0.0124(18) Uani 1 1 d U . .
O4 O 0.3294(3) 1.0615(4) 0.5634(4) 0.0179(16) Uani 1 1 d U . .
C4 C 0.4291(5) 0.8673(6) 0.7720(6) 0.016(2) Uani 1 1 d U . .
H4 H 0.4503 0.8899 0.8235 0.020 Uiso 1 1 calc R . .
C5 C 0.3706(5) 0.8015(6) 0.7576(5) 0.014(2) Uani 1 1 d U . .
H5 H 0.3470 0.7744 0.7982 0.017 Uiso 1 1 calc R . .
C6 C 0.4911(6) 0.6431(7) 0.6634(7) 0.031(3) Uani 1 1 d U . .
H6 H 0.4594 0.6126 0.6219 0.037 Uiso 1 1 calc R . .
C7 C 0.5459(5) 0.7065(6) 0.6526(6) 0.025(3) Uani 1 1 d U . .
H7 H 0.5573 0.7261 0.6019 0.030 Uiso 1 1 calc R . .
C8 C 0.5809(5) 0.7361(6) 0.7291(6) 0.022(3) Uani 1 1 d U . .
H8 H 0.6193 0.7792 0.7385 0.027 Uiso 1 1 calc R . .
C9 C 0.5492(5) 0.6910(6) 0.7888(6) 0.021(3) Uani 1 1 d U . .
H9 H 0.5628 0.6973 0.8457 0.026 Uiso 1 1 calc R . .
C10 C 0.4926(5) 0.6336(6) 0.7485(6) 0.019(2) Uani 1 1 d U . .
H10 H 0.4615 0.5958 0.7740 0.023 Uiso 1 1 calc R . .
C11 C 0.4185(5) 0.8401(6) 0.5527(6) 0.013(2) Uani 1 1 d U . .
C12 C 0.4789(5) 0.8939(6) 0.4549(5) 0.018(2) Uani 1 1 d U . .
H12A H 0.5326 0.8813 0.4548 0.021 Uiso 1 1 calc R . .
H12B H 0.4646 0.9465 0.4211 0.021 Uiso 1 1 calc R . .
C13 C 0.4310(5) 0.8151(6) 0.4236(6) 0.022(3) Uani 1 1 d U . .
H13A H 0.3916 0.8324 0.3786 0.026 Uiso 1 1 calc R . .
H13B H 0.4620 0.7680 0.4047 0.026 Uiso 1 1 calc R . .
C14 C 0.2842(5) 0.5563(6) 0.4531(5) 0.015(2) Uani 1 1 d U . .
C15 C 0.2164(5) 0.5207(6) 0.4749(6) 0.017(2) Uani 1 1 d U . .
C16 C 0.1940(5) 0.4429(6) 0.4286(6) 0.019(3) Uani 1 1 d U . .
H16 H 0.1509 0.4080 0.4313 0.023 Uiso 1 1 calc R . .
C17 C 0.2489(5) 0.4288(6) 0.3784(6) 0.018(2) Uani 1 1 d U . .
H17 H 0.2492 0.3816 0.3411 0.022 Uiso 1 1 calc R . .
C18 C 0.3037(5) 0.4966(6) 0.3926(6) 0.020(2) Uani 1 1 d U . .
H18 H 0.3465 0.5018 0.3662 0.024 Uiso 1 1 calc R . .
C19 C 0.3778(6) 0.4306(7) 0.5978(6) 0.026(3) Uani 1 1 d U . .
H19 H 0.4040 0.4809 0.6210 0.031 Uiso 1 1 calc R . .
C20 C 0.3102(6) 0.3972(6) 0.6165(6) 0.024(3) Uani 1 1 d U . .
H20 H 0.2818 0.4225 0.6540 0.029 Uiso 1 1 calc R . .
C21 C 0.2909(6) 0.3195(6) 0.5706(6) 0.024(3) Uani 1 1 d U . .
H21 H 0.2485 0.2830 0.5724 0.028 Uiso 1 1 calc R . .
C22 C 0.3474(6) 0.3074(7) 0.5218(6) 0.030(3) Uani 1 1 d U . .
H22 H 0.3496 0.2610 0.4841 0.036 Uiso 1 1 calc R . .
C23 C 0.3993(6) 0.3754(7) 0.5383(6) 0.029(3) Uani 1 1 d U . .
H23 H 0.4426 0.3831 0.5131 0.034 Uiso 1 1 calc R . .
C24 C 0.1734(5) 0.5519(6) 0.5361(6) 0.018(2) Uani 1 1 d U . .
C25 C 0.0688(5) 0.5497(6) 0.5983(6) 0.019(2) Uani 1 1 d U . .
H25A H 0.0547 0.5068 0.6381 0.023 Uiso 1 1 calc R . .
H25B H 0.0230 0.5792 0.5709 0.023 Uiso 1 1 calc R . .
C26 C 0.1250(5) 0.6163(6) 0.6389(6) 0.020(2) Uani 1 1 d U . .
H26A H 0.1023 0.6756 0.6387 0.024 Uiso 1 1 calc R . .
H26B H 0.1434 0.5991 0.6957 0.024 Uiso 1 1 calc R . .
C27 C 0.0737(5) 0.7827(5) 0.4990(5) 0.010(2) Uani 1 1 d U . .
C28 C 0.0526(5) 0.7164(6) 0.4383(5) 0.009(2) Uani 1 1 d U . .
C29 C -0.0224(5) 0.6855(6) 0.4438(6) 0.020(2) Uani 1 1 d U . .
H29 H -0.0491 0.6407 0.4117 0.024 Uiso 1 1 calc R . .
C30 C -0.0485(5) 0.7346(6) 0.5061(5) 0.014(2) Uani 1 1 d U . .
H30 H -0.0966 0.7301 0.5221 0.017 Uiso 1 1 calc R . .
C31 C 0.0105(5) 0.7921(6) 0.5406(5) 0.015(2) Uani 1 1 d U . .
H31 H 0.0081 0.8309 0.5847 0.018 Uiso 1 1 calc R . .
C32 C -0.0074(5) 0.9430(6) 0.3813(6) 0.021(3) Uani 1 1 d U . .
H32 H 0.0297 0.9831 0.4057 0.025 Uiso 1 1 calc R . .
C33 C -0.0790(6) 0.9323(6) 0.4019(6) 0.024(3) Uani 1 1 d U . .
H33 H -0.0994 0.9639 0.4426 0.029 Uiso 1 1 calc R . .
C34 C -0.1160(6) 0.8650(6) 0.3504(6) 0.025(3) Uani 1 1 d U . .
H34 H -0.1654 0.8437 0.3510 0.030 Uiso 1 1 calc R . .
C35 C -0.0669(5) 0.8363(6) 0.2994(6) 0.021(2) Uani 1 1 d U . .
H35 H -0.0768 0.7920 0.2590 0.025 Uiso 1 1 calc R . .
C36 C -0.0001(5) 0.8841(6) 0.3182(6) 0.020(2) Uani 1 1 d U . .
H36 H 0.0429 0.8777 0.2925 0.024 Uiso 1 1 calc R . .
C37 C 0.0919(5) 0.6828(6) 0.3736(6) 0.014(2) Uani 1 1 d U . .
C38 C 0.1024(5) 0.5874(6) 0.2719(6) 0.020(2) Uani 1 1 d U . .
H38A H 0.0697 0.5972 0.2195 0.024 Uiso 1 1 calc R . .
H38B H 0.1206 0.5258 0.2742 0.024 Uiso 1 1 calc R . .
C39 C 0.1685(5) 0.6531(6) 0.2837(5) 0.017(2) Uani 1 1 d U . .
H39A H 0.2165 0.6227 0.3020 0.020 Uiso 1 1 calc R . .
H39B H 0.1720 0.6855 0.2329 0.020 Uiso 1 1 calc R . .
C40 C 0.2721(5) 0.9382(6) 0.3696(5) 0.013(2) Uani 1 1 d U . .
C41 C 0.3000(5) 0.9986(6) 0.4355(6) 0.018(2) Uani 1 1 d U . .
C42 C 0.3468(5) 1.0606(6) 0.4034(5) 0.013(2) Uani 1 1 d U . .
H42 H 0.3729 1.1073 0.4333 0.015 Uiso 1 1 calc R . .
C43 C 0.3488(5) 1.0429(5) 0.3219(5) 0.009(2) Uani 1 1 d U . .
H43 H 0.3757 1.0749 0.2869 0.011 Uiso 1 1 calc R . .
C44 C 0.3024(5) 0.9675(6) 0.3010(6) 0.014(2) Uani 1 1 d U . .
H44 H 0.2933 0.9410 0.2489 0.017 Uiso 1 1 calc R . .
C45 C 0.1285(5) 1.0760(6) 0.3048(5) 0.013(2) Uani 1 1 d U . .
H45 H 0.0949 1.0276 0.2962 0.016 Uiso 1 1 calc R . .
C46 C 0.1489(5) 1.1220(6) 0.3793(6) 0.016(2) Uani 1 1 d U . .
H46 H 0.1315 1.1101 0.4291 0.019 Uiso 1 1 calc R . .
C47 C 0.2003(5) 1.1895(6) 0.3649(6) 0.016(2) Uani 1 1 d U . .
H47 H 0.2234 1.2306 0.4039 0.020 Uiso 1 1 calc R . .
C48 C 0.2109(5) 1.1849(6) 0.2835(6) 0.019(2) Uani 1 1 d U . .
H48 H 0.2421 1.2224 0.2578 0.022 Uiso 1 1 calc R . .
C49 C 0.1667(5) 1.1144(6) 0.2464(6) 0.019(2) Uani 1 1 d U . .
H49 H 0.1635 1.0963 0.1915 0.023 Uiso 1 1 calc R . .
C50 C 0.2889(5) 0.9986(6) 0.5177(6) 0.013(2) Uani 1 1 d U . .
C51 C 0.3143(5) 1.0539(6) 0.6466(5) 0.018(2) Uani 1 1 d U . .
H51A H 0.2913 1.1085 0.6638 0.021 Uiso 1 1 calc R . .
H51B H 0.3608 1.0416 0.6844 0.021 Uiso 1 1 calc R . .
C52 C 0.2604(5) 0.9772(6) 0.6433(5) 0.012(2) Uani 1 1 d U . .
H52A H 0.2822 0.9287 0.6789 0.014 Uiso 1 1 calc R . .
H52B H 0.2127 0.9958 0.6605 0.014 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.003(9) . ?
Au1 N2 2.056(7) . ?
Au1 Au2 2.8618(6) . ?
Au1 Au3 3.3487(5) . ?
Au2 C14 2.003(9) . ?
Au2 N1 2.068(8) . ?
Au3 C27 2.001(9) . ?
Au3 N4 2.062(7) . ?
Au3 Au4 2.8865(5) . ?
Au4 C40 2.012(9) . ?
Au4 N3 2.066(7) . ?
Fe1 C2 2.021(8) . ?
Fe1 C10 2.028(9) . ?
Fe1 C6 2.038(10) . ?
Fe1 C7 2.047(10) . ?
Fe1 C3 2.049(9) . ?
Fe1 C8 2.066(9) . ?
Fe1 C9 2.066(9) . ?
Fe1 C4 2.069(9) . ?
Fe1 C1 2.086(9) . ?
Fe1 C5 2.086(9) . ?
Fe2 C20 2.021(10) . ?
Fe2 C15 2.021(9) . ?
Fe2 C23 2.038(10) . ?
Fe2 C16 2.041(9) . ?
Fe2 C17 2.042(9) . ?
Fe2 C19 2.054(9) . ?
Fe2 C22 2.054(10) . ?
Fe2 C21 2.059(9) . ?
Fe2 C18 2.061(9) . ?
Fe2 C14 2.090(9) . ?
Fe3 C28 2.020(9) . ?
Fe3 C29 2.038(9) . ?
Fe3 C34 2.039(9) . ?
Fe3 C33 2.041(9) . ?
Fe3 C36 2.042(9) . ?
Fe3 C32 2.043(9) . ?
Fe3 C30 2.045(9) . ?
Fe3 C35 2.047(9) . ?
Fe3 C31 2.074(9) . ?
Fe3 C27 2.082(9) . ?
Fe4 C42 2.016(9) . ?
Fe4 C47 2.041(9) . ?
Fe4 C43 2.041(9) . ?
Fe4 C48 2.046(9) . ?
Fe4 C49 2.049(9) . ?
Fe4 C41 2.049(9) . ?
Fe4 C46 2.054(9) . ?
Fe4 C45 2.056(9) . ?
Fe4 C44 2.060(9) . ?
Fe4 C40 2.094(9) . ?
N1 C11 1.281(11) . ?
N1 C13 1.465(11) . ?
C1 C5 1.420(12) . ?
C1 C2 1.463(12) . ?
O1 C11 1.359(10) . ?
O1 C12 1.452(10) . ?
O2 C24 1.360(11) . ?
O2 C25 1.460(11) . ?
C2 C11 1.432(12) . ?
C2 C3 1.464(12) . ?
N2 C24 1.310(11) . ?
N2 C26 1.482(11) . ?
O3 C37 1.345(10) . ?
O3 C38 1.472(10) . ?
N3 C37 1.267(11) . ?
N3 C39 1.481(11) . ?
C3 C4 1.392(12) . ?
C3 H3 0.9500 . ?
N4 C50 1.303(11) . ?
N4 C52 1.473(10) . ?
O4 C50 1.365(10) . ?
O4 C51 1.460(10) . ?
C4 C5 1.448(12) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.412(13) . ?
C6 C10 1.424(13) . ?
C6 H6 0.9500 . ?
C7 C8 1.408(13) . ?
C7 H7 0.9500 . ?
C8 C9 1.402(13) . ?
C8 H8 0.9500 . ?
C9 C10 1.431(12) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.520(12) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.436(13) . ?
C14 C18 1.441(12) . ?
C15 C16 1.436(12) . ?
C15 C24 1.454(13) . ?
C16 C17 1.410(13) . ?
C16 H16 0.9500 . ?
C17 C18 1.425(12) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C23 1.400(13) . ?
C19 C20 1.403(13) . ?
C19 H19 0.9500 . ?
C20 C21 1.421(13) . ?
C20 H20 0.9500 . ?
C21 C22 1.414(13) . ?
C21 H21 0.9500 . ?
C22 C23 1.394(13) . ?
C22 H22 0.9500 . ?
C23 H23 0.9500 . ?
C25 C26 1.519(12) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C31 1.433(12) . ?
C27 C28 1.439(11) . ?
C28 C29 1.453(12) . ?
C28 C37 1.470(12) . ?
C29 C30 1.418(12) . ?
C29 H29 0.9500 . ?
C30 C31 1.429(11) . ?
C30 H30 0.9500 . ?
C31 H31 0.9500 . ?
C32 C33 1.399(13) . ?
C32 C36 1.403(12) . ?
C32 H32 0.9500 . ?
C33 C34 1.435(13) . ?
C33 H33 0.9500 . ?
C34 C35 1.392(13) . ?
C34 H34 0.9500 . ?
C35 C36 1.403(12) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C38 C39 1.546(12) . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C44 1.415(12) . ?
C40 C41 1.461(12) . ?
C41 C50 1.418(12) . ?
C41 C42 1.424(12) . ?
C42 C43 1.392(11) . ?
C42 H42 0.9500 . ?
C43 C44 1.432(11) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C49 1.405(12) . ?
C45 C46 1.425(12) . ?
C45 H45 0.9500 . ?
C46 C47 1.429(12) . ?
C46 H46 0.9500 . ?
C47 C48 1.403(12) . ?
C47 H47 0.9500 . ?
C48 C49 1.421(12) . ?
C48 H48 0.9500 . ?
C49 H49 0.9500 . ?
C51 C52 1.514(11) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 172.0(3) . . ?
C1 Au1 Au2 94.5(3) . . ?
N2 Au1 Au2 92.9(2) . . ?
C1 Au1 Au3 95.7(2) . . ?
N2 Au1 Au3 87.4(2) . . ?
Au2 Au1 Au3 88.810(14) . . ?
C14 Au2 N1 172.2(4) . . ?
C14 Au2 Au1 95.3(3) . . ?
N1 Au2 Au1 92.5(2) . . ?
C27 Au3 N4 170.0(3) . . ?
C27 Au3 Au4 93.6(2) . . ?
N4 Au3 Au4 93.9(2) . . ?
C27 Au3 Au1 95.7(2) . . ?
N4 Au3 Au1 89.78(19) . . ?
Au4 Au3 Au1 97.288(15) . . ?
C40 Au4 N3 171.9(3) . . ?
C40 Au4 Au3 94.7(3) . . ?
N3 Au4 Au3 93.4(2) . . ?
C2 Fe1 C10 146.6(4) . . ?
C2 Fe1 C6 112.5(4) . . ?
C10 Fe1 C6 41.0(4) . . ?
C2 Fe1 C7 105.7(4) . . ?
C10 Fe1 C7 67.9(4) . . ?
C6 Fe1 C7 40.4(4) . . ?
C2 Fe1 C3 42.2(3) . . ?
C10 Fe1 C3 170.9(4) . . ?
C6 Fe1 C3 146.7(4) . . ?
C7 Fe1 C3 115.2(4) . . ?
C2 Fe1 C8 129.1(4) . . ?
C10 Fe1 C8 67.9(4) . . ?
C6 Fe1 C8 68.1(4) . . ?
C7 Fe1 C8 40.0(4) . . ?
C3 Fe1 C8 108.5(4) . . ?
C2 Fe1 C9 168.4(4) . . ?
C10 Fe1 C9 40.9(3) . . ?
C6 Fe1 C9 68.6(4) . . ?
C7 Fe1 C9 67.2(4) . . ?
C3 Fe1 C9 131.1(4) . . ?
C8 Fe1 C9 39.7(4) . . ?
C2 Fe1 C4 68.6(4) . . ?
C10 Fe1 C4 133.8(4) . . ?
C6 Fe1 C4 171.2(4) . . ?
C7 Fe1 C4 148.4(4) . . ?
C3 Fe1 C4 39.5(3) . . ?
C8 Fe1 C4 118.4(4) . . ?
C9 Fe1 C4 112.2(4) . . ?
C2 Fe1 C1 41.7(3) . . ?
C10 Fe1 C1 115.5(4) . . ?
C6 Fe1 C1 106.1(4) . . ?
C7 Fe1 C1 128.8(4) . . ?
C3 Fe1 C1 69.9(3) . . ?
C8 Fe1 C1 167.7(4) . . ?
C9 Fe1 C1 149.9(4) . . ?
C4 Fe1 C1 68.6(3) . . ?
C2 Fe1 C5 68.2(4) . . ?
C10 Fe1 C5 111.0(4) . . ?
C6 Fe1 C5 130.8(4) . . ?
C7 Fe1 C5 167.8(4) . . ?
C3 Fe1 C5 67.9(4) . . ?
C8 Fe1 C5 151.8(4) . . ?
C9 Fe1 C5 120.5(4) . . ?
C4 Fe1 C5 40.8(3) . . ?
C1 Fe1 C5 39.8(3) . . ?
C20 Fe2 C15 108.6(4) . . ?
C20 Fe2 C23 67.3(4) . . ?
C15 Fe2 C23 157.8(4) . . ?
C20 Fe2 C16 122.9(4) . . ?
C15 Fe2 C16 41.4(3) . . ?
C23 Fe2 C16 159.5(4) . . ?
C20 Fe2 C17 158.4(4) . . ?
C15 Fe2 C17 68.1(4) . . ?
C23 Fe2 C17 123.9(4) . . ?
C16 Fe2 C17 40.4(4) . . ?
C20 Fe2 C19 40.3(4) . . ?
C15 Fe2 C19 122.6(4) . . ?
C23 Fe2 C19 40.0(4) . . ?
C16 Fe2 C19 158.7(4) . . ?
C17 Fe2 C19 159.7(4) . . ?
C20 Fe2 C22 67.6(4) . . ?
C15 Fe2 C22 160.9(4) . . ?
C23 Fe2 C22 39.8(4) . . ?
C16 Fe2 C22 123.6(4) . . ?
C17 Fe2 C22 108.1(4) . . ?
C19 Fe2 C22 67.4(4) . . ?
C20 Fe2 C21 40.8(4) . . ?
C15 Fe2 C21 124.6(4) . . ?
C23 Fe2 C21 67.5(4) . . ?
C16 Fe2 C21 107.5(4) . . ?
C17 Fe2 C21 122.2(4) . . ?
C19 Fe2 C21 68.1(4) . . ?
C22 Fe2 C21 40.2(4) . . ?
C20 Fe2 C18 159.8(4) . . ?
C15 Fe2 C18 67.8(4) . . ?
C23 Fe2 C18 108.1(4) . . ?
C16 Fe2 C18 68.5(4) . . ?
C17 Fe2 C18 40.7(3) . . ?
C19 Fe2 C18 123.5(4) . . ?
C22 Fe2 C18 122.5(4) . . ?
C21 Fe2 C18 157.8(4) . . ?
C20 Fe2 C14 123.5(4) . . ?
C15 Fe2 C14 40.9(4) . . ?
C23 Fe2 C14 121.7(4) . . ?
C16 Fe2 C14 69.8(4) . . ?
C17 Fe2 C14 69.0(3) . . ?
C19 Fe2 C14 107.0(4) . . ?
C22 Fe2 C14 157.1(4) . . ?
C21 Fe2 C14 160.5(4) . . ?
C18 Fe2 C14 40.6(3) . . ?
C28 Fe3 C29 41.9(3) . . ?
C28 Fe3 C34 147.4(4) . . ?
C29 Fe3 C34 115.8(4) . . ?
C28 Fe3 C33 169.4(4) . . ?
C29 Fe3 C33 148.0(4) . . ?
C34 Fe3 C33 41.2(4) . . ?
C28 Fe3 C36 108.2(4) . . ?
C29 Fe3 C36 132.3(4) . . ?
C34 Fe3 C36 67.3(4) . . ?
C33 Fe3 C36 67.4(4) . . ?
C28 Fe3 C32 130.5(4) . . ?
C29 Fe3 C32 170.9(4) . . ?
C34 Fe3 C32 68.1(4) . . ?
C33 Fe3 C32 40.1(4) . . ?
C36 Fe3 C32 40.2(3) . . ?
C28 Fe3 C30 69.3(4) . . ?
C29 Fe3 C30 40.6(3) . . ?
C34 Fe3 C30 110.1(4) . . ?
C33 Fe3 C30 116.4(4) . . ?
C36 Fe3 C30 171.5(4) . . ?
C32 Fe3 C30 147.4(4) . . ?
C28 Fe3 C35 115.5(4) . . ?
C29 Fe3 C35 109.4(4) . . ?
C34 Fe3 C35 39.8(4) . . ?
C33 Fe3 C35 68.0(4) . . ?
C36 Fe3 C35 40.1(3) . . ?
C32 Fe3 C35 67.8(4) . . ?
C30 Fe3 C35 132.8(4) . . ?
C28 Fe3 C31 67.8(3) . . ?
C29 Fe3 C31 68.0(4) . . ?
C34 Fe3 C31 133.9(4) . . ?
C33 Fe3 C31 110.1(4) . . ?
C36 Fe3 C31 146.9(4) . . ?
C32 Fe3 C31 115.9(4) . . ?
C30 Fe3 C31 40.6(3) . . ?
C35 Fe3 C31 172.3(4) . . ?
C28 Fe3 C27 41.0(3) . . ?
C29 Fe3 C27 69.8(3) . . ?
C34 Fe3 C27 171.4(4) . . ?
C33 Fe3 C27 130.8(4) . . ?
C36 Fe3 C27 114.5(4) . . ?
C32 Fe3 C27 107.4(4) . . ?
C30 Fe3 C27 69.3(3) . . ?
C35 Fe3 C27 146.6(4) . . ?
C31 Fe3 C27 40.3(3) . . ?
C42 Fe4 C47 107.8(4) . . ?
C42 Fe4 C43 40.1(3) . . ?
C47 Fe4 C43 126.3(4) . . ?
C42 Fe4 C48 117.9(4) . . ?
C47 Fe4 C48 40.2(3) . . ?
C43 Fe4 C48 106.9(4) . . ?
C42 Fe4 C49 151.7(4) . . ?
C47 Fe4 C49 67.9(4) . . ?
C43 Fe4 C49 118.4(4) . . ?
C48 Fe4 C49 40.6(3) . . ?
C42 Fe4 C41 41.0(3) . . ?
C47 Fe4 C41 118.8(4) . . ?
C43 Fe4 C41 68.8(3) . . ?
C48 Fe4 C41 152.0(4) . . ?
C49 Fe4 C41 166.1(4) . . ?
C42 Fe4 C46 128.2(4) . . ?
C47 Fe4 C46 40.8(3) . . ?
C43 Fe4 C46 164.8(4) . . ?
C48 Fe4 C46 68.1(4) . . ?
C49 Fe4 C46 68.0(4) . . ?
C41 Fe4 C46 108.4(4) . . ?
C42 Fe4 C45 166.6(4) . . ?
C47 Fe4 C45 68.1(4) . . ?
C43 Fe4 C45 152.6(4) . . ?
C48 Fe4 C45 67.9(4) . . ?
C49 Fe4 C45 40.0(3) . . ?
C41 Fe4 C45 128.6(4) . . ?
C46 Fe4 C45 40.6(3) . . ?
C42 Fe4 C44 67.6(4) . . ?
C47 Fe4 C44 164.6(4) . . ?
C43 Fe4 C44 40.9(3) . . ?
C48 Fe4 C44 127.6(4) . . ?
C49 Fe4 C44 108.7(4) . . ?
C41 Fe4 C44 68.1(4) . . ?
C46 Fe4 C44 153.3(4) . . ?
C45 Fe4 C44 119.6(3) . . ?
C42 Fe4 C40 68.6(3) . . ?
C47 Fe4 C40 153.9(4) . . ?
C43 Fe4 C40 68.5(3) . . ?
C48 Fe4 C40 165.0(4) . . ?
C49 Fe4 C40 127.7(4) . . ?
C41 Fe4 C40 41.3(3) . . ?
C46 Fe4 C40 119.9(4) . . ?
C45 Fe4 C40 109.1(3) . . ?
C44 Fe4 C40 39.8(3) . . ?
C11 N1 C13 108.6(8) . . ?
C11 N1 Au2 135.3(7) . . ?
C13 N1 Au2 116.0(6) . . ?
C5 C1 C2 106.0(8) . . ?
C5 C1 Au1 123.6(7) . . ?
C2 C1 Au1 130.3(7) . . ?
C5 C1 Fe1 70.1(5) . . ?
C2 C1 Fe1 66.8(5) . . ?
Au1 C1 Fe1 130.0(4) . . ?
C11 O1 C12 106.4(7) . . ?
C24 O2 C25 108.8(7) . . ?
C11 C2 C1 129.5(8) . . ?
C11 C2 C3 122.0(8) . . ?
C1 C2 C3 108.1(8) . . ?
C11 C2 Fe1 117.8(6) . . ?
C1 C2 Fe1 71.6(5) . . ?
C3 C2 Fe1 70.0(5) . . ?
C24 N2 C26 108.4(8) . . ?
C24 N2 Au1 135.3(7) . . ?
C26 N2 Au1 116.2(6) . . ?
C37 O3 C38 106.8(7) . . ?
C37 N3 C39 108.9(7) . . ?
C37 N3 Au4 133.9(7) . . ?
C39 N3 Au4 116.9(6) . . ?
C4 C3 C2 107.7(8) . . ?
C4 C3 Fe1 71.0(5) . . ?
C2 C3 Fe1 67.9(5) . . ?
C4 C3 H3 126.2 . . ?
C2 C3 H3 126.2 . . ?
Fe1 C3 H3 126.5 . . ?
C50 N4 C52 108.8(7) . . ?
C50 N4 Au3 133.3(6) . . ?
C52 N4 Au3 117.3(6) . . ?
C50 O4 C51 108.3(7) . . ?
C3 C4 C5 108.8(8) . . ?
C3 C4 Fe1 69.5(5) . . ?
C5 C4 Fe1 70.3(5) . . ?
C3 C4 H4 125.6 . . ?
C5 C4 H4 125.6 . . ?
Fe1 C4 H4 126.2 . . ?
C1 C5 C4 109.4(8) . . ?
C1 C5 Fe1 70.1(5) . . ?
C4 C5 Fe1 69.0(5) . . ?
C1 C5 H5 125.3 . . ?
C4 C5 H5 125.3 . . ?
Fe1 C5 H5 127.3 . . ?
C7 C6 C10 106.8(9) . . ?
C7 C6 Fe1 70.1(6) . . ?
C10 C6 Fe1 69.1(5) . . ?
C7 C6 H6 126.6 . . ?
C10 C6 H6 126.6 . . ?
Fe1 C6 H6 125.7 . . ?
C8 C7 C6 109.2(9) . . ?
C8 C7 Fe1 70.7(6) . . ?
C6 C7 Fe1 69.4(6) . . ?
C8 C7 H7 125.4 . . ?
C6 C7 H7 125.4 . . ?
Fe1 C7 H7 126.1 . . ?
C9 C8 C7 108.2(9) . . ?
C9 C8 Fe1 70.2(6) . . ?
C7 C8 Fe1 69.3(6) . . ?
C9 C8 H8 125.9 . . ?
C7 C8 H8 125.9 . . ?
Fe1 C8 H8 126.3 . . ?
C8 C9 C10 107.6(9) . . ?
C8 C9 Fe1 70.1(5) . . ?
C10 C9 Fe1 68.1(5) . . ?
C8 C9 H9 126.2 . . ?
C10 C9 H9 126.2 . . ?
Fe1 C9 H9 127.1 . . ?
C6 C10 C9 108.1(9) . . ?
C6 C10 Fe1 69.9(5) . . ?
C9 C10 Fe1 71.0(5) . . ?
C6 C10 H10 125.9 . . ?
C9 C10 H10 125.9 . . ?
Fe1 C10 H10 124.8 . . ?
N1 C11 O1 116.2(9) . . ?
N1 C11 C2 130.9(9) . . ?
O1 C11 C2 112.8(8) . . ?
O1 C12 C13 104.8(7) . . ?
O1 C12 H12A 110.8 . . ?
C13 C12 H12A 110.8 . . ?
O1 C12 H12B 110.8 . . ?
C13 C12 H12B 110.8 . . ?
H12A C12 H12B 108.9 . . ?
N1 C13 C12 103.7(8) . . ?
N1 C13 H13A 111.0 . . ?
C12 C13 H13A 111.0 . . ?
N1 C13 H13B 111.0 . . ?
C12 C13 H13B 111.0 . . ?
H13A C13 H13B 109.0 . . ?
C15 C14 C18 104.5(8) . . ?
C15 C14 Au2 131.9(7) . . ?
C18 C14 Au2 122.9(7) . . ?
C15 C14 Fe2 67.0(5) . . ?
C18 C14 Fe2 68.6(5) . . ?
Au2 C14 Fe2 134.8(5) . . ?
C16 C15 C14 110.8(9) . . ?
C16 C15 C24 120.6(9) . . ?
C14 C15 C24 128.6(9) . . ?
C16 C15 Fe2 70.1(5) . . ?
C14 C15 Fe2 72.2(5) . . ?
C24 C15 Fe2 122.9(7) . . ?
C17 C16 C15 106.2(9) . . ?
C17 C16 Fe2 69.8(6) . . ?
C15 C16 Fe2 68.5(5) . . ?
C17 C16 H16 126.9 . . ?
C15 C16 H16 126.9 . . ?
Fe2 C16 H16 126.3 . . ?
C16 C17 C18 109.0(9) . . ?
C16 C17 Fe2 69.8(6) . . ?
C18 C17 Fe2 70.4(5) . . ?
C16 C17 H17 125.5 . . ?
C18 C17 H17 125.5 . . ?
Fe2 C17 H17 125.9 . . ?
C17 C18 C14 109.4(9) . . ?
C17 C18 Fe2 69.0(5) . . ?
C14 C18 Fe2 70.8(5) . . ?
C17 C18 H18 125.3 . . ?
C14 C18 H18 125.3 . . ?
Fe2 C18 H18 126.6 . . ?
C23 C19 C20 106.7(9) . . ?
C23 C19 Fe2 69.4(6) . . ?
C20 C19 Fe2 68.6(6) . . ?
C23 C19 H19 126.6 . . ?
C20 C19 H19 126.6 . . ?
Fe2 C19 H19 126.9 . . ?
C19 C20 C21 109.4(9) . . ?
C19 C20 Fe2 71.1(6) . . ?
C21 C20 Fe2 71.1(6) . . ?
C19 C20 H20 125.3 . . ?
C21 C20 H20 125.3 . . ?
Fe2 C20 H20 124.1 . . ?
C22 C21 C20 106.2(9) . . ?
C22 C21 Fe2 69.7(6) . . ?
C20 C21 Fe2 68.2(5) . . ?
C22 C21 H21 126.9 . . ?
C20 C21 H21 126.9 . . ?
Fe2 C21 H21 126.7 . . ?
C23 C22 C21 108.3(10) . . ?
C23 C22 Fe2 69.4(6) . . ?
C21 C22 Fe2 70.1(6) . . ?
C23 C22 H22 125.8 . . ?
C21 C22 H22 125.8 . . ?
Fe2 C22 H22 126.2 . . ?
C22 C23 C19 109.4(10) . . ?
C22 C23 Fe2 70.7(6) . . ?
C19 C23 Fe2 70.6(6) . . ?
C22 C23 H23 125.3 . . ?
C19 C23 H23 125.3 . . ?
Fe2 C23 H23 125.0 . . ?
N2 C24 O2 114.0(9) . . ?
N2 C24 C15 131.2(9) . . ?
O2 C24 C15 114.9(8) . . ?
O2 C25 C26 103.2(7) . . ?
O2 C25 H25A 111.1 . . ?
C26 C25 H25A 111.1 . . ?
O2 C25 H25B 111.1 . . ?
C26 C25 H25B 111.1 . . ?
H25A C25 H25B 109.1 . . ?
N2 C26 C25 104.6(7) . . ?
N2 C26 H26A 110.8 . . ?
C25 C26 H26A 110.8 . . ?
N2 C26 H26B 110.8 . . ?
C25 C26 H26B 110.8 . . ?
H26A C26 H26B 108.9 . . ?
C31 C27 C28 105.4(8) . . ?
C31 C27 Au3 122.9(6) . . ?
C28 C27 Au3 131.6(7) . . ?
C31 C27 Fe3 69.5(5) . . ?
C28 C27 Fe3 67.1(5) . . ?
Au3 C27 Fe3 124.5(4) . . ?
C27 C28 C29 109.3(8) . . ?
C27 C28 C37 130.9(8) . . ?
C29 C28 C37 119.7(8) . . ?
C27 C28 Fe3 71.8(5) . . ?
C29 C28 Fe3 69.7(5) . . ?
C37 C28 Fe3 121.3(6) . . ?
C30 C29 C28 107.2(8) . . ?
C30 C29 Fe3 69.9(5) . . ?
C28 C29 Fe3 68.3(5) . . ?
C30 C29 H29 126.4 . . ?
C28 C29 H29 126.4 . . ?
Fe3 C29 H29 126.9 . . ?
C29 C30 C31 107.8(8) . . ?
C29 C30 Fe3 69.4(5) . . ?
C31 C30 Fe3 70.8(5) . . ?
C29 C30 H30 126.1 . . ?
C31 C30 H30 126.1 . . ?
Fe3 C30 H30 125.3 . . ?
C30 C31 C27 110.2(8) . . ?
C30 C31 Fe3 68.6(5) . . ?
C27 C31 Fe3 70.2(5) . . ?
C30 C31 H31 124.9 . . ?
C27 C31 H31 124.9 . . ?
Fe3 C31 H31 128.0 . . ?
C33 C32 C36 107.9(9) . . ?
C33 C32 Fe3 69.9(5) . . ?
C36 C32 Fe3 69.9(5) . . ?
C33 C32 H32 126.1 . . ?
C36 C32 H32 126.1 . . ?
Fe3 C32 H32 125.8 . . ?
C32 C33 C34 107.4(9) . . ?
C32 C33 Fe3 70.0(5) . . ?
C34 C33 Fe3 69.3(5) . . ?
C32 C33 H33 126.3 . . ?
C34 C33 H33 126.3 . . ?
Fe3 C33 H33 125.9 . . ?
C35 C34 C33 107.9(9) . . ?
C35 C34 Fe3 70.4(5) . . ?
C33 C34 Fe3 69.5(5) . . ?
C35 C34 H34 126.1 . . ?
C33 C34 H34 126.1 . . ?
Fe3 C34 H34 125.6 . . ?
C34 C35 C36 108.0(9) . . ?
C34 C35 Fe3 69.8(6) . . ?
C36 C35 Fe3 69.7(5) . . ?
C34 C35 H35 126.0 . . ?
C36 C35 H35 126.0 . . ?
Fe3 C35 H35 126.1 . . ?
C35 C36 C32 108.8(9) . . ?
C35 C36 Fe3 70.1(5) . . ?
C32 C36 Fe3 69.9(6) . . ?
C35 C36 H36 125.6 . . ?
C32 C36 H36 125.6 . . ?
Fe3 C36 H36 125.9 . . ?
N3 C37 O3 116.9(8) . . ?
N3 C37 C28 129.8(8) . . ?
O3 C37 C28 113.3(8) . . ?
O3 C38 C39 103.1(7) . . ?
O3 C38 H38A 111.1 . . ?
C39 C38 H38A 111.1 . . ?
O3 C38 H38B 111.1 . . ?
C39 C38 H38B 111.1 . . ?
H38A C38 H38B 109.1 . . ?
N3 C39 C38 102.9(7) . . ?
N3 C39 H39A 111.2 . . ?
C38 C39 H39A 111.2 . . ?
N3 C39 H39B 111.2 . . ?
C38 C39 H39B 111.2 . . ?
H39A C39 H39B 109.1 . . ?
C44 C40 C41 106.3(8) . . ?
C44 C40 Au4 121.7(7) . . ?
C41 C40 Au4 131.9(7) . . ?
C44 C40 Fe4 68.8(5) . . ?
C41 C40 Fe4 67.7(5) . . ?
Au4 C40 Fe4 131.0(5) . . ?
C50 C41 C42 123.0(9) . . ?
C50 C41 C40 130.2(8) . . ?
C42 C41 C40 106.7(8) . . ?
C50 C41 Fe4 127.7(7) . . ?
C42 C41 Fe4 68.2(5) . . ?
C40 C41 Fe4 71.0(5) . . ?
C43 C42 C41 110.2(8) . . ?
C43 C42 Fe4 70.9(5) . . ?
C41 C42 Fe4 70.8(5) . . ?
C43 C42 H42 124.9 . . ?
C41 C42 H42 124.9 . . ?
Fe4 C42 H42 125.0 . . ?
C42 C43 C44 106.9(8) . . ?
C42 C43 Fe4 68.9(5) . . ?
C44 C43 Fe4 70.3(5) . . ?
C42 C43 H43 126.5 . . ?
C44 C43 H43 126.5 . . ?
Fe4 C43 H43 125.8 . . ?
C40 C44 C43 109.8(8) . . ?
C40 C44 Fe4 71.4(5) . . ?
C43 C44 Fe4 68.9(5) . . ?
C40 C44 H44 125.1 . . ?
C43 C44 H44 125.1 . . ?
Fe4 C44 H44 126.2 . . ?
C49 C45 C46 108.3(9) . . ?
C49 C45 Fe4 69.7(5) . . ?
C46 C45 Fe4 69.6(5) . . ?
C49 C45 H45 125.9 . . ?
C46 C45 H45 125.9 . . ?
Fe4 C45 H45 126.4 . . ?
C45 C46 C47 107.1(8) . . ?
C45 C46 Fe4 69.8(5) . . ?
C47 C46 Fe4 69.1(5) . . ?
C45 C46 H46 126.5 . . ?
C47 C46 H46 126.5 . . ?
Fe4 C46 H46 126.2 . . ?
C48 C47 C46 108.4(8) . . ?
C48 C47 Fe4 70.1(5) . . ?
C46 C47 Fe4 70.1(5) . . ?
C48 C47 H47 125.8 . . ?
C46 C47 H47 125.8 . . ?
Fe4 C47 H47 125.6 . . ?
C47 C48 C49 108.1(8) . . ?
C47 C48 Fe4 69.7(5) . . ?
C49 C48 Fe4 69.8(5) . . ?
C47 C48 H48 126.0 . . ?
C49 C48 H48 126.0 . . ?
Fe4 C48 H48 126.1 . . ?
C45 C49 C48 108.2(9) . . ?
C45 C49 Fe4 70.3(5) . . ?
C48 C49 Fe4 69.6(5) . . ?
C45 C49 H49 125.9 . . ?
C48 C49 H49 125.9 . . ?
Fe4 C49 H49 125.8 . . ?
N4 C50 O4 114.2(8) . . ?
N4 C50 C41 132.3(9) . . ?
O4 C50 C41 113.5(8) . . ?
O4 C51 C52 103.9(7) . . ?
O4 C51 H51A 111.0 . . ?
C52 C51 H51A 111.0 . . ?
O4 C51 H51B 111.0 . . ?
C52 C51 H51B 111.0 . . ?
H51A C51 H51B 109.0 . . ?
N4 C52 C51 104.7(7) . . ?
N4 C52 H52A 110.8 . . ?
C51 C52 H52A 110.8 . . ?
N4 C52 H52B 110.8 . . ?
C51 C52 H52B 110.8 . . ?
H52A C52 H52B 108.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C14 158.5(4) . . . . ?
N2 Au1 Au2 C14 -18.6(3) . . . . ?
Au3 Au1 Au2 C14 -106.0(3) . . . . ?
C1 Au1 Au2 N1 -22.5(3) . . . . ?
N2 Au1 Au2 N1 160.5(3) . . . . ?
Au3 Au1 Au2 N1 73.1(2) . . . . ?
C1 Au1 Au3 C27 -165.7(4) . . . . ?
N2 Au1 Au3 C27 6.8(3) . . . . ?
Au2 Au1 Au3 C27 99.8(2) . . . . ?
C1 Au1 Au3 N4 5.9(3) . . . . ?
N2 Au1 Au3 N4 178.5(3) . . . . ?
Au2 Au1 Au3 N4 -88.5(2) . . . . ?
C1 Au1 Au3 Au4 99.9(3) . . . . ?
N2 Au1 Au3 Au4 -87.6(2) . . . . ?
Au2 Au1 Au3 Au4 5.407(15) . . . . ?
C27 Au3 Au4 C40 157.2(3) . . . . ?
N4 Au3 Au4 C40 -16.2(3) . . . . ?
Au1 Au3 Au4 C40 -106.5(3) . . . . ?
C27 Au3 Au4 N3 -22.3(3) . . . . ?
N4 Au3 Au4 N3 164.2(3) . . . . ?
Au1 Au3 Au4 N3 73.9(2) . . . . ?
C14 Au2 N1 C11 -169(2) . . . . ?
Au1 Au2 N1 C11 18.1(9) . . . . ?
C14 Au2 N1 C13 7(3) . . . . ?
Au1 Au2 N1 C13 -166.2(6) . . . . ?
N2 Au1 C1 C5 1(3) . . . . ?
Au2 Au1 C1 C5 -157.4(7) . . . . ?
Au3 Au1 C1 C5 113.4(7) . . . . ?
N2 Au1 C1 C2 -175.6(19) . . . . ?
Au2 Au1 C1 C2 26.1(8) . . . . ?
Au3 Au1 C1 C2 -63.1(8) . . . . ?
N2 Au1 C1 Fe1 92(2) . . . . ?
Au2 Au1 C1 Fe1 -66.0(6) . . . . ?
Au3 Au1 C1 Fe1 -155.2(5) . . . . ?
C2 Fe1 C1 C5 -118.4(7) . . . . ?
C10 Fe1 C1 C5 92.7(6) . . . . ?
C6 Fe1 C1 C5 135.7(6) . . . . ?
C7 Fe1 C1 C5 174.0(5) . . . . ?
C3 Fe1 C1 C5 -79.2(6) . . . . ?
C8 Fe1 C1 C5 -164.0(16) . . . . ?
C9 Fe1 C1 C5 60.7(9) . . . . ?
C4 Fe1 C1 C5 -36.9(5) . . . . ?
C10 Fe1 C1 C2 -148.9(5) . . . . ?
C6 Fe1 C1 C2 -106.0(6) . . . . ?
C7 Fe1 C1 C2 -67.6(7) . . . . ?
C3 Fe1 C1 C2 39.1(5) . . . . ?
C8 Fe1 C1 C2 -45.6(19) . . . . ?
C9 Fe1 C1 C2 179.1(7) . . . . ?
C4 Fe1 C1 C2 81.5(5) . . . . ?
C5 Fe1 C1 C2 118.4(7) . . . . ?
C2 Fe1 C1 Au1 123.9(9) . . . . ?
C10 Fe1 C1 Au1 -25.0(8) . . . . ?
C6 Fe1 C1 Au1 17.9(7) . . . . ?
C7 Fe1 C1 Au1 56.3(8) . . . . ?
C3 Fe1 C1 Au1 163.1(7) . . . . ?
C8 Fe1 C1 Au1 78.3(19) . . . . ?
C9 Fe1 C1 Au1 -57.0(10) . . . . ?
C4 Fe1 C1 Au1 -154.6(7) . . . . ?
C5 Fe1 C1 Au1 -117.7(9) . . . . ?
C5 C1 C2 C11 170.7(8) . . . . ?
Au1 C1 C2 C11 -12.3(14) . . . . ?
Fe1 C1 C2 C11 111.3(9) . . . . ?
C5 C1 C2 C3 -1.3(10) . . . . ?
Au1 C1 C2 C3 175.7(6) . . . . ?
Fe1 C1 C2 C3 -60.7(6) . . . . ?
C5 C1 C2 Fe1 59.4(6) . . . . ?
Au1 C1 C2 Fe1 -123.6(7) . . . . ?
C10 Fe1 C2 C11 -67.6(10) . . . . ?
C6 Fe1 C2 C11 -36.4(8) . . . . ?
C7 Fe1 C2 C11 6.0(8) . . . . ?
C3 Fe1 C2 C11 116.4(9) . . . . ?
C8 Fe1 C2 C11 43.1(9) . . . . ?
C9 Fe1 C2 C11 57(2) . . . . ?
C4 Fe1 C2 C11 153.1(8) . . . . ?
C1 Fe1 C2 C11 -125.6(9) . . . . ?
C5 Fe1 C2 C11 -162.9(8) . . . . ?
C10 Fe1 C2 C1 58.0(9) . . . . ?
C6 Fe1 C2 C1 89.2(6) . . . . ?
C7 Fe1 C2 C1 131.5(5) . . . . ?
C3 Fe1 C2 C1 -118.0(8) . . . . ?
C8 Fe1 C2 C1 168.7(5) . . . . ?
C9 Fe1 C2 C1 -177.7(17) . . . . ?
C4 Fe1 C2 C1 -81.4(6) . . . . ?
C5 Fe1 C2 C1 -37.4(5) . . . . ?
C10 Fe1 C2 C3 176.0(7) . . . . ?
C6 Fe1 C2 C3 -152.8(6) . . . . ?
C7 Fe1 C2 C3 -110.5(6) . . . . ?
C8 Fe1 C2 C3 -73.3(7) . . . . ?
C9 Fe1 C2 C3 -60(2) . . . . ?
C4 Fe1 C2 C3 36.7(5) . . . . ?
C1 Fe1 C2 C3 118.0(8) . . . . ?
C5 Fe1 C2 C3 80.7(6) . . . . ?
C1 Au1 N2 C24 -143(2) . . . . ?
Au2 Au1 N2 C24 15.7(9) . . . . ?
Au3 Au1 N2 C24 104.3(9) . . . . ?
C1 Au1 N2 C26 32(3) . . . . ?
Au2 Au1 N2 C26 -169.7(6) . . . . ?
Au3 Au1 N2 C26 -81.1(6) . . . . ?
C40 Au4 N3 C37 -152(2) . . . . ?
Au3 Au4 N3 C37 24.7(9) . . . . ?
C40 Au4 N3 C39 21(3) . . . . ?
Au3 Au4 N3 C39 -162.2(6) . . . . ?
C11 C2 C3 C4 -171.1(8) . . . . ?
C1 C2 C3 C4 1.6(10) . . . . ?
Fe1 C2 C3 C4 -60.1(6) . . . . ?
C11 C2 C3 Fe1 -111.0(8) . . . . ?
C1 C2 C3 Fe1 61.8(6) . . . . ?
C2 Fe1 C3 C4 119.1(8) . . . . ?
C10 Fe1 C3 C4 -47(3) . . . . ?
C6 Fe1 C3 C4 169.3(7) . . . . ?
C7 Fe1 C3 C4 -155.2(6) . . . . ?
C8 Fe1 C3 C4 -112.5(6) . . . . ?
C9 Fe1 C3 C4 -74.2(7) . . . . ?
C1 Fe1 C3 C4 80.4(6) . . . . ?
C5 Fe1 C3 C4 37.6(5) . . . . ?
C10 Fe1 C3 C2 -166(2) . . . . ?
C6 Fe1 C3 C2 50.2(9) . . . . ?
C7 Fe1 C3 C2 85.7(6) . . . . ?
C8 Fe1 C3 C2 128.4(6) . . . . ?
C9 Fe1 C3 C2 166.7(6) . . . . ?
C4 Fe1 C3 C2 -119.1(8) . . . . ?
C1 Fe1 C3 C2 -38.7(5) . . . . ?
C5 Fe1 C3 C2 -81.4(6) . . . . ?
C27 Au3 N4 C50 -119.0(18) . . . . ?
Au4 Au3 N4 C50 20.1(8) . . . . ?
Au1 Au3 N4 C50 117.4(8) . . . . ?
C27 Au3 N4 C52 51(2) . . . . ?
Au4 Au3 N4 C52 -169.5(5) . . . . ?
Au1 Au3 N4 C52 -72.2(6) . . . . ?
C2 C3 C4 C5 -1.3(10) . . . . ?
Fe1 C3 C4 C5 -59.5(6) . . . . ?
C2 C3 C4 Fe1 58.2(6) . . . . ?
C2 Fe1 C4 C3 -39.0(5) . . . . ?
C10 Fe1 C4 C3 170.7(6) . . . . ?
C6 Fe1 C4 C3 -139(2) . . . . ?
C7 Fe1 C4 C3 46.2(9) . . . . ?
C8 Fe1 C4 C3 84.9(6) . . . . ?
C9 Fe1 C4 C3 128.5(6) . . . . ?
C1 Fe1 C4 C3 -84.0(6) . . . . ?
C5 Fe1 C4 C3 -120.0(8) . . . . ?
C2 Fe1 C4 C5 80.9(5) . . . . ?
C10 Fe1 C4 C5 -69.3(7) . . . . ?
C6 Fe1 C4 C5 -19(3) . . . . ?
C7 Fe1 C4 C5 166.2(7) . . . . ?
C3 Fe1 C4 C5 120.0(8) . . . . ?
C8 Fe1 C4 C5 -155.1(5) . . . . ?
C9 Fe1 C4 C5 -111.5(6) . . . . ?
C1 Fe1 C4 C5 36.0(5) . . . . ?
C2 C1 C5 C4 0.5(10) . . . . ?
Au1 C1 C5 C4 -176.7(6) . . . . ?
Fe1 C1 C5 C4 57.8(6) . . . . ?
C2 C1 C5 Fe1 -57.3(6) . . . . ?
Au1 C1 C5 Fe1 125.5(6) . . . . ?
C3 C4 C5 C1 0.5(10) . . . . ?
Fe1 C4 C5 C1 -58.5(6) . . . . ?
C3 C4 C5 Fe1 59.0(6) . . . . ?
C2 Fe1 C5 C1 39.1(5) . . . . ?
C10 Fe1 C5 C1 -105.0(6) . . . . ?
C6 Fe1 C5 C1 -62.5(7) . . . . ?
C7 Fe1 C5 C1 -23(2) . . . . ?
C3 Fe1 C5 C1 84.7(6) . . . . ?
C8 Fe1 C5 C1 172.8(7) . . . . ?
C9 Fe1 C5 C1 -149.5(5) . . . . ?
C4 Fe1 C5 C1 121.2(8) . . . . ?
C2 Fe1 C5 C4 -82.1(6) . . . . ?
C10 Fe1 C5 C4 133.7(5) . . . . ?
C6 Fe1 C5 C4 176.3(6) . . . . ?
C7 Fe1 C5 C4 -143.7(17) . . . . ?
C3 Fe1 C5 C4 -36.5(5) . . . . ?
C8 Fe1 C5 C4 51.6(10) . . . . ?
C9 Fe1 C5 C4 89.3(6) . . . . ?
C1 Fe1 C5 C4 -121.2(8) . . . . ?
C2 Fe1 C6 C7 87.9(6) . . . . ?
C10 Fe1 C6 C7 -117.8(8) . . . . ?
C3 Fe1 C6 C7 53.9(9) . . . . ?
C8 Fe1 C6 C7 -36.8(6) . . . . ?
C9 Fe1 C6 C7 -79.6(6) . . . . ?
C4 Fe1 C6 C7 -176(2) . . . . ?
C1 Fe1 C6 C7 131.7(6) . . . . ?
C5 Fe1 C6 C7 167.9(5) . . . . ?
C2 Fe1 C6 C10 -154.3(6) . . . . ?
C7 Fe1 C6 C10 117.8(8) . . . . ?
C3 Fe1 C6 C10 171.8(6) . . . . ?
C8 Fe1 C6 C10 81.0(6) . . . . ?
C9 Fe1 C6 C10 38.2(5) . . . . ?
C4 Fe1 C6 C10 -58(3) . . . . ?
C1 Fe1 C6 C10 -110.5(6) . . . . ?
C5 Fe1 C6 C10 -74.2(7) . . . . ?
C10 C6 C7 C8 0.0(11) . . . . ?
Fe1 C6 C7 C8 59.7(7) . . . . ?
C10 C6 C7 Fe1 -59.7(6) . . . . ?
C2 Fe1 C7 C8 133.2(6) . . . . ?
C10 Fe1 C7 C8 -81.5(6) . . . . ?
C6 Fe1 C7 C8 -120.2(9) . . . . ?
C3 Fe1 C7 C8 89.2(6) . . . . ?
C9 Fe1 C7 C8 -37.1(6) . . . . ?
C4 Fe1 C7 C8 58.6(9) . . . . ?
C1 Fe1 C7 C8 172.9(5) . . . . ?
C5 Fe1 C7 C8 -168.8(16) . . . . ?
C2 Fe1 C7 C6 -106.6(6) . . . . ?
C10 Fe1 C7 C6 38.8(6) . . . . ?
C3 Fe1 C7 C6 -150.6(6) . . . . ?
C8 Fe1 C7 C6 120.2(9) . . . . ?
C9 Fe1 C7 C6 83.2(6) . . . . ?
C4 Fe1 C7 C6 178.9(7) . . . . ?
C1 Fe1 C7 C6 -66.9(7) . . . . ?
C5 Fe1 C7 C6 -49(2) . . . . ?
C6 C7 C8 C9 0.7(11) . . . . ?
Fe1 C7 C8 C9 59.6(7) . . . . ?
C6 C7 C8 Fe1 -58.9(7) . . . . ?
C2 Fe1 C8 C9 175.8(6) . . . . ?
C10 Fe1 C8 C9 -38.0(6) . . . . ?
C6 Fe1 C8 C9 -82.3(6) . . . . ?
C7 Fe1 C8 C9 -119.5(9) . . . . ?
C3 Fe1 C8 C9 133.1(6) . . . . ?
C4 Fe1 C8 C9 91.1(6) . . . . ?
C1 Fe1 C8 C9 -146.5(16) . . . . ?
C5 Fe1 C8 C9 55.5(10) . . . . ?
C2 Fe1 C8 C7 -64.8(7) . . . . ?
C10 Fe1 C8 C7 81.5(6) . . . . ?
C6 Fe1 C8 C7 37.2(6) . . . . ?
C3 Fe1 C8 C7 -107.4(6) . . . . ?
C9 Fe1 C8 C7 119.5(9) . . . . ?
C4 Fe1 C8 C7 -149.4(6) . . . . ?
C1 Fe1 C8 C7 -27(2) . . . . ?
C5 Fe1 C8 C7 175.0(7) . . . . ?
C7 C8 C9 C10 -1.0(11) . . . . ?
Fe1 C8 C9 C10 57.9(6) . . . . ?
C7 C8 C9 Fe1 -59.0(7) . . . . ?
C2 Fe1 C9 C8 -17(2) . . . . ?
C10 Fe1 C9 C8 119.5(8) . . . . ?
C6 Fe1 C9 C8 81.2(7) . . . . ?
C7 Fe1 C9 C8 37.4(6) . . . . ?
C3 Fe1 C9 C8 -66.9(7) . . . . ?
C4 Fe1 C9 C8 -108.3(6) . . . . ?
C1 Fe1 C9 C8 166.4(7) . . . . ?
C5 Fe1 C9 C8 -153.1(6) . . . . ?
C2 Fe1 C9 C10 -136.1(17) . . . . ?
C6 Fe1 C9 C10 -38.3(6) . . . . ?
C7 Fe1 C9 C10 -82.1(6) . . . . ?
C3 Fe1 C9 C10 173.6(6) . . . . ?
C8 Fe1 C9 C10 -119.5(8) . . . . ?
C4 Fe1 C9 C10 132.2(6) . . . . ?
C1 Fe1 C9 C10 47.0(10) . . . . ?
C5 Fe1 C9 C10 87.4(6) . . . . ?
C7 C6 C10 C9 -0.7(11) . . . . ?
Fe1 C6 C10 C9 -61.0(6) . . . . ?
C7 C6 C10 Fe1 60.3(7) . . . . ?
C8 C9 C10 C6 1.1(10) . . . . ?
Fe1 C9 C10 C6 60.3(6) . . . . ?
C8 C9 C10 Fe1 -59.2(6) . . . . ?
C2 Fe1 C10 C6 46.8(10) . . . . ?
C7 Fe1 C10 C6 -38.2(6) . . . . ?
C3 Fe1 C10 C6 -150(2) . . . . ?
C8 Fe1 C10 C6 -81.6(6) . . . . ?
C9 Fe1 C10 C6 -118.5(8) . . . . ?
C4 Fe1 C10 C6 169.6(6) . . . . ?
C1 Fe1 C10 C6 85.5(6) . . . . ?
C5 Fe1 C10 C6 128.7(6) . . . . ?
C2 Fe1 C10 C9 165.3(7) . . . . ?
C6 Fe1 C10 C9 118.5(8) . . . . ?
C7 Fe1 C10 C9 80.2(6) . . . . ?
C3 Fe1 C10 C9 -32(3) . . . . ?
C8 Fe1 C10 C9 36.9(6) . . . . ?
C4 Fe1 C10 C9 -72.0(7) . . . . ?
C1 Fe1 C10 C9 -156.1(5) . . . . ?
C5 Fe1 C10 C9 -112.8(6) . . . . ?
C13 N1 C11 O1 -0.7(11) . . . . ?
Au2 N1 C11 O1 175.2(6) . . . . ?
C13 N1 C11 C2 -177.3(9) . . . . ?
Au2 N1 C11 C2 -1.3(16) . . . . ?
C12 O1 C11 N1 -2.7(10) . . . . ?
C12 O1 C11 C2 174.5(7) . . . . ?
C1 C2 C11 N1 -9.1(16) . . . . ?
C3 C2 C11 N1 162.0(9) . . . . ?
Fe1 C2 C11 N1 79.3(11) . . . . ?
C1 C2 C11 O1 174.2(8) . . . . ?
C3 C2 C11 O1 -14.7(12) . . . . ?
Fe1 C2 C11 O1 -97.4(8) . . . . ?
C11 O1 C12 C13 4.7(9) . . . . ?
C11 N1 C13 C12 3.6(10) . . . . ?
Au2 N1 C13 C12 -173.2(6) . . . . ?
O1 C12 C13 N1 -4.9(9) . . . . ?
N1 Au2 C14 C15 -151(2) . . . . ?
Au1 Au2 C14 C15 22.5(9) . . . . ?
N1 Au2 C14 C18 19(3) . . . . ?
Au1 Au2 C14 C18 -168.0(7) . . . . ?
N1 Au2 C14 Fe2 111(2) . . . . ?
Au1 Au2 C14 Fe2 -76.3(7) . . . . ?
C20 Fe2 C14 C15 -79.5(6) . . . . ?
C23 Fe2 C14 C15 -161.8(6) . . . . ?
C16 Fe2 C14 C15 37.2(5) . . . . ?
C17 Fe2 C14 C15 80.5(6) . . . . ?
C19 Fe2 C14 C15 -120.6(6) . . . . ?
C22 Fe2 C14 C15 167.4(9) . . . . ?
C21 Fe2 C14 C15 -48.3(13) . . . . ?
C18 Fe2 C14 C15 117.3(8) . . . . ?
C20 Fe2 C14 C18 163.1(6) . . . . ?
C15 Fe2 C14 C18 -117.3(8) . . . . ?
C23 Fe2 C14 C18 80.9(7) . . . . ?
C16 Fe2 C14 C18 -80.1(6) . . . . ?
C17 Fe2 C14 C18 -36.8(5) . . . . ?
C19 Fe2 C14 C18 122.1(6) . . . . ?
C22 Fe2 C14 C18 50.0(12) . . . . ?
C21 Fe2 C14 C18 -165.6(10) . . . . ?
C20 Fe2 C14 Au2 47.4(9) . . . . ?
C15 Fe2 C14 Au2 127.0(10) . . . . ?
C23 Fe2 C14 Au2 -34.8(9) . . . . ?
C16 Fe2 C14 Au2 164.2(8) . . . . ?
C17 Fe2 C14 Au2 -152.5(8) . . . . ?
C19 Fe2 C14 Au2 6.4(8) . . . . ?
C22 Fe2 C14 Au2 -65.6(13) . . . . ?
C21 Fe2 C14 Au2 78.7(14) . . . . ?
C18 Fe2 C14 Au2 -115.7(10) . . . . ?
C18 C14 C15 C16 -0.9(11) . . . . ?
Au2 C14 C15 C16 169.9(7) . . . . ?
Fe2 C14 C15 C16 -59.6(7) . . . . ?
C18 C14 C15 C24 176.9(9) . . . . ?
Au2 C14 C15 C24 -12.2(15) . . . . ?
Fe2 C14 C15 C24 118.2(10) . . . . ?
C18 C14 C15 Fe2 58.7(6) . . . . ?
Au2 C14 C15 Fe2 -130.4(8) . . . . ?
C20 Fe2 C15 C16 -119.0(6) . . . . ?
C23 Fe2 C15 C16 165.8(10) . . . . ?
C17 Fe2 C15 C16 38.2(5) . . . . ?
C19 Fe2 C15 C16 -161.2(6) . . . . ?
C22 Fe2 C15 C16 -44.1(15) . . . . ?
C21 Fe2 C15 C16 -76.7(7) . . . . ?
C18 Fe2 C15 C16 82.2(6) . . . . ?
C14 Fe2 C15 C16 120.9(8) . . . . ?
C20 Fe2 C15 C14 120.1(6) . . . . ?
C23 Fe2 C15 C14 44.9(13) . . . . ?
C16 Fe2 C15 C14 -120.9(8) . . . . ?
C17 Fe2 C15 C14 -82.7(6) . . . . ?
C19 Fe2 C15 C14 77.9(7) . . . . ?
C22 Fe2 C15 C14 -165.0(11) . . . . ?
C21 Fe2 C15 C14 162.4(5) . . . . ?
C18 Fe2 C15 C14 -38.7(5) . . . . ?
C20 Fe2 C15 C24 -4.8(9) . . . . ?
C23 Fe2 C15 C24 -80.1(14) . . . . ?
C16 Fe2 C15 C24 114.2(10) . . . . ?
C17 Fe2 C15 C24 152.4(9) . . . . ?
C19 Fe2 C15 C24 -47.0(9) . . . . ?
C22 Fe2 C15 C24 70.1(15) . . . . ?
C21 Fe2 C15 C24 37.5(9) . . . . ?
C18 Fe2 C15 C24 -163.6(9) . . . . ?
C14 Fe2 C15 C24 -124.9(10) . . . . ?
C14 C15 C16 C17 0.9(11) . . . . ?
C24 C15 C16 C17 -177.1(8) . . . . ?
Fe2 C15 C16 C17 -60.0(6) . . . . ?
C14 C15 C16 Fe2 60.9(7) . . . . ?
C24 C15 C16 Fe2 -117.2(9) . . . . ?
C20 Fe2 C16 C17 -161.6(6) . . . . ?
C15 Fe2 C16 C17 117.7(8) . . . . ?
C23 Fe2 C16 C17 -47.0(14) . . . . ?
C19 Fe2 C16 C17 166.0(10) . . . . ?
C22 Fe2 C16 C17 -78.2(7) . . . . ?
C21 Fe2 C16 C17 -119.5(6) . . . . ?
C18 Fe2 C16 C17 37.3(5) . . . . ?
C14 Fe2 C16 C17 80.9(6) . . . . ?
C20 Fe2 C16 C15 80.8(7) . . . . ?
C23 Fe2 C16 C15 -164.6(11) . . . . ?
C17 Fe2 C16 C15 -117.7(8) . . . . ?
C19 Fe2 C16 C15 48.3(13) . . . . ?
C22 Fe2 C16 C15 164.2(6) . . . . ?
C21 Fe2 C16 C15 122.9(6) . . . . ?
C18 Fe2 C16 C15 -80.3(6) . . . . ?
C14 Fe2 C16 C15 -36.7(6) . . . . ?
C15 C16 C17 C18 -0.5(10) . . . . ?
Fe2 C16 C17 C18 -59.7(6) . . . . ?
C15 C16 C17 Fe2 59.1(6) . . . . ?
C20 Fe2 C17 C16 46.2(13) . . . . ?
C15 Fe2 C17 C16 -39.1(5) . . . . ?
C23 Fe2 C17 C16 162.0(6) . . . . ?
C19 Fe2 C17 C16 -165.3(10) . . . . ?
C22 Fe2 C17 C16 120.9(6) . . . . ?
C21 Fe2 C17 C16 79.0(6) . . . . ?
C18 Fe2 C17 C16 -120.0(8) . . . . ?
C14 Fe2 C17 C16 -83.2(6) . . . . ?
C20 Fe2 C17 C18 166.2(10) . . . . ?
C15 Fe2 C17 C18 80.9(6) . . . . ?
C23 Fe2 C17 C18 -78.0(7) . . . . ?
C16 Fe2 C17 C18 120.0(8) . . . . ?
C19 Fe2 C17 C18 -45.3(13) . . . . ?
C22 Fe2 C17 C18 -119.1(6) . . . . ?
C21 Fe2 C17 C18 -161.1(6) . . . . ?
C14 Fe2 C17 C18 36.8(5) . . . . ?
C16 C17 C18 C14 -0.1(11) . . . . ?
Fe2 C17 C18 C14 -59.3(7) . . . . ?
C16 C17 C18 Fe2 59.3(7) . . . . ?
C15 C14 C18 C17 0.6(10) . . . . ?
Au2 C14 C18 C17 -171.3(6) . . . . ?
Fe2 C14 C18 C17 58.2(6) . . . . ?
C15 C14 C18 Fe2 -57.6(6) . . . . ?
Au2 C14 C18 Fe2 130.4(7) . . . . ?
C20 Fe2 C18 C17 -165.3(11) . . . . ?
C15 Fe2 C18 C17 -81.9(6) . . . . ?
C23 Fe2 C18 C17 121.4(6) . . . . ?
C16 Fe2 C18 C17 -37.1(5) . . . . ?
C19 Fe2 C18 C17 162.8(6) . . . . ?
C22 Fe2 C18 C17 79.9(7) . . . . ?
C21 Fe2 C18 C17 46.6(12) . . . . ?
C14 Fe2 C18 C17 -120.8(8) . . . . ?
C20 Fe2 C18 C14 -44.5(14) . . . . ?
C15 Fe2 C18 C14 38.9(5) . . . . ?
C23 Fe2 C18 C14 -117.8(6) . . . . ?
C16 Fe2 C18 C14 83.7(6) . . . . ?
C17 Fe2 C18 C14 120.8(8) . . . . ?
C19 Fe2 C18 C14 -76.4(7) . . . . ?
C22 Fe2 C18 C14 -159.3(6) . . . . ?
C21 Fe2 C18 C14 167.4(9) . . . . ?
C20 Fe2 C19 C23 118.5(9) . . . . ?
C15 Fe2 C19 C23 -161.3(6) . . . . ?
C16 Fe2 C19 C23 162.8(10) . . . . ?
C17 Fe2 C19 C23 -44.2(14) . . . . ?
C22 Fe2 C19 C23 37.0(6) . . . . ?
C21 Fe2 C19 C23 80.6(6) . . . . ?
C18 Fe2 C19 C23 -77.9(7) . . . . ?
C14 Fe2 C19 C23 -119.4(6) . . . . ?
C15 Fe2 C19 C20 80.1(7) . . . . ?
C23 Fe2 C19 C20 -118.5(9) . . . . ?
C16 Fe2 C19 C20 44.2(13) . . . . ?
C17 Fe2 C19 C20 -162.7(10) . . . . ?
C22 Fe2 C19 C20 -81.5(6) . . . . ?
C21 Fe2 C19 C20 -37.9(6) . . . . ?
C18 Fe2 C19 C20 163.5(6) . . . . ?
C14 Fe2 C19 C20 122.1(6) . . . . ?
C23 C19 C20 C21 1.9(12) . . . . ?
Fe2 C19 C20 C21 61.1(7) . . . . ?
C23 C19 C20 Fe2 -59.2(7) . . . . ?
C15 Fe2 C20 C19 -118.9(6) . . . . ?
C23 Fe2 C20 C19 37.8(6) . . . . ?
C16 Fe2 C20 C19 -162.4(6) . . . . ?
C17 Fe2 C20 C19 163.7(10) . . . . ?
C22 Fe2 C20 C19 81.1(6) . . . . ?
C21 Fe2 C20 C19 119.2(9) . . . . ?
C18 Fe2 C20 C19 -43.0(14) . . . . ?
C14 Fe2 C20 C19 -76.2(7) . . . . ?
C15 Fe2 C20 C21 121.9(6) . . . . ?
C23 Fe2 C20 C21 -81.4(6) . . . . ?
C16 Fe2 C20 C21 78.4(7) . . . . ?
C17 Fe2 C20 C21 44.5(13) . . . . ?
C19 Fe2 C20 C21 -119.2(9) . . . . ?
C22 Fe2 C20 C21 -38.1(6) . . . . ?
C18 Fe2 C20 C21 -162.2(10) . . . . ?
C14 Fe2 C20 C21 164.6(6) . . . . ?
C19 C20 C21 C22 -1.5(11) . . . . ?
Fe2 C20 C21 C22 59.7(7) . . . . ?
C19 C20 C21 Fe2 -61.1(7) . . . . ?
C20 Fe2 C21 C22 -117.9(9) . . . . ?
C15 Fe2 C21 C22 164.2(6) . . . . ?
C23 Fe2 C21 C22 -37.1(6) . . . . ?
C16 Fe2 C21 C22 121.7(6) . . . . ?
C17 Fe2 C21 C22 79.9(7) . . . . ?
C19 Fe2 C21 C22 -80.4(6) . . . . ?
C18 Fe2 C21 C22 45.9(13) . . . . ?
C14 Fe2 C21 C22 -159.5(10) . . . . ?
C15 Fe2 C21 C20 -77.9(7) . . . . ?
C23 Fe2 C21 C20 80.8(6) . . . . ?
C16 Fe2 C21 C20 -120.4(6) . . . . ?
C17 Fe2 C21 C20 -162.2(6) . . . . ?
C19 Fe2 C21 C20 37.5(6) . . . . ?
C22 Fe2 C21 C20 117.9(9) . . . . ?
C18 Fe2 C21 C20 163.8(9) . . . . ?
C14 Fe2 C21 C20 -41.6(14) . . . . ?
C20 C21 C22 C23 0.4(11) . . . . ?
Fe2 C21 C22 C23 59.1(7) . . . . ?
C20 C21 C22 Fe2 -58.7(7) . . . . ?
C20 Fe2 C22 C23 -80.9(7) . . . . ?
C15 Fe2 C22 C23 -162.9(11) . . . . ?
C16 Fe2 C22 C23 163.5(6) . . . . ?
C17 Fe2 C22 C23 121.7(6) . . . . ?
C19 Fe2 C22 C23 -37.2(6) . . . . ?
C21 Fe2 C22 C23 -119.6(9) . . . . ?
C18 Fe2 C22 C23 79.2(7) . . . . ?
C14 Fe2 C22 C23 42.9(13) . . . . ?
C20 Fe2 C22 C21 38.6(6) . . . . ?
C15 Fe2 C22 C21 -43.4(15) . . . . ?
C23 Fe2 C22 C21 119.6(9) . . . . ?
C16 Fe2 C22 C21 -76.9(7) . . . . ?
C17 Fe2 C22 C21 -118.8(6) . . . . ?
C19 Fe2 C22 C21 82.4(6) . . . . ?
C18 Fe2 C22 C21 -161.2(6) . . . . ?
C14 Fe2 C22 C21 162.5(9) . . . . ?
C21 C22 C23 C19 0.8(11) . . . . ?
Fe2 C22 C23 C19 60.3(7) . . . . ?
C21 C22 C23 Fe2 -59.5(7) . . . . ?
C20 C19 C23 C22 -1.7(12) . . . . ?
Fe2 C19 C23 C22 -60.3(7) . . . . ?
C20 C19 C23 Fe2 58.7(7) . . . . ?
C20 Fe2 C23 C22 81.7(7) . . . . ?
C15 Fe2 C23 C22 165.3(10) . . . . ?
C16 Fe2 C23 C22 -42.4(14) . . . . ?
C17 Fe2 C23 C22 -77.2(7) . . . . ?
C19 Fe2 C23 C22 119.7(9) . . . . ?
C21 Fe2 C23 C22 37.4(6) . . . . ?
C18 Fe2 C23 C22 -119.3(6) . . . . ?
C14 Fe2 C23 C22 -161.9(6) . . . . ?
C20 Fe2 C23 C19 -38.0(6) . . . . ?
C15 Fe2 C23 C19 45.5(14) . . . . ?
C16 Fe2 C23 C19 -162.1(10) . . . . ?
C17 Fe2 C23 C19 163.1(6) . . . . ?
C22 Fe2 C23 C19 -119.7(9) . . . . ?
C21 Fe2 C23 C19 -82.3(7) . . . . ?
C18 Fe2 C23 C19 120.9(6) . . . . ?
C14 Fe2 C23 C19 78.4(7) . . . . ?
C26 N2 C24 O2 0.2(11) . . . . ?
Au1 N2 C24 O2 175.1(6) . . . . ?
C26 N2 C24 C15 -178.1(10) . . . . ?
Au1 N2 C24 C15 -3.2(16) . . . . ?
C25 O2 C24 N2 6.4(11) . . . . ?
C25 O2 C24 C15 -175.0(8) . . . . ?
C16 C15 C24 N2 172.8(9) . . . . ?
C14 C15 C24 N2 -4.9(17) . . . . ?
Fe2 C15 C24 N2 88.0(12) . . . . ?
C16 C15 C24 O2 -5.5(13) . . . . ?
C14 C15 C24 O2 176.8(9) . . . . ?
Fe2 C15 C24 O2 -90.3(9) . . . . ?
C24 O2 C25 C26 -9.7(9) . . . . ?
C24 N2 C26 C25 -6.3(10) . . . . ?
Au1 N2 C26 C25 177.7(6) . . . . ?
O2 C25 C26 N2 9.5(9) . . . . ?
N4 Au3 C27 C31 -18(2) . . . . ?
Au4 Au3 C27 C31 -157.2(7) . . . . ?
Au1 Au3 C27 C31 105.1(7) . . . . ?
N4 Au3 C27 C28 157.4(15) . . . . ?
Au4 Au3 C27 C28 18.2(8) . . . . ?
Au1 Au3 C27 C28 -79.5(8) . . . . ?
N4 Au3 C27 Fe3 68(2) . . . . ?
Au4 Au3 C27 Fe3 -70.7(5) . . . . ?
Au1 Au3 C27 Fe3 -168.4(4) . . . . ?
C28 Fe3 C27 C31 -117.7(7) . . . . ?
C29 Fe3 C27 C31 -79.5(6) . . . . ?
C34 Fe3 C27 C31 52(3) . . . . ?
C33 Fe3 C27 C31 71.7(7) . . . . ?
C36 Fe3 C27 C31 152.2(5) . . . . ?
C32 Fe3 C27 C31 109.7(6) . . . . ?
C30 Fe3 C27 C31 -36.0(5) . . . . ?
C35 Fe3 C27 C31 -174.3(6) . . . . ?
C29 Fe3 C27 C28 38.3(5) . . . . ?
C34 Fe3 C27 C28 170(2) . . . . ?
C33 Fe3 C27 C28 -170.6(5) . . . . ?
C36 Fe3 C27 C28 -90.0(6) . . . . ?
C32 Fe3 C27 C28 -132.6(5) . . . . ?
C30 Fe3 C27 C28 81.8(5) . . . . ?
C35 Fe3 C27 C28 -56.6(8) . . . . ?
C31 Fe3 C27 C28 117.7(7) . . . . ?
C28 Fe3 C27 Au3 125.8(8) . . . . ?
C29 Fe3 C27 Au3 164.1(6) . . . . ?
C34 Fe3 C27 Au3 -64(3) . . . . ?
C33 Fe3 C27 Au3 -44.8(7) . . . . ?
C36 Fe3 C27 Au3 35.7(6) . . . . ?
C32 Fe3 C27 Au3 -6.8(6) . . . . ?
C30 Fe3 C27 Au3 -152.5(6) . . . . ?
C35 Fe3 C27 Au3 69.2(8) . . . . ?
C31 Fe3 C27 Au3 -116.5(7) . . . . ?
C31 C27 C28 C29 -0.6(10) . . . . ?
Au3 C27 C28 C29 -176.5(6) . . . . ?
Fe3 C27 C28 C29 -59.9(6) . . . . ?
C31 C27 C28 C37 175.3(9) . . . . ?
Au3 C27 C28 C37 -0.6(15) . . . . ?
Fe3 C27 C28 C37 116.0(10) . . . . ?
C31 C27 C28 Fe3 59.3(6) . . . . ?
Au3 C27 C28 Fe3 -116.7(7) . . . . ?
C29 Fe3 C28 C27 -119.5(7) . . . . ?
C34 Fe3 C28 C27 -177.2(7) . . . . ?
C33 Fe3 C28 C27 43(2) . . . . ?
C36 Fe3 C28 C27 106.7(5) . . . . ?
C32 Fe3 C28 C27 67.6(7) . . . . ?
C30 Fe3 C28 C27 -82.0(5) . . . . ?
C35 Fe3 C28 C27 149.4(5) . . . . ?
C31 Fe3 C28 C27 -38.2(5) . . . . ?
C34 Fe3 C28 C29 -57.7(9) . . . . ?
C33 Fe3 C28 C29 162(2) . . . . ?
C36 Fe3 C28 C29 -133.8(5) . . . . ?
C32 Fe3 C28 C29 -172.9(5) . . . . ?
C30 Fe3 C28 C29 37.5(5) . . . . ?
C35 Fe3 C28 C29 -91.1(6) . . . . ?
C31 Fe3 C28 C29 81.3(6) . . . . ?
C27 Fe3 C28 C29 119.5(7) . . . . ?
C29 Fe3 C28 C37 113.1(9) . . . . ?
C34 Fe3 C28 C37 55.5(11) . . . . ?
C33 Fe3 C28 C37 -85(2) . . . . ?
C36 Fe3 C28 C37 -20.7(8) . . . . ?
C32 Fe3 C28 C37 -59.8(9) . . . . ?
C30 Fe3 C28 C37 150.7(8) . . . . ?
C35 Fe3 C28 C37 22.0(8) . . . . ?
C31 Fe3 C28 C37 -165.6(8) . . . . ?
C27 Fe3 C28 C37 -127.3(9) . . . . ?
C27 C28 C29 C30 1.8(10) . . . . ?
C37 C28 C29 C30 -174.6(8) . . . . ?
Fe3 C28 C29 C30 -59.4(6) . . . . ?
C27 C28 C29 Fe3 61.2(6) . . . . ?
C37 C28 C29 Fe3 -115.3(8) . . . . ?
C28 Fe3 C29 C30 118.9(8) . . . . ?
C34 Fe3 C29 C30 -91.4(6) . . . . ?
C33 Fe3 C29 C30 -55.0(10) . . . . ?
C36 Fe3 C29 C30 -173.3(6) . . . . ?
C32 Fe3 C29 C30 155(2) . . . . ?
C35 Fe3 C29 C30 -134.2(6) . . . . ?
C31 Fe3 C29 C30 38.1(5) . . . . ?
C27 Fe3 C29 C30 81.4(6) . . . . ?
C34 Fe3 C29 C28 149.7(5) . . . . ?
C33 Fe3 C29 C28 -173.9(7) . . . . ?
C36 Fe3 C29 C28 67.8(7) . . . . ?
C32 Fe3 C29 C28 36(3) . . . . ?
C30 Fe3 C29 C28 -118.9(8) . . . . ?
C35 Fe3 C29 C28 106.9(6) . . . . ?
C31 Fe3 C29 C28 -80.8(5) . . . . ?
C27 Fe3 C29 C28 -37.5(5) . . . . ?
C28 C29 C30 C31 -2.3(10) . . . . ?
Fe3 C29 C30 C31 -60.7(6) . . . . ?
C28 C29 C30 Fe3 58.4(6) . . . . ?
C28 Fe3 C30 C29 -38.7(5) . . . . ?
C34 Fe3 C30 C29 106.5(6) . . . . ?
C33 Fe3 C30 C29 151.0(6) . . . . ?
C36 Fe3 C30 C29 36(3) . . . . ?
C32 Fe3 C30 C29 -173.0(6) . . . . ?
C35 Fe3 C30 C29 67.3(7) . . . . ?
C31 Fe3 C30 C29 -118.4(8) . . . . ?
C27 Fe3 C30 C29 -82.7(6) . . . . ?
C28 Fe3 C30 C31 79.7(5) . . . . ?
C29 Fe3 C30 C31 118.4(8) . . . . ?
C34 Fe3 C30 C31 -135.1(5) . . . . ?
C33 Fe3 C30 C31 -90.6(6) . . . . ?
C36 Fe3 C30 C31 154(2) . . . . ?
C32 Fe3 C30 C31 -54.6(9) . . . . ?
C35 Fe3 C30 C31 -174.2(5) . . . . ?
C27 Fe3 C30 C31 35.7(5) . . . . ?
C29 C30 C31 C27 2.0(10) . . . . ?
Fe3 C30 C31 C27 -57.8(6) . . . . ?
C29 C30 C31 Fe3 59.8(6) . . . . ?
C28 C27 C31 C30 -0.9(10) . . . . ?
Au3 C27 C31 C30 175.5(6) . . . . ?
Fe3 C27 C31 C30 56.9(6) . . . . ?
C28 C27 C31 Fe3 -57.8(6) . . . . ?
Au3 C27 C31 Fe3 118.6(6) . . . . ?
C28 Fe3 C31 C30 -83.6(6) . . . . ?
C29 Fe3 C31 C30 -38.1(5) . . . . ?
C34 Fe3 C31 C30 67.0(7) . . . . ?
C33 Fe3 C31 C30 107.6(6) . . . . ?
C36 Fe3 C31 C30 -173.3(7) . . . . ?
C32 Fe3 C31 C30 150.8(5) . . . . ?
C35 Fe3 C31 C30 33(3) . . . . ?
C27 Fe3 C31 C30 -122.4(7) . . . . ?
C28 Fe3 C31 C27 38.9(5) . . . . ?
C29 Fe3 C31 C27 84.3(5) . . . . ?
C34 Fe3 C31 C27 -170.5(5) . . . . ?
C33 Fe3 C31 C27 -130.0(5) . . . . ?
C36 Fe3 C31 C27 -50.8(9) . . . . ?
C32 Fe3 C31 C27 -86.7(6) . . . . ?
C30 Fe3 C31 C27 122.4(7) . . . . ?
C35 Fe3 C31 C27 156(3) . . . . ?
C28 Fe3 C32 C33 -173.1(6) . . . . ?
C29 Fe3 C32 C33 155(2) . . . . ?
C34 Fe3 C32 C33 38.6(6) . . . . ?
C36 Fe3 C32 C33 118.8(8) . . . . ?
C30 Fe3 C32 C33 -54.8(9) . . . . ?
C35 Fe3 C32 C33 81.7(6) . . . . ?
C31 Fe3 C32 C33 -91.0(6) . . . . ?
C27 Fe3 C32 C33 -133.6(6) . . . . ?
C28 Fe3 C32 C36 68.1(7) . . . . ?
C29 Fe3 C32 C36 37(3) . . . . ?
C34 Fe3 C32 C36 -80.3(6) . . . . ?
C33 Fe3 C32 C36 -118.8(8) . . . . ?
C30 Fe3 C32 C36 -173.7(7) . . . . ?
C35 Fe3 C32 C36 -37.2(6) . . . . ?
C31 Fe3 C32 C36 150.2(6) . . . . ?
C27 Fe3 C32 C36 107.6(6) . . . . ?
C36 C32 C33 C34 0.3(11) . . . . ?
Fe3 C32 C33 C34 -59.5(6) . . . . ?
C36 C32 C33 Fe3 59.8(7) . . . . ?
C28 Fe3 C33 C32 30(2) . . . . ?
C29 Fe3 C33 C32 -172.9(7) . . . . ?
C34 Fe3 C33 C32 -118.6(9) . . . . ?
C36 Fe3 C33 C32 -37.8(6) . . . . ?
C30 Fe3 C33 C32 150.6(6) . . . . ?
C35 Fe3 C33 C32 -81.3(6) . . . . ?
C31 Fe3 C33 C32 106.7(6) . . . . ?
C27 Fe3 C33 C32 65.8(7) . . . . ?
C28 Fe3 C33 C34 148(2) . . . . ?
C29 Fe3 C33 C34 -54.3(10) . . . . ?
C36 Fe3 C33 C34 80.8(6) . . . . ?
C32 Fe3 C33 C34 118.6(9) . . . . ?
C30 Fe3 C33 C34 -90.9(7) . . . . ?
C35 Fe3 C33 C34 37.3(6) . . . . ?
C31 Fe3 C33 C34 -134.8(6) . . . . ?
C27 Fe3 C33 C34 -175.6(6) . . . . ?
C32 C33 C34 C35 -0.3(11) . . . . ?
Fe3 C33 C34 C35 -60.2(7) . . . . ?
C32 C33 C34 Fe3 59.9(6) . . . . ?
C28 Fe3 C34 C35 -50.9(10) . . . . ?
C29 Fe3 C34 C35 -89.8(6) . . . . ?
C33 Fe3 C34 C35 118.8(9) . . . . ?
C36 Fe3 C34 C35 37.6(6) . . . . ?
C32 Fe3 C34 C35 81.2(6) . . . . ?
C30 Fe3 C34 C35 -133.7(6) . . . . ?
C31 Fe3 C34 C35 -173.4(6) . . . . ?
C27 Fe3 C34 C35 141(2) . . . . ?
C28 Fe3 C34 C33 -169.7(7) . . . . ?
C29 Fe3 C34 C33 151.4(6) . . . . ?
C36 Fe3 C34 C33 -81.2(6) . . . . ?
C32 Fe3 C34 C33 -37.6(6) . . . . ?
C30 Fe3 C34 C33 107.5(6) . . . . ?
C35 Fe3 C34 C33 -118.8(9) . . . . ?
C31 Fe3 C34 C33 67.9(8) . . . . ?
C27 Fe3 C34 C33 23(3) . . . . ?
C33 C34 C35 C36 0.1(11) . . . . ?
Fe3 C34 C35 C36 -59.5(7) . . . . ?
C33 C34 C35 Fe3 59.6(6) . . . . ?
C28 Fe3 C35 C34 152.4(6) . . . . ?
C29 Fe3 C35 C34 107.3(6) . . . . ?
C33 Fe3 C35 C34 -38.5(6) . . . . ?
C36 Fe3 C35 C34 -119.1(9) . . . . ?
C32 Fe3 C35 C34 -81.9(6) . . . . ?
C30 Fe3 C35 C34 67.7(7) . . . . ?
C31 Fe3 C35 C34 38(3) . . . . ?
C27 Fe3 C35 C34 -170.2(6) . . . . ?
C28 Fe3 C35 C36 -88.4(6) . . . . ?
C29 Fe3 C35 C36 -133.5(6) . . . . ?
C34 Fe3 C35 C36 119.1(9) . . . . ?
C33 Fe3 C35 C36 80.6(6) . . . . ?
C32 Fe3 C35 C36 37.2(6) . . . . ?
C30 Fe3 C35 C36 -173.1(6) . . . . ?
C31 Fe3 C35 C36 158(3) . . . . ?
C27 Fe3 C35 C36 -51.1(9) . . . . ?
C34 C35 C36 C32 0.0(11) . . . . ?
Fe3 C35 C36 C32 -59.4(7) . . . . ?
C34 C35 C36 Fe3 59.5(7) . . . . ?
C33 C32 C36 C35 -0.2(11) . . . . ?
Fe3 C32 C36 C35 59.6(7) . . . . ?
C33 C32 C36 Fe3 -59.8(7) . . . . ?
C28 Fe3 C36 C35 108.2(6) . . . . ?
C29 Fe3 C36 C35 67.5(8) . . . . ?
C34 Fe3 C36 C35 -37.3(6) . . . . ?
C33 Fe3 C36 C35 -82.1(6) . . . . ?
C32 Fe3 C36 C35 -119.8(9) . . . . ?
C30 Fe3 C36 C35 37(3) . . . . ?
C31 Fe3 C36 C35 -174.6(6) . . . . ?
C27 Fe3 C36 C35 151.9(6) . . . . ?
C28 Fe3 C36 C32 -132.0(6) . . . . ?
C29 Fe3 C36 C32 -172.7(6) . . . . ?
C34 Fe3 C36 C32 82.5(6) . . . . ?
C33 Fe3 C36 C32 37.7(6) . . . . ?
C30 Fe3 C36 C32 156(2) . . . . ?
C35 Fe3 C36 C32 119.8(9) . . . . ?
C31 Fe3 C36 C32 -54.9(9) . . . . ?
C27 Fe3 C36 C32 -88.3(6) . . . . ?
C39 N3 C37 O3 -0.1(11) . . . . ?
Au4 N3 C37 O3 173.4(6) . . . . ?
C39 N3 C37 C28 177.7(9) . . . . ?
Au4 N3 C37 C28 -8.8(16) . . . . ?
C38 O3 C37 N3 -7.7(11) . . . . ?
C38 O3 C37 C28 174.1(8) . . . . ?
C27 C28 C37 N3 -12.3(17) . . . . ?
C29 C28 C37 N3 163.3(9) . . . . ?
Fe3 C28 C37 N3 80.2(12) . . . . ?
C27 C28 C37 O3 165.6(8) . . . . ?
C29 C28 C37 O3 -18.8(12) . . . . ?
Fe3 C28 C37 O3 -101.9(8) . . . . ?
C37 O3 C38 C39 11.3(9) . . . . ?
C37 N3 C39 C38 7.4(10) . . . . ?
Au4 N3 C39 C38 -167.4(5) . . . . ?
O3 C38 C39 N3 -11.0(9) . . . . ?
N3 Au4 C40 C44 5(3) . . . . ?
Au3 Au4 C40 C44 -171.3(7) . . . . ?
N3 Au4 C40 C41 -170.2(18) . . . . ?
Au3 Au4 C40 C41 13.1(9) . . . . ?
N3 Au4 C40 Fe4 94(2) . . . . ?
Au3 Au4 C40 Fe4 -82.8(6) . . . . ?
C42 Fe4 C40 C44 -80.4(6) . . . . ?
C47 Fe4 C40 C44 -167.2(7) . . . . ?
C43 Fe4 C40 C44 -37.1(5) . . . . ?
C48 Fe4 C40 C44 38.0(16) . . . . ?
C49 Fe4 C40 C44 72.8(7) . . . . ?
C41 Fe4 C40 C44 -119.0(8) . . . . ?
C46 Fe4 C40 C44 157.0(5) . . . . ?
C45 Fe4 C40 C44 113.7(6) . . . . ?
C42 Fe4 C40 C41 38.6(5) . . . . ?
C47 Fe4 C40 C41 -48.2(10) . . . . ?
C43 Fe4 C40 C41 81.9(5) . . . . ?
C48 Fe4 C40 C41 156.9(13) . . . . ?
C49 Fe4 C40 C41 -168.2(5) . . . . ?
C46 Fe4 C40 C41 -84.1(6) . . . . ?
C45 Fe4 C40 C41 -127.3(5) . . . . ?
C44 Fe4 C40 C41 119.0(8) . . . . ?
C42 Fe4 C40 Au4 165.5(7) . . . . ?
C47 Fe4 C40 Au4 78.7(10) . . . . ?
C43 Fe4 C40 Au4 -151.3(7) . . . . ?
C48 Fe4 C40 Au4 -76.2(16) . . . . ?
C49 Fe4 C40 Au4 -41.4(8) . . . . ?
C41 Fe4 C40 Au4 126.9(9) . . . . ?
C46 Fe4 C40 Au4 42.8(7) . . . . ?
C45 Fe4 C40 Au4 -0.5(7) . . . . ?
C44 Fe4 C40 Au4 -114.2(8) . . . . ?
C44 C40 C41 C50 -178.1(9) . . . . ?
Au4 C40 C41 C50 -2.0(15) . . . . ?
Fe4 C40 C41 C50 123.7(10) . . . . ?
C44 C40 C41 C42 -0.9(10) . . . . ?
Au4 C40 C41 C42 175.1(7) . . . . ?
Fe4 C40 C41 C42 -59.1(6) . . . . ?
C44 C40 C41 Fe4 58.2(6) . . . . ?
Au4 C40 C41 Fe4 -125.8(8) . . . . ?
C42 Fe4 C41 C50 115.7(11) . . . . ?
C47 Fe4 C41 C50 31.5(10) . . . . ?
C43 Fe4 C41 C50 152.2(9) . . . . ?
C48 Fe4 C41 C50 65.9(12) . . . . ?
C49 Fe4 C41 C50 -84.4(19) . . . . ?
C46 Fe4 C41 C50 -11.9(9) . . . . ?
C45 Fe4 C41 C50 -52.5(10) . . . . ?
C44 Fe4 C41 C50 -163.7(9) . . . . ?
C40 Fe4 C41 C50 -126.6(11) . . . . ?
C47 Fe4 C41 C42 -84.2(6) . . . . ?
C43 Fe4 C41 C42 36.5(5) . . . . ?
C48 Fe4 C41 C42 -49.7(10) . . . . ?
C49 Fe4 C41 C42 159.9(15) . . . . ?
C46 Fe4 C41 C42 -127.6(6) . . . . ?
C45 Fe4 C41 C42 -168.2(5) . . . . ?
C44 Fe4 C41 C42 80.6(6) . . . . ?
C40 Fe4 C41 C42 117.7(8) . . . . ?
C42 Fe4 C41 C40 -117.7(8) . . . . ?
C47 Fe4 C41 C40 158.1(5) . . . . ?
C43 Fe4 C41 C40 -81.2(6) . . . . ?
C48 Fe4 C41 C40 -167.5(7) . . . . ?
C49 Fe4 C41 C40 42.1(18) . . . . ?
C46 Fe4 C41 C40 114.7(5) . . . . ?
C45 Fe4 C41 C40 74.1(7) . . . . ?
C44 Fe4 C41 C40 -37.1(5) . . . . ?
C50 C41 C42 C43 178.1(8) . . . . ?
C40 C41 C42 C43 0.7(10) . . . . ?
Fe4 C41 C42 C43 -60.2(6) . . . . ?
C50 C41 C42 Fe4 -121.7(9) . . . . ?
C40 C41 C42 Fe4 60.9(6) . . . . ?
C47 Fe4 C42 C43 -125.7(5) . . . . ?
C48 Fe4 C42 C43 -83.3(6) . . . . ?
C49 Fe4 C42 C43 -49.4(10) . . . . ?
C41 Fe4 C42 C43 120.5(8) . . . . ?
C46 Fe4 C42 C43 -166.4(5) . . . . ?
C45 Fe4 C42 C43 164.2(14) . . . . ?
C44 Fe4 C42 C43 38.6(5) . . . . ?
C40 Fe4 C42 C43 81.7(5) . . . . ?
C47 Fe4 C42 C41 113.7(6) . . . . ?
C43 Fe4 C42 C41 -120.5(8) . . . . ?
C48 Fe4 C42 C41 156.1(5) . . . . ?
C49 Fe4 C42 C41 -169.9(7) . . . . ?
C46 Fe4 C42 C41 73.0(7) . . . . ?
C45 Fe4 C42 C41 43.7(17) . . . . ?
C44 Fe4 C42 C41 -81.9(6) . . . . ?
C40 Fe4 C42 C41 -38.9(5) . . . . ?
C41 C42 C43 C44 -0.3(10) . . . . ?
Fe4 C42 C43 C44 -60.3(6) . . . . ?
C41 C42 C43 Fe4 60.1(6) . . . . ?
C47 Fe4 C43 C42 73.5(6) . . . . ?
C48 Fe4 C43 C42 113.4(5) . . . . ?
C49 Fe4 C43 C42 155.9(5) . . . . ?
C41 Fe4 C43 C42 -37.3(5) . . . . ?
C46 Fe4 C43 C42 44.8(15) . . . . ?
C45 Fe4 C43 C42 -172.1(7) . . . . ?
C44 Fe4 C43 C42 -118.0(7) . . . . ?
C40 Fe4 C43 C42 -81.8(5) . . . . ?
C42 Fe4 C43 C44 118.0(7) . . . . ?
C47 Fe4 C43 C44 -168.5(5) . . . . ?
C48 Fe4 C43 C44 -128.6(5) . . . . ?
C49 Fe4 C43 C44 -86.1(6) . . . . ?
C41 Fe4 C43 C44 80.7(5) . . . . ?
C46 Fe4 C43 C44 162.8(12) . . . . ?
C45 Fe4 C43 C44 -54.1(9) . . . . ?
C40 Fe4 C43 C44 36.2(5) . . . . ?
C41 C40 C44 C43 0.8(10) . . . . ?
Au4 C40 C44 C43 -175.7(6) . . . . ?
Fe4 C40 C44 C43 58.3(6) . . . . ?
C41 C40 C44 Fe4 -57.5(6) . . . . ?
Au4 C40 C44 Fe4 126.0(6) . . . . ?
C42 C43 C44 C40 -0.4(10) . . . . ?
Fe4 C43 C44 C40 -59.8(6) . . . . ?
C42 C43 C44 Fe4 59.5(6) . . . . ?
C42 Fe4 C44 C40 82.9(6) . . . . ?
C47 Fe4 C44 C40 158.4(12) . . . . ?
C43 Fe4 C44 C40 120.9(7) . . . . ?
C48 Fe4 C44 C40 -168.4(5) . . . . ?
C49 Fe4 C44 C40 -127.1(5) . . . . ?
C41 Fe4 C44 C40 38.5(5) . . . . ?
C46 Fe4 C44 C40 -49.2(10) . . . . ?
C45 Fe4 C44 C40 -84.6(6) . . . . ?
C42 Fe4 C44 C43 -38.0(5) . . . . ?
C47 Fe4 C44 C43 37.5(16) . . . . ?
C48 Fe4 C44 C43 70.8(6) . . . . ?
C49 Fe4 C44 C43 112.1(5) . . . . ?
C41 Fe4 C44 C43 -82.4(5) . . . . ?
C46 Fe4 C44 C43 -170.0(7) . . . . ?
C45 Fe4 C44 C43 154.6(5) . . . . ?
C40 Fe4 C44 C43 -120.9(7) . . . . ?
C42 Fe4 C45 C49 156.0(14) . . . . ?
C47 Fe4 C45 C49 81.3(6) . . . . ?
C43 Fe4 C45 C49 -46.4(10) . . . . ?
C48 Fe4 C45 C49 37.8(5) . . . . ?
C41 Fe4 C45 C49 -168.6(6) . . . . ?
C46 Fe4 C45 C49 119.6(8) . . . . ?
C44 Fe4 C45 C49 -84.0(6) . . . . ?
C40 Fe4 C45 C49 -126.4(6) . . . . ?
C42 Fe4 C45 C46 36.4(17) . . . . ?
C47 Fe4 C45 C46 -38.3(5) . . . . ?
C43 Fe4 C45 C46 -166.0(7) . . . . ?
C48 Fe4 C45 C46 -81.8(6) . . . . ?
C49 Fe4 C45 C46 -119.6(8) . . . . ?
C41 Fe4 C45 C46 71.8(7) . . . . ?
C44 Fe4 C45 C46 156.4(5) . . . . ?
C40 Fe4 C45 C46 114.0(6) . . . . ?
C49 C45 C46 C47 0.1(10) . . . . ?
Fe4 C45 C46 C47 59.3(6) . . . . ?
C49 C45 C46 Fe4 -59.2(6) . . . . ?
C42 Fe4 C46 C45 -169.9(5) . . . . ?
C47 Fe4 C46 C45 118.4(8) . . . . ?
C43 Fe4 C46 C45 154.8(12) . . . . ?
C48 Fe4 C46 C45 81.1(6) . . . . ?
C49 Fe4 C46 C45 37.1(5) . . . . ?
C41 Fe4 C46 C45 -128.5(5) . . . . ?
C44 Fe4 C46 C45 -50.8(10) . . . . ?
C40 Fe4 C46 C45 -84.8(6) . . . . ?
C42 Fe4 C46 C47 71.7(7) . . . . ?
C43 Fe4 C46 C47 36.4(16) . . . . ?
C48 Fe4 C46 C47 -37.3(5) . . . . ?
C49 Fe4 C46 C47 -81.3(6) . . . . ?
C41 Fe4 C46 C47 113.1(6) . . . . ?
C45 Fe4 C46 C47 -118.4(8) . . . . ?
C44 Fe4 C46 C47 -169.2(7) . . . . ?
C40 Fe4 C46 C47 156.8(5) . . . . ?
C45 C46 C47 C48 0.2(10) . . . . ?
Fe4 C46 C47 C48 59.9(6) . . . . ?
C45 C46 C47 Fe4 -59.7(6) . . . . ?
C42 Fe4 C47 C48 112.4(6) . . . . ?
C43 Fe4 C47 C48 71.9(6) . . . . ?
C49 Fe4 C47 C48 -37.8(5) . . . . ?
C41 Fe4 C47 C48 155.7(5) . . . . ?
C46 Fe4 C47 C48 -119.2(8) . . . . ?
C45 Fe4 C47 C48 -81.2(6) . . . . ?
C44 Fe4 C47 C48 42.3(16) . . . . ?
C40 Fe4 C47 C48 -170.2(7) . . . . ?
C42 Fe4 C47 C46 -128.4(5) . . . . ?
C43 Fe4 C47 C46 -168.9(5) . . . . ?
C48 Fe4 C47 C46 119.2(8) . . . . ?
C49 Fe4 C47 C46 81.4(6) . . . . ?
C41 Fe4 C47 C46 -85.1(6) . . . . ?
C45 Fe4 C47 C46 38.0(5) . . . . ?
C44 Fe4 C47 C46 161.5(12) . . . . ?
C40 Fe4 C47 C46 -51.0(10) . . . . ?
C46 C47 C48 C49 -0.3(10) . . . . ?
Fe4 C47 C48 C49 59.5(6) . . . . ?
C46 C47 C48 Fe4 -59.9(6) . . . . ?
C42 Fe4 C48 C47 -84.8(6) . . . . ?
C43 Fe4 C48 C47 -126.8(5) . . . . ?
C49 Fe4 C48 C47 119.2(8) . . . . ?
C41 Fe4 C48 C47 -50.3(10) . . . . ?
C46 Fe4 C48 C47 38.0(5) . . . . ?
C45 Fe4 C48 C47 81.9(6) . . . . ?
C44 Fe4 C48 C47 -167.0(5) . . . . ?
C40 Fe4 C48 C47 163.2(13) . . . . ?
C42 Fe4 C48 C49 156.0(6) . . . . ?
C47 Fe4 C48 C49 -119.2(8) . . . . ?
C43 Fe4 C48 C49 114.0(6) . . . . ?
C41 Fe4 C48 C49 -169.5(8) . . . . ?
C46 Fe4 C48 C49 -81.2(6) . . . . ?
C45 Fe4 C48 C49 -37.3(5) . . . . ?
C44 Fe4 C48 C49 73.8(7) . . . . ?
C40 Fe4 C48 C49 44.0(16) . . . . ?
C46 C45 C49 C48 -0.3(10) . . . . ?
Fe4 C45 C49 C48 -59.5(6) . . . . ?
C46 C45 C49 Fe4 59.2(6) . . . . ?
C47 C48 C49 C45 0.4(10) . . . . ?
Fe4 C48 C49 C45 59.9(6) . . . . ?
C47 C48 C49 Fe4 -59.5(6) . . . . ?
C42 Fe4 C49 C45 -168.5(7) . . . . ?
C47 Fe4 C49 C45 -81.8(6) . . . . ?
C43 Fe4 C49 C45 157.7(5) . . . . ?
C48 Fe4 C49 C45 -119.2(8) . . . . ?
C41 Fe4 C49 C45 39.9(18) . . . . ?
C46 Fe4 C49 C45 -37.6(5) . . . . ?
C44 Fe4 C49 C45 114.2(6) . . . . ?
C40 Fe4 C49 C45 74.0(7) . . . . ?
C42 Fe4 C49 C48 -49.3(10) . . . . ?
C47 Fe4 C49 C48 37.4(5) . . . . ?
C43 Fe4 C49 C48 -83.1(6) . . . . ?
C41 Fe4 C49 C48 159.1(15) . . . . ?
C46 Fe4 C49 C48 81.6(6) . . . . ?
C45 Fe4 C49 C48 119.2(8) . . . . ?
C44 Fe4 C49 C48 -126.6(6) . . . . ?
C40 Fe4 C49 C48 -166.8(5) . . . . ?
C52 N4 C50 O4 -1.2(10) . . . . ?
Au3 N4 C50 O4 169.8(5) . . . . ?
C52 N4 C50 C41 178.0(9) . . . . ?
Au3 N4 C50 C41 -11.0(16) . . . . ?
C51 O4 C50 N4 0.3(10) . . . . ?
C51 O4 C50 C41 -179.1(7) . . . . ?
C42 C41 C50 N4 178.6(9) . . . . ?
C40 C41 C50 N4 -4.6(17) . . . . ?
Fe4 C41 C50 N4 91.9(12) . . . . ?
C42 C41 C50 O4 -2.2(13) . . . . ?
C40 C41 C50 O4 174.5(9) . . . . ?
Fe4 C41 C50 O4 -88.9(9) . . . . ?
C50 O4 C51 C52 0.7(9) . . . . ?
C50 N4 C52 C51 1.6(9) . . . . ?
Au3 N4 C52 C51 -171.1(6) . . . . ?
O4 C51 C52 N4 -1.3(9) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        26.38
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.394
_refine_diff_density_min         -1.205
_refine_diff_density_rms         0.301
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2333lm
_database_code_depnum_ccdc_archive 'CCDC 1588450'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'tBuFOMeAu(I)' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C36 H44 Au2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C36 H44 Au2 Fe2 N2 O2'
_chemical_formula_weight         1042.37

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           trigonal
_symmetry_space_group_name_H-M   'P 31 2 1'
_symmetry_space_group_name_Hall  'P 31 2"'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z+1/3'
'-x+y, -x, z+2/3'
'y, x, -z'
'x-y, -y, -z+2/3'
'-x, -x+y, -z+1/3'

_cell_length_a                   10.9149(7)
_cell_length_b                   10.9149(7)
_cell_length_c                   24.7765(18)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_volume                     2556.3(3)
_cell_formula_units_Z            3
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    6207
_cell_measurement_theta_min      2.15
_cell_measurement_theta_max      33.22

_exptl_crystal_description       prism
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.031
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1500
_exptl_absorpt_coefficient_mu    9.450
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.1653
_exptl_absorpt_correction_T_max  0.2697
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            59326
_diffrn_reflns_av_R_equivalents  0.0506
_diffrn_reflns_av_sigmaI/netI    0.0346
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_theta_min         2.15
_diffrn_reflns_theta_max         33.22
_reflns_number_total             6543
_reflns_number_gt                6207
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.8726P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00135(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.004(4)
_refine_ls_number_reflns         6543
_refine_ls_number_parameters     204
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0252
_refine_ls_R_factor_gt           0.0220
_refine_ls_wR_factor_ref         0.0359
_refine_ls_wR_factor_gt          0.0354
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_restrained_S_all      1.046
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.539030(11) -0.074815(10) 0.784483(4) 0.01295(2) Uani 1 1 d . . .
Fe1 Fe 0.63654(4) -0.29889(4) 0.868479(14) 0.01488(8) Uani 1 1 d . . .
N1 N 0.4602(2) -0.1009(2) 0.92276(8) 0.0149(4) Uani 1 1 d . . .
O1 O 0.3351(2) -0.3193(2) 0.95664(8) 0.0228(5) Uani 1 1 d . . .
C1 C 0.5073(3) -0.2514(3) 0.82062(10) 0.0152(5) Uani 1 1 d . . .
C2 C 0.4480(3) -0.3069(3) 0.87399(10) 0.0138(5) Uani 1 1 d . . .
C3 C 0.4308(3) -0.4468(3) 0.88046(10) 0.0191(5) Uani 1 1 d . . .
C4 C 0.4811(3) -0.4761(3) 0.83238(11) 0.0203(6) Uani 1 1 d . . .
H4 H 0.4833 -0.5604 0.8250 0.024 Uiso 1 1 calc R . .
C5 C 0.5275(3) -0.3595(3) 0.79721(10) 0.0178(5) Uani 1 1 d . . .
H5 H 0.5671 -0.3536 0.7625 0.021 Uiso 1 1 calc R . .
C6 C 0.8230(3) -0.1161(3) 0.88601(11) 0.0209(6) Uani 1 1 d . . .
H6 H 0.8465 -0.0218 0.8777 0.025 Uiso 1 1 calc R . .
C7 C 0.7577(3) -0.1909(3) 0.93394(11) 0.0244(6) Uani 1 1 d . . .
H7 H 0.7296 -0.1554 0.9636 0.029 Uiso 1 1 calc R . .
C8 C 0.7414(4) -0.3288(3) 0.93024(13) 0.0288(7) Uani 1 1 d . . .
H8 H 0.7001 -0.4012 0.9567 0.035 Uiso 1 1 calc R . .
C9 C 0.7978(4) -0.3383(4) 0.87987(13) 0.0313(7) Uani 1 1 d . . .
H9 H 0.8017 -0.4182 0.8669 0.038 Uiso 1 1 calc R . .
C10 C 0.8471(3) -0.2085(4) 0.85233(12) 0.0277(7) Uani 1 1 d . . .
H10 H 0.8890 -0.1865 0.8175 0.033 Uiso 1 1 calc R . .
C11 C 0.3675(4) -0.5506(3) 0.92636(12) 0.0321(7) Uani 1 1 d . . .
H11A H 0.2643 -0.5944 0.9255 0.048 Uiso 1 1 calc R . .
H11B H 0.4034 -0.5008 0.9607 0.048 Uiso 1 1 calc R . .
H11C H 0.3938 -0.6239 0.9227 0.048 Uiso 1 1 calc R . .
C12 C 0.4193(3) -0.2336(3) 0.91661(10) 0.0161(5) Uani 1 1 d . . .
C13 C 0.3399(4) -0.2260(3) 0.99941(11) 0.0252(7) Uani 1 1 d . . .
H13A H 0.4103 -0.2135 1.0273 0.030 Uiso 1 1 calc R . .
H13B H 0.2461 -0.2636 1.0167 0.030 Uiso 1 1 calc R . .
C14 C 0.3830(3) -0.0877(3) 0.97052(10) 0.0153(5) Uani 1 1 d . . .
H14 H 0.4512 -0.0071 0.9936 0.018 Uiso 1 1 calc R . .
C15 C 0.2602(3) -0.0636(3) 0.95408(11) 0.0200(6) Uani 1 1 d . . .
C16 C 0.1879(4) -0.0520(4) 1.00552(13) 0.0304(7) Uani 1 1 d . . .
H16A H 0.1068 -0.0412 0.9956 0.046 Uiso 1 1 calc R . .
H16B H 0.2555 0.0305 1.0265 0.046 Uiso 1 1 calc R . .
H16C H 0.1552 -0.1378 1.0273 0.046 Uiso 1 1 calc R . .
C17 C 0.3164(4) 0.0743(4) 0.92308(14) 0.0340(8) Uani 1 1 d . . .
H17A H 0.3573 0.0671 0.8888 0.051 Uiso 1 1 calc R . .
H17B H 0.3895 0.1519 0.9445 0.051 Uiso 1 1 calc R . .
H17C H 0.2389 0.0928 0.9159 0.051 Uiso 1 1 calc R . .
C18 C 0.1522(4) -0.1854(4) 0.91965(14) 0.0368(8) Uani 1 1 d . . .
H18A H 0.0757 -0.1675 0.9096 0.055 Uiso 1 1 calc R . .
H18B H 0.1131 -0.2737 0.9402 0.055 Uiso 1 1 calc R . .
H18C H 0.1982 -0.1933 0.8869 0.055 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.992(3) . ?
Au1 N1 2.070(2) 5_556 ?
Au1 Au1 2.8036(2) 5_556 ?
Fe1 C2 2.021(3) . ?
Fe1 C3 2.027(3) . ?
Fe1 C9 2.030(3) . ?
Fe1 C8 2.032(3) . ?
Fe1 C4 2.034(3) . ?
Fe1 C10 2.037(3) . ?
Fe1 C5 2.045(3) . ?
Fe1 C7 2.052(3) . ?
Fe1 C6 2.062(3) . ?
Fe1 C1 2.097(2) . ?
N1 C12 1.294(4) . ?
N1 C14 1.501(3) . ?
N1 Au1 2.070(2) 5_556 ?
O1 C12 1.358(3) . ?
O1 C13 1.453(3) . ?
C1 C5 1.427(4) . ?
C1 C2 1.464(4) . ?
C2 C12 1.450(4) . ?
C2 C3 1.452(4) . ?
C3 C4 1.414(4) . ?
C3 C11 1.507(4) . ?
C4 C5 1.412(4) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.415(4) . ?
C6 C10 1.431(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.427(4) . ?
C7 H7 0.9500 . ?
C8 C9 1.418(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.414(5) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C13 C14 1.518(4) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.544(4) . ?
C14 H14 1.0000 . ?
C15 C17 1.519(4) . ?
C15 C18 1.522(4) . ?
C15 C16 1.537(4) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N1 176.40(10) . 5_556 ?
C1 Au1 Au1 91.98(7) . 5_556 ?
N1 Au1 Au1 90.84(6) 5_556 5_556 ?
C2 Fe1 C3 42.04(11) . . ?
C2 Fe1 C9 162.55(13) . . ?
C3 Fe1 C9 122.90(14) . . ?
C2 Fe1 C8 125.82(12) . . ?
C3 Fe1 C8 104.48(13) . . ?
C9 Fe1 C8 40.87(13) . . ?
C2 Fe1 C4 69.01(11) . . ?
C3 Fe1 C4 40.73(11) . . ?
C9 Fe1 C4 104.99(13) . . ?
C8 Fe1 C4 116.55(13) . . ?
C2 Fe1 C10 155.86(12) . . ?
C3 Fe1 C10 161.18(13) . . ?
C9 Fe1 C10 40.70(14) . . ?
C8 Fe1 C10 68.66(14) . . ?
C4 Fe1 C10 125.22(12) . . ?
C2 Fe1 C5 68.23(11) . . ?
C3 Fe1 C5 68.62(11) . . ?
C9 Fe1 C5 118.52(12) . . ?
C8 Fe1 C5 151.79(12) . . ?
C4 Fe1 C5 40.49(11) . . ?
C10 Fe1 C5 108.67(12) . . ?
C2 Fe1 C7 108.76(12) . . ?
C3 Fe1 C7 118.74(12) . . ?
C9 Fe1 C7 68.49(13) . . ?
C8 Fe1 C7 40.89(12) . . ?
C4 Fe1 C7 152.28(12) . . ?
C10 Fe1 C7 68.27(13) . . ?
C5 Fe1 C7 166.35(12) . . ?
C2 Fe1 C6 121.25(11) . . ?
C3 Fe1 C6 154.69(11) . . ?
C9 Fe1 C6 68.59(13) . . ?
C8 Fe1 C6 68.55(13) . . ?
C4 Fe1 C6 164.41(12) . . ?
C10 Fe1 C6 40.88(12) . . ?
C5 Fe1 C6 128.89(12) . . ?
C7 Fe1 C6 40.25(12) . . ?
C2 Fe1 C1 41.60(10) . . ?
C3 Fe1 C1 70.47(11) . . ?
C9 Fe1 C1 153.25(12) . . ?
C8 Fe1 C1 165.44(12) . . ?
C4 Fe1 C1 69.05(11) . . ?
C10 Fe1 C1 120.32(12) . . ?
C5 Fe1 C1 40.29(10) . . ?
C7 Fe1 C1 128.71(11) . . ?
C6 Fe1 C1 109.90(11) . . ?
C12 N1 C14 107.8(2) . . ?
C12 N1 Au1 130.24(18) . 5_556 ?
C14 N1 Au1 121.83(17) . 5_556 ?
C12 O1 C13 106.0(2) . . ?
C5 C1 C2 104.1(2) . . ?
C5 C1 Au1 126.38(19) . . ?
C2 C1 Au1 129.30(19) . . ?
C5 C1 Fe1 67.92(14) . . ?
C2 C1 Fe1 66.41(14) . . ?
Au1 C1 Fe1 132.88(14) . . ?
C12 C2 C3 123.3(2) . . ?
C12 C2 C1 127.1(2) . . ?
C3 C2 C1 109.4(2) . . ?
C12 C2 Fe1 121.43(18) . . ?
C3 C2 Fe1 69.23(16) . . ?
C1 C2 Fe1 71.99(14) . . ?
C4 C3 C2 106.6(2) . . ?
C4 C3 C11 123.3(3) . . ?
C2 C3 C11 130.0(3) . . ?
C4 C3 Fe1 69.90(17) . . ?
C2 C3 Fe1 68.73(15) . . ?
C11 C3 Fe1 128.2(2) . . ?
C5 C4 C3 108.7(2) . . ?
C5 C4 Fe1 70.18(16) . . ?
C3 C4 Fe1 69.37(16) . . ?
C5 C4 H4 125.7 . . ?
C3 C4 H4 125.7 . . ?
Fe1 C4 H4 126.4 . . ?
C4 C5 C1 111.2(2) . . ?
C4 C5 Fe1 69.34(15) . . ?
C1 C5 Fe1 71.79(14) . . ?
C4 C5 H5 124.4 . . ?
C1 C5 H5 124.4 . . ?
Fe1 C5 H5 126.0 . . ?
C7 C6 C10 107.4(3) . . ?
C7 C6 Fe1 69.50(17) . . ?
C10 C6 Fe1 68.62(18) . . ?
C7 C6 H6 126.3 . . ?
C10 C6 H6 126.3 . . ?
Fe1 C6 H6 127.1 . . ?
C6 C7 C8 108.4(3) . . ?
C6 C7 Fe1 70.25(16) . . ?
C8 C7 Fe1 68.82(16) . . ?
C6 C7 H7 125.8 . . ?
C8 C7 H7 125.8 . . ?
Fe1 C7 H7 126.7 . . ?
C9 C8 C7 107.7(3) . . ?
C9 C8 Fe1 69.45(17) . . ?
C7 C8 Fe1 70.29(16) . . ?
C9 C8 H8 126.2 . . ?
C7 C8 H8 126.2 . . ?
Fe1 C8 H8 125.7 . . ?
C10 C9 C8 108.2(3) . . ?
C10 C9 Fe1 69.92(18) . . ?
C8 C9 Fe1 69.68(17) . . ?
C10 C9 H9 125.9 . . ?
C8 C9 H9 125.9 . . ?
Fe1 C9 H9 126.1 . . ?
C9 C10 C6 108.2(3) . . ?
C9 C10 Fe1 69.38(18) . . ?
C6 C10 Fe1 70.51(17) . . ?
C9 C10 H10 125.9 . . ?
C6 C10 H10 125.9 . . ?
Fe1 C10 H10 125.8 . . ?
C3 C11 H11A 109.5 . . ?
C3 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C3 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N1 C12 O1 114.9(2) . . ?
N1 C12 C2 130.9(2) . . ?
O1 C12 C2 114.2(2) . . ?
O1 C13 C14 103.8(2) . . ?
O1 C13 H13A 111.0 . . ?
C14 C13 H13A 111.0 . . ?
O1 C13 H13B 111.0 . . ?
C14 C13 H13B 111.0 . . ?
H13A C13 H13B 109.0 . . ?
N1 C14 C13 100.7(2) . . ?
N1 C14 C15 112.7(2) . . ?
C13 C14 C15 115.5(2) . . ?
N1 C14 H14 109.2 . . ?
C13 C14 H14 109.2 . . ?
C15 C14 H14 109.2 . . ?
C17 C15 C18 109.5(3) . . ?
C17 C15 C16 107.9(3) . . ?
C18 C15 C16 109.3(3) . . ?
C17 C15 C14 110.3(2) . . ?
C18 C15 C14 111.0(2) . . ?
C16 C15 C14 108.7(2) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Au1 C1 C5 69.3(17) 5_556 . . . ?
Au1 Au1 C1 C5 -149.2(2) 5_556 . . . ?
N1 Au1 C1 C2 -104.9(16) 5_556 . . . ?
Au1 Au1 C1 C2 36.6(2) 5_556 . . . ?
N1 Au1 C1 Fe1 162.0(15) 5_556 . . . ?
Au1 Au1 C1 Fe1 -56.54(17) 5_556 . . . ?
C2 Fe1 C1 C5 -117.7(2) . . . . ?
C3 Fe1 C1 C5 -79.64(18) . . . . ?
C9 Fe1 C1 C5 45.6(3) . . . . ?
C8 Fe1 C1 C5 -151.6(5) . . . . ?
C4 Fe1 C1 C5 -36.12(17) . . . . ?
C10 Fe1 C1 C5 83.3(2) . . . . ?
C7 Fe1 C1 C5 168.67(18) . . . . ?
C6 Fe1 C1 C5 127.27(17) . . . . ?
C3 Fe1 C1 C2 38.05(15) . . . . ?
C9 Fe1 C1 C2 163.3(3) . . . . ?
C8 Fe1 C1 C2 -33.9(5) . . . . ?
C4 Fe1 C1 C2 81.57(17) . . . . ?
C10 Fe1 C1 C2 -158.99(16) . . . . ?
C5 Fe1 C1 C2 117.7(2) . . . . ?
C7 Fe1 C1 C2 -73.6(2) . . . . ?
C6 Fe1 C1 C2 -115.04(16) . . . . ?
C2 Fe1 C1 Au1 122.5(2) . . . . ?
C3 Fe1 C1 Au1 160.6(2) . . . . ?
C9 Fe1 C1 Au1 -74.2(3) . . . . ?
C8 Fe1 C1 Au1 88.6(5) . . . . ?
C4 Fe1 C1 Au1 -155.9(2) . . . . ?
C10 Fe1 C1 Au1 -36.5(2) . . . . ?
C5 Fe1 C1 Au1 -119.8(3) . . . . ?
C7 Fe1 C1 Au1 48.9(2) . . . . ?
C6 Fe1 C1 Au1 7.5(2) . . . . ?
C5 C1 C2 C12 174.0(2) . . . . ?
Au1 C1 C2 C12 -10.8(4) . . . . ?
Fe1 C1 C2 C12 116.2(3) . . . . ?
C5 C1 C2 C3 -1.5(3) . . . . ?
Au1 C1 C2 C3 173.6(2) . . . . ?
Fe1 C1 C2 C3 -59.34(19) . . . . ?
C5 C1 C2 Fe1 57.79(17) . . . . ?
Au1 C1 C2 Fe1 -127.0(2) . . . . ?
C3 Fe1 C2 C12 117.2(3) . . . . ?
C9 Fe1 C2 C12 82.6(4) . . . . ?
C8 Fe1 C2 C12 47.1(3) . . . . ?
C4 Fe1 C2 C12 155.4(2) . . . . ?
C10 Fe1 C2 C12 -73.8(4) . . . . ?
C5 Fe1 C2 C12 -161.0(2) . . . . ?
C7 Fe1 C2 C12 4.8(2) . . . . ?
C6 Fe1 C2 C12 -37.8(3) . . . . ?
C1 Fe1 C2 C12 -123.0(3) . . . . ?
C9 Fe1 C2 C3 -34.6(4) . . . . ?
C8 Fe1 C2 C3 -70.12(19) . . . . ?
C4 Fe1 C2 C3 38.14(15) . . . . ?
C10 Fe1 C2 C3 169.0(3) . . . . ?
C5 Fe1 C2 C3 81.76(16) . . . . ?
C7 Fe1 C2 C3 -112.43(16) . . . . ?
C6 Fe1 C2 C3 -154.98(15) . . . . ?
C1 Fe1 C2 C3 119.8(2) . . . . ?
C3 Fe1 C2 C1 -119.8(2) . . . . ?
C9 Fe1 C2 C1 -154.4(4) . . . . ?
C8 Fe1 C2 C1 170.05(16) . . . . ?
C4 Fe1 C2 C1 -81.68(16) . . . . ?
C10 Fe1 C2 C1 49.2(3) . . . . ?
C5 Fe1 C2 C1 -38.06(15) . . . . ?
C7 Fe1 C2 C1 127.74(16) . . . . ?
C6 Fe1 C2 C1 85.20(18) . . . . ?
C12 C2 C3 C4 -174.7(2) . . . . ?
C1 C2 C3 C4 1.1(3) . . . . ?
Fe1 C2 C3 C4 -60.0(2) . . . . ?
C12 C2 C3 C11 7.9(5) . . . . ?
C1 C2 C3 C11 -176.3(3) . . . . ?
Fe1 C2 C3 C11 122.6(3) . . . . ?
C12 C2 C3 Fe1 -114.7(2) . . . . ?
C1 C2 C3 Fe1 61.03(18) . . . . ?
C2 Fe1 C3 C4 117.9(2) . . . . ?
C9 Fe1 C3 C4 -73.8(2) . . . . ?
C8 Fe1 C3 C4 -114.05(18) . . . . ?
C10 Fe1 C3 C4 -48.1(4) . . . . ?
C5 Fe1 C3 C4 37.15(16) . . . . ?
C7 Fe1 C3 C4 -155.56(17) . . . . ?
C6 Fe1 C3 C4 175.7(2) . . . . ?
C1 Fe1 C3 C4 80.24(17) . . . . ?
C9 Fe1 C3 C2 168.30(15) . . . . ?
C8 Fe1 C3 C2 128.04(16) . . . . ?
C4 Fe1 C3 C2 -117.9(2) . . . . ?
C10 Fe1 C3 C2 -166.0(3) . . . . ?
C5 Fe1 C3 C2 -80.76(16) . . . . ?
C7 Fe1 C3 C2 86.54(17) . . . . ?
C6 Fe1 C3 C2 57.8(3) . . . . ?
C1 Fe1 C3 C2 -37.67(14) . . . . ?
C2 Fe1 C3 C11 -124.9(3) . . . . ?
C9 Fe1 C3 C11 43.4(3) . . . . ?
C8 Fe1 C3 C11 3.1(3) . . . . ?
C4 Fe1 C3 C11 117.2(3) . . . . ?
C10 Fe1 C3 C11 69.1(5) . . . . ?
C5 Fe1 C3 C11 154.3(3) . . . . ?
C7 Fe1 C3 C11 -38.4(3) . . . . ?
C6 Fe1 C3 C11 -67.1(4) . . . . ?
C1 Fe1 C3 C11 -162.6(3) . . . . ?
C2 C3 C4 C5 -0.1(3) . . . . ?
C11 C3 C4 C5 177.5(3) . . . . ?
Fe1 C3 C4 C5 -59.34(19) . . . . ?
C2 C3 C4 Fe1 59.22(19) . . . . ?
C11 C3 C4 Fe1 -123.2(3) . . . . ?
C2 Fe1 C4 C5 80.66(17) . . . . ?
C3 Fe1 C4 C5 120.0(2) . . . . ?
C9 Fe1 C4 C5 -116.59(18) . . . . ?
C8 Fe1 C4 C5 -158.74(18) . . . . ?
C10 Fe1 C4 C5 -77.1(2) . . . . ?
C7 Fe1 C4 C5 171.3(2) . . . . ?
C6 Fe1 C4 C5 -53.1(5) . . . . ?
C1 Fe1 C4 C5 35.95(16) . . . . ?
C2 Fe1 C4 C3 -39.33(16) . . . . ?
C9 Fe1 C4 C3 123.42(18) . . . . ?
C8 Fe1 C4 C3 81.3(2) . . . . ?
C10 Fe1 C4 C3 162.92(17) . . . . ?
C5 Fe1 C4 C3 -120.0(2) . . . . ?
C7 Fe1 C4 C3 51.3(3) . . . . ?
C6 Fe1 C4 C3 -173.1(4) . . . . ?
C1 Fe1 C4 C3 -84.04(17) . . . . ?
C3 C4 C5 C1 -0.9(3) . . . . ?
Fe1 C4 C5 C1 -59.73(19) . . . . ?
C3 C4 C5 Fe1 58.8(2) . . . . ?
C2 C1 C5 C4 1.5(3) . . . . ?
Au1 C1 C5 C4 -173.88(19) . . . . ?
Fe1 C1 C5 C4 58.29(19) . . . . ?
C2 C1 C5 Fe1 -56.80(17) . . . . ?
Au1 C1 C5 Fe1 127.8(2) . . . . ?
C2 Fe1 C5 C4 -82.74(17) . . . . ?
C3 Fe1 C5 C4 -37.37(16) . . . . ?
C9 Fe1 C5 C4 79.4(2) . . . . ?
C8 Fe1 C5 C4 43.3(3) . . . . ?
C10 Fe1 C5 C4 122.80(18) . . . . ?
C7 Fe1 C5 C4 -162.5(5) . . . . ?
C6 Fe1 C5 C4 163.96(17) . . . . ?
C1 Fe1 C5 C4 -122.0(2) . . . . ?
C2 Fe1 C5 C1 39.27(16) . . . . ?
C3 Fe1 C5 C1 84.65(18) . . . . ?
C9 Fe1 C5 C1 -158.54(18) . . . . ?
C8 Fe1 C5 C1 165.3(3) . . . . ?
C4 Fe1 C5 C1 122.0(2) . . . . ?
C10 Fe1 C5 C1 -115.19(18) . . . . ?
C7 Fe1 C5 C1 -40.5(6) . . . . ?
C6 Fe1 C5 C1 -74.0(2) . . . . ?
C2 Fe1 C6 C7 82.3(2) . . . . ?
C3 Fe1 C6 C7 40.8(3) . . . . ?
C9 Fe1 C6 C7 -81.6(2) . . . . ?
C8 Fe1 C6 C7 -37.53(19) . . . . ?
C4 Fe1 C6 C7 -149.8(4) . . . . ?
C10 Fe1 C6 C7 -119.3(3) . . . . ?
C5 Fe1 C6 C7 168.38(18) . . . . ?
C1 Fe1 C6 C7 126.99(18) . . . . ?
C2 Fe1 C6 C10 -158.43(17) . . . . ?
C3 Fe1 C6 C10 160.1(2) . . . . ?
C9 Fe1 C6 C10 37.70(18) . . . . ?
C8 Fe1 C6 C10 81.8(2) . . . . ?
C4 Fe1 C6 C10 -30.5(5) . . . . ?
C5 Fe1 C6 C10 -72.3(2) . . . . ?
C7 Fe1 C6 C10 119.3(3) . . . . ?
C1 Fe1 C6 C10 -113.72(18) . . . . ?
C10 C6 C7 C8 0.1(3) . . . . ?
Fe1 C6 C7 C8 58.4(2) . . . . ?
C10 C6 C7 Fe1 -58.3(2) . . . . ?
C2 Fe1 C7 C6 -116.53(18) . . . . ?
C3 Fe1 C7 C6 -161.43(17) . . . . ?
C9 Fe1 C7 C6 81.8(2) . . . . ?
C8 Fe1 C7 C6 120.0(3) . . . . ?
C4 Fe1 C7 C6 163.1(2) . . . . ?
C10 Fe1 C7 C6 37.91(18) . . . . ?
C5 Fe1 C7 C6 -41.7(6) . . . . ?
C1 Fe1 C7 C6 -74.2(2) . . . . ?
C2 Fe1 C7 C8 123.5(2) . . . . ?
C3 Fe1 C7 C8 78.6(2) . . . . ?
C9 Fe1 C7 C8 -38.1(2) . . . . ?
C4 Fe1 C7 C8 43.1(4) . . . . ?
C10 Fe1 C7 C8 -82.1(2) . . . . ?
C5 Fe1 C7 C8 -161.6(5) . . . . ?
C6 Fe1 C7 C8 -120.0(3) . . . . ?
C1 Fe1 C7 C8 165.78(19) . . . . ?
C6 C7 C8 C9 0.4(3) . . . . ?
Fe1 C7 C8 C9 59.6(2) . . . . ?
C6 C7 C8 Fe1 -59.3(2) . . . . ?
C2 Fe1 C8 C9 164.5(2) . . . . ?
C3 Fe1 C8 C9 124.0(2) . . . . ?
C4 Fe1 C8 C9 82.2(2) . . . . ?
C10 Fe1 C8 C9 -37.6(2) . . . . ?
C5 Fe1 C8 C9 52.3(4) . . . . ?
C7 Fe1 C8 C9 -118.6(3) . . . . ?
C6 Fe1 C8 C9 -81.6(2) . . . . ?
C1 Fe1 C8 C9 -168.3(4) . . . . ?
C2 Fe1 C8 C7 -76.8(2) . . . . ?
C3 Fe1 C8 C7 -117.4(2) . . . . ?
C9 Fe1 C8 C7 118.6(3) . . . . ?
C4 Fe1 C8 C7 -159.18(19) . . . . ?
C10 Fe1 C8 C7 81.0(2) . . . . ?
C5 Fe1 C8 C7 171.0(2) . . . . ?
C6 Fe1 C8 C7 37.0(2) . . . . ?
C1 Fe1 C8 C7 -49.7(6) . . . . ?
C7 C8 C9 C10 -0.7(3) . . . . ?
Fe1 C8 C9 C10 59.5(2) . . . . ?
C7 C8 C9 Fe1 -60.2(2) . . . . ?
C2 Fe1 C9 C10 -165.5(3) . . . . ?
C3 Fe1 C9 C10 167.61(17) . . . . ?
C8 Fe1 C9 C10 -119.4(3) . . . . ?
C4 Fe1 C9 C10 127.17(18) . . . . ?
C5 Fe1 C9 C10 85.8(2) . . . . ?
C7 Fe1 C9 C10 -81.3(2) . . . . ?
C6 Fe1 C9 C10 -37.86(18) . . . . ?
C1 Fe1 C9 C10 54.1(4) . . . . ?
C2 Fe1 C9 C8 -46.1(5) . . . . ?
C3 Fe1 C9 C8 -73.0(2) . . . . ?
C4 Fe1 C9 C8 -113.4(2) . . . . ?
C10 Fe1 C9 C8 119.4(3) . . . . ?
C5 Fe1 C9 C8 -154.79(19) . . . . ?
C7 Fe1 C9 C8 38.14(19) . . . . ?
C6 Fe1 C9 C8 81.5(2) . . . . ?
C1 Fe1 C9 C8 173.5(2) . . . . ?
C8 C9 C10 C6 0.7(3) . . . . ?
Fe1 C9 C10 C6 60.0(2) . . . . ?
C8 C9 C10 Fe1 -59.3(2) . . . . ?
C7 C6 C10 C9 -0.5(3) . . . . ?
Fe1 C6 C10 C9 -59.3(2) . . . . ?
C7 C6 C10 Fe1 58.9(2) . . . . ?
C2 Fe1 C10 C9 169.4(2) . . . . ?
C3 Fe1 C10 C9 -34.0(4) . . . . ?
C8 Fe1 C10 C9 37.74(18) . . . . ?
C4 Fe1 C10 C9 -70.4(2) . . . . ?
C5 Fe1 C10 C9 -112.33(18) . . . . ?
C7 Fe1 C10 C9 81.84(19) . . . . ?
C6 Fe1 C10 C9 119.2(2) . . . . ?
C1 Fe1 C10 C9 -155.01(17) . . . . ?
C2 Fe1 C10 C6 50.2(3) . . . . ?
C3 Fe1 C10 C6 -153.1(3) . . . . ?
C9 Fe1 C10 C6 -119.2(2) . . . . ?
C8 Fe1 C10 C6 -81.45(19) . . . . ?
C4 Fe1 C10 C6 170.39(17) . . . . ?
C5 Fe1 C10 C6 128.48(17) . . . . ?
C7 Fe1 C10 C6 -37.34(17) . . . . ?
C1 Fe1 C10 C6 85.80(19) . . . . ?
C14 N1 C12 O1 -7.3(3) . . . . ?
Au1 N1 C12 O1 167.82(17) 5_556 . . . ?
C14 N1 C12 C2 172.6(3) . . . . ?
Au1 N1 C12 C2 -12.4(4) 5_556 . . . ?
C13 O1 C12 N1 -10.3(3) . . . . ?
C13 O1 C12 C2 169.9(2) . . . . ?
C3 C2 C12 N1 160.7(3) . . . . ?
C1 C2 C12 N1 -14.3(5) . . . . ?
Fe1 C2 C12 N1 76.1(3) . . . . ?
C3 C2 C12 O1 -19.5(4) . . . . ?
C1 C2 C12 O1 165.5(2) . . . . ?
Fe1 C2 C12 O1 -104.0(2) . . . . ?
C12 O1 C13 C14 22.6(3) . . . . ?
C12 N1 C14 C13 20.5(3) . . . . ?
Au1 N1 C14 C13 -155.12(19) 5_556 . . . ?
C12 N1 C14 C15 -103.1(3) . . . . ?
Au1 N1 C14 C15 81.3(3) 5_556 . . . ?
O1 C13 C14 N1 -25.4(3) . . . . ?
O1 C13 C14 C15 96.2(3) . . . . ?
N1 C14 C15 C17 -62.1(3) . . . . ?
C13 C14 C15 C17 -177.0(2) . . . . ?
N1 C14 C15 C18 59.5(3) . . . . ?
C13 C14 C15 C18 -55.4(3) . . . . ?
N1 C14 C15 C16 179.8(2) . . . . ?
C13 C14 C15 C16 64.9(3) . . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        33.22
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         0.877
_refine_diff_density_min         -1.504
_refine_diff_density_rms         0.117
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2319lm
_database_code_depnum_ccdc_archive 'CCDC 1588448'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 'iPrFOMeAu(II)Br' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C34 H40 Au2 Br2 Fe2 N2 O2, C H Cl3'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C35 H41 Au2 Br2 Cl3 Fe2 N2 O2'
_chemical_formula_weight         1293.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 2'
_symmetry_space_group_name_Hall  'P 2 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'

_cell_length_a                   19.4272(12)
_cell_length_b                   21.3813(10)
_cell_length_c                   9.1942(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3819.1(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    130(2)
_cell_measurement_reflns_used    9960
_cell_measurement_theta_min      1.90
_cell_measurement_theta_max      30.56

_exptl_crystal_description       needle
_exptl_crystal_colour            dark-purple
_exptl_crystal_size_max          0.51
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.250
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2448
_exptl_absorpt_coefficient_mu    10.740
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.0564
_exptl_absorpt_correction_T_max  0.5970
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      130(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII DuO'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            53577
_diffrn_reflns_av_R_equivalents  0.0565
_diffrn_reflns_av_sigmaI/netI    0.0636
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         1.90
_diffrn_reflns_theta_max         30.56
_reflns_number_total             11691
_reflns_number_gt                9960
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0161P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00010(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.001(5)
_refine_ls_number_reflns         11691
_refine_ls_number_parameters     440
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0481
_refine_ls_R_factor_gt           0.0331
_refine_ls_wR_factor_ref         0.0580
_refine_ls_wR_factor_gt          0.0554
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_restrained_S_all      1.021
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.496611(12) 0.795809(8) 0.27742(2) 0.01022(4) Uani 1 1 d . . .
Br1 Br 0.60396(3) 0.84018(2) 0.39127(6) 0.01652(12) Uani 1 1 d . . .
Fe1 Fe 0.36244(4) 0.92616(3) 0.30860(8) 0.01333(17) Uani 1 1 d . . .
Au2 Au 0.387129(12) 0.760068(9) 0.15466(2) 0.01346(5) Uani 1 1 d . . .
Br2 Br 0.27746(4) 0.73095(3) 0.02435(7) 0.03056(16) Uani 1 1 d . . .
Fe2 Fe 0.50939(5) 0.82509(3) -0.12565(7) 0.01610(17) Uani 1 1 d . . .
O1 O 0.2951(2) 0.79226(17) 0.5686(4) 0.0195(9) Uani 1 1 d . . .
N1 N 0.3369(2) 0.7574(2) 0.3570(5) 0.0178(9) Uani 1 1 d . . .
C1 C 0.4395(3) 0.8644(2) 0.3661(5) 0.0109(10) Uani 1 1 d . . .
O2 O 0.6012(2) 0.66680(16) 0.0098(4) 0.0189(9) Uani 1 1 d . . .
N2 N 0.5527(2) 0.72109(18) 0.1900(4) 0.0115(9) Uani 1 1 d . . .
C2 C 0.3782(3) 0.8568(2) 0.4529(5) 0.0114(10) Uani 1 1 d . . .
C3 C 0.3645(3) 0.9140(2) 0.5313(5) 0.0159(12) Uani 1 1 d . . .
C4 C 0.4157(3) 0.9571(2) 0.4861(6) 0.0165(12) Uani 1 1 d . . .
H4 H 0.4188 0.9994 0.5172 0.020 Uiso 1 1 calc R . .
C5 C 0.4617(3) 0.9275(2) 0.3875(5) 0.0126(11) Uani 1 1 d . . .
H5 H 0.5006 0.9465 0.3432 0.015 Uiso 1 1 calc R . .
C6 C 0.3350(4) 0.9144(3) 0.0927(6) 0.0239(14) Uani 1 1 d . . .
H6 H 0.3538 0.8848 0.0265 0.029 Uiso 1 1 calc R . .
C7 C 0.2777(3) 0.9052(2) 0.1859(5) 0.0181(12) Uani 1 1 d . . .
H7 H 0.2514 0.8678 0.1926 0.022 Uiso 1 1 calc R . .
C8 C 0.2659(3) 0.9596(2) 0.2664(6) 0.0211(13) Uani 1 1 d . . .
H8 H 0.2302 0.9657 0.3356 0.025 Uiso 1 1 calc R . .
C9 C 0.3169(3) 1.0045(3) 0.2264(6) 0.0229(12) Uani 1 1 d . . .
H9 H 0.3218 1.0454 0.2650 0.028 Uiso 1 1 calc R . .
C10 C 0.3591(4) 0.9764(3) 0.1176(6) 0.0249(14) Uani 1 1 d . . .
H10 H 0.3968 0.9958 0.0698 0.030 Uiso 1 1 calc R . .
C11 C 0.3092(3) 0.9273(3) 0.6404(6) 0.0215(12) Uani 1 1 d . . .
H11A H 0.3034 0.9727 0.6503 0.032 Uiso 1 1 calc R . .
H11B H 0.3222 0.9095 0.7346 0.032 Uiso 1 1 calc R . .
H11C H 0.2658 0.9086 0.6077 0.032 Uiso 1 1 calc R . .
C12 C 0.3365(3) 0.8007(2) 0.4547(6) 0.0153(11) Uani 1 1 d . . .
C13 C 0.2580(4) 0.7335(3) 0.5431(7) 0.0316(16) Uani 1 1 d . . .
H13A H 0.2080 0.7414 0.5314 0.038 Uiso 1 1 calc R . .
H13B H 0.2648 0.7043 0.6253 0.038 Uiso 1 1 calc R . .
C14 C 0.2886(3) 0.7065(2) 0.4025(6) 0.0216(12) Uani 1 1 d . . .
H14 H 0.2513 0.7024 0.3282 0.026 Uiso 1 1 calc R . .
C15 C 0.3258(3) 0.6441(2) 0.4173(6) 0.0192(12) Uani 1 1 d . . .
H15 H 0.3465 0.6341 0.3205 0.023 Uiso 1 1 calc R . .
C16 C 0.3844(4) 0.6467(3) 0.5278(7) 0.0349(16) Uani 1 1 d . . .
H16A H 0.4074 0.6060 0.5317 0.052 Uiso 1 1 calc R . .
H16B H 0.3657 0.6569 0.6239 0.052 Uiso 1 1 calc R . .
H16C H 0.4176 0.6789 0.4986 0.052 Uiso 1 1 calc R . .
C17 C 0.2737(4) 0.5932(3) 0.4518(8) 0.0344(17) Uani 1 1 d . . .
H17A H 0.2536 0.6009 0.5479 0.052 Uiso 1 1 calc R . .
H17B H 0.2967 0.5524 0.4515 0.052 Uiso 1 1 calc R . .
H17C H 0.2372 0.5936 0.3782 0.052 Uiso 1 1 calc R . .
C18 C 0.4429(3) 0.7625(3) -0.0315(6) 0.0195(12) Uani 1 1 d . . .
C19 C 0.5107(3) 0.7350(2) -0.0585(5) 0.0144(11) Uani 1 1 d . . .
C20 C 0.5257(3) 0.7382(2) -0.2124(6) 0.0202(12) Uani 1 1 d . . .
C21 C 0.4678(3) 0.7671(2) -0.2784(6) 0.0234(13) Uani 1 1 d . . .
H21 H 0.4630 0.7750 -0.3796 0.028 Uiso 1 1 calc R . .
C22 C 0.4181(3) 0.7824(2) -0.1707(6) 0.0197(13) Uani 1 1 d . . .
H22 H 0.3754 0.8025 -0.1883 0.024 Uiso 1 1 calc R . .
C23 C 0.5200(3) 0.9047(2) -0.0001(6) 0.0185(13) Uani 1 1 d . . .
H23 H 0.4979 0.9133 0.0898 0.022 Uiso 1 1 calc R . .
C24 C 0.5842(3) 0.8749(2) -0.0183(6) 0.0230(14) Uani 1 1 d . . .
H24 H 0.6127 0.8594 0.0576 0.028 Uiso 1 1 calc R . .
C25 C 0.5991(4) 0.8719(2) -0.1704(6) 0.0250(14) Uani 1 1 d . . .
H25 H 0.6393 0.8547 -0.2138 0.030 Uiso 1 1 calc R . .
C26 C 0.5426(4) 0.8996(2) -0.2445(6) 0.0259(15) Uani 1 1 d . . .
H26 H 0.5387 0.9037 -0.3470 0.031 Uiso 1 1 calc R . .
C27 C 0.4939(4) 0.9198(2) -0.1446(6) 0.0252(13) Uani 1 1 d . . .
H27 H 0.4514 0.9398 -0.1662 0.030 Uiso 1 1 calc R . .
C28 C 0.5890(4) 0.7149(3) -0.2852(7) 0.0290(15) Uani 1 1 d . . .
H28A H 0.5916 0.7320 -0.3839 0.043 Uiso 1 1 calc R . .
H28B H 0.5876 0.6691 -0.2900 0.043 Uiso 1 1 calc R . .
H28C H 0.6295 0.7281 -0.2297 0.043 Uiso 1 1 calc R . .
C29 C 0.5546(3) 0.7092(2) 0.0523(6) 0.0147(11) Uani 1 1 d . . .
C30 C 0.6441(3) 0.6526(3) 0.1379(6) 0.0196(12) Uani 1 1 d . . .
H30A H 0.6892 0.6740 0.1320 0.024 Uiso 1 1 calc R . .
H30B H 0.6517 0.6070 0.1478 0.024 Uiso 1 1 calc R . .
C31 C 0.6006(3) 0.6782(2) 0.2654(5) 0.0142(11) Uani 1 1 d . . .
H31 H 0.6310 0.7031 0.3314 0.017 Uiso 1 1 calc R . .
C32 C 0.5615(3) 0.6307(2) 0.3543(6) 0.0193(12) Uani 1 1 d . . .
H32 H 0.5341 0.6543 0.4283 0.023 Uiso 1 1 calc R . .
C33 C 0.5112(3) 0.5921(2) 0.2653(6) 0.0252(14) Uani 1 1 d . . .
H33A H 0.4767 0.6197 0.2215 0.038 Uiso 1 1 calc R . .
H33B H 0.4882 0.5617 0.3286 0.038 Uiso 1 1 calc R . .
H33C H 0.5361 0.5699 0.1883 0.038 Uiso 1 1 calc R . .
C34 C 0.6120(4) 0.5880(3) 0.4380(6) 0.0292(15) Uani 1 1 d . . .
H34A H 0.6380 0.5625 0.3687 0.044 Uiso 1 1 calc R . .
H34B H 0.5860 0.5607 0.5038 0.044 Uiso 1 1 calc R . .
H34C H 0.6439 0.6139 0.4946 0.044 Uiso 1 1 calc R . .
C1X C 0.3561(6) 0.5432(4) 0.9291(10) 0.072(3) Uani 1 1 d . . .
H1X H 0.3185 0.5507 0.8569 0.086 Uiso 1 1 calc R . .
Cl1 Cl 0.40142(18) 0.47395(11) 0.8727(3) 0.0865(9) Uani 1 1 d . . .
Cl2 Cl 0.41358(19) 0.60646(12) 0.9177(3) 0.0891(11) Uani 1 1 d . . .
Cl3 Cl 0.3190(2) 0.53369(13) 1.0922(3) 0.0993(11) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.011(5) . ?
Au1 N2 2.094(4) . ?
Au1 Br1 2.5189(6) . ?
Au1 Au2 2.5262(3) . ?
Fe1 C2 2.014(5) . ?
Fe1 C9 2.039(5) . ?
Fe1 C4 2.043(6) . ?
Fe1 C8 2.045(6) . ?
Fe1 C7 2.046(6) . ?
Fe1 C10 2.060(6) . ?
Fe1 C5 2.060(5) . ?
Fe1 C3 2.064(5) . ?
Fe1 C1 2.066(5) . ?
Fe1 C6 2.070(6) . ?
Au2 C18 2.025(6) . ?
Au2 N1 2.101(4) . ?
Au2 Br2 2.5223(7) . ?
Fe2 C19 2.023(5) . ?
Fe2 C22 2.037(6) . ?
Fe2 C26 2.037(5) . ?
Fe2 C21 2.040(5) . ?
Fe2 C20 2.046(5) . ?
Fe2 C25 2.052(6) . ?
Fe2 C18 2.052(6) . ?
Fe2 C24 2.054(6) . ?
Fe2 C27 2.056(5) . ?
Fe2 C23 2.066(5) . ?
O1 C12 1.333(6) . ?
O1 C13 1.467(7) . ?
N1 C12 1.291(6) . ?
N1 C14 1.496(7) . ?
C1 C5 1.432(7) . ?
C1 C2 1.442(7) . ?
O2 C29 1.340(6) . ?
O2 C30 1.474(6) . ?
N2 C29 1.293(6) . ?
N2 C31 1.479(6) . ?
C2 C3 1.444(7) . ?
C2 C12 1.446(7) . ?
C3 C4 1.420(8) . ?
C3 C11 1.498(8) . ?
C4 C5 1.420(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.420(9) . ?
C6 C10 1.424(8) . ?
C6 H6 0.9500 . ?
C7 C8 1.398(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.427(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.426(8) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C13 C14 1.536(8) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.524(8) . ?
C14 H14 1.0000 . ?
C15 C17 1.520(8) . ?
C15 C16 1.526(9) . ?
C15 H15 1.0000 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C22 1.432(7) . ?
C18 C19 1.465(8) . ?
C19 C29 1.438(7) . ?
C19 C20 1.446(7) . ?
C20 C21 1.418(8) . ?
C20 C28 1.486(8) . ?
C21 C22 1.421(8) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C24 1.411(9) . ?
C23 C27 1.459(8) . ?
C23 H23 0.9500 . ?
C24 C25 1.430(8) . ?
C24 H24 0.9500 . ?
C25 C26 1.422(9) . ?
C25 H25 0.9500 . ?
C26 C27 1.388(9) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C30 C31 1.546(7) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.510(7) . ?
C31 H31 1.0000 . ?
C32 C33 1.519(8) . ?
C32 C34 1.544(8) . ?
C32 H32 1.0000 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C1X Cl3 1.676(11) . ?
C1X Cl2 1.758(10) . ?
C1X Cl1 1.799(10) . ?
C1X H1X 1.0000 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 177.04(19) . . ?
C1 Au1 Br1 90.80(15) . . ?
N2 Au1 Br1 90.94(12) . . ?
C1 Au1 Au2 86.39(15) . . ?
N2 Au1 Au2 92.04(12) . . ?
Br1 Au1 Au2 175.321(15) . . ?
C2 Fe1 C9 156.2(2) . . ?
C2 Fe1 C4 68.6(2) . . ?
C9 Fe1 C4 104.5(2) . . ?
C2 Fe1 C8 121.5(2) . . ?
C9 Fe1 C8 40.9(2) . . ?
C4 Fe1 C8 120.2(2) . . ?
C2 Fe1 C7 108.9(2) . . ?
C9 Fe1 C7 68.1(2) . . ?
C4 Fe1 C7 156.8(2) . . ?
C8 Fe1 C7 40.0(2) . . ?
C2 Fe1 C10 161.9(2) . . ?
C9 Fe1 C10 40.7(2) . . ?
C4 Fe1 C10 121.9(2) . . ?
C8 Fe1 C10 68.1(2) . . ?
C7 Fe1 C10 67.6(2) . . ?
C2 Fe1 C5 68.7(2) . . ?
C9 Fe1 C5 121.7(2) . . ?
C4 Fe1 C5 40.5(2) . . ?
C8 Fe1 C5 157.0(2) . . ?
C7 Fe1 C5 161.9(2) . . ?
C10 Fe1 C5 108.8(2) . . ?
C2 Fe1 C3 41.45(19) . . ?
C9 Fe1 C3 118.7(2) . . ?
C4 Fe1 C3 40.4(2) . . ?
C8 Fe1 C3 104.5(2) . . ?
C7 Fe1 C3 122.3(2) . . ?
C10 Fe1 C3 155.8(2) . . ?
C5 Fe1 C3 68.6(2) . . ?
C2 Fe1 C1 41.4(2) . . ?
C9 Fe1 C1 159.2(2) . . ?
C4 Fe1 C1 68.6(2) . . ?
C8 Fe1 C1 159.6(2) . . ?
C7 Fe1 C1 125.7(2) . . ?
C10 Fe1 C1 125.1(2) . . ?
C5 Fe1 C1 40.61(19) . . ?
C3 Fe1 C1 69.6(2) . . ?
C2 Fe1 C6 125.5(2) . . ?
C9 Fe1 C6 68.5(2) . . ?
C4 Fe1 C6 159.3(3) . . ?
C8 Fe1 C6 68.0(2) . . ?
C7 Fe1 C6 40.3(2) . . ?
C10 Fe1 C6 40.3(2) . . ?
C5 Fe1 C6 125.5(2) . . ?
C3 Fe1 C6 160.1(2) . . ?
C1 Fe1 C6 110.7(2) . . ?
C18 Au2 N1 175.4(2) . . ?
C18 Au2 Br2 93.24(17) . . ?
N1 Au2 Br2 91.22(13) . . ?
C18 Au2 Au1 85.40(17) . . ?
N1 Au2 Au1 90.22(13) . . ?
Br2 Au2 Au1 176.421(17) . . ?
C19 Fe2 C22 69.3(2) . . ?
C19 Fe2 C26 154.8(2) . . ?
C22 Fe2 C26 121.2(2) . . ?
C19 Fe2 C21 68.7(2) . . ?
C22 Fe2 C21 40.8(2) . . ?
C26 Fe2 C21 103.4(2) . . ?
C19 Fe2 C20 41.63(19) . . ?
C22 Fe2 C20 69.4(2) . . ?
C26 Fe2 C20 116.9(2) . . ?
C21 Fe2 C20 40.6(2) . . ?
C19 Fe2 C25 121.0(2) . . ?
C22 Fe2 C25 156.5(2) . . ?
C26 Fe2 C25 40.7(3) . . ?
C21 Fe2 C25 119.6(2) . . ?
C20 Fe2 C25 103.5(2) . . ?
C19 Fe2 C18 42.1(2) . . ?
C22 Fe2 C18 41.0(2) . . ?
C26 Fe2 C18 159.4(3) . . ?
C21 Fe2 C18 69.2(2) . . ?
C20 Fe2 C18 70.7(2) . . ?
C25 Fe2 C18 159.7(2) . . ?
C19 Fe2 C24 109.7(2) . . ?
C22 Fe2 C24 161.1(2) . . ?
C26 Fe2 C24 68.2(2) . . ?
C21 Fe2 C24 157.8(3) . . ?
C20 Fe2 C24 123.2(3) . . ?
C25 Fe2 C24 40.8(2) . . ?
C18 Fe2 C24 125.5(2) . . ?
C19 Fe2 C27 165.1(2) . . ?
C22 Fe2 C27 107.3(3) . . ?
C26 Fe2 C27 39.6(2) . . ?
C21 Fe2 C27 118.9(2) . . ?
C20 Fe2 C27 152.2(2) . . ?
C25 Fe2 C27 68.1(3) . . ?
C18 Fe2 C27 125.9(3) . . ?
C24 Fe2 C27 68.5(3) . . ?
C19 Fe2 C23 127.8(2) . . ?
C22 Fe2 C23 124.7(2) . . ?
C26 Fe2 C23 67.9(2) . . ?
C21 Fe2 C23 157.6(2) . . ?
C20 Fe2 C23 161.8(2) . . ?
C25 Fe2 C23 68.0(2) . . ?
C18 Fe2 C23 111.4(2) . . ?
C24 Fe2 C23 40.0(2) . . ?
C27 Fe2 C23 41.5(2) . . ?
C12 O1 C13 106.7(4) . . ?
C12 N1 C14 108.9(4) . . ?
C12 N1 Au2 126.8(4) . . ?
C14 N1 Au2 124.0(3) . . ?
C5 C1 C2 106.2(4) . . ?
C5 C1 Au1 125.3(4) . . ?
C2 C1 Au1 126.7(3) . . ?
C5 C1 Fe1 69.5(3) . . ?
C2 C1 Fe1 67.4(3) . . ?
Au1 C1 Fe1 139.7(3) . . ?
C29 O2 C30 106.8(4) . . ?
C29 N2 C31 108.6(4) . . ?
C29 N2 Au1 122.8(4) . . ?
C31 N2 Au1 128.3(3) . . ?
C1 C2 C3 109.5(4) . . ?
C1 C2 C12 124.2(4) . . ?
C3 C2 C12 126.3(5) . . ?
C1 C2 Fe1 71.2(3) . . ?
C3 C2 Fe1 71.1(3) . . ?
C12 C2 Fe1 122.2(4) . . ?
C4 C3 C2 106.0(5) . . ?
C4 C3 C11 125.1(5) . . ?
C2 C3 C11 128.9(5) . . ?
C4 C3 Fe1 69.0(3) . . ?
C2 C3 Fe1 67.4(3) . . ?
C11 C3 Fe1 128.8(4) . . ?
C3 C4 C5 109.8(5) . . ?
C3 C4 Fe1 70.6(3) . . ?
C5 C4 Fe1 70.4(3) . . ?
C3 C4 H4 125.1 . . ?
C5 C4 H4 125.1 . . ?
Fe1 C4 H4 125.5 . . ?
C4 C5 C1 108.6(5) . . ?
C4 C5 Fe1 69.1(3) . . ?
C1 C5 Fe1 69.9(3) . . ?
C4 C5 H5 125.7 . . ?
C1 C5 H5 125.7 . . ?
Fe1 C5 H5 126.9 . . ?
C7 C6 C10 106.8(5) . . ?
C7 C6 Fe1 68.9(3) . . ?
C10 C6 Fe1 69.4(3) . . ?
C7 C6 H6 126.6 . . ?
C10 C6 H6 126.6 . . ?
Fe1 C6 H6 126.6 . . ?
C8 C7 C6 109.4(5) . . ?
C8 C7 Fe1 70.0(3) . . ?
C6 C7 Fe1 70.8(4) . . ?
C8 C7 H7 125.3 . . ?
C6 C7 H7 125.3 . . ?
Fe1 C7 H7 125.6 . . ?
C7 C8 C9 108.0(5) . . ?
C7 C8 Fe1 70.1(3) . . ?
C9 C8 Fe1 69.4(3) . . ?
C7 C8 H8 126.0 . . ?
C9 C8 H8 126.0 . . ?
Fe1 C8 H8 126.2 . . ?
C10 C9 C8 107.3(5) . . ?
C10 C9 Fe1 70.4(3) . . ?
C8 C9 Fe1 69.7(3) . . ?
C10 C9 H9 126.4 . . ?
C8 C9 H9 126.4 . . ?
Fe1 C9 H9 125.1 . . ?
C6 C10 C9 108.4(6) . . ?
C6 C10 Fe1 70.2(3) . . ?
C9 C10 Fe1 68.9(3) . . ?
C6 C10 H10 125.8 . . ?
C9 C10 H10 125.8 . . ?
Fe1 C10 H10 126.7 . . ?
C3 C11 H11A 109.5 . . ?
C3 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C3 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N1 C12 O1 116.9(5) . . ?
N1 C12 C2 125.7(5) . . ?
O1 C12 C2 117.4(4) . . ?
O1 C13 C14 105.4(4) . . ?
O1 C13 H13A 110.7 . . ?
C14 C13 H13A 110.7 . . ?
O1 C13 H13B 110.7 . . ?
C14 C13 H13B 110.7 . . ?
H13A C13 H13B 108.8 . . ?
N1 C14 C15 111.4(5) . . ?
N1 C14 C13 101.8(4) . . ?
C15 C14 C13 116.0(5) . . ?
N1 C14 H14 109.1 . . ?
C15 C14 H14 109.1 . . ?
C13 C14 H14 109.1 . . ?
C17 C15 C14 109.2(5) . . ?
C17 C15 C16 112.5(5) . . ?
C14 C15 C16 112.4(5) . . ?
C17 C15 H15 107.5 . . ?
C14 C15 H15 107.5 . . ?
C16 C15 H15 107.5 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C22 C18 C19 105.6(5) . . ?
C22 C18 Au2 125.7(5) . . ?
C19 C18 Au2 127.9(4) . . ?
C22 C18 Fe2 68.9(3) . . ?
C19 C18 Fe2 67.9(3) . . ?
Au2 C18 Fe2 135.2(3) . . ?
C29 C19 C20 126.4(5) . . ?
C29 C19 C18 124.5(4) . . ?
C20 C19 C18 109.1(5) . . ?
C29 C19 Fe2 126.1(4) . . ?
C20 C19 Fe2 70.0(3) . . ?
C18 C19 Fe2 70.0(3) . . ?
C21 C20 C19 106.3(5) . . ?
C21 C20 C28 127.5(5) . . ?
C19 C20 C28 126.2(5) . . ?
C21 C20 Fe2 69.5(3) . . ?
C19 C20 Fe2 68.4(3) . . ?
C28 C20 Fe2 127.5(4) . . ?
C20 C21 C22 109.9(5) . . ?
C20 C21 Fe2 69.9(3) . . ?
C22 C21 Fe2 69.5(3) . . ?
C20 C21 H21 125.0 . . ?
C22 C21 H21 125.0 . . ?
Fe2 C21 H21 127.2 . . ?
C21 C22 C18 109.1(5) . . ?
C21 C22 Fe2 69.7(3) . . ?
C18 C22 Fe2 70.1(3) . . ?
C21 C22 H22 125.5 . . ?
C18 C22 H22 125.5 . . ?
Fe2 C22 H22 126.3 . . ?
C24 C23 C27 107.5(5) . . ?
C24 C23 Fe2 69.5(3) . . ?
C27 C23 Fe2 68.9(3) . . ?
C24 C23 H23 126.3 . . ?
C27 C23 H23 126.3 . . ?
Fe2 C23 H23 126.9 . . ?
C23 C24 C25 108.4(5) . . ?
C23 C24 Fe2 70.4(3) . . ?
C25 C24 Fe2 69.5(3) . . ?
C23 C24 H24 125.8 . . ?
C25 C24 H24 125.8 . . ?
Fe2 C24 H24 125.8 . . ?
C26 C25 C24 107.1(6) . . ?
C26 C25 Fe2 69.1(4) . . ?
C24 C25 Fe2 69.7(3) . . ?
C26 C25 H25 126.5 . . ?
C24 C25 H25 126.5 . . ?
Fe2 C25 H25 126.3 . . ?
C27 C26 C25 109.9(5) . . ?
C27 C26 Fe2 70.9(3) . . ?
C25 C26 Fe2 70.2(3) . . ?
C27 C26 H26 125.1 . . ?
C25 C26 H26 125.1 . . ?
Fe2 C26 H26 125.4 . . ?
C26 C27 C23 107.2(6) . . ?
C26 C27 Fe2 69.5(3) . . ?
C23 C27 Fe2 69.7(3) . . ?
C26 C27 H27 126.4 . . ?
C23 C27 H27 126.4 . . ?
Fe2 C27 H27 126.0 . . ?
C20 C28 H28A 109.5 . . ?
C20 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C20 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N2 C29 O2 116.0(5) . . ?
N2 C29 C19 127.0(5) . . ?
O2 C29 C19 117.0(4) . . ?
O2 C30 C31 102.9(4) . . ?
O2 C30 H30A 111.2 . . ?
C31 C30 H30A 111.2 . . ?
O2 C30 H30B 111.2 . . ?
C31 C30 H30B 111.2 . . ?
H30A C30 H30B 109.1 . . ?
N2 C31 C32 110.7(5) . . ?
N2 C31 C30 102.1(4) . . ?
C32 C31 C30 116.5(4) . . ?
N2 C31 H31 109.1 . . ?
C32 C31 H31 109.1 . . ?
C30 C31 H31 109.1 . . ?
C31 C32 C33 113.5(5) . . ?
C31 C32 C34 110.3(5) . . ?
C33 C32 C34 110.9(5) . . ?
C31 C32 H32 107.3 . . ?
C33 C32 H32 107.3 . . ?
C34 C32 H32 107.3 . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C32 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C32 C34 H34A 109.5 . . ?
C32 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C32 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
Cl3 C1X Cl2 114.8(5) . . ?
Cl3 C1X Cl1 111.7(5) . . ?
Cl2 C1X Cl1 107.7(7) . . ?
Cl3 C1X H1X 107.4 . . ?
Cl2 C1X H1X 107.4 . . ?
Cl1 C1X H1X 107.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C18 128.1(2) . . . . ?
N2 Au1 Au2 C18 -54.41(19) . . . . ?
Br1 Au1 Au2 C18 75.0(2) . . . . ?
C1 Au1 Au2 N1 -53.40(18) . . . . ?
N2 Au1 Au2 N1 124.10(16) . . . . ?
Br1 Au1 Au2 N1 -106.5(2) . . . . ?
C1 Au1 Au2 Br2 60.4(3) . . . . ?
N2 Au1 Au2 Br2 -122.1(3) . . . . ?
Br1 Au1 Au2 Br2 7.3(4) . . . . ?
C18 Au2 N1 C12 68(3) . . . . ?
Br2 Au2 N1 C12 -127.8(5) . . . . ?
Au1 Au2 N1 C12 48.9(5) . . . . ?
C18 Au2 N1 C14 -120(2) . . . . ?
Br2 Au2 N1 C14 44.8(4) . . . . ?
Au1 Au2 N1 C14 -138.4(4) . . . . ?
N2 Au1 C1 C5 161(3) . . . . ?
Br1 Au1 C1 C5 34.9(4) . . . . ?
Au2 Au1 C1 C5 -141.4(4) . . . . ?
N2 Au1 C1 C2 -2(4) . . . . ?
Br1 Au1 C1 C2 -127.4(5) . . . . ?
Au2 Au1 C1 C2 56.3(4) . . . . ?
N2 Au1 C1 Fe1 -99(4) . . . . ?
Br1 Au1 C1 Fe1 134.7(4) . . . . ?
Au2 Au1 C1 Fe1 -41.6(4) . . . . ?
C2 Fe1 C1 C5 -118.5(4) . . . . ?
C9 Fe1 C1 C5 37.0(7) . . . . ?
C4 Fe1 C1 C5 -37.1(3) . . . . ?
C8 Fe1 C1 C5 -156.9(6) . . . . ?
C7 Fe1 C1 C5 163.7(3) . . . . ?
C10 Fe1 C1 C5 77.7(4) . . . . ?
C3 Fe1 C1 C5 -80.5(3) . . . . ?
C6 Fe1 C1 C5 120.8(3) . . . . ?
C9 Fe1 C1 C2 155.6(6) . . . . ?
C4 Fe1 C1 C2 81.5(3) . . . . ?
C8 Fe1 C1 C2 -38.4(7) . . . . ?
C7 Fe1 C1 C2 -77.7(4) . . . . ?
C10 Fe1 C1 C2 -163.8(3) . . . . ?
C5 Fe1 C1 C2 118.5(4) . . . . ?
C3 Fe1 C1 C2 38.1(3) . . . . ?
C6 Fe1 C1 C2 -120.7(3) . . . . ?
C2 Fe1 C1 Au1 120.7(5) . . . . ?
C9 Fe1 C1 Au1 -83.8(7) . . . . ?
C4 Fe1 C1 Au1 -157.9(5) . . . . ?
C8 Fe1 C1 Au1 82.3(7) . . . . ?
C7 Fe1 C1 Au1 42.9(5) . . . . ?
C10 Fe1 C1 Au1 -43.1(5) . . . . ?
C5 Fe1 C1 Au1 -120.8(5) . . . . ?
C3 Fe1 C1 Au1 158.7(5) . . . . ?
C6 Fe1 C1 Au1 0.0(5) . . . . ?
C1 Au1 N2 C29 112(4) . . . . ?
Br1 Au1 N2 C29 -122.3(4) . . . . ?
Au2 Au1 N2 C29 54.1(4) . . . . ?
C1 Au1 N2 C31 -75(4) . . . . ?
Br1 Au1 N2 C31 51.0(4) . . . . ?
Au2 Au1 N2 C31 -132.6(4) . . . . ?
C5 C1 C2 C3 -2.2(6) . . . . ?
Au1 C1 C2 C3 162.8(4) . . . . ?
Fe1 C1 C2 C3 -61.1(4) . . . . ?
C5 C1 C2 C12 175.6(5) . . . . ?
Au1 C1 C2 C12 -19.4(8) . . . . ?
Fe1 C1 C2 C12 116.7(5) . . . . ?
C5 C1 C2 Fe1 58.9(4) . . . . ?
Au1 C1 C2 Fe1 -136.0(4) . . . . ?
C9 Fe1 C2 C1 -158.6(5) . . . . ?
C4 Fe1 C2 C1 -81.5(3) . . . . ?
C8 Fe1 C2 C1 165.3(3) . . . . ?
C7 Fe1 C2 C1 123.0(3) . . . . ?
C10 Fe1 C2 C1 47.5(9) . . . . ?
C5 Fe1 C2 C1 -37.9(3) . . . . ?
C3 Fe1 C2 C1 -119.2(5) . . . . ?
C6 Fe1 C2 C1 81.2(4) . . . . ?
C9 Fe1 C2 C3 -39.4(7) . . . . ?
C4 Fe1 C2 C3 37.7(3) . . . . ?
C8 Fe1 C2 C3 -75.5(4) . . . . ?
C7 Fe1 C2 C3 -117.7(3) . . . . ?
C10 Fe1 C2 C3 166.7(7) . . . . ?
C5 Fe1 C2 C3 81.4(3) . . . . ?
C1 Fe1 C2 C3 119.2(4) . . . . ?
C6 Fe1 C2 C3 -159.6(4) . . . . ?
C9 Fe1 C2 C12 82.2(7) . . . . ?
C4 Fe1 C2 C12 159.3(5) . . . . ?
C8 Fe1 C2 C12 46.1(5) . . . . ?
C7 Fe1 C2 C12 3.9(5) . . . . ?
C10 Fe1 C2 C12 -71.7(10) . . . . ?
C5 Fe1 C2 C12 -157.0(5) . . . . ?
C3 Fe1 C2 C12 121.6(6) . . . . ?
C1 Fe1 C2 C12 -119.2(5) . . . . ?
C6 Fe1 C2 C12 -37.9(6) . . . . ?
C1 C2 C3 C4 2.7(6) . . . . ?
C12 C2 C3 C4 -175.0(5) . . . . ?
Fe1 C2 C3 C4 -58.5(4) . . . . ?
C1 C2 C3 C11 -176.4(5) . . . . ?
C12 C2 C3 C11 5.9(9) . . . . ?
Fe1 C2 C3 C11 122.5(6) . . . . ?
C1 C2 C3 Fe1 61.2(4) . . . . ?
C12 C2 C3 Fe1 -116.5(6) . . . . ?
C2 Fe1 C3 C4 118.6(5) . . . . ?
C9 Fe1 C3 C4 -78.4(4) . . . . ?
C8 Fe1 C3 C4 -119.9(3) . . . . ?
C7 Fe1 C3 C4 -159.2(3) . . . . ?
C10 Fe1 C3 C4 -51.4(8) . . . . ?
C5 Fe1 C3 C4 37.0(3) . . . . ?
C1 Fe1 C3 C4 80.6(3) . . . . ?
C6 Fe1 C3 C4 175.3(6) . . . . ?
C9 Fe1 C3 C2 163.0(3) . . . . ?
C4 Fe1 C3 C2 -118.6(5) . . . . ?
C8 Fe1 C3 C2 121.5(3) . . . . ?
C7 Fe1 C3 C2 82.2(4) . . . . ?
C10 Fe1 C3 C2 -170.0(6) . . . . ?
C5 Fe1 C3 C2 -81.6(3) . . . . ?
C1 Fe1 C3 C2 -38.0(3) . . . . ?
C6 Fe1 C3 C2 56.7(8) . . . . ?
C2 Fe1 C3 C11 -122.6(6) . . . . ?
C9 Fe1 C3 C11 40.4(6) . . . . ?
C4 Fe1 C3 C11 118.8(6) . . . . ?
C8 Fe1 C3 C11 -1.1(5) . . . . ?
C7 Fe1 C3 C11 -40.5(6) . . . . ?
C10 Fe1 C3 C11 67.4(9) . . . . ?
C5 Fe1 C3 C11 155.8(5) . . . . ?
C1 Fe1 C3 C11 -160.6(5) . . . . ?
C6 Fe1 C3 C11 -65.9(9) . . . . ?
C2 C3 C4 C5 -2.2(6) . . . . ?
C11 C3 C4 C5 176.9(5) . . . . ?
Fe1 C3 C4 C5 -59.7(4) . . . . ?
C2 C3 C4 Fe1 57.5(3) . . . . ?
C11 C3 C4 Fe1 -123.4(6) . . . . ?
C2 Fe1 C4 C3 -38.6(3) . . . . ?
C9 Fe1 C4 C3 117.4(3) . . . . ?
C8 Fe1 C4 C3 76.3(4) . . . . ?
C7 Fe1 C4 C3 49.6(6) . . . . ?
C10 Fe1 C4 C3 157.9(3) . . . . ?
C5 Fe1 C4 C3 -120.4(4) . . . . ?
C1 Fe1 C4 C3 -83.2(3) . . . . ?
C6 Fe1 C4 C3 -175.4(6) . . . . ?
C2 Fe1 C4 C5 81.8(3) . . . . ?
C9 Fe1 C4 C5 -122.2(3) . . . . ?
C8 Fe1 C4 C5 -163.3(3) . . . . ?
C7 Fe1 C4 C5 170.0(5) . . . . ?
C10 Fe1 C4 C5 -81.7(4) . . . . ?
C3 Fe1 C4 C5 120.4(4) . . . . ?
C1 Fe1 C4 C5 37.2(3) . . . . ?
C6 Fe1 C4 C5 -55.0(7) . . . . ?
C3 C4 C5 C1 0.9(6) . . . . ?
Fe1 C4 C5 C1 -58.9(4) . . . . ?
C3 C4 C5 Fe1 59.8(4) . . . . ?
C2 C1 C5 C4 0.8(6) . . . . ?
Au1 C1 C5 C4 -164.5(4) . . . . ?
Fe1 C1 C5 C4 58.4(4) . . . . ?
C2 C1 C5 Fe1 -57.6(4) . . . . ?
Au1 C1 C5 Fe1 137.1(4) . . . . ?
C2 Fe1 C5 C4 -81.6(3) . . . . ?
C9 Fe1 C5 C4 74.4(4) . . . . ?
C8 Fe1 C5 C4 39.3(7) . . . . ?
C7 Fe1 C5 C4 -167.3(6) . . . . ?
C10 Fe1 C5 C4 117.4(3) . . . . ?
C3 Fe1 C5 C4 -36.9(3) . . . . ?
C1 Fe1 C5 C4 -120.2(4) . . . . ?
C6 Fe1 C5 C4 159.2(3) . . . . ?
C2 Fe1 C5 C1 38.6(3) . . . . ?
C9 Fe1 C5 C1 -165.4(3) . . . . ?
C4 Fe1 C5 C1 120.2(4) . . . . ?
C8 Fe1 C5 C1 159.5(5) . . . . ?
C7 Fe1 C5 C1 -47.1(8) . . . . ?
C10 Fe1 C5 C1 -122.4(3) . . . . ?
C3 Fe1 C5 C1 83.3(3) . . . . ?
C6 Fe1 C5 C1 -80.6(4) . . . . ?
C2 Fe1 C6 C7 77.0(4) . . . . ?
C9 Fe1 C6 C7 -81.0(4) . . . . ?
C4 Fe1 C6 C7 -154.5(6) . . . . ?
C8 Fe1 C6 C7 -36.8(3) . . . . ?
C10 Fe1 C6 C7 -118.4(5) . . . . ?
C5 Fe1 C6 C7 164.7(3) . . . . ?
C3 Fe1 C6 C7 34.2(8) . . . . ?
C1 Fe1 C6 C7 121.3(3) . . . . ?
C2 Fe1 C6 C10 -164.6(4) . . . . ?
C9 Fe1 C6 C10 37.4(4) . . . . ?
C4 Fe1 C6 C10 -36.1(8) . . . . ?
C8 Fe1 C6 C10 81.6(4) . . . . ?
C7 Fe1 C6 C10 118.4(5) . . . . ?
C5 Fe1 C6 C10 -76.9(4) . . . . ?
C3 Fe1 C6 C10 152.6(6) . . . . ?
C1 Fe1 C6 C10 -120.3(4) . . . . ?
C10 C6 C7 C8 0.1(7) . . . . ?
Fe1 C6 C7 C8 59.5(4) . . . . ?
C10 C6 C7 Fe1 -59.3(4) . . . . ?
C2 Fe1 C7 C8 116.8(3) . . . . ?
C9 Fe1 C7 C8 -38.0(3) . . . . ?
C4 Fe1 C7 C8 37.1(7) . . . . ?
C10 Fe1 C7 C8 -82.1(4) . . . . ?
C5 Fe1 C7 C8 -164.2(6) . . . . ?
C3 Fe1 C7 C8 72.9(4) . . . . ?
C1 Fe1 C7 C8 159.9(3) . . . . ?
C6 Fe1 C7 C8 -120.2(5) . . . . ?
C2 Fe1 C7 C6 -123.0(3) . . . . ?
C9 Fe1 C7 C6 82.1(3) . . . . ?
C4 Fe1 C7 C6 157.3(5) . . . . ?
C8 Fe1 C7 C6 120.2(5) . . . . ?
C10 Fe1 C7 C6 38.0(3) . . . . ?
C5 Fe1 C7 C6 -44.0(8) . . . . ?
C3 Fe1 C7 C6 -166.9(3) . . . . ?
C1 Fe1 C7 C6 -80.0(4) . . . . ?
C6 C7 C8 C9 -0.8(6) . . . . ?
Fe1 C7 C8 C9 59.2(4) . . . . ?
C6 C7 C8 Fe1 -60.0(4) . . . . ?
C2 Fe1 C8 C7 -82.0(4) . . . . ?
C9 Fe1 C8 C7 119.2(5) . . . . ?
C4 Fe1 C8 C7 -164.1(3) . . . . ?
C10 Fe1 C8 C7 80.8(4) . . . . ?
C5 Fe1 C8 C7 167.5(5) . . . . ?
C3 Fe1 C8 C7 -123.4(3) . . . . ?
C1 Fe1 C8 C7 -53.2(7) . . . . ?
C6 Fe1 C8 C7 37.1(3) . . . . ?
C2 Fe1 C8 C9 158.7(3) . . . . ?
C4 Fe1 C8 C9 76.7(4) . . . . ?
C7 Fe1 C8 C9 -119.2(5) . . . . ?
C10 Fe1 C8 C9 -38.4(3) . . . . ?
C5 Fe1 C8 C9 48.3(7) . . . . ?
C3 Fe1 C8 C9 117.3(3) . . . . ?
C1 Fe1 C8 C9 -172.5(5) . . . . ?
C6 Fe1 C8 C9 -82.1(4) . . . . ?
C7 C8 C9 C10 1.1(6) . . . . ?
Fe1 C8 C9 C10 60.7(4) . . . . ?
C7 C8 C9 Fe1 -59.6(4) . . . . ?
C2 Fe1 C9 C10 -167.9(5) . . . . ?
C4 Fe1 C9 C10 122.4(4) . . . . ?
C8 Fe1 C9 C10 -117.9(5) . . . . ?
C7 Fe1 C9 C10 -80.7(4) . . . . ?
C5 Fe1 C9 C10 82.2(4) . . . . ?
C3 Fe1 C9 C10 163.5(4) . . . . ?
C1 Fe1 C9 C10 54.8(8) . . . . ?
C6 Fe1 C9 C10 -37.1(4) . . . . ?
C2 Fe1 C9 C8 -50.1(7) . . . . ?
C4 Fe1 C9 C8 -119.7(3) . . . . ?
C7 Fe1 C9 C8 37.2(3) . . . . ?
C10 Fe1 C9 C8 117.9(5) . . . . ?
C5 Fe1 C9 C8 -159.9(3) . . . . ?
C3 Fe1 C9 C8 -78.7(4) . . . . ?
C1 Fe1 C9 C8 172.6(5) . . . . ?
C6 Fe1 C9 C8 80.8(4) . . . . ?
C7 C6 C10 C9 0.5(7) . . . . ?
Fe1 C6 C10 C9 -58.4(4) . . . . ?
C7 C6 C10 Fe1 59.0(4) . . . . ?
C8 C9 C10 C6 -1.0(7) . . . . ?
Fe1 C9 C10 C6 59.3(4) . . . . ?
C8 C9 C10 Fe1 -60.3(4) . . . . ?
C2 Fe1 C10 C6 44.3(10) . . . . ?
C9 Fe1 C10 C6 -119.9(6) . . . . ?
C4 Fe1 C10 C6 165.8(4) . . . . ?
C8 Fe1 C10 C6 -81.3(4) . . . . ?
C7 Fe1 C10 C6 -38.0(4) . . . . ?
C5 Fe1 C10 C6 123.0(4) . . . . ?
C3 Fe1 C10 C6 -157.5(6) . . . . ?
C1 Fe1 C10 C6 80.8(4) . . . . ?
C2 Fe1 C10 C9 164.2(7) . . . . ?
C4 Fe1 C10 C9 -74.2(4) . . . . ?
C8 Fe1 C10 C9 38.6(4) . . . . ?
C7 Fe1 C10 C9 81.9(4) . . . . ?
C5 Fe1 C10 C9 -117.0(4) . . . . ?
C3 Fe1 C10 C9 -37.6(8) . . . . ?
C1 Fe1 C10 C9 -159.2(3) . . . . ?
C6 Fe1 C10 C9 119.9(6) . . . . ?
C14 N1 C12 O1 -0.8(7) . . . . ?
Au2 N1 C12 O1 172.8(4) . . . . ?
C14 N1 C12 C2 177.7(5) . . . . ?
Au2 N1 C12 C2 -8.8(8) . . . . ?
C13 O1 C12 N1 -2.5(7) . . . . ?
C13 O1 C12 C2 178.9(5) . . . . ?
C1 C2 C12 N1 -18.5(9) . . . . ?
C3 C2 C12 N1 158.9(5) . . . . ?
Fe1 C2 C12 N1 69.6(7) . . . . ?
C1 C2 C12 O1 159.9(5) . . . . ?
C3 C2 C12 O1 -22.6(8) . . . . ?
Fe1 C2 C12 O1 -111.9(5) . . . . ?
C12 O1 C13 C14 4.5(6) . . . . ?
C12 N1 C14 C15 -120.8(5) . . . . ?
Au2 N1 C14 C15 65.4(6) . . . . ?
C12 N1 C14 C13 3.5(6) . . . . ?
Au2 N1 C14 C13 -170.3(4) . . . . ?
O1 C13 C14 N1 -4.7(6) . . . . ?
O1 C13 C14 C15 116.4(5) . . . . ?
N1 C14 C15 C17 -175.5(5) . . . . ?
C13 C14 C15 C17 68.6(7) . . . . ?
N1 C14 C15 C16 58.8(7) . . . . ?
C13 C14 C15 C16 -57.1(7) . . . . ?
N1 Au2 C18 C22 -161(2) . . . . ?
Br2 Au2 C18 C22 34.5(5) . . . . ?
Au1 Au2 C18 C22 -142.1(5) . . . . ?
N1 Au2 C18 C19 31(3) . . . . ?
Br2 Au2 C18 C19 -133.8(5) . . . . ?
Au1 Au2 C18 C19 49.5(5) . . . . ?
N1 Au2 C18 Fe2 -65(3) . . . . ?
Br2 Au2 C18 Fe2 130.0(4) . . . . ?
Au1 Au2 C18 Fe2 -46.6(4) . . . . ?
C19 Fe2 C18 C22 -117.9(4) . . . . ?
C26 Fe2 C18 C22 35.1(8) . . . . ?
C21 Fe2 C18 C22 -37.1(3) . . . . ?
C20 Fe2 C18 C22 -80.5(3) . . . . ?
C25 Fe2 C18 C22 -157.0(6) . . . . ?
C24 Fe2 C18 C22 161.9(3) . . . . ?
C27 Fe2 C18 C22 74.2(4) . . . . ?
C23 Fe2 C18 C22 118.9(3) . . . . ?
C22 Fe2 C18 C19 117.9(4) . . . . ?
C26 Fe2 C18 C19 153.0(6) . . . . ?
C21 Fe2 C18 C19 80.8(3) . . . . ?
C20 Fe2 C18 C19 37.4(3) . . . . ?
C25 Fe2 C18 C19 -39.1(7) . . . . ?
C24 Fe2 C18 C19 -80.2(4) . . . . ?
C27 Fe2 C18 C19 -168.0(3) . . . . ?
C23 Fe2 C18 C19 -123.2(3) . . . . ?
C19 Fe2 C18 Au2 122.1(5) . . . . ?
C22 Fe2 C18 Au2 -120.0(6) . . . . ?
C26 Fe2 C18 Au2 -84.9(7) . . . . ?
C21 Fe2 C18 Au2 -157.1(5) . . . . ?
C20 Fe2 C18 Au2 159.6(5) . . . . ?
C25 Fe2 C18 Au2 83.0(8) . . . . ?
C24 Fe2 C18 Au2 41.9(6) . . . . ?
C27 Fe2 C18 Au2 -45.8(5) . . . . ?
C23 Fe2 C18 Au2 -1.1(5) . . . . ?
C22 C18 C19 C29 179.6(5) . . . . ?
Au2 C18 C19 C29 -10.2(8) . . . . ?
Fe2 C18 C19 C29 120.7(5) . . . . ?
C22 C18 C19 C20 -0.3(6) . . . . ?
Au2 C18 C19 C20 169.9(4) . . . . ?
Fe2 C18 C19 C20 -59.2(4) . . . . ?
C22 C18 C19 Fe2 58.9(4) . . . . ?
Au2 C18 C19 Fe2 -130.9(4) . . . . ?
C22 Fe2 C19 C29 -157.0(5) . . . . ?
C26 Fe2 C19 C29 83.3(7) . . . . ?
C21 Fe2 C19 C29 159.1(6) . . . . ?
C20 Fe2 C19 C29 121.0(6) . . . . ?
C25 Fe2 C19 C29 46.5(5) . . . . ?
C18 Fe2 C19 C29 -118.7(6) . . . . ?
C24 Fe2 C19 C29 2.8(5) . . . . ?
C27 Fe2 C19 C29 -77.7(12) . . . . ?
C23 Fe2 C19 C29 -38.5(6) . . . . ?
C22 Fe2 C19 C20 81.9(4) . . . . ?
C26 Fe2 C19 C20 -37.7(7) . . . . ?
C21 Fe2 C19 C20 38.1(4) . . . . ?
C25 Fe2 C19 C20 -74.6(4) . . . . ?
C18 Fe2 C19 C20 120.2(4) . . . . ?
C24 Fe2 C19 C20 -118.2(4) . . . . ?
C27 Fe2 C19 C20 161.3(9) . . . . ?
C23 Fe2 C19 C20 -159.5(4) . . . . ?
C22 Fe2 C19 C18 -38.3(3) . . . . ?
C26 Fe2 C19 C18 -158.0(5) . . . . ?
C21 Fe2 C19 C18 -82.2(3) . . . . ?
C20 Fe2 C19 C18 -120.2(4) . . . . ?
C25 Fe2 C19 C18 165.2(3) . . . . ?
C24 Fe2 C19 C18 121.5(3) . . . . ?
C27 Fe2 C19 C18 41.0(11) . . . . ?
C23 Fe2 C19 C18 80.2(4) . . . . ?
C29 C19 C20 C21 179.9(5) . . . . ?
C18 C19 C20 C21 -0.2(6) . . . . ?
Fe2 C19 C20 C21 -59.4(4) . . . . ?
C29 C19 C20 C28 0.7(9) . . . . ?
C18 C19 C20 C28 -179.3(5) . . . . ?
Fe2 C19 C20 C28 121.4(6) . . . . ?
C29 C19 C20 Fe2 -120.7(5) . . . . ?
C18 C19 C20 Fe2 59.2(4) . . . . ?
C19 Fe2 C20 C21 118.1(5) . . . . ?
C22 Fe2 C20 C21 36.5(3) . . . . ?
C26 Fe2 C20 C21 -78.9(4) . . . . ?
C25 Fe2 C20 C21 -120.1(4) . . . . ?
C18 Fe2 C20 C21 80.2(4) . . . . ?
C24 Fe2 C20 C21 -159.4(4) . . . . ?
C27 Fe2 C20 C21 -51.7(7) . . . . ?
C23 Fe2 C20 C21 -179.9(7) . . . . ?
C22 Fe2 C20 C19 -81.6(4) . . . . ?
C26 Fe2 C20 C19 163.0(4) . . . . ?
C21 Fe2 C20 C19 -118.1(5) . . . . ?
C25 Fe2 C20 C19 121.8(4) . . . . ?
C18 Fe2 C20 C19 -37.9(3) . . . . ?
C24 Fe2 C20 C19 82.5(4) . . . . ?
C27 Fe2 C20 C19 -169.8(5) . . . . ?
C23 Fe2 C20 C19 62.0(8) . . . . ?
C19 Fe2 C20 C28 -119.7(6) . . . . ?
C22 Fe2 C20 C28 158.7(6) . . . . ?
C26 Fe2 C20 C28 43.2(6) . . . . ?
C21 Fe2 C20 C28 122.2(6) . . . . ?
C25 Fe2 C20 C28 2.1(5) . . . . ?
C18 Fe2 C20 C28 -157.6(6) . . . . ?
C24 Fe2 C20 C28 -37.2(6) . . . . ?
C27 Fe2 C20 C28 70.5(8) . . . . ?
C23 Fe2 C20 C28 -57.7(9) . . . . ?
C19 C20 C21 C22 0.7(6) . . . . ?
C28 C20 C21 C22 179.8(5) . . . . ?
Fe2 C20 C21 C22 -58.0(4) . . . . ?
C19 C20 C21 Fe2 58.7(3) . . . . ?
C28 C20 C21 Fe2 -122.2(6) . . . . ?
C19 Fe2 C21 C20 -39.0(3) . . . . ?
C22 Fe2 C21 C20 -121.6(5) . . . . ?
C26 Fe2 C21 C20 115.9(4) . . . . ?
C25 Fe2 C21 C20 75.4(4) . . . . ?
C18 Fe2 C21 C20 -84.3(4) . . . . ?
C24 Fe2 C21 C20 51.1(7) . . . . ?
C27 Fe2 C21 C20 155.3(4) . . . . ?
C23 Fe2 C21 C20 179.9(5) . . . . ?
C19 Fe2 C21 C22 82.6(3) . . . . ?
C26 Fe2 C21 C22 -122.5(3) . . . . ?
C20 Fe2 C21 C22 121.6(5) . . . . ?
C25 Fe2 C21 C22 -163.0(3) . . . . ?
C18 Fe2 C21 C22 37.3(3) . . . . ?
C24 Fe2 C21 C22 172.7(5) . . . . ?
C27 Fe2 C21 C22 -83.1(4) . . . . ?
C23 Fe2 C21 C22 -58.5(7) . . . . ?
C20 C21 C22 C18 -0.9(6) . . . . ?
Fe2 C21 C22 C18 -59.2(4) . . . . ?
C20 C21 C22 Fe2 58.3(4) . . . . ?
C19 C18 C22 C21 0.7(6) . . . . ?
Au2 C18 C22 C21 -169.7(4) . . . . ?
Fe2 C18 C22 C21 59.0(4) . . . . ?
C19 C18 C22 Fe2 -58.2(4) . . . . ?
Au2 C18 C22 Fe2 131.3(4) . . . . ?
C19 Fe2 C22 C21 -81.0(3) . . . . ?
C26 Fe2 C22 C21 73.4(4) . . . . ?
C20 Fe2 C22 C21 -36.3(3) . . . . ?
C25 Fe2 C22 C21 39.8(7) . . . . ?
C18 Fe2 C22 C21 -120.3(5) . . . . ?
C24 Fe2 C22 C21 -171.5(6) . . . . ?
C27 Fe2 C22 C21 114.4(3) . . . . ?
C23 Fe2 C22 C21 156.7(3) . . . . ?
C19 Fe2 C22 C18 39.3(3) . . . . ?
C26 Fe2 C22 C18 -166.3(3) . . . . ?
C21 Fe2 C22 C18 120.3(5) . . . . ?
C20 Fe2 C22 C18 84.0(3) . . . . ?
C25 Fe2 C22 C18 160.1(5) . . . . ?
C24 Fe2 C22 C18 -51.2(8) . . . . ?
C27 Fe2 C22 C18 -125.3(3) . . . . ?
C23 Fe2 C22 C18 -83.0(4) . . . . ?
C19 Fe2 C23 C24 75.0(4) . . . . ?
C22 Fe2 C23 C24 164.6(3) . . . . ?
C26 Fe2 C23 C24 -81.9(4) . . . . ?
C21 Fe2 C23 C24 -152.7(6) . . . . ?
C20 Fe2 C23 C24 27.1(9) . . . . ?
C25 Fe2 C23 C24 -37.9(3) . . . . ?
C18 Fe2 C23 C24 120.3(4) . . . . ?
C27 Fe2 C23 C24 -119.2(5) . . . . ?
C19 Fe2 C23 C27 -165.8(4) . . . . ?
C22 Fe2 C23 C27 -76.2(4) . . . . ?
C26 Fe2 C23 C27 37.3(4) . . . . ?
C21 Fe2 C23 C27 -33.5(8) . . . . ?
C20 Fe2 C23 C27 146.3(7) . . . . ?
C25 Fe2 C23 C27 81.3(4) . . . . ?
C18 Fe2 C23 C27 -120.5(4) . . . . ?
C24 Fe2 C23 C27 119.2(5) . . . . ?
C27 C23 C24 C25 0.8(6) . . . . ?
Fe2 C23 C24 C25 59.4(4) . . . . ?
C27 C23 C24 Fe2 -58.6(4) . . . . ?
C19 Fe2 C24 C23 -125.8(3) . . . . ?
C22 Fe2 C24 C23 -42.3(8) . . . . ?
C26 Fe2 C24 C23 81.2(4) . . . . ?
C21 Fe2 C24 C23 152.5(5) . . . . ?
C20 Fe2 C24 C23 -170.2(3) . . . . ?
C25 Fe2 C24 C23 119.3(5) . . . . ?
C18 Fe2 C24 C23 -81.2(4) . . . . ?
C27 Fe2 C24 C23 38.4(3) . . . . ?
C19 Fe2 C24 C25 114.9(4) . . . . ?
C22 Fe2 C24 C25 -161.5(6) . . . . ?
C26 Fe2 C24 C25 -38.1(3) . . . . ?
C21 Fe2 C24 C25 33.2(7) . . . . ?
C20 Fe2 C24 C25 70.5(4) . . . . ?
C18 Fe2 C24 C25 159.6(3) . . . . ?
C27 Fe2 C24 C25 -80.9(4) . . . . ?
C23 Fe2 C24 C25 -119.3(5) . . . . ?
C23 C24 C25 C26 -0.8(6) . . . . ?
Fe2 C24 C25 C26 59.2(4) . . . . ?
C23 C24 C25 Fe2 -60.0(4) . . . . ?
C19 Fe2 C25 C26 156.9(3) . . . . ?
C22 Fe2 C25 C26 46.6(7) . . . . ?
C21 Fe2 C25 C26 75.3(4) . . . . ?
C20 Fe2 C25 C26 115.7(3) . . . . ?
C18 Fe2 C25 C26 -173.5(6) . . . . ?
C24 Fe2 C25 C26 -118.5(5) . . . . ?
C27 Fe2 C25 C26 -36.4(3) . . . . ?
C23 Fe2 C25 C26 -81.2(3) . . . . ?
C19 Fe2 C25 C24 -84.6(4) . . . . ?
C22 Fe2 C25 C24 165.1(5) . . . . ?
C26 Fe2 C25 C24 118.5(5) . . . . ?
C21 Fe2 C25 C24 -166.2(3) . . . . ?
C20 Fe2 C25 C24 -125.8(3) . . . . ?
C18 Fe2 C25 C24 -55.0(7) . . . . ?
C27 Fe2 C25 C24 82.1(4) . . . . ?
C23 Fe2 C25 C24 37.2(3) . . . . ?
C24 C25 C26 C27 0.4(6) . . . . ?
Fe2 C25 C26 C27 60.0(4) . . . . ?
C24 C25 C26 Fe2 -59.6(4) . . . . ?
C19 Fe2 C26 C27 -172.5(5) . . . . ?
C22 Fe2 C26 C27 79.3(4) . . . . ?
C21 Fe2 C26 C27 119.4(4) . . . . ?
C20 Fe2 C26 C27 160.4(4) . . . . ?
C25 Fe2 C26 C27 -120.4(5) . . . . ?
C18 Fe2 C26 C27 53.2(8) . . . . ?
C24 Fe2 C26 C27 -82.3(4) . . . . ?
C23 Fe2 C26 C27 -38.9(4) . . . . ?
C19 Fe2 C26 C25 -52.0(7) . . . . ?
C22 Fe2 C26 C25 -160.2(3) . . . . ?
C21 Fe2 C26 C25 -120.2(3) . . . . ?
C20 Fe2 C26 C25 -79.1(4) . . . . ?
C18 Fe2 C26 C25 173.6(5) . . . . ?
C24 Fe2 C26 C25 38.2(3) . . . . ?
C27 Fe2 C26 C25 120.4(5) . . . . ?
C23 Fe2 C26 C25 81.5(4) . . . . ?
C25 C26 C27 C23 0.1(6) . . . . ?
Fe2 C26 C27 C23 59.7(4) . . . . ?
C25 C26 C27 Fe2 -59.6(4) . . . . ?
C24 C23 C27 C26 -0.6(6) . . . . ?
Fe2 C23 C27 C26 -59.6(4) . . . . ?
C24 C23 C27 Fe2 59.0(4) . . . . ?
C19 Fe2 C27 C26 167.4(9) . . . . ?
C22 Fe2 C27 C26 -118.3(4) . . . . ?
C21 Fe2 C27 C26 -75.5(5) . . . . ?
C20 Fe2 C27 C26 -39.8(8) . . . . ?
C25 Fe2 C27 C26 37.3(4) . . . . ?
C18 Fe2 C27 C26 -159.6(4) . . . . ?
C24 Fe2 C27 C26 81.3(4) . . . . ?
C23 Fe2 C27 C26 118.4(6) . . . . ?
C19 Fe2 C27 C23 49.0(12) . . . . ?
C22 Fe2 C27 C23 123.3(4) . . . . ?
C26 Fe2 C27 C23 -118.4(6) . . . . ?
C21 Fe2 C27 C23 166.1(4) . . . . ?
C20 Fe2 C27 C23 -158.2(5) . . . . ?
C25 Fe2 C27 C23 -81.1(4) . . . . ?
C18 Fe2 C27 C23 81.9(4) . . . . ?
C24 Fe2 C27 C23 -37.1(4) . . . . ?
C31 N2 C29 O2 -5.2(6) . . . . ?
Au1 N2 C29 O2 169.2(3) . . . . ?
C31 N2 C29 C19 172.6(5) . . . . ?
Au1 N2 C29 C19 -12.9(8) . . . . ?
C30 O2 C29 N2 -7.8(6) . . . . ?
C30 O2 C29 C19 174.2(4) . . . . ?
C20 C19 C29 N2 158.5(5) . . . . ?
C18 C19 C29 N2 -21.4(9) . . . . ?
Fe2 C19 C29 N2 67.8(7) . . . . ?
C20 C19 C29 O2 -23.7(8) . . . . ?
C18 C19 C29 O2 156.4(5) . . . . ?
Fe2 C19 C29 O2 -114.3(5) . . . . ?
C29 O2 C30 C31 16.3(5) . . . . ?
C29 N2 C31 C32 -109.8(5) . . . . ?
Au1 N2 C31 C32 76.2(5) . . . . ?
C29 N2 C31 C30 14.9(6) . . . . ?
Au1 N2 C31 C30 -159.1(3) . . . . ?
O2 C30 C31 N2 -18.3(5) . . . . ?
O2 C30 C31 C32 102.4(5) . . . . ?
N2 C31 C32 C33 57.4(6) . . . . ?
C30 C31 C32 C33 -58.6(7) . . . . ?
N2 C31 C32 C34 -177.5(4) . . . . ?
C30 C31 C32 C34 66.5(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        30.56
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         1.701
_refine_diff_density_min         -1.432
_refine_diff_density_rms         0.189
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2205lc
_database_code_depnum_ccdc_archive 'CCDC 1588445'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 (Rp)-iPrFOAu(I)' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H36 Au2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C32 H36 Au2 Fe2 N2 O2'
_chemical_formula_weight         986.26

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe -1.1336 3.1974 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   6.7822(6)
_cell_length_b                   12.1326(9)
_cell_length_c                   37.407(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3078.1(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    4271
_cell_measurement_theta_min      2.36
_cell_measurement_theta_max      66.24

_exptl_crystal_description       needle
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.128
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1872
_exptl_absorpt_coefficient_mu    25.166
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4366
_exptl_absorpt_correction_T_max  0.7528
_exptl_absorpt_process_details   'Blessing, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         I\mS
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            22130
_diffrn_reflns_av_R_equivalents  0.0773
_diffrn_reflns_av_sigmaI/netI    0.0655
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         2.36
_diffrn_reflns_theta_max         66.24
_reflns_number_total             5275
_reflns_number_gt                4271
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0008P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000026(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.007(10)
_refine_ls_number_reflns         5275
_refine_ls_number_parameters     366
_refine_ls_number_restraints     216
_refine_ls_R_factor_all          0.0501
_refine_ls_R_factor_gt           0.0331
_refine_ls_wR_factor_ref         0.0628
_refine_ls_wR_factor_gt          0.0594
_refine_ls_goodness_of_fit_ref   0.987
_refine_ls_restrained_S_all      0.976
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.44347(5) 0.02348(4) 0.877288(12) 0.01699(10) Uani 1 1 d . . .
Fe1 Fe 0.3414(2) 0.32686(11) 0.86701(4) 0.0157(3) Uani 1 1 d . . .
Au2 Au 0.02301(5) 0.02459(4) 0.876701(11) 0.01725(10) Uani 1 1 d . . .
Fe2 Fe 0.1180(2) -0.08262(12) 0.78383(4) 0.0192(3) Uani 1 1 d . . .
N1 N 0.0181(11) 0.1323(6) 0.92089(18) 0.0166(16) Uani 1 1 d U . .
O1 O 0.0823(9) 0.2649(5) 0.95956(16) 0.0193(14) Uani 1 1 d U . .
C1 C 0.4516(13) 0.1829(7) 0.8907(2) 0.021(2) Uani 1 1 d U . .
N2 N 0.4472(10) -0.1425(5) 0.86505(18) 0.0173(16) Uani 1 1 d U . .
O2 O 0.3924(10) -0.3074(5) 0.84014(17) 0.0249(16) Uani 1 1 d U . .
C2 C 0.3217(13) 0.2430(7) 0.9142(2) 0.016(2) Uani 1 1 d U . .
C3 C 0.4017(14) 0.3536(7) 0.9192(2) 0.018(2) Uani 1 1 d U . .
H3 H 0.3450 0.4109 0.9331 0.022 Uiso 1 1 calc R . .
C4 C 0.5789(14) 0.3598(7) 0.8994(2) 0.022(2) Uani 1 1 d U . .
H4 H 0.6632 0.4222 0.8981 0.027 Uiso 1 1 calc R . .
C5 C 0.6100(13) 0.2574(7) 0.8819(2) 0.018(2) Uani 1 1 d U . .
H5 H 0.7183 0.2405 0.8668 0.022 Uiso 1 1 calc R . .
C6 C 0.1378(15) 0.2824(8) 0.8292(3) 0.026(2) Uani 1 1 d U . .
H6 H 0.0804 0.2116 0.8263 0.031 Uiso 1 1 calc R . .
C7 C 0.0646(14) 0.3694(7) 0.8511(2) 0.020(2) Uani 1 1 d U . .
H7 H -0.0505 0.3664 0.8655 0.025 Uiso 1 1 calc R . .
C8 C 0.1922(12) 0.4605(7) 0.8476(2) 0.017(2) Uani 1 1 d U . .
H8 H 0.1785 0.5296 0.8593 0.020 Uiso 1 1 calc R . .
C9 C 0.3440(14) 0.4301(8) 0.8238(3) 0.024(2) Uani 1 1 d U . .
H9 H 0.4508 0.4755 0.8165 0.029 Uiso 1 1 calc R . .
C10 C 0.3096(13) 0.3207(8) 0.8126(2) 0.022(2) Uani 1 1 d U . .
H10 H 0.3899 0.2798 0.7966 0.026 Uiso 1 1 calc R . .
C11 C 0.1373(14) 0.2081(8) 0.9292(2) 0.018(2) Uani 1 1 d U . .
C12 C -0.1412(13) 0.1202(7) 0.9477(2) 0.017(2) Uani 1 1 d U . .
H12 H -0.2715 0.1254 0.9353 0.021 Uiso 1 1 calc R . .
C13 C -0.1097(14) 0.2244(7) 0.9700(2) 0.024(2) Uani 1 1 d U . .
H13A H -0.2130 0.2798 0.9648 0.028 Uiso 1 1 calc R . .
H13B H -0.1126 0.2070 0.9958 0.028 Uiso 1 1 calc R . .
C14 C -0.1275(13) 0.0113(8) 0.9662(2) 0.024(2) Uani 1 1 d U . .
H14 H -0.1306 -0.0469 0.9472 0.029 Uiso 1 1 calc R . .
C15 C -0.3085(14) -0.0072(7) 0.9903(2) 0.027(2) Uani 1 1 d U . .
H15A H -0.3148 0.0513 1.0083 0.040 Uiso 1 1 calc R . .
H15B H -0.2972 -0.0789 1.0022 0.040 Uiso 1 1 calc R . .
H15C H -0.4285 -0.0057 0.9757 0.040 Uiso 1 1 calc R . .
C16 C 0.0643(15) -0.0041(8) 0.9872(3) 0.033(3) Uani 1 1 d U . .
H16A H 0.1768 0.0001 0.9708 0.050 Uiso 1 1 calc R . .
H16B H 0.0633 -0.0763 0.9990 0.050 Uiso 1 1 calc R . .
H16C H 0.0756 0.0540 1.0053 0.050 Uiso 1 1 calc R . .
C17 C 0.0143(14) -0.0851(7) 0.8361(2) 0.022(2) Uani 1 1 d U . .
C18 C 0.1458(14) -0.1745(8) 0.8290(3) 0.021(2) Uani 1 1 d U . .
C19 C 0.0655(15) -0.2398(8) 0.8000(3) 0.028(2) Uani 1 1 d U . .
H19 H 0.1227 -0.3041 0.7899 0.034 Uiso 1 1 calc R . .
C20 C -0.1128(14) -0.1903(8) 0.7898(3) 0.027(2) Uani 1 1 d U . .
H20 H -0.1993 -0.2161 0.7717 0.032 Uiso 1 1 calc R . .
C21 C -0.1418(14) -0.0955(8) 0.8110(2) 0.022(2) Uani 1 1 d U . .
H21 H -0.2497 -0.0460 0.8089 0.027 Uiso 1 1 calc R . .
C22 C 0.3195(13) 0.0410(8) 0.7775(3) 0.027(2) Uani 1 1 d U . .
H22 H 0.3852 0.0797 0.7961 0.033 Uiso 1 1 calc R . .
C23 C 0.3854(14) -0.0578(8) 0.7603(2) 0.025(2) Uani 1 1 d U . .
H23 H 0.5026 -0.0974 0.7656 0.030 Uiso 1 1 calc R . .
C24 C 0.2432(16) -0.0858(7) 0.7338(2) 0.029(2) Uani 1 1 d U . .
H24 H 0.2487 -0.1474 0.7182 0.035 Uiso 1 1 calc R . .
C25 C 0.0946(15) -0.0066(7) 0.7350(2) 0.028(2) Uani 1 1 d U . .
H25 H -0.0187 -0.0048 0.7201 0.034 Uiso 1 1 calc R . .
C26 C 0.1397(15) 0.0695(9) 0.7616(3) 0.031(3) Uani 1 1 d U . .
H26 H 0.0608 0.1311 0.7680 0.037 Uiso 1 1 calc R . .
C27 C 0.3338(14) -0.2014(8) 0.8456(3) 0.022(2) Uani 1 1 d U . .
C28 C 0.6101(13) -0.2140(7) 0.8791(3) 0.022(2) Uani 1 1 d U . .
H28 H 0.7402 -0.1789 0.8737 0.027 Uiso 1 1 calc R . .
C29 C 0.5864(15) -0.3178(8) 0.8564(3) 0.028(2) Uani 1 1 d U . .
H29A H 0.6903 -0.3219 0.8379 0.034 Uiso 1 1 calc R . .
H29B H 0.5938 -0.3847 0.8715 0.034 Uiso 1 1 calc R . .
C30 C 0.5881(15) -0.2291(8) 0.9196(3) 0.029(2) Uani 1 1 d U . .
H30 H 0.5891 -0.1537 0.9304 0.035 Uiso 1 1 calc R . .
C31 C 0.3963(16) -0.2822(9) 0.9304(3) 0.040(3) Uani 1 1 d U . .
H31A H 0.3979 -0.3602 0.9235 0.060 Uiso 1 1 calc R . .
H31B H 0.2869 -0.2449 0.9183 0.060 Uiso 1 1 calc R . .
H31C H 0.3794 -0.2761 0.9563 0.060 Uiso 1 1 calc R . .
C32 C 0.7673(17) -0.2904(8) 0.9348(3) 0.038(2) Uani 1 1 d U . .
H32A H 0.7549 -0.2962 0.9608 0.057 Uiso 1 1 calc R . .
H32B H 0.8878 -0.2499 0.9288 0.057 Uiso 1 1 calc R . .
H32C H 0.7737 -0.3645 0.9244 0.057 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.000(9) . ?
Au1 N2 2.066(6) . ?
Au1 Au2 2.8518(5) . ?
Fe1 C3 2.020(9) . ?
Fe1 C7 2.036(9) . ?
Fe1 C2 2.043(9) . ?
Fe1 C8 2.043(8) . ?
Fe1 C9 2.045(10) . ?
Fe1 C10 2.046(9) . ?
Fe1 C6 2.050(10) . ?
Fe1 C4 2.055(9) . ?
Fe1 C5 2.084(9) . ?
Fe1 C1 2.097(9) . ?
Au2 C17 2.019(9) . ?
Au2 N1 2.107(7) . ?
Fe2 C26 2.029(11) . ?
Fe2 C19 2.033(9) . ?
Fe2 C18 2.033(10) . ?
Fe2 C23 2.038(10) . ?
Fe2 C21 2.041(9) . ?
Fe2 C22 2.043(10) . ?
Fe2 C20 2.051(10) . ?
Fe2 C25 2.052(9) . ?
Fe2 C24 2.055(9) . ?
Fe2 C17 2.080(9) . ?
N1 C11 1.264(11) . ?
N1 C12 1.480(11) . ?
O1 C11 1.379(10) . ?
O1 C13 1.446(11) . ?
C1 C2 1.442(12) . ?
C1 C5 1.442(12) . ?
N2 C27 1.277(11) . ?
N2 C28 1.499(11) . ?
O2 C27 1.362(11) . ?
O2 C29 1.456(11) . ?
C2 C11 1.435(12) . ?
C2 C3 1.459(12) . ?
C3 C4 1.413(13) . ?
C3 H3 0.9500 . ?
C4 C5 1.421(12) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C10 1.398(13) . ?
C6 C7 1.425(13) . ?
C6 H6 0.9500 . ?
C7 C8 1.410(12) . ?
C7 H7 0.9500 . ?
C8 C9 1.411(12) . ?
C8 H8 0.9500 . ?
C9 C10 1.411(13) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C14 1.495(12) . ?
C12 C13 1.530(12) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C16 1.532(14) . ?
C14 C15 1.540(12) . ?
C14 H14 1.0000 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C21 1.421(13) . ?
C17 C18 1.430(13) . ?
C18 C19 1.448(13) . ?
C18 C27 1.456(13) . ?
C19 C20 1.404(14) . ?
C19 H19 0.9500 . ?
C20 C21 1.412(13) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C26 1.400(13) . ?
C22 C23 1.432(13) . ?
C22 H22 0.9500 . ?
C23 C24 1.423(13) . ?
C23 H23 0.9500 . ?
C24 C25 1.393(13) . ?
C24 H24 0.9500 . ?
C25 C26 1.392(13) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C28 C29 1.526(13) . ?
C28 C30 1.535(14) . ?
C28 H28 1.0000 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.506(14) . ?
C30 C32 1.534(13) . ?
C30 H30 1.0000 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 177.1(3) . . ?
C1 Au1 Au2 91.4(3) . . ?
N2 Au1 Au2 90.9(2) . . ?
C3 Fe1 C7 115.4(4) . . ?
C3 Fe1 C2 42.1(3) . . ?
C7 Fe1 C2 108.6(4) . . ?
C3 Fe1 C8 108.4(3) . . ?
C7 Fe1 C8 40.4(3) . . ?
C2 Fe1 C8 132.0(3) . . ?
C3 Fe1 C9 131.6(4) . . ?
C7 Fe1 C9 67.8(4) . . ?
C2 Fe1 C9 171.5(4) . . ?
C8 Fe1 C9 40.4(3) . . ?
C3 Fe1 C10 170.8(4) . . ?
C7 Fe1 C10 67.7(4) . . ?
C2 Fe1 C10 146.5(4) . . ?
C8 Fe1 C10 68.0(3) . . ?
C9 Fe1 C10 40.3(4) . . ?
C3 Fe1 C6 147.8(4) . . ?
C7 Fe1 C6 40.8(4) . . ?
C2 Fe1 C6 115.0(4) . . ?
C8 Fe1 C6 68.3(4) . . ?
C9 Fe1 C6 67.7(4) . . ?
C10 Fe1 C6 39.9(4) . . ?
C3 Fe1 C4 40.6(4) . . ?
C7 Fe1 C4 147.8(4) . . ?
C2 Fe1 C4 68.8(3) . . ?
C8 Fe1 C4 116.3(3) . . ?
C9 Fe1 C4 109.9(4) . . ?
C10 Fe1 C4 132.5(4) . . ?
C6 Fe1 C4 170.6(4) . . ?
C3 Fe1 C5 68.2(4) . . ?
C7 Fe1 C5 170.8(3) . . ?
C2 Fe1 C5 67.9(3) . . ?
C8 Fe1 C5 148.1(3) . . ?
C9 Fe1 C5 116.9(4) . . ?
C10 Fe1 C5 110.1(4) . . ?
C6 Fe1 C5 131.9(4) . . ?
C4 Fe1 C5 40.1(3) . . ?
C3 Fe1 C1 69.7(3) . . ?
C7 Fe1 C1 131.6(4) . . ?
C2 Fe1 C1 40.7(3) . . ?
C8 Fe1 C1 170.8(4) . . ?
C9 Fe1 C1 147.3(4) . . ?
C10 Fe1 C1 115.3(4) . . ?
C6 Fe1 C1 108.3(4) . . ?
C4 Fe1 C1 68.5(3) . . ?
C5 Fe1 C1 40.4(3) . . ?
C17 Au2 N1 176.1(3) . . ?
C17 Au2 Au1 91.8(3) . . ?
N1 Au2 Au1 90.7(2) . . ?
C26 Fe2 C19 171.2(4) . . ?
C26 Fe2 C18 146.3(4) . . ?
C19 Fe2 C18 41.7(4) . . ?
C26 Fe2 C23 67.9(4) . . ?
C19 Fe2 C23 115.0(4) . . ?
C18 Fe2 C23 110.9(4) . . ?
C26 Fe2 C21 109.7(4) . . ?
C19 Fe2 C21 68.2(4) . . ?
C18 Fe2 C21 67.9(4) . . ?
C23 Fe2 C21 174.2(4) . . ?
C26 Fe2 C22 40.2(4) . . ?
C19 Fe2 C22 147.2(4) . . ?
C18 Fe2 C22 115.9(4) . . ?
C23 Fe2 C22 41.1(4) . . ?
C21 Fe2 C22 133.7(4) . . ?
C26 Fe2 C20 132.8(4) . . ?
C19 Fe2 C20 40.2(4) . . ?
C18 Fe2 C20 68.3(4) . . ?
C23 Fe2 C20 145.1(4) . . ?
C21 Fe2 C20 40.4(4) . . ?
C22 Fe2 C20 172.2(4) . . ?
C26 Fe2 C25 39.9(4) . . ?
C19 Fe2 C25 132.3(4) . . ?
C18 Fe2 C25 173.3(4) . . ?
C23 Fe2 C25 67.5(4) . . ?
C21 Fe2 C25 114.3(4) . . ?
C22 Fe2 C25 67.6(4) . . ?
C20 Fe2 C25 108.9(4) . . ?
C26 Fe2 C24 67.3(4) . . ?
C19 Fe2 C24 109.0(4) . . ?
C18 Fe2 C24 135.1(4) . . ?
C23 Fe2 C24 40.7(4) . . ?
C21 Fe2 C24 144.1(4) . . ?
C22 Fe2 C24 68.4(4) . . ?
C20 Fe2 C24 113.7(4) . . ?
C25 Fe2 C24 39.7(4) . . ?
C26 Fe2 C17 115.0(4) . . ?
C19 Fe2 C17 69.3(4) . . ?
C18 Fe2 C17 40.7(4) . . ?
C23 Fe2 C17 135.2(4) . . ?
C21 Fe2 C17 40.3(4) . . ?
C22 Fe2 C17 110.2(4) . . ?
C20 Fe2 C17 68.3(4) . . ?
C25 Fe2 C17 144.9(4) . . ?
C24 Fe2 C17 175.0(4) . . ?
C11 N1 C12 111.8(7) . . ?
C11 N1 Au2 129.4(6) . . ?
C12 N1 Au2 118.7(5) . . ?
C11 O1 C13 107.2(7) . . ?
C2 C1 C5 106.1(8) . . ?
C2 C1 Au1 128.7(7) . . ?
C5 C1 Au1 124.7(6) . . ?
C2 C1 Fe1 67.6(5) . . ?
C5 C1 Fe1 69.3(5) . . ?
Au1 C1 Fe1 133.6(4) . . ?
C27 N2 C28 108.6(7) . . ?
C27 N2 Au1 131.6(6) . . ?
C28 N2 Au1 119.7(5) . . ?
C27 O2 C29 106.4(7) . . ?
C11 C2 C1 128.4(9) . . ?
C11 C2 C3 123.1(8) . . ?
C1 C2 C3 108.4(8) . . ?
C11 C2 Fe1 122.8(6) . . ?
C1 C2 Fe1 71.6(5) . . ?
C3 C2 Fe1 68.1(5) . . ?
C4 C3 C2 107.4(8) . . ?
C4 C3 Fe1 71.1(5) . . ?
C2 C3 Fe1 69.8(5) . . ?
C4 C3 H3 126.3 . . ?
C2 C3 H3 126.3 . . ?
Fe1 C3 H3 124.4 . . ?
C3 C4 C5 108.7(8) . . ?
C3 C4 Fe1 68.4(5) . . ?
C5 C4 Fe1 71.0(5) . . ?
C3 C4 H4 125.7 . . ?
C5 C4 H4 125.7 . . ?
Fe1 C4 H4 126.5 . . ?
C4 C5 C1 109.4(8) . . ?
C4 C5 Fe1 68.9(5) . . ?
C1 C5 Fe1 70.3(5) . . ?
C4 C5 H5 125.3 . . ?
C1 C5 H5 125.3 . . ?
Fe1 C5 H5 127.1 . . ?
C10 C6 C7 107.4(9) . . ?
C10 C6 Fe1 69.9(6) . . ?
C7 C6 Fe1 69.1(6) . . ?
C10 C6 H6 126.3 . . ?
C7 C6 H6 126.3 . . ?
Fe1 C6 H6 126.3 . . ?
C8 C7 C6 108.3(8) . . ?
C8 C7 Fe1 70.1(5) . . ?
C6 C7 Fe1 70.1(6) . . ?
C8 C7 H7 125.9 . . ?
C6 C7 H7 125.9 . . ?
Fe1 C7 H7 125.5 . . ?
C7 C8 C9 107.5(8) . . ?
C7 C8 Fe1 69.5(5) . . ?
C9 C8 Fe1 69.9(5) . . ?
C7 C8 H8 126.2 . . ?
C9 C8 H8 126.2 . . ?
Fe1 C8 H8 125.9 . . ?
C8 C9 C10 108.2(8) . . ?
C8 C9 Fe1 69.7(5) . . ?
C10 C9 Fe1 69.9(5) . . ?
C8 C9 H9 125.9 . . ?
C10 C9 H9 125.9 . . ?
Fe1 C9 H9 126.1 . . ?
C6 C10 C9 108.6(9) . . ?
C6 C10 Fe1 70.2(6) . . ?
C9 C10 Fe1 69.8(5) . . ?
C6 C10 H10 125.7 . . ?
C9 C10 H10 125.7 . . ?
Fe1 C10 H10 125.9 . . ?
N1 C11 O1 113.2(8) . . ?
N1 C11 C2 132.5(9) . . ?
O1 C11 C2 114.2(8) . . ?
N1 C12 C14 110.8(7) . . ?
N1 C12 C13 100.7(7) . . ?
C14 C12 C13 118.0(8) . . ?
N1 C12 H12 109.0 . . ?
C14 C12 H12 109.0 . . ?
C13 C12 H12 109.0 . . ?
O1 C13 C12 105.0(7) . . ?
O1 C13 H13A 110.7 . . ?
C12 C13 H13A 110.7 . . ?
O1 C13 H13B 110.7 . . ?
C12 C13 H13B 110.7 . . ?
H13A C13 H13B 108.8 . . ?
C12 C14 C16 113.5(8) . . ?
C12 C14 C15 110.5(8) . . ?
C16 C14 C15 111.0(8) . . ?
C12 C14 H14 107.2 . . ?
C16 C14 H14 107.2 . . ?
C15 C14 H14 107.2 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C21 C17 C18 105.9(8) . . ?
C21 C17 Au2 125.2(7) . . ?
C18 C17 Au2 128.5(7) . . ?
C21 C17 Fe2 68.4(5) . . ?
C18 C17 Fe2 67.9(5) . . ?
Au2 C17 Fe2 133.4(4) . . ?
C17 C18 C19 108.7(8) . . ?
C17 C18 C27 129.6(9) . . ?
C19 C18 C27 121.7(9) . . ?
C17 C18 Fe2 71.4(5) . . ?
C19 C18 Fe2 69.1(5) . . ?
C27 C18 Fe2 124.0(7) . . ?
C20 C19 C18 107.1(8) . . ?
C20 C19 Fe2 70.6(5) . . ?
C18 C19 Fe2 69.1(5) . . ?
C20 C19 H19 126.5 . . ?
C18 C19 H19 126.5 . . ?
Fe2 C19 H19 125.4 . . ?
C19 C20 C21 108.4(9) . . ?
C19 C20 Fe2 69.2(5) . . ?
C21 C20 Fe2 69.4(5) . . ?
C19 C20 H20 125.8 . . ?
C21 C20 H20 125.8 . . ?
Fe2 C20 H20 127.1 . . ?
C20 C21 C17 109.9(8) . . ?
C20 C21 Fe2 70.2(6) . . ?
C17 C21 Fe2 71.3(5) . . ?
C20 C21 H21 125.0 . . ?
C17 C21 H21 125.0 . . ?
Fe2 C21 H21 125.0 . . ?
C26 C22 C23 106.7(9) . . ?
C26 C22 Fe2 69.3(6) . . ?
C23 C22 Fe2 69.3(6) . . ?
C26 C22 H22 126.7 . . ?
C23 C22 H22 126.7 . . ?
Fe2 C22 H22 126.3 . . ?
C24 C23 C22 107.6(8) . . ?
C24 C23 Fe2 70.3(5) . . ?
C22 C23 Fe2 69.6(5) . . ?
C24 C23 H23 126.2 . . ?
C22 C23 H23 126.2 . . ?
Fe2 C23 H23 125.5 . . ?
C25 C24 C23 107.6(8) . . ?
C25 C24 Fe2 70.1(5) . . ?
C23 C24 Fe2 69.0(5) . . ?
C25 C24 H24 126.2 . . ?
C23 C24 H24 126.2 . . ?
Fe2 C24 H24 126.3 . . ?
C26 C25 C24 108.7(9) . . ?
C26 C25 Fe2 69.2(6) . . ?
C24 C25 Fe2 70.3(5) . . ?
C26 C25 H25 125.6 . . ?
C24 C25 H25 125.6 . . ?
Fe2 C25 H25 126.5 . . ?
C25 C26 C22 109.3(10) . . ?
C25 C26 Fe2 70.9(6) . . ?
C22 C26 Fe2 70.4(6) . . ?
C25 C26 H26 125.3 . . ?
C22 C26 H26 125.3 . . ?
Fe2 C26 H26 124.9 . . ?
N2 C27 O2 116.0(8) . . ?
N2 C27 C18 130.2(9) . . ?
O2 C27 C18 113.8(8) . . ?
N2 C28 C29 101.9(7) . . ?
N2 C28 C30 110.1(8) . . ?
C29 C28 C30 116.1(8) . . ?
N2 C28 H28 109.5 . . ?
C29 C28 H28 109.5 . . ?
C30 C28 H28 109.5 . . ?
O2 C29 C28 104.8(7) . . ?
O2 C29 H29A 110.8 . . ?
C28 C29 H29A 110.8 . . ?
O2 C29 H29B 110.8 . . ?
C28 C29 H29B 110.8 . . ?
H29A C29 H29B 108.9 . . ?
C31 C30 C32 112.2(8) . . ?
C31 C30 C28 113.5(9) . . ?
C32 C30 C28 110.2(8) . . ?
C31 C30 H30 106.8 . . ?
C32 C30 H30 106.8 . . ?
C28 C30 H30 106.8 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C17 145.8(4) . . . . ?
N2 Au1 Au2 C17 -35.9(3) . . . . ?
C1 Au1 Au2 N1 -37.1(3) . . . . ?
N2 Au1 Au2 N1 141.1(3) . . . . ?
C17 Au2 N1 C11 164(5) . . . . ?
Au1 Au2 N1 C11 33.2(8) . . . . ?
C17 Au2 N1 C12 -14(5) . . . . ?
Au1 Au2 N1 C12 -145.0(6) . . . . ?
N2 Au1 C1 C2 -106(7) . . . . ?
Au2 Au1 C1 C2 36.9(8) . . . . ?
N2 Au1 C1 C5 66(7) . . . . ?
Au2 Au1 C1 C5 -152.0(7) . . . . ?
N2 Au1 C1 Fe1 159(6) . . . . ?
Au2 Au1 C1 Fe1 -58.3(6) . . . . ?
C3 Fe1 C1 C2 38.5(5) . . . . ?
C7 Fe1 C1 C2 -67.9(7) . . . . ?
C8 Fe1 C1 C2 -41(2) . . . . ?
C9 Fe1 C1 C2 175.6(7) . . . . ?
C10 Fe1 C1 C2 -149.9(5) . . . . ?
C6 Fe1 C1 C2 -107.4(6) . . . . ?
C4 Fe1 C1 C2 82.1(6) . . . . ?
C5 Fe1 C1 C2 118.5(7) . . . . ?
C3 Fe1 C1 C5 -80.0(6) . . . . ?
C7 Fe1 C1 C5 173.6(5) . . . . ?
C2 Fe1 C1 C5 -118.5(7) . . . . ?
C8 Fe1 C1 C5 -159(2) . . . . ?
C9 Fe1 C1 C5 57.1(9) . . . . ?
C10 Fe1 C1 C5 91.7(6) . . . . ?
C6 Fe1 C1 C5 134.2(5) . . . . ?
C4 Fe1 C1 C5 -36.4(5) . . . . ?
C3 Fe1 C1 Au1 161.4(8) . . . . ?
C7 Fe1 C1 Au1 54.9(8) . . . . ?
C2 Fe1 C1 Au1 122.8(9) . . . . ?
C8 Fe1 C1 Au1 82(2) . . . . ?
C9 Fe1 C1 Au1 -61.5(10) . . . . ?
C10 Fe1 C1 Au1 -27.0(8) . . . . ?
C6 Fe1 C1 Au1 15.5(8) . . . . ?
C4 Fe1 C1 Au1 -155.1(8) . . . . ?
C5 Fe1 C1 Au1 -118.7(9) . . . . ?
C1 Au1 N2 C27 177(100) . . . . ?
Au2 Au1 N2 C27 34.8(8) . . . . ?
C1 Au1 N2 C28 -5(7) . . . . ?
Au2 Au1 N2 C28 -147.8(6) . . . . ?
C5 C1 C2 C11 176.6(8) . . . . ?
Au1 C1 C2 C11 -11.0(14) . . . . ?
Fe1 C1 C2 C11 117.8(9) . . . . ?
C5 C1 C2 C3 0.5(10) . . . . ?
Au1 C1 C2 C3 172.9(6) . . . . ?
Fe1 C1 C2 C3 -58.4(6) . . . . ?
C5 C1 C2 Fe1 58.9(6) . . . . ?
Au1 C1 C2 Fe1 -128.7(7) . . . . ?
C3 Fe1 C2 C11 116.2(10) . . . . ?
C7 Fe1 C2 C11 8.6(9) . . . . ?
C8 Fe1 C2 C11 47.5(10) . . . . ?
C9 Fe1 C2 C11 72(3) . . . . ?
C10 Fe1 C2 C11 -69.0(11) . . . . ?
C6 Fe1 C2 C11 -35.1(9) . . . . ?
C4 Fe1 C2 C11 154.4(9) . . . . ?
C5 Fe1 C2 C11 -162.3(9) . . . . ?
C1 Fe1 C2 C11 -124.4(10) . . . . ?
C3 Fe1 C2 C1 -119.4(7) . . . . ?
C7 Fe1 C2 C1 133.0(5) . . . . ?
C8 Fe1 C2 C1 171.9(5) . . . . ?
C9 Fe1 C2 C1 -164(2) . . . . ?
C10 Fe1 C2 C1 55.4(8) . . . . ?
C6 Fe1 C2 C1 89.4(6) . . . . ?
C4 Fe1 C2 C1 -81.2(5) . . . . ?
C5 Fe1 C2 C1 -37.9(5) . . . . ?
C7 Fe1 C2 C3 -107.6(5) . . . . ?
C8 Fe1 C2 C3 -68.6(7) . . . . ?
C9 Fe1 C2 C3 -44(3) . . . . ?
C10 Fe1 C2 C3 174.8(6) . . . . ?
C6 Fe1 C2 C3 -151.2(5) . . . . ?
C4 Fe1 C2 C3 38.2(5) . . . . ?
C5 Fe1 C2 C3 81.5(5) . . . . ?
C1 Fe1 C2 C3 119.4(7) . . . . ?
C11 C2 C3 C4 -177.3(8) . . . . ?
C1 C2 C3 C4 -0.9(10) . . . . ?
Fe1 C2 C3 C4 -61.5(6) . . . . ?
C11 C2 C3 Fe1 -115.8(8) . . . . ?
C1 C2 C3 Fe1 60.6(6) . . . . ?
C7 Fe1 C3 C4 -152.3(5) . . . . ?
C2 Fe1 C3 C4 117.6(7) . . . . ?
C8 Fe1 C3 C4 -109.2(5) . . . . ?
C9 Fe1 C3 C4 -70.3(7) . . . . ?
C10 Fe1 C3 C4 -44(2) . . . . ?
C6 Fe1 C3 C4 172.5(7) . . . . ?
C5 Fe1 C3 C4 36.9(5) . . . . ?
C1 Fe1 C3 C4 80.3(5) . . . . ?
C7 Fe1 C3 C2 90.1(6) . . . . ?
C8 Fe1 C3 C2 133.2(5) . . . . ?
C9 Fe1 C3 C2 172.1(5) . . . . ?
C10 Fe1 C3 C2 -162(2) . . . . ?
C6 Fe1 C3 C2 54.9(9) . . . . ?
C4 Fe1 C3 C2 -117.6(7) . . . . ?
C5 Fe1 C3 C2 -80.7(5) . . . . ?
C1 Fe1 C3 C2 -37.3(5) . . . . ?
C2 C3 C4 C5 0.9(10) . . . . ?
Fe1 C3 C4 C5 -59.7(6) . . . . ?
C2 C3 C4 Fe1 60.7(6) . . . . ?
C7 Fe1 C4 C3 51.9(9) . . . . ?
C2 Fe1 C4 C3 -39.6(5) . . . . ?
C8 Fe1 C4 C3 87.9(6) . . . . ?
C9 Fe1 C4 C3 131.5(6) . . . . ?
C10 Fe1 C4 C3 171.3(5) . . . . ?
C6 Fe1 C4 C3 -155(2) . . . . ?
C5 Fe1 C4 C3 -120.1(7) . . . . ?
C1 Fe1 C4 C3 -83.5(5) . . . . ?
C3 Fe1 C4 C5 120.1(7) . . . . ?
C7 Fe1 C4 C5 172.0(6) . . . . ?
C2 Fe1 C4 C5 80.5(6) . . . . ?
C8 Fe1 C4 C5 -152.0(5) . . . . ?
C9 Fe1 C4 C5 -108.4(6) . . . . ?
C10 Fe1 C4 C5 -68.6(7) . . . . ?
C6 Fe1 C4 C5 -35(3) . . . . ?
C1 Fe1 C4 C5 36.6(5) . . . . ?
C3 C4 C5 C1 -0.6(10) . . . . ?
Fe1 C4 C5 C1 -58.7(6) . . . . ?
C3 C4 C5 Fe1 58.1(6) . . . . ?
C2 C1 C5 C4 0.1(10) . . . . ?
Au1 C1 C5 C4 -172.7(6) . . . . ?
Fe1 C1 C5 C4 57.9(6) . . . . ?
C2 C1 C5 Fe1 -57.8(6) . . . . ?
Au1 C1 C5 Fe1 129.4(7) . . . . ?
C3 Fe1 C5 C4 -37.3(5) . . . . ?
C7 Fe1 C5 C4 -152(2) . . . . ?
C2 Fe1 C5 C4 -82.8(6) . . . . ?
C8 Fe1 C5 C4 52.8(9) . . . . ?
C9 Fe1 C5 C4 89.5(6) . . . . ?
C10 Fe1 C5 C4 133.0(6) . . . . ?
C6 Fe1 C5 C4 172.8(6) . . . . ?
C1 Fe1 C5 C4 -121.1(8) . . . . ?
C3 Fe1 C5 C1 83.8(6) . . . . ?
C7 Fe1 C5 C1 -31(2) . . . . ?
C2 Fe1 C5 C1 38.3(5) . . . . ?
C8 Fe1 C5 C1 173.9(6) . . . . ?
C9 Fe1 C5 C1 -149.4(5) . . . . ?
C10 Fe1 C5 C1 -105.9(5) . . . . ?
C6 Fe1 C5 C1 -66.1(7) . . . . ?
C4 Fe1 C5 C1 121.1(8) . . . . ?
C3 Fe1 C6 C10 171.4(6) . . . . ?
C7 Fe1 C6 C10 118.7(8) . . . . ?
C2 Fe1 C6 C10 -151.3(6) . . . . ?
C8 Fe1 C6 C10 81.1(6) . . . . ?
C9 Fe1 C6 C10 37.4(5) . . . . ?
C4 Fe1 C6 C10 -40(3) . . . . ?
C5 Fe1 C6 C10 -69.3(7) . . . . ?
C1 Fe1 C6 C10 -107.9(6) . . . . ?
C3 Fe1 C6 C7 52.7(9) . . . . ?
C2 Fe1 C6 C7 90.0(6) . . . . ?
C8 Fe1 C6 C7 -37.6(5) . . . . ?
C9 Fe1 C6 C7 -81.3(6) . . . . ?
C10 Fe1 C6 C7 -118.7(8) . . . . ?
C4 Fe1 C6 C7 -158(2) . . . . ?
C5 Fe1 C6 C7 172.0(5) . . . . ?
C1 Fe1 C6 C7 133.4(5) . . . . ?
C10 C6 C7 C8 0.3(10) . . . . ?
Fe1 C6 C7 C8 59.9(6) . . . . ?
C10 C6 C7 Fe1 -59.6(7) . . . . ?
C3 Fe1 C7 C8 88.9(6) . . . . ?
C2 Fe1 C7 C8 133.9(5) . . . . ?
C9 Fe1 C7 C8 -37.9(5) . . . . ?
C10 Fe1 C7 C8 -81.7(6) . . . . ?
C6 Fe1 C7 C8 -119.1(8) . . . . ?
C4 Fe1 C7 C8 54.4(9) . . . . ?
C5 Fe1 C7 C8 -160(2) . . . . ?
C1 Fe1 C7 C8 173.6(5) . . . . ?
C3 Fe1 C7 C6 -152.0(5) . . . . ?
C2 Fe1 C7 C6 -107.0(6) . . . . ?
C8 Fe1 C7 C6 119.1(8) . . . . ?
C9 Fe1 C7 C6 81.2(6) . . . . ?
C10 Fe1 C7 C6 37.4(5) . . . . ?
C4 Fe1 C7 C6 173.5(7) . . . . ?
C5 Fe1 C7 C6 -41(2) . . . . ?
C1 Fe1 C7 C6 -67.3(7) . . . . ?
C6 C7 C8 C9 -0.1(10) . . . . ?
Fe1 C7 C8 C9 59.8(6) . . . . ?
C6 C7 C8 Fe1 -59.9(7) . . . . ?
C3 Fe1 C8 C7 -107.9(6) . . . . ?
C2 Fe1 C8 C7 -66.8(7) . . . . ?
C9 Fe1 C8 C7 118.6(7) . . . . ?
C10 Fe1 C8 C7 81.1(6) . . . . ?
C6 Fe1 C8 C7 37.9(5) . . . . ?
C4 Fe1 C8 C7 -151.1(5) . . . . ?
C5 Fe1 C8 C7 174.0(6) . . . . ?
C1 Fe1 C8 C7 -32(2) . . . . ?
C3 Fe1 C8 C9 133.5(6) . . . . ?
C7 Fe1 C8 C9 -118.6(7) . . . . ?
C2 Fe1 C8 C9 174.6(6) . . . . ?
C10 Fe1 C8 C9 -37.5(5) . . . . ?
C6 Fe1 C8 C9 -80.7(6) . . . . ?
C4 Fe1 C8 C9 90.3(6) . . . . ?
C5 Fe1 C8 C9 55.3(9) . . . . ?
C1 Fe1 C8 C9 -150(2) . . . . ?
C7 C8 C9 C10 0.0(10) . . . . ?
Fe1 C8 C9 C10 59.5(6) . . . . ?
C7 C8 C9 Fe1 -59.6(6) . . . . ?
C3 Fe1 C9 C8 -66.9(7) . . . . ?
C7 Fe1 C9 C8 38.0(5) . . . . ?
C2 Fe1 C9 C8 -28(3) . . . . ?
C10 Fe1 C9 C8 119.3(8) . . . . ?
C6 Fe1 C9 C8 82.2(6) . . . . ?
C4 Fe1 C9 C8 -107.5(6) . . . . ?
C5 Fe1 C9 C8 -150.8(5) . . . . ?
C1 Fe1 C9 C8 171.6(6) . . . . ?
C3 Fe1 C9 C10 173.8(5) . . . . ?
C7 Fe1 C9 C10 -81.3(6) . . . . ?
C2 Fe1 C9 C10 -148(2) . . . . ?
C8 Fe1 C9 C10 -119.3(8) . . . . ?
C6 Fe1 C9 C10 -37.1(5) . . . . ?
C4 Fe1 C9 C10 133.2(5) . . . . ?
C5 Fe1 C9 C10 89.9(6) . . . . ?
C1 Fe1 C9 C10 52.3(9) . . . . ?
C7 C6 C10 C9 -0.3(11) . . . . ?
Fe1 C6 C10 C9 -59.4(6) . . . . ?
C7 C6 C10 Fe1 59.1(6) . . . . ?
C8 C9 C10 C6 0.2(10) . . . . ?
Fe1 C9 C10 C6 59.6(7) . . . . ?
C8 C9 C10 Fe1 -59.4(6) . . . . ?
C3 Fe1 C10 C6 -150(2) . . . . ?
C7 Fe1 C10 C6 -38.3(6) . . . . ?
C2 Fe1 C10 C6 52.1(9) . . . . ?
C8 Fe1 C10 C6 -82.1(6) . . . . ?
C9 Fe1 C10 C6 -119.6(8) . . . . ?
C4 Fe1 C10 C6 171.8(6) . . . . ?
C5 Fe1 C10 C6 132.1(6) . . . . ?
C1 Fe1 C10 C6 88.6(6) . . . . ?
C3 Fe1 C10 C9 -31(2) . . . . ?
C7 Fe1 C10 C9 81.4(6) . . . . ?
C2 Fe1 C10 C9 171.7(7) . . . . ?
C8 Fe1 C10 C9 37.6(5) . . . . ?
C6 Fe1 C10 C9 119.6(8) . . . . ?
C4 Fe1 C10 C9 -68.5(7) . . . . ?
C5 Fe1 C10 C9 -108.2(6) . . . . ?
C1 Fe1 C10 C9 -151.8(6) . . . . ?
C12 N1 C11 O1 -4.1(11) . . . . ?
Au2 N1 C11 O1 177.6(5) . . . . ?
C12 N1 C11 C2 172.7(9) . . . . ?
Au2 N1 C11 C2 -5.6(15) . . . . ?
C13 O1 C11 N1 -5.7(10) . . . . ?
C13 O1 C11 C2 176.8(7) . . . . ?
C1 C2 C11 N1 -18.4(16) . . . . ?
C3 C2 C11 N1 157.2(10) . . . . ?
Fe1 C2 C11 N1 73.5(13) . . . . ?
C1 C2 C11 O1 158.4(9) . . . . ?
C3 C2 C11 O1 -25.9(12) . . . . ?
Fe1 C2 C11 O1 -109.7(8) . . . . ?
C11 N1 C12 C14 -114.3(9) . . . . ?
Au2 N1 C12 C14 64.2(9) . . . . ?
C11 N1 C12 C13 11.3(10) . . . . ?
Au2 N1 C12 C13 -170.2(5) . . . . ?
C11 O1 C13 C12 12.4(9) . . . . ?
N1 C12 C13 O1 -13.8(9) . . . . ?
C14 C12 C13 O1 106.9(9) . . . . ?
N1 C12 C14 C16 62.1(10) . . . . ?
C13 C12 C14 C16 -53.2(11) . . . . ?
N1 C12 C14 C15 -172.5(7) . . . . ?
C13 C12 C14 C15 72.2(11) . . . . ?
N1 Au2 C17 C21 75(5) . . . . ?
Au1 Au2 C17 C21 -153.6(8) . . . . ?
N1 Au2 C17 C18 -97(5) . . . . ?
Au1 Au2 C17 C18 34.4(9) . . . . ?
N1 Au2 C17 Fe2 168(4) . . . . ?
Au1 Au2 C17 Fe2 -60.9(6) . . . . ?
C26 Fe2 C17 C21 91.4(6) . . . . ?
C19 Fe2 C17 C21 -80.3(6) . . . . ?
C18 Fe2 C17 C21 -118.6(8) . . . . ?
C23 Fe2 C17 C21 174.5(6) . . . . ?
C22 Fe2 C17 C21 134.8(6) . . . . ?
C20 Fe2 C17 C21 -37.0(5) . . . . ?
C25 Fe2 C17 C21 55.3(8) . . . . ?
C24 Fe2 C17 C21 -152(4) . . . . ?
C26 Fe2 C17 C18 -150.0(6) . . . . ?
C19 Fe2 C17 C18 38.3(6) . . . . ?
C23 Fe2 C17 C18 -66.8(7) . . . . ?
C21 Fe2 C17 C18 118.6(8) . . . . ?
C22 Fe2 C17 C18 -106.6(6) . . . . ?
C20 Fe2 C17 C18 81.6(6) . . . . ?
C25 Fe2 C17 C18 173.9(7) . . . . ?
C24 Fe2 C17 C18 -33(4) . . . . ?
C26 Fe2 C17 Au2 -27.3(8) . . . . ?
C19 Fe2 C17 Au2 161.1(8) . . . . ?
C18 Fe2 C17 Au2 122.7(9) . . . . ?
C23 Fe2 C17 Au2 55.9(9) . . . . ?
C21 Fe2 C17 Au2 -118.6(9) . . . . ?
C22 Fe2 C17 Au2 16.2(8) . . . . ?
C20 Fe2 C17 Au2 -155.7(8) . . . . ?
C25 Fe2 C17 Au2 -63.3(10) . . . . ?
C24 Fe2 C17 Au2 89(4) . . . . ?
C21 C17 C18 C19 -1.2(11) . . . . ?
Au2 C17 C18 C19 172.0(7) . . . . ?
Fe2 C17 C18 C19 -59.3(7) . . . . ?
C21 C17 C18 C27 177.2(9) . . . . ?
Au2 C17 C18 C27 -9.6(15) . . . . ?
Fe2 C17 C18 C27 119.1(10) . . . . ?
C21 C17 C18 Fe2 58.1(6) . . . . ?
Au2 C17 C18 Fe2 -128.7(8) . . . . ?
C26 Fe2 C18 C17 54.8(9) . . . . ?
C19 Fe2 C18 C17 -119.4(8) . . . . ?
C23 Fe2 C18 C17 136.1(5) . . . . ?
C21 Fe2 C18 C17 -37.8(5) . . . . ?
C22 Fe2 C18 C17 91.4(6) . . . . ?
C20 Fe2 C18 C17 -81.5(6) . . . . ?
C25 Fe2 C18 C17 -148(3) . . . . ?
C24 Fe2 C18 C17 176.1(6) . . . . ?
C26 Fe2 C18 C19 174.1(7) . . . . ?
C23 Fe2 C18 C19 -104.6(6) . . . . ?
C21 Fe2 C18 C19 81.5(6) . . . . ?
C22 Fe2 C18 C19 -149.2(6) . . . . ?
C20 Fe2 C18 C19 37.9(6) . . . . ?
C25 Fe2 C18 C19 -29(4) . . . . ?
C24 Fe2 C18 C19 -64.6(8) . . . . ?
C17 Fe2 C18 C19 119.4(8) . . . . ?
C26 Fe2 C18 C27 -70.9(12) . . . . ?
C19 Fe2 C18 C27 114.9(11) . . . . ?
C23 Fe2 C18 C27 10.4(10) . . . . ?
C21 Fe2 C18 C27 -163.5(10) . . . . ?
C22 Fe2 C18 C27 -34.3(10) . . . . ?
C20 Fe2 C18 C27 152.8(10) . . . . ?
C25 Fe2 C18 C27 86(4) . . . . ?
C24 Fe2 C18 C27 50.4(11) . . . . ?
C17 Fe2 C18 C27 -125.7(11) . . . . ?
C17 C18 C19 C20 0.0(11) . . . . ?
C27 C18 C19 C20 -178.6(8) . . . . ?
Fe2 C18 C19 C20 -60.7(7) . . . . ?
C17 C18 C19 Fe2 60.7(7) . . . . ?
C27 C18 C19 Fe2 -117.9(9) . . . . ?
C26 Fe2 C19 C20 -40(3) . . . . ?
C18 Fe2 C19 C20 117.9(8) . . . . ?
C23 Fe2 C19 C20 -148.2(6) . . . . ?
C21 Fe2 C19 C20 37.1(6) . . . . ?
C22 Fe2 C19 C20 176.0(7) . . . . ?
C25 Fe2 C19 C20 -66.5(8) . . . . ?
C24 Fe2 C19 C20 -104.6(6) . . . . ?
C17 Fe2 C19 C20 80.5(6) . . . . ?
C26 Fe2 C19 C18 -158(3) . . . . ?
C23 Fe2 C19 C18 94.0(6) . . . . ?
C21 Fe2 C19 C18 -80.8(6) . . . . ?
C22 Fe2 C19 C18 58.1(9) . . . . ?
C20 Fe2 C19 C18 -117.9(8) . . . . ?
C25 Fe2 C19 C18 175.6(6) . . . . ?
C24 Fe2 C19 C18 137.6(6) . . . . ?
C17 Fe2 C19 C18 -37.4(6) . . . . ?
C18 C19 C20 C21 1.3(11) . . . . ?
Fe2 C19 C20 C21 -58.5(7) . . . . ?
C18 C19 C20 Fe2 59.8(7) . . . . ?
C26 Fe2 C20 C19 172.2(6) . . . . ?
C18 Fe2 C20 C19 -39.3(6) . . . . ?
C23 Fe2 C20 C19 56.6(9) . . . . ?
C21 Fe2 C20 C19 -120.2(8) . . . . ?
C22 Fe2 C20 C19 -164(3) . . . . ?
C25 Fe2 C20 C19 134.2(6) . . . . ?
C24 Fe2 C20 C19 91.8(6) . . . . ?
C17 Fe2 C20 C19 -83.2(6) . . . . ?
C26 Fe2 C20 C21 -67.6(7) . . . . ?
C19 Fe2 C20 C21 120.2(8) . . . . ?
C18 Fe2 C20 C21 80.9(6) . . . . ?
C23 Fe2 C20 C21 176.8(6) . . . . ?
C22 Fe2 C20 C21 -44(3) . . . . ?
C25 Fe2 C20 C21 -105.6(6) . . . . ?
C24 Fe2 C20 C21 -148.0(6) . . . . ?
C17 Fe2 C20 C21 37.0(5) . . . . ?
C19 C20 C21 C17 -2.1(11) . . . . ?
Fe2 C20 C21 C17 -60.5(7) . . . . ?
C19 C20 C21 Fe2 58.4(7) . . . . ?
C18 C17 C21 C20 2.0(11) . . . . ?
Au2 C17 C21 C20 -171.5(7) . . . . ?
Fe2 C17 C21 C20 59.8(7) . . . . ?
C18 C17 C21 Fe2 -57.8(6) . . . . ?
Au2 C17 C21 Fe2 128.7(7) . . . . ?
C26 Fe2 C21 C20 133.9(6) . . . . ?
C19 Fe2 C21 C20 -36.9(6) . . . . ?
C18 Fe2 C21 C20 -82.1(6) . . . . ?
C23 Fe2 C21 C20 -162(4) . . . . ?
C22 Fe2 C21 C20 172.6(6) . . . . ?
C25 Fe2 C21 C20 91.0(6) . . . . ?
C24 Fe2 C21 C20 55.7(9) . . . . ?
C17 Fe2 C21 C20 -120.3(8) . . . . ?
C26 Fe2 C21 C17 -105.8(6) . . . . ?
C19 Fe2 C21 C17 83.3(6) . . . . ?
C18 Fe2 C21 C17 38.1(5) . . . . ?
C23 Fe2 C21 C17 -41(4) . . . . ?
C22 Fe2 C21 C17 -67.1(7) . . . . ?
C20 Fe2 C21 C17 120.3(8) . . . . ?
C25 Fe2 C21 C17 -148.7(5) . . . . ?
C24 Fe2 C21 C17 176.0(6) . . . . ?
C19 Fe2 C22 C26 171.9(7) . . . . ?
C18 Fe2 C22 C26 -149.2(6) . . . . ?
C23 Fe2 C22 C26 118.1(8) . . . . ?
C21 Fe2 C22 C26 -65.8(8) . . . . ?
C20 Fe2 C22 C26 -28(3) . . . . ?
C25 Fe2 C22 C26 37.1(6) . . . . ?
C24 Fe2 C22 C26 80.0(6) . . . . ?
C17 Fe2 C22 C26 -105.2(6) . . . . ?
C26 Fe2 C22 C23 -118.1(8) . . . . ?
C19 Fe2 C22 C23 53.8(9) . . . . ?
C18 Fe2 C22 C23 92.8(6) . . . . ?
C21 Fe2 C22 C23 176.2(6) . . . . ?
C20 Fe2 C22 C23 -146(3) . . . . ?
C25 Fe2 C22 C23 -81.0(6) . . . . ?
C24 Fe2 C22 C23 -38.1(6) . . . . ?
C17 Fe2 C22 C23 136.7(5) . . . . ?
C26 C22 C23 C24 0.8(11) . . . . ?
Fe2 C22 C23 C24 60.3(7) . . . . ?
C26 C22 C23 Fe2 -59.5(6) . . . . ?
C26 Fe2 C23 C24 -80.4(6) . . . . ?
C19 Fe2 C23 C24 90.5(6) . . . . ?
C18 Fe2 C23 C24 135.8(5) . . . . ?
C21 Fe2 C23 C24 -147(4) . . . . ?
C22 Fe2 C23 C24 -118.4(8) . . . . ?
C20 Fe2 C23 C24 54.0(9) . . . . ?
C25 Fe2 C23 C24 -37.2(5) . . . . ?
C17 Fe2 C23 C24 175.7(5) . . . . ?
C26 Fe2 C23 C22 37.9(5) . . . . ?
C19 Fe2 C23 C22 -151.1(6) . . . . ?
C18 Fe2 C23 C22 -105.8(6) . . . . ?
C21 Fe2 C23 C22 -28(4) . . . . ?
C20 Fe2 C23 C22 172.4(7) . . . . ?
C25 Fe2 C23 C22 81.2(6) . . . . ?
C24 Fe2 C23 C22 118.4(8) . . . . ?
C17 Fe2 C23 C22 -65.9(7) . . . . ?
C22 C23 C24 C25 -0.2(11) . . . . ?
Fe2 C23 C24 C25 59.7(7) . . . . ?
C22 C23 C24 Fe2 -59.9(7) . . . . ?
C26 Fe2 C24 C25 -37.0(6) . . . . ?
C19 Fe2 C24 C25 134.4(6) . . . . ?
C18 Fe2 C24 C25 173.9(6) . . . . ?
C23 Fe2 C24 C25 -119.0(8) . . . . ?
C21 Fe2 C24 C25 55.6(8) . . . . ?
C22 Fe2 C24 C25 -80.5(6) . . . . ?
C20 Fe2 C24 C25 91.4(6) . . . . ?
C17 Fe2 C24 C25 -156(4) . . . . ?
C26 Fe2 C24 C23 82.0(6) . . . . ?
C19 Fe2 C24 C23 -106.6(6) . . . . ?
C18 Fe2 C24 C23 -67.1(7) . . . . ?
C21 Fe2 C24 C23 174.6(6) . . . . ?
C22 Fe2 C24 C23 38.4(6) . . . . ?
C20 Fe2 C24 C23 -149.6(6) . . . . ?
C25 Fe2 C24 C23 119.0(8) . . . . ?
C17 Fe2 C24 C23 -37(4) . . . . ?
C23 C24 C25 C26 -0.4(11) . . . . ?
Fe2 C24 C25 C26 58.6(7) . . . . ?
C23 C24 C25 Fe2 -59.0(7) . . . . ?
C19 Fe2 C25 C26 174.0(6) . . . . ?
C18 Fe2 C25 C26 -160(3) . . . . ?
C23 Fe2 C25 C26 -82.0(7) . . . . ?
C21 Fe2 C25 C26 92.0(7) . . . . ?
C22 Fe2 C25 C26 -37.4(6) . . . . ?
C20 Fe2 C25 C26 135.2(6) . . . . ?
C24 Fe2 C25 C26 -120.1(9) . . . . ?
C17 Fe2 C25 C26 56.3(9) . . . . ?
C26 Fe2 C25 C24 120.1(9) . . . . ?
C19 Fe2 C25 C24 -65.9(8) . . . . ?
C18 Fe2 C25 C24 -40(4) . . . . ?
C23 Fe2 C25 C24 38.1(6) . . . . ?
C21 Fe2 C25 C24 -147.9(6) . . . . ?
C22 Fe2 C25 C24 82.7(6) . . . . ?
C20 Fe2 C25 C24 -104.7(6) . . . . ?
C17 Fe2 C25 C24 176.4(6) . . . . ?
C24 C25 C26 C22 0.9(11) . . . . ?
Fe2 C25 C26 C22 60.2(7) . . . . ?
C24 C25 C26 Fe2 -59.3(7) . . . . ?
C23 C22 C26 C25 -1.0(11) . . . . ?
Fe2 C22 C26 C25 -60.5(7) . . . . ?
C23 C22 C26 Fe2 59.5(6) . . . . ?
C19 Fe2 C26 C25 -30(3) . . . . ?
C18 Fe2 C26 C25 175.9(7) . . . . ?
C23 Fe2 C26 C25 80.9(6) . . . . ?
C21 Fe2 C26 C25 -104.7(6) . . . . ?
C22 Fe2 C26 C25 119.7(9) . . . . ?
C20 Fe2 C26 C25 -65.2(8) . . . . ?
C24 Fe2 C26 C25 36.7(6) . . . . ?
C17 Fe2 C26 C25 -148.1(6) . . . . ?
C19 Fe2 C26 C22 -150(3) . . . . ?
C18 Fe2 C26 C22 56.3(10) . . . . ?
C23 Fe2 C26 C22 -38.7(6) . . . . ?
C21 Fe2 C26 C22 135.6(6) . . . . ?
C20 Fe2 C26 C22 175.1(6) . . . . ?
C25 Fe2 C26 C22 -119.7(9) . . . . ?
C24 Fe2 C26 C22 -82.9(6) . . . . ?
C17 Fe2 C26 C22 92.2(6) . . . . ?
C28 N2 C27 O2 -4.7(11) . . . . ?
Au1 N2 C27 O2 173.0(6) . . . . ?
C28 N2 C27 C18 172.9(9) . . . . ?
Au1 N2 C27 C18 -9.4(15) . . . . ?
C29 O2 C27 N2 -5.5(11) . . . . ?
C29 O2 C27 C18 176.5(7) . . . . ?
C17 C18 C27 N2 -15.9(16) . . . . ?
C19 C18 C27 N2 162.3(10) . . . . ?
Fe2 C18 C27 N2 77.4(13) . . . . ?
C17 C18 C27 O2 161.8(10) . . . . ?
C19 C18 C27 O2 -20.0(12) . . . . ?
Fe2 C18 C27 O2 -104.9(9) . . . . ?
C27 N2 C28 C29 12.1(10) . . . . ?
Au1 N2 C28 C29 -165.9(6) . . . . ?
C27 N2 C28 C30 -111.6(9) . . . . ?
Au1 N2 C28 C30 70.4(9) . . . . ?
C27 O2 C29 C28 12.8(10) . . . . ?
N2 C28 C29 O2 -14.7(9) . . . . ?
C30 C28 C29 O2 104.9(9) . . . . ?
N2 C28 C30 C31 59.9(10) . . . . ?
C29 C28 C30 C31 -55.1(11) . . . . ?
N2 C28 C30 C32 -173.3(7) . . . . ?
C29 C28 C30 C32 71.7(11) . . . . ?

_diffrn_measured_fraction_theta_max 0.981
_diffrn_reflns_theta_full        66.24
_diffrn_measured_fraction_theta_full 0.981
_refine_diff_density_max         0.872
_refine_diff_density_min         -0.960
_refine_diff_density_rms         0.154
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s2204lm
_database_code_depnum_ccdc_archive 'CCDC 1588443'
_audit_update_record             
;
2017-11-30 deposited with the CCDC.
2018-02-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 '(Rp)-iPrFOAu(II)Cl' 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_absolute_configuration ad
_chemical_formula_sum            'C32 H36 Au2 Cl2 Fe2 N2 O2'
_chemical_formula_weight         1057.16

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   9.0827(9)
_cell_length_b                   16.1005(13)
_cell_length_c                   20.765(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3036.6(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    4736
_cell_measurement_theta_min      1.60
_cell_measurement_theta_max      26.39

_exptl_crystal_description       needle
_exptl_crystal_colour            dark-red
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.312
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2008
_exptl_absorpt_coefficient_mu    10.779
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.4369
_exptl_absorpt_correction_T_max  0.7684
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  Triumph
_diffrn_measurement_device_type  'Bruker Kappa APEXII Duo'
_diffrn_measurement_method       'Omega + Phi Scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            22991
_diffrn_reflns_av_R_equivalents  0.0996
_diffrn_reflns_av_sigmaI/netI    0.1121
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         1.60
_diffrn_reflns_theta_max         26.39
_reflns_number_total             6227
_reflns_number_gt                4736
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEXII Software Suite, 2008'
_computing_cell_refinement       'Bruker APEXII Software Suite, 2008'
_computing_data_reduction        'Bruker APEXII Software Suite, 2008'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-plus, XP (Sheldrick, 1991)'
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0030P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.009(9)
_refine_ls_number_reflns         6227
_refine_ls_number_parameters     383
_refine_ls_number_restraints     216
_refine_ls_R_factor_all          0.0744
_refine_ls_R_factor_gt           0.0430
_refine_ls_wR_factor_ref         0.0638
_refine_ls_wR_factor_gt          0.0579
_refine_ls_goodness_of_fit_ref   0.883
_refine_ls_restrained_S_all      0.870
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.48949(4) 0.49657(2) 0.213545(18) 0.00919(9) Uani 1 1 d . . .
Au2 Au 0.34977(4) 0.52286(2) 0.10851(2) 0.01018(9) Uani 1 1 d . . .
Fe1 Fe 0.76119(14) 0.49947(9) 0.07659(7) 0.0111(3) Uani 1 1 d . . .
Fe2 Fe 0.31299(17) 0.29169(8) 0.14923(8) 0.0126(4) Uani 1 1 d . . .
Cl1 Cl 0.6291(3) 0.46112(15) 0.30656(14) 0.0250(7) Uani 1 1 d . . .
Cl2 Cl 0.2253(3) 0.54467(16) 0.00826(15) 0.0231(7) Uani 1 1 d . . .
C1 C 0.6733(11) 0.5281(6) 0.1662(5) 0.013(2) Uani 1 1 d U . .
N1 N 0.4406(9) 0.6411(4) 0.0985(5) 0.014(2) Uani 1 1 d U . .
O1 O 0.6179(7) 0.7378(4) 0.0945(3) 0.0148(17) Uani 1 1 d U . .
N2 N 0.2970(8) 0.4679(5) 0.2631(4) 0.013(2) Uani 1 1 d U . .
O2 O 0.0972(7) 0.3946(4) 0.2890(4) 0.0142(17) Uani 1 1 d U . .
C2 C 0.6925(10) 0.6013(6) 0.1261(5) 0.010(2) Uani 1 1 d U . .
C3 C 0.8439(11) 0.6100(5) 0.1101(6) 0.013(2) Uani 1 1 d U . .
H3 H 0.8866 0.6540 0.0860 0.016 Uiso 1 1 calc R . .
C4 C 0.9201(12) 0.5403(6) 0.1369(5) 0.017(3) Uani 1 1 d U . .
H4 H 1.0218 0.5280 0.1320 0.020 Uiso 1 1 calc R . .
C5 C 0.8139(9) 0.4922(6) 0.1726(5) 0.014(2) Uani 1 1 d U . .
H5 H 0.8356 0.4436 0.1967 0.017 Uiso 1 1 calc R . .
C6 C 0.6278(11) 0.4153(5) 0.0301(5) 0.011(2) Uani 1 1 d U . .
H6 H 0.5372 0.3938 0.0458 0.013 Uiso 1 1 calc R . .
C7 C 0.6462(11) 0.4857(5) -0.0077(4) 0.012(2) Uani 1 1 d U . .
H7 H 0.5689 0.5203 -0.0228 0.014 Uiso 1 1 calc R . .
C8 C 0.7988(10) 0.4981(7) -0.0204(5) 0.017(2) Uani 1 1 d U . .
H8 H 0.8412 0.5421 -0.0446 0.020 Uiso 1 1 calc R . .
C9 C 0.8745(12) 0.4324(5) 0.0101(5) 0.018(3) Uani 1 1 d U . .
H9 H 0.9780 0.4240 0.0099 0.022 Uiso 1 1 calc R . .
C10 C 0.7703(11) 0.3817(6) 0.0407(6) 0.017(3) Uani 1 1 d U . .
H10 H 0.7915 0.3328 0.0647 0.021 Uiso 1 1 calc R . .
C11 C 0.5770(11) 0.6583(5) 0.1072(6) 0.012(2) Uani 1 1 d U . .
C12 C 0.3648(12) 0.7164(5) 0.0740(5) 0.017(3) Uani 1 1 d U . .
H12 H 0.3478 0.7085 0.0268 0.020 Uiso 1 1 calc R . .
C13 C 0.4809(12) 0.7837(5) 0.0819(5) 0.017(3) Uani 1 1 d U . .
H13A H 0.4896 0.8175 0.0422 0.020 Uiso 1 1 calc R . .
H13B H 0.4565 0.8208 0.1184 0.020 Uiso 1 1 calc R . .
C14 C 0.2135(11) 0.7301(6) 0.1060(6) 0.017(2) Uani 1 1 d U . .
H14 H 0.1524 0.6801 0.0959 0.021 Uiso 1 1 calc R . .
C15 C 0.1356(12) 0.8036(5) 0.0774(5) 0.015(2) Uani 1 1 d U . .
H15A H 0.1859 0.8547 0.0905 0.023 Uiso 1 1 calc R . .
H15B H 0.0336 0.8048 0.0927 0.023 Uiso 1 1 calc R . .
H15C H 0.1366 0.7992 0.0303 0.023 Uiso 1 1 calc R . .
C16 C 0.2228(12) 0.7357(6) 0.1804(5) 0.021(3) Uani 1 1 d U . .
H16A H 0.2706 0.7879 0.1927 0.031 Uiso 1 1 calc R . .
H16B H 0.2803 0.6888 0.1970 0.031 Uiso 1 1 calc R . .
H16C H 0.1233 0.7340 0.1986 0.031 Uiso 1 1 calc R . .
C17 C 0.2548(10) 0.4106(5) 0.1207(5) 0.008(2) Uani 1 1 d U . .
C18 C 0.1790(12) 0.3842(6) 0.1791(5) 0.014(3) Uani 1 1 d U . .
C19 C 0.0952(11) 0.3106(6) 0.1653(6) 0.014(2) Uani 1 1 d U . .
H19 H 0.0350 0.2805 0.1945 0.017 Uiso 1 1 calc R . .
C20 C 0.1201(11) 0.2915(6) 0.0988(5) 0.017(3) Uani 1 1 d U . .
H20 H 0.0794 0.2463 0.0755 0.020 Uiso 1 1 calc R . .
C21 C 0.2186(11) 0.3539(6) 0.0740(5) 0.013(2) Uani 1 1 d U . .
H21 H 0.2539 0.3556 0.0309 0.015 Uiso 1 1 calc R . .
C22 C 0.5355(11) 0.2860(6) 0.1654(5) 0.013(2) Uani 1 1 d U . .
H22 H 0.6025 0.3310 0.1611 0.016 Uiso 1 1 calc R . .
C23 C 0.4594(12) 0.2646(6) 0.2216(6) 0.024(3) Uani 1 1 d U . .
H23 H 0.4652 0.2921 0.2620 0.029 Uiso 1 1 calc R . .
C24 C 0.3701(13) 0.1924(6) 0.2066(6) 0.023(3) Uani 1 1 d U . .
H24 H 0.3075 0.1634 0.2356 0.027 Uiso 1 1 calc R . .
C25 C 0.3935(11) 0.1733(6) 0.1410(5) 0.016(3) Uani 1 1 d U . .
H25 H 0.3479 0.1297 0.1174 0.020 Uiso 1 1 calc R . .
C26 C 0.4966(12) 0.2305(5) 0.1168(6) 0.018(2) Uani 1 1 d U . .
H26 H 0.5338 0.2313 0.0740 0.022 Uiso 1 1 calc R . .
C27 C 0.1950(11) 0.4171(6) 0.2428(5) 0.010(2) Uani 1 1 d U . .
C28 C 0.2609(10) 0.4955(6) 0.3303(4) 0.011(2) Uani 1 1 d U . .
H28 H 0.3505 0.4925 0.3582 0.014 Uiso 1 1 calc R . .
C29 C 0.1509(13) 0.4280(6) 0.3494(5) 0.017(2) Uani 1 1 d U . .
H29A H 0.1996 0.3842 0.3753 0.020 Uiso 1 1 calc R . .
H29B H 0.0690 0.4519 0.3749 0.020 Uiso 1 1 calc R . .
C30 C 0.2007(12) 0.5841(6) 0.3290(6) 0.017(3) Uani 1 1 d U . .
H30 H 0.2742 0.6193 0.3057 0.020 Uiso 1 1 calc R . .
C31 C 0.0571(12) 0.5911(6) 0.2933(6) 0.027(3) Uani 1 1 d U . .
H31A H -0.0175 0.5569 0.3147 0.040 Uiso 1 1 calc R . .
H31B H 0.0703 0.5718 0.2489 0.040 Uiso 1 1 calc R . .
H31C H 0.0249 0.6492 0.2930 0.040 Uiso 1 1 calc R . .
C32 C 0.1877(11) 0.6182(6) 0.3977(6) 0.023(3) Uani 1 1 d U . .
H32A H 0.1526 0.6757 0.3962 0.034 Uiso 1 1 calc R . .
H32B H 0.2843 0.6164 0.4187 0.034 Uiso 1 1 calc R . .
H32C H 0.1179 0.5842 0.4222 0.034 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 2.002(10) . ?
Au1 N2 2.081(8) . ?
Au1 Cl1 2.380(3) . ?
Au1 Au2 2.5586(6) . ?
Au2 C17 2.019(9) . ?
Au2 N1 2.085(7) . ?
Au2 Cl2 2.395(3) . ?
Fe1 C4 2.020(10) . ?
Fe1 C2 2.033(10) . ?
Fe1 C9 2.032(10) . ?
Fe1 C10 2.039(10) . ?
Fe1 C8 2.043(10) . ?
Fe1 C7 2.050(9) . ?
Fe1 C5 2.053(10) . ?
Fe1 C3 2.053(9) . ?
Fe1 C6 2.058(10) . ?
Fe1 C1 2.077(10) . ?
Fe2 C18 2.021(10) . ?
Fe2 C19 2.029(10) . ?
Fe2 C20 2.041(10) . ?
Fe2 C21 2.044(10) . ?
Fe2 C22 2.050(10) . ?
Fe2 C25 2.049(9) . ?
Fe2 C26 2.050(11) . ?
Fe2 C23 2.054(11) . ?
Fe2 C24 2.060(10) . ?
Fe2 C17 2.073(9) . ?
C1 C5 1.408(12) . ?
C1 C2 1.454(13) . ?
N1 C11 1.283(11) . ?
N1 C12 1.484(12) . ?
O1 C11 1.358(10) . ?
O1 C13 1.471(11) . ?
N2 C27 1.305(12) . ?
N2 C28 1.500(11) . ?
O2 C27 1.356(12) . ?
O2 C29 1.451(12) . ?
C2 C3 1.421(13) . ?
C2 C11 1.449(13) . ?
C3 C4 1.431(13) . ?
C3 H3 0.9500 . ?
C4 C5 1.442(13) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.387(12) . ?
C6 C10 1.421(14) . ?
C6 H6 0.9500 . ?
C7 C8 1.424(12) . ?
C7 H7 0.9500 . ?
C8 C9 1.412(13) . ?
C8 H8 0.9500 . ?
C9 C10 1.402(14) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C12 C13 1.521(13) . ?
C12 C14 1.543(14) . ?
C12 H12 1.0000 . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.502(13) . ?
C14 C16 1.549(15) . ?
C14 H14 1.0000 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C21 1.371(13) . ?
C17 C18 1.458(14) . ?
C18 C27 1.433(14) . ?
C18 C19 1.437(13) . ?
C19 C20 1.432(14) . ?
C19 H19 0.9500 . ?
C20 C21 1.440(13) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C26 1.394(13) . ?
C22 C23 1.399(15) . ?
C22 H22 0.9500 . ?
C23 C24 1.451(14) . ?
C23 H23 0.9500 . ?
C24 C25 1.414(14) . ?
C24 H24 0.9500 . ?
C25 C26 1.407(13) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C28 C30 1.528(13) . ?
C28 C29 1.529(13) . ?
C28 H28 1.0000 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.505(14) . ?
C30 C32 1.534(15) . ?
C30 H30 1.0000 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 N2 178.1(3) . . ?
C1 Au1 Cl1 90.9(3) . . ?
N2 Au1 Cl1 89.6(2) . . ?
C1 Au1 Au2 87.3(3) . . ?
N2 Au1 Au2 92.4(2) . . ?
Cl1 Au1 Au2 174.70(7) . . ?
C17 Au2 N1 177.5(4) . . ?
C17 Au2 Cl2 92.2(3) . . ?
N1 Au2 Cl2 88.0(3) . . ?
C17 Au2 Au1 87.6(3) . . ?
N1 Au2 Au1 92.3(3) . . ?
Cl2 Au2 Au1 178.01(7) . . ?
C4 Fe1 C2 69.1(4) . . ?
C4 Fe1 C9 103.4(4) . . ?
C2 Fe1 C9 158.0(4) . . ?
C4 Fe1 C10 120.0(4) . . ?
C2 Fe1 C10 161.3(4) . . ?
C9 Fe1 C10 40.3(4) . . ?
C4 Fe1 C8 119.7(4) . . ?
C2 Fe1 C8 123.9(4) . . ?
C9 Fe1 C8 40.6(4) . . ?
C10 Fe1 C8 67.9(4) . . ?
C4 Fe1 C7 158.1(4) . . ?
C2 Fe1 C7 111.3(4) . . ?
C9 Fe1 C7 67.7(4) . . ?
C10 Fe1 C7 66.9(4) . . ?
C8 Fe1 C7 40.7(3) . . ?
C4 Fe1 C5 41.5(4) . . ?
C2 Fe1 C5 68.1(4) . . ?
C9 Fe1 C5 120.7(4) . . ?
C10 Fe1 C5 107.0(4) . . ?
C8 Fe1 C5 156.6(4) . . ?
C7 Fe1 C5 160.3(4) . . ?
C4 Fe1 C3 41.1(4) . . ?
C2 Fe1 C3 40.7(4) . . ?
C9 Fe1 C3 120.4(4) . . ?
C10 Fe1 C3 156.2(4) . . ?
C8 Fe1 C3 106.4(4) . . ?
C7 Fe1 C3 124.7(4) . . ?
C5 Fe1 C3 68.6(4) . . ?
C4 Fe1 C6 157.7(4) . . ?
C2 Fe1 C6 126.0(4) . . ?
C9 Fe1 C6 68.3(4) . . ?
C10 Fe1 C6 40.6(4) . . ?
C8 Fe1 C6 68.2(4) . . ?
C7 Fe1 C6 39.5(4) . . ?
C5 Fe1 C6 123.7(4) . . ?
C3 Fe1 C6 160.9(4) . . ?
C4 Fe1 C1 69.4(4) . . ?
C2 Fe1 C1 41.4(4) . . ?
C9 Fe1 C1 157.1(4) . . ?
C10 Fe1 C1 123.3(4) . . ?
C8 Fe1 C1 161.8(4) . . ?
C7 Fe1 C1 126.4(4) . . ?
C5 Fe1 C1 39.9(3) . . ?
C3 Fe1 C1 69.2(4) . . ?
C6 Fe1 C1 109.9(4) . . ?
C18 Fe2 C19 41.6(4) . . ?
C18 Fe2 C20 69.0(4) . . ?
C19 Fe2 C20 41.2(4) . . ?
C18 Fe2 C21 67.7(4) . . ?
C19 Fe2 C21 69.1(4) . . ?
C20 Fe2 C21 41.3(4) . . ?
C18 Fe2 C22 125.2(4) . . ?
C19 Fe2 C22 160.1(4) . . ?
C20 Fe2 C22 158.4(4) . . ?
C21 Fe2 C22 124.1(4) . . ?
C18 Fe2 C25 157.9(4) . . ?
C19 Fe2 C25 120.1(4) . . ?
C20 Fe2 C25 105.2(4) . . ?
C21 Fe2 C25 122.8(4) . . ?
C22 Fe2 C25 67.7(4) . . ?
C18 Fe2 C26 160.8(4) . . ?
C19 Fe2 C26 156.8(4) . . ?
C20 Fe2 C26 121.9(4) . . ?
C21 Fe2 C26 109.0(4) . . ?
C22 Fe2 C26 39.8(4) . . ?
C25 Fe2 C26 40.1(4) . . ?
C18 Fe2 C23 108.8(4) . . ?
C19 Fe2 C23 122.9(5) . . ?
C20 Fe2 C23 158.6(4) . . ?
C21 Fe2 C23 159.2(4) . . ?
C22 Fe2 C23 39.9(4) . . ?
C25 Fe2 C23 68.5(4) . . ?
C26 Fe2 C23 67.2(4) . . ?
C18 Fe2 C24 123.1(5) . . ?
C19 Fe2 C24 105.5(4) . . ?
C20 Fe2 C24 120.8(4) . . ?
C21 Fe2 C24 158.1(4) . . ?
C22 Fe2 C24 67.8(4) . . ?
C25 Fe2 C24 40.3(4) . . ?
C26 Fe2 C24 67.2(4) . . ?
C23 Fe2 C24 41.3(4) . . ?
C18 Fe2 C17 41.7(4) . . ?
C19 Fe2 C17 70.1(4) . . ?
C20 Fe2 C17 68.6(4) . . ?
C21 Fe2 C17 38.9(4) . . ?
C22 Fe2 C17 109.8(4) . . ?
C25 Fe2 C17 157.9(4) . . ?
C26 Fe2 C17 123.8(4) . . ?
C23 Fe2 C17 124.8(4) . . ?
C24 Fe2 C17 161.2(4) . . ?
C5 C1 C2 106.1(8) . . ?
C5 C1 Au1 127.3(7) . . ?
C2 C1 Au1 125.9(7) . . ?
C5 C1 Fe1 69.2(6) . . ?
C2 C1 Fe1 67.7(6) . . ?
Au1 C1 Fe1 134.8(5) . . ?
C11 N1 C12 108.6(8) . . ?
C11 N1 Au2 124.4(7) . . ?
C12 N1 Au2 126.6(6) . . ?
C11 O1 C13 106.1(7) . . ?
C27 N2 C28 109.3(8) . . ?
C27 N2 Au1 125.1(7) . . ?
C28 N2 Au1 125.3(6) . . ?
C27 O2 C29 107.0(8) . . ?
C3 C2 C11 125.1(9) . . ?
C3 C2 C1 109.3(8) . . ?
C11 C2 C1 125.6(9) . . ?
C3 C2 Fe1 70.4(6) . . ?
C11 C2 Fe1 126.6(8) . . ?
C1 C2 Fe1 70.9(5) . . ?
C2 C3 C4 107.4(9) . . ?
C2 C3 Fe1 68.9(5) . . ?
C4 C3 Fe1 68.2(5) . . ?
C2 C3 H3 126.3 . . ?
C4 C3 H3 126.3 . . ?
Fe1 C3 H3 128.2 . . ?
C3 C4 C5 107.3(9) . . ?
C3 C4 Fe1 70.7(6) . . ?
C5 C4 Fe1 70.5(6) . . ?
C3 C4 H4 126.4 . . ?
C5 C4 H4 126.4 . . ?
Fe1 C4 H4 124.1 . . ?
C1 C5 C4 109.8(9) . . ?
C1 C5 Fe1 71.0(6) . . ?
C4 C5 Fe1 68.0(6) . . ?
C1 C5 H5 125.1 . . ?
C4 C5 H5 125.1 . . ?
Fe1 C5 H5 127.5 . . ?
C7 C6 C10 106.8(9) . . ?
C7 C6 Fe1 69.9(5) . . ?
C10 C6 Fe1 69.0(6) . . ?
C7 C6 H6 126.6 . . ?
C10 C6 H6 126.6 . . ?
Fe1 C6 H6 126.1 . . ?
C6 C7 C8 109.7(9) . . ?
C6 C7 Fe1 70.6(6) . . ?
C8 C7 Fe1 69.4(6) . . ?
C6 C7 H7 125.1 . . ?
C8 C7 H7 125.1 . . ?
Fe1 C7 H7 126.5 . . ?
C9 C8 C7 106.6(9) . . ?
C9 C8 Fe1 69.3(6) . . ?
C7 C8 Fe1 69.9(5) . . ?
C9 C8 H8 126.7 . . ?
C7 C8 H8 126.7 . . ?
Fe1 C8 H8 125.6 . . ?
C10 C9 C8 108.1(10) . . ?
C10 C9 Fe1 70.1(6) . . ?
C8 C9 Fe1 70.1(6) . . ?
C10 C9 H9 125.9 . . ?
C8 C9 H9 125.9 . . ?
Fe1 C9 H9 125.4 . . ?
C9 C10 C6 108.8(9) . . ?
C9 C10 Fe1 69.6(6) . . ?
C6 C10 Fe1 70.4(5) . . ?
C9 C10 H10 125.6 . . ?
C6 C10 H10 125.6 . . ?
Fe1 C10 H10 126.0 . . ?
N1 C11 O1 116.2(9) . . ?
N1 C11 C2 126.9(9) . . ?
O1 C11 C2 116.8(8) . . ?
N1 C12 C13 103.0(8) . . ?
N1 C12 C14 112.4(8) . . ?
C13 C12 C14 118.0(8) . . ?
N1 C12 H12 107.7 . . ?
C13 C12 H12 107.7 . . ?
C14 C12 H12 107.7 . . ?
O1 C13 C12 104.3(7) . . ?
O1 C13 H13A 110.9 . . ?
C12 C13 H13A 110.9 . . ?
O1 C13 H13B 110.9 . . ?
C12 C13 H13B 110.9 . . ?
H13A C13 H13B 108.9 . . ?
C15 C14 C12 111.2(9) . . ?
C15 C14 C16 112.0(9) . . ?
C12 C14 C16 113.0(9) . . ?
C15 C14 H14 106.8 . . ?
C12 C14 H14 106.8 . . ?
C16 C14 H14 106.8 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C21 C17 C18 106.3(8) . . ?
C21 C17 Au2 127.6(8) . . ?
C18 C17 Au2 124.5(7) . . ?
C21 C17 Fe2 69.4(5) . . ?
C18 C17 Fe2 67.3(5) . . ?
Au2 C17 Fe2 138.9(5) . . ?
C27 C18 C19 122.9(10) . . ?
C27 C18 C17 127.8(9) . . ?
C19 C18 C17 108.9(9) . . ?
C27 C18 Fe2 119.6(7) . . ?
C19 C18 Fe2 69.5(6) . . ?
C17 C18 Fe2 71.0(6) . . ?
C20 C19 C18 106.6(9) . . ?
C20 C19 Fe2 69.8(6) . . ?
C18 C19 Fe2 68.9(6) . . ?
C20 C19 H19 126.7 . . ?
C18 C19 H19 126.7 . . ?
Fe2 C19 H19 126.1 . . ?
C19 C20 C21 107.1(9) . . ?
C19 C20 Fe2 69.0(6) . . ?
C21 C20 Fe2 69.5(6) . . ?
C19 C20 H20 126.5 . . ?
C21 C20 H20 126.5 . . ?
Fe2 C20 H20 126.6 . . ?
C17 C21 C20 111.1(10) . . ?
C17 C21 Fe2 71.7(6) . . ?
C20 C21 Fe2 69.2(6) . . ?
C17 C21 H21 124.4 . . ?
C20 C21 H21 124.4 . . ?
Fe2 C21 H21 126.3 . . ?
C26 C22 C23 108.7(9) . . ?
C26 C22 Fe2 70.1(6) . . ?
C23 C22 Fe2 70.2(6) . . ?
C26 C22 H22 125.6 . . ?
C23 C22 H22 125.6 . . ?
Fe2 C22 H22 125.6 . . ?
C22 C23 C24 107.1(10) . . ?
C22 C23 Fe2 69.9(6) . . ?
C24 C23 Fe2 69.6(6) . . ?
C22 C23 H23 126.4 . . ?
C24 C23 H23 126.4 . . ?
Fe2 C23 H23 125.6 . . ?
C25 C24 C23 107.3(10) . . ?
C25 C24 Fe2 69.4(6) . . ?
C23 C24 Fe2 69.1(6) . . ?
C25 C24 H24 126.3 . . ?
C23 C24 H24 126.3 . . ?
Fe2 C24 H24 126.6 . . ?
C26 C25 C24 107.5(9) . . ?
C26 C25 Fe2 70.0(6) . . ?
C24 C25 Fe2 70.3(6) . . ?
C26 C25 H25 126.2 . . ?
C24 C25 H25 126.2 . . ?
Fe2 C25 H25 125.1 . . ?
C22 C26 C25 109.3(10) . . ?
C22 C26 Fe2 70.1(6) . . ?
C25 C26 Fe2 69.9(6) . . ?
C22 C26 H26 125.4 . . ?
C25 C26 H26 125.4 . . ?
Fe2 C26 H26 126.2 . . ?
N2 C27 O2 113.9(9) . . ?
N2 C27 C18 127.0(10) . . ?
O2 C27 C18 119.1(9) . . ?
N2 C28 C30 109.8(8) . . ?
N2 C28 C29 100.0(7) . . ?
C30 C28 C29 115.7(8) . . ?
N2 C28 H28 110.3 . . ?
C30 C28 H28 110.3 . . ?
C29 C28 H28 110.3 . . ?
O2 C29 C28 105.0(8) . . ?
O2 C29 H29A 110.7 . . ?
C28 C29 H29A 110.7 . . ?
O2 C29 H29B 110.7 . . ?
C28 C29 H29B 110.7 . . ?
H29A C29 H29B 108.8 . . ?
C31 C30 C28 112.9(9) . . ?
C31 C30 C32 111.4(9) . . ?
C28 C30 C32 110.1(9) . . ?
C31 C30 H30 107.4 . . ?
C28 C30 H30 107.4 . . ?
C32 C30 H30 107.4 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 Au2 C17 130.1(4) . . . . ?
N2 Au1 Au2 C17 -51.8(3) . . . . ?
Cl1 Au1 Au2 C17 60.1(8) . . . . ?
C1 Au1 Au2 N1 -52.4(3) . . . . ?
N2 Au1 Au2 N1 125.7(3) . . . . ?
Cl1 Au1 Au2 N1 -122.4(8) . . . . ?
C1 Au1 Au2 Cl2 48(2) . . . . ?
N2 Au1 Au2 Cl2 -134(2) . . . . ?
Cl1 Au1 Au2 Cl2 -22(2) . . . . ?
N2 Au1 C1 C5 137(11) . . . . ?
Cl1 Au1 C1 C5 33.0(9) . . . . ?
Au2 Au1 C1 C5 -142.0(9) . . . . ?
N2 Au1 C1 C2 -32(12) . . . . ?
Cl1 Au1 C1 C2 -136.4(8) . . . . ?
Au2 Au1 C1 C2 48.6(8) . . . . ?
N2 Au1 C1 Fe1 -126(11) . . . . ?
Cl1 Au1 C1 Fe1 130.3(6) . . . . ?
Au2 Au1 C1 Fe1 -44.8(6) . . . . ?
C4 Fe1 C1 C5 -37.0(5) . . . . ?
C2 Fe1 C1 C5 -118.5(8) . . . . ?
C9 Fe1 C1 C5 38.2(13) . . . . ?
C10 Fe1 C1 C5 76.0(7) . . . . ?
C8 Fe1 C1 C5 -160.2(11) . . . . ?
C7 Fe1 C1 C5 160.4(6) . . . . ?
C3 Fe1 C1 C5 -81.2(6) . . . . ?
C6 Fe1 C1 C5 119.2(6) . . . . ?
C4 Fe1 C1 C2 81.5(6) . . . . ?
C9 Fe1 C1 C2 156.7(10) . . . . ?
C10 Fe1 C1 C2 -165.5(6) . . . . ?
C8 Fe1 C1 C2 -41.7(14) . . . . ?
C7 Fe1 C1 C2 -81.2(6) . . . . ?
C5 Fe1 C1 C2 118.5(8) . . . . ?
C3 Fe1 C1 C2 37.3(5) . . . . ?
C6 Fe1 C1 C2 -122.3(6) . . . . ?
C4 Fe1 C1 Au1 -159.5(8) . . . . ?
C2 Fe1 C1 Au1 119.1(9) . . . . ?
C9 Fe1 C1 Au1 -84.2(13) . . . . ?
C10 Fe1 C1 Au1 -46.4(9) . . . . ?
C8 Fe1 C1 Au1 77.3(14) . . . . ?
C7 Fe1 C1 Au1 37.9(8) . . . . ?
C5 Fe1 C1 Au1 -122.4(9) . . . . ?
C3 Fe1 C1 Au1 156.4(8) . . . . ?
C6 Fe1 C1 Au1 -3.2(8) . . . . ?
C17 Au2 N1 C11 131(9) . . . . ?
Cl2 Au2 N1 C11 -133.4(11) . . . . ?
Au1 Au2 N1 C11 44.6(11) . . . . ?
C17 Au2 N1 C12 -55(10) . . . . ?
Cl2 Au2 N1 C12 39.8(8) . . . . ?
Au1 Au2 N1 C12 -142.2(8) . . . . ?
C1 Au1 N2 C27 129(11) . . . . ?
Cl1 Au1 N2 C27 -127.2(8) . . . . ?
Au2 Au1 N2 C27 47.9(8) . . . . ?
C1 Au1 N2 C28 -58(12) . . . . ?
Cl1 Au1 N2 C28 46.4(7) . . . . ?
Au2 Au1 N2 C28 -138.5(7) . . . . ?
C5 C1 C2 C3 -1.4(12) . . . . ?
Au1 C1 C2 C3 169.8(7) . . . . ?
Fe1 C1 C2 C3 -60.2(7) . . . . ?
C5 C1 C2 C11 -179.4(10) . . . . ?
Au1 C1 C2 C11 -8.1(15) . . . . ?
Fe1 C1 C2 C11 121.9(11) . . . . ?
C5 C1 C2 Fe1 58.7(7) . . . . ?
Au1 C1 C2 Fe1 -130.0(8) . . . . ?
C4 Fe1 C2 C3 37.6(6) . . . . ?
C9 Fe1 C2 C3 -36.1(14) . . . . ?
C10 Fe1 C2 C3 160.3(13) . . . . ?
C8 Fe1 C2 C3 -74.9(7) . . . . ?
C7 Fe1 C2 C3 -119.0(6) . . . . ?
C5 Fe1 C2 C3 82.2(6) . . . . ?
C6 Fe1 C2 C3 -161.2(6) . . . . ?
C1 Fe1 C2 C3 119.6(8) . . . . ?
C4 Fe1 C2 C11 157.3(10) . . . . ?
C9 Fe1 C2 C11 83.6(14) . . . . ?
C10 Fe1 C2 C11 -80.0(16) . . . . ?
C8 Fe1 C2 C11 44.8(10) . . . . ?
C7 Fe1 C2 C11 0.7(10) . . . . ?
C5 Fe1 C2 C11 -158.1(10) . . . . ?
C3 Fe1 C2 C11 119.7(11) . . . . ?
C6 Fe1 C2 C11 -41.5(10) . . . . ?
C1 Fe1 C2 C11 -120.7(11) . . . . ?
C4 Fe1 C2 C1 -82.1(6) . . . . ?
C9 Fe1 C2 C1 -155.7(11) . . . . ?
C10 Fe1 C2 C1 40.7(15) . . . . ?
C8 Fe1 C2 C1 165.5(5) . . . . ?
C7 Fe1 C2 C1 121.4(6) . . . . ?
C5 Fe1 C2 C1 -37.4(5) . . . . ?
C3 Fe1 C2 C1 -119.6(8) . . . . ?
C6 Fe1 C2 C1 79.2(7) . . . . ?
C11 C2 C3 C4 -179.0(10) . . . . ?
C1 C2 C3 C4 3.1(12) . . . . ?
Fe1 C2 C3 C4 -57.4(7) . . . . ?
C11 C2 C3 Fe1 -121.6(11) . . . . ?
C1 C2 C3 Fe1 60.5(7) . . . . ?
C4 Fe1 C3 C2 -120.0(9) . . . . ?
C9 Fe1 C3 C2 165.2(6) . . . . ?
C10 Fe1 C3 C2 -164.4(10) . . . . ?
C8 Fe1 C3 C2 123.4(6) . . . . ?
C7 Fe1 C3 C2 82.6(7) . . . . ?
C5 Fe1 C3 C2 -80.8(6) . . . . ?
C6 Fe1 C3 C2 52.9(16) . . . . ?
C1 Fe1 C3 C2 -38.0(6) . . . . ?
C2 Fe1 C3 C4 120.0(9) . . . . ?
C9 Fe1 C3 C4 -74.8(7) . . . . ?
C10 Fe1 C3 C4 -44.4(14) . . . . ?
C8 Fe1 C3 C4 -116.6(6) . . . . ?
C7 Fe1 C3 C4 -157.4(6) . . . . ?
C5 Fe1 C3 C4 39.2(6) . . . . ?
C6 Fe1 C3 C4 172.9(12) . . . . ?
C1 Fe1 C3 C4 82.1(7) . . . . ?
C2 C3 C4 C5 -3.5(12) . . . . ?
Fe1 C3 C4 C5 -61.3(7) . . . . ?
C2 C3 C4 Fe1 57.8(7) . . . . ?
C2 Fe1 C4 C3 -37.2(6) . . . . ?
C9 Fe1 C4 C3 121.1(6) . . . . ?
C10 Fe1 C4 C3 161.0(6) . . . . ?
C8 Fe1 C4 C3 80.9(7) . . . . ?
C7 Fe1 C4 C3 58.1(12) . . . . ?
C5 Fe1 C4 C3 -117.3(8) . . . . ?
C6 Fe1 C4 C3 -173.9(10) . . . . ?
C1 Fe1 C4 C3 -81.6(6) . . . . ?
C2 Fe1 C4 C5 80.1(6) . . . . ?
C9 Fe1 C4 C5 -121.6(6) . . . . ?
C10 Fe1 C4 C5 -81.7(7) . . . . ?
C8 Fe1 C4 C5 -161.8(6) . . . . ?
C7 Fe1 C4 C5 175.4(9) . . . . ?
C3 Fe1 C4 C5 117.3(8) . . . . ?
C6 Fe1 C4 C5 -56.6(13) . . . . ?
C1 Fe1 C4 C5 35.7(5) . . . . ?
C2 C1 C5 C4 -0.8(11) . . . . ?
Au1 C1 C5 C4 -171.9(7) . . . . ?
Fe1 C1 C5 C4 57.0(7) . . . . ?
C2 C1 C5 Fe1 -57.8(7) . . . . ?
Au1 C1 C5 Fe1 131.1(8) . . . . ?
C3 C4 C5 C1 2.7(12) . . . . ?
Fe1 C4 C5 C1 -58.8(7) . . . . ?
C3 C4 C5 Fe1 61.4(7) . . . . ?
C4 Fe1 C5 C1 121.7(8) . . . . ?
C2 Fe1 C5 C1 38.8(5) . . . . ?
C9 Fe1 C5 C1 -163.7(6) . . . . ?
C10 Fe1 C5 C1 -122.0(6) . . . . ?
C8 Fe1 C5 C1 164.6(9) . . . . ?
C7 Fe1 C5 C1 -53.3(14) . . . . ?
C3 Fe1 C5 C1 82.8(6) . . . . ?
C6 Fe1 C5 C1 -80.7(6) . . . . ?
C2 Fe1 C5 C4 -82.8(6) . . . . ?
C9 Fe1 C5 C4 74.6(6) . . . . ?
C10 Fe1 C5 C4 116.3(6) . . . . ?
C8 Fe1 C5 C4 42.9(12) . . . . ?
C7 Fe1 C5 C4 -174.9(10) . . . . ?
C3 Fe1 C5 C4 -38.9(6) . . . . ?
C6 Fe1 C5 C4 157.6(5) . . . . ?
C1 Fe1 C5 C4 -121.7(8) . . . . ?
C4 Fe1 C6 C7 -152.5(10) . . . . ?
C2 Fe1 C6 C7 79.9(7) . . . . ?
C9 Fe1 C6 C7 -80.9(6) . . . . ?
C10 Fe1 C6 C7 -118.1(9) . . . . ?
C8 Fe1 C6 C7 -37.1(6) . . . . ?
C5 Fe1 C6 C7 165.8(6) . . . . ?
C3 Fe1 C6 C7 39.9(16) . . . . ?
C1 Fe1 C6 C7 123.6(6) . . . . ?
C4 Fe1 C6 C10 -34.4(14) . . . . ?
C2 Fe1 C6 C10 -162.1(7) . . . . ?
C9 Fe1 C6 C10 37.2(6) . . . . ?
C8 Fe1 C6 C10 81.0(7) . . . . ?
C7 Fe1 C6 C10 118.1(9) . . . . ?
C5 Fe1 C6 C10 -76.1(7) . . . . ?
C3 Fe1 C6 C10 157.9(12) . . . . ?
C1 Fe1 C6 C10 -118.4(7) . . . . ?
C10 C6 C7 C8 -0.9(11) . . . . ?
Fe1 C6 C7 C8 58.4(7) . . . . ?
C10 C6 C7 Fe1 -59.4(7) . . . . ?
C4 Fe1 C7 C6 152.0(10) . . . . ?
C2 Fe1 C7 C6 -121.3(6) . . . . ?
C9 Fe1 C7 C6 82.4(6) . . . . ?
C10 Fe1 C7 C6 38.6(6) . . . . ?
C8 Fe1 C7 C6 121.0(9) . . . . ?
C5 Fe1 C7 C6 -37.0(14) . . . . ?
C3 Fe1 C7 C6 -165.2(6) . . . . ?
C1 Fe1 C7 C6 -76.7(7) . . . . ?
C4 Fe1 C7 C8 31.0(13) . . . . ?
C2 Fe1 C7 C8 117.8(6) . . . . ?
C9 Fe1 C7 C8 -38.5(6) . . . . ?
C10 Fe1 C7 C8 -82.4(6) . . . . ?
C5 Fe1 C7 C8 -158.0(10) . . . . ?
C3 Fe1 C7 C8 73.8(7) . . . . ?
C6 Fe1 C7 C8 -121.0(9) . . . . ?
C1 Fe1 C7 C8 162.3(6) . . . . ?
C6 C7 C8 C9 0.7(11) . . . . ?
Fe1 C7 C8 C9 59.9(7) . . . . ?
C6 C7 C8 Fe1 -59.2(7) . . . . ?
C4 Fe1 C8 C9 75.2(7) . . . . ?
C2 Fe1 C8 C9 158.8(6) . . . . ?
C10 Fe1 C8 C9 -37.7(6) . . . . ?
C7 Fe1 C8 C9 -117.5(9) . . . . ?
C5 Fe1 C8 C9 43.9(12) . . . . ?
C3 Fe1 C8 C9 117.8(6) . . . . ?
C6 Fe1 C8 C9 -81.6(6) . . . . ?
C1 Fe1 C8 C9 -169.1(11) . . . . ?
C4 Fe1 C8 C7 -167.3(5) . . . . ?
C2 Fe1 C8 C7 -83.6(7) . . . . ?
C9 Fe1 C8 C7 117.5(9) . . . . ?
C10 Fe1 C8 C7 79.8(6) . . . . ?
C5 Fe1 C8 C7 161.5(9) . . . . ?
C3 Fe1 C8 C7 -124.6(6) . . . . ?
C6 Fe1 C8 C7 35.9(5) . . . . ?
C1 Fe1 C8 C7 -51.6(15) . . . . ?
C7 C8 C9 C10 -0.2(12) . . . . ?
Fe1 C8 C9 C10 60.1(8) . . . . ?
C7 C8 C9 Fe1 -60.3(7) . . . . ?
C4 Fe1 C9 C10 120.9(7) . . . . ?
C2 Fe1 C9 C10 -172.0(10) . . . . ?
C8 Fe1 C9 C10 -118.9(9) . . . . ?
C7 Fe1 C9 C10 -80.1(7) . . . . ?
C5 Fe1 C9 C10 79.9(7) . . . . ?
C3 Fe1 C9 C10 161.6(6) . . . . ?
C6 Fe1 C9 C10 -37.4(6) . . . . ?
C1 Fe1 C9 C10 52.4(13) . . . . ?
C4 Fe1 C9 C8 -120.3(6) . . . . ?
C2 Fe1 C9 C8 -53.1(14) . . . . ?
C10 Fe1 C9 C8 118.9(9) . . . . ?
C7 Fe1 C9 C8 38.7(6) . . . . ?
C5 Fe1 C9 C8 -161.3(6) . . . . ?
C3 Fe1 C9 C8 -79.5(7) . . . . ?
C6 Fe1 C9 C8 81.4(6) . . . . ?
C1 Fe1 C9 C8 171.3(9) . . . . ?
C8 C9 C10 C6 -0.3(12) . . . . ?
Fe1 C9 C10 C6 59.7(7) . . . . ?
C8 C9 C10 Fe1 -60.1(7) . . . . ?
C7 C6 C10 C9 0.8(12) . . . . ?
Fe1 C6 C10 C9 -59.2(8) . . . . ?
C7 C6 C10 Fe1 60.0(7) . . . . ?
C4 Fe1 C10 C9 -74.5(7) . . . . ?
C2 Fe1 C10 C9 170.6(12) . . . . ?
C8 Fe1 C10 C9 37.9(6) . . . . ?
C7 Fe1 C10 C9 82.2(7) . . . . ?
C5 Fe1 C10 C9 -117.8(6) . . . . ?
C3 Fe1 C10 C9 -42.5(14) . . . . ?
C6 Fe1 C10 C9 119.8(9) . . . . ?
C1 Fe1 C10 C9 -158.3(6) . . . . ?
C4 Fe1 C10 C6 165.7(6) . . . . ?
C2 Fe1 C10 C6 50.8(16) . . . . ?
C9 Fe1 C10 C6 -119.8(9) . . . . ?
C8 Fe1 C10 C6 -81.8(7) . . . . ?
C7 Fe1 C10 C6 -37.6(6) . . . . ?
C5 Fe1 C10 C6 122.4(6) . . . . ?
C3 Fe1 C10 C6 -162.2(10) . . . . ?
C1 Fe1 C10 C6 81.9(7) . . . . ?
C12 N1 C11 O1 1.7(15) . . . . ?
Au2 N1 C11 O1 175.9(6) . . . . ?
C12 N1 C11 C2 -175.1(11) . . . . ?
Au2 N1 C11 C2 -0.8(19) . . . . ?
C13 O1 C11 N1 7.5(14) . . . . ?
C13 O1 C11 C2 -175.4(10) . . . . ?
C3 C2 C11 N1 151.9(13) . . . . ?
C1 C2 C11 N1 -30(2) . . . . ?
Fe1 C2 C11 N1 61.3(17) . . . . ?
C3 C2 C11 O1 -24.8(17) . . . . ?
C1 C2 C11 O1 152.8(10) . . . . ?
Fe1 C2 C11 O1 -115.4(9) . . . . ?
C11 N1 C12 C13 -9.6(12) . . . . ?
Au2 N1 C12 C13 176.3(7) . . . . ?
C11 N1 C12 C14 -137.6(11) . . . . ?
Au2 N1 C12 C14 48.3(12) . . . . ?
C11 O1 C13 C12 -12.7(10) . . . . ?
N1 C12 C13 O1 13.2(10) . . . . ?
C14 C12 C13 O1 137.7(9) . . . . ?
N1 C12 C14 C15 -176.5(9) . . . . ?
C13 C12 C14 C15 63.9(12) . . . . ?
N1 C12 C14 C16 56.7(11) . . . . ?
C13 C12 C14 C16 -62.9(12) . . . . ?
N1 Au2 C17 C21 130(9) . . . . ?
Cl2 Au2 C17 C21 34.4(9) . . . . ?
Au1 Au2 C17 C21 -143.6(9) . . . . ?
N1 Au2 C17 C18 -34(10) . . . . ?
Cl2 Au2 C17 C18 -129.3(8) . . . . ?
Au1 Au2 C17 C18 52.7(8) . . . . ?
N1 Au2 C17 Fe2 -128(9) . . . . ?
Cl2 Au2 C17 Fe2 136.5(8) . . . . ?
Au1 Au2 C17 Fe2 -41.6(8) . . . . ?
C18 Fe2 C17 C21 -118.9(9) . . . . ?
C19 Fe2 C17 C21 -81.0(7) . . . . ?
C20 Fe2 C17 C21 -36.9(6) . . . . ?
C22 Fe2 C17 C21 120.1(6) . . . . ?
C25 Fe2 C17 C21 40.6(13) . . . . ?
C26 Fe2 C17 C21 78.0(7) . . . . ?
C23 Fe2 C17 C21 162.1(6) . . . . ?
C24 Fe2 C17 C21 -160.6(12) . . . . ?
C19 Fe2 C17 C18 37.8(6) . . . . ?
C20 Fe2 C17 C18 82.0(6) . . . . ?
C21 Fe2 C17 C18 118.9(9) . . . . ?
C22 Fe2 C17 C18 -121.0(6) . . . . ?
C25 Fe2 C17 C18 159.5(10) . . . . ?
C26 Fe2 C17 C18 -163.1(6) . . . . ?
C23 Fe2 C17 C18 -79.0(7) . . . . ?
C24 Fe2 C17 C18 -41.7(15) . . . . ?
C18 Fe2 C17 Au2 117.0(11) . . . . ?
C19 Fe2 C17 Au2 154.8(10) . . . . ?
C20 Fe2 C17 Au2 -161.0(10) . . . . ?
C21 Fe2 C17 Au2 -124.1(11) . . . . ?
C22 Fe2 C17 Au2 -4.0(10) . . . . ?
C25 Fe2 C17 Au2 -83.5(14) . . . . ?
C26 Fe2 C17 Au2 -46.1(10) . . . . ?
C23 Fe2 C17 Au2 38.0(10) . . . . ?
C24 Fe2 C17 Au2 75.3(16) . . . . ?
C21 C17 C18 C27 172.0(10) . . . . ?
Au2 C17 C18 C27 -21.4(15) . . . . ?
Fe2 C17 C18 C27 113.3(11) . . . . ?
C21 C17 C18 C19 -0.7(12) . . . . ?
Au2 C17 C18 C19 165.9(7) . . . . ?
Fe2 C17 C18 C19 -59.4(7) . . . . ?
C21 C17 C18 Fe2 58.7(7) . . . . ?
Au2 C17 C18 Fe2 -134.7(7) . . . . ?
C19 Fe2 C18 C27 117.0(11) . . . . ?
C20 Fe2 C18 C27 155.6(9) . . . . ?
C21 Fe2 C18 C27 -159.8(9) . . . . ?
C22 Fe2 C18 C27 -42.9(10) . . . . ?
C25 Fe2 C18 C27 77.1(14) . . . . ?
C26 Fe2 C18 C27 -76.1(16) . . . . ?
C23 Fe2 C18 C27 -1.7(9) . . . . ?
C24 Fe2 C18 C27 41.8(10) . . . . ?
C17 Fe2 C18 C27 -123.4(11) . . . . ?
C20 Fe2 C18 C19 38.6(6) . . . . ?
C21 Fe2 C18 C19 83.1(7) . . . . ?
C22 Fe2 C18 C19 -160.0(6) . . . . ?
C25 Fe2 C18 C19 -39.9(14) . . . . ?
C26 Fe2 C18 C19 166.9(12) . . . . ?
C23 Fe2 C18 C19 -118.8(7) . . . . ?
C24 Fe2 C18 C19 -75.3(8) . . . . ?
C17 Fe2 C18 C19 119.6(9) . . . . ?
C19 Fe2 C18 C17 -119.6(9) . . . . ?
C20 Fe2 C18 C17 -81.0(6) . . . . ?
C21 Fe2 C18 C17 -36.5(6) . . . . ?
C22 Fe2 C18 C17 80.4(7) . . . . ?
C25 Fe2 C18 C17 -159.5(10) . . . . ?
C26 Fe2 C18 C17 47.3(16) . . . . ?
C23 Fe2 C18 C17 121.6(6) . . . . ?
C24 Fe2 C18 C17 165.1(6) . . . . ?
C27 C18 C19 C20 -172.8(9) . . . . ?
C17 C18 C19 C20 0.4(11) . . . . ?
Fe2 C18 C19 C20 -60.0(7) . . . . ?
C27 C18 C19 Fe2 -112.8(10) . . . . ?
C17 C18 C19 Fe2 60.4(7) . . . . ?
C18 Fe2 C19 C20 117.9(9) . . . . ?
C21 Fe2 C19 C20 38.3(5) . . . . ?
C22 Fe2 C19 C20 173.4(10) . . . . ?
C25 Fe2 C19 C20 -78.3(7) . . . . ?
C26 Fe2 C19 C20 -51.2(13) . . . . ?
C23 Fe2 C19 C20 -160.8(5) . . . . ?
C24 Fe2 C19 C20 -119.3(6) . . . . ?
C17 Fe2 C19 C20 79.9(6) . . . . ?
C20 Fe2 C19 C18 -117.9(9) . . . . ?
C21 Fe2 C19 C18 -79.6(6) . . . . ?
C22 Fe2 C19 C18 55.5(13) . . . . ?
C25 Fe2 C19 C18 163.8(6) . . . . ?
C26 Fe2 C19 C18 -169.1(10) . . . . ?
C23 Fe2 C19 C18 81.3(7) . . . . ?
C24 Fe2 C19 C18 122.8(6) . . . . ?
C17 Fe2 C19 C18 -38.0(6) . . . . ?
C18 C19 C20 C21 0.1(11) . . . . ?
Fe2 C19 C20 C21 -59.3(7) . . . . ?
C18 C19 C20 Fe2 59.4(7) . . . . ?
C18 Fe2 C20 C19 -38.9(6) . . . . ?
C21 Fe2 C20 C19 -118.7(8) . . . . ?
C22 Fe2 C20 C19 -173.9(9) . . . . ?
C25 Fe2 C20 C19 118.6(6) . . . . ?
C26 Fe2 C20 C19 158.8(5) . . . . ?
C23 Fe2 C20 C19 49.1(13) . . . . ?
C24 Fe2 C20 C19 78.0(7) . . . . ?
C17 Fe2 C20 C19 -83.8(6) . . . . ?
C18 Fe2 C20 C21 79.7(6) . . . . ?
C19 Fe2 C20 C21 118.7(8) . . . . ?
C22 Fe2 C20 C21 -55.2(12) . . . . ?
C25 Fe2 C20 C21 -122.8(6) . . . . ?
C26 Fe2 C20 C21 -82.6(7) . . . . ?
C23 Fe2 C20 C21 167.7(10) . . . . ?
C24 Fe2 C20 C21 -163.4(6) . . . . ?
C17 Fe2 C20 C21 34.8(6) . . . . ?
C18 C17 C21 C20 0.8(12) . . . . ?
Au2 C17 C21 C20 -165.2(7) . . . . ?
Fe2 C17 C21 C20 58.1(7) . . . . ?
C18 C17 C21 Fe2 -57.3(7) . . . . ?
Au2 C17 C21 Fe2 136.6(8) . . . . ?
C19 C20 C21 C17 -0.6(12) . . . . ?
Fe2 C20 C21 C17 -59.5(8) . . . . ?
C19 C20 C21 Fe2 59.0(7) . . . . ?
C18 Fe2 C21 C17 39.0(6) . . . . ?
C19 Fe2 C21 C17 83.9(6) . . . . ?
C20 Fe2 C21 C17 122.1(9) . . . . ?
C22 Fe2 C21 C17 -79.3(7) . . . . ?
C25 Fe2 C21 C17 -163.0(6) . . . . ?
C26 Fe2 C21 C17 -120.8(6) . . . . ?
C23 Fe2 C21 C17 -45.3(15) . . . . ?
C24 Fe2 C21 C17 163.3(11) . . . . ?
C18 Fe2 C21 C20 -83.1(6) . . . . ?
C19 Fe2 C21 C20 -38.2(6) . . . . ?
C22 Fe2 C21 C20 158.6(6) . . . . ?
C25 Fe2 C21 C20 74.9(7) . . . . ?
C26 Fe2 C21 C20 117.1(6) . . . . ?
C23 Fe2 C21 C20 -167.4(11) . . . . ?
C24 Fe2 C21 C20 41.2(15) . . . . ?
C17 Fe2 C21 C20 -122.1(9) . . . . ?
C18 Fe2 C22 C26 -163.7(6) . . . . ?
C19 Fe2 C22 C26 154.3(10) . . . . ?
C20 Fe2 C22 C26 -37.6(13) . . . . ?
C21 Fe2 C22 C26 -78.5(7) . . . . ?
C25 Fe2 C22 C26 36.9(6) . . . . ?
C23 Fe2 C22 C26 119.6(8) . . . . ?
C24 Fe2 C22 C26 80.6(6) . . . . ?
C17 Fe2 C22 C26 -119.5(6) . . . . ?
C18 Fe2 C22 C23 76.7(7) . . . . ?
C19 Fe2 C22 C23 34.8(14) . . . . ?
C20 Fe2 C22 C23 -157.2(9) . . . . ?
C21 Fe2 C22 C23 162.0(6) . . . . ?
C25 Fe2 C22 C23 -82.6(6) . . . . ?
C26 Fe2 C22 C23 -119.6(8) . . . . ?
C24 Fe2 C22 C23 -39.0(6) . . . . ?
C17 Fe2 C22 C23 121.0(6) . . . . ?
C26 C22 C23 C24 0.2(12) . . . . ?
Fe2 C22 C23 C24 59.9(7) . . . . ?
C26 C22 C23 Fe2 -59.8(7) . . . . ?
C18 Fe2 C23 C22 -122.8(6) . . . . ?
C19 Fe2 C23 C22 -166.7(5) . . . . ?
C20 Fe2 C23 C22 157.0(10) . . . . ?
C21 Fe2 C23 C22 -46.3(15) . . . . ?
C25 Fe2 C23 C22 80.6(6) . . . . ?
C26 Fe2 C23 C22 37.1(5) . . . . ?
C24 Fe2 C23 C22 118.1(9) . . . . ?
C17 Fe2 C23 C22 -79.2(7) . . . . ?
C18 Fe2 C23 C24 119.1(7) . . . . ?
C19 Fe2 C23 C24 75.3(8) . . . . ?
C20 Fe2 C23 C24 38.9(15) . . . . ?
C21 Fe2 C23 C24 -164.3(11) . . . . ?
C22 Fe2 C23 C24 -118.1(9) . . . . ?
C25 Fe2 C23 C24 -37.5(6) . . . . ?
C26 Fe2 C23 C24 -80.9(7) . . . . ?
C17 Fe2 C23 C24 162.8(6) . . . . ?
C22 C23 C24 C25 -1.0(11) . . . . ?
Fe2 C23 C24 C25 59.2(7) . . . . ?
C22 C23 C24 Fe2 -60.1(7) . . . . ?
C18 Fe2 C24 C25 160.3(6) . . . . ?
C19 Fe2 C24 C25 118.5(7) . . . . ?
C20 Fe2 C24 C25 76.6(8) . . . . ?
C21 Fe2 C24 C25 46.2(15) . . . . ?
C22 Fe2 C24 C25 -81.2(7) . . . . ?
C26 Fe2 C24 C25 -38.1(6) . . . . ?
C23 Fe2 C24 C25 -118.9(10) . . . . ?
C17 Fe2 C24 C25 -167.8(11) . . . . ?
C18 Fe2 C24 C23 -80.8(8) . . . . ?
C19 Fe2 C24 C23 -122.6(7) . . . . ?
C20 Fe2 C24 C23 -164.5(7) . . . . ?
C21 Fe2 C24 C23 165.1(11) . . . . ?
C22 Fe2 C24 C23 37.7(7) . . . . ?
C25 Fe2 C24 C23 118.9(10) . . . . ?
C26 Fe2 C24 C23 80.8(7) . . . . ?
C17 Fe2 C24 C23 -48.9(16) . . . . ?
C23 C24 C25 C26 1.4(12) . . . . ?
Fe2 C24 C25 C26 60.4(7) . . . . ?
C23 C24 C25 Fe2 -59.0(7) . . . . ?
C18 Fe2 C25 C26 -166.7(11) . . . . ?
C19 Fe2 C25 C26 163.8(7) . . . . ?
C20 Fe2 C25 C26 121.9(7) . . . . ?
C21 Fe2 C25 C26 80.6(7) . . . . ?
C22 Fe2 C25 C26 -36.6(6) . . . . ?
C23 Fe2 C25 C26 -79.7(7) . . . . ?
C24 Fe2 C25 C26 -118.1(9) . . . . ?
C17 Fe2 C25 C26 51.5(13) . . . . ?
C18 Fe2 C25 C24 -48.6(14) . . . . ?
C19 Fe2 C25 C24 -78.1(8) . . . . ?
C20 Fe2 C25 C24 -120.0(7) . . . . ?
C21 Fe2 C25 C24 -161.3(6) . . . . ?
C22 Fe2 C25 C24 81.5(7) . . . . ?
C26 Fe2 C25 C24 118.1(9) . . . . ?
C23 Fe2 C25 C24 38.4(7) . . . . ?
C17 Fe2 C25 C24 169.6(10) . . . . ?
C23 C22 C26 C25 0.7(12) . . . . ?
Fe2 C22 C26 C25 -59.1(8) . . . . ?
C23 C22 C26 Fe2 59.8(7) . . . . ?
C24 C25 C26 C22 -1.3(12) . . . . ?
Fe2 C25 C26 C22 59.2(7) . . . . ?
C24 C25 C26 Fe2 -60.6(7) . . . . ?
C18 Fe2 C26 C22 44.4(16) . . . . ?
C19 Fe2 C26 C22 -158.1(10) . . . . ?
C20 Fe2 C26 C22 164.7(6) . . . . ?
C21 Fe2 C26 C22 120.9(6) . . . . ?
C25 Fe2 C26 C22 -120.4(9) . . . . ?
C23 Fe2 C26 C22 -37.2(6) . . . . ?
C24 Fe2 C26 C22 -82.2(7) . . . . ?
C17 Fe2 C26 C22 80.4(7) . . . . ?
C18 Fe2 C26 C25 164.7(12) . . . . ?
C19 Fe2 C26 C25 -37.7(14) . . . . ?
C20 Fe2 C26 C25 -74.9(7) . . . . ?
C21 Fe2 C26 C25 -118.7(7) . . . . ?
C22 Fe2 C26 C25 120.4(9) . . . . ?
C23 Fe2 C26 C25 83.2(7) . . . . ?
C24 Fe2 C26 C25 38.2(6) . . . . ?
C17 Fe2 C26 C25 -159.2(6) . . . . ?
C28 N2 C27 O2 -8.2(11) . . . . ?
Au1 N2 C27 O2 166.3(6) . . . . ?
C28 N2 C27 C18 172.4(9) . . . . ?
Au1 N2 C27 C18 -13.2(14) . . . . ?
C29 O2 C27 N2 -6.7(10) . . . . ?
C29 O2 C27 C18 172.7(8) . . . . ?
C19 C18 C27 N2 159.9(10) . . . . ?
C17 C18 C27 N2 -11.9(17) . . . . ?
Fe2 C18 C27 N2 76.3(12) . . . . ?
C19 C18 C27 O2 -19.5(14) . . . . ?
C17 C18 C27 O2 168.7(9) . . . . ?
Fe2 C18 C27 O2 -103.1(9) . . . . ?
C27 N2 C28 C30 -103.8(9) . . . . ?
Au1 N2 C28 C30 81.7(9) . . . . ?
C27 N2 C28 C29 18.3(10) . . . . ?
Au1 N2 C28 C29 -156.2(6) . . . . ?
C27 O2 C29 C28 18.2(9) . . . . ?
N2 C28 C29 O2 -21.3(9) . . . . ?
C30 C28 C29 O2 96.5(10) . . . . ?
N2 C28 C30 C31 64.1(11) . . . . ?
C29 C28 C30 C31 -48.1(13) . . . . ?
N2 C28 C30 C32 -170.6(8) . . . . ?
C29 C28 C30 C32 77.2(10) . . . . ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        26.39
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.082
_refine_diff_density_min         -0.976
_refine_diff_density_rms         0.237
