# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_a150413c_sq
_database_code_depnum_ccdc_archive 'CCDC 1060012'
_audit_update_record             
;
2018-06-15 deposited with the CCDC.
2018-07-31 downloaded from the CCDC.
;
_audit_creation_date             2017-12-19
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C22.95 H16.25 Eu N0.65 O8'
_chemical_formula_sum            'C22.95 H16.25 Eu N0.65 O8'
_chemical_formula_weight         581.09
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   33.0877(8)
_cell_length_b                   13.6008(4)
_cell_length_c                   14.1080(3)
_cell_angle_alpha                90
_cell_angle_beta                 102.249(2)
_cell_angle_gamma                90
_cell_volume                     6204.3(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    6141
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      73.5590
_cell_measurement_theta_min      4.5630
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    14.779
_exptl_absorpt_correction_T_max  0.062
_exptl_absorpt_correction_T_min  0.01
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.32a (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.244
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2284
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0343
_diffrn_reflns_av_unetI/netI     0.0494
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.975
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            12348
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.975
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         73.630
_diffrn_reflns_theta_min         4.568
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, AtlasS2'
_diffrn_measurement_method       ?
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5179
_reflns_number_total             6260
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.426
_refine_diff_density_min         -0.771
_refine_diff_density_rms         0.093
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     312
_refine_ls_number_reflns         6102
_refine_ls_number_restraints     82
_refine_ls_R_factor_all          0.0472
_refine_ls_R_factor_gt           0.0399
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0597P)²+1.0603P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1019
_refine_ls_wR_factor_ref         0.1081
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Restrained distances
 N1-C22
 1.35 with sigma of 0.01
 N1-C24 = N1-C23
 1.5 with sigma of 0.01
 O8-C22
 1.25 with sigma of 0.01
 H8'A-O8'
 0.85 with sigma of 0.01
 O8'-H8'B
 0.85 with sigma of 0.01
 H8'A-H8'B
 1.37 with sigma of 0.001
 H8'B-O8'
 0.85 with sigma of 0.001
 C23-C22 \\sim C22-C24
 with sigma of 0.001
 H8'B-Eu1 \\sim Eu1-H8'A
 with sigma of 0.001
3. Uiso/Uaniso restraints and constraints
O8 \\sim N1 \\sim C22 \\sim C23 \\sim C24: within 2A with sigma of 0.005 and
sigma for terminal atoms of 0.01
Uanis(C20) \\sim Ueq, Uanis(C19) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(O8') \\sim Ueq, Uanis(O8) \\sim Ueq, Uanis(C22) \\sim Ueq, Uanis(N1)
\\sim Ueq, Uanis(C24) \\sim Ueq, Uanis(C23) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
Uanis(O8) = Uanis(O8')
4. Others
 Fixed Sof: O8(0.65) N1(0.65) C22(0.65) H22(0.65) C23(0.65) H23A(0.65)
 H23B(0.65) H23C(0.65) C24(0.65) H24A(0.65) H24B(0.65) H24C(0.65) O8'(0.35)
 H8'A(0.35) H8'B(0.35)
5.a Riding coordinates:
 O7(H7A,H7B), O8'(H8'A,H8'B)
5.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C6(H6), C10(H10), C11(H11), C13(H13), C14(H14), C16(H16),
 C17(H17), C19(H19), C20(H20), C22(H22)
5.c Idealised Me refined as rotating group:
 C23(H23A,H23B,H23C), C24(H24A,H24B,H24C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.19143(2) 0.29244(2) 0.45255(2) 0.02868(9) Uani 1 1 d D . . . .
O1 O 0.20684(9) 0.2439(3) 0.61941(19) 0.0366(6) Uani 1 1 d . . . . .
O2 O 0.26707(9) 0.1641(3) 0.6604(2) 0.0417(7) Uani 1 1 d . . . . .
O3 O 0.28716(9) -0.0597(2) 0.9511(2) 0.0427(7) Uani 1 1 d . . . . .
O4 O 0.23248(8) -0.1490(2) 0.9586(2) 0.0346(6) Uani 1 1 d . . . . .
O5 O -0.13763(9) 0.1704(3) 1.0180(2) 0.0455(8) Uani 1 1 d . . . . .
O6 O -0.12523(11) 0.3276(3) 1.0054(3) 0.0538(9) Uani 1 1 d . . . . .
O7 O 0.15890(12) 0.4329(4) 0.3556(3) 0.0703(13) Uani 1 1 d . . . . .
C1 C 0.15595(11) 0.0827(3) 0.8164(3) 0.0298(8) Uani 1 1 d . . . . .
C2 C 0.17297(12) 0.1372(3) 0.7501(3) 0.0297(8) Uani 1 1 d . . . . .
H2 H 0.1566 0.1832 0.7108 0.036 Uiso 1 1 calc R . . . .
C3 C 0.21377(12) 0.1242(3) 0.7417(3) 0.0311(8) Uani 1 1 d . . . . .
C4 C 0.23841(11) 0.0561(3) 0.8016(3) 0.0327(8) Uani 1 1 d . . . . .
H4 H 0.2660 0.0484 0.7984 0.039 Uiso 1 1 calc R . . . .
C5 C 0.22200(12) 0.0001(3) 0.8653(3) 0.0322(8) Uani 1 1 d . . . . .
C6 C 0.18058(12) 0.0114(3) 0.8723(3) 0.0319(8) Uani 1 1 d . . . . .
H6 H 0.1696 -0.0283 0.9141 0.038 Uiso 1 1 calc R . . . .
C7 C 0.23040(12) 0.1821(3) 0.6680(3) 0.0331(9) Uani 1 1 d . . . . .
C8 C 0.24887(12) -0.0746(3) 0.9282(3) 0.0342(9) Uani 1 1 d . . . . .
C9 C 0.11337(11) 0.1022(3) 0.8304(3) 0.0292(8) Uani 1 1 d . . . . .
C10 C 0.09709(13) 0.1952(3) 0.8175(3) 0.0375(9) Uani 1 1 d . . . . .
H10 H 0.1121 0.2448 0.7952 0.045 Uiso 1 1 calc R . . . .
C11 C 0.05841(14) 0.2169(4) 0.8373(4) 0.0413(10) Uani 1 1 d . . . . .
H11 H 0.0480 0.2804 0.8275 0.050 Uiso 1 1 calc R . . . .
C12 C 0.03545(12) 0.1452(3) 0.8713(3) 0.0335(9) Uani 1 1 d . . . . .
C13 C 0.05138(12) 0.0503(3) 0.8803(3) 0.0343(9) Uani 1 1 d . . . . .
H13 H 0.0360 0.0001 0.9003 0.041 Uiso 1 1 calc R . . . .
C14 C 0.08975(12) 0.0286(4) 0.8601(3) 0.0367(9) Uani 1 1 d . . . . .
H14 H 0.0997 -0.0355 0.8666 0.044 Uiso 1 1 calc R . . . .
C15 C -0.00403(12) 0.1694(4) 0.9005(3) 0.0361(9) Uani 1 1 d . . . . .
C16 C -0.03442(13) 0.0990(4) 0.8996(3) 0.0394(10) Uani 1 1 d . . . . .
H16 H -0.0307 0.0359 0.8775 0.047 Uiso 1 1 calc R . . . .
C17 C -0.07063(13) 0.1218(4) 0.9314(3) 0.0413(10) Uani 1 1 d . . . . .
H17 H -0.0905 0.0734 0.9315 0.050 Uiso 1 1 calc R . . . .
C18 C -0.07702(13) 0.2153(4) 0.9625(4) 0.0415(10) Uani 1 1 d . . . . .
C19 C -0.04692(19) 0.2847(5) 0.9618(6) 0.0683(18) Uani 1 1 d . U . . .
H19 H -0.0508 0.3483 0.9826 0.082 Uiso 1 1 calc R . . . .
C20 C -0.01099(18) 0.2627(5) 0.9310(6) 0.0671(17) Uani 1 1 d . U . . .
H20 H 0.0087 0.3115 0.9309 0.081 Uiso 1 1 calc R . . . .
C21 C -0.11590(13) 0.2386(4) 0.9970(3) 0.0389(10) Uani 1 1 d . . . . .
O8 O 0.1559(5) 0.2191(8) 0.3021(10) 0.0582(14) Uani 0.65 1 d D U P A 1
N1 N 0.1467(2) 0.1461(7) 0.1544(5) 0.0778(18) Uani 0.65 1 d D U P A 1
C22 C 0.1699(3) 0.1895(8) 0.2325(6) 0.0716(18) Uani 0.65 1 d D U P A 1
H22 H 0.1980 0.1979 0.2346 0.086 Uiso 0.65 1 calc R . P A 1
C23 C 0.1025(2) 0.1429(10) 0.1371(8) 0.088(3) Uani 0.65 1 d D U P A 1
H23A H 0.0941 0.0874 0.1702 0.132 Uiso 0.65 1 calc GR . P A 1
H23B H 0.0914 0.1368 0.0687 0.132 Uiso 0.65 1 calc GR . P A 1
H23C H 0.0924 0.2023 0.1607 0.132 Uiso 0.65 1 calc GR . P A 1
C24 C 0.1671(4) 0.0893(8) 0.0885(6) 0.089(3) Uani 0.65 1 d D U P A 1
H24A H 0.1965 0.0950 0.1095 0.133 Uiso 0.65 1 calc GR . P A 1
H24B H 0.1587 0.1147 0.0238 0.133 Uiso 0.65 1 calc GR . P A 1
H24C H 0.1592 0.0215 0.0893 0.133 Uiso 0.65 1 calc GR . P A 1
O8' O 0.1572(10) 0.2342(15) 0.291(2) 0.0582(14) Uani 0.35 1 d D U P A 2
H8'A H 0.1364 0.1950 0.2794 0.087 Uiso 0.35 1 d DR . P A 2
H8'B H 0.1578 0.2629 0.2377 0.087 Uiso 0.35 1 d DR . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.393(3) . ?
Eu1 O2 2.388(3) 7_556 ?
Eu1 O3 2.447(3) 4_556 ?
Eu1 O4 2.684(3) 4_556 ?
Eu1 O4 2.368(3) 6 ?
Eu1 O5 2.531(3) 2_556 ?
Eu1 O6 2.435(3) 2_556 ?
Eu1 O7 2.461(4) . ?
Eu1 C8 2.932(4) 4_556 ?
Eu1 C21 2.836(4) 2_556 ?
Eu1 O8 2.413(15) . ?
Eu1 O8' 2.45(3) . ?
O1 C7 1.248(6) . ?
O2 Eu1 2.388(3) 7_556 ?
O2 C7 1.265(5) . ?
O3 Eu1 2.447(3) 4_546 ?
O3 C8 1.256(5) . ?
O4 Eu1 2.684(3) 4_546 ?
O4 Eu1 2.368(3) 6_556 ?
O4 C8 1.266(5) . ?
O5 Eu1 2.531(3) 2_556 ?
O5 C21 1.247(6) . ?
O6 Eu1 2.435(3) 2_556 ?
O6 C21 1.261(6) . ?
C1 C2 1.401(5) . ?
C1 C6 1.398(6) . ?
C1 C9 1.488(5) . ?
C2 H2 0.9300 . ?
C2 C3 1.391(5) . ?
C3 C4 1.394(6) . ?
C3 C7 1.500(5) . ?
C4 H4 0.9300 . ?
C4 C5 1.375(6) . ?
C5 C6 1.403(5) . ?
C5 C8 1.508(6) . ?
C6 H6 0.9300 . ?
C8 Eu1 2.932(4) 4_546 ?
C9 C10 1.372(6) . ?
C9 C14 1.388(6) . ?
C10 H10 0.9300 . ?
C10 C11 1.398(6) . ?
C11 H11 0.9300 . ?
C11 C12 1.383(6) . ?
C12 C13 1.390(6) . ?
C12 C15 1.488(5) . ?
C13 H13 0.9300 . ?
C13 C14 1.390(5) . ?
C14 H14 0.9300 . ?
C15 C16 1.387(7) . ?
C15 C20 1.374(8) . ?
C16 H16 0.9300 . ?
C16 C17 1.400(6) . ?
C17 H17 0.9300 . ?
C17 C18 1.376(7) . ?
C18 C19 1.374(8) . ?
C18 C21 1.503(5) . ?
C19 H19 0.9300 . ?
C19 C20 1.382(7) . ?
C20 H20 0.9300 . ?
C21 Eu1 2.836(4) 2_556 ?
O8 C22 1.238(9) . ?
N1 C22 1.340(8) . ?
N1 C23 1.430(8) . ?
N1 C24 1.476(8) . ?
C22 H22 0.9300 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
O8' H8'A 0.8581 . ?
O8' H8'B 0.8504 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O3 72.78(12) . 4_556 ?
O1 Eu1 O4 68.85(9) . 4_556 ?
O1 Eu1 O5 70.65(11) . 2_556 ?
O1 Eu1 O6 80.19(12) . 2_556 ?
O1 Eu1 O7 137.54(14) . . ?
O1 Eu1 C8 68.18(11) . 4_556 ?
O1 Eu1 C21 72.38(12) . 2_556 ?
O1 Eu1 O8 135.5(2) . . ?
O1 Eu1 O8' 141.8(3) . . ?
O2 Eu1 O1 133.78(10) 7_556 . ?
O2 Eu1 O3 91.58(11) 7_556 4_556 ?
O2 Eu1 O4 67.86(9) 7_556 4_556 ?
O2 Eu1 O5 142.70(11) 7_556 2_556 ?
O2 Eu1 O6 142.01(13) 7_556 2_556 ?
O2 Eu1 O7 71.48(12) 7_556 . ?
O2 Eu1 C8 79.49(11) 7_556 4_556 ?
O2 Eu1 C21 153.30(12) 7_556 2_556 ?
O2 Eu1 O8 75.9(2) 7_556 . ?
O2 Eu1 O8' 71.1(3) 7_556 . ?
O3 Eu1 O4 50.53(9) 4_556 4_556 ?
O3 Eu1 O5 125.36(10) 4_556 2_556 ?
O3 Eu1 O7 73.24(15) 4_556 . ?
O3 Eu1 C8 24.98(11) 4_556 4_556 ?
O3 Eu1 C21 103.86(12) 4_556 2_556 ?
O3 Eu1 O8' 143.5(6) 4_556 . ?
O4 Eu1 O1 74.74(11) 6 . ?
O4 Eu1 O2 79.69(11) 6 7_556 ?
O4 Eu1 O3 124.12(10) 6 4_556 ?
O4 Eu1 O4 75.73(10) 6 4_556 ?
O4 Eu1 O5 82.65(10) 6 2_556 ?
O4 Eu1 O6 133.78(11) 6 2_556 ?
O4 Eu1 O7 147.06(12) 6 . ?
O4 Eu1 C8 25.56(11) 4_556 4_556 ?
O4 Eu1 C8 100.14(11) 6 4_556 ?
O4 Eu1 C21 107.91(12) 6 2_556 ?
O4 Eu1 C21 138.46(11) 4_556 2_556 ?
O4 Eu1 O8 81.9(4) 6 . ?
O4 Eu1 O8' 85.2(8) 6 . ?
O5 Eu1 O4 137.76(11) 2_556 4_556 ?
O5 Eu1 C8 136.21(11) 2_556 4_556 ?
O5 Eu1 C21 26.08(13) 2_556 2_556 ?
O6 Eu1 O3 82.68(12) 2_556 4_556 ?
O6 Eu1 O4 129.12(12) 2_556 4_556 ?
O6 Eu1 O5 52.32(11) 2_556 2_556 ?
O6 Eu1 O7 70.91(13) 2_556 . ?
O6 Eu1 C8 105.68(13) 2_556 4_556 ?
O6 Eu1 C21 26.31(14) 2_556 2_556 ?
O6 Eu1 O8' 91.6(7) 2_556 . ?
O7 Eu1 O4 106.60(13) . 4_556 ?
O7 Eu1 O5 111.12(14) . 2_556 ?
O7 Eu1 C8 90.13(15) . 4_556 ?
O7 Eu1 C21 92.02(14) . 2_556 ?
C21 Eu1 C8 122.52(12) 2_556 4_556 ?
O8 Eu1 O3 149.1(3) . 4_556 ?
O8 Eu1 O4 140.1(3) . 4_556 ?
O8 Eu1 O5 69.21(17) . 2_556 ?
O8 Eu1 O6 90.0(4) . 2_556 ?
O8 Eu1 O7 76.0(4) . . ?
O8 Eu1 C8 154.56(16) . 4_556 ?
O8 Eu1 C21 79.8(3) . 2_556 ?
O8' Eu1 O4 137.1(5) . 4_556 ?
O8' Eu1 O5 74.85(13) . 2_556 ?
O8' Eu1 O7 70.9(7) . . ?
O8' Eu1 C8 148.76(10) . 4_556 ?
O8' Eu1 C21 83.8(4) . 2_556 ?
C7 O1 Eu1 134.7(3) . . ?
C7 O2 Eu1 134.9(3) . 7_556 ?
C8 O3 Eu1 99.7(3) . 4_546 ?
Eu1 O4 Eu1 104.27(10) 6_556 4_546 ?
C8 O4 Eu1 88.2(2) . 4_546 ?
C8 O4 Eu1 158.5(3) . 6_556 ?
C21 O5 Eu1 90.7(3) . 2_556 ?
C21 O6 Eu1 94.9(3) . 2_556 ?
C2 C1 C9 121.3(3) . . ?
C6 C1 C2 118.3(3) . . ?
C6 C1 C9 120.3(3) . . ?
C1 C2 H2 119.2 . . ?
C3 C2 C1 121.6(4) . . ?
C3 C2 H2 119.2 . . ?
C2 C3 C4 119.1(4) . . ?
C2 C3 C7 119.9(4) . . ?
C4 C3 C7 121.1(3) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 C3 120.2(3) . . ?
C5 C4 H4 119.9 . . ?
C4 C5 C6 120.8(4) . . ?
C4 C5 C8 119.5(3) . . ?
C6 C5 C8 119.7(4) . . ?
C1 C6 C5 119.8(4) . . ?
C1 C6 H6 120.1 . . ?
C5 C6 H6 120.1 . . ?
O1 C7 O2 125.7(4) . . ?
O1 C7 C3 117.2(4) . . ?
O2 C7 C3 117.2(4) . . ?
O3 C8 Eu1 55.4(2) . 4_546 ?
O3 C8 O4 121.6(4) . . ?
O3 C8 C5 118.7(4) . . ?
O4 C8 Eu1 66.2(2) . 4_546 ?
O4 C8 C5 119.8(4) . . ?
C5 C8 Eu1 174.0(3) . 4_546 ?
C10 C9 C1 120.2(4) . . ?
C10 C9 C14 118.3(4) . . ?
C14 C9 C1 121.4(4) . . ?
C9 C10 H10 119.4 . . ?
C9 C10 C11 121.2(4) . . ?
C11 C10 H10 119.4 . . ?
C10 C11 H11 119.5 . . ?
C12 C11 C10 121.0(4) . . ?
C12 C11 H11 119.5 . . ?
C11 C12 C13 117.4(4) . . ?
C11 C12 C15 121.3(4) . . ?
C13 C12 C15 121.3(4) . . ?
C12 C13 H13 119.2 . . ?
C12 C13 C14 121.6(4) . . ?
C14 C13 H13 119.2 . . ?
C9 C14 C13 120.4(4) . . ?
C9 C14 H14 119.8 . . ?
C13 C14 H14 119.8 . . ?
C16 C15 C12 121.4(4) . . ?
C20 C15 C12 120.4(4) . . ?
C20 C15 C16 118.1(4) . . ?
C15 C16 H16 119.6 . . ?
C15 C16 C17 120.8(5) . . ?
C17 C16 H16 119.6 . . ?
C16 C17 H17 119.8 . . ?
C18 C17 C16 120.4(5) . . ?
C18 C17 H17 119.8 . . ?
C17 C18 C21 119.9(4) . . ?
C19 C18 C17 118.2(4) . . ?
C19 C18 C21 121.9(5) . . ?
C18 C19 H19 119.1 . . ?
C18 C19 C20 121.7(5) . . ?
C20 C19 H19 119.1 . . ?
C15 C20 C19 120.7(5) . . ?
C15 C20 H20 119.6 . . ?
C19 C20 H20 119.6 . . ?
O5 C21 Eu1 63.2(2) . 2_556 ?
O5 C21 O6 121.8(4) . . ?
O5 C21 C18 119.8(4) . . ?
O6 C21 Eu1 58.8(2) . 2_556 ?
O6 C21 C18 118.5(4) . . ?
C18 C21 Eu1 175.0(3) . 2_556 ?
C22 O8 Eu1 129.6(11) . . ?
C22 N1 C23 122.7(6) . . ?
C22 N1 C24 119.3(6) . . ?
C23 N1 C24 117.6(8) . . ?
O8 C22 N1 123.3(10) . . ?
O8 C22 H22 118.3 . . ?
N1 C22 H22 118.3 . . ?
N1 C23 H23A 109.5 . . ?
N1 C23 H23B 109.5 . . ?
N1 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N1 C24 H24A 109.5 . . ?
N1 C24 H24B 109.5 . . ?
N1 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Eu1 O8' H8'A 124.8 . . ?
Eu1 O8' H8'B 125.4 . . ?
H8'A O8' H8'B 106.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C7 O2 41.6(7) . . . . ?
Eu1 O1 C7 C3 -138.4(3) . . . . ?
Eu1 O2 C7 O1 -11.1(7) 7_556 . . . ?
Eu1 O2 C7 C3 168.9(3) 7_556 . . . ?
Eu1 O3 C8 O4 2.5(4) 4_546 . . . ?
Eu1 O3 C8 C5 -179.3(3) 4_546 . . . ?
Eu1 O4 C8 Eu1 -126.4(7) 6_556 . . 4_546 ?
Eu1 O4 C8 O3 -128.7(6) 6_556 . . . ?
Eu1 O4 C8 O3 -2.3(4) 4_546 . . . ?
Eu1 O4 C8 C5 179.6(3) 4_546 . . . ?
Eu1 O4 C8 C5 53.2(9) 6_556 . . . ?
Eu1 O5 C21 O6 5.7(5) 2_556 . . . ?
Eu1 O5 C21 C18 -175.5(4) 2_556 . . . ?
Eu1 O6 C21 O5 -5.9(5) 2_556 . . . ?
Eu1 O6 C21 C18 175.2(4) 2_556 . . . ?
Eu1 O8 C22 N1 177.0(8) . . . . ?
C1 C2 C3 C4 -0.7(6) . . . . ?
C1 C2 C3 C7 178.3(4) . . . . ?
C1 C9 C10 C11 -175.1(4) . . . . ?
C1 C9 C14 C13 174.8(4) . . . . ?
C2 C1 C6 C5 3.7(6) . . . . ?
C2 C1 C9 C10 -30.5(6) . . . . ?
C2 C1 C9 C14 152.0(4) . . . . ?
C2 C3 C4 C5 2.4(6) . . . . ?
C2 C3 C7 O1 3.2(6) . . . . ?
C2 C3 C7 O2 -176.8(4) . . . . ?
C3 C4 C5 C6 -1.0(6) . . . . ?
C3 C4 C5 C8 178.9(4) . . . . ?
C4 C3 C7 O1 -177.7(4) . . . . ?
C4 C3 C7 O2 2.2(6) . . . . ?
C4 C5 C6 C1 -2.1(6) . . . . ?
C4 C5 C8 O3 28.1(6) . . . . ?
C4 C5 C8 O4 -153.7(4) . . . . ?
C6 C1 C2 C3 -2.3(6) . . . . ?
C6 C1 C9 C10 147.0(4) . . . . ?
C6 C1 C9 C14 -30.5(6) . . . . ?
C6 C5 C8 O3 -152.0(4) . . . . ?
C6 C5 C8 O4 26.1(6) . . . . ?
C7 C3 C4 C5 -176.7(4) . . . . ?
C8 C5 C6 C1 178.0(4) . . . . ?
C9 C1 C2 C3 175.2(4) . . . . ?
C9 C1 C6 C5 -173.9(4) . . . . ?
C9 C10 C11 C12 0.5(7) . . . . ?
C10 C9 C14 C13 -2.8(6) . . . . ?
C10 C11 C12 C13 -3.1(7) . . . . ?
C10 C11 C12 C15 174.7(4) . . . . ?
C11 C12 C13 C14 2.8(6) . . . . ?
C11 C12 C15 C16 155.5(4) . . . . ?
C11 C12 C15 C20 -25.7(7) . . . . ?
C12 C13 C14 C9 0.1(7) . . . . ?
C12 C15 C16 C17 177.1(4) . . . . ?
C12 C15 C20 C19 -177.5(6) . . . . ?
C13 C12 C15 C16 -26.7(6) . . . . ?
C13 C12 C15 C20 152.1(6) . . . . ?
C14 C9 C10 C11 2.5(7) . . . . ?
C15 C12 C13 C14 -175.1(4) . . . . ?
C15 C16 C17 C18 1.3(7) . . . . ?
C16 C15 C20 C19 1.4(10) . . . . ?
C16 C17 C18 C19 -0.4(8) . . . . ?
C16 C17 C18 C21 -179.6(4) . . . . ?
C17 C18 C19 C20 0.0(11) . . . . ?
C17 C18 C21 O5 16.0(7) . . . . ?
C17 C18 C21 O6 -165.2(5) . . . . ?
C18 C19 C20 C15 -0.5(12) . . . . ?
C19 C18 C21 O5 -163.3(6) . . . . ?
C19 C18 C21 O6 15.6(8) . . . . ?
C20 C15 C16 C17 -1.8(7) . . . . ?
C21 C18 C19 C20 179.2(7) . . . . ?
C23 N1 C22 O8 9.7(19) . . . . ?
C24 N1 C22 O8 -163.2(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
